#DEFINITION	Reference Metabolome for Castanea crenata
#IDENTTFIER	RefMeta-Castanea crenata.R1
#FORMAT	msr
#VERSION	1.0/R1
#KEYWORDS	RefMeta
#ORGANISM	Castanea crenata
#CREATION	31-MAY-2024
#PUBLICATION	CropMetabolome: a comprehensive metabolome database for major crops cross eight categories
#JOURNAL	The Plant Journal
#AUTHORS	Shi H, Wu X, Zhu Y, Chen P, Xu X, and Li X.
#COMMENT	Reference metabolome for Castanea crenata was generated from multi-tissue LC-MS/MS data with redundance removed
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.1343
Annotation	Dihydrokanakugiol
Peak:m/z	Relative Intensity
151.2069397	0.02
185.0808411	0.05
195.2117615	0.05
199.2603302	0.02
201.1448517	0.10
220.1944885	0.11
220.9513550	0.04
237.4637756	0.04
239.1818848	14.03
240.3753967	0.02
241.2709656	0.04
245.3200684	0.07
249.2961426	0.05
253.2575073	0.02
255.6624146	0.16
257.1629639	100.00
259.3247681	0.03
265.2065125	0.32
283.1632690	10.71
287.0319519	0.08
291.2736206	0.08
299.0781250	0.07
301.0971069	43.84
301.7620544	0.15
303.3785400	0.16
309.2708435	0.51
311.3782043	0.03
314.9449463	0.18
317.2729187	0.03
327.1750488	1.94
328.1351318	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	535.2006
Annotation	Isosyringinoside
Peak:m/z	Relative Intensity
160.1533966	0.13
161.0993042	0.76
168.9702759	0.06
170.0705109	1.21
175.3168640	0.06
179.0311127	8.13
190.1241913	0.05
193.0983276	2.47
203.1829987	0.39
210.9919128	31.21
211.6334076	0.48
223.3701019	0.04
244.2507324	0.09
319.2609863	0.04
341.2914429	1.03
355.4298706	0.65
359.9828491	0.21
361.4088745	0.27
369.5225220	0.25
373.0707397	100.00
373.6744995	0.51
374.6047974	0.33
396.7969360	0.10
405.3720093	0.16
416.1257324	0.12
433.8839722	0.42
435.4284668	0.20
445.9216309	0.06
455.3087769	0.11
464.3808594	0.34
469.4127808	1.35
489.2273560	0.14
491.2893066	0.27
499.4906006	0.63
517.2730103	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1301
Annotation	O-Acetylgeniposidic acid
Peak:m/z	Relative Intensity
138.0506897	0.07
143.0468750	0.05
152.9843903	0.39
168.8964691	0.12
170.9622498	0.12
181.1159668	0.04
182.0065918	0.17
183.0274658	1.51
185.9275513	0.03
188.9393768	0.33
197.0997925	8.50
211.0567627	0.07
231.0661621	0.36
233.8265533	0.04
239.1753387	0.66
242.2566223	0.12
249.1092529	0.38
253.0587158	0.82
257.0278625	20.80
263.1871643	20.08
271.1839294	5.31
281.1503601	6.58
285.1690674	3.63
288.2680054	0.05
298.0562744	0.06
299.2045593	1.28
306.9550781	0.13
336.9787903	0.08
339.3608398	0.10
341.4432068	0.15
351.2781982	0.07
369.1823120	0.03
370.0647888	0.16
379.1447144	0.02
385.2399597	15.50
397.1358337	0.25
411.1799927	0.11
414.2716064	0.13
415.1520996	1.24
417.2027283	1.39
425.0540161	0.14
427.4414978	0.19
429.1783447	100.00
430.3943176	0.09
446.5091248	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
129.1992035	0.40
138.9866791	0.17
149.0403748	0.99
169.0274353	0.40
171.1235504	0.29
173.2573853	0.69
183.1290283	0.16
185.1325684	0.93
187.2105713	0.17
189.0179138	0.47
198.9625854	0.18
201.2159424	1.34
211.2989044	0.61
213.1305237	1.20
215.0313721	1.16
227.1488037	0.37
229.0203552	0.54
231.2369385	0.92
235.2049561	0.38
239.21698	0.82
241.3510437	0.80
243.3738098	0.95
245.1690369	0.74
255.1770935	0.55
257.3477173	0.30
259.2457581	0.60
261.3261108	0.16
263.4167786	1.02
267.268219	1.23
268.1609497	0.20
269.2469788	1.09
271.3211365	1.58
273.2938232	1.19
283.3027649	0.29
285.3847656	3.93
287.3248291	0.18
289.1819458	0.33
295.2294617	2.43
297.2524109	1.31
299.0010986	0.41
301.0965881	0.27
303.1773071	0.35
311.1596985	3.80
313.2443848	3.23
314.0805054	0.59
315.5700684	0.57
321.366333	1.74
322.1497192	0.46
323.3830566	11.20
325.4519043	0.21
327.5655212	0.35
329.1706543	2.06
337.1226807	0.57
339.24823	100.00
339.8562927	1.48
341.2887268	13.86
342.2414246	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	587.91
Annotation	Unknow
Peak:m/z	Relative Intensity
230.1285706	0.10
273.0706482	1.87
274.0412598	1.27
274.9643555	0.16
359.0379639	0.39
360.1810913	0.12
367.2968750	0.14
387.0190430	0.57
388.1268921	0.22
408.0298462	0.18
426.9492798	3.20
428.0284424	6.10
429.1415405	0.27
430.2791748	0.17
473.1773071	1.67
473.9567871	1.56
486.1807251	0.52
498.0695801	0.71
500.8684692	0.23
503.2389526	0.28
505.2622681	0.16
514.9899292	0.38
516.0172729	0.14
525.6903687	0.31
532.0494995	0.14
541.2321167	12.67
541.9453125	100.00
543.8015137	0.24
560.7996826	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.2029
Annotation	3-[4-[1-(4-Hydroxy-3-methoxyphenyl)-1,3-dihydroxyisopropoxy]-2-hydroxyphenyl]propyl alpha-L-rhamnopyranoside
Peak:m/z	Relative Intensity
148.9302673	0.29
158.9300385	0.30
160.9907990	4.07
178.1800232	0.20
178.9754944	0.62
213.1249695	0.47
221.1986389	1.89
223.1159363	80.26
238.8743439	1.35
240.9331360	8.37
259.1504517	5.27
267.1119385	10.58
285.1438599	8.29
301.1431885	0.33
303.3456421	0.12
318.9508057	3.81
329.1530762	100.00
343.1593628	0.32
347.2216187	3.13
389.1826782	0.25
403.3127441	0.60
421.3772583	7.86
437.2740479	0.20
447.3774414	0.38
465.2662964	94.82
490.7642212	0.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.92
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9908905	2.46
159.9683990	1.23
199.0657043	0.57
200.0305786	0.35
217.0736389	0.12
228.9891052	0.55
230.0498657	0.58
238.2014008	0.07
272.9379578	37.25
274.0122375	38.93
387.0206909	45.38
388.0335693	100.00
411.8402100	0.06
427.8286438	0.07
456.0307007	0.05
483.3007202	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	495.2574
Annotation	Cuniloside
Peak:m/z	Relative Intensity
144.4446869	0.27
145.1522522	0.18
146.2573547	0.28
156.8934174	0.69
158.7277527	0.05
161.0755463	0.36
162.8253326	0.18
169.2398071	0.15
170.2753296	0.06
173.3288116	0.27
175.1602325	0.21
177.0542603	0.10
183.1412964	0.13
184.8020935	0.05
187.1357727	0.06
191.2407684	0.05
193.2059174	0.10
195.3210144	0.07
197.3201904	0.10
199.1730347	0.09
201.1279907	0.11
205.0455322	0.10
209.3837891	0.07
213.1437073	0.26
218.8942566	0.22
223.2017212	0.10
225.2871094	0.12
226.8855286	0.18
228.9486694	0.11
231.2100830	0.71
233.0343170	0.04
241.2352753	4.04
243.2480774	2.28
251.2529449	3.09
253.3161621	0.67
255.3024292	0.28
259.0119629	0.43
269.2154541	11.84
271.3894653	0.22
272.3213806	0.09
273.0664978	0.11
279.0310974	0.13
285.1880188	0.31
287.1793213	8.95
289.2834167	0.13
293.4634399	0.05
297.0968628	4.34
303.0928345	0.15
305.1320801	0.59
307.0346069	0.08
311.2147217	0.04
313.0463257	0.18
315.1809692	20.18
316.2868042	0.13
317.3248291	2.00
325.4288635	0.43
326.0756836	0.37
331.1790771	0.31
333.2127686	7.97
334.4723816	0.18
342.2129822	0.20
343.4553223	0.10
347.2327881	0.12
348.0060425	0.27
353.2000427	0.54
356.8922729	0.52
358.4445496	0.12
359.2145996	0.24
361.2905884	0.17
363.2288818	0.18
366.2821350	0.05
369.9427185	0.30
372.4429321	0.11
376.9945068	0.35
381.2792664	0.61
382.2818909	0.36
387.4241638	0.94
389.3015442	0.12
393.4697266	0.23
395.2804871	0.30
397.4456787	0.05
402.7254333	2.45
403.4612122	1.14
405.4839172	1.31
406.4919128	0.18
409.3397827	0.77
411.4217529	0.66
413.2148743	1.26
415.3702698	0.31
416.0101013	0.10
421.3933411	0.53
423.1969604	0.58
425.0225830	0.06
430.7566223	0.46
431.3682556	6.21
433.3264771	0.28
441.2676086	0.27
444.9975891	0.43
446.7604675	0.17
448.5141907	6.47
449.2384949	100.00
450.6288147	0.29
452.6571655	0.42
458.6539001	0.50
459.2896423	5.02
463.8594055	0.11
467.0143127	0.41
477.2164612	9.31
478.1343689	0.09
492.2939758	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	561.2972
Annotation	Unknow
Peak:m/z	Relative Intensity
195.8875427	2.16
206.8624268	0.10
213.0129852	14.34
222.9998474	0.82
275.1919556	0.38
293.1516724	0.08
296.3812866	0.11
307.1043091	0.33
308.7841797	0.42
313.7393799	0.22
355.4399414	0.25
387.0186768	100.00
387.6816406	0.43
390.9277344	1.58
392.3008423	0.82
392.9655762	4.58
406.1495972	5.66
409.5761719	0.58
415.5352173	0.06
424.3255005	0.35
426.1254883	0.31
449.1450195	0.09
455.1459351	0.10
468.7753296	0.04
475.2628784	0.12
476.3277588	0.97
477.0384521	2.67
493.1474609	0.08
500.9705200	0.29
513.6818237	0.09
514.4703979	0.11
515.0895386	1.62
516.1326904	0.05
526.4417725	0.10
541.2205200	0.09
543.4058838	0.10
544.0261841	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	227.1272
Annotation	1-Acetoxy-7-hydroxy-3,7-dimethyl-2E,5E-octadien-4-one
Peak:m/z	Relative Intensity
65.0536346	0.04
66.9140930	0.96
70.8985214	0.08
84.9416199	10.18
86.1111755	0.02
98.9137878	0.48
100.1470947	0.13
110.9278412	0.33
115.1511383	0.04
116.7823029	0.02
119.0276184	0.46
121.0452271	0.25
125.0428009	0.13
127.0070953	0.15
129.1147461	0.08
131.0628510	1.34
135.0988464	0.17
138.6688690	0.02
141.0893707	0.02
143.0050812	1.30
145.0684357	2.17
147.0897980	0.17
148.8673859	1.10
154.8363495	0.07
163.0552521	1.91
165.0514679	0.28
167.0792084	4.20
168.9289551	0.05
173.0482635	0.17
179.2058716	0.28
181.1384125	0.11
183.2240906	0.13
191.0495300	41.63
197.1019592	0.26
205.3940582	0.01
209.0597382	100.00
229.6521454	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.2
Annotation	Abelioside A
Peak:m/z	Relative Intensity
176.8357239	0.06
190.2431183	0.09
201.0764465	0.36
237.4673767	0.10
245.0169220	0.26
255.0894318	0.05
256.8894043	0.05
264.9229736	0.09
273.3854370	0.07
275.1707153	0.23
289.1659546	0.10
301.1641235	0.38
317.1213989	0.75
319.3665771	1.14
334.3425903	0.04
345.1772461	2.20
347.3864746	0.33
363.2063599	100.00
364.2229614	0.13
368.5833740	0.09
377.1951294	0.95
395.5625610	0.04
403.3449097	0.06
405.2524414	22.14
417.2969360	0.05
427.2314453	0.24
431.4905396	0.25
435.2535400	10.03
447.5086670	0.19
463.5097046	0.05
465.1885376	69.79
479.3042603	3.35
481.3543091	1.27
495.4994507	0.12
507.2326050	6.68
508.0835571	0.08
508.7139282	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.1721
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9176025	0.14
161.0665436	3.39
176.8393707	0.39
177.9284668	0.10
178.9748993	100.00
191.1649170	0.46
194.9847107	0.20
209.1500854	13.07
241.8878784	0.08
265.2143555	0.12
267.0098877	0.53
285.0346680	0.16
296.1981201	0.24
302.9666138	0.07
304.9566040	0.10
311.1961060	1.57
329.0894775	0.83
329.7856445	0.35
340.9837036	0.40
342.0223389	0.08
347.8486328	0.12
350.0938721	0.17
356.0799561	0.08
369.8801880	0.16
383.0902100	0.14
391.8475342	0.15
400.2905884	0.33
407.4874268	0.19
415.1236572	0.59
429.0868530	0.10
431.1049194	0.16
436.3114014	0.14
437.2361450	0.34
461.1463013	0.06
475.5168457	0.29
476.6823120	0.07
483.3339844	0.32
484.6534424	0.28
488.6887817	0.13
502.8555298	0.63
503.6001587	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
102.9786835	0.11
105.0421143	0.19
108.7926178	0.21
120.9192352	0.10
124.9326324	0.39
127.0279846	0.20
139.0524597	0.58
146.2161102	0.98
157.1085205	0.25
161.1087799	1.07
176.9616547	0.09
179.0109711	0.72
179.9676056	0.35
181.0815582	0.37
182.1305542	0.08
183.1771545	0.34
185.091507	0.09
189.451355	0.21
192.2394562	0.19
193.307312	0.16
195.2329559	0.66
205.941452	0.11
207.0069733	4.92
208.2905121	2.46
209.1645508	3.26
210.9061584	0.46
222.022934	2.19
223.246521	5.63
233.2050781	2.05
235.2775269	0.69
251.081604	100.00
252.1186066	16.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	643.3049
Annotation	Unknow
Peak:m/z	Relative Intensity
191.1089172	0.09
195.2866974	0.09
197.2658386	0.26
201.0243225	0.07
207.2796021	1.02
211.1913300	0.14
213.0464325	0.08
219.0217896	0.14
221.9948120	0.08
225.3651428	0.09
227.0084229	0.10
234.1806946	0.98
235.0788727	1.97
239.4452209	0.27
241.4217987	0.19
251.0596008	0.25
253.2370605	0.04
255.2106934	0.06
257.1111450	0.16
262.1121521	0.49
267.2649536	0.21
269.1672974	0.56
275.1929321	0.38
279.1785278	52.67
283.3081970	0.19
285.1954651	2.16
287.2352295	0.57
303.5541382	0.30
304.8512573	0.27
308.0380249	0.07
312.7933655	0.44
313.5025635	0.69
314.9179382	0.36
323.2599487	0.17
330.3066101	0.55
331.1459351	1.87
336.2159424	0.32
338.1898804	0.07
349.5073242	0.21
356.2019653	1.50
356.8193970	0.18
376.9548340	0.06
381.8196411	0.79
382.4592285	2.80
391.1256714	0.07
392.0385742	0.24
393.2243652	0.88
397.1554565	0.08
399.2481689	4.02
400.2101440	0.86
409.3413086	1.82
410.1964111	2.31
411.1015015	0.12
412.4625244	0.49
417.2061768	0.42
418.4472046	0.32
427.2414551	14.06
428.2953491	31.63
429.5162964	0.28
431.1394653	0.21
435.1937866	0.31
445.2122192	100.00
446.1682129	2.85
447.3859253	0.43
448.7575073	0.42
463.3087158	31.89
465.4543457	0.29
467.1784058	0.14
470.2379761	0.13
478.3355103	0.05
481.2238159	0.42
482.5603638	0.30
485.2527466	0.32
487.2271729	0.28
491.8748169	0.05
493.3284302	0.31
494.2037354	0.65
502.2510986	0.17
510.2675781	0.08
511.5507812	0.13
518.1212769	0.35
528.6156616	0.28
529.2838135	0.25
533.4063721	0.14
538.3643188	0.14
544.3867188	0.21
549.8555298	0.50
553.6525879	0.25
554.6121216	0.18
561.5375366	0.31
562.4628296	0.13
570.1331177	0.62
571.6599731	0.35
581.3264771	0.11
589.3564453	4.36
590.2434692	0.39
597.1249390	0.09
607.2146606	50.92
608.0755005	0.53
613.1466064	0.18
625.2614136	43.67
625.9246826	0.18
634.1823730	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	573.25
Annotation	Iandonoside B
Peak:m/z	Relative Intensity
177.9950409	0.03
182.8227234	0.06
196.1781616	0.07
255.3502655	0.02
277.1123047	0.02
283.2678223	0.03
331.5721436	0.04
359.9128418	0.03
363.4843140	0.04
365.2929688	0.23
375.3589478	0.59
377.3063354	0.01
381.4167480	0.05
391.0766602	0.04
393.3490601	0.05
395.8583374	0.01
407.2642212	0.10
408.1630249	0.01
411.3673706	0.09
413.4234619	0.06
434.2651367	0.03
447.4577026	0.05
453.2628784	0.08
466.4624634	0.09
477.1441040	0.18
485.2752686	0.06
498.7871704	0.06
501.3748779	0.01
505.1168213	0.03
510.3649292	0.04
511.4606323	0.02
527.3204346	100.00
527.9263306	0.25
529.0879517	0.02
531.1735840	0.05
537.3403931	0.36
539.3571777	0.04
543.3442993	0.04
548.1373901	0.01
548.8654175	0.10
555.3757935	0.12
558.1991577	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	365.1605
Annotation	Orizabin
Peak:m/z	Relative Intensity
113.1807556	0.10
116.9448776	0.24
133.1181335	0.08
147.3656769	0.23
157.1001587	0.04
166.9928894	0.06
169.1291199	0.19
175.0740051	0.24
183.1158295	0.20
185.3038025	0.34
187.2840881	0.10
189.0045166	0.54
199.1573181	0.82
201.2090454	1.61
203.1692657	0.61
204.9458923	0.08
206.1123657	0.17
207.2794189	0.08
211.1919556	0.10
215.2250061	34.02
217.2369385	5.54
219.1476746	2.56
223.3938293	0.55
227.1891785	0.25
229.1947021	4.42
231.2096863	4.09
233.4231873	0.04
235.3140564	0.05
241.3230896	4.29
245.2562866	9.91
247.2323303	3.71
257.1900330	8.46
259.2186890	49.52
263.4258728	0.08
267.2073059	0.14
273.2773743	0.14
275.1517944	100.00
277.1253967	42.00
285.2644958	0.45
293.0564575	0.09
301.2305298	0.08
303.1919556	4.59
309.1075745	0.11
317.3095703	0.10
319.2797852	0.30
321.1484985	44.91
321.7745972	0.07
329.2747803	0.19
331.2882690	0.22
335.0645142	0.05
347.3340454	10.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	365.1953
Annotation	Cinncassiol A
Peak:m/z	Relative Intensity
136.8338318	0.08
147.1869202	0.11
152.8920135	0.06
157.8538513	0.20
159.0311890	0.33
164.8992615	0.19
167.1631622	0.16
177.3187866	0.62
183.0795441	0.13
190.7671356	0.17
203.1044617	0.31
225.1033936	0.35
244.1281128	0.39
253.2565308	0.15
255.2637329	0.61
257.2621765	0.52
261.1927795	1.18
262.4289246	0.25
267.4799194	0.14
272.9744873	0.56
275.2856445	0.95
283.2515564	0.44
285.2712097	0.40
288.3337097	0.41
294.1706543	0.06
299.3394775	0.04
301.1813965	2.13
303.2066956	0.28
309.3184204	0.18
311.1519165	2.53
319.1069336	7.68
329.1844482	9.51
337.2830200	10.23
347.1948547	100.00
348.5062866	0.15
349.6696777	0.41
355.7645569	0.20
356.6639709	0.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	148.06
Annotation	3-Aminopentanedioate
Peak:m/z	Relative Intensity
83.9390106	1.06
88.0530243	0.07
101.9481964	20.78
112.1290741	0.02
129.9292297	100.00
130.9072571	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	258.1095
Annotation	Glycerophosphocholine
Peak:m/z	Relative Intensity
85.8933411	0.01
103.9630890	100.00
104.8191528	0.03
112.0265656	0.02
180.9624023	0.03
183.9595795	0.27
198.8597870	0.15
214.2566376	0.07
240.0391998	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	541.2293
Annotation	3-[4-[1-(4-Hydroxy-3-methoxyphenyl)-1,3-dihydroxyisopropoxy]-2-hydroxyphenyl]propyl alpha-L-rhamnopyranoside
Peak:m/z	Relative Intensity
161.1776123	0.24
165.2541046	0.10
169.0098572	0.99
211.0924377	0.16
221.1926422	0.16
223.2085876	0.22
227.1208954	1.61
228.0820770	0.52
229.2935181	0.42
240.7457581	0.18
260.9754333	0.10
271.4606934	0.20
273.3397217	2.34
275.3786011	0.15
287.2732544	0.17
289.4992676	0.06
291.2504883	0.64
297.2257080	0.14
301.1097412	0.15
303.2762451	0.79
305.0118408	0.35
307.2526245	0.06
308.2460327	0.05
313.1826172	2.85
314.0300293	0.26
317.2738647	7.52
318.7374268	0.39
331.2569580	0.68
332.5790405	0.68
333.3320923	2.88
335.2741699	11.01
336.3521118	0.12
349.3215942	1.72
358.1155396	0.05
359.3101807	0.29
361.2027588	100.00
362.1578979	0.32
371.2918091	0.14
373.3192749	0.15
375.3021240	22.56
377.2423706	4.80
379.3574219	3.91
380.2788086	0.50
383.0965576	0.22
399.4498291	0.13
402.2714233	0.10
403.2152710	6.20
403.8474731	0.07
411.3941040	0.16
415.1295166	0.56
421.2708740	8.11
431.5136719	0.22
433.2839966	0.16
435.1849365	0.08
445.2692261	0.13
451.4045410	0.56
453.1534424	0.31
457.4668579	0.09
462.9511719	0.22
467.1112061	0.49
477.5093384	0.32
479.1159058	0.13
481.4043579	1.96
483.0314331	0.05
493.4695435	0.18
495.1431274	3.50
497.3003540	1.11
498.4350586	0.25
505.4302368	0.12
509.3237305	2.20
511.4370728	0.19
522.9645996	1.06
523.5877686	1.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.1976
Annotation	Iandonoside B
Peak:m/z	Relative Intensity
195.3921814	0.13
211.1567383	0.21
229.3542480	0.09
239.4012604	0.41
241.0973206	0.04
255.1553345	0.23
257.1268311	1.89
267.0487671	0.03
269.1268616	1.69
282.9505005	0.16
284.9614258	0.07
287.1925659	17.78
288.2744141	0.19
300.9097595	0.10
313.2235718	0.43
331.2606812	8.09
357.1212769	6.60
375.2106323	100.00
376.1507568	0.84
389.4286499	0.10
417.2661133	17.35
418.3742065	0.24
483.0004272	0.18
493.1229858	0.04
520.0968628	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.1607
Annotation	Triptriolide
Peak:m/z	Relative Intensity
165.1589508	0.02
197.1776886	0.01
201.3210754	0.02
205.0878296	0.02
213.3735352	0.05
226.8330383	0.06
242.9416504	0.10
245.0337219	0.11
253.1610718	0.09
257.1517639	0.02
261.2088013	0.08
271.1603088	0.06
273.1994324	0.02
275.2043762	0.03
281.1526184	0.06
289.2602539	0.17
297.3038330	0.08
303.3062134	0.03
305.3787231	0.01
313.3630676	0.02
315.2908936	0.11
317.0845947	0.30
319.4208069	0.21
329.0659180	0.02
331.6853333	0.02
333.2975464	1.09
341.5395508	0.11
359.2095032	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	349.2
Annotation	Perseanol
Peak:m/z	Relative Intensity
107.0806961	0.06
109.0059509	0.05
119.1831512	0.03
122.8689194	0.04
130.9746857	0.09
132.9926605	0.24
135.0367737	0.18
136.9265747	0.05
141.0707397	0.06
144.9416962	0.04
149.1361389	0.10
150.9657745	0.16
153.1347198	0.10
159.3346558	0.10
161.2426758	0.01
165.0910950	0.01
167.0829163	0.09
169.1250916	0.03
171.9197998	0.02
173.0431213	0.01
174.8921204	0.09
177.2982483	0.02
181.1618958	0.03
183.0516968	0.12
190.4587402	0.06
191.0953369	0.09
192.9251404	0.10
197.2099304	0.07
199.2442627	0.06
200.6305847	0.06
207.0763245	0.10
208.9930725	0.10
213.1051941	0.01
219.2554321	0.04
221.2360840	0.09
223.2300415	0.06
225.4739990	0.01
227.0892029	0.06
229.3052673	0.06
230.9038086	0.03
235.0165405	0.07
236.9099426	0.13
239.2121277	0.37
241.1972961	0.23
243.1312561	0.17
243.8761902	0.01
246.0775757	0.02
249.0828247	0.06
253.0556641	0.02
255.1767883	0.05
257.1880493	0.82
259.0115662	0.14
261.3686523	0.06
264.4629517	0.05
267.1860352	0.90
269.2508850	0.17
273.0600586	0.14
275.2760010	0.30
277.4024353	0.04
283.2153320	0.18
285.1999512	3.58
287.2515259	0.36
289.1780090	0.03
291.2142334	0.01
295.2348633	0.43
301.1262817	0.90
303.1113892	4.97
303.7524414	0.01
305.1085205	0.43
307.3611450	0.13
308.2278748	0.02
310.4301147	0.14
313.1195068	13.59
314.0270691	0.02
321.1970825	0.16
325.7544556	0.20
329.6235352	0.09
331.0983276	100.00
332.4100952	0.14
340.1667175	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	529.2253
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0395813	0.02
179.0475464	0.20
185.0136414	0.13
187.0750732	100.00
191.0571289	0.08
193.3755798	0.03
204.8519592	0.12
217.0974731	0.05
231.1738586	0.19
247.1450653	0.62
259.0032349	0.09
261.0089722	0.10
275.0820923	0.15
276.9710083	0.11
281.2060242	1.67
285.2504272	0.04
305.8402710	0.02
306.9808960	0.22
323.9148560	0.04
334.9901123	3.31
337.0360718	0.27
341.2113037	34.57
347.1498413	0.16
348.7738037	0.21
364.9185791	0.11
368.2268066	0.18
379.1196289	0.18
384.1126709	0.22
396.1117554	0.10
397.1981201	0.27
399.3169556	0.05
409.2429810	0.06
414.3900757	0.05
431.3042603	0.15
437.1812744	0.02
439.2331543	0.25
440.4254761	0.10
441.0399780	0.20
449.3278198	0.04
451.2611694	0.08
455.3660278	0.10
467.2277222	0.08
469.0387573	0.24
485.4230957	0.17
486.2422485	0.07
493.1869507	0.03
499.2496948	0.20
509.5231323	0.05
510.7470093	0.31
511.3712769	1.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.1977
Annotation	Abelioside A
Peak:m/z	Relative Intensity
158.6921692	0.04
170.2174072	0.03
177.2967224	0.09
183.1850281	0.14
201.2081604	0.34
213.2323608	0.20
215.2308655	0.04
223.9039612	0.12
225.5251160	0.07
227.3842316	0.06
229.2832642	0.11
233.1309814	0.02
237.2655792	0.02
239.2550659	0.90
243.1301270	0.30
245.2820587	0.15
253.4711151	0.02
257.2803955	2.10
259.1548462	0.20
271.2134399	0.43
273.0807190	0.06
275.3649902	0.74
281.3656616	0.45
283.1903687	1.04
287.4743042	0.06
289.1367798	0.16
295.1537476	0.04
299.2205811	0.37
301.2639771	3.45
301.9655762	0.08
303.2576294	0.90
311.0285645	0.39
313.4276733	0.08
314.2304077	0.07
317.1344604	0.44
319.4911499	0.40
324.8554688	0.13
327.2166748	0.70
329.3454590	0.02
331.0076904	0.08
333.2762451	0.08
335.1976929	0.04
341.1411133	0.04
345.2763672	7.48
347.2400513	0.26
357.3115845	0.04
363.2778931	100.00
364.3488159	0.09
367.3392944	0.03
369.1611938	0.09
373.4595337	0.01
377.4732056	0.04
381.4325562	0.10
387.3069458	0.75
388.1888428	0.03
399.4539185	0.04
405.2717285	13.07
407.1126099	0.10
411.4025879	0.05
417.3425293	0.38
419.5789795	0.14
429.3212891	0.05
433.3488770	0.08
435.2661133	1.31
437.4094849	0.69
441.4151611	0.09
444.9859009	0.19
447.1531372	0.12
453.4332886	0.20
459.2385254	0.08
463.3922729	0.13
465.3312988	7.38
479.3729858	0.35
481.3143311	1.20
482.3021851	0.15
487.1355591	0.05
488.0619507	0.02
488.8666382	0.07
489.4820557	0.02
490.3112793	0.06
491.8013306	0.08
493.3045654	0.01
495.4361572	0.04
497.5099487	0.05
505.1314087	0.03
507.2766724	7.17
508.1043701	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	591.23
Annotation	Ligurobustoside M
Peak:m/z	Relative Intensity
167.0712128	0.05
179.0424347	2.13
189.4646149	0.05
205.1242676	1.14
207.1339569	0.23
221.2196045	0.32
223.1895142	5.47
227.1352539	0.03
241.3090057	0.05
249.1906433	0.05
265.1480713	0.74
267.1560059	9.80
277.4242554	0.13
291.2142944	0.58
295.0671997	0.34
307.0569458	0.12
308.6801453	0.10
309.2868958	0.17
321.2797852	0.15
323.2012939	9.17
324.8137817	0.36
332.8616943	0.07
339.0662842	3.94
341.2231445	100.00
363.1751709	0.06
369.1616821	6.75
383.1879883	29.99
385.3300171	0.16
386.9645386	0.34
389.2465210	0.03
393.2332764	0.14
411.1974487	1.28
423.2412720	0.31
425.2893677	0.09
429.1945801	32.33
437.1830444	0.09
438.7275391	0.06
483.0538330	0.28
493.4761353	0.12
495.3262329	0.21
496.5800171	0.11
505.2615967	0.04
507.3195190	1.04
527.4964600	0.08
528.5033569	1.18
529.2088013	3.70
531.1771851	0.09
545.2583618	0.66
547.2946167	1.77
553.3818970	0.23
573.3133545	9.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	389.2159
Annotation	Rehmaionoside C
Peak:m/z	Relative Intensity
111.0652847	0.47
119.0553055	0.31
121.0274048	3.75
123.0454407	0.81
125.1055450	0.17
127.1462784	0.24
130.2349243	0.06
131.0403900	0.26
133.0711060	1.61
135.0461578	2.35
137.2683716	0.19
138.9400024	0.14
145.0947723	0.49
147.1056519	0.50
149.0730286	6.95
151.1348572	0.29
152.7059021	0.20
163.1769562	7.35
167.0729370	0.29
169.1200256	0.08
170.0021057	0.16
171.2290955	0.20
173.2110596	5.62
175.0786743	0.15
177.0031128	0.04
178.3951416	0.14
179.2504272	0.04
180.0467529	0.09
183.0458679	0.06
191.0744171	24.76
193.0438232	0.18
196.1293182	0.18
196.9558716	0.10
199.0670471	0.22
205.0407715	0.40
206.8030090	0.12
209.0535431	100.00
209.6836243	0.15
211.0299530	0.15
213.3358459	0.05
219.2433319	0.27
221.0147705	0.21
227.0432739	56.06
228.0568237	0.09
228.8327942	0.06
231.1472778	0.17
235.3518372	0.24
244.8713074	0.16
246.8238220	0.30
249.1029053	0.09
251.0983276	0.25
253.3985596	0.04
255.0474243	0.34
255.6998596	0.09
257.1840820	0.28
258.0765076	0.08
261.0804443	0.21
263.4158936	0.06
264.0442200	0.09
265.2026062	0.17
268.1552429	0.34
273.1387634	0.09
283.3973999	0.10
286.4398193	0.41
299.3533936	0.05
300.2617188	0.86
306.9222717	0.30
307.7544556	0.16
309.0442505	0.27
312.8856506	0.36
317.1772766	0.10
323.2697449	0.18
327.3314209	0.33
328.8592224	0.60
331.3630371	0.21
335.2650146	0.41
339.3294067	0.29
342.7665405	0.32
343.3761597	0.17
344.6740723	0.10
346.0395508	0.36
346.7403870	0.22
347.9309692	0.22
353.1490479	0.85
357.2835083	1.21
359.2489624	0.40
360.3035278	0.28
366.0443420	0.27
370.5883484	1.49
371.2551270	3.38
372.3079529	1.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	543.2806
Annotation	Virescenoside N
Peak:m/z	Relative Intensity
263.0587769	0.01
273.0917358	0.03
317.6187134	0.01
331.3080444	0.02
335.2738037	2.39
335.9479980	0.01
358.9818115	0.01
363.1435547	0.02
395.1163940	0.03
396.3056030	0.19
440.2228394	0.01
455.6641235	0.01
477.2536011	0.04
497.3385620	100.00
498.2204590	0.01
499.2849121	0.09
507.3291626	0.05
511.3511353	0.03
519.5527954	0.03
525.2188721	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	598.2837
Annotation	Unknow
Peak:m/z	Relative Intensity
174.9611969	0.10
178.0994873	0.22
181.0491333	0.09
190.0500183	0.52
194.0472412	0.18
196.9473114	0.34
199.0128632	0.29
206.3103943	0.13
209.0849304	0.74
224.2093964	7.17
234.5311279	0.13
235.1807404	0.12
238.5807495	0.10
239.3025513	0.27
241.2694397	0.15
243.1480865	0.29
252.1473389	45.14
255.2773590	0.22
256.6344604	0.13
257.3183899	1.25
264.1015625	0.40
267.2668762	0.15
271.1555786	0.30
275.2489014	1.33
276.8353271	0.42
285.3146362	0.12
296.3383179	0.14
299.2109375	0.15
303.1294861	0.52
309.2991943	0.06
316.5305176	0.89
347.3583374	0.28
354.3005371	0.92
357.4003906	0.09
364.4316406	0.06
366.3775635	0.13
372.2115479	13.25
382.2850342	16.03
383.3601074	0.32
384.3220825	0.44
390.3663940	3.43
397.2835693	0.32
400.2114868	29.08
402.4212646	2.58
408.3571777	1.39
418.2835693	100.00
419.4904175	0.19
420.5141602	0.58
425.9523315	0.11
434.3566895	0.58
436.3373413	47.38
437.6486206	0.20
443.3745117	0.08
447.6654663	0.20
452.5315552	0.08
454.2783203	0.24
460.1817017	0.04
464.4349976	0.41
471.2014771	0.18
472.9046631	0.14
484.5009155	0.07
500.0938110	0.43
503.3679199	0.12
505.9144897	0.09
518.1361084	0.19
534.4133911	0.37
536.4508057	0.18
544.3714600	1.57
552.2882080	1.73
554.9796143	0.11
556.4512329	0.14
562.3248291	4.17
565.1820679	0.76
575.6786499	0.31
580.1984863	70.28
581.0297241	0.44
589.9804077	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	455.1691
Annotation	7,8,3',4',5'-Pentamethoxy-6'',6''-dimethylpyrano[2'',3'':5,6]flavone
Peak:m/z	Relative Intensity
145.1483612	0.01
154.7622986	0.02
161.5782471	0.01
168.9629059	0.03
187.2077332	0.01
197.2618408	0.01
198.3092804	0.01
211.1704102	0.03
221.2503052	0.02
223.1436462	0.02
237.1742859	0.05
239.0378265	0.10
241.7678833	0.02
248.9750977	0.01
251.3100586	0.01
255.1610107	0.03
257.3146667	0.03
261.2099609	0.01
265.5753784	0.01
266.6032410	0.01
269.5108643	0.05
275.0657349	0.03
283.0671997	0.23
285.2353516	0.20
288.9844360	0.02
291.4676514	0.03
293.2156982	1.92
293.8366394	0.00
295.2499695	0.01
297.2046509	0.03
299.4876099	0.06
301.1848450	0.06
309.5423584	0.02
311.1491699	2.45
313.1743164	0.12
317.2354736	0.04
323.1541748	0.02
327.5042725	0.09
329.1883545	1.66
331.3468018	0.01
335.1355896	0.08
347.5209656	0.01
353.3905945	0.06
355.2124329	0.05
357.0389099	0.09
358.0148315	0.02
361.2271729	0.01
363.2441101	0.21
365.3814087	0.07
367.0588684	0.04
379.0729370	0.04
381.3586121	0.13
383.1416626	0.01
385.0318298	0.08
388.3020325	0.07
388.9518127	0.04
391.1841736	0.41
393.1818542	0.01
395.1657410	0.73
395.7668152	0.01
397.5003052	0.04
398.9852600	0.05
401.4936218	0.02
405.1392517	0.10
406.1823425	0.60
407.1421204	0.07
409.2708435	1.00
410.8679810	0.01
411.4930725	0.01
413.2296448	0.07
419.1806946	0.18
420.0761414	0.04
425.2332153	100.00
425.8401489	0.21
427.2409363	0.08
437.1517944	1.18
438.0455017	0.20
440.2320251	0.13
441.4800415	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	365.1586
Annotation	Nagilactone B
Peak:m/z	Relative Intensity
139.1776276	0.07
203.1950073	0.05
241.3306274	0.11
255.4772644	0.05
257.0841064	0.09
259.2422180	0.05
273.0262451	0.25
283.1323547	2.33
285.2031250	0.38
287.0372009	0.04
290.9772034	0.13
301.1689758	2.94
303.3411865	0.06
305.2913818	0.07
310.5222473	5.20
311.1266479	32.73
316.7701416	0.09
318.9959717	0.14
327.4100647	0.04
329.0459595	100.00
329.7796631	0.59
337.2922974	0.02
347.1271667	91.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1817
Annotation	Montanin G
Peak:m/z	Relative Intensity
159.0426941	0.10
161.0488586	0.17
178.9689331	0.04
203.0925446	0.27
206.1631927	0.10
236.9592590	0.27
239.2770996	0.11
255.2356567	30.03
280.8028870	0.44
297.2487793	4.17
299.0260925	18.86
312.9701538	0.07
319.8648071	0.21
327.3759155	0.34
335.4308777	0.13
341.2808228	0.19
343.3744812	0.32
369.2315063	0.17
370.3783569	0.13
371.3144836	0.28
375.6066284	0.31
386.3155823	0.46
395.6627197	0.22
399.4878540	0.42
401.3846436	0.10
415.4138184	0.94
417.2596130	100.00
418.1087952	0.31
419.1417847	0.19
425.9231262	0.28
431.3243713	0.12
442.9972839	0.77
443.7300110	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	245.0761
Annotation	Pseudouridine
Peak:m/z	Relative Intensity
72.8862915	0.05
73.9718018	0.13
83.9435501	0.31
84.9626617	0.07
96.8801422	0.63
98.0448761	0.05
98.7298431	0.07
100.1569672	0.02
112.8822174	100.00
113.5303955	0.29
114.8577728	0.14
115.9460907	1.15
124.3171234	0.04
126.1167755	0.10
127.1555023	0.05
129.0445099	0.06
130.0334320	0.43
130.9054413	0.04
132.0940552	0.40
132.9847107	1.12
139.3292084	0.03
141.9560699	0.56
144.0020294	0.02
147.9114838	0.04
154.9440155	0.14
156.0666962	0.05
159.1937866	0.06
162.0032501	0.09
169.8220673	0.82
170.4292297	0.04
172.8211517	0.11
174.7183990	0.14
181.9762421	0.61
183.1054993	0.08
185.2220001	0.15
186.1978912	0.05
188.2453308	0.01
194.9752960	0.04
197.0616608	0.07
199.0587769	1.39
201.1615753	0.74
203.8767395	0.17
209.1346283	0.79
209.8830719	0.03
211.2138367	0.13
217.1166534	0.14
227.0504150	6.72
228.0226593	1.01
236.7614594	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.1144
Annotation	Aralidioside
Peak:m/z	Relative Intensity
129.0989075	0.09
138.9167786	0.27
143.0994568	0.07
153.0365143	0.39
157.0221252	0.77
168.1469116	0.19
168.7758636	0.26
170.9155579	0.35
175.0067139	0.10
182.0969238	0.63
183.0572205	3.12
189.2658691	0.13
196.9862671	12.73
212.3645020	0.04
223.1668854	0.21
225.0113831	0.27
231.0845337	2.59
239.1925964	2.06
240.9559021	0.15
242.0950928	1.26
249.1298828	57.44
252.9349365	0.19
254.1689453	0.24
256.5711060	2.36
257.1804504	37.62
267.1319885	27.59
270.2044983	0.08
271.1858826	9.83
283.6737671	0.36
285.1587524	5.82
297.0281067	0.07
299.2307129	2.75
329.2011719	0.18
339.1391907	2.16
340.9841309	0.48
353.1377258	0.13
355.0491333	0.06
356.9714355	0.11
359.3377075	0.17
369.3401489	0.27
371.1574707	1.74
385.2827148	5.74
387.1644592	12.04
397.2733459	0.90
401.3026733	0.43
403.1921082	2.00
411.2531433	0.25
415.1611633	45.88
429.2411804	100.00
432.3393250	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	441.1765
Annotation	Serruloside
Peak:m/z	Relative Intensity
124.7729797	0.31
130.9675140	1.35
133.1129913	0.25
137.1215668	0.28
139.1244965	9.52
142.8150940	2.24
148.9779663	0.63
150.8445435	0.49
157.2120972	0.31
159.1399231	0.52
161.0627594	6.47
168.7522888	2.00
172.7932129	0.20
174.0517883	0.12
178.9422607	5.17
187.2455750	0.31
189.1380005	0.93
194.8843689	0.17
201.4241028	0.26
204.0816040	0.12
205.1574402	5.36
207.0400391	0.07
211.1654358	1.32
217.1085052	4.52
219.1504211	0.32
223.2564697	0.52
225.4029388	0.24
235.2034302	4.72
243.2674255	0.17
249.1926270	0.27
255.0709229	0.28
259.4476318	0.17
261.1705017	0.68
277.2677002	0.22
279.2646790	0.43
287.0723267	0.13
291.5572815	0.16
299.2438660	0.19
300.3557129	0.47
315.2854004	0.20
330.1595154	100.00
331.2214355	37.70
334.7902527	0.29
344.9355469	0.35
347.2589111	0.44
353.3018494	0.13
353.9150391	0.48
363.4579468	0.24
379.2207336	2.98
385.2960815	0.22
394.8438110	0.59
395.4480591	1.90
397.2900696	32.95
405.2151794	1.04
423.1662903	8.81
423.9257202	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	467.1186
Annotation	Glochidionolactone D
Peak:m/z	Relative Intensity
137.0757904	0.30
139.3003387	0.12
143.9151611	0.12
146.0680237	0.08
151.0172272	0.04
157.5393829	0.03
160.9985809	0.28
163.6596680	0.18
164.9245605	1.35
167.0558167	0.10
173.2799377	0.06
174.2471313	0.11
175.1680603	0.04
177.0565186	0.60
177.8416748	0.13
179.0923462	2.47
181.1050720	0.16
187.0951233	0.13
189.1552429	0.09
190.0361023	0.25
191.0108337	0.63
198.9710083	0.18
201.2011261	0.82
203.0455170	0.32
204.0366974	0.11
207.0716248	0.15
213.9564667	0.10
216.2719421	0.15
217.1127014	0.07
219.0213165	2.40
221.0675049	3.18
228.1940613	0.08
231.1740723	2.36
233.3067627	0.31
235.5049133	0.03
241.2579041	0.20
243.0170898	0.62
247.2222900	0.40
259.3247375	0.15
259.9254456	0.05
261.0760498	6.81
261.6838684	0.07
263.2824402	0.38
272.1531067	0.12
273.2031555	0.22
278.9216614	0.04
285.1653748	0.06
287.1365356	2.72
296.8466187	0.46
298.3119812	0.13
305.1592407	100.00
306.0131836	0.04
307.3877869	0.08
308.0042114	0.13
311.1246338	0.20
323.0352173	0.03
327.3526917	0.20
329.2130127	3.77
333.0222473	0.36
334.4376221	0.12
339.8929749	0.28
341.2043762	1.80
346.3115234	0.13
347.2138672	1.31
351.2503967	5.57
352.1614990	4.00
354.9503174	0.33
359.4950562	0.04
363.1501465	0.18
367.0770264	0.13
375.0603027	0.11
377.1888428	3.04
379.2080688	0.09
381.2506409	0.11
382.0374756	0.10
382.9663391	0.62
383.6451721	0.16
400.9402466	0.06
405.1377869	0.54
407.0513916	0.13
409.1532288	0.23
413.4994507	0.16
420.3471680	0.22
421.2648621	2.65
423.1283875	4.14
424.1712341	0.11
431.4432678	0.23
439.2820435	0.08
447.2774353	0.05
449.0987549	2.21
449.8779602	0.07
457.7057190	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	647.2037
Annotation	Unknow
Peak:m/z	Relative Intensity
184.8443451	0.15
189.1341248	0.38
200.8956604	0.21
203.2243958	0.05
205.1256714	0.33
207.0619812	0.24
215.0748291	0.92
217.0381622	0.24
220.9842072	0.46
227.1775818	0.47
233.4451447	0.32
244.7787781	0.51
247.0305939	1.91
250.9494324	0.15
252.9620667	0.15
263.1873169	0.98
265.0649719	18.45
269.4507141	0.07
277.1481628	1.29
280.9702454	0.45
283.0749207	10.88
285.3328247	0.12
287.1914062	0.28
289.3663330	0.06
298.9539185	0.08
316.9589844	0.68
321.2799072	0.16
325.1666260	0.12
329.1655273	1.37
331.3248291	0.48
337.4521484	0.27
341.1842651	0.15
343.2515259	0.07
349.1531982	0.17
359.1374512	1.03
361.2553711	0.09
373.2673340	0.16
375.2655029	0.43
376.9399414	0.78
379.1643677	8.61
379.9816284	0.31
382.7761841	0.49
394.4982910	0.19
397.2922363	17.09
402.2524414	0.23
403.1320190	0.07
404.3984375	0.46
407.3447266	0.05
415.2910767	33.52
417.1225586	1.02
419.1138916	0.26
428.5872192	0.43
435.2047119	0.30
437.0447998	0.42
439.2247925	0.43
443.2467651	0.36
454.2842407	0.79
455.3793335	0.34
457.0863037	1.46
463.1234741	0.47
467.4716187	0.68
472.2297363	0.20
474.7676392	0.19
482.2489624	0.06
485.2577515	1.76
493.3962402	2.15
495.1819458	0.52
511.3036499	3.23
513.2471313	1.03
514.3973999	2.97
515.2005005	2.63
516.1897583	1.54
529.2375488	9.15
529.8375854	0.04
535.5629272	0.12
536.6223755	0.59
551.3339233	0.05
553.4161987	0.21
555.2136841	9.28
561.3716431	1.28
567.4642944	0.18
568.3808594	1.26
569.3109131	1.73
571.5252686	0.07
573.2891235	9.93
586.1940308	5.15
587.3198853	92.64
597.3453979	1.41
605.3067017	100.00
614.1052246	0.12
615.3059082	55.27
616.4471436	0.78
628.0757446	0.36
629.3239136	5.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.2078
Annotation	Unknow
Peak:m/z	Relative Intensity
139.2320709	0.03
160.9755554	0.29
178.7998962	0.06
191.2451630	0.08
195.0052185	0.09
209.2239227	0.14
222.6379700	0.02
224.9382324	0.11
234.2283630	0.04
235.1403503	0.13
253.0027771	0.17
266.9892883	0.08
269.4883728	0.02
271.1926880	0.19
329.4111023	0.07
361.5072327	0.02
365.2541809	0.02
369.1674194	0.07
387.2373352	100.00
387.8669739	0.45
389.1517334	0.13
397.2381287	0.04
415.3033752	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	454.2916
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
131.0291138	0.18
136.1562500	0.05
137.0183105	0.13
145.0180664	0.99
165.1280212	0.31
166.9234619	0.09
169.2352753	0.04
177.2592468	0.12
183.1773071	0.45
184.0172424	0.19
184.9862366	0.06
187.1300049	0.17
195.0736542	0.05
198.1011047	0.08
215.3186188	0.27
216.0510712	0.55
223.1412964	0.12
235.2830353	0.18
246.2200012	0.09
259.4831238	0.19
261.1634827	0.21
277.1831360	0.13
280.1133423	0.09
282.1374512	2.46
282.7636719	0.06
290.7687378	0.17
296.8532104	0.31
300.0556946	0.10
313.2597656	55.39
353.4119263	0.35
358.1533203	0.11
363.7922363	0.39
380.2608948	0.03
387.2151184	0.26
393.2514954	4.89
394.8118286	0.27
395.7181396	0.04
400.6082458	0.19
405.3999634	0.64
408.4357605	1.19
410.5877380	0.33
417.8162537	0.08
418.5664978	0.08
423.4038696	0.09
436.2574158	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	731.2538
Annotation	Unknow
Peak:m/z	Relative Intensity
212.9382935	0.08
221.3350830	0.59
228.0320892	0.09
233.1469269	0.66
247.0993042	0.14
255.0818329	0.12
256.2280273	0.54
259.4451904	0.71
260.1709290	4.64
260.9989929	0.62
264.7380066	0.30
271.1604309	0.28
272.2526245	0.67
277.2218933	0.18
285.2315063	0.94
286.3992615	0.27
300.9429321	0.32
302.8913574	0.24
305.1632385	0.28
309.5111389	0.29
312.1722412	0.58
321.2676392	0.60
323.5186157	0.23
331.3450317	0.58
339.1715088	0.34
340.3410034	0.15
342.3410034	0.29
343.6602783	0.25
358.3840942	0.39
364.7324219	0.53
376.3439941	0.97
379.1842041	0.65
381.3597412	0.07
383.1958008	0.74
384.0786743	0.21
385.7330933	0.41
387.2433472	0.52
391.5334473	0.13
395.1804810	0.53
396.9451294	0.50
401.2440186	0.10
406.0913086	1.21
408.2287598	0.17
408.9060669	0.16
413.3040771	0.35
417.2301025	0.46
419.1365967	0.48
420.5249634	0.22
423.4785767	0.07
425.3461914	0.34
431.5535278	0.66
436.5984497	0.31
440.0640259	0.45
441.3113403	0.21
444.2014160	0.33
448.0370483	0.86
449.1520386	0.31
451.1873779	0.53
453.3549194	0.75
456.2665405	0.88
457.9676514	0.22
459.2150269	0.22
467.0025024	2.79
468.5316162	0.39
469.2606201	0.36
481.4226074	0.33
483.4694214	0.08
486.4757080	0.25
489.3314819	1.04
491.0584717	0.24
495.4262085	0.31
496.3033447	1.32
497.0659790	0.30
498.2810059	0.31
507.1776733	0.74
509.3825073	0.70
512.4355469	0.17
514.0900879	0.09
515.3505859	1.43
520.3504639	0.33
528.0842896	0.89
529.5006104	0.41
530.8972778	0.70
531.7316284	0.18
537.6872559	1.12
540.1489258	0.22
547.6424561	0.15
548.8805542	2.42
550.7014771	0.25
551.8543091	0.40
553.1608276	0.18
554.8515015	0.15
555.9695435	0.85
557.7623901	1.71
563.1040649	2.56
567.3078003	0.42
568.0512085	0.34
569.2377319	0.91
570.8399048	1.04
572.2861938	0.52
575.8283691	1.28
578.3314209	0.72
579.7566528	0.87
581.9537964	0.13
583.3104858	0.39
584.3207397	1.06
587.1920776	2.38
593.3634644	0.17
595.6723022	0.82
596.4555054	0.30
597.6052246	1.19
600.3433228	1.10
602.2073364	0.16
605.7644043	0.80
607.0797729	1.11
608.5039673	2.50
610.3717651	0.34
613.4037476	1.17
614.4713745	0.19
615.8202515	1.64
616.8045044	1.02
617.8101807	0.86
621.0780640	2.10
622.0436401	3.76
622.6889648	2.18
623.9834595	0.47
624.9439697	1.03
625.5919800	0.83
627.0369263	2.15
627.8104858	2.69
630.8460693	0.42
631.9724731	0.26
633.3897095	4.57
634.2077637	2.77
634.9918823	1.27
636.1926270	3.36
636.9240723	0.58
638.6659546	10.77
639.5207520	6.76
640.3549805	1.10
641.8750610	2.04
643.0482788	2.63
644.3364868	0.87
645.0841675	14.40
645.9232178	0.75
648.0682373	4.44
649.3657837	1.66
651.1936646	3.14
653.5926514	2.79
654.8951416	1.46
656.6208496	1.17
657.6697388	2.21
659.2258911	3.66
660.3258057	3.77
661.3432007	2.45
662.6668701	6.42
663.9866943	2.34
665.5167847	4.50
666.4101562	2.91
667.7268677	3.91
668.4945679	2.06
669.8349609	5.39
671.3532715	10.28
672.3016968	6.15
673.5012207	1.76
674.6112671	3.63
675.6403809	4.55
676.8176270	15.35
677.8250732	12.07
679.1036987	3.50
679.8307495	1.07
680.5357056	1.04
681.8025513	6.32
682.9237671	7.92
684.1536255	2.56
684.9197998	1.09
685.9196167	6.03
687.4845581	37.49
688.2610474	9.38
688.9521484	0.05
691.3242798	2.30
692.1697388	4.08
693.2168579	64.41
693.8538818	20.97
694.9466553	1.91
695.8537598	2.94
696.7780762	11.36
698.0218506	5.14
699.1647949	6.14
699.7991943	2.99
700.9545288	3.45
701.7731934	7.87
702.6765747	15.05
703.7048950	5.54
704.3416748	1.90
705.4337769	15.69
706.1135864	8.47
706.7752075	4.30
707.5745239	23.92
708.5038452	3.78
709.4140015	3.36
710.8789673	29.95
711.7994995	48.08
713.1463013	4.38
714.2354126	12.01
714.9608765	8.53
716.6124878	39.38
717.5988159	14.41
718.5089722	0.69
719.7457886	100.00
720.4932251	58.76
721.3933716	0.53
722.4265747	19.30
725.5049438	5.79
737.0225220	0.22
742.0092163	0.13
747.8525391	0.72
751.3786011	0.58
753.0836792	0.30
757.2413330	0.66
757.9677124	0.27
759.5325317	0.28
761.8268433	0.13
762.7424927	0.41
764.0800171	0.23
765.3956909	0.10
770.3928223	0.39
771.2511597	0.84
772.1611938	0.54
775.3287964	0.36
777.3884277	0.16
780.4172974	2.37
781.3442383	0.80
782.0997925	0.83
782.9192505	1.00
785.8635864	0.95
786.8602295	1.07
790.3682251	0.11
792.4785767	0.11
793.2745361	0.20
797.6383667	0.38
800.9014282	1.23
803.0903320	0.24
804.4265137	0.34
805.4788208	1.91
807.5629272	1.61
809.9844360	0.89
810.9143066	0.73
811.7250366	0.21
814.6199341	0.08
818.1918335	0.33
819.1821899	2.07
819.9977417	3.24
820.8801880	0.71
821.8888550	0.46
826.6225586	0.16
835.3565674	0.53
838.4564209	1.05
839.7382202	0.94
840.4459839	0.90
842.7355957	0.11
845.1893921	0.57
848.5282593	0.90
853.2385864	0.15
853.9867554	4.02
855.0366211	2.15
856.9102783	0.33
860.3952637	0.63
861.4900513	0.36
867.0401001	1.06
867.9791870	1.05
871.5433350	0.68
875.2868652	2.76
876.5819702	2.59
877.6647949	3.04
880.0156860	0.83
883.7272339	0.33
884.5559692	2.20
885.3114624	0.65
887.2324829	0.31
888.2861328	1.68
890.3686523	0.31
893.3966675	0.77
895.8229980	0.72
896.5371704	0.35
900.2399902	1.83
902.9448853	0.75
904.4155884	1.54
905.8464355	0.37
907.8122559	0.84
908.8709106	2.82
909.4973755	0.42
911.4914551	0.35
912.6086426	1.11
913.4006958	1.62
915.2214966	1.07
916.0999146	0.97
917.0581055	1.35
918.4443970	2.87
919.8703003	1.62
922.3700562	1.09
923.0371094	0.97
924.1035156	3.03
925.8352661	0.77
926.8396606	0.65
927.8386841	0.64
928.5409546	0.63
931.0361938	0.54
932.2626343	2.27
933.1239624	3.96
934.4006348	0.55
935.8825073	0.75
936.5038452	1.88
937.6308594	2.71
939.2123413	0.69
941.0029297	13.25
941.8341675	3.00
942.5719604	0.67
943.7478027	0.60
945.2691040	2.82
946.2243042	1.72
947.2844849	0.76
949.2523804	14.32
949.9817505	26.42
951.0046387	1.02
952.2692871	0.87
953.1367798	2.12
954.4734497	0.34
957.6884766	2.85
958.6387329	10.47
959.4575806	1.16
961.0582886	4.24
962.1277466	4.21
962.8817749	0.31
963.7749634	0.81
966.4235229	1.87
967.2431030	0.46
967.8679199	0.60
969.8495483	0.61
970.6176147	1.22
971.9614868	1.18
973.6683960	0.45
974.5891113	0.80
975.9807739	0.67
978.5745239	0.33
981.5268555	1.08
982.4492188	0.16
983.5604858	2.08
984.6151733	2.29
985.4630737	1.08
986.4158325	0.44
992.5522461	0.93
993.5783691	2.16
994.6330566	0.40
997.1489258	2.59
998.0454102	2.75
999.5390015	0.35
1001.2714840	1.46
1002.1954960	0.55
1003.1842650	0.67
1004.3574220	0.12
1006.4782710	4.64
1007.4586790	2.62
1009.2758180	0.89
1010.4338380	2.24
1011.1483760	0.23
1012.4801640	0.07
1015.0287480	0.83
1016.0470580	0.98
1016.6992800	0.24
1018.5024410	5.40
1019.3970340	2.94
1020.6230470	0.77
1023.3922730	2.37
1024.0104980	0.11
1025.8968510	0.67
1027.2988280	2.09
1027.9410400	1.97
1028.6510010	0.43
1033.3300780	1.22
1034.4078370	0.59
1036.0498050	1.04
1039.6807860	1.81
1044.3975830	0.06
1045.0798340	0.70
1067.1699220	1.69
1068.0175780	0.42
1075.5020750	0.40
1081.6848140	0.42
1095.0505370	1.31
1098.0045170	0.28
1101.4273680	0.13
1119.5437010	0.27
1127.2380370	0.12
1129.4001460	0.13
1133.5393070	0.15
1162.2554930	0.19
1165.3831790	0.38
1166.3582760	1.36
1198.4851070	0.09
1204.5200200	0.45
1262.7193600	0.23
1271.5531010	0.27
1277.1285400	0.13
1280.3424070	0.53
1284.2357180	0.24
1287.6512450	0.35
1305.6589360	0.22
1312.0598140	0.19
1319.6212160	0.24
1334.3854980	0.09
1335.5672610	0.73
1340.4390870	0.27
1354.5018310	0.63
1368.5345460	0.41
1403.7136230	0.13
1407.5244140	0.14
1416.3966060	0.61
1423.3332520	0.14
1451.6343990	0.15
1551.5679930	0.41
1562.4249270	0.33
1576.8165280	0.13
1611.4742430	0.41
1662.4743650	0.47
1719.8991700	0.42
1760.2395020	0.17
1761.4283450	0.22
1847.8961180	0.28
1938.7117920	0.09
1970.4212650	0.26
1975.4836430	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	282.2785
Annotation	Oleamide
Peak:m/z	Relative Intensity
80.9225006	1.58
82.9922256	0.88
85.0784073	0.27
85.9357147	0.46
87.1517029	0.03
91.1006546	0.06
93.0000839	0.60
94.9205475	6.36
96.9724121	3.85
98.7736816	0.55
99.9484558	1.04
101.1479034	0.06
104.9399719	0.29
107.0099640	1.10
109.0832901	4.38
111.0121765	4.30
112.9387817	0.23
114.0448914	2.81
114.7643280	0.03
120.9485474	3.13
122.9989090	3.38
124.9961090	2.75
126.4345398	0.16
127.9808578	4.41
129.0558472	0.28
135.1129608	6.06
137.0989990	4.17
139.0199890	2.51
140.6454315	0.32
141.5749512	0.25
142.1785278	3.99
143.1474609	0.13
149.0009766	8.28
151.0427094	3.09
153.1359253	3.59
154.3250732	0.28
155.0991821	0.75
155.9885254	4.07
163.0494690	7.90
165.1382751	2.72
167.1409302	2.13
168.2033997	0.08
169.0967407	0.42
170.1771545	4.56
171.0170593	0.09
177.1192017	6.65
179.2059479	0.38
181.0253143	2.38
182.1448669	0.28
183.0553131	0.26
184.1204834	5.67
191.1406555	3.30
193.0059814	0.59
195.1349487	0.91
196.2576599	0.20
198.2251892	4.67
205.1343079	0.66
207.3273010	0.57
209.2587891	1.21
210.4559021	0.10
212.1223145	4.47
219.2332458	0.25
221.3840027	0.34
223.1743164	0.83
224.1262512	0.39
226.2603149	4.74
240.3289795	1.20
247.1996155	84.09
251.1787720	0.39
265.2656555	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	297.15
Annotation	Unknow
Peak:m/z	Relative Intensity
94.7946701	0.25
96.7270660	0.28
118.9389801	0.11
128.9307861	0.11
151.1529236	0.18
152.9876099	0.16
170.0717163	2.97
171.1024170	0.21
181.1697083	0.24
182.9843445	100.00
184.0364685	12.22
185.0596771	0.64
197.0101929	4.15
198.0473938	4.80
199.1172485	0.29
211.2781677	1.07
212.0085144	2.89
213.1732788	0.45
225.2903137	4.66
226.0231323	1.52
227.1615906	0.06
229.2055359	0.17
233.2767029	3.89
234.2941895	1.49
235.2194214	0.90
237.3959351	1.18
239.1997681	1.36
240.0468750	1.98
241.2468567	0.38
241.8741760	0.12
249.3665466	0.39
250.8746338	0.70
251.5101318	0.53
253.2912903	18.87
254.1249695	0.83
255.1526794	0.20
259.9825439	0.50
260.9991760	0.24
261.9703979	0.40
267.0889282	0.44
268.0737305	0.07
268.9775391	0.81
269.6521606	0.18
279.3224487	8.78
281.2620850	0.67
282.0728149	0.06
297.2440186	41.59
298.2304077	5.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
108.8761978	0.14
115.3016357	0.18
118.83992	0.35
145.0690002	0.20
154.896698	0.59
165.0614014	0.23
169.1571045	0.91
171.107132	3.71
173.0093842	1.38
183.1707764	0.23
185.1208954	2.81
187.0493164	3.96
199.0676575	2.08
201.0706177	3.92
203.4732971	0.29
205.068573	0.16
211.2623596	0.48
213.1867981	1.52
215.1085815	3.12
217.2697449	0.51
225.244873	0.09
227.1497803	0.46
229.1519165	5.24
231.1914673	0.25
232.1661682	0.30
239.386261	0.42
241.1909485	2.02
243.2495422	5.07
245.3348694	1.53
255.2609558	1.15
257.0917969	4.29
259.1943665	1.00
261.4101562	0.86
263.3891602	3.39
267.1597595	0.31
269.3165588	1.63
271.2248535	6.19
273.1958618	2.43
275.219635	0.56
277.3651733	0.38
283.1890564	1.81
285.2763672	9.72
287.2124023	5.04
289.0668945	0.61
295.3053284	0.56
297.3395081	5.71
299.2973022	5.21
301.3229065	1.85
308.1969604	0.27
309.2268066	0.30
311.2093506	1.40
312.3922424	1.17
313.296875	2.39
315.3859253	4.70
318.8207397	0.34
321.3250732	2.84
323.3442993	6.50
325.0899963	0.53
327.3998413	0.13
332.3143921	0.14
337.2680664	0.31
339.2442017	100.00
339.9787598	0.56
341.3298035	24.28
355.2026062	0.14
357.0365295	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.0474
Annotation	UDP-glucose Disodium Salt
Peak:m/z	Relative Intensity
163.1094208	0.02
177.092453	0.02
180.8391571	0.03
181.9553528	0.15
193.0678406	0.08
211.0446167	2.60
219.842514	0.03
241.0885773	0.85
259.0626831	0.03
273.0924683	0.14
280.0087891	1.41
281.0093384	0.03
305.1836548	0.22
321.0304565	0.55
323.0389404	100.00
385.0309448	2.08
390.7871704	0.03
396.6017456	0.03
403.0995483	2.88
409.8291016	0.05
428.6634521	0.01
445.085144	0.10
467.1473389	0.07
478.6854248	0.98
479.489624	0.03
480.6813354	2.61
518.8644409	0.18
522.0887451	0.33
547.1233521	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	557.2238
Annotation	Abelioside A
Peak:m/z	Relative Intensity
540.2478638	100.00
540.9487915	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.1568
Annotation	Unknow
Peak:m/z	Relative Intensity
146.9507904	1.04
164.9697266	100.00
239.3002625	0.13
267.0961914	0.06
471.2883911	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	434.2007
Annotation	Unknow
Peak:m/z	Relative Intensity
122.9813690	0.70
132.8560486	0.07
136.0108032	6.16
136.9929199	0.02
144.7067871	0.03
146.9958191	3.80
157.1456604	0.05
163.0021515	0.04
165.0214539	17.25
182.0000305	100.00
184.2026672	0.02
216.9292297	0.01
239.3461304	0.02
251.9692078	0.07
253.3263245	0.06
267.2283936	0.02
270.3652039	0.08
272.2090759	0.09
287.4640808	0.04
302.2532959	0.15
308.7624207	0.01
312.3250122	0.11
317.0267334	0.03
328.9078369	0.10
335.4786682	0.11
338.0997925	0.07
363.5541077	0.04
390.3772278	0.06
396.8644409	0.06
398.2492371	0.10
413.9735718	0.04
416.0757141	0.49
416.6782532	0.01
425.3410339	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	636.19
Annotation	Unknow
Peak:m/z	Relative Intensity
221.1418762	0.07
221.9533844	0.10
249.1491394	0.06
251.0063324	0.04
280.9177856	0.03
324.1641235	0.04
340.9973755	0.43
341.8912964	0.10
342.5744629	0.03
473.2507935	0.33
503.2247925	100.00
504.1997681	43.67
504.8451538	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.17
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
115.1809921	0.33
137.8109741	0.21
138.7979889	0.23
160.2496338	0.30
161.1537476	0.63
167.2158813	0.85
169.8614807	6.93
183.0109558	100.00
184.0605774	13.93
184.819046	0.65
197.1151428	31.50
198.1053772	12.27
199.2115479	0.34
205.3050537	0.53
211.151062	1.90
212.0151367	1.53
217.0482483	0.53
222.8392029	0.55
225.1595154	2.89
226.1626282	3.48
227.2235107	0.18
239.1947021	5.19
240.1471558	3.25
243.1356506	1.51
247.2438965	9.59
248.3404541	0.89
249.3299255	7.69
253.2541504	4.57
263.244873	0.47
264.9178162	0.62
267.2690735	10.04
269.2180176	0.58
271.1014099	0.50
274.8228455	0.50
280.6507568	1.63
283.1940002	0.61
290.9157104	2.52
293.1763	22.42
293.9924927	0.43
311.2319031	18.15
312.4277344	3.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	599.2343
Annotation	Unknow
Peak:m/z	Relative Intensity
177.0779877	0.02
179.9571686	0.03
181.3262329	0.01
182.1831512	0.05
192.0674133	0.04
192.8580933	0.01
195.1629639	0.33
196.0684662	0.11
196.9653168	0.02
209.3820648	0.06
210.1974487	0.07
211.2268066	0.23
225.1666870	0.98
282.7890625	0.03
303.2970886	0.03
313.2223816	0.02
317.2295837	0.05
318.1831665	0.02
325.2608032	0.03
331.1978760	0.04
346.2320557	0.11
347.6056519	0.02
353.2618408	0.01
357.0996704	0.74
358.3301392	0.74
359.3444214	0.92
365.4348755	0.02
369.0648804	0.02
371.2911987	0.14
373.2310181	7.93
387.2664795	0.57
388.2874756	0.47
389.1699219	1.22
389.9473267	0.01
397.2489624	0.04
399.1126099	0.02
403.3332520	0.24
415.0584106	0.05
417.3920288	0.09
418.3390503	0.15
419.2045898	0.31
427.2255859	0.48
431.3621216	0.04
436.1838989	0.03
437.2484741	0.19
439.3115234	0.03
443.5761108	0.01
459.1624756	0.05
460.2119141	0.05
460.8814087	0.01
461.5504150	0.15
471.3098145	0.06
472.7582397	0.02
473.3615723	0.01
476.9961548	0.28
478.0983887	0.26
479.1741943	1.81
489.7069702	0.06
491.1337891	0.28
503.0991211	0.08
508.3194580	0.10
509.3410645	0.17
511.2273560	0.04
525.3906860	0.02
531.3042603	0.07
533.5987549	0.02
551.2425537	100.00
552.2092896	0.01
553.2167969	0.11
554.9899292	0.04
562.2562866	0.02
563.2479858	0.19
581.1030273	2.19
581.8355103	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	613.69
Annotation	Unknow
Peak:m/z	Relative Intensity
182.6958771	0.21
214.9155121	0.10
331.6666870	0.22
338.8769531	0.23
385.1436768	0.13
386.0656128	0.34
450.8987427	0.14
452.7049561	0.04
455.8015747	0.41
471.8900757	0.44
473.4703979	0.42
485.2391968	0.46
498.3051147	1.26
499.1399536	0.35
500.1441040	0.70
506.8409424	0.19
510.1264038	0.08
514.0095825	0.20
515.7266846	0.23
516.9819946	0.61
518.2644043	0.41
519.1503296	0.23
525.7864380	0.51
531.1524048	0.06
536.0665894	0.30
537.8706665	0.06
539.9387207	1.38
540.8562012	0.56
555.9976807	0.17
556.8659668	0.40
557.7531128	0.26
559.2996216	0.89
565.8621826	2.42
566.9318237	20.82
567.8597412	100.00
568.6994019	0.63
576.5144043	0.52
584.0646362	4.02
585.1702271	29.28
586.2673950	0.56
587.6052856	0.56
588.7399902	0.33
596.4749146	0.25
604.4315796	0.78
613.9876099	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	549.2117
Annotation	Unknow
Peak:m/z	Relative Intensity
162.9357147	9.93
171.0525055	0.63
190.9929047	0.42
200.9606934	0.11
209.0335541	0.98
214.0480042	0.06
219.0809021	0.54
226.4780579	0.15
237.1227112	1.18
244.0362244	0.10
254.9340973	100.00
277.9921265	0.34
290.8277283	0.57
295.0900574	1.32
296.4223022	0.59
297.1417847	0.22
298.1700439	0.22
299.5058289	0.24
306.9934387	0.13
315.7590942	0.10
318.2269897	0.21
319.2077026	1.06
324.3115234	1.39
325.0040283	3.98
362.4725342	1.96
370.5385132	0.44
379.0231934	4.40
387.0884399	0.19
397.0619507	0.38
416.2147827	5.07
416.9602661	37.07
418.2675171	0.31
426.7998047	11.12
427.4508057	2.66
428.0682983	1.25
435.4590454	0.72
448.5810547	0.26
450.6208496	1.78
456.9392090	0.28
464.4028931	0.10
482.1145020	0.59
483.9249878	15.95
484.7799683	1.17
491.1174927	4.65
492.0055542	0.49
499.9960938	3.21
500.9485474	0.83
539.5307007	5.70
540.3053589	2.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.0026
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9644470	0.07
131.1591949	0.03
173.0167542	1.37
179.2364502	0.07
190.9915771	100.00
209.2318878	0.02
215.2143555	0.05
241.1025085	0.03
254.4378357	0.05
255.0935059	0.04
272.7237549	0.35
299.0050354	0.31
306.9720459	0.24
317.0738831	0.96
322.8453979	0.09
331.1257324	0.04
351.1803284	0.07
358.9578552	0.20
369.2820129	0.05
375.2329407	0.27
377.3100281	0.04
384.8028564	0.21
402.9585266	2.98
404.1235962	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.24
Annotation	Unknow
Peak:m/z	Relative Intensity
177.1706390	0.03
204.3081665	0.13
207.0115051	0.56
256.8882751	0.08
297.5278320	0.02
306.1978149	0.04
320.4254150	0.02
323.1361694	0.04
327.1137695	0.21
343.9914551	0.17
358.9232178	0.05
361.4179688	0.15
368.2095947	0.06
378.6538086	0.05
384.9202271	0.10
387.2058105	0.19
395.3218384	0.05
401.1060791	0.06
403.0744019	0.14
404.4236450	0.05
412.3703003	0.04
417.2864990	0.05
445.4996948	0.10
457.2843628	0.05
459.2613525	0.05
475.3965454	0.02
503.2630005	100.00
513.1987915	0.05
519.3938599	0.10
527.4063110	0.03
528.4927368	0.15
529.4907837	0.29
531.1445923	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	349.23
Annotation	Unknow
Peak:m/z	Relative Intensity
111.8965378	0.03
113.1486435	0.01
114.2704926	0.02
116.0290527	0.56
126.2806702	0.03
128.9644012	0.02
130.1122284	0.35
133.0274048	0.04
147.1599274	0.02
150.0561829	0.06
151.1802521	0.02
157.0961304	0.60
158.0357666	0.58
162.1727295	0.04
175.0358734	100.00
176.1376495	0.02
187.0886841	0.02
194.0702362	0.35
196.0323334	0.02
203.1425171	0.01
209.0574341	0.07
212.8272247	0.07
216.0667725	0.01
221.1421814	0.01
231.0831604	0.02
231.9868164	0.01
232.7286072	0.02
234.1510010	0.30
234.9715271	0.04
241.1591797	0.19
243.8921814	0.01
254.7860718	0.02
259.1633911	0.09
261.1539917	0.12
262.0944824	0.02
265.1659546	0.01
267.0983276	0.01
268.1443787	0.01
271.1197510	0.11
271.7605591	0.09
276.3268433	0.01
279.0939026	0.01
281.0803223	0.04
284.5698853	0.02
289.3590393	0.02
294.1913452	0.02
303.1288452	0.12
304.1463013	0.14
305.0118713	0.15
313.1932068	0.11
314.2066956	0.01
326.3524170	0.09
331.2069092	3.57
332.2398987	0.17
339.7307739	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
117.0008469	0.08
120.9307175	0.23
156.9475708	0.17
171.1051788	1.37
173.1038971	0.45
177.2505798	0.10
185.1128845	3.13
187.1087646	3.29
194.6014862	0.21
199.2197266	3.56
201.065979	1.51
212.6352539	0.23
213.26297	0.53
214.1556702	0.06
215.1978455	4.74
217.17453	0.49
225.1998596	0.15
227.1383362	0.41
229.0892334	2.14
230.2827759	0.16
231.3181763	0.73
241.2354736	1.70
243.0482788	2.89
245.2825317	0.34
253.2657166	0.08
255.2288818	3.05
257.272583	3.53
259.3186035	1.12
263.5523071	0.46
269.1792603	0.79
270.2839661	0.16
271.1690369	3.94
273.229126	2.61
277.1348877	0.94
281.2932129	0.13
283.1686707	2.94
285.2223511	6.79
287.2037964	2.21
288.1185608	0.37
289.100769	0.38
295.2842102	0.76
297.2922668	5.55
299.2731934	5.43
301.2339478	2.86
303.1514587	0.32
305.091156	0.20
311.2896118	1.25
313.2894897	2.28
315.2264709	6.20
319.3771973	0.07
321.1835938	2.04
323.4414368	5.44
325.3512573	1.26
339.2487488	100.00
340.2321777	0.30
341.3609924	15.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.1988
Annotation	Unknow
Peak:m/z	Relative Intensity
246.0766907	0.05
323.3358154	0.15
415.2100220	0.82
416.2945557	2.40
417.1679688	0.60
503.1942749	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.1398
Annotation	Trichogoniolide
Peak:m/z	Relative Intensity
114.8540878	0.46
117.0972137	1.34
118.0803680	0.11
119.2394943	0.05
121.2869186	0.02
131.1148682	0.18
133.2114258	0.62
142.9065247	0.09
145.2605743	0.03
148.9273834	0.25
150.9463196	0.18
154.7891235	0.04
157.1137390	0.08
158.0961609	0.11
159.0757599	0.21
171.1189728	0.04
173.1601868	8.22
177.0919952	0.24
178.0713501	0.07
185.6334076	0.14
188.8869019	0.50
198.1788483	0.25
199.2962646	0.08
211.2062073	0.37
215.3987427	0.11
217.0690460	44.09
218.2505493	0.23
219.3557739	0.14
221.3849792	0.04
222.0883179	0.04
229.2043762	0.75
231.3955688	0.08
233.3050232	0.06
239.0487061	0.10
243.2987976	0.05
245.3188171	0.73
247.3870544	0.46
255.1143494	1.16
259.2394409	0.15
261.0721130	3.39
273.1680908	24.13
279.2185059	0.05
285.2165527	0.05
289.1350098	0.56
291.2396240	23.17
292.1801147	0.06
299.3699646	0.07
303.2206421	0.12
305.2574768	0.24
306.2441406	0.13
317.1860657	67.47
318.5448608	0.42
331.4553223	0.05
333.0971069	0.96
335.2132568	100.00
336.1084595	0.21
343.3059692	0.65
351.1878052	0.35
361.2750244	32.76
362.3784485	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	586.91
Annotation	Unknow
Peak:m/z	Relative Intensity
273.0352173	1.46
340.8760986	0.07
359.0618896	0.08
387.0795898	0.45
402.9755859	0.03
406.1978760	0.10
427.0462036	7.20
428.9338989	0.52
430.1487427	0.05
431.0767822	0.12
432.9995728	0.08
456.9671021	0.11
470.9701538	0.09
472.9381104	5.18
476.5654907	0.07
482.0044556	0.10
485.2210693	0.07
485.9639282	0.05
500.7777710	0.04
501.9704590	0.16
503.8908081	0.03
513.0305786	0.20
513.8779297	0.13
514.9187622	0.20
517.7614136	0.09
530.0819702	0.11
540.7979126	100.00
541.4204712	0.27
542.2533569	0.07
543.0159912	0.28
554.9505005	0.13
556.3021240	0.10
557.2615967	0.12
559.1235352	0.15
568.9801025	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	699.3802
Annotation	all-trans-Heptaprenyl diphosphate
Peak:m/z	Relative Intensity
262.0225525	0.06
280.2952576	0.46
320.5987549	0.10
377.0820312	0.06
397.2304688	12.61
415.3671875	1.69
417.4404907	0.11
423.2565308	0.09
437.1591797	0.15
487.3120728	0.06
497.8320312	0.57
545.4878540	0.28
601.3259888	0.06
623.4097290	0.09
635.5681763	0.08
636.5187988	0.21
639.6290283	0.25
641.4120483	0.35
653.2760620	100.00
657.6065063	0.06
663.5111694	0.13
680.4856567	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.92
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9763184	1.56
159.8690186	1.22
160.9940186	1.61
161.9602203	0.25
198.8816528	0.46
200.1186676	0.09
200.8874207	0.82
202.0563812	0.31
217.0279541	0.33
217.8417664	0.30
218.9163055	0.20
229.1963043	0.17
230.0312195	0.19
231.0251465	0.70
232.2498169	0.26
272.9454346	17.39
273.9403381	30.66
275.0044861	33.43
276.0052185	18.80
276.6163330	0.45
325.1780396	0.06
387.1078186	6.03
387.9461365	39.80
388.8949280	55.16
389.8952332	100.00
419.2062378	0.30
430.0776978	0.19
449.0209045	0.09
457.9965210	0.51
458.9126587	1.14
477.0633850	0.11
486.1348572	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	775.2659
Annotation	Formylmethanofuran
Peak:m/z	Relative Intensity
289.1695251	2.47
323.1621399	100.00
323.7738647	0.25
329.3081055	0.29
353.3021240	0.34
375.4797363	0.25
389.4086914	0.14
397.2117310	0.20
405.2053223	0.39
406.0462646	0.09
445.5164795	0.15
451.2269287	13.31
452.0462036	0.08
466.4429321	0.07
479.4585571	0.10
512.2131348	0.12
527.2773438	0.16
533.1207886	0.10
534.9160767	0.15
540.9226074	0.13
567.0140991	0.33
568.2504883	0.16
585.3681030	0.14
613.0939941	0.54
629.0482788	0.06
631.3088989	0.23
642.1137085	0.16
643.4279175	0.07
686.4782715	0.16
692.5334473	0.30
695.2419434	0.25
730.6528320	0.40
731.3654175	0.22
757.3596802	0.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	511.2183
Annotation	gibberellin A2 O-beta-D-glucoside
Peak:m/z	Relative Intensity
158.9859009	1.49
161.0208282	2.24
178.6136017	0.44
183.1543274	0.28
215.3404083	0.29
231.3426819	0.33
243.3115234	0.52
257.2655029	0.18
259.2789917	0.13
261.1085205	3.25
269.2607422	0.31
275.0021973	1.79
287.2103882	6.89
289.4303589	0.30
301.2508545	1.04
303.3064575	0.73
305.1568604	10.30
305.8523560	0.31
313.0222778	0.22
319.2294312	49.98
329.1423950	0.56
331.2589722	6.13
333.4240112	2.45
343.1106567	0.37
347.1950073	0.29
349.2557983	70.73
357.2573853	0.37
361.2276611	9.30
391.2656860	18.75
405.4365234	0.37
419.4644775	0.28
421.2663574	27.61
423.2406006	1.48
449.3025513	1.52
451.2500000	32.43
467.2730713	70.02
476.0399780	0.22
481.2061157	100.00
481.8417969	0.10
493.3765869	2.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	182.0806
Annotation	4,6,7-Trihydroxy-1,2,3,4-tetrahydroisoquinoline
Peak:m/z	Relative Intensity
109.9102631	0.04
118.8637238	0.06
123.1734467	0.02
136.0710602	24.11
140.8341827	0.01
147.1565399	0.05
150.0146637	0.04
158.6595459	0.03
164.9489899	100.00
165.7353973	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	443.1769
Annotation	Unknow
Peak:m/z	Relative Intensity
167.0757599	0.08
190.9559021	0.12
218.3323975	0.06
225.2846680	0.04
230.6716461	0.07
234.1200409	0.06
251.3815613	0.05
278.1522522	0.87
299.1772461	0.05
309.1583252	0.04
341.3116150	0.07
353.1103210	0.10
379.1937561	0.11
380.9345703	0.21
395.3381042	0.05
397.2129211	100.00
399.1701355	0.19
408.2028198	0.18
426.2773743	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.1289
Annotation	Psilostachyin C
Peak:m/z	Relative Intensity
82.8277435	0.08
101.2140198	0.07
108.9890137	0.02
110.9877930	1.99
121.1275787	0.11
123.0240631	0.08
124.8008118	0.10
136.1819000	0.09
137.9636078	0.42
139.0774078	0.15
150.9095459	0.12
153.0129700	100.00
155.0781860	0.04
161.1381836	0.69
171.1223907	0.04
174.9510040	0.03
176.1126862	0.04
177.1258850	0.22
181.2923431	0.06
184.9376068	0.04
186.1123657	0.07
188.9171295	0.18
190.9145508	0.05
192.9861908	0.08
201.1620483	3.40
203.1282196	0.18
204.0742950	2.31
211.3148346	0.02
217.0587006	0.19
218.0304718	0.05
219.2310791	32.60
220.6928253	0.22
221.3103333	0.03
224.6916962	0.09
227.2478790	0.06
233.1940460	0.06
235.0435791	0.05
243.2665863	0.12
244.2114258	0.09
245.0807648	1.83
245.9236298	0.04
247.0768433	0.03
247.9930573	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	407.1723
Annotation	Ethotoin
Peak:m/z	Relative Intensity
115.9117966	0.03
121.9878922	0.04
123.0627670	0.06
125.3105392	0.08
131.2699432	0.08
132.0516510	0.03
142.1790314	1.02
147.1358948	0.05
157.0697479	0.18
159.2008057	1.32
160.9484863	0.24
161.7850037	0.31
166.0241089	0.04
173.1179810	0.07
179.0484619	0.27
181.1759949	0.04
183.3237915	0.02
186.1267395	0.34
192.2332153	0.06
199.0831604	0.65
203.0651703	100.00
203.9632263	0.08
209.0842896	0.03
211.3345947	0.04
225.1257324	0.27
227.0051422	0.04
231.3161316	0.16
235.9242554	0.05
243.2499695	0.26
244.1332703	0.16
245.2218628	0.53
246.9530640	0.02
250.5903625	0.38
253.0687866	0.14
255.0700989	0.12
256.1366272	0.10
260.8912964	0.27
262.3294373	0.02
269.3448792	0.03
270.2079773	0.06
271.1137390	0.05
273.0968018	0.03
277.4291992	0.03
278.8692627	0.04
281.0112305	1.03
282.0811462	0.02
283.5447998	0.24
284.2233276	0.13
285.2215881	0.55
286.0942383	0.06
292.3366699	0.03
297.2840881	0.08
301.3372192	0.14
305.3065491	0.04
307.1250305	0.04
309.0832825	0.24
309.9585876	0.06
321.1118469	0.03
323.1089172	0.10
327.2416687	0.14
328.2250366	0.08
329.1315002	0.24
333.2722168	0.19
335.1495056	0.02
339.1876831	0.10
340.1956787	0.11
346.0752563	0.29
347.0625000	0.30
349.1996155	0.15
361.0794373	1.35
362.1279907	0.08
363.2738037	0.87
364.3571472	0.04
371.1471558	0.05
372.2944641	0.16
378.5591736	0.05
387.2423096	0.07
388.2365417	2.61
389.2544250	3.33
393.2289734	0.04
398.5351868	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.85820007	0.53
79.06319427	0.49
81.03283691	1.02
82.85417938	0.28
84.84074402	0.49
91.16040039	1.37
94.94742584	1.57
96.93891907	1.84
101.1665955	0.16
102.9016113	1.28
103.824707	0.15
104.8943024	1.78
107.0509186	1.51
109.0297852	1.00
110.1168671	0.21
111.0305786	1.40
113.0676422	0.62
114.9885101	0.62
116.0453644	0.06
119.0141602	0.72
121.0520935	0.78
123.047699	3.51
124.9497528	0.28
126.902298	0.92
128.9702759	6.83
130.1238861	0.07
130.9224701	0.13
133.172699	0.19
135.1233521	1.80
137.1598511	1.45
139.1268005	1.05
141.0449066	1.30
142.062439	1.10
143.0611572	0.33
144.9838715	0.50
147.1156464	1.45
149.2263947	1.01
150.9537354	52.19
151.9573212	5.07
154.8937531	0.85
156.9466705	0.93
158.9639587	0.99
160.9352264	1.00
163.0630035	1.52
165.0475769	0.84
165.9713898	0.46
167.0599365	2.31
169.2479095	1.15
171.173111	0.78
175.0600128	3.18
177.1458282	1.13
178.1036682	0.89
178.9974823	1.11
181.1286163	0.62
183.1741791	1.38
184.0496674	0.47
184.8859406	0.88
189.0555725	0.28
189.9620514	0.10
191.3479309	0.29
193.0295258	1.85
193.9167175	1.16
194.8699036	1.00
197.1426849	7.55
198.1380463	0.34
198.8447723	0.91
205.1549988	0.29
207.1259308	3.49
209.0724182	0.88
209.9436493	0.35
211.0427704	3.25
212.3065643	0.29
217.1742249	8.57
223.281601	0.08
225.2366791	12.34
226.1142426	0.21
235.2039032	27.32
236.2221832	0.64
238.0541382	10.67
239.2157135	1.32
253.0811615	100.00
254.1813965	19.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	791.8976
Annotation	Unknow
Peak:m/z	Relative Intensity
227.0357208	0.39
232.2017212	0.84
247.1237793	0.43
252.3863220	0.23
258.2318420	0.07
282.4364014	0.36
300.0621338	0.52
312.1125183	0.08
313.2879028	0.10
316.2960815	0.27
326.3306885	2.77
331.4430542	0.05
354.0572815	0.26
357.9904175	0.49
369.4389954	0.16
390.1798706	0.13
398.1472168	0.26
407.2676392	0.25
415.2113647	2.26
416.1611938	2.43
418.4279175	0.23
423.5517578	0.07
425.9047241	0.23
429.2186890	1.97
439.1551514	0.41
440.4962158	0.81
441.3852539	2.21
444.0048218	0.06
446.3586426	0.11
458.3243408	49.90
459.4129639	0.26
486.2541504	0.06
491.8632812	0.14
509.0921631	0.07
509.7567139	0.10
510.4163208	0.14
528.2265625	6.13
553.2120361	0.15
554.5529175	0.59
564.4067993	0.10
569.1584473	0.25
571.3818359	7.06
572.1324463	0.27
580.3573608	0.20
581.3416138	0.06
594.0662231	0.09
595.3881226	0.60
597.5844727	0.17
599.1903076	15.43
599.8370361	0.05
601.5326538	0.52
609.7173462	0.70
618.4328613	0.17
626.2410278	0.17
627.6272583	0.30
630.1942749	1.18
640.5640259	0.09
642.3979492	1.38
655.3588257	0.08
657.2833252	0.73
658.0651245	0.13
666.4769897	0.65
668.1918335	1.04
669.4393921	0.74
670.3783569	0.25
676.3132935	0.44
686.2145996	16.31
687.3125610	0.73
688.1241455	0.18
694.3681030	19.55
695.2860718	0.61
697.6276245	0.85
702.3145142	0.23
704.0645142	0.24
711.7282104	1.06
712.4053955	0.49
713.3422241	0.33
716.8354492	5.43
718.6341553	0.16
725.8877563	65.23
727.5575562	1.32
729.3119507	1.14
730.4303589	0.87
731.3900757	0.58
732.0418091	0.21
732.9772339	0.24
739.1970825	86.55
740.2622070	2.12
741.4952393	0.10
746.3828735	0.28
748.5528564	0.86
757.0733643	66.09
758.0503540	1.76
758.7680054	0.06
765.3793945	5.56
770.1069946	0.41
774.3448486	0.51
796.0673218	0.12
808.6062012	0.74
809.6121216	0.19
822.7803955	1.08
826.4243774	100.00
827.4534912	4.71
846.6843872	0.33
852.1322632	1.54
852.9127808	0.13
853.6032715	0.41
854.2654419	0.12
880.3793335	0.22
897.3644409	13.50
898.5544434	0.08
900.5698853	0.13
905.2832642	0.50
913.8710327	0.17
921.6328735	0.20
923.3621216	0.72
940.5998535	0.53
941.3364868	0.10
966.5729370	0.84
981.3003540	0.30
984.2940063	6.32
984.9611816	0.25
989.3195190	0.35
990.1212769	0.78
994.1278687	6.65
1004.0820920	0.32
1009.0117190	0.20
1012.3232420	5.51
1013.3313600	0.52
1054.0234380	0.27
1055.4837650	1.86
1070.3946530	0.16
1072.6341550	0.31
1077.0329590	0.76
1107.3974610	2.79
1124.6652830	6.45
1125.3477780	65.27
1126.1842040	2.34
1151.5576170	0.49
1154.3433840	0.71
1155.0595700	0.21
1222.2023930	0.75
1239.4241940	0.19
1333.5625000	0.25
1342.4818120	1.17
1351.1922610	1.01
1449.5931400	0.76
1450.4484860	1.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	925.9683
Annotation	Unknow
Peak:m/z	Relative Intensity
258.9934692	0.43
277.2720337	0.38
312.9891968	0.49
371.3806152	0.34
383.2146606	0.68
387.2248535	0.98
390.1886597	0.89
397.3342896	0.95
415.3784180	1.00
416.1292725	0.16
422.2809448	0.79
455.7054443	0.51
471.9671021	1.15
496.9346924	0.57
500.3886719	0.42
501.4729004	0.14
508.3079224	0.22
514.2763672	0.52
518.5842285	1.13
526.2636719	0.22
542.1096191	0.15
544.2188110	0.26
577.9414062	0.54
589.0535889	0.15
592.2606812	0.38
596.8117065	0.44
599.3422241	0.32
605.8021240	3.08
606.6782837	0.21
629.4327393	0.35
638.1185303	0.11
643.6059570	1.23
644.3891602	0.67
647.5668335	0.51
660.9743652	0.58
661.7772827	0.10
668.3390503	0.19
669.1567383	0.30
669.8909302	0.34
679.1345825	9.40
679.8733521	1.77
696.6235962	1.47
697.5170288	0.72
706.7266235	0.31
717.0404663	0.20
739.8703613	7.90
743.4390869	0.88
744.3351440	1.18
746.8815308	0.41
749.9440308	1.87
755.4278564	0.55
758.9061279	0.14
777.6205444	0.39
780.3000488	0.64
782.5265503	6.04
783.2573853	1.47
784.2998657	0.16
814.9232788	0.64
825.4257202	1.12
826.4091187	0.94
829.2103882	1.72
829.9556274	0.32
831.1790771	0.16
838.4138794	1.05
839.5277710	0.76
840.4573364	0.41
843.3970337	10.87
844.4812012	5.96
845.5330200	0.46
848.0850220	0.48
849.9871826	2.28
857.1510620	3.51
859.2722778	0.45
862.0541382	0.28
865.9130249	1.32
866.8252563	0.07
867.6506348	0.78
870.5130615	0.35
872.0163574	4.67
877.8643188	0.87
882.5980225	0.80
883.3055420	0.21
889.6896362	50.31
890.7686768	0.21
891.7307739	0.54
892.5254517	0.98
894.4171753	0.09
896.1503296	0.68
899.0305786	0.39
905.3602905	1.35
908.6162720	1.01
909.3768921	0.72
913.5014648	0.16
914.5139771	1.17
942.0613403	1.20
943.6017456	1.59
944.3654785	0.86
945.2925415	0.20
948.1945190	0.47
951.7098999	0.49
952.4428711	0.33
953.8342285	21.74
954.6876831	3.63
955.5400391	2.16
956.2873535	0.49
966.4365845	0.56
969.2329712	0.31
986.2979126	0.53
988.1599731	2.03
1001.6411130	0.60
1007.4690550	0.13
1008.5700070	0.13
1017.5636600	1.73
1018.9602660	3.82
1019.5861820	6.34
1023.6102910	1.03
1025.7500000	0.53
1052.9621580	2.46
1053.7797850	0.08
1056.6777340	1.12
1057.8441160	0.40
1059.5209960	3.16
1060.4914550	0.65
1062.4122310	12.28
1068.1623540	1.08
1071.6738280	1.32
1075.0319820	0.52
1075.9150390	0.36
1081.0969240	0.27
1088.5469970	0.82
1100.3027340	0.43
1102.3226320	0.61
1104.5217290	0.40
1105.1979980	9.13
1106.3103030	0.57
1106.9519040	0.32
1108.6613770	8.88
1109.5982670	2.59
1110.3754880	1.10
1113.5177000	0.22
1118.9395750	2.40
1124.4007570	1.72
1125.3842770	0.65
1131.0640870	2.79
1132.5302730	0.72
1137.0595700	0.16
1142.7674560	100.00
1143.5153810	12.99
1144.4522710	0.64
1145.3758540	0.51
1148.9321290	0.72
1154.6230470	0.42
1164.0913090	0.28
1164.8515620	0.24
1173.4058840	26.75
1174.3652340	13.01
1177.9812010	1.68
1178.9384770	0.27
1179.7363280	1.63
1183.3670650	0.21
1184.8575440	0.77
1185.8311770	32.87
1187.0770260	1.38
1188.4150390	0.36
1206.5307620	0.86
1209.5703120	1.45
1210.3518070	1.16
1215.5799560	0.85
1222.4208980	0.67
1236.7265620	0.44
1238.5815430	0.21
1241.3410640	0.14
1250.6392820	1.37
1264.9155270	0.41
1265.7365720	1.63
1271.8393550	0.30
1273.9591060	0.85
1294.6634520	0.17
1309.6500240	0.99
1315.8048100	0.39
1320.7325440	0.94
1321.7946780	0.26
1339.7232670	0.17
1356.6864010	1.49
1357.6704100	1.25
1358.5845950	1.26
1367.8016360	0.22
1380.4617920	1.44
1381.0804440	5.23
1409.7989500	0.37
1411.0455320	0.59
1412.3189700	0.88
1420.7105710	0.50
1430.1187740	3.71
1430.9874270	4.16
1431.8004150	0.20
1438.5462650	0.48
1468.9182130	0.14
1476.9888920	0.15
1485.3674320	0.55
1486.9034420	0.38
1507.9178470	0.40
1509.8808590	0.22
1536.6298830	0.25
1558.2784420	0.85
1573.2427980	0.69
1592.7673340	0.24
1661.9309080	0.09
1664.2312010	0.09
1697.8737790	0.36
1718.1867680	0.17
1731.1691890	0.50
1761.1834720	0.32
1805.6138920	0.13
1878.9748540	0.20
1915.5338130	7.52
1962.2777100	0.25
1978.9669190	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.187
Annotation	Abelioside A
Peak:m/z	Relative Intensity
154.5280457	0.15
155.2051086	0.48
157.2735138	0.23
168.8322906	0.21
170.9630585	0.11
179.2366638	0.14
182.0353699	0.15
182.8687744	0.23
193.8532715	0.10
195.9428406	0.12
197.3867798	0.13
199.0997009	0.62
200.1971130	0.05
206.1896362	0.21
209.0594482	0.11
211.2097931	1.02
212.0562439	0.05
219.3168793	0.14
221.2126312	2.16
222.0617676	0.11
223.2056732	0.32
224.2601013	0.18
237.0859985	1.73
239.1552124	29.32
240.1139526	0.03
254.9682617	0.06
265.3466187	0.44
281.0876465	0.14
283.1574097	100.00
284.1665039	0.17
285.1430359	0.09
299.1498413	0.04
301.3140564	1.28
315.2737122	0.06
325.1623535	0.07
327.1953125	64.66
328.3937988	0.19
329.1834717	0.08
343.3223877	0.30
345.2285461	0.32
347.2793274	0.07
371.1368408	0.02
384.8606262	0.05
387.4057007	0.05
445.4334412	0.38
463.3456726	0.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	400.1592
Annotation	Unknow
Peak:m/z	Relative Intensity
115.1372070	0.06
116.9777145	0.38
120.1243820	0.04
132.1058502	0.06
136.3704834	0.09
144.9820251	4.61
149.1076813	0.11
152.7552185	0.04
161.3016052	0.06
162.0880432	0.29
176.9564209	100.00
179.1902161	0.03
188.8575439	0.10
189.8704376	0.39
191.8939972	0.30
192.8928223	0.16
194.6371307	0.06
195.3499146	0.09
200.2727661	0.11
202.9372559	0.12
204.1125031	0.03
205.2028198	0.10
207.0365143	0.03
215.1430511	0.13
217.2851257	0.05
221.0400085	0.58
227.0894470	0.05
233.1827698	0.05
238.0724792	77.56
239.2147217	0.10
244.2925720	0.03
244.9078369	0.04
245.9797058	0.07
247.3281555	0.12
250.1507263	0.41
253.1904297	0.10
255.2488098	0.10
261.0308533	0.62
262.2733154	0.13
263.0126343	0.11
265.3257446	0.06
269.0454712	0.08
283.1828613	0.13
284.3186646	0.16
285.1331787	0.16
286.2014160	0.14
291.2599182	0.16
293.2420349	0.05
296.9386597	0.04
298.3090820	0.16
301.1433716	0.29
303.2119141	0.03
308.9770508	0.05
310.3284607	0.31
311.2207642	0.04
312.0410767	0.05
314.7402954	0.03
319.2650452	0.09
321.1039429	4.40
325.1616211	0.06
325.9266663	0.18
327.1640625	0.08
339.0162354	8.31
343.7048950	0.16
347.0173340	0.19
347.8754578	0.17
349.7589722	0.16
354.1596069	0.17
355.1547241	0.88
356.1979370	0.07
358.7092590	0.16
364.1676331	1.48
365.0144348	0.05
365.9128723	0.22
368.1169128	0.06
369.1805115	0.12
370.1183167	0.32
372.0294189	0.16
373.1007080	0.16
382.1971130	0.86
383.0018921	0.42
387.7050781	0.54
390.8111877	0.80
391.5359802	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.1979
Annotation	Abelioside A
Peak:m/z	Relative Intensity
154.9877319	0.38
157.0823517	2.51
164.9577637	0.05
168.9150543	0.18
170.1934662	0.37
176.2848969	0.04
179.0589600	0.07
185.2021637	0.16
189.0515747	0.05
195.0987549	0.17
197.1628876	0.17
198.4297028	0.19
199.2169342	0.49
201.1000366	15.63
202.0779877	0.08
210.9631195	0.13
213.1395111	1.77
215.2583313	0.42
227.1011810	0.32
229.1962433	0.56
239.2505646	0.48
241.3746948	0.11
245.1587830	1.09
255.2462311	0.02
257.1875610	18.48
258.1041260	0.23
259.2173462	0.68
273.5111084	0.05
275.2534485	0.43
279.2750244	0.64
298.0555420	0.08
299.3916626	0.14
301.1840820	100.00
302.2094116	1.92
303.3121338	6.45
307.6829224	0.08
312.9492188	0.30
315.1560059	0.39
317.3853760	0.09
319.2838135	0.73
321.0296631	0.44
343.2715454	0.84
345.2485352	24.04
346.3481445	0.44
361.2864990	0.58
363.2180176	38.50
377.3695068	0.12
381.1271362	0.06
383.1855469	0.06
385.1187134	0.13
387.1836548	0.28
389.5754395	0.08
405.1899414	7.78
409.1093140	0.08
419.3545532	0.26
435.1543579	1.76
437.3341064	2.63
445.3545532	0.17
447.3811035	0.49
452.0616455	0.05
463.1749878	1.22
465.2440796	14.93
479.0270996	0.07
481.2874146	5.85
482.3728638	0.14
489.3069458	0.66
495.3720093	0.17
507.3298340	18.97
508.3385620	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	573.255
Annotation	Canavalioside
Peak:m/z	Relative Intensity
175.1859131	0.04
178.9758606	0.17
259.2863770	0.02
345.3161011	0.08
347.3565063	0.91
349.3193970	0.04
362.0112305	0.03
365.3571777	2.62
375.2161255	0.02
379.2880859	0.01
381.3167725	0.01
387.3678589	0.02
391.5752563	0.06
393.3632202	0.04
399.1614990	0.11
407.4099731	0.08
411.3562622	0.10
425.1752319	0.07
431.2860107	0.01
437.2514038	0.10
452.6456909	0.04
455.3138428	0.02
465.5645752	0.11
469.2127075	0.07
482.5389404	0.06
483.3250732	0.03
496.9968872	0.05
508.4879761	0.19
509.4252319	0.46
513.6708374	0.07
525.1240845	0.09
527.2933960	100.00
527.9232178	0.24
537.2355347	4.62
537.8449097	0.03
542.7842407	0.02
553.3441162	0.08
554.0980835	0.18
555.2977905	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	987.4224
Annotation	Unknow
Peak:m/z	Relative Intensity
449.0013428	0.27
493.3548889	100.00
622.3389893	0.19
787.7122803	0.28
836.4605713	0.24
942.4656982	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.1706
Annotation	Thymifodioic acid
Peak:m/z	Relative Intensity
105.1847610	0.04
110.9708099	0.03
119.9803085	0.03
120.8818054	0.02
131.1234589	0.05
132.9565430	0.07
135.1320801	0.05
137.1938782	0.05
149.1028748	0.10
151.2733459	0.05
155.1022949	0.03
161.0751343	0.06
163.0276489	0.05
165.0943298	0.36
167.1922302	0.05
175.1652374	0.15
176.0481415	0.05
177.0404816	0.14
185.0521240	0.20
187.2020569	0.12
191.3551331	0.03
193.1192932	0.03
195.2128448	0.04
197.3778534	0.18
199.0564575	0.05
203.1596680	0.24
209.2940369	0.11
211.1807556	0.10
213.1454773	0.13
215.3516541	0.05
216.0718079	0.05
218.7592468	0.03
219.9826965	0.03
221.1146851	0.07
223.3761292	0.04
225.1677246	0.06
227.0529175	0.33
229.2512817	0.13
230.1532593	0.05
230.8780212	0.09
233.1964111	0.03
235.1896667	0.16
237.2350464	0.04
239.1542969	3.94
243.1520081	0.24
245.2301025	2.30
251.1335144	0.14
253.3099365	0.69
255.2399292	2.13
257.2463989	9.58
258.0430298	0.39
259.1554565	0.12
265.2343140	1.58
267.1784668	0.05
271.2706909	1.20
272.4131470	0.47
273.2393188	1.55
274.1370239	0.32
281.2679138	0.08
283.2624512	9.53
284.3455811	0.08
285.2405396	0.03
293.4624329	0.05
297.3051758	0.12
299.3107300	2.38
301.1828003	100.00
302.2191467	2.11
309.0615234	0.43
310.1722412	0.02
327.3389282	3.01
328.3194580	0.09
336.9693909	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	544.2375
Annotation	Abelioside A
Peak:m/z	Relative Intensity
156.9622040	0.10
165.8777466	0.07
177.3550110	0.04
179.7249603	0.14
184.0428467	0.04
187.1398926	0.03
211.1711121	0.10
215.1766663	0.29
230.8228912	0.06
235.0286255	0.03
239.1380310	0.05
255.0236359	0.02
257.2083130	1.41
272.9998779	0.09
283.1016846	1.31
287.0868530	0.03
295.5402832	0.07
301.0653687	0.53
313.2230225	0.08
315.0293579	0.13
319.0955811	9.16
329.1964722	2.48
347.0384521	100.00
348.1308594	0.09
351.2546997	0.31
358.0718384	0.04
360.2714233	0.05
361.4497681	0.06
365.0223389	49.98
367.2998047	0.09
369.3335571	0.04
371.5584106	0.03
374.2420654	0.24
381.0950928	0.05
382.1488037	2.98
387.9838257	0.02
390.3931885	0.08
412.4197998	0.06
415.3930664	0.02
423.3652344	0.05
431.6181030	0.03
458.4325562	0.31
463.1489258	0.59
474.8657227	0.13
478.5215454	0.07
482.3733521	0.17
492.1734619	0.01
500.0076294	0.05
509.1715698	0.15
510.8648071	0.07
520.9865723	0.38
523.6129761	0.14
526.1716919	0.62
527.2477417	0.18
535.2035522	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	365.1967
Annotation	Sporotrichiol
Peak:m/z	Relative Intensity
115.8979492	0.02
123.0353241	0.04
141.7559814	0.02
153.0925903	0.02
160.0774231	0.05
161.1255188	0.07
163.1579285	0.03
165.0912170	0.05
167.1051025	0.15
175.0881653	0.13
175.9672394	0.09
176.9788208	0.09
178.9458923	0.10
181.0813751	0.06
185.1524811	0.02
186.2306366	0.01
189.1783295	0.07
197.2443542	0.34
211.2172394	0.14
215.1726379	0.14
217.1916504	0.06
219.1312866	0.02
223.2607727	0.28
224.3104858	0.02
229.3645020	0.17
230.9715576	0.06
235.1605530	0.06
238.1241760	0.09
239.6473694	0.09
241.2167053	0.23
243.3239746	0.35
245.3645325	0.40
247.3728333	0.51
249.0870361	0.07
257.1059570	1.39
259.2730408	0.38
261.2614136	0.20
265.3212585	0.03
267.2464294	0.17
269.5030823	0.01
271.4531250	0.03
273.2142944	0.87
275.2850952	11.99
277.3359375	0.15
279.1813354	0.04
283.2958374	0.12
285.2301025	1.49
286.9612427	0.38
289.1738892	0.15
290.0707703	0.25
291.2001343	0.53
293.5084839	0.04
296.2335815	0.05
301.3133545	0.81
303.2201233	4.80
304.2628784	0.03
305.3112793	0.27
308.0886841	0.01
310.9674683	0.05
319.1698608	0.78
319.8403931	0.01
321.2797241	55.24
322.3059082	1.94
329.0739746	0.25
330.1730042	0.27
331.1769409	0.42
335.2746582	0.20
337.3264771	1.61
345.0419006	0.14
347.2290955	100.00
348.2733154	4.01
349.0851746	0.07
366.6522522	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	527.2136
Annotation	Dutasteride
Peak:m/z	Relative Intensity
151.2107239	0.55
158.8938904	0.49
160.9834900	2.87
169.1962128	0.64
179.1642761	1.28
203.4179993	0.51
213.0611420	1.57
216.7993469	0.23
223.2761536	0.60
227.4663391	0.31
229.1860046	1.32
235.2554321	0.30
238.9185028	2.02
239.5212860	0.17
240.1956177	1.59
241.3735352	2.30
243.1940002	0.74
247.2296906	2.69
255.1635437	0.64
257.1275024	1.20
258.1072388	0.30
259.3206177	2.24
265.2907715	1.72
273.3917847	0.68
275.1434937	0.51
277.2600098	11.40
283.1118164	0.42
285.1593628	0.92
289.4160156	0.16
290.7434692	0.53
293.2309875	0.90
302.1996765	1.09
303.2753906	3.98
317.0140991	0.15
319.2990112	0.27
321.2548218	9.78
323.5914307	0.31
327.1845093	0.25
328.1695557	2.16
329.3250732	0.70
331.4141846	1.16
334.1914673	0.43
336.9870605	0.36
345.2119751	3.61
346.3293457	3.55
347.3168945	9.90
361.4672852	0.46
365.1755371	0.87
366.4494629	0.18
367.1859741	0.46
383.5610352	1.15
401.3107300	0.50
413.0600586	0.23
429.2216797	0.45
431.2064819	0.22
433.3732300	0.28
439.1605835	5.02
447.3108521	1.85
453.3538208	0.16
465.3373413	13.05
466.4331055	0.76
481.3826904	1.96
483.3807983	100.00
484.3380737	1.74
489.4113159	0.45
491.1830444	4.17
497.4248657	1.04
507.2485352	0.29
509.3098755	33.83
510.3046265	1.98
518.0621338	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	765.3334
Annotation	Chantriolide B
Peak:m/z	Relative Intensity
221.3000946	0.12
239.1410522	24.60
239.9699707	0.30
243.3975983	0.08
313.1920471	0.25
345.1094971	0.12
359.3698730	0.08
373.3579102	0.54
379.3490601	0.06
380.0322876	0.24
385.3120728	0.09
391.4241943	0.07
413.2966309	0.06
426.8153687	0.13
429.3265381	0.31
463.3743286	0.16
492.9642944	0.26
505.3416748	0.55
507.4735718	0.08
521.4238892	1.37
523.2695923	0.84
525.3972778	100.00
535.4600830	0.31
536.3721313	0.23
552.9505005	0.08
557.3421021	0.12
563.2068481	0.20
571.3700562	0.05
572.3836060	0.14
583.2926025	0.22
584.7658081	0.36
588.4292603	0.22
601.5454102	0.20
603.4937134	0.87
606.3052368	0.10
607.0184326	0.12
622.5773315	0.14
629.3197632	0.06
636.5872192	0.38
663.4804077	0.24
668.9122925	0.28
679.1771851	0.36
691.3713989	0.46
695.1046143	0.07
702.4253540	0.13
705.6234131	0.27
713.0759277	0.13
717.1563110	0.48
718.6326294	0.13
721.4634399	0.72
722.3278198	0.10
734.3556519	0.15
734.9911499	0.48
736.9147339	0.07
744.7242432	0.46
747.2738037	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	658.2535
Annotation	Validamycin E
Peak:m/z	Relative Intensity
241.0187988	0.05
271.0606995	0.06
332.2368164	0.18
332.9230347	0.03
354.2292480	0.04
368.3013916	0.09
420.2312012	0.08
422.0997925	0.04
449.9288940	0.09
450.5648804	0.17
475.2938232	0.03
477.1808472	0.12
478.3333740	0.05
479.4640503	0.07
480.2855835	0.05
483.5253906	0.10
485.0862427	0.10
490.1140747	0.25
495.5405884	0.11
496.4012451	0.44
510.3505859	0.08
514.4789429	0.07
522.3085938	0.10
524.3278809	0.19
525.5324707	0.08
526.4132080	0.08
529.0815430	0.15
540.3801880	0.19
544.0646362	0.11
545.4788208	0.11
561.6614380	0.03
566.3002319	0.37
567.4547729	2.34
568.2533569	5.51
572.3946533	0.12
581.4741821	0.03
585.6442261	0.04
595.2102051	0.17
612.1385498	100.00
612.8400879	1.13
613.4685669	0.39
614.6050415	0.07
622.1864624	0.43
630.6218872	0.05
639.4758911	0.06
640.1482544	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.1608
Annotation	3-Methyl-3-butenyl apiosyl-(1->6)-glucoside
Peak:m/z	Relative Intensity
117.2375793	0.25
125.1777649	0.04
143.1583862	2.71
145.1497192	0.23
155.1134644	2.33
157.2475433	0.13
158.8614197	0.07
171.0823059	0.04
173.1993561	0.76
177.1007538	0.10
179.0112610	0.08
187.2117615	0.15
188.9640045	0.12
195.0678406	0.07
199.0214233	2.18
201.0767517	0.03
215.3692322	0.06
217.0853729	100.00
227.0502930	0.29
229.2167664	0.34
231.4257507	0.06
233.2093811	0.16
234.9017944	0.12
237.2166443	0.21
241.2500000	0.03
243.2758789	0.80
244.9893799	0.11
247.0185242	1.28
249.1802673	0.13
255.1699219	0.72
259.1940308	1.18
261.0998535	1.38
262.3862915	0.15
263.2975159	0.13
269.1949158	0.08
271.3227539	0.33
273.1461792	7.55
275.3531494	0.44
279.1979980	0.10
281.4069214	0.14
283.1814575	0.06
287.3696899	0.11
289.2568665	0.56
291.1746826	4.80
293.0999146	0.28
299.2181396	0.38
301.0440674	0.04
305.1471558	0.04
307.3276062	0.40
313.3427429	0.17
317.1968079	20.19
319.2439575	1.64
333.2020264	0.97
335.2040100	42.05
341.1683350	0.20
347.1778870	0.08
349.3764648	0.22
351.2376404	2.86
359.2444458	0.11
361.1306458	19.88
361.8148804	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	483.14
Annotation	Unknow
Peak:m/z	Relative Intensity
140.9910583	0.15
184.1809998	0.53
202.1504822	0.60
253.0761719	0.28
256.2103577	0.06
262.1592407	0.10
263.0455017	0.04
263.8994751	0.68
278.0131226	1.11
280.1828003	0.68
282.0115051	1.22
293.9997559	0.41
295.1700134	2.03
296.1130981	0.08
301.0736389	0.11
303.0489502	0.38
304.9378052	0.05
306.0236206	0.04
307.0783691	2.05
308.0360107	0.44
312.7208862	0.06
315.2056885	0.33
317.8872681	1.43
320.0838623	0.07
321.1224976	1.35
324.0727539	0.42
333.1850586	0.20
335.4746094	13.83
336.1865234	71.67
337.2937622	0.09
345.1198120	0.22
347.2334595	0.79
348.0141602	18.40
348.6947632	0.34
351.9931641	0.20
353.1231995	34.75
353.8930664	2.90
354.6091614	0.16
361.2241516	2.29
363.0051270	2.55
363.9873657	0.18
365.1001587	2.71
366.1038513	100.00
366.8977661	0.08
374.9965210	0.17
376.1103210	0.16
376.7389832	0.14
379.3031616	0.13
381.0616760	0.27
391.2026672	0.12
393.3095703	2.93
394.1257019	28.65
399.2732849	0.27
407.2737732	0.87
409.1479797	0.24
411.1408386	3.09
412.0560608	0.08
417.0984192	2.42
418.6021423	0.58
419.2658691	1.92
423.2381897	0.65
429.3151550	2.23
430.1375427	0.23
435.1898499	3.83
437.1613159	0.40
438.2953796	0.22
440.5132751	0.06
441.5930176	0.06
447.1385803	30.18
448.1042786	0.63
451.0825195	0.12
453.6254578	0.09
463.5254517	0.19
465.1879578	97.08
466.1663513	1.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	687.3226
Annotation	Wattoside H
Peak:m/z	Relative Intensity
254.1196747	0.06
256.7921753	0.08
257.3961792	0.14
299.2971191	0.20
325.0546570	0.34
337.3421631	0.07
345.2055054	0.25
363.2330322	1.06
364.5383911	0.10
393.2435303	0.24
397.2346802	0.08
415.4313354	0.10
436.3686523	0.16
463.3884277	0.05
479.2934570	100.00
495.4556885	0.07
499.0410156	0.07
505.2210693	0.26
507.4193726	0.12
519.3756714	0.13
524.3734131	0.70
525.5979614	0.03
541.2877808	0.16
563.0405884	0.08
569.5236816	0.11
579.1978149	0.33
583.0458984	0.23
583.7918091	0.16
601.1821289	0.32
603.4970093	0.11
623.2467651	0.11
627.0271606	0.23
640.4671021	6.54
641.1076660	53.34
642.2387085	0.23
643.4457397	0.49
645.7396851	0.18
649.4393921	0.15
651.1370239	0.13
654.5864258	0.15
656.4530640	0.15
657.4264526	0.16
668.4611206	0.05
669.2301636	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	640.2941
Annotation	Unknow
Peak:m/z	Relative Intensity
195.0707092	0.16
197.2213593	0.53
202.1340790	0.10
203.7711334	0.21
209.2807312	0.22
211.2596283	0.42
219.4076843	0.29
220.0841370	0.17
223.0463409	0.05
225.1513977	0.64
227.0220490	0.40
229.0963135	0.54
239.1692810	0.62
241.4827271	0.23
249.2309418	0.19
250.1297913	0.06
251.1988831	0.61
252.2756653	0.11
255.2399139	0.24
256.5728760	0.51
257.3132324	1.45
258.0801392	0.19
260.0991211	0.42
265.0618896	0.11
267.1899414	1.01
269.4775696	0.62
271.4934692	0.20
274.1383667	0.22
278.0924072	0.89
280.0664673	0.41
281.3988647	0.25
283.5598755	0.06
284.2952271	0.29
285.1737366	1.06
286.1946716	0.39
287.2642822	0.09
295.0404053	0.10
296.1196899	0.26
308.1386719	0.04
311.4956970	0.16
312.3284302	0.12
313.2584839	0.56
317.7542114	0.07
323.2265015	0.13
325.6018982	0.13
329.1823120	0.13
330.3227539	1.56
331.3408508	0.21
332.1867676	0.20
344.7662964	0.04
348.2584229	0.60
350.3264771	0.16
356.3287964	0.22
368.4331055	1.11
378.3807373	0.23
380.4281616	0.08
381.2391357	0.17
386.3659058	0.62
396.3500977	2.55
397.5604858	0.10
399.3546753	0.04
404.5288696	0.16
408.2379150	0.10
411.3690186	0.03
414.2689209	8.37
415.4064331	0.60
424.4207153	0.71
430.2217407	0.27
432.3443604	1.63
442.3008423	7.66
444.4818726	0.05
458.2244263	0.07
460.2896118	100.00
461.4843140	0.73
478.2350464	11.13
479.0972290	0.39
488.5336304	0.10
493.3984985	0.76
494.5853882	0.14
502.1868286	0.14
508.6786499	0.30
510.0238037	0.11
548.6135254	0.26
551.0456543	0.18
567.2865601	0.05
568.3133545	0.13
575.2869263	0.09
576.1955566	0.14
580.5358276	0.27
585.9753418	0.37
586.6226196	0.05
594.2037964	1.17
595.8173828	0.06
604.5363159	0.64
605.2920532	0.10
612.2612305	0.06
622.3745728	12.90
623.7734985	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	608.2369
Annotation	Unknow
Peak:m/z	Relative Intensity
180.1916046	0.16
180.9894714	0.36
188.6122437	0.28
191.1464539	0.28
193.0676575	1.15
195.2067566	0.16
196.8237305	0.34
199.3172913	0.28
200.9645996	0.31
204.2848969	0.07
207.2031555	0.91
210.9677734	0.78
214.4178772	0.09
217.1079254	1.04
223.0780487	3.76
225.0789642	0.39
228.6894379	0.23
229.3930817	0.51
231.1078491	0.19
235.0778198	1.15
241.2256317	1.75
243.0431061	0.43
246.5729980	0.05
247.2109070	0.70
253.0440674	3.71
253.6795349	0.11
255.1931152	0.58
257.4330750	0.34
258.8670959	7.86
263.8467712	0.38
265.2148438	0.31
266.0643616	6.46
271.0325317	9.06
275.2532959	0.12
276.3450928	0.68
277.0036621	1.93
283.9055176	2.80
284.8726807	0.50
286.9828491	0.67
288.3723755	4.87
289.0604248	24.85
291.0969238	0.11
306.3510437	1.08
306.9804688	5.29
313.5451050	0.12
321.7440186	0.30
324.8815308	100.00
325.5933838	0.24
342.8153076	30.84
343.7509155	0.23
381.7115479	0.10
405.0897217	0.40
420.6293945	1.18
428.0914307	15.62
446.0953369	36.58
450.7144165	0.29
468.5599976	0.20
469.2225952	0.56
476.0611572	0.47
485.5202026	0.08
486.8743286	10.69
503.1328735	0.50
503.9507446	0.46
504.9825439	0.95
518.7065430	0.23
521.5317383	0.19
562.9563599	0.23
572.4747925	0.21
590.1624146	1.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	347.148
Annotation	Dihydrokanakugiol
Peak:m/z	Relative Intensity
101.0508270	0.09
105.1585999	0.13
109.3605347	0.12
113.0858459	0.10
129.2120056	0.04
131.1313782	0.18
135.9923096	0.85
147.0924683	0.32
148.8527069	0.14
153.1129761	0.14
161.1236877	0.06
162.9746399	0.16
167.1139526	0.10
181.1048889	0.05
184.0508270	0.60
185.2453918	0.08
187.1560669	0.26
191.0267334	0.04
192.8606110	0.05
197.2408142	0.16
205.0674744	0.03
208.4620056	0.43
209.1103821	14.42
210.1075592	0.10
211.2305603	0.11
217.0441589	0.12
219.2436829	0.17
221.0228271	0.16
224.2499695	0.12
225.1492004	0.25
225.8389587	0.18
226.9582520	3.15
232.0339966	0.11
234.8186035	0.10
239.2294006	1.60
240.1607666	7.90
245.1767273	0.04
252.3804932	0.22
256.3691101	0.11
257.6000977	0.38
258.2752075	0.64
259.2664795	0.08
262.3226013	0.17
265.4017944	0.12
266.3505859	0.34
267.3364563	1.52
270.5965576	0.18
272.4018555	0.14
274.0915833	0.11
277.1812439	0.11
280.9477844	0.30
284.1757812	0.80
285.2277222	1.53
286.2133484	13.35
286.9925232	0.03
288.3915100	0.08
289.0179443	0.13
290.3701172	0.11
291.1876831	0.19
294.9688721	0.11
299.1849976	1.17
301.0612793	0.31
302.0070801	1.44
303.5976257	0.32
304.7668152	0.12
307.0591431	0.59
312.4573975	4.62
313.1353149	13.80
316.7550049	0.27
317.5906372	0.49
319.8522949	0.41
326.3420715	0.31
330.1867676	29.26
330.9739075	100.00
331.6130981	0.60
339.1541443	0.18
339.8758240	0.36
348.0598450	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	557.2606
Annotation	gibberellin A2 O-beta-D-glucoside
Peak:m/z	Relative Intensity
161.1098480	0.26
178.9396667	0.19
331.2526245	0.78
348.7177734	0.31
349.3182373	3.74
390.7881470	0.03
409.2473145	0.14
461.3098755	0.02
483.5061035	0.01
497.2307739	0.05
511.2710571	100.00
537.1627808	0.03
538.8671875	0.08
539.4686890	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.114
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
109.1071091	0.03
113.0524063	0.16
118.8264618	0.02
131.1117249	0.01
134.8677368	0.02
142.8034973	0.02
149.0789642	0.05
161.1584778	0.02
163.1210327	0.02
175.0324707	0.10
179.1380920	0.05
187.2227325	0.07
190.8256836	0.13
201.2354431	0.04
205.0413818	0.12
223.1308899	1.44
225.0838928	0.04
236.3007812	0.01
237.0978394	0.05
241.4815674	0.02
247.1861877	0.26
249.0571289	3.62
265.1813354	0.59
267.0886536	100.00
267.8471375	0.01
275.1113892	0.02
277.0935364	0.02
285.3023682	0.03
295.1051331	0.16
297.1002808	0.03
305.1728516	0.01
312.4181519	0.04
321.4542236	0.03
325.2456055	0.39
338.3211670	0.06
338.9821472	0.10
340.9727783	0.21
349.3506165	0.12
350.2557678	0.05
354.4267883	0.04
355.3861389	0.15
366.3265381	0.09
367.1579895	0.11
370.1729431	0.04
385.1146240	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	414.1404
Annotation	Unknow
Peak:m/z	Relative Intensity
119.0739288	1.65
164.0703278	0.09
178.3197937	0.06
206.0534515	100.00
207.0589294	0.77
208.0065002	0.06
228.3778687	0.08
229.0756226	0.16
249.2408447	0.06
251.3105164	0.09
271.2206116	0.14
277.4644775	0.04
280.1502991	0.09
283.0628052	0.26
284.2687073	0.13
290.0548706	0.12
298.1416321	0.07
303.0338135	0.16
310.2969360	0.14
317.9033813	0.12
326.3920898	0.13
336.2334595	0.28
348.4021606	0.08
350.9733887	0.07
354.1716309	0.34
362.6166382	0.09
367.3210144	0.89
368.1859436	7.87
369.1122131	0.36
369.8890686	0.92
371.4307556	0.16
378.0635071	0.05
379.0752563	0.03
384.3063049	0.18
396.2257690	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	575.2708
Annotation	gibberellin A2 O-beta-D-glucoside
Peak:m/z	Relative Intensity
226.2396698	0.02
281.1312256	0.03
366.1105347	0.05
367.3253174	0.08
423.1143799	0.04
431.5003052	0.02
463.1528320	0.01
507.4782104	0.01
527.4996948	0.07
529.2907104	100.00
529.9309692	0.34
537.6101685	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	527.2499
Annotation	Parvifoliside
Peak:m/z	Relative Intensity
160.9420776	0.24
165.3830414	0.03
178.5637817	0.03
183.0284424	0.06
191.0928955	0.05
222.7850952	0.04
229.3890991	0.04
231.2552490	0.02
243.2347717	0.09
245.3430328	0.16
253.9523468	0.06
257.1873169	0.03
272.2112427	0.10
275.1437988	0.14
285.3253479	0.03
287.3905640	0.02
293.0794678	0.03
301.4247437	0.07
303.3665466	3.29
304.4992676	0.19
305.2826538	0.45
317.2583618	0.05
319.2852783	0.50
321.3426514	2.07
322.2341309	0.04
329.2606812	0.08
330.3651123	0.14
331.3541260	0.04
335.2556763	0.07
337.3999634	0.07
345.1696167	0.03
346.1701660	0.03
347.3799438	0.68
348.4517212	0.11
349.3988647	0.13
363.3805542	0.26
365.2338867	6.99
385.3566895	0.05
388.2979126	0.03
389.3408203	0.16
398.2781982	0.25
401.1527710	0.20
406.3607788	0.06
407.4506226	0.16
419.5985107	0.02
423.1547852	0.18
429.6917725	0.06
435.4887695	0.15
439.1917725	0.04
440.4443359	0.14
447.3018188	0.22
453.5586548	0.03
463.2851562	0.63
465.3977661	5.38
467.0311279	0.76
479.5560303	0.03
481.3389893	100.00
482.5668335	1.57
483.4669189	6.50
484.3803101	0.24
491.1410522	0.45
496.1481323	0.06
497.3648071	1.08
499.3225708	0.36
509.3251343	30.71
510.4325562	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1664
Annotation	Verbasoside
Peak:m/z	Relative Intensity
162.6921692	0.03
211.0629425	0.06
266.8844604	0.06
269.1493835	0.53
299.4796143	0.02
363.2001343	0.04
415.2698059	100.00
429.3440857	0.17
443.0432129	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.2183
Annotation	Dendromoniliside E
Peak:m/z	Relative Intensity
178.8978882	0.27
180.0455780	0.70
195.0562439	3.64
208.1351776	0.08
209.2017212	1.12
210.2964478	0.15
225.1201935	6.84
249.0099792	0.37
255.1243134	0.06
263.1338501	0.07
294.9501953	0.10
297.2691650	0.04
305.2742310	0.15
315.1729736	0.51
325.0596313	0.06
337.1253052	0.09
339.3317261	0.23
340.4166260	0.06
345.2250366	0.39
347.0961914	0.24
357.1412964	23.93
357.7570190	0.13
369.1754761	0.62
371.1536255	0.04
372.0417480	0.22
377.3059082	0.04
381.1430664	0.05
387.2365112	100.00
399.0534058	0.10
405.1040649	0.17
407.3492432	0.06
417.1484985	7.72
417.8706055	0.05
421.0908813	0.10
429.3449707	0.53
435.1448975	10.40
441.4000854	0.44
447.3608398	0.26
459.2913208	3.59
471.3078003	0.32
474.9094849	0.21
477.1348267	15.17
477.7353516	0.45
489.3209229	2.41
501.2662964	0.19
507.1923218	1.84
519.2319946	0.10
529.3659058	6.64
531.2387085	0.05
533.2915649	0.13
535.3178101	0.04
537.3268433	0.04
547.9423218	0.04
549.1316528	18.01
551.1557007	0.67
553.4367676	0.07
561.1528931	0.87
563.4738770	0.04
569.1380615	0.32
574.8135376	1.32
579.2138062	7.03
580.5325317	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	305.0779
Annotation	Unknow
Peak:m/z	Relative Intensity
88.0499878	2.25
97.9894104	0.12
110.9836884	0.11
113.9391403	0.53
114.9883804	17.96
127.1679764	0.14
128.0835876	0.64
129.9516907	0.08
132.0403137	96.83
141.0918884	0.09
144.0610352	2.40
146.0880432	38.40
150.7143555	0.20
157.1322327	0.12
158.2333374	0.44
171.0584564	16.34
172.0275116	3.20
173.2145233	0.22
173.9911957	0.05
183.9596710	0.53
187.2489624	0.44
189.0538940	91.07
190.0205994	65.65
198.0577545	0.12
199.1073914	2.18
200.1174622	0.41
201.0063477	1.00
208.0119019	0.05
217.1438293	0.83
223.9876099	0.66
224.9240723	0.44
225.8963623	0.12
227.1187134	0.14
230.4107971	0.17
231.3938293	0.10
241.3256226	0.05
243.0569153	24.29
244.1582642	0.95
245.4699707	0.15
261.1324463	100.00
269.0741577	2.09
273.0923462	0.14
274.9761353	0.11
277.4650879	0.42
285.3610535	0.17
287.1548462	72.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	591.26
Annotation	Swietenin F
Peak:m/z	Relative Intensity
195.2171478	0.37
197.2453918	0.06
201.2731628	0.05
225.1332092	0.31
237.1997070	0.19
241.2844849	0.09
257.3469849	0.19
283.1113892	0.19
293.3540649	0.11
296.9760437	0.12
302.1194458	0.31
320.1640320	0.22
330.3159180	0.28
336.0812988	0.39
337.9406738	0.17
344.3399048	0.30
363.4246826	0.21
365.1824951	0.07
369.2772827	0.17
375.6744385	0.11
381.3095093	0.18
406.4011230	0.18
417.2374268	0.24
429.4649658	0.12
433.0098877	0.13
444.4265747	0.23
445.5547485	0.33
446.4626465	0.21
448.4805298	1.08
449.1406250	0.16
450.2122803	0.35
455.1265869	0.14
457.1710205	0.10
458.9467773	1.47
459.9269409	0.68
460.7457886	0.55
469.3027954	0.56
470.5310669	0.58
471.3875122	0.14
472.2451782	0.49
473.3722534	1.58
474.3707886	2.03
475.5721436	1.84
476.6048584	0.12
477.2109985	0.17
485.3731689	1.47
486.3921509	2.25
487.4110107	6.15
488.3515015	2.43
489.5272827	0.29
490.3646851	0.67
491.3739624	0.28
492.0191040	0.47
492.7219849	0.38
500.2422485	0.74
502.3505249	0.92
503.3966675	3.63
504.2755737	1.01
505.3472290	0.10
506.4589233	0.13
515.4177246	8.83
516.3312988	3.15
517.2699585	0.97
518.4293823	1.63
519.3247681	2.99
520.2959595	1.30
523.2872314	0.54
529.9142456	0.44
531.3071899	100.00
532.3500977	61.78
533.2722778	5.44
533.9079590	0.23
541.3807373	0.04
545.7022705	0.46
547.1630249	1.74
548.1115112	0.46
549.1741333	0.38
555.7603149	0.09
559.2930298	2.07
560.3668823	1.76
563.3865356	1.75
564.2391968	0.48
573.2628784	0.62
576.4375000	0.28
577.4014282	0.14
591.2875977	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0852
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.90493774	0.24
80.86653137	0.75
82.89458466	0.43
85.01960754	0.40
90.86790466	1.11
94.89196777	1.08
96.87086487	1.22
98.9357605	0.24
102.9879608	1.09
103.8134155	1.40
105.0357513	1.15
107.040329	0.84
108.9860077	1.68
109.8885345	0.66
111.0316162	0.75
112.9775391	0.66
121.1690063	0.37
123.068985	2.17
125.0258331	0.24
126.914444	0.88
129.021286	5.16
133.146698	0.65
135.0517426	1.38
135.9901733	0.62
137.2540588	0.36
141.0151672	3.08
144.7244263	0.22
147.0938263	0.73
148.8765106	1.75
150.9710846	48.56
152.027298	1.93
153.1827087	1.02
154.1231232	0.21
156.7840729	1.26
161.0604553	0.73
162.89888	4.23
165.0583344	2.12
165.9657135	1.04
167.0528412	2.79
168.2750549	2.30
169.0101776	2.72
170.9459686	0.28
175.134079	2.19
177.1006775	0.92
179.1835022	0.98
181.1996765	0.21
182.5855713	2.52
185.0652771	0.83
186.2853699	0.61
189.1717682	1.32
193.0970459	0.94
194.6982574	1.29
197.139328	3.89
198.9850159	1.56
207.184494	0.56
209.1655273	1.93
210.0544891	0.50
211.2497559	0.95
212.312973	0.84
213.0197601	0.83
217.1910553	6.94
225.1247711	9.97
233.1437988	1.27
235.0776215	27.86
236.1179199	0.57
237.984436	10.84
239.1406708	0.33
250.8855591	1.47
253.0804443	100.00
254.2305145	14.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	612.3
Annotation	Unknow
Peak:m/z	Relative Intensity
178.0791321	0.01
197.0477295	0.03
199.0382233	0.04
204.2015076	0.01
204.9954834	0.01
209.1078796	0.05
213.1089172	0.01
234.5160522	0.03
239.2376556	0.01
245.0106201	0.01
249.8279266	0.02
255.2602539	0.09
257.2903442	0.01
259.1575928	0.03
260.1837769	0.03
262.2285156	0.06
263.0231934	0.02
267.4163208	0.01
280.0930481	0.08
283.1426392	0.07
285.2732849	0.01
287.3014526	0.03
292.9141235	0.02
295.3059692	0.02
301.2955017	0.01
303.4976196	0.01
305.2638550	0.04
306.1604004	0.01
328.5246582	0.01
340.4976807	0.02
343.2484131	0.03
352.4295654	0.02
363.4216919	0.04
369.8048096	0.02
370.7219238	0.01
386.2071533	0.15
388.2379150	0.15
401.4487305	0.02
402.3554077	0.01
404.2634888	0.06
414.3127441	0.72
416.1027222	0.06
417.4261475	0.07
418.8310547	0.03
430.1383667	0.05
432.3514404	6.81
433.2849731	0.16
450.3320312	100.00
451.4923096	0.10
489.5000610	0.04
492.2435913	0.01
501.6422729	0.02
505.6471558	0.08
522.5795288	0.06
524.4373169	0.03
548.6004028	0.02
550.3881226	0.04
558.7335815	0.01
566.4599609	0.05
576.3533936	0.08
579.0223999	0.02
581.5818481	0.01
585.4688110	0.03
594.3571167	1.80
595.3688354	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1115.96
Annotation	Unknow
Peak:m/z	Relative Intensity
451.1983643	1.50
537.6125488	0.69
539.3417969	100.00
540.5492554	0.93
555.4061279	0.92
557.2894897	86.64
558.4322510	1.11
559.2479858	0.50
1671.4586180	0.28
1672.6970210	1.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	628.69
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9225922	0.08
250.9543457	0.02
280.0947876	0.05
290.3272400	0.04
290.9274292	0.46
292.6422119	1.05
374.7230835	0.28
376.7556763	0.71
434.8647461	0.07
454.0758057	0.14
458.0362549	0.18
458.6966553	3.94
460.0981445	2.23
460.7117920	10.86
462.7949219	0.13
466.1140137	0.06
484.0768433	0.10
492.7662964	0.14
522.5671997	0.83
542.5182495	15.94
544.4904175	100.00
545.2046509	0.47
568.6461792	0.18
581.9740601	0.24
582.9566040	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	416.19
Annotation	Unknow
Peak:m/z	Relative Intensity
136.0529938	0.15
141.7036438	0.10
151.9388123	0.24
158.0466919	0.33
160.9496307	0.08
178.1224365	0.05
191.1564941	0.15
192.9536438	2.73
212.7008972	0.19
227.0377808	0.20
231.0741882	0.67
244.9935303	0.43
254.1902771	0.75
255.1412048	0.25
267.0739746	0.12
269.8568420	0.08
273.4081421	0.11
277.1453857	0.11
282.3012390	0.18
283.0137329	0.17
285.3126221	0.52
294.1305542	0.33
297.0262451	0.20
299.2906799	0.11
315.2334290	1.32
318.2302856	0.13
326.9666138	0.37
328.4004822	0.10
329.8310242	0.65
332.5942383	0.45
335.1987915	0.27
348.3485413	0.17
352.2143860	0.73
354.6755371	0.32
355.7256775	0.16
358.1013794	0.10
360.3485413	0.44
363.0084839	80.82
363.6223755	1.31
371.4581604	0.68
372.1772156	0.15
373.5148621	0.15
375.1459045	0.42
380.4525452	23.92
381.1023254	100.00
393.1896667	0.32
394.8034363	0.22
397.4693604	0.48
398.2612610	3.74
398.9931030	6.30
400.4202271	0.12
401.0560608	0.46
407.4491272	0.28
408.5379639	0.36
424.0508118	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0851
Annotation	7-Methoxyisoflavone
Peak:m/z	Relative Intensity
76.82618713	0.63
90.88873291	0.22
95.96879578	0.20
103.0901031	2.17
104.8764496	0.26
106.9731598	0.98
108.9859009	0.13
115.0260315	0.35
123.044632	0.26
128.9919586	7.78
130.7399139	0.22
137.0836792	0.36
140.8795319	0.60
150.9295349	55.04
152.0952454	5.47
154.0798492	0.39
155.3195343	0.23
162.8803253	0.29
166.103653	0.36
167.0811768	1.30
168.0651245	0.21
169.0753479	1.29
179.0777435	0.87
183.0635529	0.58
185.0583496	1.35
186.067688	0.80
189.1044464	0.43
190.2769012	0.12
191.1394348	0.12
193.2143555	1.09
196.9938507	1.85
207.0084076	0.42
208.3664856	0.98
210.3128204	0.55
211.2447205	0.57
211.9279022	0.88
225.0463562	2.12
226.0652008	2.89
235.0866547	0.56
235.7360687	0.32
238.0396271	4.84
239.0626068	1.25
249.8863525	0.92
253.0764771	100.00
254.1663361	15.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0983
Annotation	Glochidionolactone A
Peak:m/z	Relative Intensity
123.1832657	0.74
138.1677551	0.22
151.1247253	0.63
155.0786743	0.17
161.2355957	0.35
165.0856628	0.06
179.0032349	0.31
182.1939392	0.09
193.1495056	0.19
197.2347260	0.21
202.9679871	0.06
219.0063782	0.06
222.8981323	0.53
225.1984558	0.09
233.2012634	0.05
237.0037842	0.15
239.2375183	0.12
240.9536743	0.09
257.1223450	0.12
263.0529480	0.22
266.9650269	0.12
268.9171753	0.32
283.4430542	0.06
285.4929199	0.14
287.1306152	0.07
297.2877197	0.10
299.0780029	0.69
300.3102417	0.06
311.3397522	0.16
313.0335083	100.00
313.6806641	0.20
315.1551819	0.44
318.9392090	0.10
323.2973328	0.26
324.3121338	0.05
328.9772949	0.04
338.6784363	0.33
341.0509033	1.47
343.3500977	0.08
344.2915955	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.22
Annotation	Acetyl-T2 Toxin
Peak:m/z	Relative Intensity
155.1255341	0.06
167.2930603	0.16
170.2579651	0.10
171.1219025	0.59
179.1560364	0.13
181.2259369	0.65
196.9316101	0.31
219.2237701	0.23
221.4251404	0.11
223.1006927	0.30
224.1759491	0.36
227.1263580	0.07
237.2584991	0.28
239.1430359	20.10
240.9304199	0.14
241.5552063	0.12
243.2210846	0.06
251.5401306	0.33
253.3203430	0.96
255.2716370	0.68
257.4695435	0.84
265.0580750	0.67
269.3304443	0.19
279.0964050	0.05
281.2463379	0.05
283.1504211	41.61
283.8091736	0.15
288.9343567	0.12
297.0003052	0.07
299.1042480	0.43
301.3345337	5.16
325.1898804	0.24
327.2620850	94.03
328.2285156	0.69
329.3263855	0.13
343.3640137	1.24
345.1869507	100.00
345.7883911	1.68
346.4642029	0.86
347.3286133	0.25
387.2426758	3.55
403.3038330	0.09
409.3205872	0.31
413.4957581	0.14
415.0716858	0.41
427.2037659	0.11
433.6658936	0.23
446.3599548	0.10
447.4745483	1.57
449.3873291	0.62
450.5838318	0.45
461.0521240	0.93
462.5167236	0.81
463.3186340	0.97
469.4250183	0.08
471.2127380	0.63
489.3907166	0.68
490.3377075	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1882
Annotation	Atalanine
Peak:m/z	Relative Intensity
174.9391632	0.04
187.2493896	0.02
205.1826172	0.02
207.0570068	0.03
231.2153320	0.07
249.1602478	1.19
267.0565491	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.2077
Annotation	Glaucarubinone
Peak:m/z	Relative Intensity
178.4650879	1.01
179.1498718	1.25
223.3209686	1.08
225.3329773	0.35
239.1241455	0.29
269.1450195	100.00
269.7752380	0.29
287.1059570	0.75
299.3132629	1.30
313.0267334	5.75
313.6961975	0.12
331.1719055	11.38
347.2244873	0.17
447.2779846	0.45
449.3778992	42.86
450.3997498	0.44
455.2593384	1.45
475.0617981	1.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
128.9311523	0.60
130.9394531	0.23
143.3123322	0.18
157.1118164	0.72
171.0552673	1.71
173.196701	3.19
182.9236755	0.21
185.1140137	2.41
187.2355957	1.39
199.1419678	0.94
201.0522766	2.89
203.1729584	1.20
213.0933838	0.71
215.0906067	3.19
217.1046143	0.71
229.2171631	2.57
231.0710449	1.46
239.4100647	0.18
241.3430786	1.84
243.3580933	4.12
245.2718811	0.22
247.0001221	0.35
253.2475891	0.36
255.3482666	2.35
257.1097412	5.20
257.7695007	0.21
259.3009949	1.93
263.3648682	4.81
267.2190552	0.22
269.1521606	1.09
270.6131592	0.52
271.2908325	5.01
272.9902954	3.24
273.6297913	0.53
277.1858521	0.35
279.0632935	0.45
283.3408203	3.37
285.2611694	9.17
287.3643799	0.56
289.1185913	0.73
293.4155579	0.38
295.5473328	1.55
297.3361511	5.88
299.3718872	8.25
301.3696899	1.85
311.3091431	2.43
313.3225708	3.02
315.2646484	2.59
317.0360718	0.32
321.2450562	2.67
322.2257996	0.70
323.3444824	7.28
329.406189	0.54
339.2448425	100.00
340.1900635	0.68
341.2597351	13.90
342.2987671	0.55
357.3132629	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	705.3336
Annotation	Unknow
Peak:m/z	Relative Intensity
254.3087463	0.08
257.0381470	0.21
281.2080688	0.10
319.4109497	0.07
345.0574341	0.13
363.3963013	0.07
373.4763184	0.21
388.9879150	0.13
441.2582397	0.05
443.0171509	0.24
445.9926758	0.16
453.4730225	0.47
463.3914795	0.07
480.2753296	0.29
481.4340820	0.40
482.9931030	0.13
485.1235962	0.17
488.0441895	0.14
495.5381470	1.00
497.3053589	100.00
497.9214478	0.35
506.5115967	0.18
512.4161377	0.20
521.2260132	0.17
527.3165894	0.26
528.2446289	0.40
529.3530884	0.19
531.1541138	0.08
539.4019775	2.02
540.2413940	3.03
556.3665771	0.19
563.4203491	0.14
569.5289307	0.23
578.7495728	0.68
583.1579590	0.09
597.9846191	0.40
599.2697144	0.23
603.7188110	0.19
632.9870605	0.16
643.6439819	0.29
645.4235229	0.19
658.4556885	4.58
659.1933594	43.43
661.4075317	0.34
669.3718872	0.90
672.5900879	0.32
686.8379517	0.79
687.5663452	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
77.03720093	0.43
112.9143677	0.12
123.1372833	0.61
123.985733	0.26
137.8408051	0.53
143.1147919	0.30
145.9949341	0.45
148.7550354	0.16
161.1475677	0.87
163.1111603	0.75
169.12323	1.08
180.0816956	0.13
181.0935364	1.49
183.1966858	1.05
187.2792511	0.21
193.2568817	0.12
193.9405975	0.56
195.1607361	0.38
196.9046173	0.24
206.0370636	2.33
207.1260986	3.60
208.1745758	0.32
209.2867279	3.80
222.0873566	1.10
223.1605377	3.71
224.278244	0.27
233.1821442	2.41
235.5271606	0.29
251.0770264	100.00
252.1947784	11.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	363.145
Annotation	Nagilactone B
Peak:m/z	Relative Intensity
108.9545975	0.02
120.1494446	0.05
121.1303864	0.21
123.0841370	0.13
123.9224396	0.07
125.1858673	0.06
126.1364441	0.09
134.9923706	0.79
138.9600525	0.41
143.0240631	0.06
145.8544312	0.08
149.1835022	0.11
155.0108032	0.01
159.1348114	0.06
161.0224762	0.31
174.9395752	0.05
177.3282318	0.11
179.0855408	0.56
185.2527161	0.06
187.4688416	0.08
191.2664337	0.07
195.2157288	0.13
197.1896515	0.03
199.8030396	0.09
201.3376770	0.16
203.1041107	0.21
205.2178345	0.04
206.0161591	0.04
213.2557983	0.95
215.1395874	0.43
217.1489563	0.36
219.0616150	0.27
221.1882019	0.22
224.2613220	0.02
227.1567688	0.22
229.1866760	0.87
231.0352478	0.30
233.2967529	0.16
234.1797180	0.06
237.2203674	0.09
239.2134705	6.08
240.0625610	0.03
241.0832214	0.68
242.1950684	0.02
245.1882629	0.65
247.2539062	1.31
255.2403870	1.21
257.1752930	24.25
258.3037415	0.35
259.1333923	0.56
259.7954407	0.05
265.3526306	0.25
271.1143494	0.05
273.2212219	2.43
275.2607727	8.43
283.1144104	3.41
289.2742615	0.13
299.1570740	0.28
301.2102051	17.82
302.2513428	0.20
315.2053223	0.02
317.2510071	0.38
319.1979370	100.00
320.2715149	0.87
327.2286987	0.04
345.2612915	2.53
346.3317566	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	543.2444
Annotation	gibberellin A2 O-beta-D-glucoside
Peak:m/z	Relative Intensity
159.0416412	0.57
160.8244476	0.22
179.4020538	0.42
180.5152435	0.28
183.1292725	0.44
191.1238556	0.07
198.9765015	0.20
215.2275696	0.28
219.0327148	0.19
227.3304443	0.26
229.8234863	0.47
235.4552917	0.27
241.4847260	0.30
242.3001709	0.08
243.3615112	0.13
246.4274902	0.73
247.2312012	0.28
249.0561523	0.27
255.2333069	2.18
256.3237305	0.56
257.2979126	1.46
258.4393311	0.76
259.4808044	1.12
261.8975525	0.17
263.4160156	0.92
267.2687378	0.50
268.3670654	0.28
272.4999390	0.52
273.3471680	1.20
274.3162231	1.14
275.3368530	3.50
276.3096313	3.32
283.4078369	1.97
284.2425232	1.93
285.1849670	2.46
286.2462158	0.96
287.1165161	0.09
289.1107178	0.32
291.2347412	2.77
292.3663330	3.16
294.3177490	0.22
301.2617798	3.45
302.2645874	4.88
303.2526855	2.39
304.2415161	1.42
305.3273926	1.84
306.1417847	0.82
307.0627441	0.31
307.8005371	0.16
308.4017334	0.06
309.1540527	0.63
310.3883667	0.18
317.1289673	1.82
318.2062988	1.47
319.3443604	19.60
320.3067627	25.07
321.5208130	0.22
322.4136353	0.14
328.2111816	1.49
335.3168335	8.65
336.3032837	10.63
337.2461548	22.19
338.3319092	20.55
345.1665039	41.20
346.2941895	27.86
347.1220093	0.17
357.3201904	0.26
363.1915283	100.00
364.2372437	84.95
365.1597290	0.57
366.3682251	0.25
381.2304688	0.60
481.9247437	0.14
482.5966187	0.18
483.4008789	0.10
497.4998169	0.23
499.3568726	39.84
500.3109131	68.29
501.4569092	0.89
509.2360229	0.15
525.2841187	3.31
526.3121948	5.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	747.27
Annotation	Sylvestroside I
Peak:m/z	Relative Intensity
209.2338867	0.92
321.2141724	0.30
328.2496948	0.06
329.0223999	0.44
344.3041992	0.25
357.0345459	0.74
359.1864014	3.23
373.0908203	0.10
383.9219360	0.21
385.3378296	0.43
413.2137451	14.18
431.1880493	1.42
450.2603149	0.19
453.0726318	0.23
506.4551392	0.42
537.0870972	0.10
543.3831177	0.75
549.3300171	0.56
551.5436401	0.23
555.3645630	0.07
567.1214600	3.64
569.3251343	0.07
573.2709351	0.22
575.1985474	0.20
576.1859131	0.72
583.3534546	0.12
585.1770630	100.00
596.3082275	0.11
600.5023804	0.16
610.6212769	0.12
615.4238281	0.17
645.1105347	0.05
650.4110718	1.07
657.4692383	0.18
659.2180786	0.32
667.4534302	0.11
671.3839111	0.38
684.3883667	0.58
685.4421997	0.30
688.3449097	0.12
689.4533081	0.25
701.1923218	1.02
702.5791016	0.24
703.5783691	0.52
704.4002075	0.76
705.3670654	0.27
711.5981445	0.20
717.2532349	0.43
729.2158813	0.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	306.08
Annotation	Glutathione
Peak:m/z	Relative Intensity
90.0150986	0.05
98.9589615	0.24
115.9352036	0.12
119.9951172	0.30
126.0923767	0.23
128.0874634	9.11
130.0126953	0.10
143.0549011	9.75
145.2077637	0.21
145.9060974	1.04
153.1191101	0.12
159.9500122	11.57
166.2338867	0.41
167.1493530	0.79
169.0669861	0.17
171.1410675	0.66
176.9735718	9.59
179.0719604	10.49
182.9956207	0.04
184.0482178	0.17
185.0021820	0.66
190.1144714	0.07
191.7397614	0.29
197.0610504	1.62
203.1134033	0.04
210.1598816	6.15
213.0603943	2.18
215.1557922	0.08
226.2929993	0.03
228.1094666	0.65
231.1778564	1.19
236.0894470	1.15
242.1412964	1.38
254.0491333	91.75
260.1780396	0.11
269.9881897	0.14
272.0977173	100.00
288.0860901	59.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.1453
Annotation	Isopropyl apiosylglucoside
Peak:m/z	Relative Intensity
101.0145111	0.09
102.9554291	0.05
108.5487061	0.05
113.0131302	1.09
119.0015106	0.11
125.0434952	0.49
126.6991730	0.11
128.8874207	0.26
143.0566101	0.62
145.1448364	0.27
158.9611511	1.00
161.0536194	5.87
162.8608398	0.41
173.1734924	0.12
175.0654602	0.07
179.0104370	0.16
187.1142883	0.12
189.1110382	0.52
207.1085205	100.00
229.0765686	0.10
233.2985229	0.08
235.0172729	0.16
237.0386963	0.23
247.1023560	0.05
249.0570068	0.38
263.1169434	0.10
267.5678711	0.07
273.0060425	0.22
288.9855042	0.04
291.4761658	0.04
293.2179565	0.04
307.2088318	0.27
308.9569092	0.11
311.1314087	0.14
321.2304077	0.24
333.9728699	0.09
335.1611633	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	598.2868
Annotation	gibberellin A2 O-beta-D-glucoside
Peak:m/z	Relative Intensity
178.1000671	0.01
185.3060150	0.01
206.9203491	0.08
208.1067810	0.06
209.0954285	0.03
209.9323273	0.04
234.1273346	0.14
275.3394165	0.05
314.3804932	0.07
332.3591309	0.14
334.3301392	0.01
344.1746216	0.22
354.3684082	0.15
355.4853516	0.04
356.3547363	0.04
362.3322754	0.44
372.3113403	0.94
374.4177856	0.77
377.3745117	0.01
384.5918579	0.03
387.0187378	0.05
388.0562134	0.24
390.3697510	0.29
391.7658081	0.18
392.4121704	1.15
400.2322998	0.21
401.0224609	0.01
403.3784180	0.03
406.4441528	0.02
416.1045532	0.06
418.3801270	0.71
434.1993408	0.04
434.8685303	0.01
436.0828857	0.42
436.6840210	0.02
437.4705200	0.04
477.1245117	0.02
478.1074219	0.16
489.2474365	0.04
490.0515137	0.04
493.2753296	0.02
508.1759033	0.10
511.3378296	0.02
520.3809204	0.05
524.4252930	4.19
525.4630737	0.14
526.4096069	0.12
537.6890259	0.03
552.4021606	0.20
554.3270264	0.39
555.7258911	0.02
562.4346313	0.50
563.3167725	0.06
565.4597778	0.12
568.4844360	0.09
570.6819458	0.02
575.4169312	0.01
578.4392700	0.01
580.3674927	100.00
581.3881836	4.90
583.6793213	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	628.2217
Annotation	Unknow
Peak:m/z	Relative Intensity
193.0433350	0.28
286.4745483	0.10
313.3131714	0.45
334.3380127	0.04
340.0300903	0.12
363.2510986	0.15
364.4683228	0.06
372.5867310	0.06
375.2390137	0.13
401.1896973	0.12
417.3928833	0.07
419.2997437	0.09
468.6595459	0.22
495.7645264	0.35
496.5805664	0.08
500.1991577	0.07
507.2686157	100.00
509.1956177	0.17
536.2957153	0.13
577.5590820	0.19
581.8011475	0.60
582.4631348	0.09
584.2937012	0.15
585.4690552	0.23
592.2736206	0.08
609.3984985	0.04
611.0810547	0.10
632.3607178	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.1305
Annotation	Galactotriose
Peak:m/z	Relative Intensity
182.3791199	0.48
200.1214600	0.37
201.0726776	0.54
259.6488037	0.22
290.5540771	0.39
363.1141968	24.52
370.9956055	0.75
372.0991821	0.43
381.1805420	100.00
483.2346191	0.26
525.4531250	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.2133
Annotation	Abelioside A
Peak:m/z	Relative Intensity
160.8700409	0.36
175.0138855	0.16
177.0596619	0.10
191.3185883	0.25
207.1931305	0.10
215.1171875	0.42
240.8867798	0.20
249.4655304	0.17
251.3116760	0.59
253.4677887	1.29
255.2761841	2.64
259.2246704	0.30
261.2348022	0.40
271.2530518	7.14
272.1441040	0.29
275.3533325	0.05
287.2308960	0.06
289.3041992	5.54
290.2225952	0.52
293.1249695	0.15
299.3045044	0.82
300.2444763	0.13
301.4841309	0.22
305.3204346	0.21
307.2490234	3.48
313.2384033	0.39
315.2883911	7.45
319.4321899	0.12
325.3713989	0.17
327.4646606	0.30
329.1680298	0.69
331.2567749	0.62
333.2689819	9.17
334.3668213	0.07
335.1914673	0.67
339.4794922	0.11
343.2490845	4.93
344.4020386	0.41
347.3402710	0.53
349.1053467	0.28
351.2474365	0.40
355.3273926	0.12
357.3870850	0.31
359.3002319	46.98
360.2757568	1.05
373.3246460	8.95
375.3264160	1.66
377.2289429	27.74
378.2182617	2.48
385.4523315	0.26
391.3257446	0.79
401.1792603	3.49
405.0797119	0.34
419.2858887	2.20
450.7705688	0.50
451.4151611	6.18
452.3812866	0.13
467.5092773	1.29
468.4309692	0.19
477.1688843	7.00
478.0640259	0.52
479.5032349	0.12
481.2838745	0.10
492.7141724	0.34
495.2350464	100.00
496.2728271	5.32
503.3582153	0.18
518.9307861	0.10
519.5465698	0.26
521.3839722	5.37
522.3577881	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	570.45
Annotation	Unknow
Peak:m/z	Relative Intensity
178.0728302	0.02
205.9611816	0.17
207.2654877	0.29
212.1187134	0.18
212.9702148	0.11
228.1454620	0.34
232.7876587	0.07
233.4659729	0.04
234.1356049	0.06
234.7634277	0.19
255.0832520	0.15
256.2627258	0.19
260.1008911	0.43
261.0714111	0.39
264.9127502	1.63
265.7944641	0.09
272.3415527	0.30
278.7322998	0.46
280.2439575	0.26
287.3052063	0.02
295.0253906	0.08
305.2800293	0.49
312.2160034	0.09
321.1361084	0.03
322.2155762	0.04
330.3074341	0.05
331.0913696	0.11
350.3121338	0.10
358.5240479	0.13
366.1052856	0.17
367.1027222	0.05
369.0779419	0.09
370.0521851	0.10
372.2955322	0.15
380.3121338	0.13
406.9427490	0.04
407.9451904	0.12
417.7411499	0.04
419.4080811	0.28
431.6898193	0.11
436.2011108	0.09
441.2481079	0.20
451.2615967	0.12
456.2506714	0.37
463.1746826	0.10
465.2780151	0.15
467.4749146	0.06
474.9652100	0.04
475.6881714	0.42
477.6408081	0.56
480.5451050	0.03
483.8062744	0.26
486.3801270	0.03
490.8112183	0.50
493.0587769	0.34
497.5332642	0.56
503.5463257	0.60
506.1681519	0.43
510.7749634	0.62
512.2356567	0.15
516.4700317	0.05
522.8198242	0.67
523.6764526	0.03
525.4885254	1.09
528.2178345	0.51
529.8438110	17.22
530.5775757	4.75
531.5975952	0.76
534.2324829	2.41
536.0581665	0.08
537.5078125	0.75
538.1369629	1.88
538.9266357	0.88
540.0486450	0.71
540.9337769	0.41
542.4731445	0.71
543.0934448	0.02
544.3284912	1.37
545.2651367	1.33
546.8547974	0.58
549.1897583	3.71
550.0275269	0.74
550.9970703	0.83
552.4644165	2.30
553.2106934	0.52
555.1862183	3.27
556.2949829	1.15
557.0606079	0.47
558.0100708	0.49
559.3919067	5.99
560.2416382	0.72
561.9085693	4.78
562.5471802	2.42
563.9303589	4.81
565.6804199	0.06
570.5646973	0.20
591.8200684	0.08
606.5639038	1.38
607.5629272	0.08
615.4404907	0.52
618.3590088	0.49
623.5219116	0.43
626.8671265	0.22
628.7688599	0.23
633.9520264	0.16
635.4241333	0.06
636.0243530	0.11
637.6033936	0.21
640.0549927	0.22
641.0127563	0.16
642.0723267	0.27
643.0839233	0.34
644.9377441	1.03
646.6830444	0.11
649.7797241	0.30
650.7859497	1.40
651.8058472	0.20
655.4223022	0.43
656.4905396	0.51
657.4839478	0.40
659.8778687	0.58
660.9110107	0.82
661.6890259	0.40
662.6511841	1.57
665.3773804	0.91
666.1083374	0.47
667.9251099	4.36
668.8080444	1.50
672.1420898	0.28
673.9408569	19.41
674.8708496	0.18
676.9483032	1.30
677.6900635	0.39
679.1823120	0.47
680.6313477	0.38
686.2106323	0.18
687.0183105	0.21
689.2755737	0.60
691.3836060	0.47
692.9940796	0.31
694.7894287	0.43
696.0587769	1.74
696.9287720	3.14
697.5678101	1.26
700.1912231	5.10
700.8446655	4.95
701.5221558	0.93
703.7783813	0.22
704.9132690	0.22
705.7232666	0.80
706.4798584	100.00
708.1697388	0.31
709.1113892	0.52
711.2604370	0.29
715.0398560	3.36
716.4141235	0.30
719.0862427	0.21
720.0101929	0.30
722.2937622	0.13
722.9003296	0.57
724.3789673	0.18
726.3236694	0.23
728.0908813	0.48
728.8854370	0.03
731.6775513	0.09
732.5598145	0.15
735.3963013	0.41
740.7485962	0.49
742.1397095	0.36
745.3150024	0.51
749.1663208	0.82
754.9323120	1.80
755.7277832	0.24
756.9447021	0.09
767.2469482	0.03
780.3778076	0.60
781.3649292	0.34
782.5397949	0.17
783.6854858	0.04
799.7880249	0.25
801.9135742	0.38
805.4855347	0.23
814.2843628	0.27
823.2963257	0.03
824.3486938	0.29
848.3215942	0.12
853.7915649	1.57
854.5324097	0.36
855.3660278	0.23
862.2493286	0.88
863.0803223	3.59
863.9936523	0.50
883.3098145	0.16
885.5034790	0.08
887.3635864	0.42
897.5065918	0.29
900.0346680	0.19
914.7322388	0.53
920.3287964	0.21
920.9605103	0.11
922.8224487	0.20
940.3131714	0.11
973.2096558	0.05
985.5441895	0.15
1054.6918950	0.32
1058.9719240	0.16
1143.1368410	0.23
1174.6469730	0.13
1285.2258300	0.11
1293.6009520	0.07
1378.1928710	0.44
1388.7484130	0.19
1483.2823490	0.09
1569.3289790	0.08
1708.7183840	0.05
1861.2628170	0.89
1876.0955810	0.06
1932.6451420	0.17
1982.0240480	0.09
1987.7037350	4.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	589.0667
Annotation	Unknow
Peak:m/z	Relative Intensity
175.1354218	0.06
179.0758972	0.19
181.1507416	0.33
184.9430695	0.11
187.1160278	0.24
197.1696625	0.28
198.0754089	0.09
199.0403442	1.34
201.2964325	0.08
202.9257507	0.10
211.1831360	0.34
213.0898132	0.10
217.0197449	0.85
217.8171234	0.11
222.7110596	0.07
225.2418671	0.05
226.1340027	0.07
227.2582550	0.36
229.0581818	0.21
234.8783875	0.33
239.0449829	0.15
240.9786072	0.27
244.1050720	0.68
244.9827423	0.46
246.0631866	0.17
247.0054626	0.06
254.2889099	0.12
258.9581909	0.18
260.7097168	0.33
264.9225769	0.08
268.0954895	0.09
268.7297058	0.48
270.9424133	0.35
274.9597473	0.15
275.7366943	0.14
277.0116577	11.86
289.0702515	3.07
293.2336426	0.32
294.4146729	0.09
295.0238647	0.70
301.0219116	0.19
302.9639282	1.55
304.9758301	0.38
306.8865967	22.23
307.5053711	0.07
309.8515320	0.09
310.9069519	0.21
317.0732422	0.33
319.0493774	5.82
320.7324219	0.15
325.2604980	0.09
327.2302246	1.48
328.1397705	0.80
328.9056396	0.20
331.0926514	0.48
333.2496948	0.12
336.9733887	10.51
342.2493896	0.41
343.0731812	0.59
344.0234375	0.13
345.2177734	1.13
346.6351318	1.22
348.9205933	0.99
354.7296143	0.43
361.1477661	0.47
365.2674561	0.99
366.9234009	24.22
372.3322754	0.82
373.1459351	2.24
375.8102417	0.09
378.9492188	0.63
382.1228638	0.41
383.0494385	0.72
391.0397949	17.23
397.0585938	26.37
399.0050049	0.12
407.8234253	0.18
409.0473633	62.53
413.1232910	0.18
414.3344727	0.14
415.3033447	0.24
424.4875488	0.14
427.0085449	100.00
428.1658936	0.22
437.8515625	0.19
441.4561157	0.37
442.1851196	0.49
446.2258911	0.05
451.2756348	0.09
454.6925659	0.18
456.1277466	1.46
457.4012451	0.33
463.1015625	0.07
469.1880493	0.42
474.5353394	0.38
481.0404053	0.33
485.5157471	0.30
491.2808228	0.09
498.6250000	1.10
499.2945557	0.63
500.1608276	0.15
500.9865723	0.04
514.3123779	0.40
515.1690063	0.44
527.2701416	0.23
528.4267578	0.22
529.2282715	0.50
544.9727783	8.71
545.6763306	0.08
552.9597168	0.37
570.3175659	2.25
571.1832275	9.46
572.3010864	1.80
579.5169678	0.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	541.2289
Annotation	3-[4-[1-(4-Hydroxy-3-methoxyphenyl)-1,3-dihydroxyisopropoxy]-2-hydroxyphenyl]propyl alpha-L-rhamnopyranoside
Peak:m/z	Relative Intensity
163.0784607	0.02
243.0496826	0.01
301.5382080	0.04
316.9035645	0.04
317.5599976	0.05
332.5988770	0.04
333.2355347	0.05
345.3483887	0.08
361.3364868	0.21
378.9649048	0.23
379.6068726	0.02
472.8134155	0.09
479.5291138	0.03
495.7064819	0.04
497.2588501	0.38
509.3500366	0.09
523.2685547	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	558.2064
Annotation	Unknow
Peak:m/z	Relative Intensity
159.7412415	0.04
169.9879761	0.70
173.9671783	0.85
188.0020447	51.49
189.1175232	0.11
192.0013580	9.25
192.6148071	0.11
204.9878845	100.00
205.5990601	0.30
206.7951813	0.03
233.9095459	0.18
258.1940918	0.06
297.1513062	0.14
308.1644897	0.12
315.3540039	0.25
318.0866699	0.07
324.1087646	0.02
331.9089966	0.07
333.0889282	0.02
336.1542358	0.09
342.9718628	0.12
347.3707275	0.06
354.0552368	15.34
354.7229004	0.10
360.4853516	0.12
361.1787720	0.58
367.3033447	0.02
374.1792603	0.02
378.9949951	0.04
381.0741577	0.07
396.0913086	0.15
408.9722290	0.03
419.2711182	0.03
420.2781372	0.32
424.5375366	0.03
437.9776611	0.14
440.4895020	0.12
445.3587646	0.03
454.2965698	0.12
455.9642944	0.02
463.9238892	0.10
475.1575317	0.05
522.5003662	0.03
525.9047241	0.03
536.7784424	0.04
538.1864014	0.02
539.2918701	0.41
540.2137451	0.33
541.3171997	0.03
543.9114990	0.03
545.8800659	0.19
546.7489624	0.05
550.6866455	0.04
569.4556885	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
81.0607605	0.73
89.13253784	0.08
94.97093201	0.60
103.1319733	0.33
104.9821014	0.22
106.9730835	0.36
108.9894562	0.53
117.2005463	0.35
119.1532288	0.26
121.0179443	1.62
123.1673584	0.26
126.7410431	0.15
128.9941406	4.27
130.0173798	0.92
135.203186	0.23
137.3595581	0.11
141.1200409	0.49
145.0332794	0.35
147.046875	0.87
149.052124	0.41
150.9933777	44.42
152.0168915	2.62
153.0604401	0.45
155.1070557	1.12
157.0545807	0.86
162.9776611	2.58
165.2068024	1.27
165.8388062	0.12
167.0920105	2.73
168.1774445	0.15
169.1131592	3.06
175.2518768	0.56
178.4348297	0.45
179.0611725	2.04
180.3092499	0.35
181.4148254	0.57
182.0912628	0.14
183.1907196	3.23
185.1973114	3.18
188.9330597	0.31
189.9241791	0.16
191.2317657	0.96
193.9308929	0.75
194.9011841	0.76
197.1492157	4.92
198.1016388	1.39
207.1504059	1.10
210.083786	0.63
211.1657867	0.55
217.1298065	2.84
225.183609	2.21
235.1739044	6.49
236.0018921	0.12
238.087204	7.33
239.346756	0.29
251.1641388	0.15
253.0918579	100.00
254.1916656	18.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.2756
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
151.0747833	0.17
154.9650726	0.23
155.9629517	0.12
165.1481476	0.09
173.1756287	0.05
176.9224243	0.19
180.0280457	0.20
198.1225433	0.17
219.4987488	0.10
225.8563538	0.10
251.4592285	0.12
255.0866089	0.03
257.7865295	0.97
261.5387878	0.20
263.5007935	0.13
273.1695862	0.39
279.3562317	0.07
281.2690735	0.08
286.2277527	0.09
290.3400574	0.25
295.1109619	0.06
304.0518188	0.11
308.4387817	0.21
317.3031921	0.05
331.2314453	0.20
332.1676331	0.05
335.3390503	100.00
337.2043762	0.17
343.5654297	0.05
344.7104492	0.14
351.0797729	0.09
364.2048340	0.27
374.4361572	0.14
375.9791870	0.05
379.0344238	0.13
388.3341370	0.20
407.4961548	0.06
409.5586853	0.11
411.2702332	0.11
413.2931213	0.15
414.0101013	0.14
415.3417053	0.05
416.3420715	0.11
421.9469910	0.10
427.2604675	0.06
428.3764343	0.10
429.9519958	0.11
432.6359558	0.24
434.5094604	0.26
440.7744751	0.15
441.4693909	0.06
446.9454651	0.07
458.1118469	4.03
459.2402039	0.89
466.7258911	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.1142
Annotation	Aralidioside
Peak:m/z	Relative Intensity
137.9619598	0.19
139.0375366	0.70
152.8765869	0.17
156.9456787	1.03
166.8956909	0.09
169.2260742	0.13
171.0358734	0.33
174.9010315	0.40
182.3303833	0.54
183.0463867	6.69
186.7806091	0.12
193.0582275	0.48
197.0457764	11.87
205.1329956	0.18
231.1428070	2.20
239.0672913	1.56
242.0826111	0.67
249.1543579	48.04
257.0824890	39.55
263.3071289	0.04
267.1481934	32.13
271.1825256	6.77
275.2149658	0.08
283.1353455	0.04
285.0489807	5.51
289.2392578	0.13
297.2974854	0.19
299.1718140	0.97
309.2597046	0.43
311.1682129	0.42
337.3448486	0.13
339.0587769	1.36
341.1825562	0.42
351.0343933	0.05
353.0160522	0.13
357.1184082	0.73
367.4444275	0.06
368.9844055	0.74
369.7043152	0.12
371.1760559	0.68
373.3192139	0.11
385.1312561	4.19
387.2361145	11.62
397.3846130	0.04
400.3594666	0.19
401.2864685	1.18
403.2463379	1.43
411.4507141	0.47
415.1549377	44.34
415.7729797	0.08
416.7431641	0.09
429.1498718	100.00
429.7588196	0.23
432.1520081	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	349.1292
Annotation	Unknow
Peak:m/z	Relative Intensity
120.8872223	0.03
136.9293365	0.03
145.1340637	0.02
175.2648926	0.03
187.2189789	0.03
189.2159424	0.01
191.4617157	0.04
193.3265228	0.02
199.3913727	0.07
201.2039490	0.21
213.3285522	0.09
215.2808838	0.04
219.0154419	0.03
231.1642761	0.45
232.9403076	0.04
241.1847229	0.02
243.1546936	0.95
245.4128418	0.02
251.4958496	0.02
257.1478882	0.21
259.3290405	0.12
261.1836548	0.80
269.3813782	0.15
275.2365723	4.86
277.4190369	0.06
285.2851562	0.14
287.1997070	1.21
289.8967285	0.02
301.1153870	1.31
303.3280029	0.16
305.2478027	6.44
313.4359741	0.15
314.1491394	0.05
317.6920776	0.02
319.1485596	100.00
320.1392822	0.18
331.2223816	4.02
333.3822021	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.2192
Annotation	Unknow
Peak:m/z	Relative Intensity
199.1707764	0.05
235.1972809	0.05
277.2433472	0.02
281.1758423	0.05
285.3484192	0.12
299.2994385	0.03
305.2865601	0.11
318.1546631	0.05
329.2261963	0.03
347.5272827	0.02
355.3721313	0.44
358.6958618	0.04
365.1477661	0.07
373.3535767	1.17
397.3348389	0.13
399.5219116	0.26
415.3827515	0.31
417.3584595	0.23
432.8849487	0.07
435.1973267	0.15
443.3376465	0.12
457.3897705	0.05
461.2965088	0.07
473.5192261	0.04
495.5425415	0.05
508.3674927	0.15
517.2361450	0.02
527.3921509	0.05
530.9265747	0.03
533.2200317	0.09
535.3284302	0.77
549.1736450	0.13
550.8753662	0.02
558.6351318	0.15
561.4081421	0.78
577.2232056	100.00
577.8624268	0.35
579.3533325	1.00
581.3566284	0.08
587.4396362	0.10
593.4931030	0.07
603.4293823	0.04
605.1453247	0.40
606.3716431	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	505.1624
Annotation	Unknow
Peak:m/z	Relative Intensity
143.9375305	0.06
185.0359497	0.11
187.1875610	0.02
202.2404175	0.05
235.4857178	0.04
236.1806183	0.03
241.0183868	0.04
247.1325378	0.06
254.2230835	0.32
260.3544312	0.09
264.7492371	0.02
269.2833252	0.03
271.0558777	0.09
276.2599792	0.04
286.0066528	0.03
297.3010559	0.04
298.1828003	0.20
299.0556030	0.32
300.1698303	6.84
301.1038208	0.21
304.3143005	0.16
310.3119202	0.08
312.2830811	0.45
313.0710144	0.10
314.8943481	0.46
325.2506409	0.06
326.3260498	0.07
330.1834717	0.50
332.2027588	0.08
338.2257385	0.02
340.2995605	0.62
341.0593262	0.05
348.2404480	0.06
351.9665222	0.04
356.2810669	1.90
358.2840576	6.73
368.3092957	0.06
369.3734436	0.03
376.1446533	0.84
384.3428040	0.16
395.1004944	0.14
397.2272949	0.19
402.1809998	57.41
403.2123108	1.82
407.1309814	0.04
413.2022705	30.97
413.8380737	0.09
415.2453918	3.43
430.2200012	0.50
431.3421326	0.86
439.2593079	0.05
441.1464539	3.95
443.3514099	0.13
452.1927795	0.08
459.2041626	100.00
460.1101685	0.13
461.1338196	2.49
461.7527771	0.01
469.2456665	0.06
476.0835571	0.13
477.2882690	2.37
487.1116638	40.41
487.7548523	0.10
488.5208130	0.15
504.9593201	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	491.19
Annotation	Campenoside
Peak:m/z	Relative Intensity
151.1347351	0.42
202.4038391	0.29
231.4852295	0.69
237.1660004	0.09
240.9470215	0.40
253.4725952	0.44
255.0663757	0.26
271.3235474	0.89
289.3270874	0.33
301.0917969	1.27
302.0765686	0.16
306.7517700	0.09
307.6920471	0.11
311.1382446	0.95
312.9611206	0.59
329.1001587	1.94
331.3969421	0.11
333.5499878	0.33
353.1715698	0.51
355.2337646	0.15
356.6306152	0.33
370.3493042	0.53
373.3460999	0.15
379.2471008	0.20
383.5052490	0.28
389.1803894	0.17
396.6826477	0.09
404.7416992	0.11
409.1674500	0.63
410.0602112	0.31
413.1449585	4.47
417.3863831	0.16
419.5656738	0.32
425.3364868	4.60
426.8890076	0.58
427.5457153	0.18
430.3374329	0.12
431.1452332	0.24
437.3324890	0.26
447.3567810	0.29
449.4910889	0.69
455.1923523	100.00
461.3972168	0.10
473.1436462	17.50
473.7635803	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	390.1384
Annotation	Deacetylasperuloside
Peak:m/z	Relative Intensity
115.9406128	0.07
122.8183746	0.12
126.9548798	0.06
131.2447968	0.04
132.1583862	0.14
149.1611938	0.16
154.9502258	0.07
156.9349060	0.44
161.1362915	0.16
165.9376221	0.15
169.1088257	0.14
173.1145630	0.16
178.9429016	0.69
181.9895020	0.45
185.0714417	0.11
187.2092133	0.06
188.9997559	0.22
190.9574890	0.04
192.1029053	0.28
197.0576172	17.82
201.8188934	0.15
207.9960022	0.10
208.8117676	0.35
210.0005188	0.69
210.8876038	0.11
220.7655945	0.22
222.1679535	0.16
226.3339233	0.05
227.3497620	0.11
228.1018372	1.63
235.0847778	0.06
251.1306152	0.06
251.9261475	0.11
257.3692627	0.11
259.1739197	0.05
265.3689575	0.10
267.2886047	0.05
269.1979065	0.35
274.3218994	0.18
275.1820068	0.37
280.3657532	0.23
283.1278687	0.15
283.8621521	0.11
286.2412109	0.10
288.1902771	0.10
291.4496765	0.41
296.3770142	0.07
300.9623413	0.34
304.3697510	0.16
309.1603699	0.78
311.3533325	0.20
313.3032837	0.14
321.1119080	0.14
323.0955505	0.08
326.1359558	0.58
326.9562378	0.70
327.6260681	0.13
329.0261230	0.09
330.5233154	0.10
331.2733765	0.30
341.0269165	0.29
343.2246399	0.18
344.3428345	0.62
345.2668762	0.15
347.0014954	0.13
348.9970093	1.74
352.8724976	0.04
355.1229553	19.59
359.1770935	0.18
360.1285095	0.04
362.4136047	0.46
363.1593933	0.20
368.2132568	0.22
372.0719910	8.34
372.8876648	100.00
379.0234680	0.06
380.6996460	0.24
389.9967346	0.24
393.0767822	0.03
400.8321533	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	306.0765
Annotation	Glutathione
Peak:m/z	Relative Intensity
98.5761108	0.20
99.2497635	0.23
112.0578308	0.06
116.0541916	0.21
120.0190125	0.14
124.7499542	0.17
126.1297302	0.05
127.1043472	0.13
128.0617371	8.14
130.0726013	0.07
143.0675964	9.40
143.9573669	0.10
145.1445618	0.40
146.0309143	1.46
154.9601135	0.18
160.0505524	11.53
167.0280609	0.53
169.0121460	0.22
170.9761658	0.70
177.0634460	10.60
179.0790405	10.07
179.8855438	0.05
181.9527283	0.03
185.0990448	0.67
192.1213989	0.19
193.1666870	0.09
197.1239624	1.68
210.0626221	5.59
211.0198975	0.16
213.0770264	1.24
228.1497192	0.56
231.0910339	1.50
234.3419495	0.05
236.2389221	0.41
237.2712097	0.10
242.1576233	0.95
249.0365295	0.07
252.0955200	0.08
254.1587830	94.67
260.1120911	0.09
272.0687866	100.00
288.1264954	64.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.77
Annotation	Unknow
Peak:m/z	Relative Intensity
212.8430786	1.52
296.7706604	18.53
323.1076050	0.43
378.0236206	0.35
380.6012573	70.79
381.3405151	0.12
386.9077148	0.42
428.8764648	0.03
462.1618652	0.53
464.4483032	100.00
465.1849976	0.38
488.8529663	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	502.209
Annotation	Unknow
Peak:m/z	Relative Intensity
147.1615448	0.08
150.3281403	0.03
157.9828796	0.09
160.1598816	0.10
165.8048248	0.11
171.1567688	0.03
176.1106720	0.07
211.1089630	0.02
213.1636353	0.11
221.2652893	0.06
235.2035675	0.05
243.1050415	0.07
257.1064758	0.05
259.2716980	0.03
265.3794250	0.10
271.2462158	0.03
272.7538757	0.25
275.6290894	0.10
282.3054810	0.03
283.3698730	0.13
293.9028015	0.05
301.3978577	0.08
306.9078979	0.06
312.4138184	0.10
317.0574951	0.05
325.4790039	0.18
327.4220886	0.43
333.0608521	0.12
334.9728088	0.09
340.1157532	0.31
343.2899170	0.05
345.1422729	0.27
356.2437744	0.10
358.9898071	0.05
360.0581665	0.03
363.1186523	0.13
370.2165527	0.02
371.4677124	0.03
377.1500854	4.79
378.7864380	0.15
382.6162415	0.06
393.0941467	0.03
395.1800232	6.30
403.0826111	0.12
404.9983521	0.16
410.2588806	0.17
413.2499695	0.22
420.3004150	0.06
421.0635681	0.18
422.2148132	0.39
427.6076965	0.39
430.2543030	0.25
431.8565979	0.18
436.5956726	0.08
438.3854675	1.24
439.1560974	0.07
440.2806702	0.44
444.0765381	0.10
448.2839661	3.68
449.1958618	0.70
452.5691833	0.04
456.1570740	0.70
457.3568726	0.04
458.1811218	0.16
459.5186462	0.03
463.4403687	0.35
466.2437439	25.82
467.2311401	2.12
469.2282104	0.02
469.9719543	0.05
473.4247131	0.25
479.1234436	0.12
484.1979675	100.00
485.2234802	2.98
489.6929016	0.22
491.8234253	0.42
493.3880005	0.16
496.0405579	0.33
509.5697937	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1087.495
Annotation	Medicagenic acid 3-O-b-D-glucuronide 28-O-[b-D-xylosyl-(1->4)-a-L-rhamnosyl-(1->2)-a-L-arabinosyl] ester
Peak:m/z	Relative Intensity
307.3341370	0.12
319.2920837	0.37
320.4621277	0.04
335.4050293	0.06
337.3001099	0.28
345.1358643	0.38
363.3010864	1.25
387.0818787	0.06
460.6405029	0.01
499.3500977	1.91
499.9555664	0.04
525.3529053	0.04
537.3681641	0.03
538.6343994	0.05
543.3071289	100.00
544.2269287	0.59
549.2458496	0.11
550.3580322	0.06
597.3419189	0.04
599.3692627	0.05
653.5341797	0.06
654.4879761	0.11
697.6785889	0.05
711.4785156	0.06
739.9345703	0.06
911.2091064	0.04
1044.2565920	0.05
1065.4632570	0.03
1071.1693120	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	209.0667
Annotation	Sedoheptulose
Peak:m/z	Relative Intensity
68.9039154	0.87
70.8734283	0.89
72.9439774	0.14
82.9155731	1.09
84.8708572	10.32
86.8812103	14.18
88.9624176	1.16
96.9971466	3.34
98.9369354	4.59
101.1110687	0.14
102.8942261	0.22
110.9468231	12.59
114.3589783	0.62
115.0196381	3.29
118.8708191	0.29
129.0109863	100.00
129.7253723	0.07
130.9264221	0.11
131.9570007	0.13
140.9879761	9.08
158.9406281	48.69
162.9929810	0.96
165.0695038	0.66
173.1459656	0.43
177.0142212	0.70
190.9522858	4.72
209.1527710	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	566.0212
Annotation	Unknow
Peak:m/z	Relative Intensity
160.7480316	0.03
169.9920654	0.16
171.7956696	0.53
173.2885132	0.05
182.1208496	0.08
183.8766785	1.97
190.9497986	0.64
196.0107269	1.10
197.9868469	1.60
199.8390503	0.04
205.1256409	0.14
206.0981750	0.43
209.7304077	0.11
211.8975677	0.38
212.9649353	0.09
213.9974670	0.37
214.9579468	0.15
219.9981232	0.48
221.2435150	0.07
223.9905090	0.36
225.9548950	0.52
227.9433899	58.17
229.2747955	0.11
230.0776062	0.09
231.0563354	0.27
232.0539703	0.05
240.1388855	1.10
240.9197083	0.33
242.1939850	0.15
243.9418945	0.26
250.0478058	0.05
252.0307312	0.25
253.9570312	4.50
258.1423645	0.23
258.9436646	0.09
262.0669861	0.20
266.9883118	0.03
267.8503418	0.09
269.9125977	26.04
271.1433716	0.62
271.8938599	0.97
276.0729370	0.69
280.1024170	0.09
284.1015015	0.92
286.1844177	0.08
289.7694702	0.06
296.0247803	4.31
298.0422363	1.28
302.0471191	0.77
303.0362549	0.64
304.1068726	0.73
306.3088379	0.06
309.9761353	0.07
311.8832703	1.21
313.9602051	19.80
315.2455750	0.82
316.1514893	0.11
317.9627075	0.09
320.8640137	0.11
323.1966553	3.48
323.9480591	1.46
327.1326904	0.04
328.1857910	0.55
329.9503784	100.00
338.4623413	0.41
340.0140381	1.09
342.8286133	0.11
344.1738281	0.37
345.0290527	0.13
345.9366455	0.14
347.0344849	0.09
347.7498779	0.15
357.9076538	9.72
359.0660400	6.60
360.0666504	13.00
360.9779053	3.02
362.0621948	0.88
362.8926392	0.10
374.0731201	5.69
375.9005127	2.86
376.9580688	0.05
378.0443115	0.16
385.0711060	0.23
386.2196655	0.08
387.7985229	0.57
392.1636963	0.17
393.4479370	0.23
396.0191040	0.46
398.0593872	0.53
401.9211426	0.67
403.9069824	0.15
405.2818604	0.08
406.9727173	0.17
413.9370728	0.03
415.9833374	1.41
418.3274536	0.71
420.0097046	0.25
424.2061157	0.17
428.1307373	0.03
430.9904175	0.49
431.8615723	5.89
432.9302979	0.16
434.1780396	0.60
434.8421021	0.07
442.0882568	1.08
444.0556030	1.67
445.0343018	0.07
446.8406982	0.13
450.3270874	0.21
458.9450684	0.34
460.0160522	0.11
461.9223022	39.59
462.5274658	0.31
464.8173828	0.05
467.8844604	0.18
476.1380615	0.83
478.0174561	2.85
488.0514526	0.32
489.7011108	0.05
504.0492554	0.47
506.0001831	0.15
521.3976440	0.59
522.0236206	2.11
530.2559814	0.14
546.9281006	1.01
548.0614014	29.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	615.17
Annotation	Unknow
Peak:m/z	Relative Intensity
172.0922546	0.15
179.0063629	5.29
187.0096130	0.36
188.4031372	0.59
211.1106873	0.12
213.2299194	0.59
214.9592133	0.07
233.0436554	3.32
272.2016602	0.23
290.2961426	1.07
291.1520386	0.88
308.0997009	100.00
333.1403809	0.15
347.2059326	0.66
355.1052856	0.69
356.1865234	2.64
357.0311890	2.65
361.0706177	0.42
387.1162720	0.41
405.0106201	3.01
407.0839233	0.48
411.0853271	0.52
423.1043701	38.56
439.0442505	0.18
443.1802979	0.61
468.1730957	0.35
484.0615234	0.37
485.1793823	0.90
486.0722046	9.03
499.3878174	0.20
512.7013550	0.36
540.4765625	0.29
571.2291870	1.29
580.9487915	0.08
597.0421753	4.30
597.6741333	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.94
Annotation	3,3-Dibromo-2-n-butylacrylic acid
Peak:m/z	Relative Intensity
95.0804596	0.16
95.9524460	0.14
115.9290314	0.16
127.2518845	0.32
141.9638824	0.24
142.8201599	0.22
145.1809082	0.15
148.9866028	0.31
152.2276306	0.32
171.0810852	0.27
178.0608368	0.12
180.0114746	0.57
181.0888977	0.24
182.9684143	0.32
184.5713806	0.94
185.2795105	0.45
185.8820038	0.30
190.2189941	0.21
198.2875061	0.14
205.6875305	0.73
212.2605286	0.26
212.9982300	4.28
214.2594604	0.47
215.1154480	0.60
223.0788574	0.21
228.7630615	0.79
233.0408020	1.61
236.2389221	0.49
237.9994507	0.50
238.9537048	0.22
241.1489563	0.78
241.9763184	0.23
244.6066284	0.30
250.1309814	0.86
253.9044189	0.08
254.9937744	0.94
257.2183838	0.26
264.7553711	1.31
265.3687744	0.39
268.1378479	18.22
269.1661377	100.00
270.1401367	10.16
270.8557129	0.06
279.3019714	0.66
280.8790894	1.51
282.9757996	0.67
284.8059387	67.62
285.7652588	4.19
287.6637573	1.01
289.8330994	0.14
293.9384766	0.51
296.2146606	1.29
297.9658203	0.87
298.8202820	1.31
302.8283386	2.48
304.7347717	16.54
305.3385010	12.91
305.9903564	1.14
307.5172729	2.30
308.3447571	0.60
309.4458008	0.26
310.3341980	0.49
311.1879272	0.23
312.0410767	0.24
313.3562317	4.01
314.2150879	3.98
314.8947449	0.46
316.6730347	4.45
317.2768860	0.32
321.4047546	0.53
326.0875549	3.25
327.0856323	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	270.154
Annotation	2,3-Butanediol glucoside
Peak:m/z	Relative Intensity
81.0559082	0.12
82.9975510	0.04
94.8835144	0.30
110.2974396	0.08
112.0751343	0.17
115.9466553	0.50
119.8358154	0.08
125.0789490	0.28
126.9376831	0.35
133.9336548	0.04
136.1407623	0.15
138.0019073	0.45
141.1284180	0.16
146.0350189	0.17
150.0743256	0.20
155.0115509	5.08
158.2294312	0.28
162.8813019	0.08
166.1668549	0.07
182.2814789	0.10
188.1566315	0.16
196.4008484	0.19
198.3298798	0.19
206.2203522	0.05
211.2050323	0.09
216.6642914	0.20
219.1401825	0.34
224.2022858	1.21
226.0764008	0.07
227.2152863	0.33
228.1999207	0.45
228.9980469	0.97
231.0662231	0.17
234.0273438	0.20
239.1703491	0.19
241.8412323	0.13
247.0386505	0.18
252.8738251	100.00
253.5896454	0.31
260.9901123	1.14
261.6737061	0.43
262.2795715	0.43
264.6554565	0.53
274.0182800	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	422.2011
Annotation	Unknow
Peak:m/z	Relative Intensity
132.9833679	0.09
135.3494263	0.22
137.0043030	0.52
138.0802612	0.47
143.1559906	0.21
144.6685791	0.13
146.9866333	0.21
159.9970398	0.05
161.1383514	3.99
163.0285034	2.00
163.9127197	0.16
164.8992615	4.21
175.0724182	0.18
175.8500671	0.07
177.1113892	0.25
180.0201111	1.42
180.9149780	0.39
182.9015198	0.18
189.0593262	4.16
195.9589539	0.14
207.0345459	44.22
211.0944824	1.14
213.0116730	0.17
220.9476624	0.17
224.9182281	47.59
225.5287476	0.24
226.1355286	0.28
229.0544434	0.42
232.1068268	0.06
236.1232605	0.13
238.3342285	0.40
239.2532349	0.05
242.8358765	100.00
243.5238953	0.54
244.8375244	0.34
251.8134460	0.06
254.3845520	0.43
260.0215149	4.05
261.1252747	0.15
270.3495483	0.12
274.8764038	0.14
280.9738159	0.23
283.1440430	0.42
284.2576294	0.33
284.9965210	0.32
293.0836182	0.39
297.4553528	0.20
301.2130127	0.78
303.3084717	0.10
308.5703735	0.77
310.6550598	0.11
311.8896484	0.08
316.1759949	0.20
317.1335449	0.31
319.3887024	0.12
322.9982300	0.21
330.2245483	0.26
332.2194519	0.13
333.1132202	0.51
337.9621887	0.37
340.4063721	0.53
347.3267517	0.30
351.4120483	0.06
360.4086914	0.19
361.6036072	0.27
362.3460999	0.08
366.1486206	0.24
367.0783386	0.27
368.9606018	0.20
372.0135803	0.08
376.2697754	0.65
377.3242493	0.39
378.4359131	0.33
380.4121399	0.31
381.3999939	0.11
383.9563293	0.09
386.1845398	1.89
387.0588379	1.42
391.0927429	0.72
391.8414917	0.22
401.2078552	0.09
402.2265320	0.32
404.2153015	14.92
404.9241943	4.75
407.2364807	0.06
412.8540344	0.18
413.7647705	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	555.28
Annotation	Tricalysioside I
Peak:m/z	Relative Intensity
160.9748077	0.21
178.8508759	7.17
224.9702454	2.98
253.0408936	0.10
327.2067871	0.44
347.3388062	5.96
353.1381836	0.15
372.1533203	0.15
375.4047241	0.14
381.3238525	0.39
392.0392456	0.06
407.3252563	0.20
409.4706421	0.11
419.4673462	0.29
422.5356445	0.19
434.4805298	0.05
463.4166870	0.09
469.3751221	0.47
469.9793091	0.53
474.4424438	0.14
477.3661499	0.07
479.3498535	0.10
489.2650757	0.33
491.4154053	0.26
509.3403931	100.00
510.9596558	0.40
512.1260986	0.09
517.1364746	0.10
519.5289917	0.29
525.1543579	0.42
535.2058716	0.39
537.2406616	1.77
538.4484253	0.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	383.2055
Annotation	Cinncassiol A
Peak:m/z	Relative Intensity
122.9763947	0.01
130.8275452	0.03
132.8933258	0.01
137.2769012	0.11
147.0158081	0.18
155.8764648	0.01
163.2070312	0.02
165.2426147	0.06
173.1952820	0.05
175.1533813	0.03
191.0348053	0.08
195.2101288	0.04
200.9293365	0.03
205.1756134	0.13
205.9820862	0.02
207.2167969	0.02
207.8533325	0.02
209.0576172	0.40
212.7422791	0.02
215.3654175	0.01
220.9522552	0.08
223.1323547	0.01
227.2432861	0.05
235.2199402	0.03
237.2873230	0.01
239.0448608	0.21
255.2720947	0.12
257.4527588	0.05
258.3768311	0.07
261.0747681	0.43
263.1408997	0.02
265.2164001	0.10
267.3209839	0.23
269.3164978	0.03
273.3092651	0.26
276.3442078	0.08
283.1454773	0.65
285.3106689	0.26
286.1396179	0.06
287.4805908	0.06
291.4008789	0.10
293.4223328	0.01
295.2530518	0.08
297.2025757	0.05
299.1540527	0.16
301.0850220	1.20
311.2428589	4.36
317.1487122	1.20
319.1647949	1.73
320.2577209	0.03
321.2590637	0.02
329.0481873	8.81
329.8038025	0.11
335.2677917	0.14
337.2593994	2.16
339.3184204	0.17
347.0948181	26.26
347.8009033	0.12
350.9868774	0.05
353.6833801	0.04
359.7218933	0.02
363.4226379	0.03
365.1136169	100.00
365.9110413	0.18
367.5127258	0.05
374.2184143	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	295.1188
Annotation	Phomopsolide B
Peak:m/z	Relative Intensity
94.9876633	0.33
109.0748062	0.14
110.9886398	0.29
112.9913177	0.15
114.9719543	0.05
118.9844284	0.07
119.9983215	0.03
121.0797577	0.15
121.8660126	0.05
122.9402771	0.47
125.0138016	0.06
126.9601135	0.02
137.1224670	0.41
138.0614014	0.09
139.1030884	0.09
145.2440186	0.03
155.1423340	0.08
159.0593262	0.04
163.1480103	0.54
164.1160736	0.03
165.1158447	0.67
167.0812988	0.03
171.1341248	2.42
183.0605927	0.44
189.1610260	15.32
192.3048096	0.10
200.8176880	0.07
205.4246826	0.04
207.1738586	2.33
215.2143555	0.12
220.9731445	0.03
222.3220825	0.12
226.8316650	0.01
233.0857544	1.18
237.3150024	0.08
249.2521667	0.16
251.0962524	100.00
253.4729004	0.02
267.6124268	0.06
277.2568665	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	273.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9785385	4.67
115.9692535	4.56
131.0326233	0.25
131.9463196	0.49
158.9317169	92.90
159.9853821	100.00
160.7469330	0.04
198.9402771	0.68
199.9978333	4.14
217.9573669	1.19
229.8653564	48.43
246.0744629	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	512.25
Annotation	Glaucarubinone
Peak:m/z	Relative Intensity
146.1764374	0.18
166.2371216	0.11
197.1658783	0.12
219.0844421	0.11
223.2446899	0.39
225.2292786	2.29
241.0506592	1.60
243.2306213	0.45
257.3143311	0.45
269.2222900	11.24
287.1588135	19.30
290.1268005	0.12
295.1797485	0.18
297.1051941	17.50
307.3892212	0.14
313.0482178	0.26
315.0930786	100.00
324.4530640	0.23
327.4171143	0.36
332.8892212	39.07
336.1436157	0.40
349.1956177	0.40
350.1752930	0.30
352.2319336	0.39
361.1762085	0.24
365.2608032	0.30
366.3738403	0.22
370.2463989	0.30
386.2451782	0.43
390.4319458	0.68
391.3280029	0.12
409.2838135	0.34
428.3220825	0.12
431.3621826	0.30
433.3170776	0.19
434.3209839	0.13
441.2616577	0.19
448.3503418	0.25
449.0831299	0.17
451.2506714	0.19
452.3275146	0.19
454.3537598	0.14
458.9722290	0.50
466.3020630	0.28
467.4621582	0.16
468.3896484	0.17
469.6091309	0.19
476.4376221	0.38
477.1387329	0.19
478.3099365	0.29
494.4617920	1.85
495.1892700	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	564.2116
Annotation	Unknow
Peak:m/z	Relative Intensity
162.9476318	3.81
170.9971161	0.93
200.2275391	0.69
200.9624176	0.45
218.8198242	0.76
237.0147552	1.88
254.8959351	100.00
255.5193634	0.47
270.8661499	0.34
310.2533569	1.32
324.8195190	3.42
325.4291382	0.05
397.1768799	0.07
401.4085693	0.13
416.1741333	3.69
416.9212036	32.44
472.2886353	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.1896
Annotation	6beta-Angeloyloxy-10alphaH-9-oxofuranoeremophilane
Peak:m/z	Relative Intensity
95.0076981	0.74
96.0125275	0.25
96.9953156	0.19
100.9152985	0.07
104.8690338	0.70
107.1170197	0.84
109.0385895	3.09
116.9648819	0.20
119.0844421	1.09
120.1729355	0.21
121.0700531	1.53
121.9616547	0.10
123.0339661	0.13
124.6171341	0.63
128.8477478	0.81
130.9418030	0.08
131.8583679	0.33
132.8875732	0.42
135.0484314	3.27
137.0764008	1.03
139.2363281	0.30
141.0796814	0.27
145.0512848	0.57
147.1253357	1.16
148.9942017	1.83
151.0932617	1.07
152.8959351	0.30
155.2829895	0.31
157.7065277	0.42
159.0880127	1.72
161.0740051	1.38
163.2409058	0.56
165.0193481	0.57
167.1107941	0.94
169.2262573	0.86
171.1568909	0.08
172.2451477	0.34
173.1546326	0.47
175.0223236	0.81
176.9897614	2.84
179.0772400	1.14
180.0795288	0.19
181.0459595	0.21
183.1610718	0.43
187.2942200	1.11
189.2118988	0.46
191.1255798	0.44
193.1334229	1.75
195.2031403	1.07
196.9220276	0.08
197.5506287	0.47
198.9754486	2.08
201.1032715	0.24
202.7897949	0.07
205.1052704	0.91
206.9953003	0.16
209.3477478	0.94
211.2616272	0.83
213.1102905	1.40
216.8432922	1.02
219.1776733	1.31
220.3011169	0.38
221.2082520	0.48
223.1947937	1.31
225.1583862	1.40
227.1627197	1.91
228.1150513	0.11
229.0718079	0.72
233.4014893	0.08
237.0468140	0.34
239.1947327	1.04
239.9717102	0.16
241.2030029	15.69
243.1637878	2.89
243.8963318	0.40
245.0519714	0.54
247.3611145	0.87
251.2263184	13.12
253.2963562	0.90
254.3649902	0.75
255.0942383	0.04
256.3507690	1.30
257.2131348	1.71
259.1442871	10.21
261.1742249	0.28
262.3363953	0.26
263.1970825	0.68
266.0350342	0.11
267.3023987	0.07
269.2247925	36.56
271.2946777	0.95
273.2243042	0.56
273.8732910	0.15
274.5967407	0.25
275.2276001	0.54
277.5058289	0.07
279.5863953	0.99
282.1287842	0.21
284.1398621	0.08
285.1557312	3.41
287.2553101	51.33
289.1691895	1.19
290.5024109	0.22
291.2484436	0.58
292.2012939	0.17
297.2264404	32.71
298.3160400	0.18
302.1731567	0.31
303.2913818	4.76
305.0209961	1.55
305.6287231	0.93
312.0073242	0.52
312.6295776	0.64
314.0156555	1.34
315.2136841	100.00
316.0931396	0.23
318.2750244	0.65
323.3722534	0.63
332.7269897	0.08
333.4079590	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1419.85
Annotation	Unknow
Peak:m/z	Relative Intensity
410.3667603	0.59
414.3422241	0.47
465.9284973	0.19
470.4158325	0.45
499.4251709	1.10
502.3739624	0.12
503.1327820	0.18
548.0830078	0.39
571.1903687	0.30
581.0509033	0.40
600.2913818	1.11
602.6237793	0.14
605.5116577	1.55
616.7177734	0.85
625.1651611	0.32
633.0803223	0.87
639.2939453	0.41
658.3670654	0.54
659.2650146	0.64
670.4321289	0.66
673.0877075	0.16
675.2572021	0.48
677.2026978	0.33
686.0781250	0.26
691.3013306	0.52
692.2775879	0.94
692.9655762	0.85
704.5567627	0.86
707.8242188	0.28
714.5709229	0.12
715.4332275	0.24
716.3941650	0.35
719.5106201	0.39
722.7663574	0.29
724.6437988	0.15
725.5602417	0.56
733.5550537	0.34
734.6788330	1.97
739.2186890	0.51
743.3258057	0.36
744.2857666	1.80
745.5603638	1.21
747.3718872	0.19
761.3825684	3.11
770.6271362	0.68
779.3269043	3.40
780.2052002	0.35
783.0910645	0.44
784.1441650	0.37
786.0756836	0.28
798.4656982	0.65
802.1511841	1.13
804.4031372	0.50
805.5267334	1.64
815.1470337	0.21
817.6198730	0.29
818.4389648	0.25
820.3289795	0.41
829.4671631	0.46
830.4801025	0.19
836.5087280	0.46
839.1840820	0.34
843.4156494	0.85
845.2486572	0.94
854.3988647	3.05
857.2196045	1.48
872.1952515	1.50
888.2685547	0.16
893.2225342	2.43
894.4416504	0.99
905.4414062	0.26
906.8963623	0.91
911.4222412	8.55
912.2637939	1.22
932.1713867	0.28
953.7976074	0.93
968.5026855	0.50
974.9468994	0.71
982.2452393	2.64
991.8280029	0.23
995.5915527	1.10
1003.2738040	0.44
1004.1469730	0.51
1014.4398190	0.60
1021.4041750	0.99
1022.4932860	0.24
1025.8839110	0.33
1039.4328610	12.63
1040.4666750	1.25
1048.1831050	0.79
1063.4340820	0.55
1068.4221190	1.26
1073.6506350	0.87
1080.3607180	0.34
1083.0561520	1.38
1099.6585690	0.63
1110.5039060	0.86
1117.8186040	0.26
1133.9101560	1.55
1138.4699710	0.44
1161.5406490	0.73
1179.9138180	0.72
1182.7832030	3.63
1188.6030270	0.21
1193.0377200	0.90
1194.0358890	0.85
1205.0598140	1.01
1206.7133790	1.29
1224.0004880	1.39
1225.6475830	0.35
1230.4367680	0.82
1231.2845460	1.08
1234.0419920	3.46
1236.8645020	0.65
1237.5361330	0.73
1239.9434810	0.46
1240.6284180	1.27
1241.4686280	0.51
1243.0257570	1.81
1244.5603030	1.43
1255.3751220	3.80
1257.6287840	2.04
1264.1071780	5.59
1265.1784670	0.52
1266.4510500	3.20
1272.5185550	2.18
1274.6674800	0.14
1275.2939450	1.35
1277.5968020	2.35
1279.0109860	4.57
1279.8208010	1.33
1280.6052250	2.44
1282.2076420	1.08
1284.8952640	3.17
1285.6765140	3.57
1287.5784910	1.13
1288.4815670	1.00
1289.8817140	0.67
1291.1401370	1.98
1292.5341800	2.70
1294.4355470	1.63
1296.1912840	0.20
1296.9597170	1.51
1297.8986820	4.10
1298.9367680	4.37
1299.8310550	5.08
1303.1707760	8.26
1304.7849120	1.56
1305.5040280	3.52
1306.1586910	2.57
1307.2176510	1.58
1309.0264890	1.63
1310.4257810	0.74
1311.2764890	7.04
1311.8822020	4.65
1314.4301760	1.74
1315.6037600	1.49
1316.8284910	3.02
1317.6267090	5.72
1318.3266600	2.58
1319.2766110	3.30
1320.9764400	3.26
1322.0815430	6.47
1322.8901370	6.61
1323.7550050	3.02
1325.2558590	2.89
1325.9588620	0.61
1326.6054690	0.90
1327.3754880	1.23
1328.0845950	9.56
1328.8321530	4.48
1330.0053710	2.28
1332.1577150	10.54
1333.2352290	10.11
1334.3443600	22.60
1335.8386230	4.49
1337.2976070	3.57
1338.4223630	3.89
1339.9011230	3.07
1340.5058590	15.87
1341.2299800	2.49
1342.1943360	2.28
1342.8288570	1.46
1344.1781010	6.57
1346.0035400	12.03
1346.9169920	8.79
1348.0534670	6.00
1349.1699220	3.41
1350.2436520	3.36
1350.8768310	2.59
1351.4953610	12.55
1352.2474370	6.95
1353.0554200	1.90
1353.8278810	1.75
1354.6212160	5.45
1355.6787110	3.72
1356.4550780	0.69
1357.5731200	25.66
1358.6235350	5.10
1359.2700200	6.07
1360.1259770	5.51
1360.9980470	6.67
1361.8540040	7.17
1363.4184570	46.32
1364.2602540	7.32
1365.2612300	3.36
1367.2753910	8.27
1369.1918950	25.55
1370.0212400	8.10
1370.7192380	20.82
1371.6147460	1.86
1372.9975590	2.69
1373.7197270	6.42
1375.2102050	19.62
1376.3420410	30.16
1377.0236820	11.08
1377.9333500	0.98
1378.7857670	3.14
1379.6125490	7.33
1380.3222660	5.62
1381.4887700	4.70
1382.5715330	24.11
1383.3779300	3.44
1384.4613040	10.45
1385.2504880	0.36
1386.0822750	2.15
1387.2137450	10.31
1388.4099120	31.82
1389.6134030	5.77
1391.0979000	3.32
1392.6738280	23.72
1393.4215090	5.62
1394.4124760	21.56
1395.6751710	55.35
1396.4027100	13.91
1397.2138670	4.40
1398.0129390	11.21
1398.9686280	45.01
1399.7165530	0.52
1401.5885010	100.00
1402.2863770	9.17
1403.2749020	4.14
1404.2319340	1.17
1404.8581540	4.88
1448.4388430	0.72
1450.5987550	0.72
1451.4272460	0.73
1470.1026610	0.41
1472.2117920	1.04
1475.6094970	0.97
1489.0733640	1.29
1490.4696040	0.17
1498.0490720	0.23
1499.3861080	1.66
1509.4434810	2.51
1514.5440670	0.96
1515.2092290	2.71
1515.8470460	0.28
1523.4849850	2.38
1530.4970700	0.13
1537.1822510	0.78
1545.2298580	0.93
1549.6146240	1.49
1551.9350590	0.22
1560.6502690	1.89
1563.2186280	0.80
1564.4056400	2.72
1565.5611570	2.58
1567.8702390	0.45
1569.2098390	0.82
1570.7263180	1.92
1575.0303960	0.53
1577.2581790	3.30
1582.6322020	0.18
1583.4511720	1.18
1586.5694580	2.59
1591.8585210	2.32
1598.4810790	1.82
1599.9719240	9.02
1600.6324460	8.21
1601.4322510	3.84
1608.8072510	10.68
1609.5059810	12.52
1610.3430180	4.12
1613.4016110	0.77
1616.2456050	4.24
1618.0072020	0.57
1620.1065670	0.56
1620.7558590	1.23
1622.8643800	0.65
1623.9765620	1.13
1625.2813720	2.15
1627.0716550	0.96
1628.0565190	1.10
1628.9909670	5.87
1629.7259520	0.11
1632.6627200	2.50
1635.9993900	1.00
1637.7525630	9.88
1638.4410400	1.70
1641.1822510	2.13
1642.0300290	1.37
1644.2833250	1.26
1646.0723880	0.72
1647.2789310	4.22
1651.6617430	0.91
1655.2465820	12.23
1656.2221680	8.11
1657.1224370	3.42
1658.8934330	1.01
1659.6680910	0.67
1663.9698490	8.33
1664.7691650	29.80
1668.0235600	1.27
1670.5091550	1.47
1672.0823970	1.79
1673.3140870	40.32
1674.2707520	2.72
1674.9583740	1.61
1676.4714360	0.55
1678.9366460	0.56
1682.0054930	1.08
1684.8231200	2.22
1686.7569580	0.75
1692.7833250	12.85
1693.8741460	2.39
1697.3996580	2.15
1701.5493160	11.06
1702.2065430	8.47
1719.8248290	0.68
1726.8232420	1.63
1727.8580320	1.93
1731.1101070	0.08
1735.4981690	0.95
1737.5991210	1.38
1745.2435300	0.43
1745.8719480	1.31
1752.7679440	0.34
1753.9334720	0.94
1760.1047360	4.05
1762.3903810	2.78
1763.1765140	0.18
1765.2071530	1.10
1770.3244630	0.84
1771.3220210	1.14
1777.8485110	0.32
1782.9525150	0.13
1791.1380620	1.61
1794.6624760	1.39
1796.5174560	2.61
1800.6395260	2.40
1803.5758060	0.27
1805.8270260	1.63
1806.5496830	0.90
1807.8380130	2.33
1812.1975100	2.38
1816.0948490	2.95
1817.8516850	1.87
1820.6003420	0.33
1822.0437010	0.60
1823.1843260	1.18
1826.1511230	0.95
1826.9522710	1.20
1830.3814700	0.96
1832.5352780	1.00
1834.6600340	2.18
1838.2419430	0.49
1845.3724370	0.30
1846.6203610	3.16
1848.4586180	1.66
1849.4361570	0.33
1856.9083250	1.32
1858.8513180	0.59
1859.5931400	0.95
1861.1732180	0.61
1865.9918210	2.53
1867.6280520	0.97
1868.6727290	1.13
1870.2974850	0.80
1871.3513180	3.17
1874.2878420	2.82
1875.3820800	1.99
1878.0831300	0.57
1879.8192140	0.77
1881.0954590	0.67
1883.6414790	1.09
1886.1960450	2.14
1892.8206790	4.48
1897.3864750	0.65
1899.2575680	2.09
1901.5711670	1.07
1905.6379390	0.79
1906.5612790	0.75
1908.3599850	1.90
1913.7972410	1.60
1914.7780760	1.23
1920.3356930	0.89
1921.9569090	0.68
1924.2891850	0.33
1925.1086430	1.24
1925.7131350	0.19
1928.6081540	0.56
1930.3363040	0.79
1932.4147950	0.49
1933.6009520	0.95
1936.2570800	0.37
1938.4642330	0.17
1940.1380620	1.33
1940.9216310	0.66
1942.3829350	0.90
1946.5745850	1.13
1949.1156010	0.65
1953.1519780	0.76
1953.7608640	0.51
1955.9266360	0.53
1957.7454830	2.47
1959.6345210	0.92
1961.8963620	1.55
1963.3439940	1.50
1965.1363530	0.58
1965.9548340	3.99
1966.6180420	6.67
1967.3557130	2.32
1969.1668700	0.19
1971.7169190	0.32
1973.9813230	12.27
1975.1878660	10.70
1975.8260500	13.91
1979.1368410	1.54
1981.8165280	1.49
1983.8026120	1.04
1988.9976810	42.35
1991.3365480	0.57
1992.9328610	2.92
1995.8742680	1.06
1998.1500240	1.04
1999.9982910	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.0856
Annotation	Gerfelin
Peak:m/z	Relative Intensity
92.9456253	0.08
100.8789978	0.08
104.8764648	0.41
111.0727768	0.22
118.9921417	0.14
122.9300003	100.00
124.0130005	0.05
125.1316376	0.28
126.8689575	0.59
137.0159607	0.59
138.9450989	94.35
139.7796326	0.10
142.9989319	0.17
144.8329163	0.06
146.9466858	6.02
147.9229736	0.10
150.9218140	23.44
153.1038513	0.66
159.3063354	0.19
161.5618896	0.16
162.8949127	0.07
165.0285797	38.94
166.5102844	0.25
167.1742249	0.13
169.1044312	2.20
173.2270508	0.18
174.8205872	0.12
179.1055145	0.10
181.1261597	0.68
185.0078278	0.15
187.4333496	0.07
188.1502075	0.05
197.1530457	0.04
201.1268921	0.26
204.9000244	0.23
209.6128845	0.18
215.2394409	0.09
218.0848083	0.05
221.1329956	0.04
226.0857239	0.33
226.8750000	0.06
229.1695862	0.40
231.2613220	0.35
233.3374329	0.03
245.0771484	0.55
249.0724792	0.40
249.8240051	0.29
255.0554199	0.19
258.2987976	0.03
262.1559448	0.03
267.5964966	0.27
273.0606079	22.30
274.1105957	0.22
276.0912476	0.58
281.8109436	0.50
284.9809875	0.61
290.7689819	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	385.1119
Annotation	10-Dehydrogardenoside
Peak:m/z	Relative Intensity
112.8815079	0.58
114.9574890	0.13
119.0536423	0.02
122.8764038	0.54
124.9871521	0.26
128.9036560	0.17
130.9515686	0.78
133.6490631	0.16
141.0103912	3.14
143.1582947	0.09
145.0913696	0.36
148.8773193	0.17
150.9378967	0.37
152.3832092	0.19
153.0206451	5.95
155.2386322	0.02
157.1291809	0.38
158.9943542	2.38
162.7903442	0.15
164.7820435	0.08
166.9530029	0.02
169.0586548	5.48
171.0370789	0.87
173.2327271	0.39
175.1448059	0.05
176.9325409	0.71
179.0169983	0.52
187.0241547	6.67
189.1074219	0.12
190.7784576	0.02
192.0757446	0.07
193.1521454	0.20
194.1960449	0.20
194.8733826	0.29
197.0700989	5.34
203.0010376	1.37
205.0764465	0.95
209.1153107	100.00
211.1059723	0.11
215.0222473	20.34
219.0261841	0.27
223.2186584	0.85
223.9474792	0.04
226.9302673	1.33
229.2223511	0.14
231.0008850	0.21
233.0408936	5.49
237.1939392	1.27
242.9739990	0.09
247.0612488	0.32
249.0250244	2.95
251.0092773	32.00
251.6776428	0.07
256.8415833	0.12
259.3504333	0.14
261.3221741	0.19
262.9967957	0.39
265.0160828	0.29
269.0560913	1.42
270.3494873	0.02
271.4650574	0.23
272.2514648	0.09
273.1269226	0.15
275.1851501	0.62
276.8710938	0.16
279.0717468	0.26
285.2035828	0.31
287.1590881	0.03
293.0892334	9.61
295.2816772	0.17
300.9645386	0.17
303.1693115	1.69
304.0994263	0.03
305.1266479	0.89
307.1310425	0.74
310.1450195	0.12
311.0457153	0.16
313.6048584	0.72
314.4006653	0.20
317.2940674	0.11
318.1102905	0.52
321.1098633	5.31
323.0025940	0.14
325.0874023	0.59
331.1294556	4.20
332.0061340	0.11
339.0149841	3.12
341.4395447	0.04
344.1246948	0.03
349.1307373	21.53
349.9039612	0.09
352.8509521	0.03
354.1152954	1.85
357.3182373	0.28
366.6019592	1.93
367.2170715	16.90
368.0688171	0.51
368.7080994	0.15
376.1126404	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	615.9
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0516663	0.03
200.0800018	0.04
229.9975433	0.07
273.0222778	6.29
274.0996094	3.68
386.8991089	9.80
387.8994751	11.70
441.1713867	0.04
482.0921021	0.07
487.2015991	0.06
498.8982544	0.20
500.9131470	28.20
501.9727783	100.00
512.7352295	0.04
513.9970093	0.10
515.1978760	0.05
526.1422119	0.06
541.9736938	0.06
544.2030029	0.07
560.1417847	0.03
569.8182373	0.46
571.2235718	0.05
572.1190796	0.14
587.9564209	0.20
589.0545044	0.04
597.5921631	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	414.1404
Annotation	Niazicinin A
Peak:m/z	Relative Intensity
157.7152557	0.15
247.3692627	0.10
248.2510681	0.08
249.1660767	0.09
271.1616211	0.24
277.3132935	0.07
278.7461243	0.11
293.0866089	0.02
308.4289551	0.03
317.6500244	0.06
324.0691528	0.09
325.8320007	0.13
326.9566345	0.18
336.1701355	0.05
342.2628784	0.05
349.9700928	0.04
351.1304321	0.02
353.1794128	0.10
354.3425293	0.10
366.2370911	0.14
368.1805115	100.00
369.3292542	0.02
377.2336731	0.03
378.0708923	0.23
383.2228088	0.34
384.0165710	0.12
386.1633301	0.02
395.1037292	0.13
396.2083740	0.22
397.2862549	0.23
398.2923584	0.06
399.0839539	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	363.1448
Annotation	Nagilactone B
Peak:m/z	Relative Intensity
117.1091080	0.30
139.0367889	0.05
144.9049530	0.07
156.9424133	0.85
171.3928528	0.04
173.1023254	0.59
177.1959381	0.05
180.9120178	0.10
197.3195801	0.07
201.1083984	6.56
203.1159668	0.13
209.0867615	0.06
215.1795959	0.83
217.1689453	0.73
223.1793213	0.04
229.1582031	0.49
231.3173523	0.22
233.1611633	0.13
239.2369080	8.12
242.0932617	0.79
243.0694275	0.03
245.1551208	0.90
247.1975708	0.25
249.2178955	0.21
253.0646667	0.13
255.2861023	0.28
257.1788940	23.78
260.3334351	0.19
263.0155640	0.05
265.1866150	0.05
269.0767212	0.16
271.1322327	0.06
273.2333374	3.56
275.2019653	7.08
281.2683105	0.37
283.2573242	1.06
287.3673096	0.10
289.0328979	0.19
291.1041260	0.17
292.0746460	0.07
299.3075256	0.48
301.2695923	73.69
302.3302612	0.36
309.3226013	0.18
314.9783630	0.14
317.3396606	8.10
319.2697144	42.59
320.1763000	0.33
321.1908569	0.12
323.5675659	0.03
327.3223572	0.63
329.4184570	0.40
335.3889771	0.06
343.0740662	0.11
345.1355286	100.00
345.9465637	0.61
347.1094971	0.20
363.5921936	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	548.92
Annotation	Unknow
Peak:m/z	Relative Intensity
175.0978241	0.21
176.0339508	0.14
206.9699554	0.18
208.7406006	0.05
210.4573364	0.02
212.8954163	0.38
214.4305878	0.03
253.0755005	0.15
290.7054138	0.54
292.8819580	0.06
294.8732300	0.25
296.8041382	1.73
298.5836182	0.06
310.4815979	0.09
312.6840210	0.05
325.4180908	0.08
335.2743530	0.05
336.9632568	0.04
356.1031494	0.04
357.0999146	0.11
371.0698853	0.04
373.0745239	0.22
374.1926270	0.28
374.9235840	0.23
378.5269165	0.04
380.7502441	20.79
387.0955811	0.19
388.6845093	0.02
393.2789307	0.06
394.2471313	0.07
410.7763062	0.07
413.2796631	0.07
418.8641357	0.07
462.5521240	1.08
464.5883179	100.00
465.2949219	1.16
472.9132690	0.02
475.0064697	0.12
480.9625244	0.05
489.0984497	0.02
502.6889038	0.28
503.3627319	0.01
513.4907837	0.02
516.3488159	0.03
525.9865723	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1921
Annotation	Unknow
Peak:m/z	Relative Intensity
130.9972534	0.09
131.9803772	0.21
139.0101013	0.21
143.0001831	0.26
144.9854126	0.31
148.9221191	0.27
153.0896912	0.05
154.0020752	0.10
161.1240845	3.32
162.0108032	0.06
163.2251892	0.12
178.8918304	3.95
180.0931396	1.22
181.1469116	1.38
189.1557007	0.41
193.1298523	0.10
199.2601166	0.06
205.1772461	0.62
209.3376160	0.42
223.0523224	0.15
224.0276031	0.53
225.1235809	1.71
226.0783081	0.42
227.0514679	1.06
247.4056702	0.28
249.0628662	0.43
252.8961182	0.97
255.9103088	0.19
263.1609192	0.45
271.2393188	0.76
272.2586060	0.17
281.1642151	1.29
289.4663391	0.14
291.1419373	0.15
301.2407837	0.54
313.9081116	0.20
317.1338806	0.51
328.9331055	0.12
343.2055664	0.36
345.3646851	0.06
365.4218445	0.23
369.1574402	100.00
369.9414673	0.51
378.9975891	0.14
385.1098328	1.27
386.0307312	1.81
387.2517395	22.57
389.2887878	1.48
397.2520752	0.56
398.4930420	0.57
400.7059326	0.09
401.3570862	0.09
405.5468140	0.35
414.2721863	0.13
415.3090210	0.95
416.4747009	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	730.88
Annotation	Unknow
Peak:m/z	Relative Intensity
229.0985413	0.24
230.3991699	0.07
272.9713440	12.46
273.9078369	4.06
275.0716858	5.08
277.1308594	0.10
290.0626221	0.18
305.3319702	0.07
386.9630737	10.85
387.9788208	6.30
388.8894043	6.55
487.4196167	0.03
500.8880615	32.92
501.8587036	29.73
502.9679565	51.34
504.0186157	0.99
555.2081909	0.12
573.0127563	0.33
575.8790894	0.09
587.8605347	0.11
610.2283936	0.61
611.1264038	0.47
612.1521606	0.49
614.8175659	24.71
615.8238525	51.10
616.8366699	100.00
617.7769165	0.27
618.3923340	0.10
629.1583862	0.98
631.6061401	0.05
647.9069214	0.17
654.7835693	0.10
655.8587646	2.06
656.9639893	3.39
658.0072632	2.75
669.0662231	0.19
673.7581177	0.58
675.0196533	2.24
676.0191040	0.53
682.9191284	0.25
684.0042114	0.59
684.8806152	0.68
686.0653076	0.22
702.0648804	0.30
702.9359741	0.48
708.7180786	0.47
712.8667603	0.20
843.4028931	2.16
844.6541138	0.92
845.6517944	1.59
847.0267944	0.39
931.6772461	0.17
956.6790161	0.99
957.8020630	1.96
959.0272827	2.23
959.8853149	2.43
960.5563965	0.13
1070.6491700	0.31
1071.8991700	0.26
1072.5811770	0.18
1073.5977780	2.18
1184.7730710	0.05
1185.3902590	1.59
1186.5412600	2.51
1187.5102540	5.21
1188.5092770	0.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.1487
Annotation	Methyl di-alpha-L-rhamnoside
Peak:m/z	Relative Intensity
96.8538513	0.13
99.0261917	0.15
105.0659637	0.10
117.0079498	0.25
121.2266846	0.54
122.9984970	0.15
125.7482910	0.05
126.9007797	0.05
133.0599213	0.21
135.0146484	0.14
135.9039764	0.29
144.9692688	0.06
146.9630737	0.09
149.6654968	0.68
150.9367981	0.36
154.9846497	0.10
156.3302612	0.32
161.0354462	0.73
162.8585663	2.52
168.1748962	0.09
178.1959229	0.12
178.9742737	0.28
181.1167603	0.05
181.9534454	0.16
184.1390686	0.62
185.0834808	0.64
187.0296783	0.12
191.1701355	0.08
197.1983337	0.16
199.0823975	0.21
201.1665497	0.14
209.3187256	0.34
212.1365051	1.42
213.0407104	1.57
215.2238159	0.13
217.3093872	0.17
221.0563354	0.24
223.2971191	0.19
233.3283386	0.25
235.1272583	0.28
237.2614136	0.18
238.7197266	0.37
241.0114746	0.19
242.9334717	0.09
245.6911011	0.06
248.8278503	0.06
250.9798584	0.21
252.1415405	0.36
253.1411743	0.37
254.1617432	0.23
259.0599365	0.07
260.1229858	0.07
261.1422729	0.13
262.0989380	0.46
265.2667847	0.05
266.3693848	0.16
267.1295166	0.21
268.2072144	29.23
269.2278748	100.00
270.4013062	0.07
271.2454224	0.16
279.0675659	1.12
280.3200684	0.54
281.2009583	0.51
284.0701599	0.70
288.9856873	0.14
291.8231201	0.03
293.4079590	0.31
297.0241089	0.34
301.3653259	0.08
302.7121887	0.85
303.8422852	1.58
307.1699829	3.58
308.1944885	3.88
309.2987671	0.39
310.3716736	0.15
313.2170410	0.17
316.6434937	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0928
Annotation	Glochidionolactone A
Peak:m/z	Relative Intensity
94.9774704	0.06
96.8877411	0.06
99.1317139	0.17
100.9688110	0.68
107.0638123	3.97
112.9765015	0.96
124.7685547	0.14
129.0423889	0.09
132.9110413	0.05
142.9375610	0.84
147.1338196	0.03
150.9546814	100.00
152.8829346	0.09
159.1866150	0.14
161.0331116	9.10
172.9483490	0.13
175.0140076	1.88
181.9235229	0.20
188.8602142	0.22
191.2908173	0.22
193.0765686	1.76
204.8986816	0.51
217.2083435	0.12
221.0056458	0.10
223.0933228	0.53
225.3102722	0.09
234.7784119	0.24
249.2786255	0.03
253.0524902	0.81
266.9902954	0.33
269.1520996	0.40
285.0998535	0.04
294.1187744	0.11
295.2846985	0.46
296.0303650	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	685.3618
Annotation	Unknow
Peak:m/z	Relative Intensity
227.1245728	0.03
297.1027832	0.07
303.3901367	0.04
361.3459473	0.07
370.8712158	0.09
381.3147583	0.04
384.3460083	0.06
400.9122925	0.11
425.3341064	0.09
426.4407959	0.18
428.4559937	0.05
442.9816284	0.08
471.5913086	0.02
505.6992798	0.57
512.4536743	0.23
522.4956665	0.05
523.3715210	0.38
530.2880249	0.24
536.9408569	0.03
546.3692017	0.03
552.3698120	0.13
562.9840698	0.18
569.2036743	0.06
578.7882080	0.04
579.4238892	0.55
581.4030762	0.06
606.6055908	0.15
623.3772583	45.46
624.0137329	0.28
632.5570068	0.05
640.1362915	0.11
641.3074341	0.14
641.9381714	0.04
644.3749390	0.03
649.4550781	0.40
650.6607056	0.10
667.4569092	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	287.15
Annotation	Crispine C
Peak:m/z	Relative Intensity
86.9159698	0.14
93.1178513	0.09
95.0013428	0.18
107.0282898	0.29
111.0624847	0.26
126.8566818	0.02
139.2091370	0.11
141.2359314	0.08
159.1727600	0.22
163.1517639	0.41
165.1979980	0.27
167.2809906	0.08
172.8768768	0.07
183.2871246	0.05
185.0162354	0.12
189.4017334	0.14
191.0606537	0.31
199.2731323	0.11
207.2308960	4.04
209.2027893	6.07
212.9584656	0.71
215.0802002	0.45
225.2244568	15.48
227.1031189	100.00
233.3323059	0.05
241.0684509	0.21
243.2830811	1.85
245.0903015	0.48
251.2263794	7.43
254.1469727	0.13
259.2968750	0.13
267.2314758	0.13
269.2185364	86.68
270.6172485	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	544.73
Annotation	Unknow
Peak:m/z	Relative Intensity
206.7849426	0.58
208.8708038	0.45
217.8847961	0.03
272.9300232	0.01
290.8268127	6.76
292.2616882	1.47
292.8735352	8.85
333.3958740	0.12
337.0317383	0.04
370.7717285	0.32
374.0111084	0.07
374.6593628	2.05
376.0811768	0.20
376.7089844	4.67
382.7137451	0.20
396.8141479	0.06
408.6967773	0.04
424.7423706	0.45
437.9533691	0.08
438.8795166	0.07
454.5725098	0.02
458.5437012	17.30
460.5299683	100.00
461.2240601	0.59
480.6504517	0.10
482.6275024	0.04
483.8311157	0.01
484.8127441	0.69
498.6705933	0.37
526.0236206	0.07
528.6484985	0.09
536.0698853	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.276
Annotation	Tricalysioside J
Peak:m/z	Relative Intensity
161.1161346	0.02
179.1788635	0.05
217.1152649	0.09
226.1345520	0.02
303.2189941	0.05
329.2392578	0.17
349.3673096	0.06
350.2653198	0.17
351.2699585	12.07
361.2864380	0.04
363.2916870	0.08
373.2758789	0.04
378.3830566	0.03
379.2237549	0.01
393.3028564	0.24
397.0183716	0.30
399.8698730	0.02
401.4511108	0.03
426.3755493	0.02
441.1988525	0.03
459.5223999	0.05
463.3545532	0.13
465.5191650	0.03
471.1055298	0.06
473.4664917	0.18
485.4118042	0.02
487.1195679	0.03
491.1406250	0.03
492.9545288	0.01
495.4524536	0.07
497.1814575	0.14
499.6626587	0.11
511.6264038	0.25
513.3309937	100.00
514.0029907	0.08
515.3298950	0.09
521.3439941	0.06
523.2508545	0.35
526.1231689	0.06
526.9284668	0.11
529.5348511	0.16
541.2521362	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.1506
Annotation	Ile-HoPhe-OH
Peak:m/z	Relative Intensity
127.2080002	0.17
147.1753845	0.08
148.1485901	0.15
150.7698975	0.19
166.0937195	0.30
167.1452942	0.42
179.1560364	0.57
181.1426392	1.49
209.1807861	0.66
210.9259033	0.27
216.8627319	0.13
220.928009	0.54
221.9429321	0.16
225.0674744	0.23
235.1253967	0.10
237.0714417	0.36
239.0987854	0.16
249.073822	0.98
253.071991	0.13
253.9530029	0.33
263.1542664	0.05
265.0648193	1.47
266.8936157	0.07
277.0267944	0.07
279.0559082	0.32
291.0314026	0.07
292.1433716	0.12
295.0645447	0.49
305.0897827	0.10
312.6954956	0.12
323.2474365	0.53
325.2382812	0.43
341.1737671	0.04
351.2896729	0.22
353.1898804	11.04
354.1760254	5.22
355.1697998	100.00
357.0013428	0.40
358.3038635	0.12
359.3245544	0.27
367.1480408	0.15
371.974884	0.10
382.7775269	1.13
383.4371643	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	381.08
Annotation	Unknow
Peak:m/z	Relative Intensity
169.2723999	0.13
184.9603424	0.15
194.2254639	0.22
208.9203491	2.18
210.9291229	2.40
212.8976746	15.53
292.9530029	0.13
294.9046326	1.60
296.8081665	100.00
334.7358093	32.70
363.1543274	1.21
380.7361755	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.2235
Annotation	HC-toxin
Peak:m/z	Relative Intensity
137.0505066	0.07
142.8313904	0.08
151.2178345	0.06
160.8605957	0.48
173.3206177	0.30
179.1079407	0.09
198.0260925	0.09
209.0187683	0.10
227.0949707	0.13
228.9805298	1.18
236.9972534	0.04
243.1140137	0.03
245.3352661	0.14
253.5509644	0.04
255.1180725	3.31
269.1304321	0.07
273.0958557	12.20
287.2281494	0.20
304.3211060	0.16
307.1936035	0.04
313.1565552	0.07
315.1007080	0.32
323.4028931	0.08
331.2533264	0.22
339.2678833	0.48
345.0477600	0.06
347.1484985	0.17
349.2731628	0.52
351.2606201	0.19
357.2835083	0.08
358.8920288	0.04
373.2987366	0.20
375.2410278	0.31
387.0191650	0.33
389.2182617	100.00
389.8357849	0.19
391.3066711	1.53
392.3043518	0.19
399.2764282	0.33
405.0377502	0.22
417.1657104	1.52
418.4358521	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	511.2526
Annotation	Parvifoliside
Peak:m/z	Relative Intensity
146.9959717	0.18
149.2205811	0.10
151.1811829	0.17
153.1530762	0.06
155.0179901	0.34
157.1553650	0.14
159.1696167	0.45
161.0699921	0.33
161.7927094	0.15
164.9938660	0.94
168.9668884	0.55
170.9100037	0.15
173.1091919	0.37
175.0437012	0.07
177.0523376	1.15
178.0295715	0.04
178.9944305	0.09
181.0110474	0.19
182.8372040	0.39
184.8312836	0.15
187.5122528	0.22
189.0557861	0.10
193.1380920	0.63
195.0230103	1.11
197.1885376	0.25
199.2040100	0.80
203.1709900	0.12
205.1255341	0.18
207.1348419	0.81
209.1522369	0.26
211.2102966	0.51
213.1288300	0.07
214.9996338	0.08
217.2921753	0.80
221.1738281	0.09
223.2630920	0.32
225.1645813	0.78
227.0775909	0.21
228.9884949	0.40
231.2096100	0.05
235.2712097	0.23
237.3747559	0.13
239.2066040	3.31
241.1486511	2.46
243.2398071	0.29
245.1233215	1.19
247.1225433	0.53
249.1889648	2.20
251.2940216	1.12
253.4619598	0.03
255.1066895	0.64
257.1940613	3.89
258.8746643	0.09
261.1766968	1.04
263.0830078	0.57
267.1784058	11.36
269.2465210	0.66
271.0789795	0.20
273.1088562	0.42
275.0722656	0.04
276.9887085	0.06
279.1780396	0.12
281.3224792	0.71
283.0809326	0.20
285.1642456	27.29
287.1082153	1.65
293.3708496	0.13
295.2338562	4.85
297.1796875	0.46
301.2180786	1.38
303.1331787	4.19
305.2867432	0.24
311.2847290	0.40
313.1627197	39.19
315.1621094	0.74
319.0151367	1.12
321.1679077	0.78
323.4533081	0.27
325.0808716	0.05
328.4953613	0.14
329.1122437	0.35
331.2081299	100.00
331.8491821	0.18
333.1865845	1.47
338.9689941	0.31
341.2065430	0.08
347.1743774	0.16
349.2612305	65.22
351.3194580	0.44
353.4512329	0.08
367.1139526	0.15
369.2268066	0.86
372.5695190	0.33
373.2081909	0.06
376.4721069	0.47
377.5355835	0.45
379.5458984	0.05
383.0979614	0.32
391.3294678	0.57
397.2593994	0.65
403.5244141	0.12
411.2825928	0.15
413.3682861	0.29
415.1903076	0.11
417.0155029	0.05
419.3715210	0.33
421.4131470	0.28
428.4436646	0.06
429.2368774	1.31
431.3256226	0.13
433.0426636	0.10
439.2009888	0.52
447.1807251	1.31
449.2915039	0.41
457.3805542	1.87
463.0657349	0.31
465.4343262	1.50
475.1930542	2.81
481.5873413	0.18
490.8857422	0.13
493.3519897	34.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.1762
Annotation	[3aR-(3aalpha,4beta,6alpha,6aalpha,7beta,7abeta,8abeta,8balpha,8cbeta)]-Dodecahydro-6,7-dihydroxy-6,8a-dimethyl-3-methylene-2-oxooxireno[2,3]azuleno[4,5-b]furan-4-yl ester 3-methylbutanoic acid
Peak:m/z	Relative Intensity
115.1114731	0.03
121.1982956	0.20
127.0556107	0.09
127.9866409	0.08
133.0334015	0.11
135.0883179	0.26
143.1141357	0.05
161.2268982	0.13
163.1105194	0.04
165.9408875	0.09
173.0923462	0.83
175.3154602	0.14
177.3423309	0.11
183.2543030	0.10
185.2075958	0.12
187.0394897	0.66
191.3040466	0.39
193.3269501	0.18
197.1525116	0.06
198.4011230	0.06
199.3086395	0.15
203.2621460	0.23
205.1935425	1.63
207.1036987	0.58
209.2047424	0.09
212.0256195	0.05
213.4611053	0.14
215.2725830	1.26
217.1444397	3.60
218.0969543	0.08
219.1560974	1.21
221.2582397	3.98
222.2760315	0.35
225.1425476	0.03
227.2518921	0.06
228.1705933	0.11
229.2285461	0.43
231.1881104	0.44
233.2446289	1.66
234.1287231	0.03
236.9859619	0.25
239.1853027	0.09
241.3099976	0.05
243.1856079	0.85
245.2707214	1.85
247.2465820	4.68
248.2743835	0.69
253.2174072	0.05
255.2362671	1.60
256.3214722	0.09
257.2461548	0.20
258.4017944	0.15
259.4317627	0.06
261.2366943	4.41
262.1384583	0.10
263.1761780	1.46
269.1679382	0.05
271.1944580	2.22
273.2887878	10.17
279.4352722	0.03
285.1402588	0.15
287.2070923	0.65
289.2892456	8.47
291.2489014	14.03
292.3349304	0.28
299.2194214	0.56
300.2838745	0.22
305.3198242	0.59
307.2999878	5.46
308.0537109	0.06
309.9624329	0.05
315.2894287	1.47
317.2661133	22.05
318.3494263	0.64
319.1838989	0.06
323.1858826	0.08
333.3399048	0.73
335.2204895	100.00
336.3315735	4.67
342.8901367	0.06
349.3035278	0.07
351.1668396	0.79
359.2089539	0.16
361.1842041	55.17
362.2379761	2.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	864.7647
Annotation	Unknow
Peak:m/z	Relative Intensity
254.3705444	0.15
268.1777344	0.19
269.2051697	0.15
284.7709045	0.18
297.2687073	0.51
304.9515686	0.05
325.0709839	0.13
326.4544067	0.10
330.0591125	0.27
344.2736816	7.57
345.1078491	0.78
353.1960449	0.22
366.3265381	0.33
369.3088989	0.26
379.2803345	0.14
393.4226685	0.21
407.1240234	0.29
410.0618286	0.16
415.1958618	0.07
421.0301514	0.18
425.3287964	0.35
426.4417725	0.33
443.3203125	0.58
449.1054688	0.07
477.9970703	0.18
514.2609253	3.71
515.2797852	0.15
553.4857788	0.16
554.3016968	0.36
559.1877441	0.07
568.7474976	0.05
569.3514404	0.49
579.2644653	0.07
604.8427124	1.20
611.8886108	0.05
618.7355347	0.26
632.5671997	0.56
638.1223755	0.25
667.4602661	0.08
679.4618530	0.20
682.4634399	0.25
683.8192749	1.45
685.1933594	0.10
689.9581299	0.39
690.5812378	0.16
692.6874390	0.13
703.1116943	0.36
707.6889038	0.32
708.4177856	0.57
710.6997681	0.33
711.6322632	0.56
712.2332764	1.08
713.6121216	0.63
717.5890503	0.26
719.0383301	1.91
722.1524048	0.31
728.3753662	0.06
735.3682861	0.22
741.0119019	0.50
741.8345947	0.58
751.3616333	0.24
754.4426270	1.06
765.6839600	0.49
768.1748657	0.29
772.2986450	0.44
773.5034790	0.26
775.4371948	0.64
776.6998291	1.16
777.4310913	0.04
783.2295532	3.10
783.9142456	0.27
789.5986938	0.23
794.4728394	0.32
795.4735718	0.71
796.4442749	0.60
797.7781372	0.32
802.9641724	0.14
804.1353149	12.77
805.1558228	1.72
806.3344116	0.08
809.9262085	0.64
810.9319458	0.49
813.9367065	0.76
816.2172241	4.97
817.2565918	0.19
818.3131104	0.39
819.6996460	0.78
822.7738647	0.65
837.8987427	0.41
839.4667969	0.46
840.6560669	0.09
843.8372192	0.38
847.3068237	0.65
848.4163208	0.13
849.1390991	0.45
851.0302124	0.19
854.4118042	0.75
868.1079712	0.82
891.4335938	0.93
894.5540161	0.19
902.8374634	0.32
907.2566528	0.16
916.9342651	0.48
918.2192993	0.65
922.6463013	0.17
923.6495972	0.33
931.9101562	0.68
939.5753784	0.15
940.5868530	0.36
941.5592651	0.22
951.7677612	0.17
957.5927734	0.56
960.6442871	0.36
961.6152954	0.34
967.0794067	0.20
968.2354126	0.21
974.6726685	0.20
983.7927246	0.21
986.2112427	4.19
987.4008179	0.75
988.6445923	0.53
996.5615845	0.43
1008.0437010	0.14
1011.0256960	1.75
1011.8768920	0.17
1021.1303100	0.32
1033.6052250	0.51
1036.6635740	0.40
1038.7460940	0.19
1046.3978270	0.55
1061.9514160	1.09
1068.4127200	0.31
1069.9096680	0.21
1072.4305420	0.05
1075.7471920	6.95
1076.7478030	1.28
1080.6466060	0.08
1085.4790040	0.27
1090.1018070	0.06
1092.5656740	0.20
1094.3083500	0.21
1099.5083010	0.32
1107.2991940	0.86
1108.0891110	0.24
1111.5140380	1.25
1112.2146000	0.50
1115.8787840	0.53
1116.5053710	0.82
1117.3194580	1.06
1119.0043950	0.56
1124.9853520	61.43
1125.7230220	100.00
1126.7320560	1.17
1127.3474120	0.11
1128.1824950	0.59
1129.6848140	0.10
1137.8063960	0.39
1138.8449710	0.30
1152.3532710	0.80
1173.6513670	0.79
1175.0277100	0.36
1179.5478520	0.31
1181.1308590	0.13
1182.5897220	1.04
1210.5183110	0.14
1213.8940430	0.34
1222.8146970	3.08
1223.5166020	6.93
1225.0897220	0.38
1227.4895020	0.70
1236.7410890	0.11
1251.1007080	0.12
1282.6956790	0.26
1298.5889890	0.13
1303.9887700	0.20
1310.0211180	0.24
1354.6568600	0.20
1377.7507320	0.15
1378.8195800	0.22
1437.6508790	0.52
1452.9591060	0.12
1490.9577640	0.13
1505.6051030	0.15
1524.4742430	0.43
1525.9058840	0.10
1538.6885990	0.65
1557.0025630	0.10
1569.0913090	0.11
1609.7913820	1.25
1696.6402590	0.10
1712.5887450	0.45
1726.1651610	0.37
1735.8863530	0.16
1840.9864500	0.84
1892.9503170	0.06
1908.3167720	0.23
1941.6447750	0.14
1966.2525630	0.89
1979.0189210	0.08
1996.9322510	1.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	379.1377
Annotation	8-Hydroxy-3'',4''-dihydrocapnolactone-2',3'-diol
Peak:m/z	Relative Intensity
135.2188721	0.02
161.1401062	0.04
177.2496643	0.01
183.3240051	0.03
187.3329315	0.12
213.1131897	0.05
243.1508789	0.03
251.2265015	0.03
264.9851074	0.02
269.3233948	0.06
271.2400513	0.29
274.1429749	0.05
283.3290405	0.03
287.1116333	0.20
292.3092346	0.04
297.1098328	0.16
305.0477295	0.69
307.3851013	0.03
315.0617981	3.34
315.6725159	0.01
319.3218384	0.02
331.3485413	0.10
333.0210876	100.00
341.1002197	0.02
342.5057068	1.34
343.1774902	7.31
347.8412170	0.05
358.5780640	0.23
360.7927551	24.83
361.4943848	0.11
366.8369446	0.06
370.3329468	0.03
379.0609131	1.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	719.2769
Annotation	Semperoside
Peak:m/z	Relative Intensity
273.4926147	0.04
319.1604919	0.01
341.0980835	0.01
345.4468384	0.01
399.1776123	0.02
461.2794189	0.02
471.2997437	0.01
479.5242920	0.01
499.1751099	0.01
501.2567749	0.05
511.2694702	0.12
521.3112183	0.00
529.4030762	0.01
539.4816284	0.08
543.3316040	0.05
545.1674805	0.05
557.1918335	0.02
589.7233276	0.01
597.1401978	0.02
599.3543091	0.02
606.4581299	0.02
633.4590454	0.01
639.1195679	0.08
669.4853516	0.02
673.2263794	0.01
675.6307983	0.03
683.0000610	0.01
687.8629150	0.03
699.2954712	0.07
701.3208008	100.00
702.3904419	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	347.1499
Annotation	Armexin
Peak:m/z	Relative Intensity
166.9886169	0.10
199.2441101	1.02
209.3378754	0.10
215.2087402	0.07
221.0838318	0.02
223.2842102	0.08
229.1069946	0.07
237.3236084	0.04
239.2030945	0.94
241.1472473	71.47
251.5064392	0.05
255.2893066	0.30
256.9954834	0.03
258.5809631	0.24
259.2593994	1.50
267.3644409	0.11
269.1691284	0.15
285.1206055	3.85
286.2032471	0.03
293.1920776	0.04
301.1356201	0.35
303.1860352	100.00
310.4022522	0.09
311.2963867	0.22
320.1332397	0.05
329.2702026	1.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1056.01
Annotation	Unknow
Peak:m/z	Relative Intensity
303.1979370	0.19
317.3501587	0.12
319.2005005	0.11
321.3696594	0.07
335.2675171	0.09
337.2021790	0.40
347.2052002	0.14
365.2925720	0.55
437.4617004	0.05
465.5000305	0.32
482.9299927	0.05
497.3737793	0.71
499.3918762	0.87
500.1422119	0.03
509.2591248	0.05
527.2890015	100.00
528.0892334	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	817.5134
Annotation	Unknow
Peak:m/z	Relative Intensity
279.2641907	0.61
280.0697021	0.32
281.0686035	0.17
283.1512146	0.50
283.8940125	0.12
329.3725586	0.46
339.3645630	0.14
387.5007935	0.21
449.5687866	0.11
458.4932251	0.09
459.2401123	0.29
528.9938354	0.09
535.4906616	1.42
537.3334351	33.42
538.4378662	4.49
555.3924561	3.87
556.4580688	1.01
559.5832520	0.17
561.3256226	100.00
562.2424927	15.73
563.1919556	1.41
563.7957764	0.07
564.4949341	0.62
579.5132446	2.14
645.3886108	0.29
658.7390137	0.22
694.6388550	0.19
711.7113647	0.15
739.3631592	0.18
743.6400757	0.39
757.5323486	0.10
781.7791138	0.12
799.4985962	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	589.2146
Annotation	Dracunculifoside Q
Peak:m/z	Relative Intensity
211.1041565	0.10
238.0983276	0.04
263.1701355	0.25
281.1713867	0.09
289.3770142	0.44
299.2944946	0.05
306.2252808	0.05
339.0368652	0.07
352.2183838	0.22
353.3644409	0.07
367.2486572	0.13
371.0529175	0.11
377.0754395	0.04
381.2404175	0.49
385.3356323	0.25
389.4779663	0.37
391.2694092	0.04
402.1193237	0.24
418.9785767	0.04
422.9694214	0.29
429.1231689	0.11
436.9385376	0.35
442.3236084	0.26
443.2411499	0.08
460.8549194	0.28
487.2933350	0.27
524.6809692	0.11
527.1894531	0.07
539.0208740	0.27
543.3104248	100.00
543.9350586	0.60
544.7824097	0.26
545.3972778	0.13
552.9526367	0.13
554.4314575	0.15
556.1211548	0.08
558.3575439	0.10
570.0711060	0.53
571.3664551	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	562.2839
Annotation	Agnucastoside B
Peak:m/z	Relative Intensity
200.9975128	0.30
240.1182861	0.06
249.2214508	0.08
270.9870605	0.05
274.9912109	0.22
308.5103149	0.11
317.5851440	0.18
319.0922852	0.10
337.1043091	0.19
338.1908569	0.03
347.5604858	0.42
350.1400757	0.05
353.9406738	0.07
355.3082886	0.03
357.6232910	0.24
358.3941040	0.07
364.6248779	0.85
365.2458496	3.22
371.1445312	0.03
377.2599487	0.11
378.3652954	0.45
381.2180786	0.03
383.1018677	58.40
383.7613525	0.23
399.6433105	0.57
400.2946167	0.71
401.1626587	0.80
402.0967407	0.13
407.8841553	0.04
412.9299316	0.04
417.2376099	0.27
434.1852417	0.03
436.8150024	0.31
449.7667847	0.57
452.3421631	0.04
460.3094482	0.07
461.4124146	0.03
463.6461792	0.08
472.1711426	0.20
472.8958130	0.51
474.1154785	0.26
480.9998779	1.28
482.1180420	0.31
489.1292114	0.15
498.0759277	0.05
508.7609253	0.33
509.5676880	0.09
512.2390137	0.49
517.2048950	0.04
518.2888794	0.97
519.4081421	0.03
526.3851929	0.41
527.2454224	1.02
527.8548584	0.08
529.8616333	0.13
531.1217651	0.47
534.0274048	0.03
537.5729370	0.03
538.9048462	0.05
539.8322144	0.26
544.8897095	100.00
545.8616333	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	557.2241
Annotation	Abelioside A
Peak:m/z	Relative Intensity
161.1213684	0.14
179.1016693	0.22
315.0192871	0.04
323.8403320	0.16
331.2756958	0.29
333.5515747	0.05
348.7889404	0.75
349.3919678	3.23
351.5170898	0.03
353.2377319	0.08
359.1237793	1.03
363.1970825	0.10
387.3292847	0.04
391.3109741	0.06
393.9338379	0.06
395.1592407	0.09
401.2163696	0.13
409.3724976	0.05
411.5253906	0.22
413.5968018	0.04
418.8680420	0.20
428.3704834	0.10
461.0904541	0.24
462.4812012	0.04
497.4189453	0.17
509.0745239	0.15
511.3552246	100.00
513.2025757	0.36
514.3158569	0.27
515.3706055	0.10
519.5539551	0.20
521.1716919	1.84
529.1946411	0.12
539.3909302	3.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	367.2108
Annotation	Sporotrichiol
Peak:m/z	Relative Intensity
105.1067123	0.26
106.7755661	0.12
109.0520172	0.58
119.0278778	0.26
120.0269775	0.02
120.8325958	0.18
123.2260590	0.02
131.0732422	0.06
133.1020660	1.73
135.0335388	0.05
136.2614746	0.02
137.0740051	0.29
139.0828552	0.21
145.0753326	0.10
147.0450745	0.19
149.1455231	0.20
151.0221405	0.19
152.9706116	0.22
154.7959595	0.05
157.3021851	0.07
159.2528992	0.18
160.9167786	0.04
165.0157471	0.38
166.8836823	0.31
169.1162415	0.09
175.0269318	0.21
177.0788422	0.43
179.2077637	0.04
180.1873474	0.06
181.2372589	0.04
183.2341766	0.04
187.2736206	0.06
189.2510986	0.09
191.3183594	0.13
193.0308838	0.04
195.0193787	2.95
197.3471985	0.08
199.2103577	0.59
201.1673584	0.04
207.2401581	0.24
209.1078491	0.04
211.1705627	0.30
213.0823822	0.06
217.1856384	0.40
220.1293335	0.03
221.1989441	0.25
223.1810913	0.36
225.1269531	0.11
226.9978943	0.54
229.0368347	0.05
237.2940979	0.44
238.1974487	0.04
239.1652222	1.05
241.2793274	0.81
243.1981812	0.09
245.2561340	1.23
247.0698853	0.23
249.1860046	1.15
251.3330078	0.19
255.1949768	0.25
257.2058716	0.70
259.1701660	0.43
261.0676880	3.30
261.6965332	0.07
263.2525635	4.93
264.6357422	0.05
267.2198792	12.29
269.3261414	0.49
273.1404114	0.40
275.2311707	0.63
278.9729004	0.07
283.1312866	0.04
285.1660461	16.64
287.3025513	0.96
289.1072388	0.21
291.1887512	0.05
295.3371582	1.84
301.1939697	3.42
303.1236572	3.90
305.1968384	1.13
313.2000122	26.90
319.2536621	0.35
321.2156982	1.65
323.1148682	0.38
325.9929199	0.12
331.2423401	24.62
347.8982544	0.10
349.2208252	100.00
349.8877258	0.24
373.4266663	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	347.1479
Annotation	Dihydrokanakugiol
Peak:m/z	Relative Intensity
116.6756287	0.02
119.0692749	0.07
120.9584045	0.46
122.7702026	0.08
131.0833435	0.04
132.0758667	0.03
133.0508423	0.29
135.1882172	0.03
136.0563812	0.37
137.0670319	0.05
141.0776367	0.18
145.0239868	0.06
146.9466400	0.16
148.9839935	0.21
151.2031555	0.33
156.9985657	0.06
161.0415344	0.12
163.0640564	0.13
164.9489288	0.05
169.0255737	0.39
175.0962219	0.10
176.8552246	0.05
181.4931946	0.48
183.3317871	0.06
184.9468689	0.19
187.1374664	0.08
188.9960632	0.15
190.9221802	0.82
192.8685913	0.11
194.9843445	0.53
196.9116821	0.18
199.1945343	0.13
200.3523865	0.08
207.1585693	0.38
209.1322937	1.17
210.9371490	0.14
212.8251343	0.06
215.2171021	0.08
217.1737976	0.11
220.6988831	0.16
223.0624084	0.28
225.1263123	0.27
230.3784180	0.06
231.1061707	0.04
233.2121887	0.50
239.2792664	0.45
241.1951904	0.36
244.8056030	0.07
246.9703064	0.51
251.1710205	0.32
255.2807312	0.29
257.2609863	0.39
258.0061646	0.09
259.0960083	0.10
260.4216309	0.09
261.2201233	0.34
263.0081177	0.08
267.0603333	0.77
267.9461975	0.49
269.1343689	0.84
271.1404419	0.07
271.8767700	0.03
273.1377563	0.06
275.1155701	0.06
277.4377136	0.22
283.1541748	0.18
285.0716553	2.64
286.1481628	0.22
287.2609863	0.51
288.4452515	0.04
289.3206787	0.28
295.1541138	2.64
299.8753662	0.09
301.1283569	0.19
303.0474243	17.27
303.6707764	0.06
305.2836914	0.33
306.2001953	0.04
311.1408081	0.19
313.1713562	21.19
313.8423462	0.43
315.1159058	0.18
317.3620605	0.11
319.2133484	0.10
320.5061646	0.03
321.2605286	0.28
328.0814819	0.59
329.2282410	0.17
331.0109253	100.00
331.7147827	0.50
332.3186035	0.16
334.6624146	0.25
339.9180298	0.47
340.8497925	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.114
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
128.9483185	0.13
134.9528046	0.07
137.0910645	0.03
146.8952484	0.14
164.0777283	1.02
164.6851807	0.03
174.1438904	0.48
175.1034241	0.04
179.1239166	0.74
191.0409088	4.99
193.1966705	0.08
197.1439972	0.37
208.1236877	2.68
209.1347046	0.43
223.0338593	100.00
224.0875244	0.05
239.2477417	0.21
252.8427124	0.40
265.1031799	1.12
266.9768066	0.25
279.1408081	0.43
286.0856934	0.21
288.9247131	0.05
293.4747314	0.04
295.2024536	1.73
313.0653381	0.08
323.3759155	0.13
325.2038879	0.94
339.6119080	0.06
340.5832520	0.06
341.4701538	0.03
367.1032410	1.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	545.2604
Annotation	Canavalioside
Peak:m/z	Relative Intensity
164.3166351	0.27
179.0134430	1.56
243.3470306	0.24
245.1524353	0.47
247.3112488	1.22
257.1540527	0.16
259.1941528	2.27
267.3239746	0.16
273.2081604	0.11
275.1563721	1.64
285.4221802	0.57
289.1858521	1.74
293.0810242	0.15
299.0675049	0.30
301.3372803	0.19
303.2572021	1.19
319.4031372	2.68
321.2947998	18.59
322.3577271	0.34
329.3137207	0.80
335.4245605	0.09
339.2294312	34.63
340.3100586	1.80
345.2462158	2.32
347.2365723	59.39
348.4616699	1.40
365.2526245	49.14
366.4772949	1.02
425.3519897	0.36
437.4589233	0.43
455.3031006	0.62
480.7935181	0.07
483.4124146	0.76
501.3917236	77.90
502.3970337	2.99
509.1906128	2.18
515.4994507	0.12
527.3352661	100.00
528.4152222	4.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1019.412
Annotation	Unknow
Peak:m/z	Relative Intensity
285.2323914	0.07
311.2774353	0.17
329.1777344	2.62
331.3859253	0.22
347.3394470	0.17
349.0884399	0.11
363.1624146	0.07
389.5742493	0.06
403.5209045	0.31
415.6393433	0.08
421.5823364	0.04
465.2473755	2.87
493.3373718	0.05
509.2473450	100.00
509.8492126	0.33
553.7003174	0.31
566.2676392	0.25
616.3215332	0.06
629.5056152	0.05
633.3970947	0.07
695.7941284	0.12
842.1359863	0.08
857.9555664	0.09
884.2648926	0.06
970.7327881	0.18
971.4964600	0.16
973.5598145	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	573.2553
Annotation	Canavalioside
Peak:m/z	Relative Intensity
179.0796509	0.03
301.3920898	0.05
365.3352051	0.66
391.4329224	0.02
407.3578491	0.02
411.5377197	0.01
497.3478394	0.06
527.2968140	100.00
527.9234619	0.23
555.4807739	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	464.8
Annotation	Unknow
Peak:m/z	Relative Intensity
168.3557129	0.06
211.0928040	0.02
212.8017883	1.84
284.1158752	0.28
290.0336609	0.13
296.6851807	28.00
308.8424683	0.06
334.2546387	0.11
345.0303345	0.03
378.1874084	4.56
380.5213928	100.00
381.4272156	0.17
418.2939758	0.05
447.2091675	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.2137
Annotation	Abelioside A
Peak:m/z	Relative Intensity
169.8803558	0.08
201.0816956	0.01
213.2468872	0.06
215.2692413	0.23
243.2431488	0.05
253.3242798	0.02
254.7687988	0.06
271.0697327	0.09
285.1909790	0.03
289.2671509	0.09
298.9348755	0.03
305.0219727	0.02
313.3045044	0.06
315.2642212	0.22
329.1947021	0.56
333.0546875	0.53
333.6860962	0.02
343.3042603	0.03
354.4453735	0.04
359.2448120	5.32
360.0945435	0.05
365.1849365	0.04
373.2293091	0.39
375.2923584	0.58
377.3706055	0.74
387.2848511	0.03
395.3468018	0.04
401.2855225	0.24
419.1249390	0.23
425.0698242	0.03
430.1401367	0.03
448.4177246	0.10
451.3455811	0.35
460.4775391	0.04
463.5866089	0.22
466.6032715	0.07
477.4010010	0.02
479.2909546	0.16
493.4309082	0.45
495.1248779	0.71
496.1197510	0.18
503.2529907	0.04
509.5664062	0.03
521.3471680	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	740.2039
Annotation	Unknow
Peak:m/z	Relative Intensity
210.6597595	0.20
231.1321411	0.03
243.0892639	0.03
249.1498718	3.63
254.2378540	0.22
256.9806519	0.19
267.1438904	5.91
283.1863708	0.11
289.1806641	0.05
314.2908325	0.07
323.1818237	0.03
325.4384766	0.07
327.2591248	0.15
328.2792358	0.16
352.1970825	8.24
359.3123169	0.05
369.1706543	0.30
385.8546143	0.08
387.1864624	100.00
389.2785645	0.08
395.3309326	0.14
407.0850830	0.06
407.9678955	0.05
415.0883789	0.07
441.3433838	0.08
450.8294678	0.06
452.0195923	0.03
457.7621460	0.11
463.5584717	0.04
467.2057495	0.12
496.3074951	0.06
497.6384888	0.19
537.4052124	0.08
538.3922729	0.03
568.4748535	0.11
569.1187744	0.13
570.2881470	0.26
572.1939697	0.23
577.5071411	0.14
579.6262817	0.14
583.5054932	0.20
594.4176636	0.14
608.1422729	0.02
614.5863037	0.07
618.1866455	0.20
655.9187622	0.07
665.4336548	0.03
696.0435181	0.36
696.6439819	0.62
704.5474243	0.04
708.5884399	0.08
718.1354980	0.27
721.4240723	1.13
722.2427368	0.20
723.2805176	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	361.1293
Annotation	Trichogoniolide
Peak:m/z	Relative Intensity
112.8550568	0.10
129.1062927	0.03
134.9851379	0.10
161.3672180	0.05
165.0906067	0.03
173.3379211	0.03
176.9961090	0.10
181.0606537	0.05
184.1054840	0.19
187.8558655	0.04
191.1568756	0.09
199.0499725	0.85
211.3056030	0.12
215.2300110	0.17
225.1270142	0.06
229.1212158	0.21
235.2770081	0.10
237.2588806	0.26
240.1378174	0.21
255.1053162	71.14
267.5473633	0.10
273.1430664	100.00
287.4164734	0.13
293.2084045	0.04
299.1399536	20.59
301.1660767	0.06
315.2463379	0.07
317.1617432	12.51
325.0486145	0.04
343.1598206	0.24
344.1932068	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	694.4931
Annotation	Unknow
Peak:m/z	Relative Intensity
244.8979492	0.09
252.7633972	0.43
261.4136047	0.17
329.0567017	0.13
332.9916382	0.46
360.1757812	0.36
364.7500610	0.16
380.1358643	0.07
392.5684204	0.20
399.1035767	0.11
405.5365601	0.19
410.7233276	0.33
413.0357666	0.31
435.2640991	0.34
439.3666992	0.10
440.8978271	0.26
447.3602295	1.02
458.5251465	0.67
462.4224243	0.20
463.9381104	0.47
506.5341187	0.39
508.2344971	0.08
520.9793701	0.65
526.5530396	0.37
542.9877319	0.26
545.5902710	0.11
547.2858887	0.31
549.4476318	0.31
553.5835571	0.76
567.5772095	0.34
591.4294434	0.26
594.5681763	0.12
607.3140869	6.02
609.2600098	0.19
610.5162354	0.19
611.4855347	0.06
618.5701904	0.29
623.1804810	0.49
624.4675903	0.25
627.4440308	0.77
638.2982788	0.34
640.0054321	0.30
645.0061035	0.76
645.7052612	1.58
647.4234619	0.24
663.3609009	100.00
664.0070190	0.23
676.8741455	0.40
695.3847046	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	613.16
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
179.1533051	0.18
183.9482727	0.04
199.2252655	0.04
208.3547668	0.09
208.9772339	0.59
210.9721069	0.63
225.3096771	0.03
231.0322571	0.26
235.1174469	0.46
243.3650513	0.05
256.2222595	0.12
257.0189514	0.10
274.0763245	0.06
288.1609497	0.47
291.5033569	0.15
297.8912354	0.14
306.0764465	0.05
308.0847168	0.09
317.3554993	0.04
322.3654480	0.08
330.0936279	0.08
337.1049194	0.33
349.7271118	0.06
355.1200562	83.76
355.7857056	0.06
361.1662598	0.02
381.3202515	0.02
391.1372070	0.37
393.3488159	0.10
407.1375122	0.24
409.2139893	4.93
418.8864136	0.08
419.5973511	0.03
421.1060181	0.73
433.0880737	0.12
438.1362915	0.08
438.9138794	0.16
444.0797119	0.05
450.1030884	0.03
450.9792480	0.02
451.6287842	0.20
466.2556152	4.92
467.3748169	0.06
477.4372559	0.12
481.0173950	0.01
484.1494141	100.00
484.7760620	0.68
487.0747681	0.04
499.4224243	0.04
509.0079956	0.06
520.2023926	0.29
538.2327271	3.65
553.9360352	0.04
577.0848999	0.13
595.1749878	21.04
596.1823120	0.24
597.3339233	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	464.8
Annotation	Unknow
Peak:m/z	Relative Intensity
212.9425354	2.01
291.0827332	0.19
296.7689209	28.71
301.0658875	0.21
309.1604004	0.70
378.1436768	0.43
379.3543396	1.17
380.6006165	100.00
381.3387756	0.20
447.1773987	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.1713
Annotation	Rhododendroketoside
Peak:m/z	Relative Intensity
130.9423676	1.89
133.2848206	0.80
143.0532684	3.83
147.1663666	0.34
148.3077698	0.32
148.9452515	1.61
161.0664673	4.82
163.2797699	0.72
167.0517578	0.46
169.1147614	0.39
171.1661072	7.25
174.1487427	1.13
178.9369202	5.30
186.8054810	0.54
189.1330109	26.26
190.9582825	1.03
207.4368591	0.43
215.1540833	9.47
225.2685242	0.59
233.0977783	18.26
251.1690063	1.24
277.1672974	100.00
295.3900757	1.21
301.3793335	0.37
311.0559692	0.69
337.1069946	0.15
379.3308411	0.78
395.1528015	1.26
411.0024109	0.50
413.2288208	15.68
414.4037170	0.49
439.0997925	3.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.1241
Annotation	Ethyl (S)-3-hydroxybutyrate glucoside
Peak:m/z	Relative Intensity
85.0096054	1.48
87.0183334	0.15
88.9436874	1.68
94.7744904	0.06
100.9470215	5.56
104.9426422	0.16
113.0117645	5.70
115.0349731	0.73
118.9697418	4.19
125.0983276	0.08
127.3724060	1.16
128.0783539	8.51
129.0251617	0.47
130.9907837	100.00
139.0007477	0.17
143.0615845	2.62
144.9334564	0.49
147.0000305	0.14
149.0046234	0.44
154.8713226	0.08
158.9723663	0.31
160.8166504	1.37
164.2176819	0.18
165.0342407	0.07
172.9922028	5.81
177.1413269	0.06
178.8418884	1.57
181.0957031	0.07
185.1334686	0.40
199.1807556	0.06
202.9896851	0.83
205.4299927	0.03
215.0240784	0.18
216.7580872	0.04
227.1140442	0.20
233.2582703	0.24
234.9112549	0.04
236.9594116	0.15
247.0996399	0.29
249.2658386	0.44
257.1139526	1.15
275.2110291	8.36
278.0205688	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	297.119
Annotation	2,3-Butanediol glucoside
Peak:m/z	Relative Intensity
101.0102386	0.04
113.1301422	0.06
119.1004944	0.04
120.9560165	0.07
137.1055756	0.02
142.9358826	0.21
144.1482544	0.16
159.1094360	0.02
160.9780273	0.36
187.2842255	0.11
193.0113220	0.15
199.0104980	0.15
204.9319763	0.14
206.9626770	0.16
209.3072815	0.03
210.4945679	0.07
211.1314697	0.03
213.1234131	0.06
217.9662476	0.27
225.2620544	0.12
237.2940369	0.04
251.0747070	100.00
252.4332275	0.20
253.3034058	0.14
279.0737305	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	368.135
Annotation	Niazicinin A
Peak:m/z	Relative Intensity
110.9056702	0.06
112.9713440	1.01
116.8761978	0.09
118.9469147	100.00
125.0371704	0.07
130.0644836	0.11
131.0543823	0.13
142.9753113	1.39
155.9241028	0.09
158.0985107	0.33
158.9913025	0.54
161.0137939	2.48
179.0854797	1.77
188.0882263	2.05
204.0617218	0.07
206.1041870	1.28
221.9745789	0.44
248.1272278	20.91
248.8849487	0.14
280.0249023	0.49
288.4320068	0.15
300.3626099	0.27
306.1184082	0.18
323.4071655	0.09
324.0371094	0.12
326.1732788	0.22
332.4081726	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	315.1582
Annotation	(+)-7-(3-Methylbut-2-enyloxy)-8-(2-hydroxy-3-methylbut-3-enyl)coumarin
Peak:m/z	Relative Intensity
93.0274506	0.06
106.9034576	0.06
108.9218140	0.27
110.8691177	0.06
112.0210571	0.06
114.9415741	0.05
119.2346191	0.06
120.8327484	0.07
122.1016846	0.17
127.2653427	0.03
136.9715881	0.21
145.2117615	0.19
156.9830017	0.13
159.0757294	0.19
161.0324097	0.14
169.0815277	0.22
169.9578400	0.06
173.1806946	0.06
177.3359375	0.21
181.0262451	0.16
185.0617065	0.39
187.1615601	0.24
189.2242126	0.09
190.1047821	0.09
191.1857147	0.09
194.1226959	0.81
195.1389313	0.08
196.1234131	0.15
197.2706909	0.32
199.2069397	0.28
200.2183380	0.23
201.1398621	0.27
203.2421570	0.16
204.7131653	0.04
206.9558411	0.10
209.3114624	0.50
211.3213806	0.38
212.2966309	0.08
213.2184143	0.02
214.0964966	0.09
215.1959839	0.05
216.0244751	0.13
217.1382751	0.25
218.0046692	0.23
219.2307434	0.23
221.0809937	0.05
223.1825562	0.52
225.1219788	0.33
226.1114502	3.49
227.0332642	2.02
228.4376221	0.40
229.2041321	0.52
231.1610413	0.11
233.0629883	0.23
238.3345642	0.16
241.1945801	2.85
242.2722168	0.07
243.2158508	1.14
244.2062378	0.16
245.0785828	0.48
251.2480469	0.57
252.2613220	0.04
253.2868958	0.63
255.0618896	1.78
255.6773071	0.02
256.7386169	0.22
257.3465271	0.21
259.0929565	1.34
261.1904907	0.14
265.1667480	0.08
269.1854858	39.34
271.1245422	2.99
273.1673584	1.10
274.1323547	0.71
279.2070312	0.98
280.3829956	0.04
282.0607605	0.08
283.0159302	0.30
285.1967163	1.65
287.2019653	82.89
288.1494751	0.06
295.0202637	0.65
297.0687866	100.00
298.1557312	1.03
299.5339355	0.47
301.2462158	0.21
305.5292053	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	705.3335
Annotation	Unknow
Peak:m/z	Relative Intensity
207.1679993	0.03
245.2656097	0.12
288.8144531	0.09
335.3829346	0.26
356.2059326	0.03
373.4489136	0.02
377.3165283	0.01
399.2333984	0.08
415.2891846	0.01
462.5955811	0.04
491.8452759	0.03
497.3338013	100.00
498.1746216	0.02
501.4725952	0.01
525.1913452	0.07
527.5194092	0.10
539.2400513	0.59
543.0889893	0.82
557.1585083	0.07
581.2526245	0.08
589.1668091	0.02
613.3898315	0.01
621.1695557	0.05
643.8312378	0.18
644.4783325	0.04
645.7496338	0.11
659.0801392	9.23
659.7565308	0.03
660.4242554	0.11
661.4517212	0.03
668.7839966	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
91.01393127	0.57
94.95011902	0.38
99.07576752	0.57
101.1241455	0.36
105.009819	0.29
107.1246338	0.34
108.4011154	0.61
109.1221924	1.58
112.917099	0.61
115.014801	0.41
117.1602554	0.18
121.0925446	1.20
123.228241	0.29
127.1440353	0.17
128.9708557	0.09
131.1540222	0.57
132.9729919	0.71
135.0615234	1.03
136.7626801	0.27
138.8855286	0.42
139.5177917	0.22
140.9684601	0.51
143.0062866	1.30
144.9096985	0.17
145.994812	0.11
147.1615295	0.65
149.0870514	0.37
150.7277374	0.47
152.9856262	1.75
155.0105896	1.23
157.015625	0.87
158.9741516	0.39
161.2078857	1.14
163.047699	0.25
165.0016479	0.22
166.9107056	0.97
169.1046295	1.53
171.1397095	0.97
172.9508667	0.35
175.9060669	0.19
177.3392334	0.51
178.9246674	0.35
180.9966125	0.60
182.973053	0.92
185.0177612	0.20
186.0065308	0.36
186.897995	0.71
191.2594452	1.95
193.2457275	1.01
194.9444275	2.00
197.0671387	1.29
199.071991	0.30
203.2671204	0.09
209.2117615	1.68
211.1587219	1.24
213.1240845	1.40
213.9819641	0.26
215.013031	0.60
217.0741272	0.17
223.1785583	2.15
225.0121155	0.40
227.325531	0.10
229.0670776	1.37
231.9078369	0.71
233.0425415	1.41
235.20224	1.13
237.1586304	0.98
239.0956726	1.81
240.243927	0.26
241.0046692	0.51
247.2437744	2.49
251.2098999	3.64
253.130249	2.34
254.9780273	0.79
257.4141846	0.38
258.7877197	0.56
263.2294617	1.07
265.1585083	2.48
266.102417	0.21
267.1283875	1.24
269.0291748	1.62
270.1411438	1.63
275.1612549	10.42
279.2950439	0.96
283.0726318	0.90
291.4646912	0.33
293.2041321	100.00
293.8708496	0.28
311.0328979	0.14
314.7897339	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1815
Annotation	(-)-11-hydroxy-9,10-dihydrojasmonic acid 11-beta-D-glucoside
Peak:m/z	Relative Intensity
112.9898529	1.97
118.6448593	1.48
125.0614624	0.72
129.1693726	0.26
130.9338989	0.28
132.4947968	0.16
142.9437103	1.41
148.9056702	0.61
159.0169983	0.23
161.0235596	4.47
167.2018127	0.35
176.9658203	0.10
178.8344727	1.04
206.9602661	0.15
209.1564484	2.10
211.1367493	0.39
227.2033691	13.07
227.9213867	0.31
239.2053833	0.59
251.0939331	0.17
253.0741577	0.45
269.1155701	0.12
281.2589111	1.80
289.1240845	0.67
293.5294495	0.84
311.2343750	4.63
329.3132324	5.12
345.3609009	0.96
371.2229309	100.00
371.8469849	3.33
372.4529114	1.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	541.229
Annotation	3-[4-[1-(4-Hydroxy-3-methoxyphenyl)-1,3-dihydroxyisopropoxy]-2-hydroxyphenyl]propyl alpha-L-rhamnopyranoside
Peak:m/z	Relative Intensity
159.1223755	0.42
160.8153687	0.31
178.9938965	0.39
183.2355957	0.13
196.8778839	0.16
199.1142273	0.08
202.2921906	0.15
205.2099609	0.10
215.3091278	0.06
217.3021851	0.19
220.1596832	0.27
221.1472931	0.59
229.2290192	0.95
232.1752167	0.14
237.2553558	0.36
241.1925354	0.28
243.0513763	0.18
245.1800079	0.44
247.1987915	0.88
255.1600037	1.50
255.9524689	0.39
257.2548828	0.40
263.4315186	0.25
271.3616943	0.54
273.3417664	4.51
274.0776367	0.35
281.5642090	0.46
288.3387451	0.13
289.1932678	3.09
290.2547302	0.53
291.2294922	3.67
292.3496704	1.22
299.2003784	1.68
300.4757080	0.18
301.2631226	2.02
307.3210449	6.76
308.3317871	0.79
315.1024780	1.17
317.2304077	29.88
318.2730103	4.51
327.0723877	0.68
331.4594727	0.40
335.2898560	57.05
336.2656860	4.83
343.2674561	9.56
344.1436768	1.07
345.2421265	0.28
346.4293823	0.31
349.2379761	0.35
361.2570190	22.64
362.4095459	1.31
363.3392944	0.20
378.1014404	0.19
379.2120361	7.65
380.9527588	0.41
397.0051880	0.21
407.3571777	0.60
432.0982666	0.08
451.4478760	0.35
452.5065918	0.07
469.3156128	2.90
479.2462158	1.89
481.4660034	0.06
495.3176270	2.82
497.3184814	100.00
498.2675171	14.61
498.9763794	0.27
505.5553589	0.15
513.4687500	0.93
519.0178833	0.08
523.2646484	29.56
524.2962646	4.22
524.9380493	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.1398
Annotation	Trichogoniolide
Peak:m/z	Relative Intensity
157.2227783	0.02
211.2269897	0.01
217.0846863	0.22
231.0146484	0.01
245.0682373	0.01
247.1838074	0.07
271.0171814	0.01
273.0839844	0.11
275.2247009	0.17
281.1782227	0.10
291.3816833	0.27
293.0429688	0.05
294.0618286	0.03
299.4487305	0.02
301.0202942	0.03
305.3740845	0.09
315.3254700	0.03
317.2181396	0.35
319.1296082	100.00
319.7592773	0.12
331.1461182	0.02
333.2636719	0.04
335.2117615	0.59
341.9896240	0.02
343.3803406	0.03
344.4165039	0.04
349.4281006	0.08
361.2378540	0.63
362.0512390	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	616.2944
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0570831	0.25
181.1667175	0.45
182.9421692	2.58
185.2390442	0.21
190.8716583	0.13
193.1229706	0.92
195.0756378	1.03
196.1434021	0.65
197.1730652	1.41
199.2401733	0.34
201.2407227	0.30
210.9703217	1.19
213.3093109	0.32
214.8339233	0.10
219.1769104	0.21
221.1571045	0.95
224.0443268	0.97
225.2005920	0.71
227.3652344	0.24
229.2906189	1.05
233.2940369	0.59
236.3953094	0.76
237.1756744	0.32
239.1669922	5.68
241.2624512	0.64
243.2581787	0.49
247.3865509	0.89
249.2387238	1.23
251.4756470	3.46
252.2347260	16.68
253.2123871	0.11
254.0481415	0.13
255.3763580	0.10
257.1807251	14.40
267.1735229	9.98
268.1000366	0.63
269.1607361	10.25
271.1381226	0.74
273.2608643	0.25
275.2662659	8.40
277.3745728	0.14
282.9666748	0.13
285.2144165	28.52
287.3441772	1.30
295.1934509	2.69
297.3600159	1.12
303.1375732	4.37
313.1685486	20.45
315.2277527	1.77
321.0905762	0.35
327.0933838	0.91
329.9981689	0.45
331.2001953	39.03
333.2696533	0.14
343.4064941	0.30
345.3358154	0.10
349.2661743	0.85
354.6557007	0.29
372.2679443	3.07
377.3994141	0.15
382.3532104	5.71
387.5384521	0.24
390.4628906	0.20
400.3129272	8.24
401.1830444	1.12
402.4927368	0.26
405.0829468	0.84
418.2528687	27.05
419.0372314	2.66
420.3610840	0.14
422.9219971	0.32
426.2760620	0.83
436.3632202	41.23
438.0722046	0.10
440.3915405	1.30
447.5363770	0.47
448.2579346	0.42
451.9681396	0.34
454.3371582	6.18
457.1561890	0.29
470.2374878	0.18
475.1657104	0.34
482.4821167	0.12
493.1154175	1.85
527.3692017	0.44
532.3909912	0.53
539.3982544	0.18
543.8024292	0.47
550.3643188	0.20
562.3471069	1.30
570.2225952	0.36
580.2399902	5.09
588.5254517	0.10
598.4259033	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
93.07054901	0.13
95.11904907	0.87
98.998703	0.18
100.8708572	0.11
107.1339111	0.15
109.063797	0.06
111.0501251	0.26
112.9785767	0.29
116.9910431	0.21
119.0798492	0.39
121.4100494	0.10
122.8633041	1.43
124.9861908	0.32
126.8930359	0.46
131.079895	0.18
132.9495544	0.37
135.0118256	0.67
137.0518188	0.88
138.3787231	0.37
139.0606995	1.36
141.0440063	0.81
143.1018982	1.71
147.1351166	0.13
148.0190887	0.39
149.1419067	0.32
151.043457	0.48
152.6788635	0.56
155.0853271	3.00
156.0419312	0.10
157.122467	0.39
158.9351196	0.57
160.4226074	0.13
161.1107025	0.36
162.9124451	0.94
165.1544189	0.65
166.0067291	0.04
167.0625	0.63
168.9914093	1.34
170.0397339	0.21
170.9237671	0.27
173.1163483	0.54
175.0596161	0.96
177.1169891	1.12
179.1329498	0.12
181.0290833	1.78
183.0742188	1.50
187.1378784	0.64
189.0832672	0.66
191.2021332	1.16
193.0131683	0.58
195.03125	2.68
196.5285645	0.51
197.1456299	2.45
197.9298248	0.15
199.0713654	0.93
201.068161	0.54
205.4243774	0.22
207.244812	0.09
209.1367798	1.19
211.1971741	3.16
213.1647339	0.74
214.9274597	0.87
217.0568542	1.02
219.3918152	0.21
221.0214233	0.20
223.3049927	0.42
225.2257385	0.94
227.2040405	0.88
228.1556091	0.39
229.2829895	1.18
231.9107971	0.35
233.2363892	1.53
235.1838074	0.92
237.1894531	2.01
239.0162354	1.19
241.3033447	0.30
245.1357117	0.07
247.3361816	2.72
248.943573	0.59
251.1509399	1.15
252.4558716	1.53
253.1827698	4.83
255.1408997	0.72
256.1893311	0.20
257.2456055	0.49
265.1027527	0.76
266.3850098	0.17
267.0090942	0.89
269.190918	0.62
270.0942383	0.13
275.2076111	17.13
281.1507263	0.47
283.1765442	0.86
287.3948364	0.18
293.2136536	100.00
294.2237854	0.49
297.3255615	0.10
302.3022461	0.23
312.2248535	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	220.1174
Annotation	Pantothenic acid
Peak:m/z	Relative Intensity
71.8864746	3.26
86.9196014	0.08
89.9473724	43.67
95.2947846	0.02
97.8819427	0.72
100.0918884	0.04
113.1127777	0.35
115.9173279	6.09
123.9966125	0.26
131.0953369	0.18
142.0777283	0.35
156.1252289	0.55
156.9329987	0.04
158.4205780	0.03
159.8966980	0.12
166.1425934	0.96
172.1024017	0.11
174.0787964	4.33
179.1046295	0.05
183.9912567	24.97
184.6083221	0.13
193.0992126	0.03
202.0545044	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	381.1553
Annotation	7alpha,8alpha-Dihydroxycalonectrin
Peak:m/z	Relative Intensity
113.0411377	0.11
115.2484818	0.04
126.9445114	0.04
130.2025299	0.06
145.0614319	0.28
169.4004822	0.28
171.2668152	0.21
172.9837036	0.09
179.1416779	0.10
181.0505981	0.08
184.2463684	0.15
187.1519623	0.18
189.2068481	0.10
191.2039642	0.25
201.1442566	2.05
206.4475708	0.11
209.1732483	0.15
214.2596436	0.17
215.1544495	1.09
216.8744659	0.39
219.1999512	0.51
221.1098328	1.42
222.4566650	0.07
224.9420471	0.47
225.9686890	0.12
227.2162781	1.02
229.3605347	0.34
233.2298584	0.09
235.2012939	2.12
239.2179565	1.03
243.1064758	0.08
245.1318665	3.64
247.2987061	0.72
255.2171631	0.26
257.2972412	4.53
258.0672913	0.38
262.8508606	0.17
265.4046326	0.26
271.2090454	0.03
273.1916504	5.22
274.0979309	0.43
275.2259827	100.00
276.2435913	0.21
283.3788452	0.31
289.0899048	0.25
290.6183167	0.17
291.3365784	0.07
293.2399902	12.81
299.2737427	0.07
301.3411255	1.43
317.2787170	0.30
318.1251831	0.05
319.2687988	9.03
320.2880249	0.22
321.2965088	0.42
323.2164307	0.07
326.9839783	0.11
335.1080627	1.18
335.7576904	0.03
337.2867432	24.31
338.0873718	0.62
339.1708374	0.06
345.4148560	0.06
360.9285583	0.06
363.1615906	8.95
364.5430603	0.10
382.3005676	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	474.1715
Annotation	Folinic acid
Peak:m/z	Relative Intensity
147.3523560	0.02
166.0351562	0.14
170.9485474	0.09
178.3559570	0.02
190.2294312	0.03
194.2903900	0.04
219.3986053	0.01
228.1422272	0.10
244.3266296	0.03
246.4089661	0.02
259.2991943	0.01
274.3701172	0.05
291.2232666	0.02
301.0657654	0.32
312.2539673	0.03
315.2031555	0.01
316.7665710	0.05
323.2850952	0.03
327.1466064	100.00
328.2177429	0.15
338.1772461	0.05
345.1293945	20.53
353.3201294	0.03
362.0938110	0.01
362.7933960	0.01
382.9289551	0.03
412.4124756	0.21
428.0414429	1.20
429.0853882	0.13
430.3298340	1.04
432.3801575	0.02
434.4932556	0.06
435.8630676	0.06
438.2879944	0.09
456.1367188	16.64
456.9774170	0.06
465.7406311	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.1978
Annotation	Abelioside A
Peak:m/z	Relative Intensity
159.0384216	0.06
161.1132507	0.07
166.9286499	0.10
173.2089233	0.04
179.0499573	0.13
181.1672516	0.03
201.1042786	0.02
207.2588196	0.18
210.3881683	0.06
214.2570648	0.05
229.5332184	0.10
231.3098907	0.31
238.9967957	0.31
241.2523956	1.20
253.4303284	0.04
255.2978821	0.07
257.2186890	1.63
265.0175781	0.31
273.1876831	0.84
275.3647461	0.74
281.4826050	0.08
283.1891479	0.63
284.1525879	0.05
285.3237305	0.06
291.4093018	0.04
301.1828003	6.97
303.2476196	0.70
307.1765137	0.11
314.9230957	0.07
316.4312744	0.03
317.1655884	0.85
319.2481079	2.09
320.4562988	0.05
327.1642456	0.05
328.9904175	0.06
343.3389893	0.14
345.2288818	6.25
347.4036255	0.34
361.1271973	0.08
363.2983398	100.00
375.4317627	0.13
377.2304077	0.09
405.2731934	23.16
417.1345215	0.29
433.3496094	0.09
435.1490479	2.08
435.7579346	0.01
437.5645142	0.18
439.0299683	0.14
445.2875977	0.11
451.3160400	0.05
453.2653809	0.04
462.7376709	0.26
463.4559937	1.22
465.3267822	12.81
477.2283936	0.09
479.3689575	0.49
481.2864380	32.94
482.3592529	2.82
507.1679077	3.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	257.1547
Annotation	1,9Z,16-heptadecatrien-4,6-diyn-3,8-diol
Peak:m/z	Relative Intensity
76.9680939	0.03
83.8386002	0.16
85.1226578	0.04
92.9689026	0.38
94.7660065	0.50
115.0877075	0.16
129.3198547	0.14
131.0831604	2.35
132.0733795	0.15
133.1900482	0.21
136.2713928	0.05
137.0913391	0.06
139.2992249	0.26
141.1047516	0.51
145.0390015	0.11
147.2205048	0.05
149.1803131	0.33
151.2392120	0.14
157.2072144	0.38
158.1031952	0.05
159.1060333	0.18
160.9561310	1.42
162.0999298	0.31
163.3276978	0.31
166.9164886	0.06
169.0621490	0.44
170.0436707	0.43
171.0496826	3.20
172.0031433	0.18
173.1358795	0.52
174.2218475	0.09
175.3116608	0.10
177.0100861	0.61
179.1636200	0.20
183.3625946	0.09
184.2186432	0.07
185.0667419	2.19
186.3433990	0.23
189.0666504	7.90
193.1480560	0.14
195.1727753	0.90
195.9673462	0.37
197.2039337	0.80
198.3295441	0.43
199.1645050	1.78
200.2266083	0.82
201.1767273	1.09
209.1871643	0.03
209.9866791	0.41
211.1105042	6.86
213.1617279	3.73
214.1346283	0.62
215.8290405	2.40
216.5104218	0.04
217.3896942	0.05
221.1644745	0.27
221.8625641	0.13
223.1807556	0.33
224.1848450	15.85
225.2220459	0.31
227.2172089	3.97
229.1134796	87.72
230.0102386	0.46
237.2237701	1.87
239.1472168	100.00
240.0951385	1.55
241.1341553	0.81
242.1732178	1.63
255.2879486	0.07
257.2546997	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	303.1601
Annotation	Prosolanapyrone II
Peak:m/z	Relative Intensity
106.9527054	0.04
151.0630188	0.04
187.9802856	0.03
199.0976257	3.94
201.2610779	0.13
203.1331482	0.10
207.0644531	0.07
215.0041809	0.03
217.3431091	0.05
217.9505310	0.03
223.1042786	0.93
225.1481934	0.05
229.4265137	0.02
231.2432251	0.10
233.0821228	0.07
237.2601013	0.11
239.1677856	0.80
241.1463623	100.00
241.7536621	0.12
243.1751404	0.14
245.1430054	0.09
250.1477661	0.02
251.0856323	0.02
254.0653687	0.03
255.1923828	0.13
257.1510010	0.13
259.2473450	4.28
260.1986694	0.02
266.2416382	0.05
267.2354126	0.27
269.0052490	0.09
273.2057190	0.07
275.2115173	0.16
276.0282593	0.07
285.1830750	6.58
285.8435059	0.01
287.3036499	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	641.2923
Annotation	Unknow
Peak:m/z	Relative Intensity
227.2070618	0.07
236.0690155	0.22
237.2085266	0.19
289.2535706	0.27
361.3005981	0.08
373.3148804	0.04
378.0211792	0.05
388.4401245	0.03
391.3628540	0.48
397.2030640	0.06
399.3931274	5.03
403.0640259	0.07
404.4007568	0.06
417.2510986	56.04
418.5850830	0.07
427.2425537	0.33
434.6968384	0.82
453.2703247	0.16
458.9581909	1.46
459.6120605	0.30
475.2747803	0.08
477.0653687	1.36
479.1835327	0.24
488.2900391	0.15
489.4099731	0.29
508.3395386	1.34
520.3644409	0.06
524.7129517	0.07
526.4086304	2.63
527.3938599	0.18
531.3566284	0.23
535.6591797	0.08
548.8844604	0.23
551.4062500	0.34
554.4821777	1.71
559.8701782	0.06
562.4324341	0.23
563.2636108	0.04
567.6254883	0.20
569.1908569	0.30
577.0521240	0.24
579.3082886	100.00
579.9356079	0.44
591.2055054	0.15
595.3376465	0.68
597.2603760	29.57
597.9355469	0.24
605.2984009	0.76
606.3778687	1.40
617.6127319	0.48
621.6034546	0.13
623.2961426	5.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	796.61
Annotation	Unknow
Peak:m/z	Relative Intensity
290.7394409	3.34
292.1295776	0.27
292.8826294	2.83
374.6687012	0.73
376.6936035	0.38
437.1774902	0.05
458.5093994	8.67
460.0422363	0.84
460.6823730	12.46
461.6934204	0.18
541.9446411	2.60
542.6843262	38.52
544.5022583	89.11
545.2100830	0.39
564.8320923	0.16
569.3661499	0.22
583.5679932	0.36
588.5542603	0.28
592.1177368	0.09
604.6666870	0.06
616.2575684	0.07
625.8010864	1.62
626.4889526	12.08
628.3556519	52.81
629.0905151	0.14
630.5159302	0.17
659.4689941	0.26
677.6217651	0.13
690.1373291	0.41
690.7670898	0.27
710.2799683	10.68
712.2202759	100.00
713.0599976	0.45
737.3160400	0.42
749.9403076	0.72
750.6909180	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	333.06
Annotation	alpha-D-Galactosyl-(1,1')-sn-glycerol 3-phosphate
Peak:m/z	Relative Intensity
96.9813538	0.66
150.8097229	1.01
152.9357605	100.00
154.0359497	0.07
170.9936829	2.90
223.2722168	0.26
241.0903320	89.77
259.1278687	1.08
276.9204407	0.28
314.9788208	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	262.0569
Annotation	Ascorbalamic acid
Peak:m/z	Relative Intensity
77.7947388	0.06
84.8474426	0.12
95.9253082	20.42
97.9842300	0.38
108.0129700	0.35
110.0882721	0.09
111.1154633	0.16
116.1456909	0.14
119.1321869	0.16
126.1738434	0.47
127.9537354	8.95
128.8729706	1.30
132.2713470	0.04
134.7644653	0.06
138.0778809	3.19
139.1359100	0.15
140.0848541	1.15
141.9548950	45.57
145.1205444	0.11
146.0686188	0.19
147.1292877	0.10
156.0520172	2.91
158.0587006	94.67
159.1072693	0.49
165.0843201	0.05
170.0122528	0.45
172.0036774	5.37
173.8919830	0.73
175.0473328	0.22
182.1040192	0.51
183.1119995	0.08
184.0509491	0.12
186.8623962	0.05
187.9573517	2.83
200.0697784	13.10
202.0190277	100.00
214.1035919	0.39
217.9259186	22.49
219.0012054	9.36
226.0769348	0.17
232.0575562	0.46
243.9356689	8.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	257.07
Annotation	Posoquenin
Peak:m/z	Relative Intensity
131.1268158	0.24
154.0695953	0.17
173.1231689	100.00
210.9240875	0.04
212.6695709	0.17
215.3138275	0.06
226.5983734	0.06
239.2205963	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	298.1
Annotation	5'-Methylthioadenosine
Peak:m/z	Relative Intensity
96.9034195	0.83
102.9109650	0.01
114.7847748	0.05
119.0963440	0.01
133.0742188	0.02
135.9613495	100.00
144.9226685	1.84
151.9739380	0.02
153.2667542	0.02
162.8912964	5.66
165.0986938	0.04
174.8358002	0.04
178.0978088	0.03
182.0653992	0.29
192.2550049	0.06
193.1784821	0.06
199.2562561	0.04
204.2333984	0.04
208.0748291	0.06
208.9042358	0.11
210.0307617	0.03
210.6340942	0.02
211.2596436	0.01
216.0494080	0.01
219.9577637	0.04
226.6554871	0.02
227.2969971	0.04
228.0121765	0.01
229.2471008	0.04
231.3779907	0.05
232.0859375	0.03
233.9352417	0.02
237.1071167	0.01
238.1458740	0.55
239.4692688	0.04
244.0746460	0.06
252.0468445	4.25
253.0629578	0.09
254.2067261	0.11
256.8527222	0.36
260.2198486	0.02
262.0951233	0.16
262.8439636	0.17
269.0649414	0.06
277.5912170	0.07
279.4120483	0.16
280.0660706	3.45
281.6417847	0.28
286.9973755	0.06
288.8268433	0.35
290.0440979	0.01
308.4367981	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	371.1436
Annotation	Sambucus nigra Degraded cyanogenic glycosides (2'-Epimer)
Peak:m/z	Relative Intensity
106.8116837	0.37
108.0258942	0.07
109.0757217	0.11
114.9355011	0.29
118.9737549	0.44
120.2761765	0.37
120.9546204	2.12
129.0557556	0.06
129.9380035	0.74
130.9542542	0.51
137.0692291	0.23
143.1319733	0.18
145.1035156	0.26
147.0360107	1.60
150.2182007	0.12
155.0030212	0.07
158.1174011	1.15
159.2823181	0.20
164.1533203	0.07
165.1764832	1.09
166.0652161	0.39
168.1959229	0.21
168.9999695	0.56
175.0971985	0.21
176.9615479	0.20
180.0391998	0.89
182.1764374	0.95
187.0742798	0.44
189.1664734	0.16
190.0725861	0.20
191.0626831	0.47
195.1001434	3.22
197.0878601	0.19
198.4905396	0.17
204.0716858	0.21
205.3261566	0.23
206.1518707	0.31
207.0971680	2.02
209.1882324	3.38
209.8594513	0.14
213.1087036	1.75
213.8458557	0.09
217.0186462	0.28
220.0485840	0.33
224.2514648	3.10
225.1794739	0.10
232.3158569	0.25
233.0183105	0.11
234.2199402	0.17
237.0306396	0.06
238.0227966	0.04
239.2817688	0.10
240.1067810	0.48
242.1864929	100.00
248.1442261	3.12
250.2281189	0.43
251.6329346	1.12
254.3570251	0.37
257.2326050	0.11
258.3506165	0.37
260.2231140	3.81
262.1495056	0.27
265.2699585	0.42
266.2750244	0.67
267.2105103	0.37
268.2630005	0.13
269.2354736	0.98
271.8097534	0.19
273.3497925	0.42
274.4230957	0.49
275.1837463	0.18
279.0239868	2.67
282.3178101	0.23
283.2625732	1.44
287.2270813	0.20
290.0244751	1.89
290.9629822	0.13
293.3927612	0.46
294.1893311	0.60
295.2637939	2.73
296.5632019	1.14
299.2836304	0.19
302.8933105	0.10
308.2839355	5.38
309.4612122	1.38
310.2168274	0.28
311.3758545	1.52
312.3707886	0.53
313.1787720	0.47
315.2450256	0.17
318.1433716	0.90
321.3030090	0.08
325.2784424	16.63
326.1402588	5.41
327.1925049	1.48
328.9383240	0.23
330.0955200	0.14
335.1697388	1.73
336.3250732	0.53
339.2637024	0.22
340.3760681	0.16
341.5234375	0.26
343.2685547	6.45
344.2711487	0.09
350.9454956	0.16
353.3159790	23.90
354.2111511	60.07
355.1865540	0.75
360.0684814	0.68
362.0254517	1.39
383.4076843	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	529.2654
Annotation	Tricalysioside Q
Peak:m/z	Relative Intensity
159.0620422	2.17
161.0535431	9.70
163.2502441	1.03
178.9271393	13.36
181.0807343	1.96
232.4172668	0.76
257.0346985	0.69
261.0733643	3.49
265.5042114	0.41
273.4147644	2.44
275.3789062	4.72
277.3086548	1.57
279.1021423	3.63
287.2878418	1.25
289.3720093	1.36
291.3471680	1.21
293.2455750	1.36
295.1517334	12.08
303.3546753	2.99
305.2153320	24.22
321.2533569	27.80
323.4133911	7.68
331.3041992	16.26
333.6501465	0.53
339.4393921	4.25
349.2661743	76.91
365.4025879	0.64
367.2249756	29.96
433.0396729	1.60
483.2780762	0.95
485.2665405	8.38
499.6807861	1.65
501.4417114	3.08
511.3120728	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.2136
Annotation	Glaucarubinone
Peak:m/z	Relative Intensity
158.9787445	0.12
201.0862885	0.59
216.7906189	0.12
225.1965942	0.08
227.2304077	1.19
245.2226715	1.26
253.0742645	0.56
271.1689453	1.58
289.1965332	0.13
297.0363770	0.07
315.2803955	4.71
316.9950562	0.15
319.4164429	0.18
331.1936035	0.38
333.6505127	0.25
337.0537109	0.06
359.1000366	10.34
365.2074585	0.09
373.1511841	0.05
377.2719116	100.00
378.2564087	0.78
386.9694824	0.18
389.1986694	0.19
391.0894775	0.91
401.2020874	0.26
402.9948730	0.28
405.1061401	0.09
408.1550293	0.13
410.8915405	0.33
413.5653076	0.08
419.2664185	16.99
433.3032837	0.12
444.1562500	0.41
447.2230225	0.23
449.2606201	6.61
450.2445068	0.09
453.3839111	0.03
461.3176270	0.07
468.3995972	0.07
477.5932007	0.08
479.2861938	22.38
480.7059937	0.51
493.3771362	8.58
495.1390991	0.73
496.3966675	0.05
497.7853394	0.07
503.3130493	1.10
508.6469116	0.25
509.4078979	0.42
519.5680542	0.05
521.1743164	3.92
522.0148315	0.04
524.1723633	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	468.2
Annotation	Unknow
Peak:m/z	Relative Intensity
163.1296387	0.06
171.8616638	0.15
191.1130066	0.21
210.9674988	0.40
219.1139832	0.08
224.9738464	0.12
241.9402924	0.05
243.0165558	0.47
255.2691345	0.07
264.9204712	0.19
279.1137085	0.26
283.3512268	0.30
288.1477051	0.04
291.4778748	0.21
300.7852783	0.08
305.5808411	0.55
309.3671570	0.08
311.2243958	0.30
316.8532410	0.31
329.1123962	0.29
336.8194275	0.09
347.5411377	0.35
350.2500000	0.08
352.1027832	0.51
378.7449036	0.41
379.4312439	0.05
380.0873108	0.40
386.1350708	0.15
387.9477234	0.11
409.3111877	0.47
412.4521484	0.16
414.3584290	0.27
422.2286072	0.15
425.1319275	0.41
426.2500000	0.32
426.8808289	0.17
432.1866455	7.34
433.0965881	1.63
433.6982117	0.15
450.2710876	100.00
451.5274658	0.44
454.3137207	0.07
455.2856140	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.1398
Annotation	Trichogoniolide
Peak:m/z	Relative Intensity
117.0063095	2.24
127.0776672	0.07
140.9422302	0.69
143.1229553	4.64
144.0098877	0.07
145.1450958	0.17
154.0739136	0.15
155.1186066	1.40
173.1060486	6.77
187.1933289	0.30
189.0698547	1.43
199.2462769	0.24
200.2358856	0.06
201.1430664	0.08
215.2040405	0.50
217.1535339	31.24
218.3319092	0.33
227.1767883	0.43
229.2325134	2.20
231.3014526	0.37
232.9973450	0.61
243.0809937	1.00
245.1823120	0.37
247.1855164	1.30
255.2005310	0.87
261.2025757	10.67
271.1937256	0.08
273.2109375	28.70
274.1550598	0.13
287.4213867	0.38
289.3673706	0.55
291.2880554	78.00
292.2257385	1.60
305.2081299	1.25
307.3748474	0.68
317.2586060	71.77
318.2457275	1.22
333.1755981	1.66
335.1806641	100.00
336.4022827	0.73
343.2758179	0.45
349.0845032	1.42
359.0379333	0.25
361.1117249	48.27
362.2557678	0.90
363.3485107	0.25
364.5373230	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	794.61
Annotation	Unknow
Peak:m/z	Relative Intensity
290.8226929	4.40
293.2191162	0.10
335.0800171	0.06
374.5783691	1.89
386.2905273	0.08
419.1268311	0.07
420.9570923	0.06
458.5564575	20.20
459.3306885	0.03
460.4630737	0.02
542.5882568	100.00
550.2368164	0.07
573.9373779	0.04
582.0490112	0.04
586.6192627	0.12
620.1978149	0.02
626.3528442	54.80
627.1189575	0.16
628.6602173	0.19
631.9647217	0.09
642.6699219	0.05
658.7857056	0.19
672.6488647	0.04
687.9943237	0.13
688.6156616	0.46
700.7081299	0.09
707.7490845	0.55
709.5886841	6.22
710.3096313	77.92
711.0037231	0.21
734.7852173	0.06
748.1575928	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.015
Annotation	Myricatin
Peak:m/z	Relative Intensity
171.0564117	0.09
185.1518097	0.01
186.1279297	0.04
187.9755249	0.20
189.3766632	0.01
194.1890259	0.13
202.8669434	0.05
215.0169220	0.40
216.9565125	0.01
227.1255493	0.05
229.0209656	0.36
230.3390503	0.05
231.2017975	0.09
237.0534668	0.08
239.9496307	0.02
244.0655518	0.04
254.0890198	0.12
255.9958191	0.06
257.9920349	0.12
267.1470337	0.04
269.2082825	0.05
271.0258179	0.26
273.0133057	0.02
280.8253784	0.13
282.0531616	0.02
283.1908569	0.13
284.3331909	0.02
284.9717407	0.03
286.0984497	0.03
297.9885864	0.11
306.3043823	0.04
309.9445496	0.08
311.0877686	0.06
312.5528564	0.03
315.0611572	4.56
324.8742676	0.04
327.0665283	2.56
333.1106567	0.48
337.6492920	0.03
340.0626831	0.01
341.0535278	0.29
343.0703735	0.03
347.1305542	0.11
356.9683838	0.03
359.0352173	100.00
360.1864624	2.20
361.0392456	0.40
372.8995361	0.09
378.0052490	0.06
400.8883667	0.05
416.9341431	0.14
428.9014893	0.06
436.2512817	0.12
446.8927612	0.16
452.1252441	0.09
461.1609497	0.04
462.8638916	0.05
481.1745605	0.02
488.0128784	0.05
498.8885498	0.07
503.6785278	0.07
504.4039917	0.02
505.0145264	0.09
505.7310181	0.08
507.0280151	5.34
515.1066895	0.01
532.9541016	1.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	468.1674
Annotation	Unknow
Peak:m/z	Relative Intensity
135.8908997	0.06
154.9179993	0.06
178.8861084	0.03
184.8676453	0.03
190.9519501	0.06
195.3103027	0.23
211.3171997	0.07
213.2097168	0.03
221.0741272	0.11
222.9550629	0.39
235.1544189	0.04
239.1360474	0.22
240.9312744	0.11
244.0605774	0.02
249.1294250	0.02
255.0544739	0.36
257.1748962	0.16
265.2056274	0.10
266.8215332	0.29
267.4447937	0.06
279.3301086	0.08
283.1518250	2.66
285.1878967	0.80
288.3408813	0.14
299.0875854	0.86
299.8438416	0.01
301.2550354	0.31
306.9387817	0.03
311.0199585	2.66
314.0377808	0.25
316.9752197	0.14
320.2093811	0.03
321.2764893	0.02
324.5061035	0.13
325.1100769	0.20
327.2697754	0.52
329.1589355	3.45
331.0053711	0.04
334.3002930	0.09
335.6961365	0.03
337.1399536	0.09
339.7569275	0.13
340.4630127	0.37
341.4157104	0.11
342.6022644	0.11
343.3094788	0.02
344.9186707	1.03
346.0090942	0.92
347.0951843	0.22
353.3095703	0.15
354.3573608	0.11
360.2160339	1.23
361.2661743	0.17
363.2695312	0.86
364.3699341	0.20
365.1566467	0.11
368.1863098	0.61
369.1528015	0.18
369.8559570	0.03
371.0424194	0.08
372.6622009	0.11
376.5637207	0.13
378.2236938	1.20
379.0479431	0.15
382.9393005	0.03
386.1704712	3.31
387.2893677	0.40
388.3094788	0.39
396.0251465	0.58
396.9909363	0.29
398.3015442	0.16
404.2141113	1.67
404.8493347	0.04
408.1886292	0.07
414.2276917	2.67
415.2984009	0.98
418.6466980	0.05
419.3533020	0.08
422.1908264	0.29
424.1352844	0.12
425.1246338	0.03
426.2588806	0.07
432.1935730	54.57
433.1379089	0.25
436.0852966	0.06
450.1842346	100.00
451.4341125	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	207.0662
Annotation	Sinapinaldehyde
Peak:m/z	Relative Intensity
67.2145996	0.04
103.0222321	0.09
117.0195770	0.14
135.0387573	0.04
141.1107483	0.03
146.9548492	100.00
160.9638824	0.26
163.0343323	0.68
164.9927521	72.29
175.0880890	0.03
179.0749664	0.09
181.0266418	0.02
188.9831848	0.18
192.1396332	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.33
Annotation	Unknow
Peak:m/z	Relative Intensity
201.9091644	0.01
255.2010498	0.04
279.3486938	2.40
294.4174805	0.01
302.0661011	0.05
306.8074036	0.02
311.8984375	0.06
391.1948853	0.15
409.3583984	0.01
413.1373901	0.02
459.4528809	0.10
468.1339722	0.06
472.5573120	0.04
495.0555420	0.03
496.3057251	0.03
500.1760254	0.14
502.0711670	0.02
504.2960205	100.00
505.1841431	0.31
506.5991821	0.01
517.5531616	0.03
518.3157349	0.04
528.1865234	0.04
532.3900757	0.02
535.7295532	0.03
546.3865967	0.07
549.2365112	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	363.1793
Annotation	Anisocoumarin C
Peak:m/z	Relative Intensity
175.1628265	1.12
177.0548248	1.16
209.1150818	2.09
211.1950684	0.74
226.8419495	4.11
227.4674377	0.40
237.4355164	1.88
242.0354004	1.66
255.1532898	17.97
271.2031250	4.39
272.7027588	13.07
273.3973083	5.87
281.1420898	0.92
283.0266113	0.38
289.2079468	1.48
291.4221497	0.60
299.1102600	34.19
300.9296875	2.01
303.4027100	4.46
308.9582520	0.67
317.0627136	74.01
323.6382141	0.27
327.0812073	7.80
333.2780151	0.79
335.2314758	1.61
345.1328735	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.13
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
161.1531982	0.11
173.2264557	0.15
174.8211670	0.06
184.9733124	0.11
188.0718842	0.07
199.2788696	0.03
201.0238190	0.08
203.1394043	0.23
205.0590515	0.24
207.0842133	0.04
215.2059021	0.03
217.2850494	0.09
225.3775787	0.03
227.1964417	0.19
229.2712708	0.34
230.3079834	0.08
231.1943665	0.01
243.2161865	0.47
245.1130829	2.30
247.3982697	0.06
249.0942078	0.24
250.1360779	0.03
255.2120972	0.25
269.1160889	0.53
270.0155029	0.17
270.8352661	0.19
273.1219482	1.44
275.3908691	0.03
281.0271301	0.10
283.1077271	0.11
285.1013184	0.17
287.1513062	4.81
289.1616821	16.66
299.0656738	4.95
301.0388794	0.08
303.1140137	0.02
305.0874634	0.06
306.3040466	0.05
316.9829712	0.08
327.3338013	0.19
329.1848145	0.29
331.2191162	0.59
333.0858765	0.13
335.0803833	0.02
339.1860962	0.14
341.3185425	0.17
347.0991211	0.03
351.2091064	0.19
352.3406372	0.09
355.3353271	0.06
357.0848999	0.19
359.3274536	0.04
365.3587646	0.06
367.0681152	0.08
368.3421631	0.03
381.1615601	1.42
387.3923340	0.02
389.2167969	0.06
393.0750122	0.16
396.1387329	0.05
401.1993408	0.16
405.5126953	0.09
407.1764526	50.71
409.3063354	0.43
411.1948242	0.57
413.1476440	0.09
414.2728882	0.33
415.0750732	0.09
422.4429932	0.15
423.1672363	0.53
425.1779785	100.00
427.2757568	0.05
433.1718750	0.38
437.4008789	0.08
439.0156250	0.02
443.3879395	0.05
445.1600342	0.02
449.2535400	1.07
451.2094727	23.31
453.3344116	0.08
467.0808716	0.57
475.2335205	0.20
481.2330933	0.42
487.2041626	0.71
491.2866211	0.33
493.2604370	0.07
514.3476562	0.18
515.2918091	0.32
530.2646484	0.19
531.2219849	0.17
532.3544922	0.22
533.2348022	0.60
534.3145142	0.04
537.3867798	0.14
541.1995239	0.38
542.3143311	0.06
546.2902832	0.19
547.8094482	0.06
558.2659912	0.15
559.2369995	6.71
568.3493042	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	347.1482
Annotation	Nagilactone B
Peak:m/z	Relative Intensity
114.8704681	0.01
115.4946594	0.05
125.0401230	0.02
136.7845459	0.02
147.0583801	0.04
149.1362915	0.55
151.0603638	0.04
158.9936829	0.11
160.9628448	0.04
163.0934753	0.11
164.9844055	0.08
178.1681061	0.02
183.1343079	0.10
184.9841766	0.06
186.3050537	0.01
186.9732208	0.08
189.1114807	0.03
191.0994873	0.14
199.9936523	0.07
203.1425934	0.09
205.2680817	0.09
211.3090515	0.02
213.0067444	0.04
219.0644531	0.04
221.2115173	0.04
222.2256775	0.03
224.7757874	0.05
226.1524048	0.03
229.1401367	0.02
231.2043152	0.04
235.2727661	0.01
237.1720581	0.05
239.0674133	0.56
240.0778503	0.07
240.8773193	0.02
255.0158386	0.41
257.2037964	0.11
259.1152954	0.52
261.0923462	0.02
265.4106750	0.03
267.0428162	0.33
269.2053833	0.05
273.1563110	0.36
274.1582947	0.14
283.1608887	7.05
285.0603333	0.55
287.0048218	0.11
291.2008057	0.02
297.1372681	0.03
301.1207581	24.35
301.7613525	0.06
303.1477051	0.06
305.7779541	0.03
310.9691772	15.70
312.2666626	0.08
315.5276489	0.14
318.9349060	0.03
319.6517639	0.03
329.0385742	100.00
329.6997070	0.32
332.1578674	0.02
336.9317017	0.05
347.2909241	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	557.2601
Annotation	Cuniloside
Peak:m/z	Relative Intensity
160.8603363	0.33
179.0044250	0.35
349.3485718	1.57
379.2677002	0.01
511.3092651	100.00
511.9173584	0.10
513.4844971	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	531.2645
Annotation	Unknow
Peak:m/z	Relative Intensity
157.0881042	0.16
158.0526733	0.14
169.1995239	0.04
173.0902557	0.06
175.1445312	0.14
185.2508545	0.02
195.1351318	0.05
199.3890533	0.17
200.1172485	0.07
206.8146973	0.05
209.3015137	0.03
211.0044250	0.04
217.1562805	1.27
218.1136017	0.03
233.8744812	0.01
235.3867188	0.07
252.0645905	0.06
267.3510742	0.03
285.1860962	0.06
287.3004150	0.06
310.2295532	0.04
313.2827148	0.09
319.1348267	0.04
330.2444458	0.20
331.3219604	0.11
332.4102783	0.06
337.5255737	0.04
339.4537354	0.07
346.0382080	0.04
348.2918091	0.20
349.1549683	0.74
350.8936768	0.10
356.0173950	0.10
363.5861816	0.03
364.3386841	0.07
365.5831299	0.11
367.2721558	0.07
374.2529907	0.58
383.3880615	7.50
387.1120605	0.05
392.2570801	0.25
393.2460327	0.04
397.2125244	0.10
399.4137573	0.04
406.2532349	0.07
407.6080322	0.04
409.3397827	0.41
410.3455200	0.17
425.1315918	0.16
427.3400879	13.26
428.2360840	0.11
441.2131958	0.08
443.4309692	0.07
445.3202515	6.27
446.0725098	0.25
452.3991089	0.50
453.3861694	0.03
459.3915405	0.05
469.3145752	1.84
470.1322632	0.34
471.2797852	0.09
472.3890991	0.09
487.3823853	100.00
488.3158569	0.85
489.3834229	0.14
496.2387085	0.16
497.2567749	0.04
513.2849121	2.83
514.3318481	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2781
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
140.1185608	0.07
152.9458923	0.19
166.2998962	0.02
196.0141144	1.72
205.1855316	0.02
214.1430359	1.49
229.2720795	0.05
261.1415100	0.30
279.2353821	100.00
279.8379822	0.20
311.2641296	0.14
344.5957031	0.02
347.3031006	0.08
356.1341858	0.04
414.7352295	0.08
415.4811707	0.10
419.0520630	0.03
420.0372620	0.06
422.2432861	0.10
424.8783569	0.06
430.5587463	0.14
431.2576904	0.03
433.2496338	0.05
440.5154419	0.04
458.0458374	0.09
458.8353271	0.02
459.4512024	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.2079
Annotation	Glaucarubinone
Peak:m/z	Relative Intensity
143.0838776	0.26
160.9753723	4.13
165.2884827	0.16
170.8200378	0.13
178.9213562	0.37
223.1196747	0.42
225.1817780	10.68
229.2677307	0.12
239.1447449	0.17
241.3885040	0.14
266.9535217	0.70
269.2326660	18.30
287.0709839	0.88
313.1515808	100.00
313.7557068	0.32
315.2176819	0.14
326.9885559	0.29
405.3462219	0.70
447.3832092	0.32
449.2657776	59.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
90.78279114	0.60
94.93968201	0.33
96.79418945	0.13
104.9050293	0.12
107.021225	0.36
108.9148712	0.85
114.9725113	0.20
116.0360031	0.72
117.1015167	0.20
121.1329346	0.49
122.9951477	1.09
125.3264771	0.13
126.9067154	0.84
129.7613678	0.17
131.0414124	0.58
132.903656	0.32
133.9622803	0.31
135.0805359	1.43
137.2037659	0.65
137.8984375	0.29
139.0374146	1.55
140.0367432	0.12
141.1079865	0.45
143.0572357	1.63
149.1472473	0.40
151.2153168	1.50
153.2702332	0.78
154.1085205	0.09
155.0143738	1.29
157.0917511	1.29
159.0610046	0.56
160.8790283	0.14
163.0919647	0.78
165.1620331	0.53
166.0064087	0.24
167.0193024	0.41
168.9543152	1.44
171.0513611	0.54
173.2987671	0.89
175.0577545	0.73
176.9080353	0.30
179.1285553	1.40
180.9779816	1.44
183.059845	0.48
185.2674713	0.63
189.0546265	0.21
191.1711121	1.56
193.1524811	1.48
195.0613251	1.51
197.0606537	2.76
201.1647797	0.35
206.1334534	0.45
206.9759827	0.38
209.0663452	1.49
211.2667847	1.43
212.5593567	0.42
213.3405457	1.66
214.7172241	0.44
215.3416138	0.37
217.200592	0.09
221.5629883	0.30
223.1032104	0.68
225.1156921	1.47
227.0235901	0.45
229.1585999	1.08
231.0877075	0.69
232.6184082	0.57
233.2465515	1.19
235.1420898	0.77
237.1853027	2.07
239.2613831	2.45
241.2803345	1.66
247.2536011	0.62
248.3459778	0.29
249.1635132	0.24
251.2909851	1.11
251.9043579	0.70
253.3309937	3.56
256.4480591	0.36
257.1602783	2.05
265.3406677	2.37
266.5041809	0.30
267.1178894	0.51
267.9856262	0.67
269.2562561	2.06
275.1764526	17.83
283.5033264	0.57
289.0760193	0.26
290.8530579	0.91
293.215271	100.00
294.1216125	0.28
311.1669922	0.38
321.0101929	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.2761
Annotation	Canavalioside
Peak:m/z	Relative Intensity
282.2922974	0.03
291.5745850	0.02
351.2603149	1.93
378.2446899	0.05
379.4621582	0.02
391.2197266	0.03
393.0916748	0.11
423.0823364	0.04
509.2224731	0.02
511.4629517	0.02
513.3372192	100.00
513.9461060	0.45
515.1763916	0.02
540.5745239	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	363.1448
Annotation	Nagilactone B
Peak:m/z	Relative Intensity
116.4667358	0.27
117.0683289	1.54
118.0682068	1.00
143.9626312	0.05
154.8940430	0.05
157.0806885	1.33
158.1151276	1.69
164.0694580	0.10
187.4059906	0.06
199.2388306	0.13
201.0667725	14.35
202.1486816	24.77
214.4536896	0.20
216.3448792	0.20
217.0786438	0.15
217.8544922	0.07
220.0990295	0.05
229.7218018	0.04
230.3265991	0.05
231.4981384	0.08
245.2766724	2.22
246.1982117	4.60
248.4761047	0.16
249.3569641	0.08
257.3213806	3.81
258.2100525	21.70
261.3130188	0.21
275.1810913	3.23
276.3085022	21.13
284.2455444	0.08
301.4550171	6.62
302.1809998	58.75
303.4657288	0.29
318.2865295	1.29
320.1364746	100.00
320.7575073	0.47
321.4264832	0.05
328.2765503	0.11
335.8466797	0.06
346.1650696	37.47
347.2031555	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1184.0807
Annotation	Unknow
Peak:m/z	Relative Intensity
412.3548279	0.99
413.1616516	0.08
456.1763916	1.05
457.0870972	0.14
474.2604065	0.14
475.4328613	0.07
500.4514771	0.07
531.1040039	0.22
552.4568481	0.37
553.4506836	0.16
571.4968262	0.05
580.0280762	0.06
586.4956055	0.10
596.6071777	0.23
614.4125977	0.78
615.3594971	0.21
616.8156738	0.06
624.7133789	0.17
632.4798584	0.33
638.4252930	0.18
652.0101318	0.12
655.3493652	0.38
656.3414917	0.37
658.4478760	0.97
662.7463379	0.05
676.2184448	0.19
681.2407227	0.66
682.8333740	0.09
699.5153198	1.95
700.6503296	0.63
708.9433594	0.60
717.4511719	0.91
725.4960938	0.22
743.3779907	4.35
744.5382080	2.30
751.4587402	0.22
755.3283691	0.20
761.4396362	1.75
762.6025391	0.14
769.1912231	0.19
769.8892822	0.09
770.5067749	0.15
779.5411377	0.17
780.6906738	0.15
787.3155518	6.27
788.3983154	1.69
796.3684082	0.21
805.0085449	0.22
805.6287842	2.14
806.3587646	1.01
807.4061279	0.04
830.4985352	0.34
838.6127930	0.08
841.3702393	0.53
846.0854492	0.59
850.5153809	0.31
858.2681885	0.35
862.6292725	0.12
866.5611572	0.10
867.2288818	0.13
869.3682861	0.23
870.4306641	0.13
877.1406250	0.23
879.4449463	0.16
885.3854980	0.33
886.0024414	0.16
890.2486572	0.11
893.6984863	0.09
898.7895508	0.32
899.6627197	0.56
902.7788086	0.77
903.6339111	0.06
912.8784180	0.13
915.4217529	0.69
916.1711426	0.60
917.6024170	0.24
919.4711914	0.33
920.5281982	0.26
921.3187256	0.12
922.4133301	0.12
924.9224854	0.33
926.7888184	0.52
930.9647217	0.23
934.6157227	0.14
947.2073975	0.24
948.8023682	0.41
953.1096191	0.09
954.1864014	0.13
957.6134033	0.65
963.2379150	0.10
963.9804688	0.33
966.6912842	0.88
969.2695312	0.13
970.7242432	0.35
972.5087891	0.52
973.4011230	0.85
974.4810791	0.14
976.4144287	0.09
979.4691162	0.73
980.8415527	1.15
981.8085938	4.82
985.7160645	0.52
986.8372803	0.59
988.6251221	2.37
989.7528076	0.33
992.8292236	0.16
994.6754150	4.09
995.3156738	2.38
996.0010986	0.19
998.9780273	0.46
1000.9274900	0.17
1001.7446290	0.42
1002.4641110	0.21
1003.7172850	25.26
1004.8002930	0.49
1006.3079830	0.06
1007.9545900	2.54
1010.6715090	1.66
1011.2802730	0.24
1012.6831050	0.42
1016.6567380	4.87
1017.5966800	1.31
1018.7762450	0.41
1019.6817630	0.26
1025.6926270	31.92
1026.7312010	0.41
1032.8706050	0.19
1034.5985110	0.16
1040.9858400	0.48
1042.4910890	0.17
1043.8061520	0.22
1049.3038330	0.05
1052.8214110	0.05
1054.8686520	0.20
1056.8629150	0.40
1057.6668700	0.39
1059.1063230	0.28
1062.3701170	0.55
1065.1058350	0.55
1066.3027340	0.53
1069.9984130	0.29
1070.8283690	0.16
1072.0352780	0.07
1074.6695560	0.79
1079.5327150	1.70
1080.3094480	1.83
1083.6337890	0.14
1084.5994870	0.39
1086.0104980	0.16
1088.0002440	5.12
1089.0717770	3.24
1093.3288570	0.52
1096.2862550	2.87
1097.1700440	1.42
1098.5241700	0.16
1101.2202150	5.41
1102.2131350	3.81
1103.5048830	0.95
1104.9310300	0.12
1107.8085940	0.54
1109.8808590	5.03
1110.5119630	8.15
1111.2812500	0.22
1112.0067140	2.04
1112.8791500	0.23
1113.7158200	0.85
1114.7830810	0.18
1116.7657470	1.15
1118.7026370	4.60
1119.5424800	0.15
1120.5563960	0.71
1121.6240230	0.05
1122.3654790	1.46
1123.1597900	1.29
1123.8212890	0.32
1125.2070310	2.64
1126.0844730	0.49
1130.0433350	1.73
1131.0197750	3.20
1131.8367920	5.23
1132.6215820	0.32
1134.1118160	0.26
1135.3242190	1.42
1136.6381840	0.78
1138.3364260	8.77
1139.4162600	2.37
1140.0173340	9.35
1140.8756100	3.70
1144.5451660	10.78
1145.6791990	0.10
1147.3435060	23.43
1148.2302250	0.87
1149.2913820	0.27
1151.1966550	1.21
1152.1746830	1.30
1153.3763430	52.10
1154.1552730	8.25
1154.9942630	1.03
1157.0788570	0.88
1157.7292480	0.88
1158.4445800	0.75
1160.3613280	8.89
1162.2912600	100.00
1163.2087400	5.08
1164.5029300	0.08
1166.5047610	18.85
1167.2923580	2.33
1169.2918700	29.97
1170.1816410	1.81
1200.3791500	0.06
1209.8345950	0.15
1244.5026860	0.05
1245.4407960	2.36
1246.1125490	0.17
1246.7687990	0.53
1266.0125730	0.43
1320.6026610	0.18
1331.5810550	0.24
1334.0471190	0.14
1336.0429690	0.30
1349.5058590	0.31
1357.9542240	0.17
1362.2423100	0.09
1402.4385990	0.05
1411.5223390	0.08
1413.4913330	0.26
1429.6102290	0.10
1435.6715090	0.37
1436.6785890	0.23
1447.5726320	0.18
1448.7071530	0.25
1450.8392330	0.37
1465.8131100	1.08
1466.7867430	0.13
1467.6658940	0.51
1473.4538570	0.47
1480.6300050	0.07
1485.6666260	0.21
1496.7425540	0.12
1501.4368900	0.10
1515.1716310	0.14
1519.4305420	0.11
1532.6884770	2.19
1533.7186280	1.98
1534.7574460	0.20
1544.5526120	2.73
1545.6196290	0.80
1546.2392580	0.55
1546.9198000	0.38
1559.4990230	0.09
1562.6138920	15.72
1563.6824950	6.42
1564.8212890	0.52
1580.7706300	0.11
1582.7803960	0.12
1595.8131100	0.10
1612.7082520	0.18
1630.4835210	0.14
1631.7371830	0.07
1674.8435060	0.25
1680.0396730	0.05
1683.8096920	0.30
1691.7653810	0.49
1692.8054200	0.37
1694.0023190	0.35
1709.8342290	0.76
1710.6439210	0.07
1717.2969970	0.12
1718.8280030	0.09
1720.9899900	0.15
1732.7014160	0.04
1735.6971440	0.07
1736.9259030	0.15
1788.6691890	0.11
1791.9118650	0.04
1802.5438230	0.15
1809.7888180	0.04
1810.6726070	0.42
1813.5670170	0.22
1820.7307130	0.09
1821.9064940	0.22
1849.4971920	0.06
1850.1802980	0.28
1858.8397220	0.05
1875.5950930	0.33
1917.7448730	0.14
1990.8439940	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
95.20770264	0.29
97.04364014	0.56
99.02676392	0.12
100.8175812	0.15
104.9459457	0.29
106.8701096	0.22
108.9986877	0.52
113.0553894	0.54
115.0712509	0.31
118.9100723	0.31
121.2216644	0.86
122.9772873	0.65
124.675354	1.12
126.8499451	0.36
128.8306427	0.62
130.2358704	0.22
131.0402832	0.21
133.2435913	0.40
135.1378174	0.82
136.9110107	1.08
138.9824829	1.43
140.9316864	0.25
143.2283936	0.92
145.3043823	0.32
147.010437	0.16
149.1238098	1.25
151.2016144	0.56
151.9703979	0.23
153.2565002	1.25
157.2464447	1.38
161.0028076	0.72
163.0847626	1.56
165.1395416	0.32
166.9052429	0.72
169.0028076	4.32
171.2867432	0.10
173.0952759	0.26
175.1276703	1.57
177.1177063	2.13
178.0978546	0.15
179.0402527	0.62
179.9783325	0.53
181.1898651	3.25
182.9801331	1.67
185.019989	0.38
186.8076935	0.36
188.9715729	0.15
191.015625	0.16
193.0917511	0.10
195.0133667	2.45
197.0742493	2.75
198.9510956	1.16
200.733963	0.35
201.3569336	0.09
207.0673523	0.29
209.190094	1.15
211.2241821	0.94
213.2365417	1.03
215.1477966	0.24
216.1694336	0.93
220.1073608	0.08
221.3714294	0.52
222.896759	1.00
224.1116943	0.09
225.1903992	3.44
227.1750793	0.50
229.3487854	0.34
231.1838379	0.36
233.2537842	0.64
234.9043579	1.08
237.2216797	0.42
239.2333069	0.69
241.1777344	1.55
247.284729	0.87
251.1856079	2.53
253.1613464	6.11
255.0211487	0.29
257.4480286	0.09
259.5958862	0.78
265.1169739	1.79
267.0556946	0.68
268.9911499	1.27
270.2072144	0.21
271.2493286	0.14
273.5490112	0.35
274.6891479	1.10
275.2926331	12.70
279.1012878	0.17
280.178833	0.50
283.1841736	0.31
284.0480652	0.55
287.836853	0.77
289.2526245	0.31
290.2293701	0.69
291.1509399	0.19
293.2086792	100.00
294.0344543	0.51
296.1306763	0.33
301.7691956	0.86
302.9704895	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	402.1378
Annotation	Unknow
Peak:m/z	Relative Intensity
165.2271729	0.04
171.0481567	0.01
184.9184875	0.03
210.9934845	0.07
262.3034973	0.04
274.0675659	0.11
279.8329773	0.07
295.1838379	0.06
296.2238770	0.06
303.3657227	0.11
312.3978271	0.03
313.2194824	0.02
317.0437927	0.06
323.9559631	0.09
330.3047485	0.04
331.4685669	0.07
337.9242249	0.09
339.2395630	0.04
340.2918701	0.12
356.1894226	0.16
358.1994324	100.00
359.3657532	0.22
364.0687866	0.08
365.2226868	0.04
366.2729797	0.18
367.3886108	0.09
374.2652893	0.04
384.2107544	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1194
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
122.9158401	0.16
135.1124878	0.90
136.0736389	2.02
147.1197510	0.41
149.0828705	0.76
150.0482941	0.11
150.9463196	2.94
161.2332153	0.34
162.1489716	0.27
163.9575195	0.19
165.9017487	0.18
166.9821625	0.41
177.0612488	1.08
178.8494873	0.32
180.0843201	0.27
181.1108093	1.56
183.2893982	0.11
189.0563660	0.34
191.1047821	0.53
192.2953033	0.13
195.0291138	62.30
196.1898804	0.52
203.0859222	0.36
205.0514069	0.06
206.9318237	0.06
209.2003326	0.88
216.7993164	0.62
219.2463684	0.14
221.2120972	0.37
223.1336060	24.58
227.4765778	0.22
236.7689819	0.11
239.4268799	0.17
241.0571289	0.17
242.9183044	0.08
249.0604553	0.15
251.0531311	8.20
254.8341980	0.66
263.0976562	0.84
267.2878418	0.06
269.1002808	18.64
272.4191895	0.12
278.3961487	0.22
281.3021851	0.74
311.3066406	0.31
313.5129395	0.09
316.3739319	0.12
335.0921631	0.10
341.1895447	0.19
343.2734985	0.26
344.3409424	0.14
350.3222656	0.06
355.2799683	2.11
357.3601379	0.50
359.1492920	0.17
363.3039856	0.95
368.1507568	0.19
369.4314880	0.08
385.1888123	100.00
387.3883362	0.05
396.0432739	0.13
399.0317383	2.17
411.0986938	0.48
413.2645569	16.26
414.3114014	0.12
415.9268494	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.9713
Annotation	Unknow
Peak:m/z	Relative Intensity
202.0285339	0.09
214.1339417	0.02
245.7470093	0.09
246.3582153	0.01
263.8044434	0.01
273.3348389	0.03
295.2536316	0.04
304.0480957	0.46
307.1481323	0.03
309.1469116	0.02
315.7288208	0.01
329.4767456	0.02
330.0917664	0.02
331.9052734	0.34
333.8609619	0.03
347.9537354	0.93
358.1154480	0.04
376.0675354	0.20
393.9776001	100.00
394.5880432	0.16
402.0614929	0.01
419.8770142	1.28
420.5144958	0.02
426.0005188	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	361.0774
Annotation	Unknow
Peak:m/z	Relative Intensity
110.9959564	0.55
113.0117874	1.09
114.9567490	0.02
123.1159668	0.05
127.2452545	0.03
128.0466309	0.07
150.9880524	0.03
157.0132751	0.03
160.9299011	0.03
163.1660156	0.03
169.1248627	0.03
175.0695648	0.62
182.2075043	0.08
184.1263428	0.02
193.0231628	0.30
195.1727753	0.01
197.0724487	0.38
198.8196106	1.31
225.1049194	0.03
226.9019165	0.03
231.1135254	2.88
231.9748535	0.05
239.0892944	0.05
245.6703491	0.03
246.3355713	0.07
247.1852417	0.04
249.0450745	100.00
257.0375977	0.03
259.1571655	0.21
262.8916321	0.02
265.1917725	0.12
271.4211426	0.10
272.3880920	0.04
273.0452881	0.31
279.5364685	0.05
287.0482483	0.04
297.0515442	0.07
299.1582336	0.24
301.2091980	0.02
315.1538696	0.40
317.0946045	0.18
330.9202576	0.07
333.1453247	0.03
340.9004822	0.03
343.0876160	1.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	319.1187
Annotation	Arteglasin B
Peak:m/z	Relative Intensity
113.1647873	0.04
152.9205322	0.09
157.1391907	0.65
169.0388031	0.02
173.4559479	0.03
182.7959747	0.07
187.3493652	0.14
201.0336609	2.23
213.1251526	10.14
221.2793579	0.12
229.2955322	0.06
231.1764832	35.36
232.1857300	0.31
239.2887573	0.02
245.1524658	0.74
253.1894531	0.03
257.1722412	8.87
258.2213135	0.09
267.3364563	0.02
271.1818848	0.04
272.9540100	0.06
275.2442627	100.00
276.2708740	0.53
283.2773438	0.14
285.0960388	0.06
286.9799500	0.04
290.9819336	0.13
299.1362000	0.09
301.0896912	6.05
301.7148132	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
105.1954193	0.31
123.2028656	0.47
128.9359131	0.26
167.0515137	0.16
170.9814911	2.24
173.0775604	0.96
185.1866455	2.50
187.1135101	0.38
189.1476135	0.91
195.2420654	0.13
198.9408569	0.73
201.0631561	0.48
213.0737305	1.58
214.9998779	1.00
217.0845337	0.22
227.30896	0.78
229.302002	2.80
237.1260376	0.34
239.1663818	0.19
241.4524841	0.44
243.3075867	2.24
245.5834045	0.41
251.0349731	0.87
255.1437073	0.93
257.2536011	0.84
259.0548096	1.39
263.3179016	3.88
267.3213501	2.34
268.2115479	0.25
269.2199707	3.17
271.3031616	5.65
273.3287964	0.22
277.1223145	0.76
283.3690186	1.12
285.0877686	1.32
287.4296875	1.27
293.1019287	0.20
295.2546997	2.56
297.274353	3.96
299.4222107	1.48
301.2887268	0.28
303.2142639	0.57
311.1066895	5.77
313.2560425	2.54
315.1087952	0.69
315.7198486	0.47
320.1044312	0.75
321.3686218	1.32
323.2739258	10.53
325.2513428	0.64
326.953949	0.09
329.0040894	0.15
337.2017212	0.76
339.2492676	100.00
340.1341858	1.71
341.3348083	12.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	716.84
Annotation	Unknow
Peak:m/z	Relative Intensity
222.3559265	0.28
294.6724243	0.29
334.8968506	0.20
362.1364746	0.41
364.2033081	0.08
380.5238647	0.61
395.8753662	0.18
400.3559570	0.68
404.9954834	0.45
411.2145386	0.44
412.0861206	0.04
413.0798340	2.16
418.0010376	1.32
419.0262451	0.61
421.1497803	0.55
458.6185913	0.28
460.5062256	1.08
461.1716309	0.16
462.8513184	4.54
464.4680176	3.15
465.2105103	1.60
488.0503540	0.10
490.7317505	0.16
505.1675415	0.11
517.8930664	0.08
523.1627197	0.22
535.7855225	1.28
537.0714722	1.08
541.9139404	0.79
544.4035034	0.30
545.0321655	0.15
546.5382690	4.16
547.2958984	1.19
548.7075806	19.25
553.8704834	0.29
554.9500122	0.10
601.9488525	0.04
630.6298218	3.20
632.4967041	100.00
633.3104858	0.98
643.2338257	0.58
648.9939575	0.08
656.3195190	1.10
670.3116455	0.25
671.1027222	0.23
698.1840210	1.01
699.2946167	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	342.1749
Annotation	Unknow
Peak:m/z	Relative Intensity
102.8692169	0.04
122.8883514	0.16
126.9765396	1.44
133.1446533	0.33
145.0069885	3.15
153.1203918	0.04
157.0383453	0.43
162.9077759	8.23
163.6347656	0.07
168.1365662	0.05
168.9557648	0.34
177.0489044	0.04
179.3492432	0.21
180.0483704	0.09
188.1726990	0.06
193.1437988	0.14
198.9880219	1.22
204.9510040	0.18
211.0502625	0.25
216.8422852	4.05
217.9667664	0.09
219.3711853	0.02
224.5960388	0.13
227.0406494	0.04
229.7786255	0.20
234.9761047	0.47
241.3169861	0.17
251.0301208	0.11
252.9196167	100.00
253.6005859	0.26
261.1512146	0.21
268.0850220	0.16
288.2651672	0.04
292.1529541	0.11
293.3059998	0.08
294.9582520	0.02
296.0916748	0.08
297.1642761	0.19
298.2466431	0.08
299.8063660	0.17
300.9536133	0.46
306.1750488	0.17
307.2056885	0.17
314.1574707	0.06
320.3473511	0.10
321.5411987	0.42
324.0979309	3.86
325.4481506	0.43
332.9971619	0.09
333.8136902	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1053.4919
Annotation	Fusacandin A
Peak:m/z	Relative Intensity
303.3008423	0.28
321.3344116	0.11
337.2832336	0.37
347.2854919	0.80
364.3084412	0.18
383.1376038	0.07
437.2660522	0.07
446.0094604	0.19
497.2779541	0.93
499.3910828	0.26
509.4498596	0.76
525.3236084	0.06
527.3778076	100.00
545.1018677	0.20
546.4652710	0.15
549.0625610	0.38
667.5737915	0.21
673.2893066	0.14
829.4645996	0.10
854.9509277	0.08
873.3126221	0.50
938.2397461	0.25
964.9289551	0.14
990.4193115	0.27
1009.2110600	0.19
1014.6511230	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	317.2104
Annotation	7-Oxo-8,15-isopimaradien-18-oic acid
Peak:m/z	Relative Intensity
90.7638855	0.08
92.9787979	0.26
94.0125961	0.14
94.9895782	0.31
97.9959412	0.04
104.9245071	0.06
106.8950348	0.32
109.1916046	0.15
111.0305481	0.04
118.9273453	0.02
121.0686874	0.09
123.0433121	0.11
131.1356201	0.23
133.0356598	0.07
135.0811005	0.89
136.9676971	0.46
139.1914978	0.03
143.0619812	0.14
144.7711029	0.09
146.7454834	0.03
147.3615265	0.10
148.1186523	0.07
149.1852722	0.34
151.3142395	0.06
153.0368195	3.27
157.0533142	0.19
159.0186768	0.24
161.1562500	0.17
163.0870819	0.57
166.8846283	0.09
170.0160522	0.03
171.1318054	0.90
173.1437378	0.37
177.0316925	0.32
179.1276093	0.08
180.9705505	0.09
182.9662781	0.02
188.2119141	0.24
189.0400848	0.52
191.2258911	0.06
193.1118317	0.23
194.1623230	0.05
194.9862213	0.03
197.2922668	0.10
199.3367004	0.07
203.0592651	0.25
205.0546265	0.16
207.4022217	0.17
208.9747925	0.38
211.1187744	0.49
212.5557251	0.42
213.1743164	0.19
215.1243896	0.18
217.1467590	0.86
218.9656677	0.11
221.1813660	0.03
225.2077942	0.16
227.0585022	0.17
229.0787964	0.48
231.1375732	0.05
237.5343018	0.04
239.0848694	0.18
241.0960083	0.18
243.2090149	2.27
244.2861023	0.02
245.4693909	0.02
247.0833435	0.18
247.8275146	0.01
253.2592773	18.85
255.4068909	0.97
257.1195374	0.94
259.1220093	0.07
260.4613953	0.05
261.0744019	0.07
263.3178101	0.32
269.4020691	0.12
271.1729126	100.00
272.2695312	0.09
273.2349854	0.62
276.0647583	0.08
281.1516113	6.85
282.4395142	0.09
287.1914673	0.21
289.1487732	1.23
290.2491455	0.06
296.4796753	0.22
297.4286499	0.15
299.1953735	62.63
300.0462952	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.14
Annotation	Unknow
Peak:m/z	Relative Intensity
160.8824158	0.33
179.0212402	2.10
221.1384125	0.94
232.9175262	0.20
249.7626801	0.04
250.3889008	0.06
268.2225342	0.03
280.8618164	0.18
305.1647339	0.10
310.9506836	0.07
323.0273438	0.52
341.0292969	2.25
377.1106567	8.50
377.7622681	0.08
503.1913452	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	553.1924
Annotation	Abelioside A
Peak:m/z	Relative Intensity
169.1241608	0.10
180.1985016	0.04
236.9425964	0.05
283.0743408	0.49
313.0855103	0.12
313.9569092	0.06
315.0992432	0.01
317.2301025	0.12
318.3289185	0.04
321.1558838	0.12
327.2793579	0.61
328.5799561	0.06
333.2105713	0.06
345.1205444	0.94
346.2570801	0.93
347.4534302	0.48
350.2586060	0.01
372.1668091	0.16
373.2710571	0.16
385.4105835	0.04
389.8544922	0.10
391.2538452	0.09
395.2479248	0.01
423.4920044	0.03
431.6043091	0.05
437.2277222	0.08
445.2982788	0.02
447.6916504	0.02
449.7888184	0.06
457.5468750	0.06
461.2273560	0.09
467.2586670	0.19
473.5993042	0.02
479.1737671	0.07
488.6369629	0.05
490.5020142	0.14
491.4401245	0.02
492.1134644	0.01
493.2552490	0.18
507.1817017	100.00
507.8479004	0.37
509.2371826	0.28
514.9540405	0.06
517.2102661	0.05
534.3649292	0.03
535.2816772	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1195
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
139.1054688	0.10
149.1809387	0.10
151.1424713	0.05
163.0544739	0.03
163.9755859	0.08
166.1340332	0.08
167.2422180	0.10
171.1234436	0.04
172.8947754	0.05
179.1274567	0.09
181.1902466	0.36
188.9412842	0.02
191.2568359	0.04
194.8277740	0.30
206.9987183	0.14
208.2969666	0.04
221.0778198	0.18
223.1437531	26.76
249.1168823	0.28
250.1693726	0.07
251.0992432	1.00
258.9051819	0.03
267.2140503	0.21
269.3130188	0.07
271.8825378	0.03
281.0937805	0.04
282.2565613	0.04
283.3464355	0.06
286.8938293	0.03
296.9676208	0.05
299.3355713	0.03
313.1618042	0.14
317.3240967	0.05
329.5580750	0.07
338.8580017	0.06
343.3043518	0.24
357.3540649	0.19
363.2660828	0.55
365.1958923	0.08
367.1080933	0.11
369.5652161	0.12
371.1710510	0.11
385.1157227	100.00
385.7544250	0.26
387.2709045	0.07
391.3091736	0.06
395.2841492	0.15
399.2654114	0.51
401.5196533	0.10
411.2093811	0.29
413.2487793	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	537.93
Annotation	Unknow
Peak:m/z	Relative Intensity
182.7986298	0.26
285.7198486	0.22
297.9622803	0.05
326.6564331	0.11
337.2380981	0.22
352.9152832	0.36
372.0663452	0.08
387.1284180	0.13
391.1497803	0.27
420.9815674	0.35
422.0957031	0.37
422.9763794	1.91
423.9421997	5.75
425.1063843	4.08
428.0148926	0.11
431.7479248	0.19
440.2078857	0.24
441.7506104	0.78
442.8040771	0.51
464.1044312	0.17
466.7151489	0.16
480.9392700	0.22
482.1744995	0.60
489.9535522	0.48
491.9440308	100.00
492.9540405	31.97
494.0097046	2.24
495.1162720	0.15
501.7831421	2.05
509.8538208	32.69
510.9035645	10.33
511.7161255	0.09
519.6157227	0.46
521.1813354	0.14
527.8831787	1.14
528.5717773	1.10
532.7197876	0.41
537.9918823	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.2018
Annotation	Unknow
Peak:m/z	Relative Intensity
155.0906372	12.57
157.0395660	0.04
158.8334503	0.14
169.0594482	0.11
177.2393799	0.23
178.8228455	0.37
181.1618652	0.29
183.2346802	0.13
192.2232666	0.15
199.1237946	53.54
213.0762787	0.30
237.1445923	0.46
241.1089783	3.07
251.3173523	0.12
253.1979980	4.83
255.3933105	0.31
260.9603271	0.08
267.0782471	0.16
269.2493896	0.04
271.0328369	1.19
281.4760742	0.38
286.9806213	0.18
291.2737427	0.12
293.1534119	0.15
297.3468018	0.11
299.2847900	32.22
300.3815308	0.55
301.0469360	0.08
302.9262695	0.10
306.9724121	0.16
313.2830200	0.27
315.4310303	1.06
317.1602783	1.81
325.2802734	0.77
327.4686890	0.10
329.3771973	0.16
331.1827393	0.17
333.4356689	0.07
341.1132202	0.37
343.1878052	100.00
344.3128052	0.88
346.1557007	0.08
361.2644653	20.30
363.3833618	0.09
365.0684814	0.23
379.3109741	0.18
385.4252319	0.43
391.2526245	0.13
396.9683228	0.10
403.1627808	1.74
405.8817139	0.14
427.5108032	0.16
434.0585327	0.28
435.4675293	0.09
438.2449951	0.16
445.1870728	0.28
449.2257690	0.23
451.3645020	0.35
461.1964722	0.32
462.4633789	0.45
463.3799438	0.29
477.2979126	7.40
479.2588501	3.30
480.2374268	0.14
485.2335205	0.44
493.2186890	0.23
494.9132080	0.19
505.3700562	3.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
97.16517639	0.54
104.7200928	0.07
141.3793793	0.14
146.0070648	0.15
148.9502411	0.84
153.0687866	0.06
161.074234	0.49
164.9107513	0.21
165.9407501	0.16
179.1587982	0.97
185.1463165	0.13
194.1362152	0.85
195.154068	0.96
205.2178497	0.03
206.1829987	0.08
207.1907654	3.49
208.1769867	1.52
209.0077057	1.23
221.0659332	0.21
222.1447906	2.69
223.0999451	2.61
224.1799774	0.18
233.0710907	0.30
251.0781708	100.00
252.140686	21.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0984
Annotation	3-Methoxy-4-hydroxyphenylglycol glucuronide
Peak:m/z	Relative Intensity
123.0463486	0.03
138.0101776	0.34
143.1286774	0.03
146.1363983	0.05
147.8365479	0.01
148.7399292	0.03
153.0034790	0.90
160.8617859	0.03
166.9795532	0.14
179.2289124	0.08
180.8594666	0.04
182.0308228	4.78
190.9997253	0.06
195.1660156	0.02
197.0084991	100.00
197.7657471	0.02
206.9512329	0.04
211.2606812	0.02
215.1691895	0.02
232.9761047	0.01
238.9861755	0.56
263.4624634	0.04
265.1500244	0.06
276.7268677	0.02
281.2850342	0.05
287.3479614	0.02
296.9312134	0.04
311.0980225	0.02
313.2116394	0.05
315.1901855	0.13
327.1903076	0.02
341.0725098	0.16
343.4109192	0.07
344.2109680	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	213.1117
Annotation	F 11334A1
Peak:m/z	Relative Intensity
68.8759079	0.02
80.9673233	0.03
87.7273560	0.10
93.1298523	0.06
94.9305267	0.03
96.9953461	0.15
98.9399109	0.08
106.9749603	0.33
112.9267883	0.03
115.2261200	0.17
116.9958344	0.22
125.1333008	0.02
127.0034790	0.05
131.0254974	0.14
133.0569153	0.01
134.9805756	0.96
137.2438507	0.07
139.1695251	0.17
143.1175995	0.03
148.9605865	1.32
149.6055603	0.03
153.1510162	0.09
155.0976410	0.06
157.1630402	0.09
163.0051880	79.19
165.2859955	0.02
166.9352875	87.43
167.8113861	0.04
168.8919373	0.41
170.9316101	0.06
177.1793060	0.30
181.0235138	3.58
183.0633392	0.04
185.2720795	0.05
194.9906158	100.00
195.9427948	0.07
198.0285797	0.03
213.3392487	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
115.2754364	0.30
131.03508	0.22
142.8997345	0.19
159.2357178	0.48
165.0912781	0.26
169.0740662	0.43
171.1696167	1.15
173.0948029	0.91
178.7140045	0.51
182.7403564	0.40
185.0641479	4.21
187.1889801	1.08
189.3119354	0.45
199.2115021	1.64
201.1676636	2.74
203.1130371	0.54
213.1881714	1.46
215.2179565	2.69
217.2953186	1.14
227.4760742	0.55
229.1992493	6.36
231.2030945	0.58
239.0265503	0.50
241.2618408	1.86
243.2411499	5.85
245.1893616	0.86
252.9887695	0.28
255.2171631	0.77
257.2919312	4.46
259.1595764	1.11
262.1639404	0.10
263.1548767	0.61
267.5291138	0.08
269.2797241	0.45
271.2461548	3.82
273.0852661	2.18
283.2573242	0.76
285.303894	2.90
286.0510864	0.60
287.2315674	2.46
289.2541199	0.14
295.2805176	1.24
297.3610229	2.51
299.3529053	7.24
301.3041382	0.40
311.2345886	0.96
313.2452698	4.59
314.3851929	0.30
315.3571777	3.15
315.971283	0.44
321.2611084	2.39
322.1184387	0.53
323.3258667	6.90
337.3612976	0.18
339.2481689	100.00
341.3614807	17.55
342.9109802	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	798.1267
Annotation	Unknow
Peak:m/z	Relative Intensity
233.7974854	0.57
242.2311859	0.69
248.0393677	0.90
249.9538269	0.89
261.0083313	0.17
262.0846558	0.29
267.8891602	0.87
283.3900452	0.29
290.0006104	0.28
292.1207886	0.66
293.4573364	0.31
298.2871704	0.34
305.6130066	0.08
310.1518555	0.53
319.2053223	0.15
320.1068726	0.84
321.0330505	0.44
322.1643372	0.40
324.0305786	0.75
332.2572632	0.60
333.9503174	2.10
334.9483032	0.17
336.1069336	0.57
346.0757751	0.31
349.8463745	0.57
351.9410400	1.35
355.2260132	0.74
362.0114136	0.34
363.1492004	0.09
364.1176147	3.83
366.3023682	0.24
372.3827820	0.44
373.4272461	0.95
377.9458008	2.42
379.7403564	0.80
380.8628540	0.90
381.7321167	1.64
382.3355713	0.84
397.3660278	0.75
398.1184082	0.06
399.8259888	0.36
407.9440308	40.75
409.1016846	2.39
414.1446533	0.39
416.5472412	0.18
423.6606445	0.34
424.5566406	0.17
425.9743042	26.50
427.0551758	0.89
428.0477295	7.23
434.1348267	0.54
442.9575806	1.11
443.9976196	0.15
445.9380493	5.43
451.0980225	0.34
454.2039185	1.04
460.2738647	0.11
467.8720703	2.32
472.0903931	0.15
474.0395508	0.22
475.2674561	0.42
480.2355957	0.60
481.1751709	0.21
485.9869995	3.70
494.3632202	0.69
497.9754639	0.22
499.1132812	1.50
502.0009766	2.10
503.8566284	0.45
511.6129150	0.49
513.2468872	0.06
514.2109985	0.46
515.4730835	0.30
516.0888062	0.27
522.1635132	2.00
524.9948120	0.38
525.8198242	0.25
529.7493286	1.24
530.4564819	0.13
539.8615723	0.23
542.2031250	3.12
543.2177734	0.14
547.8763428	0.19
575.8938599	0.18
582.2377930	0.44
583.8651123	3.91
584.5283813	0.36
585.9696655	3.47
599.4898682	0.27
601.8823853	4.45
603.9094849	47.95
605.1154785	0.27
614.8639526	0.28
617.1328125	0.20
620.1043701	0.08
622.0261841	37.00
632.1818848	1.04
633.1212769	3.82
635.5308838	0.17
636.3533936	0.41
640.0734863	0.21
646.1671753	0.27
647.7533569	0.30
649.9671021	0.87
653.5612183	0.07
656.2530518	0.51
657.9722900	0.35
663.6029663	0.37
688.1157837	0.10
689.8643188	0.94
693.1622925	0.30
699.9365234	2.49
709.5547485	1.06
712.5755005	0.23
718.1185913	1.01
721.2700806	0.49
726.9281616	0.11
727.7302856	0.20
734.3887329	0.12
735.6961060	0.23
762.0986328	9.03
778.2332153	0.35
779.9541626	100.00
780.6798706	0.34
785.2059937	0.44
799.9006958	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1019.4498
Annotation	Unknow
Peak:m/z	Relative Intensity
299.2459106	0.27
314.8206787	0.13
333.2388611	2.10
343.1653137	0.14
351.2711792	3.23
356.0123901	0.07
417.2594604	0.41
434.4202271	0.38
460.8938293	0.16
495.4630127	0.07
505.2137451	21.96
506.1575928	0.17
507.3448792	0.21
511.2940674	0.81
513.3944092	100.00
514.1171875	0.04
567.2935181	0.47
578.4343262	0.17
608.5888672	0.15
630.1634521	0.11
857.1900635	0.41
892.2254639	0.78
917.4361572	0.23
970.9777832	0.35
996.7792969	0.30
998.4025879	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1245
Annotation	Curculigoside B
Peak:m/z	Relative Intensity
137.0167389	1.58
159.9563141	0.02
161.0432434	2.59
164.7655334	0.05
167.1639404	0.03
178.9884796	0.24
184.3036499	0.06
188.1465607	0.02
191.0139465	0.27
203.2131348	0.06
205.1236267	0.29
208.8141479	0.11
212.3770142	0.06
221.0822449	0.04
227.2585602	0.26
238.7747192	0.14
243.2959595	0.02
245.1438904	2.07
271.3394470	0.06
280.9916077	0.04
288.0222168	0.02
289.1010132	100.00
299.0740356	3.69
311.0583496	0.10
313.1937256	0.17
325.3995667	0.03
327.4426880	0.05
331.2498779	0.09
343.2040405	0.03
355.3040161	0.23
359.2490234	0.05
367.0954895	0.12
373.1553040	0.13
405.0327148	0.25
407.2703247	0.46
423.1029968	0.07
432.6057434	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1055.5056
Annotation	Neosibiricoside C
Peak:m/z	Relative Intensity
320.4937439	0.07
337.3186340	0.48
346.8905334	0.23
348.6259460	0.63
363.3440857	0.28
365.4725952	0.23
366.2356262	0.57
465.6846313	0.19
466.3372192	0.26
497.2481689	0.58
498.5196838	1.23
499.5363159	0.80
500.8270264	0.13
527.3250732	100.00
528.2822266	80.89
528.9255371	0.31
839.5733643	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
110.8909912	0.19
128.9074707	0.93
131.049408	0.33
149.8580627	0.33
170.6229248	0.68
171.2519073	0.21
172.9391785	0.76
176.8691711	0.13
185.2225952	0.97
187.0298004	1.80
191.2258759	0.60
201.2687073	1.73
210.8219604	0.38
211.4560547	0.41
212.2539062	0.31
213.0937195	0.94
215.1884155	0.78
217.3490906	0.19
227.2128601	1.55
229.1957703	1.75
243.2867432	0.67
253.250061	0.95
255.3704834	0.46
257.293335	0.71
259.2196655	1.14
260.6023865	0.79
263.0335083	2.51
267.4338074	1.40
269.1885986	1.27
271.3569031	3.72
273.4055176	0.79
277.3382263	1.14
283.117981	1.29
285.2480774	1.72
285.9517212	0.46
287.3484802	0.14
289.0045776	0.21
293.2998047	0.98
297.4130859	2.53
299.2901611	0.60
311.246582	4.26
312.1763306	0.35
313.0637512	2.14
315.3557739	1.56
321.112793	2.75
323.3486328	9.12
327.3984985	0.55
329.1026306	0.81
331.1199341	0.46
339.2452087	100.00
340.0504761	2.84
341.3264465	19.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	402.9169
Annotation	Unknow
Peak:m/z	Relative Intensity
130.9239655	0.05
174.9866333	0.38
229.2742920	0.07
244.9713135	0.19
273.0314026	4.94
287.3029175	0.07
288.9311829	100.00
289.5484619	0.19
313.7331238	0.08
329.0079956	0.32
356.9448547	0.21
358.8271179	0.26
374.7452698	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.1484
Annotation	Methyl di-alpha-L-rhamnoside
Peak:m/z	Relative Intensity
98.5911179	0.11
102.8435135	0.24
116.2708130	0.05
118.9331055	0.16
126.9233246	1.57
127.9881668	0.10
131.1854248	0.23
139.1256104	0.19
144.8849792	2.02
145.7730713	0.02
149.0953674	0.66
151.2483521	0.15
153.1284790	0.06
157.2258606	0.06
163.0077209	12.55
168.1855164	0.24
177.0154724	0.13
183.1234283	0.07
185.1051025	0.14
189.1993561	0.09
191.4483337	0.33
193.8506470	0.16
196.1828003	0.03
205.0451355	0.12
207.0271301	0.31
209.0045776	0.08
209.7615356	0.10
211.9754639	1.86
213.1589661	2.87
220.0296936	0.06
223.2335205	0.19
225.3268738	0.31
226.3165283	0.17
235.1319275	0.36
239.0474243	6.64
240.3794250	0.12
241.1145325	0.12
242.0245056	0.15
247.3468323	0.20
249.1042480	0.14
251.1447144	0.15
254.4312134	0.17
256.8433838	0.51
259.1907959	0.19
264.9042358	0.17
266.7643738	0.27
268.1566772	32.00
269.1290894	100.00
269.9452820	0.14
273.1611328	0.19
276.1229858	0.20
276.9853821	0.06
278.8468018	0.23
279.9593506	0.49
280.7014465	0.05
282.8321533	5.00
283.4908142	0.22
284.1105652	1.19
286.9548950	0.18
289.1156921	0.13
290.2218628	0.06
297.1569214	0.87
301.8126526	0.40
305.1513062	5.20
306.3516541	0.06
307.1658325	2.31
308.2788391	0.44
309.4169617	0.51
315.4680176	0.14
317.3117981	0.12
324.4616699	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	511.2527
Annotation	Parvifoliside
Peak:m/z	Relative Intensity
145.0583954	0.42
153.0571442	0.08
157.0135040	0.22
161.1385193	0.17
162.9992981	0.09
164.3499756	0.15
165.0933228	0.15
169.1553192	0.25
170.8668823	0.09
173.0736084	0.25
176.8663483	0.39
179.0740967	0.16
180.8269348	0.32
183.2201843	0.44
185.4896545	0.10
187.2773438	0.25
195.0071869	0.10
197.4576111	0.22
199.1052856	0.13
201.2760010	0.06
205.1111450	0.12
209.2229004	0.81
211.1728210	0.54
213.2481995	0.27
215.2492676	0.14
219.1869354	0.34
223.1676788	0.24
225.1833344	1.04
227.2367401	0.08
229.0549316	0.69
237.2676392	0.12
239.0099182	2.19
239.6159363	0.17
241.2148438	1.82
244.0152740	0.06
249.2999268	0.77
253.0345764	0.09
255.1939697	0.38
257.2185669	1.95
259.4011230	0.21
265.3173523	0.54
267.1372070	8.79
267.9258118	0.05
269.1544800	0.21
270.9078979	0.28
273.1928406	0.12
283.3331299	0.83
285.2480469	11.62
287.4184875	0.18
295.2445068	1.60
297.1781616	0.28
301.1390991	1.66
303.2828979	1.97
313.2661743	88.35
315.1857910	0.81
325.1353149	0.31
331.2356567	100.00
343.3549194	0.26
349.2156372	15.02
355.3641357	0.36
357.3220825	0.49
363.2553101	0.07
365.4102173	0.15
367.0548706	0.45
369.3338013	0.45
371.1641235	0.59
381.0991211	0.17
389.5744629	0.63
391.4089966	0.11
399.6473389	0.16
408.3516235	0.14
409.1021118	0.17
421.2352905	0.39
439.3610229	0.31
457.3576660	1.61
465.4434204	0.62
467.1175537	0.09
475.2728882	0.33
481.3700562	0.24
492.5812378	0.42
493.2658081	5.10
494.0529175	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.2264
Annotation	Canavalioside
Peak:m/z	Relative Intensity
217.0354919	0.03
243.8371124	0.08
307.2500610	0.20
317.2411499	0.11
337.1851196	0.03
359.6087036	0.10
365.3764648	0.11
367.2504883	0.17
379.3001709	0.36
391.0619507	0.11
401.2094727	0.57
419.7582397	0.05
421.2518921	0.04
435.2392578	0.09
443.2637939	0.11
444.9227295	0.08
447.3120117	0.08
455.4683228	0.03
460.1953125	0.08
465.4763184	0.06
469.4675903	0.10
472.3209839	0.15
497.2994995	0.11
498.6051636	0.13
501.6110229	0.23
503.4589233	0.12
517.3460083	0.46
518.9461060	0.04
519.8584595	0.10
525.4238892	0.06
527.3233643	100.00
545.3688965	0.14
546.5786133	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	761.2866
Annotation	Patellamide C
Peak:m/z	Relative Intensity
225.1756592	0.07
231.0374756	0.11
249.1080933	2.41
264.3238831	0.07
329.2395630	0.31
335.2891235	0.05
353.3491821	0.34
358.4188232	0.05
365.2182007	0.35
371.1519775	77.43
373.2366333	0.27
375.0187988	0.09
389.1994019	100.00
390.1392822	0.57
397.4815063	0.38
419.3571777	0.29
421.8793335	0.20
451.2108765	0.26
457.1508789	0.07
481.5967407	0.20
484.1400757	0.08
520.4167480	0.20
531.2089233	0.12
536.2383423	0.12
553.3217163	0.22
563.4157104	0.17
564.1969604	0.08
568.3453979	0.73
580.6380615	0.13
581.3970947	0.10
589.0442505	0.38
595.5813599	0.08
597.5396118	0.05
599.4318848	0.90
612.4111328	0.07
613.6259155	0.07
667.2297363	0.07
674.5298462	0.09
686.4935913	0.12
698.9546509	0.29
712.3770142	0.30
713.9685059	0.18
717.2527466	0.59
730.5985718	0.07
738.7954712	0.13
742.5299683	0.58
743.3248291	1.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	336.3255
Annotation	Pipericine
Peak:m/z	Relative Intensity
97.1140747	0.45
98.1481705	0.08
98.9062195	0.28
100.0306931	0.60
101.1289978	0.11
104.9192200	0.35
106.9774475	2.47
109.0800323	2.03
110.8472061	0.26
112.1371384	0.08
113.0697021	0.22
114.0587769	1.98
116.7703094	0.16
118.9951630	0.87
120.9242172	2.17
123.0432739	0.81
125.0441132	1.43
126.7992477	0.07
128.0877991	1.27
133.0708771	1.12
135.0573425	4.00
137.0759277	2.09
139.0082703	0.56
142.0848541	1.17
144.8223572	0.18
147.0153503	0.64
149.0213623	2.30
150.9183044	1.38
153.1659088	1.08
154.2089539	0.12
156.0116119	3.41
157.2388000	0.15
158.9642944	0.31
161.1080933	1.01
163.1047974	1.56
164.9521027	1.03
167.0192261	0.51
167.9831238	0.75
169.0627594	0.27
170.1137085	2.37
173.2456970	0.07
175.2138672	2.18
177.1497803	2.81
178.9398499	1.95
181.1238403	1.04
182.0852051	1.10
184.1281738	2.60
189.0395203	1.86
191.1181335	1.92
193.2138824	2.00
194.4677429	0.29
195.3328247	0.49
196.2177734	1.58
198.1214294	4.40
199.0530396	0.08
203.1077423	1.38
205.1134644	3.67
207.0730286	2.74
208.1651306	0.04
209.2068481	0.88
210.1885681	3.71
211.1003723	0.53
212.2351685	4.63
215.1835022	0.43
217.1383972	1.67
219.1958618	1.31
221.1473694	2.64
222.0459595	0.15
223.1814880	1.15
224.2153931	3.12
226.1916199	6.35
231.2129211	1.26
233.2395935	0.31
235.1332703	1.06
237.6134949	1.38
238.4067383	1.63
239.6147156	0.96
240.2775574	5.89
244.9974976	0.42
245.6138306	0.34
247.1211243	0.08
249.1400146	1.76
250.3490906	0.33
251.1601868	0.09
252.2089233	2.73
254.2854614	4.10
259.3931580	0.16
261.1519775	0.36
263.2316589	0.27
265.0704346	0.14
266.2605591	4.57
267.0484619	0.15
268.1870117	0.18
269.0659180	0.94
273.1117249	0.49
274.1096191	0.17
275.1201172	0.56
275.9564209	0.12
277.3033447	1.32
278.3851013	0.14
280.2617493	3.73
282.2598267	0.51
287.0926819	0.75
290.2636108	0.11
294.2994995	0.58
301.3339844	36.44
304.9909058	0.87
308.3131714	0.32
309.5652161	0.22
319.2808533	100.00
319.9265442	0.52
337.4042358	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	390.1748
Annotation	Syringin
Peak:m/z	Relative Intensity
114.9201279	0.45
119.1386261	0.13
130.8964996	0.05
132.9894714	4.28
142.9309692	0.12
144.2552795	0.13
148.9317627	0.17
150.8594055	0.07
153.2767029	0.06
154.2099304	0.04
160.9723511	18.81
162.1753845	0.16
167.1763916	0.24
180.0048523	1.49
192.9809723	100.00
194.0831909	0.21
195.1263885	0.18
196.8643036	0.17
203.0086670	0.05
203.6352997	0.13
211.0639191	5.40
214.0186462	0.10
227.1726685	0.06
228.2087708	0.64
239.1860657	0.14
245.7879028	0.06
251.1318359	0.24
254.7516479	0.29
255.8030090	0.11
258.9781189	0.18
265.7056580	0.06
267.8111267	0.06
269.0991516	0.24
273.3164978	0.07
280.2850647	0.12
283.0474243	0.06
284.2329102	0.06
294.0751953	0.10
300.1600952	0.19
313.8622437	0.03
316.0347290	0.10
317.1675110	0.21
318.1417847	0.06
322.1408386	0.28
323.6154785	0.07
325.1257935	0.16
326.0196838	0.04
328.2503967	0.28
329.9425659	0.69
332.8319702	0.02
333.6781311	0.24
335.5462341	0.22
342.0606079	0.31
344.1400757	0.11
347.4283447	0.06
348.9183350	0.36
354.3107605	0.09
358.3783875	0.08
359.2306824	0.33
362.1524963	0.16
363.4262390	0.13
372.1018066	3.91
373.0090637	2.74
375.1336365	0.09
380.6899719	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	497.2754
Annotation	Virescenoside N
Peak:m/z	Relative Intensity
142.8558960	0.07
158.9325867	0.04
160.9495697	0.04
179.0150146	0.06
199.1809998	0.03
267.1035767	0.04
271.1168213	0.13
288.9484863	0.04
317.2631226	21.65
318.5166016	0.51
323.3257751	0.07
333.4918518	0.21
335.2528687	100.00
336.3377380	1.17
351.0651855	0.04
375.4892578	0.08
377.2750549	0.10
383.2145081	0.04
393.4260864	0.02
394.9874268	0.04
405.5498047	0.08
407.1922302	0.04
419.5564270	0.02
437.5395813	0.04
451.3272095	0.07
453.4650879	0.07
461.2540894	0.24
462.1964417	0.09
479.2448120	0.66
480.2189026	0.04
482.6909790	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	591.2658
Annotation	Canavalioside
Peak:m/z	Relative Intensity
173.7667236	0.05
193.1467896	0.04
205.2138367	0.04
222.6284943	0.04
269.0515137	0.02
276.8005676	0.01
315.0115662	0.11
319.3451538	0.01
323.3721924	0.02
341.3914795	0.05
345.0795288	0.02
352.9928589	0.02
359.4374390	0.01
365.4956665	0.03
369.4843750	0.02
373.1513062	0.04
380.4310913	0.03
383.4147949	0.07
395.3330688	0.07
403.5459595	0.04
411.4033203	0.28
421.2634277	0.06
427.1914673	0.19
429.1508789	0.28
438.9826660	0.09
443.0494385	0.02
449.3555908	0.02
453.3803101	0.12
455.0640259	0.03
463.3691406	0.03
465.3213501	0.04
475.3577881	0.03
476.1488647	0.03
485.2871704	0.05
501.1968384	0.14
503.4663696	0.03
515.4210815	0.33
526.2014771	0.05
527.4793091	0.53
528.3369141	0.61
541.6071167	0.06
545.3119507	100.00
545.9264526	0.31
547.3140259	0.08
553.2748413	0.06
555.3866577	0.09
561.0306396	0.03
571.2828979	0.07
572.5843506	0.26
573.3894653	0.25
582.2544556	0.01
591.0856323	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	666.3219
Annotation	Unknow
Peak:m/z	Relative Intensity
195.0463867	0.07
245.4102783	0.07
258.3357849	0.05
279.0074158	0.08
280.1907959	0.18
283.8814087	0.07
302.1049805	0.78
330.1877136	0.07
331.2962036	0.07
360.3343506	0.07
366.2427979	0.03
376.4806519	0.03
403.0256958	0.08
417.2125854	0.03
424.2744141	0.05
437.5421753	0.15
438.4260864	0.17
441.3989258	0.02
443.3659058	0.11
452.3867798	0.06
468.2728882	0.54
472.1249390	0.21
476.1868286	0.04
486.3486328	0.19
494.3629761	0.04
504.4006348	0.20
505.3371582	0.02
519.6026001	0.17
520.4288940	0.02
530.9207764	0.10
535.6382446	0.23
537.3967896	0.20
549.2963867	0.21
556.4099121	0.07
558.1437378	0.04
558.8881226	0.15
562.3860474	0.05
577.7510986	0.04
581.4067383	0.19
582.4079590	0.49
584.1657104	0.04
586.5744019	0.44
589.5176392	0.15
595.2268677	0.27
600.3774414	0.16
604.4609985	4.42
605.0971680	0.08
612.3564453	0.29
620.4422607	0.13
622.3952026	0.31
630.3819580	2.66
632.6804199	0.05
648.3594360	100.00
649.0211182	0.43
651.4813232	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	490.1749
Annotation	Unknow
Peak:m/z	Relative Intensity
147.9240417	100.00
246.7377625	0.10
271.2644043	0.15
310.0691223	0.46
327.9895630	0.34
342.8859253	0.65
344.0059814	0.18
375.4649353	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	321.0827
Annotation	Lepidimoic acid
Peak:m/z	Relative Intensity
94.7578888	0.05
102.9845276	0.91
115.0914993	0.08
131.0433807	0.03
145.4019165	0.02
156.9551392	0.99
175.0413208	36.88
199.1535797	0.10
200.9377136	0.03
212.9687500	0.13
216.0746460	0.05
217.1257019	1.97
231.2344971	0.07
243.0899963	0.13
248.9543457	0.09
258.4011230	0.16
259.0065002	0.31
260.9244080	0.08
303.0179138	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.1239
Annotation	8-Hydroxy-3'',4''-dihydrocapnolactone-2',3'-diol
Peak:m/z	Relative Intensity
112.9595108	0.49
121.0677948	0.05
130.8729248	0.20
157.0858765	1.22
158.8254089	0.14
180.9793091	0.05
199.3025360	0.04
201.0451660	14.64
203.2183838	0.08
217.0688782	0.54
221.0862427	1.75
225.2513733	0.43
227.0929871	22.81
228.2108154	0.16
229.0005493	0.11
231.2429504	0.12
241.3215942	0.07
245.0686646	39.55
246.3062439	0.17
253.2351074	4.08
269.0342102	0.13
271.2006226	28.24
272.1552734	0.13
275.0980835	0.04
287.3776855	0.45
289.2003784	5.33
297.0679321	4.77
315.2318726	83.63
316.3294067	0.57
319.0927124	0.76
331.1889038	0.08
333.2371216	8.56
341.1807861	0.83
359.1481934	100.00
360.2695618	0.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	349.2
Annotation	Armexin
Peak:m/z	Relative Intensity
107.1779327	0.22
109.0439377	0.10
118.9622345	0.22
123.0634766	3.64
127.2237167	0.18
134.9824982	0.45
137.1263123	0.27
139.2828217	0.12
141.0758972	0.16
141.9844971	0.06
142.8208618	0.04
145.1336975	0.06
150.7400513	0.14
153.9220123	0.05
157.0373840	0.13
159.1401978	0.22
161.1080933	0.14
163.0117798	0.07
164.4918823	0.05
168.9622040	1.93
175.2026672	0.32
182.5273590	0.50
185.1954956	0.41
186.8791809	0.11
189.2169647	0.10
191.1601105	0.30
193.1046295	0.22
197.1511536	0.31
201.0475159	0.19
207.0910645	8.62
209.1229095	1.09
211.1887512	0.64
212.0627441	0.04
215.1934814	0.34
217.1566162	0.07
217.9483032	0.35
219.1555176	0.31
221.2579956	0.22
227.1562500	0.37
229.1454773	1.09
231.2727661	0.27
231.9263306	0.67
233.2549133	0.13
235.3423157	0.20
237.2097778	0.11
239.2745667	0.68
241.2396545	0.92
245.1707153	0.74
249.1495972	0.78
253.3597717	0.16
255.3850708	0.09
257.2431641	2.94
261.2068787	1.38
262.9756470	0.22
267.1593628	1.32
268.1387939	0.55
269.4980164	0.05
271.2394104	0.07
271.9658203	0.06
272.9608765	0.95
275.1903076	1.22
277.4057922	0.17
282.3812256	0.14
283.1338806	0.09
285.1444397	15.96
287.1162415	0.50
291.1551208	0.34
292.2930298	0.17
295.2093506	1.82
298.8624268	0.15
300.1153870	0.66
301.1207275	0.12
303.0644226	34.39
303.6669617	0.09
305.3756104	0.80
308.0348511	0.28
310.0974731	0.06
313.2019653	12.81
314.0719299	0.17
317.1310120	0.30
318.2327576	0.20
319.3121948	0.18
321.3707886	0.42
322.3420715	0.80
325.6927795	0.17
329.2249451	0.14
331.0701599	100.00
332.0956116	2.60
334.1646423	0.10
337.8308411	0.09
340.1946411	0.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	475.1823
Annotation	Kanokoside A
Peak:m/z	Relative Intensity
143.0732727	0.05
145.1595154	0.24
160.9628601	0.23
162.9268951	7.62
168.8566437	0.05
204.9480896	0.18
206.8999176	0.08
233.1816254	0.12
234.0157776	0.73
234.8407593	2.76
258.5452576	0.06
264.0487366	0.81
264.8889771	4.74
277.0519409	0.04
289.1593933	0.14
295.2935486	0.20
307.1639099	1.34
313.0546265	0.06
324.3209839	0.64
325.0610657	4.18
337.3848267	0.04
387.7377319	0.21
413.6312866	0.10
429.0925903	100.00
429.7505188	0.17
431.2203979	0.23
439.0760498	0.05
447.2792053	0.06
457.1388245	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	571.2395
Annotation	gibberellin A2 O-beta-D-glucoside
Peak:m/z	Relative Intensity
160.9285278	0.05
178.0858765	0.02
179.2277679	0.13
183.0253601	0.08
229.2889099	0.02
255.1105652	0.13
293.0775146	0.12
297.2864990	0.11
328.7131348	0.07
335.2897339	1.35
341.2202148	0.19
346.7648926	0.05
363.0962524	0.14
365.2207031	0.60
381.1687622	0.06
393.3510132	0.15
407.2065430	0.15
409.4932861	0.03
411.0261230	0.14
414.9609985	0.06
437.1537476	0.02
441.1968994	0.12
442.4487915	0.10
443.3568115	0.08
449.1110840	0.13
463.0618286	0.02
469.2993164	0.06
472.1053467	0.09
475.2309570	0.03
477.2838745	0.11
483.4803467	0.17
485.2780151	0.12
486.3378906	0.13
487.4984131	0.02
497.2424316	10.28
498.7424927	0.05
513.2368774	0.05
516.1968994	0.33
517.7258911	0.20
527.2626343	100.00
528.3915405	0.08
529.3143921	0.66
537.3269043	0.08
540.0571289	0.15
553.4705811	0.09
555.2213135	0.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.9393
Annotation	Unknow
Peak:m/z	Relative Intensity
114.7439117	0.02
159.0626526	0.50
228.9790649	0.17
245.7909241	0.02
271.2058716	0.09
272.9556885	100.00
312.9933167	0.11
314.9622498	0.23
341.2627563	0.04
360.2337952	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	511.2184
Annotation	gibberellin A2 O-beta-D-glucoside
Peak:m/z	Relative Intensity
178.6329651	0.10
187.0937500	0.25
199.1099091	0.47
201.2017822	1.31
225.3054810	0.43
237.4145966	0.25
243.2260895	10.21
265.3743286	0.12
269.0010986	0.27
269.6933899	0.08
275.3461914	0.33
283.3129272	1.92
285.2991943	0.25
287.2639160	12.76
289.5418701	0.13
301.2523804	8.38
303.2994995	2.93
304.2996826	3.00
305.3621826	1.97
311.3632202	0.39
312.0524292	0.31
313.3163452	0.26
319.2192993	1.14
323.0234375	0.15
327.1482544	0.73
329.3922729	0.32
331.2384644	94.60
332.1654053	0.29
339.1548462	0.46
345.1902466	25.10
349.2218628	100.00
350.4345093	0.77
355.0172119	0.25
357.1568604	0.40
362.9494629	0.30
367.2853394	0.51
373.1774902	14.82
390.7286377	1.19
391.3752441	25.12
403.0375366	1.60
410.6190186	0.36
417.4772949	1.15
421.4167480	1.31
423.3516235	0.25
427.4498901	0.63
433.3597412	1.01
451.3059692	6.69
465.4179077	0.98
466.5523682	0.45
467.3794556	14.77
468.4878540	0.21
474.0016479	0.65
481.3943481	0.14
491.3344116	0.19
493.2523804	12.79
494.0353394	0.58
494.6990967	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.2132
Annotation	Ajugamarin C1
Peak:m/z	Relative Intensity
142.7276306	0.05
160.4418335	0.22
161.0991211	0.20
176.1186523	0.06
193.1594238	0.50
195.0733032	0.03
208.0618439	0.10
211.2477722	0.04
220.9583130	0.06
223.0613403	100.00
223.6764832	0.33
225.1604309	0.18
228.2109985	0.09
237.2539062	0.34
237.9290161	0.10
239.3004913	0.36
240.7729340	2.72
241.4252777	0.02
255.1106873	0.10
259.1689453	0.29
267.0734253	4.26
270.8258667	0.09
276.2516479	0.04
278.9270020	0.06
285.0538635	3.30
289.0765686	0.14
290.1821289	0.08
299.1649170	0.07
301.0377808	0.41
302.0563049	0.18
303.0703125	0.59
313.4711914	0.35
315.0867920	0.15
329.0088501	0.13
332.2312927	0.18
342.7645569	0.06
360.0603027	0.04
361.1860352	0.15
362.2426147	0.08
364.0451050	0.08
375.3609924	0.13
378.1170349	0.09
381.5233154	0.10
385.1906738	0.09
393.3949890	0.30
403.4961548	0.21
407.1831970	0.25
419.3431091	0.93
421.4129944	0.62
427.3096008	0.10
428.1380310	0.03
429.3710632	0.09
430.1560364	0.38
442.8984680	0.43
445.1140442	0.07
447.3365173	0.18
448.1941223	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	381.1534
Annotation	Trichogoniolide
Peak:m/z	Relative Intensity
147.0142670	0.37
150.9042358	0.26
167.2126770	0.16
172.2548523	0.35
176.9519043	0.14
183.1884155	0.22
185.3475189	0.24
195.3147125	0.64
197.2108154	0.38
199.9937134	0.52
205.0188599	0.30
208.1453552	0.07
209.0632935	0.31
223.4159851	0.17
233.1964111	0.22
234.0587158	0.21
234.8891602	0.72
237.3037720	0.47
249.3415527	0.69
252.0483398	0.11
255.0278320	0.19
261.2103577	0.26
269.0500183	0.27
271.4219971	0.31
273.1876221	0.24
276.0625916	0.70
277.3872986	0.23
281.1129150	0.79
287.3291931	0.47
289.2380371	0.73
291.5910645	1.04
293.1764526	0.29
298.2544250	0.08
299.4740601	0.23
300.1389465	0.45
301.0316162	0.28
306.1161194	0.76
311.2328186	0.66
315.1311035	0.85
317.0189209	1.12
321.2098999	0.40
327.2858887	0.55
328.0245667	0.13
331.4768066	1.91
335.0137939	4.14
336.1408081	0.25
337.0966492	1.85
339.4383545	0.20
345.1489868	16.77
349.3705139	0.42
350.0622253	0.21
351.1018677	0.11
353.2247925	0.47
363.0661926	100.00
363.9060364	0.46
365.2451172	0.24
371.7482605	2.05
381.1052551	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	489.1823
Annotation	Unknow
Peak:m/z	Relative Intensity
146.0757904	0.09
147.1298065	0.05
153.1413574	0.10
155.1982269	0.05
171.0836334	0.56
173.0224457	0.46
191.0024414	100.00
193.1693115	0.12
221.2530518	0.05
259.0424500	0.02
262.3542480	0.04
289.4778748	0.05
297.0766602	0.06
327.2484741	0.05
341.3654175	0.02
342.1766968	0.04
352.0625000	0.03
357.1008301	0.08
370.8747559	0.02
429.2542725	0.16
441.1284180	0.02
454.3745728	0.02
471.3246155	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	511.2553
Annotation	Cuniloside
Peak:m/z	Relative Intensity
143.0383759	0.41
158.9970398	1.39
160.9264526	12.63
178.9991608	6.79
223.1345673	6.45
224.3611450	1.01
225.1351929	0.94
226.2814941	0.94
242.5696564	0.23
243.1984253	0.79
245.0497894	0.81
286.2461548	0.18
287.4891357	0.74
303.4739380	1.12
305.4656372	0.39
329.1602173	0.40
330.1884766	0.40
331.2484741	4.19
347.4098511	0.56
349.3236084	100.00
367.1486206	0.29
381.3258667	2.95
382.3292236	11.65
385.1803589	0.33
408.8916016	3.58
414.2247314	0.77
431.4238892	0.47
437.2018433	1.10
464.9953613	0.27
467.1406250	7.85
468.0144653	0.30
481.4002075	2.64
490.9629517	0.64
493.6212769	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.2029
Annotation	3-[4-[1-(4-Hydroxy-3-methoxyphenyl)-1,3-dihydroxyisopropoxy]-2-hydroxyphenyl]propyl alpha-L-rhamnopyranoside
Peak:m/z	Relative Intensity
158.9633636	0.05
161.0046844	0.06
173.0401306	0.10
179.0238342	0.11
191.1419067	0.06
197.1941528	0.08
211.1900482	0.04
221.1071625	0.03
223.0503235	0.08
225.5366516	0.03
229.4068146	0.04
239.2030945	0.26
240.1520386	0.02
241.2091064	1.51
257.1647949	0.13
259.2034607	0.29
265.2510986	0.04
267.2230225	1.08
269.3963013	0.06
281.3203735	0.22
283.3382568	0.23
285.2080078	5.13
287.5596313	0.01
301.1268921	0.16
302.1966553	0.09
303.2437134	1.94
311.1148682	0.05
319.0647583	0.18
327.1528320	0.66
329.1967773	5.78
330.2929688	0.07
345.4852295	0.24
347.2628174	100.00
348.4691772	0.12
359.3876343	0.19
361.3850098	0.36
363.3237305	0.09
371.3320312	0.18
389.2352905	25.48
401.0341187	0.10
417.5320435	0.05
419.2017212	2.43
421.2850342	0.75
423.3256226	0.07
429.3814697	0.11
431.1989746	0.18
445.2116089	0.09
449.2222900	14.68
449.8481445	0.03
463.1631470	0.17
465.2445068	0.47
471.5442505	0.17
473.2066040	0.13
479.0226440	0.03
479.7028198	0.06
481.2161865	0.06
491.3355103	1.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	638.68
Annotation	Unknow
Peak:m/z	Relative Intensity
290.3192749	0.13
300.0969849	0.08
302.8651123	0.25
308.8365479	0.28
340.0433350	0.12
385.9839478	0.15
386.8408813	1.89
403.3488770	0.07
405.4523926	0.04
417.0383301	0.24
418.0401611	0.17
425.9757080	0.22
431.1246948	0.32
437.9025879	0.08
440.2154541	0.26
441.1957397	0.17
447.6298218	0.07
458.1535034	0.11
464.0028076	2.16
464.9713135	1.49
468.7190552	0.10
470.6286621	34.02
471.3741455	0.32
482.9597778	3.00
483.7139893	0.14
502.8858643	0.53
539.0571899	0.42
540.2291870	0.36
549.0129395	0.36
552.1044922	4.58
553.7532349	13.03
554.5347290	100.00
555.6709595	0.04
564.3016357	0.28
594.4078979	0.08
604.0328979	0.30
620.9784546	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.09
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
80.85951233	1.04
83.01631927	0.24
84.82419586	0.24
90.89749146	0.43
92.87792969	0.33
95.06446838	1.47
97.06695557	0.71
98.77888489	0.84
103.0202942	0.26
105.0626984	0.46
106.9855957	1.07
109.0276642	1.73
110.9073639	0.15
113.0218506	0.47
114.8996429	0.59
118.974762	2.85
121.0900879	1.23
122.9938049	1.35
123.9082336	0.48
124.9842377	0.22
126.9952087	1.92
127.7433777	0.13
128.933609	4.22
129.9979858	1.10
131.0645294	0.83
132.8735962	1.45
135.1955872	2.09
139.0640259	0.46
141.0931396	2.46
143.1898651	0.28
145.0753479	1.08
147.0408783	2.25
149.0428314	0.69
150.9556885	50.20
152.1013336	1.40
152.9000397	0.76
154.9244385	0.16
157.0143433	0.48
159.1619415	0.43
161.0517426	1.75
163.0726166	0.52
165.0293274	1.16
166.0011749	1.00
167.1031342	1.88
169.0462799	1.65
171.0185852	1.22
175.0653992	3.08
176.9028625	0.47
178.1057892	0.46
178.9714966	1.62
181.2611847	0.23
183.0778198	1.29
185.1555481	1.85
189.0887451	0.48
190.9558563	2.13
193.1484375	1.28
194.5992889	2.06
195.2169189	2.87
197.0432892	7.12
197.8005524	0.26
199.1862946	0.85
200.9835052	0.57
207.066391	0.93
208.2420959	0.47
209.030777	0.69
210.1421967	1.34
211.2073059	1.26
212.1962738	1.01
217.1628876	14.01
223.0288391	0.16
225.0630951	12.45
226.0397339	0.90
231.9812775	0.71
235.1856537	21.45
238.020462	5.90
239.3054962	0.32
253.090683	100.00
254.0621948	16.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.1976
Annotation	Abelioside A
Peak:m/z	Relative Intensity
155.0876312	0.06
156.9333191	0.03
201.0646515	0.45
213.2634430	0.08
229.3069458	0.05
245.3416595	0.06
257.2711792	0.68
271.2583618	0.08
275.2333374	0.35
301.3143311	1.01
317.1964111	0.03
319.2539062	1.51
333.0358887	0.09
345.1630859	2.90
363.1490479	100.00
363.8270874	0.38
377.1961670	0.66
387.2042847	0.04
405.2301025	22.34
417.1804810	0.06
419.4055176	0.26
435.1726074	6.66
447.3870850	0.26
459.1634521	0.04
463.4183350	0.10
465.2840576	36.82
489.3831177	0.06
507.3257446	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.1497
Annotation	4-[4-Hydroxy-6-hydroperoxy-7,9-dehydro-6,7-dihydrogeranyloxy]-5-methylcoumarin
Peak:m/z	Relative Intensity
105.9296112	0.08
108.9075165	0.14
121.0354233	1.39
128.9626770	0.23
133.1062317	0.11
140.9260864	0.10
147.2551727	0.18
153.1076050	0.06
159.1246185	0.07
170.9948578	0.24
173.0917053	0.75
174.9379578	0.26
177.1233215	0.37
178.8286285	0.49
181.3341064	0.25
185.0087585	0.39
189.1027222	0.09
189.9862976	0.13
201.2239990	2.48
203.1572266	0.37
211.3521729	0.54
213.1177063	1.85
214.2158203	0.08
215.3140259	0.34
218.1655884	0.09
222.9711609	0.07
225.3009644	0.15
227.1562500	1.32
228.2929993	0.11
229.1298218	0.66
231.4566345	0.06
233.3627014	0.33
238.1675720	0.11
241.1427612	1.10
243.1526489	0.24
245.2799683	0.41
246.0856323	0.05
253.2369080	3.79
255.1769714	0.28
258.9132996	0.09
263.3535461	0.15
267.0960388	0.12
269.2091064	4.17
271.2233582	100.00
272.1160583	1.95
275.2046509	0.15
279.2233887	0.31
285.3161011	0.44
287.1270752	2.31
288.2092285	0.70
293.3035889	0.05
294.9876404	0.61
297.1393127	12.96
298.3057861	0.93
305.3394775	0.22
313.1204529	1.56
315.2780151	43.61
316.3754883	0.36
321.1998901	0.18
322.1066589	0.50
323.2376709	1.50
324.1198425	0.22
327.3003845	0.07
331.3585205	0.18
341.2746277	28.84
342.2783508	0.76
343.3161316	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
96.97360229	0.12
104.9954224	0.13
125.0904999	0.06
143.14888	0.12
145.9690399	0.08
147.0744781	0.12
149.0748138	1.04
177.1139984	0.25
179.3119354	0.60
181.017807	0.08
193.1812439	0.18
194.9836884	0.33
207.1629944	2.41
208.1063995	2.01
208.9827728	0.39
221.9642487	1.21
223.0300598	2.44
224.1067047	1.20
233.2579193	0.19
251.065567	100.00
252.1906738	18.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	573.2553
Annotation	Canavalioside
Peak:m/z	Relative Intensity
179.1096802	0.04
199.2390442	0.01
315.2517395	0.04
321.3487549	0.01
325.4624023	0.01
330.9949341	0.01
333.0600586	0.05
335.3900146	0.06
359.2444458	0.02
363.3612061	0.07
364.4957886	0.08
365.2616577	0.43
375.3380127	0.06
383.2793579	0.02
391.1204834	0.01
395.3802490	0.02
396.4154663	0.01
407.3561401	0.01
415.0442505	0.02
439.1763306	0.09
441.4641113	0.02
442.3940430	0.03
451.2965698	0.02
452.1450195	0.08
455.2484741	0.01
457.5670776	0.01
465.4049683	0.01
474.4378052	0.02
477.0193481	0.04
479.2798462	0.34
485.6304932	0.02
487.6842651	0.03
495.4685059	0.01
497.3618774	30.90
498.7385864	0.04
509.4839478	0.08
527.2009888	100.00
528.1394653	0.02
529.5729370	0.05
535.4231567	0.08
537.4647827	0.03
541.3965454	0.03
550.4468994	0.09
553.3307495	0.16
554.2438965	0.01
555.3610229	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.11
Annotation	D-Fructofuranose 1,2':2,3'-dianhydride
Peak:m/z	Relative Intensity
84.7620850	0.05
96.9589233	1.27
108.9300385	0.65
112.5516052	0.09
115.0723572	0.08
118.9036713	0.17
126.9387131	1.90
133.0160675	0.36
134.0011292	0.04
144.8664856	2.56
149.1143646	0.06
150.1684265	0.29
151.2405396	0.04
155.9804077	0.10
161.4140625	0.05
162.8677063	7.27
167.0586243	0.12
170.8375854	0.15
179.4577179	0.08
181.1296692	0.09
184.2423706	0.18
184.9433441	0.21
195.9272919	0.15
199.3131104	0.13
203.2143860	0.25
205.1101990	0.08
207.1209106	0.24
212.0458679	1.97
213.1054688	3.29
216.9390259	0.06
222.8244019	0.64
229.2036438	0.18
235.1440735	0.07
237.1525269	0.43
240.2046204	0.27
241.1833801	0.74
244.2118835	3.83
245.0079041	0.06
246.2783813	0.44
247.0819702	0.33
252.8287964	1.56
254.5645752	0.15
258.7301941	1.90
259.4329224	0.09
264.7072754	0.62
268.0894165	40.60
269.2341003	100.00
270.9685669	3.06
276.2572021	0.29
276.9170227	0.26
278.2357483	0.26
279.0912781	0.22
279.9925232	0.46
283.2960510	0.62
284.1497192	0.31
287.1264343	1.02
288.9288330	10.76
296.3246155	0.11
305.4650574	0.07
307.0556030	2.87
307.9576111	0.06
309.1546631	0.14
310.3415527	0.04
312.7762451	0.22
324.9524536	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	667.3519
Annotation	Unknow
Peak:m/z	Relative Intensity
204.8749084	0.08
301.1869202	0.34
304.1691284	0.09
332.4622803	0.09
399.2198486	0.07
415.7015381	0.38
425.3402100	0.13
427.4030762	1.01
428.4426270	0.96
442.1968994	0.61
453.0226440	0.35
466.4151001	4.37
468.5081787	5.69
470.4998169	0.72
487.5856934	0.51
500.3191528	0.12
504.2329102	0.26
510.7375488	0.29
512.3883667	100.00
513.0427856	0.47
514.3746338	0.47
520.1019897	0.27
547.2282715	0.28
562.2407227	0.12
564.4181519	3.39
579.4055786	66.64
581.4838257	25.69
586.5894165	0.62
588.6203003	0.14
605.6678467	0.26
606.3789062	1.37
607.4430542	3.74
608.2687378	1.25
616.8224487	0.32
623.4148560	53.03
624.1656494	0.04
630.9364624	0.12
649.1876221	3.83
650.1277466	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	349.2
Annotation	Gelomulide X
Peak:m/z	Relative Intensity
104.9230347	0.61
107.1527100	0.44
109.0883789	0.09
115.9516983	0.05
116.8817978	0.11
119.0007858	0.34
120.9588623	0.63
122.9378281	0.14
129.7547150	0.06
131.0927429	2.06
133.0280151	0.15
134.9924927	3.93
137.1393433	0.39
138.9923401	0.26
140.8930969	0.08
143.0942535	0.10
145.0754852	0.18
147.0494232	0.39
148.9818115	0.91
150.9120026	0.72
152.9547577	0.42
157.0347900	0.29
159.0731506	0.88
161.0314026	0.46
163.0293579	0.10
165.0786438	0.65
166.7473450	0.27
169.0630798	0.86
171.2585602	0.09
175.2380981	0.06
177.0465698	0.08
179.2152710	0.19
181.0786438	1.12
182.9507446	0.33
184.8255005	0.12
186.7995300	0.23
189.2745667	0.06
191.0717316	0.15
193.0631256	1.00
195.1631775	0.14
197.1392059	1.16
199.2281189	0.23
201.0266266	0.39
203.1468811	0.17
205.0501099	0.26
207.1050720	0.63
209.1317444	0.94
211.0431824	0.93
213.2091980	0.41
214.8719177	0.14
215.5195007	0.09
217.1804504	0.03
219.0438232	0.34
221.0914001	0.28
223.1357117	0.15
225.0886841	0.38
227.1407166	0.16
229.1178894	0.82
233.0839233	0.16
235.0281982	0.26
237.2407227	0.32
239.1702881	3.58
241.1675110	0.66
243.2031250	0.19
244.9113770	0.09
247.0172424	0.16
249.1815491	2.21
251.3398743	0.67
253.0324402	0.17
255.3091736	0.64
257.2471008	3.33
259.2896118	0.48
261.3052673	0.47
265.0845032	0.30
267.2607422	7.07
269.2073975	1.04
271.1588745	0.50
273.2773743	0.79
275.3273926	0.65
277.2613525	0.52
283.2002869	1.18
285.1538391	30.76
286.3643188	0.20
287.1874084	0.23
289.1536255	0.24
295.2463074	4.70
297.6871643	0.13
301.2714233	4.32
303.2348938	35.36
305.2217407	0.21
313.2654724	20.27
317.1838074	0.03
319.1662903	0.38
321.0716553	0.19
329.1163635	0.07
331.1596680	100.00
332.0248718	0.39
349.2904358	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.135
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
165.2772827	0.03
175.2779388	0.24
179.0205383	0.10
183.1603699	0.05
186.1446838	0.07
187.0634155	0.08
187.8274841	0.02
201.2896118	0.05
203.1169891	0.38
205.1557922	0.28
217.3399353	0.06
228.2084808	0.11
229.0836182	0.14
230.0513916	0.09
231.0726013	0.29
239.9801483	0.01
243.0381317	0.25
245.1554718	2.43
246.9277954	0.17
247.5735321	0.03
249.1627197	0.08
253.1665497	0.04
255.1013794	0.09
257.2648926	0.04
259.2274780	0.07
269.0377808	0.92
270.0090332	0.04
271.2832031	0.08
273.1959839	2.10
274.1541748	0.08
277.5247192	0.05
282.0317993	0.08
283.1831665	0.43
285.1081543	0.08
287.1485596	4.30
289.1100464	16.85
291.1373901	0.02
297.2717896	0.03
299.1837769	3.69
301.0625000	0.19
311.2041626	0.19
323.0441284	0.05
326.3133545	0.02
327.1764526	0.14
329.2138062	0.46
330.2132568	0.04
331.2272949	0.43
337.0661011	0.03
339.0353394	0.22
341.2212524	0.08
357.2505493	0.11
361.5299683	0.09
367.3437500	0.05
368.3242798	0.58
377.5718994	0.15
378.2385864	0.02
379.6030273	0.03
381.2091064	1.53
383.2669678	0.03
389.0808716	0.11
393.1121826	0.33
395.2422485	0.04
397.0872803	0.32
401.5821533	0.06
403.3530884	0.17
405.3663330	0.05
407.1188965	59.50
407.9031982	0.19
409.2354126	0.54
410.8793335	0.20
413.1517334	0.16
415.1958618	1.17
423.4891968	0.27
425.1182251	100.00
425.7534180	0.12
427.2692261	0.33
431.2448730	0.04
433.2120972	0.55
439.3404541	0.16
449.1392822	0.39
450.1036987	0.39
451.1234131	23.39
457.0852661	0.05
461.2637329	0.14
467.2742310	0.81
471.4951172	0.12
473.1388550	0.06
479.1112671	0.06
481.0852051	0.86
484.2415771	0.06
487.1644287	0.72
487.8832397	0.04
489.3629761	0.07
497.1148071	0.02
509.3795776	0.05
511.1851196	0.12
514.7321167	0.04
515.3934937	0.19
517.3486328	0.03
530.2595215	0.03
531.2962646	0.60
532.5973511	0.61
533.2991333	1.52
541.3517456	0.23
544.3713989	0.03
546.3746948	0.12
549.3552246	0.05
557.1831665	0.05
558.2062988	0.44
559.1959839	8.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	604.1726
Annotation	Unknow
Peak:m/z	Relative Intensity
183.0222168	0.02
188.0133057	0.12
200.0007324	0.91
202.0867615	7.66
214.0372162	0.13
218.0131226	1.17
219.0160675	0.32
232.2079926	0.19
244.0133057	0.11
262.0014648	100.00
262.9305420	0.20
318.2405090	0.14
365.1887817	0.11
377.3575439	0.04
379.4528198	0.08
398.2141113	0.21
411.2845459	0.07
471.3062134	0.28
472.1652222	0.09
494.3405151	0.06
499.9089966	0.05
514.4376221	0.03
525.0851440	0.04
526.3765259	0.16
542.9436646	0.12
543.9553833	0.37
572.1642456	0.13
573.3339233	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	664.1124
Annotation	NAD
Peak:m/z	Relative Intensity
186.1672668	0.06
214.2374115	0.18
232.1032257	5.92
250.2133026	0.26
276.9469299	0.14
348.0538940	0.72
371.0562744	0.35
389.0693970	0.07
398.5087280	0.20
409.8777466	0.21
427.9998779	3.66
444.2100830	0.98
453.9782104	0.41
472.0055542	0.47
486.3583984	0.05
502.5627441	0.06
517.3804932	0.25
524.0751343	91.86
524.7510376	0.07
528.9052124	0.92
542.0153198	100.00
542.7333984	0.82
574.1113281	0.12
612.2852173	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	328.1738
Annotation	Unknow
Peak:m/z	Relative Intensity
109.0107880	0.13
110.0856171	0.22
131.0465546	0.50
136.1387939	0.40
137.0179291	0.61
145.0071106	0.12
154.0787354	100.00
158.8440247	0.10
173.0759583	3.47
184.0609131	0.10
239.1798706	0.08
260.1048889	0.12
263.8818359	0.05
282.0334167	1.35
293.1319275	0.15
310.1492615	0.62
311.0152283	0.11
314.1156006	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	263.02
Annotation	Demeton-S-methylsulphon
Peak:m/z	Relative Intensity
87.9840775	2.84
97.8412628	0.35
109.0362701	0.13
111.3269806	0.35
115.9410858	7.79
118.0295715	0.08
128.1080475	0.45
130.1252594	0.45
132.6831665	0.34
134.0486603	78.95
142.2914886	0.18
147.1415863	1.40
148.0953369	0.72
153.9611664	0.28
170.0994415	0.53
172.1954498	0.20
182.1275482	0.31
188.2050476	0.34
191.2679291	0.25
199.0343933	0.94
200.0448456	0.62
201.9642181	0.09
203.3100739	0.23
205.9660492	0.24
209.3207550	0.19
211.4293518	0.14
212.7151337	0.09
216.9650574	2.97
221.9510803	0.06
227.0767059	0.83
228.0199432	0.13
232.7751465	1.39
245.0792847	100.00
246.0048828	1.93
253.5195312	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	279.1238
Annotation	Villosin B
Peak:m/z	Relative Intensity
95.9299011	0.10
96.8742981	0.22
99.0472259	0.04
107.2493286	0.04
108.9625397	0.36
110.0254745	0.12
111.0001068	0.83
121.0786438	0.36
123.0323486	1.10
124.1892014	0.27
125.1104813	2.79
126.9817047	0.08
134.9768677	0.26
135.9722595	1.03
137.2922058	0.07
139.0658875	9.86
147.1128235	0.57
149.0993958	0.17
151.0222168	27.71
153.0448151	0.08
161.1939697	0.29
161.9956818	0.04
165.0562897	0.77
166.9598083	0.29
168.1442261	3.25
169.0543823	18.61
171.0872192	0.66
173.0940247	0.57
175.0388489	0.76
176.0728607	0.10
177.1403809	0.28
179.0773773	1.09
180.0717468	0.44
184.2259827	0.44
187.1719513	17.77
189.1324768	0.76
191.1145782	2.60
192.1068878	0.11
193.1331177	0.03
199.0422058	3.61
202.1322937	0.27
202.9925232	0.04
205.1255798	21.52
207.2344971	0.19
215.2582703	1.31
217.0919495	100.00
219.1772156	0.28
220.0892334	0.09
231.1869202	0.14
233.9484558	0.03
235.0758057	20.46
237.1263123	0.03
238.0589600	0.07
243.1517029	0.41
247.1147156	0.11
249.0936890	19.02
251.1237183	0.10
258.8247070	0.32
261.1737061	14.28
264.1803589	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1609
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
119.0885391	0.07
137.0897675	0.08
146.8300476	0.06
160.9840393	0.16
178.9093323	0.36
181.2016296	0.37
193.2937012	0.11
197.0983124	20.06
202.9408722	0.06
205.2565155	0.01
223.1854553	0.31
225.1596680	0.03
236.6191101	0.09
239.1557922	0.05
241.0543518	100.00
258.9340210	0.05
265.1913452	0.19
283.0145874	0.71
295.1409912	0.09
299.2388306	0.04
312.5758667	0.16
313.2807007	0.41
319.2745361	0.09
343.1120300	1.78
344.8664551	0.08
359.2729187	0.17
367.0552673	0.12
372.9181824	0.02
375.2611389	0.02
385.0356445	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	662.1014
Annotation	NAD
Peak:m/z	Relative Intensity
192.9403992	0.19
226.0583496	0.15
306.2636108	0.50
354.8865356	0.05
356.1060791	0.06
380.3073730	0.14
407.9656372	1.29
408.6081543	0.10
415.1137085	0.10
426.1506348	0.38
470.2901611	0.28
482.3276367	0.12
499.9398804	0.33
540.0759888	100.00
540.6901245	0.93
584.7049561	0.21
616.0279541	0.12
619.1387939	0.36
644.6233521	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	179.06
Annotation	D-Hamamelose
Peak:m/z	Relative Intensity
58.7292099	0.27
69.0800552	0.03
71.0035858	2.56
72.9476547	0.64
74.8755493	9.35
81.0240326	7.29
87.0266647	3.84
88.8877029	0.63
96.8584442	0.47
98.9132996	23.52
115.1507111	0.61
116.9992828	0.83
118.7516327	0.11
125.0043335	6.21
125.9584503	0.05
132.9757385	0.21
135.2132263	0.04
141.0053101	0.06
142.9535980	100.00
149.0023956	0.03
158.9949188	0.18
161.0166473	40.94
179.0194550	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	188.07
Annotation	Indoleacrylic acid
Peak:m/z	Relative Intensity
118.0138550	0.24
129.2302094	0.08
131.9683990	0.03
142.0453339	1.49
143.9429169	10.87
145.9235382	100.00
146.6750336	0.01
159.9767761	0.64
165.1279297	0.03
167.5062103	0.06
169.9358978	3.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	656.2833
Annotation	Unknow
Peak:m/z	Relative Intensity
199.4469452	0.25
202.0865479	0.10
203.0536041	0.24
215.1066589	0.15
229.3027802	0.58
233.0991211	2.76
235.2356873	0.08
245.1304321	0.23
249.3057251	0.63
251.2126923	0.16
257.3908081	0.32
267.0139160	0.17
273.3348694	0.08
279.0606995	0.52
279.9703979	0.32
285.3602600	1.51
288.4367065	0.17
289.9274902	0.22
291.0954895	0.59
296.0602417	0.28
297.1631775	0.11
308.2043152	17.04
313.3338318	0.17
315.2059326	0.19
317.4475708	0.25
324.4150391	0.12
325.2172241	0.06
331.4507446	0.34
332.6103210	0.17
341.0989990	0.24
342.2102661	0.25
345.2449341	1.19
361.2458496	1.05
362.2286377	0.16
363.5505371	0.11
370.2420044	0.39
371.3387451	0.33
377.0185547	0.98
388.3306885	0.34
389.2225342	0.21
392.1240234	0.75
398.0200806	0.18
401.0400391	0.24
406.2045898	1.04
407.0762939	1.30
415.9670410	0.16
419.1694946	0.51
424.3257446	0.76
428.3415527	0.56
429.4453125	0.30
432.2193604	0.22
434.3914185	2.19
443.9977417	0.17
445.1879883	3.23
448.3583984	0.14
458.1824341	0.41
463.2834473	1.21
465.7584839	0.20
470.2903442	0.52
473.2851562	4.30
476.1090698	0.67
485.2783813	0.29
491.3591309	77.28
492.4696045	0.31
494.2442017	1.02
506.9706421	0.54
509.2105713	100.00
510.1693115	1.22
512.4694214	0.09
516.1132202	0.31
524.4192505	0.21
526.4353638	0.22
527.4089355	1.97
532.2076416	0.30
540.0985107	0.08
557.3762817	0.38
563.3793335	1.12
575.2391968	0.65
579.2801514	0.23
581.3657837	12.19
583.7527466	0.59
592.3500366	0.08
593.2191162	0.18
602.1557007	0.14
610.3248291	0.76
612.3972778	0.20
620.1906738	2.99
621.2713623	0.45
626.1587524	0.10
627.1957397	0.07
633.7951050	0.10
635.3853760	0.92
638.3740845	27.47
639.1119385	0.33
643.0990601	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	274.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9709091	4.36
115.8920364	0.46
116.9453888	4.91
130.9558411	0.30
131.9064026	0.08
132.8988953	0.13
158.9239655	98.67
159.9784546	18.41
160.9621735	100.00
201.0445557	4.96
217.2376404	0.46
218.9847107	0.87
228.8434753	0.55
230.9098816	54.47
231.5483093	0.13
246.9780884	1.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	259.1187
Annotation	Glycerol tripropanoate
Peak:m/z	Relative Intensity
80.8551331	0.87
85.1028824	0.32
93.0699310	0.42
94.9607697	0.11
96.9433441	0.37
99.0484772	0.42
101.9888382	0.08
102.9526520	1.39
109.0838470	0.67
111.0390778	0.56
113.1185150	0.09
119.0592804	4.93
121.1224060	0.82
122.0511780	0.19
122.8777771	0.76
124.9584503	4.65
130.1564484	0.14
135.1482239	0.22
137.0620117	100.00
141.0058899	3.14
144.2350616	0.53
153.1967163	0.50
155.0959625	3.24
160.1167145	0.17
160.9983826	0.11
163.1965790	1.36
170.0942078	0.26
171.1090240	6.55
174.9239960	0.26
179.0979462	1.00
181.0415039	37.90
185.1487122	0.41
186.9553070	4.09
197.3553925	1.83
199.0485687	47.25
213.0718842	0.75
215.2125702	5.72
216.2555389	0.39
229.0132294	0.09
231.1654663	0.29
232.4013062	0.12
239.0826874	0.20
241.0186005	3.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	643.1719
Annotation	Lepidimoic acid
Peak:m/z	Relative Intensity
217.0281677	0.69
250.4647217	0.17
258.7773743	0.23
300.1062622	0.12
303.1184082	12.43
321.0718079	7.25
381.2590942	1.01
387.7069702	0.39
409.2390137	0.20
419.1069336	0.66
423.3572998	0.19
424.9602661	0.34
437.2634277	1.13
443.3091431	0.28
451.0053101	0.28
467.3289795	0.21
478.6030273	1.46
479.2238770	20.69
479.8845215	0.19
485.1840210	0.07
492.9417725	0.06
495.4834595	0.19
497.1548462	14.80
521.3256226	0.06
539.2666626	35.10
581.2398071	0.39
607.2437134	0.21
625.1152344	100.00
625.7973022	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	266.02
Annotation	Unknow
Peak:m/z	Relative Intensity
96.0464630	0.02
122.3019104	0.01
222.0289001	0.08
224.0809631	12.40
224.9073029	100.00
238.0611572	0.06
242.0346680	2.24
242.8849640	11.12
247.9829102	0.03
253.8952484	0.04
266.0095215	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	478.2939
Annotation	PC(15:1(9Z)/0:0)
Peak:m/z	Relative Intensity
152.9510956	0.39
196.0760803	1.87
214.0644226	1.06
223.0416412	0.05
228.1484222	0.09
234.0688019	0.06
238.5092926	0.11
265.8802185	0.16
281.3629150	100.00
337.5594482	0.12
347.0750427	0.20
351.3455200	0.31
357.9155884	0.15
399.1284790	0.12
409.7453308	0.10
417.3453064	1.32
417.9631042	0.38
420.1466980	0.05
421.1867981	0.17
425.9737854	0.29
442.0461731	0.18
443.5372925	0.36
460.3102722	0.79
461.1706848	0.07
462.5850525	0.18
474.3550110	0.07
477.4452515	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	539.9322
Annotation	Unknow
Peak:m/z	Relative Intensity
298.2009277	0.28
311.0239258	0.76
369.5410156	0.21
387.5892944	0.15
398.9874268	0.59
402.7670898	0.11
424.0787354	1.28
424.9134521	5.75
426.0187378	9.62
427.0137329	19.14
441.5096436	1.27
442.6391602	0.69
443.7994995	0.53
444.7438965	1.30
448.3176270	0.51
465.5291138	0.35
467.1316528	0.26
468.0308228	0.70
483.0067749	1.12
484.9367065	0.13
492.9491577	1.48
493.9409180	100.00
495.0209351	9.65
495.8512573	0.64
497.2461548	0.11
505.4961548	0.12
509.6387939	0.73
510.5871582	0.71
511.8374634	26.81
513.0017700	1.65
513.8382568	0.24
517.8823242	1.67
528.3798218	0.41
529.4769287	1.84
531.3286743	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	545.2602
Annotation	Canavalioside
Peak:m/z	Relative Intensity
160.9920959	0.55
177.1163177	0.05
179.0532074	0.17
185.2860413	0.01
191.0151978	0.03
259.4203491	0.12
265.2368164	0.02
277.0322876	0.05
278.3703003	0.09
285.3317871	0.13
290.0301514	0.08
293.5249634	0.08
296.2880859	0.08
318.3792114	0.02
319.4728394	0.28
320.3499146	0.43
321.3204956	2.10
335.4785156	0.06
337.3455811	1.14
338.1828003	0.28
339.2452393	3.53
339.9618530	0.04
346.0880127	0.05
347.2420044	4.97
348.0324707	0.13
351.7137451	0.10
363.3330688	0.26
364.6580200	0.58
365.3613281	5.89
366.3199463	0.09
367.2312622	0.12
368.2659302	0.03
371.3341064	0.03
381.3172607	0.05
382.3635864	0.16
383.6970215	0.05
387.3798828	0.08
391.1040649	0.04
395.4332886	0.02
397.0517578	0.10
422.9519043	0.13
427.4754639	0.04
428.2895508	0.10
429.5887451	0.14
461.1217041	0.15
483.4249878	0.16
497.6417236	0.04
499.3762207	100.00
501.3452759	5.32
502.1900635	0.11
507.2359009	0.13
509.2379150	0.48
515.4377441	0.01
526.5020142	0.55
527.3339233	1.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	305.0779
Annotation	Unknow
Peak:m/z	Relative Intensity
87.9759064	2.97
97.8853073	0.55
98.5221863	0.12
113.9970398	1.29
114.8917084	16.17
128.0776978	1.06
132.0343018	86.58
135.2503052	0.28
143.1418152	0.20
143.9289093	1.56
146.0180359	30.39
158.0347443	0.22
165.1770935	0.41
167.0982056	0.35
171.1169739	17.87
172.0017242	4.65
174.1103821	0.18
181.2380676	0.10
183.3804016	0.14
187.0139771	0.59
189.0056000	81.50
190.0534515	60.65
192.7290955	0.17
199.1696777	0.74
200.8411865	0.28
209.3148499	0.23
217.1289978	1.81
224.1939697	0.54
225.7453308	0.63
227.1359253	0.35
231.2666931	0.68
243.1799927	23.58
244.2313843	0.28
245.1631775	1.16
257.1428833	0.13
261.1428223	100.00
269.0930481	2.81
285.3145752	0.05
287.0475769	66.24
288.2947998	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	735.3074
Annotation	Jasnudifloside K
Peak:m/z	Relative Intensity
289.1695862	0.01
302.2248840	0.04
347.4140625	0.08
365.3251953	0.74
378.2388306	0.02
387.4970703	0.09
401.5164185	0.07
431.2659912	0.03
444.1138306	0.08
445.3807983	0.06
454.7338867	0.06
485.4353027	0.02
507.0121460	0.19
509.3720703	4.16
527.2921143	100.00
527.9246826	0.14
538.9581909	0.02
555.0753174	0.04
566.3841553	0.03
568.5848389	0.04
569.3740845	0.43
573.3444824	0.18
574.1143188	0.03
596.8473511	0.12
598.8051147	0.14
613.3041992	0.07
628.8732300	1.38
632.6015625	0.17
638.9416504	0.02
643.4270630	0.06
647.5770874	0.07
653.5254517	0.08
659.2019653	0.05
671.2666626	0.07
672.0390625	0.09
686.3253174	0.01
687.7200928	0.20
689.1536865	32.06
689.9273682	0.08
691.0549316	0.22
698.3241577	0.07
705.5277710	0.09
715.3661499	0.09
717.2085571	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	331.0669
Annotation	2-Galloylglucose
Peak:m/z	Relative Intensity
120.1804276	0.06
124.9410553	4.52
167.0343323	0.12
168.9694366	100.00
170.0372925	0.10
174.9602051	0.01
178.8478394	0.10
230.0819397	0.07
242.9874573	0.06
259.1212769	0.02
268.9921875	0.18
271.2505188	0.04
277.1234436	0.02
287.3845825	0.02
303.2330322	0.02
311.0798950	0.03
312.3290710	0.05
313.1690674	0.35
316.1548462	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	516.8972
Annotation	Unknow
Peak:m/z	Relative Intensity
154.6888428	0.02
159.0522003	0.57
161.0184937	0.06
175.0550079	0.61
198.9949799	0.03
227.1015930	0.09
245.0217743	0.52
260.9216919	0.16
273.0290527	6.20
289.0197754	12.07
387.0877686	0.44
400.9639282	0.17
402.8762207	100.00
403.5090942	0.24
442.8932495	0.32
443.9827271	0.05
444.9664917	0.18
460.6785278	0.07
470.2540894	0.10
471.1632080	0.16
472.8359985	0.17
487.1520386	0.07
488.9194336	0.07
499.6924438	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.09
Annotation	Lactulose
Peak:m/z	Relative Intensity
113.0674820	0.12
118.8064270	0.25
160.8853149	0.02
179.1613770	0.47
197.0604553	0.51
215.1101379	9.82
321.2595520	0.02
341.1269836	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	297.119
Annotation	4'-N-desmethylolanzapine
Peak:m/z	Relative Intensity
113.0799255	0.04
134.9717865	0.21
142.9379272	0.02
151.0595398	0.06
161.0414581	0.33
179.0887756	0.20
180.9903870	0.10
181.8763580	0.11
191.3421936	0.03
195.1032410	0.06
204.8838806	0.04
206.7664185	0.12
208.2865601	0.03
208.9060669	0.04
235.2047729	0.24
235.9234924	0.03
237.0690308	0.05
249.2286072	0.03
251.1371460	100.00
253.2127075	0.03
265.1222534	0.02
269.0597534	0.04
279.2842102	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	543.2445
Annotation	gibberellin A2 O-beta-D-glucoside
Peak:m/z	Relative Intensity
161.1555634	0.17
163.0790710	0.02
178.9960785	0.39
199.0902863	0.03
204.9871368	0.05
227.2543793	0.04
243.3900757	0.04
245.1699829	0.02
247.2330017	0.07
251.2767029	0.14
255.0861206	0.11
257.1246643	0.11
263.1705627	0.04
265.1152344	0.04
267.3100891	0.12
269.5346069	0.04
273.3110046	0.44
275.2069702	0.27
283.1359253	0.40
287.2421265	0.04
289.3335571	0.19
291.3513184	0.08
292.3039551	0.02
293.1583862	0.09
299.3607178	0.13
301.3317566	0.85
303.4570923	0.10
305.2004395	0.12
307.2185669	0.08
317.3723755	0.22
319.2105103	2.12
327.2238159	0.17
335.2022705	0.80
336.5211792	0.19
337.4036865	2.82
338.6879272	0.08
345.2163086	2.69
346.4871216	0.10
361.2241821	0.23
363.2671509	4.22
379.1835327	0.10
380.1477661	0.40
381.2738037	0.30
382.4205933	0.11
388.5157471	0.08
394.9753418	0.08
412.9403687	0.15
423.1944580	0.08
427.1369019	0.20
435.6752319	0.06
441.4136353	0.14
451.3218994	0.03
454.1469116	0.03
460.8766479	0.08
463.4345093	0.41
469.3334961	0.88
470.3282471	0.05
471.7265015	0.05
477.5533447	0.03
479.4856567	0.10
481.7001953	0.12
489.4204102	0.06
495.2915039	0.10
497.2778320	100.00
498.8781738	1.42
499.4791870	2.43
502.1420288	0.09
507.4094849	0.28
513.2939453	7.55
513.9221802	0.03
515.3167725	0.08
524.1878662	0.32
525.2835083	3.08
526.1971436	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.1506
Annotation	Isopropyl apiosylglucoside
Peak:m/z	Relative Intensity
128.8684387	0.04
151.1152649	0.05
180.5865479	0.10
181.2817993	0.07
207.2423706	0.14
232.9406433	0.06
234.3487854	0.05
235.7486572	0.03
244.7420654	0.03
256.3597717	0.04
263.8953247	0.06
277.9733582	0.05
284.7033997	0.02
310.7332153	0.08
313.9470520	0.03
320.9006348	0.05
331.9499817	0.08
353.3410950	10.19
354.1890259	100.00
355.5014343	0.15
356.3426208	0.11
371.6893005	0.03
382.1840515	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	247.0573
Annotation	L-beta-aspartyl-L-aspartic acid
Peak:m/z	Relative Intensity
98.9090576	0.05
113.2923279	0.09
114.2756653	0.09
126.6879883	0.01
128.1430359	0.04
131.0178680	3.83
132.0555420	0.03
143.1690521	0.04
155.2182922	0.02
163.1670685	0.02
168.0487518	0.07
169.2893066	0.01
186.1342163	0.07
193.0891571	0.05
194.0673676	0.05
201.1304321	0.04
202.8417664	0.16
210.9624176	5.15
215.2221985	0.02
228.9958038	100.00
230.0473633	1.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	971.4851
Annotation	Acankoreoside E
Peak:m/z	Relative Intensity
394.4678650	0.11
408.4396973	0.29
409.5452881	0.04
410.5491333	0.31
424.4338989	0.17
435.3539429	0.06
462.1842041	0.05
469.5081177	0.04
470.1250000	0.11
471.9541626	0.20
477.5283203	0.71
485.0612793	0.24
486.4760742	0.11
494.5642090	0.27
495.3953247	0.11
496.4539185	0.11
503.1372681	0.17
505.5959473	0.47
521.5360718	0.98
522.9096680	0.10
529.4295654	0.11
539.4898071	2.70
540.4971924	2.47
541.6659546	0.17
553.9810181	0.62
565.4677734	0.19
568.4080200	1.10
581.9684448	0.21
582.5830078	0.16
584.3616943	0.44
585.5322876	0.67
586.5702515	2.24
591.9885864	0.59
593.5608521	0.08
599.5728760	0.06
604.3820801	0.26
612.1603394	0.57
613.0027466	0.15
629.7719116	0.82
630.4188232	4.61
644.7059937	0.10
648.4555054	0.48
664.5413818	0.04
671.3675537	0.27
672.4866943	0.56
676.2692261	0.14
693.3126831	0.06
702.2677612	0.12
704.4428711	0.07
723.9766235	0.14
726.2002563	0.08
742.5235596	0.40
748.5348511	5.76
765.7415161	0.78
766.5861206	1.19
774.1680298	0.47
791.8383179	2.33
792.5228271	10.41
809.6578369	30.11
810.4797974	100.00
811.4024658	0.38
815.0869751	0.12
823.6229858	0.08
851.9634399	1.76
852.5941772	5.02
882.3995361	0.10
912.4453735	0.69
913.6749878	0.33
954.2106323	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	589.17
Annotation	Rivulobirin C
Peak:m/z	Relative Intensity
174.7783356	0.68
192.0029449	0.08
192.9707947	2.62
199.9310913	0.39
211.0150757	12.26
217.0437927	0.14
229.0467987	28.64
230.1086731	0.47
243.8048553	0.07
245.1363220	0.48
247.0650024	100.00
256.5197144	0.15
261.5047913	0.23
263.3221436	0.66
267.2177124	0.91
268.3333130	0.05
273.9750977	0.60
274.7628174	0.58
281.3162231	0.15
283.4428101	0.16
285.0095215	0.09
288.1747742	0.20
289.8341064	0.16
300.9164734	0.08
303.2289429	0.23
303.8707275	0.13
306.0858154	2.64
307.0555420	1.13
311.4394531	0.04
321.0988770	3.23
322.0377808	0.05
334.9973755	0.71
339.5695190	0.44
341.2956543	0.08
360.3291626	0.19
365.9791870	0.12
367.1211548	0.23
369.0563965	0.37
373.2012329	0.29
376.3118286	0.21
383.3022461	0.38
390.0857544	0.44
395.0368042	2.73
396.3123779	0.54
398.2907715	0.17
399.0886230	1.54
400.1311035	0.46
401.1749268	3.84
406.1480713	0.25
408.1489868	0.30
411.8994751	1.21
412.9777222	0.60
415.3950195	0.73
417.5977173	0.46
438.9897461	0.38
443.2320557	0.68
444.1909790	0.30
453.2993774	0.26
454.2238770	0.65
455.3134766	0.26
457.3182373	0.40
467.9863892	0.06
468.8328247	0.20
472.2258911	0.22
474.3668823	0.34
484.1226807	0.51
491.2042847	0.17
493.2460938	0.46
497.1685181	0.04
499.9793091	0.39
503.2474365	0.44
504.2836914	0.34
511.3228149	0.06
513.2011108	0.09
514.3845215	0.30
526.5723267	0.28
529.2001343	0.31
530.2324219	0.07
542.9834595	0.61
545.0360718	1.17
553.3225098	0.25
556.3533325	0.22
557.1422729	0.71
570.3358765	2.07
571.2266235	5.49
573.3129272	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
92.87580872	0.46
94.9941864	1.02
96.94812012	0.13
98.92355347	0.28
102.1210098	0.12
106.9025345	0.73
108.9576035	1.21
113.262619	0.60
121.2428589	0.14
123.174118	0.38
124.8426208	1.89
127.3268127	0.11
133.330368	0.83
135.0827637	1.06
136.9608765	1.11
138.8195038	0.08
141.2154083	0.47
143.0033112	0.93
145.1192627	2.88
146.2130737	0.32
149.0987701	0.43
151.1110229	0.45
153.0610962	1.14
153.9904785	0.07
155.0717468	2.95
157.0319061	1.23
159.3463745	0.17
161.2500763	0.83
167.1911163	0.50
168.9809875	3.17
171.177887	1.60
173.1077728	0.40
175.1820068	0.50
177.1178284	1.35
178.8643188	0.32
180.0433655	0.19
181.0089111	0.59
182.1600647	1.28
183.1800842	2.26
184.9217377	0.51
189.1567078	0.31
190.9787903	0.48
193.1069489	0.80
195.0838165	3.70
197.0131989	1.90
199.1274719	1.55
205.1960144	0.15
205.9747009	0.08
207.0258179	0.40
209.6072998	0.18
211.1424561	2.20
213.2023621	2.32
215.0383911	0.79
217.0548401	0.22
219.2047729	0.54
221.2803345	1.14
223.1244812	2.06
225.2823792	1.03
226.8260803	0.70
228.6199646	1.21
229.502533	0.43
231.5324402	0.41
233.2272949	1.71
235.0350342	0.47
236.1385193	0.69
237.1843567	0.57
239.2093201	3.18
241.0386658	0.85
243.1981812	0.31
245.1679382	0.23
247.1008606	1.49
248.8026123	0.81
251.1859131	4.30
253.1372681	5.75
253.8269653	0.43
254.984314	0.51
257.2295837	0.63
263.8561707	0.50
265.0757446	2.34
266.4463196	0.90
267.1890869	0.60
269.1940918	0.93
269.9667053	2.44
270.8547363	0.24
275.2191467	16.22
282.3607788	0.13
283.507843	0.36
287.2286377	0.44
288.4348755	0.46
290.2514648	1.55
291.4577637	0.86
293.2155762	100.00
294.0725098	0.30
298.550293	0.23
302.032959	4.10
307.1495361	0.08
311.1458435	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	352.1036
Annotation	Sambucus nigra Degraded cyanogenic glycosides (2'-Epimer)
Peak:m/z	Relative Intensity
100.9425812	8.34
112.9679337	3.92
118.9877090	9.36
124.8787689	2.02
129.0159912	1.46
130.0088043	2.56
131.1309509	0.85
142.8274536	1.63
143.8631439	4.64
146.1072693	40.86
154.1582642	0.20
155.9968567	2.56
157.9843597	2.25
159.0478210	6.35
160.9749756	20.58
164.0600433	4.60
165.9664917	0.32
170.1450195	9.65
172.0823669	0.96
173.9865875	14.16
182.3729858	0.21
186.1445007	1.61
188.1043396	66.74
190.0014038	2.38
191.9047241	0.21
198.2487488	3.95
200.0754395	8.45
202.0645447	0.60
206.0885925	40.29
210.1461487	3.85
216.0037537	1.30
218.0508423	100.00
226.0558167	0.34
228.0922852	6.88
230.1259766	16.63
232.0568542	4.61
234.0568542	0.74
236.2460327	0.47
242.1369629	3.70
248.0978088	4.36
254.1405029	34.73
260.1566162	3.27
264.1368408	3.86
272.0807800	2.01
278.2191772	0.23
290.1555786	10.87
306.1067505	0.23
308.2168274	82.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.1928
Annotation	Unknow
Peak:m/z	Relative Intensity
158.8111877	0.17
178.7507782	0.41
193.1346130	0.14
207.0236511	0.15
233.0682526	0.10
252.9987488	0.04
260.8801270	0.11
263.1019592	0.10
265.1524048	0.21
277.1477051	0.22
294.1170654	0.26
309.0440063	0.08
323.2672729	0.08
327.3646851	0.17
333.4607239	0.08
335.2073975	0.13
342.2657166	0.08
352.9743958	0.24
360.4005737	0.12
361.0815430	0.09
371.1430664	0.17
373.4102478	0.17
383.2715759	1.01
384.3014221	0.23
409.5357971	0.13
411.2085266	100.00
412.2207336	0.40
413.4740601	0.11
414.2558594	0.07
417.4580383	0.25
439.1738586	0.70
440.3508606	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	349.2
Annotation	Sporotrichiol
Peak:m/z	Relative Intensity
105.0500793	0.21
107.1383133	0.29
107.8720398	0.10
109.1011505	0.17
115.0135803	0.04
117.0357971	0.04
121.0272751	1.24
122.0556030	0.09
128.0305328	0.07
129.0569763	0.12
131.0878448	3.66
132.9023743	0.70
135.0748291	2.75
137.0405273	0.07
139.1097870	0.06
141.0442810	0.04
143.0844574	0.18
144.9249573	0.08
146.9956055	0.48
149.0415344	1.19
150.8283386	0.36
153.0690308	0.52
156.2850952	0.16
157.1312103	0.12
159.0691528	0.50
161.0433044	0.32
163.0229187	0.38
165.0757751	0.59
167.1778107	0.15
168.2827148	0.20
169.0925293	0.43
171.3487854	0.08
172.9691315	0.58
176.9487457	0.06
179.1262207	0.39
181.0773468	0.35
182.0411072	0.26
182.9586639	0.24
185.2921753	0.04
187.0481873	0.50
189.1660309	0.15
190.8533478	0.06
193.0476074	0.54
195.2630768	0.19
197.0623932	0.69
201.0391083	0.77
204.6678772	0.07
207.0903625	0.12
209.2044067	0.58
211.1419373	0.77
213.2757263	0.16
214.7228394	0.05
216.9050598	0.08
219.4646606	0.04
221.2297058	0.39
222.0784302	0.12
225.2187195	0.34
226.9963684	0.16
229.0600281	0.92
231.3244934	0.30
233.5534668	0.10
235.2174988	0.08
237.2427979	0.41
239.1723022	2.78
241.1969299	0.46
242.1328735	0.04
243.0179443	0.37
247.2149048	0.08
249.1590271	1.21
251.4014893	0.68
253.0346069	0.56
254.2114563	0.10
255.0854492	0.47
257.1533813	4.01
258.1589355	0.05
259.0711060	0.51
260.1082153	0.07
261.1685181	0.40
263.0620728	0.10
265.0341797	0.19
267.2053223	6.81
269.1848755	1.52
271.2274170	0.40
273.0664978	0.45
275.1591187	0.55
277.2767639	0.42
279.2900391	0.10
281.0952759	0.15
283.2597656	1.72
285.2149048	21.69
287.1911926	0.86
289.2567139	0.46
290.9588623	0.16
293.2359314	0.07
295.1245728	5.12
295.7600708	0.05
299.1781921	1.08
300.6116943	0.32
301.2239990	3.66
303.2295532	28.26
304.6881714	0.08
313.1719666	22.81
317.7215576	0.25
319.1693420	0.72
321.2730103	0.09
325.0801697	0.09
326.1317749	0.05
328.6612549	0.22
331.1492615	100.00
331.7623596	0.44
340.2448425	0.29
341.1288147	0.14
348.9145203	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	229.14
Annotation	Traumatic Acid
Peak:m/z	Relative Intensity
71.11938477	0.03
72.17979431	0.01
77.08857727	0.02
81.01565552	0.06
84.99085999	0.06
85.81158447	0.01
98.70689392	0.04
100.0559692	0.13
105.0894165	0.06
106.944931	0.02
108.0419159	0.05
109.0860291	0.09
118.8395081	0.05
124.0621033	0.03
126.821228	0.05
128.9217529	0.28
130.3271484	0.02
133.1181183	0.13
135.0146179	0.09
139.2126465	0.01
141.0500641	0.11
142.0721283	0.09
144.6042328	0.09
146.9760742	0.39
149.0560455	0.04
150.9916534	0.13
153.0510864	0.03
155.0078583	0.13
157.1002655	0.04
169.0503845	0.11
171.1655121	0.13
173.0080261	0.06
175.3043823	0.03
179.4365997	0.07
181.2132416	0.02
182.2654572	0.04
183.0702362	0.27
185.0728607	0.18
186.1805267	0.04
187.9294281	0.09
191.1909027	0.12
193.0506897	5.68
198.0690155	0.13
199.4670258	0.01
201.0391388	0.24
207.0652008	0.05
208.023056	0.09
209.2251129	0.06
211.1315918	100.00
212.4471893	0.11
214.385849	0.03
219.881424	0.04
228.9659271	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
82.97064972	0.07
96.71926117	0.35
109.1997986	0.14
111.2284241	0.16
113.2029114	0.43
123.1944885	0.27
128.9036407	0.35
132.8015289	0.11
141.3322296	0.08
145.1158905	0.13
149.0648956	0.81
150.8996124	0.36
155.3028412	0.15
160.962204	0.52
167.32901	0.46
178.9367218	0.46
181.2992554	0.21
183.1678925	0.15
191.1957855	0.52
195.2114868	0.41
205.0118256	0.09
207.1620331	4.15
208.1572418	1.98
209.104187	2.37
222.0845032	2.61
223.0404205	2.37
224.2734985	0.77
233.1415863	2.46
236.2026978	0.15
251.0743561	100.00
252.1295929	19.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.1786
Annotation	Unknow
Peak:m/z	Relative Intensity
131.0468750	0.23
140.1814575	0.23
144.9963684	12.36
159.0511780	0.26
167.1182251	0.19
193.9961243	0.05
195.9193420	0.31
197.0200653	0.20
211.2966614	0.03
213.0886230	2.00
213.8624268	0.23
222.9580383	1.16
227.2143860	0.06
231.0459900	0.66
231.9710083	0.06
239.2355652	0.22
240.1754150	7.59
241.1542053	0.34
243.1862183	0.12
245.0627441	0.09
253.0815125	0.35
257.9377441	0.72
264.6776428	0.09
266.0481262	0.04
267.1384888	0.11
269.1569519	0.27
275.0222168	0.04
277.4823608	0.13
279.1164551	1.53
280.2142334	1.64
281.2471924	0.12
287.1419373	0.09
291.2169189	0.32
294.2726135	1.00
296.1790466	11.93
297.2732544	0.94
298.2173462	0.07
305.2315674	0.03
311.9199524	0.22
313.1982422	100.00
314.1928101	4.27
314.9497681	0.41
316.0010986	0.31
322.8091431	0.06
323.9785461	0.05
331.0972595	20.19
332.4213562	0.73
333.2951660	0.07
339.0783386	0.32
341.1943054	1.72
342.1417542	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	571.2398
Annotation	gibberellin A2 O-beta-D-glucoside
Peak:m/z	Relative Intensity
179.0163269	0.20
267.1091309	0.03
331.3007812	0.08
344.3842163	0.04
345.0981445	0.11
361.3987427	0.17
363.2778320	4.78
375.3799438	0.04
395.2006836	0.11
396.2221680	0.02
405.2547607	0.04
408.1052246	0.09
409.3820190	0.02
417.2936401	0.11
422.2119751	0.06
423.2355957	0.04
435.1676636	0.23
441.1593628	0.21
442.2468262	0.12
450.2565308	0.05
481.3253174	0.36
482.3403931	0.11
487.4700928	0.08
511.4369507	0.05
525.2552490	100.00
541.1868286	0.11
553.2388306	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1095
Annotation	Unknow
Peak:m/z	Relative Intensity
94.8265915	1.48
112.9932709	9.92
113.9977341	2.93
131.0245972	100.00
139.9547119	0.04
149.8488617	0.08
179.0846863	0.06
183.0607605	0.80
197.2089539	0.29
197.9827576	0.22
213.3182983	0.05
213.9782410	0.19
223.5375366	0.25
224.1753540	0.07
240.3336792	0.05
254.0723572	0.19
267.0603638	0.19
292.8998718	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.1084
Annotation	Hydroxytyrosol 1-O-glucoside
Peak:m/z	Relative Intensity
92.7332153	0.07
94.7824249	0.06
100.9913712	0.06
108.0128937	0.29
109.0967712	0.56
112.9494781	0.07
120.9343719	0.09
122.9565430	7.22
135.1386719	0.05
135.9126740	0.06
136.8618164	0.10
141.1090393	0.05
143.1289673	0.04
146.1076965	0.22
151.0237427	0.73
153.0178528	100.00
154.1587219	0.06
158.9378204	0.04
163.1093597	0.45
167.1163330	0.17
174.0194855	0.02
177.1289978	0.28
184.2971497	0.15
187.1131134	0.06
192.9475250	0.09
195.0652313	0.14
207.2095032	0.03
210.8995056	0.13
213.2568054	0.12
219.1045837	0.07
223.1866760	0.16
225.1512451	0.23
226.9470825	0.17
237.3856201	0.15
253.1544189	0.06
255.1141357	0.09
269.1339417	0.59
271.2327271	0.36
272.7084351	0.05
281.1223145	0.06
283.1183777	0.06
285.2365112	0.07
287.1103516	0.10
296.8345337	0.36
297.8848267	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	635.21
Annotation	Unknow
Peak:m/z	Relative Intensity
178.8871918	0.03
221.0936279	0.07
232.9856567	0.02
250.5063324	0.09
281.1576538	0.10
311.1731262	0.11
323.1647034	0.16
341.1523438	0.75
382.9859009	0.02
439.1928711	0.02
442.8720093	0.16
472.9666138	0.12
503.1809082	100.00
536.8148193	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	377.1585
Annotation	(3S)-7-Hydroxy-8,2',3',4',5'-pentamethoxyisoflavan
Peak:m/z	Relative Intensity
128.1831207	0.02
135.1471100	0.01
149.0450897	0.07
167.2183990	0.03
172.0026855	0.02
177.1391602	0.02
200.2205811	0.05
203.1066284	0.04
204.0752106	0.06
214.9775085	0.01
225.9585266	0.01
236.9246216	0.04
241.0866089	0.11
243.1852112	0.70
266.6528320	0.07
267.3433838	0.05
269.1642761	0.29
285.2740784	0.14
287.2380371	1.23
303.1802368	0.10
305.3041687	0.03
313.1406250	0.77
315.1435547	0.25
323.0746765	0.17
331.1059875	7.17
332.5625305	0.10
333.2894897	0.06
337.3475342	0.03
340.9166870	0.83
341.6017151	0.01
349.1756287	0.07
355.1509094	0.02
359.0374451	100.00
360.0120544	0.02
377.1918335	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	395.1711
Annotation	Nagilactone B
Peak:m/z	Relative Intensity
208.1456604	0.01
223.9685364	0.03
249.3811646	0.02
257.2435608	0.02
261.1272583	0.01
269.1911621	0.01
271.4139099	0.02
289.1463623	0.01
291.2428894	0.01
303.2846375	0.01
307.2804871	0.01
315.1783447	0.02
317.2747803	0.01
321.3822937	0.01
333.2798462	0.14
337.4129639	0.05
342.8858337	0.05
349.3314819	0.21
351.2226562	0.24
359.3265991	0.06
365.2251892	0.02
369.2306824	0.02
377.2328186	100.00
378.0543518	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.0933
Annotation	Erinoside
Peak:m/z	Relative Intensity
112.9974823	0.43
129.1116638	0.03
131.2075500	0.14
137.0342712	8.52
138.9851074	0.04
157.0971375	0.16
168.9368591	0.09
174.9856262	0.37
187.2290802	0.11
189.0224152	0.04
193.1112671	0.33
196.9534454	0.02
204.9937897	0.24
207.2035522	0.08
211.1073456	6.13
225.2296753	0.06
231.1388855	1.50
242.1261902	0.14
249.0931702	66.04
250.2749939	0.05
251.1225281	0.21
253.1106873	0.02
267.1766357	100.00
268.1098022	0.19
277.2390747	0.18
281.1517334	0.19
293.3068237	0.24
295.0344849	0.11
311.2131348	0.09
312.0628357	0.05
313.0583496	0.07
323.1593323	0.03
325.1448364	2.60
327.3685303	0.16
341.1395874	4.00
343.1611328	1.04
343.9069519	0.04
351.2062073	0.14
351.9899902	0.06
357.1255798	0.05
367.2746887	0.02
369.2059021	4.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.26
Annotation	Unknow
Peak:m/z	Relative Intensity
170.0454254	0.13
180.8816376	0.09
187.9765930	58.50
189.0189209	1.75
204.9900513	100.00
205.6163788	0.45
207.1365356	7.67
213.1611328	0.54
225.0303345	16.73
243.0846863	8.96
249.4126282	0.05
254.9576874	0.25
288.1249390	0.10
290.0997925	0.08
302.0296021	0.13
304.9607849	0.09
336.1828613	0.41
337.3049316	0.08
341.5839844	0.07
355.9607544	0.06
367.1422729	0.48
369.3666382	0.62
372.5269775	0.11
377.3206177	0.11
387.0635376	1.45
403.2866211	0.13
404.7954102	0.77
405.5541382	0.45
428.2392578	0.06
429.2772217	0.60
430.2119751	0.40
446.8900146	0.80
450.8424683	0.47
456.0302734	0.40
457.1985474	0.42
459.3333740	0.37
468.4513550	0.40
470.1369629	0.34
487.8693237	0.21
489.9681396	0.20
506.7728271	0.64
524.3989868	0.30
547.0294800	0.50
556.0731812	0.38
562.9092407	0.12
564.7511597	0.15
573.1703491	0.27
580.1625366	0.19
591.2344971	2.98
592.4793091	0.17
600.4870605	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.2234
Annotation	Acetyl-T2 Toxin
Peak:m/z	Relative Intensity
149.1091766	0.14
178.9277039	0.25
193.0068970	0.15
204.9946594	0.03
225.0650177	0.03
239.2297974	0.09
257.0561829	0.04
259.0112000	0.18
266.3564148	0.04
267.3983765	0.04
269.2673340	0.03
283.1147766	0.48
285.7574463	0.09
299.3515625	0.22
300.2852173	0.04
301.2315674	0.10
307.1539307	0.16
313.4646606	0.07
319.5557861	0.03
327.2368164	2.20
329.2450867	0.15
339.0469971	0.20
341.4259644	0.31
345.2519836	100.00
346.0030518	0.25
359.3512878	0.23
369.0882263	0.27
383.4225159	0.23
387.3147888	22.28
390.3787842	0.17
391.2786560	0.06
405.2436218	0.16
409.2671204	0.17
411.2182007	0.30
412.2841187	0.07
413.4205627	0.05
415.2888489	0.05
417.1350708	2.83
419.1618958	1.18
427.2925720	0.07
432.5015259	0.08
439.3462524	0.08
445.6557312	0.12
447.2033386	8.63
449.2208862	0.14
461.1310425	0.50
463.4607239	0.91
471.1581116	0.24
472.0334167	0.93
473.3462219	0.17
477.0591736	0.08
478.8054504	0.09
487.1480408	0.03
489.1851501	0.77
490.2617493	0.11
490.9258423	0.04
493.0534973	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.1398
Annotation	Trichogoniolide
Peak:m/z	Relative Intensity
114.8942032	0.17
116.8037872	1.09
129.0302887	0.13
131.1584930	0.08
145.0540619	0.34
154.8901367	0.14
156.2124023	0.11
157.9243164	0.06
159.0617676	0.08
163.4280090	0.03
171.1083069	0.45
173.0760193	7.70
175.2962799	0.08
176.9702148	0.25
187.0826416	0.07
189.1408997	0.23
199.1746521	0.18
201.0759125	0.18
205.3226929	0.09
211.2520752	0.12
217.1366882	44.13
223.1973267	0.07
225.0662842	0.23
227.6087952	0.03
229.1486206	1.27
231.1564941	0.07
233.1398010	0.17
235.1856689	0.09
237.0185852	0.16
243.2807922	0.10
245.2868652	0.39
247.2613220	0.35
253.1698303	0.24
254.5863342	0.09
255.1947632	1.84
257.0972595	0.05
258.1777649	0.10
259.0091553	0.07
261.1633606	4.36
262.3114929	0.03
263.1679382	0.08
264.9822998	0.03
271.3434448	0.05
273.2384644	24.50
274.3243713	0.14
277.3647461	0.04
283.1274414	0.13
289.2472839	0.96
291.1610718	25.72
291.7775269	0.21
293.1688232	0.16
299.1383972	0.16
303.1716614	0.08
305.3026428	1.07
307.2936707	0.27
317.1659241	74.20
318.1094360	0.74
333.4204102	0.36
335.1964417	100.00
336.3179932	0.71
343.2257996	0.08
351.3708801	0.33
361.2308960	32.26
362.1199036	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	696.2936
Annotation	Unknow
Peak:m/z	Relative Intensity
270.1856689	0.12
298.0777588	0.91
299.9929810	0.04
344.1074219	0.08
352.4271851	0.05
364.1961670	0.19
385.9624634	0.09
398.8709106	0.24
416.1131592	0.13
452.1482544	0.07
457.0275269	0.05
462.3892822	0.03
468.4810791	0.07
480.3381958	0.49
494.5310669	0.22
498.2772217	6.77
516.2938843	6.60
520.2537231	0.11
532.1963501	0.09
534.3899536	0.51
548.0191040	0.18
573.9784546	0.10
581.4420776	0.19
616.4373779	0.47
625.4688110	0.08
627.3068848	0.10
631.3593750	0.23
632.2428589	0.06
634.1835327	0.15
634.8024292	0.08
642.2379761	0.92
643.4826050	0.06
651.9013062	0.10
660.4017944	11.47
670.2490845	0.21
678.2841187	100.00
679.0057373	0.08
686.8056641	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	365.1606
Annotation	Orizabin
Peak:m/z	Relative Intensity
112.8886642	0.29
129.1221313	0.15
131.0110626	0.11
143.1940613	0.17
147.3260193	0.22
157.2061157	0.12
159.2226868	0.15
173.0933228	0.36
185.2126770	1.00
187.2912598	0.43
190.9404907	0.46
199.1755066	0.87
201.1613922	0.06
203.1511536	0.08
205.2242432	0.46
211.2210999	0.30
213.1579285	0.12
215.3614960	0.38
217.0466461	0.68
219.2229614	0.11
221.1946106	0.39
223.1778564	0.74
225.1757202	0.14
226.8618774	0.20
229.1490784	2.15
229.8303223	0.08
231.2785034	2.20
233.1330566	2.47
235.2002563	0.86
239.2216797	0.32
241.2058411	4.94
243.2640686	3.30
247.2361450	0.24
249.2331238	0.16
250.1495667	0.05
255.1513367	0.60
257.2340698	7.04
259.1459045	100.00
261.0397949	0.43
263.1957092	0.78
267.0910339	0.24
268.9387207	0.10
273.5327759	0.38
275.2220459	2.51
277.1664734	39.71
285.2961426	0.69
286.3424072	0.08
291.3486938	0.52
301.2133484	0.73
303.3025208	11.06
304.4849243	0.15
319.1824036	0.26
321.1863098	92.66
322.5244141	0.14
329.3726807	0.36
330.0785522	0.05
331.5540161	0.18
332.9974976	0.31
335.3461609	0.42
345.1045837	0.23
347.1358948	11.35
348.0673218	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1299
Annotation	O-Acetylgeniposidic acid
Peak:m/z	Relative Intensity
139.0106506	0.26
152.0388489	0.31
153.1549835	0.21
156.8837280	0.27
166.9944153	2.13
171.0031586	0.91
175.0715027	1.44
181.8937378	0.35
184.9569702	0.15
189.0597839	0.17
192.9942322	0.11
196.9379730	5.79
211.0824890	17.09
231.0715179	9.61
234.2520294	0.06
236.0306702	0.18
249.1179810	100.00
252.8818665	0.08
263.4261475	0.22
271.0288696	2.62
279.2520752	0.09
281.2949219	0.09
283.2775269	0.24
286.3045044	0.08
299.5023193	0.13
300.7296753	0.07
317.1281128	0.70
345.4248047	0.28
346.1726990	0.10
347.0858459	0.08
363.0755005	0.14
365.2889404	0.05
369.6181641	0.18
371.0611267	0.54
383.2779236	0.16
384.8786926	0.08
399.2355042	0.17
401.2156067	2.20
406.3229980	0.07
415.3527832	1.17
417.3147583	0.13
425.3171082	0.06
429.1280518	3.18
443.2294617	10.97
444.3727722	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	581.2086
Annotation	Cellulose triacetate
Peak:m/z	Relative Intensity
187.0449524	0.16
191.2456665	0.06
213.2551270	0.05
218.1582642	0.04
219.1023865	0.29
228.3289795	0.29
256.9154663	0.13
265.9331360	0.05
267.2493286	0.15
273.1392517	0.03
289.1303711	0.21
321.1718140	0.09
323.7653809	0.13
340.9358521	0.36
353.0134277	0.47
354.5147705	0.04
363.6398926	0.12
365.3836060	0.32
367.3459473	0.05
368.3466187	0.11
373.1872559	100.00
378.9436035	0.08
383.2951050	0.05
393.3051147	0.22
397.2229614	3.61
401.3297729	0.15
407.1785889	0.16
411.0253906	0.16
414.2470093	0.30
415.2189941	0.06
419.3840332	0.80
423.4354858	0.05
425.4916382	0.27
428.8357544	0.12
433.3909302	0.17
448.3154907	0.10
448.9975586	0.38
453.1768188	0.07
466.4815674	0.29
470.2785645	0.54
485.0795288	0.21
488.0487061	0.42
490.7187500	0.14
492.3330078	0.05
493.3370972	0.07
494.3916626	0.29
500.9974976	0.30
507.1973267	0.07
516.6981812	0.12
519.2294922	0.53
521.0234985	0.59
522.1541748	0.05
524.8023071	0.07
532.6985474	0.27
534.8528442	48.78
535.5119019	0.49
536.6528931	0.58
537.4932861	0.19
543.4573975	0.29
545.3018188	0.27
548.0087891	0.19
562.7190552	0.19
563.3956909	0.67
564.5804443	0.29
572.6586304	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	333.1689
Annotation	Gibberellin A4
Peak:m/z	Relative Intensity
97.04146576	0.05
102.9583893	0.05
107.8380508	0.29
108.9740906	0.21
117.1242905	0.04
119.8421555	0.03
121.0130157	0.15
131.2302399	0.58
133.1410522	0.09
134.8092041	0.21
137.8719482	0.08
139.1312408	0.13
141.0851288	0.11
146.9936829	0.09
148.9629517	0.26
149.9004211	0.04
151.0773621	0.22
153.0365295	0.03
154.9299774	0.10
157.1966553	0.04
159.08461	0.10
165.0039062	0.04
171.0232544	0.26
173.0997772	0.20
175.0591888	0.19
177.0232849	0.32
179.2200775	0.15
181.1605377	0.12
186.9515228	0.18
188.9541168	0.20
191.1365662	0.22
193.0951996	0.81
194.0421448	0.46
195.2021484	0.29
196.233429	0.45
197.2900238	0.20
198.9178619	0.24
201.2384033	0.11
202.9552002	0.26
205.0544128	0.38
206.0477295	0.05
209.1736145	0.33
211.2010803	0.35
212.9527893	0.37
214.2182007	0.18
215.09552	0.15
217.2190552	0.29
219.1668701	0.19
220.947937	0.27
223.2385559	0.31
225.1138	0.40
227.0469666	0.18
227.8230591	0.17
229.188385	0.42
231.1957397	0.11
233.0723267	0.30
239.2903442	0.57
241.1908875	2.15
243.2051392	1.54
245.1673584	0.79
246.3579407	0.44
247.2285767	0.12
251.1542969	0.77
252.2376404	0.13
253.1922607	0.62
255.1964722	0.76
257.081604	0.70
258.2069092	0.16
259.1472168	2.33
261.0727844	0.14
263.0324402	0.15
269.1619568	8.56
270.2409363	0.60
271.1853638	2.10
272.3897705	0.69
273.2030029	0.46
275.1104736	0.16
276.3706055	0.67
277.2347412	0.25
279.2793579	0.41
283.0551147	0.09
284.3182373	0.23
285.2721863	0.93
287.1292725	51.43
287.9381104	0.16
289.1737366	0.32
291.1861877	0.33
292.4550781	0.08
295.2862549	0.17
297.1013184	4.03
298.1385803	0.14
299.0869446	0.15
301.0049744	0.22
302.308136	0.09
303.2208862	1.22
305.1150513	0.94
312.8348694	0.11
315.1695862	100.00
317.1479492	0.51
318.0574036	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	541.23
Annotation	3-[4-[1-(4-Hydroxy-3-methoxyphenyl)-1,3-dihydroxyisopropoxy]-2-hydroxyphenyl]propyl alpha-L-rhamnopyranoside
Peak:m/z	Relative Intensity
158.9100647	0.14
161.4780884	0.18
164.9653320	0.09
167.0931396	0.20
173.0785675	0.17
178.8612671	0.12
180.6396637	0.14
213.2965698	0.52
217.2395477	0.11
229.3833008	0.05
230.2592316	0.11
235.1163330	0.47
237.2582092	0.21
243.4084778	0.11
269.2030945	0.25
272.4000244	0.50
273.3704834	0.43
281.4368896	0.29
287.3170776	0.10
289.2204590	0.07
291.2713623	0.18
299.1201782	0.77
301.1922607	2.58
301.8706055	0.42
303.2984009	0.21
305.3345947	0.55
317.2291260	27.18
318.4136963	1.84
327.3350220	0.15
328.0701904	0.14
329.1634521	0.31
332.2822876	0.20
335.2177734	63.70
336.1544189	4.83
337.5783691	0.22
341.1730957	0.05
342.3458252	0.18
343.4163818	1.81
344.2149658	0.27
345.1774292	0.16
346.6988525	0.10
348.3464966	0.09
349.4091797	0.18
359.2987061	0.63
360.2745972	0.34
361.2230835	27.07
362.1991577	0.45
363.2019653	0.21
371.4052734	0.09
375.2196655	0.04
376.8025513	0.93
379.1611328	39.80
379.9999390	0.62
380.7350464	0.20
381.3527832	0.24
387.4475098	0.09
391.2857666	0.07
393.3000488	0.17
397.6171875	0.22
404.8916626	0.08
417.4756470	0.26
421.3106689	5.76
422.3996582	0.08
425.7736206	0.07
435.2026978	0.17
437.4244995	0.41
451.2954102	1.06
463.4650269	0.76
467.0872803	0.22
469.4446411	0.08
475.2891846	0.14
479.3190308	0.84
480.3212280	0.06
481.2114868	8.94
488.2869263	0.22
495.3306885	1.12
497.3380737	100.00
498.2802734	8.27
505.6350708	0.10
509.5296021	0.06
511.3355713	0.19
523.2633667	4.20
524.4057617	0.29
532.3110352	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	363.22
Annotation	Limbatolide B
Peak:m/z	Relative Intensity
105.2309723	0.16
108.9372101	0.25
118.8497314	0.21
120.6671143	0.27
123.1605988	0.18
125.0449295	0.04
128.8336487	0.11
131.2056427	0.13
135.0129089	0.18
140.3704529	0.03
145.0294800	0.15
147.1987152	0.16
148.9575500	0.31
150.8526154	0.09
155.0639954	0.52
157.1147461	0.34
159.1482849	0.92
161.0906982	0.71
161.9443359	0.03
163.2338562	0.33
165.0264282	0.25
166.9119568	0.03
170.0377197	0.04
171.1053772	0.87
173.1029663	0.22
175.0789185	0.41
177.1259308	1.11
182.9145813	0.09
185.1455688	0.22
187.1120911	0.64
189.0529175	0.64
190.9834595	0.10
193.2791443	0.03
195.1375732	0.17
197.1987305	0.16
199.1078186	0.61
201.3516541	0.25
202.9370575	0.64
205.0260773	0.26
207.2729492	0.10
208.1750793	0.11
209.2571716	0.17
210.8766174	0.09
213.3114929	0.39
215.2529907	0.18
217.1474304	0.79
219.0012512	0.80
221.2467346	0.36
223.0419006	1.37
225.0749512	0.22
227.0831604	0.18
229.1224670	0.41
231.1148071	1.94
232.8872681	0.06
235.1845398	0.30
237.3338623	0.09
239.2063904	0.24
241.2829285	0.18
243.2637634	0.26
244.0839233	0.05
245.1802673	2.14
249.2534180	1.84
251.0757751	0.77
253.3362122	0.64
255.2680359	0.30
256.4237671	0.04
257.3406067	0.09
261.1264038	0.67
263.2140503	8.43
265.2331848	1.60
267.2258606	2.13
269.1240234	1.23
271.1702271	1.95
272.1784058	0.15
273.2320251	0.10
275.1918945	0.40
278.8713074	0.28
281.2774048	10.90
282.6638794	0.05
283.2640991	2.47
285.1515503	0.61
287.2379150	5.09
291.2368469	1.63
293.1730957	0.11
295.0666199	0.08
295.8823853	0.08
299.2394714	11.73
300.0941162	0.05
301.2105408	2.93
303.2280273	0.26
305.2158813	0.09
309.2151489	22.77
310.2149658	0.16
312.2520447	0.08
314.3074951	0.35
315.1401367	0.17
317.0755310	1.02
319.2651367	0.18
321.8963928	0.19
322.5058594	0.10
327.3059082	24.74
332.9405518	0.18
335.2687988	0.31
340.3476562	0.24
342.7388611	0.10
345.2187805	100.00
346.2491760	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0712
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
149.0581665	0.26
180.1756744	0.19
181.2814636	0.68
183.0491486	0.09
206.0189362	0.64
207.0590973	2.03
208.2175751	0.85
209.1440277	0.78
221.778244	0.85
222.6278992	1.01
223.276535	1.08
224.2780762	0.30
233.1081696	0.37
236.1043549	0.17
237.2214813	0.11
251.082901	100.00
252.1019135	15.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.1186
Annotation	5,7,2',5'-Tetramethoxyflavanone
Peak:m/z	Relative Intensity
121.0071259	0.66
152.8691406	0.19
169.1732025	0.20
179.0734711	0.09
181.1571045	0.63
197.2651672	0.14
199.1315918	0.34
203.3089905	0.05
207.3222198	0.10
209.2702637	0.27
211.3330383	0.07
213.2185974	0.07
219.1539612	0.08
229.0711670	0.19
230.8678894	0.11
235.1837158	12.55
237.1049500	100.00
238.3241577	0.18
240.4589539	0.12
243.3890686	0.22
251.2043762	0.19
254.2087708	12.99
254.8739014	62.75
255.5943909	0.03
258.9743958	0.13
263.3969421	0.13
265.1307373	0.06
267.8535767	0.14
269.4050293	0.16
271.1381836	0.06
280.8706055	0.11
283.4111328	0.30
285.1735840	0.16
293.1781006	0.08
296.9837036	0.22
298.9572449	20.36
305.2604980	0.20
307.1953735	0.78
308.0907898	0.82
309.5371094	0.15
311.4855347	0.08
315.4354553	0.05
325.1246033	1.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
81.13197327	0.07
106.0974731	0.17
133.8954926	0.12
140.0790558	0.22
147.0095978	0.07
169.0275269	0.11
179.1194763	0.64
180.0645905	0.36
181.1972504	0.23
182.8287354	0.17
193.0728149	0.05
194.139389	0.14
195.177536	0.39
196.1156158	0.36
206.018692	0.72
207.1448212	4.23
208.1020355	1.53
209.1564941	0.92
222.0466766	1.63
223.2036743	3.82
224.0935822	0.53
233.166214	0.24
236.3141479	0.47
251.0840912	100.00
252.09729	21.69
252.8425446	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.2027
Annotation	3-[4-[1-(4-Hydroxy-3-methoxyphenyl)-1,3-dihydroxyisopropoxy]-2-hydroxyphenyl]propyl alpha-L-rhamnopyranoside
Peak:m/z	Relative Intensity
153.2999878	0.14
155.2156219	0.29
160.9084930	3.31
172.6336365	0.17
177.2799072	0.06
178.7677002	0.17
183.1768188	0.47
185.1082611	1.07
193.2385559	0.09
197.2462006	0.09
211.2063904	1.61
213.1603699	0.37
219.1685181	0.19
221.0655975	0.13
223.1983795	32.09
229.2386627	0.10
231.2920532	0.09
233.0608368	0.23
237.8555450	0.08
239.2354584	3.59
241.1953278	32.24
249.1069946	0.29
251.9330444	0.19
255.1676941	5.22
257.1978149	1.62
259.1890259	1.00
267.0713501	8.78
269.1930542	0.30
275.0563049	0.06
283.1983643	0.42
285.2027588	7.62
295.2410278	0.14
303.3009644	5.64
311.1392212	6.03
313.2257690	0.18
329.2037354	100.00
330.3303833	0.26
331.3944092	0.52
347.1448364	9.22
349.3637695	0.58
403.2594604	6.31
421.3026733	2.64
445.6702271	0.16
447.4139404	1.09
463.2945557	0.35
465.3309937	52.65
491.3204956	6.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	401.1089
Annotation	10-Dehydrogardenoside
Peak:m/z	Relative Intensity
112.8609695	0.20
127.1169891	0.05
128.7574768	0.09
131.0109253	0.12
133.0156708	0.15
137.2239990	0.07
138.8473053	0.10
140.9692993	0.02
142.9337769	0.02
149.0258179	0.07
151.0157623	1.64
156.9602356	0.10
165.2799683	0.02
171.3071594	0.02
174.9527283	0.23
177.1057434	0.11
187.2480774	0.04
188.9607239	0.15
192.9425507	0.27
205.1548157	0.36
207.3028259	0.01
211.1571960	0.35
223.1159668	0.31
224.9507141	0.57
231.0007935	1.25
239.1833801	0.04
249.0457458	20.10
250.2369080	0.02
255.2615051	0.03
263.1610107	0.56
264.9744873	0.11
267.0903320	100.00
268.1080322	0.16
269.1728516	0.05
281.1909790	2.99
286.0880737	0.07
295.1420288	0.19
297.2184448	0.06
305.2448120	0.01
309.1993103	0.06
311.2343750	0.05
321.4610596	0.07
323.0634155	0.02
325.0730286	0.90
339.2759399	0.34
341.0919189	0.73
355.0617065	0.42
357.2582397	0.29
364.9512939	0.08
369.2028503	0.19
373.2311707	0.16
381.4078064	0.11
383.2055054	4.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	427.1562
Annotation	Chitobiose
Peak:m/z	Relative Intensity
124.9760742	0.04
128.8934937	0.03
138.8133392	0.10
150.0426941	4.00
159.3146667	0.03
185.0553894	0.02
192.9836121	0.06
195.0157928	0.03
200.9055939	0.08
203.3731079	0.08
204.9835052	0.03
209.2216339	0.11
211.0742035	0.06
213.0026245	0.04
217.2370911	0.05
219.9844971	0.02
232.7306213	0.04
239.8114624	0.06
241.3044739	0.02
247.1585999	0.16
259.0413513	0.04
262.1578674	0.05
265.3172302	0.06
274.9888306	0.03
282.1971741	5.05
286.9718018	0.08
287.9945374	0.09
288.7063904	0.05
291.2107239	0.09
295.0844727	100.00
295.9318848	0.03
296.9428101	0.03
301.1503296	0.29
301.9040527	0.05
307.1671753	0.02
310.0317383	0.05
315.2250061	0.07
322.0480957	0.08
325.7562256	0.19
326.4689941	0.04
335.3747864	0.39
339.3226929	0.11
342.2592773	0.18
343.0161133	0.02
346.2296753	0.49
349.1384888	0.04
366.9824524	0.08
380.7148438	0.15
381.4243774	0.05
383.1402588	0.13
384.2207642	0.37
385.0505676	0.07
386.3104248	0.20
391.3005676	0.11
394.8999329	0.08
408.2323303	0.07
409.2831726	0.61
410.3780212	0.08
417.7095032	0.21
418.4190979	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	589.2499
Annotation	Serrulatoside
Peak:m/z	Relative Intensity
185.0068359	0.18
201.0840759	0.05
218.9120941	0.24
220.4296417	0.03
223.2024231	0.21
234.1139221	0.05
269.1086121	0.06
271.2313232	0.07
275.2961731	0.17
281.3738403	0.09
298.0630493	0.19
325.6021118	0.08
329.0558472	0.35
359.0877686	0.06
365.2680664	0.02
366.8687134	0.05
369.3645020	0.09
377.1248169	0.20
381.1237183	0.56
383.0906982	0.13
386.3424072	0.11
389.4534912	0.39
390.0588379	0.13
405.9732666	0.14
410.4436035	0.32
427.2763062	0.72
438.4329834	0.07
450.2897339	0.04
456.4832153	0.13
457.1299438	0.28
461.0390625	0.11
493.1472778	0.06
494.8584595	0.08
499.4635620	0.12
501.6784058	0.10
503.0156860	0.22
507.2562866	0.07
523.2178955	0.23
525.9396362	0.21
527.3118286	0.19
543.3154907	100.00
543.9208984	0.20
545.0250244	0.24
551.4041748	0.26
557.1732178	0.27
558.8344727	0.12
566.4107056	0.41
570.4338989	0.27
571.2534790	0.37
572.3132324	0.33
574.0156860	0.07
575.2853394	0.06
579.4940796	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	288.9365
Annotation	Unknow
Peak:m/z	Relative Intensity
115.0130844	0.26
130.9798584	1.17
145.1947937	0.11
147.0392303	0.52
158.9807129	8.79
174.9267273	100.00
184.1552124	0.03
207.0035095	0.12
214.7375793	0.05
216.9940796	0.23
232.9422302	0.23
242.1289673	0.06
243.1058350	0.03
244.9378052	24.80
258.9984741	0.13
260.9907227	0.42
270.9890747	0.28
289.1083984	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	705.1827
Annotation	Unknow
Peak:m/z	Relative Intensity
209.0384674	0.03
363.0288086	0.15
365.3590088	0.03
381.3059692	0.12
397.1937256	0.04
457.0115356	0.04
493.3386230	0.05
525.1860962	1.06
531.9054565	0.01
533.3787231	0.17
535.1173096	0.21
543.1856689	100.00
544.1685791	0.20
557.4492798	0.05
568.8984375	0.22
573.1510620	0.32
573.7538452	0.04
586.7832642	0.08
600.0678101	0.08
607.0559692	0.63
629.0730591	0.03
638.2775879	0.04
639.0054321	0.06
639.6162720	0.06
645.2963867	0.04
661.2680054	0.03
668.9432983	0.02
675.1756592	0.12
686.7763062	0.24
687.4458618	0.03
688.3370361	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	471.1717
Annotation	alpha-L-Rhamnopyranosyl-(1->3)-alpha-D-galactopyranosyl-(1->3)-L-fucose
Peak:m/z	Relative Intensity
142.8825684	0.07
145.1967163	0.47
146.1216736	0.48
148.1135254	0.48
160.8550415	0.27
162.9963531	15.77
164.0043030	8.01
168.8667450	0.16
205.0640106	1.48
206.2920227	0.23
232.1739502	0.08
234.7846375	3.96
235.7115021	2.79
236.3430176	0.08
253.3255310	0.30
264.7741089	1.51
265.4095764	1.14
266.0467529	1.39
275.0976257	0.73
277.7874451	1.25
284.2268066	0.17
290.0991211	0.14
296.2562256	0.41
299.0599976	0.37
300.1924438	53.88
307.0245361	4.19
308.1956787	2.49
322.1983643	0.44
323.2380371	0.40
325.0872192	12.38
326.0826416	11.24
343.0881958	28.27
354.3811646	0.21
356.4279175	0.14
357.2372742	0.20
360.4216003	0.87
367.3110657	0.07
376.2214355	0.09
377.3902283	0.50
384.3169250	0.80
385.2601318	7.41
386.2283020	5.88
392.3321838	0.07
400.3658142	0.09
404.3106384	100.00
405.2652893	0.26
411.2082825	12.86
425.8861694	0.76
426.6097412	0.07
428.1520691	1.88
429.1825256	22.25
429.9335022	0.13
444.3906555	0.10
454.2604675	20.11
455.7864075	0.33
463.2015076	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.2025
Annotation	Acetylchapliatrin
Peak:m/z	Relative Intensity
183.4384003	0.09
211.0315399	0.22
225.1478424	0.11
236.9210968	0.08
245.2420349	0.11
251.2006378	0.27
253.2717285	3.37
267.2464600	0.47
269.3757935	0.09
271.2059631	1.49
272.2982788	0.11
273.0344849	0.07
283.3141479	0.33
295.2351074	1.09
297.1870117	5.68
298.2348938	0.10
311.2623901	1.23
315.2520142	18.55
316.5045776	0.23
318.3857422	0.16
329.3125000	1.24
339.0560303	0.13
341.1392822	100.00
342.0869141	0.42
345.4702148	0.10
355.1588745	13.60
357.2778320	4.41
359.2618408	1.49
369.5579224	0.12
371.2310791	0.14
381.1567993	0.03
383.1165161	7.10
386.9939575	0.26
391.1290894	0.04
401.2455444	4.49
406.2643433	0.04
407.0605469	0.08
413.0375366	0.05
417.4506226	0.57
425.0504761	0.07
425.7092896	0.13
429.1538696	0.07
431.2520752	0.20
432.0059204	0.18
432.8148804	0.04
443.3244629	0.03
458.4238892	0.11
459.5051880	0.19
461.1937866	1.22
464.1185913	0.18
468.0291138	0.14
475.1588745	0.35
477.3204956	1.10
489.0223999	0.09
503.2302856	0.99
503.8478394	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	390.17
Annotation	Syringin
Peak:m/z	Relative Intensity
115.0835114	2.10
121.9902344	0.29
127.0773315	0.42
128.9461060	0.28
130.5580902	0.13
132.9941254	4.17
138.7935181	0.17
144.8180695	0.23
147.0620270	0.33
154.1842651	0.21
155.9462128	0.26
161.0296326	25.55
162.2088013	0.57
167.0025635	0.12
178.9137573	0.22
179.9538879	2.17
187.1470642	0.27
190.1076508	0.17
191.2149506	0.31
193.0719299	100.00
195.1362915	1.40
203.7345581	0.55
205.1717987	0.11
208.0880737	0.14
209.0739594	0.37
211.0023499	4.55
214.1015015	0.28
217.0034027	0.34
220.8989563	0.05
224.9364014	0.13
226.1097717	0.16
227.1434021	0.97
228.1716309	0.67
236.8990173	0.15
239.3130188	0.34
242.1599426	0.17
246.1857300	0.27
251.0557251	0.20
253.2076721	0.35
255.2973938	0.78
255.9873352	0.15
259.2074280	0.97
262.9001160	0.29
265.0716858	0.82
266.1345825	0.57
276.2416077	1.24
279.2172241	0.18
280.0605469	0.13
283.1631470	0.17
285.6535645	2.03
287.0315552	0.17
292.2562256	1.11
298.3081055	0.12
299.2473450	0.81
300.4829102	2.84
301.1920471	1.23
306.2567139	0.22
308.0258789	0.80
309.1219788	1.53
309.7695618	0.17
313.2582397	0.55
313.8739319	0.19
316.3266907	0.26
318.2126465	0.56
318.8880005	0.59
321.3725586	0.61
323.2775574	0.49
325.0471191	0.85
326.2404785	1.73
327.0985413	0.28
328.2764893	0.80
330.3256531	0.42
332.3634338	0.12
332.9649048	0.35
336.8742981	0.31
340.5593872	0.41
341.2087708	0.30
343.6818848	0.14
344.3374329	3.81
345.3940430	0.15
348.8763428	0.33
353.0302124	0.09
354.0408020	1.67
358.0490417	0.87
362.0289612	0.07
363.6784363	0.41
372.1678772	4.46
373.1101990	2.12
377.2957458	0.28
380.8527527	1.19
381.5115051	0.95
382.4794922	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	383.2054
Annotation	Cinncassiol A
Peak:m/z	Relative Intensity
112.0990295	0.02
119.2203979	0.02
123.0398865	0.01
136.0733948	0.01
136.9136963	0.02
146.9512939	0.20
149.0617371	0.05
165.2211914	0.15
183.1718750	0.06
201.0058289	0.05
203.4287720	0.10
204.2233887	0.07
208.9598389	0.18
211.0292511	0.10
214.9669495	0.01
221.3633575	0.01
237.4193726	0.04
239.3186646	0.26
240.7939758	0.11
249.4130554	0.11
251.9418945	0.02
255.0339355	0.08
261.1371155	0.77
264.9587097	0.05
273.1148987	0.43
279.0163574	0.02
283.2125854	0.75
285.3947144	0.25
287.0243530	0.04
301.2738953	0.33
303.2644653	0.04
311.1770020	3.64
317.2743530	0.03
319.2906799	1.39
329.1694641	7.19
337.2514648	3.04
341.3288574	0.06
347.1733093	25.98
350.2596436	0.02
351.3247375	0.12
365.1057434	100.00
366.0240784	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	831.2671
Annotation	Xylostosidine
Peak:m/z	Relative Intensity
233.2960815	0.08
235.3580017	0.14
238.9796143	0.14
245.0249481	0.69
249.2012787	0.07
250.9087067	2.45
252.2530670	0.06
263.1307983	1.61
268.3741455	0.07
279.1978760	0.22
279.9237671	0.49
281.0304565	16.63
281.9415588	0.09
291.1460266	0.14
298.8609314	0.28
323.1088867	1.04
336.8865967	0.31
340.1455688	0.19
341.0851440	0.68
352.5852051	0.39
353.1876831	0.31
359.3697510	0.29
364.2186279	0.23
364.9887695	0.18
368.3268433	0.27
369.0540771	0.18
373.1808472	0.44
375.0933838	0.20
376.8483276	0.05
381.7445679	0.56
382.9849243	0.83
391.2072754	0.14
395.1597900	0.07
406.2880859	0.24
413.1580811	0.39
425.1403809	0.56
428.2591553	0.04
442.2071533	14.18
443.2003174	100.00
460.0682373	0.15
467.0003052	0.14
477.2546997	0.05
482.7163696	0.04
487.4741821	0.22
506.0084229	0.62
507.0962524	1.79
548.6830444	0.32
549.5517578	0.09
569.1106567	0.45
603.7153320	1.11
604.4548340	2.94
605.1498413	3.09
632.6613159	0.19
633.4796753	0.04
636.5494995	0.36
667.9612427	0.88
668.9974976	4.19
670.3231812	0.63
671.1401978	0.10
675.4940796	0.40
682.8760986	0.33
690.2356567	0.33
693.2239380	0.07
708.0899048	0.24
772.1204224	0.04
777.4502563	0.26
794.2788696	0.22
795.5164185	0.17
797.5603638	0.04
812.7158813	1.56
813.4768677	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	475.1458
Annotation	Polygalatenoside D
Peak:m/z	Relative Intensity
137.1617126	0.12
138.0512695	0.10
143.0162964	0.34
152.0018768	3.00
153.1003265	0.94
156.8990021	0.57
167.0403442	5.64
171.0828247	2.27
186.9894867	1.55
189.2043457	0.64
196.2837219	0.63
197.1030273	7.49
211.0815277	56.15
231.1511078	5.68
253.1227112	0.12
263.0544434	100.00
271.1317749	2.81
279.0776367	0.16
283.5226440	0.20
295.1262207	0.70
297.3818665	0.19
329.3511963	0.28
345.2948914	0.13
387.4461365	0.22
403.7110901	0.17
425.2837830	0.31
429.2189636	0.97
431.4703064	0.38
443.2156677	13.61
456.3525696	0.67
457.2986145	0.37
458.5574951	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0852
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
79.1104126	0.28
94.99767303	0.13
97.08312988	0.10
102.9023895	2.69
105.1060486	0.76
106.9335938	0.76
108.9375763	0.87
115.8609619	0.13
118.879715	0.62
123.0978699	0.77
128.8556519	6.05
130.0901337	0.56
132.9581909	0.11
135.0578003	0.25
141.0576324	1.86
144.8071442	1.09
146.9022369	0.23
148.8116608	0.30
150.9677887	58.79
152.0072021	2.15
152.9817657	0.20
155.0161591	1.62
156.1427917	0.25
156.9653473	0.54
162.9609528	0.92
165.160141	0.24
166.0046997	0.19
166.9796295	0.29
169.1346893	1.19
179.1864471	4.08
180.0967865	0.31
181.0327606	0.45
181.9671478	0.34
185.0447693	1.33
191.1638031	0.29
193.3310394	0.72
194.2229004	0.34
194.9715424	0.18
197.0582581	1.48
198.1249084	0.77
199.0190125	0.34
207.1031494	2.06
210.2380829	0.40
211.1478424	0.88
211.8365936	0.19
217.1884003	0.82
225.136322	5.41
226.2248077	1.20
235.2211761	2.41
238.0871582	9.64
253.0891724	100.00
254.164856	17.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
80.88760376	0.21
84.99124908	0.15
96.84745026	0.42
101.0331268	0.04
104.4690094	0.32
109.0696564	0.30
109.9784088	0.18
128.9223633	0.11
131.6884308	0.13
135.8853607	0.13
139.0685425	0.45
141.1427155	0.13
149.1699982	0.40
160.7555695	0.20
165.1540222	0.69
167.0990448	0.07
174.9715424	0.11
179.1768646	0.54
180.0973969	0.33
181.1785431	0.21
183.3860321	0.63
190.9575348	0.14
193.0990601	0.07
195.1844025	0.13
197.3801117	0.16
206.1839142	0.47
207.2354431	4.22
208.1678772	2.34
209.130661	1.29
215.5066071	0.08
221.2059174	0.10
222.0949554	1.26
223.1447906	3.52
224.0468903	0.38
231.3000031	0.04
232.1429901	0.06
233.1199341	1.75
234.9840698	0.13
251.0717621	100.00
252.1147919	17.71
252.7528229	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	666.3195
Annotation	Unknow
Peak:m/z	Relative Intensity
200.1579742	0.22
216.1974945	0.17
221.0633850	0.12
258.2811279	0.33
269.4013062	0.09
281.1823730	0.10
302.3446350	0.30
314.3602905	0.25
317.3693848	0.07
318.6328735	0.11
323.0604858	0.10
330.2170410	0.03
331.9110107	0.44
360.0491943	0.08
364.9393921	0.07
366.9282227	0.10
401.2524414	0.92
405.3449097	0.36
411.0278320	0.06
413.4500732	0.04
417.0034180	0.59
429.4872437	0.10
446.1390381	0.13
455.3201294	0.10
468.3296509	0.81
473.2742310	0.26
475.4528198	0.13
486.2747192	0.46
519.2150879	0.38
520.6480103	0.05
536.5236816	0.10
551.9094238	0.17
558.5519409	0.23
568.3093262	0.31
580.8717041	0.96
584.1300659	0.05
585.5963135	0.52
586.4338989	0.63
602.0552979	0.33
604.3928223	7.69
607.1714478	0.06
621.9542847	0.03
622.7037964	0.33
625.8468628	0.33
630.3007202	7.38
631.0927124	0.02
639.1633301	0.06
648.3504028	100.00
649.0125732	0.31
657.1661377	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.1983
Annotation	Kanamycin A 3'-phosphate
Peak:m/z	Relative Intensity
167.1249695	0.02
191.1529236	0.38
233.2119904	0.28
239.1597595	0.24
249.0190430	0.11
251.1012878	0.04
269.1022949	0.12
293.1080933	18.78
301.3554688	0.04
341.3007812	0.21
363.0337524	0.10
379.3507690	0.14
383.3657227	0.15
397.2700195	0.13
401.2857056	0.23
419.2686157	0.11
421.2484131	0.04
433.1269531	0.16
442.1063232	0.09
467.4548950	0.13
471.3114624	0.16
475.2174683	0.18
479.0597534	0.07
484.3272095	0.47
489.4260864	0.10
497.5350342	0.13
516.9949951	100.00
517.6915894	0.40
519.3643188	0.16
525.2499390	0.16
527.2185669	1.82
529.2022705	0.07
545.3875122	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	513.2704
Annotation	Tricalysioside J
Peak:m/z	Relative Intensity
160.9996490	0.14
165.1183319	0.11
179.1817932	0.12
225.0084534	0.19
227.1380310	0.31
241.5426941	0.12
259.2295837	0.24
261.1313477	0.09
271.1854248	1.29
275.5513916	0.12
277.4136963	0.12
287.3131104	6.89
289.2731934	3.04
290.1818848	0.25
303.3587036	11.90
304.3206787	0.09
305.3416748	5.47
306.1526489	0.14
307.4514771	1.53
308.7412720	0.73
315.2542725	2.82
316.2691040	0.11
321.3508301	36.85
322.3916626	2.48
331.2973022	2.36
333.2337036	79.44
334.3300171	1.83
336.3471069	0.13
343.0590210	0.20
348.2053833	0.44
349.2849121	2.17
351.2674561	100.00
352.2106934	1.12
365.2983398	0.14
377.5020752	0.81
383.4828491	0.29
391.0823975	0.29
393.4056396	1.51
401.5971680	0.19
403.3421021	0.15
415.1757812	0.76
421.3475342	0.77
423.1358032	0.52
427.1530762	0.23
433.5033569	0.24
435.0026245	0.17
445.5017090	0.38
447.4389648	0.23
451.2078247	0.62
453.1429443	0.32
465.2716064	0.19
467.4779663	1.12
469.3737183	0.98
476.8704224	0.26
483.3863525	18.51
484.3859253	0.12
493.3680420	0.38
495.4031372	12.52
496.5781860	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	696.2943
Annotation	Unknow
Peak:m/z	Relative Intensity
269.4789429	0.13
334.2359009	0.17
372.9887085	0.27
425.1121826	0.09
455.3501587	0.11
477.3969116	0.29
478.2266846	0.37
480.1896362	0.17
498.2829590	5.89
500.1454468	0.25
516.3731689	9.20
534.1636963	1.24
535.3816528	0.10
549.5748901	0.11
564.2644653	0.21
572.3925781	0.07
614.0219727	0.17
616.4523926	0.48
619.2303467	0.37
628.3688965	0.50
634.3363647	0.17
642.2492065	0.66
649.9048462	0.62
660.3323364	8.74
660.9379883	0.16
678.3042603	100.00
678.9340210	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	488.1618
Annotation	Unknow
Peak:m/z	Relative Intensity
146.0464935	100.00
165.1177063	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.2182
Annotation	Excavatolide D
Peak:m/z	Relative Intensity
211.1627808	0.15
226.6564789	0.14
229.4758759	0.04
240.0054321	0.04
249.1961517	0.06
255.1989899	0.47
271.0588989	0.08
273.4165649	0.20
277.0067139	0.11
289.3168640	0.04
297.2985840	0.26
299.1582031	0.21
303.2094727	0.04
312.1180420	0.06
313.2813110	0.07
315.3632202	0.09
317.2882080	0.04
318.1950073	0.08
325.1657715	0.13
343.1953735	100.00
343.8518066	0.39
345.3497925	0.25
355.5236816	0.06
359.3532715	0.84
361.1677856	1.36
377.3674927	0.04
379.0811768	0.15
401.0742798	0.06
403.2957153	0.12
407.4290771	0.11
415.9669189	0.13
423.2890625	0.31
433.4021606	0.08
435.6207275	0.04
437.2494507	0.09
451.2213135	0.03
461.4901123	0.10
463.1352539	0.32
465.3415527	0.11
477.0415649	0.67
479.2927856	1.39
485.1279907	0.35
487.5441895	0.68
488.4246826	0.05
489.5839233	0.15
493.3282471	0.08
504.2854004	0.06
505.2501831	0.85
506.0684204	0.07
508.2589111	0.08
513.1169434	0.24
523.7192993	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.26
Annotation	Unknow
Peak:m/z	Relative Intensity
169.9838715	0.11
179.2061462	0.14
180.9794769	0.28
183.0914612	0.13
188.0854797	50.78
189.0493317	0.72
203.3767090	0.03
205.0712128	100.00
207.0897369	6.70
209.1115875	0.15
221.1412506	0.08
225.1121216	11.14
225.9544067	0.06
243.0861511	5.03
245.2868347	0.10
267.9802856	0.10
301.1934204	0.15
305.1062622	0.14
314.9297485	0.15
346.1661377	0.29
386.5448608	0.74
387.1536255	0.15
402.9765625	0.05
404.6766357	0.79
405.3961792	0.29
413.3798828	0.03
429.1462402	0.16
447.3060303	0.66
455.0476074	0.05
457.0601196	0.17
458.8093872	0.12
461.2652588	0.14
476.3999634	0.16
477.3389282	0.31
480.4259644	0.07
485.4852295	0.16
493.4455566	0.15
499.0541992	0.19
513.3408813	0.06
518.8981323	0.13
535.1741943	0.17
537.7338257	0.12
545.0790405	0.08
547.5559692	0.09
561.1272583	0.14
563.5308838	0.46
565.3568726	0.07
566.1854248	0.04
567.6870728	0.14
575.6295776	0.18
591.2065430	2.20
592.4638062	0.74
605.3521118	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.77
Annotation	Unknow
Peak:m/z	Relative Intensity
212.7776642	2.37
252.0377808	0.16
257.0437622	0.22
296.1974487	1.89
296.8447266	23.64
323.1240845	1.08
378.4492188	0.24
380.1046753	10.18
380.7323608	74.97
461.9653320	2.55
463.9572144	24.37
464.5592041	100.00
465.3642578	0.47
502.0908813	0.24
502.7443237	0.12
530.1254272	0.30
530.8223267	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0197
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
84.9817810	0.45
86.8994598	1.00
93.0173950	0.10
101.1448822	0.03
110.8927002	100.00
127.1317902	0.09
128.9302521	2.20
130.9252930	0.87
155.0339355	0.26
172.9796906	20.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	588.9
Annotation	Unknow
Peak:m/z	Relative Intensity
245.0829773	0.07
273.0916138	1.85
274.1617737	0.31
275.0632629	0.54
427.0464478	0.81
428.0327148	0.37
429.0462646	3.64
473.5482788	0.41
474.9485474	5.53
503.7440796	0.05
526.9254761	0.07
542.7637329	100.00
543.4653931	0.63
544.9499512	1.10
557.1112061	0.79
560.5350952	0.73
562.0308838	0.04
570.9323120	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	453.78
Annotation	Unknow
Peak:m/z	Relative Intensity
176.1339417	0.09
248.1886597	0.13
278.9205322	0.03
318.8615417	1.60
319.9042358	1.18
320.9362488	0.09
321.7166138	0.04
327.0016174	0.11
347.7620850	0.13
361.9044495	0.07
363.8004456	100.00
364.7991943	2.20
365.9490051	0.30
368.8824463	0.04
374.8588257	0.07
377.9720459	0.15
378.7516785	0.17
379.8930664	4.63
381.0909424	1.67
381.7777405	0.64
382.7418518	0.04
390.0083923	0.39
391.8590393	0.09
392.9235840	0.18
394.1369324	0.23
395.5236511	0.09
397.5431213	0.28
404.7729187	0.30
405.9759216	0.14
408.8080444	23.67
409.6854858	0.99
410.9960327	0.27
412.4372864	0.45
413.2966919	0.17
416.8427429	0.19
418.2264099	0.25
423.8700562	0.13
424.5699158	0.08
425.7437439	0.80
426.6243896	0.57
433.1183472	0.93
435.7106934	0.29
436.4396667	0.07
438.8334656	0.98
439.5604553	0.13
442.2537537	0.20
444.2456055	0.24
445.1886292	0.08
448.9309998	0.10
451.7536316	0.12
453.4268494	0.28
454.9216003	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
94.71827698	0.59
96.99604797	0.25
110.6111908	0.25
124.1017151	0.22
125.1266479	0.15
132.6326447	0.20
146.0544281	0.08
149.1274261	0.54
155.2121429	0.10
161.1536407	0.63
163.0111237	0.49
165.8532257	0.12
167.2483978	0.41
175.0935669	0.19
179.2510834	0.78
181.3045807	0.24
189.35495	0.07
193.1907043	0.18
194.3296967	0.14
195.1433716	1.00
205.2698059	0.23
205.8816833	0.43
207.3027802	3.28
208.0738983	1.83
209.3275604	2.25
210.0106354	0.12
221.0469513	0.16
222.1611176	1.84
223.2479401	4.17
223.8742981	0.22
233.1433868	2.04
234.9888916	0.44
236.262558	0.07
251.077652	100.00
252.1290283	18.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	575.2706
Annotation	gibberellin A2 O-beta-D-glucoside
Peak:m/z	Relative Intensity
283.0062866	0.06
286.8771362	0.03
320.9367676	0.05
343.1326904	0.08
365.2454224	0.22
366.3305054	0.20
367.4180908	0.56
368.2961426	0.02
385.2911377	0.08
409.4671021	0.02
443.3804932	0.06
449.2928467	0.03
455.3489990	0.05
465.3049927	0.03
487.9606323	0.01
511.3159790	0.18
512.1897583	0.03
527.1934814	0.72
529.3489380	100.00
530.0148315	0.18
530.9909058	0.07
537.1784058	0.01
538.3174438	0.02
539.2268677	0.05
551.5885620	0.33
554.4394531	0.02
556.3161011	0.07
557.2280884	0.01
558.4325562	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	643.3048
Annotation	Unknow
Peak:m/z	Relative Intensity
190.1832886	0.41
199.3715515	0.40
205.2466431	0.49
207.1869202	2.00
215.0549622	0.45
227.1073151	0.29
229.0110779	0.07
232.2000122	0.24
234.1257629	1.72
235.1464539	1.93
239.1602020	1.23
241.3550720	0.21
249.2328033	0.65
251.1757050	4.23
251.9926453	0.16
257.1460571	1.33
261.2915955	0.69
262.1624146	0.33
267.3737793	1.18
269.0348816	0.13
275.2344360	0.12
277.2740173	0.48
279.1770630	59.62
285.1427612	1.95
303.1649170	1.03
313.0038452	0.38
315.4808350	0.14
321.2158203	0.33
328.9605103	0.25
331.1015625	3.30
355.7977905	0.44
356.5938110	0.14
364.5291138	0.38
373.5289307	0.08
374.5856934	0.19
382.1536255	1.04
399.2763672	0.55
400.3911133	1.70
401.2269287	0.23
409.6063843	0.58
410.3591919	3.87
412.2479248	0.69
417.1950684	1.16
418.3903198	1.08
419.3518677	0.36
427.1804810	13.33
428.2703857	52.41
431.2077637	0.09
437.0499268	0.45
439.2720947	0.09
445.2191162	56.89
446.3272095	20.59
447.1684570	0.32
463.2186890	41.57
463.8511353	0.48
465.2990723	0.24
479.4466553	0.11
481.2484131	0.75
488.1935425	0.28
493.3480225	0.42
509.7902222	0.24
537.2001343	0.91
543.4758301	0.30
559.6375122	0.52
561.0324097	0.62
571.4259644	0.53
572.3281860	0.75
577.4790649	1.67
579.3519287	1.13
589.3954468	4.47
590.2824097	4.24
597.0332642	0.12
600.9538574	0.53
602.6197510	2.81
607.2398071	35.14
608.2321777	1.88
612.0919800	0.16
624.7261963	7.94
625.3451538	100.00
626.8717041	0.18
631.2273560	2.42
631.9076538	0.28
633.0263062	0.16
636.6708984	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	893.4179
Annotation	Unknow
Peak:m/z	Relative Intensity
255.2487793	0.28
257.1815796	0.71
274.8599243	0.10
283.2077942	0.31
283.9098816	0.55
301.2259521	0.15
302.1657715	0.93
319.2783203	2.17
320.2481995	3.84
363.2224121	100.00
364.1917114	65.85
376.4871216	0.10
447.0291138	0.08
457.2526855	0.30
512.1868286	0.08
528.0959473	0.37
529.2555542	2.90
530.5080566	3.76
563.6386719	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.1559
Annotation	(R)-Pantothenic acid 4'-O-b-D-glucoside
Peak:m/z	Relative Intensity
113.0577011	0.49
115.7802811	0.35
118.9226608	0.12
124.9648895	0.23
128.2151794	0.72
131.0304413	0.30
142.0539246	0.08
143.0054169	0.47
146.0172119	52.51
147.0868530	0.43
161.1564026	2.25
173.0202026	0.90
174.1972351	0.96
179.0690765	0.54
188.1130066	0.32
200.0767212	3.01
206.2005615	0.09
213.2909546	0.20
216.1539459	0.15
218.0613861	2.78
218.9268799	0.10
223.2917786	0.18
225.9955444	0.14
235.0390015	0.09
238.8773499	0.22
242.1373291	0.17
245.1092224	0.27
247.4501038	0.41
260.4365540	0.31
263.1906433	3.50
271.8653564	0.27
273.2650146	0.45
274.0841064	0.34
275.0630493	0.17
277.2933350	0.17
280.4074707	0.12
290.2028198	14.60
291.4371948	0.20
292.2539673	0.17
301.0864563	0.30
302.2502441	0.20
308.2130432	71.37
309.3652344	0.44
318.3447266	0.64
319.1749268	0.22
334.1187744	1.06
334.9514771	0.20
336.2966919	4.08
337.1888123	3.26
342.3092346	0.54
343.9314880	0.27
360.1921997	0.12
362.1989136	100.00
363.0179138	1.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.2134
Annotation	Abelioside A
Peak:m/z	Relative Intensity
157.0706482	0.03
161.0407715	0.05
175.1780090	0.05
179.0306854	0.03
217.1459808	0.02
227.2190247	0.05
229.1383057	0.11
237.3897858	0.08
238.1321716	0.03
243.2622986	0.06
244.3358002	0.05
252.9979401	0.23
255.2071228	0.03
271.2750549	2.29
285.1969604	0.09
289.4156189	0.65
295.3103638	0.05
301.3328857	0.09
311.3223877	0.09
313.2464600	1.46
315.2736816	8.62
316.3546143	0.07
329.2643433	0.93
331.2196045	0.26
333.2243042	7.46
334.5134277	0.08
339.3200684	0.09
347.2539673	0.21
355.1939087	0.49
357.2335815	0.50
359.2741699	100.00
360.2818604	0.35
363.2282715	0.04
365.6937256	0.06
369.6509399	0.02
371.0514526	0.08
373.2651367	11.40
375.2172241	2.52
377.2910156	2.15
387.2496338	0.30
389.2619019	0.13
401.2815552	20.26
402.3296509	0.13
415.2908936	0.17
417.2387085	0.07
419.3222046	8.54
420.0632935	0.19
431.3392944	0.92
435.2818604	0.16
439.1750488	0.05
440.9519043	0.04
441.8442383	0.07
443.2858887	0.12
449.2383423	0.06
461.0938721	0.62
477.2430420	0.16
479.5275269	0.16
493.0519409	0.11
495.3664551	1.80
496.4744873	0.04
503.4207153	0.10
521.1300659	2.19
521.8979492	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	446.2003
Annotation	N-Oxide abiraterone sulfate
Peak:m/z	Relative Intensity
130.8739014	0.32
148.9009399	0.47
166.0329895	100.00
263.0859680	0.04
268.9622192	0.21
281.3168335	0.08
293.2187805	0.04
364.5158997	0.08
388.3019714	0.16
400.5506897	0.09
428.4386292	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.085
Annotation	6-Methylflavonol
Peak:m/z	Relative Intensity
78.81383514	0.12
102.7612305	0.25
104.9454803	0.35
107.0370331	0.75
122.6134796	0.18
129.0196228	3.82
130.0783539	0.22
133.1789093	0.21
140.9527588	0.16
147.0366364	0.28
150.9594269	54.18
151.8622131	2.20
155.2051239	0.25
165.0400696	0.61
165.9350739	0.83
166.9416046	1.09
169.2086182	0.43
170.3283234	0.21
179.0950775	0.67
180.2593689	0.46
181.8853302	0.50
183.217804	0.54
185.0040588	1.36
189.971344	0.20
194.0795593	0.32
197.1560974	3.87
198.2257538	0.65
210.1994476	0.11
225.1520691	6.72
226.1610565	0.13
237.2533112	0.43
237.9715576	6.24
239.1041718	1.79
253.0787354	100.00
254.1605377	14.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	472.9246
Annotation	Unknow
Peak:m/z	Relative Intensity
272.8735962	0.35
287.0799561	0.11
359.0152588	0.90
401.1066589	0.21
426.9737244	100.00
428.9541321	0.38
429.9386292	0.13
445.9990540	0.13
455.4458923	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	529.2651
Annotation	Tricalysioside Q
Peak:m/z	Relative Intensity
159.0093384	0.87
232.8882751	0.25
237.3108215	0.12
245.3493500	0.40
247.1812744	0.56
248.3619690	0.24
250.9033203	0.27
257.1505737	0.19
269.2041626	2.09
275.2048950	0.64
283.2464294	0.92
285.3558350	1.16
287.2663269	7.86
288.0806885	0.28
303.1813354	5.54
305.2382812	10.56
306.3958130	0.18
309.0749512	0.22
313.1478882	0.49
319.5056152	0.50
321.3173828	1.93
331.2908936	21.75
332.2887573	0.62
338.9549561	0.15
345.2086182	0.30
349.2406616	77.74
350.2636108	3.92
351.1777954	0.33
359.1421509	0.35
365.2697144	0.61
367.3294678	100.00
368.3200684	5.93
401.4550781	0.66
409.1340332	0.32
433.4587402	0.19
441.4690552	0.35
451.3819580	0.50
483.1538696	2.81
483.8268433	0.42
486.3981323	0.72
491.1221313	0.28
493.3101807	0.95
497.1961060	0.86
499.2879028	0.34
505.3805542	2.46
511.2858887	25.56
512.2985840	1.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	562.2839
Annotation	Agnucastoside B
Peak:m/z	Relative Intensity
200.1370087	0.34
203.0881958	0.06
209.0747986	0.18
227.0940552	0.80
228.2788696	0.08
269.3153687	0.13
271.2991943	0.85
272.2731934	0.20
283.5175781	0.36
304.0656738	0.04
305.8612061	0.08
311.1138916	0.17
312.8356323	0.04
315.5877686	0.09
317.2833252	0.07
325.1826172	0.05
328.8891602	0.07
333.1307373	0.17
338.3096924	0.13
343.9215088	0.12
347.0501099	1.61
348.1130371	0.15
349.4893799	0.09
355.5313721	0.85
356.2610474	1.96
360.3230591	0.25
365.3027954	5.81
366.9153442	0.03
373.1877441	0.19
373.7938843	0.18
383.1225586	63.08
383.7430420	0.22
399.1168823	1.97
400.2645264	5.11
401.2951050	2.00
404.4432373	0.31
408.6087036	0.36
422.0753174	0.20
427.7755737	0.27
433.3058472	0.08
434.2676392	0.11
439.9410400	0.46
440.7283936	1.44
441.8595581	0.03
443.4144287	0.13
445.2819824	0.99
448.8970947	0.90
449.8096924	2.58
450.4221191	0.44
454.0574951	0.52
457.6741943	0.87
458.5561523	1.21
459.2680054	0.13
460.1957397	0.15
462.8841553	0.46
463.9320068	0.27
471.8865356	3.63
472.7460938	1.27
473.4529419	0.05
474.4838867	0.16
476.1217041	0.24
480.6561890	3.85
481.6174316	0.98
483.2845459	0.19
484.1759033	0.06
489.6268921	0.17
497.8279419	0.04
508.3573608	0.05
514.0458984	0.03
516.0328369	2.16
518.2784424	5.83
519.1267700	0.21
521.9490356	0.93
524.0353394	0.26
527.0806274	2.68
530.1315308	0.51
530.9480591	3.00
533.5685425	0.15
535.2985229	0.11
540.3796997	0.16
542.9660034	0.03
544.3027344	9.66
544.9910278	100.00
545.7906494	0.21
551.8723755	0.10
553.4486694	0.18
566.3816528	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.1924
Annotation	3-[4-[1-(4-Hydroxy-3-methoxyphenyl)-1,3-dihydroxyisopropoxy]-2-hydroxyphenyl]propyl alpha-L-rhamnopyranoside
Peak:m/z	Relative Intensity
154.9178162	0.14
158.8279419	0.05
160.9877167	0.83
203.3564758	0.14
205.5079498	0.09
211.2939453	0.18
221.1325073	0.57
223.2202301	4.83
239.2455597	1.19
240.9125671	0.16
267.1567688	8.91
283.1317139	0.62
285.2316589	0.07
286.8426514	0.10
299.5805054	0.03
311.1924438	100.00
315.1843872	0.03
319.2840576	0.12
327.2112427	0.20
328.0621948	0.18
329.1196899	1.56
330.4193115	0.16
333.0858459	0.14
343.3323364	0.16
350.8807983	0.10
363.1396790	0.04
371.1113281	0.12
392.8069763	0.16
395.2181091	0.33
403.4119568	0.34
404.9317627	0.04
419.4372253	0.12
445.2569275	0.39
445.9909973	0.09
447.3537903	10.34
453.2264404	0.53
455.1076355	0.43
456.2330017	0.08
460.3805847	0.09
473.3641052	0.69
474.5469055	0.07
475.9043884	0.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	397.1502
Annotation	Methyl (3x,10R)-dihydroxy-11-dodecene-6,8-diynoate 10-glucoside
Peak:m/z	Relative Intensity
116.9649048	0.34
135.0653076	0.04
139.0784607	0.11
140.9640045	0.13
143.0777893	1.44
147.2781219	0.04
155.1264648	0.02
158.9148407	0.04
173.1176147	2.37
181.1368561	0.05
185.1632690	0.03
187.0164642	0.21
189.1566467	0.09
191.0769196	0.99
192.2755432	0.04
194.9727783	0.09
199.2657318	0.10
205.0332184	0.04
215.1669312	0.08
217.1069183	2.36
218.2007446	0.02
219.3730469	0.05
228.9458923	0.39
229.5482788	0.05
232.9696655	0.46
233.6039124	0.04
235.1021118	31.62
236.1465149	0.17
239.1679688	0.08
241.9829407	0.08
243.2096252	0.25
245.3452454	0.31
247.2337036	2.43
252.9913635	0.05
255.1778870	0.04
261.0907898	0.77
263.3347168	0.05
265.3934631	0.21
271.1665039	0.08
273.1337280	1.58
275.1891785	0.03
279.1317749	1.66
287.2385864	0.06
289.2241211	1.37
291.1718140	14.76
301.4633789	0.08
302.7800598	0.03
307.1789246	0.08
309.2551270	26.97
310.5114136	0.03
317.2965698	0.94
318.8966064	0.11
323.1204529	0.02
325.3135681	0.05
335.1905823	59.36
336.3386841	0.34
337.4932251	0.08
351.3218994	1.52
353.2153625	100.00
354.2803345	0.38
355.1148376	0.33
361.2397766	0.37
367.5217590	0.10
369.3052673	0.19
379.2247620	13.64
380.2816162	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	468.1671
Annotation	Unknow
Peak:m/z	Relative Intensity
155.1538696	0.05
170.9976349	0.27
173.0680695	0.47
183.3920898	0.29
185.1855164	0.31
187.3323059	0.10
193.2993927	0.36
197.2281494	0.12
199.0825958	0.09
201.2166443	0.26
209.4079590	0.16
211.3665161	0.75
213.2265472	1.60
215.2561951	0.44
227.0998230	0.09
229.0617065	0.11
233.4442139	0.12
235.0839233	0.08
235.9942322	0.47
239.1424713	0.92
241.2355957	0.65
250.2921753	0.55
255.1634521	2.80
257.2824707	5.90
259.0667419	0.51
266.3133850	0.28
269.3285828	0.32
270.9530029	0.26
273.1439209	17.66
283.1103516	4.01
285.2781677	4.51
287.1104431	0.68
288.1997681	0.14
293.2218628	0.30
301.1832886	61.32
303.0820312	1.00
305.3372803	0.14
306.1055908	0.07
311.0932617	12.47
315.0198669	0.80
316.3078003	0.35
317.3705139	2.00
319.0744934	0.52
329.1002197	100.00
333.1934204	3.51
334.2634888	0.18
334.9140930	0.55
343.1416016	0.19
347.0092468	19.80
348.1050415	0.11
349.3152466	0.35
350.9460449	0.22
360.3279419	3.40
361.1811218	4.05
362.2463379	1.53
363.2583008	0.52
370.2038574	0.14
371.4477844	0.49
376.1372070	0.91
378.0609741	2.16
378.9786072	0.62
380.5605469	0.08
384.8609924	0.17
386.1969299	0.85
387.4765320	0.27
388.2162476	1.43
390.3797302	0.24
393.2777710	0.42
395.1786804	0.09
398.2989197	0.15
401.2878113	0.29
403.1619568	0.50
404.0400085	0.84
404.8253784	0.37
406.2955627	0.47
407.3908997	0.25
408.3000793	0.10
414.2165222	2.52
422.1199646	20.33
424.3951721	0.55
425.4018860	0.06
426.2286682	0.12
432.2270508	6.78
433.3749084	0.35
435.7496033	0.06
450.1709900	17.98
451.1452026	21.69
459.0625610	1.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	759.2347
Annotation	Adinoside D
Peak:m/z	Relative Intensity
222.9824066	0.09
254.0841675	0.23
289.1076050	0.04
311.3042603	0.10
325.4459229	0.11
329.1852417	0.04
357.3999023	0.16
365.4168701	0.12
366.3829346	0.03
387.1486816	0.07
395.0881958	0.04
397.3554077	0.03
411.2907715	0.10
416.9453735	0.02
429.2994995	0.14
477.2641602	1.04
485.0126953	0.07
507.1929321	0.37
508.2966919	0.12
519.2233887	76.44
519.8541870	0.43
522.4193115	0.08
531.2349854	2.22
531.9360962	0.25
532.9405518	0.04
534.3455811	0.22
535.4530029	0.38
543.3566895	0.16
545.6255493	0.09
549.3499146	100.00
551.4622192	0.03
561.3067017	4.52
567.5846558	0.12
573.5359497	0.06
575.2904053	0.07
579.2345581	43.55
585.3674927	0.54
589.4863892	0.03
591.1624146	2.51
597.5374146	0.13
599.1248169	0.08
603.3679810	1.97
609.2656250	1.80
615.0986938	0.20
619.3372803	0.05
621.2357178	21.72
621.9090576	0.13
625.4957886	0.06
633.3755493	1.64
639.2586060	63.67
651.2724609	18.31
663.4426270	0.73
669.2355347	15.77
675.1909180	0.10
681.3148804	0.98
693.3840942	0.05
699.4417114	0.09
705.4224243	0.15
711.5003662	0.06
713.3418579	0.35
715.4382935	0.05
716.0508423	0.05
723.4154663	3.02
736.8645630	0.21
741.2002563	14.03
741.8453979	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	549
Annotation	Unknow
Peak:m/z	Relative Intensity
191.7905273	0.19
206.8239594	16.89
208.9303131	1.57
210.9508820	0.47
213.0115662	0.45
227.1614227	0.09
252.2789764	0.10
264.1426392	0.05
265.0636902	0.24
270.3563232	0.15
292.9093018	1.98
294.8611145	3.19
296.3128662	1.44
297.0723877	0.47
298.4985962	0.30
299.2843628	0.09
310.3997192	0.07
323.1729126	0.06
334.8460083	0.14
336.3610229	0.43
356.0274658	0.06
358.7826538	0.05
361.1405640	0.28
362.2759399	0.98
363.0521240	0.51
369.0700073	0.33
375.0242310	1.92
376.6669922	0.52
378.9868774	16.20
380.8885498	25.13
382.3486328	0.10
383.1171265	0.07
387.2269897	0.18
397.3928223	0.06
402.2456055	0.07
406.0292358	0.07
410.5712280	0.27
411.1800537	0.15
413.1923218	0.53
415.8076782	0.68
417.4497681	1.03
418.7208862	14.94
420.3907471	0.13
421.1029053	0.10
422.1705933	0.12
426.7694702	6.50
427.4744263	2.23
428.5175781	0.24
435.4540405	0.43
450.9915771	0.14
454.6194458	0.25
460.7524414	0.21
462.6567993	17.02
464.1946411	14.82
464.8090820	94.37
474.9521484	0.71
476.4537354	0.43
482.1144409	0.78
483.9518433	8.94
484.9728394	1.48
488.9131470	0.29
490.9069824	2.13
492.3894043	0.30
494.7828979	0.14
499.8781128	0.25
500.4968262	1.09
502.0856323	6.57
502.7730103	100.00
504.5272217	0.47
510.2633667	0.13
511.7942505	0.21
519.9000854	0.17
525.4868164	0.10
530.3374023	0.30
531.0975952	1.24
532.4907837	0.36
539.8214722	4.31
540.4852905	0.98
541.1787720	0.12
548.4602661	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.1112
Annotation	Thiamine
Peak:m/z	Relative Intensity
80.0073166	0.07
80.9397888	1.10
84.7352905	0.09
87.0254059	0.06
97.0560150	0.02
104.2204742	0.04
109.7190094	0.57
117.1168365	0.03
121.9430542	100.00
125.9087830	0.71
127.2121124	0.03
129.0789185	0.03
137.9812012	0.06
139.8364868	0.03
143.8998871	53.68
144.5074005	0.08
155.9564972	3.32
164.0136414	0.03
177.1941223	0.06
190.9206696	0.63
207.0577545	0.07
209.0338745	0.10
224.1421051	0.07
234.2308502	0.02
246.9013672	0.07
247.9793243	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	666.0711
Annotation	Unknow
Peak:m/z	Relative Intensity
185.9926300	0.02
187.9466858	0.08
198.8360596	0.01
207.0942535	0.02
208.9467773	0.15
211.8269196	0.07
212.8746185	0.15
214.1144714	0.17
214.9908447	1.73
216.0951691	0.53
216.8956604	0.05
221.0921173	0.03
225.0820007	0.17
226.8720398	0.06
229.0333862	1.72
230.0095215	0.17
231.0531311	0.62
235.0692139	0.03
236.1056824	0.26
237.1634216	1.44
239.0808868	0.02
252.0080414	0.01
253.9012909	0.36
255.0269928	0.13
257.0243225	0.59
268.0558777	0.06
269.1016235	0.18
271.0892334	1.24
273.0559082	0.02
281.0594788	0.78
282.1519470	0.03
285.1751099	0.05
285.9390259	0.03
289.8544006	0.02
297.9689331	0.32
299.0847778	0.05
302.9612122	0.10
305.1340942	0.01
312.1828003	0.02
312.9765625	0.02
315.0989685	10.47
321.2359619	0.02
325.0957031	0.03
326.2006531	0.13
340.9319458	0.23
356.9089966	0.99
358.9912720	100.00
360.2091064	0.14
386.4603271	0.05
393.0216675	0.02
396.6681519	0.02
408.4492798	0.02
430.0651245	0.04
437.0377808	0.06
437.8733521	0.14
455.9508057	0.01
474.1791992	0.09
475.2236328	0.11
489.1934814	0.03
535.6676636	0.03
537.2336426	0.20
551.2462769	0.01
587.7434082	0.04
604.0016479	0.06
614.0686646	0.25
622.5495605	0.07
629.9810791	0.02
632.0183105	0.06
632.9948730	0.15
647.5597534	0.45
648.1790771	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	401.1088
Annotation	10-Dehydrogardenoside
Peak:m/z	Relative Intensity
112.8931351	0.01
116.0108795	0.03
128.9049377	0.10
130.9903717	0.02
132.0343628	0.02
139.1883087	0.02
148.8744202	0.07
151.0743561	0.59
156.1907043	0.02
156.9129028	0.13
172.9565735	0.04
174.9942322	0.31
177.0806885	0.10
187.1948547	0.08
191.1317291	0.19
193.1133575	0.24
205.0699768	0.45
207.2187653	0.14
209.0577698	0.01
215.2998199	0.01
217.1646423	0.04
223.2506714	0.23
225.0887451	0.11
227.3212433	0.02
231.1387024	0.28
236.9384460	0.01
238.5039978	0.04
239.3277283	0.06
249.1539307	5.43
265.0701294	0.06
267.0587769	100.00
267.8604126	0.02
277.0679321	0.10
279.1299438	0.03
285.3481445	0.19
286.3530273	0.42
287.1402588	0.02
292.2337036	0.01
293.3997803	0.03
295.0667725	0.37
295.8650818	0.01
309.3609619	0.03
311.0068359	0.03
311.9279175	0.03
314.1587524	0.01
315.4763184	0.02
317.1938782	0.02
324.9649048	0.07
328.2429199	0.04
339.1617432	0.05
341.0537720	0.06
353.9642334	0.06
355.2327881	0.20
355.9562988	0.02
357.2892761	0.09
365.0502014	0.05
381.7253723	0.03
383.1665955	2.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1059.5385
Annotation	Tricalysioside Q
Peak:m/z	Relative Intensity
305.2490540	0.26
321.3851929	0.17
323.0158997	0.07
349.3600769	1.14
367.2756653	0.03
483.3486328	0.19
511.3008728	0.95
513.5244751	0.05
529.3272705	100.00
529.9293213	0.42
572.2810059	0.14
894.6444092	0.05
899.3453369	0.10
1021.0883790	0.03
1025.8051760	0.09
1041.3022460	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	225.0752
Annotation	5-(3',4',5'-Trihydroxyphenyl)-gamma-valerolactone
Peak:m/z	Relative Intensity
66.8782806	0.02
70.2507629	0.02
79.0828400	0.01
81.0707016	0.04
82.9195251	0.02
84.9151459	0.02
89.8700867	0.01
96.0517578	0.02
99.0772552	0.01
99.8355866	0.07
104.9635773	0.03
107.0539093	0.02
109.2379761	0.01
122.9628906	0.03
135.0782623	0.01
137.0495453	0.02
138.9069672	0.01
145.0853271	0.05
147.0130768	0.12
151.0393066	0.03
152.1087036	0.02
161.0277252	0.09
163.2551727	0.02
165.0856781	0.11
166.7220917	0.02
178.9453278	0.06
181.0208282	0.21
181.8982391	0.03
183.1487885	0.10
184.0581207	0.03
189.0020599	0.14
190.1808929	0.03
194.0859222	0.02
195.0969238	0.26
201.0003815	0.06
201.8286285	0.01
204.1024475	0.08
207.0444183	100.00
208.0738678	0.03
210.0273438	0.04
213.9458160	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	535.1882
Annotation	Unknow
Peak:m/z	Relative Intensity
157.0047302	0.04
159.4294434	0.06
170.8009033	0.02
172.9785919	0.11
175.0857239	9.73
179.0269318	0.06
191.0971680	4.96
193.0105591	100.00
194.0661163	0.07
209.0188293	7.18
211.0783539	0.09
256.9255066	0.04
266.9943237	0.04
282.8204956	0.02
312.9544067	0.13
317.3053589	0.06
323.1315308	0.91
325.2634277	0.72
327.2409668	0.02
329.8973389	0.14
341.4336548	0.02
342.5634766	0.15
355.0908203	0.15
356.0352173	0.05
358.9776001	0.02
373.1591187	0.03
385.1893921	0.23
401.9545288	0.02
403.1817017	0.25
421.0769043	0.04
455.0295410	0.09
457.0189819	0.06
517.1996460	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	589.2498
Annotation	Serrulatoside
Peak:m/z	Relative Intensity
203.2297363	0.02
227.1909485	0.03
245.1263428	0.04
281.4749756	0.04
310.2611084	0.20
331.9133911	0.07
333.2664185	0.05
341.3794556	0.03
351.1794434	0.18
370.9655762	0.06
381.2221069	0.13
388.2911377	0.02
389.2141724	0.43
390.4578247	0.04
392.0764160	0.06
397.1965942	0.02
408.9994507	0.09
419.3469849	0.09
421.6393433	0.13
423.1165161	0.02
427.2709351	0.07
443.2514648	0.03
445.1832886	0.05
453.2339478	0.03
459.1764526	0.03
469.1144409	0.05
497.0458374	0.10
513.1553345	0.14
526.8513794	0.23
543.3193970	100.00
544.0350952	0.25
545.0281372	0.14
553.3027344	0.04
567.4024048	0.17
570.3590698	0.19
571.2926636	0.19
572.2987061	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	383.2074
Annotation	Perseanol
Peak:m/z	Relative Intensity
151.1782684	0.24
153.1106110	0.11
179.0805511	0.80
199.3560791	0.03
221.5547180	0.05
227.0044861	0.08
235.3570557	0.08
241.3918762	0.10
243.2149658	0.51
245.2466736	1.76
247.2775574	1.29
248.2788086	0.09
257.1512146	0.51
259.2825623	0.91
263.2480469	0.12
265.2084961	0.16
273.3864441	0.03
275.3363953	6.80
277.4213867	0.15
285.2419434	1.36
286.5156250	0.03
289.2759094	3.26
290.3115845	0.06
293.1445923	0.46
295.2660828	0.04
301.2327576	0.21
303.3406372	4.46
304.4113159	0.12
319.3417664	12.57
321.2923584	3.92
329.2298279	2.33
330.2408752	0.18
337.4073486	0.05
339.2730103	100.00
340.3710938	2.06
345.2869873	1.73
347.2449036	33.66
348.1944580	0.31
363.1762390	0.03
365.2243958	52.13
366.4084778	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	416.1906
Annotation	Unknow
Peak:m/z	Relative Intensity
129.1239319	0.04
147.8494415	0.05
162.9703217	0.09
174.8533020	0.13
186.1325073	0.33
201.1486816	0.16
211.3503418	0.17
226.8991394	0.33
238.1968079	0.09
253.0469055	0.06
255.1165771	0.11
267.1275330	0.11
285.3030701	0.45
286.2700500	0.03
287.1737976	0.06
293.3249512	0.23
299.1858215	0.54
303.2391357	0.24
305.3502502	0.04
315.3831177	0.21
317.8427124	0.33
327.1293640	0.17
334.8965454	1.12
338.9382935	0.05
344.6784668	0.49
347.2684021	0.28
353.0101624	0.25
354.0181885	0.12
363.0079651	64.75
363.6082458	0.62
366.1589355	0.24
370.1301575	0.26
370.7658386	0.30
372.3274231	0.88
373.4071960	0.16
374.1558533	0.27
375.3470764	0.76
376.8650818	0.11
379.1562195	0.54
380.9358826	100.00
381.9302673	0.44
385.7480774	0.29
388.0629578	0.16
398.0415039	2.10
398.9373474	6.32
399.5848389	0.09
406.6011658	0.70
408.1930237	0.49
415.3045654	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.2761
Annotation	Canavalioside
Peak:m/z	Relative Intensity
217.2663574	0.01
227.8684235	0.03
259.0029297	0.03
313.1871338	0.01
327.1525879	0.01
349.6316528	0.01
351.2470703	3.28
351.8516235	0.03
357.2274780	0.02
381.2991943	0.01
383.1627808	0.01
393.0653076	0.05
397.4598999	0.02
405.4207764	0.02
435.2606201	0.02
437.8430786	0.01
439.4813232	0.06
447.2432861	0.02
457.6456909	0.03
461.2158203	0.01
462.8687744	0.03
469.0576172	0.01
472.8220825	0.01
480.9992065	0.02
497.3032227	0.14
499.5682983	0.02
513.3320312	100.00
515.4404907	0.10
521.1753540	0.04
523.0484009	0.11
523.8818359	0.01
540.5929565	0.13
541.2662964	0.14
544.3491821	0.02
559.2308960	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1688
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
93.15422821	0.05
98.80679321	0.19
119.1039429	0.38
153.210083	0.17
170.0227661	4.97
171.1407318	0.26
176.9512939	0.04
178.823761	0.23
183.0138855	100.00
184.0330048	10.21
185.06073	0.08
189.1544647	0.09
190.1155701	0.04
194.8165283	0.05
197.073761	2.28
198.0833435	2.73
199.1257629	0.13
209.0711365	0.04
210.9787903	1.32
212.0610657	1.59
213.1331787	0.30
217.1622925	0.16
225.2155457	2.18
226.1088562	1.98
226.8977966	0.17
231.1369934	0.04
235.4897156	0.24
239.1896057	3.11
240.0942993	1.26
240.9669495	0.14
247.2515869	3.79
248.3308105	0.16
249.2479248	0.32
253.0489502	0.68
253.8846741	0.25
256.8270874	0.09
261.2749023	0.13
265.2870178	0.07
267.2913208	1.36
268.1680298	0.14
269.3152771	0.12
275.0510864	0.13
281.1461792	0.08
283.050293	0.07
293.2662354	1.38
311.2140503	16.78
312.2537231	2.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	397.1501
Annotation	Methyl (3x,10R)-dihydroxy-11-dodecene-6,8-diynoate 10-glucoside
Peak:m/z	Relative Intensity
114.9622192	0.27
116.9259644	0.77
118.8694000	0.07
131.0646973	0.31
143.0880127	0.18
152.9666138	0.06
158.1537323	0.09
173.2309265	1.25
175.9312744	0.10
189.1748505	0.33
191.1972656	3.86
192.3937378	0.06
205.1645050	0.84
209.4537964	0.04
211.1640625	0.14
217.1382141	7.93
229.2138367	0.61
233.2327881	0.65
235.1826477	51.27
236.2521057	0.95
247.3009338	2.47
249.3645020	0.10
251.3403625	0.09
253.2782288	0.07
254.9963074	0.15
261.0985718	4.52
263.3033447	0.49
265.1187744	1.09
273.2741699	2.38
279.0993042	2.73
287.5005188	0.07
289.1550903	0.26
291.2208557	17.87
292.2210388	0.24
305.1672668	0.14
307.2131348	0.07
309.3163757	26.17
310.3993835	0.67
317.1684265	1.04
325.5789185	0.21
333.0604553	0.16
335.2276611	70.50
336.1667175	1.29
351.3804016	0.52
353.2287598	100.00
354.3147278	1.82
361.3487244	0.06
367.2981873	0.19
369.2544861	0.06
370.3168030	0.04
379.2745056	28.10
380.1511841	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
85.07374573	0.80
96.86149597	1.72
101.0159149	1.39
110.3400116	0.53
116.8463898	0.47
143.22612	0.86
144.90242	0.44
154.90065	0.31
160.9881744	0.83
173.9603271	0.29
179.2308197	0.52
180.9084778	1.41
182.888916	0.43
185.1946259	0.31
189.2218475	0.42
190.9267883	0.37
195.3265839	0.93
207.1504822	7.91
208.1679993	2.50
209.188736	3.63
222.2934723	0.50
223.1195831	2.73
231.1095581	0.48
233.1061249	3.19
236.0573883	0.93
251.0752563	100.00
252.1499023	13.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	657.3562
Annotation	Unknow
Peak:m/z	Relative Intensity
203.2891693	0.13
220.2202301	0.11
262.2796631	0.07
281.2577209	0.31
291.2173462	0.17
332.9688721	0.08
348.9619751	0.35
362.8531494	0.05
415.5944824	0.14
418.7564697	0.47
429.1552734	0.39
430.7274780	0.15
449.3688354	0.20
455.8909912	0.05
459.6872559	0.05
470.9175415	0.14
473.1835327	0.16
484.9884644	0.19
494.5604248	0.54
495.2578125	0.33
496.9385376	0.05
509.0768433	0.15
510.2858276	0.16
510.8953857	0.25
513.2897339	0.44
527.1917725	0.12
531.6260376	0.28
549.1961670	0.50
561.2752075	0.04
571.4318237	0.48
594.7115479	0.19
621.3712158	0.08
624.1402588	0.37
639.3993530	100.00
640.0914307	0.27
644.2729492	0.24
648.4317017	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	147.11
Annotation	Lysine
Peak:m/z	Relative Intensity
72.8624878	0.01
83.9850006	1.91
101.0544281	0.14
111.9013214	0.03
115.2835846	0.02
129.1510773	13.72
129.9379120	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	629.26
Annotation	Swietmanin D
Peak:m/z	Relative Intensity
193.0061340	0.42
211.2267303	0.08
217.1179962	1.22
225.0470734	0.13
225.8580780	0.13
235.2056427	0.07
239.2950897	0.14
240.1679077	0.07
242.2279053	0.13
243.0673065	0.17
245.1051483	0.24
262.1704102	0.07
289.2466431	0.38
314.3257446	0.13
315.4425049	0.54
321.1268311	0.24
323.2764893	0.20
351.4617310	0.08
352.1636963	0.34
356.3114624	0.12
369.2819824	1.49
374.8613281	0.25
383.3248901	1.64
394.1245117	0.25
401.0510254	2.34
401.6854858	0.14
418.7055664	0.78
421.1989136	0.41
431.1923828	2.80
433.4093628	0.18
436.3840942	0.09
438.8584595	0.23
441.1022339	0.29
443.3869019	0.13
446.2463379	0.53
448.3574829	0.33
449.5222168	0.90
457.2220459	0.31
458.8195190	0.72
462.1632690	0.09
462.9526978	0.91
464.4877930	0.24
467.0355225	1.53
477.0056763	0.26
478.2695923	0.51
482.0130615	0.33
485.1094360	0.11
492.4959717	0.30
498.1969604	0.30
500.5770874	0.62
503.7049561	0.12
508.0851440	0.42
511.1694336	0.34
514.5415039	0.50
516.9036255	0.25
526.1970215	0.35
528.0896606	0.14
531.3682251	0.84
538.8701782	0.33
544.2100830	0.13
547.3577271	0.52
548.0366821	0.22
549.2149048	0.20
556.9886475	0.39
561.3546143	0.09
564.6952515	1.44
565.4017334	4.35
570.0720825	0.80
573.2911987	0.31
574.8182983	0.42
579.1627808	0.62
581.6151123	0.48
583.1634521	100.00
584.1246948	0.36
585.3132324	0.11
593.2570190	1.08
597.2226562	0.35
599.3731079	1.23
600.8866577	0.06
605.1224976	0.40
608.5339355	0.15
611.1232910	12.33
611.7613525	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	411.0236
Annotation	Turgorin
Peak:m/z	Relative Intensity
125.0182037	1.29
138.8876953	1.06
143.0448761	0.07
151.0872345	0.17
165.0419617	0.03
166.8167725	0.09
169.0144348	9.73
170.0419922	0.16
179.0942688	0.42
180.9896851	0.17
187.1752014	0.06
191.0810242	0.08
192.9222717	0.14
196.2180176	0.22
199.2948608	0.31
201.9190521	0.13
221.2051849	0.12
222.9082642	1.30
224.2369080	0.15
233.5527954	0.05
235.1249084	0.07
241.0757141	100.00
242.0671082	0.78
246.3214722	0.22
249.0969849	0.22
249.8127441	0.28
251.2199402	0.08
252.8873291	0.05
259.2870789	0.39
272.9932251	0.13
279.1959534	0.63
287.3065491	0.26
305.2208252	0.27
307.3705444	0.15
309.3632202	0.06
313.0137329	0.10
321.1562805	0.73
323.1761169	0.32
331.0871277	8.71
332.6610718	0.24
341.3000488	0.05
344.9356079	0.27
346.9776306	0.06
349.2123413	0.93
351.0596924	0.10
353.5751343	0.10
363.3564758	0.17
365.4629822	1.00
367.1528015	3.08
368.2939758	0.23
377.3561096	0.03
391.1031189	0.37
393.1879578	6.20
394.1618042	0.11
410.8644104	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	530.27
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0186157	0.63
160.9299011	0.11
180.9070435	0.23
187.2476349	0.07
192.2760315	0.38
194.1479492	0.88
205.2958679	0.12
215.0709229	0.47
217.2038116	0.12
218.0887451	0.41
231.2292786	1.97
232.1800842	1.10
233.4057465	0.13
240.3606567	0.53
244.0260468	0.30
246.2574768	0.09
247.3828583	0.18
252.3869934	0.18
254.0922852	0.19
256.4246826	0.12
258.2015076	0.26
260.2583923	0.37
262.8352051	0.20
268.0480347	0.42
269.2427673	0.23
270.2697144	0.96
271.2457275	0.17
272.2679138	0.39
273.5347900	0.17
275.4548950	0.35
276.3646545	0.38
279.2172852	0.23
284.6509399	1.14
285.2794800	1.11
286.2192993	2.71
287.3948975	0.09
288.3927612	0.34
289.4306641	0.23
290.3762512	0.06
291.4300537	0.30
301.3638916	0.53
303.2840576	3.43
304.2401123	4.54
305.3638306	2.40
306.2462769	2.93
308.3207397	0.21
313.3537598	0.27
313.9895630	0.15
316.3901367	0.84
319.0524902	0.19
320.2183228	0.45
321.1681519	0.17
324.1701660	0.07
330.1397705	0.10
331.1790161	3.18
332.2891846	11.18
333.2471313	2.10
334.1908569	1.19
337.0958862	0.22
338.6163940	0.40
346.4356079	0.13
347.2403564	3.73
348.4952393	10.90
349.3713379	32.96
350.3602905	79.18
351.3142090	3.60
362.2233276	0.17
365.3646240	7.65
366.3551636	7.89
367.2315674	38.69
368.2994995	100.00
369.2606812	5.42
428.4460449	0.22
466.5959473	0.72
483.7301025	0.12
484.4771118	0.05
494.4442749	0.65
500.4334106	0.53
510.3431396	6.86
511.2904053	5.02
512.3400269	48.59
513.3261108	3.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
82.81920624	0.20
97.0040741	0.07
101.0915222	1.17
110.7927399	0.18
113.3780518	0.21
127.2085724	0.11
137.9221649	0.16
149.1304169	0.22
155.1195984	0.24
160.0443878	0.11
167.3307037	0.12
174.3345642	0.26
181.1605377	0.59
183.1773529	0.19
189.5355988	0.12
191.0184174	0.22
193.2020569	0.40
195.2100983	0.78
206.0185089	0.38
207.1900482	4.26
208.103775	3.35
209.0978851	1.27
215.0539398	0.20
221.9498749	1.47
223.1904907	2.88
224.0279083	0.84
233.0112915	1.05
234.4184113	0.17
236.2924042	1.16
251.0841064	100.00
252.1195221	17.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	384.2214
Annotation	Unknow
Peak:m/z	Relative Intensity
127.0102539	0.08
131.9510193	100.00
132.9230347	0.14
134.0270081	0.15
145.0410156	0.09
161.9533234	0.15
162.8436890	0.52
166.2786865	0.06
169.1452942	0.06
199.2305298	0.08
203.9201050	0.17
217.0711975	0.17
218.1601105	0.10
221.1276703	0.03
221.8329926	0.30
222.4704285	0.09
235.3858948	0.05
252.9172974	3.83
264.1804810	0.15
272.4153748	0.15
278.2064819	0.13
278.9472656	0.07
293.9797668	0.12
295.3469543	0.10
297.3031616	0.03
337.3584595	0.07
348.1364441	0.03
354.2129517	0.07
366.1139221	1.00
374.8299561	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	301.2155
Annotation	Angustanoic acid A
Peak:m/z	Relative Intensity
91.0434952	0.04
92.8680878	0.20
95.0440979	0.87
96.8352508	0.04
100.7377319	0.06
104.9984741	0.15
106.9913635	1.25
108.9962311	2.03
110.0309601	0.17
110.9850311	0.16
112.9562836	0.04
114.9969330	0.18
116.0709076	0.03
117.1437912	0.04
119.1169891	0.22
121.0856094	0.51
122.9943085	0.48
127.1452484	0.05
128.2173157	0.05
131.0303955	0.46
132.9548035	1.19
134.5995941	0.03
135.2323608	0.12
137.1224365	0.27
139.1800537	0.11
142.8111115	0.03
144.9934998	3.05
146.2996521	0.04
147.1056213	1.80
149.0803833	0.90
151.0748749	0.64
155.0351868	0.02
158.9956207	3.49
161.0644989	1.40
163.0823059	0.64
164.8169098	0.30
169.3898468	0.04
170.6379700	0.06
173.1017609	2.33
174.9247437	0.28
176.8696289	0.12
179.0737457	3.53
183.0975952	0.33
185.0818176	0.73
187.0813904	0.51
189.1522064	0.29
191.1101990	1.39
193.1530914	3.84
195.0435944	0.70
197.2033234	0.08
199.2019653	1.71
201.0793762	0.28
203.1643677	0.22
205.0765686	3.94
207.1842346	2.16
209.0804749	0.42
211.3986511	0.21
213.1952820	2.11
214.1838074	0.15
215.2539978	0.34
217.0459595	0.16
219.0429382	1.45
221.1137085	2.00
223.2243958	0.04
225.2105103	0.15
227.0841675	5.19
227.6856384	0.02
229.3738098	0.09
231.1648560	0.83
233.2147522	0.04
237.0281982	0.21
239.1093750	0.23
240.2219543	0.06
241.1749878	0.71
241.9604492	0.04
242.7352295	0.14
244.5982361	0.08
245.2047424	3.24
253.3590698	0.01
255.1506042	100.00
255.8739014	0.31
257.2059937	0.40
259.1489563	0.74
259.9162598	1.40
263.1614075	0.04
265.2137451	3.30
266.1884766	0.06
269.9243774	0.02
273.2114868	4.19
277.7269287	0.20
280.4908752	0.68
283.2210999	35.11
284.3253174	0.59
292.1571655	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	548.6934
Annotation	Unknow
Peak:m/z	Relative Intensity
163.0034332	0.04
182.1906738	0.08
207.2881165	0.22
213.2016296	0.10
221.2072754	0.16
226.3914490	0.16
231.0897217	0.06
233.1505127	0.20
239.2370911	0.01
243.2404175	0.10
248.3020172	0.18
255.0389404	0.10
255.9790955	0.42
257.1849976	0.16
258.0380859	0.05
260.3006592	0.16
261.1652222	0.06
262.2226562	0.05
264.8270264	3.50
265.7533569	0.22
272.2418213	0.20
277.2864990	0.10
278.9430542	0.93
285.2026367	0.03
295.2376099	0.07
296.2850952	0.04
298.3969421	0.11
304.7703857	0.19
307.5582886	0.12
312.2169800	0.05
313.3916626	0.03
321.2267456	0.16
330.3162231	0.18
365.1672363	0.07
367.4928589	0.07
374.2427368	0.16
383.4727783	0.10
392.3898926	0.19
402.6079102	0.09
419.5487671	0.05
428.9936523	0.01
430.1315918	0.07
446.6481934	0.27
455.0814209	0.39
462.8023682	0.05
474.1463623	0.23
479.2662354	0.24
480.0941772	0.76
483.1045532	0.29
484.0473022	1.25
484.8220215	0.43
486.2463989	0.16
487.6488647	0.12
488.6632690	0.13
493.5148315	0.14
496.1519165	0.12
501.6360474	2.05
503.1886597	0.08
504.2592773	1.10
506.7722778	0.28
508.3710327	19.17
509.6601562	0.12
512.4303589	3.26
513.3786621	0.46
514.0604248	0.46
514.6919556	0.36
516.0950317	1.62
517.0167847	0.05
518.0354614	0.36
519.1565552	0.62
520.5203247	2.36
521.4685669	0.28
522.4454956	0.16
523.5272827	1.09
524.1877441	0.20
526.7496948	0.44
528.3179321	1.09
530.0640869	0.61
530.9786987	0.35
531.8135376	0.15
533.7102661	1.33
534.8439941	1.17
536.0304565	0.99
536.6591187	0.23
538.0015259	9.21
538.7628784	1.32
540.6690063	6.65
542.1691284	6.80
543.0346680	1.00
544.6699829	0.05
550.8754272	0.02
565.7035522	0.04
570.7507935	0.71
575.5200806	0.06
576.2554932	0.04
580.5270996	0.10
586.9564209	0.14
590.0334473	0.19
592.9567261	0.23
606.7197876	0.53
607.9597168	0.14
608.6713867	0.16
614.0775757	0.29
615.7964478	0.48
620.5562744	0.06
622.2899780	1.57
622.9757690	0.30
623.6293335	0.21
624.6867676	0.29
625.6898804	0.27
627.5070190	0.10
628.6409302	0.60
629.3279419	0.19
631.1188354	0.96
633.3862915	0.67
634.0538940	1.21
634.9901733	0.76
635.7907104	1.17
636.6273804	0.71
637.2788696	1.87
637.9301147	0.47
639.0740356	0.85
639.7994385	1.56
640.9216919	0.42
642.6940918	0.51
644.9499512	8.88
645.7961426	8.99
646.7565308	0.61
648.7161865	0.48
649.7445679	0.44
652.2583008	0.27
653.3305664	0.04
655.1393433	0.20
656.7323608	0.29
657.3660278	0.95
660.3217163	0.30
663.1035767	0.55
664.4705811	0.33
665.3396606	0.07
666.2334595	0.70
668.2533569	1.47
669.1945190	0.40
671.5213013	8.04
672.6057129	2.38
673.4624023	0.15
677.0582886	6.57
677.7205811	100.00
679.1504517	1.55
680.3057861	0.67
680.9515381	0.19
682.5460205	0.57
683.1553955	0.09
685.0618286	0.55
686.2077026	2.42
687.3096313	0.46
688.0383301	0.34
688.7360840	0.63
689.7481079	0.08
692.2456055	0.29
693.5470581	0.61
694.3333130	0.21
697.7150269	0.12
698.7052612	0.22
699.3242798	0.17
702.3051147	0.10
703.3163452	0.33
711.4719238	0.10
712.4619751	0.11
715.1847534	0.25
716.8076172	0.39
720.9708862	1.67
721.8228760	0.18
726.5184937	2.29
727.4353027	0.09
728.6046143	0.04
733.3907471	0.17
737.4666138	0.21
738.5509644	0.17
744.9937134	0.16
757.0502319	0.13
761.2406616	0.28
777.2423096	0.04
781.0541382	0.13
782.7003174	0.17
784.3190308	0.24
791.0946655	0.62
792.9638062	0.04
797.9523926	0.06
802.9631958	0.16
810.9397583	2.24
811.8425293	0.74
812.8576660	0.22
813.5346069	0.23
814.3874512	0.05
815.4365234	0.05
819.5045166	3.60
820.5868530	1.38
841.4037476	0.13
848.5197144	0.06
849.5140991	0.24
853.5902710	0.08
854.6499023	0.31
855.7422485	0.34
858.7645874	0.05
864.8410034	0.22
868.9247437	0.25
869.5990601	0.11
879.4394531	0.12
886.3732300	0.07
890.3484497	0.15
951.1235962	0.02
953.2373047	0.13
972.3779297	0.03
1005.9638060	0.20
1059.3164060	0.06
1110.7536620	0.09
1134.3795170	0.04
1177.5574950	0.06
1246.4543460	0.06
1346.4462890	0.04
1811.0301510	0.05
1894.1340330	0.05
1947.4945070	0.02
1954.9678960	0.29
1991.2225340	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0878
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
107.9597244	1.01
119.9815674	0.04
123.0248795	1.38
129.3462067	0.03
133.1728973	0.07
148.6319580	0.02
152.0284424	3.21
161.1558990	0.09
166.9541321	100.00
173.0925598	0.04
176.9326935	0.01
181.2119598	0.04
208.9895020	0.12
213.4589539	0.05
214.4314575	0.02
233.0239563	0.07
234.9504700	0.02
237.0917969	0.02
250.9519653	0.17
255.2127075	0.06
266.3362122	0.01
268.9927979	0.03
282.9572144	0.17
284.6881104	0.20
285.3099976	0.28
291.4061279	0.03
295.0282288	0.07
309.1286011	0.03
311.0999146	0.32
313.1246033	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.09
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
73.0369873	0.39
76.71637726	0.53
78.64822388	0.63
80.88764954	3.84
82.93508148	2.47
84.896698	1.40
87.03246307	0.62
91.13428497	0.13
93.02355957	0.78
94.96974182	3.97
97.29844666	3.16
98.97671509	0.34
100.2767639	0.57
101.1296082	0.25
102.9400177	1.57
107.0573883	0.69
109.0126953	1.08
111.1426544	2.48
115.0171967	0.93
119.0632935	1.58
120.1435699	0.68
121.0110168	1.60
123.0083008	4.11
124.2309723	1.24
125.1959229	0.79
126.9644318	2.04
128.9711304	8.98
131.1039124	0.37
133.0643921	4.43
135.0817261	2.84
136.9985199	2.36
139.0521545	2.62
141.0121613	3.21
143.0312042	0.34
145.0375519	3.70
147.0790558	5.42
148.8547363	2.89
150.9369354	56.17
152.1848602	4.08
153.2214508	0.59
153.8862915	0.19
155.0630035	4.39
157.1354828	3.07
159.0167084	2.96
160.9263458	2.01
162.934494	0.71
165.1405334	2.17
166.0593414	0.17
167.2354126	1.47
167.9573364	0.87
169.1096039	6.66
170.0193634	0.25
174.7398682	0.74
177.0943909	5.55
178.0965118	1.40
179.1182404	5.25
183.0557098	4.83
185.0077667	0.74
189.2300415	4.45
191.2145081	0.22
193.1446075	2.99
194.0691986	0.39
195.2017059	4.45
197.0124969	14.12
199.0805206	1.02
202.9151764	0.19
204.9640045	0.23
207.1939545	7.09
208.8773499	1.15
210.0657196	0.25
211.2632599	7.54
212.1094208	0.24
217.0382996	17.49
221.0827942	0.39
223.0366821	1.26
225.1838684	13.94
226.0533905	0.67
235.1864471	51.69
238.0877838	5.45
239.1493378	0.96
253.0911255	100.00
254.1833038	12.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	763.21
Annotation	Unknow
Peak:m/z	Relative Intensity
289.2933350	0.03
307.2266235	2.56
321.1873169	0.10
322.7901306	0.06
325.2324219	1.35
338.0897217	0.31
343.2111206	0.07
349.1573181	0.31
364.8357544	0.03
376.7434692	0.04
377.4337769	0.04
411.3042603	0.04
421.2293091	0.12
439.1638184	1.50
440.8070068	0.10
449.2246094	0.13
457.2482910	0.35
463.5634155	0.06
467.0204468	0.16
479.2084961	0.04
481.4183350	0.28
493.2917480	0.93
499.2797241	1.82
509.1738281	0.06
511.3489990	1.75
526.0003662	0.15
527.4316406	0.11
529.1544189	0.06
535.1672974	0.30
541.2229004	0.69
553.1436157	10.70
553.8945923	0.22
559.9967041	0.08
569.4905396	0.06
571.2163696	16.75
583.0494995	0.11
589.1809082	1.95
595.3430786	0.28
607.4598999	0.09
611.1835327	0.11
613.2100220	1.82
617.3276367	0.06
625.2380981	1.52
629.2040405	0.10
631.2973022	27.84
633.4797974	0.54
643.1900635	3.52
655.5062866	0.10
661.3419189	0.78
665.0460205	0.36
667.2413940	0.79
673.2684937	1.75
685.2319946	36.24
685.9265747	0.05
701.8488159	0.10
703.1686401	100.00
703.9728394	0.63
715.3297729	0.23
719.0824585	0.43
721.3534546	3.91
727.2828369	0.10
733.3107300	0.10
745.1976929	1.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	779.3701
Annotation	(-)-11-hydroxy-9,10-dihydrojasmonic acid 11-beta-D-glucoside
Peak:m/z	Relative Intensity
239.3143616	0.09
240.8003998	0.01
269.1766357	0.03
272.2576904	0.04
281.2608643	0.03
311.3076782	0.02
329.3380737	0.03
341.3568115	0.04
371.3201904	1.24
375.2132568	0.02
378.1746826	0.01
389.1901245	100.00
390.3929443	0.03
397.4199829	0.11
407.5030518	0.07
411.5274048	0.01
413.1016846	0.02
417.3424683	0.11
443.0505371	0.04
445.9863892	0.04
521.3121338	0.02
524.4091187	0.01
529.2371216	0.04
537.2663574	0.34
551.1866455	0.06
581.0684814	0.27
587.2540894	0.10
589.2134399	0.30
605.8777466	0.20
617.2335205	0.05
664.6159058	0.13
685.0106812	0.08
692.2412109	0.04
696.1735229	0.03
702.3449097	0.03
716.4721069	0.03
732.3121948	0.04
735.9920044	0.08
739.4093018	0.07
744.2721558	0.04
758.3828125	0.02
761.3196411	0.76
770.1494751	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	763.1886
Annotation	Unknow
Peak:m/z	Relative Intensity
220.9300079	0.08
241.1573486	0.08
250.7571869	0.05
259.1257629	1.24
263.0097961	0.13
279.7373047	0.07
292.9703064	0.20
322.9526367	0.34
328.8581543	0.15
341.1396484	4.92
344.8108521	0.15
345.8015747	0.07
346.9842529	0.08
383.2373657	9.45
410.8723755	0.07
412.7137451	1.62
413.3470459	0.10
425.2442017	0.07
442.7120972	3.76
443.3486938	0.15
467.1123657	0.37
473.3276367	0.30
485.2476807	4.08
502.9336548	4.26
541.0302734	0.23
545.2925415	0.54
583.1129150	3.07
587.1755981	0.75
588.7954712	0.12
591.4489136	0.13
593.2302246	0.49
601.2202759	10.15
605.2150269	0.12
626.9391479	0.35
630.8513794	0.42
665.3059082	100.00
726.8230591	0.10
745.1974487	17.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
79.0495224	0.23
95.14849854	0.50
101.1982422	0.20
118.9961853	0.38
123.0340271	0.33
149.2614288	0.28
169.1390839	0.20
179.2289276	0.11
180.1421509	0.11
183.2166443	0.09
189.1147461	0.08
191.2412567	0.24
193.0420074	0.19
194.0783081	0.18
195.2560883	0.35
197.126709	0.29
206.1598816	0.62
207.1687775	2.88
207.9817963	2.49
209.1388855	1.54
214.9093781	0.45
222.1883392	2.06
223.1761932	2.67
233.0147858	3.00
234.9488525	1.02
249.33815	0.10
251.0775757	100.00
252.1435699	20.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	567.2294
Annotation	Unknow
Peak:m/z	Relative Intensity
163.2762909	0.05
165.0877075	0.57
166.7964630	0.20
179.0781555	1.05
181.2480469	0.81
183.0937195	3.28
194.9628754	0.25
199.2609558	0.45
209.1809082	0.13
220.8795319	0.09
225.2063751	4.70
226.9666443	0.32
243.2253418	100.00
247.2021027	0.11
249.1447906	0.53
255.2456970	0.11
257.0830383	0.12
261.1898193	0.07
267.2873840	0.27
279.2840881	0.87
285.3094177	2.03
291.0456543	0.14
293.1049194	0.17
296.2507324	0.22
297.2305298	0.50
299.3012695	0.34
315.1403809	3.66
317.1322021	0.31
323.1397095	3.90
325.2885742	0.11
327.2440186	1.38
341.1602173	56.26
343.0156250	0.06
345.2432251	11.69
346.5016479	0.22
353.2912598	0.37
357.1192017	4.17
369.2944336	0.09
375.1148071	1.26
383.1613770	4.90
387.1914673	5.80
391.2216187	0.13
403.2910156	0.37
405.2770996	74.13
406.7693481	0.38
421.1182251	0.33
427.6338501	0.16
429.4775391	0.36
437.3444214	0.10
447.0155640	0.28
450.2995605	0.12
451.2959595	0.08
464.1690674	0.52
468.1052246	0.05
518.9362183	0.22
519.6686401	0.23
521.2525024	1.65
523.3104858	0.52
529.4354858	6.33
530.2885742	0.61
531.3289795	2.20
537.2960205	0.16
549.3482666	33.88
551.8244019	0.41
557.9791870	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	831.467
Annotation	Unknow
Peak:m/z	Relative Intensity
299.1651917	0.17
313.5498047	0.07
344.9562988	0.06
347.0342407	0.61
362.9664307	0.49
365.8495483	0.29
390.3311157	0.46
403.1868286	0.69
405.1105957	2.26
413.3003540	9.84
414.2741699	0.78
464.8764648	0.07
475.1950073	0.19
497.4725342	2.07
498.3218994	0.34
507.5543213	0.67
508.5042725	0.18
515.1298828	0.05
519.5654907	0.10
563.6690063	0.22
573.3975220	0.04
575.3135376	100.00
576.4246216	11.61
580.3508301	0.17
599.8087158	0.10
625.2844849	0.09
659.4591675	46.85
660.4863281	7.28
669.5103760	15.02
670.6273193	1.67
693.8416138	0.03
699.3771362	0.20
711.8332520	0.35
725.5460815	0.04
768.1719971	0.13
793.1072388	0.15
813.5352783	0.77
815.4720459	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	333.2051
Annotation	Rabdokunmin D
Peak:m/z	Relative Intensity
94.9137726	0.60
104.9955673	1.19
107.0396271	1.23
108.9981232	2.52
110.9320526	0.45
113.0822449	0.39
114.9891663	0.12
116.8052673	0.21
119.0683899	2.84
121.0451202	3.31
122.9419250	1.67
125.0745392	0.24
127.1275253	0.13
128.1066132	0.09
128.9962769	0.06
131.1564026	1.03
133.1365051	2.04
135.0665283	7.97
137.1020355	2.46
138.9089661	1.40
142.0360870	0.21
143.0492401	0.28
145.0241089	2.36
147.0831146	2.14
148.9987488	2.66
150.9703979	0.35
153.0010681	0.73
154.9738770	0.38
155.7176208	0.28
157.0905457	1.18
159.1874542	2.40
161.0926971	3.02
163.1433411	1.08
165.1094360	1.85
167.0648499	2.19
169.0396423	0.67
171.1141205	0.34
173.0303955	1.43
175.0686493	0.73
177.0939026	2.90
179.1782837	2.43
181.0795746	0.55
184.0058746	0.11
185.1325989	2.18
187.0435181	0.94
189.0992584	0.66
191.1132660	0.53
192.9390259	1.25
193.5466919	0.04
195.0568390	3.94
197.1275024	1.45
199.1788940	1.43
201.2198334	0.87
203.0784912	0.82
204.9225616	0.91
206.8158569	0.08
207.4488525	0.07
209.1729736	2.13
211.1604004	0.18
213.1304321	2.50
215.0913391	1.51
217.0972900	1.48
219.2629700	0.56
221.2148132	0.85
223.1427917	3.50
225.3556519	0.09
227.2109985	2.57
229.0877991	0.89
231.1940918	1.86
233.1229248	0.32
235.1240845	0.24
237.3580322	0.60
239.1147461	2.39
241.1616516	29.12
241.7824402	0.11
243.2907410	10.24
245.2075500	1.34
249.4186096	0.18
251.1684570	24.23
253.2630615	1.62
255.1328735	1.47
257.2116394	3.78
259.2329102	18.56
259.8623657	0.03
261.1077271	0.42
263.1984863	0.74
269.2218018	74.72
271.2343445	1.38
273.4799194	0.28
274.8415222	0.20
279.1583862	2.16
285.2531128	3.94
287.1581421	98.90
297.1759644	25.10
297.8865051	0.03
301.4679565	0.05
303.1578369	3.10
305.2062988	7.28
315.2012024	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	375.1448
Annotation	(3S)-7-Hydroxy-8,2',3',4',5'-pentamethoxyisoflavan
Peak:m/z	Relative Intensity
120.8706589	0.01
175.1325378	0.01
194.2276306	0.01
195.2152100	0.01
211.2661743	0.01
213.0337524	0.06
225.2042847	0.06
239.0061340	0.10
241.2085876	0.09
243.1005859	0.10
251.2724304	0.14
255.2189026	1.32
257.2200012	10.61
269.1973877	1.19
283.0909119	0.39
285.2955933	0.03
287.2053833	100.00
288.3395691	0.04
289.1086426	0.01
294.9713135	0.06
301.2617798	1.22
313.1309204	2.67
327.3367310	0.02
329.3333130	0.11
331.2297974	41.43
332.5652466	0.03
357.2150879	0.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	467.167
Annotation	Unknow
Peak:m/z	Relative Intensity
148.8068390	0.06
159.3306885	0.11
161.2563782	0.11
189.0549622	1.57
203.0391998	0.54
204.8792572	0.09
245.0693359	0.07
248.4305420	0.09
251.0494385	0.07
287.2544556	0.07
289.1785278	0.21
295.2335815	0.17
301.3836365	0.06
305.2009888	7.94
323.1551819	100.00
339.1014404	0.09
341.4507446	0.04
345.0482178	0.06
359.1697693	0.06
363.2419128	0.14
365.1581726	9.82
369.4043579	0.06
379.2341003	1.18
380.2771301	5.62
381.1228943	0.05
383.1683044	0.31
388.4178162	0.04
405.1338806	2.30
419.3913879	0.06
421.2916260	0.86
431.2345276	0.28
447.5210266	0.11
449.1841125	0.78
450.2835388	0.04
466.3868713	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	583.2394
Annotation	Briaexcavatolide K
Peak:m/z	Relative Intensity
171.8825989	0.05
180.7911835	0.01
195.2262421	0.04
203.0867767	0.05
205.0271454	0.05
214.1293640	0.01
233.3807373	0.04
239.1531219	0.02
253.3423920	0.01
276.0715332	0.02
316.9960938	0.07
335.4240112	0.02
341.0358276	0.04
355.4168091	0.01
373.3400269	0.04
374.2213135	0.02
375.3156128	0.04
381.4213867	0.02
385.4156494	0.04
387.3320923	0.04
388.3933105	0.08
391.3373413	0.07
402.3789062	0.04
403.4483643	0.07
406.5206909	0.11
419.4135132	0.10
421.2196045	100.00
421.8579712	0.33
422.9610596	0.04
427.1416016	0.01
462.4202271	0.03
463.3120728	0.10
495.1205444	0.05
499.2505493	0.02
506.9669800	0.01
536.3502197	0.05
537.0494995	0.05
539.4175415	0.01
545.2019653	0.02
547.2615356	0.02
549.4298706	0.02
551.1539917	0.08
563.4464722	0.02
564.0552368	0.02
565.2979126	0.33
567.4234009	0.02
568.4081421	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	527.25
Annotation	Canavalioside
Peak:m/z	Relative Intensity
158.9388580	0.59
160.9259338	8.97
178.9900665	4.09
233.4026947	0.35
261.3286743	0.28
272.9611816	0.57
275.2268066	15.03
291.2343750	5.53
293.2451477	0.31
303.1470947	35.51
319.2841187	1.15
321.3699341	12.01
331.4004517	0.38
337.2336426	1.02
345.4323120	0.31
347.2133789	23.03
363.2296753	0.45
365.2947388	23.93
381.3757935	0.38
387.1243896	0.52
437.2804565	0.59
465.4061890	14.55
481.4163818	0.31
483.3279419	4.98
497.3085938	100.00
497.9196167	0.35
499.3735962	66.78
500.5933228	0.91
509.4065552	11.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	365.1451
Annotation	Unknow
Peak:m/z	Relative Intensity
112.8750687	0.16
139.0802002	0.04
140.1598816	0.24
147.8840332	0.13
159.1194458	0.32
161.0274353	0.94
178.4542236	0.12
179.1439667	0.34
180.2763824	0.12
184.0773315	0.08
185.0229797	1.17
201.2285309	0.29
203.0399170	0.27
213.2600250	0.21
241.3810425	0.20
273.2430420	0.09
276.2545166	0.04
277.4299927	0.08
279.0568848	0.71
285.3447876	0.18
291.2569275	0.03
293.2217102	0.13
304.3441772	0.09
305.1549988	0.16
307.0588989	0.06
309.8696289	0.09
319.1552124	100.00
321.1601257	1.76
322.8822021	0.07
329.0759277	0.66
347.2309570	1.42
348.3436584	0.04
350.2790833	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.84
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9635162	8.25
130.9660492	0.16
155.0893555	0.15
167.9586487	0.17
202.4053040	0.11
212.8127594	5.71
245.2621460	0.47
268.4176025	0.84
270.1529541	0.86
270.9892273	0.52
295.3108521	0.53
296.6918945	100.00
297.4192810	0.18
334.2695923	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	558.2164
Annotation	Unknow
Peak:m/z	Relative Intensity
203.2705536	0.22
234.2043152	0.30
257.0877686	0.09
269.1422729	0.13
271.1936646	0.26
287.1349487	0.14
301.0497437	0.48
305.1580200	0.23
315.0783081	5.52
329.3580933	0.58
332.9989624	26.13
342.3901978	0.29
343.0763550	1.69
347.0817871	0.78
351.4370728	0.06
357.2395020	0.36
360.8494873	5.29
368.3372803	0.25
377.4702148	0.28
379.0129395	100.00
394.3724976	0.08
396.1051025	11.84
397.4022827	0.13
403.2754517	0.05
427.0997925	0.17
435.0115967	0.14
438.3908691	0.08
465.3195801	0.09
468.1544189	0.26
476.1820679	0.18
476.8428955	0.81
481.1996460	0.05
484.7394409	0.15
511.3571167	0.32
512.3000488	0.14
513.6395874	0.06
514.5385742	0.85
533.3565063	0.39
535.4962769	0.47
539.1307983	0.09
540.2507324	1.15
541.4743042	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.1976
Annotation	Iandonoside B
Peak:m/z	Relative Intensity
175.2693176	0.46
176.1143799	0.06
200.6875458	0.03
212.4721375	0.04
213.3403320	0.17
215.3726654	0.09
225.4426880	0.09
227.3125153	0.04
228.3796539	0.06
236.0008545	0.10
237.3125916	0.07
243.1395721	0.05
251.2075653	0.24
253.2749634	0.04
254.2314911	0.04
255.4798889	0.05
267.1708374	0.24
269.2778625	4.71
280.9977722	0.12
283.2576904	0.28
284.1781616	0.05
287.2321167	2.15
291.2256470	0.08
295.3433838	0.20
299.1499634	0.93
301.2951660	0.08
306.9230347	0.07
309.2694702	0.37
311.2236328	3.98
313.1441040	5.94
327.3128052	1.29
331.2878418	16.50
343.3410034	0.13
345.3180542	1.21
353.2206421	0.88
355.3093872	0.30
357.1770630	100.00
358.3602905	0.19
369.3389282	0.05
371.1763306	20.61
373.2576904	5.94
374.5228271	0.16
375.2027588	1.52
375.8446655	0.02
379.0733643	0.07
382.8714600	0.04
397.3017578	0.04
399.2618408	23.67
400.3342285	0.10
403.2678833	0.11
411.2805786	0.09
417.2733765	10.02
417.9750977	0.04
423.3066406	0.09
429.1965942	0.94
433.2492065	0.68
441.1448364	0.27
447.2151489	0.23
449.3353271	0.03
451.1923218	0.17
453.3021240	0.05
458.6528320	0.19
459.3330688	0.45
471.2510376	0.03
475.4417725	0.40
477.3179932	0.64
489.3941040	0.05
491.1343384	0.07
493.3818970	0.92
503.5184937	0.04
506.0042114	0.32
507.8079224	0.21
517.2785645	0.04
519.1622925	4.17
520.1196899	0.03
536.8998413	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	239.0926
Annotation	Ethyl 3,4,5-trimethoxybenzoate
Peak:m/z	Relative Intensity
83.0216522	0.02
95.1067352	0.03
97.0300674	0.02
109.0344391	0.18
133.0211792	0.11
135.0775146	0.52
141.1026917	0.43
149.1303864	0.02
151.1222076	0.61
153.0994873	0.02
158.9315491	0.05
163.0372314	0.06
177.0618134	3.60
179.0512390	0.36
195.0626984	100.00
196.1223297	0.04
205.1495972	0.03
221.0403290	6.73
223.1139374	0.06
223.9801483	0.02
239.2799225	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	689.3024
Annotation	Unknow
Peak:m/z	Relative Intensity
221.1583099	3.66
245.2488251	2.46
257.3192139	0.81
263.0994873	2.43
275.2937317	3.31
303.3833618	2.35
317.3013000	3.18
319.3798828	2.19
321.5867615	0.36
323.2687988	2.63
335.2614441	4.06
341.2364807	0.38
347.2789307	9.63
363.4235840	0.22
365.2693481	10.56
437.2763062	0.84
447.2428589	2.89
465.3820190	11.39
479.4345703	0.37
481.2730103	0.61
483.3258057	1.31
491.4502563	0.79
493.6068115	0.24
497.3983154	5.49
499.3666992	1.34
509.2030640	0.84
527.3615112	37.25
528.2009888	0.23
551.2476196	0.44
581.7507324	0.29
593.2531128	0.13
599.1786499	0.48
627.3617554	6.65
643.3414307	8.24
644.3177490	0.13
645.3897095	1.50
659.4257812	100.00
661.3520508	18.02
662.4502563	0.46
671.3744507	2.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	830.2606
Annotation	Aromatized deshydroxy-C-1027 chromophore
Peak:m/z	Relative Intensity
232.1064911	0.09
234.1150513	0.29
244.0136108	0.10
246.1529846	0.08
248.0979919	0.12
250.0566406	1.39
252.1426697	0.80
256.0887451	0.07
260.2901306	0.36
262.1783752	0.47
263.4619141	0.36
264.1347046	0.22
266.4125366	0.12
268.0267944	0.16
277.8612061	0.14
278.7498779	0.45
280.0790100	9.60
281.1720886	0.97
282.0413208	0.60
288.0673828	0.30
289.1495972	0.14
292.1590576	0.19
296.0077209	0.27
298.2844238	0.14
301.0786438	0.07
306.2643127	0.05
310.3103638	0.74
320.4205322	0.07
322.1043091	0.63
324.1400146	0.07
335.9778442	0.41
339.9920044	5.13
352.0188599	0.93
353.1499329	0.68
358.1328430	0.44
362.1678467	0.09
363.2100220	0.04
364.2427979	0.52
365.1050720	0.08
368.2360840	0.09
369.3498535	0.15
373.3801270	0.31
380.1654053	0.07
382.0852661	1.74
382.9969482	0.53
392.6895752	0.11
393.9028931	0.14
406.2766724	0.05
412.0769043	2.80
413.0576782	0.25
414.3261108	0.43
416.4265137	0.23
424.2284546	1.58
439.8797607	0.23
442.1186523	100.00
443.1565552	1.33
444.1016235	0.23
446.3424072	0.26
476.2396240	0.23
477.3165894	0.24
501.0343628	0.16
501.8806763	0.19
506.0989990	8.35
514.1097412	0.12
531.8468018	0.09
548.1646729	0.08
567.4625244	0.09
582.2116089	0.26
583.7113037	0.38
587.3661499	0.09
592.8853149	0.88
596.3936768	0.33
604.0791626	29.44
632.1133423	0.15
638.0877686	0.58
640.2921753	0.09
642.4735718	0.12
649.8037720	0.53
657.9901733	0.21
667.8794556	19.43
668.6705322	0.75
682.9534302	0.86
687.8642578	0.21
709.0374146	0.77
727.1245728	0.21
748.8790894	0.37
763.8752441	0.33
770.4564209	0.32
771.0831299	1.74
810.2699585	0.88
811.4360352	0.24
812.2809448	1.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	407.1727
Annotation	Vernoflexuoside
Peak:m/z	Relative Intensity
158.8740845	0.77
160.8990173	0.14
178.9765015	0.08
213.0104370	0.10
215.1678162	0.20
232.7438660	0.20
261.0477295	7.34
311.1234131	0.40
315.1708069	6.74
346.0158691	0.18
361.0680237	100.00
361.7389221	0.54
363.8002625	0.44
372.1200256	0.11
389.2900391	0.15
389.9861145	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	534.1768
Annotation	Unknow
Peak:m/z	Relative Intensity
184.1007385	0.10
215.1389923	0.05
234.9273834	0.03
296.4010620	0.04
315.3197021	0.05
322.9849243	0.13
326.3117676	0.05
354.2341309	0.44
356.2990723	0.16
372.2109985	100.00
373.0299683	0.02
424.1658325	0.05
467.4168701	0.17
488.5134888	0.07
493.7008667	0.03
503.4312134	0.17
516.3341064	0.18
516.9952393	0.16
525.3166504	0.19
532.4103394	0.43
535.4227905	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	401.1088
Annotation	10-Dehydrogardenoside
Peak:m/z	Relative Intensity
113.0894012	0.14
115.0542450	0.04
130.7237854	0.14
132.9338989	0.16
150.8959351	1.76
157.1236267	0.18
166.9707336	0.09
175.1077271	0.31
177.1483765	0.07
178.1991119	0.04
189.0064850	0.30
191.0327454	0.02
193.0027771	0.20
204.9629211	0.66
206.6361389	0.09
207.3554535	0.07
221.0766907	0.07
222.9990845	0.21
225.0985260	0.41
231.1273499	0.72
239.2214355	0.05
249.0956726	21.50
250.1397705	0.02
253.1640015	0.01
265.1076965	0.07
267.0818176	100.00
268.0195007	0.12
295.1458435	0.15
311.1803284	0.05
319.2613525	0.08
323.4743958	0.04
325.3089294	0.10
339.1722412	0.38
341.0567627	0.33
354.9898682	0.10
356.3005676	0.05
357.4220886	0.18
365.2561951	0.35
383.1827698	4.59
383.8756409	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyisoflavone
Peak:m/z	Relative Intensity
76.63723755	0.12
81.02539062	1.00
82.98202515	0.41
85.11103821	0.61
92.77784729	0.08
102.7897186	1.40
104.9921417	0.37
106.8684387	0.21
109.095932	0.57
111.0287628	0.42
114.9269257	1.50
120.9373779	0.64
122.800766	0.16
124.863205	0.51
126.8335876	0.51
127.8071899	0.11
128.9095001	4.66
130.1276093	0.08
137.1355896	0.36
140.9476471	0.58
145.2984924	0.30
146.9957733	0.30
150.9135284	53.78
152.0228271	5.53
157.0144501	0.51
159.1060638	0.36
161.096756	1.06
163.0909119	0.28
167.0011749	1.72
167.7386475	0.45
168.8786011	1.81
170.134964	0.25
170.9864349	0.65
175.1695709	0.89
175.8512421	0.13
177.2141266	0.36
179.0406952	1.70
179.967392	0.29
182.0932312	0.37
183.0036316	0.71
185.0433197	0.94
190.0772552	1.90
191.1668854	0.46
193.1114655	0.86
194.0078583	1.56
197.1393738	5.10
199.1865387	1.58
207.2461548	0.21
208.4056396	0.40
209.6528015	0.36
211.0949554	2.68
212.2375793	0.22
212.8556366	0.28
217.0797272	3.34
225.1101685	4.75
226.180542	1.05
235.1710358	7.04
238.1239624	7.52
239.0489655	2.02
250.9452057	0.30
253.0764771	100.00
254.0677948	24.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.9581
Annotation	Unknow
Peak:m/z	Relative Intensity
127.9693298	0.30
129.7439575	0.40
137.1159668	0.05
141.8445129	0.16
155.8168793	1.11
159.9621429	0.18
169.9671021	0.98
172.0938568	0.06
178.8354034	0.04
183.8022766	1.20
184.9388123	0.31
191.1592102	0.15
198.0137939	0.19
199.9478455	19.40
200.9255371	1.60
213.8494873	4.94
214.5080566	0.05
217.8252106	0.27
226.1015930	0.04
227.8439789	0.13
239.0945740	0.15
240.2819824	0.04
241.9810486	0.50
243.9020081	7.28
245.1082764	0.40
245.9568787	0.60
254.2749634	0.15
255.3417053	0.12
257.9158936	85.48
258.5218506	0.20
262.0290527	0.91
268.0817261	0.26
270.1401978	0.14
272.0101929	0.22
284.0172729	1.69
285.8577881	5.69
287.9323730	10.93
289.7104797	3.00
299.4270020	0.15
301.2557373	7.62
301.9368286	37.45
303.9834595	2.91
306.1577759	1.94
307.1348572	0.15
308.0273438	0.09
312.5855103	0.10
314.0438843	1.30
319.1781006	0.13
321.3296509	0.09
327.9588318	4.31
329.5295410	8.51
330.2472534	0.69
331.8990173	100.00
332.5583191	0.44
338.2096252	0.84
343.2853394	0.12
345.2332153	3.95
345.9424438	21.05
347.9592285	1.99
357.8916016	0.26
365.3396606	0.10
372.1067810	0.06
373.5822449	2.04
374.8069153	0.29
375.8114319	0.08
383.2074585	0.32
384.5918884	0.20
391.3719788	3.03
392.0184631	35.03
399.8185730	2.36
401.3046570	1.40
402.2278442	0.17
417.8467712	81.49
418.5041809	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2783
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
139.9202271	0.11
152.8078918	0.10
170.8926239	0.03
177.1808929	0.03
196.0475769	1.94
199.1021729	0.02
214.0920868	1.71
237.4177856	0.01
252.0608215	0.03
255.2181702	100.00
255.8410034	0.16
321.0736389	0.02
329.4475403	0.06
367.0008240	0.03
387.2585144	0.06
391.2707520	0.29
396.5354309	0.02
406.3816528	0.10
408.4646606	0.02
409.2282715	0.02
416.8863831	0.14
434.1036682	0.32
435.2673035	0.11
450.8145142	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	406.1704
Annotation	8-Dimethylaminoriboflavin
Peak:m/z	Relative Intensity
119.0764084	0.08
121.0487976	0.09
123.1916504	0.03
126.8568573	0.16
128.1120605	0.16
131.0340118	0.67
136.6701202	0.20
138.0373077	0.44
141.0458374	0.27
143.1402283	0.05
145.3130188	0.22
147.0137482	0.14
149.1714783	0.11
153.3512878	0.08
155.1287842	0.57
155.9303589	0.30
158.4984894	0.18
160.3031921	0.12
163.1546021	0.20
165.1799469	0.15
167.0087280	7.34
167.8956451	0.03
169.9239960	0.06
173.1965942	0.08
174.0336456	0.20
175.2095032	0.10
177.0256348	1.97
180.0352173	1.90
181.0547180	0.05
182.8256836	0.08
187.1370239	0.03
191.1239929	0.33
195.2373505	0.19
196.2095032	0.07
197.2257996	0.16
198.1858826	0.11
207.1644897	0.03
209.0129700	26.66
211.0540466	0.22
213.0294037	1.19
215.1628723	0.50
216.1061859	0.18
225.3211823	0.07
227.0855408	100.00
229.1187134	0.70
230.1886292	0.68
233.0623474	0.15
234.0614319	0.06
243.8141174	2.92
244.4965210	0.13
245.2622070	0.12
251.0525513	0.14
251.9797058	0.07
254.1832886	0.13
259.1464539	1.80
269.0323486	0.06
271.5449219	0.42
272.1733704	0.77
274.3000183	0.18
276.8476868	0.20
285.2393799	0.30
287.2092285	0.12
289.0340576	0.34
294.5753479	0.47
295.3915405	0.11
296.0935669	0.20
301.2996826	0.06
305.8982239	0.15
307.2422791	0.42
308.2765808	0.04
316.0643616	0.66
317.2287598	0.24
318.0553284	0.10
320.0050659	0.05
321.4080505	0.04
323.0768433	0.14
324.0444336	0.46
324.7826538	0.37
325.8569336	0.45
328.2973022	0.05
329.1362305	0.16
331.0772095	0.19
333.1217651	0.08
334.2498474	0.43
342.0384827	0.29
343.1134949	0.05
344.3703613	0.03
347.0934448	0.06
349.2533569	0.07
352.0866394	0.59
352.7580261	0.08
356.0953369	0.13
360.0752563	6.47
361.1336975	0.23
362.3805847	0.17
363.3962402	0.26
364.3999939	0.05
368.2404480	0.38
370.0334473	0.76
370.7857361	0.09
371.4477234	0.05
376.1115112	0.24
377.3745117	0.11
382.5214844	0.18
384.5092773	0.07
386.3627625	0.32
388.2049866	2.82
389.2317810	0.57
391.1216125	0.13
396.9770813	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.085
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.94184875	0.60
78.72911835	0.30
83.95668793	0.24
91.20524597	0.17
103.2234955	0.89
103.9164276	0.26
106.7020111	1.02
122.8041534	0.22
128.9630585	4.09
129.7666321	0.11
131.008728	0.45
132.8999023	0.20
140.8816376	0.48
142.0650482	0.23
146.9734039	0.36
150.917572	54.54
152.0200806	2.30
156.7658997	0.11
165.1488953	0.43
166.1063232	0.56
167.0322418	1.50
168.9897614	0.91
178.8957977	1.71
182.2599945	0.22
183.265274	0.59
185.166275	1.49
186.1024323	0.51
196.4248657	0.97
197.232605	1.97
207.1022339	0.36
210.0923615	1.07
211.1395111	0.16
224.653656	0.76
225.2860413	1.93
225.9759369	0.65
235.0474396	0.42
237.9878998	8.60
239.1626129	2.85
251.1488495	1.84
253.0879059	100.00
254.1515045	19.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	472.1586
Annotation	Folinic acid
Peak:m/z	Relative Intensity
148.1104736	0.24
160.9100952	0.06
163.2443237	0.06
164.1355591	0.20
206.2580719	0.02
222.1872253	0.16
233.2095947	0.08
235.9450378	0.04
258.2334900	0.38
264.4785156	0.09
274.4013062	0.25
275.3052063	0.49
282.8741455	0.05
292.1725159	0.10
300.1376038	38.80
301.0740051	0.14
305.8000183	0.03
308.1665649	0.16
309.1515198	0.13
310.1570129	0.09
316.2525635	0.08
323.3466492	0.20
325.4195862	0.18
326.2742615	0.07
333.0329895	0.11
340.8513184	0.07
343.1120605	22.18
346.0169983	0.09
357.3872986	0.08
360.3174744	0.52
367.1154175	0.37
376.3315735	0.05
384.2413025	0.19
385.2382202	7.96
386.2997742	2.94
387.2907104	0.17
404.2487488	100.00
404.9504395	0.48
411.1745300	9.27
412.1289978	0.15
413.3041687	0.05
425.5177917	0.34
426.3579407	0.29
428.2631226	2.25
429.3175354	18.48
436.2488708	0.06
441.5050354	0.10
454.1827087	17.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.1429
Annotation	Psilostachyin C
Peak:m/z	Relative Intensity
77.0227661	0.03
81.0609436	0.03
82.9002609	0.02
92.8828125	0.36
95.0164185	0.58
97.0774994	0.26
98.9928589	0.45
105.1039886	0.25
107.0269012	0.44
109.0450287	0.84
111.0148010	1.01
113.0487366	0.58
117.2423706	0.08
118.9913483	0.61
120.9054108	1.24
122.9404144	0.33
125.0145416	0.59
131.0048218	0.23
132.9568176	0.21
135.0494080	4.53
137.0793762	3.13
138.9599304	1.26
142.9651337	0.08
145.0585480	1.22
147.0382538	1.31
149.0085602	0.86
151.0415802	0.10
153.1846161	0.12
155.0018768	0.95
157.0756683	2.18
157.8785553	0.05
159.1306763	2.03
160.9774933	3.51
162.2322235	0.02
163.2368317	0.65
165.0507660	2.50
166.9680023	0.03
169.1046143	0.12
171.1264191	0.57
173.0905457	2.78
175.1102142	12.38
175.8230133	0.01
177.0419617	0.27
180.1618347	0.04
180.9626617	0.04
183.1130676	0.85
185.0928497	2.41
187.0495453	5.95
189.0303650	3.22
191.0781708	0.37
193.1443329	5.43
195.1720734	0.09
199.0309906	0.52
201.1463165	4.52
203.0909576	10.22
205.1199341	1.38
207.1311188	0.81
211.1528168	4.39
217.0257416	9.79
219.1126862	5.24
221.0895844	0.68
224.1073151	0.03
229.1434631	12.07
235.0472260	6.84
236.6475372	0.06
237.2594452	0.43
244.1030731	0.33
246.9967041	100.00
247.7660065	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.234
Annotation	gibberellin A2 O-beta-D-glucoside
Peak:m/z	Relative Intensity
201.0841675	0.71
203.1835480	0.27
211.1457367	0.10
217.5724792	0.13
221.2030029	0.18
225.3002625	0.04
229.4190674	0.30
237.3262634	0.24
243.3370667	0.49
245.2221069	0.13
253.2089539	0.64
254.1339417	0.09
255.2503357	4.24
256.1273193	0.31
257.4097595	0.95
259.2348022	0.14
261.2446594	0.37
263.5142822	0.06
265.1773682	0.43
268.8880615	0.18
271.2641602	0.70
273.2278442	4.18
273.9616699	0.29
275.2739258	0.06
281.2692871	0.42
283.3256226	1.09
284.1824341	0.46
285.4270020	0.33
287.2518311	0.08
289.2529297	0.39
290.0264282	0.17
291.2434082	0.36
297.1633301	0.09
299.1937866	3.91
300.2784729	0.09
301.1964111	1.94
303.2216797	0.17
317.3682251	0.87
319.2484741	3.10
320.1500244	0.16
321.5390625	0.08
327.2780762	0.54
329.2747192	3.07
330.3692627	0.08
337.3071899	0.14
343.3433838	0.05
345.1959229	87.09
346.2927246	5.54
347.3895264	0.13
358.8831787	0.34
363.2563477	100.00
364.3432007	5.09
365.4374390	1.26
366.3392334	0.24
377.4240112	0.07
405.2562866	0.47
437.3339233	0.33
439.0531006	0.12
447.2832642	0.10
463.0160522	0.52
479.3969116	0.76
481.2670288	5.17
489.2029419	0.04
495.3299561	0.54
504.9812622	0.11
507.3442383	5.23
508.4308472	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	400.1799
Annotation	Unknow
Peak:m/z	Relative Intensity
117.9144440	100.00
118.5181503	0.44
157.9479828	0.11
186.8973846	0.20
218.7672729	0.65
237.9813843	0.09
264.8765564	4.23
267.9878540	0.07
282.9302979	1.50
307.6113586	0.07
308.2843323	0.27
310.2189636	0.74
354.2207031	0.22
382.1395569	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0712
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
145.9437866	0.06
164.884964	0.10
166.7889252	0.10
169.0943604	0.05
174.00914	0.07
179.1902618	0.54
180.1106262	0.37
181.1906891	0.28
193.2358398	0.47
195.2278137	0.09
205.9724274	0.44
207.105484	1.89
208.0061798	2.20
209.2177734	1.07
222.2667084	1.38
223.1864471	2.49
224.2095184	0.71
233.3950195	0.71
249.1217499	0.15
251.082962	100.00
252.1696777	21.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	347.15
Annotation	Armexin
Peak:m/z	Relative Intensity
98.9958496	0.03
100.9359283	0.03
108.9254761	0.02
127.1069794	0.01
130.9407501	0.02
133.0981140	0.01
138.9403687	0.06
143.0520020	0.01
144.1366272	0.03
147.0479279	0.03
171.2495880	0.01
173.1083984	0.03
187.1760712	0.02
194.9177704	0.04
199.2933502	0.08
201.1046295	0.02
203.1568756	0.53
213.2764587	0.24
215.2250977	0.04
217.2434692	0.17
223.2569885	0.73
225.5867310	0.02
229.1743469	1.89
231.3167114	2.05
232.2823792	0.01
239.2126770	0.81
241.2417908	15.02
242.2659302	0.09
243.2673950	0.02
245.2342224	0.03
255.2964478	0.04
257.3065796	1.59
259.2190857	13.84
260.2702026	0.18
261.2102356	0.06
267.2166443	1.94
275.4681091	0.06
277.2207031	0.02
283.0660095	0.02
283.8453369	0.04
285.1737671	10.58
286.3413086	0.13
287.0575562	0.02
295.4807129	0.02
299.0291443	0.04
301.2214355	0.48
303.1822510	100.00
304.2567749	0.74
311.1927490	0.22
312.0098267	0.06
313.3517761	0.08
317.2402039	0.04
318.0003052	0.02
318.7151184	0.07
327.8601685	0.02
329.2269897	3.98
330.2315369	0.10
332.1140747	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	589.2502
Annotation	gibberellin A2 O-beta-D-glucoside
Peak:m/z	Relative Intensity
179.0608521	0.41
263.3330078	0.04
272.9677429	0.10
333.2293091	0.25
360.0684814	0.16
379.5958252	0.13
389.3513184	0.11
403.4981079	0.10
409.3269653	0.54
424.3117676	0.03
427.1802368	0.50
441.3208008	0.08
445.3855591	0.06
467.4542847	0.38
469.2091064	0.33
475.2724609	0.07
477.1842651	0.05
478.4000854	0.06
483.0427856	0.58
484.2409668	0.34
492.2483521	0.09
497.4027100	0.14
498.0412598	0.20
499.1793823	0.28
513.3914185	0.26
525.3109741	0.05
526.5718994	0.06
527.2625122	0.13
538.4811401	0.10
541.3215942	0.13
543.2805786	100.00
544.0873413	0.02
545.4417725	0.49
553.3843384	0.33
554.5869751	0.09
557.3805542	0.12
559.2405396	0.13
569.3766479	1.08
571.4293823	2.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	197.08
Annotation	4-Hydroxy-6-methyl-3-(1-oxobutyl)-2H-pyran-2-one
Peak:m/z	Relative Intensity
68.8860855	0.06
77.0478821	0.02
81.0700378	0.04
83.0746613	0.02
84.0552216	0.02
85.0114593	0.02
86.9355011	0.07
93.0653534	0.01
95.0951386	0.01
97.1060944	0.15
105.0166626	1.35
108.9108887	0.03
112.8417511	0.04
114.9336853	0.04
116.8647766	0.02
119.0410461	0.18
121.0089264	0.11
122.9591370	0.12
124.8926392	0.05
128.8900299	0.03
129.9640045	0.02
132.9095764	0.01
133.9643707	0.04
134.8980103	0.09
137.0351257	0.08
138.0020599	0.04
139.0344696	0.04
140.0963745	0.04
141.0403290	0.19
143.0753326	0.02
151.0363312	0.21
152.0682526	0.07
152.8039398	0.04
153.9414520	0.02
155.0408020	0.27
156.0719452	0.10
161.0617218	0.26
162.0885315	0.05
164.1071930	0.03
164.9994354	0.24
167.2571564	0.02
168.2012329	0.05
168.9715881	0.23
174.0906067	0.01
178.9821777	100.00
180.0006714	0.14
182.0119476	0.38
182.9079437	0.02
185.2575989	0.05
186.9018860	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
72.4056778	0.20
73.13461304	0.46
76.79368591	1.33
78.87232208	0.88
80.97112274	1.44
83.11616516	0.93
85.01280975	0.86
90.58317566	1.22
92.93717957	0.60
93.79649353	0.46
95.01939392	3.03
96.95828247	1.51
99.0559082	0.46
102.6421051	0.33
104.9686127	1.05
106.9059906	0.20
109.1442413	1.47
111.0661926	2.16
113.1963806	0.56
119.1092377	0.31
121.1146545	1.46
123.0126343	2.68
124.9135437	0.41
126.7969971	0.19
128.9252014	5.89
133.028717	2.69
135.0526428	1.16
137.0002899	2.55
139.0595093	0.95
141.0691986	3.30
145.141098	2.17
147.0457611	2.32
147.8393402	0.65
149.2576752	0.39
150.925354	57.69
152.0310516	2.69
153.0665436	3.09
154.0378571	0.52
155.2737122	1.27
157.1040039	0.68
158.8863831	0.26
161.079071	1.89
163.0416718	3.81
164.9910278	2.10
166.9743652	2.34
169.0366821	0.77
170.079422	0.78
171.287735	0.65
175.0971375	1.36
177.0337372	0.90
178.0804901	0.54
178.8702545	4.38
180.0512695	0.31
181.2346954	0.99
182.9547882	3.12
185.0739899	2.13
186.0635681	0.33
189.4637146	0.34
190.1750946	0.36
192.1856079	0.26
193.0765839	4.65
193.8665619	1.23
195.2062836	0.74
197.0927887	2.65
198.013443	0.51
199.4342499	0.11
202.9164276	0.33
207.1344299	1.85
209.1362762	0.73
209.9944153	0.85
211.0717926	4.60
212.0426025	2.54
217.14888	10.82
225.1416473	7.76
226.4135742	0.93
232.3900604	0.99
235.1899872	33.69
236.1193237	0.28
237.9216919	10.69
239.0983276	1.29
251.0791779	1.11
253.0902557	100.00
254.1204681	19.57
264.4299927	1.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	558.2062
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0897980	0.07
167.1140594	0.02
169.9440002	0.81
173.9821777	1.25
175.1278381	0.07
183.1430359	0.02
188.0111694	53.42
189.0773773	0.34
192.0646820	5.39
204.9957886	100.00
206.0888062	0.73
215.8643341	0.10
223.2663879	0.05
233.9829102	0.07
258.2060242	0.05
300.1032715	0.09
310.0728760	0.05
318.1115112	0.04
330.1151733	0.12
332.2863770	0.06
336.3026733	0.14
337.0278931	0.13
343.3016357	0.14
353.3937378	1.77
354.1422729	12.21
357.4086304	0.07
360.1854858	0.09
364.9775391	0.07
389.4184570	0.02
395.8096924	0.02
419.1121826	0.04
421.9885864	0.02
425.1215820	0.06
426.2066040	0.02
429.0368652	0.11
437.4624023	0.08
451.4674072	0.03
453.3955078	0.06
465.2599487	0.07
475.9778442	0.06
483.1644287	0.06
486.5389404	0.09
496.1317139	0.03
498.0989990	0.02
499.1030273	0.06
500.0155640	0.18
500.9959717	0.23
512.0284424	0.07
513.2841187	0.08
518.4894409	0.02
521.5944214	0.08
522.5332642	0.02
536.4799194	0.13
539.2271118	0.24
540.0953979	0.39
541.5410767	0.04
544.0397949	0.02
549.4485474	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.198
Annotation	Dracunculifoside Q
Peak:m/z	Relative Intensity
159.1210327	0.31
161.0455475	3.01
169.2150574	0.09
179.2416077	0.22
184.9992371	0.07
186.1134796	0.28
193.0023956	0.31
195.1099701	0.95
196.1177979	0.25
197.1889954	1.14
198.0317383	0.13
199.0189514	0.35
201.0494385	0.09
203.2013245	1.04
209.2428436	0.41
211.3011475	0.25
213.2860870	0.04
215.0920715	0.29
219.3350830	0.05
221.2352600	2.08
223.1254578	0.14
227.2007294	0.57
235.4264526	0.08
237.1478882	2.19
239.1778870	16.52
257.0818176	12.68
275.1533203	6.75
283.0585327	6.23
299.2844849	0.07
301.2847900	22.24
303.1080322	0.12
314.9605713	0.11
318.9500122	0.10
322.2537231	0.14
327.3482666	0.24
334.7512207	0.87
335.3613892	0.52
341.3233643	0.05
345.2015991	100.00
347.4172974	0.22
351.4378662	0.05
361.3953247	0.18
363.2562256	2.12
378.2360229	0.17
405.4004517	0.10
406.2877197	0.08
407.0864258	0.20
419.3480225	2.99
427.3578491	0.08
429.5660400	0.07
437.2537842	6.26
462.2963257	0.06
463.4269409	1.37
479.3673096	0.61
481.2896118	36.40
482.2792358	0.42
489.2246704	0.14
507.1099854	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	349.2002
Annotation	Sporotrichiol
Peak:m/z	Relative Intensity
104.9366379	0.22
109.1374435	0.51
119.0887680	0.04
121.0112152	0.24
123.0406876	4.25
124.9037094	0.04
127.1341019	0.15
131.1436157	0.47
132.1823273	0.02
132.8968506	0.13
134.9981232	0.03
137.0192413	0.53
139.3272095	0.08
143.0272980	0.31
144.9939880	0.41
147.0789795	0.09
149.0080719	0.18
151.0791931	0.11
153.0573578	0.25
154.9289856	0.16
157.0456238	0.13
159.0813904	0.25
160.9188843	0.02
162.9593811	0.39
165.0510864	1.40
166.9803772	0.26
169.0760498	5.76
173.3047943	0.07
175.0612183	0.06
177.0093079	0.37
179.1617584	0.44
181.1696472	0.19
183.0461426	0.05
184.9828796	0.01
189.1840820	0.87
191.0533142	0.44
193.1554871	0.27
195.0386200	0.44
197.0606995	0.11
199.1298065	0.25
201.1792145	0.17
206.9979553	14.52
208.8990173	0.02
211.1639099	0.17
213.1801758	0.18
215.1562195	0.25
216.9854126	0.03
219.1255188	0.25
221.1481323	0.45
223.1855774	0.84
225.1271057	0.05
227.2322083	0.16
229.1694031	0.43
230.9249878	0.07
232.9832458	0.36
235.4477844	0.02
237.2609863	0.37
239.2630005	1.46
241.1634521	1.01
243.2084351	0.15
245.0355225	0.61
247.0519104	0.19
249.1162415	1.72
250.1987000	0.01
251.5777283	0.20
253.2397156	0.10
255.1430359	0.36
257.1837463	3.91
259.2938843	0.16
261.2111816	3.17
263.1488342	0.37
265.1109314	0.06
267.1753845	7.10
268.5113831	0.16
269.2825012	0.14
271.1583557	0.27
273.1380005	1.13
275.3094788	0.34
277.1558838	0.08
283.1589355	0.46
285.1708679	24.01
285.7739258	0.31
287.2349854	0.62
289.1427307	0.09
295.2064819	1.31
301.3080444	0.46
303.1306152	21.96
305.2815552	0.98
313.2215576	19.67
321.2889099	0.03
331.1779175	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.0826
Annotation	Methyl gallate 3-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
119.1432343	0.11
120.0234833	0.02
123.9698639	0.95
136.0678101	0.05
139.0225525	1.55
161.8414307	0.07
164.8143158	0.03
167.9443359	3.89
179.0281982	0.04
182.9761658	100.00
199.0001526	0.04
239.1872253	0.16
241.3807678	0.15
271.3788757	0.02
273.2346497	0.09
279.6301270	0.02
281.0294800	0.04
283.2609253	0.11
299.0776062	0.19
301.2210083	0.07
327.0988770	0.21
330.1930847	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	805.2924
Annotation	Unknow
Peak:m/z	Relative Intensity
299.3224792	0.04
301.3099060	0.06
347.3602295	0.12
357.3345337	0.22
386.3529663	0.46
387.3947754	1.13
389.3648682	0.20
403.3344727	0.43
415.2896118	0.37
416.2982788	0.89
417.2819214	11.62
421.1812744	0.17
443.1773682	0.24
454.1615601	0.18
471.4264526	0.16
499.1763306	0.48
500.3175049	0.30
511.2981567	0.54
520.2157593	0.42
549.2515259	0.13
565.0570679	0.22
574.5338135	0.10
579.1632690	0.25
595.2297363	21.70
596.9020996	0.08
607.3416748	0.14
612.8641357	0.04
624.9412842	2.83
625.5974731	0.07
643.1412964	100.00
643.8588867	0.29
683.5034790	0.30
705.5070801	0.12
723.8406982	0.36
727.5062256	0.14
731.7871094	0.05
751.4810181	0.11
757.0155640	2.51
758.8961792	0.14
760.4865112	0.44
761.3880005	1.46
769.3128052	0.18
773.4295044	0.31
787.4973755	1.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
94.94360352	0.18
96.81427002	0.04
109.1278229	0.09
110.7451477	0.07
117.0801239	0.28
124.9052582	0.03
130.0576935	0.15
132.9084473	0.06
135.2036133	0.24
137.0274048	0.06
145.921051	0.07
149.1473541	0.13
151.1058197	0.11
152.5799103	0.10
160.8282623	0.09
169.2701569	0.06
178.9745331	0.28
180.0700684	0.04
181.0353546	0.05
183.2262878	0.22
185.1491394	0.10
192.9916534	0.06
194.0829926	0.17
195.2614441	0.44
196.2085266	0.05
205.0297852	0.27
206.0909576	0.29
207.1553345	5.21
208.1537933	2.19
209.1882019	0.85
222.1579742	1.55
223.1398773	3.79
224.0684662	0.50
232.9932709	0.66
233.6468964	0.18
236.0795135	0.18
251.0832672	100.00
252.1987305	17.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.1872
Annotation	Gibberellin 2-O-beta-D-glucoside
Peak:m/z	Relative Intensity
142.9035187	0.38
149.2097015	0.50
159.0988312	0.45
161.0510101	2.91
172.0509338	0.60
178.8742981	1.98
211.2819824	0.07
216.2585754	0.21
229.0961304	0.21
237.2742157	0.56
239.2227478	74.57
255.1683655	0.74
257.1577759	12.00
262.7066650	0.19
281.3759766	0.43
283.1348267	37.25
299.3070068	1.54
301.2025757	6.17
323.1897278	1.34
327.1972046	57.10
329.3190002	0.53
343.2456665	0.26
345.2457275	0.67
375.3019714	0.30
386.7642517	0.27
401.2291565	0.16
417.1187439	0.26
419.2496643	100.00
432.3017578	0.23
445.2524719	1.48
447.4211426	0.11
461.3111572	0.46
463.3186951	2.96
489.3202515	0.96
490.4982605	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	296.88
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9309692	100.00
183.9710083	0.25
186.2404022	0.48
191.0200958	0.31
211.0538940	0.52
212.7383118	44.05
213.3390198	0.07
253.4336548	0.11
254.0731506	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	400.1591
Annotation	Unknow
Peak:m/z	Relative Intensity
144.9583130	0.33
151.0407410	0.02
156.1237793	0.02
156.9994812	0.06
160.1288605	0.05
165.1324158	0.02
174.9177246	0.05
177.0759888	14.84
177.7136383	0.02
185.0084839	0.04
186.0641174	0.03
191.1922913	0.02
213.2469330	0.01
220.0595703	0.06
221.1740112	0.19
222.1271973	0.01
223.2056427	0.04
223.9239502	0.03
238.0608826	100.00
238.6775818	0.27
240.0799561	0.01
251.2342834	0.03
255.1466064	0.03
261.2513733	0.03
265.2218933	0.06
266.8847961	0.02
271.2017517	0.07
274.2761841	0.03
276.5718994	0.05
283.8607788	0.02
288.3385010	0.09
294.4514771	0.04
298.1843872	0.08
301.1360168	0.20
310.1691895	1.22
311.3917847	0.02
314.2388916	0.04
318.2424316	0.03
319.1819458	0.48
323.1460571	0.03
324.1954651	0.52
325.9785156	0.01
327.4579468	0.02
331.4819641	0.09
339.3631287	0.02
340.1622620	0.22
348.3098755	0.10
350.0334167	0.13
352.2957764	0.32
354.2965698	0.18
355.3108215	0.01
356.3757629	0.15
357.3262634	0.05
358.9303284	0.09
364.1182556	0.06
365.0249023	0.03
366.2499390	0.11
369.3777161	0.05
372.3290405	0.06
373.2806702	0.05
378.6765747	0.22
380.0904236	0.24
382.0517273	1.35
383.2321777	0.28
384.9040527	0.03
391.0190125	0.20
399.6861877	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	344.1515
Annotation	Unknow
Peak:m/z	Relative Intensity
115.1502151	0.11
117.9914856	0.18
121.9631805	0.61
131.8038635	0.11
133.2446899	0.27
135.0172119	0.27
143.9533539	0.22
146.0012360	0.21
148.9975586	9.58
156.0578918	0.21
158.3744202	0.12
159.0917969	0.21
163.0339661	0.36
164.1475830	0.16
165.4297333	0.40
166.9401855	0.27
167.9845276	0.20
176.9175110	0.26
178.0663910	0.74
181.3853455	0.07
182.1236877	0.22
187.0726929	0.46
189.2076874	0.18
190.0705872	0.53
190.9189301	0.14
195.2042236	0.06
197.2424622	0.16
200.0790863	0.24
204.9591064	100.00
205.5851746	0.10
207.1773224	0.48
208.0929260	0.27
209.2421570	0.25
212.1717834	0.24
214.1820374	0.06
215.0527649	0.48
219.1426697	0.21
222.9718933	2.72
224.2586365	0.06
226.1293640	0.13
228.1380005	0.12
229.1668396	0.91
236.7083130	0.05
239.1643066	0.25
240.1034241	0.06
241.2546387	0.65
242.1521912	0.25
243.4457703	0.33
244.1201172	0.68
248.3737793	0.22
255.1359863	0.10
256.2970276	0.72
258.1047974	0.15
262.5941162	0.14
263.2985840	0.44
265.7184448	0.22
267.3737183	0.12
273.3543091	0.31
280.2797546	0.18
280.9846191	0.60
283.0771484	0.25
284.0840454	0.12
285.3462219	0.09
286.1758728	0.11
290.8920898	0.79
293.0776367	0.19
294.0346985	0.20
295.3030396	0.38
298.2358398	1.81
299.3020325	0.40
300.1022034	0.24
308.7299805	1.44
309.4094849	0.32
314.1425781	1.04
316.1616821	3.18
320.8190918	0.45
325.3869324	7.28
326.0481262	12.18
326.9912109	1.60
327.6042480	0.39
335.4470825	0.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	541.2286
Annotation	3-[4-[1-(4-Hydroxy-3-methoxyphenyl)-1,3-dihydroxyisopropoxy]-2-hydroxyphenyl]propyl alpha-L-rhamnopyranoside
Peak:m/z	Relative Intensity
197.1472473	0.02
219.4310455	0.02
227.3195190	0.08
255.2568665	0.06
261.1086731	0.07
269.1323853	0.03
271.3819275	0.04
273.2727051	0.05
303.0959473	0.06
317.5527344	0.07
318.3892822	0.06
319.4022827	0.10
323.3560181	0.03
333.1822510	0.02
334.5208130	0.04
347.2169189	0.02
361.1553955	0.54
365.9627686	0.12
375.3618164	0.05
378.1586304	0.02
379.1759033	0.53
379.8465576	0.02
380.4943237	0.04
391.3167114	0.03
397.2472534	0.02
403.0248413	0.03
417.4725342	0.02
419.3244629	0.06
421.4884644	0.04
453.3281250	0.04
455.2302856	0.05
479.1707153	0.14
481.4420166	0.36
495.2128296	0.33
497.3838501	0.22
498.1365967	0.03
511.4984741	0.04
521.4867554	0.03
523.2786255	100.00
524.3170776	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	767.4213
Annotation	Perseanol
Peak:m/z	Relative Intensity
231.2434235	0.08
238.9274902	0.03
245.3291473	0.07
247.3689728	0.21
256.2809143	0.02
257.1086121	0.08
258.0415039	0.09
259.4182739	0.02
270.2868347	0.02
275.3494873	0.29
283.1397400	0.04
285.1697388	0.37
287.4422913	0.12
289.2764893	0.41
301.1633911	0.03
303.1865540	0.51
319.2359619	0.91
321.2597656	0.52
331.3547974	0.11
332.2999878	0.10
333.1311646	0.03
339.2838135	4.56
345.4677124	0.02
347.3609619	1.37
363.1259460	0.19
365.3618774	2.30
375.1934814	1.82
376.3093872	1.35
377.1817017	0.33
380.1890259	0.05
381.4659424	0.02
383.2488403	100.00
384.0972900	0.07
391.1808472	0.15
401.2888184	0.03
419.3219604	0.06
437.2594604	0.04
522.6152954	0.12
551.3988647	0.04
554.1797485	0.03
556.2041016	0.04
565.5029907	0.18
566.9450073	0.03
569.6576538	0.06
597.3938599	0.01
604.4906616	0.09
619.3801270	0.10
642.2932739	0.01
646.4079590	0.14
662.5418091	0.04
669.6118774	0.11
681.2776489	0.03
693.2468262	0.06
705.3304443	0.33
721.4679565	0.15
722.7946777	0.11
724.7520752	0.03
726.3775024	0.02
734.9005737	0.03
747.4838867	0.10
749.3780518	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.18
Annotation	Geniposide pentaacetate
Peak:m/z	Relative Intensity
174.9276733	0.09
179.0167542	0.19
194.9510498	0.39
205.2348022	0.20
209.0742798	0.65
225.0941010	1.03
251.1814575	0.16
254.0812378	0.12
303.1334839	0.79
315.2571106	1.25
339.1030273	0.10
345.2723999	0.19
346.2958984	0.10
347.3076782	0.05
355.1556396	0.51
357.2101440	100.00
369.2522583	2.73
371.3308105	0.26
381.6203613	0.13
387.2804565	86.79
388.1946411	0.04
399.2260132	3.60
405.3455200	0.10
411.2073975	0.28
417.2304077	24.59
423.3162842	0.23
429.2337646	1.61
431.1510620	0.17
434.2464600	0.26
435.1690674	1.41
441.1829834	1.33
443.1532593	0.08
447.1361084	0.73
453.4099731	0.04
459.2116089	19.00
469.3587036	0.13
471.2309570	2.05
475.2788086	0.13
477.0838013	70.35
477.7854004	0.20
483.3665161	0.10
489.2397461	16.92
490.6367798	0.03
500.0563354	0.06
501.3574219	0.20
505.4473267	0.14
507.2380981	5.09
509.1232300	0.08
515.4093628	0.05
519.3934326	0.39
529.4039917	2.04
531.3096924	0.24
542.9362793	0.48
549.1801758	1.99
551.5127563	0.30
561.2034302	2.67
565.1026611	0.09
566.1605835	0.21
567.1762085	0.09
579.2852783	15.78
580.2717896	0.15
582.4389648	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	427.182
Annotation	Pyridinoline
Peak:m/z	Relative Intensity
132.0716248	0.06
223.1346130	0.07
235.2069702	0.31
246.1012573	0.04
265.1651306	0.06
271.1760559	0.05
277.8296814	0.04
281.2877808	0.04
305.0552673	0.05
306.7633057	0.03
311.1962891	0.11
312.0085449	0.06
331.0442505	0.14
340.3045959	0.45
347.2386475	0.03
353.2436218	0.08
365.1083984	0.12
381.1895752	100.00
383.2745056	0.21
395.5959778	0.03
409.0279236	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	428.2634
Annotation	Unknow
Peak:m/z	Relative Intensity
126.9863586	0.08
137.0502014	0.10
144.9006195	0.01
151.1795349	0.09
154.7617798	0.05
156.0034637	0.04
164.1911621	0.11
165.1198425	0.01
168.0734100	0.06
185.1253510	0.04
186.2738190	0.06
191.2644196	0.11
195.9032745	0.13
196.8316803	0.02
198.8370514	0.02
205.9230499	0.12
207.1285400	0.04
209.8878937	0.03
213.1101379	0.08
224.2229614	0.10
224.9826965	0.06
228.1632385	0.02
229.2097321	0.06
236.2418518	0.04
239.4036255	0.02
241.2881775	0.09
242.2271423	0.10
247.4611816	0.04
249.3007507	0.17
257.1308289	0.05
259.2660217	0.17
265.2404480	0.04
266.1348877	0.15
267.2608643	0.77
269.4163513	0.05
272.2062378	0.05
283.1871948	0.14
285.2216797	1.04
287.2976074	0.08
293.3537903	0.09
295.2156677	0.61
296.7833862	0.05
301.2044983	2.42
303.1459351	0.53
306.2716064	0.11
307.5662231	0.11
310.5050659	0.03
311.4820557	0.03
313.2581787	1.33
315.0376587	0.04
316.1111755	0.01
319.0202332	0.07
321.4955444	0.03
331.2210083	3.49
333.2837524	0.05
337.9834595	0.17
341.9376831	0.05
344.8218079	0.01
347.2285156	0.06
349.2215271	4.86
355.2160034	0.09
356.3714600	0.77
362.4053650	0.21
365.4959106	0.08
366.1451111	0.13
367.3164673	2.67
368.6237488	0.05
374.3176270	1.54
374.9846497	0.02
382.5015564	0.13
383.1584167	0.08
384.1280823	0.09
385.4790039	0.09
386.2892151	0.02
387.0125427	0.02
392.3124695	17.16
393.1543579	0.05
396.8835754	0.08
398.2446594	0.06
410.2521057	100.00
411.3070374	0.06
418.3996887	0.07
419.3564148	0.07
428.4507141	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.09
Annotation	6-Methylflavonol
Peak:m/z	Relative Intensity
77.09809113	0.60
78.83586121	1.33
80.89196014	2.99
82.87320709	0.14
84.78601074	0.48
86.82229614	0.41
90.90719604	0.40
93.0597229	1.04
94.86606598	5.21
95.47719574	0.15
96.85739136	0.36
99.17367554	0.21
103.2141266	0.78
104.9528656	2.14
107.0849762	1.15
108.108963	0.18
108.9879303	3.37
110.9606171	2.24
113.0082397	0.51
119.1524811	1.06
121.0641327	1.89
122.9859314	3.22
126.9798279	1.77
127.8164368	0.31
128.9470367	4.85
129.9028168	0.08
132.9665833	2.24
135.0361633	2.23
136.2078705	0.30
137.0937042	1.85
138.9980774	1.07
141.1200867	1.49
143.2989349	0.40
145.2348328	1.54
147.0018768	2.53
148.9488983	0.48
150.9305115	45.83
151.9773712	4.73
152.9069519	2.49
154.121933	0.60
154.9765472	2.08
157.0800018	1.29
158.2140656	0.56
161.073349	0.91
163.1108551	1.22
165.1594086	2.41
167.0735016	0.78
168.0615387	0.65
169.0797119	2.51
171.1403656	0.33
173.1204071	0.51
175.0653229	3.43
176.9586792	0.62
178.2659607	0.58
179.2345428	1.50
179.8748627	0.15
181.0471954	0.28
182.018158	0.69
183.0275574	1.67
184.2588959	0.30
185.0601501	0.58
189.2790985	0.71
193.0833282	3.53
194.2682343	0.60
195.1236725	2.60
197.2094574	9.00
199.1178436	1.10
203.1308594	0.71
205.3616333	0.68
207.2180023	2.28
209.3141632	1.45
210.298172	1.77
211.1289062	5.74
217.0999146	12.93
221.1777649	0.47
223.2531128	0.17
225.1394806	7.59
226.2530518	0.30
230.0341797	0.17
232.5812531	0.60
235.1541138	45.66
236.1833954	0.64
238.0568237	7.68
239.1350708	2.20
240.5753021	0.41
243.7036133	1.33
251.0440063	0.67
253.0791016	100.00
254.2074127	15.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	779.2455
Annotation	Unknow
Peak:m/z	Relative Intensity
227.1215973	0.27
244.4428558	0.36
245.1309204	1.88
246.9598999	0.26
263.2160034	0.24
265.1676941	1.92
265.8919678	0.25
277.1555176	0.08
283.1977539	3.39
287.0299988	0.19
305.0514832	1.11
321.1433411	2.55
324.7672729	0.08
337.2120972	0.17
339.1625366	0.23
341.2636108	0.69
349.3749390	0.21
359.0944214	0.23
371.0626221	0.18
377.1425781	0.25
379.1575928	4.45
397.1458130	2.87
415.2137451	0.84
419.4279785	0.26
421.6026611	0.12
431.2236328	0.38
436.6511230	0.26
439.0592651	0.05
449.2356567	0.98
454.1455078	0.10
463.2444458	0.03
479.3691406	0.04
481.1914062	0.38
482.3796997	0.29
485.1642456	0.08
491.3493042	0.71
493.5321045	0.60
509.3087769	0.13
511.2580566	1.36
513.0607300	0.09
522.9172363	0.17
524.3193359	0.14
525.2149658	0.13
528.8829956	0.55
529.5424194	0.80
543.4492188	0.56
553.2581177	0.09
561.4818726	0.87
566.9133911	0.74
568.6549072	0.26
569.4267578	0.48
570.9241943	0.06
585.2103882	0.13
587.3952026	0.12
603.2521362	0.08
605.3206787	0.31
609.7429810	0.26
617.3291626	0.11
624.7055054	0.53
627.5531616	0.25
629.3236694	0.07
643.2485352	1.64
644.3575439	0.24
645.3575439	0.31
646.2587891	0.90
647.2991943	1.83
661.2409058	5.73
661.8532715	0.08
668.3410034	0.06
669.2682495	0.38
675.4584961	0.55
687.3527222	2.89
693.3352661	1.78
699.3278198	0.57
701.3722534	2.03
703.1859741	0.32
704.6401978	0.17
705.2808228	3.01
717.8904419	0.67
719.2971191	100.00
720.4895630	1.49
729.4306030	0.17
737.3401489	48.40
738.3544312	0.91
747.3168335	12.36
748.3624878	0.22
761.3359985	1.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	527.2527
Annotation	Canavalioside
Peak:m/z	Relative Intensity
163.0688477	0.27
170.8231201	0.26
172.0964661	0.10
179.0623474	0.50
180.9749146	0.26
185.1047821	0.39
187.0554962	0.26
191.2653503	0.54
192.1395264	0.26
202.9126434	0.46
210.9486847	0.24
212.9002686	0.19
219.2555695	0.37
221.0638123	0.28
223.1864624	0.11
224.9357910	0.14
226.9697723	0.41
229.2011871	0.27
233.0855713	0.68
235.3228760	0.56
239.2986450	0.13
243.4077911	0.69
244.3732910	0.53
245.1867981	0.14
246.0401306	0.39
247.3635101	0.63
249.4949341	1.70
250.9723816	0.23
253.2831573	0.13
255.3366699	0.80
257.2322388	2.60
260.7728577	1.21
265.2912598	0.31
266.2822876	0.19
273.2540894	1.63
275.4552002	0.43
277.0200500	0.23
277.7164917	0.93
283.1241150	0.47
285.2392273	11.23
286.3736572	0.92
288.9073792	0.32
291.4705200	0.85
299.0224609	0.13
301.2200928	2.48
303.2541504	30.46
304.2032471	1.42
307.2147827	0.62
309.2325439	0.21
311.3486938	0.96
316.3214111	0.19
317.3557739	0.86
319.3156738	3.24
321.2391357	5.19
322.2224731	0.20
329.1652222	5.18
330.2170410	1.48
331.4374390	0.52
333.3363037	0.26
335.6553955	0.15
337.2747192	2.33
338.3588867	0.51
343.2988281	0.68
345.1175537	0.34
347.3288574	66.26
348.2833252	5.40
349.3027954	1.10
354.8193970	0.15
360.8286743	0.23
361.5148315	0.41
362.5546265	0.45
363.4274292	0.45
365.2423706	97.89
366.1824951	8.05
367.4990234	0.36
368.5020752	0.31
369.5155640	0.29
373.4203491	0.17
379.3217163	0.37
389.2581787	0.59
400.9979248	0.30
404.9586792	0.44
407.3142090	1.00
408.3705444	0.20
449.3056641	52.26
465.3404541	0.97
479.0498047	0.75
481.1914673	100.00
481.8555298	0.47
483.3104248	16.41
484.3037720	1.70
486.5106812	0.66
491.2639160	0.75
497.1831665	2.02
499.4214478	13.72
500.3762207	0.11
507.3989868	1.47
508.1403809	0.39
509.3220825	37.84
510.3175659	2.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.119
Annotation	2-(3-Hydroxyphenyl)ethanol 1'-glucoside
Peak:m/z	Relative Intensity
112.9724503	0.02
118.9364700	0.08
128.9098969	0.05
134.1705627	0.04
142.9764404	0.07
149.0653534	0.06
161.0415344	0.22
167.9884949	0.07
179.0664520	0.50
183.0043488	0.52
197.0811768	0.06
223.0793152	0.05
224.2933655	0.04
230.0675964	0.02
239.1956482	0.08
241.2366333	0.03
255.1881104	0.07
257.1985779	0.14
271.1913452	0.07
285.3365173	0.05
295.1568298	0.16
299.0910034	100.00
301.1834106	0.27
306.6340332	0.02
327.1997986	0.13
328.2742920	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	182.0807
Annotation	4,6,7-Trihydroxy-1,2,3,4-tetrahydroisoquinoline
Peak:m/z	Relative Intensity
136.0348511	25.41
146.9288940	0.03
164.9840698	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	538.1249
Annotation	Unknow
Peak:m/z	Relative Intensity
164.8189697	0.03
181.0830383	0.70
184.9185028	0.18
198.9420471	0.38
211.0621033	0.07
228.1864929	0.12
231.0937042	5.65
235.1091919	0.11
246.8523560	0.23
256.2034912	0.15
256.9929199	0.12
260.8869629	0.02
263.1136169	0.97
265.2073975	0.13
271.3948364	0.11
288.3406372	0.08
289.1488037	0.23
290.1307068	0.05
306.0655518	12.06
308.1148071	0.10
317.0379028	5.47
322.1143799	0.07
334.0314941	100.00
364.1600952	0.30
373.0017090	0.16
374.2465820	0.08
375.2987061	0.11
376.1772461	0.10
380.9888916	0.15
391.1343994	0.98
392.2847290	0.54
405.6994629	0.09
409.0647583	69.76
409.6769409	0.40
417.1398315	0.10
443.8577881	0.04
445.2132568	0.62
463.1420898	1.01
475.1984253	0.35
477.9821777	0.27
490.1555786	0.06
493.1663818	0.07
520.2087402	12.15
521.2092896	0.31
529.3595581	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
129.3766479	0.42
139.1380005	0.27
142.9585876	0.15
157.2590637	0.31
164.6547241	0.41
171.02034	0.51
175.1916809	0.45
179.3836365	0.17
184.8313904	0.57
187.1659241	2.02
193.0853577	0.21
199.133667	2.32
201.2605896	3.68
203.2585144	0.67
213.1128235	1.26
215.1057129	0.73
224.9020081	0.52
227.1476746	0.38
229.1248474	0.64
243.3075867	1.65
245.1981201	0.35
251.3732605	0.27
257.3208618	0.74
259.2493896	0.70
261.0105286	0.14
262.3201294	1.05
269.2367554	1.21
270.1186829	0.29
271.2565613	3.16
273.3533325	2.57
285.2758789	5.65
289.3195496	1.68
295.1506958	1.65
297.1635742	1.29
299.4509888	0.56
301.3417969	2.04
307.3678894	0.20
311.1403503	7.95
313.1130371	4.88
315.2879333	0.78
321.3013306	0.99
322.063324	0.62
323.3677063	7.98
325.0041199	0.51
329.2147827	0.14
330.074585	0.27
334.2859192	0.51
337.0480347	1.28
339.2555542	100.00
341.3531189	12.29
342.1476746	0.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	383.1195
Annotation	Unknow
Peak:m/z	Relative Intensity
110.9781952	0.09
126.8925629	0.05
172.8766479	0.16
191.0418701	100.00
196.1048584	0.04
205.1987000	0.03
218.0399170	0.05
263.2259216	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
111.1025772	0.29
117.090126	0.31
118.0466614	0.10
129.0589294	0.44
140.7052002	0.56
155.2472229	0.20
157.2867126	0.62
171.0296173	2.39
172.9624634	1.09
175.1256409	0.28
185.0158081	0.90
187.0628815	3.12
197.1343536	0.15
199.1448364	2.08
201.0827637	5.19
202.6248474	0.55
203.3845215	0.43
208.8081512	0.17
213.0220184	1.23
215.0958862	5.52
217.1349182	0.49
227.0559387	1.68
229.1311951	5.67
231.3357239	0.16
235.2353821	0.27
241.1865234	0.97
243.1490784	2.53
245.247345	1.03
247.3588257	0.52
255.2724304	1.30
257.3177795	5.05
259.1981506	0.67
261.4810791	0.84
263.4025879	3.49
267.6703491	0.40
269.2507629	2.23
271.282959	3.12
272.9949341	0.86
274.9475098	0.31
276.2085571	0.51
279.2169495	0.19
281.531189	0.20
283.3422852	3.33
285.1870422	8.25
287.2696228	1.10
288.4049377	0.41
295.2334595	5.19
297.2780151	7.56
299.4108582	7.87
301.3037109	2.71
303.1080017	0.19
310.2357178	0.17
310.9991455	0.43
312.4101257	0.28
313.398468	1.44
314.0205688	0.18
315.3712158	5.67
321.3320312	2.05
323.2885132	6.27
325.0722656	0.34
329.5346985	0.23
334.9890137	0.34
337.4258423	0.94
339.244873	100.00
340.6754456	3.20
341.3716125	20.62
342.7076721	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.225
Annotation	Lactulose
Peak:m/z	Relative Intensity
281.0794678	0.01
339.2962036	0.08
341.1260986	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
153.0041199	0.46
170.9676514	0.15
173.1310272	0.57
183.1310272	1.27
185.0415039	0.53
197.280365	0.22
199.2621613	2.32
213.3709106	0.77
215.2207336	1.69
217.2369385	0.54
227.3312683	0.62
229.1839294	1.52
239.5542603	0.27
241.1233521	2.32
243.3604431	1.71
245.2148132	0.46
255.3385925	3.31
257.1488037	2.95
259.2755127	0.96
263.4737549	2.45
265.1358948	0.38
269.1873169	1.69
271.103241	1.49
272.8906555	0.29
273.5166931	0.25
277.3778381	1.15
283.2876282	0.41
284.3211975	0.22
285.228241	1.56
287.4006958	1.47
289.2642212	1.13
290.9825134	0.55
295.4368591	2.00
297.3222046	2.26
299.2745056	2.02
300.4292908	0.46
303.4371948	0.34
309.576416	0.48
311.3196411	6.94
313.211792	5.63
315.3729858	2.98
321.3056641	2.04
322.0015564	1.05
323.2399902	8.11
325.4135437	1.50
326.9637146	0.64
339.2558594	100.00
340.1105957	0.33
341.2546082	18.13
342.1583557	1.82
357.1947937	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1659
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
111.0365295	0.10
112.8860626	0.42
118.9446640	0.24
129.1201782	0.08
131.1632843	0.03
132.1620636	0.08
143.1360168	0.21
144.9228973	0.17
147.0751343	0.19
151.1606445	0.16
153.1203308	0.04
158.9192657	0.06
160.8451233	0.14
163.1419067	30.72
164.0649872	0.22
165.0483398	0.03
166.1313019	0.44
179.1374207	0.09
180.1183472	0.06
181.0853577	0.07
193.0564423	0.14
207.2676544	0.30
207.8756409	0.03
209.1901550	1.47
223.0243530	1.04
224.0289307	0.95
225.0427246	100.00
225.6541138	0.79
239.0129700	0.21
245.1694641	0.03
249.2408752	0.09
253.4861450	0.05
265.1305542	0.12
266.0117493	0.05
267.0183716	0.79
271.2122192	0.12
281.3682251	0.08
287.3057861	0.31
289.1202698	0.07
297.0699463	0.10
319.4055786	0.07
322.9716187	0.14
327.1046143	0.20
328.3633118	0.04
329.0736694	0.11
341.2437744	1.66
342.9364319	0.03
357.1366577	0.10
369.2306213	5.38
370.7968445	0.30
372.2729187	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	644.03
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
180.8492432	0.06
190.0912933	0.06
197.0329132	0.07
197.9491577	0.15
208.1002655	0.14
211.1835785	0.10
214.9145203	1.38
233.0044708	1.67
238.2096252	0.03
242.0757141	0.09
243.9651794	0.13
246.3361664	0.05
256.8167114	0.25
262.0092468	1.30
263.9774475	1.26
273.2801208	0.10
280.1367798	0.37
282.1311646	3.21
284.0976562	0.14
291.0590820	0.07
299.1151123	0.19
300.1007080	3.31
301.9588623	0.05
304.9769897	0.03
307.8447266	0.12
310.9963989	0.53
314.0819702	0.06
317.0579224	1.92
317.8932495	0.09
323.0961304	2.16
324.0242920	0.03
326.0294800	0.05
329.0073853	2.17
329.8406067	0.03
333.0594482	0.25
334.1223145	0.20
335.9169312	0.03
340.0707397	0.43
342.0176392	0.43
348.3172607	0.09
349.0919800	0.05
350.0305176	0.40
351.1860962	0.10
354.1508179	0.08
356.9202271	0.14
360.2471313	0.05
361.0433350	0.26
362.1267700	0.37
364.2188110	0.69
367.2689819	0.13
369.4328613	0.04
371.2073975	0.91
372.0845947	0.14
375.0895386	0.45
380.0797729	0.71
383.9641724	0.17
386.0219727	0.41
392.7019043	0.99
393.3674927	2.31
398.1212769	0.76
400.0554810	1.84
401.8528442	0.06
404.0990601	0.19
405.1630859	0.06
409.6093750	0.77
411.1681519	0.35
412.1425171	0.31
413.0767212	0.28
418.0145264	30.19
419.1856079	0.31
421.2294312	0.10
422.2105103	0.11
423.0594482	1.69
427.1618042	0.07
427.9837036	0.11
429.1994629	0.36
430.9428711	0.21
432.1060181	0.41
434.3298950	0.18
439.8591309	0.05
441.0212402	7.80
441.6865234	0.12
445.9777832	0.07
447.1366577	1.27
450.2981567	0.05
450.9003296	0.45
455.4859619	0.12
457.1107178	0.11
460.1480103	14.05
463.8609619	0.04
465.2335815	6.47
467.0408936	0.11
468.9677734	0.17
469.8109741	0.18
470.7466431	0.04
471.9864502	1.75
472.7651367	0.02
474.4656372	0.08
475.9446411	0.48
476.8407593	0.45
482.4483643	0.06
483.3353271	0.36
484.6145630	0.54
485.2704468	0.16
485.9331665	0.04
487.0862427	0.32
489.9808350	2.15
493.1293945	0.18
494.2536621	2.18
499.1141357	1.20
499.9083252	0.23
503.0999756	1.21
511.1314087	38.96
512.2072144	0.20
514.1348877	0.41
515.3021851	0.39
523.3085327	0.29
526.3179321	0.89
527.1503296	0.24
529.0816650	4.44
532.0891724	4.51
540.8323364	0.25
545.1199341	0.05
553.1880493	0.18
555.2633057	0.28
557.6137695	0.41
558.8748779	0.33
559.8591919	0.95
560.7265625	0.19
565.1412354	6.25
583.1535645	2.37
601.0410156	100.00
601.8172607	0.69
606.1701050	0.14
626.1683350	0.16
626.8515015	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	580.2737
Annotation	Unknow
Peak:m/z	Relative Intensity
170.9937439	0.09
180.1791077	0.10
183.2064209	0.35
198.9854736	0.12
205.2230835	0.20
207.3364563	0.17
220.2807922	0.15
223.2231598	0.15
224.2154541	0.34
230.1779633	0.24
231.2278442	0.06
236.1365814	0.19
238.9828949	0.37
239.6457825	0.13
249.2073517	0.24
251.8281250	0.37
260.9322510	0.05
262.7642517	0.21
264.2274475	0.10
267.3775330	0.65
270.2842407	0.19
274.3953247	0.24
277.8740845	0.10
288.2105713	0.09
295.4161377	0.75
296.4049988	0.22
299.4299927	0.11
301.1111145	0.18
303.0095825	0.27
314.2861938	0.42
326.0845947	0.06
327.1516724	0.09
336.2343140	0.22
344.1948853	0.18
344.9768066	0.10
355.3777466	0.30
362.1804810	0.10
364.2653809	0.08
372.4953003	0.33
374.4710083	0.21
388.2459106	3.47
390.3904419	0.38
396.2501831	0.11
400.2623901	2.65
401.3472290	0.33
402.7409668	0.22
406.3844604	0.03
416.3368530	0.11
418.2705078	100.00
419.3107300	2.52
423.4948120	0.22
425.2760620	0.06
430.8596191	0.15
433.0009766	0.09
440.5896606	0.49
446.3392944	0.19
448.3829956	0.23
449.0502319	0.13
451.3851318	0.22
458.1797485	0.32
459.7645264	0.21
460.4567871	0.30
462.2607422	0.35
471.4425659	0.04
482.5993042	0.08
484.4664307	1.30
489.8248901	0.31
498.3078003	0.24
506.1260376	0.17
518.5170898	0.09
520.0998535	0.04
527.2122803	0.16
534.2044067	0.19
535.1437988	0.04
536.0087280	0.46
537.4750977	0.26
539.4888306	0.26
550.3507690	0.64
552.5775757	0.28
561.7616577	0.91
562.4790039	1.70
567.4261475	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.2555
Annotation	5beta-cholestan-3alpha,4alpha,11beta,12beta,21-pentol-3,21-disulphate
Peak:m/z	Relative Intensity
179.0385132	0.80
191.0875397	0.24
207.1961212	0.44
209.2361298	0.84
217.0189056	0.11
225.1746216	10.39
227.1889343	35.91
235.3738098	1.02
243.4048004	0.32
245.2351074	0.09
251.1817932	0.81
262.8021851	0.41
269.2298279	21.76
273.1672363	0.17
278.6635742	0.25
281.1787109	0.13
282.4363708	0.17
283.1198730	0.41
287.1768799	100.00
293.3186035	0.17
304.9749451	0.68
311.0423584	0.25
315.2467651	0.18
323.2016907	7.88
329.2128296	0.80
341.1390381	36.67
359.2097168	2.60
371.0231323	0.49
383.0663452	4.67
389.1756592	2.16
395.3028564	0.06
413.1490479	1.33
424.7471924	0.43
431.2689819	11.49
449.2265015	24.22
449.8697510	0.12
524.4232178	0.07
533.1126709	0.69
557.3800659	0.08
565.3966675	0.28
566.6585693	0.16
575.2544556	1.71
593.3596191	71.15
594.2074585	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	630.1055
Annotation	Oganomycin A
Peak:m/z	Relative Intensity
188.0098267	0.07
196.9393921	0.18
202.0970764	0.09
203.6049194	0.06
208.1288147	0.07
252.8731384	0.09
254.0421753	0.20
263.9413452	0.19
266.1342468	0.10
272.0094604	0.34
276.1973877	0.13
287.6510925	0.12
288.2854004	0.13
292.2344666	0.05
306.0527649	0.16
306.7242432	0.44
311.8831177	0.05
318.7491150	0.07
320.0894165	0.30
328.9278564	0.06
332.0775146	0.09
340.1445312	0.20
348.0499268	2.12
358.5109863	0.07
360.4773560	0.09
364.1717529	0.74
366.6318970	0.09
394.0538330	100.00
394.6875000	0.43
409.2078247	0.07
410.1506348	0.19
419.9204712	0.33
432.3143921	0.43
436.1105347	0.11
438.1062622	67.05
439.9596558	0.10
450.1696777	0.66
458.5932617	0.04
468.0835571	0.74
510.0191650	0.15
518.0878906	0.09
519.1067505	0.04
540.1505737	0.14
552.4548340	0.09
570.0271606	1.37
575.8837280	0.10
582.3916626	0.24
584.0432129	0.07
585.5783691	1.97
594.0910034	0.15
610.3789062	0.10
611.8254395	2.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	645.1881
Annotation	beta-D-4-Deoxy-Delta4-GlcA-(1->4)-beta-D-Glc-(1->4)-alpha-L-Rha-(1->3)-D-Glc
Peak:m/z	Relative Intensity
198.8325806	0.05
202.9310150	0.10
206.5988159	0.17
214.9449463	0.31
223.0779114	0.33
227.2163849	0.04
228.8059082	0.32
245.1142273	0.97
249.1193848	0.51
257.3117981	0.08
263.2545471	0.10
285.0064087	0.08
302.1439514	0.10
303.0093384	0.07
304.9965210	1.25
317.0929565	0.49
321.0792236	1.27
341.4336548	0.51
343.1701050	0.10
349.3837891	0.15
358.8692627	0.80
363.0736084	0.54
364.2673340	0.10
371.3977661	0.04
375.1921387	0.36
377.0089722	0.52
381.1804199	3.48
393.1281738	1.26
395.4354248	0.03
400.8898315	0.08
403.2220459	1.31
409.3071289	0.34
411.0627441	0.33
417.4473267	0.75
419.1886597	0.56
421.1598511	1.65
435.1317749	3.21
451.0202026	0.17
453.1589966	10.13
462.9368896	0.24
471.2539673	2.11
475.2155762	0.20
476.9620972	0.56
481.2014160	0.75
483.0683594	0.38
493.2301025	0.10
495.2221680	2.06
503.4417725	0.11
507.1915283	0.38
513.2800903	33.58
525.2337036	1.98
535.2180786	1.52
543.2188110	1.95
549.2230225	0.34
553.3272705	1.46
555.2534790	0.66
567.2304077	26.52
585.2180176	100.00
586.0936279	0.02
597.4666138	0.15
599.4758911	0.15
603.3059082	6.98
606.1966553	0.47
609.2398682	0.10
610.8167114	0.08
613.2208862	2.14
615.4852295	0.11
627.3018799	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	718.3077
Annotation	Maytanbutine
Peak:m/z	Relative Intensity
223.3171692	0.07
249.2574768	0.11
332.9309692	0.63
418.1029053	0.10
430.3735962	0.10
440.3115234	0.09
451.9772339	0.20
480.0657349	0.62
505.2459106	0.06
584.4096069	0.28
620.4756470	0.21
622.0712280	0.16
628.4359131	0.14
645.2928467	0.52
652.1482544	0.74
654.1790771	0.13
656.6631470	0.17
657.6892700	0.16
672.3023682	100.00
672.9959106	0.57
674.9105225	0.85
677.1036987	0.07
700.3713989	1.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	272.96
Annotation	Ribose-1-arsenate
Peak:m/z	Relative Intensity
114.9880829	4.85
131.0697937	0.09
158.9177856	100.00
159.9576263	0.24
198.9551392	2.49
200.8683777	0.07
217.0693665	0.80
228.8788452	27.72
229.8559875	0.04
245.0249023	0.35
246.8114014	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	472.1648
Annotation	Unknow
Peak:m/z	Relative Intensity
148.0445862	100.00
181.1428833	0.52
187.1179199	0.19
229.3486176	0.45
245.1913452	0.32
271.9058838	0.10
288.9465027	0.14
292.4307251	0.23
309.2761841	0.64
310.2679443	0.71
325.0437927	0.55
347.1897278	0.18
396.1138000	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	383.2054
Annotation	Cinncassiol A
Peak:m/z	Relative Intensity
123.0430984	0.02
146.9885864	0.02
148.9773560	0.02
154.6959686	0.04
165.2264404	0.05
182.9495544	0.04
184.9888153	0.04
193.0247803	0.08
201.1724548	0.04
203.4371948	0.05
204.0410461	0.06
208.8966064	0.06
211.0003662	0.07
235.3186646	0.03
237.1466370	0.09
239.2049255	0.41
240.2286987	0.05
253.3152161	0.02
255.2970581	0.09
259.3224182	0.03
261.1030884	0.72
265.2283020	0.12
273.2550659	0.11
279.3146973	0.15
281.2456055	0.04
283.3060913	0.59
285.2430420	0.06
287.0124207	0.02
293.3058167	0.11
295.2810059	0.06
299.1608887	0.09
301.1941223	0.42
303.4760132	0.05
305.3256836	0.04
310.7017517	0.51
311.3040771	3.19
317.3038635	0.02
319.1682739	1.20
329.1057739	6.92
337.2739258	2.53
345.7715454	0.08
347.2177429	25.56
351.3676758	0.05
365.1332703	100.00
366.1513367	0.06
368.8780212	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	285.1343
Annotation	Unknow
Peak:m/z	Relative Intensity
93.0593033	0.07
97.2615814	0.06
142.8909607	0.09
152.8472748	0.20
155.3027649	0.05
165.5039062	0.17
169.2825165	0.08
181.1671753	100.00
183.5182800	0.20
204.2593994	0.06
205.0912781	0.37
207.0876465	0.70
211.2553406	0.15
212.8999939	0.74
214.2958984	0.13
214.9941406	0.22
223.3240967	0.49
225.0908813	88.28
233.3700562	0.11
239.2369690	1.13
240.4231567	0.18
241.0913391	4.85
243.1560364	4.23
249.2005310	0.28
267.1071167	8.73
268.1924744	0.88
269.2882080	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	381.1554
Annotation	7alpha,8alpha-Dihydroxycalonectrin
Peak:m/z	Relative Intensity
117.0929260	0.08
136.8813629	0.04
142.9929504	0.09
153.2076721	0.03
159.2854614	0.08
161.0552673	0.06
162.9089661	0.06
166.7431335	0.13
170.8508606	0.04
175.2570190	0.20
177.3478851	0.04
193.1083984	0.12
199.8016205	0.09
201.1506653	0.17
203.4515686	0.02
215.2406158	0.34
217.1809692	0.48
218.2607422	0.10
219.1611938	0.06
221.2412415	0.18
222.2266846	0.07
227.1498413	0.32
229.1976624	0.66
230.3042297	0.06
231.0864258	0.08
232.3606262	0.03
233.3325806	0.66
235.1956787	0.22
237.2261658	0.39
239.1550903	0.73
242.0875244	0.02
243.0849915	0.08
245.1772461	0.71
247.2997742	0.69
248.2899170	0.03
253.2128906	0.07
255.4802856	0.34
257.1944580	2.32
259.1903381	0.11
261.2653809	0.08
263.1840820	1.27
265.1235657	0.66
267.3842773	0.03
273.2393188	1.13
275.2462158	9.79
276.3966064	0.31
283.3344727	0.12
284.3102722	0.03
289.2686157	0.09
291.1547241	2.52
292.1547852	0.06
293.2249146	6.96
294.3160400	0.32
295.3515625	0.07
301.2235107	3.02
307.4331665	0.10
317.3875427	0.02
319.1832886	11.17
320.2733154	0.39
335.1387634	3.08
337.2116394	100.00
338.3487854	3.12
343.0530396	0.02
345.2676086	0.30
349.2185974	0.02
363.2900696	2.32
364.4515686	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	614.9
Annotation	Unknow
Peak:m/z	Relative Intensity
198.8662872	0.10
228.8426514	0.06
272.9820557	9.04
288.8582153	0.03
384.9178467	0.05
386.4641724	0.88
387.0739746	18.18
406.9566650	0.03
481.5935669	0.12
485.0187378	0.04
499.2136230	0.06
500.8361206	100.00
501.4364624	0.53
525.2528687	0.02
526.9663696	0.02
530.2089233	0.12
541.0126953	0.13
542.9428101	0.02
568.8377075	0.26
571.0069580	0.07
582.8746948	0.10
587.7339478	0.08
597.1198120	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	465.04
Annotation	Unknow
Peak:m/z	Relative Intensity
174.9874878	0.13
209.0254059	1.06
211.2373047	0.23
250.8824768	0.24
253.0340576	0.32
260.7887878	0.18
267.4507446	0.09
284.8858643	0.15
291.1644287	0.84
294.6260376	2.24
295.4679871	0.16
296.7588501	0.38
300.9636230	0.36
303.2638550	0.78
304.1859131	0.11
323.9775391	0.31
326.2412109	0.27
327.9815674	0.33
329.3140259	0.13
331.4646606	0.18
332.9075623	3.08
336.1082153	2.86
337.4968872	0.11
345.0136719	0.46
364.3540039	0.73
367.1203308	1.04
378.3843994	0.65
379.1258545	0.89
381.1697693	100.00
403.6397400	0.07
408.2319031	0.40
419.0564270	23.01
419.8707581	0.14
423.1839294	0.11
434.9518127	0.27
441.5403442	0.41
446.0963440	0.28
447.2463989	2.15
447.9728088	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	477.1765
Annotation	Scorzodihydrostilbene D
Peak:m/z	Relative Intensity
136.0810242	0.05
143.0715332	1.16
145.0741882	0.12
148.7038727	0.41
160.9082336	1.95
178.9843445	3.54
203.3927307	0.08
239.0826416	0.26
243.3209839	0.87
253.1478577	20.22
255.3521423	0.28
256.0611572	0.12
257.3340759	0.10
269.1301270	2.15
271.2256470	56.56
273.1897583	0.28
283.1808777	0.48
291.0524597	0.41
295.2265930	0.33
296.7196655	0.13
312.2134399	0.08
313.1799622	0.25
314.7025146	0.75
315.3059387	0.40
324.8948364	0.31
327.2130737	0.49
331.3592529	0.11
355.4137878	0.42
365.1474304	0.19
374.3015442	0.10
377.6460266	0.14
379.2562866	0.08
380.2139893	0.17
381.0130615	0.04
387.3871460	0.19
389.1492004	0.38
394.8443298	0.06
396.9662781	0.11
403.1112061	0.12
404.3804016	0.23
405.2361755	0.10
415.3257751	0.12
416.3669128	0.11
417.2515869	0.13
419.5903320	0.89
421.1003113	0.15
431.0551453	0.20
433.2315063	100.00
433.8581238	0.09
434.6101685	0.45
439.1859741	0.38
441.1796265	0.20
449.2137756	0.15
459.1128540	2.27
460.2341309	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.1768
Annotation	4,6,2',4'-Tetramethoxychalcone 2'-beta-glucoside
Peak:m/z	Relative Intensity
173.0527191	0.16
177.1622162	0.06
181.1453552	0.08
246.9930420	0.15
263.3618774	0.29
281.2459106	0.53
301.2460327	0.05
325.0816040	0.75
329.1710205	0.09
341.2294312	0.07
343.0702515	0.34
351.2451172	0.11
355.9577026	0.17
369.2611084	0.18
371.4332886	0.60
375.1942749	0.06
376.2267456	0.14
379.2912598	0.24
388.2463989	0.16
389.3079834	0.62
391.1419067	0.04
432.2739258	0.04
447.0509033	0.20
449.8547974	0.15
453.2664795	0.08
455.0588379	0.21
461.2059326	0.04
463.6931763	0.06
470.3972778	0.08
471.3385620	0.15
482.9616699	0.10
488.9901123	0.04
497.7617798	0.03
505.2495728	100.00
506.4254150	0.18
507.2257690	0.39
508.2911377	0.27
513.3880005	13.05
514.3839722	1.49
515.3939819	2.64
517.3834229	0.08
529.4934692	0.11
532.8361206	0.07
533.6239624	0.51
550.8890991	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	915.3859
Annotation	Unknow
Peak:m/z	Relative Intensity
263.1266174	3.86
319.4468384	0.17
321.2685242	0.05
323.1800232	0.13
347.4811401	0.10
353.2393188	0.40
363.3463745	0.54
385.1257935	100.00
385.7620850	0.38
387.2257690	0.04
401.9783325	0.10
411.9777222	0.19
431.3497314	0.11
527.2539673	0.25
529.2554321	0.48
531.4362183	0.04
533.3754883	0.11
551.3768311	0.30
564.3613892	0.18
625.2503052	0.03
687.5183716	0.12
753.6043701	0.09
754.7990723	0.05
895.8517456	0.03
897.5440063	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	203.0827
Annotation	Ethotoin
Peak:m/z	Relative Intensity
69.9489441	0.02
71.9863510	0.52
74.0139694	1.39
96.7649231	0.03
114.7780304	0.06
115.9570770	32.30
117.8080292	0.02
128.0275879	0.41
128.8933868	0.61
130.0101166	0.74
131.0944061	0.03
132.0854950	0.67
142.1063080	14.21
143.1448517	0.06
149.1654053	0.02
157.1525726	0.34
159.0389557	100.00
160.9452362	0.07
162.3783264	0.01
167.0388794	0.05
171.0366516	0.03
173.0505219	1.52
173.9582062	0.02
175.0710602	0.03
176.1018372	0.07
185.2075043	1.23
186.0744934	9.45
203.0009460	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	649.1964
Annotation	Esperamicin A1
Peak:m/z	Relative Intensity
216.8208466	0.25
240.8022308	0.08
258.9136963	0.09
261.1298828	0.25
264.0816650	0.12
271.3621521	0.19
276.8047791	0.22
288.7517395	1.35
289.3905945	0.20
298.8973999	1.07
307.1395874	13.71
308.4951172	0.23
318.4079895	0.05
323.0524292	1.05
324.8475342	6.15
337.2910767	0.21
340.0320435	0.09
342.2403564	2.33
342.8520508	5.38
343.4561157	0.23
354.0333862	0.14
355.2440796	0.43
360.0801392	0.35
360.7772827	3.75
366.8048706	0.07
381.2182007	0.41
391.1976929	0.27
404.1240845	0.08
407.1592407	0.30
413.0761108	0.18
427.2526855	0.31
428.1744995	0.12
441.0182495	0.07
443.1213379	1.04
466.3204346	0.30
468.7586060	0.15
469.3932495	0.07
478.0269165	32.11
478.7312622	1.51
480.0123901	0.28
480.9502563	0.89
481.5982056	0.28
484.2266846	0.58
485.0563354	0.05
486.3358154	0.51
487.1105347	0.81
494.2692871	0.40
502.7515259	1.32
503.9627686	1.09
504.6840820	1.84
514.2278442	0.74
519.0711670	0.30
521.3759766	0.69
522.2970581	1.39
523.0137939	0.07
528.3232422	0.06
531.3523560	0.24
535.7835083	0.44
540.2606201	0.08
543.2271118	0.61
557.1768188	0.21
558.8969116	0.79
571.2706909	0.17
573.3690796	0.14
595.5111084	0.15
601.2348633	0.05
605.0360107	0.09
613.1912231	100.00
614.1795044	0.70
616.9615479	0.14
631.1643677	1.05
684.4326782	0.85
685.1220093	0.36
822.5830078	0.16
954.8828125	1.93
1088.1101070	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	581.2814
Annotation	Unknow
Peak:m/z	Relative Intensity
178.3007202	0.04
179.9842377	0.11
193.0737305	1.06
195.1244049	0.28
211.0946045	0.05
225.0390015	0.28
237.2276764	0.03
257.0921021	0.06
273.2331848	0.09
289.1367188	0.14
292.9374390	0.04
297.2720032	0.06
313.0786743	0.08
327.0137329	0.05
329.1314087	0.20
338.9003296	0.07
341.3729858	0.18
342.2994385	0.02
346.4800415	0.11
355.4730835	0.16
369.1257324	0.05
371.1051636	0.89
373.8237305	0.19
392.6460571	0.10
397.4771729	0.15
401.3141479	0.93
407.0935059	0.12
411.1100464	0.08
417.0750122	0.64
418.4497681	1.98
419.2360840	8.40
427.2548218	0.05
429.1961060	0.08
432.9965820	0.06
439.2760010	0.03
445.2429810	0.04
451.3414307	0.19
455.0212402	0.14
457.3518677	0.05
461.1123047	0.05
464.0619507	0.08
465.1707764	0.04
467.8828125	0.13
481.2563477	0.10
483.4295044	0.08
491.2092285	0.21
493.1249390	0.07
497.3324585	0.06
501.6619873	0.04
503.2928467	0.10
513.7727661	0.15
517.1423340	0.09
518.5269775	0.18
519.3479004	0.50
521.4290161	0.11
533.8588257	1.18
535.2778931	100.00
535.9218140	0.12
537.4154663	0.27
543.3204956	0.05
544.2697144	0.09
545.3723755	1.17
553.2111206	0.06
558.9733276	0.03
561.5288696	0.11
563.3062134	0.84
564.2037964	0.03
571.3413696	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	555.2079
Annotation	3-[4-[1-(4-Hydroxy-3-methoxyphenyl)-1,3-dihydroxyisopropoxy]-2-hydroxyphenyl]propyl alpha-L-rhamnopyranoside
Peak:m/z	Relative Intensity
195.0339661	0.07
197.2097168	0.05
313.2868652	0.01
375.0344849	0.02
389.3144531	0.02
393.3505249	0.06
430.8632202	0.02
435.6852417	0.04
494.5729370	0.04
506.9746094	0.01
509.3074951	0.17
511.2721558	0.16
537.2550049	100.00
538.0985718	0.00
539.0458374	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	281.0879
Annotation	beta-L-Arabinofuranosyl-(1->2)-beta-L-arabinofuranose
Peak:m/z	Relative Intensity
80.8749542	0.12
82.9816208	2.31
84.8987884	8.71
86.8555908	4.11
94.9973526	9.16
97.0106049	1.08
98.9923859	2.08
100.9523773	1.63
103.0055466	12.65
106.9423981	2.70
108.9639130	0.44
110.9311600	1.74
112.9834366	100.00
115.0253677	0.88
123.0816269	0.12
125.0337601	0.45
127.0147095	2.81
128.9726868	6.20
129.9206848	0.14
130.9154510	7.08
138.9152374	3.94
142.8753815	2.06
144.0635834	0.20
145.0748596	0.55
146.7836914	0.22
151.1894989	0.37
156.9499664	4.19
159.1301575	0.31
160.4489594	0.68
161.2269745	0.87
162.9710693	2.71
168.9601440	0.83
170.9296570	0.14
187.0339050	5.82
189.1007843	4.63
202.8194275	0.47
204.9831238	79.97
206.9489136	0.30
231.1430054	5.58
233.2522583	0.39
235.0664978	0.29
237.2731934	7.01
249.1711426	98.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	352.1035
Annotation	Sambucus nigra Degraded cyanogenic glycosides (2'-Epimer)
Peak:m/z	Relative Intensity
100.9115677	9.86
112.9574890	3.25
115.9138412	0.53
118.9080048	8.08
124.8403397	0.21
128.0123138	0.34
129.7133484	0.69
142.0729065	1.83
142.9583130	2.82
144.0655212	6.32
146.0422668	55.57
155.9168091	1.21
159.0245056	5.88
161.0129089	24.01
163.9916840	8.10
165.8754578	0.92
170.0149231	8.32
172.1041870	3.68
174.0667419	17.52
186.0047913	4.18
188.0485077	73.07
190.2189941	0.46
193.1493073	0.17
198.2761536	2.04
200.1108551	10.71
202.2154388	1.83
203.8120880	0.34
206.0985107	49.63
210.1637421	6.43
212.1414490	2.45
216.0212402	1.40
218.0688477	100.00
228.1987610	1.78
230.1710815	10.58
232.0992126	4.43
234.0528259	1.55
234.8833923	0.26
242.1509094	3.33
246.1278687	0.19
248.0403442	3.75
250.2297058	0.28
254.1701965	37.04
260.1443787	3.83
264.1486206	4.08
272.1920166	7.44
278.1628113	1.05
290.1884155	16.09
306.2108765	0.74
308.1255493	80.56
320.0834961	0.38
333.9058838	0.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	377.1585
Annotation	(3S)-7-Hydroxy-8,2',3',4',5'-pentamethoxyisoflavan
Peak:m/z	Relative Intensity
155.0648499	0.02
162.8529663	0.04
167.1830139	0.01
221.1728821	0.04
223.1752625	0.02
225.2238770	0.01
231.8972168	0.02
238.4603882	0.02
241.3198853	0.02
243.1372070	0.01
254.3502502	0.08
255.0205078	0.02
257.1929321	0.04
267.2693787	0.04
269.2118530	0.14
271.0704956	0.03
282.7584839	0.08
285.0195923	0.36
287.2318420	1.30
294.2773743	0.02
295.0584717	0.09
297.2123108	0.01
303.2516479	0.29
306.8506775	0.01
313.1310120	0.60
315.0810242	0.14
315.7005615	0.04
316.3104858	0.01
322.1501465	0.03
327.1040955	0.03
329.7601318	0.02
331.0583496	10.24
331.6796265	0.09
340.9092712	0.60
341.5971680	0.01
345.1391296	0.02
355.4973450	0.04
358.9924011	100.00
359.6759338	0.22
368.2142029	0.08
376.9862976	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	315.1948
Annotation	Rabdokunmin D
Peak:m/z	Relative Intensity
91.0839996	0.09
92.9653778	0.17
94.9726486	0.25
105.0270386	0.08
107.0869293	0.12
109.0955505	0.28
111.1175385	0.13
119.1029968	0.16
120.9948959	0.03
129.0647888	0.04
131.0398560	0.15
132.9375000	0.22
135.0265198	0.23
137.0293579	0.36
142.1267700	0.04
143.0784302	0.17
145.2679138	0.09
146.9928131	0.27
149.1898193	0.04
150.9067078	0.19
153.2198029	0.02
154.7348785	0.05
157.0509338	0.61
158.9655609	0.59
161.0385742	0.93
163.0553131	0.25
168.0996399	0.05
169.0767822	0.06
171.1192932	0.35
173.1762543	0.12
175.1284790	0.60
181.0952606	0.05
182.9315186	0.06
187.2036438	0.15
189.1698303	0.10
190.5256042	0.03
191.2165680	0.14
193.1597900	0.24
195.0861511	0.51
197.2391205	0.25
199.1819611	0.12
201.2721252	0.05
203.2196350	0.35
205.0769043	0.02
207.0652466	0.26
209.1279297	1.68
211.1701660	1.11
213.0629578	0.95
215.3374023	0.10
217.2413635	0.71
219.0575867	0.26
221.0188293	0.64
223.1901245	2.04
225.1262207	0.10
227.1263428	0.94
229.0379944	0.05
231.0564575	0.13
233.2762146	0.76
235.0542603	0.09
237.1940002	0.06
239.2096863	0.47
241.1701965	3.98
243.3233948	0.22
245.1239014	0.19
249.0107117	0.03
251.2205811	10.96
253.1332397	5.80
255.0888062	0.59
257.2656860	1.48
259.1225586	2.51
261.1984558	0.56
262.5531616	0.06
267.3053284	0.03
269.1539612	67.36
270.1832886	0.07
271.1837158	0.85
273.0399170	0.33
273.7306519	0.09
276.2117615	0.19
279.2349854	1.18
285.1460571	1.97
285.7749634	0.06
287.1676331	12.73
288.5644531	0.04
293.8814087	0.29
294.4842224	0.73
297.1432495	100.00
298.1301270	0.17
300.3587036	0.02
303.8634338	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	477.1768
Annotation	TyrMe-HoPhe-OH
Peak:m/z	Relative Intensity
142.8585358	1.55
149.0711975	0.62
152.7737732	1.44
158.7675476	0.45
160.8834229	4.91
178.0770721	0.98
179.0297241	28.64
199.2454987	0.34
249.4972534	1.93
253.1313782	26.99
254.9880371	1.32
271.1671143	13.29
313.9779053	0.81
315.2527161	0.65
328.5087585	0.79
330.9802856	3.66
339.2249756	0.96
340.1988525	0.78
349.0636292	0.97
357.2723999	1.26
369.1504211	1.01
373.8435059	0.57
374.9253235	0.64
381.4172668	4.27
389.3240051	2.22
393.0920715	0.93
398.9876709	0.38
401.0357971	2.13
403.1079407	0.67
419.3534851	1.23
431.1202087	2.64
433.166687	100.00
434.290802	1.87
435.537262	1.72
439.1648865	1.52
440.4093933	0.86
441.5932617	2.14
442.3743286	0.67
443.3728638	3.03
458.0762329	1.29
459.2741089	6.31
460.4100952	0.41
467.9717712	6.63
468.8711853	2.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	397.1505
Annotation	Methyl (3x,10R)-dihydroxy-11-dodecene-6,8-diynoate 10-glucoside
Peak:m/z	Relative Intensity
114.7162399	0.08
116.9332886	0.71
134.9711761	0.15
143.0634003	0.83
159.1488953	0.21
162.4405518	0.06
169.3884888	0.17
171.2824402	0.04
173.1115875	0.79
185.1532288	0.44
187.2022552	0.68
191.0811462	0.75
195.0885468	0.13
203.2883301	0.26
205.1673584	0.08
211.3452759	0.11
215.1681519	0.09
217.1790161	5.83
219.1719818	0.32
223.2339783	0.03
227.2220764	0.12
229.0818787	0.89
230.3119202	0.15
231.2370911	0.08
233.2327271	0.44
235.1195984	42.99
235.8112793	0.37
236.4669495	0.37
237.2374268	0.16
241.3735657	0.24
245.1505127	1.25
247.2673645	3.04
249.4155884	0.25
253.4519958	0.33
255.0054321	0.10
257.0890198	0.49
259.1428223	0.12
260.9751587	1.84
263.1925964	0.75
265.2417908	0.85
267.0935059	0.34
270.1053467	0.10
273.1232300	0.71
274.2241516	0.33
275.4233398	0.05
279.1355591	3.27
279.8612061	0.08
281.0883789	0.24
287.2359314	0.45
289.3505249	1.47
290.2964478	0.69
291.1896057	20.10
292.3937073	0.10
297.3872681	0.22
299.3519287	0.20
300.9424438	0.17
305.2575684	0.59
307.3916626	0.35
309.2285156	34.42
310.1770630	0.58
316.3679810	0.18
317.1638489	1.56
319.1083374	0.26
323.1413574	1.61
324.1917725	0.13
329.3834839	0.25
335.1661987	76.23
336.0404053	1.31
349.3600464	0.20
351.2796326	3.64
353.2304993	100.00
354.3318176	3.32
361.1663513	0.64
367.1922607	0.14
369.1180115	0.24
371.1275940	0.18
379.2595825	51.57
380.2522278	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1723
Annotation	Unknow
Peak:m/z	Relative Intensity
171.1473389	0.03
173.2004700	0.52
191.0198059	100.00
418.3900146	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	616.9
Annotation	Unknow
Peak:m/z	Relative Intensity
198.8631897	0.06
201.0529480	0.12
217.0337524	0.10
230.7766724	0.02
273.0311890	6.46
274.0093994	1.53
275.0267334	3.51
386.9359741	8.80
387.9689331	3.36
389.0144043	14.99
402.9630127	0.06
436.4991455	0.03
500.8770142	22.47
502.0565796	23.08
502.9000854	100.00
510.9962769	0.04
515.1524048	0.04
519.0724487	0.14
526.7033081	0.09
532.0181885	0.18
542.9071045	0.02
545.2808838	0.05
570.8435669	0.24
571.8507690	0.10
572.8805542	0.18
573.8938599	0.06
585.1245117	0.16
590.4080811	0.06
598.8557129	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	875.4087
Annotation	Unknow
Peak:m/z	Relative Intensity
257.3392944	0.07
258.8674927	0.32
259.5600281	0.16
267.3981628	0.05
275.2369385	0.46
285.3654785	0.08
303.3090515	1.92
319.1997070	0.05
321.2242432	0.20
335.4865723	0.35
337.3066406	0.10
345.1375122	0.14
347.2038879	47.23
360.3703003	0.10
363.5214233	0.09
365.2952271	1.18
381.1690063	0.03
465.3997803	0.08
483.2897949	0.13
497.3796997	1.55
499.4382324	0.83
509.2274780	0.77
513.1527710	0.06
527.3187256	100.00
527.9388428	0.46
572.8666382	0.22
653.2243042	0.20
740.0571289	0.13
789.3519897	0.04
831.2743530	0.06
842.1130981	0.04
860.4626465	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	637.23
Annotation	Kanokoside C
Peak:m/z	Relative Intensity
267.0631714	0.09
273.2203674	0.05
277.3247070	0.06
289.3811951	0.12
307.3184814	0.08
325.1277771	0.10
367.1959839	1.42
377.2457275	0.03
397.1264648	0.61
399.2083130	0.14
416.1041260	0.03
426.3394165	0.09
426.9906616	3.26
429.1055298	0.10
435.1198730	0.03
463.1713867	0.03
467.3038940	0.04
469.0661011	0.05
474.3981934	0.14
475.4281616	0.22
484.5950317	0.04
486.9450684	1.17
498.8050537	0.05
509.1876831	0.10
517.6544800	0.09
531.0104370	0.06
539.5734253	0.03
540.2187500	0.05
544.2117920	0.15
548.3629150	0.03
552.8973999	0.10
557.3614502	0.07
575.1506958	0.04
577.3786011	0.10
591.2882690	100.00
592.4335327	0.07
601.6235352	0.09
617.0824585	0.07
619.1715088	0.07
620.1636353	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	616.28
Annotation	Unknow
Peak:m/z	Relative Intensity
207.0873413	0.10
223.6674500	0.10
251.2073975	0.06
252.0974121	0.07
258.8623047	0.18
265.0352478	0.09
279.1795349	0.06
283.2232666	0.11
290.1883850	0.08
292.1996765	0.06
297.3285522	0.07
315.2143555	0.26
319.6943970	0.45
329.3513794	0.73
331.4195557	0.15
338.4024048	0.18
347.1033325	3.24
347.7584839	0.02
367.3836670	0.14
372.2771606	0.21
390.2296143	0.44
408.1611328	0.07
409.2100830	0.08
410.4942627	0.07
418.3320923	4.92
419.1699219	0.45
436.3356323	100.00
448.1723022	0.05
450.3607178	0.04
453.0925293	0.37
454.1850586	16.68
454.8832397	0.45
460.4735718	0.08
472.2781982	0.44
478.4774780	0.68
486.4465942	0.10
490.3123779	0.21
495.3139648	0.20
502.2439575	1.01
508.7244873	0.17
510.1761475	0.06
514.5300293	0.70
518.7094116	0.05
520.4862061	0.34
526.4112549	0.35
527.4088745	0.08
530.1589355	0.30
532.3232422	0.44
542.4054565	0.20
544.3776245	0.63
552.3069458	0.34
552.9083862	0.05
556.1842041	0.14
557.7549438	0.37
562.2614136	0.99
568.2855835	0.05
570.2313843	2.38
575.2445068	0.14
580.1924438	3.89
598.2145996	42.24
598.8502197	0.55
607.0305786	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.1
Annotation	Deacetylasperuloside
Peak:m/z	Relative Intensity
110.9224777	0.03
113.0279083	1.09
114.9476395	0.09
120.9855499	2.36
125.0643311	0.05
129.1468048	0.11
139.0690308	0.07
145.0351868	0.07
157.0699310	0.19
174.9104919	0.43
176.6764526	0.10
184.9877930	0.03
187.0546265	0.11
189.0632782	0.30
192.9852905	0.04
231.1168213	4.34
249.1058655	100.00
309.5604553	0.05
311.0337524	0.26
335.3249512	0.18
353.1468811	2.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
96.00402069	0.11
100.7447968	0.52
109.0366669	0.20
111.1009064	0.11
123.1210327	0.35
132.9439545	0.22
148.9979095	0.43
161.1395874	0.13
165.1034088	0.42
167.3512268	0.40
168.6910858	0.14
174.0978394	0.21
179.2040558	0.85
181.0797577	0.10
183.2223663	0.23
195.2310028	0.50
206.1689301	0.33
207.204483	4.37
207.9992981	2.10
209.2643738	1.58
222.7641449	4.36
224.2597504	0.79
233.0034332	0.68
235.2564545	0.44
235.9364624	0.73
251.075058	100.00
252.208786	17.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	751.2961
Annotation	(3S)-7-Hydroxy-8,2',3',4',5'-pentamethoxyisoflavan
Peak:m/z	Relative Intensity
211.3659058	0.08
229.0382538	0.03
239.1800537	0.46
240.1315765	0.05
255.2005157	0.76
257.1221619	2.73
269.3715210	0.13
283.1824036	0.10
285.2847290	0.07
287.2319336	10.86
289.0151978	0.07
290.1980591	0.05
301.0537109	0.11
312.9407654	0.14
317.2081909	0.05
321.0171509	0.06
331.2827148	4.22
357.3124390	0.38
359.2464600	0.18
375.1933594	100.00
376.0520020	0.32
385.0900879	0.14
386.2774658	0.33
386.9804688	0.18
393.3651123	0.09
423.3424072	0.06
455.2986450	0.11
461.4022827	0.08
483.4258423	0.09
504.0780640	0.19
507.3233032	0.10
511.3478394	0.45
521.3038330	0.07
523.1757812	0.04
525.5007324	0.18
539.3335571	0.22
571.4435425	0.10
586.2135620	0.53
586.8473511	0.06
587.6694946	0.83
594.9690552	0.04
607.2000732	0.12
613.1049805	0.26
630.4360962	0.17
634.4054565	0.09
635.7345581	0.03
654.2873535	0.10
661.7479858	0.24
665.2247925	0.07
679.0475464	0.11
684.7768555	0.05
687.2253418	0.06
688.4057007	0.05
703.3328247	0.03
704.4606323	0.13
705.3050537	0.59
706.2769165	0.03
707.5004272	0.27
708.6242676	0.09
715.1131592	0.14
731.3724365	0.05
732.6093750	0.68
733.4780273	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	556.2375
Annotation	Pyrronamycin B
Peak:m/z	Relative Intensity
166.0901794	2.49
175.1688080	0.13
211.1000824	0.05
223.0069885	0.22
225.2723694	0.17
228.9147949	0.35
255.2686615	0.12
258.8954468	0.17
260.3209839	0.22
268.0005493	0.14
269.1640625	0.68
280.1343384	0.06
282.3150024	0.28
283.0432129	0.05
285.0660400	0.29
287.2384033	1.56
295.1394653	0.31
308.2461548	0.11
313.0856934	2.46
314.9276733	0.12
316.4227295	0.07
331.0817261	3.59
340.6694336	0.10
345.3633423	0.13
349.1040039	0.08
359.1098022	32.58
377.0219727	100.00
377.6746826	0.22
380.0290527	0.68
385.3431396	0.59
392.8693237	0.33
394.1182861	0.13
408.4650269	0.23
409.1040039	0.31
412.9151001	0.22
415.3128052	0.15
426.2686768	0.04
435.1087036	0.17
457.0544434	0.82
458.1819458	0.49
464.2773438	0.50
466.0275879	0.79
466.6813965	0.05
469.1763306	0.10
474.5250854	0.86
475.4528198	0.77
482.3977661	0.64
484.4812622	0.42
492.3038940	0.04
495.9712524	0.20
497.2271729	0.30
505.5007935	0.42
510.2157593	0.06
512.1497192	0.18
513.1731567	0.15
519.6874390	0.40
520.3348999	0.49
537.5875854	0.17
538.2417603	0.36
547.0056763	0.44
567.0708008	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	379.1741
Annotation	Triptriolide
Peak:m/z	Relative Intensity
112.9160538	0.09
118.1772003	0.14
121.1029129	0.12
125.8330841	0.10
130.9994507	0.84
132.9148560	0.30
135.2490997	0.08
137.2691803	0.14
140.7609253	0.10
153.0336304	0.41
161.1360474	0.16
161.8553162	0.16
175.2248230	0.12
181.1838531	0.12
183.9564209	0.09
187.1793823	0.33
197.0821075	0.47
206.4598694	0.35
210.9545746	0.31
213.2834473	0.31
214.0839233	0.22
217.1629333	0.24
220.8342896	0.38
230.2281189	0.10
233.0018616	0.39
234.4171448	0.77
235.9906616	0.30
239.2721558	0.90
241.2681885	0.27
242.2747803	0.67
249.1318665	0.07
253.3230286	0.42
267.3292542	0.17
271.2538147	0.73
272.1918945	0.08
277.2447510	1.03
279.2603760	0.45
285.5458374	0.34
286.9758301	1.21
290.2634583	0.42
291.2330933	1.10
292.0906982	0.33
293.1152954	0.31
301.0814819	0.18
302.1694946	0.30
303.4190674	0.55
305.1757202	1.09
307.3499146	0.39
307.9695435	0.27
311.1097107	0.07
312.3236694	0.08
314.9993286	5.37
317.3981323	0.60
319.2608643	0.49
321.3335571	0.34
323.2476196	0.25
325.2724304	0.69
329.2661743	0.37
329.9577637	0.33
332.3273315	3.71
333.0669556	100.00
335.2971802	0.45
337.9954834	0.69
343.0101318	10.74
347.2253418	0.32
347.9282227	0.27
351.4489441	0.38
356.3027344	0.24
360.4590759	13.77
361.1475525	30.51
362.2800293	1.02
363.7554016	0.18
370.1439514	1.60
373.1203613	0.77
379.0954285	2.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	361.1656
Annotation	(+)-Jurinelloide
Peak:m/z	Relative Intensity
118.8050537	0.01
120.8538208	0.03
125.0365982	0.05
133.1425323	0.03
135.2187653	0.02
147.0206299	0.12
149.4618530	0.02
157.0528259	0.14
159.1663513	0.10
175.4229431	0.03
176.7944336	0.07
185.1302795	0.12
186.9882507	0.04
189.1285095	0.12
191.1026154	0.10
199.2140808	0.11
203.2373352	0.17
208.2674255	0.03
211.3565063	0.08
213.3330078	0.24
214.3157959	0.04
215.2421265	0.02
221.2333984	0.87
223.1920166	23.45
224.2629700	0.40
225.0090332	0.47
226.1972046	0.07
227.3615723	0.05
229.2919006	1.77
232.6050415	0.08
237.4376831	0.51
240.9064331	4.07
241.6095886	0.14
242.2342224	0.04
243.1682434	0.28
247.4944763	0.05
249.1546021	0.19
251.2124634	2.73
253.1619263	0.84
254.5665894	0.25
255.2641296	1.37
259.4743042	0.04
261.3090820	0.10
265.1643066	0.15
267.1943359	0.06
269.1735229	8.42
270.3993530	0.33
271.2387695	1.79
273.0994873	1.31
274.8152161	0.02
281.2666321	2.78
282.2014465	0.09
287.2049866	0.57
291.1712036	0.02
293.6832886	0.04
297.3045044	0.19
299.2274475	12.39
300.4003601	0.13
301.1777954	0.24
303.0509033	0.29
315.3140259	5.00
317.2339783	100.00
318.2579651	2.26
325.2333984	0.43
331.2518921	0.09
343.2670288	40.89
344.3173523	0.69
345.1011658	0.02
346.4610901	0.06
361.3154602	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	536.2322
Annotation	Jioglutoside B
Peak:m/z	Relative Intensity
165.0590210	14.92
174.9381561	0.30
181.9993134	100.00
187.0962524	0.19
199.0081329	0.23
200.1837463	0.24
214.1819916	0.08
228.1235962	0.28
229.0484619	0.49
235.1950989	0.17
237.2710266	0.41
253.0952454	0.14
258.2776184	0.16
266.2053833	0.08
273.8621216	0.13
275.1560059	0.66
284.5064697	0.54
286.1966553	0.53
287.0546875	0.34
294.9971924	0.06
296.3552856	0.26
299.1005859	0.18
304.4517822	0.12
305.4406738	0.07
316.1434937	0.40
318.9577026	0.28
325.2419434	0.36
328.1511841	1.89
329.2339478	0.17
333.1483154	0.54
345.0081787	0.28
346.4342041	0.22
350.2593994	0.11
354.8620605	0.15
356.2572632	0.18
361.2311401	0.11
366.6208496	0.22
371.4155273	0.08
374.1204224	0.40
375.3055420	0.28
377.1462402	0.27
381.5786133	0.07
385.1255493	0.08
386.9782715	0.24
389.1234741	0.22
390.1414185	0.24
396.9125977	0.26
399.4096680	0.41
404.0750122	0.08
407.2053223	0.60
409.8303223	0.22
413.0624390	0.29
414.4130249	0.18
415.9661865	0.15
417.2382812	0.24
418.0072021	0.20
418.6409912	0.19
430.5864258	0.23
431.4075317	0.29
435.3619385	0.59
436.0507812	0.27
438.4234619	0.31
439.2283936	0.49
446.3743286	0.46
455.6803589	0.33
461.3765869	0.11
473.3909912	0.08
474.4040527	0.11
482.1992798	0.59
490.7413940	0.85
491.5588379	0.13
492.2467651	0.10
493.3294678	0.14
501.0206909	0.78
504.9108276	0.32
513.2291260	0.14
518.1939087	2.46
519.1063843	0.65
527.6630249	0.68
536.0723877	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0852
Annotation	4'-METHOXYFLAVONE
Peak:m/z	Relative Intensity
78.92848206	0.48
80.80751038	4.21
84.86942291	0.24
88.98365784	0.57
94.9982605	3.86
96.93926239	1.47
101.0330048	0.75
105.0328064	0.78
109.0175171	3.02
110.9406891	2.04
113.006012	2.34
114.74263	0.57
118.8739929	1.94
121.0709381	1.97
123.1932526	0.88
125.2290955	2.23
126.9111633	0.78
128.9010773	2.50
129.810379	0.25
133.0011749	0.86
134.9964752	2.01
137.2076263	0.62
139.0428925	0.86
141.0536041	0.54
144.9375305	0.97
147.0603485	1.31
147.9147034	0.32
148.9589233	1.32
150.9608612	52.81
152.0483246	1.35
152.827713	1.11
154.9206085	3.28
157.3542786	0.45
160.9875946	2.09
162.9580383	1.79
165.1631927	0.64
166.1656342	0.50
167.0408478	1.65
169.0442047	3.15
170.5231171	0.32
174.9858704	2.93
177.0725861	0.90
179.066864	1.35
180.9459381	0.59
182.9562225	0.56
184.9308472	0.61
186.1556549	0.21
189.1893005	1.76
190.1592255	0.62
193.0528412	0.66
195.0017853	1.44
196.8302917	3.30
197.5330963	0.56
198.9663391	1.64
202.984024	0.32
203.6675568	0.26
207.0484314	2.45
209.232193	0.96
211.0570831	9.98
217.2221375	15.20
224.1329803	2.49
225.1790009	10.99
226.718399	0.77
233.0379639	1.21
235.1410065	51.51
238.0615845	11.73
239.1543121	0.24
251.0423584	0.29
253.0834503	100.00
254.0996094	17.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	565.2377
Annotation	Unknow
Peak:m/z	Relative Intensity
159.1436768	0.35
160.1909180	0.59
169.8610382	0.83
173.9121246	0.20
188.0808411	45.22
201.0604248	0.42
204.9942932	100.00
205.6059418	0.52
218.0851746	0.24
227.0463257	0.06
230.2235260	0.31
235.0720062	0.57
242.7234497	0.41
258.0470581	0.14
271.3206177	0.16
285.0982666	0.27
288.1070557	0.13
298.0582886	0.18
314.0545959	0.06
315.9313965	0.44
316.9421997	0.34
324.9503174	0.37
334.1777344	0.18
336.2321777	0.13
340.3093872	0.20
342.5203857	0.31
348.9924927	0.18
357.1499634	0.21
360.8197632	1.09
361.5051270	0.27
362.1094971	0.24
364.4149170	0.15
367.1428223	1.09
373.2257080	0.19
374.8500366	0.24
385.2597656	0.33
386.1407471	0.43
387.1952515	0.30
398.3167725	0.24
402.3751831	0.14
403.0941162	0.49
404.2606812	0.12
414.0890503	0.07
431.3702393	0.18
451.9445801	0.59
474.6022339	0.62
475.5875244	0.15
479.8676758	0.31
481.4260254	0.10
490.2365723	0.44
493.3342896	0.51
497.6050415	0.74
509.3624268	0.23
520.9155273	0.10
525.6586914	0.22
535.4887695	0.17
547.0881958	2.05
548.1227417	1.49
564.9840698	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.28
Annotation	Unknow
Peak:m/z	Relative Intensity
170.0240173	0.37
171.4375916	0.48
173.3921051	0.18
187.9911499	46.50
189.0715485	3.74
190.1349030	1.98
191.1466675	1.69
195.2764587	0.06
204.9802856	100.00
206.0383453	3.93
207.1133575	3.78
208.2535095	0.12
209.1994019	5.97
210.8426514	0.10
217.2505035	0.21
219.0279236	0.12
225.0742950	0.36
227.0075378	45.19
228.9648132	0.06
234.9902191	0.16
243.0159302	0.29
245.0024109	2.63
260.2139282	0.91
271.1171570	0.59
272.9841003	0.28
287.1723633	0.14
289.0625610	1.48
291.2185669	0.08
297.1716919	0.35
318.1224365	1.13
343.1663208	0.10
346.7855225	0.28
347.7525635	0.11
353.3934326	0.31
362.6753540	0.14
365.3784180	0.16
367.6204224	0.09
371.5261230	0.25
373.1277466	0.11
386.4323120	0.17
388.9085693	15.34
389.5343018	0.32
391.2598877	0.24
395.1650391	0.20
397.4036865	0.18
404.2365112	0.12
407.0225830	7.80
408.3561401	0.87
409.2823486	0.06
421.1597900	0.30
428.2043457	0.43
431.4099731	0.12
432.5729980	0.34
436.8831177	0.10
441.5494385	0.06
446.0155029	0.08
449.1437378	0.25
450.1931152	0.23
459.2744751	0.06
466.9988403	0.47
469.2949829	0.09
471.2431641	0.14
482.1589966	0.94
491.0505371	1.33
501.0247192	0.06
505.1826782	0.14
508.3314209	0.45
521.0033569	0.09
522.9131470	0.50
537.0491333	0.39
548.1587524	0.21
550.4392700	0.54
565.2123413	0.30
567.1084595	1.20
569.3862915	0.29
575.2449341	0.18
576.4699097	0.56
578.1143799	1.38
584.2774048	0.47
593.0982056	44.31
594.4197388	1.34
602.7483521	0.30
624.2557983	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	612.64
Annotation	Unknow
Peak:m/z	Relative Intensity
174.0323181	0.03
181.0730743	0.06
186.0670013	0.08
188.0411682	1.77
189.0285950	1.39
190.0570984	0.20
191.0085907	0.13
191.9735718	0.05
194.1804047	0.07
197.0742645	0.53
199.2891388	0.08
201.1374207	0.10
205.0695496	4.81
206.1612549	3.07
207.0279236	0.57
208.0754089	0.13
208.9776917	0.11
210.2161407	0.08
214.0481262	0.11
216.1568909	0.16
218.2500305	0.03
219.0038147	0.06
221.7274780	0.05
227.0542908	3.18
228.1245880	1.36
237.1636963	0.12
238.0150452	0.09
239.2944336	0.16
242.7369537	0.05
245.1645355	0.83
246.0868530	1.06
249.4452209	0.05
255.0475464	0.82
256.1980286	0.13
257.2005615	0.06
262.2032776	0.03
263.0837097	0.06
269.2320251	0.30
270.0895691	0.08
271.2128601	0.36
273.0834656	0.62
274.1646729	0.16
277.3860474	0.06
283.1914062	0.36
284.1936646	0.32
285.2609253	0.03
291.8848877	0.05
298.1660767	0.17
299.3137817	0.08
301.2857666	0.12
307.1943970	0.11
309.2429810	0.03
310.3408813	0.04
314.2775269	0.04
316.3771973	0.04
318.2581787	0.04
321.6030273	0.05
324.2841797	0.11
328.2785645	0.18
334.2053223	0.10
336.5949097	0.08
340.1168213	0.10
342.3214111	0.14
343.2057495	0.15
344.3403931	0.07
347.9130859	0.16
350.1723633	0.17
354.0256958	0.13
355.3154907	0.10
358.3936157	0.13
360.1040039	0.29
368.2620850	0.40
370.0235596	0.61
370.7412109	0.30
371.5452881	0.05
372.3007202	0.06
377.9204712	0.04
386.3079224	2.09
387.5955811	0.11
388.4224854	1.32
389.7010498	1.51
390.4740601	0.04
392.2584229	0.09
395.2979126	0.07
395.9653931	0.06
399.3604736	0.15
402.6592407	0.08
404.4242554	0.24
405.4204102	0.11
406.4525757	0.41
407.1948242	0.24
408.0610352	1.99
409.0926514	0.04
410.3314819	0.20
414.3036499	3.69
415.2474365	0.50
416.3746948	0.68
417.3422852	0.21
425.1286621	0.05
428.3808594	0.09
429.1976929	0.02
432.3474731	23.23
433.4057617	3.20
436.3741455	0.19
440.4028931	0.05
442.0894775	0.03
450.3024292	100.00
451.3829346	9.73
459.9968872	0.09
469.6588135	0.18
472.1770630	0.12
479.8491821	0.05
482.8640137	0.22
491.7749634	0.02
492.5101929	0.02
493.5459595	0.05
498.4970093	0.13
512.9940796	0.04
516.2089844	0.07
523.3297729	0.11
532.3759766	0.08
536.2843628	0.10
538.2098999	0.03
539.4918213	0.24
550.2760620	0.39
551.7814331	0.07
557.5873413	0.13
559.2676392	0.18
566.4735718	1.82
567.3506470	0.24
568.4662476	0.20
569.4295044	0.21
571.0935059	0.09
574.1346436	0.28
576.6345825	0.23
577.5534668	0.02
578.9096680	0.12
584.5663452	0.10
591.5461426	0.28
594.2533569	10.54
595.4257202	2.68
597.0048218	0.03
603.2579956	0.11
613.4025879	0.03
622.0515747	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	415.1245
Annotation	O-Acetylgeniposidic acid
Peak:m/z	Relative Intensity
150.9820099	0.04
156.9584045	0.07
164.9692688	0.42
175.0258484	0.18
187.2761078	0.01
205.2699127	0.13
223.2008057	0.08
231.0907898	0.44
235.3951111	0.12
243.3733826	0.13
249.1034851	16.13
267.0691528	100.00
269.2111511	0.05
354.2569580	0.04
355.1272583	0.04
369.1511536	0.06
377.2694702	0.03
383.3049927	0.01
397.1980896	0.36
400.4953308	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	352.1036
Annotation	Sambucus nigra Degraded cyanogenic glycosides (2'-Epimer)
Peak:m/z	Relative Intensity
101.0278168	11.11
112.8645859	2.73
114.9492493	0.94
119.0160675	13.33
124.9449005	1.94
129.9539185	2.27
141.9320068	1.08
143.3626099	3.22
144.1962891	6.34
146.0732727	49.55
156.1650085	2.40
158.1263580	5.05
158.9855957	1.96
160.9161987	28.39
161.5188293	0.31
164.1194763	7.83
166.2073669	2.09
168.0822449	0.24
170.0086212	10.29
172.1499329	2.49
172.9725494	1.04
174.1841431	21.73
179.9456482	0.66
183.0759735	0.46
184.0544434	1.51
185.1808167	0.46
186.2560730	2.79
188.0069122	98.85
188.6202698	0.60
189.9770050	2.43
198.1802063	1.79
200.1078033	11.94
202.1148071	0.57
203.9144135	0.46
206.1276855	49.03
210.1379395	4.35
216.0142212	2.18
218.1046753	98.50
220.4902649	1.25
224.3088989	0.48
228.0098267	7.92
230.1705933	15.44
230.9902649	1.36
232.0637817	7.37
234.1310120	0.82
236.2691650	0.39
242.1225281	4.48
248.2095642	4.27
254.1390686	41.92
260.1787109	4.28
264.2718811	4.32
272.1760864	3.61
274.3191528	0.53
278.4551697	0.88
290.0885620	15.87
298.1793823	0.41
306.1937561	1.40
308.1660156	100.00
334.0683289	2.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	573.2551
Annotation	Canavalioside
Peak:m/z	Relative Intensity
161.0015869	0.03
179.0529938	0.17
241.2802734	0.02
365.2586670	1.67
425.1915894	0.46
465.5521851	0.05
527.2931519	100.00
527.9220581	0.11
537.3674316	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	610.29
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0216064	0.09
210.8914185	0.05
220.1612091	0.13
244.1712341	0.06
245.1289062	0.02
246.1390228	0.02
247.0400238	0.04
255.1206055	0.06
285.2203064	0.03
286.1702271	0.17
289.1831665	0.08
301.3411865	0.12
320.2609253	0.06
332.4703369	0.04
341.9802246	0.09
343.1026611	0.04
344.1897583	0.09
346.2985229	0.04
357.8931885	0.03
360.1625366	0.42
375.6572876	0.07
376.3363647	0.31
384.9826660	0.06
386.4104614	0.88
388.2860107	0.05
401.2380981	0.04
404.3242798	3.39
405.6408691	0.03
430.5405273	0.03
436.1549072	0.05
442.1518555	0.03
448.1328735	0.14
464.4541626	0.03
478.4620972	0.68
479.4112549	0.04
497.0108643	0.05
504.9376221	0.04
522.3844604	3.20
526.6930542	0.03
547.1644287	0.32
548.7131958	0.04
564.1839600	0.12
566.3541870	100.00
574.4277954	0.06
588.4517212	0.03
592.4613647	0.34
593.4197388	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.1342
Annotation	Dihydrokanakugiol
Peak:m/z	Relative Intensity
101.0310593	0.01
108.6908417	0.02
139.0295105	0.01
151.0262451	0.04
160.9145966	0.03
164.1807861	0.01
169.1556549	0.01
173.5074310	0.03
178.7725983	0.01
185.0722961	0.11
186.0738373	0.03
186.8828735	0.06
187.6999969	0.04
197.3472595	0.19
199.2960663	0.08
204.3476410	0.01
209.3077850	0.01
211.0625916	0.06
213.0025330	0.03
214.7032471	0.05
221.2040100	0.22
227.2084045	0.68
229.2585754	0.99
230.1109619	0.01
237.1021729	0.22
239.1917419	10.36
240.2577820	0.13
241.1972046	0.19
249.1813660	0.05
255.1716309	0.57
255.9774170	0.03
257.1699219	8.43
258.3928528	0.04
259.1341553	0.05
260.9493408	0.05
265.2395630	0.49
267.4583740	0.03
273.0516968	0.04
277.3095093	0.02
283.1611633	7.37
284.3631897	0.08
299.2119141	0.22
301.1726074	100.00
302.2580261	1.00
309.2253113	0.06
327.2221069	2.51
328.0528259	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.08
Annotation	Didymocalyxin C
Peak:m/z	Relative Intensity
161.1985474	0.04
179.0822144	0.92
180.1312256	0.04
181.0704956	0.08
197.1159363	0.03
199.0458374	0.38
215.2569275	0.20
217.0366058	8.96
341.2285767	100.00
342.5838013	0.62
343.2525024	8.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.1769
Annotation	7-Deoxygardoside metyl ester tetraacetate
Peak:m/z	Relative Intensity
155.1534729	0.02
157.2314453	0.03
159.0956726	0.11
172.9279785	0.05
178.9668732	0.01
196.9888306	0.10
201.1222992	0.42
203.1040344	0.01
221.1405029	0.02
227.2333221	3.14
245.1555481	1.46
253.2347870	0.33
266.9438477	0.02
271.2166138	1.11
287.1875000	0.09
289.3267212	0.08
290.8346558	0.01
297.3129272	0.46
299.3951416	0.02
311.0532227	0.07
313.2726440	0.02
315.2884521	3.41
316.0828857	0.06
317.3008423	0.01
326.1599731	0.03
331.2327881	0.22
333.1949463	0.58
341.2073975	0.03
343.0546875	0.02
347.3463135	0.04
357.2578735	0.04
359.2151489	8.53
360.3503418	0.05
373.2739258	0.03
377.1616211	100.00
378.2115479	0.08
385.2821655	0.01
391.0571899	0.06
401.1499634	0.04
419.1831665	1.08
423.4545288	0.01
433.0925903	0.03
437.5339355	0.01
443.1792603	0.04
449.2682495	0.42
449.9011230	0.02
451.1978760	0.02
453.3806152	0.02
459.4738770	0.04
461.0112305	0.07
463.1795654	0.02
475.3536987	0.03
477.2326660	0.02
478.0234985	0.02
479.3029785	1.07
493.3735352	0.40
494.1156616	0.04
494.9528809	0.09
495.6005249	0.05
497.3541870	0.03
503.1607056	0.07
509.1223145	0.01
519.2670288	0.08
521.2177124	1.14
524.3923340	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.0826
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
103.0540924	0.73
113.0176392	0.13
116.7936707	0.05
119.0245209	0.45
120.9150848	0.36
123.0011826	0.08
137.0326538	5.22
142.9651031	0.18
150.3014526	0.25
161.0517883	0.15
163.8170471	0.10
165.0091858	2.66
167.9408417	0.14
178.9250793	0.29
181.1274567	0.04
182.0740051	0.18
182.9194031	1.39
195.2828674	0.08
209.1458435	0.11
213.1331177	0.08
214.0353088	0.04
214.8650208	0.19
221.2467651	0.13
227.1088562	0.60
249.0461731	0.07
255.0697021	0.08
257.1157532	0.39
261.1630859	0.09
267.0725098	0.11
281.2077942	0.31
297.1434326	0.23
299.1139832	100.00
300.1553040	0.41
301.1199646	0.97
302.1283569	0.15
315.0076294	0.06
317.2354431	0.35
327.1261292	0.22
328.4125366	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	318.3
Annotation	Phytosphingosine
Peak:m/z	Relative Intensity
92.8323746	0.24
94.8956909	0.33
98.9805450	0.52
102.9083939	0.07
106.9584885	0.45
109.3378220	0.08
110.9975891	0.35
112.9499817	0.57
118.6031036	0.08
119.2599030	0.42
121.0765762	0.83
125.0283737	0.05
127.1431808	0.24
132.0582733	0.31
135.0033569	0.55
137.0555267	0.58
139.1334076	0.28
141.0632324	0.21
146.9864197	0.40
149.1353149	0.51
151.0336304	0.21
153.7979431	0.13
155.0657959	0.22
155.9905396	0.42
157.3970795	0.40
161.0712433	0.32
162.1033020	0.12
163.0555267	0.41
164.0780029	0.07
165.1864166	0.08
169.0913239	0.67
170.0098877	0.05
170.8529205	0.45
175.3025513	0.10
179.0507507	0.05
181.2031403	0.31
183.0772705	1.00
184.9324646	0.12
189.1196899	0.22
190.1787415	0.11
191.2589111	0.11
193.0187531	0.54
196.6551666	0.22
197.4810486	0.09
199.0177460	0.27
200.7868805	0.24
203.0026703	0.06
205.2348328	0.30
207.2973022	0.30
210.2057495	0.18
211.4228210	0.33
212.6645813	0.10
213.9479980	0.04
217.1636658	0.04
219.0997009	0.60
221.3051758	0.12
222.1913147	0.31
225.0184326	0.47
227.0555725	0.14
229.0199585	0.75
232.0287476	0.42
232.8778381	0.19
234.9520264	0.32
237.4964600	0.09
239.2051392	0.43
241.2272034	0.30
246.0532837	0.58
247.2669373	2.42
248.1090698	0.05
249.1950989	0.06
250.2198792	0.06
251.3378601	0.14
252.4024963	0.95
253.3547363	0.39
254.4292603	0.20
257.9308472	0.15
259.6522827	0.14
261.2419434	0.14
262.3031006	0.06
265.2575073	4.79
266.1335754	0.57
267.1481934	0.11
268.4072876	0.23
269.2406616	1.48
270.2941284	1.41
273.0703430	0.38
273.9714355	0.51
276.9738464	0.89
282.2670898	42.05
283.1043396	1.75
287.4054871	0.16
288.6138916	1.53
291.1010437	0.34
294.9424438	0.15
296.1848755	0.08
297.5098267	0.41
300.2448120	100.00
300.9148560	3.64
301.5289917	0.08
303.1430054	0.36
325.1893005	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.1605
Annotation	Triptriolide
Peak:m/z	Relative Intensity
120.1799622	0.02
159.3679199	0.01
182.7857056	0.01
197.5607147	0.01
199.2023621	0.01
201.1072235	0.02
227.3509827	0.03
235.3116760	0.01
237.4903259	0.01
241.1929016	0.01
243.1541748	0.02
245.1678162	0.03
247.3908691	0.03
253.1792908	0.02
259.4316406	0.01
261.4757690	0.01
265.1069946	0.01
271.1334839	0.16
287.1566772	0.02
289.2785645	0.36
297.5782166	0.02
298.4684143	0.01
307.5523987	0.01
315.2597351	0.16
317.2444458	0.22
319.1995239	0.02
331.3430176	0.23
333.2110291	0.50
334.2630615	0.02
335.2952271	0.01
337.3181763	0.03
339.3685608	0.02
341.1506348	0.10
349.1190796	0.03
357.5236816	0.01
359.2033691	100.00
360.0998840	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	558.1583
Annotation	Unknow
Peak:m/z	Relative Intensity
159.9093628	0.16
167.8458099	0.24
181.8274384	1.30
185.7747650	0.41
186.8859558	0.15
196.0330811	0.43
199.1734772	0.05
200.0230560	0.33
203.9255066	2.41
204.7853699	0.15
213.7382965	0.21
216.0193329	1.16
217.0805359	0.41
221.9510040	0.16
225.8266144	1.72
229.9580383	0.50
232.0166931	0.20
233.7878876	0.61
243.8762512	0.60
245.0014038	0.05
246.0359344	3.54
246.9088135	0.19
252.1187897	0.30
257.9250793	0.36
261.9194946	9.99
263.9761658	0.08
273.7993164	0.09
276.1423340	3.86
276.8630371	0.31
287.9366455	1.47
289.8374634	0.22
300.1852417	0.09
304.0405579	0.88
306.0299683	53.19
307.5472412	0.84
308.1478271	1.79
311.9436035	0.52
317.8332520	0.25
323.8804321	0.92
327.3916626	0.05
330.0089111	0.14
335.9633789	0.81
337.9179077	0.21
341.1888428	0.13
342.0260620	1.15
348.1892090	3.54
349.7404785	0.22
351.9243774	14.26
352.5922241	0.11
359.9994507	1.17
366.0856934	9.01
367.0413818	0.23
371.9613647	0.18
378.0273438	49.60
379.2778320	0.12
389.1152344	0.20
389.8872681	0.94
391.9853516	0.31
393.8971558	0.24
395.9381714	49.25
396.6756592	0.05
397.3465576	0.08
402.0095215	0.68
407.3612061	0.16
419.7144775	0.13
424.0332031	1.96
432.0060425	0.55
436.0817871	0.50
437.6279297	0.77
438.2440796	1.96
439.1026001	0.31
450.0744629	3.28
456.1882324	0.07
461.9227905	1.73
468.0148315	100.00
468.9477539	0.29
470.0399170	0.23
485.5728760	0.06
492.1174927	0.39
496.3677368	0.16
502.4172363	0.62
514.0803223	0.43
517.7364502	1.21
540.4468384	1.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.9582
Annotation	Unknow
Peak:m/z	Relative Intensity
130.0809784	0.24
156.0776672	0.85
170.0601807	1.55
183.3320007	0.06
183.9530640	0.18
188.1963196	0.35
199.9460754	19.60
201.0815430	0.30
205.3309784	0.17
208.8311157	0.08
213.9281769	3.85
218.1329346	0.29
227.1685638	0.05
227.9600830	0.35
235.6531525	0.08
239.1243286	0.23
242.1327820	0.15
243.9434814	6.88
246.0482178	1.35
255.0113220	0.14
257.8757935	68.43
258.6686401	0.03
261.9651184	4.32
267.9940491	0.06
272.0498047	0.21
278.2057190	0.08
284.0625610	2.11
285.9266663	3.66
287.9328003	7.82
289.8855591	2.15
299.9422607	0.08
301.8660278	45.89
303.2248535	0.25
304.0714111	1.03
306.1162109	0.11
313.9743042	2.27
318.2078857	0.10
320.3371582	0.17
327.9598694	3.60
329.7193909	6.02
331.8803711	100.00
332.5160217	0.26
339.3942871	0.08
345.1847229	2.00
345.8810730	18.25
348.0000305	1.05
357.0604248	0.27
358.1544800	0.43
360.1866760	0.30
373.8346252	4.17
375.7259216	0.11
383.1554260	0.07
391.8969116	32.65
392.5311890	0.26
399.3750305	0.16
400.0199585	3.02
401.0877075	0.19
417.8555603	66.71
418.5003967	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	614.73
Annotation	Unknow
Peak:m/z	Relative Intensity
234.8813019	0.12
307.5539856	0.63
340.0512695	0.32
385.0612793	0.13
386.0091553	0.34
387.1135254	0.41
429.1066895	0.33
442.8153076	0.14
454.9689331	0.08
457.1416626	0.18
461.4735718	0.32
466.8988647	0.18
475.1069946	0.23
496.2749023	0.37
498.8550415	0.58
499.9529419	0.17
500.9644165	0.63
513.1588745	0.15
516.5515137	0.18
518.5094604	0.32
541.2395020	0.28
542.2936401	0.10
557.6405640	0.55
566.7789917	0.15
568.9044800	100.00
570.4448242	0.37
584.4064331	0.74
585.5993652	11.91
586.3705444	15.82
587.7941284	2.30
588.6817017	0.60
589.2824707	0.15
590.1049805	0.22
596.9810181	0.28
609.2769165	0.12
614.8829956	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	610.56
Annotation	Unknow
Peak:m/z	Relative Intensity
214.9581604	0.04
227.3766327	0.17
285.2061768	0.17
450.8330688	0.55
455.2160034	0.25
456.9423218	0.03
467.8979492	0.16
468.7861328	0.09
470.7239380	0.48
480.7806396	0.07
494.0432739	3.58
495.0738525	10.93
496.0565186	4.93
496.9619751	9.54
497.9857178	1.38
510.1660156	0.18
511.8932495	0.54
512.8994141	2.50
513.8154907	0.84
514.8831177	2.23
525.0236206	0.25
533.9312744	0.13
534.8855591	1.09
536.0251465	11.32
536.9904785	17.70
538.0478516	1.25
538.9237671	0.19
554.1456299	3.48
555.0559692	4.75
555.8900757	0.18
556.9744263	0.04
564.8848877	100.00
565.6016235	0.51
567.0946655	0.05
573.8902588	0.19
580.9475098	2.74
582.2525024	22.02
583.2846680	1.76
584.4131470	1.36
592.8909302	0.29
595.6082153	0.47
601.4175415	0.77
609.9678955	3.92
611.0839233	0.93
614.4468994	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.119
Annotation	3,4,5-Trimethoxyphenyl glucoside
Peak:m/z	Relative Intensity
118.9507065	0.04
120.0232620	0.33
120.9596176	0.13
132.9568024	0.02
142.7376404	0.04
161.1218262	0.13
163.0886230	0.04
174.9371338	0.10
178.8699646	0.47
180.0767975	0.03
182.1563416	0.08
183.1329498	1.29
184.1286926	0.06
185.0328064	0.12
199.3534546	0.06
222.9750977	0.18
224.0891724	0.12
239.1187744	0.47
243.3074341	0.08
255.1770630	0.02
257.2082520	0.17
259.1703186	0.10
267.2910461	0.05
268.0051575	0.06
283.1766968	0.17
299.1801758	100.00
300.1941528	0.33
301.1091919	0.26
315.0312500	0.09
316.0574951	0.12
327.0809937	1.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
104.9790192	0.33
118.1677551	0.33
145.3377228	0.49
146.1598053	0.19
148.9052277	0.47
149.7986908	0.11
153.3249969	0.08
169.9660492	0.31
174.2472534	0.20
175.3150177	0.09
178.8700714	0.30
181.2849731	0.13
192.7081146	0.27
193.3154144	0.18
194.2525787	0.29
195.1378784	0.46
199.1002045	0.08
206.0355988	0.46
207.1192169	2.39
208.1160278	1.24
209.1310577	0.07
222.0509796	2.11
223.165802	2.26
224.0673676	0.16
235.4181366	0.33
251.0634003	100.00
252.1789398	15.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0197
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
84.9678726	0.64
86.9229507	0.87
100.7900085	0.06
110.9989319	100.00
111.7176971	0.12
114.9563293	0.03
128.9102631	2.73
130.7655792	1.32
146.7514191	0.01
154.8361664	0.19
172.9676666	21.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	393.1556
Annotation	Samaderine Z
Peak:m/z	Relative Intensity
117.0208893	0.03
161.2554321	0.01
217.1213837	0.01
261.1527710	0.02
291.1994629	0.02
307.3029175	0.01
317.2285767	0.04
321.1417236	0.02
331.2673340	0.14
333.4485779	0.02
335.2199097	0.54
347.0101929	0.03
349.1134338	0.34
356.2654114	0.05
364.3421021	0.02
375.2225952	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	356.1847
Annotation	Pestalotiopsone A
Peak:m/z	Relative Intensity
122.9560776	0.06
131.9664307	0.15
134.0862885	0.06
138.7962799	0.06
147.1554871	0.07
149.0529938	0.07
161.0117188	0.23
173.1231384	0.06
174.0101318	0.05
186.1542816	0.21
187.2416687	0.11
193.2790527	0.20
204.2495117	0.06
212.0799713	0.08
213.4176941	0.07
239.9579163	0.15
244.2625732	0.12
250.6668396	0.17
253.0733032	0.06
261.1248169	0.07
262.1654968	0.11
266.9846497	0.24
268.3334961	0.11
269.1106567	0.06
272.7341919	0.07
275.2102661	0.78
278.2258911	0.10
283.7444458	0.15
286.0802002	0.28
286.7802429	0.13
292.5819092	0.48
294.1716309	0.23
296.1778564	0.08
297.0361328	0.13
303.3708191	0.11
309.2309875	0.28
310.0314636	0.09
311.1030273	0.09
312.4254150	0.20
313.1473999	0.03
315.0098267	1.12
320.0396729	1.29
321.0594177	1.26
324.9430847	0.20
327.2789001	0.44
328.9811401	0.11
333.0973816	0.46
338.1741028	100.00
339.3388367	1.01
346.1400452	0.16
347.4417419	0.51
363.9746399	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.119
Annotation	3,4,5-Trimethoxyphenyl glucoside
Peak:m/z	Relative Intensity
98.8455505	0.23
100.9466400	5.05
102.9649200	14.38
105.9999695	3.16
106.9093323	0.20
109.2033386	0.09
112.9774628	9.15
118.9725494	11.62
120.9570465	22.69
122.9927750	0.22
124.9996567	0.88
126.8463211	0.16
130.9934082	1.35
137.1738892	0.55
138.9089966	3.55
142.9825134	8.36
148.5841675	0.30
151.2219543	0.62
158.8312683	0.85
160.9612122	4.16
165.0765991	100.00
178.9130859	7.75
181.0516357	0.77
182.9728699	4.07
192.0223083	0.26
193.3457947	0.13
204.9968262	0.20
207.2494659	0.37
224.8656616	2.71
226.7735901	0.11
234.9728394	0.27
253.4117126	0.28
255.1559448	0.30
258.9425964	0.21
267.2365723	1.23
283.2403870	0.24
297.2144775	0.37
298.1435547	0.35
299.0820312	2.53
301.2235718	0.47
302.2011108	0.60
307.1510010	0.11
308.7671204	0.17
312.2074890	0.48
327.1895142	0.29
344.7865295	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	529.2653
Annotation	Tricalysioside Q
Peak:m/z	Relative Intensity
151.2561340	0.07
160.9897461	0.26
193.1494751	0.20
213.2013855	0.31
215.1973572	0.15
221.2177734	0.42
223.4480591	0.18
228.7251129	0.20
229.3630219	0.03
231.0827637	1.88
233.0733490	0.07
239.3403625	0.05
243.1534882	0.23
245.3919830	0.26
247.4275513	0.09
255.3524170	0.14
267.2683716	0.39
269.0943604	0.63
271.0781860	0.91
272.2412109	0.16
273.2884521	0.11
275.1059265	0.50
285.3157959	3.48
286.2155457	0.15
287.3034668	2.32
288.1581421	0.23
289.2817993	0.41
291.3829041	0.21
293.2691650	0.14
297.2038269	0.10
302.6428223	0.56
303.3909302	4.22
305.1869202	5.73
306.3632812	0.82
313.0049438	0.12
319.2879639	0.09
321.4296265	0.22
322.3515625	0.33
323.1519165	0.27
324.4372559	0.39
329.5216675	0.37
331.3336792	13.06
332.2041626	0.75
333.2789917	2.47
334.1226196	0.30
347.3256836	5.11
349.2137451	76.95
350.3049927	6.60
365.2843018	6.69
366.1434326	2.52
367.2494507	100.00
368.3410034	8.62
407.4348145	0.04
456.2343750	0.31
483.1775513	0.35
499.4728394	0.34
502.6235962	0.08
509.2951660	1.31
511.3110352	10.58
512.4027710	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	285.21
Annotation	Hexadecanedioic acid
Peak:m/z	Relative Intensity
94.00580597	0.12
130.0201569	0.08
155.2541351	0.17
169.132782	2.00
171.1928101	0.46
172.9819183	0.30
181.315094	0.54
184.2798767	0.48
185.0014496	0.15
189.074173	0.50
190.9925537	0.15
196.248291	0.19
197.3822021	0.21
198.2156067	0.28
207.3852234	0.14
212.9176331	0.26
213.9287415	0.24
223.267334	27.15
224.2706299	0.26
225.3113403	1.88
227.2235413	0.20
239.6113586	0.49
241.1958618	3.39
242.2422791	0.95
243.7411499	0.08
249.1456604	0.37
257.1960144	0.77
265.4069824	1.07
267.194519	100.00
268.1381226	5.34
269.2161255	2.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	543.2442
Annotation	gibberellin A2 O-beta-D-glucoside
Peak:m/z	Relative Intensity
161.2118378	0.49
178.3840942	0.17
179.1141357	0.93
229.2078705	0.18
247.3165588	0.26
254.1555023	0.12
255.2642212	0.80
257.4689941	0.44
273.4148254	0.96
275.2385254	2.39
282.9696655	1.57
285.1043701	2.76
291.4238586	4.46
292.0792542	0.23
301.3100586	7.98
303.1905518	3.05
305.1342773	2.16
306.1281738	0.45
308.1785889	0.31
317.2169800	1.13
319.3721313	24.38
320.1895752	0.48
327.2581177	0.42
333.3992920	0.29
335.2769775	4.92
337.2734375	25.87
338.3096313	0.89
345.2778931	36.31
346.1573486	1.90
363.2906494	100.00
364.3474731	2.78
377.0648804	0.19
381.2008057	1.42
421.2290649	0.51
481.3669434	0.18
497.4335938	0.35
499.3858643	65.54
500.3457642	6.14
525.3236694	6.14
526.1064453	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	285.21
Annotation	Hexadecanedioic acid
Peak:m/z	Relative Intensity
86.96107483	0.34
92.94541931	0.25
132.2501526	0.40
169.0577698	1.18
171.2255859	0.81
181.2000122	0.37
183.2950134	0.61
185.1869659	0.40
187.0053101	0.45
191.0374298	0.07
196.6401672	0.50
199.0405273	0.37
200.2634583	0.14
201.0257263	0.16
205.1872253	0.33
211.2021484	0.21
213.3796082	1.05
215.9572144	0.19
223.1894531	28.90
224.0081177	0.72
225.2224731	0.85
227.1156616	0.18
239.2134094	2.89
241.2528687	5.12
242.1002808	0.18
243.0952148	0.74
249.5549927	0.80
253.2849121	0.39
255.3078003	0.33
256.3288574	0.44
257.1107483	0.53
267.192627	100.00
268.2419434	2.69
269.24823	2.01
269.9544067	0.49
285.465271	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	529.2289
Annotation	Eurycomaoside
Peak:m/z	Relative Intensity
150.9637909	0.06
159.1087799	0.13
160.7838593	0.11
225.1339569	0.14
231.3430481	0.03
257.3430481	0.08
261.3077087	0.21
271.2618713	0.03
287.3599854	0.84
289.0822449	0.06
303.3367310	0.11
305.2670288	2.27
306.2278442	0.17
307.1887817	0.07
313.2689209	0.03
315.2520142	0.05
316.5231323	0.06
319.4818115	0.08
321.2225342	0.04
323.3711548	2.49
331.1724243	0.83
332.3138428	0.15
333.2761230	0.05
337.4342041	0.57
349.2409058	2.32
350.3594971	0.25
359.0511475	0.10
365.1034546	0.04
367.3441162	1.19
368.2647095	0.02
390.9837036	0.04
397.1534424	0.07
407.5208740	0.09
409.4966431	0.14
424.4839478	0.08
431.4298706	0.05
432.2439575	0.07
433.1087646	0.03
441.4201050	0.25
449.4486084	0.33
451.4578857	0.12
457.3699341	0.06
467.2717896	6.65
468.1676025	0.06
469.6676025	0.06
481.2824097	0.14
483.3970337	0.07
485.3772583	5.99
486.3727417	0.60
491.0177612	0.03
493.2488403	1.08
499.4337769	4.66
511.2690430	100.00
512.2789917	3.52
529.0178833	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.83402252	0.16
78.99525452	0.34
80.96601105	0.27
90.9394989	0.11
93.09753418	0.11
95.03753662	0.16
97.08164978	0.49
103.2567596	0.41
104.9290924	0.68
107.0362549	1.80
108.9820099	0.54
110.8318176	0.50
112.9284058	0.24
121.245575	0.65
122.9021759	0.61
128.9474182	4.95
133.0478058	1.10
134.981308	0.18
141.1139984	1.49
145.1041565	1.69
150.9271851	50.87
152.1311951	4.70
153.175705	1.01
155.0138702	0.70
161.2255096	0.90
163.1507111	0.35
165.1598053	0.18
166.2139435	1.25
168.921051	0.72
170.7143402	0.66
174.9613647	0.36
176.9693451	0.36
179.1195679	1.05
182.923111	0.95
185.2026825	0.89
189.3677826	1.00
190.8243866	0.88
193.4672394	0.27
197.0261993	4.52
197.8977661	0.45
198.9535522	0.49
206.802536	0.17
209.9789124	0.45
211.1070404	0.60
217.0544128	3.51
225.1522064	4.34
226.036972	0.41
235.1234741	5.65
238.0911865	8.31
244.083313	0.17
251.0435333	0.11
253.0947876	100.00
254.1295929	20.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.16
Annotation	Unknow
Peak:m/z	Relative Intensity
167.0975800	0.61
179.0104675	0.21
199.0530548	0.10
217.0348816	0.02
227.0173645	0.39
231.0881195	0.22
241.1328125	0.18
249.0422516	2.16
254.9295654	0.12
265.0000610	0.05
267.2028809	1.35
269.3155518	0.08
313.3447266	0.12
316.9750977	0.08
323.2993164	0.10
332.1887817	0.02
335.3751221	0.21
340.9380493	0.46
351.3756104	0.09
353.4121704	0.22
356.9741821	0.52
359.1397705	0.15
371.1406860	0.05
374.9751587	0.04
377.2097168	0.08
381.2150269	0.02
385.2025146	1.86
394.9871826	0.07
397.3605957	0.07
399.1798096	10.52
403.2670288	0.24
417.1520386	100.00
417.7550049	0.15
425.2131348	0.14
432.3991699	0.08
433.2727661	0.04
441.0525513	0.30
449.2513428	0.04
451.1460571	0.09
455.1217651	0.05
459.1937866	1.21
465.2005005	0.09
466.1527710	0.04
474.1864624	0.08
483.0267944	0.04
488.7890625	0.03
489.5058594	0.04
495.1229248	0.09
505.8516235	0.20
520.2816772	0.05
525.3524780	0.14
532.8196411	0.94
533.4589233	0.24
535.0750732	0.33
544.2976685	0.03
545.2329102	0.08
555.5640869	0.13
556.5509644	0.31
559.3959351	0.03
561.1411743	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	543.2447
Annotation	gibberellin A2 O-beta-D-glucoside
Peak:m/z	Relative Intensity
160.9672241	0.42
179.0538025	0.41
235.2870789	0.11
247.2494049	0.03
257.2169189	3.27
263.3679199	0.09
273.2139893	2.34
275.1921997	0.27
289.3015747	0.06
291.2092896	0.29
301.1851196	0.47
317.2889404	67.41
319.3037720	3.00
329.3406372	0.09
335.2883911	74.63
336.4326782	0.10
337.4323120	0.13
345.0926514	0.94
347.4105835	0.15
363.3030396	3.11
381.2940063	1.05
405.3863525	0.29
423.2174683	0.25
465.1439819	0.22
479.4621582	0.08
481.3457031	2.17
497.3043213	100.00
498.0972900	0.42
499.4100952	3.48
507.4636841	0.30
513.0742798	0.09
515.3569336	0.07
525.3049927	87.54
526.2413940	1.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	643.1722
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
217.1948547	1.12
241.2209473	0.26
255.9827881	0.11
259.1599426	0.11
269.1829834	0.32
281.2765198	0.33
282.1470947	0.12
283.0166321	0.42
300.1338806	0.55
301.0491638	1.81
303.1318359	36.03
307.3258057	0.14
315.8806152	0.08
321.0697937	100.00
323.1062012	0.07
337.0072021	0.12
339.4158936	0.60
357.0447998	0.11
357.7620239	0.13
359.0664062	0.10
360.1215820	0.57
373.6855469	0.28
375.0852661	0.69
386.8259888	0.53
390.6411743	0.11
423.7257080	0.54
424.8763428	0.66
436.7393188	0.09
451.1846924	0.12
463.2145996	0.16
467.1854248	0.17
469.2266235	0.33
479.2198486	2.05
481.9490967	0.07
497.1447754	0.50
499.2309570	0.50
511.2731934	0.59
539.0864868	13.30
539.7022095	0.10
545.1243896	0.55
552.9645386	0.20
555.0064087	0.10
559.2885742	0.37
571.4011230	2.42
583.0926514	0.43
625.1893921	16.33
626.0128174	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	529.26
Annotation	Parvifoliside
Peak:m/z	Relative Intensity
151.2835693	0.17
152.0132751	0.03
152.7378540	0.18
156.8726349	0.31
159.2316284	0.32
164.4829865	0.05
165.1077576	0.22
167.1797180	0.02
169.1259308	0.14
171.2550507	0.16
177.1719818	0.69
181.0653992	0.24
183.1711426	0.20
185.0190277	0.62
187.0048981	0.02
189.0446014	0.35
192.9840088	0.27
195.1341400	1.43
197.2243500	0.25
199.2766876	0.65
201.0256348	0.06
203.1735687	0.07
205.0978088	0.22
207.1668396	0.06
207.9734344	0.06
209.1249847	0.46
211.2144623	0.66
214.9455719	0.10
217.2690430	0.85
219.2145996	0.28
221.3276672	0.17
223.1060791	0.58
225.2179108	0.67
227.1807556	1.22
229.0025024	0.34
237.2151947	0.27
239.0998383	1.85
241.2024994	1.59
242.8177490	0.25
243.4777222	0.18
245.1421814	0.88
247.2343445	0.37
249.0946960	2.25
251.2957153	0.30
253.4332581	0.03
255.0149231	0.03
257.2213135	2.49
259.2012634	0.53
261.1884155	0.91
263.1707764	0.41
267.2164307	17.91
269.0599365	0.82
273.2286987	0.15
275.0407715	0.05
277.0841675	0.31
278.9916992	0.10
282.8288574	0.10
285.1398621	18.43
287.2985229	0.49
293.2310791	0.05
295.0142822	3.54
301.2372437	1.66
302.5531616	0.20
303.2856750	4.49
305.2744751	1.77
311.0168457	0.06
312.6358032	1.81
313.2463379	46.72
315.2420044	0.38
319.2308350	0.02
321.4526978	0.22
323.2708130	0.10
331.1937256	68.36
333.2629395	0.28
337.3544922	0.32
343.2173462	0.33
349.2314453	100.00
349.9152222	0.68
351.2646484	0.25
355.2748413	0.18
359.3113403	0.14
367.2022095	15.85
367.8438721	0.12
379.2277832	0.25
395.4676514	0.10
409.2319946	0.13
415.3741455	0.09
420.2019653	0.10
429.0314331	0.06
431.5205078	0.04
439.2960815	0.56
445.3997192	0.08
447.1777344	0.14
456.6641235	0.06
457.5436401	0.17
465.0111694	0.12
475.4118042	0.45
493.1407471	7.81
493.8010864	0.22
511.3335571	11.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.14
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
174.8225250	0.23
177.0947266	0.26
178.9696503	3.28
183.0781555	0.21
184.6797485	0.08
192.1774139	0.79
196.5402374	0.13
197.2297058	0.15
205.0865631	0.15
208.1716614	0.18
210.0880127	2.70
213.0924683	0.52
226.2998047	0.08
227.9555054	0.31
230.9616699	0.17
236.0041351	0.08
242.2778320	0.17
254.1462708	16.79
262.8445435	0.19
268.8463745	0.15
270.0947876	0.13
272.0679932	41.64
272.6699829	0.13
286.1041260	2.38
288.1726685	4.25
304.0848389	14.91
306.1067505	100.00
307.1354675	0.08
319.7802124	0.21
338.0215454	39.31
353.0039673	0.45
360.0118408	0.10
417.8202515	0.12
419.1372681	0.17
437.0629272	0.09
449.0900879	0.08
464.0562744	0.64
482.1455688	29.90
523.1857300	0.06
528.5661011	0.19
567.3359985	0.07
575.2455444	0.68
593.2402954	13.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	791.0638
Annotation	Unknow
Peak:m/z	Relative Intensity
248.2911987	0.09
254.3303528	0.52
256.0671387	1.57
257.1661377	0.30
270.2517700	0.07
271.9925537	0.16
282.2817383	0.34
282.9420776	0.45
289.2850037	0.09
300.1414185	2.06
301.1353455	0.15
314.1622314	0.17
316.1325989	0.76
326.2994385	0.25
341.2935181	1.67
345.6062622	0.50
347.3540649	3.26
353.6414795	0.08
355.2365112	0.11
360.2438660	0.24
362.3674316	0.42
369.2713318	1.35
370.0563354	0.19
378.1381226	0.33
392.8107910	0.37
394.6427612	0.41
396.3614502	0.22
403.5327148	0.73
410.8231201	0.19
415.3585205	0.09
419.2763062	0.40
423.3380737	0.26
429.0457764	8.08
430.2990112	0.23
440.3766479	2.00
441.4059448	0.47
458.5959473	0.94
461.2966919	1.50
463.8279419	0.98
471.2673340	0.25
475.2653809	0.51
476.2829590	5.68
477.5989990	0.49
485.1173706	0.56
486.3204346	0.54
497.6814575	0.29
509.2962036	1.17
510.3023682	0.26
511.3096924	0.21
520.1802368	0.17
524.2736206	0.90
528.0583496	22.15
528.9901733	2.39
537.2207642	0.20
554.4094849	0.79
555.6286011	0.49
563.2960815	5.87
564.4364624	0.08
567.3602905	0.30
573.3321533	0.16
575.1068726	0.13
577.2499390	4.47
578.8010864	0.25
580.1336060	0.43
581.1493530	1.13
597.5981445	1.32
599.1665649	39.01
600.2382202	6.25
611.3029785	0.22
614.0266113	0.34
615.1611328	1.35
615.7975464	0.40
624.0482178	28.99
625.1256714	0.68
626.6024170	0.58
627.3145142	0.22
628.3565674	0.56
629.3961792	0.72
644.5142212	0.33
658.2899780	1.40
662.3560181	0.51
666.8678589	0.51
667.9525146	1.25
669.1260376	0.94
670.4951782	0.10
671.9957886	0.09
674.5573120	0.42
676.3273315	0.26
678.3871460	3.27
679.4883423	1.61
680.4877930	4.29
682.4335327	0.26
686.1531982	37.11
687.1015625	4.47
687.7811279	0.98
694.5374756	1.71
695.3430786	0.81
697.5627441	0.17
698.5769653	0.15
717.0692749	1.90
725.8572998	4.20
727.0043945	0.19
739.2085571	51.67
740.1345825	10.89
741.5712280	0.95
747.6340332	0.32
753.4063110	2.66
754.3392944	0.61
755.0363770	0.31
757.0617065	35.79
758.1704712	7.02
758.9898071	0.44
760.3345337	0.53
761.1524048	0.33
765.3635864	1.72
766.6344604	0.15
769.0850830	0.37
771.4963989	0.87
773.0996094	0.53
773.9813843	0.45
774.5913086	0.62
777.8065796	0.56
779.3047485	4.43
780.3634644	0.66
783.0454102	0.23
787.0897827	0.38
799.3960571	2.72
807.6802979	8.19
808.3018799	70.82
810.1135864	0.96
810.7590332	0.09
813.4105835	0.22
823.2207642	0.12
826.3434448	0.47
834.6755981	5.12
836.9104614	0.50
838.6324463	0.72
841.5290527	0.55
843.6013794	100.00
844.5390015	2.53
845.7387085	3.06
847.7904053	2.27
852.3913574	0.98
854.2256470	0.35
866.7429810	0.36
868.9629517	0.96
870.1643677	0.32
871.0894775	0.32
878.1177368	2.96
879.1269531	2.47
879.7349854	0.21
881.6520386	0.15
882.5371094	0.30
887.1358032	75.99
888.0908203	1.32
888.9320679	0.26
889.7362671	0.96
890.3396606	0.24
891.0664673	0.58
898.2987671	0.21
899.4379272	0.22
900.6083984	0.86
901.4265137	0.80
903.1583862	0.22
904.1785278	0.20
905.3165894	0.37
908.7783813	0.65
913.2615356	1.69
914.5288086	0.86
916.1942749	0.21
921.3979492	7.83
922.6895142	45.86
923.8830566	0.68
924.9192505	0.83
926.4706421	0.56
929.0129395	0.10
929.9338989	0.09
930.5363770	1.06
937.0772095	0.97
938.3896484	0.16
939.3618164	2.70
940.0225220	1.01
941.0288086	0.88
948.5812378	3.29
949.4213257	1.14
955.5150757	0.32
959.7738647	0.11
961.5192261	0.42
963.3823242	2.62
964.1439819	1.00
964.9982910	0.44
972.1515503	19.95
973.2813110	0.68
973.9235229	0.94
975.1133423	0.12
977.1973267	0.31
978.1091309	0.41
985.4735718	0.39
994.2624512	2.17
995.0615845	1.63
995.7042847	0.13
999.4562988	1.87
1000.9482420	0.14
1003.6857910	1.75
1004.3246460	1.38
1004.9494020	0.38
1006.6257320	0.18
1009.3032840	0.79
1012.0850220	5.18
1012.7354130	3.81
1013.3732300	3.25
1014.0789180	0.13
1016.4265140	0.30
1020.8041990	1.56
1028.0672610	1.55
1028.7308350	0.68
1030.5187990	0.56
1036.6928710	25.64
1037.6673580	1.09
1038.6408690	1.26
1039.7174070	0.65
1040.6152340	0.09
1053.7946780	1.64
1054.9443360	0.97
1056.4587400	1.16
1062.9166260	8.72
1063.5869140	0.04
1065.2968750	0.45
1066.4592290	0.53
1083.0969240	0.43
1092.0806880	0.27
1095.1044920	0.21
1100.6787110	0.71
1101.4395750	1.06
1103.6582030	1.35
1104.2971190	1.60
1106.2059330	0.38
1107.3448490	2.07
1108.3505860	0.20
1112.8331300	17.63
1113.6101070	12.12
1114.6708980	0.79
1115.4394530	0.16
1116.2907710	0.36
1118.0124510	0.32
1120.1140140	0.23
1120.9621580	0.43
1121.5722660	0.54
1122.2862550	1.21
1125.1824950	11.66
1126.2593990	5.17
1127.5988770	0.55
1135.6096190	0.15
1139.7353520	0.98
1149.8878170	0.07
1150.9583740	1.07
1159.2297360	0.32
1211.4531250	0.06
1213.4466550	2.02
1214.2377930	0.46
1228.5621340	1.20
1229.7901610	1.16
1232.4870610	1.36
1246.5523680	28.67
1247.5709230	9.54
1250.4918210	2.39
1255.5821530	0.62
1268.6885990	0.79
1269.4117430	1.14
1321.5858150	0.54
1350.8627930	0.26
1359.8651120	0.75
1367.4456790	2.39
1368.2081300	0.47
1371.4273680	0.15
1430.4097900	0.54
1432.3812260	0.32
1439.1129150	0.15
1450.6397710	1.52
1451.4617920	0.07
1453.6240230	0.46
1468.4710690	3.75
1469.6373290	2.42
1491.6994630	0.12
1497.7392580	0.37
1517.5170900	0.13
1518.9967040	0.37
1527.4731450	0.10
1528.1647950	1.16
1538.8419190	0.11
1539.6633300	0.66
1557.9746090	0.17
1561.4603270	0.06
1597.4406740	0.57
1598.5809330	0.40
1627.0764160	1.06
1695.7449950	0.31
1902.6971440	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	416.1691
Annotation	Ceratocapnine
Peak:m/z	Relative Intensity
121.9981003	0.01
129.1481323	0.05
129.9894409	0.03
133.0735168	0.02
138.0469055	0.05
141.0021057	0.10
145.1814270	0.04
146.0722809	0.06
147.1487274	0.06
149.7759552	0.02
152.0474548	0.19
155.1722412	0.07
158.0162048	0.10
164.8306885	0.08
167.0455017	0.03
170.0286560	0.06
173.0760803	0.02
174.0472107	0.02
178.0657043	0.02
179.0659485	0.05
180.8291321	0.47
181.5463562	0.02
182.3096008	0.13
183.1566467	0.10
186.8224182	0.05
188.7924805	0.02
190.0117035	0.07
192.1629791	0.02
195.0098419	0.07
198.2137299	0.18
199.6338806	0.04
201.1381073	0.02
202.2300873	0.14
203.0259705	0.03
204.1380463	0.24
205.1440430	0.06
207.4797821	0.09
209.0570679	0.12
210.2609253	0.04
211.0624695	0.07
213.1236877	0.14
214.2387085	0.03
215.1385040	0.14
217.1269836	0.28
218.1976929	0.29
219.1691284	0.05
219.9417725	0.15
221.1504059	0.22
223.1159058	0.58
224.3340454	0.50
225.2064209	0.30
226.3104248	0.13
227.1645050	0.07
229.1639404	0.06
234.1505432	0.12
235.4093628	0.03
236.1004028	0.05
237.2576904	0.03
238.1698608	0.20
240.2043152	0.29
241.1775208	0.65
242.5001221	0.15
246.1270752	0.08
247.1931458	0.05
248.2035217	0.37
249.0394287	0.02
250.0366211	0.71
251.2018433	0.24
252.2407837	0.04
253.7571716	0.53
254.5105286	0.01
255.1743774	0.03
256.3032837	0.05
258.5059814	0.14
259.2162170	0.50
261.3132935	0.04
262.3109741	0.10
263.0924377	0.06
264.0507507	0.24
266.2412720	0.41
267.0027771	0.15
268.1490784	2.33
269.2398682	0.81
270.2630005	0.32
271.3024902	0.03
274.1045227	0.09
275.2304077	0.09
277.8678589	0.14
278.8831482	0.02
280.0819397	0.20
282.2192993	1.82
283.3173218	0.31
284.1960754	0.91
285.3273926	0.24
286.0819702	0.08
290.2419434	0.17
291.3307190	0.22
292.2738647	1.73
293.3754272	0.12
296.3459473	0.22
297.3415527	0.05
298.2337646	0.32
300.3583984	0.07
301.2055969	0.16
306.2774048	0.10
308.1285400	0.96
309.0069580	0.23
310.3132324	0.85
311.2042542	0.05
313.2200317	3.01
314.2234192	0.33
315.2786865	0.19
318.0048523	0.25
319.3088989	0.10
324.2288818	0.82
326.1868286	16.59
327.1943970	2.07
328.1771240	3.81
329.3319702	0.35
330.2714539	0.83
331.3630371	0.06
334.3414917	0.71
335.1502075	0.18
336.2857361	0.58
337.0042114	0.17
338.3456726	0.05
342.2772827	0.32
344.2709961	1.02
345.2496948	0.10
346.0395813	0.04
349.4855652	0.02
350.3192139	0.05
352.2568970	1.02
353.6271973	0.32
354.3271484	2.72
355.1992188	0.21
356.2568665	0.14
358.1248779	0.09
360.2684631	0.25
363.1229248	0.63
367.1086121	0.07
370.2191467	100.00
371.2527771	9.20
372.2359009	11.95
373.2112732	0.81
374.0597839	0.34
374.9378662	0.08
376.0764465	0.09
380.1842957	1.46
381.1407471	0.60
388.2048950	17.34
389.3321228	1.51
395.0370789	0.06
398.2148438	82.25
399.2864075	8.95
406.7481079	0.16
407.4451294	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.2371
Annotation	Magnesium protoporphyrin monomethyl ester
Peak:m/z	Relative Intensity
179.1952362	0.11
181.0773010	0.19
205.1958160	0.12
211.1046448	0.15
249.1376495	4.60
269.1988831	0.13
275.5888672	0.09
283.0617676	100.00
287.4102783	0.57
313.1959839	1.43
321.1148071	0.07
331.3182983	47.67
341.2157593	0.22
345.4593506	0.23
347.2861938	12.13
369.1355591	0.11
373.2683105	1.12
387.1041260	0.05
389.1999512	0.04
403.1488647	0.04
403.9661255	0.17
425.1730957	0.13
433.3448486	0.82
435.2422485	4.62
477.2156372	0.22
493.2295532	2.31
501.1889648	0.08
509.2778931	0.45
519.3770142	0.14
527.1465454	0.09
532.6607666	0.22
535.4505005	0.12
537.2123413	0.07
539.4253540	0.23
541.0421143	0.15
545.5933838	0.11
551.0848389	0.49
553.6549683	0.08
560.9076538	0.51
563.5017090	0.40
566.8040161	0.07
579.2751465	0.55
581.4093628	0.04
583.7381592	0.06
588.8963623	0.53
591.0373535	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	221.12
Annotation	0AP Silane 55
Peak:m/z	Relative Intensity
69.1175919	0.07
71.0035400	0.12
72.0081787	1.28
72.9602814	1.10
85.8446198	0.07
87.0433044	0.06
87.8907089	0.15
89.8834686	25.38
90.9910812	14.30
95.0296478	0.13
95.8488312	0.29
97.8365936	0.48
101.2190094	0.06
103.0952148	0.05
106.0220642	0.07
107.0002289	0.02
114.1228333	0.13
115.9776154	2.57
117.0088043	2.17
118.0119629	0.08
119.2167664	0.05
125.0536804	0.12
125.9916077	0.06
127.1420898	0.07
132.0591583	0.02
133.1010284	0.05
136.1362762	0.10
141.3117676	0.11
142.4233551	0.28
143.0725098	0.14
147.0479279	0.04
151.1309967	0.02
153.0502625	0.03
155.0510101	0.02
156.0159454	0.08
157.0651703	0.72
163.2166138	0.19
165.0509949	0.42
167.0704193	1.20
172.9491119	0.04
174.1216431	0.28
175.0205231	4.89
176.9180298	0.20
178.7364349	0.05
179.9447021	0.10
185.0698853	26.65
193.1232452	0.12
200.5362244	0.19
203.0396576	100.00
203.9854126	0.51
215.2114410	0.17
220.9863892	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0852
Annotation	6-Methylflavonol
Peak:m/z	Relative Intensity
80.85075378	1.45
82.96140289	0.78
84.43751526	0.11
85.03942871	0.35
93.0949173	0.39
94.92552185	1.42
96.91789246	0.77
98.90396118	0.77
102.8977203	0.82
104.9167328	1.46
106.923645	1.09
109.0174561	1.46
110.8742981	0.66
112.4849091	0.64
113.1585388	0.44
119.2405548	0.19
121.2482452	1.00
123.0294037	3.28
124.9850769	1.28
127.0018158	0.93
129.0014954	4.72
130.0159912	0.50
130.933609	0.19
133.1359711	0.33
135.0071869	1.59
137.1720734	0.47
141.0326996	2.47
142.9548187	0.41
144.7777252	0.31
147.047699	1.93
149.0429535	0.91
150.9112396	45.34
151.8654327	2.18
153.1049347	0.63
154.94841	0.85
157.0061493	0.57
158.9266968	0.13
161.1111603	1.28
162.7761383	1.92
165.0703278	0.24
166.0182037	0.83
166.9334564	0.46
169.0210419	1.91
169.9526825	0.33
171.0854645	0.97
174.9871063	0.43
176.8070679	0.62
177.8744507	0.10
179.1246948	3.32
180.1422119	0.34
181.1517487	0.87
181.9450531	0.94
182.9733276	1.37
185.1287842	0.86
188.8812561	0.27
191.0958862	1.56
193.160202	0.88
194.1141815	0.91
195.0635986	0.98
197.1073456	3.54
199.0377808	0.56
206.9444275	0.72
209.326355	0.68
210.1856384	0.51
211.1465759	3.88
211.9756317	0.30
217.2092743	4.58
220.1768951	0.37
221.9472961	0.35
225.1542206	11.24
226.3694305	1.13
235.0781708	16.91
235.8923187	1.08
238.0684662	4.17
239.1392059	2.04
251.1925201	0.43
253.076767	100.00
254.0990601	16.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1659
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
113.0000916	1.36
118.8712006	1.52
120.1939392	0.25
125.0937958	0.14
130.8029327	0.34
142.8745728	1.72
144.8909760	0.13
147.1064758	0.57
148.8870239	0.26
158.8429565	0.15
160.9548187	1.89
163.1493530	100.00
164.0670471	0.26
166.0450134	0.27
178.9424744	0.97
181.2334595	0.30
184.2079315	0.17
192.2433929	0.57
192.9794617	0.61
206.4852295	0.13
207.0983887	9.34
209.1308289	0.54
210.1844788	0.77
225.0927429	54.38
240.9718628	0.08
249.1264038	0.66
252.7261047	0.13
257.0939331	0.21
267.3931274	1.63
270.4388428	0.14
281.1437378	0.26
282.5121765	0.37
287.1305542	0.38
297.1143188	0.47
325.4718933	0.21
341.1657410	4.94
343.2199707	0.26
344.3848267	0.22
351.2066956	0.24
369.2673340	32.97
370.2271423	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	379.1743
Annotation	Triptriolide
Peak:m/z	Relative Intensity
111.0851059	0.06
132.8518372	0.04
144.9882812	0.05
145.8002930	0.24
199.0450897	0.15
200.2255554	0.07
200.8576355	0.11
203.1594238	0.04
207.0008240	0.18
213.0502319	0.08
217.0426331	0.13
220.2796326	0.08
223.1297607	0.04
238.8032532	0.08
239.4416809	0.39
243.0046082	0.50
248.1808472	0.06
249.2654724	0.09
253.2695618	0.04
258.0619507	0.08
261.4737549	0.05
263.1266785	0.04
266.1461792	0.23
269.4635010	0.21
271.1358643	1.05
272.0296631	0.22
273.2067566	0.10
275.0801392	0.12
285.0120850	0.16
287.2990112	0.84
289.2725220	9.61
291.2639771	0.23
297.1614990	0.49
298.1826782	0.08
299.0567627	0.04
303.0444946	0.38
307.0806885	0.11
313.3565674	0.09
315.0498962	2.42
316.8579102	0.31
325.2418823	0.20
331.5459900	0.78
332.9434814	18.22
333.6756287	0.08
335.3439331	0.16
336.3853760	0.19
343.0482788	3.48
344.2548828	0.22
345.4694519	0.14
350.9600525	0.08
351.9833069	0.16
359.1657104	1.38
360.9635010	100.00
361.6723633	0.74
369.1763611	0.12
370.2380371	1.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	399.2492
Annotation	Tris(butoxyethyl)phosphate
Peak:m/z	Relative Intensity
124.8444519	0.49
126.9125366	0.29
134.9276733	0.23
136.0431366	0.17
137.3043823	0.45
142.8502350	1.45
150.6938629	0.23
153.0131531	0.27
156.8514709	0.20
165.9816589	0.22
167.2512665	0.06
170.1339722	0.34
171.0131989	0.38
178.7716370	0.33
180.0255432	0.11
184.9171906	0.17
191.2244415	0.31
193.0130310	0.28
199.0526428	29.29
201.2261353	0.37
205.1938019	0.10
211.0612335	0.33
212.0187531	0.14
213.0169525	0.35
214.1561432	0.24
215.0345764	0.17
219.2385712	0.15
225.0830688	1.22
227.3602905	0.30
229.1509705	0.77
233.2263794	0.29
235.4921265	0.22
237.2353210	0.93
238.9128418	0.33
241.1936035	0.60
242.5851746	0.72
243.5043945	0.31
248.1246643	0.13
249.2032166	0.59
250.9581909	0.36
253.1709290	0.43
255.0160828	0.30
256.2327881	0.69
260.1974182	0.05
260.9888611	0.22
265.3242188	0.50
266.9922485	0.43
268.4457397	0.08
269.0579529	0.59
271.1914368	0.33
273.0847473	0.35
276.1741943	0.39
277.2918091	1.04
279.1931763	2.91
280.1452332	0.06
282.2267456	0.15
283.3360901	0.54
286.9197693	0.10
288.2860413	0.15
289.2470093	0.37
296.2523499	0.31
297.0902710	0.39
299.1259155	100.00
305.2767334	0.73
308.4119263	0.05
311.1668701	0.26
312.5355835	0.13
313.4555969	0.20
315.1196899	0.10
325.1964111	0.40
327.2723999	0.12
329.2053223	0.12
337.1405029	0.13
339.9272461	0.07
341.0582886	0.26
343.0432129	1.07
349.8007202	0.33
352.7433472	0.09
354.3947754	0.17
357.8800354	1.26
363.2789001	1.22
364.0435181	0.14
367.2965393	0.14
371.2765808	0.11
375.9253845	0.66
379.3072510	0.41
381.2665710	7.03
382.1153564	0.36
383.4237061	0.30
384.7728882	0.08
389.7139587	0.42
400.2684326	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	614.26
Annotation	Pervilleine D
Peak:m/z	Relative Intensity
177.3508453	0.04
178.4701691	0.02
179.8471985	0.01
180.8947601	0.03
186.0917816	0.03
197.0049591	0.04
198.0316772	0.06
199.5186005	0.02
204.8167114	0.02
209.3326569	0.15
211.1732178	0.04
221.3087769	0.06
223.3789825	0.07
224.2089539	0.02
225.2038879	0.04
227.2507019	0.21
229.4383850	0.02
230.9781036	0.01
235.1274261	0.03
235.8117981	0.05
237.2397766	0.01
238.3113403	0.23
239.2885895	0.34
240.1976776	0.02
241.1676025	0.01
242.2224884	0.10
244.2573547	0.04
248.7370605	0.05
249.3790894	0.01
250.1707001	0.03
251.2275391	0.06
253.3462372	0.01
254.8473053	0.05
256.1358032	0.02
257.3622131	0.08
258.8963928	0.05
260.8665466	0.01
262.2490234	0.01
264.4452515	0.01
266.1346741	0.09
267.3335266	0.04
269.2454834	0.08
270.2221375	0.02
271.3731079	0.18
273.0916748	0.08
276.2876587	0.04
282.1822205	0.05
283.2611084	0.18
284.0241394	0.03
285.6380005	0.09
286.3589478	0.07
289.0920105	0.01
290.0200500	0.01
295.2536011	0.06
296.0032959	0.04
297.3282471	0.09
300.0335693	0.01
310.2072754	0.04
312.2501221	0.05
318.2400513	0.04
321.0204468	0.01
323.3433838	0.02
324.3714600	0.01
330.4009399	0.04
331.4857788	0.04
332.2850952	0.04
341.9424438	0.08
343.3853149	0.09
344.3195190	0.08
345.1772461	0.09
346.1115723	0.04
348.4476318	0.02
353.6237793	0.02
354.3590698	0.03
358.0196533	0.03
360.2240601	0.10
362.2659912	0.12
370.2287598	0.31
372.2711792	0.36
374.3248901	0.02
378.3912354	0.01
380.2048340	0.10
386.2614746	0.01
386.9711914	0.02
388.2701416	0.75
390.4050293	0.48
398.3733521	0.12
403.7265625	0.01
404.4420166	0.06
405.2592163	0.05
406.2443237	0.09
408.0658569	0.03
416.1897583	3.37
416.8417969	0.03
418.3392944	0.27
422.1845093	0.12
430.3793945	0.01
434.3623047	9.80
435.0703735	0.10
450.4375000	0.03
452.2669678	100.00
453.2215576	0.07
458.2730103	0.03
460.5229492	0.01
463.5453491	0.03
482.3732910	0.07
510.6137085	0.01
516.0162354	0.02
541.2713013	0.09
542.6234741	0.03
550.4303589	0.31
552.2802124	0.14
568.2280884	0.22
569.2129517	0.05
570.6437378	0.10
573.1544800	0.04
578.0033569	0.01
596.3930054	6.76
598.2437134	0.04
600.2205200	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	601.1384
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0177612	1.13
220.9005737	0.22
241.0761719	0.19
250.0947723	0.31
259.0920410	11.48
262.8859558	0.58
280.9188843	1.13
310.7441406	0.26
323.0014343	1.68
340.9414673	0.93
379.1596680	0.90
421.2695923	2.67
439.1898193	58.05
442.9745483	0.63
468.0764771	0.46
503.2389526	100.00
583.3085938	41.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	594.2223
Annotation	Unknow
Peak:m/z	Relative Intensity
162.8433533	0.44
178.4118652	0.14
180.2305450	0.29
180.9417419	0.44
199.0637817	0.05
223.0934448	0.20
235.0701599	0.10
240.9151764	0.18
246.7982788	0.05
252.1265717	0.54
253.1769104	0.28
258.6931458	0.26
259.3288574	0.06
265.1212769	0.11
270.9321899	6.20
276.9591064	0.12
285.3394165	0.09
286.7145996	0.04
287.7235107	0.47
288.8166504	8.37
296.8630371	0.05
301.4053345	0.26
306.2788086	3.20
306.9131470	5.80
320.8427124	0.03
322.3828125	0.07
324.8241577	100.00
325.6058960	0.15
335.3947754	0.26
338.0659180	0.33
338.7391968	0.32
340.6026001	0.72
342.2543335	22.43
342.9366455	68.92
349.2613525	0.20
381.0549927	0.03
414.0648193	0.10
415.1072998	0.05
421.0012207	0.24
432.0653687	10.08
432.9425049	0.87
433.5502930	0.26
437.6870117	0.05
438.6862183	0.21
439.5300903	0.09
450.9302979	1.02
451.5613403	0.09
468.7386475	0.62
486.5626221	1.65
487.1777954	1.41
503.2814331	0.07
504.0717773	0.93
504.7299194	1.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	581.2083
Annotation	Unknow
Peak:m/z	Relative Intensity
179.1827087	0.15
183.3531494	0.12
202.0817261	0.05
213.3933868	0.12
214.1925659	0.05
220.8802338	0.09
226.8522949	0.12
238.9635620	0.07
256.5119324	0.12
257.2072144	0.28
269.2788696	0.05
272.2104187	0.18
291.3091431	0.23
323.1429443	26.45
329.1270142	0.33
331.9263916	0.10
335.3724976	0.02
338.9663696	0.17
341.3997803	0.33
359.2835693	0.07
360.9251099	0.11
375.3482666	0.03
393.5236206	0.05
397.6000366	0.30
401.5143433	0.04
403.4223633	0.32
411.2158203	0.14
417.3110962	0.04
419.2919312	1.63
424.4541626	0.11
429.0705566	0.31
437.2029419	0.38
439.4073486	0.10
455.1095581	0.05
481.0292969	0.14
485.2673950	0.03
497.2116089	0.03
501.0401611	0.05
519.5527954	0.25
535.0415039	100.00
535.7500610	0.16
536.5488892	0.15
537.2069702	0.25
538.1329956	0.09
543.3140259	21.79
544.3532104	7.25
545.3643799	5.15
550.4607544	0.04
551.9501343	0.06
553.4657593	0.41
562.0668335	0.07
563.2732544	2.01
566.4179077	0.07
581.2204590	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	349.1655
Annotation	Ambuic acid
Peak:m/z	Relative Intensity
147.0342712	0.11
148.5880127	0.10
171.1496887	0.06
178.2012634	0.02
183.2788849	0.02
194.9526825	0.02
197.2366028	0.01
201.0890350	0.10
211.1460114	0.05
213.0454407	0.09
221.2410889	0.03
231.3142700	0.01
233.3919983	0.05
236.1347351	0.05
241.1596680	0.06
243.1711121	15.39
245.3088684	1.72
252.1681824	0.03
253.5933838	0.04
255.4180908	0.24
261.4147949	0.14
269.1990356	0.07
273.3415833	0.03
275.2602844	0.09
277.4223633	0.09
281.0727844	0.05
285.3799133	0.19
287.2341309	10.63
290.2207031	0.02
297.1922302	0.03
303.2246094	0.17
305.3369141	1.41
310.9257202	0.06
313.2651367	0.72
314.2418213	0.11
315.0240784	0.10
317.1490479	0.02
318.1906738	0.04
319.2526550	0.87
329.4002686	0.04
331.2027893	100.00
332.2908020	0.17
333.2239990	0.13
334.2872925	0.03
350.3144226	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.15
Annotation	Unknow
Peak:m/z	Relative Intensity
160.9813232	0.08
170.9661102	0.09
173.8792419	0.05
175.1774597	0.20
179.0977478	0.03
192.9896698	0.03
199.0394897	0.14
207.2416382	0.15
211.1258240	0.77
231.0620422	0.54
249.0909271	5.09
267.1065063	8.16
269.1054688	0.14
289.2551880	0.20
298.9055481	0.06
311.2008667	0.49
325.0321655	0.46
329.0921021	0.08
330.2013550	0.05
351.1903076	0.20
365.3476562	0.05
369.1849976	9.05
379.8743286	0.11
383.1904907	0.06
384.2575684	0.04
387.2213745	100.00
388.1481934	0.13
402.0906372	0.06
411.1912231	0.14
416.5222168	0.06
429.1308594	2.50
439.3511353	0.03
441.3902588	0.08
451.1744385	1.18
458.4226074	0.14
459.3970337	0.08
465.0053711	0.07
495.3466797	0.38
503.2344971	6.13
530.2449951	0.17
531.2026978	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	541.14
Annotation	Resveratrol 4'-(6-galloylglucoside)
Peak:m/z	Relative Intensity
178.9716339	1.93
180.0286865	0.07
181.0907135	0.02
216.2934113	0.02
221.1668243	0.58
222.9053040	0.03
232.9400635	0.07
250.6700745	0.38
281.1038208	0.16
305.3085327	0.12
311.3000488	0.02
323.1046753	0.33
340.9855957	1.36
342.6932373	0.20
343.5298462	0.11
361.1632080	0.18
377.0482788	0.48
378.5261841	0.76
379.2105713	11.37
503.2752686	100.00
505.2292480	17.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	642.2761
Annotation	Unknow
Peak:m/z	Relative Intensity
211.1175232	0.34
235.4492493	0.15
241.3339539	0.14
243.4292450	0.08
249.2051392	0.11
299.0750732	0.41
311.1798096	0.08
327.1582947	0.04
329.4007263	0.69
344.9664307	0.11
346.3500977	0.19
349.0969849	0.11
363.0709229	0.08
380.9969482	0.10
383.3569336	0.12
390.2734375	0.16
391.3538818	0.15
400.3493042	0.38
415.3185425	0.35
416.3676147	0.05
433.8699341	0.17
434.9758911	0.76
440.8076782	0.07
445.0189819	0.06
453.2223511	0.18
457.2350464	0.13
463.4672241	0.21
465.6871338	0.15
466.9536133	0.08
475.9983521	0.10
481.3596802	0.13
483.0712280	0.34
485.1382446	0.15
501.1239624	0.29
507.1555176	0.07
509.4754028	0.13
511.4492798	0.09
523.3160400	0.17
527.3029175	1.43
529.3880615	3.20
534.3041382	0.41
535.3231201	2.48
538.3903198	0.13
552.3147583	1.05
553.4430542	11.75
558.9762573	0.08
564.4613647	0.40
567.1276245	13.07
567.7658081	0.23
569.2216187	0.26
579.0228882	0.12
579.8558960	0.37
584.8235474	0.13
585.6619263	0.26
594.0511475	0.54
595.1312866	0.55
597.0960083	100.00
597.8377075	0.16
598.5947266	0.62
599.4041138	0.68
605.1430054	0.69
606.6961060	0.52
607.3447876	0.32
614.8466797	0.30
625.1632690	0.30
626.5111084	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	663.1985
Annotation	Unknow
Peak:m/z	Relative Intensity
210.8540649	0.06
217.0555878	1.56
232.7548523	0.05
258.6847534	0.28
259.3224487	0.08
281.0955811	0.08
303.0297852	38.44
303.6727905	0.08
321.1104736	100.00
329.4778442	0.07
330.3826294	0.16
334.6884766	0.04
341.4488525	0.05
358.2764893	0.07
380.0434570	0.17
390.1840820	0.05
411.1271362	0.10
413.3909912	0.05
469.5164795	0.11
482.0877075	0.10
483.1963501	0.06
485.0683594	0.08
486.1177979	0.10
489.0192261	0.19
493.0789795	0.09
499.8095093	0.07
500.4465332	0.16
501.2843628	0.03
503.0292969	0.16
516.1489868	0.05
517.2302856	0.05
530.0040283	0.05
533.5859985	0.11
534.4048462	0.08
538.2197266	0.02
543.4411621	0.09
545.9721069	0.15
565.0671997	0.32
568.2743530	0.11
569.4025269	0.06
572.8463745	0.21
587.3704224	0.32
588.2002563	0.05
603.4728394	0.07
644.1958618	0.19
645.3778687	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.2133
Annotation	Abelioside A
Peak:m/z	Relative Intensity
196.0234222	0.02
215.1684875	0.06
225.2196198	0.06
229.5694733	0.02
239.1487427	0.18
253.3005676	0.54
269.2353516	0.24
270.3333130	0.02
271.2402954	2.04
285.2536011	0.13
287.2678833	0.05
288.1551514	0.08
289.2688904	0.93
297.3711548	0.16
301.3441772	0.77
303.1708374	0.07
313.3049316	0.25
315.2799072	4.68
329.3280029	2.70
331.1372070	0.10
333.2190552	12.59
333.8525391	0.02
341.0993042	0.17
343.3234253	0.15
347.2929077	1.95
355.1489258	0.03
357.1906738	0.07
359.2075195	100.00
360.2541504	0.21
368.9461060	0.03
373.2024536	19.79
375.2886963	6.52
377.1911011	1.71
391.2763062	0.04
401.1911621	5.56
402.1358032	0.03
413.5631104	0.12
415.2415161	0.13
419.3421021	6.79
431.3107910	0.28
433.0885010	0.05
443.2690430	0.25
449.2975464	0.55
451.4581909	0.19
461.0883179	0.29
464.4567871	0.18
467.0742798	0.04
470.2802124	0.09
478.2669067	0.13
479.2462769	3.45
495.3827515	0.76
509.2523193	0.03
521.2700806	0.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	612.3
Annotation	Unknow
Peak:m/z	Relative Intensity
193.1763916	0.01
197.0274200	0.01
213.1397400	0.03
220.0938721	0.02
227.1048889	0.04
234.3951263	0.02
235.1440582	0.04
237.1204834	0.01
239.2778931	0.03
248.1378326	0.04
251.1264038	0.02
255.2538147	0.07
260.1912537	0.01
262.1752014	0.13
272.8636475	0.04
273.5762329	0.03
283.1033325	0.05
287.1464233	0.01
298.4421997	0.03
301.4505920	0.02
314.4426270	0.02
318.3097229	0.02
319.4605713	0.02
326.3196411	0.04
328.9962158	0.01
353.9532471	0.02
368.4091797	0.05
370.1445923	0.10
386.3695068	0.06
388.2808228	0.15
402.3508301	0.03
404.3491211	0.02
406.3330688	0.03
414.2762451	0.78
415.4583130	0.01
416.3521118	0.25
417.4364624	0.07
426.1547241	0.01
432.3448486	5.39
433.4438477	0.03
437.2164917	0.02
450.3161011	100.00
451.3653564	0.16
474.1131592	0.02
492.6412354	0.10
493.4874268	0.02
510.4603882	0.04
535.4292603	0.01
537.7587891	0.02
550.6410522	0.01
553.3505249	0.02
564.3462524	0.02
566.0442505	0.06
566.6817017	0.00
568.3073730	0.02
594.4162598	1.86
595.4770508	0.12
604.4430542	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	560.27
Annotation	Unknow
Peak:m/z	Relative Intensity
161.1655426	0.04
162.7116089	0.42
164.0143127	0.05
179.1782837	0.08
180.1527252	0.10
181.0751343	0.23
334.4360962	0.05
350.3102417	0.06
351.1239624	0.07
352.3486938	0.89
396.1105957	0.05
410.3843994	0.08
471.2488403	0.60
489.4297485	0.07
498.1784058	0.06
511.2709351	0.26
512.2574463	12.57
513.4204712	14.28
514.3275146	100.00
517.2333984	0.06
536.9628906	0.22
543.1569214	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.1672
Annotation	Unknow
Peak:m/z	Relative Intensity
158.8246307	0.08
174.1981201	0.17
188.9813385	0.99
207.0062256	100.00
237.3371582	0.03
267.3676758	0.09
323.2408447	0.16
503.2547607	14.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	472.2349
Annotation	Unknow
Peak:m/z	Relative Intensity
142.9855804	0.06
145.0208130	0.07
155.0087585	0.12
158.2235107	0.04
173.0091248	0.11
174.1036072	0.07
177.0341492	0.08
185.0554047	0.09
197.2554321	0.04
199.2603455	0.11
215.3595886	0.07
225.1756897	0.11
241.1487427	1.49
242.9825745	0.37
251.2570496	0.57
253.2164001	0.38
259.1036377	0.57
265.0832825	0.05
266.4298706	0.03
269.2252197	1.11
270.8792114	0.27
285.3827515	0.33
287.2431946	3.00
288.1072083	0.04
289.4328918	0.14
291.1228027	0.39
293.1973877	0.03
297.0911255	0.72
301.0882263	0.20
303.1633301	1.27
305.3100281	0.52
309.9538269	0.12
315.2553711	1.90
318.7086182	0.11
319.3395386	1.55
321.1192932	0.87
329.2800293	0.25
331.2540283	0.05
333.2661743	2.40
337.2525330	0.23
338.0833740	0.12
342.1451721	0.05
343.9758301	0.03
347.2384949	1.75
349.2880554	0.59
351.0112305	0.11
355.3040771	0.11
360.1053772	0.07
362.2313232	0.42
363.2337036	0.05
365.2247314	5.45
365.9801636	0.09
372.4760132	0.29
373.2489014	0.03
375.0264893	1.73
375.7295532	0.06
380.2796631	3.15
381.8971252	0.20
383.3153687	0.25
384.2962341	0.15
385.0568848	0.09
390.3220825	2.59
391.2109680	1.01
392.3069153	0.91
393.1636963	0.45
395.2633057	0.10
400.3989868	0.20
408.2518616	14.99
409.3812256	0.26
411.0591736	0.08
418.2677307	2.04
419.3474121	0.27
424.2397766	0.08
426.2731018	3.12
436.2391052	29.32
437.1090698	4.87
437.7793884	0.06
442.5597534	0.05
449.2661438	0.09
454.2105713	100.00
455.1665344	27.10
455.8367310	0.05
463.3464966	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	737.3232
Annotation	Unknow
Peak:m/z	Relative Intensity
295.2310791	0.14
303.2464600	0.17
305.2043152	0.03
327.2270203	0.11
337.3956299	0.11
349.2379761	0.31
354.9373474	0.03
377.3262329	0.17
379.5015259	0.09
381.3264771	0.15
383.2485352	0.17
385.0614014	0.36
413.3191528	0.09
417.5673828	0.07
423.0427856	0.06
438.9171753	0.07
441.2180176	0.20
442.3804932	0.03
447.4373169	0.13
448.9743652	0.15
450.1477661	0.07
457.0956421	0.03
466.1076660	0.06
477.4089966	0.03
481.5067139	0.11
493.3255615	0.08
510.3344116	0.10
527.5056152	0.25
528.4964600	0.14
529.5095825	0.19
531.3304443	0.03
543.3298340	0.17
545.5091553	0.08
559.5038452	0.05
565.4680176	0.04
572.9378052	0.13
575.5140991	0.51
585.1863403	0.09
593.1924438	0.04
616.3623047	0.03
622.3464966	0.08
630.8948364	0.03
640.2794800	0.22
644.1508179	0.15
645.4212036	0.07
647.1242065	0.21
651.2256470	0.14
657.1883545	0.11
661.2967529	0.06
675.4931030	0.13
678.4016724	0.06
691.4199219	100.00
693.6566772	0.23
705.9412842	0.15
719.3493652	0.44
737.2879028	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.16
Annotation	Unknow
Peak:m/z	Relative Intensity
142.9243164	0.04
146.8366394	0.09
149.0532990	100.00
175.2097321	0.55
179.1467590	2.33
180.9528503	0.21
191.3257141	0.53
192.2167969	0.19
193.0559998	0.16
206.9386597	0.22
209.1619873	0.73
241.9676514	0.13
243.1229858	0.07
251.1081696	0.12
271.9933472	0.17
280.3530884	0.41
281.1968079	0.55
299.2894592	0.53
303.3358459	0.17
311.1334839	0.25
329.1491089	1.00
341.1053162	0.40
342.4522095	0.52
346.3749695	0.31
359.2469482	0.39
365.0157471	0.29
387.3138733	0.32
398.9207153	0.35
417.0668030	0.75
425.3835754	0.25
445.0614014	0.38
445.8977966	0.40
461.0333862	0.28
473.2821655	0.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	270.154
Annotation	2,3-Butanediol glucoside
Peak:m/z	Relative Intensity
87.5743713	0.09
112.1779785	0.19
128.0198822	0.04
140.2156830	0.13
149.3679047	0.03
153.2849731	0.07
157.2915192	0.03
158.2505035	0.02
163.0783234	0.31
168.0735626	0.04
169.1360931	0.16
171.0233002	0.09
181.0433197	0.08
203.1842804	0.08
210.1636810	0.09
212.1918182	0.03
217.1413727	0.07
224.0430756	0.37
225.3883362	0.06
227.0729065	0.09
228.5023193	0.03
229.2231293	0.06
234.3003540	0.03
239.0958405	0.02
242.2586670	0.06
252.4978790	17.64
253.0987549	100.00
260.5479431	0.16
261.6792603	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	607.1145
Annotation	Unknow
Peak:m/z	Relative Intensity
188.0291290	0.20
227.2060089	0.03
255.9768982	0.38
261.2621765	0.15
277.0150146	0.79
288.8916626	0.19
303.1966858	0.23
305.8772583	0.04
307.1246948	1.20
315.4291992	0.31
321.2894897	0.18
323.0720825	0.06
323.8415527	0.22
325.0856628	1.16
332.6196289	0.05
335.1503296	0.03
336.9459839	0.61
339.2023926	0.05
342.0964966	0.04
346.2731934	0.04
347.8538818	0.09
353.0114746	0.23
354.0735474	0.29
354.7333374	0.07
364.5347900	0.05
366.8974609	4.48
367.5014648	0.01
377.2737427	0.05
379.1374512	0.10
384.9192505	0.39
391.2551270	0.29
395.1039429	0.07
397.0103149	12.69
398.0427856	0.06
401.0639038	0.08
405.0640259	0.23
407.6101074	0.23
409.0402832	2.26
412.1915283	0.19
415.3557129	0.07
418.0515137	0.40
425.0215454	0.07
426.2755737	0.91
427.0353394	12.70
435.8863525	2.45
438.1883545	0.15
444.7519531	1.72
445.4453125	0.08
451.0950317	0.14
461.0491943	0.14
468.9696655	0.43
483.2420654	0.21
488.9399414	0.05
492.9228516	1.94
499.3458862	0.24
501.9887695	1.90
502.6129761	0.16
505.3117676	0.28
517.1008911	0.24
520.2507935	0.11
525.7151489	0.05
528.7195435	0.41
556.6983643	0.14
560.8191528	0.28
570.9650879	0.16
574.8667603	0.07
587.2290649	0.43
588.9114990	100.00
589.6342163	1.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	199.99
Annotation	Unknow
Peak:m/z	Relative Intensity
69.1158524	0.17
69.9348068	0.26
71.9604034	0.23
72.8457184	0.07
74.1331329	0.08
75.1272201	0.15
78.8786697	0.04
80.0327225	0.02
80.9181061	0.11
81.9087067	0.30
82.9029388	0.06
83.9609375	0.22
85.0368042	0.06
86.2509308	0.03
87.2114945	0.11
88.0220489	0.01
90.5268860	0.04
92.7977142	0.06
95.8272400	0.17
96.9165649	0.18
97.9275971	0.21
101.1146393	0.05
101.9962921	0.07
106.9348755	0.05
108.1870575	0.22
109.3644867	0.12
110.0005035	0.12
111.1534576	0.20
112.0362701	0.04
114.8911438	0.02
115.8636475	0.02
118.0194092	0.10
120.0120392	0.06
122.1354675	0.10
125.1349182	0.09
126.1270447	0.04
128.9854431	0.12
140.1176758	0.21
140.8267365	0.03
142.3661346	0.52
143.1592407	0.03
154.0926514	0.60
155.9258881	0.06
158.9353180	100.00
159.7315216	0.06
160.7509613	0.02
163.4387665	0.14
164.2170715	0.65
168.8825226	0.25
171.3844299	0.03
172.9141693	0.09
176.7264557	0.94
179.4636993	0.75
182.0202484	1.55
183.1527252	0.97
184.4174347	0.33
185.9238739	0.21
186.6855621	0.47
188.0077820	0.27
191.2697906	2.25
194.0561523	0.12
199.4922028	0.15
201.0100098	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	527.2476
Annotation	Agnucastoside B
Peak:m/z	Relative Intensity
150.7549896	0.22
153.0374603	0.11
155.0648956	0.19
157.2037659	0.09
163.1057434	0.07
165.0571899	0.04
170.5459442	0.14
184.2687378	0.07
191.0128937	0.29
197.0415497	0.08
210.9400940	0.04
214.9980774	0.09
225.2041473	0.10
226.8056946	0.14
237.0885315	0.21
239.2261200	0.86
241.1887817	0.09
243.0882568	0.22
245.3358154	0.13
247.5097961	0.08
255.1563416	0.65
257.2055664	0.04
261.0712891	0.24
265.2415771	1.01
273.3282471	0.16
283.0332031	1.29
285.2070007	0.15
293.2164917	0.12
294.0166626	0.19
299.0249023	0.12
301.2097778	12.63
302.1649170	0.30
311.1513062	2.91
313.3787842	0.14
317.4016113	0.12
319.0933838	2.32
319.7655640	0.02
329.1925659	10.75
331.3363037	0.11
336.6099854	0.27
337.2290649	0.23
347.0787964	100.00
347.7682495	0.19
353.3679199	0.04
365.1777954	7.02
375.1115723	0.06
387.0614624	0.27
389.1614380	0.08
391.0816040	0.19
406.3930054	0.09
407.4257202	0.18
411.3137207	0.07
413.2424316	0.07
414.2092285	0.07
424.1144409	0.16
425.2720947	0.11
431.1128540	0.91
443.5686035	0.04
445.6268311	0.24
449.3193359	0.33
455.0714722	0.22
473.1016235	0.69
481.2131958	1.41
491.3058472	1.11
492.0464478	0.05
509.1441040	19.38
515.4371948	0.05
518.2673950	0.11
526.9265747	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	397.1867
Annotation	Lushanrubescensin G
Peak:m/z	Relative Intensity
116.8866501	0.10
123.0558014	0.05
135.0962677	0.27
136.1002960	0.02
137.0839233	0.10
139.0064697	0.01
143.1030884	0.03
151.0858154	0.02
163.0998993	0.03
172.9886932	0.08
178.9384766	0.05
187.0403137	0.01
189.0706787	0.12
191.2452850	0.14
201.1034546	0.01
215.2095337	0.09
217.1699066	0.40
227.3122559	0.02
229.1657104	0.05
231.0140686	0.19
233.1339417	0.69
235.0715332	1.61
235.6934509	0.02
243.2940369	0.80
245.3185730	0.13
247.2102966	0.20
249.2242737	0.38
251.2327576	0.05
252.9983826	0.05
255.2144775	0.23
257.3302917	0.13
259.1522522	0.05
261.1774597	1.11
262.1717834	0.06
263.2485352	0.08
265.3060913	0.04
267.2829590	0.07
271.4436646	0.08
273.3381042	1.08
275.4077148	0.13
277.1574707	0.02
279.1797485	1.39
279.9249268	0.01
282.2581177	0.02
287.1465454	0.02
289.2998657	0.26
289.9770813	0.08
291.2190247	1.15
292.6313477	0.05
293.3358459	0.92
298.9852295	0.02
301.2754517	0.20
303.2637634	0.02
305.3198242	0.38
307.3289795	0.52
308.3941650	0.05
309.3351746	1.08
310.4414673	0.19
315.4952393	0.06
317.3543701	0.53
319.1696472	0.35
320.4470825	0.05
323.4131470	0.98
325.3441467	0.26
329.1708069	0.02
331.3463745	0.02
333.1265869	0.20
333.9407349	0.05
335.2077942	7.96
337.0195312	0.73
349.2933960	0.51
351.1950378	0.80
351.9124756	0.39
353.2453308	100.00
354.2974854	1.67
361.2087402	1.62
367.3232727	1.18
379.2846375	2.35
380.5176697	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	381.1554
Annotation	7alpha,8alpha-Dihydroxycalonectrin
Peak:m/z	Relative Intensity
108.5690842	0.01
114.9656067	0.02
116.9381180	0.04
123.0025330	0.02
124.8758087	0.02
126.9019012	0.03
130.8458099	0.01
139.2397766	0.02
141.1136475	0.02
142.0002594	0.02
143.7351837	0.05
145.1365356	0.13
149.0805054	0.08
153.3113251	0.05
161.0842285	0.03
163.1301575	0.03
175.1727295	0.05
179.2433472	0.07
187.0912933	0.08
189.0423279	0.67
191.2107849	0.01
193.2391052	0.18
197.1631622	0.01
199.2730713	0.11
201.1459656	0.27
203.1527710	0.36
207.2338867	0.05
209.1412354	0.11
213.2194519	0.03
215.1619263	0.40
217.1817932	0.41
219.1667786	0.40
220.2868042	0.14
221.3428650	0.04
227.1982117	0.19
229.2614441	0.32
231.3215027	0.15
233.2315979	0.23
235.3300476	0.04
237.1391602	1.05
239.1177673	0.20
240.4279175	0.07
243.2087097	0.08
245.1854553	0.57
246.0648499	0.01
247.2278748	0.68
249.2009888	0.22
255.2197876	0.03
257.2634583	1.66
258.2502136	0.07
259.2113037	0.03
261.3815308	0.14
263.1644897	0.91
265.1285400	0.32
267.2178955	0.20
271.2312012	0.03
273.3225403	1.12
275.2792664	11.34
276.2316284	0.28
277.4439697	0.14
279.3134155	0.17
283.0044861	0.43
291.1867065	2.29
293.2438965	7.71
294.0553589	0.04
295.0224609	0.15
301.2011108	2.76
302.1834412	0.01
307.2100220	0.03
317.3275757	0.06
319.2497864	11.70
320.4403076	0.29
321.3778992	0.04
335.1448364	1.07
337.2488708	100.00
338.3110352	1.96
341.0231934	0.06
343.2355957	0.02
345.2990112	0.11
349.0135803	0.05
350.9038391	0.03
363.1558533	3.64
364.1065979	0.11
364.7734680	0.02
382.8418579	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	719.3129
Annotation	Unknow
Peak:m/z	Relative Intensity
273.0707397	0.04
353.2380981	0.13
369.6276855	0.12
450.5692139	0.03
493.4443359	0.05
505.1109009	0.02
511.3626709	0.13
513.3068848	0.04
521.6956787	0.06
539.6108398	0.15
548.2429199	0.02
551.3659058	0.05
558.3175659	0.09
571.5972900	0.04
597.8190308	0.02
599.6649780	0.05
605.2781372	0.02
620.5267334	0.06
623.2890015	0.07
626.9490356	0.12
629.2443237	0.09
633.2282715	0.07
645.4721680	0.43
647.2031250	0.07
655.3527222	0.52
656.3234863	0.07
657.0913696	0.06
659.6577148	0.04
661.3308716	0.05
670.8728027	0.20
673.3175659	100.00
673.9343872	0.56
675.2152710	0.33
686.4618530	0.20
699.2773438	0.10
699.9865112	0.11
701.1626587	0.39
701.9891357	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	612.64
Annotation	Unknow
Peak:m/z	Relative Intensity
170.9543304	0.06
184.2426147	0.12
189.2971191	0.14
193.7452850	0.19
202.0566711	0.09
204.9913177	0.19
212.7619629	0.21
219.0701904	0.77
251.3688965	0.21
257.0473633	0.06
258.2785034	0.04
268.3258057	0.27
273.1782227	0.06
299.2452393	0.41
305.1021118	0.15
306.3654175	0.27
308.7482910	0.25
323.6649170	0.06
331.4312744	0.19
333.3638916	0.06
336.1437988	0.30
339.5099487	0.07
347.3499146	0.09
348.1763306	0.04
350.1577759	0.23
356.2400513	0.04
360.3886719	0.11
365.1043701	0.07
366.3060913	0.25
372.3150024	0.08
376.2993774	0.25
381.0315552	0.14
383.3018188	0.17
386.1613770	0.90
387.8727417	2.42
388.5477295	1.06
389.4749756	0.20
390.1869507	0.21
396.1669312	0.48
397.3677979	1.10
400.1914062	0.68
402.2811890	0.18
404.3671875	0.71
405.0250854	0.39
406.2125244	1.05
408.2029419	0.13
409.0993042	0.47
414.1262207	0.77
415.4907227	0.10
416.5929565	1.26
419.3148804	0.19
421.6947632	0.66
429.0982056	0.04
432.3084717	9.88
433.3157349	0.87
436.1825562	0.22
437.0097046	0.07
438.2038574	0.12
439.1226196	0.19
440.4658203	0.37
446.4191284	0.18
448.3452759	0.25
450.2968140	100.00
451.3449097	13.82
453.4114380	0.10
462.5369873	0.16
463.8980103	0.46
467.2028809	0.11
469.1322632	0.45
472.5017700	0.26
478.4706421	0.17
479.4607544	0.26
491.1059570	0.74
492.3561401	0.05
507.0373535	0.05
511.1625366	0.12
516.0652466	0.22
532.3093262	0.11
535.3119507	0.35
537.5598755	0.05
539.2870483	0.22
543.4120483	0.42
549.5241089	0.17
550.5713501	0.58
551.8466797	0.35
553.3430786	0.23
560.6444702	0.35
566.2702637	1.41
567.2122803	0.18
568.2791748	0.79
572.7721558	0.53
576.2636719	2.37
577.3775024	0.13
578.2525024	0.09
579.1793823	0.08
583.4642944	0.16
594.1981812	13.17
595.3483887	1.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.21
Annotation	Zizybeoside II
Peak:m/z	Relative Intensity
179.1822205	0.49
205.0941620	0.18
223.2465515	0.37
249.1612549	0.26
251.2436523	0.23
265.0736694	0.04
267.0493164	0.08
269.1105652	2.14
283.2960815	0.19
287.3320923	0.10
293.0356750	0.08
301.1188965	0.18
302.8828735	0.08
323.2031250	0.13
339.0810547	0.07
341.2301025	0.45
342.2134399	0.19
345.0694580	0.17
349.0645142	0.09
357.3646851	0.33
365.3695679	0.18
369.0146484	0.17
369.9450073	0.08
371.1369019	0.48
379.2823486	0.11
384.0803223	0.27
385.4291382	0.77
388.1305542	0.19
389.0765991	0.20
395.2445068	0.07
413.3510742	0.66
429.2805176	0.49
430.1732788	1.08
431.2408447	0.87
433.3991089	0.11
439.3192139	0.17
443.3626099	0.42
449.0519409	0.18
457.2177734	0.12
473.2886353	0.43
483.1243896	0.10
488.8765869	0.30
491.7578125	0.07
497.2100220	0.58
499.6108398	0.08
507.2096558	1.24
525.3796997	0.10
531.8518066	0.22
533.2770386	0.06
547.2630005	100.00
548.6544189	0.55
549.3427734	0.36
574.2902222	0.10
575.2222290	2.06
579.1044312	0.25
583.8430786	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0984
Annotation	3-Methoxy-4-hydroxyphenylglycol glucuronide
Peak:m/z	Relative Intensity
128.1699524	0.02
135.9927979	0.03
138.0002747	0.37
149.2598877	0.02
151.1195374	0.03
153.1146851	0.58
160.9757538	0.03
161.8035583	0.03
166.9696198	0.04
172.0367737	0.02
173.3429871	0.10
178.9436340	0.24
182.0590820	4.85
197.0161438	100.00
197.8522034	0.09
199.1448822	0.02
207.0845642	0.04
208.9547729	0.03
211.1818542	0.02
227.8535767	0.03
230.3159790	0.02
239.1761169	0.90
244.1796265	0.03
247.3079529	0.03
249.0717773	0.05
251.1256714	0.01
256.6640015	0.08
269.3307190	0.09
271.0730591	0.06
312.9806213	0.77
315.0061035	0.16
323.3308411	0.18
327.0287170	0.02
329.3009949	0.09
331.4556580	0.05
339.3205566	0.01
341.0601196	0.44
344.2306213	0.09
345.1455383	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	606.1065
Annotation	Unknow
Peak:m/z	Relative Intensity
182.0970459	0.17
192.3675232	0.05
198.8130493	0.19
216.3254395	0.08
231.1318665	0.20
245.0597992	0.06
256.0053101	0.54
264.1585693	0.32
274.1510010	0.19
277.0560303	1.35
279.2730103	0.18
281.2188110	0.06
285.8848877	0.25
288.7413940	0.04
301.9379578	0.18
307.0650024	1.70
321.5054321	0.06
323.9679565	0.38
325.1347046	0.54
336.7593994	1.45
340.9591064	0.03
342.6531982	0.29
344.4032593	0.12
352.0913086	0.36
353.9818726	0.12
354.9368286	1.10
367.0028687	5.58
374.2224121	0.13
379.1813965	0.43
384.8589478	0.17
396.9488525	12.60
398.9899292	0.15
401.1723633	0.09
409.1641846	3.27
412.1215820	0.36
415.0008545	0.23
416.8011475	0.14
420.5950928	0.03
427.0155640	11.83
435.0317993	0.32
436.0510254	1.11
437.9290771	0.04
444.1724854	0.34
445.1035156	1.76
460.9249878	0.10
469.0762939	0.30
473.9292603	0.30
480.8980713	0.09
491.4034424	0.14
493.0278931	1.67
499.0407104	0.41
502.1251221	1.56
502.7405396	0.28
505.1023560	0.21
515.0795288	0.24
516.0396118	0.08
517.0710449	0.20
527.4921265	0.08
529.0563354	0.36
544.8331909	0.22
547.2099609	0.13
557.3919067	0.17
561.0054932	0.22
571.1773071	0.21
588.9907837	100.00
590.1289673	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.1978
Annotation	Abelioside A
Peak:m/z	Relative Intensity
160.6971283	0.04
165.1181030	0.08
177.2113037	0.04
178.7690582	0.10
187.0105896	0.03
191.1402893	0.04
201.1127930	0.02
217.1611176	0.05
221.2551270	0.03
229.3330078	0.15
237.1304932	0.08
239.0919189	0.12
241.3114166	0.07
245.4100494	0.07
253.2588348	0.07
257.1736450	0.73
262.6122437	0.08
273.2492065	1.79
274.6445312	0.02
275.2746582	0.09
283.2048340	0.31
299.5167847	0.04
301.2556152	3.94
303.5465698	0.01
315.2303467	0.02
317.3706665	0.27
319.3312988	1.80
327.4133301	0.03
343.1658325	0.05
345.1182251	3.87
361.2476807	0.01
363.1999512	100.00
365.4648438	0.05
377.4196777	0.01
397.3677979	0.03
405.1680298	25.69
417.2166138	0.35
419.2139893	0.03
427.4503784	0.08
429.0979004	0.04
433.2936401	0.09
434.0993042	0.04
435.2357178	2.78
446.5383911	0.06
447.2028809	0.06
463.2774658	0.10
465.2873535	15.04
467.3522339	0.07
479.1915894	0.06
481.3743896	0.54
482.3203125	0.17
495.2236328	0.06
507.2803345	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	423.1872
Annotation	Unknow
Peak:m/z	Relative Intensity
125.0762329	0.04
143.0900879	0.01
169.0222778	0.03
181.3159790	0.10
187.0089111	1.07
195.0493011	0.10
199.1796112	0.58
201.1685791	1.23
209.2289429	0.03
225.2184296	0.20
229.0188599	0.03
231.2168427	0.02
241.2955017	0.02
243.2043762	1.81
247.3667908	0.09
249.2127380	0.06
261.1074524	100.00
267.3888245	0.07
268.2322388	0.03
269.1356812	0.08
272.9617004	0.17
285.5255127	0.07
287.3843689	0.01
292.2061157	0.01
297.0252991	0.02
303.2196045	1.53
304.1710205	0.01
305.0676880	0.08
313.1292725	0.12
315.1946716	0.08
316.8999329	0.03
325.1857605	0.12
327.4919128	0.09
331.2636414	0.03
332.9847717	0.81
334.8103027	0.10
345.2998047	0.03
349.1694031	0.04
363.2210693	2.01
364.4794312	0.04
369.2162781	0.09
375.1207275	0.04
377.1978455	1.02
378.1147766	0.02
379.2122498	0.30
380.3485413	0.07
384.9888000	0.04
387.2882080	0.65
393.0979919	0.09
404.1877441	0.01
405.2542419	0.93
408.5219727	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	637.23
Annotation	Unknow
Peak:m/z	Relative Intensity
195.0730133	0.32
211.1234131	0.77
223.1315613	0.32
229.3004913	0.23
241.1414337	0.57
247.4056244	0.33
259.0158997	0.79
271.0983887	5.65
288.4112244	5.44
289.1748962	1.71
295.0871277	15.36
304.2360840	0.36
306.7444763	8.82
324.8516541	100.00
325.6012268	0.49
341.6798706	4.30
342.8397827	63.19
343.5298462	0.98
395.2672119	0.22
433.0285034	1.49
439.3333740	1.00
450.8717041	2.23
457.1414795	1.28
474.9425659	62.49
486.7409058	6.80
504.6269531	2.33
619.1145020	0.61
620.2324829	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.133
Annotation	Ciprofloxacin
Peak:m/z	Relative Intensity
106.1343536	0.02
107.9212646	2.89
109.0348816	0.03
123.0007629	0.06
124.0513763	0.21
126.854248	0.04
134.0006866	0.50
136.0041504	1.60
137.1522217	0.05
138.0230713	0.03
145.0654907	0.03
152.0030518	6.27
154.1290283	0.16
162.2617188	0.01
170.082901	7.78
194.0785522	0.01
199.9565125	0.03
210.817688	0.05
212.1972351	0.01
232.0740356	0.01
250.0724792	0.14
251.0400391	0.05
256.28125	0.03
262.43927	0.04
268.3875427	0.01
278.0938721	0.03
285.2915649	0.04
286.3343811	0.03
296.1987915	0.27
298.0694885	0.02
314.1262512	100.00
314.9253235	0.01
337.29245	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	472.1585
Annotation	Folinic acid
Peak:m/z	Relative Intensity
143.2195587	0.08
147.9800110	0.09
151.8682098	0.24
162.9728699	0.38
164.0058594	0.41
171.7396851	0.12
193.1355591	0.03
197.0568542	0.05
198.1232605	0.03
217.1103210	0.26
232.0086365	0.15
232.7051392	0.05
234.0926056	0.16
234.9951630	0.22
235.8969574	0.22
254.1807556	0.24
258.1834412	0.23
265.4052124	0.14
266.1696777	0.23
273.2687683	0.06
274.6955566	0.41
275.4053650	0.05
277.0282898	0.23
289.5497742	0.09
292.0642700	0.32
296.1898193	0.04
297.3269958	0.06
300.2033691	48.94
308.1103821	0.08
310.0068970	0.18
323.4908142	0.16
324.7864075	0.14
325.9981689	0.23
327.8590698	0.03
343.0914612	24.08
351.8666992	0.06
353.1505127	0.03
360.2066345	0.45
363.4284668	0.03
366.0651245	0.24
367.3499451	1.11
369.2763062	0.12
376.0271301	0.35
377.1722717	0.12
383.2532959	0.11
385.2388611	7.19
386.0865784	1.39
387.4460144	0.20
398.2289124	0.09
404.2265930	100.00
404.9137878	0.22
409.0283508	0.05
411.2040405	10.44
412.2779236	0.04
426.1365662	0.90
429.1662903	20.33
430.0715637	0.21
436.3253174	0.08
437.2731934	0.20
438.1703796	0.05
441.2129822	0.05
449.7868042	0.25
454.1947327	17.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	498.1803
Annotation	Adiposin 1
Peak:m/z	Relative Intensity
160.9726257	0.02
163.0663147	0.02
171.1580811	0.02
192.3781738	0.07
240.5198669	0.03
250.2878876	0.02
264.1333313	0.07
271.5244446	0.05
272.5525513	0.08
274.4013062	0.03
293.4266968	0.02
305.0804138	0.04
313.4171143	0.05
333.1761169	0.29
336.2903137	0.02
337.1423035	0.05
341.3152466	0.02
341.9628601	0.01
347.3541260	0.06
359.3372192	0.29
365.3837585	0.02
367.1119995	1.19
368.1654053	0.14
374.9213562	0.03
377.3002319	1.19
381.2042847	0.06
383.2841187	0.03
386.9715881	0.02
393.1980286	1.01
402.3227234	0.71
406.5911255	0.08
411.2095947	100.00
412.1626282	1.18
420.1191406	0.07
427.4016418	0.05
434.2029724	0.04
435.9227600	0.09
437.3491516	0.34
438.1824036	0.03
451.5946655	0.08
452.3055725	0.18
453.3502502	0.06
454.2572937	0.29
464.3147888	0.19
465.1893921	0.10
480.0135193	0.21
481.1637268	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	805.2917
Annotation	Unknow
Peak:m/z	Relative Intensity
283.0986023	0.05
327.1476440	0.03
331.1722717	0.02
354.1335449	0.03
360.4521484	0.05
385.1949463	0.06
386.6644897	0.02
387.3412476	0.66
399.1769409	0.03
403.3688354	0.27
415.1931763	0.35
416.4144897	0.48
417.3005371	1.81
433.0375977	0.03
447.3342285	0.11
459.1339722	0.31
471.0912476	0.10
492.2263794	0.02
507.2437744	1.24
508.2564087	0.05
525.4616089	0.05
545.2774658	0.03
565.2942505	0.19
577.2427979	0.04
578.9304810	0.09
580.9023438	0.04
586.4091797	0.26
589.0591431	0.06
595.1671753	7.55
595.7793579	0.14
603.2644653	0.08
605.1945190	0.14
607.1888428	0.99
613.1998901	0.20
625.0237427	1.09
643.1582642	100.00
643.8417358	0.24
672.5963745	0.09
679.2898560	0.05
682.6832886	0.10
683.8634644	0.07
691.4150391	0.07
728.9754028	0.08
744.1190796	0.19
745.2920532	0.15
757.2413940	2.09
759.1846313	0.16
761.2244873	0.09
768.9077148	0.11
786.5056152	0.08
787.1602783	0.88
788.5392456	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.09
Annotation	Gerfelin
Peak:m/z	Relative Intensity
93.0463791	0.12
104.8413467	0.21
110.9517593	0.13
112.9286270	0.12
115.0530624	0.10
118.9505157	0.48
122.9202271	100.00
124.2543793	0.14
126.3940735	0.14
127.0213776	0.72
136.9802551	0.38
138.9902344	87.89
146.9994202	5.97
150.9890137	22.21
152.1116638	0.13
153.4791260	0.15
154.8289185	0.05
160.8808136	0.05
162.9006348	0.33
165.0237427	41.85
168.1306152	0.04
169.0193329	2.19
172.9997406	0.03
180.9839478	0.31
182.9010010	0.09
192.0006409	0.04
192.8997803	0.14
195.2094421	0.12
201.0337524	0.28
205.0080872	0.08
213.0130310	0.05
215.1116028	0.26
217.0372620	0.11
218.7313538	0.22
220.1490173	0.04
227.2565002	0.25
231.1047974	0.16
232.4771118	0.04
234.1560669	0.16
237.0803223	0.03
238.5312195	0.42
245.1398315	0.65
246.3751526	0.12
248.0150757	0.08
249.0687866	1.26
249.9292603	0.29
255.1322021	0.93
260.0811462	0.03
262.1808167	0.15
263.3161926	0.08
269.8658447	0.22
270.4788513	0.22
273.0157471	26.17
276.0453186	0.12
281.6337585	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
79.09662628	0.11
85.24801636	0.36
88.81134033	0.27
95.01774597	2.68
96.91366577	0.64
98.9675293	0.82
103.1328125	1.42
104.6986847	0.52
106.9353485	2.47
109.0120392	2.75
111.0842133	1.06
122.0656433	0.29
122.8974609	1.58
124.9434662	0.55
128.9687347	4.33
133.1180115	0.46
135.1692657	1.03
137.1021118	1.20
139.364502	0.25
141.0548248	0.24
147.1746368	1.42
148.8885193	0.22
151.0110321	40.87
152.0600739	3.98
153.0019073	0.46
155.2136536	0.53
157.11203	0.72
159.2144928	1.96
165.1488953	0.13
167.1422272	3.13
169.1244507	2.07
170.0787048	0.70
171.1105042	2.36
177.0109406	1.52
179.2420654	3.04
180.1917725	0.13
182.0467682	0.21
185.032547	2.46
189.5217438	0.20
191.0818329	0.69
192.9266815	0.26
194.8852539	0.45
197.0764008	3.82
198.0909119	0.71
199.3530731	0.20
203.0783844	0.38
207.3639069	0.91
210.1064301	0.27
211.2046356	2.43
217.1839142	2.41
225.1626434	3.29
235.1733551	18.11
235.8794403	0.22
238.1666412	7.02
253.088501	100.00
254.1717072	19.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1059.5371
Annotation	Tricalysioside Q
Peak:m/z	Relative Intensity
303.4490662	0.04
305.3632812	0.07
306.2529602	0.07
310.3065796	0.02
321.3438110	0.02
323.5438843	0.02
329.1647034	0.02
331.2729492	0.29
332.4101868	0.06
333.4891357	0.03
334.7368774	0.01
347.0822754	0.19
348.7428589	0.06
349.3605652	1.21
350.3509521	0.86
365.2743225	0.09
367.2739258	1.84
368.4069824	1.06
499.7104492	0.03
508.2282410	0.01
509.4468994	0.02
511.3311157	0.27
512.4564209	0.14
527.4255981	0.67
529.3516846	100.00
530.3474121	80.12
531.4530640	0.06
548.2443848	0.01
582.4316406	0.01
801.0858154	0.01
879.5743408	0.04
939.5385742	0.08
978.6745605	0.01
1042.4191890	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	439.1819
Annotation	Unknow
Peak:m/z	Relative Intensity
144.9892273	0.09
161.1255035	0.09
162.8938904	2.55
163.5341492	0.01
168.7767334	0.03
173.3093872	0.04
179.2555847	0.05
224.9133911	0.08
234.7503357	0.85
235.3868561	0.04
247.3187561	0.10
255.9392395	0.02
259.0759888	0.02
264.7716370	1.22
265.4048462	0.07
276.2862244	0.08
281.0837402	0.04
289.1401978	0.12
293.1314697	0.08
300.0576172	0.21
303.0904846	0.02
307.0111084	0.26
308.8322754	0.08
315.3335876	0.17
325.0892334	1.07
349.1662292	0.06
351.2163086	0.07
352.2001648	0.02
367.3892822	0.03
379.2269897	0.14
393.1520691	100.00
393.7613220	0.48
395.2786560	0.14
403.1446228	0.03
409.2480774	0.03
421.1780090	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	244.0922
Annotation	gamma-Glutamyl-beta-cyanoalanine
Peak:m/z	Relative Intensity
93.9855194	0.01
94.8379974	0.04
111.9154510	100.00
112.6916351	0.02
130.1716156	0.02
146.8965454	0.02
165.8427124	0.01
180.8857422	0.01
185.9191742	0.02
197.8826752	0.05
199.1865387	0.01
226.2213135	0.09
227.1893768	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	513.1097
Annotation	MK 571
Peak:m/z	Relative Intensity
156.9565887	0.48
171.0185242	18.26
172.9876099	1.11
175.0324097	6.29
176.0562897	0.07
187.2201080	0.08
190.5253448	0.36
191.1558838	2.43
193.0376892	0.39
215.2234192	0.11
216.9190979	0.08
245.0781250	0.17
247.0375977	0.07
257.2905579	0.05
258.6766968	0.17
276.0579834	0.24
281.1275635	1.02
301.0043335	0.15
303.0172119	17.63
303.6323853	0.15
321.0877686	100.00
325.4451294	0.21
336.1865234	0.05
337.1212158	0.06
338.9456787	0.42
340.9065552	0.07
342.1357422	0.11
360.1353149	0.24
396.0752563	1.52
398.4020386	0.21
399.3294067	0.05
408.9672241	0.07
410.1273193	0.07
420.9283447	0.09
424.4961548	0.04
429.0885620	0.14
441.1754761	0.17
453.1109009	0.48
467.0600586	0.26
469.2562256	0.46
470.2559814	0.04
494.7626343	79.53
495.5121460	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	669.287
Annotation	Moluccensin E
Peak:m/z	Relative Intensity
300.9533081	0.06
302.4269409	0.01
318.3008728	0.03
327.2526245	0.05
333.2402344	0.03
347.2212524	0.04
370.3488770	0.06
371.3600464	0.03
373.4555054	0.01
417.4890747	0.05
462.2648926	0.15
481.6868286	0.02
482.5681763	0.13
492.3259277	0.49
495.2572021	0.16
510.3885498	0.08
520.3245239	0.02
521.4807739	0.01
524.3275757	0.17
526.3359375	3.14
527.0863647	0.05
536.0873413	0.75
536.8724976	0.01
552.3093872	0.02
554.6719360	0.03
561.3468628	4.54
563.7009888	0.02
564.4093018	0.06
573.6788330	0.03
579.3566284	28.37
580.3419189	0.52
581.8490601	0.03
597.4087524	0.01
605.4013062	0.17
623.2843628	100.00
623.9280396	0.31
625.3425903	0.68
633.4510498	0.11
649.3479614	0.06
650.6879272	0.05
651.5111694	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	614.32
Annotation	Unknow
Peak:m/z	Relative Intensity
173.2426910	0.07
177.7777100	0.21
181.1251221	0.38
182.2653961	0.09
183.1453552	0.74
186.3475647	0.03
187.3096008	0.08
189.0677185	0.49
191.0614624	0.07
193.0099792	0.65
194.1741791	0.13
195.0859680	0.23
197.0848541	0.38
199.1455994	0.14
201.1269073	0.29
205.1271362	0.54
209.0855255	0.79
211.1085510	1.01
212.2327271	0.37
215.2254944	0.76
220.3826599	0.07
221.1185455	0.12
223.3673706	0.32
224.2740173	0.17
225.1207886	0.30
227.3543091	0.11
229.0176086	0.64
229.9932251	0.34
234.0022888	0.10
235.2254944	0.27
237.1309204	0.28
239.3317413	2.20
241.2404633	0.03
242.3837891	0.30
247.1318054	0.11
249.2049866	1.00
250.3899536	0.41
251.2789612	0.40
255.2183075	1.99
256.5458984	0.15
257.2277527	2.78
258.8657532	0.23
260.0805359	0.40
262.1823425	0.11
267.1943054	3.73
269.2117310	1.46
271.2117310	0.44
272.0258179	0.22
273.1641846	0.46
275.2086182	0.70
277.2313232	0.06
280.5299377	0.30
283.4375000	0.18
284.3810425	0.60
285.2672119	5.55
287.3269653	0.19
288.3052979	0.13
294.9523315	0.50
296.3383789	0.16
297.3540649	0.33
301.1286621	0.19
302.2418518	0.23
303.1191406	0.58
308.4309082	0.35
310.1350708	0.38
312.2325439	0.26
313.3110352	4.01
314.2394409	0.04
315.4105225	0.32
324.3562622	0.60
328.3142090	0.05
330.6280518	1.88
331.2876587	1.24
332.3574219	0.34
334.4016113	0.29
338.3870239	0.18
340.1760864	0.22
342.2655640	0.59
348.2841797	1.26
349.4304199	0.19
352.3411865	1.07
359.2276001	0.04
361.9938354	0.20
366.3884277	0.11
370.2365723	2.85
371.1230469	0.34
375.6676025	0.06
377.2626343	0.23
380.3393555	1.76
384.3999023	0.15
386.2954102	0.11
388.3328857	1.46
390.3640137	0.06
398.2589722	4.54
400.5995483	0.17
403.8903198	0.23
406.1859131	0.10
407.7235107	0.07
408.3970337	0.19
414.2913208	0.13
416.4138794	15.93
418.1665649	0.43
419.3999023	0.08
432.1940308	0.10
434.3129883	48.37
435.2769775	0.39
445.2190552	0.18
450.2681274	2.10
451.5006714	7.56
452.3580933	61.84
453.3084717	0.33
454.0119019	0.20
481.3145142	0.06
495.4895020	0.13
510.4479980	0.68
511.4280396	0.19
514.5698853	0.05
517.5364990	0.11
528.3426514	0.47
529.2988281	0.10
550.8445435	0.30
552.8570557	0.07
554.8485718	0.05
560.1495361	0.12
560.7697144	0.62
562.3607788	0.11
568.6076050	0.41
569.4888916	0.13
570.4038086	0.46
571.4254761	0.31
576.9314575	0.06
578.3417358	1.89
579.5066528	0.13
596.3540649	100.00
597.5682983	2.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	361.2018
Annotation	Limbatolide B
Peak:m/z	Relative Intensity
108.8812561	0.18
121.3683167	0.22
123.0454483	0.24
128.9544678	0.14
131.1954346	0.17
135.2741699	0.08
136.8848114	0.09
143.1286774	0.14
146.0981598	0.12
154.9580078	0.51
155.6392212	0.13
159.0729218	0.38
169.0748291	0.08
186.0245361	0.08
187.1641846	0.10
191.1034241	1.34
192.1770020	0.07
194.0292358	0.05
199.1997070	0.06
201.0669861	0.27
204.9737701	0.30
211.2165375	0.10
215.3097229	0.15
217.0184021	0.10
219.0770874	0.07
223.2590027	0.07
229.1648254	0.10
231.1324463	0.06
239.2632751	0.27
241.0276489	0.73
243.3069153	0.08
245.1798096	0.90
248.2307739	0.14
253.3966370	0.14
255.1585999	1.33
256.9765015	0.42
263.2324524	0.31
269.4369202	0.26
271.0851746	0.39
273.1426086	1.76
274.2786865	0.72
277.2732239	0.11
279.0339966	0.04
280.6249390	1.66
281.3192444	35.88
282.3006287	2.06
283.1459961	0.08
287.3025513	0.13
297.2096863	100.00
298.2723389	6.49
299.3072205	1.45
300.3320618	0.78
301.4172058	0.03
307.0288696	0.19
308.5707397	0.19
311.1500244	0.16
313.2887573	0.12
314.6633301	0.61
315.3072510	22.34
316.5108337	2.39
317.2494507	3.89
319.2769165	0.39
323.0805054	0.14
324.1474915	0.08
325.3353271	2.14
326.0891724	0.09
327.3495483	0.13
329.0571289	0.08
330.2033997	0.13
331.2720642	0.15
333.2780151	0.05
343.2084351	8.06
344.3002930	0.60
345.0101013	0.25
345.9660034	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	573.2551
Annotation	Canavalioside
Peak:m/z	Relative Intensity
497.2236938	0.05
527.2941895	100.00
527.9292603	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.2137
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0137329	2.55
181.1420746	2.81
193.1338806	0.12
197.1341553	11.75
221.1630554	0.89
223.0321198	1.06
241.1297913	41.61
255.3712921	0.42
265.2497559	0.25
269.3592224	0.13
277.2203674	0.12
283.0456543	4.38
287.3462524	0.43
295.1244507	3.74
313.0362549	10.14
323.1707764	5.71
325.0333252	1.47
341.1295166	82.74
343.1290283	30.13
344.8394165	0.47
367.1738892	1.14
373.1848755	0.69
381.0936890	3.31
383.1298828	30.47
385.1477051	12.67
397.1732178	0.23
403.2254639	100.00
445.1470947	0.15
449.3539429	0.30
502.8359375	0.62
505.2872925	0.51
518.5440063	0.20
519.2702026	0.48
524.3720093	0.55
527.3880615	1.45
529.1630249	1.54
547.2870483	48.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	495.2598
Annotation	Pierisformoside D
Peak:m/z	Relative Intensity
161.1223602	0.29
255.0587158	0.13
269.3738403	0.50
271.3558044	1.05
273.3977966	0.08
287.2878113	0.94
289.4023743	0.42
299.3545837	1.23
315.2629395	35.51
316.5871887	2.06
317.2521057	8.03
318.1867065	0.27
331.1694641	2.89
333.3109131	100.00
334.2673340	1.52
345.2683105	0.09
357.2123108	0.29
361.0786133	0.44
366.2959900	0.23
373.2065430	0.09
389.4325256	0.09
401.3657227	0.26
407.0618286	0.07
435.3061218	0.34
437.4402771	0.20
449.2051697	0.13
475.3852844	0.06
477.3042908	13.43
478.2546082	1.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	370.21
Annotation	Unknow
Peak:m/z	Relative Intensity
108.8337708	0.10
117.9094772	100.00
119.0464325	0.26
119.9641571	0.35
122.2495804	0.25
126.7493286	0.22
130.8179016	0.47
144.8817291	2.12
147.3072205	0.11
148.0560150	0.65
150.0276184	0.30
162.0256805	0.43
162.9057922	0.67
166.0912170	0.48
171.9773712	0.29
175.0453033	0.17
182.1325226	1.08
182.8266449	0.23
188.9187012	0.65
204.2158661	0.26
208.1052094	2.08
216.8127289	0.08
221.0310669	0.28
227.9913025	0.47
231.0828247	0.11
234.9623108	0.77
239.2727966	0.11
241.1817932	0.53
248.3246155	0.55
249.1321411	0.23
250.9960327	0.43
252.9812927	5.78
255.2146301	0.15
262.8991699	0.39
279.6142578	0.06
289.1039124	1.34
295.1291199	0.20
308.4091797	0.10
309.5972290	0.66
324.1021118	0.85
328.0300293	1.00
334.1304321	0.55
342.2116089	0.08
352.2411804	4.18
353.1912537	0.08
354.4113464	0.55
358.3251648	0.41
360.8161011	0.18
361.8844299	0.73
378.9739685	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1243
Annotation	Curculigoside B
Peak:m/z	Relative Intensity
135.0526276	0.05
137.0385742	1.73
145.9101868	0.03
151.1468811	0.09
159.0252991	0.08
161.0237732	2.79
167.1765137	0.03
179.0551147	0.28
185.9970703	0.03
190.9113159	0.16
203.1236572	0.20
205.3198395	0.03
221.2395935	0.01
231.0834656	0.03
243.1048279	0.07
245.1551208	2.64
247.1410828	0.05
261.1530151	0.02
271.0706177	0.17
289.0631409	100.00
289.6766357	0.18
298.9806519	3.09
299.5999756	0.05
313.4288025	0.12
357.5994263	0.04
366.9371643	0.06
405.0192566	0.34
407.1664429	0.15
408.3091736	0.11
409.6653748	0.02
416.2125854	0.03
423.4339600	0.02
433.2395325	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	641.2927
Annotation	Unknow
Peak:m/z	Relative Intensity
271.2559814	0.10
285.4290771	0.13
286.2336731	0.46
295.1497192	0.21
306.2999878	0.16
328.2425537	1.50
344.2395630	0.12
346.3132935	13.54
347.3421631	0.13
354.9555664	0.17
356.3783569	0.09
358.1679688	0.32
362.3374634	0.58
370.2987061	0.10
374.5628052	0.15
388.5287476	0.05
406.0265503	0.28
409.4405518	0.15
417.5327148	0.25
418.2241821	0.05
423.3531494	0.43
429.2352295	0.10
432.4351196	0.09
433.3947754	0.16
435.3588867	0.49
448.2385254	0.05
450.0508423	0.06
459.3002319	0.14
465.4732056	0.20
468.3450317	0.09
479.3723755	1.20
490.1420898	0.25
508.3388062	100.00
524.4602661	1.49
526.4782715	1.67
535.2805786	0.47
537.4775391	0.07
543.3318481	5.92
550.5339355	0.09
551.1723022	0.53
552.9819336	0.47
554.4722290	0.64
563.4344482	0.21
568.3337402	0.34
569.3261108	0.08
579.3622437	0.66
580.5397339	0.27
581.5388794	0.12
586.6220093	0.22
595.1974487	3.26
596.0993652	0.15
597.2836304	5.09
598.0973511	0.06
605.4577026	2.82
606.5879517	0.21
610.8758545	0.16
613.3768921	0.16
619.9485474	0.38
621.0991211	0.09
622.7175903	4.52
623.3484497	73.05
624.4272461	19.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	670.2349
Annotation	Unknow
Peak:m/z	Relative Intensity
202.9692078	0.07
205.2988892	0.18
210.1231689	0.09
211.2676239	0.17
217.0721588	0.07
226.7750854	0.08
239.1792603	0.05
245.1644592	0.46
272.1049805	0.22
289.1161194	12.44
299.0122070	1.44
305.6687622	0.28
320.1173706	0.12
328.0841064	0.09
330.9583740	0.20
355.2075195	0.04
396.3068848	0.21
397.1284790	0.06
407.2496338	0.21
443.4940186	0.49
448.9962158	0.12
451.1883545	100.00
453.0869141	0.08
506.4281616	0.09
536.0614624	0.15
537.3699341	0.22
540.1137695	0.59
554.6012573	0.43
560.9526978	0.12
573.2214355	0.15
604.4245605	0.11
610.0728149	0.27
624.4808350	0.26
625.3358154	0.42
626.2180176	0.15
634.2624512	0.21
651.5361328	0.60
652.2772827	0.65
653.2476196	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	397.1503
Annotation	Methyl (3x,10R)-dihydroxy-11-dodecene-6,8-diynoate 10-glucoside
Peak:m/z	Relative Intensity
116.1333923	0.06
117.0125885	0.58
130.9509430	0.42
137.0705719	0.06
143.0438080	0.16
145.1350098	0.06
151.2700958	0.16
152.0548706	0.10
155.1543274	0.22
160.8618469	0.11
162.0199585	0.05
166.9310608	0.21
173.1364136	1.80
179.1324463	0.30
184.9923401	0.11
189.2165833	0.33
191.1089935	2.65
203.3764954	0.06
205.2091064	1.11
211.2616272	0.28
217.1681671	7.17
218.2834167	0.08
229.1567383	0.70
233.2717896	0.52
235.0921021	43.63
236.2109985	0.53
244.9979858	0.62
247.2448425	1.73
253.1429749	0.04
255.3619080	0.11
261.1637573	2.74
262.5488892	0.34
263.3755188	1.06
265.2581177	0.84
273.1671143	0.92
274.4957581	0.08
279.2013245	2.49
289.4005127	0.29
291.2017822	12.89
292.0619507	0.22
307.2632446	0.12
309.2331543	21.00
310.2380371	0.52
313.1903076	0.07
317.3341370	0.41
329.0993958	0.08
335.2906799	57.37
336.2430725	0.88
348.8562622	0.13
351.1628723	0.82
353.1824646	100.00
354.2753296	1.26
361.1555786	0.17
367.2366943	0.07
379.2034607	19.76
380.3044434	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	259.0786
Annotation	4'-Hydroxyflurbiprofen
Peak:m/z	Relative Intensity
123.8663177	0.09
139.9829712	0.86
145.1247711	1.42
154.9781189	0.18
158.1411285	0.04
166.8989105	0.08
186.0934906	0.08
187.0986023	0.21
189.3994904	0.06
196.0609894	5.51
201.3051758	0.05
203.8032684	0.03
213.0381927	100.00
214.0688171	0.97
215.0289307	0.32
225.4416962	0.06
231.0278931	18.29
240.8110352	1.05
242.1564941	0.43
259.2536621	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	500.92
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0254211	3.81
170.9604187	0.05
198.9904175	1.20
216.7633667	0.09
228.9404602	1.14
272.9889526	49.41
386.9423218	100.00
427.0027466	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.1139
Annotation	Tetraphenylphosphonium
Peak:m/z	Relative Intensity
101.0014496	2.32
106.5263290	0.21
112.9362183	7.58
114.8274231	0.37
118.9981689	6.20
124.7600098	0.83
130.9497528	1.60
136.0332947	0.09
142.9570770	9.46
148.9877319	1.37
160.9441833	8.91
165.0934143	0.16
178.9658508	100.00
224.9234619	19.99
246.7214355	0.07
259.0113831	0.13
271.1494751	0.11
275.3567200	0.06
277.3595581	0.37
291.2233887	2.94
307.3153381	0.18
318.1369629	0.05
319.2990112	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	307.0826
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
102.0917969	0.58
115.9356079	0.42
127.0556641	0.16
129.9328308	100.00
131.0061493	7.14
132.0859070	0.17
144.1042480	0.19
144.8469238	0.24
160.0617828	0.41
162.0227661	1.21
163.9688721	0.27
170.1972198	0.06
176.9338684	0.90
179.0200043	2.87
192.2367554	0.06
199.2550964	0.12
208.9980774	0.39
210.8323975	0.79
217.6572266	0.05
219.5012512	0.40
231.0747681	1.32
232.1841125	0.65
233.7932739	0.94
235.0274963	0.26
237.0577698	0.30
238.1920776	0.22
239.1721497	0.16
242.5935059	24.82
243.2104797	8.84
244.0910034	0.31
245.0722656	1.17
246.7503357	1.39
247.6672363	0.10
256.8359070	0.62
257.4459839	0.26
260.5296021	2.26
262.2581177	0.73
267.8109741	0.47
269.7178955	37.00
270.7179565	1.74
272.1704102	0.06
274.2355957	0.19
275.6705627	36.84
276.6327209	6.08
277.3479614	0.20
278.9060059	1.47
288.2535095	0.61
289.0981750	1.53
289.8992920	0.35
290.5529175	0.84
298.5737305	72.65
299.2938843	22.78
300.1092529	0.08
307.9812317	0.15
322.1214905	0.44
337.2266846	0.34
339.9323120	0.47
355.2101135	83.08
356.1997681	10.53
357.1274109	7.70
364.0881042	0.71
366.0555420	0.15
380.5158386	0.83
381.1379700	3.39
382.1575928	0.31
382.9061890	0.54
391.2490234	1.72
409.1920776	12.30
410.2241211	2.74
411.2374268	1.33
421.0545349	0.24
422.0419006	0.39
466.0938110	2.44
467.0623474	0.74
475.3115540	0.27
484.1282043	54.23
485.1133423	8.80
486.2007751	2.64
520.0114136	0.75
521.1298218	0.20
522.4670410	0.96
538.2485962	11.09
539.1835938	3.57
540.1862183	0.50
550.0821533	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.204
Annotation	Unknow
Peak:m/z	Relative Intensity
188.3145752	0.04
193.3042908	0.12
199.0693817	0.07
205.1101074	0.30
230.9939117	0.19
236.8827057	0.32
249.2342834	1.03
280.0559998	0.27
281.1610107	100.00
337.2129517	0.94
341.0612793	0.18
342.9537354	0.06
355.0737915	0.23
359.1128540	0.28
385.3035278	0.38
390.2830200	0.11
395.1310425	0.03
400.7206421	0.05
401.3428955	0.35
431.4386597	0.11
434.4997559	0.13
435.3884277	0.07
439.0263672	0.28
473.0889893	0.09
478.1622314	0.02
486.2623291	0.20
503.1121216	0.05
504.4450073	0.13
517.7728271	0.07
519.4125366	0.19
524.8442993	0.08
539.3428955	0.55
563.1298218	0.17
579.2287598	0.09
585.3244019	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	389.1068
Annotation	Erinoside
Peak:m/z	Relative Intensity
119.2264175	0.05
120.9469299	3.81
125.2337418	0.06
127.0927200	0.16
139.1978912	0.06
143.0803528	0.03
147.0641785	0.25
162.8001404	0.16
168.0678711	0.06
169.1335144	0.29
173.0500183	0.22
180.9674683	0.22
195.0033569	5.02
202.8346252	0.17
205.0698242	0.13
206.9516449	0.08
209.1199493	0.22
210.0735474	0.06
213.0638733	22.60
214.0975647	0.26
217.1016846	0.05
219.0520630	0.06
224.2221985	0.14
225.1597900	0.32
227.0869446	0.55
239.1776123	0.13
241.0987854	0.05
242.2030029	1.91
249.1675110	0.14
251.1154175	0.32
251.9450073	0.17
255.1971436	0.38
260.3786926	0.80
269.0790405	0.09
270.1336060	0.04
273.4032593	0.22
276.1561890	0.35
278.9830322	1.77
280.2911682	0.03
285.1410522	0.34
287.5229797	0.08
294.0595703	0.30
296.1191406	0.28
297.1193542	0.57
301.0065918	0.42
304.8184204	0.09
308.1055603	0.08
309.3512878	0.11
311.0599365	0.20
313.1778564	0.81
315.9889832	0.22
318.1728516	0.15
323.1406860	0.21
325.2595825	0.41
327.2026367	0.10
329.2082214	0.28
331.1871643	0.04
335.4337158	0.12
336.3781128	0.70
339.1235962	0.08
340.0877380	0.10
341.1646729	0.04
343.1713257	0.66
344.3096313	0.19
345.4014893	0.48
346.4036865	0.07
347.3083496	0.05
348.4731750	0.11
349.0827637	0.09
353.0848083	1.78
354.2167969	6.13
357.1622314	0.20
358.9526367	0.13
366.2165222	0.17
369.2389832	0.11
371.2079163	100.00
372.2920532	0.53
379.8259583	0.27
380.5785828	0.10
381.4530640	0.04
395.7774353	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	719.2767
Annotation	Semperoside
Peak:m/z	Relative Intensity
245.2382507	0.04
287.3024902	0.13
333.2956543	0.19
345.3793945	0.01
347.2794800	0.03
351.2965698	0.03
361.3906860	0.06
373.3125610	0.09
377.0520630	0.44
391.2833862	0.31
433.5044556	0.03
461.3249512	0.04
467.0583496	0.12
469.5712891	0.06
481.1670532	0.07
493.3479614	0.05
495.3793945	1.81
508.4381714	0.10
509.2595215	0.23
512.1929932	0.21
513.3411865	3.72
517.3444824	0.06
520.1903687	0.04
521.2145996	0.45
527.3685913	1.45
535.6119385	0.13
537.4107056	0.30
539.2542725	100.00
539.8550415	0.47
553.2288208	4.87
555.3219604	1.60
556.4317017	0.15
557.4027100	2.84
581.3121338	3.46
583.4694214	0.05
593.2272949	0.15
597.2872925	0.07
599.2600708	31.02
599.9238892	0.11
609.3180542	0.03
611.3427124	0.18
623.3085327	0.28
627.4736938	0.07
628.6907349	0.73
629.4000854	6.62
631.1380615	0.09
641.3193359	0.05
647.3425903	0.07
652.3433228	0.11
659.3451538	19.83
671.2797241	0.22
672.5209351	0.12
673.5107422	0.37
675.4656372	0.05
683.1183472	0.17
689.1766968	0.09
699.6249390	0.04
701.2964478	18.89
701.9794312	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	297.119
Annotation	4'-N-desmethylolanzapine
Peak:m/z	Relative Intensity
100.8295441	0.03
112.9758148	0.05
118.9271698	0.03
131.0425568	0.18
135.0060120	0.06
137.0208435	0.04
143.0816956	0.05
148.8301392	0.10
151.0263367	0.07
161.0316467	1.14
179.0096283	0.07
184.8881531	0.29
191.1244202	0.15
209.1758423	0.04
210.9689331	0.09
213.3104553	0.04
221.1858521	0.02
251.0639954	100.00
251.6844788	0.11
252.9968567	0.10
268.9743652	0.19
277.1171875	0.07
279.1400452	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.1208
Annotation	Ascorbalamic acid
Peak:m/z	Relative Intensity
156.0325317	0.12
158.0318298	2.97
158.7232056	0.03
170.0504150	0.08
172.1292419	0.10
174.4241486	0.12
181.0247192	0.06
182.8311768	2.38
183.5094757	0.03
187.9685516	0.24
200.1137848	0.64
202.0462189	8.31
217.8985138	1.24
219.1907959	0.51
223.2492676	0.03
243.9872589	0.49
257.3242188	0.15
262.0280457	100.00
267.1380615	0.12
304.3827515	0.05
318.1585083	0.12
333.1730957	0.26
340.9052734	0.10
361.1691895	0.08
362.0151367	0.13
373.9783936	0.09
387.2778320	0.24
388.1759644	0.05
421.1900024	0.09
441.2484741	0.08
445.2191772	0.11
446.9228516	0.05
453.1129761	0.05
463.9350586	0.13
465.1337891	2.44
478.9956665	0.35
497.1528320	0.15
507.0062256	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0712
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
179.8388062	0.32
180.9990845	0.41
193.3183441	0.13
195.0615387	0.51
207.0972137	1.31
207.9897003	1.30
209.1363068	1.95
222.098114	2.90
223.2182465	2.73
224.0473022	0.26
233.2509003	0.60
251.0775757	100.00
252.1484985	15.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2624
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
170.2275391	0.10
196.0625916	1.79
205.6371765	0.16
214.0240173	1.50
221.8183594	0.21
233.3969116	0.46
259.3496094	0.54
275.2911682	0.83
277.2241211	100.00
340.2813721	0.14
366.0326843	0.21
381.3712769	0.21
384.5151978	0.29
386.3634033	0.15
413.4044495	0.48
419.3926697	0.14
428.2258911	0.06
430.4513245	0.23
431.3522339	0.25
433.2810059	0.37
456.2206726	0.96
457.4549561	0.24
464.8845825	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	775.3391
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
257.1966553	0.09
269.1351013	0.04
270.0944824	0.13
271.0189819	0.03
341.1265869	0.05
343.2097778	0.04
349.9728394	0.03
364.3304138	0.12
365.4392090	0.11
366.2423096	0.04
369.1734009	0.22
387.2772217	100.00
388.3518066	0.09
390.1223755	0.09
397.2031860	0.07
411.4574585	0.17
412.1801758	0.07
416.3707275	0.04
431.4250488	0.10
433.3048096	0.06
441.3359985	0.05
448.2937012	0.11
449.4505005	0.03
450.2449951	0.17
451.9936523	0.09
465.1664429	0.03
474.0653076	0.04
487.1975098	0.04
496.3158569	0.08
545.6105347	0.02
548.7911987	0.07
549.3991089	0.19
550.4349365	0.14
577.2649536	0.08
580.9445190	0.01
590.5396729	0.22
593.1337280	0.28
594.3587036	0.75
595.4198608	2.39
596.4824829	0.03
597.2214966	0.08
612.3454590	0.11
613.2100830	0.39
614.3167725	0.29
615.4157104	0.02
630.6815796	0.03
642.5852051	0.02
643.3873901	0.05
653.2091675	0.06
684.7804565	0.05
688.4055786	0.09
713.7868042	0.19
715.2785034	0.09
729.3251953	0.23
731.9848022	0.05
755.3688354	0.16
756.0558472	0.03
757.3986206	1.32
758.2231445	0.24
759.4301147	0.14
766.9526978	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	527.2131
Annotation	Dutasteride
Peak:m/z	Relative Intensity
161.0891113	6.07
178.9059906	0.85
183.3930359	2.11
221.6044312	0.30
223.1898193	3.19
229.2276917	3.15
235.1121216	4.06
238.9499359	0.55
241.1806946	2.38
242.1268921	0.39
255.0793152	0.40
257.1670532	2.65
259.2633362	2.74
267.2509155	2.88
269.2245483	1.15
270.0807495	0.46
275.1858215	2.81
276.9951172	6.83
285.3076172	32.51
285.9685059	0.34
289.0778198	0.34
293.0383606	0.84
299.4227295	0.46
301.1230469	0.30
303.2572021	19.08
305.4933167	0.27
311.1491699	0.85
317.3930664	3.21
319.3594971	2.69
321.2899780	16.59
329.2128296	0.95
331.3292236	0.48
346.1099243	0.60
347.2361450	5.66
363.4877319	0.94
365.1998901	7.26
375.0572510	1.01
381.5440063	0.27
397.4425049	0.48
407.2026367	0.52
421.1597900	2.92
439.2261353	6.21
447.6060791	0.39
465.2643433	63.31
466.1060791	0.72
481.3746948	1.20
483.3547974	100.00
484.6406860	0.58
491.3145142	3.71
497.3558960	2.81
498.7153931	0.21
507.6975708	0.30
509.2898560	83.61
510.2350464	4.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	617.9
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0108948	0.20
202.1060181	0.10
231.9235840	0.08
235.8047943	0.05
272.9242249	5.56
273.9988098	5.34
275.0296326	3.34
276.0955811	1.63
387.0632324	4.05
388.0133057	8.11
388.9192505	9.02
389.9702759	9.84
427.2060547	0.04
501.2278442	3.67
501.8914795	31.16
502.9178467	39.75
503.8745728	100.00
504.5054932	0.20
528.1354370	0.05
533.3361206	0.14
534.7323608	0.06
543.9390869	0.20
561.9033203	0.14
571.6856689	0.77
572.2972412	0.11
573.9308472	0.48
589.6845093	0.08
600.1542358	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.1714
Annotation	4,6,2',4'-Tetramethoxychalcone 2'-beta-glucoside
Peak:m/z	Relative Intensity
159.0621948	0.04
160.8718719	0.21
179.1772461	0.05
185.1837769	0.13
187.1409912	0.08
193.3859253	0.33
194.1814880	0.05
196.1374969	0.15
198.0683899	0.07
202.9989929	0.04
209.2694397	0.60
211.1137695	0.07
219.2205811	0.23
220.1155701	0.21
221.0413666	0.66
222.1635895	4.19
223.0786743	0.18
225.1944885	0.32
227.2412109	0.21
233.9362640	0.14
235.1937561	2.52
237.1280823	100.00
238.0613098	0.10
238.8867798	0.14
240.3804016	0.28
251.1903381	0.46
253.1107788	2.91
255.2017517	26.85
261.1729736	0.18
265.3948669	0.08
267.1752014	0.61
279.2278442	1.21
281.1221924	36.19
291.4100647	0.27
297.2912598	1.46
299.2109375	18.68
301.1387024	0.33
303.2566223	0.08
305.3148193	0.12
307.6159973	0.25
309.3320923	0.24
313.1588440	0.13
315.1489563	0.28
321.3914795	0.17
325.0649719	6.31
327.3248901	0.29
333.2247620	0.10
339.0250244	0.14
341.0947266	0.46
343.1607056	7.37
359.3205566	0.10
371.3980408	0.10
372.8941040	0.17
381.3604431	0.20
385.2482910	0.15
399.2832947	0.40
417.2866821	16.71
419.2944336	0.18
444.9938354	0.08
459.3487854	0.27
461.1087646	1.14
466.9101868	0.06
486.3736267	0.12
487.2492065	0.68
490.9605408	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	589.2499
Annotation	gibberellin A2 O-beta-D-glucoside
Peak:m/z	Relative Intensity
207.1622009	0.12
215.0758820	0.26
261.2882996	0.05
281.1390381	0.18
287.2747803	0.11
309.4541016	0.28
323.3839722	0.03
330.3411865	0.03
333.5172729	0.05
345.0947266	0.05
353.0582886	0.08
357.4077759	0.04
367.2252197	0.09
375.4097290	0.10
379.1124268	0.02
381.3518677	0.65
391.2538452	0.13
395.1956787	0.08
413.2025146	0.21
417.3078613	0.03
423.4498291	0.19
427.4158325	0.15
433.4014282	0.06
442.6298828	0.22
445.2807007	0.06
449.1722412	0.08
468.5429688	0.03
471.2412109	0.03
473.1806030	0.19
500.1666870	0.21
501.4749146	0.06
503.3585205	0.12
513.1828613	0.04
519.6032104	0.16
525.4547119	0.08
526.9534302	0.21
529.4153442	0.09
530.0897217	0.03
543.2944336	100.00
543.9328613	0.45
544.8263550	0.46
545.5115356	0.11
547.3646851	0.05
551.4254761	0.25
553.4593506	0.82
556.5550537	0.04
570.2269897	0.10
571.1899414	0.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	326.1436
Annotation	Glucopyranosylmoranoline
Peak:m/z	Relative Intensity
118.0434265	100.00
164.0018005	0.28
165.0743103	0.05
166.1320190	0.07
186.0255127	0.26
194.1613159	0.33
195.1082153	0.06
202.4126740	0.05
204.0238342	0.28
205.0081482	0.06
213.1182556	0.05
214.9467163	0.17
216.2502747	0.10
227.0347595	0.24
228.1876221	0.28
230.4201965	0.12
233.0600586	0.23
251.3815613	0.42
252.0828247	0.11
268.0710449	0.53
269.3410339	0.59
270.2112427	0.24
278.7445679	0.12
280.2412415	0.07
281.9425049	0.29
284.1687012	0.12
290.2999268	0.37
294.1472168	0.10
305.4907227	0.24
307.9314270	1.07
309.2430420	0.15
317.3170776	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	387.2003
Annotation	(6R)-9,10-Dihydroxy-4,7-megastigmadien-3-one-9-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
119.0151672	0.28
120.9116821	0.09
122.9806671	0.31
134.9784546	0.17
137.1859283	0.08
138.9128113	2.00
143.1003265	0.12
147.1205139	0.42
148.7438354	0.05
150.9140930	0.70
153.0319977	1.23
161.1376343	0.17
162.8355408	0.03
165.0735168	15.59
166.8620911	0.35
170.9547119	0.06
176.2236328	0.05
179.0054321	0.34
189.2832489	0.12
192.9377594	0.67
195.1625824	0.09
196.4019928	0.07
203.0971375	0.06
205.8867798	0.09
207.1172180	7.78
208.9759521	0.17
210.6433258	0.04
214.9942322	0.10
217.1195221	0.15
218.9777832	0.06
225.0892639	100.00
237.0814819	0.12
239.7572327	0.03
241.1945801	0.05
242.7787476	0.12
245.0462036	0.22
247.1878052	0.18
248.9309998	0.13
263.3699036	0.10
265.3166809	0.14
267.3774414	0.12
269.0683899	0.07
270.3634338	0.03
275.1128540	0.10
279.1051636	0.52
283.4035950	0.09
287.1135864	0.16
291.4699097	0.05
293.3378906	0.03
295.2071228	0.04
301.1749878	0.27
303.0968018	0.44
305.0440674	0.13
306.0662842	0.07
307.2239380	0.49
309.2099609	0.57
311.0486450	0.18
312.4994507	0.17
316.0419617	0.03
319.0047913	0.34
323.1927185	2.92
324.2406311	0.24
325.1296082	0.14
325.9248657	0.24
329.4166565	0.07
333.1674194	0.34
336.9321899	0.30
339.1928406	0.78
341.1600037	0.27
342.0665588	0.03
343.3233643	0.33
344.4273682	0.09
346.2418213	0.09
351.1547546	1.89
352.2932434	0.25
355.2191467	3.23
356.5747375	0.63
357.3569031	0.74
358.3033142	0.60
359.0615540	0.10
360.0401001	0.05
364.1452332	0.95
365.2637634	0.11
369.0976868	6.65
370.2943420	0.26
371.0751953	0.09
372.1697388	0.13
378.4370117	1.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.1294
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
112.9355087	0.22
124.9564056	0.05
127.1085434	0.05
128.9761047	0.09
131.1563110	0.03
134.8905029	1.32
138.9714050	0.03
142.8748627	0.03
157.0882874	0.05
163.1297607	0.03
169.0794067	0.05
187.0863037	0.06
188.5716858	0.03
189.2238312	0.01
205.0663147	2.24
208.9243469	0.09
231.1151428	0.11
237.1885986	0.31
247.2557678	0.05
249.1238708	4.15
257.1407776	0.08
263.1598511	17.16
275.9606018	0.02
281.1060181	100.00
303.3345642	0.04
307.3352661	0.09
311.2300415	0.03
323.1079712	0.08
325.2058716	0.08
327.5053711	0.08
337.5199890	0.11
342.5200500	0.04
343.2157593	0.09
353.2747192	0.14
363.0479431	0.24
367.1414795	0.30
369.3620300	0.04
370.8509827	0.06
379.3615112	0.09
380.7171631	0.13
381.3321838	0.25
384.2884521	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	562.3148
Annotation	Unknow
Peak:m/z	Relative Intensity
183.7098999	0.03
211.3475342	0.06
218.0167389	0.11
263.2560425	0.02
277.2758789	3.29
293.1593323	0.09
325.0111694	0.08
347.5445557	0.04
358.0223999	0.06
386.2133789	0.05
417.5582275	0.08
419.5043335	0.04
427.7501221	0.08
438.3249512	0.06
443.1699219	0.05
453.9613037	0.08
457.3161621	0.09
462.4476318	0.04
499.7299805	0.03
502.3021851	100.00
503.0009766	0.92
503.6096191	0.06
506.3231812	0.04
507.5331421	0.06
508.5573120	0.05
515.7469482	0.23
516.4058838	0.29
524.6296387	0.02
525.4226685	0.30
528.0841064	0.04
543.3427124	0.06
544.0445557	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	915.4216
Annotation	Unknow
Peak:m/z	Relative Intensity
272.8553467	0.13
341.1577759	0.08
349.3865051	0.16
361.0515747	0.06
367.4259033	0.19
385.3886108	0.06
399.1567993	0.06
511.6594238	0.16
523.0112915	0.07
529.4429932	1.65
591.4828491	0.17
691.5579834	1.35
704.1179810	0.07
735.3359985	100.00
736.0239868	0.38
753.2933350	0.23
819.0851440	0.09
871.8109131	0.24
883.7136230	0.37
893.1737061	0.12
897.1896973	0.12
898.4769897	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1186.0934
Annotation	Unknow
Peak:m/z	Relative Intensity
347.2543945	0.65
396.4664307	0.06
400.5972290	0.08
412.1929321	0.22
428.5050354	0.98
429.1341553	3.14
440.4631348	0.07
458.2665100	0.26
468.3638306	0.16
476.4113464	0.88
485.2036133	0.14
492.4704285	0.19
499.9940796	0.14
510.0863647	0.25
528.1078491	8.89
528.7126465	0.25
537.4407959	0.22
539.4184570	0.05
569.1782227	0.11
577.4351196	0.37
581.4117432	0.35
598.5936279	2.52
599.2330322	13.59
600.5393066	0.44
626.3341064	1.84
638.7827759	0.29
666.4246826	0.15
668.1901245	8.77
669.2343750	0.06
678.3587646	1.36
679.3081055	0.34
686.1932983	2.12
694.2306519	0.13
711.3111572	0.06
739.1378784	50.31
740.1958008	0.70
756.9956055	18.74
757.8477173	0.34
765.4299316	0.15
807.2324829	0.37
824.3416748	0.12
826.2157593	0.41
843.9625244	0.52
854.1643066	0.24
881.5201416	0.03
883.5267334	0.18
898.0855713	0.46
903.5008545	0.19
904.1394043	0.22
913.7618408	0.06
921.5023193	5.61
922.4930420	0.33
923.4935303	1.37
940.4724121	0.16
941.3277588	0.16
962.9183350	2.50
963.6381836	0.65
967.8731689	0.24
972.1363525	3.49
972.9763184	0.43
976.3884277	0.83
977.7473145	0.10
994.1403809	14.12
994.9366455	0.12
999.5068359	0.42
1012.0781250	8.28
1013.0458980	0.06
1018.5974120	1.13
1020.5325930	1.19
1021.3327640	0.36
1027.6956790	0.21
1036.6318360	1.18
1037.4853520	0.95
1038.1866460	0.12
1039.5848390	0.21
1053.3840330	1.28
1062.0649410	0.44
1073.5554200	0.89
1085.9591060	0.57
1094.7906490	0.55
1100.3778080	0.34
1101.2127690	0.05
1105.8812260	0.15
1106.9130860	1.09
1107.6038820	2.17
1108.5075680	0.28
1113.8776860	0.27
1120.3720700	0.32
1125.2629390	35.62
1125.9567870	0.50
1129.4101560	1.87
1130.9113770	0.34
1139.8696290	0.20
1145.8751220	0.43
1149.6325680	0.45
1168.1169430	1.04
1186.8356930	0.45
1191.3607180	0.27
1228.4570310	1.11
1229.5114750	0.68
1246.5791020	69.31
1247.6071780	2.69
1248.2517090	0.41
1250.3602290	1.14
1268.5692140	2.02
1303.7907710	0.12
1333.6428220	0.32
1341.3824460	0.30
1342.6445310	0.64
1351.0418700	0.44
1359.0352780	2.75
1359.6932370	39.75
1360.5937500	0.47
1367.3602290	0.60
1368.0655520	0.12
1408.6837160	0.09
1426.5007320	0.13
1430.6268310	3.69
1432.2102050	1.03
1438.9967040	0.56
1450.3389890	7.05
1451.7882080	0.35
1467.4062500	0.67
1468.5117190	1.22
1486.7303470	0.28
1499.6153560	0.11
1517.8426510	0.72
1578.7027590	0.36
1579.6557620	0.79
1596.7570800	2.55
1597.5863040	0.87
1608.9533690	0.10
1614.6929930	100.00
1615.7899170	2.41
1626.6888430	0.11
1675.3592530	0.79
1685.7437740	7.28
1686.3482670	0.12
1692.6290280	0.33
1693.5841060	2.17
1726.8653560	0.26
1737.7091060	0.07
1754.8958740	0.18
1772.7694090	6.31
1774.0900880	0.69
1794.5510250	2.45
1796.1179200	0.28
1825.8072510	1.55
1826.7867430	0.28
1843.1595460	1.32
1843.9337160	2.73
1844.7839360	1.20
1868.0079350	0.11
1877.4813230	0.58
1895.4425050	0.66
1896.1173100	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	614.74
Annotation	Unknow
Peak:m/z	Relative Intensity
178.1099701	0.14
178.9725647	0.11
181.1533508	0.24
183.2374115	0.11
187.4839935	0.09
191.1160583	0.07
195.3001862	0.08
196.1169281	0.13
197.1042328	0.09
197.8707886	0.13
199.1208191	0.24
200.1229858	0.06
206.8584442	0.04
208.0066833	0.07
209.4070740	0.07
210.0085602	0.04
211.1539307	0.12
211.8163147	0.18
213.4041290	0.05
214.1023254	0.02
214.9763794	0.14
217.4547424	0.09
222.1428833	0.16
223.1303711	0.08
224.1065979	0.30
225.1619568	0.62
226.1482544	0.10
227.1625671	0.35
228.1639252	0.07
229.2580566	0.02
230.2405701	0.09
231.1515503	0.06
234.3623657	0.20
236.2328491	0.06
237.3638000	0.39
238.1475830	0.15
239.2798157	0.89
240.0632629	0.04
242.1558838	0.10
243.1261597	0.07
247.5033722	0.03
249.2768707	0.11
250.1517181	0.12
251.2518005	0.42
252.2695160	0.48
253.1729736	0.07
254.1267395	0.14
255.2327576	0.38
256.2349854	0.20
257.2269897	0.19
258.3028564	0.02
259.2171021	0.04
262.2741089	0.08
266.2436829	0.04
267.4144287	0.06
269.1312866	0.10
270.1599121	0.20
271.2673035	0.56
273.3882141	0.07
274.5488892	0.02
278.0403137	0.13
280.3842468	0.22
282.2190247	0.07
283.3143921	0.64
284.8406067	0.14
286.3729858	0.12
287.3082275	0.10
289.4117432	0.05
295.1946716	0.15
296.1936035	0.07
297.1957397	0.05
299.1815186	0.21
300.1891785	0.02
301.2455444	0.24
302.4879150	0.13
306.1616211	0.06
308.0502625	0.07
310.1875610	0.21
311.1853638	0.15
312.2484741	0.14
313.2808228	0.13
315.3930054	0.05
317.2760010	0.09
318.0067444	0.03
322.0315552	0.16
323.3482971	0.01
328.2636719	0.16
329.4311523	0.13
330.3514404	0.24
331.2138672	0.05
332.3428345	0.06
333.3249512	0.08
336.2991943	0.22
341.1043701	0.07
342.4682617	0.10
344.0526733	0.04
345.4125366	0.05
348.6679688	0.10
354.3020020	0.01
356.4334106	0.10
358.2344360	0.17
359.3005981	0.06
360.3831787	0.50
361.2429810	0.16
362.2727661	0.41
364.5272217	0.06
370.3933716	1.13
371.1526489	0.22
372.3395996	2.02
373.2972412	0.39
376.2826538	0.02
378.4149170	0.16
379.6393433	0.02
380.3690186	0.11
388.2690430	4.11
389.1588135	0.65
390.3122559	1.81
391.3419189	0.49
398.5498657	0.04
401.5476685	0.07
404.2299194	0.38
405.0267944	0.17
406.3405151	0.54
407.3782959	0.54
408.3400269	0.44
416.2802734	13.45
417.3905640	3.01
418.3369751	0.50
425.4490967	0.04
432.4039917	0.07
434.2636108	34.16
435.3574219	6.91
436.7245483	0.04
445.4445190	0.01
450.3329468	0.25
452.2778931	100.00
453.2698364	14.73
453.9385376	0.06
494.4553833	0.08
495.2225342	0.02
499.4884644	0.02
510.4117432	0.05
524.2163696	0.05
532.6482544	0.02
540.4113159	0.03
542.2502441	0.21
543.3616943	0.03
550.3941040	1.01
551.3198853	0.25
552.2585449	0.33
555.0756226	0.15
560.5126953	0.09
568.2929077	1.53
569.2991333	0.52
570.2291260	0.12
570.9895630	0.05
578.2420654	0.32
579.4580078	0.06
580.5432739	0.05
586.6478271	0.03
593.2086792	0.10
596.3527222	29.10
597.3811646	10.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.1979
Annotation	Abelioside A
Peak:m/z	Relative Intensity
150.0848083	0.02
165.1471405	0.05
179.2484741	0.05
182.1083984	0.05
186.1734009	0.02
192.9331665	0.07
195.0151825	0.03
201.3513336	0.02
201.9591675	0.10
207.1888733	0.05
208.9733582	0.04
217.1555939	0.17
221.3090820	0.08
229.0274963	0.04
231.1822815	0.05
245.1980286	1.06
251.1257477	0.10
253.1255035	0.21
255.0874939	0.18
257.5023193	0.09
261.1466675	0.19
273.1189270	0.03
275.1499939	0.09
279.0603638	0.08
283.1527100	0.50
289.3466797	0.18
291.2590637	0.12
293.2391357	0.07
295.3746338	0.08
299.1146851	0.16
301.4334717	0.59
303.3058472	0.07
307.1921997	0.65
309.4517212	0.05
317.3190918	0.19
319.3747559	0.15
325.3067627	0.02
327.3074951	0.10
329.0833740	0.17
335.2216187	0.28
337.4468384	0.02
342.3651123	0.06
345.1578369	0.76
347.2881470	1.05
359.4646606	0.09
361.2591553	0.17
363.3380737	4.21
375.4196777	0.09
377.4810181	0.06
381.4147949	0.03
405.3964233	0.33
406.3341675	0.04
436.1704102	0.09
437.1917114	0.03
447.2474365	0.05
463.1008301	0.17
479.4313354	0.59
481.4085693	0.79
491.3679810	0.22
495.3184204	0.13
497.4818115	0.09
507.3098755	100.00
508.6029663	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.14
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
132.8132629	0.31
134.7805481	0.33
143.1457520	0.47
153.1670227	0.90
160.8928528	3.07
167.0507202	4.49
173.9024506	0.42
175.8504944	0.41
177.9610596	0.12
178.8715363	0.42
181.2232971	0.33
182.1210938	0.37
191.2802429	0.51
194.0509338	6.39
195.2268829	0.11
207.0368347	27.44
209.0697021	100.00
223.2087097	0.45
223.9010773	0.25
227.1006927	18.22
231.1056824	2.05
235.2753601	0.27
241.2286072	3.18
249.1031799	28.12
255.0619202	3.90
267.0966492	15.78
269.1978760	0.18
296.9252014	0.41
301.4589233	0.38
309.0506592	1.17
325.1070251	1.09
327.2163086	0.16
341.0828857	1.28
355.2489929	2.18
357.1279602	4.20
370.3777161	3.16
371.0092773	9.42
373.2486267	1.21
381.1128235	1.27
385.1725464	19.83
399.2641907	33.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.1979
Annotation	Abelioside A
Peak:m/z	Relative Intensity
158.9462585	0.41
161.0231476	1.53
166.9455261	0.13
168.9752502	0.56
170.1484375	0.22
170.9390717	0.05
177.2980652	0.08
178.9447479	0.27
182.7750092	0.26
184.2205048	0.17
193.3603210	0.08
195.1286926	0.26
211.2923279	0.39
213.1926270	0.26
214.2509003	0.07
219.0469666	0.37
221.2022705	3.39
223.0766449	0.39
237.3086090	0.80
239.1529541	44.68
257.2426758	9.24
273.1428223	0.38
275.1141968	2.32
283.1336060	4.63
301.2714233	8.50
335.0343018	0.42
345.1647949	100.00
345.7901001	0.47
363.1945801	2.92
381.0761719	0.31
382.9829712	0.10
424.3484497	0.10
437.1517944	2.49
463.2305908	0.41
479.2434082	0.26
481.1833496	18.72
481.8427124	0.12
507.3618774	2.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	473.1147
Annotation	Unknow
Peak:m/z	Relative Intensity
150.3675995	0.10
156.9345398	0.01
162.8870544	0.02
163.8655396	0.08
175.0100708	0.02
179.0269623	0.04
188.7319946	0.04
190.9960785	0.23
194.0798950	0.08
205.1860962	0.51
218.2388000	0.07
223.2259064	0.02
231.1664276	0.05
249.2211914	0.90
255.2341003	0.05
265.1990662	0.08
266.9744263	0.08
279.0299072	0.03
281.1047668	100.00
283.0429382	0.06
285.0913696	0.31
299.0476685	0.21
300.0219421	0.12
301.2915039	0.11
307.1145325	0.05
323.1175537	0.13
337.1451416	0.06
341.1806641	5.18
343.1942139	0.12
345.0898743	0.13
351.0603027	0.03
354.1022644	0.02
356.1289978	0.22
358.1729736	0.08
358.9436035	0.02
369.1025391	0.38
384.6878052	0.11
386.7659302	0.18
388.6978455	0.14
389.3318176	0.12
393.3478394	0.05
411.2345276	0.06
413.1639709	0.16
425.9815369	0.09
426.9868469	1.77
428.9375916	0.10
430.3872375	0.03
437.0411682	0.05
446.0085144	0.09
454.7692261	6.92
455.5167542	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.2345
Annotation	gibberellin A2 O-beta-D-glucoside
Peak:m/z	Relative Intensity
159.2519989	0.04
169.1405945	0.06
179.0980988	0.09
189.2431793	0.04
191.1893463	0.06
201.2275848	0.18
203.4682770	0.08
215.4846497	0.09
239.1954041	0.51
241.4364929	0.03
243.1177979	0.14
253.2674561	0.05
255.1907654	0.15
256.2331543	0.17
257.2513428	0.84
259.2779541	0.41
265.2645264	0.05
273.3753052	0.08
274.2340088	0.10
275.5035400	0.14
282.2393799	0.07
283.1742554	0.45
285.1906128	0.19
289.2433777	0.19
299.4204102	0.16
301.2120361	7.82
303.3280640	10.69
304.2920532	0.22
306.6652832	0.02
315.4161987	0.13
317.3261108	0.79
319.2345581	4.80
320.1589966	0.14
327.2592163	0.59
329.2786865	2.99
330.2471924	0.08
335.4135742	0.11
337.5183105	0.03
341.3565674	0.08
343.2009888	0.10
345.2078247	12.08
347.2438354	100.00
348.2796021	0.72
349.1032715	0.16
355.5162354	0.16
359.0792847	0.02
361.1475830	0.15
363.1473389	49.26
364.3154297	0.31
371.6629028	0.05
375.3068237	0.10
377.3161621	0.05
381.3294067	0.60
385.2359009	0.04
394.4646606	0.17
405.2595825	0.48
406.1774902	0.20
408.4316406	0.05
409.4408569	0.04
417.2822876	0.67
418.2199097	0.27
419.5889282	0.06
435.3425903	0.06
436.3390503	0.10
445.2929688	0.05
447.2003174	0.51
451.3352051	0.09
452.2211304	0.06
453.3184204	0.17
459.3522949	0.10
463.3049316	0.59
464.4354248	0.12
469.2337036	0.21
477.3706665	0.07
479.3847046	1.29
481.3455200	22.47
482.4290161	1.61
483.4023438	0.08
487.2870483	0.07
489.1895142	0.50
489.9365234	0.07
496.5946655	0.09
497.3246460	0.04
505.5326538	0.04
507.2796021	10.89
508.1611328	0.83
509.8884277	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	691.3541
Annotation	Nicandrose C
Peak:m/z	Relative Intensity
255.3658752	0.11
275.5067749	0.03
303.1287231	0.12
308.4767456	0.15
319.3898315	0.08
345.1906128	0.04
347.0832825	0.12
348.0770874	0.25
351.1998291	0.09
355.3665771	0.05
365.3749390	0.12
366.6651001	0.47
367.6042480	0.27
420.4309692	0.09
429.0025024	0.24
431.3950806	0.31
448.5426636	0.13
460.9876709	0.26
463.4552612	0.05
465.4193115	0.11
466.3071899	0.08
467.1126709	0.28
468.4822998	0.05
481.1299438	0.09
483.4400024	5.89
485.3579102	0.17
489.4177856	0.06
493.5982056	0.12
497.5092773	0.18
499.3188477	0.12
507.3396606	0.06
508.3927612	0.17
509.5725098	0.40
510.4088745	0.20
511.2572021	1.51
514.3557129	0.10
524.3526001	0.06
525.2494507	0.09
527.6527710	0.23
529.2114258	6.31
533.4563599	0.22
543.1544800	0.04
547.0676880	0.07
551.2841187	0.16
555.5438843	0.04
557.3167725	0.07
571.3228149	0.10
576.3845215	0.05
585.4712524	0.07
595.2105713	0.25
605.4443970	0.13
607.2338867	0.11
612.9204102	0.10
629.6385498	0.08
631.4725952	0.17
645.3329468	100.00
645.9395142	0.61
647.3002319	0.70
655.3150024	0.28
659.8023071	0.04
661.6622314	0.19
672.3223877	0.16
673.4417725	1.49
674.5044556	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.2818
Annotation	Unknow
Peak:m/z	Relative Intensity
178.6033325	0.15
197.0057068	0.22
241.0144806	0.11
262.9242554	0.38
284.3160706	0.21
290.3439331	0.09
300.1104126	0.15
302.3538513	2.11
307.3449707	0.17
328.5058594	0.13
329.1755981	0.41
330.3677979	0.13
337.3995972	0.25
346.2583618	0.81
355.2900391	19.21
356.4007568	0.30
364.4683838	0.06
365.1918945	0.14
369.3821411	0.16
373.3772583	100.00
381.6087646	0.23
385.1493530	0.23
397.3698120	0.17
399.3649902	3.02
401.6388550	0.12
404.7325439	0.22
417.4114380	2.24
425.5562134	0.13
429.1534424	1.39
431.3330078	0.31
443.3245850	3.93
461.1806641	17.73
462.0486450	0.45
463.0222168	0.06
464.2854004	3.58
475.2693481	0.12
480.7717896	0.17
482.3646240	1.06
492.3750610	2.70
494.4609375	0.63
508.4612427	0.94
511.1580200	0.20
517.4956055	4.59
518.3780518	1.56
525.3440552	1.49
527.1390991	0.27
531.2105103	0.39
535.3109741	22.64
536.3814087	1.62
552.6246948	0.56
561.3538208	73.46
563.1392212	0.31
577.0314941	2.66
579.3738403	65.43
592.5640259	0.62
594.6739502	0.17
603.4390259	0.23
605.3130493	3.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	432.1485
Annotation	Unknow
Peak:m/z	Relative Intensity
191.0013123	0.12
202.0964966	0.07
240.1146545	0.08
269.1914062	15.78
278.3898621	0.16
284.2013550	0.22
286.1929932	0.34
295.8591309	0.13
296.4727173	0.15
301.1265259	100.00
301.7624207	0.25
310.1899719	0.61
312.0856934	1.00
313.2288208	0.04
314.3094788	0.20
336.1158447	0.29
340.0416260	0.22
342.2943420	0.19
345.1741943	10.32
352.2966919	0.10
356.1772766	7.11
356.8445435	0.19
367.5986938	0.11
386.7196960	0.65
388.1618347	5.52
393.8116150	0.05
396.0433350	0.48
406.2112122	0.06
414.3143616	0.40
415.1287231	0.05
417.2561951	0.13
432.1505737	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	557.26
Annotation	Cuniloside
Peak:m/z	Relative Intensity
160.8956299	0.28
179.1203613	0.24
202.4175415	0.02
207.2121277	0.04
227.1411591	0.06
243.9894104	0.10
275.3133545	0.02
341.2083740	0.03
345.3087769	0.03
347.1697388	0.16
348.2014771	0.44
349.3680420	2.58
367.3538818	0.16
371.3634644	0.05
373.5044556	0.02
377.0743408	0.04
387.4052124	0.08
389.3883057	0.03
390.3316040	0.01
391.3139648	0.10
394.4141846	0.11
398.1348267	0.02
409.1288452	0.12
415.0051880	0.07
433.2440796	0.17
439.2777100	0.03
443.4594727	0.04
444.4003906	0.10
451.0126953	0.14
461.3285522	0.01
465.3972778	0.03
467.6700439	0.07
469.7861938	0.10
471.3121948	0.11
480.9677734	0.04
494.6295166	0.05
495.2783813	0.06
497.4855347	0.05
508.8750000	0.06
511.2793579	100.00
512.0499878	0.21
513.3638306	0.12
519.3247681	0.21
521.5640259	0.08
525.2449341	0.04
537.2708740	0.02
539.3652954	1.05
542.1263428	0.06
547.5646362	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	392.1905
Annotation	Orysastrobin
Peak:m/z	Relative Intensity
113.1300430	0.05
114.1183167	0.01
121.0717621	0.16
132.8401184	0.03
135.1254578	0.31
136.0437012	0.10
142.1057739	0.04
145.1710510	0.05
148.9696655	1.02
150.0232391	0.56
158.0393982	0.02
163.0105743	2.40
166.9532471	5.01
167.8339996	0.19
175.4456635	0.03
177.3285217	0.10
179.9848328	0.33
181.0953064	0.10
192.2685852	0.08
192.9936218	0.33
195.0284424	3.69
199.0609283	0.03
213.0526733	100.00
213.8908234	0.02
227.2475281	0.01
229.4682922	0.37
230.1058960	0.24
232.8658142	0.02
236.0958252	0.06
238.5500488	0.02
250.8367004	0.02
260.4547729	0.26
261.6097412	0.08
269.2064209	0.09
271.1617432	0.02
275.3425903	0.04
279.2314758	0.22
279.9959106	0.16
284.7880249	0.05
286.0419312	0.02
287.3397522	0.05
290.0941467	0.12
294.0034790	0.09
295.3903809	0.02
302.1918335	0.06
303.1748047	0.03
304.1244507	0.06
310.7729797	0.26
318.4965820	0.15
319.4614868	0.06
320.8653564	0.09
322.0751648	0.03
326.1903076	0.12
336.8620605	0.05
338.2199097	0.23
339.1762695	0.02
346.3100586	0.26
347.3809814	0.14
356.4145203	0.31
357.3655396	0.43
361.2115784	0.10
364.1461792	0.08
374.2685242	0.64
375.1403503	0.38
382.8629456	0.23
383.4656067	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	679.2944
Annotation	Hv-NCC-1
Peak:m/z	Relative Intensity
203.8808746	0.24
204.6938629	0.09
218.0412445	0.17
229.0257416	0.14
235.1747131	0.15
236.2072754	0.06
246.3016205	0.94
248.9121246	0.25
271.2858887	0.50
287.3089600	0.19
293.1983948	0.07
299.1778564	0.43
313.2935791	0.37
315.1942749	0.82
323.3221130	0.45
330.5037842	0.32
337.0516968	1.33
341.2922974	0.71
343.2526855	0.23
357.2940063	0.13
359.3903809	0.44
369.2418213	0.21
371.3037109	1.42
373.1005859	0.52
375.4461060	0.18
383.0581665	0.08
401.3031006	1.80
415.5183716	0.78
428.2421875	0.09
429.4616089	0.14
433.1642456	1.07
446.2200317	0.08
450.2736206	0.64
464.2632446	15.22
472.1205444	0.18
476.3639526	0.71
482.3726807	0.98
484.4725342	0.11
490.2901001	7.79
494.0944214	0.20
496.1403809	0.28
499.6738892	0.44
502.2938232	0.90
508.1122437	6.80
508.7603760	0.04
512.2415161	0.30
514.1867065	1.20
517.3715820	0.82
518.6049194	0.16
522.2723389	26.06
524.3874512	0.08
526.2422485	0.63
540.6407471	0.07
543.5918579	0.37
557.1766968	0.49
561.9308472	0.40
567.2544556	0.30
573.4425659	0.14
576.1862183	0.08
585.2755127	0.41
587.3494263	1.20
591.0910034	0.16
593.2739868	0.18
593.8831177	0.09
597.9274292	0.18
603.1661377	2.99
604.2445679	0.21
606.3713379	0.40
611.3074951	2.32
614.9552002	0.64
619.2112427	2.07
629.1516724	12.07
638.0360107	0.43
639.1098022	0.67
643.1066895	7.19
643.7273560	1.91
647.2832031	100.00
648.0392456	1.29
656.2245483	0.15
661.1683960	4.69
662.0504761	0.19
664.3964233	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	434.2006
Annotation	Unknow
Peak:m/z	Relative Intensity
122.9630661	0.49
136.0494843	6.37
146.9910583	4.42
165.0253754	17.07
177.1004639	0.16
182.0029755	100.00
221.0466461	0.09
253.1747437	0.19
255.1878052	0.07
264.2687988	0.24
301.9458618	0.11
308.2232056	0.55
351.4509277	0.47
390.1414185	0.08
404.2898865	0.14
415.2645569	0.07
416.1639099	0.10
417.0045471	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.2137
Annotation	Abelioside A
Peak:m/z	Relative Intensity
168.9487305	0.11
253.2077026	0.67
271.2426758	0.04
272.3858032	0.03
299.4330444	0.05
315.2500610	1.01
331.2373047	0.02
343.5360107	0.03
359.2999268	5.19
360.5322876	0.03
371.2356567	0.06
377.3143921	2.65
409.2928467	0.05
432.8780518	0.07
441.3989258	0.07
451.4666138	0.06
453.1387939	0.07
479.3035278	0.06
493.4234009	0.03
495.1006470	0.29
496.1223145	0.08
511.4897461	0.09
521.2872925	100.00
522.0281372	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
93.02516174	0.28
95.18721771	0.30
96.88362122	0.23
98.57817078	0.28
104.896637	0.16
109.1863098	0.33
110.9992447	0.29
113.0112	0.57
117.0300293	0.10
120.8503571	0.63
123.0201416	0.97
124.9982452	1.57
126.9151001	1.22
128.7236023	0.37
131.1187134	0.15
133.0067749	0.93
135.126297	0.55
137.0050049	0.82
138.9746094	2.85
141.0530701	0.99
142.8733521	1.07
145.0882568	0.62
148.9100952	0.64
151.01828	0.39
152.0587769	0.16
153.1195679	2.58
154.9750061	1.24
156.9140778	0.29
161.0169678	1.14
163.0350342	1.44
165.0410767	0.70
166.9507904	0.88
169.0883331	0.53
170.9880066	0.38
173.3043823	0.25
175.2022705	0.96
176.8078918	0.13
179.1783752	0.10
180.0116882	0.26
181.0708008	3.18
183.0188599	0.25
187.1741791	0.29
190.9607849	0.80
193.0982056	0.78
194.9483337	3.79
197.0644989	2.30
199.0240021	1.04
203.1721802	0.40
204.0513916	0.13
207.1333313	1.32
209.2905273	1.65
211.1914368	5.12
213.0957031	1.13
214.8311768	0.25
217.3411255	0.28
219.2762146	0.10
221.1238403	1.98
223.0195923	0.75
225.1477356	1.46
227.1184082	2.26
229.224762	0.79
230.9503784	1.48
233.1552429	0.81
235.1247864	2.59
236.9595947	1.73
239.0548401	0.89
241.3345337	1.13
243.1101685	0.26
243.8769226	0.12
247.3526306	1.08
249.0966492	1.06
251.2894287	3.06
252.6944885	3.93
253.3079529	5.41
254.095459	0.21
255.1350098	1.36
257.2498779	0.94
261.2287292	0.25
265.0968018	2.95
267.0811157	1.55
269.067749	1.41
269.7001343	0.35
270.6113281	0.47
275.2238159	16.03
276.3085022	0.33
283.2879639	0.39
290.1905518	1.50
291.2697144	0.26
293.2033386	100.00
294.3970947	0.92
302.2070618	0.16
311.2190552	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	573.26
Annotation	Canavalioside
Peak:m/z	Relative Intensity
178.9553680	0.30
207.2899170	0.17
223.1006470	0.15
238.9306335	0.13
241.1397705	0.03
247.3879089	0.07
275.3685303	0.03
280.0101318	0.05
299.0787964	0.07
303.4609375	0.16
335.3602295	0.06
347.2280273	0.30
352.2840576	0.04
365.3765259	19.66
367.2823486	0.08
373.3238525	0.03
407.6483765	0.07
409.8480225	0.24
411.2353516	1.02
444.1008301	0.17
445.0764160	0.12
446.0377197	0.05
449.1884155	0.15
450.0626831	0.03
453.4356079	0.03
455.0689697	0.05
457.4909668	0.05
470.9298096	0.14
477.1233521	0.17
497.3845825	3.10
509.5289917	0.03
510.3176880	0.06
511.2120361	0.04
525.1149902	0.15
525.8865356	0.12
527.2149048	100.00
528.0989990	0.57
529.2511597	0.98
531.5141602	0.04
534.8267822	0.35
542.0427856	0.14
549.7569580	0.06
550.5427856	0.45
553.3438721	0.58
555.2114868	1.42
555.9439087	0.34
564.1118774	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	968.4211
Annotation	Unknow
Peak:m/z	Relative Intensity
287.2297363	0.11
293.5336609	0.15
306.1946106	0.73
324.2901611	0.95
353.1695557	1.54
394.5538940	0.05
419.3673096	0.23
436.2877808	0.10
437.7894287	0.30
443.9607544	0.24
462.3262939	0.82
476.3002930	0.51
489.6172485	0.06
547.5178223	0.15
556.2494507	1.53
581.4993896	0.16
587.6409912	0.30
612.2915039	0.26
613.2484131	1.11
625.4376221	0.22
642.8518677	0.31
643.6149292	0.16
644.3039551	0.15
651.5516968	0.22
669.6101074	0.45
701.3242798	0.39
708.3218384	0.11
719.3357544	0.29
726.2593994	1.53
727.2792358	0.14
744.8599243	0.69
756.3728638	0.89
762.6063232	0.33
770.2557983	0.12
776.3554077	3.27
788.2965088	1.28
806.4215698	5.24
807.0984497	0.12
825.5040283	0.29
837.3049316	0.11
842.6356812	0.29
863.4308472	1.33
876.5055542	0.09
881.4919434	15.52
906.2922363	0.38
920.4047241	2.81
932.3532104	0.64
938.4086304	100.00
939.4843140	1.74
949.8676758	0.12
950.4770508	14.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	737.235
Annotation	Unknow
Peak:m/z	Relative Intensity
215.0411835	0.79
216.9816284	0.28
219.1284790	1.73
221.1731110	0.29
227.1681213	0.68
229.0145721	0.59
232.4669342	0.41
233.0824280	0.43
239.1588135	0.25
242.9373474	0.29
244.5459595	1.47
245.1559753	9.67
247.0829773	1.28
261.0922852	0.44
263.0958557	3.13
265.2403564	11.80
276.9488220	2.63
283.1774292	5.98
286.9835205	1.38
289.1083679	3.33
291.2597046	0.37
294.8715820	1.05
303.2024231	2.10
305.0361938	31.74
311.0949402	0.34
313.2922058	0.96
317.2843323	3.48
319.1630554	2.40
321.0654602	3.95
329.1148376	0.20
334.6954346	0.42
337.2468567	9.41
339.2884521	0.30
341.0491943	1.31
343.0937500	0.19
346.8752441	1.50
349.1510315	1.00
351.0311279	0.21
359.0004272	1.48
360.7426147	2.34
361.3843384	0.66
371.0860596	2.06
373.2737427	0.34
376.1228027	0.65
376.9440308	1.06
379.2010498	0.49
381.1657715	0.31
390.9713745	0.43
395.0767822	3.22
397.2509766	18.30
401.1177979	0.51
403.1859741	0.16
405.4230957	0.21
409.6261597	0.40
415.2629395	14.68
433.2325439	0.11
437.3184814	0.45
439.0063477	0.19
449.2265625	17.18
454.1683350	0.59
455.0038452	2.13
461.1083984	0.60
466.3524780	0.33
472.4655151	0.37
473.3580933	0.16
478.4807739	0.45
480.3283081	0.23
481.2769165	5.63
482.7212524	0.43
485.2598267	1.34
491.1813354	2.43
493.2747803	0.36
495.2254028	0.59
509.3092041	0.99
511.2423096	4.73
523.3168335	1.14
525.2315674	0.62
529.1699829	20.81
530.3600464	0.34
534.8315430	0.15
537.3646851	0.21
543.2739868	0.94
553.1867676	0.87
555.3896484	4.25
556.2308960	0.76
557.2669067	1.05
561.1139526	3.49
562.8140869	0.66
570.7727661	1.69
573.1719971	2.08
574.1453247	0.41
575.1533813	2.10
585.3485718	0.88
587.4431763	2.56
599.3510742	0.29
604.0957642	2.96
605.2898560	4.53
638.9511108	0.47
658.3823853	4.53
659.2489014	0.24
661.3505859	39.36
676.4176636	4.51
677.1409302	2.13
691.2758179	0.54
693.3887329	7.95
694.6912231	0.92
701.1538696	0.33
705.2183228	100.00
706.1026001	0.69
718.3327026	0.10
719.3118896	4.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	413.218
Annotation	Desacetylvindoline
Peak:m/z	Relative Intensity
128.6047363	0.21
160.0890198	0.31
166.1397705	0.20
170.2150269	0.23
179.1199646	0.18
194.9647217	0.09
208.980072	0.78
217.319809	0.33
223.1718292	0.50
228.190033	0.19
233.3673706	0.28
251.184906	0.70
254.7457275	0.22
257.1489258	0.92
259.5401306	0.19
267.0664368	0.53
271.3077087	0.38
299.8428955	0.23
305.1052856	0.69
317.3921204	0.89
327.1914368	0.30
333.8096313	1.52
339.2489624	0.45
345.9488525	0.12
351.4651184	0.05
353.1955261	100.00
359.1927185	0.63
367.255127	15.67
368.2013855	0.28
369.2195129	0.50
371.3580627	2.64
375.0702209	0.22
377.1896057	1.58
377.9703369	0.65
381.1091003	0.18
394.4904785	1.25
395.207428	2.02
395.8359985	0.09
396.4682922	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	614.26
Annotation	Unknow
Peak:m/z	Relative Intensity
171.9498749	0.14
174.9061279	0.04
176.9995270	0.32
178.1781464	0.38
179.0903473	0.12
180.1248016	0.33
181.1999664	0.19
183.4050751	0.27
185.1319885	0.20
185.8039856	0.05
190.1874084	0.09
191.3287964	0.14
192.7762299	0.25
193.9421692	0.63
195.1805420	0.22
196.1164246	0.39
197.1647797	0.70
198.1414642	0.36
199.1300659	0.35
201.0607452	0.68
203.7253571	0.08
204.9906158	0.34
206.0243073	0.33
207.1872864	0.04
208.0304108	0.25
209.1909485	0.72
210.1466370	0.44
211.2124176	1.60
212.0074158	0.19
213.1043396	0.19
214.1125488	0.19
218.2406616	0.08
221.2358398	0.05
222.3449707	0.10
223.0414734	0.34
224.1494446	0.55
225.3227997	0.42
226.1707153	0.23
226.8917847	0.08
228.1408386	0.03
229.0236969	0.18
231.4628143	0.16
232.3186798	0.06
234.2819214	0.24
235.1978760	0.37
236.2612305	0.04
237.3751221	0.12
239.0829773	2.98
239.8167725	0.16
241.2588501	0.40
243.1094666	0.36
246.8380127	0.42
248.1116333	0.06
249.1950531	1.20
250.1187744	0.25
251.3297424	0.96
252.3134155	1.41
253.2534637	1.07
254.0755463	0.42
255.1929016	0.45
255.9479675	0.37
257.2844238	1.14
258.5233459	0.27
259.3139038	0.07
260.1148987	0.13
262.0558472	0.26
265.2941589	0.30
266.3297729	0.48
267.2607117	1.98
268.2257385	1.23
269.3844604	0.39
270.2254333	0.20
271.0041199	0.22
272.1517639	0.11
276.2059631	0.60
278.2947998	0.32
281.0847168	0.49
282.2306519	0.29
283.0046387	0.14
284.8614197	1.59
285.9672852	0.47
287.2667847	1.22
288.1469116	0.19
292.3991089	0.17
293.2228394	0.16
294.2450562	0.31
295.3538818	1.13
297.1581421	0.33
298.2677002	0.61
299.2606812	0.43
300.1257935	0.42
300.9858093	0.23
302.2105103	0.72
302.9677429	0.29
304.2362976	0.03
305.9412842	0.23
308.3477478	0.44
309.1775208	0.28
310.2238159	0.16
312.1630249	1.65
313.3071899	0.49
314.3017578	0.70
315.2169189	0.43
316.3375854	0.35
320.2402954	0.56
322.3761597	0.24
324.1491699	0.34
325.0979309	0.20
326.1749878	0.20
327.1284180	0.69
328.2306519	0.93
329.4605103	0.48
330.2951660	3.77
331.3629761	0.50
332.3306274	0.25
333.1427612	0.13
335.9610596	0.20
342.3917847	0.87
344.1254272	1.52
346.5598755	0.49
347.1924438	0.15
348.3903809	1.75
349.4675293	0.26
352.3526611	0.53
355.2316284	0.05
360.3175049	2.20
361.6210938	0.65
362.3696289	1.35
363.2824707	0.36
368.0667114	0.06
369.5784302	0.17
370.2896729	4.75
371.4982910	0.37
372.3721924	0.75
374.9929199	0.41
376.0373535	0.08
380.2929077	1.49
388.2155151	23.05
389.2428589	2.72
390.6087036	0.24
398.2758789	0.70
399.3519287	0.06
400.3632202	0.18
404.5846558	0.09
406.2097168	5.43
407.0290527	0.34
408.4050293	0.37
414.4290771	0.05
416.2589722	11.56
417.2640381	2.45
418.2866821	1.31
419.1036377	0.15
424.2907104	0.14
432.2455444	0.17
434.2286377	100.00
435.2092896	17.53
435.8345947	0.02
447.3142090	0.12
450.3067627	1.95
451.4896851	4.45
452.3126831	30.78
453.3641357	1.96
464.2329102	0.28
465.3143311	0.15
473.3644409	0.16
474.3757324	2.65
476.1523438	0.42
482.3460693	0.18
490.7050171	0.19
492.3462524	0.34
493.3253174	0.47
500.4060669	0.16
510.4653931	0.69
513.5623169	0.35
516.5290527	0.44
524.3023071	0.15
524.9806519	0.11
540.1937866	0.04
542.5219727	0.64
543.3609009	0.86
549.5617065	0.14
550.3245850	0.76
551.4284668	0.29
552.5523682	0.20
560.5020752	0.06
568.4232788	3.15
569.4876099	0.20
570.4293213	1.22
571.4082642	0.09
578.6945190	0.06
586.5854492	1.69
587.5275269	0.23
596.3181763	52.86
597.4182129	10.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	351.2157
Annotation	Rabdokunmin D
Peak:m/z	Relative Intensity
100.9841309	0.60
105.0632172	0.53
121.9438477	0.15
122.8783417	0.80
126.7856522	0.11
128.4539490	0.08
133.0628815	0.36
145.1220551	0.06
148.7999573	0.25
156.9979858	0.18
159.0290680	0.28
162.9107056	0.41
165.1894379	0.10
166.9886932	0.33
172.8567200	0.33
179.3074646	0.10
181.1204987	0.13
182.0786743	0.07
183.0975342	0.30
188.8923035	0.14
191.0220032	0.36
193.0761566	0.16
202.6601257	0.17
207.2915955	0.71
212.1912231	0.56
214.1655273	0.09
218.8430176	0.06
235.1689148	0.16
236.0577393	0.11
245.2760620	0.56
251.0588379	0.13
257.5246277	0.26
259.2863464	0.48
261.0801086	0.38
262.0173035	1.16
262.9884949	0.14
265.1876831	0.23
269.2074585	1.05
270.1219177	0.34
271.0916138	0.10
273.2314148	0.09
279.5622253	0.26
283.4670410	1.14
284.1375427	0.29
285.0149536	0.46
287.1443481	4.67
287.8022156	0.06
288.8935242	0.06
291.2321777	0.32
297.2355957	0.69
302.0325623	0.39
303.1771240	0.14
304.6312256	1.84
305.2900085	17.71
307.3365479	0.08
308.3710327	0.31
309.2060852	0.23
311.0792236	0.12
315.1577148	2.37
316.3695068	0.59
318.2379456	0.23
319.8880005	0.15
323.2906799	0.49
327.6884155	0.06
331.0561523	0.25
333.0545044	100.00
333.9461060	0.80
336.1771851	0.33
337.1736450	0.06
342.3554382	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.06
Annotation	Sedoheptulose
Peak:m/z	Relative Intensity
58.8564034	2.05
60.8955040	0.64
70.9937134	3.18
81.0459595	2.88
82.8932343	1.62
84.8826447	98.98
86.9640808	14.67
92.9877319	53.53
95.8708496	0.65
98.8376923	2.17
109.0030365	21.48
110.8619080	37.14
114.9427948	0.50
124.9330902	0.62
126.9986725	100.00
128.8646851	3.07
137.0954132	1.54
142.9730988	1.68
144.8705902	0.76
146.9452515	2.05
153.0453949	6.33
155.0325470	10.37
171.0144348	31.98
173.0557709	82.74
191.0061493	5.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.0984
Annotation	Deacetylasperuloside
Peak:m/z	Relative Intensity
110.8840714	0.03
113.0396576	3.09
116.7635422	0.05
118.9692535	0.05
121.0745850	4.75
128.9446716	0.29
131.1409302	0.11
133.0510712	0.06
139.0456390	0.03
145.0466309	0.04
157.0733032	0.31
163.0925598	0.05
169.0631104	0.19
173.0705566	0.07
175.0480042	1.02
179.2332001	0.04
189.0325928	0.03
192.9700623	1.08
195.1903992	0.04
205.1504211	0.25
209.3517303	0.06
223.2621155	0.12
231.0122375	7.23
249.0653381	100.00
250.1329651	0.33
253.0942078	0.19
282.2234497	0.05
283.0950012	0.04
295.3026733	0.19
310.9608154	0.47
326.3552246	0.61
327.3108826	1.03
335.1070862	0.05
353.1549072	4.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	643.2238
Annotation	Unknow
Peak:m/z	Relative Intensity
193.9862366	0.16
195.0820465	1.82
207.2603760	0.12
209.0683289	1.81
225.0837402	8.45
257.1064758	0.03
299.1593018	0.10
324.9441528	0.08
327.1544189	0.06
351.2969971	0.01
367.0258179	0.97
387.2453613	10.49
416.9387207	0.64
418.1622925	0.22
419.5260620	0.03
421.1929932	0.23
426.9652710	0.12
433.3089600	0.08
435.0169067	100.00
435.6669312	0.13
463.3639526	0.14
479.0078735	0.04
481.7683716	0.09
486.7484741	0.17
510.1074829	0.07
513.1410522	0.15
518.8703003	0.05
521.3740845	0.19
523.1932983	0.03
527.2843628	0.05
528.3750000	0.07
534.6469116	0.02
552.2402954	0.04
553.5197754	0.07
566.2907715	0.19
570.2811890	0.03
579.4072266	0.40
580.3401489	0.42
581.3978882	0.16
583.0518799	0.05
585.6373901	0.09
595.9988403	0.47
596.7254028	5.26
597.8158569	0.10
598.8069458	0.49
599.5027466	1.01
607.4583130	0.09
624.3494873	1.28
625.4093628	1.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	241.154
Annotation	Pirbuterol
Peak:m/z	Relative Intensity
69.9662552	1.26
82.0380249	0.36
83.8591614	22.48
84.8063660	0.28
95.9918823	0.04
97.9882202	3.45
100.0430298	0.65
104.9086609	0.10
111.0581665	0.14
114.0365295	0.36
116.0310669	0.67
124.0996704	0.14
126.0875854	1.40
128.0787354	31.53
129.1250458	0.27
129.9434204	0.03
136.1085663	0.08
140.1366425	0.09
141.2262726	0.16
142.9094391	0.19
144.0749359	15.52
145.2116547	0.28
150.0694122	0.81
151.9761047	0.82
154.2524567	0.12
156.9955597	0.07
158.0124359	1.89
165.0351715	0.06
168.0712433	3.64
169.0647888	0.18
171.8204193	0.09
178.0813751	0.26
184.1078339	0.31
196.0493774	100.00
197.0670776	1.38
198.0946808	0.35
199.9397736	0.29
213.1486359	4.87
223.1224213	0.71
224.0988464	0.48
241.2333221	1.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.1395
Annotation	Methyl (3x,10R)-dihydroxy-11-dodecene-6,8-diynoate 10-glucoside
Peak:m/z	Relative Intensity
120.7905273	0.06
123.1549149	0.12
125.0225983	0.27
132.7955017	0.07
134.5122070	0.02
135.2038879	0.14
137.2878418	0.05
138.0271759	0.06
138.9388733	0.46
141.0859680	0.02
147.1537781	0.08
149.1391449	0.04
150.8887939	0.02
152.1663055	0.08
153.1097412	0.17
157.1552582	0.04
158.9671021	0.17
161.0673218	0.27
165.1058044	0.06
171.0570374	0.06
173.0899963	0.27
175.1983643	0.23
176.1841888	0.44
177.0758972	0.94
183.1841431	0.04
185.1599426	0.07
188.9765015	0.03
191.2073975	0.10
193.6997070	0.05
195.0616913	0.20
197.1560059	0.09
199.2969818	0.20
199.9826965	0.04
202.8686981	0.05
205.1808472	0.16
207.0943298	0.10
211.0154114	0.27
213.1510620	0.06
214.9739990	0.25
217.2597046	0.61
218.8234253	0.28
221.0814819	0.16
225.1046448	0.24
227.2099609	0.74
228.1784058	0.03
229.0643311	0.53
231.1878052	0.12
233.1010742	0.81
235.2632141	0.20
237.0801086	1.36
238.2284546	0.05
243.2041931	1.32
245.3385620	3.11
247.2044983	0.21
249.3108215	0.04
252.5235291	0.17
255.1390686	4.36
259.1131897	0.47
261.2009583	0.65
263.3079224	1.13
265.4033203	0.08
266.0778503	0.06
271.1183472	0.29
273.1651611	49.69
274.0635681	0.06
275.0819702	0.10
279.0308228	0.03
281.2075195	0.07
287.4505005	0.12
289.1742554	1.15
291.2742310	31.51
292.1380310	0.10
293.0188293	0.02
299.2347412	1.53
300.3069153	0.10
305.2243652	0.12
307.2319946	0.12
315.0552063	0.02
317.1737366	22.72
319.2006226	0.40
330.9921875	0.03
333.2894592	0.35
335.1531372	100.00
336.2085571	1.08
341.3984985	0.11
343.4704590	0.33
345.0541382	0.05
349.3912659	0.25
351.1590576	0.05
359.2464905	0.04
361.2765503	3.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.1397
Annotation	Trichogoniolide
Peak:m/z	Relative Intensity
114.9373093	0.62
116.9762573	1.00
126.9987335	0.36
131.1244507	0.88
143.1633453	0.51
145.1412048	0.22
153.2201538	0.05
155.0946808	0.35
156.7660522	0.06
171.1189270	0.11
173.1580200	4.31
189.0750885	1.02
195.3938293	0.05
199.2350006	0.19
201.6185608	0.08
205.2069397	0.08
208.9933014	0.05
211.1749115	0.31
215.1269531	0.15
217.1107941	33.48
218.2282715	0.19
225.1339722	0.07
227.1968384	0.37
229.1793213	2.43
229.9490356	0.19
231.2120056	0.27
233.1761780	0.32
235.2382507	0.07
237.2705078	0.05
243.1503906	0.33
245.4255371	0.22
247.3881531	0.43
255.1042786	0.67
258.3095093	0.08
259.2291260	0.33
261.1578369	3.01
265.3590088	0.13
269.3463135	0.14
271.1737061	0.32
273.2362366	21.18
275.2910767	0.07
287.2341309	0.34
289.2240601	0.95
290.1969604	0.04
291.1728516	25.08
292.0680237	0.04
299.1638184	0.44
301.0802612	0.08
307.4200745	0.61
317.1651001	49.76
318.2925415	0.45
333.2203979	0.63
335.1932373	100.00
336.2576294	0.42
361.1127014	26.78
362.1936340	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	794.4017
Annotation	Unknow
Peak:m/z	Relative Intensity
262.1593933	0.02
349.4145813	0.05
382.5281982	0.01
529.3687744	100.00
530.4354248	4.86
751.0971069	0.01
767.5394897	0.01
1057.1315920	0.08
1059.1928710	37.71
1060.3492430	4.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1051.4762
Annotation	Taxumairol Y
Peak:m/z	Relative Intensity
317.2563782	0.12
329.1445923	0.22
345.2987976	1.08
363.3204346	2.40
377.4207153	0.05
507.2292786	0.21
523.3814697	0.66
525.2799072	100.00
526.4362793	0.36
527.4993286	0.45
557.6173096	0.04
650.1510010	0.03
660.4056396	0.09
687.3871460	0.04
740.6205444	0.37
801.1865234	0.12
802.0966797	0.09
809.2117920	0.08
810.8565674	0.07
824.4099121	0.03
841.4309082	0.08
853.0239258	0.11
888.6638184	0.18
932.2698975	0.06
964.2503662	0.04
973.7037354	0.07
1003.4167480	0.21
1033.4516600	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.13
Annotation	2,3-Butanediol glucoside
Peak:m/z	Relative Intensity
72.9074173	2.56
81.0547333	0.09
84.9242020	7.23
88.9901581	0.25
90.7213135	3.88
94.8392944	0.06
96.9991684	2.93
100.8604736	0.11
106.0169373	0.25
109.0499573	0.88
111.0669861	0.39
113.1547089	0.09
118.8436737	0.09
120.9897614	0.08
122.9729309	0.43
126.8938293	15.20
128.9826813	0.22
130.1809692	0.13
132.4225922	0.34
133.0681763	0.86
139.2829590	0.13
141.0143280	0.05
142.1297455	0.09
144.9170380	35.08
147.2976227	0.18
149.8735809	0.09
150.9543457	2.51
152.0720825	0.14
155.0875092	0.35
156.2780914	0.56
156.9752350	5.88
161.2651825	0.44
162.8748474	100.00
164.9861298	0.61
168.1213837	0.18
168.9659119	5.63
171.2407837	0.27
174.7519989	0.41
177.1556702	0.09
179.8185730	0.03
182.9967041	0.04
185.7801208	0.13
186.4841766	0.17
194.8262939	0.16
197.2955780	0.11
198.9427338	19.99
206.8600616	0.10
208.8013916	0.14
211.0613861	0.28
211.7810974	0.46
216.4330750	3.55
217.0581818	19.49
218.0644836	0.15
221.6634216	0.39
223.3120880	0.14
225.1754303	1.89
226.2661743	0.11
230.1060791	0.09
231.6143646	0.45
232.9897614	0.15
235.0095978	12.43
236.2526093	0.15
238.2021027	0.15
243.9361725	0.15
244.6554108	0.73
245.3212891	0.43
253.0926971	1.94
254.2320099	0.18
333.1299438	0.14
421.6183777	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	594.5622
Annotation	Unknow
Peak:m/z	Relative Intensity
184.0505981	0.05
195.1395874	0.11
197.1241150	0.09
209.0771790	0.17
214.1795044	0.04
219.1156921	0.06
231.0590820	0.14
237.3002930	0.03
247.3424377	0.04
250.9357758	0.03
252.8783569	0.09
257.1786499	0.05
260.7714844	0.21
264.4403687	0.17
266.2554932	0.16
267.3266602	0.06
278.1811218	0.10
295.2456055	1.59
296.3617554	0.46
304.3073730	0.24
305.5097351	0.14
308.2887573	0.12
311.0249023	0.26
312.5303345	1.78
313.3628540	2.52
314.3143616	0.21
315.0600586	0.09
322.4959106	0.25
323.2583618	0.13
324.3176270	0.33
325.7011719	0.19
326.5671387	0.10
330.3206177	13.63
331.4170532	1.24
332.2190552	0.09
340.3860474	3.07
341.2473755	0.11
342.3329468	0.05
347.4233398	0.10
354.1851807	0.18
355.2561035	0.20
358.0084229	0.53
373.4220581	0.06
389.5147095	0.06
419.2955322	0.08
436.4486694	0.16
441.5614014	0.09
459.3101807	0.17
460.6148682	0.14
462.4064331	0.08
465.5445557	0.26
473.3632202	0.12
474.5249634	0.42
476.8303223	0.09
477.8973999	0.17
490.6596069	0.18
492.4761963	0.27
493.3439331	0.11
494.2531128	0.50
500.1538086	0.10
506.2621460	0.21
510.9358521	0.05
516.4112549	0.21
517.4955444	0.11
518.9069214	0.08
521.2312012	0.23
524.1826172	0.14
527.6738892	0.22
532.3221436	0.09
533.6141968	3.28
534.3469849	19.19
535.3435669	4.88
536.6803589	0.05
544.6801147	0.13
545.3369751	0.21
548.3082886	1.52
549.4481201	0.33
560.7678833	1.27
562.2228394	0.96
565.3942261	0.14
566.5443726	0.14
567.3786011	0.18
570.6311035	0.15
574.4873657	0.07
576.6608276	100.00
577.6577148	24.11
578.5706177	1.59
579.5204468	0.17
594.5683594	0.64
595.6754761	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	443.1768
Annotation	Unknow
Peak:m/z	Relative Intensity
162.6253357	0.07
213.5533142	0.04
218.1521301	0.07
234.9057465	0.29
241.0635071	0.15
249.7736511	0.05
251.2284851	0.35
278.0649719	0.21
307.0360718	0.15
311.0346069	0.08
323.0623169	0.07
325.1162109	0.18
345.3992310	0.40
383.0519104	0.14
389.3999634	0.06
395.3546753	0.14
397.1752625	100.00
397.7838440	0.45
399.2791138	0.18
425.2084045	0.17
426.2057495	0.12
427.8028259	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	156.08
Annotation	L-Histidine
Peak:m/z	Relative Intensity
82.9015350	0.13
95.0153198	2.52
100.1209412	0.04
109.9255524	100.00
110.9664917	0.08
112.0316620	0.80
114.7347412	0.01
128.9720306	0.01
138.0183258	0.86
138.8974762	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2624
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
140.1953125	0.33
153.0195160	0.76
195.9373779	0.08
199.9879456	0.22
214.0256195	2.40
225.1228943	0.13
233.2342072	1.16
275.2933960	0.16
277.3012695	100.00
286.1812744	0.09
292.9537354	0.21
302.1997986	0.07
306.1295776	0.18
358.3110962	0.22
386.3450012	0.24
392.2444763	0.08
402.3102112	0.13
403.6467285	0.08
410.2507629	0.57
419.9387512	0.06
427.6833191	0.37
428.3451843	0.16
430.2992554	0.09
431.2882996	0.82
438.2452698	0.89
439.3547363	0.23
442.2344055	0.10
456.6304626	1.11
457.3494263	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	381.1533
Annotation	Trichogoniolide
Peak:m/z	Relative Intensity
137.0563965	0.05
167.0913086	0.03
178.9947357	0.02
181.5200043	0.09
183.6481934	0.02
186.6913452	0.11
206.0443726	0.09
235.3573608	0.16
237.4165039	0.17
242.0281372	0.12
242.9687805	0.04
250.0608826	0.03
255.2551575	0.46
259.1532898	0.02
270.1329956	0.08
273.0036621	0.11
281.1294556	0.06
288.4584656	0.06
289.8228149	0.04
292.8938904	0.09
298.5404358	0.03
299.1878662	0.05
300.0182800	0.02
301.0704651	0.41
303.1847229	0.09
309.2519531	0.09
315.5429077	0.07
316.9173889	0.27
317.5394592	0.02
319.1752319	0.22
324.6657715	0.07
327.1907043	0.33
328.1621399	0.19
335.1554565	1.65
337.1694946	0.10
345.2111206	2.24
353.2358704	0.64
361.1592712	0.18
363.0557556	100.00
363.7089539	0.31
365.1609192	0.14
366.3605652	0.20
367.0121155	0.05
372.0721130	0.68
372.7061157	0.04
375.1297302	0.21
380.9451294	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.135
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
160.9264526	0.16
165.1048279	0.05
175.1467743	0.02
177.0327911	0.07
179.3011932	0.09
187.0608215	0.11
198.0763397	0.18
200.7893677	0.09
203.1649170	0.56
204.8948669	0.31
209.1729126	0.05
211.8051453	0.09
217.0733032	0.03
225.0859375	0.14
226.8881989	0.11
229.1906128	0.05
230.1939545	0.18
231.0571594	0.07
243.1691284	0.05
245.1351929	4.01
253.0737762	0.12
255.0957336	0.36
257.2035522	0.24
257.9522705	0.03
261.0818481	0.12
263.2344360	0.06
269.1266785	0.48
270.1014404	0.12
273.0916748	2.74
275.1337280	0.06
281.3298340	0.06
287.1641846	8.16
289.1414795	24.00
299.0994263	6.29
301.0471191	0.48
303.2935486	0.06
305.4026489	0.04
306.1358032	0.11
308.9995117	0.11
311.0878906	0.08
313.1660156	0.12
314.2575684	0.09
322.9597778	0.02
327.2608032	0.13
328.9726562	0.26
331.1793213	0.54
337.5553589	0.07
339.0700073	0.27
341.2374268	0.86
350.3990479	0.05
353.1035767	0.04
357.3672485	0.09
367.1839600	0.58
368.2808838	0.69
369.3983154	0.11
371.2166748	0.37
381.2189941	1.03
389.1475220	0.08
392.3767090	0.05
395.3273926	0.07
401.1990356	0.11
404.7818604	0.16
405.5603638	0.07
407.2166138	63.61
408.2597046	0.11
409.3341064	0.39
410.6225586	0.25
411.3063965	0.09
414.0883789	0.02
415.1323242	0.22
417.1541748	0.10
422.9837646	0.25
425.2050781	100.00
433.0803223	0.52
437.3374634	0.15
445.1912842	0.32
447.1560059	0.14
449.3345337	0.47
451.1358643	31.40
451.8894653	0.21
456.4606323	0.18
467.1110229	0.74
471.3637695	0.11
473.4059448	0.03
489.2300415	0.20
491.0557861	0.39
493.1809082	0.23
497.2194214	0.03
501.6635132	0.07
505.2905273	0.07
511.1682739	0.03
515.2517700	0.55
517.4536133	0.07
530.3941650	0.04
531.2606812	0.08
532.2148438	0.03
533.3967896	1.61
541.3131714	0.72
547.2891235	0.09
553.1650391	0.30
557.8649292	0.24
559.2174683	11.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	352.1036
Annotation	Sambucus nigra Degraded cyanogenic glycosides (2'-Epimer)
Peak:m/z	Relative Intensity
100.9646683	13.67
112.9656372	6.24
118.8937683	12.24
125.0753479	3.51
127.9253922	1.11
128.9908447	1.29
130.0413971	1.20
134.1253967	0.51
142.0589600	1.10
143.0176544	1.39
144.0750427	2.60
146.0275269	44.72
146.9920044	0.93
155.9142761	4.23
157.8332520	0.94
159.0022736	3.08
159.9970093	2.78
161.0017090	25.21
164.0157471	5.72
165.9940186	2.85
167.9279175	0.76
170.0274658	6.89
172.1823730	2.27
174.0145569	14.81
182.1165924	0.47
183.8702087	1.88
185.1160278	0.29
186.0817261	3.25
188.0686035	80.44
190.1029358	2.96
192.0554810	0.93
198.1894531	3.41
199.9943237	20.76
202.1102142	0.76
206.1546936	27.71
208.2100983	0.15
210.2527008	3.59
212.0729980	0.32
214.1576233	0.54
216.1547241	0.76
218.1169739	100.00
228.1672668	4.77
230.0963745	9.03
231.9504395	8.86
234.0885315	0.56
236.1520996	2.40
242.1338196	6.25
246.0870056	0.69
248.1315308	2.31
254.1422729	43.13
260.0251160	1.65
264.2868958	3.28
272.1088562	5.44
278.0224304	1.93
290.2110901	9.64
304.1378174	1.18
308.2566528	73.74
334.2354736	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	701.3694
Annotation	Gingerglycolipid B
Peak:m/z	Relative Intensity
203.0387573	0.32
240.1870728	0.22
245.1798553	0.44
258.9998779	0.54
299.2098389	0.07
305.2743835	0.39
336.9711914	0.12
347.1489868	2.79
363.2822266	0.22
364.0797119	0.07
365.2374268	7.64
366.2011719	0.15
377.4725342	0.26
397.6710205	0.04
404.7245483	0.70
407.1653442	0.29
414.3515625	0.32
421.2068481	3.16
422.2396240	0.29
437.4434814	0.18
441.4437256	0.10
446.8947144	0.12
482.9435425	0.22
510.6860352	0.42
539.3560791	100.00
540.4262085	20.79
541.0942993	0.05
553.3834229	0.16
555.6516113	0.06
567.1116333	0.21
569.3544312	0.10
573.3352051	0.08
630.7423096	0.14
639.3576660	0.14
656.1940308	0.07
665.2192383	0.80
673.3908691	0.07
683.4099731	1.17
702.7927246	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	333.1686
Annotation	Gibberellin A4
Peak:m/z	Relative Intensity
95.06008911	0.81
105.0937424	0.68
107.0083542	0.99
109.1021118	2.09
117.0803528	0.61
118.8752747	1.51
121.0829468	2.08
123.0526123	0.61
125.0677795	0.41
128.9116516	0.69
130.9336243	1.04
133.1790619	1.10
135.113678	4.86
136.960968	0.67
138.6185455	0.51
141.4294128	0.12
143.0968628	0.54
144.9825897	1.36
146.9924622	1.30
149.0917358	1.72
151.125	0.03
153.0238647	1.00
155.0346375	0.33
157.0882568	0.46
157.7412872	0.39
159.0619202	2.68
161.0556793	1.06
162.9428101	0.74
165.0426331	2.18
166.9191895	0.77
168.9684448	0.74
171.2746582	0.31
172.980957	0.37
175.126297	1.00
176.1111755	0.05
177.1342773	3.76
179.025116	0.95
181.0171356	0.85
182.9959106	0.26
185.0141296	0.61
185.8599854	0.09
187.104126	1.02
189.2338257	0.59
191.0852966	0.45
193.1243896	1.34
195.1497803	2.02
196.4831238	0.14
197.1956787	1.04
199.1427765	1.81
201.0571747	1.70
202.9500427	0.55
204.5692444	0.33
205.1819153	0.29
207.1894379	0.37
209.109436	1.23
211.2103271	0.80
213.1680603	0.95
215.3302307	0.12
217.2075195	0.17
219.2285461	1.48
221.2971802	0.56
223.1725464	1.40
225.1926575	0.32
227.2086792	3.57
228.2527771	0.08
229.0724182	0.75
231.1809998	0.39
234.7724304	0.40
237.1358337	0.64
239.1700134	2.93
241.2526855	18.24
243.2023621	6.04
245.1636963	0.97
247.1543274	0.27
251.2199097	16.79
253.2540283	1.29
255.177948	1.78
257.1391602	1.72
258.0290833	0.16
259.2184448	11.22
261.1850586	1.38
263.277771	0.14
267.1715698	0.18
269.1625366	45.61
269.9187012	0.03
271.2390137	1.66
272.227478	0.07
273.0912781	1.82
275.2496948	0.63
279.3183594	2.20
281.2828064	0.11
284.1437988	0.49
285.2427368	4.04
287.2420044	72.65
288.2589417	0.62
291.7528381	0.30
297.2237549	20.37
303.0031433	1.25
305.2037354	8.47
313.388916	0.34
314.1841431	0.69
315.1586304	100.00
316.1849976	0.22
318.2705688	0.23
324.3239136	0.49
327.3217773	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	413.2177
Annotation	Desacetylvindoline
Peak:m/z	Relative Intensity
129.1493988	0.24
161.016037	0.11
178.9490814	0.18
189.2692413	0.30
223.039032	0.10
230.1880188	0.09
243.0349731	0.34
251.050293	0.48
256.9746704	0.23
258.2985535	0.18
265.3382874	0.07
267.1732178	0.22
268.1552124	0.22
284.2536011	0.42
297.2762451	0.54
307.1257324	0.27
312.0031128	0.09
313.0545044	0.77
316.908783	0.67
323.1359863	0.30
325.3954468	0.62
327.4394226	0.16
335.2523804	0.11
345.0613708	0.31
350.2382812	0.31
351.4212036	0.08
353.1818237	100.00
355.1907959	0.22
365.2151489	0.32
367.2485657	12.27
369.3757019	1.40
371.3905945	2.30
376.3694153	0.49
377.1397705	0.58
378.1759033	0.40
393.2053223	0.34
395.0822449	2.74
396.3712158	0.32
397.1571045	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	765.2299
Annotation	Unknow
Peak:m/z	Relative Intensity
233.1452942	0.04
245.0494385	0.31
260.8709717	0.05
262.5207520	0.04
263.1964417	0.14
265.1372070	0.38
283.1891479	1.27
289.1341553	0.16
303.1486206	0.21
305.2324219	0.39
307.1046448	6.80
308.2418213	0.03
310.7633057	0.11
320.7390442	0.08
322.9042358	0.04
334.9445190	0.09
346.9541016	0.17
349.2904053	0.02
367.0974121	0.02
377.2541504	0.09
379.0819702	2.10
380.4169922	0.19
388.9593506	0.03
397.1677246	1.04
401.2614136	0.05
404.7415771	0.12
407.3188477	0.04
415.2728271	0.64
423.0496216	0.16
431.2637939	0.14
432.8848267	0.02
438.9268188	0.30
449.2313232	0.37
457.2291260	0.19
461.3138428	0.07
467.2185669	0.06
483.0625610	0.10
491.5350952	0.27
498.9978638	0.13
499.6912231	0.05
501.3343506	0.08
511.2883911	0.56
512.1194458	0.04
513.2791748	0.02
528.2035522	0.31
529.2584839	1.05
541.2369995	0.04
547.3385010	0.27
553.5026245	0.36
554.3464966	0.14
555.2238159	0.28
557.1765137	0.12
561.1541138	0.07
565.1862793	0.10
571.3461304	0.82
572.3264771	0.82
573.2453003	0.94
591.2954712	0.33
606.1461792	0.07
613.3926392	0.28
615.2590332	0.88
627.4159546	0.26
631.1251221	0.56
632.3171997	1.35
633.2271118	1.57
643.4760742	1.09
645.3583374	0.10
649.1234131	0.04
661.2263794	0.70
667.0357666	0.04
667.8598022	0.09
674.5380249	0.27
679.3018188	0.48
680.2973022	0.11
685.2214966	0.54
686.1166382	0.84
687.2214966	2.67
703.1592407	0.13
705.2070923	100.00
706.2470703	1.45
721.3662109	0.17
723.2700195	51.55
724.2438354	1.03
746.3491821	0.10
747.3096924	4.56
748.4257202	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	351.2159
Annotation	Rabdokunmin D
Peak:m/z	Relative Intensity
104.7778625	0.07
107.1645508	0.41
109.0808105	0.66
111.0711746	0.10
119.1031647	0.73
120.9801178	0.85
122.9443970	0.59
131.2474060	0.14
133.1216888	0.28
135.0550995	7.30
137.1820984	1.02
138.9803162	0.07
141.1074219	0.21
143.0056610	0.14
146.9517822	0.74
149.0902557	0.06
151.1379700	0.39
153.2381897	0.09
155.0199432	1.79
156.8793335	0.08
159.1416626	1.01
161.2063599	0.54
162.9916687	0.10
164.9824524	0.86
167.1261597	0.06
169.1204834	0.86
171.1108398	0.19
173.0608521	0.41
175.1665497	0.04
177.0573883	1.31
179.1798706	0.94
180.5991516	0.07
182.7287445	0.26
185.0281067	0.75
187.0988312	0.59
191.0039215	0.35
192.8978577	0.06
195.0966644	0.35
196.9399261	0.45
199.2471924	0.16
201.0249786	0.07
203.3697357	0.05
205.0723572	0.23
207.1932983	0.28
209.2146912	0.43
211.0564117	0.08
213.4822083	0.49
215.0424805	0.11
217.0118103	0.16
221.2271423	0.05
223.1648560	0.64
227.2092285	0.92
228.7997437	0.29
229.4224854	0.27
230.6316223	0.28
237.1474609	0.13
239.2266235	0.38
241.2656860	8.45
243.2558289	5.97
245.2401733	0.47
251.2353516	5.72
253.3120422	0.47
255.0497742	0.15
257.0834045	0.30
259.2216797	9.94
267.1165771	0.31
269.2531738	26.73
271.0212402	0.45
273.3826294	0.23
276.9757080	0.20
279.2321777	0.99
284.5157166	0.18
285.1693726	1.63
287.2553711	33.36
289.3739014	0.24
292.8546753	0.14
297.1648865	22.37
297.8380127	0.08
303.1405029	1.54
305.1505432	1.32
307.1492615	0.51
315.1748047	100.00
318.1943054	0.10
319.1651611	0.18
323.3748474	0.09
333.2656250	37.37
336.0516968	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	175.12
Annotation	Unknow
Peak:m/z	Relative Intensity
59.8478203	51.60
60.5966110	0.03
69.9379654	6.20
70.6035004	0.05
71.9833832	1.83
83.9637375	0.35
96.8947907	0.27
98.0058594	0.28
111.9765930	6.39
113.0287476	0.54
114.0151825	3.91
115.9886475	59.97
130.0325317	49.94
131.1659698	0.21
133.0520020	1.52
139.9982300	2.02
141.1160583	0.12
157.0211182	79.04
158.0335541	100.00
175.1531830	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1089
Annotation	Lactulose
Peak:m/z	Relative Intensity
97.0570679	0.16
99.0162125	0.27
100.9960785	6.86
106.8518524	0.09
113.0443115	20.35
115.0419617	0.68
118.9722366	12.32
125.0472260	4.07
130.8764954	6.23
143.0149994	23.35
149.0146484	6.49
159.0218201	0.10
161.0048218	25.43
178.8825378	100.00
191.1038513	11.67
197.1771545	0.21
209.0086975	0.59
220.7997742	0.37
237.2778625	0.46
250.9946289	0.27
263.1010132	0.71
277.0230713	0.26
279.9637451	0.13
295.2507935	0.20
296.7107544	0.11
321.1622314	0.13
323.3245239	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	558.2069
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0924683	0.06
160.1668396	0.41
170.0236206	0.73
171.1207581	0.39
174.0329895	0.73
178.9555664	0.20
187.9942780	49.28
189.1095123	0.31
192.0447235	3.08
195.1094971	0.08
205.0582581	100.00
206.2923584	0.10
233.9656830	0.42
237.2683411	0.16
255.0317535	0.48
258.3091431	0.19
262.0465698	0.91
270.0925293	0.30
288.1935120	0.20
300.1403198	0.32
312.3062744	0.08
317.9448242	0.17
321.0682373	0.34
323.2107544	0.19
325.0874634	0.33
329.3073120	0.28
330.1729736	0.17
332.2021484	0.23
336.1530151	0.23
338.1715698	0.09
341.2844849	0.25
341.8997803	0.07
344.3524780	0.34
354.1388550	10.82
356.2860107	0.18
356.9254150	0.29
361.0466919	1.51
377.3395996	0.37
378.8229370	0.40
383.9912109	0.14
393.3713379	0.34
394.1477051	0.52
396.1491089	0.99
397.2971802	0.70
397.9589844	0.20
413.9096069	0.07
415.6317139	0.12
424.0892334	0.16
425.2363281	0.21
431.2915649	0.10
434.7220459	0.31
438.1878662	0.28
439.4605103	0.25
442.1444702	0.08
442.9657593	0.80
457.3331299	0.46
467.8361816	0.62
470.0549316	0.07
472.5285034	0.24
483.1650391	0.19
488.8388672	0.29
504.3402100	0.17
511.5653687	0.13
514.0864868	0.21
521.0815430	0.08
522.3460083	1.04
522.9860229	0.33
538.3402710	0.25
539.1516113	0.73
540.2186279	0.91
541.3607788	0.56
548.8087769	0.26
565.2500000	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.0029
Annotation	Unknow
Peak:m/z	Relative Intensity
129.0274963	0.17
130.7947083	0.05
138.8668213	0.24
173.0012817	0.93
185.1235046	0.08
190.9750366	100.00
191.8381348	0.12
195.9109802	0.04
209.9070892	0.11
213.0317841	0.58
231.0406494	0.30
240.1230164	0.08
241.2403564	0.15
252.0009155	0.20
256.6114197	0.07
263.1286011	0.52
273.0175171	1.56
274.2843018	0.14
288.2201538	0.24
289.0506592	0.02
298.9871521	0.67
317.0244141	2.95
348.8016968	0.15
351.1946106	0.15
359.0122681	0.79
377.1808472	0.46
384.9273987	0.39
385.9320679	0.27
402.9785461	6.65
403.5941467	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	381.1533
Annotation	Trichogoniolide
Peak:m/z	Relative Intensity
129.0682068	0.04
132.8917847	0.17
142.9793854	0.05
147.1740723	0.06
153.1322479	0.10
183.9062347	0.05
201.0093079	0.04
202.0903625	0.09
204.0742035	0.23
218.3943176	0.09
220.2667847	0.08
222.9040833	0.11
237.0903015	0.06
239.0578308	0.03
240.8625488	0.05
244.7129211	0.11
248.1941223	0.12
249.1812744	0.04
252.0503540	0.04
253.0932617	0.08
255.2529602	0.52
266.2741089	0.06
267.1575317	0.03
269.1831360	0.06
270.3480835	0.02
273.3428345	0.30
274.0921631	0.26
281.3062744	0.14
283.1919556	0.21
290.4998169	0.10
294.7545166	0.12
296.3150024	0.21
299.1151733	1.07
300.0494690	0.03
301.3297119	0.24
303.3436279	0.04
304.6195679	0.13
305.3468018	0.31
315.2718811	0.41
317.1374512	0.85
318.1065063	0.15
319.1511841	0.44
325.0143433	0.19
327.0114441	0.86
331.0640869	0.14
333.0391846	0.64
334.4865723	0.40
335.1858215	2.80
337.3128052	0.39
339.0880127	0.02
340.9481812	0.14
344.5853577	0.45
345.2350159	1.75
346.0618591	0.04
348.5342712	0.33
349.3388977	0.34
350.8316956	0.04
352.9790955	0.41
363.0557861	100.00
364.2012024	0.10
366.0876770	0.05
369.3831482	0.33
370.8996887	0.09
372.1528625	1.98
373.0821838	0.14
374.0085144	0.05
381.0314636	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	205.0965
Annotation	Indoleacrylic acid
Peak:m/z	Relative Intensity
158.8991547	0.08
188.0166473	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	439.1564
Annotation	Unknow
Peak:m/z	Relative Intensity
135.9698639	1.31
137.0062561	0.02
146.9662018	0.55
147.9338989	0.14
157.1817627	0.05
161.0753021	0.01
233.1708527	0.16
256.0979004	0.03
261.0902710	0.09
261.9798584	0.02
265.0658264	0.34
273.0258484	0.08
277.2914429	0.02
278.9769592	0.23
292.4141235	0.05
327.1905518	0.03
352.5079346	0.05
384.2294617	0.07
389.5980530	0.12
397.0852966	0.05
401.1972961	0.24
403.7175598	0.11
406.4172058	2.15
407.2704773	0.15
408.1902771	0.02
408.9467468	0.17
410.9297180	0.28
412.1666260	0.07
419.1520386	0.03
421.4282227	0.04
422.6771545	0.07
426.4591980	0.19
427.1709595	0.32
428.4918518	0.21
430.5406799	2.13
431.2831116	0.12
432.6863403	0.26
470.1958313	0.13
472.7190857	0.28
474.6322632	0.02
476.7605896	0.06
479.4089661	0.48
484.1119690	6.94
484.9368286	0.27
486.7640991	0.30
490.7926331	0.03
493.6029663	0.07
494.4450989	0.22
495.5060425	0.07
497.8979797	0.15
501.3311462	1.43
502.0115051	0.66
503.9523315	1.59
504.7059631	0.08
507.6449280	2.85
508.4126892	100.00
509.4520874	1.03
510.1349487	0.07
512.7711792	0.14
514.3910522	0.11
515.7361450	0.12
518.4659424	0.18
520.1940918	0.13
520.9988403	0.10
530.4289551	0.26
537.7284546	0.16
540.5975952	0.19
544.8483276	8.20
545.8780518	0.43
546.6302490	0.23
547.5261230	0.10
587.3966675	0.03
618.6679077	0.10
621.6080933	0.11
622.3132935	0.14
631.2624512	0.13
640.0471191	0.15
643.4990845	0.23
644.1823120	0.28
645.2642212	0.74
677.5017700	0.72
678.1878052	0.12
693.3499756	0.04
721.5103149	0.04
737.5477905	0.19
738.7549438	0.05
772.2072754	0.01
788.5298462	0.07
811.2358398	0.06
920.8635864	0.02
1108.3863530	0.03
1121.6142580	0.09
1376.3992920	0.06
1389.5008540	0.02
1915.6566160	0.64
1933.7453610	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
74.15610504	0.10
76.91049194	0.16
80.9254837	0.60
83.00068665	0.26
84.84936523	0.16
90.82330322	0.70
95.06715393	0.81
97.11608887	0.54
98.95477295	1.31
102.8619843	0.19
105.1260223	1.23
106.9246063	0.71
108.8710938	1.14
110.9815521	1.47
117.2054749	0.14
120.9619446	2.71
122.9024353	0.86
124.9703217	0.54
127.0093384	0.35
127.9957886	0.19
128.9505157	3.54
132.9666595	0.41
135.0671997	2.35
137.1764984	1.96
138.8152313	0.11
141.2482758	0.94
145.0191803	0.82
147.1296234	1.63
148.9517059	3.81
150.9233398	48.07
151.9936523	3.53
152.957016	0.11
154.8608246	2.10
156.963028	0.34
159.1494904	1.71
161.1136017	2.87
162.9787445	1.59
166.066803	0.56
167.0363007	2.03
169.0423431	1.77
170.0641022	0.46
171.0953064	0.99
173.0851898	0.72
177.05336	5.38
179.0967255	1.73
181.090683	0.71
181.9988861	0.34
182.9953308	0.49
185.1345367	1.01
189.6464233	0.46
191.021286	1.53
193.1588287	3.55
194.2269135	0.16
195.2764893	1.63
197.1132355	5.20
199.1400604	1.77
204.6782379	0.47
207.0493011	2.72
207.6937714	0.32
209.2707367	0.26
210.273819	0.20
211.1699524	2.26
212.0696259	1.13
215.089798	0.17
217.1717987	10.11
220.8318024	1.22
223.039856	1.29
225.0190735	8.51
226.1412354	0.11
232.8228912	1.13
235.1149445	20.85
237.4394531	1.32
238.0957184	5.71
239.1534424	1.09
240.9195099	0.19
250.924881	0.55
253.0825958	100.00
254.0958862	14.53
264.2459717	0.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.2136
Annotation	Unknow
Peak:m/z	Relative Intensity
163.0693970	0.74
181.9754944	0.28
186.8562469	0.08
204.9700928	0.38
229.0473480	0.52
231.3581390	0.11
234.8384399	0.47
239.2722168	0.04
245.1464081	0.12
247.1186523	1.41
268.9718018	0.05
280.8927002	0.36
289.2583008	0.29
290.8696289	0.33
307.1192017	55.50
323.0703125	0.22
326.5008545	0.04
333.1369629	0.07
335.1316528	0.03
337.3127441	0.17
345.1372681	0.17
355.4654541	0.19
359.0768433	0.11
365.3343506	0.04
367.9934692	0.12
369.3101196	1.79
378.3737183	0.04
389.3078003	0.18
392.5123291	0.09
395.2816162	0.26
396.9948120	0.17
399.4100342	0.12
401.3355713	0.22
407.2877808	0.10
411.3325195	0.09
415.0492554	0.07
425.2114258	0.25
429.2142334	0.09
433.1072388	0.13
457.5612183	0.24
459.5274048	0.08
481.1569214	0.10
483.5825806	0.11
487.1259155	0.57
488.9992065	0.27
493.2334595	0.13
499.5496826	0.46
500.3533325	0.09
501.1599121	0.15
512.3082886	0.08
514.9343872	0.22
519.2196655	0.15
528.0806885	0.81
529.2326050	0.28
530.4849243	18.77
531.1328125	100.00
533.0065308	1.14
534.1207275	0.06
539.3678589	0.11
547.4100952	0.08
556.3966675	0.06
558.3655396	0.14
559.1093140	0.18
560.2258911	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	345.1537
Annotation	(-)-erythro-Anethole glycol 2-glucoside
Peak:m/z	Relative Intensity
100.9835358	0.09
102.8027954	0.11
109.0544434	2.76
119.0421066	0.11
120.9157410	0.24
126.8166885	3.58
135.0873718	0.81
137.0193176	8.31
138.9071960	0.19
141.2246094	0.07
144.9936218	0.43
153.0870209	0.12
154.9457092	4.73
156.8349304	0.12
160.1184082	0.39
165.0756226	58.87
171.3580017	0.67
172.6124268	0.35
173.2261200	0.52
177.2152863	0.33
180.3455200	0.19
181.0374146	0.15
182.9739990	62.53
186.0639343	0.15
189.2252197	0.62
191.0686646	0.31
192.8882141	0.68
194.9716034	0.11
198.8657227	0.36
200.8506775	11.24
205.1602173	0.17
208.1387939	0.09
210.2431335	0.36
213.1676025	0.89
214.8403015	1.28
216.9890747	0.08
219.2749939	0.26
221.0663452	0.73
223.1870422	0.49
224.9870911	1.69
226.9730835	0.28
229.7070618	0.25
233.0250549	0.13
235.0846863	0.98
237.1665649	2.21
239.9936523	0.33
241.0900269	0.94
243.1749268	1.09
245.1692505	0.65
247.9477234	0.34
249.3621216	0.22
251.3384705	0.61
253.2073059	1.42
254.3660889	1.11
255.2480469	2.55
257.1306458	1.16
259.3211365	0.61
261.0568237	0.60
263.0326233	0.58
264.0541382	0.29
265.5726318	0.19
266.8688965	8.28
268.2852173	1.00
268.9983826	0.98
271.2269897	23.73
272.0526123	0.19
273.1969604	1.28
275.2722778	0.30
278.0607300	4.98
278.7334290	21.49
279.3630676	0.66
281.1176758	5.58
282.9760132	1.02
285.1977539	0.79
287.2092590	7.82
289.3041687	1.79
290.9012451	8.44
297.1849060	1.39
299.2093811	74.37
300.2293701	0.32
301.2913818	1.34
303.1251831	0.85
304.0294800	1.95
309.1940308	56.64
312.2757874	0.77
313.1606445	1.82
313.9043884	0.10
315.0802307	1.51
317.1049805	21.89
317.9990845	0.27
327.0830383	100.00
328.0783691	1.72
329.0920715	0.21
335.6188049	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	382.21
Annotation	Unknow
Peak:m/z	Relative Intensity
132.0501404	100.00
133.0744934	0.56
148.0225525	0.19
164.1389160	0.10
172.9160461	0.38
173.9490814	0.10
197.2040100	0.28
200.7936707	1.62
202.0048828	1.21
203.0569458	0.27
206.1451416	0.34
210.0699768	0.09
214.2373047	0.12
215.0751953	0.29
215.9338226	0.18
216.8571167	0.99
217.9761505	0.09
219.0589142	1.21
219.9678192	1.95
222.0986328	0.48
231.9761658	0.13
233.0888672	0.78
234.7045288	1.40
239.9930115	0.21
241.7685852	0.28
247.9510803	0.09
249.2678833	0.09
251.1011047	1.98
253.0891418	0.54
255.9700317	0.17
257.9008179	0.26
274.0067139	1.06
290.2342834	0.32
292.0947876	0.45
300.4265137	0.31
301.6903992	0.11
320.0748596	0.91
336.2716980	0.15
337.9680176	1.03
346.3352661	0.19
364.1085510	1.97
365.4009705	0.63
366.2333984	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	685.3618
Annotation	Unknow
Peak:m/z	Relative Intensity
325.0249023	0.02
333.4941406	0.04
342.2587280	0.02
344.2460938	0.04
375.3482666	0.06
397.0130005	0.02
424.2124023	0.10
429.3471680	0.02
430.3553467	0.01
441.7233276	0.04
469.1340332	0.05
523.3102417	0.01
530.2050781	0.02
555.4942017	0.01
569.5691528	0.02
580.5388794	0.01
597.4356079	0.02
598.2927856	0.09
601.5524292	0.06
615.7572021	0.13
623.7215576	0.06
651.1682129	0.01
655.5636597	0.04
657.3571777	0.02
659.0510864	0.03
667.3570557	100.00
668.2541504	0.00
673.7398682	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	739.187
Annotation	Pelargonidin 3-O-beta-D-glucoside 5-O-(6-coumaroyl-beta-D-glucoside)
Peak:m/z	Relative Intensity
215.0682373	0.09
216.7117920	0.06
241.2052002	0.06
242.9106903	0.47
245.0849304	2.69
250.8907928	0.18
254.9068298	0.43
259.1379395	0.12
269.1273804	0.36
271.2505188	0.06
272.9786377	0.38
278.6781311	0.04
281.1522827	0.43
287.1429749	3.58
289.1119690	6.43
293.1906128	0.53
297.3145752	0.18
299.1095581	4.42
313.1885681	0.23
315.0888367	0.21
321.2015991	0.31
323.2670898	0.26
329.1162720	0.24
331.3599854	0.27
341.1184692	0.06
343.2904053	0.16
349.0568237	0.11
355.2067566	0.14
370.0266724	0.36
379.2472534	0.18
379.9933472	0.36
381.2947388	1.09
387.9193726	0.16
388.7669678	0.07
397.4675903	0.41
403.3838501	0.30
407.2155762	6.02
409.5406494	0.09
423.2539062	0.44
425.1881104	4.82
431.2344971	0.10
432.3132324	0.17
433.3457031	0.20
435.2559814	0.12
436.0708008	0.13
449.3414917	0.38
451.1942749	54.30
461.3323975	0.16
463.1756592	0.25
474.0794678	1.08
489.1746216	0.03
491.1387329	0.47
492.3618774	0.10
493.1805420	0.54
515.3603516	0.23
517.1535645	0.10
526.8552856	0.06
530.3587646	0.15
532.1233521	0.11
533.2349854	4.07
535.1635742	0.85
539.3519287	0.07
543.2500610	1.72
548.8915405	0.06
551.2770996	0.39
558.1766968	0.11
559.1680298	7.00
569.2124634	100.00
570.1841431	0.18
571.2182007	0.65
572.4036255	0.23
573.3746948	0.14
577.1614990	10.88
585.0742188	0.21
587.2048950	37.42
589.4132690	0.37
595.0639038	1.01
599.3679810	0.10
601.1989136	0.04
607.4421997	0.80
611.3428955	0.82
613.2167358	36.19
614.0042114	0.03
624.3743896	0.11
629.1541138	2.06
631.0329590	0.64
653.3533936	0.34
655.2884521	0.16
661.1979980	0.32
662.4352417	0.27
677.1657104	0.50
692.0615845	0.12
693.1843872	0.50
694.8289795	0.74
695.5441284	0.58
702.5914917	0.40
703.3912354	0.37
720.1962891	0.37
721.3063354	23.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.1769
Annotation	7-Deoxygardoside metyl ester tetraacetate
Peak:m/z	Relative Intensity
163.0144348	0.11
164.9779358	0.38
177.1264038	0.29
179.1334076	0.05
181.0283356	0.32
193.1154785	1.18
195.0580444	1.41
217.0826721	0.10
221.1033325	0.13
229.3276215	0.08
235.0295563	7.45
253.0877075	1.88
255.1566010	0.20
271.2757568	0.21
281.1375122	1.09
287.5588684	0.07
297.2376709	0.45
298.2214966	0.32
307.3971558	0.07
309.2670898	0.24
329.1675415	3.49
331.1036987	0.34
333.4412842	0.15
341.1815186	7.75
343.1257935	0.61
347.2418213	0.11
359.0888672	38.36
375.4101562	0.33
377.0665894	100.00
377.6673584	0.19
381.3966675	0.07
387.5802002	0.09
418.1003418	0.24
419.1693115	0.16
433.3828735	0.43
451.4046021	0.67
465.3164673	0.09
467.3002930	0.66
477.4880981	0.17
491.3308716	4.34
493.1848755	2.62
495.4456177	3.57
503.2251587	0.46
521.3571167	2.70
522.7463989	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	199.99
Annotation	Unknow
Peak:m/z	Relative Intensity
67.0817108	0.06
68.8726425	0.02
70.0404511	0.10
70.9553451	0.20
71.9245453	0.12
79.1206055	0.18
79.9071350	0.06
80.8865890	0.14
81.8034668	0.10
82.8564529	0.17
83.8846512	0.10
85.0061493	0.03
86.8724060	0.01
87.7749023	0.06
92.8964081	0.02
93.8755341	0.09
94.9832459	0.17
96.0325775	0.11
96.9829712	0.38
97.8782959	0.13
98.9270325	0.15
100.0915222	0.14
100.8737030	0.04
101.8424072	0.05
106.9419098	0.12
107.9469604	0.04
109.0746918	0.15
109.9446411	0.04
111.0930939	0.27
111.9782410	0.17
114.1565857	0.05
115.1436615	0.20
115.8300934	0.04
116.9701996	0.05
120.6939087	0.09
122.8466034	0.23
126.0127869	0.15
127.9034424	0.06
129.1060028	0.25
129.8863525	0.09
135.9453278	0.17
136.9837189	0.10
143.3068085	0.26
144.1674652	0.05
153.9556122	0.02
155.8914032	0.18
158.8463287	100.00
164.0171661	0.66
171.9702606	0.27
173.3497009	0.03
176.7772217	1.11
181.9672699	1.93
183.0774994	0.03
183.8922119	0.11
200.2036285	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	298.15
Annotation	Hymenoside M
Peak:m/z	Relative Intensity
86.8901520	0.70
96.9903564	0.06
100.9464111	3.53
106.0836182	0.06
112.6707001	0.13
116.0134811	0.42
118.9223022	100.00
126.9485474	0.23
134.8695679	0.05
135.9799805	0.88
152.0453339	0.24
155.9324341	0.16
163.1387329	0.13
165.9181976	0.07
168.0277710	0.19
169.1747131	0.20
170.1513672	0.10
179.0055847	0.08
181.1638947	0.37
182.0381165	0.06
198.0891724	0.10
208.0520630	0.35
209.1401062	0.70
210.7439880	0.27
212.9258118	0.73
217.2735901	0.08
220.1595459	0.93
221.0591431	0.13
225.9805298	1.35
228.4515076	0.35
229.2040100	0.16
232.2261963	0.27
238.2769165	0.53
242.1822510	0.08
252.1715088	1.25
253.8921509	0.15
256.8441162	2.26
257.4921875	0.45
262.1375122	0.38
263.3226929	0.14
266.0086670	0.18
267.8843689	0.25
269.1152649	0.31
271.0219421	0.35
274.1947632	0.24
274.8741455	0.12
276.4537048	0.62
277.7977295	0.10
278.7620850	0.56
280.0927734	32.54
280.8834534	19.28
282.8287659	0.26
288.7402344	1.27
298.7225037	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.114
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
113.0857697	0.27
121.0640259	0.01
124.9606628	0.05
134.8896484	0.09
149.1365051	0.03
156.9955597	0.07
175.1694641	0.12
179.0521240	0.01
183.2165833	0.04
193.0004578	0.02
204.9284515	0.06
207.1096497	0.06
218.9080811	0.02
223.1123657	0.08
231.2857361	0.06
241.4024658	0.06
249.0754395	10.08
267.0629883	100.00
267.9348755	0.09
285.1494751	0.02
292.5265808	0.07
294.9651489	0.02
298.1981506	0.02
313.3552856	0.01
324.9927979	0.01
347.4439087	0.06
349.2615356	0.01
355.2421570	0.09
367.2472229	0.03
368.3735962	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.1771
Annotation	7-Deoxygardoside metyl ester tetraacetate
Peak:m/z	Relative Intensity
165.2555389	0.03
183.9992828	0.02
201.0904846	0.13
203.1195068	0.04
227.1059875	0.26
245.2432709	0.41
253.4912262	0.03
255.2362823	0.06
271.2340698	0.26
287.1611328	0.03
289.2419128	0.02
297.2408142	0.09
315.2172241	0.92
331.4204712	0.07
333.3346558	0.09
347.2416992	0.04
349.3018799	0.03
357.1780396	0.27
359.2656860	2.79
377.2131348	100.00
391.3743286	0.02
403.2393188	0.04
417.4537964	0.05
419.2360229	0.47
449.1576538	0.78
451.2484741	0.08
453.3927002	0.06
458.4406738	0.06
477.1768188	0.09
479.2743530	3.69
493.1578979	0.05
495.1294556	0.03
503.5222778	0.02
521.4133911	0.08
522.4495239	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	413.1662
Annotation	Unknow
Peak:m/z	Relative Intensity
221.0895996	0.38
239.1480408	0.02
240.3321228	0.02
244.9658508	0.03
249.2439575	0.06
251.0948792	0.15
256.9589539	0.05
269.9737244	0.03
281.3755493	0.06
283.1359253	0.20
289.0882568	0.04
291.1148071	0.04
307.5710754	0.10
325.4574585	0.06
326.0698242	0.04
333.4746399	0.03
337.3730774	0.07
339.1011963	0.11
341.5704346	0.02
345.6044922	0.07
350.2065125	0.01
351.1939392	0.16
353.2164917	0.10
355.3300171	0.02
367.1260071	100.00
367.7625122	0.30
369.1316833	0.36
377.2067566	0.05
380.9978943	0.04
385.1376953	0.03
393.4031982	0.04
395.1067810	0.58
396.1198425	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.1925
Annotation	Unknow
Peak:m/z	Relative Intensity
142.9220123	0.12
162.2132874	0.07
162.9792786	0.41
193.9655151	0.12
215.3416290	0.03
233.0002136	0.39
234.9593811	0.15
239.3432007	0.13
258.9498291	0.18
265.0239868	0.13
274.1398010	0.24
277.2579041	0.39
295.2846069	0.09
310.5463562	0.11
324.7974854	0.38
336.9952087	0.05
351.4364929	0.05
365.0392456	0.03
370.7188721	0.03
411.2203064	100.00
413.1026306	0.36
414.2185974	0.08
428.3033142	0.08
438.8582153	0.06
439.4652405	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
83.01299286	0.23
97.01908875	0.31
151.1319427	0.36
161.1970062	0.14
166.2890778	0.12
169.1640472	1.05
170.9265289	0.76
179.0731659	0.57
180.3756866	0.18
181.0640411	0.09
183.3435822	0.11
190.0071259	0.16
193.3786163	0.12
194.2786407	0.68
195.0778961	0.97
202.2371063	0.20
207.1650696	4.97
208.0285034	2.22
209.2268677	3.23
215.0968475	0.37
220.8356171	0.36
222.3326263	1.20
223.0725555	5.01
224.2423553	0.23
233.1504974	1.71
234.8292999	0.07
251.0771027	100.00
252.1399078	16.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	719.3123
Annotation	Unknow
Peak:m/z	Relative Intensity
203.2367096	0.03
258.0230408	0.07
281.1419067	0.07
323.0969238	0.03
341.0764771	0.07
377.1316528	0.06
387.2421875	0.10
399.9097900	0.08
417.5240479	0.03
436.8957520	0.03
449.0317383	0.04
452.3589478	0.08
463.2733765	0.04
475.1441650	0.07
483.0080566	0.03
493.1345825	0.05
503.5380249	0.06
509.1738892	0.11
511.2671509	0.73
511.8802490	0.05
529.4879761	0.17
533.3253174	0.04
545.7954712	0.02
547.2851562	0.03
559.0137329	0.03
587.3128052	0.03
597.1054077	0.05
609.4494629	0.05
611.1832275	0.17
614.3329468	0.07
615.5177002	0.06
627.1189575	0.07
629.3745728	0.11
659.4439697	0.14
673.2777710	100.00
673.9225464	0.26
675.3747559	0.19
683.3214722	0.06
686.3533325	0.11
687.1656494	0.15
700.0846558	0.24
701.4627686	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	804.063
Annotation	Unknow
Peak:m/z	Relative Intensity
240.9883270	0.40
243.2784424	0.52
258.9800110	4.00
277.2236633	1.50
281.9935913	0.23
284.1405945	0.24
298.2704163	1.07
344.1230469	0.28
348.9075928	0.36
353.4217529	0.83
369.2744751	1.09
370.1206055	0.24
371.2135620	2.16
378.3341675	0.81
379.2405396	0.71
388.5519409	0.43
390.1900635	0.17
397.2474365	0.94
399.8921509	0.33
404.7178955	1.34
413.8983154	1.99
415.1766968	1.47
416.3950195	2.35
422.5211182	15.10
423.1763916	0.19
426.5071411	0.83
440.2760620	0.15
449.4701538	1.34
451.2088623	1.04
452.4136963	0.28
454.6514282	0.68
460.0812988	0.35
463.4638672	0.35
464.5814819	0.52
465.9551392	0.11
469.7037964	0.64
471.8869019	1.49
479.4900513	0.32
480.2284546	0.90
492.3258057	1.80
500.2893677	2.06
501.4317017	0.81
502.4114990	0.46
514.0987549	3.41
515.3796387	0.86
516.3980713	0.93
517.9691162	0.98
518.6455688	3.56
519.2726440	0.18
519.8767700	0.23
520.6620483	0.19
527.4261475	5.53
528.1862183	3.09
528.8168945	0.33
533.2983398	0.37
536.2265625	0.62
539.4121094	3.42
540.4871826	0.72
541.9963989	0.94
544.5034790	0.80
545.3161621	1.58
551.2859497	1.50
555.3431396	0.59
558.3818970	0.67
567.3594971	0.81
568.7020264	0.65
569.8640747	0.33
573.5671997	0.32
578.1368408	0.70
585.1714478	0.43
586.5839233	3.36
587.4439697	0.31
596.8310547	0.23
600.5358887	0.84
605.7138672	1.77
606.5797119	2.32
607.7308960	0.68
608.7174072	0.74
611.9223022	2.13
615.4618530	1.06
618.7526855	1.02
625.7170410	1.21
629.4430542	0.35
637.6203613	0.60
640.1598511	1.59
643.2985840	2.82
644.2372437	1.17
645.2427368	1.13
647.4130249	2.89
648.4655151	1.94
652.3295288	0.82
659.0178223	1.29
659.9788818	0.43
661.2308960	3.92
661.8650513	0.69
663.2880249	0.68
666.3953247	0.99
667.4769897	4.47
668.3736572	7.09
669.2691040	1.98
670.0391846	4.27
671.0347290	1.37
673.1752319	0.36
674.4822998	1.57
675.2122803	3.56
676.9036255	3.09
677.6411133	0.41
679.1340942	29.29
679.9912109	12.35
682.4620972	1.38
684.2691040	0.90
685.5523682	0.23
687.9838257	0.72
694.4112549	1.02
696.5922241	4.15
697.2855225	2.03
701.9371948	0.40
704.3097534	0.61
706.2882690	2.24
706.9191284	2.28
708.5384521	1.84
710.8195190	1.83
711.8107910	1.01
712.5097046	3.45
713.5885620	1.11
714.3152466	0.36
716.9984741	3.96
718.1902466	1.97
719.9219360	1.31
722.1586304	1.31
724.3078003	2.08
726.0101929	13.77
726.9768066	2.49
729.1276245	0.61
731.6272583	0.15
734.8799438	15.87
735.9797974	3.97
737.4855347	9.56
738.3265991	2.31
739.3505249	1.22
743.6254883	16.27
744.7393799	0.31
746.3435669	1.81
749.0380249	6.01
749.9397583	1.53
750.7666016	0.47
755.3554077	22.62
756.0282593	1.59
757.2750244	2.51
761.0802002	3.81
766.3078003	2.28
767.4059448	4.36
768.7451782	0.85
770.2474976	1.15
771.0548706	0.72
772.1950073	0.23
773.2285156	1.57
775.4708862	19.13
776.4150391	4.02
778.1317749	0.95
779.2317505	0.79
784.5885620	100.00
785.4723511	17.14
786.2764893	5.14
789.8055420	1.28
790.5294800	0.26
792.1171265	5.71
792.9227905	2.15
793.5717163	0.78
795.3313599	0.54
796.4227905	0.19
809.1764526	1.28
824.8722534	0.50
826.0574341	4.73
826.8167114	1.61
828.5191040	0.86
829.3958740	1.52
833.1776123	0.38
839.4032593	0.39
843.4105225	57.61
844.4630737	26.95
845.6154785	5.29
846.5377197	0.38
864.0029907	0.85
882.6257935	6.40
883.4370728	1.32
884.4628906	1.74
885.5238037	3.31
899.9570923	2.42
900.6655273	1.14
901.7301636	5.91
902.4612427	1.81
907.4850464	5.37
908.6669312	2.29
909.4648438	0.57
924.3964233	0.30
925.4797974	13.59
926.6106567	5.49
927.7280273	0.53
938.3880005	2.04
940.4808960	0.45
942.5173340	13.48
943.6577148	5.28
944.6933594	2.28
947.1525269	12.73
948.0083008	2.70
953.3086548	0.59
954.5576782	0.37
955.5145874	1.11
968.6163940	1.06
981.9050903	0.41
983.0307617	0.63
1001.6029660	1.36
1011.1928100	7.38
1011.9838260	6.74
1013.3735350	3.81
1018.4648440	0.38
1019.2145390	0.23
1023.5300290	0.80
1025.6184080	0.73
1030.4040530	1.07
1036.4731450	11.58
1037.5294190	3.63
1038.5046390	2.22
1043.4005130	0.13
1049.6794430	1.32
1054.4210210	18.38
1055.4075930	10.90
1056.5889890	1.43
1057.7799070	0.36
1058.7427980	21.17
1059.6793210	12.33
1060.5981450	0.22
1065.8360600	0.41
1067.9450680	73.06
1068.6591800	10.33
1071.4843750	2.92
1072.2749020	2.38
1076.7751460	2.40
1077.8559570	1.73
1080.3377690	0.39
1082.4608150	0.34
1092.2590330	0.64
1096.2177730	0.30
1097.3803710	0.20
1098.5708010	0.28
1101.6367190	0.58
1105.6195070	1.80
1110.0765380	1.31
1115.2388920	1.02
1123.2583010	15.61
1124.1455080	7.19
1124.8521730	0.46
1132.3115230	45.93
1133.3328860	13.41
1135.2983400	0.25
1136.1594240	0.21
1147.0570070	1.04
1153.6639400	0.52
1154.7608640	0.63
1165.4311520	0.85
1172.2520750	1.16
1181.7974850	1.04
1182.4327390	0.56
1183.5166020	1.28
1191.6464840	1.61
1209.8287350	4.24
1210.8464360	2.21
1211.5466310	0.17
1221.5571290	0.17
1239.6652830	0.38
1250.7291260	0.59
1255.4344480	0.40
1259.7347410	0.70
1260.4862060	0.80
1268.9167480	0.32
1296.7404790	0.77
1321.6707760	1.55
1322.5743410	0.87
1328.6738280	0.70
1338.4442140	1.89
1341.9947510	1.20
1354.6094970	0.34
1356.5894780	4.09
1357.6068120	2.16
1358.7492680	1.33
1380.3585210	0.25
1432.5247800	1.15
1439.6140140	1.08
1440.7239990	0.50
1467.6801760	0.26
1469.0576170	1.09
1469.7891850	1.56
1478.6204830	0.97
1484.5621340	0.97
1486.4896240	2.39
1507.7493900	1.16
1549.4495850	0.75
1550.6080320	1.28
1567.5689700	3.46
1568.9195560	3.07
1569.8856200	1.10
1579.9118650	0.49
1602.9171140	0.97
1621.5047610	0.46
1950.5267330	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	705.1818
Annotation	Lactulose
Peak:m/z	Relative Intensity
200.9042358	0.07
276.0364380	0.07
291.0151062	0.11
363.1618652	4.87
381.2179565	10.30
381.9396973	0.08
453.1566772	0.02
483.1878662	0.08
523.5012817	0.03
525.1410522	30.39
526.0179443	0.25
529.6236572	0.06
533.0166626	0.31
539.9429932	0.04
543.1940308	100.00
544.2672119	0.29
594.4152222	0.06
615.1056519	0.20
645.4154663	0.19
646.3954468	0.08
675.3624878	0.15
687.3377075	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.167
Annotation	Unknow
Peak:m/z	Relative Intensity
322.9724731	0.08
326.1322632	0.01
340.9203491	0.15
415.2315674	0.76
416.1972046	0.71
417.1792603	0.05
442.8829956	0.02
503.2285156	100.00
503.8386230	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	545.2604
Annotation	Canavalioside
Peak:m/z	Relative Intensity
171.3533020	0.12
178.9343414	0.37
182.8524780	0.05
216.7161407	0.09
265.3056335	0.07
271.0979919	0.05
274.1736450	0.02
275.3707886	0.08
277.1051636	0.12
303.1690674	0.05
317.3515625	0.04
319.2242432	0.16
321.3782349	0.14
333.2096558	0.05
337.3579102	3.22
338.4041748	0.07
339.3638916	0.36
345.2545166	0.10
346.1494751	0.20
347.1564331	0.12
363.2593384	0.08
364.7642212	0.59
365.4200439	2.50
366.2965088	0.11
367.0258179	0.12
379.3058472	0.05
383.2968750	3.07
384.7648926	0.06
409.2260132	0.36
431.3449097	0.22
437.5299072	0.05
443.7041016	0.13
467.0571289	0.27
469.3193970	0.07
471.5086670	0.12
482.2860718	0.08
483.2758179	0.16
484.1698608	0.13
485.2778931	0.22
497.4691772	0.09
499.2793579	100.00
500.6729736	0.21
501.3720093	0.39
502.1452637	0.07
503.3576050	0.04
507.1441040	0.03
509.3842163	0.07
515.4894409	0.04
525.5437622	0.13
527.4924927	0.83
528.2775879	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	543.2078
Annotation	Dracunculifoside Q
Peak:m/z	Relative Intensity
158.9564972	0.02
161.0290222	0.12
179.1093750	0.04
183.2407990	0.01
193.2015533	0.01
197.2098999	0.02
210.2271576	0.05
211.0196228	0.03
213.1067200	0.09
229.4218445	0.07
232.1573486	0.10
233.0788574	0.02
237.1598206	0.06
239.3803711	0.06
240.3216248	0.04
241.3901672	0.04
245.2308044	0.33
253.3147278	0.08
257.2558594	0.85
261.2979126	0.03
263.4094238	0.40
265.2230225	0.07
273.1581421	0.37
274.7592773	0.38
275.3624268	1.51
276.3457642	0.12
277.1682129	0.03
283.1170044	0.20
285.4942017	0.15
290.3149719	0.03
291.3818970	0.81
293.3231812	2.40
294.4143066	0.08
299.5039673	0.02
301.2563477	1.68
302.1271362	0.02
303.3291626	1.49
304.3182068	0.06
315.1379395	0.02
317.2635498	0.14
319.2686157	5.07
320.2404175	0.23
321.0092163	0.03
331.0942993	0.05
337.2657471	4.89
338.3176880	0.56
343.3066406	0.17
345.0130615	0.06
347.1826782	0.13
351.3298950	0.02
352.9135742	0.03
355.0650635	0.05
361.1120605	0.09
363.2431641	1.00
369.5172119	0.04
371.3710938	0.05
373.1719971	0.16
373.9884033	0.06
376.8806152	0.04
379.3189087	0.04
381.1824341	0.57
385.4355469	0.02
397.3849487	0.04
398.1160278	0.09
399.2091064	0.08
401.3234253	0.08
404.0983887	0.03
406.9795532	0.02
409.4298706	0.02
410.2148438	0.05
411.3859863	0.19
418.2685547	0.06
419.1840820	0.08
420.3117676	0.07
421.0737915	0.04
423.3270264	0.22
425.2142334	0.06
437.4448853	0.10
439.1905518	0.02
445.4198608	0.07
453.3908081	0.33
454.5430298	0.04
455.4077148	0.18
456.3220215	0.04
459.1497192	0.04
463.3516846	0.16
474.8526611	0.03
476.1081543	0.05
479.3912964	0.08
481.2859497	7.82
482.3361206	0.67
483.2363892	0.37
497.3208618	2.22
499.3435669	100.00
500.4205322	5.10
506.4069214	0.03
507.5397339	0.08
513.2599487	0.03
521.6530762	0.06
523.2224731	0.05
524.6579590	0.05
525.2716064	1.98
526.3731689	0.35
533.3285522	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	290.85
Annotation	Unknow
Peak:m/z	Relative Intensity
122.9093018	2.26
206.8276978	100.00
268.2606812	0.11
272.0015259	0.03
273.1632080	0.07
274.1472778	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	377.1584
Annotation	(3S)-7-Hydroxy-8,2',3',4',5'-pentamethoxyisoflavan
Peak:m/z	Relative Intensity
169.5729065	0.01
218.7355347	0.03
225.2609253	0.02
241.2038879	0.06
267.2571411	0.03
269.1617737	0.10
285.1928711	0.29
287.2496033	0.92
295.2601624	0.01
312.9680176	0.74
315.1959839	0.06
323.3347778	0.05
328.0159607	0.04
331.0660706	8.54
331.6875000	0.07
333.5140381	0.02
339.1034851	0.01
341.0132141	0.68
351.6400146	0.01
357.0453186	0.08
359.0317383	100.00
359.6726990	0.17
376.7715149	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
94.79463959	0.12
95.77308655	0.72
97.12886047	0.60
117.1782532	0.27
135.0076447	0.22
137.3025818	0.16
139.068924	0.37
148.8232269	0.27
161.0766144	1.03
179.0523682	1.30
180.261795	0.53
183.1206818	0.79
183.7555237	0.54
187.0683899	1.08
188.2345428	0.13
189.2177582	0.22
191.8738251	0.25
193.636734	0.19
195.0697784	1.04
207.1400299	6.25
208.061203	1.44
209.166153	3.83
221.9784088	1.17
222.8975067	2.32
223.5345306	0.19
233.2429657	3.16
234.1364594	0.15
236.231369	0.20
251.0739899	100.00
252.1329498	14.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	241.9991
Annotation	Unknow
Peak:m/z	Relative Intensity
70.5458908	0.09
81.0610275	0.09
82.0462265	0.06
84.7244492	0.47
162.6912689	0.16
182.9123383	15.13
195.9781342	11.77
196.8421478	0.10
198.9932251	0.65
200.8314056	63.09
214.0406952	0.81
215.1426086	0.21
217.7613068	0.08
218.7959290	4.72
221.0258636	0.23
223.8750000	100.00
241.7625885	6.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	363.1449
Annotation	Nagilactone B
Peak:m/z	Relative Intensity
106.9885788	0.41
112.9648285	0.08
119.1289368	0.05
120.9678040	0.23
123.1292572	0.10
124.9115982	0.25
127.2052155	0.04
131.2144470	0.03
134.9293365	0.06
136.1503601	0.05
137.2527618	0.07
139.1310730	0.29
143.0923462	0.10
144.8705750	0.13
147.2101898	0.04
150.8071899	0.08
153.1423645	0.38
157.0933838	0.05
158.0948334	0.08
158.9558411	0.29
161.0606079	0.26
163.0529785	0.50
163.9630737	0.06
165.1238556	0.57
170.9043427	0.09
175.0720062	0.17
176.3428040	0.06
177.2551575	0.13
180.0815582	0.02
183.3588257	0.18
185.2424469	0.03
187.1402283	0.24
189.0422363	0.09
193.2872314	0.03
195.3829651	0.03
198.5370026	0.07
199.2559052	0.08
200.1433258	0.04
201.2479553	0.42
201.9601440	0.49
203.0875549	1.62
205.1014557	0.14
209.1284027	0.05
210.8976746	0.08
213.2040100	4.01
214.5440674	0.34
215.2405701	0.15
216.0989990	0.04
216.9990540	0.02
218.4988403	0.05
219.1194458	0.35
221.3616943	0.08
223.2354736	0.29
225.1345520	0.07
227.2408142	0.90
229.2419128	1.08
231.1566772	14.95
232.0408630	0.34
239.1709290	2.79
241.3062744	0.04
242.2581177	0.02
245.0231323	0.12
247.2589111	0.86
255.2868042	0.71
257.2459412	12.47
258.2387390	0.28
261.0203857	0.14
267.2652588	0.05
271.0565491	0.06
273.1681519	1.07
275.1610107	14.16
276.2391357	0.14
281.5131836	0.02
283.0773010	0.48
287.1502686	0.09
299.4799805	0.07
301.1306763	5.55
302.1484985	0.11
303.3941345	0.09
315.4553833	0.03
317.3367920	0.26
319.1957703	100.00
320.2378540	0.82
321.1845398	0.04
327.5899658	0.02
344.0063782	0.02
345.2189636	3.34
346.0899353	0.08
362.6001587	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	423.1511
Annotation	Unknow
Peak:m/z	Relative Intensity
121.0679398	0.15
124.7103729	0.05
145.2120667	0.02
160.9735718	0.39
169.0633545	0.19
179.1082916	0.15
181.4276123	0.12
187.0272217	0.49
195.2171021	0.07
197.2642670	0.09
199.1544189	0.50
201.1926422	1.39
211.2550659	0.07
215.4651947	0.06
223.3259277	0.09
225.0172119	0.34
226.9124451	0.10
235.2679749	0.06
242.1610718	0.28
243.0921021	0.99
255.3352356	0.05
257.1820374	0.04
259.0205688	0.43
261.1333313	100.00
267.2362976	0.19
279.2214355	0.14
282.9302673	0.47
285.0971985	0.26
287.3056030	0.02
290.9788208	0.11
293.3721924	0.05
294.8856201	0.05
297.0382385	0.09
299.2397461	0.06
302.6025391	0.07
303.2139282	1.35
304.4353333	0.06
305.3092041	0.07
309.1271057	0.23
310.3932495	0.08
313.2443848	0.53
315.4937439	0.07
327.0683594	0.09
331.2796631	0.23
333.0909424	0.74
335.2494507	0.05
343.0130005	0.06
347.1089783	0.05
349.3914490	0.18
351.4878540	0.09
360.4957886	0.09
361.3921204	0.10
363.2547913	4.09
369.0184631	0.05
375.2878723	0.33
377.2167358	51.17
378.1693420	0.45
379.4234314	0.41
380.3200989	0.02
387.3701782	2.98
393.3572083	0.06
395.3176575	0.17
403.4671326	0.25
404.4471741	0.25
405.1124268	1.97
407.1013489	0.03
408.4471741	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	522.1826
Annotation	Herbicidin E
Peak:m/z	Relative Intensity
161.0727844	0.26
179.0068970	2.06
180.1255951	0.44
213.3111877	0.06
239.4364624	0.19
254.0447998	0.07
280.0906372	0.13
309.0380249	0.16
330.2272339	0.60
331.2317505	0.06
341.1452026	100.00
341.7616577	0.13
396.3123169	0.04
418.2541504	0.03
435.1970215	0.07
487.5119019	0.03
491.1268311	0.06
504.2664185	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
92.97439575	0.04
94.97441864	0.84
98.97286224	0.18
100.8944321	0.21
105.0102844	0.15
108.9599686	0.88
111.0616074	0.36
111.8600464	0.21
113.0576324	0.27
115.2806931	0.09
117.0455017	0.11
120.9063416	0.59
123.1045609	0.54
125.0034943	0.84
126.8445435	0.18
129.1031036	0.87
131.0463715	0.77
135.1234131	0.69
136.9522552	0.81
137.7887268	0.10
139.0254517	1.38
141.0173645	1.30
143.0301819	2.30
146.970871	0.20
149.0318909	2.33
150.8245544	0.11
152.9341736	1.50
154.9503784	1.00
156.086792	0.06
157.1402283	1.11
159.0842896	0.36
160.9112244	0.64
163.1131592	0.34
164.8948059	0.17
167.1638184	1.63
167.9632568	0.04
169.1443634	2.35
171.0340271	1.01
173.0976868	0.79
175.242981	0.82
176.0401611	0.26
176.9788513	0.62
179.0313721	1.34
181.2285309	0.56
183.0458984	3.57
184.9466248	0.28
187.3544922	0.15
189.0491943	1.13
190.9962921	2.00
193.15625	2.40
195.0775757	2.05
196.3957062	0.82
197.0974426	2.50
199.1006317	0.78
201.0756683	0.65
203.2652283	0.36
205.0408325	0.68
207.0968018	1.11
209.2209473	1.49
211.111908	5.89
213.0392761	1.30
214.1226807	0.14
215.2038879	1.77
217.3701477	0.61
219.1612549	0.29
221.088501	0.21
223.5700378	0.94
225.1197815	2.70
227.0211792	0.61
229.1298523	1.01
230.0469666	0.33
230.8225098	0.25
232.0274048	0.42
233.1509705	1.29
234.0715027	1.62
235.0748596	3.15
237.1975098	1.08
239.1451721	2.34
240.9966125	2.05
247.3145752	0.47
249.1125488	0.65
249.9958801	0.10
251.1259155	0.91
253.2330933	10.06
255.1688843	0.32
257.2999268	0.82
265.1278381	1.68
266.4414062	0.59
267.2759399	1.31
269.2006226	1.38
269.9108276	0.29
275.1963806	15.50
276.406311	0.68
281.1045227	0.09
283.1078491	0.52
290.938324	0.63
293.2020569	100.00
294.2891235	0.78
296.3344116	0.56
302.2331543	2.03
302.9483643	0.31
310.5085449	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	614.26
Annotation	Unknow
Peak:m/z	Relative Intensity
173.9244537	0.01
178.0164337	0.09
179.2502899	0.02
183.2531281	0.04
187.9257202	0.02
190.1442108	0.06
193.1252441	0.25
195.1759338	0.10
196.1153870	0.02
197.2534637	0.13
198.0440216	0.02
199.3209839	0.06
205.1101074	0.01
206.1440277	0.03
206.9965973	0.08
208.4761353	0.02
209.1759033	0.05
210.0943909	0.04
211.2574463	0.07
213.4768982	0.05
215.2591400	0.10
216.2011108	0.03
217.0441284	0.04
219.0897827	0.02
222.0326843	0.00
223.0502625	0.05
224.0934601	0.18
225.0899200	0.11
225.9742279	0.13
227.1633606	0.16
228.9705811	0.12
230.5334930	0.08
231.2919769	0.01
234.1333618	0.03
235.2561798	0.03
236.0206146	0.03
237.4602661	0.19
238.2264099	0.22
239.1519165	0.19
240.2248230	0.06
241.3388062	0.05
242.1801147	0.01
243.1145630	0.09
244.2378235	0.02
245.1100159	0.05
247.1653290	0.02
249.2880249	0.24
250.1416931	0.14
251.1493225	0.28
252.1585693	0.03
253.1597900	0.06
254.1187286	0.01
255.2532654	0.17
256.2570190	0.06
257.0646362	0.11
259.0744019	0.08
261.2434692	0.01
262.1457214	0.12
263.6325684	0.17
265.0109863	0.01
266.0893860	0.16
267.1305237	0.06
268.0622559	0.11
269.3070068	0.31
270.1667480	0.01
271.2438965	0.08
273.2235718	0.13
275.5130310	0.02
276.3298645	0.05
277.2283020	0.01
278.1536255	0.11
280.4049988	0.03
282.2828674	0.03
283.1309814	0.48
284.1354370	0.02
284.9429932	0.01
286.2311401	0.27
287.5566406	0.03
288.1838989	0.01
289.3123169	0.06
295.3819885	0.06
296.1889648	0.03
297.4064026	0.01
298.2543945	0.16
300.4749756	0.04
301.1502686	0.12
305.1945190	0.03
308.1427612	0.04
309.3109741	0.05
311.2983398	0.03
312.3280640	0.14
313.2799683	0.08
314.2329407	0.05
316.4171753	0.06
317.3311157	0.08
318.2777405	0.04
320.0493774	0.04
321.2711182	0.01
325.5581665	0.02
326.2472534	0.04
327.3912354	0.02
328.3670044	0.04
329.2391357	0.04
330.4080200	0.28
333.2612305	0.03
334.0443115	0.01
338.2625122	0.03
342.1976318	0.07
343.3099365	0.06
344.3865967	0.19
345.1531372	0.01
345.9797363	0.04
347.4300537	0.07
348.3907471	0.15
352.2792969	0.03
358.2186279	0.02
359.2268066	0.05
360.2649536	0.19
362.3279419	0.15
363.3204956	0.09
368.3284302	0.06
370.2294922	0.76
372.3609009	1.10
374.2456055	0.10
376.3214111	0.07
378.3217773	0.09
380.2596436	0.05
386.5289917	0.01
388.2158203	1.64
390.3002319	1.16
392.2988892	0.02
394.5912476	0.03
398.3649292	0.07
399.3261719	0.01
404.3416138	0.25
406.3482666	0.31
407.1497803	0.04
408.2170410	0.22
411.5257568	0.11
416.2947388	9.02
417.2018433	0.18
418.3284912	0.51
419.3912964	0.06
422.5117798	0.20
425.3909912	0.03
432.3182983	0.14
434.2512207	22.27
435.2333984	0.09
438.4616089	0.03
443.9620361	0.06
449.2103271	0.04
452.2505493	100.00
453.4404297	0.17
463.2193604	0.03
469.4510498	0.02
476.2508545	0.02
491.1554565	0.01
493.1405640	0.04
494.5120850	0.07
496.8200073	0.04
507.9309692	0.06
510.2072144	0.12
515.9634399	0.01
524.8483276	0.06
533.5289307	0.04
536.7857666	0.02
540.2894897	0.03
541.2125854	0.01
542.3996582	0.16
550.3237915	0.70
552.1464844	0.23
555.0084229	0.01
560.4498901	0.04
568.4136353	1.51
570.1565552	0.27
571.5739746	0.02
578.3647461	0.34
589.2809448	0.05
596.3023071	20.20
597.0713501	0.10
597.8043213	0.02
605.9777222	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.3078
Annotation	PE(18:1(9Z)/0:0)
Peak:m/z	Relative Intensity
167.1445923	0.35
198.1459961	0.67
234.1570587	0.41
249.1820679	0.10
252.0665588	0.64
257.3151245	0.58
261.1563416	0.07
268.0179443	0.46
269.1759949	0.11
290.0858154	0.14
308.5039673	0.07
339.2786255	100.00
340.1653442	0.95
352.2613525	0.63
355.0108643	0.09
358.7875366	0.19
361.5279541	0.41
398.521637	0.47
399.3927917	0.20
406.4768982	0.58
407.9862671	0.10
413.289978	0.20
422.7530212	0.32
427.4701233	0.47
434.3847046	0.67
444.5843811	0.25
445.2207336	0.33
449.4779053	0.08
462.3531189	4.06
470.7865906	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	670.83
Annotation	Unknow
Peak:m/z	Relative Intensity
206.6630249	0.08
250.9861298	0.86
289.9389038	0.03
290.7882690	0.06
334.9323730	3.18
336.2574463	0.02
363.7481079	0.01
364.4743652	0.05
374.4884033	0.06
411.0786133	0.09
418.8436279	16.90
456.0347290	0.39
456.6874390	0.02
458.1118164	0.92
458.9666138	0.17
463.1026611	0.02
494.9799194	0.05
502.6766968	24.93
503.3372803	0.03
507.3856812	0.03
509.2226562	0.13
526.9202881	0.07
534.7095337	0.04
539.3103638	0.02
550.4966431	0.02
551.1654053	0.04
564.9044800	0.04
586.6337280	100.00
587.3587646	0.31
589.2839966	0.03
599.1009521	0.03
607.0036011	0.04
610.6574707	0.08
623.8887939	0.05
624.8303833	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	459.1869
Annotation	Crosatoside B
Peak:m/z	Relative Intensity
137.3599548	0.39
139.0337524	2.16
143.0779114	2.25
143.9266052	1.55
146.9929962	7.93
148.9071655	11.73
151.0962677	0.17
155.4502563	0.55
158.9919434	3.43
161.0364075	2.38
165.0803528	8.59
168.3588867	0.55
173.3272400	0.53
175.0285034	2.14
177.0972900	35.33
178.3830109	1.12
179.0074768	2.60
181.1404266	0.82
183.0673523	0.28
187.0979309	0.16
189.2080688	2.07
191.1183167	1.04
193.0300903	8.50
195.1372833	0.57
199.1906433	2.15
200.9803467	0.55
202.2313538	0.27
204.0376587	0.93
206.9848022	0.55
208.9325409	0.40
215.3750000	0.13
217.1117401	36.63
218.1851501	0.12
219.2053070	0.88
220.9390564	9.70
232.8769836	2.27
235.1678314	13.76
237.1018677	0.44
243.4623413	1.41
251.1913757	1.33
257.2309875	0.37
261.0203247	32.66
263.1363831	1.56
266.9281616	0.39
279.0567322	100.00
281.4560547	0.42
297.1956177	2.69
319.3314819	1.09
323.3093872	0.27
328.5634460	0.16
333.1730652	0.29
354.7079468	0.26
365.1063232	0.39
371.1056519	0.38
395.3114319	0.16
397.2563782	1.50
405.0779724	0.26
413.2485657	2.05
414.1218567	0.22
415.2518921	4.03
441.2069397	37.08
449.6333008	1.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	728.88
Annotation	Unknow
Peak:m/z	Relative Intensity
228.9416504	0.29
248.1593628	0.03
273.0492859	11.68
300.3770142	0.08
304.9243164	0.03
387.0037231	14.23
411.1840820	0.07
499.0339355	0.38
500.8425903	66.61
501.9765625	0.20
516.8757935	0.08
541.3142090	0.09
566.7966919	0.12
571.1060181	0.07
581.1095581	0.02
588.8964844	0.07
599.0830078	0.07
607.8764038	0.16
608.9362183	1.00
609.9776001	0.30
611.1216431	0.14
613.1467896	0.20
614.7841187	100.00
615.6416016	1.36
616.5018921	0.10
624.9806519	0.04
625.8897095	0.08
626.8987427	1.29
627.5162354	0.03
638.9464111	0.22
640.3016968	0.05
640.9494019	0.10
644.3649902	0.03
654.0778809	0.86
654.9395142	6.47
655.9567871	2.74
657.0830078	0.04
669.2862549	0.07
671.8054199	0.22
672.9353027	1.38
673.7570190	1.13
680.0927124	0.08
682.8042603	1.53
683.7672729	0.57
685.0004272	0.22
696.8582153	0.24
700.0868530	0.12
700.8576660	0.62
710.7856445	0.35
711.9904175	0.06
935.8093262	0.03
954.5680542	0.03
956.7255249	0.07
1070.4327390	0.27
1181.2283940	0.03
1182.8842770	0.18
1184.6562500	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.2762
Annotation	Canavalioside
Peak:m/z	Relative Intensity
190.9922638	0.01
199.0303192	0.01
256.2153931	0.03
281.1646118	0.01
303.2196655	0.01
304.0366821	0.03
310.7651978	0.01
311.4173584	0.04
325.2949219	0.05
333.4691162	0.01
341.5543213	0.01
347.3162842	0.02
351.2511597	100.00
361.3496704	0.03
379.4114990	0.02
387.3422852	0.01
389.1481323	0.03
393.1621704	0.96
394.6688843	0.01
396.3919067	0.01
399.7431641	0.01
402.1658325	0.02
405.4378052	0.01
411.4609985	0.03
415.3827515	0.01
443.3577271	0.01
453.0880737	0.12
463.2792358	0.03
472.6329346	0.02
475.3305054	0.05
479.8865356	0.03
487.3591919	0.01
495.2284546	0.01
498.4198608	0.01
499.4286499	0.01
512.5073853	1.17
513.1972656	5.08
513.8802490	0.01
515.1400757	0.10
521.1694336	0.09
523.3095093	0.07
526.6107788	0.04
528.4984741	0.02
540.4357300	0.08
541.3588257	0.33
542.3592529	0.02
543.9509888	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.34
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
165.8995972	0.78
184.0211029	100.00
196.8555145	0.09
240.2351379	0.14
258.2276611	0.90
283.4981079	0.05
304.1303101	0.07
333.9149170	0.07
335.3391113	0.07
433.3765259	0.06
453.2050171	0.07
454.9431152	0.06
470.2734375	0.19
482.4003296	0.09
502.3674316	57.26
503.0845337	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1089
Annotation	Lactulose
Peak:m/z	Relative Intensity
100.9252319	6.57
105.8145523	0.13
107.0015945	0.33
112.8998108	18.81
114.9991074	0.11
118.9123688	18.79
125.1501999	2.54
130.9105682	7.87
142.9120483	19.05
148.8545837	2.96
160.8723145	23.47
178.9769745	100.00
220.5163269	0.20
262.2527771	0.22
281.0702515	1.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	751.29
Annotation	Unknow
Peak:m/z	Relative Intensity
244.0011139	0.23
269.2229919	0.08
325.0849609	1.33
341.1802368	0.76
347.1165161	0.05
350.2677002	0.17
350.8821716	0.48
365.0533142	0.20
369.3675537	0.31
387.1549072	100.00
412.3996582	0.13
419.1301270	0.66
446.0239868	0.10
504.2014771	0.23
548.9712524	0.09
569.3739624	0.24
577.3591919	0.08
585.1175537	0.27
588.3242188	0.32
589.1112061	0.21
597.2249146	0.11
604.2580566	0.61
643.3314819	0.20
659.4221802	0.38
679.2247925	0.43
687.5149536	0.47
705.2576294	1.35
707.2577515	0.15
714.4868164	0.21
733.2634277	1.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	363.1447
Annotation	Nagilactone B
Peak:m/z	Relative Intensity
116.9490509	0.03
124.9936676	0.07
142.9377747	0.03
165.0362549	0.05
171.1683044	0.09
173.0003052	0.61
176.7843170	0.07
187.3742065	0.03
193.4602661	0.03
201.1910095	0.63
213.1549377	0.31
215.2202454	1.75
217.0260620	1.90
229.2059631	0.43
231.2932129	0.15
239.1396484	7.82
239.7635193	0.04
241.2807312	0.08
242.3460999	0.20
244.8778381	0.04
247.3851013	0.06
255.3466187	0.17
257.2158203	21.79
258.4219666	0.03
265.3297119	0.06
267.4273376	0.03
268.2370911	0.06
273.1057739	3.46
273.7625122	0.05
275.2549438	3.87
276.2604675	0.05
283.2118835	0.18
299.4426880	0.04
301.1574097	71.91
317.1953430	0.83
319.2622070	23.21
320.3806763	0.03
327.4451904	0.49
335.5329590	0.08
345.1613159	100.00
346.3240051	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.1532
Annotation	Anisocoumarin C
Peak:m/z	Relative Intensity
106.9912262	0.12
109.1125793	0.05
113.0261765	0.02
114.2272797	0.14
119.0879135	0.02
121.0523224	0.54
123.1834259	0.09
124.9589691	0.13
126.9394073	0.02
131.3988342	0.10
135.1352234	0.04
137.1184082	0.10
138.3532715	0.05
142.8920898	0.07
145.1205139	0.02
146.7064819	0.02
148.9754333	0.43
151.0086212	0.07
154.8908081	0.26
157.1543274	0.24
158.9320984	0.22
161.0402832	0.54
163.2053833	0.06
165.2599792	0.08
167.0601196	0.13
169.1430664	0.19
173.2836914	0.02
174.9677734	0.21
176.6382141	0.25
181.1575317	0.24
183.2706146	0.10
184.8798523	0.21
187.1582642	0.10
189.3317719	0.11
191.1062927	0.16
193.1083069	0.05
196.7971802	0.17
199.4486847	0.20
200.8878174	0.07
203.1453247	0.42
205.0669861	0.02
207.1465454	0.29
209.0445862	0.12
210.1026611	0.08
211.0892029	0.18
213.5768127	0.05
214.8905334	0.05
217.0457153	0.07
219.0870972	0.23
221.1253357	0.35
223.1879578	0.58
225.2920227	0.57
227.1154480	2.18
229.1294861	0.45
230.9023438	0.16
232.0879517	0.04
233.0584412	0.21
234.9754028	0.02
237.3756409	0.07
239.1828308	1.63
241.1958923	14.39
243.2860107	0.59
245.2129517	0.91
246.8308105	0.02
249.3151245	1.04
251.1942749	0.63
253.0620728	0.08
255.1362915	0.99
257.1553650	2.81
259.1491394	0.77
264.2095947	0.08
265.3693848	0.10
267.1786804	13.54
268.1892090	0.08
269.2226562	3.40
270.9562378	0.50
273.1253967	0.13
277.0722656	0.21
283.1906738	4.35
285.1206970	32.68
285.9801025	0.21
287.1812439	5.02
287.7861328	0.08
289.2957458	0.05
295.0863342	11.15
295.6874390	0.10
299.6502075	0.05
301.2213440	1.98
302.1467590	0.03
303.2394714	7.84
313.1271362	100.00
314.0723877	0.05
315.9948120	0.05
321.7132263	0.11
331.1694031	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	245.0432
Annotation	Sedoheptulose
Peak:m/z	Relative Intensity
78.8875809	0.96
80.7861786	0.07
96.9765778	0.19
136.8603821	0.07
151.0892792	0.23
152.9338684	100.00
153.9413605	0.03
171.0319366	8.16
227.1775513	0.14
228.1388702	0.03
245.1016846	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	671.2662
Annotation	Kamalachalcone A
Peak:m/z	Relative Intensity
317.0377502	0.02
318.3349915	0.07
347.5791626	0.03
365.4108887	0.10
387.1962280	0.05
403.3225708	0.10
417.3452148	0.04
463.3491821	0.07
491.5477295	0.05
494.2518311	0.19
507.2409058	0.02
509.5691528	0.14
527.5565186	0.07
535.2034302	0.04
538.4869995	13.05
539.3140259	100.00
539.9334106	0.18
550.2421265	0.06
573.4451294	0.09
575.4376831	0.09
585.1207275	0.13
591.4670410	0.10
592.4605103	0.08
599.3678589	0.58
610.3552856	0.89
625.1317139	0.13
627.3164062	0.16
635.1818237	0.02
636.2598267	0.18
641.6606445	0.03
651.7308960	0.08
653.2870483	34.02
654.3438110	4.52
656.8853149	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.14
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
171.1223755	0.12
175.0407715	0.09
176.9762115	0.24
179.0911407	2.17
185.1937408	0.51
192.0055542	0.45
197.0871887	0.41
198.2950897	0.20
203.3843842	0.16
210.1475220	2.44
210.9831848	0.36
212.6370850	0.10
223.2540283	0.16
242.3410339	0.12
252.1425476	0.12
254.1604919	14.65
255.2398682	0.13
263.0207520	0.23
269.1472473	0.08
272.0907288	37.77
286.2124634	1.85
288.1636963	5.85
304.0771790	14.98
306.1167603	100.00
306.7642212	0.15
320.0772400	0.55
338.1171875	39.75
353.1192627	0.29
464.1768799	0.78
467.2975464	0.10
482.2330322	29.27
505.6004028	0.14
528.2677612	0.14
549.5346069	0.04
575.2406616	0.26
593.2501831	16.30
594.3916626	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	363.1791
Annotation	[3aR-(3aalpha,4beta,6alpha,6aalpha,7beta,7abeta,8abeta,8balpha,8cbeta)]-Dodecahydro-6,7-dihydroxy-6,8a-dimethyl-3-methylene-2-oxooxireno[2,3]azuleno[4,5-b]furan-4-yl ester 3-methylbutanoic acid
Peak:m/z	Relative Intensity
107.2341537	0.46
115.8596802	0.05
132.1042480	0.15
147.0915527	0.69
151.0935974	0.09
165.1695251	0.07
178.0801086	0.17
179.1780701	0.07
181.1334991	0.09
187.1748352	0.13
201.2079163	0.09
207.1634521	0.35
217.3704529	0.15
221.0722961	0.38
223.1005249	0.09
228.2622681	0.05
229.2454529	0.33
230.8752136	0.05
237.5297546	0.09
238.2255249	0.25
240.7952576	0.18
242.1839294	0.03
243.1294556	0.04
247.1374207	0.19
249.3135071	0.05
253.1115112	0.15
254.2465820	0.49
255.2994385	0.14
256.7158203	0.17
260.2517090	0.06
269.1876221	0.13
270.5604248	0.48
271.2516479	1.32
272.1348877	1.29
273.2515869	0.83
275.9817200	0.08
278.8669434	0.19
281.1026611	0.86
283.1633301	0.14
289.0705872	0.66
290.8517456	0.09
295.7662964	0.04
297.2301025	0.05
299.1692505	6.14
300.8359070	0.46
301.6399841	0.28
303.1686401	0.66
305.2917175	0.37
307.2733154	0.15
308.4248657	0.17
309.2252808	1.02
315.2863159	0.26
317.0528259	8.86
317.7570190	0.09
319.6321411	0.64
321.9862671	0.06
327.1256409	4.74
331.2986450	0.29
332.9175415	0.16
333.8255920	0.12
335.0896301	6.03
336.2416992	0.24
339.4370728	0.11
345.0708008	100.00
345.7391357	0.84
347.9784851	1.21
353.7968445	0.54
354.4648743	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	477.1765
Annotation	Scorzodihydrostilbene D
Peak:m/z	Relative Intensity
253.0448914	0.17
254.2145386	0.59
272.0123291	1.07
311.3658752	0.26
314.2207031	0.03
315.2474365	0.06
316.1934204	0.03
331.0097351	0.05
333.0090027	0.04
337.1176453	0.07
355.1247253	0.11
372.2280273	0.13
374.2279053	0.23
377.4844666	0.05
382.2802734	0.14
386.2984619	0.08
387.9831848	0.06
389.9610291	0.04
390.8640747	0.04
397.5738220	0.12
398.7709351	0.29
402.1801147	0.14
418.1156311	0.14
431.0245667	0.22
432.0806885	4.26
434.2089539	100.00
435.1895142	0.10
442.5044556	0.34
449.9132080	0.06
452.3757019	0.11
455.6480713	0.09
460.2500000	0.63
461.2651367	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	206.89
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8014526	100.00
132.9769592	0.07
145.0694733	0.13
151.1470795	0.03
164.9592896	0.01
166.0781860	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	739.3168
Annotation	Ixerisoside L
Peak:m/z	Relative Intensity
261.0666504	0.06
313.4559326	0.02
347.3055420	0.04
363.4748535	0.06
376.4340210	0.09
377.0789185	0.03
387.2100830	0.26
391.2815552	0.07
393.3574219	0.04
397.2774048	0.07
408.4692993	0.02
457.2996216	0.03
482.4256592	0.02
493.2809448	0.06
535.7926636	0.06
571.8583374	0.12
577.6862793	0.04
578.8330688	0.12
591.6852417	0.02
607.7584229	0.13
617.5097656	0.06
618.5430908	0.21
621.7935181	0.09
629.4069214	0.08
631.1591187	0.02
632.4324951	0.05
641.3348389	0.04
652.1622314	0.16
653.2786255	0.07
653.8992920	0.15
656.2068481	0.08
667.3182373	0.09
676.7310181	0.10
693.2626343	0.07
694.2136841	0.20
695.3349609	0.58
701.0310669	0.11
703.3349609	0.60
719.2135620	0.10
721.3591919	100.00
722.0178223	0.48
738.8574829	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	763.3899
Annotation	Cinncassiol A
Peak:m/z	Relative Intensity
217.2019196	0.10
229.2770691	0.09
233.1719971	0.03
249.0722504	0.04
255.2471313	0.10
257.2717285	0.15
259.2976074	0.04
271.0418091	0.10
273.3489685	0.21
275.3087769	0.10
285.2418823	0.09
287.2857666	0.06
291.1098633	0.05
293.1009827	0.13
301.1118164	0.07
309.2452393	0.14
319.4548340	0.19
335.3013000	0.07
337.3450317	7.91
339.0637207	0.06
344.1173706	0.02
345.4027710	0.13
363.2800293	0.08
371.1333008	0.18
372.3120117	0.07
377.2085571	0.13
379.3934937	0.08
381.3270874	100.00
383.3395996	0.07
391.2681274	0.11
411.3446655	0.09
417.2299805	0.03
498.5824585	0.12
531.2279053	0.02
534.7260742	0.02
535.3854980	0.19
537.2962646	0.06
550.3930054	0.06
552.5431519	0.10
554.8944092	0.07
567.3242798	0.05
570.6072388	0.04
583.3888550	0.02
589.1038208	0.09
600.3734741	0.09
601.0177612	0.02
603.2431030	0.11
641.0324707	0.08
655.5501709	0.05
657.3765259	0.03
664.2123413	0.06
667.2752075	0.04
675.7857056	0.47
694.6971436	0.05
703.0625000	0.04
712.8933716	0.09
714.0327759	0.25
715.1729126	0.63
719.4384155	0.42
720.4072266	0.25
726.5007935	0.04
733.5297241	0.15
743.3170776	0.04
744.7410278	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	374.2318
Annotation	Rabdokunmin D
Peak:m/z	Relative Intensity
122.8402786	0.13
132.2073059	0.11
133.0094299	0.15
141.9108887	0.24
151.4649048	0.14
153.2559357	0.25
157.0063019	0.21
159.2946472	0.10
161.0422668	0.33
162.0999756	0.41
163.1285095	0.26
163.9631348	0.55
165.0957336	0.16
180.0851898	0.08
181.1436462	0.35
189.2511292	0.10
190.8623199	0.52
192.9314117	0.27
194.6334076	0.63
197.0857849	0.09
206.0840759	0.08
211.5888824	4.12
212.2421722	2.46
214.1406555	0.47
220.7990723	0.12
222.3310547	0.10
223.2749939	0.36
225.0802307	0.30
229.1709595	0.19
230.0779114	0.26
231.3192444	0.31
239.4375610	0.26
240.2067566	0.18
241.3715515	0.28
251.1244202	0.45
252.1590271	0.31
253.3035278	0.54
257.1788635	0.48
264.2452393	0.28
267.1771545	0.56
267.8900146	0.57
269.1975708	4.07
272.2507935	0.08
275.1101379	0.42
280.2675171	0.27
282.3385010	0.57
284.0238647	1.14
285.3931885	0.94
287.3793640	0.32
288.1401062	0.10
289.2542114	0.08
293.3517151	0.07
294.2622681	0.09
295.1427917	0.11
296.1632385	0.42
297.1899109	1.22
303.0744629	0.21
310.2209473	5.27
311.1584778	0.40
312.4389648	0.33
314.3101501	1.96
315.1681824	1.90
316.1274109	0.34
320.4364929	0.17
321.0555420	0.15
328.2262268	100.00
329.5004883	1.35
330.3622437	1.99
331.0278320	0.12
332.3163452	1.95
333.2130737	0.51
338.3350830	1.03
338.9733887	0.16
346.2266541	0.27
347.3611755	0.28
356.2585754	82.60
357.3432617	1.56
365.4054871	1.61
374.9283752	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.26
Annotation	5beta-cholestan-3alpha,4alpha,11beta,12beta,21-pentol-3,21-disulphate
Peak:m/z	Relative Intensity
173.2319641	0.23
207.2014313	1.34
209.2230835	0.66
215.2623901	0.37
216.9483032	0.36
223.1374512	0.24
225.1786652	11.14
227.1054382	28.68
233.2666473	0.14
235.1961212	0.36
243.0997620	0.23
245.2439575	0.20
247.1114044	0.48
251.0549316	1.53
259.3436890	0.23
262.9429321	0.95
269.1393127	23.38
274.9987793	0.30
281.1513062	0.13
283.4693298	0.13
287.1612549	100.00
305.3483276	0.15
323.1114502	24.39
329.3526001	0.15
341.1238403	9.20
359.2489624	0.69
371.2646484	3.28
382.9827881	5.00
383.6164551	0.16
385.2675171	0.48
387.1306763	0.08
389.1790771	0.30
395.2071533	0.20
413.2440186	12.85
419.5609741	0.74
427.4280396	0.20
431.2942505	32.47
447.1882324	0.18
449.3116455	0.66
480.3317261	0.37
483.3876953	0.21
491.3140869	0.08
521.2745361	0.41
524.3936768	0.17
527.4508667	0.07
534.3103027	0.44
557.3632202	0.74
565.4816895	0.50
567.6233521	1.19
575.1779785	0.80
591.2305298	0.30
593.2962036	49.04
594.2963867	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	624.2322
Annotation	Unknow
Peak:m/z	Relative Intensity
162.9632416	0.11
206.9227448	0.41
210.8150940	0.50
241.0140991	0.59
253.1980896	0.46
258.7796021	2.22
270.8948975	7.16
271.5050659	0.06
280.5728149	0.33
282.0424805	1.42
288.8088684	11.81
303.6038513	0.52
306.0119019	0.73
306.8518372	7.83
311.4492798	0.26
321.5124512	0.12
323.3536377	0.28
324.9414673	100.00
329.9740601	0.16
337.0953979	0.23
337.9719238	0.13
339.9760132	0.10
340.7699585	0.51
342.7672119	72.34
343.6046143	0.37
347.3168335	0.17
367.2752686	0.46
413.8470459	0.40
420.6193848	0.64
431.7275391	0.20
444.2469482	0.34
450.2935181	0.21
451.1519165	1.00
462.0108643	15.95
462.6138916	0.30
468.9505005	0.30
486.7554932	1.93
503.5151978	0.21
504.4818726	0.91
505.2247925	0.15
588.3628540	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	553.1923
Annotation	Gibberellin 2-O-beta-D-glucoside
Peak:m/z	Relative Intensity
209.1748352	0.04
282.8842163	0.05
292.7034302	0.04
313.2506714	0.07
331.0372314	0.03
332.9743652	0.07
341.3883667	0.05
343.9429321	0.01
345.2912598	0.33
355.3900146	0.02
364.1723022	0.04
365.3479004	0.09
369.3518066	0.02
372.2509155	0.03
373.6035156	0.05
390.5776978	0.13
391.3211060	0.01
405.1559448	0.14
419.4012451	0.31
420.2885132	0.03
431.1031494	0.10
447.6558228	0.02
457.1702271	0.17
459.3646851	0.06
463.5695801	0.09
465.1720581	0.12
470.1477661	0.02
485.2491455	0.05
489.3764648	0.15
493.7286987	0.02
507.1658325	100.00
507.8427124	0.25
509.5182495	0.13
517.4191284	0.06
521.1768188	0.03
523.4221191	0.19
534.2513428	0.19
535.2802124	0.31
537.3564453	0.05
538.1499634	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.1328
Annotation	Ciprofloxacin
Peak:m/z	Relative Intensity
97.05311584	0.05
105.9463654	0.10
107.9538422	2.19
113.0835419	0.02
115.9867859	0.15
123.0557632	0.33
123.9926071	0.08
130.7789001	0.02
133.1255188	0.04
134.0011902	1.20
134.8390961	0.01
136.0452881	1.60
137.276886	0.02
140.1312561	0.01
142.1409302	0.02
147.0788574	0.01
151.9498749	6.68
154.0986023	0.17
158.9177856	0.03
170.0982819	9.52
170.7732849	0.01
176.2963257	0.01
181.0250854	0.06
184.1308289	0.01
190.2975464	0.03
193.0841675	0.04
194.0424194	0.01
195.2985229	0.03
203.2210846	0.02
211.8727722	0.07
216.1314087	0.06
217.0805054	0.06
220.0479736	0.01
222.2844849	0.02
226.9129944	0.02
229.8996277	0.07
232.3785706	0.05
236.5153809	0.04
238.1838684	0.01
240.2333069	0.05
242.9795837	0.05
245.1262817	0.02
255.0957642	0.04
260.9574585	0.01
270.0874939	0.02
272.0899658	0.04
274.2064514	0.01
278.0987549	0.10
286.0409241	0.02
288.4217834	0.06
296.1035156	0.16
312.3284302	0.03
314.1412964	100.00
315.1722107	0.17
323.8432617	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	606.0735
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
175.0429535	0.27
176.9187927	0.58
193.0196381	0.04
210.9865570	0.59
217.0675659	0.10
222.0011749	0.50
240.2125549	0.43
246.1280212	0.61
255.2494354	0.44
261.0511475	1.77
261.9943237	0.07
264.1007080	2.92
273.0276489	14.84
280.2228394	0.13
282.1227722	28.90
283.1220703	0.12
287.1348267	0.19
290.9788818	0.30
300.0405884	5.77
305.0655518	3.62
308.8278809	0.08
323.0478516	16.30
324.2123413	0.31
326.1697388	0.13
344.0499268	1.77
360.8590698	0.12
362.0466309	19.55
363.0873413	0.37
367.1206665	0.27
380.4378662	0.06
385.0516357	100.00
386.1201782	0.81
393.8096924	0.26
396.2199097	0.35
403.0877075	61.82
404.0149536	0.37
432.6029663	0.17
444.0683594	0.16
461.1792603	0.27
493.9893799	0.55
508.1357422	7.17
509.1622925	0.07
522.0386963	0.49
523.0549927	0.19
526.0162964	0.03
546.2939453	0.14
560.0394897	0.08
563.1887207	1.31
588.0089722	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
132.9961243	0.14
138.210144	0.41
148.9851532	0.17
153.0079041	0.11
165.0013428	0.30
165.9672394	0.15
169.1399536	0.28
174.982254	0.57
179.3297424	0.21
193.2369537	0.28
205.2675476	0.67
206.2052155	0.74
207.0433502	2.16
208.0433655	1.50
209.3860931	0.51
210.098526	0.20
221.0101929	0.26
222.2441711	0.90
223.2209473	2.80
224.1346283	0.29
230.8953247	0.10
233.2222748	1.40
251.0845184	100.00
252.0995636	16.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	545.257
Annotation	Agnucastoside B
Peak:m/z	Relative Intensity
155.1258698	0.06
157.0254822	0.06
164.9273071	0.16
177.0616150	0.14
180.9248352	0.08
183.4238892	0.03
185.1110840	0.03
190.7536011	0.09
192.1253967	0.06
199.2793427	0.03
202.1049652	0.06
215.3206787	0.10
217.2455597	0.02
237.1390076	0.21
239.1828308	0.43
241.0513763	0.04
243.0782776	0.10
245.1900635	0.07
249.1768646	0.09
251.0099335	0.06
255.2799377	0.16
261.0941162	1.20
265.1380005	0.30
267.2984314	0.10
273.2364502	0.20
283.3156433	1.21
285.2015381	0.19
293.3161011	0.06
299.2822266	0.04
301.1711731	1.74
311.2375488	3.70
313.1469727	0.05
319.2387085	6.10
329.1646118	7.76
333.1976929	0.10
337.2182617	3.66
339.1242065	0.10
347.1286011	67.43
347.7529907	0.14
365.2071533	100.00
374.6824951	0.06
375.5803833	0.07
383.1649170	89.79
391.6419678	0.09
397.2225952	0.16
410.4378052	0.05
423.9534302	0.06
431.3966064	0.10
463.3032227	0.02
477.9783936	0.06
481.2732544	0.13
487.4349976	0.06
488.5355835	0.02
491.3233032	0.19
492.6820068	0.02
499.2802124	1.97
509.0129395	4.82
510.1458740	0.09
527.0794067	61.76
527.7863159	0.61
545.6632690	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.015
Annotation	Myricatin
Peak:m/z	Relative Intensity
170.9243164	0.08
185.8862915	0.04
187.9253387	0.23
204.7909851	0.02
212.1004181	0.03
213.1144409	0.05
214.9590607	0.16
215.8395844	0.04
228.8785400	0.27
230.0637817	0.01
230.8793182	0.09
231.8739624	0.04
235.9854126	0.01
237.0248718	0.24
240.0748596	0.03
255.0505676	0.01
256.2946472	0.04
256.9847412	0.01
258.0153809	0.10
269.0150757	0.01
271.0623779	0.24
272.0632324	0.03
280.3804321	0.07
281.0362549	0.09
282.9215088	0.18
283.8854980	0.03
284.9082031	0.03
296.9914551	0.03
297.9876404	0.18
300.1394043	0.01
310.1353455	0.02
313.3629761	0.04
315.0735474	4.50
316.1181030	0.01
325.1574097	0.04
327.0839233	2.74
328.9556274	0.03
333.1459351	0.51
340.9708252	0.17
343.1518555	0.03
345.9808350	0.02
347.2992554	0.13
357.1646729	0.10
359.0023804	100.00
360.1035767	2.64
360.9205933	0.61
372.2398071	0.03
373.2392578	0.01
378.1411743	0.07
383.0348511	0.05
387.3137817	0.05
399.9860840	0.03
401.8521729	0.03
416.0919189	0.15
416.9567261	0.05
421.8881836	0.04
435.0778198	0.02
436.4323120	0.02
445.0505371	0.02
446.2295532	0.04
446.9526978	0.13
460.9202271	0.12
462.4569092	0.01
463.2673950	0.05
504.5875854	0.05
506.9486084	6.08
514.9190063	0.04
532.9730835	1.57
533.6863403	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2781
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
152.9667511	0.03
187.2701416	0.06
195.8961334	0.04
212.1997070	0.12
214.1092834	1.08
243.1277771	0.11
252.0696106	0.03
261.4747620	0.04
274.2919006	0.17
279.2560425	100.00
306.4762573	0.47
386.2341003	0.05
388.6746521	0.12
391.9007874	0.13
404.5327454	0.05
430.3861389	0.19
433.3043823	0.28
447.2919006	0.25
449.0068054	0.18
458.3691711	0.15
459.0901794	0.27
467.2140503	0.28
476.6846619	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
92.8296814	0.38
94.9515686	0.60
96.98948669	0.08
99.07832336	0.31
100.9841995	0.55
107.1082153	0.40
107.9041138	0.10
109.0344315	1.03
111.1692352	0.39
113.0229568	0.42
114.9907074	1.64
115.6055756	0.14
119.0707703	0.38
121.1490097	0.26
122.5895157	0.07
124.1145859	0.17
124.9483185	2.11
126.880127	0.07
128.8704834	0.09
131.0840759	0.26
133.0453796	0.54
134.9707336	2.02
136.8739624	0.33
139.1105347	1.51
141.2356873	0.12
143.0185547	1.34
144.9182739	0.85
148.3873596	0.22
149.0186157	0.86
150.1869812	0.48
151.2579498	1.01
152.1998291	0.36
153.1915894	0.45
154.419632	0.47
155.1989288	1.43
157.0617218	0.44
157.9966431	0.53
159.1530304	0.67
163.0496063	2.01
165.1864014	0.64
166.1116638	0.30
167.1010437	0.49
168.9906006	1.23
170.8971252	1.84
172.7230988	0.27
176.4491272	0.76
177.1109619	0.46
178.981842	0.30
181.2096252	0.83
182.9307251	1.11
186.8640747	0.69
188.8683472	0.38
191.3435364	0.16
192.2492981	0.16
192.9528198	0.42
195.1478271	1.74
197.1159973	1.80
198.203064	0.47
199.0058594	1.41
203.3760071	0.17
206.7377625	0.17
208.9158936	1.52
210.4384155	0.31
211.1766357	3.08
213.299469	0.84
214.4906311	0.52
215.2176208	0.68
217.1235657	1.34
221.1997375	0.62
223.0971985	0.31
225.1949463	1.60
227.2823181	1.12
228.1515198	0.10
229.3785706	0.12
232.1631775	0.22
233.149353	1.08
235.1914673	1.72
237.1373291	0.61
239.2961731	0.55
240.9861755	0.68
242.3517151	0.20
247.3050232	0.55
249.4268188	0.56
251.0658569	0.40
252.7032776	1.47
253.425293	2.98
254.1853333	0.15
255.1950684	0.77
257.2384338	0.50
265.1116333	3.36
266.3482666	0.48
267.3702393	1.51
268.1331177	0.08
269.4628601	0.90
270.1343689	0.26
275.3084412	16.57
282.1621094	0.77
283.1581421	1.89
284.5757446	0.38
287.6760864	0.16
291.0306091	0.31
293.207489	100.00
294.1140747	0.48
297.2096252	0.12
310.7061157	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	589.2499
Annotation	gibberellin A2 O-beta-D-glucoside
Peak:m/z	Relative Intensity
184.9896393	0.07
201.2017975	0.04
211.3678589	0.05
224.0889587	0.02
226.9543610	0.02
232.5905304	0.12
233.2932587	0.04
245.1455383	0.02
255.0142670	0.05
257.0580444	0.05
275.0346680	0.07
287.2060547	0.15
314.4609985	0.04
329.1639404	0.13
343.3595581	0.01
359.2379761	0.02
363.1566162	0.03
374.8619995	0.02
377.0593872	0.10
379.3364868	0.02
381.3398438	0.14
389.3533936	0.14
395.2304077	0.05
398.3608398	0.06
412.1646118	0.04
419.2290649	0.02
425.1289062	0.05
426.3367920	0.04
427.3010864	0.20
465.4422607	0.12
468.3407593	0.04
469.5074463	0.19
471.3589478	0.02
477.4164429	0.01
483.1187744	0.02
485.3740234	0.03
495.1499634	0.03
497.4602051	0.09
499.0059204	0.04
513.0579224	0.02
515.1746826	0.04
524.3900757	0.04
525.9844360	0.05
527.1992188	0.04
535.6051636	0.01
538.5576172	0.06
540.2582397	0.03
543.2976074	100.00
544.3801880	0.18
545.2009888	0.15
550.8368530	0.15
553.5481567	0.13
554.6041260	0.03
560.0778198	0.06
566.9099731	0.02
569.2298584	0.01
570.6495361	0.24
571.5516968	0.06
573.5983276	0.03
589.2473755	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.3068
Annotation	PC(15:1(9Z)/0:0)
Peak:m/z	Relative Intensity
147.2837067	0.19
159.1158447	0.17
187.0319214	0.28
233.3980255	0.32
248.8900146	0.42
250.3123474	0.06
251.3284302	0.62
257.3022766	0.10
262.7165833	0.09
291.0263062	0.35
293.1385803	0.50
302.3650818	0.07
305.0338745	0.05
308.5892029	0.52
316.6373291	0.16
322.1509094	0.17
339.2712708	100.00
347.3392944	0.12
350.9541931	0.05
365.6974487	0.57
376.1675720	0.13
379.5339355	0.16
388.4809875	0.08
413.4378052	1.15
415.1886597	0.25
417.3449097	0.26
419.0286255	0.19
421.2725220	0.52
422.0000916	0.35
423.9226685	0.47
430.9594116	0.49
434.2482300	0.08
436.0621033	0.38
438.8211975	0.09
439.9829712	0.43
446.2730408	0.22
449.3978271	0.20
455.4677429	0.34
462.2442932	5.73
462.9866028	0.90
464.3047791	0.10
471.1847534	0.26
481.1271362	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	405.1765
Annotation	Unknow
Peak:m/z	Relative Intensity
123.0410309	0.07
124.8780136	0.02
127.1108093	0.04
131.2264404	0.01
139.0076599	0.12
150.1125183	0.02
163.2213593	0.05
163.8572845	0.02
181.2176514	0.71
183.1794891	1.29
187.1757355	0.03
188.2755432	0.01
191.2587128	0.04
199.1322632	0.76
207.1451263	0.20
217.2233124	0.05
221.0607910	0.06
225.2236938	0.92
227.1231689	0.02
233.1313782	0.10
239.2886963	0.06
240.8328552	0.08
243.1382751	100.00
247.1495972	0.07
249.0805054	0.20
255.5571289	0.04
257.3293152	0.02
259.5208130	0.03
266.9096985	0.10
279.1073303	0.06
285.1196289	0.82
287.1046448	0.03
299.3687439	0.02
306.9950562	0.08
308.9854736	0.16
313.2815552	0.05
315.2054749	0.26
319.1949463	0.02
325.4391479	0.06
329.0787659	0.03
330.3489990	0.09
331.2080383	0.05
332.9780884	0.02
340.2309570	0.03
343.5235291	0.03
345.0590820	0.86
345.6737366	0.01
347.4183044	0.03
359.2131653	0.62
360.5640259	0.03
361.1968689	0.14
362.2137146	0.02
367.4215393	0.18
369.2002258	0.09
372.2946167	0.07
375.2847290	0.06
385.3236389	0.05
386.2225647	0.02
387.4067078	0.46
390.1105652	0.13
405.2851562	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	470.1828
Annotation	Unknow
Peak:m/z	Relative Intensity
136.8269348	0.06
146.8272095	0.03
182.9926147	0.02
195.1204529	0.02
225.1900940	0.42
241.0453796	0.04
247.9743042	0.10
257.4353638	0.05
259.2242432	0.05
267.2081604	0.18
269.1656189	2.13
285.2701416	0.25
287.0831299	0.19
291.3858032	0.02
301.0467529	0.48
303.0232849	0.09
308.1222229	0.64
309.2938843	0.04
312.9663391	0.60
317.2433167	0.10
319.0092163	0.09
326.3888855	0.04
327.5817871	0.10
331.1607361	5.01
339.0092163	0.11
344.8906250	0.46
347.3001099	0.07
349.1490784	0.79
355.5892639	0.08
361.4591675	0.05
363.0923157	1.92
369.0406494	0.06
371.1771851	0.05
372.1531372	0.14
378.5732727	0.07
383.9865417	0.02
386.1487732	0.04
387.5649414	0.04
388.7851562	0.91
390.1915588	2.24
391.2665710	0.07
391.9185181	0.07
406.2511902	1.11
408.2440186	1.75
409.3802185	0.07
414.0845642	0.05
416.0213928	0.05
423.5704041	0.14
425.8465271	0.07
426.4970703	0.10
434.3499451	6.96
435.0918884	8.86
436.2121277	0.04
452.1926270	100.00
453.2024536	6.12
461.8333130	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	545.2577
Annotation	Agnucastoside B
Peak:m/z	Relative Intensity
156.8919220	0.16
163.1489410	0.22
165.1320496	0.12
170.9719086	0.09
172.9967499	0.33
181.0181580	0.29
184.9505615	0.75
190.0575562	0.16
192.9075012	0.18
194.8860931	0.17
197.3029480	0.68
205.5469666	0.13
209.0547638	0.49
211.1194458	0.85
212.9563293	0.21
219.2015076	0.29
222.9414368	0.16
225.2008362	0.41
235.0111389	1.01
237.2960510	0.46
239.1167145	0.94
241.0598602	0.14
243.0977478	0.23
244.2653809	0.27
247.1519318	0.66
247.7734985	0.29
249.0981750	0.60
251.2091980	0.09
252.8242493	0.25
255.1541748	3.40
257.3363647	1.89
259.2341614	0.18
261.0976257	0.38
265.1505737	3.20
267.2233887	1.42
269.1271973	0.19
273.4204712	0.35
275.1520996	0.33
277.0917358	0.26
278.5476379	0.24
279.3605347	0.30
283.1518555	9.04
285.3809814	1.95
288.8721619	0.34
290.1146240	0.26
293.2255249	1.26
298.7918701	0.51
301.2267456	6.24
302.7292480	0.24
304.8531494	0.09
309.9888916	0.22
311.1306763	6.92
316.1082153	0.08
317.1970825	0.41
319.2984009	1.82
320.9967041	0.26
326.4193726	0.11
327.1463013	0.24
329.1848145	34.61
331.1018677	0.38
333.1392822	0.28
337.1455078	0.38
347.1837769	100.00
347.8402100	0.13
349.2228394	0.09
354.7719116	0.18
365.3038940	42.28
366.1504517	0.19
367.2647705	0.70
377.5112305	0.10
379.5078735	0.25
383.1019897	12.06
383.8496704	0.11
393.3983154	0.07
399.0995483	0.25
401.5615845	0.18
406.5956421	0.53
409.4686279	0.32
416.1362305	0.18
418.3253784	0.08
429.3002930	0.12
430.3261719	0.24
437.5584717	0.27
438.2828979	0.22
450.6079712	0.41
455.1326294	0.11
456.1207275	0.55
456.9647217	0.19
462.7962646	0.45
463.8015137	1.58
473.8598633	0.30
478.1642456	1.06
488.5571899	0.18
491.2672729	1.51
497.5444946	0.13
499.2416992	0.43
500.0800171	0.64
501.5231323	0.26
504.4042969	0.16
509.0819702	11.33
510.1930542	0.48
513.3305664	0.26
513.9419556	0.94
516.9302368	0.16
527.2606201	29.16
528.4672852	0.06
531.3662720	0.92
535.7290649	0.94
536.4500122	0.19
544.6719360	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	335.2208
Annotation	bicyclo-PGE2
Peak:m/z	Relative Intensity
94.9558258	0.04
104.9256134	0.09
107.0749664	0.06
109.1787415	0.13
116.0404968	0.06
119.1099091	0.25
126.9315643	0.03
128.9985046	0.21
131.2947235	0.05
131.9319763	0.04
135.0653992	0.23
136.9738770	0.19
139.1860504	0.17
142.9373169	0.20
144.9332428	0.26
146.8840027	0.70
149.1621704	0.20
151.1246338	0.26
153.1999817	0.10
154.9315491	0.06
157.1599426	0.06
158.1464844	0.11
158.8543701	0.07
161.1308594	0.04
165.0991516	0.15
171.1194611	5.62
173.0409698	0.08
174.8939362	0.21
175.6107788	0.27
179.2293396	0.13
180.9908905	0.06
182.3078156	0.14
183.0227966	0.11
191.1550446	0.18
191.9082642	0.15
192.7420654	0.22
193.3506622	0.14
195.0861816	0.49
196.3952332	0.08
197.1022034	0.17
199.0932617	0.13
202.8511353	0.07
204.0304871	0.11
205.0838013	0.23
206.8949890	0.43
211.8223572	0.06
215.3912659	0.09
217.1293030	1.53
219.1554871	0.23
222.1708069	0.31
223.2357788	0.21
225.3021240	0.13
229.5036926	0.11
231.1761169	0.61
238.8652039	0.32
242.2520447	0.09
243.4122009	0.37
244.8114014	0.15
245.9737549	0.29
249.3938599	0.02
253.1653442	27.71
253.8463135	0.06
255.3363037	0.33
257.1365662	0.13
259.1892090	0.40
263.1129761	0.94
264.9500732	0.20
271.2282104	100.00
272.3436584	0.20
273.4045105	0.35
275.3345947	0.13
277.2718811	0.03
279.0059814	0.04
281.2415771	7.48
286.0681152	0.66
287.2427368	0.27
289.1541138	12.01
291.0343323	0.11
293.3901978	0.22
294.1498718	0.13
297.2468262	0.04
299.2380981	77.45
300.0687256	0.27
303.6763916	0.77
305.1051941	0.41
308.2387695	0.11
312.4046021	0.28
314.8695984	0.08
317.1235352	74.40
318.2141113	0.53
326.2743835	0.25
331.1343079	0.18
335.5269775	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
104.7842255	0.29
129.9462738	0.14
170.0761566	0.71
178.8159027	0.55
182.2505341	0.18
202.9738464	0.24
206.2104187	0.21
207.075882	1.38
208.1611481	2.46
209.0874634	2.15
210.2155304	0.22
214.9498901	0.19
222.1473999	2.83
223.0822601	3.64
224.0300446	0.35
233.5279083	1.12
234.9624176	0.37
251.0814209	100.00
252.1990356	17.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	406.2061
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
119.0213776	0.27
120.9115753	0.07
125.0154572	0.08
127.0664673	0.04
128.8481598	0.07
131.0369110	0.07
134.8380280	0.10
143.1058350	0.03
144.8690948	0.18
147.0616302	0.16
148.9958801	0.80
157.9996338	0.06
163.0028229	0.03
165.1235046	0.06
167.1216431	0.79
173.1224060	0.12
179.2948914	0.03
186.7798462	0.03
191.1481628	3.77
193.0906525	0.20
194.1202698	0.20
195.3466034	0.03
199.0876312	0.04
202.0401764	0.03
205.2345276	0.03
209.1327667	6.22
211.9077148	0.01
215.3012848	0.03
215.9315796	0.06
218.9498901	0.04
221.7240143	0.02
227.0449524	100.00
229.0841980	0.06
239.9892883	0.05
243.0363159	0.02
243.9897461	0.11
247.3831482	0.04
250.7984924	0.01
253.2535095	0.04
260.8543701	0.03
262.0876465	0.15
267.2409058	0.04
272.6196899	0.02
277.2491150	0.01
285.0565796	0.10
286.2456360	0.02
293.6333618	0.08
299.3450317	0.01
303.8118286	0.07
316.0183105	0.02
316.6994019	0.12
324.1236572	0.08
325.5851746	0.07
327.1087646	0.02
329.4295044	0.06
331.5666504	0.06
332.3100586	0.07
339.5120544	0.02
342.0977478	0.07
347.2598877	0.04
353.2216797	0.04
353.9025269	0.07
355.0827026	0.03
360.2000427	0.07
363.3722229	0.13
365.0838013	0.09
368.4340210	0.06
370.7101746	0.21
371.4407654	0.22
373.3847351	0.01
375.0193787	0.11
384.5842590	0.03
386.4032898	0.02
388.1464539	2.81
388.7807007	9.17
389.5178528	0.01
397.5060120	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	316.2839
Annotation	Dehydrophytosphingosine
Peak:m/z	Relative Intensity
90.9395447	0.55
93.1542511	0.10
94.8779373	1.63
95.9940109	0.11
96.9974060	0.07
101.6900711	0.23
105.0916824	0.11
107.0858307	0.64
109.1159668	1.28
110.9514694	0.95
112.8562317	0.31
115.8546066	0.17
118.9866638	1.15
119.8869324	0.05
121.0443497	1.01
123.0254822	1.75
124.0383606	0.24
125.1700821	0.59
126.1112747	0.22
126.9967422	0.14
128.1412354	0.04
132.1625977	0.17
132.8971863	1.00
134.3554077	0.48
135.0978088	0.97
137.0528259	1.50
145.1700134	0.18
147.1334229	1.43
149.1420898	0.62
150.9113922	0.86
153.0148773	0.67
155.1043854	0.11
161.1332397	1.26
161.9548035	0.03
163.0998230	0.50
165.0230408	0.23
166.8477020	0.13
170.9170837	0.31
175.2125244	0.54
178.9194031	0.09
181.1148224	0.33
182.8197937	0.71
184.9461060	0.03
186.1800232	0.07
187.4154663	0.06
189.1390686	0.14
191.0964355	0.13
193.3184814	0.89
194.0548401	0.08
196.1643372	0.69
198.2180328	0.95
201.1505737	0.13
204.2510681	0.08
205.0682983	0.14
206.7269287	0.34
207.3375854	0.72
209.2813110	0.03
211.0438538	0.17
214.3690796	0.49
215.2412415	0.20
217.0863342	0.50
218.0944519	0.06
219.1265869	0.84
221.2064819	1.96
223.1662292	0.10
225.3523254	0.25
227.0728149	0.40
229.3640747	0.38
231.1041565	0.15
233.2076416	1.47
234.0654907	0.06
235.2662048	0.05
236.4726257	0.26
239.0310059	1.56
240.9501953	0.04
242.2132263	1.33
245.1097717	4.15
246.5433350	0.33
247.6785278	0.12
249.3400574	0.27
250.4601746	1.24
251.2689209	2.90
253.1477661	0.32
253.9900208	0.44
255.4197388	0.10
256.2615356	0.09
258.0507812	0.05
262.2345886	4.87
263.2376404	3.05
267.0695190	1.12
268.3270264	2.38
269.9574280	1.28
271.0047607	1.08
271.9334106	0.86
273.1474304	0.32
275.0379944	0.22
280.2586670	58.74
281.1730347	0.96
282.0877075	0.39
284.9827271	0.44
287.1799622	0.24
288.2942505	2.44
298.2836914	100.00
299.1416016	3.20
300.8981323	0.27
306.6241760	0.50
307.4012146	0.45
317.1796265	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	545.2576
Annotation	Agnucastoside B
Peak:m/z	Relative Intensity
159.4108124	0.09
166.0866089	0.26
177.1670532	0.12
179.2613983	0.12
205.2577820	0.55
223.1477966	0.08
231.1999817	0.39
237.0627747	0.24
239.1904297	0.50
245.2325134	0.12
255.0353394	0.15
265.3031006	0.19
267.3589172	0.07
270.3082886	0.29
273.1052856	0.66
283.8251953	0.23
291.1100464	1.35
300.7734985	1.54
301.3742065	1.39
311.0466919	0.63
312.3549805	0.23
319.1776733	1.46
329.0608521	1.62
333.2343140	0.14
335.2279663	1.32
337.2481079	12.50
338.6514282	0.40
339.2964478	0.19
346.9810181	6.83
348.2557983	0.81
349.3464355	0.48
355.1026611	0.14
362.3395386	0.29
365.1335449	45.39
371.3135986	0.24
375.0214233	0.30
379.0801392	0.34
383.2005005	100.00
390.8494263	0.31
408.6761475	0.76
413.4447021	0.13
419.1667480	0.13
427.0136108	0.45
431.3293457	0.24
453.3054199	0.34
456.1141357	0.17
460.0037231	0.38
463.1888428	0.49
464.2335815	0.74
467.3486328	0.18
471.2781372	0.38
473.7301025	0.19
479.0458984	0.30
480.9384766	0.32
481.5492554	0.15
484.9859619	0.27
490.6990356	0.55
498.8588867	0.60
499.6680908	0.78
500.6267700	1.05
501.3903198	0.78
502.2913818	0.07
507.4706421	0.18
509.1217651	4.17
517.3226929	1.03
521.2407837	0.54
527.0587769	14.34
527.6859741	0.23
535.9872437	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	716.69
Annotation	Unknow
Peak:m/z	Relative Intensity
212.8799744	0.27
296.8034363	8.07
380.6629639	25.85
463.8087158	3.61
464.5064697	40.82
465.1738281	0.09
496.6787109	0.18
508.8621826	0.11
545.8472900	0.95
548.4022827	100.00
549.1795044	0.10
550.5891113	1.23
580.5614624	0.19
586.9268188	0.11
596.2747803	0.08
610.3457031	0.17
629.2072754	0.08
629.8388062	0.79
631.3812866	3.11
632.3759155	74.19
633.9777222	0.06
669.9055176	0.46
670.9835815	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.22
Annotation	Abelioside A
Peak:m/z	Relative Intensity
143.1332703	0.04
161.1415863	0.08
178.9812775	0.50
179.9429779	0.12
213.1039124	0.05
221.4003754	0.11
223.4488373	0.23
237.4975891	0.05
239.2481384	4.47
253.0286560	0.13
255.2032166	0.35
257.1864929	0.13
271.2262268	0.08
283.2729797	1.66
299.0825195	0.34
301.3381958	0.91
327.2241516	7.45
328.0572815	0.08
329.0927429	0.65
343.0184021	0.14
345.1748657	2.40
346.1008606	0.38
387.2668457	0.10
403.2834473	0.17
409.2815247	0.04
411.3744507	0.04
419.2434387	100.00
419.8490906	0.47
445.4276123	0.16
447.4093018	0.15
463.2462463	2.13
489.1736450	0.29
491.0841370	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	685.3624
Annotation	14-Deacetyl-14-isobutyrylajadine
Peak:m/z	Relative Intensity
311.0120544	0.05
355.1499634	0.06
396.1944580	0.01
407.5563965	0.01
426.3779907	0.04
427.2279053	0.08
429.7471924	0.10
444.5399780	0.01
457.5479126	0.03
470.2514038	0.02
477.3124390	0.02
504.8233032	0.01
512.4195557	0.01
522.6976929	0.09
528.8217163	0.01
530.4846802	0.08
548.9938965	0.12
564.1715698	0.02
568.8988647	0.06
570.2113037	0.02
572.2428589	0.01
579.3148193	0.35
581.5950317	0.08
588.8606567	0.07
606.4316406	0.02
623.5060425	26.30
624.7391357	0.05
632.6804199	0.01
638.9818726	0.04
641.3131104	0.58
641.9164429	0.01
642.6652832	0.05
644.2281494	0.05
649.2157593	0.05
655.5884399	0.09
667.3869019	100.00
668.0162964	0.08
668.7316895	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.1828
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9884644	0.74
190.1578369	0.01
191.1688232	0.07
206.9291992	0.28
209.0570984	100.00
272.4565430	0.05
289.0140381	0.06
319.7809448	0.01
323.3629761	0.12
333.2100220	0.01
341.0899048	0.03
342.5027466	0.04
356.1971436	0.09
359.0126953	0.02
360.5056763	0.16
371.3341675	0.11
375.1419678	0.02
377.3659058	0.09
491.3453369	0.02
503.0147705	0.08
505.3205566	1.42
507.3428345	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	513.2705
Annotation	Tricalysioside J
Peak:m/z	Relative Intensity
143.8413696	0.06
161.3351898	0.05
251.3774719	0.04
259.3497925	0.12
260.2606201	0.05
271.3013916	0.96
272.2162476	0.10
287.2968140	0.68
289.1570129	0.12
301.6878662	0.21
305.4223022	0.26
307.2988281	0.28
315.4122314	3.99
316.3970947	0.05
317.3466797	0.23
321.2462769	0.15
329.3306885	0.12
330.6807251	0.21
331.3624878	2.09
333.2344360	78.24
334.3101196	3.52
335.2588501	0.06
347.5470581	0.03
349.2901001	2.98
351.2666016	100.00
352.3432007	4.03
365.3564453	0.06
379.5490723	0.04
393.3295288	0.07
396.9014893	0.07
409.6051025	0.06
435.3961792	0.09
451.1481323	0.17
453.8447876	0.05
457.6062012	0.14
467.1355591	0.03
468.9409180	0.20
471.6099854	0.04
477.3907471	0.09
483.2625122	0.09
495.3121948	6.04
496.4910889	0.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.24
Annotation	Parvifoliside
Peak:m/z	Relative Intensity
148.7615967	0.10
157.0275269	0.17
161.7674866	0.15
181.1106262	0.13
223.2135315	0.11
226.0291748	0.06
239.2631226	0.88
240.2016907	0.84
241.2221832	2.42
267.1584473	1.39
284.6211548	0.93
285.3524170	4.56
286.3667603	0.35
288.4334717	0.35
301.4837036	0.48
303.3179321	39.40
304.2662354	3.15
311.2457275	0.99
312.2772827	0.76
317.0917358	0.08
327.2277222	0.60
328.1735840	0.76
329.2891235	7.47
330.8554688	0.44
343.8411865	1.08
345.1448975	1.40
346.6488647	0.36
347.2642822	6.38
348.4145508	0.22
349.3411255	0.09
359.3878174	0.27
361.5821533	0.20
362.3064575	0.12
371.4111328	0.07
373.4409180	0.78
389.2541504	2.03
401.6150513	0.19
404.0281982	0.10
413.2042236	0.57
417.3611450	0.07
419.2997437	7.73
420.6831055	10.31
421.3027954	34.33
431.2092285	0.92
447.3237305	0.71
457.4758911	0.99
463.2337036	0.72
465.3123779	57.83
466.3258667	10.42
473.1836548	0.24
486.2126465	0.22
491.3092041	100.00
492.3875732	7.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.2364
Annotation	Unknow
Peak:m/z	Relative Intensity
142.6740265	0.27
146.0757141	0.12
148.9961548	0.18
157.0307159	0.04
171.3120117	0.03
174.2686462	0.06
175.9120941	0.20
190.0975647	0.54
192.0488892	0.51
199.1434326	3.72
201.0631714	0.31
240.0186462	0.08
244.1436768	0.24
249.2565002	0.06
259.3603516	0.46
285.3064270	0.12
299.3843079	0.03
301.2079773	0.20
309.9696655	0.35
323.2500916	0.07
326.9965210	0.33
333.0251160	0.12
341.3057861	0.21
342.2230530	0.18
344.0505981	0.23
346.5483093	0.07
361.2018433	0.12
370.3746948	0.87
372.3062744	0.51
374.3268738	0.24
388.2527161	4.79
390.3075256	25.56
391.3279724	0.70
392.5162354	0.57
398.4270325	0.82
399.2489319	0.45
400.0958557	0.24
406.1378784	0.06
414.9360657	0.08
416.2508850	21.55
416.8667297	0.65
418.2016602	0.51
422.2711182	0.07
426.2471008	25.27
427.1274719	0.15
431.0623169	0.29
434.2999878	100.00
435.1666870	0.74
436.2795105	4.98
437.3373413	0.14
439.2074890	0.35
444.2210999	10.30
445.2201843	0.32
449.3591309	0.14
462.3042908	44.36
463.1752014	0.47
465.1061707	0.08
466.9068909	0.10
470.8733521	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	459.1594
Annotation	Antibiotic RP 1551-4
Peak:m/z	Relative Intensity
145.3257446	0.06
151.0247192	0.30
154.8964539	0.30
156.9884338	0.12
159.9773865	0.77
161.0917816	0.07
161.9365845	0.07
175.1076965	0.16
200.7370300	0.10
237.2719574	0.11
239.2772827	0.44
254.1518250	0.45
262.1434326	0.69
269.1727295	1.88
269.9541626	0.18
271.1706238	2.20
275.9982300	0.17
280.2639465	0.40
281.4189758	0.04
284.0917969	0.56
286.2070923	0.30
288.1836243	0.06
294.2612305	0.23
296.2618408	1.32
298.1600342	1.80
303.5585022	0.03
306.2341309	33.04
307.2290039	0.27
308.3345032	4.78
312.2001038	2.82
315.1834106	0.15
317.0859375	0.03
319.1765747	1.40
324.3899536	0.15
327.2886047	0.07
328.2653198	0.64
329.9013672	0.30
331.2518921	0.17
332.2913818	0.36
337.3168335	2.04
338.1826477	0.07
340.2295532	24.08
341.2001343	0.31
342.1105957	1.09
343.1604919	0.16
350.2511292	0.49
352.2152405	0.47
353.2515869	0.66
354.3787231	1.11
356.1296387	0.26
358.3522339	0.58
359.8843079	0.04
362.9626770	0.30
364.1618347	0.17
367.2542114	0.03
369.4691162	0.03
371.5524597	1.64
372.3405457	4.38
375.5552063	0.20
379.1563416	0.53
381.3231506	10.42
384.1697693	99.94
385.3181763	0.49
386.1856384	0.81
387.3356018	0.59
388.1410217	0.04
395.3767395	0.05
397.3544617	0.99
402.5854492	0.10
403.3659973	0.21
404.2414551	0.05
407.4480896	0.42
413.3788147	0.94
415.2861633	100.00
416.2083435	0.47
425.1663513	8.48
431.2453918	0.06
441.2228699	0.81
442.6291809	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	589.2498
Annotation	gibberellin A2 O-beta-D-glucoside
Peak:m/z	Relative Intensity
191.4076843	0.02
205.1154633	0.02
241.3301239	0.02
319.1946411	0.04
325.0037231	0.04
338.2092896	0.04
351.2153320	0.02
357.1952515	0.04
363.2680054	0.04
381.3578491	0.04
387.4124756	0.04
391.2640381	0.01
395.1113281	0.05
409.4375610	0.04
427.2513428	0.11
439.5494385	0.01
448.6245117	0.07
453.3875122	0.12
456.2948608	0.10
467.4139404	0.07
472.4335938	0.03
481.3881836	0.19
491.5811157	0.07
493.2295532	0.06
496.3205566	0.02
501.6160278	0.01
525.5411987	0.06
526.2515259	0.05
527.3648071	0.03
529.3547974	0.11
543.3176270	100.00
544.2980957	0.05
545.3643799	0.30
547.1432495	0.05
553.1948853	0.03
559.4286499	0.04
567.6207275	0.03
569.5718384	0.02
570.9107056	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	401.1088
Annotation	10-Dehydrogardenoside
Peak:m/z	Relative Intensity
136.9819794	10.15
137.7326050	0.04
138.8401642	0.06
147.1183472	0.07
157.1303864	0.31
160.9017029	0.21
165.0823669	0.11
169.0980530	0.34
173.2805176	0.03
174.9568024	0.22
177.0528870	0.21
187.3777618	0.05
189.0331726	0.07
193.0144348	0.70
195.1335754	0.24
202.9156952	0.02
205.1741486	0.53
211.1217651	8.68
215.1657104	0.05
231.0503540	2.46
232.8923340	0.09
239.1479492	5.03
249.0105896	5.07
253.1296692	0.03
255.2658691	0.10
263.0759583	77.12
263.8391113	0.34
267.1389465	0.33
269.4951477	0.18
281.1258850	100.00
285.7395630	0.07
287.3304138	0.10
293.0598145	0.19
295.0479126	0.14
309.2585449	0.10
311.3699341	0.12
325.1989746	34.11
341.3038940	1.06
355.0541382	0.14
357.1618347	2.33
359.3742371	0.79
369.1557007	13.45
383.1640625	0.93
384.5392456	0.06
386.2550049	0.11
392.7703857	0.07
402.0628357	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	613.14
Annotation	CMP-N-acetyl-beta-neuraminate(2-)
Peak:m/z	Relative Intensity
176.1631775	0.15
177.1551819	0.96
178.2770081	0.05
179.1265259	4.85
180.0250549	0.39
181.1458893	0.15
183.2141571	0.05
185.0636139	1.05
187.0177155	0.11
192.1246948	0.61
197.2487793	0.44
204.7160339	0.12
205.3988037	0.15
208.2517395	0.22
210.1413879	5.03
211.1447296	2.05
214.9794464	0.28
226.4410095	0.25
227.1283875	0.06
227.9141846	0.38
236.2573700	0.95
242.0467834	0.16
243.1268311	0.35
254.1623840	19.67
255.0857849	1.85
256.2106018	1.79
262.5795288	0.06
264.7276306	0.23
272.0676880	56.60
273.0767822	8.45
274.1629944	10.51
286.0992432	0.44
287.4773254	0.95
288.1881409	5.44
289.0935669	0.89
290.1063232	4.56
304.0919189	11.24
306.0902710	100.00
307.0998840	22.93
308.1033325	83.37
319.9931641	0.05
321.9884644	1.01
337.9899292	9.18
339.0112305	9.29
340.1179199	46.14
351.2015381	0.13
355.2199097	0.10
362.1451416	0.19
391.0479126	0.49
395.2227783	0.04
419.3201904	0.12
433.1017456	0.05
451.3245239	0.52
464.2575073	0.32
464.9739380	0.10
466.1920166	1.92
482.3237305	2.65
484.0437012	56.75
484.6669922	0.13
485.3057861	0.17
524.1916504	1.18
528.9818115	0.07
569.1190186	0.69
577.3765259	1.73
595.2033081	24.10
596.4747925	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.80800629	0.09
80.92340088	0.16
94.99894714	0.42
96.94775391	0.35
102.9763947	0.70
107.0983887	0.46
108.8862152	0.14
109.7628632	0.39
119.132309	0.09
123.0236206	0.88
129.0006866	5.67
133.1503296	0.44
140.8602142	0.61
145.002182	0.53
149.0423431	0.53
150.9483643	44.68
151.9180908	4.37
152.8433075	0.55
156.9521027	0.70
161.1564941	0.55
162.7169342	0.10
164.9041595	0.26
167.1199493	1.27
169.0664062	0.18
170.2179413	0.45
175.2146301	2.04
177.0192413	1.00
178.9179535	1.53
181.2645111	0.22
183.0511322	0.76
184.9293823	0.93
186.0289154	0.17
190.18013	0.20
192.080246	0.26
193.3306732	1.25
194.2670746	0.40
195.0405731	0.51
197.0464935	2.78
198.2218628	1.07
198.9186707	0.20
207.1330872	1.59
210.1645508	0.37
211.9121704	0.29
216.9998169	0.72
220.3195648	0.14
225.1352386	4.39
226.1553497	0.92
235.045166	4.45
237.163269	0.14
238.1226044	9.43
239.0571747	1.17
251.0983734	1.07
253.0904388	100.00
254.0778656	18.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.0932
Annotation	Erinoside
Peak:m/z	Relative Intensity
112.9931946	0.65
126.8566284	0.02
131.3055573	0.08
136.9592438	8.22
157.2108917	0.17
167.2049561	0.06
169.0863037	0.07
175.0627136	0.60
178.8652954	0.10
187.1512909	0.12
188.9065094	0.11
191.0509033	0.03
193.0830383	0.21
205.0424805	0.15
207.2972717	0.10
211.1040802	4.58
213.4052124	0.04
227.1181946	0.03
231.1384583	3.49
243.1393433	0.07
249.0604248	67.45
249.6881714	0.06
250.9120483	0.05
267.1130981	100.00
281.0467834	0.06
282.3662109	0.06
291.1338196	0.04
293.3451538	0.02
295.2890625	0.15
299.1567078	0.03
307.2053528	0.02
311.1694641	0.13
325.0917969	2.18
326.8409424	0.11
327.4671021	0.10
341.2411194	3.50
342.1112061	0.05
343.3029785	0.37
345.5058289	0.02
351.2009888	0.05
353.1699219	0.03
355.0979309	0.01
367.4991455	0.03
369.1145325	5.86
371.8595886	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	650.2142
Annotation	Unknow
Peak:m/z	Relative Intensity
340.9699707	0.93
503.1609497	100.00
504.2271118	17.55
517.4146729	0.21
632.0924072	1.05
632.8092651	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	564.1876
Annotation	Unknow
Peak:m/z	Relative Intensity
169.0131531	0.08
222.0211487	0.08
227.2308350	0.06
253.1678162	0.05
297.1575317	0.19
302.2044067	0.06
308.3267212	0.04
309.2867432	0.09
330.1381836	0.22
353.2716064	0.05
355.7577515	0.13
356.3907471	0.51
359.4630127	0.07
361.0922852	0.10
366.0779419	0.28
389.1760864	0.03
402.1763306	100.00
427.3938599	0.06
481.3548584	0.43
485.1751709	0.19
496.0768433	0.52
500.1292114	0.36
505.4653931	0.05
518.3080444	0.66
521.6857910	0.05
522.8899536	0.07
528.2719727	0.71
544.8939819	0.18
546.3064575	0.69
547.4970703	0.34
555.6525269	0.40
556.7203979	0.35
566.8139648	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	437.2139
Annotation	Unknow
Peak:m/z	Relative Intensity
140.9438934	0.04
146.1491241	0.85
218.1679840	100.00
243.2028198	0.02
257.1986389	0.07
271.1867981	0.04
272.1988831	0.09
275.3008423	0.08
306.8102722	0.03
307.9966431	0.07
329.1432190	0.15
333.0670166	0.09
338.3926392	0.04
340.8876038	0.08
347.1348877	0.08
349.3691711	0.16
363.1838074	0.20
374.3271179	0.18
377.0675964	0.20
378.2804871	0.09
389.1091003	0.10
391.1343079	0.26
393.3084412	0.24
402.1174622	0.06
405.3056946	0.02
419.2740173	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.14
Annotation	Methyl (3x,10R)-dihydroxy-11-dodecene-6,8-diynoate 10-glucoside
Peak:m/z	Relative Intensity
129.0999146	0.03
136.8435822	0.05
147.0973969	0.06
150.9716797	0.03
160.9890442	0.06
175.0435791	0.05
179.0112305	0.28
183.1640015	0.11
185.8523865	0.04
197.0125885	0.33
199.2059021	0.16
210.8827209	0.03
215.2738953	0.12
217.1760712	0.65
219.1845398	0.11
222.2681274	0.04
224.9655762	0.13
229.1897583	0.17
231.2902222	0.03
235.2072754	0.04
237.3451843	0.07
240.9312439	0.06
243.3193359	0.03
245.1235352	2.29
245.7752686	0.02
247.1607056	0.34
249.1730652	0.21
250.0032959	0.03
253.0986633	0.10
255.2387695	0.49
259.3866577	0.02
262.8382874	0.24
266.8496094	0.16
271.4013367	0.12
273.1761475	19.04
279.1561584	0.04
281.2719116	0.12
282.2061157	0.06
283.1088257	0.07
284.1277161	0.04
287.3869019	0.07
289.3217468	0.59
291.1951599	100.00
299.2810364	0.18
300.2573242	0.03
305.5018616	0.10
309.0230103	0.04
315.3786926	0.08
317.1726990	16.84
319.5270996	0.09
329.0971069	0.02
333.4148865	0.24
335.2531433	64.96
336.2854614	0.10
341.2290649	0.10
351.3590698	0.09
361.1121521	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	524.1953
Annotation	Herbicidin E
Peak:m/z	Relative Intensity
147.1539459	0.19
164.9918976	13.65
182.0731812	100.00
245.0134125	0.10
258.8838501	0.10
288.9000854	0.24
307.1854248	0.08
326.2454834	0.27
332.2127075	0.23
343.2672119	0.79
344.1101685	2.28
349.1535645	0.02
360.6517944	0.06
361.6133423	2.55
362.3023071	0.05
395.1929321	0.14
402.1437988	0.11
408.9941406	0.07
410.1885376	0.58
417.4560547	0.47
449.3218994	0.19
478.2171021	0.24
480.1604614	0.18
506.2268677	0.67
507.4135132	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	373.221
Annotation	9-Hydroxy-7-megastigmen-3-one glucoside
Peak:m/z	Relative Intensity
109.0127029	1.80
115.4005737	0.39
117.0279160	0.18
119.0688858	7.25
120.8633270	0.08
127.2748871	0.13
132.9281921	3.18
135.0653381	14.02
151.0316010	0.33
153.1139526	0.57
155.0989990	0.32
156.7790527	0.35
163.1166840	0.18
175.0520020	12.92
179.1535797	0.16
181.0876160	0.19
185.1493225	0.38
191.1550446	0.20
193.0521851	26.87
201.1794586	0.12
203.0329590	0.12
206.9512024	0.19
211.1210785	100.00
215.1607361	0.27
241.1028137	0.16
247.0273743	0.38
251.4172974	0.51
264.4714355	0.73
268.8523560	0.09
270.8050537	0.28
273.1138916	0.37
277.0994263	0.12
281.2392273	0.51
282.7794495	0.29
284.4098511	0.77
285.1905823	0.21
286.3119812	0.42
289.4057617	0.46
291.5333557	0.46
299.1412964	0.21
300.2849426	0.15
305.4741516	0.34
311.1784058	0.08
313.0360718	0.68
315.2496338	0.66
319.0191040	0.17
324.3724976	0.41
327.0757446	0.18
328.2876892	0.34
331.3082275	0.08
337.1622620	3.79
342.3348694	0.30
355.0921936	7.93
355.9572754	0.76
360.8055420	1.29
361.8455200	0.31
364.3105164	0.37
373.2992554	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	691.0225
Annotation	Unknow
Peak:m/z	Relative Intensity
203.1811523	0.15
217.0620880	0.06
229.1048889	0.61
231.2581787	0.14
259.4180298	0.09
260.3379517	0.39
277.1231689	1.21
294.1846313	17.80
295.2243042	1.94
299.9317017	0.16
311.3368225	1.24
312.0326233	0.16
312.9154053	0.27
323.3436279	0.10
328.1716919	1.67
334.5298462	0.51
340.2584229	0.09
346.3039246	0.58
369.0170288	0.14
392.1843872	0.19
393.3398438	0.15
402.8040161	0.13
417.3989258	1.02
433.4281006	2.39
435.2998657	0.10
446.0480347	0.20
449.3386841	0.04
450.4431152	0.15
456.2520142	0.17
474.4704590	0.07
487.9633179	0.09
489.4751587	0.29
493.3225708	0.26
498.6451416	0.10
501.2127075	0.52
507.1940918	0.71
516.1617432	1.61
518.0612793	0.44
519.4573364	0.53
535.1140137	0.07
539.4497070	0.12
543.2549438	0.26
544.4801636	0.35
572.5692749	0.35
576.0396118	0.33
590.5239868	0.09
595.6696777	0.36
604.1246948	0.79
609.0620728	0.14
612.4485474	0.34
620.0101929	0.08
621.2576904	1.85
622.6439819	0.20
636.1724854	0.13
644.5325317	0.25
645.4479980	0.93
646.3467407	0.39
655.0441895	0.16
657.1719971	0.15
658.2161255	0.27
663.3489380	0.35
667.3003540	0.37
674.2239990	0.29
676.0680542	0.88
700.3046265	0.26
701.1121826	0.38
711.6555786	0.19
719.4085693	0.56
720.4550171	0.15
721.2391357	0.09
726.3262329	1.66
758.1309814	0.18
768.6372681	0.26
769.4929810	0.16
774.6611328	0.93
777.6018677	0.21
780.6151733	0.30
806.3931274	0.18
815.6521606	0.44
825.8873901	0.33
830.8906860	0.25
833.2904663	0.92
837.9505005	0.09
840.2149048	7.28
841.0340576	0.11
844.6482544	0.28
847.4356079	0.39
848.3143921	0.28
849.5505981	0.16
865.6306152	2.68
866.6694336	0.20
874.1025391	0.28
875.7388306	3.18
876.8253784	0.77
880.1955566	0.31
880.9797363	0.47
889.5959473	100.00
890.6057739	6.09
891.5571289	0.77
892.4558105	0.77
894.1061401	0.16
896.7052612	0.37
905.3071899	0.22
906.7417603	0.30
908.5768433	0.12
909.6921997	0.48
912.7312012	1.55
913.4159546	0.88
914.0870972	0.12
917.6028442	0.51
930.5818481	0.81
953.5270386	2.92
954.1598511	0.88
955.1574707	0.59
961.6087036	0.18
972.4396362	0.08
999.4223633	0.23
1015.7814330	0.11
1016.8312990	0.16
1020.5837400	0.32
1056.8319090	0.21
1059.5391850	2.20
1060.3156740	1.99
1064.5654300	0.09
1078.1595460	0.19
1089.6030270	0.17
1093.5815430	0.37
1107.3574220	0.17
1121.7114260	0.10
1134.5561520	0.17
1163.7907710	1.12
1188.4698490	2.13
1189.4245610	0.44
1206.5301510	4.22
1207.4659420	0.89
1208.4667970	0.25
1234.6625980	0.43
1262.6395260	1.84
1263.4046630	0.45
1285.5057370	0.38
1303.3607180	0.46
1304.8986820	0.16
1404.7735600	0.16
1423.8444820	0.11
1432.6495360	0.79
1433.7413330	0.51
1450.4040530	3.80
1451.4035640	5.00
1452.4132080	1.00
1477.6805420	0.25
1651.6544190	0.12
1678.3211670	0.14
1679.9339600	0.49
1680.7613530	1.17
1778.8975830	0.40
1779.9671630	0.15
1983.7940670	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	381.192
Annotation	Cinncassiol A
Peak:m/z	Relative Intensity
137.0822144	0.29
148.1228027	0.04
149.0821533	0.04
153.1034241	0.02
175.1130981	0.03
183.3248138	0.03
191.0749054	0.04
215.2513428	0.01
217.3609772	0.09
219.3345032	0.01
229.2492676	0.09
233.1611633	0.07
235.2662354	0.30
239.2859497	0.03
241.2691956	0.04
243.4034424	0.02
245.2453613	0.24
247.2194519	0.26
249.2792664	0.01
255.3239136	0.13
257.2756348	0.70
259.1763306	0.01
261.1948853	0.12
263.2308655	0.26
265.2492065	0.04
273.3129272	0.38
275.3078308	0.99
276.4682007	0.02
277.1824951	0.03
279.3783875	0.09
282.9355164	0.04
284.3735046	0.01
289.2891235	0.04
291.2813721	0.61
293.2709961	0.83
296.8881226	0.02
301.2416992	0.45
303.3046265	0.04
304.3015747	0.03
309.3536682	0.30
317.4248047	0.06
319.2223511	1.16
319.8436890	0.01
321.0873413	0.02
335.2553711	1.52
335.9254150	0.06
337.2432861	100.00
338.3515930	1.51
345.3251038	0.20
361.2327576	0.02
363.2569275	2.25
364.2518005	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	542.73
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9068604	0.93
212.8227081	0.03
290.7980957	12.23
335.0866089	0.05
362.5141602	0.01
369.1796265	0.03
374.5745850	5.72
375.2684326	0.03
398.7279663	0.01
405.3374634	0.04
422.8442383	0.01
428.2066650	0.01
436.7577515	0.17
448.6682739	0.04
458.5499268	100.00
459.2740479	0.30
478.5869751	0.04
482.6362305	0.18
496.8332520	0.19
525.1055908	0.11
526.0413208	0.04
END