#DEFINITION	Reference Metabolome for Asparagus officinalis
#IDENTTFIER	RefMeta-Asparagus officinalis.R1
#FORMAT	msr
#VERSION	1.0/R1
#KEYWORDS	RefMeta
#ORGANISM	Asparagus officinalis
#CREATION	31-MAY-2024
#PUBLICATION	CropMetabolome: a comprehensive metabolome database for major crops cross eight categories
#JOURNAL	The Plant Journal
#AUTHORS	Shi H, Wu X, Zhu Y, Chen P, Xu X, and Li X.
#COMMENT	Reference metabolome for Asparagus officinalis was generated from multi-tissue LC-MS/MS data with redundance removed
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	408.79
Annotation	Unknow
Peak:m/z	Relative Intensity
157.0596313	0.18
187.0871887	0.13
205.2538147	0.07
227.1449432	0.23
274.8536987	0.52
290.5284424	0.12
318.8316040	100.00
320.0328979	0.46
332.8194580	0.14
334.9278564	0.21
336.0905457	1.80
336.7975464	0.20
343.3116455	0.34
344.1256714	0.68
344.9116211	0.11
345.9913330	0.12
347.8447266	1.07
348.9310608	0.20
350.9635620	1.00
359.9883118	0.06
362.0437622	0.42
362.6733093	0.46
363.7980042	3.47
364.5375366	0.41
365.2792969	0.35
365.9140320	0.37
367.8549500	1.17
368.6617737	0.14
371.6266785	0.67
372.7691956	0.67
380.1184387	0.17
381.0059509	0.65
381.8797607	0.22
385.5982361	0.87
386.8311157	0.64
387.6978455	0.80
388.4012756	2.78
389.1197205	0.27
389.7199097	0.15
390.6750793	1.31
392.3182068	0.05
393.4621887	0.79
394.6027527	4.93
395.5142212	1.06
396.7961121	0.99
397.4176331	0.39
399.6086121	1.33
403.1784668	0.05
407.6445618	0.48
408.6796265	0.18
418.0519104	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	857.2874
Annotation	Unknow
Peak:m/z	Relative Intensity
259.0807190	0.04
277.1023560	0.09
294.1137695	0.08
303.6297607	0.06
306.1833191	0.21
320.2766113	0.08
323.3696899	0.23
327.3437195	0.04
327.9844971	0.09
337.1443481	13.33
338.2694397	2.16
343.2846680	3.14
344.2310181	0.41
355.3189697	0.15
357.2946777	3.07
358.2845459	0.43
380.8170166	0.06
399.0026245	0.04
409.5888672	0.04
411.8126831	0.11
448.1818237	0.04
472.0619507	0.04
487.3330688	0.18
488.4267578	0.12
489.1196289	0.10
496.3040771	0.12
497.3460083	0.02
501.3935547	0.20
505.2863159	0.33
515.7840576	0.09
516.4365234	0.18
519.2623901	0.08
523.1340942	0.13
525.4640503	0.06
529.3645020	0.06
533.4387817	0.19
535.3092041	0.05
546.5541992	0.03
549.2747803	0.04
561.3734131	0.09
575.1137695	0.05
609.2343140	0.14
611.4494019	0.10
612.4249878	0.17
629.2397461	0.34
639.2895508	0.03
644.5911865	0.12
651.6165771	0.22
658.4552612	0.07
659.2788696	0.05
665.3192749	0.23
666.3590088	0.04
677.6082153	0.66
678.6881104	0.11
679.7882690	0.16
695.2855225	100.00
696.3562622	35.50
699.7545776	0.12
705.2807617	0.04
711.6126709	0.13
713.4010010	0.89
714.3737183	0.06
720.3538818	0.15
721.5639038	0.09
736.6737671	0.18
737.3532104	0.34
738.1782227	0.25
739.3732300	0.07
747.4531860	0.17
755.1287231	0.19
755.8250122	0.06
761.5454712	0.03
770.4545288	0.12
776.6441650	0.16
791.6293335	0.06
795.4486084	0.42
796.6123047	0.09
797.5612183	0.18
807.5784912	0.08
813.6682739	0.41
819.5924683	0.04
821.7023315	0.13
822.3493042	0.12
834.4705811	0.43
836.0989380	0.22
838.8648682	0.14
839.6498413	0.62
840.4990845	0.27
842.3926392	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	548.92
Annotation	Unknow
Peak:m/z	Relative Intensity
190.8061523	0.18
206.9891968	0.16
212.9111481	1.15
250.8519287	0.25
252.9458008	0.08
254.3754425	0.13
254.9788513	1.30
284.8948364	0.65
287.3092041	0.08
290.6311035	0.35
292.7260742	0.37
294.6478271	0.75
296.7272034	0.24
314.9261475	3.02
334.6671143	0.51
336.7479858	0.09
338.7014160	0.25
357.1499634	0.12
368.9904175	1.26
374.9289551	32.96
378.5693970	0.95
380.1403198	0.29
380.8159790	10.30
387.1395264	0.54
388.1951294	0.07
393.7711792	0.27
395.0339355	0.14
396.2341309	0.23
397.3197021	0.57
411.1585083	0.42
412.9027100	0.10
418.7098999	9.60
423.2513428	0.15
428.8736572	1.81
442.7221680	0.83
457.0676880	0.64
458.8644409	0.75
460.7064209	0.29
462.5310669	11.13
464.6105347	100.00
465.3865967	1.10
470.0155640	0.14
479.9860229	0.09
480.7357788	0.40
487.0640869	0.10
487.8133545	0.30
488.9578247	6.28
502.4967041	50.28
503.2509155	0.04
519.0572510	0.26
525.7487183	0.62
529.7634277	0.08
531.1708374	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.3914
Annotation	(20R)-24-Hydroxy-19-norgeminivitamin D3
Peak:m/z	Relative Intensity
149.1100616	0.06
150.9478760	0.10
164.1466675	0.04
167.0056305	0.09
178.0519104	0.03
179.0800629	0.04
181.0430603	0.05
188.9591370	0.07
227.1734924	0.03
232.3617249	0.05
236.8430176	0.09
243.3088684	0.02
251.4342194	0.07
252.0492554	0.04
254.8924561	0.03
257.4047852	0.07
263.3392639	0.06
268.1929932	0.07
278.8555298	0.04
293.0282593	0.05
294.9108582	0.13
304.2556458	0.06
319.2614136	0.08
323.4871521	0.04
339.2645874	0.08
343.1309204	0.03
354.6085205	0.15
357.9732056	0.06
375.2503052	0.26
386.2751465	0.03
387.2065125	0.03
391.5964661	0.30
393.5093384	0.06
399.1143799	0.03
401.5780945	0.03
405.3811951	0.08
413.2410889	0.12
417.5896606	0.20
418.2481995	0.09
419.5025635	0.37
425.5981140	0.98
426.4869080	0.05
427.1698303	0.13
427.7875977	0.05
431.3269958	0.43
432.3199158	0.03
433.4980164	0.14
441.7448120	0.08
443.4821167	8.58
444.5943909	0.79
446.2561646	0.11
447.4336548	0.27
448.4582520	0.06
449.4712219	0.28
451.4792786	0.14
455.6404724	0.32
457.1400452	0.03
459.5394287	4.16
461.5482483	6.23
462.6033630	0.36
463.5976868	0.07
465.2737732	0.06
467.4402466	0.19
469.5126343	15.61
470.4866333	1.33
472.5575256	0.13
474.4841003	0.09
475.5318298	0.03
477.7649536	0.24
485.6139526	0.38
487.4737854	100.00
488.4660950	7.27
489.2212830	0.08
490.4494019	0.18
502.6288147	0.09
504.4197083	0.06
506.5552063	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	589.0529
Annotation	Unknow
Peak:m/z	Relative Intensity
174.0676422	0.19
175.0400085	0.34
216.9452209	0.37
221.0069885	0.13
231.0853577	0.48
235.0343475	1.50
247.0719452	0.34
247.9878235	0.58
258.8972778	30.06
259.5112915	0.11
269.1530762	0.98
277.0383301	20.56
294.9025269	28.90
307.0549927	0.74
315.3986816	0.30
319.0697327	5.15
330.3120728	0.14
330.9777832	0.70
335.1730347	0.29
336.1829224	0.19
339.1649780	0.17
343.1516724	0.20
348.8864746	0.64
360.2941895	0.33
360.9108276	0.41
366.0838013	1.50
367.1480713	2.01
372.5780640	0.31
378.1823120	0.98
379.0514526	3.04
384.8942261	4.01
386.4489746	0.70
401.1083374	0.78
401.8013916	0.34
402.9818115	9.97
409.2326660	1.03
421.0133057	0.86
423.3135376	0.42
424.6333008	0.23
427.2118530	1.60
439.0332031	0.98
441.4505005	0.38
445.8417969	0.58
455.1497192	0.56
468.7730103	2.75
472.4312744	0.13
474.4575806	0.50
482.1788330	0.10
484.8403931	0.75
489.1111450	0.19
499.5587158	0.25
502.8519897	3.53
515.1250000	0.56
517.0868530	1.04
528.7592773	8.50
534.9049683	16.79
536.0314331	1.07
539.4166870	2.48
544.2036133	3.84
545.2883911	0.78
545.8929443	0.26
550.9588013	0.27
552.3796387	12.56
553.0379639	43.06
568.5095825	0.65
569.1281128	0.28
570.9128418	100.00
571.6163940	2.40
572.3451538	0.12
580.1533813	2.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.3303
Annotation	Unknow
Peak:m/z	Relative Intensity
201.8325806	0.01
202.7205505	0.01
224.2196655	0.01
255.5005188	0.01
278.0366821	0.01
279.3073120	0.51
295.4134521	0.01
323.5206299	0.04
386.4166870	0.01
391.3128052	0.09
423.2955322	0.05
433.3795776	0.02
447.1687012	0.03
456.3540039	0.01
459.3552856	0.01
468.1154785	0.04
474.3377686	0.03
484.5985718	0.02
504.3710327	100.00
505.4050903	0.22
507.5871582	0.04
517.3860474	0.03
518.3535156	0.03
520.1588745	0.02
526.5132446	0.01
527.2281494	0.02
527.8606567	0.09
545.3657837	0.06
546.3358765	0.06
547.4024658	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	642.1002
Annotation	Unknow
Peak:m/z	Relative Intensity
238.2123413	0.88
259.1446533	0.83
277.0878601	1.89
293.0907593	0.88
294.3935547	1.16
331.0058594	4.15
342.9581909	2.49
384.4379272	2.61
385.0686646	2.84
403.0104980	13.49
409.1541748	2.90
410.0321655	0.68
421.1455688	2.69
427.0960083	1.03
444.1426392	1.31
444.9942017	6.71
469.1584473	1.51
486.4606323	2.43
498.8110352	1.79
516.9512939	0.68
534.8079834	11.27
536.2508545	1.31
537.5401001	1.64
552.2256470	6.91
552.9547729	71.90
569.9074097	8.85
570.9581299	70.64
588.8544922	100.00
589.5230103	2.41
597.2130127	1.64
605.3630981	2.46
623.2432251	1.03
630.1343384	2.54
632.2468262	0.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	259.009
Annotation	Unknow
Peak:m/z	Relative Intensity
80.9100037	3.21
83.0300293	9.98
93.0292206	0.17
96.9559326	8.27
104.9001770	8.44
108.9918213	68.10
110.9805145	100.00
117.0260315	0.34
126.4107208	2.43
127.0115814	20.82
130.8890533	3.58
132.7780762	60.20
134.9464111	0.13
138.0808105	0.30
144.9814911	0.32
146.8641663	0.67
148.9531860	11.74
149.9086304	0.41
153.1524200	0.26
156.2087555	0.18
181.0559845	9.98
184.7177734	0.09
194.6217194	0.96
195.2271423	0.37
202.0908661	0.16
212.9233856	0.72
215.1029510	0.49
216.0486908	0.13
216.9970245	0.10
223.2266693	0.30
227.5242157	0.09
228.9292908	9.16
229.5603790	0.38
231.1870117	0.29
241.0647125	2.93
242.0022125	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	272.0887
Annotation	Unknow
Peak:m/z	Relative Intensity
81.7211533	0.12
85.9616013	0.51
96.9330597	0.15
98.9537277	0.73
109.0864258	0.09
128.0158691	19.61
135.2979584	0.07
143.0474243	24.10
145.0035248	1.90
146.0834808	3.41
152.9672089	0.17
153.9082947	0.05
166.0992889	0.80
167.0312958	0.77
169.9531403	0.06
179.1089630	23.16
183.1264496	0.27
184.0399017	0.07
185.0779114	3.30
192.1595306	0.05
192.9991150	0.15
197.1235809	1.60
208.2913971	0.14
210.1115112	11.62
211.2303619	0.04
212.1119995	0.05
225.8346405	0.19
228.0950775	2.78
230.1560059	0.17
236.1458282	0.51
242.2176514	0.11
252.0674286	0.13
254.1379852	100.00
257.1994019	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	542.83
Annotation	Unknow
Peak:m/z	Relative Intensity
189.2101746	0.02
206.8860474	0.60
290.8316345	7.97
296.8353882	0.02
334.8397217	0.10
338.9096680	0.13
368.9799805	0.09
374.6406860	6.17
375.3584595	0.09
376.7554321	0.06
380.7982178	1.22
394.7122192	0.02
398.7633667	0.66
406.8825684	0.27
412.8052368	0.04
422.7710571	2.00
435.4801025	0.05
436.1297607	0.12
436.7545776	4.78
448.7117310	0.08
452.8208008	0.77
458.5825195	100.00
459.3389282	0.13
460.3880005	0.06
465.2672729	0.05
466.7480469	0.15
478.7117310	2.26
482.7162476	10.82
483.3341675	0.03
489.1848755	0.09
496.2011719	1.20
496.8255005	3.63
512.7023315	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	500.9198
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9568634	2.41
199.0617371	0.44
217.0235596	0.22
228.9701843	0.65
272.9682617	50.06
273.8979187	0.06
384.9594727	0.52
386.9211121	100.00
427.1695251	0.09
444.7994690	0.07
455.2169495	0.03
457.1755066	0.09
470.1936646	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	709.312
Annotation	Gypsin B
Peak:m/z	Relative Intensity
253.1331177	0.07
279.2471924	0.04
337.1975098	0.42
339.4098206	0.18
357.2803345	0.07
403.4216309	0.03
420.4430542	0.10
431.5193481	0.09
449.7095337	0.08
468.0817261	0.16
473.5543213	0.17
479.5043945	0.04
486.2845459	0.11
501.4667358	0.04
502.9349976	0.20
507.8350830	0.30
508.5253296	0.18
509.5535889	0.04
511.4765015	0.31
519.8167114	0.22
529.3229370	1.06
537.3338623	0.05
542.1676025	0.05
546.4738159	0.06
547.4384155	1.90
555.3888550	0.03
559.4448853	0.06
564.2991333	0.09
565.5067749	0.23
569.2196655	0.42
584.2946167	0.07
594.2953491	0.08
601.0789185	0.04
601.7640381	0.04
605.3005981	0.06
617.1317749	0.09
624.3998413	0.07
647.5825806	0.10
649.5434570	0.10
655.4737549	0.30
663.4285278	0.45
665.2581787	0.38
673.5081177	100.00
685.6995239	0.21
686.3510132	0.08
691.2977905	0.34
692.2662964	0.49
701.3108521	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	762.2243
Annotation	Unknow
Peak:m/z	Relative Intensity
212.0630646	0.04
222.1312408	0.51
223.0301819	0.08
235.1287384	0.04
239.9474487	0.26
241.2053223	0.03
243.2371826	0.05
244.1388092	0.13
255.0404968	0.17
260.9909058	0.29
264.2984924	0.22
273.0933228	16.07
274.1187744	0.99
276.2493286	0.32
277.0073853	0.04
279.9988403	0.36
282.0938721	4.91
283.0929565	0.50
286.8684998	0.03
291.0164185	0.72
293.5101013	0.04
298.2840881	0.03
304.5430298	0.51
305.2069702	3.59
306.2993774	0.30
318.2351074	0.53
320.2836914	0.04
323.1125488	13.99
324.1164551	1.11
336.1557312	0.07
340.1596375	0.08
342.0663452	0.04
345.1352539	0.04
346.4905396	0.07
355.8875732	0.04
360.3480225	0.26
361.0518799	0.04
362.2883911	0.12
367.0656128	0.08
385.0841675	100.00
386.1924438	8.52
397.3250732	0.06
403.0894165	68.33
404.2009277	5.11
409.4451294	0.10
410.2561646	0.02
413.3593140	0.07
416.3847046	0.02
420.2979126	6.45
421.3508301	0.86
438.2654419	72.49
439.3414917	12.33
440.1784058	0.07
456.3087158	10.10
457.3041382	2.43
470.4260254	0.05
482.2523193	0.13
484.2667236	0.17
484.9920654	0.04
500.3140259	1.35
501.2160645	0.16
508.1751099	1.64
509.2775879	0.29
518.2281494	53.41
519.3088989	9.60
536.1906738	0.82
536.9494019	0.11
547.4552612	0.17
550.3513794	0.04
562.0896606	0.06
562.7693481	0.04
564.5256348	0.04
600.3882446	0.04
601.1577759	0.04
606.2131958	2.15
607.1724243	0.32
621.2691040	0.17
622.4967041	0.10
628.6561279	0.02
638.9956665	0.08
641.8275757	0.02
642.4541016	0.32
646.1986694	0.38
647.4118042	0.19
650.3200073	1.63
651.5061035	0.16
654.4019775	0.07
664.3698120	10.48
665.3397217	3.04
675.5270386	0.11
682.4628296	0.75
683.3273315	0.36
698.5618896	0.13
699.5759888	0.03
701.6322021	0.07
716.1489868	0.05
719.2523193	2.73
720.1870728	0.80
720.9317017	0.02
724.6907349	0.05
732.6459351	0.03
744.2238770	1.37
745.2072144	0.39
746.7451782	0.03
747.9769287	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	773.2106
Annotation	Kaempferol 3-glucosyl-(1->2)-gentiobioside
Peak:m/z	Relative Intensity
235.1537781	0.05
254.1802063	0.08
257.0086975	0.23
262.6678162	0.04
278.8768005	0.03
299.3446960	0.09
303.1255493	26.83
303.9408569	0.12
305.2141724	0.14
309.0432434	0.22
310.1845398	0.16
314.9585571	0.07
332.2266235	0.05
339.1797485	0.07
343.2202148	0.05
345.3269043	0.37
362.3848877	0.05
369.0455322	0.51
375.0117188	0.08
392.9971924	0.07
395.1955566	0.36
399.0427856	0.37
413.0297852	1.07
414.3577881	0.12
417.3276367	0.17
421.3441772	0.22
429.3698120	0.28
431.1876831	0.97
440.6347046	0.12
443.2130737	0.11
447.3199463	0.91
449.1760864	8.61
449.8562622	0.06
453.3688965	0.04
455.3284302	0.29
459.0535278	0.21
465.0675049	100.00
465.7577515	0.15
473.1411743	0.29
479.0269165	0.11
480.2003784	0.11
484.9302368	0.33
489.2036743	0.63
491.1187744	0.76
497.0398560	0.19
507.1637573	0.40
509.3495483	0.09
514.1794434	0.07
539.1604614	0.13
542.6056519	0.04
557.1098633	0.33
573.0797729	0.13
575.1465454	0.69
591.3637085	0.14
593.2023315	1.00
609.1228027	0.28
611.0509033	50.00
626.9517212	68.79
627.6834106	0.22
635.6032104	0.27
651.1134644	0.11
653.3269043	0.19
654.5977173	0.17
656.5005493	0.11
668.9129028	0.39
678.5916138	0.04
680.4884644	2.56
681.3576050	0.06
682.7380981	0.18
697.7273560	0.13
698.7050171	0.05
704.3042603	0.45
715.1787109	0.20
718.2385254	0.84
719.5370483	0.21
730.6683960	0.07
737.3504028	0.39
739.6092529	0.19
741.6817017	0.13
748.2833862	0.41
753.0642090	0.15
754.8330688	0.57
755.4990845	0.22
761.7037964	0.52
763.9626465	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	707.3433
Annotation	Unknow
Peak:m/z	Relative Intensity
199.1853180	0.08
201.9869080	0.11
205.3081207	0.61
212.1991272	0.20
214.1674194	0.56
223.0611572	0.16
227.1190796	0.68
230.0605469	1.87
238.3368225	0.42
242.0788422	8.51
243.2214966	0.65
244.1108551	0.18
245.1747589	0.05
248.3817749	0.15
249.6908569	0.15
265.9387207	0.14
266.8907166	0.33
268.1081238	1.63
270.2140503	1.58
283.3337402	0.49
284.2607422	0.30
285.1694641	5.18
285.9923096	0.14
301.2239075	1.17
302.2270508	0.82
307.1652222	1.49
311.2861328	0.07
313.1727905	16.51
314.2216797	1.71
319.1711426	5.93
320.0245361	0.32
323.5849304	0.24
326.0312805	0.87
327.5041504	0.16
339.1826477	0.28
344.2645264	0.29
355.3827515	0.28
356.6634521	0.18
358.3189697	0.54
369.1005859	0.75
379.4754028	0.46
382.0376587	0.76
384.3932495	0.41
385.3269653	0.27
386.5028076	0.32
394.2553711	0.50
397.3147583	0.36
398.3887939	0.26
400.2767334	0.25
401.4904785	0.55
402.1153564	0.30
410.4085083	0.94
412.5194092	0.74
422.7991333	0.51
428.1109009	0.15
429.1874390	0.98
430.2720947	2.08
431.2579346	0.55
440.0294800	0.07
441.3270264	0.19
443.2442017	0.09
447.3274536	16.56
448.2123413	1.14
448.9283447	0.06
449.7926025	0.40
454.2454834	0.55
455.1749878	0.82
456.2710571	0.25
458.2174683	0.51
459.3930664	0.23
463.2416992	0.42
468.2949829	0.22
469.2849731	0.36
470.2514038	0.25
471.5822144	0.28
472.2931519	0.28
480.3568726	0.19
483.5999146	0.38
484.4285278	0.10
486.4298706	0.38
489.0406494	0.30
495.2019043	0.54
496.1807861	0.17
500.6791382	0.45
501.5254517	0.36
502.5910645	0.05
507.1704102	1.94
511.2125854	0.05
514.2408447	0.10
518.3796997	7.94
519.3638916	1.79
520.0918579	0.21
523.2211914	0.13
525.1476440	1.21
526.4538574	0.33
527.4119263	0.55
533.8608398	0.27
537.3840942	0.12
538.0860596	0.06
539.2972412	4.23
540.3538208	0.38
542.3623047	2.45
543.0339966	1.83
546.5955811	0.15
548.3231201	1.87
549.0289917	0.64
550.3583374	0.14
551.5866089	20.67
553.1887207	0.06
554.0177612	0.36
555.2251587	0.33
556.3726196	0.60
557.1890869	0.07
558.1757812	0.28
559.3740845	0.44
561.5356445	0.38
567.4285278	0.40
569.3241577	0.89
570.4120483	0.22
571.6486816	0.16
572.3960571	0.26
573.5426636	0.09
575.6881714	0.41
578.0975952	15.54
579.0332642	0.85
580.1354370	0.04
582.2208252	0.43
583.0736694	0.92
584.3330688	1.94
585.3875732	0.75
587.1329956	28.13
587.8639526	0.36
591.2984009	0.71
592.1580200	0.07
593.5077515	0.25
594.3338013	0.16
596.3914185	1.42
597.2719116	2.32
598.4395142	0.65
599.6243896	0.79
600.4598999	0.75
601.5351562	0.31
604.2406616	0.15
605.3079834	4.17
605.9339600	1.10
607.3666992	0.08
608.8917236	0.35
610.2140503	0.60
610.8336792	0.39
611.5648193	0.28
613.3471069	5.95
614.0179443	7.24
614.7686768	0.10
615.8687744	0.10
618.6006470	0.26
620.4985352	0.46
621.1973877	0.38
622.4828491	43.10
623.5204468	0.65
624.1323853	0.08
626.1038208	0.44
627.5048828	1.05
628.4444580	0.66
629.6102905	2.20
630.5579834	0.59
631.3899536	0.53
635.1210327	0.43
635.7794189	0.26
637.0329590	0.36
638.3624878	15.77
639.4371948	5.20
640.4030762	1.15
641.3523560	1.07
643.2440796	0.68
645.8105469	0.62
647.3206787	9.26
648.8847656	9.97
649.6536255	9.94
653.7459106	1.34
654.6090088	6.98
655.4721069	3.83
656.3529053	1.80
660.0707397	0.90
661.3856812	0.46
663.1140747	94.68
664.4953003	2.15
665.6588745	1.55
666.4858398	0.72
668.0718384	1.23
668.8113403	0.40
670.3851929	0.71
671.4603882	3.42
672.4954224	1.15
675.9531860	2.85
677.1872559	2.92
678.0241699	0.19
679.1056519	0.38
681.4430542	1.73
684.7844849	2.45
685.4187622	1.18
687.4109497	1.84
689.7225342	10.71
690.5399170	3.50
695.5398560	0.42
696.3032837	0.35
698.3157349	6.82
698.9191284	1.35
699.5906372	0.14
708.4357300	0.23
713.6194458	0.20
724.0694580	0.13
726.4329224	3.96
727.4078979	0.36
728.0412598	0.11
736.6062012	0.08
739.5000000	0.86
741.3937988	1.61
742.4634399	1.68
743.4382935	0.47
747.5597534	0.28
749.2862549	0.19
754.7766724	0.41
755.6697388	0.21
756.2722778	0.28
758.3414917	2.13
759.4942017	1.79
760.3599243	0.77
767.4622803	10.93
768.3146362	3.08
769.4154053	0.15
776.3990479	12.88
777.4203491	4.76
783.3847046	1.54
784.6656494	1.12
786.1044312	0.12
797.3655396	1.66
798.3495483	1.32
800.5564575	0.93
801.8671875	0.06
812.5326538	0.29
813.5167236	0.85
820.2677612	0.12
825.2872314	1.48
826.6754761	1.23
828.3583984	0.23
829.3649902	0.12
839.6000977	0.12
840.5064087	0.20
852.3494263	0.08
854.7775879	0.92
855.6021729	0.40
857.4379883	0.34
858.3198242	0.67
862.7946777	0.27
868.5004272	1.43
869.4851074	0.84
870.5443726	0.29
871.6845093	0.71
872.3518066	0.10
875.4934692	4.04
876.4358521	3.01
877.8974609	0.54
878.6040649	0.55
879.5534058	1.16
880.6328125	0.23
882.2910767	0.07
894.5393677	0.30
896.3588257	13.59
897.4726562	8.33
898.6928711	0.34
899.2987671	0.18
901.6320801	0.40
902.2664185	0.12
907.3283691	0.39
911.5969849	0.27
917.6488647	0.13
922.7116089	0.49
925.4133301	3.94
926.5747681	1.77
928.4479980	0.12
929.4368286	0.31
930.9921875	0.19
938.7000122	0.09
939.3161621	0.28
942.7130737	0.14
949.5512085	0.52
950.7836304	0.28
955.6824341	0.14
957.6474609	0.33
967.4175415	26.64
968.4650269	13.15
969.7588501	0.09
977.5973511	0.21
985.8113403	0.52
986.7153931	0.20
987.7243042	0.07
988.6222534	0.21
994.5106812	0.09
995.3041382	0.24
996.5449219	0.13
1000.3666990	0.27
1004.4769900	1.81
1005.6132810	0.41
1007.4970090	0.47
1012.5379030	9.32
1013.6522830	4.88
1022.1149900	0.62
1025.7066650	0.27
1027.4818120	0.13
1028.5531010	0.17
1030.7004390	0.52
1031.5369870	0.13
1034.3825680	0.12
1035.6351320	0.15
1037.7302250	0.14
1039.6368410	0.51
1040.7158200	0.34
1043.5803220	0.23
1054.5139160	0.15
1056.4091800	0.15
1061.4926760	0.08
1065.4802250	0.08
1066.4057620	0.18
1067.5000000	1.22
1070.1750490	0.23
1071.2851560	0.56
1072.7435300	0.24
1077.7001950	0.29
1078.6042480	0.41
1079.3503420	0.22
1081.7420650	0.05
1083.4523930	6.15
1084.4776610	13.44
1085.5417480	3.52
1086.3360600	0.46
1095.5341800	21.44
1096.5021970	11.88
1101.4846190	100.00
1102.5616460	45.81
1103.4680180	1.93
1110.5581050	0.09
1122.8325200	0.11
1137.6708980	0.23
1138.9096680	0.08
1152.8782960	0.08
1154.5427250	4.38
1155.6402590	3.14
1156.5708010	0.69
1165.8204350	0.24
1168.7382810	0.04
1170.7153320	0.27
1172.5872800	16.82
1173.5275880	5.34
1174.6240230	0.98
1192.3801270	1.05
1193.5549320	0.19
1208.8184810	0.35
1209.6082760	4.77
1210.6939700	1.35
1211.6372070	0.30
1226.4791260	1.44
1227.6971440	1.08
1243.5603030	10.85
1244.7313230	3.11
1245.6320800	0.18
1251.0242920	0.13
1267.7379150	1.02
1268.8089600	1.37
1296.7381590	0.56
1297.5872800	0.92
1298.4786380	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	275.1183
Annotation	Sudan II
Peak:m/z	Relative Intensity
118.9034424	0.22
131.0928040	2.55
138.9115601	0.02
145.1514587	0.06
147.1721497	0.10
151.0794067	0.10
155.9682007	0.37
169.1944885	0.08
171.1229248	0.02
173.1060486	14.17
175.0070648	0.18
175.9815216	0.16
177.1542969	0.10
180.2143555	0.05
181.0416412	0.21
182.0402832	0.09
187.2200165	0.04
189.0102234	1.20
190.0522766	0.07
196.9440308	0.05
199.0976257	10.14
203.2692871	0.04
212.2338257	0.11
213.0620422	0.15
215.1269226	7.72
224.1762695	1.78
229.2252197	1.47
231.1509094	0.57
231.7846069	0.05
233.0680237	34.88
241.1787720	100.00
244.2243958	0.10
244.8617554	0.15
257.0971375	1.25
258.2501526	4.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	709.1158
Annotation	Unknow
Peak:m/z	Relative Intensity
254.3906708	0.10
271.8501892	0.08
306.2452393	0.19
338.0732422	0.35
340.3873901	0.04
347.8109741	0.03
366.3636475	0.07
391.1384277	0.07
393.3029785	0.03
401.1248779	0.14
420.1925659	0.12
421.1663208	0.04
427.2236328	0.10
428.0294800	0.05
447.1635742	0.05
451.7454224	0.03
459.9595947	0.04
461.0950928	0.03
465.2446289	0.07
482.1853638	2.41
482.8670044	0.03
485.0623779	0.07
498.8541260	0.07
507.2139893	0.04
523.6080322	0.09
524.3640137	0.29
525.1953735	0.62
531.3162842	0.03
536.2218628	0.02
537.2465820	0.04
559.1404419	0.18
560.7794800	0.05
577.1937866	0.25
580.0215454	0.21
587.0822754	0.05
593.1654053	0.97
593.8920898	0.20
603.1859131	0.02
611.1929932	100.00
612.3254395	0.08
621.0227051	0.02
648.4204712	0.04
662.1389771	0.03
665.4184570	0.03
687.9685669	0.04
690.0941772	0.03
691.0653687	0.68
691.9323120	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	225.0867
Annotation	Hydroxykynurenine
Peak:m/z	Relative Intensity
73.8896027	2.20
83.8417740	1.09
84.9720993	0.07
101.8974152	90.64
123.9041443	100.00
134.7445679	0.09
138.0835114	0.73
163.0546265	1.50
164.0130768	1.49
179.0548096	1.49
180.3400269	0.95
181.1186676	0.99
189.2406921	0.19
207.1110382	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	977.2555
Annotation	Kaempferol 3-O-sinapoyl-sophoroside 7-O-glucoside
Peak:m/z	Relative Intensity
271.1290894	0.24
271.9653320	0.06
275.1875000	0.03
281.0861816	0.06
283.1184082	0.80
284.0937500	0.28
293.1078186	0.03
297.1640015	0.26
300.0975342	5.29
301.0732727	15.67
302.1687012	1.96
310.3586121	0.07
313.1035767	0.12
315.1130371	7.64
316.1389771	1.49
325.2172852	0.07
343.0150757	0.90
344.0400085	0.06
344.7021484	0.11
353.1616821	7.25
354.1187744	0.88
355.3363647	0.08
357.3341064	0.12
367.2787170	0.15
373.2648315	0.03
395.0679932	0.03
430.6133423	0.03
444.2285156	0.06
445.0198975	0.11
446.3546143	0.10
457.3526001	0.09
457.9664917	0.05
468.4514771	0.04
473.3787842	0.12
489.1425781	0.19
490.0110474	0.02
499.3504639	0.23
500.4632568	0.09
503.1306763	0.04
506.4077148	0.06
513.3609619	0.20
519.2994385	0.36
520.2347412	0.07
521.4738770	0.05
537.2888794	0.04
538.4420776	0.14
545.5921631	0.18
547.1713867	2.92
548.3654785	0.79
559.4888306	0.04
564.9335938	0.04
577.5148315	0.04
591.1520386	0.42
592.6206055	0.02
609.2470093	100.00
610.3099365	27.81
623.2368774	2.53
624.4783936	0.26
633.2174072	0.17
637.0809937	0.11
651.1536255	1.34
652.2802124	0.05
653.6293335	0.07
654.4969482	0.05
655.2441406	0.04
661.2882080	1.31
662.3789062	0.93
668.5628052	8.18
669.2339478	81.69
670.3136597	31.38
693.4033203	0.13
698.5325928	0.07
711.2100830	0.90
712.0372314	0.43
718.4978027	0.07
752.9207153	0.05
753.5440063	0.16
754.5040894	0.23
771.2951050	2.69
772.1908569	1.23
796.4735718	0.04
815.2094116	2.90
816.3526611	1.10
831.1405640	0.09
832.7529297	0.09
880.9246826	0.09
887.5968628	0.06
900.4837036	0.28
904.1057129	0.05
917.5285034	0.09
934.6868286	0.04
940.9904175	0.03
943.7843628	0.12
948.2714233	0.18
959.8527222	0.41
960.7881470	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	583.4134
Annotation	Pectenol B
Peak:m/z	Relative Intensity
167.8858643	0.24
168.9786072	0.31
171.0168304	0.11
172.5536041	0.11
175.0549774	0.68
177.2719269	0.44
178.0123596	0.21
179.0817413	0.07
179.9690857	0.15
181.1025696	0.31
183.1862183	1.13
185.1144257	0.42
187.2002563	0.68
189.1517181	0.19
189.9485321	0.32
191.1305237	0.87
192.2442474	0.13
193.2801819	0.26
194.1405945	0.14
195.1684723	1.22
196.3661652	0.05
197.1170959	0.31
198.5415039	0.70
199.4104004	0.12
201.1986389	0.47
203.0343933	0.40
203.7107086	0.26
205.2063446	0.13
206.3914337	0.06
207.1183624	1.38
208.4318237	0.20
209.1708832	3.17
211.4159698	0.43
213.2630615	0.26
217.1251831	0.05
219.2126465	0.86
220.5606689	0.91
221.1794586	8.11
223.2777405	1.49
224.2648163	0.13
225.2517700	0.74
225.9734192	0.05
227.2022552	0.48
229.1842957	0.34
231.0149231	0.07
232.0879517	0.24
233.1735687	0.69
234.2176208	0.30
235.2215271	2.14
237.2563171	0.52
239.0775757	0.22
241.3284607	0.16
243.1154175	0.20
245.3225098	0.48
247.1913757	1.21
249.1808472	1.19
251.2804565	0.81
253.1526642	0.20
255.1727142	0.43
257.0621643	0.29
258.3377075	0.31
259.1549072	0.11
260.3257141	0.34
261.2238159	1.47
262.1376648	0.27
263.2733765	0.49
265.0644226	0.86
267.1405945	0.10
269.1685181	0.11
271.3082275	0.96
272.2624512	0.29
273.1773987	0.82
275.2453613	1.45
276.1647949	0.05
277.2044067	0.30
279.3144226	0.46
283.1450500	0.76
284.3223267	0.25
285.1586304	0.43
286.1926880	0.18
287.1788330	2.60
289.2308350	0.48
291.3466797	1.17
292.6647339	0.17
293.3063965	1.34
295.3621216	0.08
297.2534790	0.45
298.9998169	0.55
300.3043823	0.22
301.2864380	1.30
303.3784180	0.36
305.3210449	0.28
307.1960449	0.28
308.1073608	0.10
309.2594910	1.39
311.3489990	0.62
312.6744690	0.09
313.3840637	0.20
315.1270752	0.26
316.1550903	0.06
317.1786499	0.29
318.2694092	0.15
321.2563477	0.71
323.0888672	0.40
325.5234375	0.22
328.2042847	0.09
329.2873535	0.54
331.4172974	1.00
333.2805176	1.12
334.9363403	0.12
335.5458984	0.10
336.3329468	0.27
337.3065796	0.56
338.1819458	0.33
339.2772217	0.25
340.2789307	0.08
341.3427734	0.62
343.2919922	0.39
344.7275391	0.88
345.4533081	0.46
346.3185425	0.10
347.3547363	0.61
349.3016968	0.75
351.2901001	0.42
353.2413330	0.10
355.3073120	0.21
357.3610840	1.58
359.4240112	2.79
361.4681396	0.49
362.2407837	0.07
363.6649780	0.21
364.4061890	2.44
365.5095825	0.33
367.2000732	0.14
367.8021240	0.11
369.4219971	0.20
371.3247681	0.76
373.2810669	1.03
375.4230347	2.18
377.2520752	4.86
377.8809204	0.13
378.7231445	0.11
379.4758301	0.05
383.7814331	0.05
385.3143921	3.62
387.1358643	0.24
389.1616211	0.86
390.6444702	2.44
391.4943237	0.25
392.3365479	0.15
392.9598389	0.12
393.8035278	0.20
394.5338745	0.08
395.4025879	0.17
397.4030151	0.38
398.5426025	0.26
399.4361572	5.10
401.1901245	0.25
403.3118896	0.24
407.3741455	0.19
409.3144531	1.27
411.3154907	1.06
413.1235352	0.76
413.7249146	0.11
415.4757690	0.22
417.3347778	0.87
419.5894165	0.06
421.2991333	0.33
423.3765259	0.48
424.8326416	0.50
425.4827881	10.04
427.4030151	0.52
429.4351807	0.39
430.4005127	2.46
431.2763672	0.39
433.2324829	0.16
435.4597778	0.10
437.7044678	1.02
438.4840698	0.91
439.5576172	0.24
441.5643921	0.44
443.3360596	1.48
445.2777710	0.49
447.4197388	0.46
449.3589478	0.34
451.6313477	0.09
453.7201538	0.56
455.1295776	0.28
459.5197144	0.42
462.7103882	0.10
463.3487549	0.34
464.3077393	0.17
465.1473999	0.11
466.7560425	0.12
467.6369629	0.04
471.6604614	0.29
473.4837036	0.86
477.4262695	4.46
478.2985229	0.16
479.5695190	0.39
480.7504883	0.22
481.3818970	0.29
482.6946411	0.06
483.4018555	0.14
484.7263794	0.05
487.2227173	0.06
488.5653687	0.22
491.3826904	100.00
492.0375366	0.52
497.3666382	0.21
499.5130615	0.49
501.3045654	0.22
503.7548218	0.39
504.5480957	0.61
505.1848145	0.67
507.5995483	0.05
509.5160522	1.64
519.4362183	1.02
520.5357666	0.11
521.8023071	0.20
523.5905151	0.22
525.5858154	0.22
527.4765015	2.36
529.3231812	0.11
530.1712646	0.10
534.1497803	0.16
537.5520630	0.85
540.5043945	0.12
547.4136353	2.67
550.8922729	0.08
552.3923950	0.23
553.5393066	0.22
555.0575562	0.41
565.5015869	16.31
566.7406006	0.14
572.3379517	0.05
582.4805298	0.20
583.7116089	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	424.0852
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8120804	0.13
127.9925232	1.18
143.1024780	1.55
143.9381561	0.08
146.0438538	0.30
147.1578979	0.04
150.9003296	0.56
155.0963440	0.04
158.8382874	0.16
159.9474182	0.54
160.8749542	0.05
166.2997131	0.18
167.1838989	0.15
176.9992065	0.63
177.8511658	0.05
179.0667725	2.81
180.0151978	0.46
195.2721252	0.07
196.9779816	0.06
199.1010742	0.20
210.1814880	1.65
211.0912170	1.03
212.9690552	0.08
217.2815552	0.12
228.1670837	0.16
229.3250275	0.09
231.0233154	0.06
234.7568054	0.09
236.1827393	0.08
237.0926514	0.28
242.1570129	0.24
244.7994080	0.07
254.1379395	25.75
255.1420593	7.82
261.1185608	0.15
262.2425842	0.19
267.2832947	0.05
272.1097107	42.73
273.1664124	11.35
275.0620117	0.10
277.1623535	0.16
286.2722168	0.15
287.0596008	0.06
288.1748962	7.75
288.9897156	1.21
293.0945129	0.20
295.1700439	3.96
296.0372314	0.66
298.0911255	0.04
304.2404175	0.12
306.0960693	100.00
307.1215515	22.02
310.4099731	0.10
311.4748535	0.09
327.1771851	0.52
332.3437500	0.10
335.4636536	0.11
337.0291138	0.17
338.0420532	0.15
344.1373291	0.04
345.2134399	0.06
346.2736816	0.25
351.1474915	0.04
372.2432251	2.04
373.2934875	0.30
377.8712769	0.17
379.3144226	0.12
380.3890686	0.11
381.1817932	0.38
383.3981628	0.10
386.1580505	0.12
390.1437683	53.69
391.2342834	19.67
394.1671143	0.10
406.1152649	12.81
407.1786194	4.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	175.1186
Annotation	L-Arginine
Peak:m/z	Relative Intensity
59.8727188	17.97
69.9470978	2.75
71.8406906	0.56
84.0109253	0.08
97.1442566	0.11
105.8576050	0.09
111.9477539	7.58
113.1094666	1.45
114.0810852	3.09
114.9848022	2.92
115.9777679	40.74
129.9930267	35.70
131.2265320	0.43
133.0965576	2.21
139.9882965	4.59
148.3119659	0.10
155.3725433	0.24
157.0235291	83.14
158.0432281	100.00
166.3701935	0.56
175.3768921	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	219.1
Annotation	Alanyl-Glutamate
Peak:m/z	Relative Intensity
71.8188629	1.41
83.9956970	0.44
85.8532715	0.08
89.9090271	70.75
97.9963379	0.13
101.9881592	0.05
111.8686371	0.11
113.8151398	0.07
119.8855286	1.56
121.1034241	0.09
126.6400604	0.11
129.9986420	18.05
135.1308289	0.10
139.0870514	0.10
144.2258911	0.07
148.0570831	0.90
155.9261322	9.70
158.0160217	0.49
158.8653412	0.07
173.0316467	11.33
174.0296173	0.31
175.1592255	0.19
176.9766388	0.53
183.1779327	1.15
184.0610199	1.76
187.0782166	0.39
189.2361298	0.19
190.3716278	0.10
191.0063782	1.49
200.0186005	0.58
201.0589600	26.52
202.0341034	100.00
203.0982666	0.22
204.1205902	0.22
210.0771027	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.0928
Annotation	Veranisatin B
Peak:m/z	Relative Intensity
119.0568619	4.52
126.9905853	0.05
151.2844849	0.02
154.5075073	0.02
155.1145020	0.44
162.9929504	100.00
163.7794189	0.02
173.0304871	4.44
175.2052307	0.08
185.0804596	0.03
191.0957947	7.81
219.3762512	0.07
227.0265503	0.06
229.0979919	0.08
245.1601257	0.11
254.1173096	0.04
265.9771118	0.02
269.1553345	0.06
273.0803223	0.19
293.0738831	0.14
301.0865173	0.03
303.3091736	0.11
304.1390991	0.15
304.7399597	0.07
307.1874084	0.02
319.1930542	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.0706
Annotation	N-Acetylcystathionine
Peak:m/z	Relative Intensity
85.9606323	0.05
96.9919739	0.10
99.0431213	3.17
100.8339081	0.07
112.8921661	0.06
119.0063324	1.22
129.0720825	0.07
133.9954376	0.07
142.9555054	100.00
147.8020325	0.06
158.1560516	0.06
160.0174866	0.07
172.8668976	0.04
175.3478546	0.07
177.0525208	17.34
178.9828949	0.12
198.9951019	0.10
217.0134888	0.10
218.4138336	0.04
219.2207947	0.18
228.2783661	0.06
229.0446014	0.10
245.2630768	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.2182
Annotation	Excavatolide D
Peak:m/z	Relative Intensity
158.9297180	0.05
160.9669800	0.12
163.1182098	0.05
164.9786072	0.20
173.2731018	0.04
174.3106384	0.02
175.2378540	0.08
178.1631470	0.02
179.0850830	0.26
191.1134949	0.16
192.2083435	0.04
193.2283936	0.10
207.2150269	0.03
211.1428680	0.07
247.1262817	0.06
265.1679077	0.02
266.1637573	0.01
267.0575562	0.09
281.2283325	0.06
283.1403198	0.02
284.1263428	0.15
285.1843262	0.07
286.1678467	0.03
287.4102173	0.03
298.5691528	0.46
299.3687439	0.43
301.2227783	0.07
307.1247559	0.02
308.1920166	0.02
311.3880005	0.11
313.2770386	1.11
314.3060913	0.27
315.1661987	0.37
316.3499756	0.03
317.5971069	0.03
319.9664917	0.05
321.8378906	0.02
323.3165283	0.03
328.4880371	0.37
329.2410889	5.36
330.4555054	0.04
332.0429688	0.16
333.3218994	0.30
341.3130493	0.02
343.2613525	4.43
345.1873779	0.01
346.1978149	0.50
347.2371216	8.81
348.4205322	0.18
355.2454224	0.08
359.2844238	0.07
361.2547607	100.00
362.3016968	0.20
363.4182129	0.01
371.3769531	0.01
375.2691650	0.11
379.3052979	0.23
385.4478760	0.02
389.2490234	0.05
402.7601929	0.08
403.4566650	0.07
407.5135498	0.01
410.9353027	0.02
421.4905396	0.02
423.3870850	0.02
425.4511108	0.01
438.2854614	0.03
438.9867554	0.03
441.2385254	0.03
443.1045532	0.01
446.8461304	0.02
457.4058838	0.04
459.3878784	0.03
461.2783813	0.26
462.3504639	0.01
463.1867676	0.01
473.1997681	0.03
476.8656006	0.18
477.5464478	0.02
478.3701782	0.07
479.0014648	0.03
485.1489258	0.02
491.2990112	0.23
493.4056396	1.98
494.1945190	0.01
495.6790771	0.06
503.1010132	0.02
505.2044067	1.06
506.4396973	0.04
508.2771606	0.20
514.3280029	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	308.0901
Annotation	Glutathione
Peak:m/z	Relative Intensity
115.7698517	0.64
117.0217361	0.39
120.1071243	0.08
143.9204712	2.92
144.9529724	2.44
150.8722839	0.05
161.9318085	22.17
162.9582825	16.24
174.9370880	0.22
178.9629974	100.00
180.0613708	81.55
186.0461731	0.13
205.8849792	0.24
215.1273499	0.23
216.0085449	0.06
222.8626099	0.17
226.0898743	0.10
232.9850159	9.62
234.0093689	20.03
245.0047913	0.18
246.1636963	2.20
249.9099121	0.05
272.1381836	0.62
273.1250000	1.50
290.2044678	3.32
291.1087646	10.91
292.2027588	2.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	327.07
Annotation	Unknow
Peak:m/z	Relative Intensity
85.4643707	0.07
109.9504013	0.07
117.0467987	0.14
122.0341949	0.16
124.0346298	0.02
149.0596924	0.05
151.9691772	0.08
156.0626831	0.58
188.1979980	1.13
189.0532532	2.31
203.2337189	0.14
206.0832825	10.98
219.9901428	7.37
222.0972900	0.04
233.8733826	0.08
238.0302429	100.00
240.0671082	0.77
245.0890198	0.11
246.1738586	0.06
250.7163086	0.07
263.0270386	2.26
265.7556458	0.08
269.2240295	0.03
270.3756714	0.12
280.9820862	1.36
284.0368652	0.03
290.0139465	0.09
290.8370667	0.08
291.5854187	0.08
292.2919006	0.23
298.3572388	0.02
309.0825195	14.96
310.1661987	0.42
317.7010498	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	392.18
Annotation	Unknow
Peak:m/z	Relative Intensity
115.9252319	0.46
120.0596161	4.72
131.0951538	1.42
149.0289764	2.59
152.9664612	0.79
166.0008850	37.36
166.9737854	0.58
167.6484985	1.08
208.8911285	1.34
227.0575256	100.00
245.1911621	0.79
257.1193237	0.69
260.2931213	0.62
261.8135376	0.37
264.0696106	0.81
278.9022217	0.44
348.0916748	0.81
374.1187439	1.33
382.7330933	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.3437
Annotation	Unknow
Peak:m/z	Relative Intensity
161.0742340	0.07
208.0403137	0.04
225.2902832	0.10
240.0089264	0.09
241.1724854	0.05
307.1751404	0.04
326.4153442	0.03
332.6339111	0.03
336.9766235	0.03
343.3701172	0.09
345.0772705	0.07
346.1817627	0.03
351.4956665	0.07
359.6206665	0.07
369.4140015	0.10
371.2593384	4.30
372.2391968	0.12
377.2590942	0.07
386.0512085	0.04
387.4690552	0.19
388.5687866	0.20
389.5387573	0.35
392.4710693	0.04
394.9879761	0.13
399.2927856	0.09
401.3953247	0.04
403.0933228	0.04
407.9826050	0.13
430.4045410	0.07
435.3676758	0.10
436.0645752	0.04
443.4771118	0.05
446.1903687	0.04
453.3416138	0.07
455.2205811	0.13
458.8873291	0.07
460.4442139	0.17
461.1450195	0.11
463.0127563	0.03
472.4421997	0.92
473.5583496	0.28
479.5651855	0.15
489.1102905	0.04
491.0275879	0.40
491.7817383	0.43
492.8628540	0.12
494.9702148	0.03
504.5264282	0.04
506.1197510	0.22
507.1199341	0.10
512.3795776	0.06
513.2971802	0.21
514.2207642	0.10
515.3082886	2.14
516.3180542	0.52
518.4274902	0.10
522.7097778	0.13
523.8482056	0.05
529.6117554	0.16
533.4211426	100.00
534.5453491	0.83
536.1767578	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.266
Annotation	Unknow
Peak:m/z	Relative Intensity
235.0371246	0.06
262.2349243	0.15
265.0694580	0.07
295.1076660	2.01
295.9501343	0.14
341.4530029	0.09
353.2544556	41.22
355.2296753	0.18
396.4157104	0.09
397.7681885	0.07
456.3164062	0.12
457.1360474	0.47
457.7650146	0.05
465.6095581	0.08
466.3300171	0.07
499.3576660	0.05
516.4656372	0.06
518.1288452	100.00
518.8342896	0.09
530.3429565	0.11
554.2929077	0.05
564.1397705	0.05
567.6621094	0.52
599.0846558	0.21
614.1940308	0.17
617.4993286	0.21
622.9907837	0.19
637.2781982	0.23
639.3551025	0.11
652.3607178	0.16
653.4210815	0.09
660.2760620	0.26
663.0627441	0.10
665.1798706	0.97
665.7972412	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2875
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
118.4886627	5.76
124.9759903	1.56
134.8831482	9.37
144.8957825	2.97
149.1658325	2.43
159.1873474	2.99
167.1596985	9.15
215.1125031	2.80
227.1332092	2.24
228.3080139	3.83
233.1690369	4.67
239.120575	3.16
263.1585999	3.53
272.0729065	8.83
275.3167114	8.04
281.2880859	3.48
294.4297485	4.09
325.3588562	2.43
326.1766968	2.80
328.7228394	7.35
337.4396973	9.20
338.3346252	3.17
339.2966614	8.81
340.3792725	9.17
343.3171997	2.04
352.1080017	6.43
357.3108521	7.16
363.2004089	7.91
367.387085	1.68
375.0843811	2.98
377.2810364	4.78
385.014679	2.61
385.9523621	2.38
389.8020935	3.53
397.9075012	8.74
407.2684021	17.93
408.2739258	100.00
409.3686829	32.80
417.1728821	36.59
427.0158997	3.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	267.07
Annotation	6-Isoinosine
Peak:m/z	Relative Intensity
101.1212769	0.28
107.9199371	0.07
114.9016418	0.14
130.9216309	0.09
134.8932343	0.19
151.0073090	100.00
159.0021820	0.22
164.9665985	2.93
177.1052246	0.63
182.7680206	0.09
187.3604889	0.45
193.9588776	0.15
194.9938812	0.06
207.0922241	0.36
209.1747589	0.20
218.9980621	0.21
221.1485748	0.52
223.1264496	0.87
230.7141266	0.12
232.3458252	0.24
247.2677002	0.11
249.0680084	1.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	378.2478
Annotation	Broussonetine T
Peak:m/z	Relative Intensity
119.1652145	0.01
120.9785919	0.04
127.2053680	0.02
133.0058594	0.03
141.1699219	0.02
144.9114838	0.02
146.1019592	0.03
147.0222473	0.02
151.3366089	0.03
157.0830688	0.04
161.1546021	0.08
165.1201782	0.06
167.2446899	0.01
168.0810242	0.02
168.9077148	0.03
175.0708618	0.06
179.0307465	0.03
180.8720856	0.05
191.3459930	0.04
199.2166138	0.01
231.1284180	0.02
232.9696655	0.01
237.0603027	0.04
240.9042969	0.02
247.1082764	0.05
255.2533264	0.01
263.2539062	0.03
270.9125366	0.03
282.3755493	0.11
287.0870056	0.02
289.0137329	0.05
290.1968689	0.01
291.2316895	0.02
294.3372498	0.01
295.0532227	0.01
301.5132446	0.01
302.2954712	0.02
307.4675293	0.01
314.2932434	0.01
315.0842285	0.05
324.1423950	0.09
324.9301758	0.02
329.1306763	0.12
330.0000000	0.03
332.4559937	0.02
333.3255005	0.04
335.1011963	0.03
342.2285156	2.38
343.1999512	0.06
351.4852600	0.03
360.2110291	100.00
361.1642761	0.21
362.4880676	0.05
377.5061340	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	467.2131
Annotation	1-Octen-3-yl primeveroside
Peak:m/z	Relative Intensity
246.9626465	0.02
288.7268372	0.03
293.1578979	0.06
313.4891357	0.01
317.1443787	0.03
352.0815430	0.07
370.9319763	0.02
382.2102051	0.04
383.1089172	0.01
384.3566589	0.02
387.2538147	0.02
403.3581848	0.03
421.1977844	100.00
421.8831482	0.30
423.2248230	0.07
429.3549500	0.01
430.2811584	0.05
431.4811707	0.01
449.0069885	0.10
449.7322083	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	517.25
Annotation	Unknow
Peak:m/z	Relative Intensity
213.0978851	0.16
227.1854553	0.24
277.4478760	1.39
290.0123291	0.20
302.4447632	0.29
303.2373047	0.62
320.4260254	0.23
329.2915039	0.27
337.4910889	1.04
338.1281128	0.24
345.0001831	0.14
355.2739258	100.00
356.0078125	0.12
360.9168701	1.35
380.9769287	0.13
397.8729248	0.20
400.2745361	0.55
401.7078247	0.82
411.1972046	0.19
432.2204590	0.14
436.7752075	0.88
446.4837646	0.31
455.1496582	0.13
457.6564941	1.29
471.7129517	1.33
481.3827515	0.25
490.3965454	0.29
499.0999146	3.09
500.6165161	0.64
504.6315308	1.03
508.3792725	0.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	454.02
Annotation	Unknow
Peak:m/z	Relative Intensity
145.1286621	0.09
161.0616150	0.09
162.9954681	0.43
169.0018005	0.06
181.0311890	0.09
185.0624542	0.11
187.1716461	1.72
187.8202515	0.28
189.0244751	0.23
199.9489899	0.41
213.3445435	0.07
215.0294495	5.60
215.9174347	0.27
216.9633484	0.11
223.0526123	0.79
237.0694733	0.29
243.1480103	0.12
257.1908264	0.13
258.0215149	0.10
260.4099731	2.82
264.1968384	0.14
271.1643066	0.43
276.0658264	0.14
281.2698364	0.15
288.1140747	0.84
291.2449951	0.39
292.4935608	0.21
298.1639709	0.46
299.5304871	0.13
301.9635315	0.87
304.0886536	0.10
308.4046631	0.41
309.3074951	0.08
312.4120483	0.10
316.0836182	4.58
317.1932983	0.57
317.9189453	0.29
320.4925537	0.14
322.1937256	0.09
322.8700256	0.07
324.1066284	0.71
325.1795349	0.18
339.1447754	0.11
343.6976624	0.35
348.5884399	1.44
350.1450806	0.40
362.0367737	2.13
364.2501831	0.88
370.0958557	0.88
372.3671570	0.49
376.1112976	21.72
376.8700867	2.16
378.1760864	1.04
379.6572571	0.10
382.1303406	7.56
382.8655396	0.33
389.3292542	0.15
392.3349304	0.20
393.1646423	0.36
395.0478210	0.12
398.1765747	0.89
399.4946289	0.07
405.9925842	0.10
408.0058899	100.00
408.9393311	3.18
409.5485535	3.39
411.6133728	0.07
413.0427551	0.07
415.3651428	0.18
416.9219971	1.89
418.6549988	0.50
421.3168640	0.05
423.9785461	1.19
425.4661560	0.26
433.7934265	0.53
434.8157959	0.89
435.5721130	2.48
436.4988098	1.04
437.4592285	0.13
441.5339050	8.36
442.5683289	0.62
444.3085632	0.89
445.1508484	0.64
445.8962708	0.57
447.4099426	16.43
448.1143188	0.33
457.3666077	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	488.1617
Annotation	Unknow
Peak:m/z	Relative Intensity
145.0936127	15.33
145.9600830	100.00
146.8161316	0.21
173.8766785	1.00
246.9632721	0.26
262.9416809	0.10
263.8279114	0.22
280.8721924	0.07
308.9986572	0.10
313.2285156	0.46
323.0543213	0.08
341.1573486	19.77
342.1898193	6.90
349.3587341	0.07
359.2834473	0.36
440.3741760	0.06
452.5361328	0.24
470.2234497	0.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	562.3148
Annotation	Unknow
Peak:m/z	Relative Intensity
203.0021667	0.06
230.9792633	0.04
235.3160706	0.13
245.9498138	0.05
265.0087585	0.08
276.8538818	0.32
277.4993896	0.98
278.3755798	0.25
279.5748901	0.11
286.9456177	0.03
298.1289062	0.05
299.3559875	0.04
322.0453491	0.06
335.0368042	0.05
347.3865356	0.05
360.3480835	0.02
363.4708862	0.08
401.8673096	0.03
414.3004761	0.03
415.0750122	0.04
448.5678101	0.09
466.4308472	0.14
468.2982788	0.07
473.1794434	0.08
474.3998413	0.06
476.3701782	1.15
477.4912720	1.14
478.3624878	0.18
482.1461792	0.11
488.4353638	0.07
489.5635376	0.07
491.6771240	0.13
498.1193848	0.05
499.3992310	0.04
502.3083496	100.00
503.1521606	0.46
515.0740356	1.36
516.1709595	0.33
518.2362061	0.21
524.1979370	0.26
525.3709106	0.08
526.0064087	0.06
526.6362305	0.12
527.4271851	0.03
529.9525146	0.17
541.2562866	0.09
543.5797119	0.15
544.2909546	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	647.2036
Annotation	Unknow
Peak:m/z	Relative Intensity
189.1548615	0.15
190.0947113	0.18
193.2115021	0.05
196.9748077	0.26
198.0550537	0.17
199.1687164	0.08
201.3396606	0.11
203.0171204	0.25
205.1393890	0.56
206.0177917	0.13
215.1822052	1.04
215.8999634	0.13
216.9944916	0.26
221.0919495	1.23
222.9878845	0.06
227.1450958	0.67
229.2116852	0.06
233.2030945	0.08
244.2594299	0.55
245.0364380	0.90
245.7131805	0.03
247.0326691	2.56
248.1094818	0.56
263.1052246	1.99
265.1199341	21.43
266.2848816	2.58
272.7503662	0.13
274.3170776	0.04
277.3369141	0.13
283.1104126	11.06
284.1950073	1.05
287.2251587	0.39
299.2146606	0.27
304.9352722	0.28
307.2405396	0.35
310.9122314	0.31
315.2043457	0.15
316.2954102	0.17
317.1149902	0.52
318.3692627	0.33
319.2840576	0.12
319.9401245	0.19
321.0334473	0.10
325.0960083	0.29
329.2504883	0.94
330.5020142	0.03
331.3081055	0.07
332.3302002	0.04
340.1303101	0.06
341.2475586	0.04
349.2214966	0.19
359.2315063	0.65
360.0584717	0.04
362.5236206	0.05
371.1916504	0.16
375.0556030	0.27
377.2155762	1.34
379.2412109	9.83
380.3131714	1.51
381.2135620	0.12
382.4426880	0.23
383.3864746	0.08
391.1676025	0.27
395.3749390	0.14
397.2113647	23.02
398.2341919	3.15
409.4114990	0.53
415.2058716	31.79
416.2898560	3.56
417.3006592	0.35
418.5979004	0.05
427.5728760	0.08
433.3335571	0.37
435.3718262	0.28
436.4841919	0.05
438.1735840	0.09
439.2972412	0.46
453.1240234	0.49
454.2375488	0.48
455.3508301	0.35
457.2108765	2.17
458.0405884	0.22
467.5328979	0.08
468.2804565	0.26
474.5441895	0.03
485.3487549	0.94
486.1666870	0.18
493.2661743	1.60
494.3787231	0.29
495.4802246	0.08
496.1856689	0.46
497.4093628	0.18
511.2787476	2.70
512.4770508	0.89
513.2706299	0.07
514.9843140	0.31
515.6065674	0.23
516.4213257	0.49
527.1701050	0.35
529.2251587	8.24
530.3803101	1.67
537.2226562	1.01
538.3786621	0.24
543.1347656	0.05
544.1049805	0.04
550.2026978	0.11
555.2554321	6.59
556.3319702	1.85
561.2585449	1.24
562.2998047	0.11
567.4859009	0.20
569.2424316	1.34
570.4644165	0.07
571.2937012	0.10
573.2463379	6.32
574.3689575	2.61
587.2976685	76.24
588.3157349	21.84
597.2830811	3.02
598.3646240	0.80
603.5304565	0.10
605.2421265	100.00
606.3323364	23.14
611.3629761	0.26
615.2722778	59.18
616.3304443	13.57
618.1079102	0.11
629.2289429	4.69
630.3515015	2.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0855
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
92.91558838	2.00
126.8813782	1.36
128.210556	2.41
129.078064	2.67
130.172226	1.89
150.9741058	100.00
152.1419525	6.40
161.2115021	2.20
167.2158661	4.34
169.2703094	0.73
185.0213623	9.61
191.1340027	3.15
192.7963257	1.56
211.1846771	8.74
217.2870941	8.41
225.0426483	12.99
235.211441	27.78
235.9233246	1.80
238.14711	34.23
251.026474	1.89
253.0885468	70.25
254.2647095	3.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	636.3255
Annotation	Unknow
Peak:m/z	Relative Intensity
200.0926819	0.10
215.7508240	0.11
245.1446686	0.11
256.2388306	0.15
282.2777405	0.04
320.1363831	0.04
344.0915527	0.12
346.2190552	4.98
359.3831177	0.09
374.4407349	0.09
375.2245483	0.06
385.2917480	0.10
389.2778320	0.06
390.1870117	0.19
391.2486572	0.21
392.1430054	0.09
395.2692871	0.05
425.6232300	0.06
445.9534302	39.63
446.7530518	0.05
461.9968872	0.09
473.1518555	0.07
481.1511230	0.05
487.9491577	0.16
490.0134888	100.00
490.6965332	0.78
502.4407959	0.06
511.1334229	0.10
538.4934692	0.30
548.4719238	0.20
554.2633667	0.05
567.2459106	0.09
569.1812134	0.14
582.0249634	0.42
590.2015991	0.40
600.7618408	0.05
607.2546997	0.08
613.7180786	0.42
617.1840210	0.41
618.4159546	0.43
627.3313599	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1015
Annotation	Scopolin
Peak:m/z	Relative Intensity
107.0683517	0.02
116.9802628	0.64
135.0004883	0.48
136.0400085	0.02
140.0138245	0.02
143.1135254	0.03
144.8889160	2.46
153.0963440	0.02
162.9763794	100.00
164.0672913	0.08
181.1945496	0.13
192.5228119	0.21
193.1244202	0.08
223.0308838	0.03
228.8158264	0.03
257.1635742	0.06
268.2823181	0.07
272.1463318	0.09
279.2952271	0.01
293.6607666	0.04
295.2303467	0.02
298.9307861	0.22
308.4035339	0.09
309.1862183	0.05
313.2413330	0.06
314.8999634	0.03
319.0949402	0.11
321.2572021	0.06
325.0525513	0.17
326.8053589	0.06
331.2565308	0.04
331.8870850	0.05
336.1654663	0.26
337.1144409	0.83
345.7499390	0.38
346.3661804	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	307.1398
Annotation	Unknow
Peak:m/z	Relative Intensity
87.0821686	0.07
88.8825455	1.06
94.6554871	0.38
96.9693985	0.42
99.0362473	4.45
100.7693176	3.79
105.0917511	0.07
106.6247253	0.05
113.0006638	4.41
115.0400238	0.18
118.9637909	3.12
123.2122421	0.08
124.9696045	0.49
127.0073547	2.95
129.0061798	1.59
131.0348053	0.85
141.1112671	2.38
143.0970459	2.68
144.9962463	100.00
145.6060028	0.14
149.0476685	0.07
153.0592651	0.06
156.9189758	0.15
158.9550323	0.51
161.0104980	0.58
163.0565796	0.13
169.1686096	0.27
173.0740051	0.14
175.1603394	0.19
176.9579163	0.27
178.9671326	1.94
183.0877686	0.05
187.0840759	6.39
188.3557434	0.10
189.0991821	0.38
195.1406860	0.16
197.1916504	0.12
199.1726379	2.05
200.0256958	0.14
203.2556763	0.06
211.1365662	0.04
214.2683105	0.15
216.4776611	0.25
217.1055603	0.32
218.3820190	0.06
219.4284058	0.11
226.8514404	0.27
229.3279724	0.09
234.7671204	0.14
237.1713257	0.21
241.1968689	4.28
242.2333069	0.56
243.1856384	0.77
247.0214539	0.13
254.2764587	0.24
255.0950623	0.36
259.1112671	1.05
260.2888184	0.36
260.9977722	2.22
261.6172180	0.06
263.0573120	0.50
271.0469971	1.59
271.9793701	1.45
272.9943848	1.75
278.3726807	0.22
279.2233582	0.10
287.4369507	0.41
288.2544556	0.89
289.1053772	1.69
291.6967468	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	625.1405
Annotation	Myricetin 3-neohesperidoside
Peak:m/z	Relative Intensity
190.9393463	0.19
210.1082764	0.25
269.3691406	0.17
281.1017761	1.02
299.1399536	0.54
300.1502075	0.94
301.1360474	24.39
314.1453857	0.20
315.0565796	0.52
316.0873413	1.80
317.1619263	0.78
325.3157959	0.11
343.1885986	4.42
353.2627563	0.76
365.1487427	0.16
386.2648926	0.44
402.9637451	0.74
417.4685059	0.19
418.4591675	0.15
445.2291260	1.06
462.1608887	13.23
463.1663208	100.00
463.8061523	0.34
471.6484985	0.39
492.4666138	0.59
494.4542236	0.12
499.4464722	0.37
505.3397217	4.34
508.8675537	0.43
510.3746338	2.00
511.5437012	1.26
518.7846680	0.23
529.3735962	0.28
537.2894897	0.83
538.4575195	0.35
547.2109985	0.44
561.0392456	0.30
563.4186401	0.21
564.0732422	0.19
564.9349365	0.29
569.9143677	0.47
578.2802124	0.15
579.0184937	0.81
581.5567627	1.68
589.2036743	0.40
594.3900757	1.59
595.4280396	0.34
607.1243286	1.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	409.1158
Annotation	Unknow
Peak:m/z	Relative Intensity
150.1534729	0.65
155.9944611	0.14
157.0439911	3.41
168.0787506	0.14
181.0642090	0.25
184.1054688	0.22
188.1822662	2.92
205.0250244	10.97
226.2622681	0.12
228.1680603	1.18
229.2487183	0.20
230.1198120	0.34
242.1762695	6.57
243.1077271	2.40
244.0972290	0.53
245.0378113	0.31
247.0070496	0.67
248.0318298	0.53
249.0394592	0.20
256.3757935	0.20
261.3017273	0.64
273.1357422	3.91
274.1131287	1.38
275.2384644	4.74
276.1914673	0.43
277.0440674	0.25
279.8684998	0.58
282.1973877	0.14
288.0349426	0.13
289.2462158	1.18
290.3543701	1.90
291.2015991	0.58
293.3778076	0.69
304.2359619	0.18
305.3532104	0.50
307.1153564	100.00
308.1710510	9.94
309.2436523	9.28
310.2241821	0.55
322.1220093	0.43
323.2090454	0.63
324.3148804	0.43
334.1176758	0.44
339.1824036	27.77
340.2152100	8.58
341.1307983	9.82
343.2279053	0.92
349.0799255	0.28
351.0601807	1.84
352.1455688	0.98
353.3525391	1.34
357.5223083	14.92
358.2572937	0.26
359.6459656	1.00
363.2496643	0.57
365.5581360	1.63
366.1959534	0.27
367.2949524	0.57
369.2239685	0.80
372.8857727	0.77
373.4922791	0.81
374.1593323	0.30
375.0237732	0.74
383.1152344	13.38
383.9375305	2.12
389.0516663	4.82
389.6718750	84.63
391.4711304	2.32
392.3019104	1.23
394.3899231	7.21
397.6163635	26.99
398.5745239	11.53
399.6334534	1.55
400.8191528	1.86
403.4098816	68.33
404.4181213	2.72
414.3498840	0.77
415.3011475	0.41
421.8699036	0.45
424.1199036	0.28
425.2081604	0.48
427.1585999	1.54
427.8174744	1.76
428.7600403	0.52
430.4396362	1.45
431.2062683	1.06
433.4158020	0.89
434.1582336	0.15
435.6641541	2.31
436.7623596	0.49
441.3216858	0.23
443.4338989	3.40
444.3251343	9.42
445.2998657	1.56
447.3020325	0.75
448.8883667	0.33
451.3022156	5.15
451.9506531	0.74
452.6209412	0.89
457.1633606	5.86
458.5071716	1.21
459.2457581	0.76
460.3812561	29.65
461.4361877	3.01
468.8729858	0.31
477.8846741	1.46
489.3012390	0.30
490.2446594	0.10
493.5182800	1.38
495.8601990	0.13
496.7637634	0.48
505.4285583	4.48
506.4805603	0.65
511.5788269	0.35
517.4542236	0.19
518.3754883	1.48
519.2326050	0.76
526.6404419	12.47
527.4055176	11.73
528.1276855	0.84
535.4369507	47.99
536.2682495	15.50
536.9898071	3.93
541.2171021	0.11
548.2171631	0.28
553.1103516	0.25
554.2296753	0.23
555.3311768	1.56
563.4889526	0.50
568.5712891	0.10
573.6522827	0.56
575.1909790	1.44
579.4724731	1.07
581.3406982	6.17
582.3435059	1.43
583.4894409	0.59
584.1286621	0.34
588.3584595	1.05
596.3060913	0.25
597.7489624	0.62
600.2985229	0.42
604.1539307	0.41
605.6193237	0.90
611.1728516	0.21
613.3815918	3.08
614.3718872	0.85
615.5133667	0.53
617.5153809	1.01
618.3265991	0.23
627.3861694	0.11
628.2526855	0.67
630.3315430	0.61
644.9238281	0.90
645.5452881	0.37
647.3209839	0.76
648.4981689	0.21
669.1712036	0.47
671.4170532	0.71
698.3372803	0.17
704.4172974	0.31
714.2639771	0.18
731.1575928	0.27
733.0719604	0.55
762.6906738	0.25
763.3371582	1.62
764.2726440	0.10
796.4852905	0.49
897.6599731	0.96
913.1376343	0.43
1150.2153320	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	730.88
Annotation	Unknow
Peak:m/z	Relative Intensity
228.9292908	0.24
230.1976929	0.33
262.6797485	0.09
273.0359497	15.23
274.0296021	3.54
275.0223389	4.91
387.0036621	13.49
387.9412842	7.78
389.0107422	8.52
427.4382324	0.07
500.9315186	43.92
501.9274292	54.41
502.9146118	45.05
503.9032593	0.07
567.9954224	0.09
572.9075317	0.08
584.6878662	0.20
607.9071655	0.09
608.9670410	0.12
609.9387817	1.38
611.1032104	0.17
615.0057373	46.12
615.8539429	91.11
616.8217163	100.00
617.4839478	0.79
627.8483887	0.68
628.7902222	0.53
639.4352417	0.08
645.8659058	0.15
655.9199829	3.43
656.8760986	1.43
657.7991333	0.31
674.0087280	1.51
675.0126343	1.09
676.1973267	0.65
683.5255737	0.84
684.2000122	0.67
684.8738403	0.65
695.0150757	0.05
698.0573730	0.19
701.8226929	0.23
703.0822144	0.83
712.3406372	0.08
840.7186890	0.19
843.1275024	0.11
843.8649292	0.44
844.9337769	2.03
846.0236206	0.25
902.8324585	0.14
956.6867676	1.14
957.7661133	2.69
958.6804199	3.86
959.6752319	3.41
1015.7378540	0.10
1070.5373540	0.65
1071.6800540	1.69
1072.7188720	4.49
1073.6845700	2.84
1075.0576170	0.14
1184.9587400	1.72
1185.6657710	2.67
1186.6494140	8.19
1187.7099610	4.15
1188.4155270	0.08
1300.9398190	0.05
1301.7651370	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.1651
Annotation	Ugonin P
Peak:m/z	Relative Intensity
142.5059204	0.03
145.9903564	0.18
147.0682831	0.20
197.0739899	0.02
200.1113129	0.05
209.3787842	0.05
217.1243286	0.54
218.2992096	0.02
220.0019836	0.04
225.1563416	0.05
229.0711975	0.04
241.1253662	0.04
243.2442932	0.08
259.2201538	0.38
277.1351318	100.00
291.0995178	0.05
319.2135620	2.29
319.9724121	0.05
323.2554626	0.02
335.1059570	0.16
358.9915466	0.30
360.4935303	0.05
381.8165588	0.14
391.4319153	0.02
403.3455505	0.11
404.2113037	0.02
406.0445251	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.0876
Annotation	Unknow
Peak:m/z	Relative Intensity
175.0643463	0.04
194.9260406	0.06
197.1762238	0.06
199.0522461	0.10
204.9270630	0.07
223.1384125	0.06
253.9328918	0.09
264.8154602	0.07
267.9489746	0.09
276.0163879	0.15
283.1048584	0.41
287.3582458	0.24
297.3091125	0.20
303.0401001	0.33
319.2263794	0.07
335.9988403	0.24
337.1295166	0.06
339.1427002	0.06
349.1909790	3.62
367.2597046	1.36
380.1817017	0.07
381.1033325	6.90
385.4293213	0.32
392.6670532	0.22
403.4550781	0.22
404.8150024	0.09
411.3094482	0.07
413.1670532	0.14
415.0648193	100.00
415.6751099	0.24
427.0883179	0.06
433.6381836	0.13
447.0543823	0.13
460.9721069	0.41
468.0717773	0.07
477.3400269	0.47
481.1763916	0.21
486.8598022	0.41
504.2587891	0.21
513.1646118	0.34
515.8239746	0.44
517.2194824	0.30
521.1978760	0.06
530.2709351	0.45
531.4329834	8.34
532.5043335	0.14
533.4843750	0.18
539.2769165	0.26
540.1909180	0.90
541.5488892	0.38
542.9413452	0.12
544.9995117	0.20
557.5231934	0.38
559.1165771	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
141.5142517	3.97
159.1588898	10.12
170.9078979	18.38
192.9346924	9.84
236.9220581	7.43
243.3136597	9.18
259.2954712	8.54
265.2320557	5.92
281.4802551	38.13
283.5452576	25.49
290.9644165	7.19
359.5050049	37.54
366.0159912	9.30
367.0663757	14.55
387.9517822	35.32
395.2151794	17.03
404.5628052	37.89
408.2674255	100.00
409.5581055	20.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.34
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
184.0080566	14.82
239.5205231	0.18
245.3650055	0.13
258.0584106	0.30
337.2988892	0.09
355.0956421	0.06
365.0947266	0.41
443.5574341	0.38
502.4179077	100.00
503.5325317	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	613.1694
Annotation	Unknow
Peak:m/z	Relative Intensity
183.1825714	0.08
201.0248871	0.03
211.3718262	0.01
212.3280029	0.03
219.9867859	0.10
225.1647949	0.01
226.1587372	0.43
229.1518250	0.70
243.2590485	0.01
247.0393524	1.66
248.0794983	1.18
260.8742981	0.08
265.0787048	0.04
272.0736084	0.02
273.1405945	0.50
280.0540161	0.03
289.1380310	0.28
290.1743164	0.70
305.1107178	0.03
307.1134338	100.00
308.2279663	0.01
337.2429199	0.02
382.2736816	0.02
383.1956177	0.08
384.2313843	0.04
387.4183960	0.05
406.0128174	0.04
440.7277222	0.04
457.0960693	0.04
475.0980225	0.03
479.8286743	0.04
495.1915283	0.01
523.1485596	0.01
531.7846680	0.05
550.1274414	0.05
596.8851929	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0852
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
77.00561523	1.29
82.95991516	0.93
103.1820984	2.63
108.7090302	1.73
123.1960754	0.37
129.0684967	14.09
130.20784	2.13
130.9572754	0.88
140.857132	3.07
151.006546	100.00
152.0037079	9.71
165.108078	0.94
166.3802948	2.59
167.1630859	6.61
169.0110016	1.07
179.1517639	1.55
180.1573944	3.14
182.2884216	0.94
183.0512543	2.43
185.3177643	1.51
193.0440979	0.49
197.0889282	3.68
207.1858063	1.68
210.0977936	1.06
210.8895111	0.54
217.5451508	0.83
225.1142426	16.88
226.255127	0.66
232.4309082	1.11
235.0839996	2.49
238.0914154	7.45
239.2828979	1.94
250.975174	6.54
253.0869293	78.56
254.1757202	11.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2875
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
139.4805908	17.07
160.8296356	7.76
169.7894897	8.55
173.0682068	8.97
242.1853638	4.92
258.1391907	5.59
310.8817749	23.00
338.11203	6.04
358.9983826	6.54
364.178894	8.16
367.307251	25.04
370.2219543	21.57
380.5801086	8.21
381.2114563	13.02
382.8548889	10.09
390.2893982	21.43
408.2726135	100.00
409.2477722	34.60
426.2883301	16.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	754.0663
Annotation	Unknow
Peak:m/z	Relative Intensity
296.3663635	0.54
397.0983887	0.64
450.9826660	0.54
517.1921997	2.16
566.4544678	1.07
675.5684204	1.05
677.6085815	4.00
696.4418335	1.90
698.3643188	0.64
700.6744385	0.73
710.5112915	1.33
716.3970947	5.63
721.3673706	26.84
722.7640381	1.05
725.6824951	4.52
731.9570923	1.94
736.4174194	2.67
739.1443481	13.82
740.0959473	3.83
741.5285034	2.22
742.5097046	0.45
743.2249756	11.74
745.2669678	5.18
749.4965820	0.44
799.9114380	2.99
845.6887207	3.24
863.6546021	7.61
864.9608765	0.65
874.3917847	1.66
880.2319946	1.79
892.5574341	0.91
899.6046753	2.27
900.8710938	6.14
909.5784302	1.26
910.3212280	8.31
912.6577148	4.30
916.1581421	4.98
918.1836548	6.69
918.9976196	6.00
920.3175659	4.89
921.9469604	5.28
923.8903198	2.67
927.6064453	5.97
928.9037476	1.33
930.3143921	4.28
931.0211792	3.47
932.3883667	4.66
933.2141113	6.99
937.0128784	10.29
938.2114258	31.53
939.5913696	8.44
942.5175171	4.22
944.1010742	1.03
947.3314819	2.44
949.6687622	3.92
950.5304565	1.23
952.0715942	1.83
952.8164673	7.70
954.2880859	3.82
955.2081909	19.69
955.9407349	1.39
957.0914917	1.25
958.7048950	15.69
960.1245117	1.79
961.2719727	55.98
961.9834595	4.45
962.7578125	4.00
965.5951538	2.56
966.8356934	14.07
967.7185669	23.11
968.7995605	1.15
970.5437622	1.38
971.1790161	0.59
972.5741577	20.19
973.3106079	2.35
975.3513184	0.77
978.5461426	3.27
1013.6367800	1.39
1018.1207890	1.90
1048.1079100	4.38
1106.4702150	4.28
1227.0651860	3.23
1257.8753660	0.31
1288.8964840	3.98
1393.5179440	3.35
1630.6505130	1.34
1729.2227780	0.35
1740.9473880	0.93
1749.1164550	5.02
1754.5860600	7.41
1757.1076660	0.31
1759.5909420	1.49
1766.8756100	0.96
1806.4967040	1.93
1813.8709720	1.75
1816.3475340	1.19
1831.8298340	1.96
1836.8157960	3.83
1842.5238040	2.72
1851.9725340	60.67
1866.2410890	0.78
1880.8626710	14.64
1885.9613040	39.89
1887.7196040	1.68
1894.7839360	100.00
1900.2111820	1.16
1904.9478760	2.11
1907.0133060	0.45
1914.8367920	1.69
1921.6584470	2.58
1925.2268070	0.87
1933.2077640	4.79
1937.0550540	0.99
1937.7261960	3.31
1943.1036380	1.30
1947.0618900	1.75
1947.9283450	65.97
1949.2897950	0.91
1960.0827640	4.16
1962.0159910	6.12
1964.0145260	0.91
1965.8782960	0.41
1966.7487790	0.63
1970.3400880	5.95
1971.5687260	0.87
1973.3903810	14.30
1975.3426510	15.21
1976.6248780	22.22
1978.3475340	8.64
1979.0203860	13.53
1979.9753420	1.00
1981.0877690	4.30
1982.1922610	6.99
1983.9671630	0.61
1985.4691160	0.52
1987.0280760	2.69
1989.6807860	28.58
1991.4669190	0.65
1992.5260010	1.30
1993.2225340	65.72
1995.4366460	0.41
1996.2297360	1.37
1996.9224850	20.92
1997.5799560	17.37
1998.9256590	0.45
1999.9920650	20.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	644.03
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
182.0809784	0.04
184.1410065	0.14
193.1553497	0.07
197.1272888	0.05
206.2564087	0.05
211.0396271	0.37
214.9427948	1.27
217.9957428	0.05
224.4168243	0.10
232.8931122	0.79
236.2444000	0.10
240.0846405	0.11
244.3621979	0.14
246.0496826	0.04
255.0513458	0.06
256.9183044	0.58
262.0936890	1.20
264.1202087	0.59
270.8439941	0.34
271.9670105	0.07
273.1674194	0.14
273.8485413	0.03
279.1652222	0.06
280.1458740	0.18
282.1625671	5.13
293.3922119	0.06
297.1448975	0.08
298.9652710	0.41
300.1533813	2.86
305.0034790	0.28
308.0764160	0.04
310.4531860	0.23
311.0966187	0.54
317.0357056	1.52
318.2266846	0.27
320.2151489	0.04
323.1065063	1.32
326.2165527	0.05
329.0365601	2.14
336.0428467	0.04
341.8096313	0.34
343.8347168	0.07
349.2161865	0.23
350.1245728	0.12
357.0166626	0.22
359.0292969	0.12
361.2738037	0.24
362.0366821	0.44
364.1264038	0.07
367.0993042	0.34
368.9855957	0.03
373.1142578	0.16
375.1677246	0.52
380.0517578	0.82
381.0668945	0.04
384.9250488	0.19
386.2431030	0.04
388.8874512	0.05
391.2060547	0.15
393.2540283	2.57
394.3464966	0.07
396.4204102	0.04
397.9451904	0.36
398.7272339	0.18
400.0842896	1.79
402.2647705	0.08
404.2921753	0.17
405.3090820	0.08
409.9273071	1.08
411.4281006	0.11
416.7776489	0.08
418.0444946	29.56
418.6779175	0.05
421.0296021	0.13
422.2972412	0.55
423.1866455	2.36
426.2671509	0.02
429.2012329	0.07
430.9526367	0.51
432.2357178	0.19
437.4442139	0.31
441.0275879	12.46
442.0045776	0.04
443.0947266	0.05
444.3345947	0.05
446.1040649	0.09
447.2316895	1.64
450.8990479	0.15
460.0864258	12.88
464.0833130	0.21
465.2559814	4.87
468.8999023	0.89
469.9882812	0.05
470.9853516	0.90
472.1954346	1.23
474.9972534	0.23
483.2536011	0.14
484.0844116	0.14
484.9207764	0.84
485.6472778	0.05
487.2272339	0.65
488.7432861	0.11
490.1482544	1.42
493.1439819	0.08
494.2149658	1.45
499.1237793	0.90
500.0473633	0.57
502.4322510	0.19
503.2899780	1.05
506.7471313	0.02
507.7764282	0.17
511.0559692	30.24
511.6709595	0.05
512.3446655	0.13
514.1011353	0.91
515.1431274	0.21
518.3601685	0.18
521.1709595	0.10
522.6410522	0.07
523.5259399	0.05
526.3446045	0.31
527.2777710	0.24
529.0410156	3.22
532.0427856	4.74
541.1458130	0.19
541.8997192	0.03
545.1648560	0.16
554.7236938	0.04
555.8660278	0.06
557.1534424	0.10
559.3066406	0.66
560.2380371	0.20
565.1561890	8.12
567.7377930	0.09
569.9745483	0.17
582.0143433	0.18
583.1081543	3.78
583.9959106	0.08
586.0003662	0.08
597.9600220	0.18
601.0982056	100.00
602.1817017	0.70
603.2670288	0.42
605.2957153	0.10
626.0578003	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	461.2917
Annotation	Unknow
Peak:m/z	Relative Intensity
146.9153595	0.02
204.3089600	0.10
209.1334534	0.04
213.1260376	0.06
235.3416595	0.08
236.9651642	0.05
239.1159821	0.10
239.8745422	0.01
244.0089417	0.03
245.2790527	0.04
252.2372131	0.03
256.1831055	0.03
257.2553101	0.03
258.2319946	0.06
261.0400696	0.01
270.9450378	0.18
274.3520813	0.06
275.4296570	0.09
276.3927612	0.08
280.5049744	0.03
281.2552185	0.08
286.0662537	0.02
297.1281433	0.11
299.2146606	0.02
304.2315369	0.40
310.3870239	0.05
311.2875977	0.07
311.9866028	0.05
313.4256287	0.06
315.1966553	100.00
317.4754639	0.04
319.0997314	0.04
322.2710266	0.02
328.4046631	0.10
329.1674805	0.13
331.1286011	0.03
332.3866577	0.07
333.2918091	0.19
336.1987915	0.04
339.4066467	0.12
346.2269287	0.06
347.6513367	0.02
348.6651001	0.02
353.2798767	0.02
354.0046387	0.04
355.0779724	0.05
359.3344727	0.03
373.1841125	0.16
374.2242737	0.24
379.6706543	0.14
385.3496399	0.05
388.7509460	0.19
399.2024231	0.32
402.3569641	0.28
409.4570312	0.11
414.8254395	0.18
417.2737122	0.05
420.0139465	0.09
423.2299194	0.04
426.1414490	0.14
426.7683105	0.03
427.3823242	0.03
431.2652588	0.02
442.6494141	0.75
443.3536072	2.67
444.2909241	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0196
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
84.9840546	0.49
86.9398804	1.15
110.9582214	100.00
116.9677887	0.07
128.9918976	2.61
130.8983612	0.96
154.9674530	0.41
172.9433289	24.30
191.1524048	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	607.0632
Annotation	Unknow
Peak:m/z	Relative Intensity
238.1472473	0.27
247.0359650	0.21
258.3255005	3.09
258.9402161	0.88
286.2047729	4.32
292.7425842	1.32
294.9511108	0.30
301.1634521	100.00
308.3295898	0.55
334.2100830	0.33
391.1496582	1.77
441.2167358	1.46
447.4608154	0.36
459.0853882	0.76
463.0548706	23.00
503.2603149	0.49
505.1931763	0.82
519.4760742	0.71
534.3425903	3.82
554.6880493	1.29
578.8698120	1.88
589.0075073	0.43
590.4114990	0.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.77
Annotation	Unknow
Peak:m/z	Relative Intensity
210.8721619	0.09
212.8775330	1.57
220.1388397	0.08
234.9889069	0.07
259.1524353	0.16
289.1967773	0.07
296.7878418	15.89
302.9186401	1.08
323.1304932	3.52
326.9606323	0.33
345.1709595	0.81
355.2365112	0.06
374.7385864	0.20
380.1270142	12.10
380.7839355	56.11
386.8078003	3.23
394.2456665	0.30
404.7604980	0.38
413.0595703	0.12
416.3762817	0.05
428.7871094	1.67
441.2189331	0.08
442.6772461	0.77
458.4469604	0.27
460.0092773	0.57
462.9373169	0.35
463.9913330	16.98
464.6014404	100.00
465.4401245	0.10
480.3959961	0.08
488.6653442	1.61
502.2238159	0.49
503.0142212	0.70
530.1016846	0.19
531.3533936	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	220.1174
Annotation	Trans-Zeatin
Peak:m/z	Relative Intensity
71.87503052	1.99
89.97935486	21.87
95.02682495	0.84
115.9378052	2.60
117.6982422	0.23
126.9288635	0.57
130.9467621	1.60
141.7988586	0.15
156.253891	0.91
159.761261	0.13
165.9770355	1.25
171.9140167	0.19
174.0558929	6.60
179.1655426	0.57
184.0648651	27.60
190.3208771	0.16
202.1117401	100.00
203.170517	1.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.1242
Annotation	Ethyl (S)-3-hydroxybutyrate glucoside
Peak:m/z	Relative Intensity
84.9344940	2.11
86.8832321	0.22
88.9543762	2.56
91.0110169	0.10
94.8469086	0.14
96.8819427	0.15
98.8648682	0.09
100.9026184	4.47
112.9034882	8.01
115.0157013	0.55
118.9490051	4.72
123.0010681	0.06
125.0413055	0.29
127.0625763	1.65
128.1874695	0.05
129.1601868	0.52
130.9422302	100.00
133.8101959	0.24
136.9118500	0.07
141.1160583	0.29
142.9293823	3.17
144.9512939	0.79
147.1262207	0.05
148.9457855	0.28
154.1234741	0.18
155.0629730	0.17
156.0842285	0.16
161.1371155	0.62
164.1795654	0.10
167.0956421	0.08
173.0231171	9.09
179.0456848	1.28
183.0893402	0.24
185.0686646	0.79
187.1472473	0.92
202.2429199	0.05
203.0339661	1.63
227.0116882	0.41
229.0782471	1.39
230.2119141	0.05
232.4231567	0.11
233.2168884	0.23
247.1421204	0.16
249.0931396	0.34
259.0787659	1.79
265.2135620	0.10
272.9162903	0.04
274.0590210	0.21
275.1820068	0.62
275.9751587	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	301.0555
Annotation	Fludiazepam
Peak:m/z	Relative Intensity
86.1584625	0.18
94.9673462	2.05
95.5917511	0.05
96.8862000	0.42
97.9316864	0.07
113.0070190	14.84
114.0323944	3.34
130.9250793	100.00
131.8977203	0.04
145.0930786	0.04
173.4055481	0.07
185.0848083	0.05
198.9614258	0.57
200.0980530	0.12
203.2703247	0.10
257.1509399	0.11
282.1301270	0.56
283.1627502	2.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	932.2473
Annotation	Unknow
Peak:m/z	Relative Intensity
269.4158325	0.02
271.0726624	0.15
273.2754517	0.03
285.1207886	0.02
297.1481323	0.14
299.1551514	0.16
300.4874878	0.68
301.1852112	5.51
304.9811401	0.01
314.3005981	0.08
315.0618896	0.02
318.0831299	0.02
339.2029724	0.02
343.2227173	0.30
364.0882874	0.02
427.4031982	0.02
432.3663940	0.10
445.2207642	0.22
463.0319214	0.01
474.2857666	0.59
483.3291626	0.10
492.2949829	0.12
500.3247070	0.10
502.2598877	0.60
532.3485107	0.05
546.0288696	0.04
558.4089966	0.02
560.4575806	0.03
577.4808960	0.03
578.5372314	0.03
582.2424316	2.04
582.8477783	0.01
591.5285034	0.06
606.3751831	0.04
609.3540649	14.78
617.5468140	0.03
624.2079468	100.00
624.8428345	0.40
630.0200195	0.02
634.2299194	0.03
641.1121216	0.02
648.2506714	0.06
651.3261719	0.08
666.4317627	0.11
696.0440063	0.03
751.0819092	0.04
752.9834595	0.08
766.5827026	0.04
768.3245850	0.03
770.2593384	1.01
772.4899292	0.02
781.2072144	0.05
786.2314453	0.03
787.6835327	0.04
811.9652100	0.02
815.4849243	0.01
827.1046753	0.03
839.2163696	0.05
851.7561646	0.04
855.4549561	0.02
871.1762695	0.01
875.1438599	0.05
887.3817749	0.06
888.3542480	0.05
890.3328857	0.55
896.0251465	0.03
902.7227173	0.03
904.2936401	0.01
912.0614624	0.02
912.8988647	0.07
913.9114380	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0711
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
116.9193115	0.53
145.2622681	0.29
149.0109711	1.16
173.9765778	0.38
178.2637482	0.31
179.0571594	0.44
189.0540009	0.21
192.8771973	1.00
195.1070862	1.01
206.1565399	0.67
207.1127625	18.14
208.0272064	5.91
209.2144623	3.43
221.3816376	0.65
222.027298	1.12
223.12117	13.39
223.8690033	0.82
251.0792847	100.00
252.1121979	10.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.0605
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0079956	0.11
190.9357300	0.05
192.1910400	0.12
212.0522308	0.06
215.1697388	0.15
221.1260681	0.09
226.0502625	0.06
227.0672760	0.08
228.0188904	0.10
229.0319366	0.06
230.8620453	0.06
233.1062012	0.17
239.2108765	0.04
240.0419312	0.10
242.0865784	0.05
243.1745605	0.13
243.9307251	0.08
254.0338745	0.25
255.1109467	2.24
256.0695190	0.06
259.2804565	0.07
263.2170105	0.06
264.8986816	0.15
270.2746277	0.57
271.0922852	5.42
271.9975586	0.71
279.2443848	0.06
281.1387024	0.07
285.0579529	0.20
287.1875610	1.51
293.0414429	0.12
294.2987671	0.35
297.2252808	0.59
300.0371704	22.79
300.6761780	0.10
306.0454102	0.15
309.1875610	0.09
310.9862366	1.20
313.3138428	1.15
315.0862427	100.00
315.7188110	0.47
316.9372559	0.04
322.9339600	0.06
324.2504883	0.04
325.1464844	0.18
329.0789490	0.06
341.1376953	1.38
351.1797485	0.03
357.2058105	2.05
359.0860596	0.13
370.1534424	0.16
374.3437500	0.05
387.3213501	0.15
397.2830200	0.32
399.3723755	0.03
401.2607422	0.10
406.1598511	0.14
427.1182251	0.54
431.1361084	0.06
432.1516113	0.20
439.1322021	0.15
442.8106689	0.70
453.2145996	0.07
460.7993164	0.91
471.2127686	0.11
473.1649780	1.98
489.1600952	0.13
491.0801392	0.34
492.1506348	0.16
501.2969971	0.06
503.3207397	0.05
505.3308716	0.21
507.3806763	0.07
521.2330933	0.13
524.2837524	0.06
527.0496216	0.53
535.3253784	0.13
537.0028687	0.16
551.0933838	0.09
560.4778442	0.14
563.2376099	0.08
567.5983887	0.05
576.6941528	0.18
577.7576294	0.12
579.2905884	0.22
586.4558105	0.29
587.1557007	0.08
591.1304321	0.34
592.3833618	0.23
593.3157959	0.14
595.3409424	1.52
604.0659180	0.20
605.3228149	0.65
606.0285034	0.14
608.1570435	0.08
614.3248901	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	367.1032
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
111.0634918	0.04
117.0141602	0.07
118.9465408	0.09
121.0068359	0.01
122.8869019	0.05
127.2423782	0.02
134.0409393	5.96
136.7661133	0.14
148.8822784	1.09
155.0221252	0.34
160.8290100	0.05
173.1132812	2.77
178.0490570	0.02
191.0678558	1.94
192.9964447	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	689.352
Annotation	all-trans-Heptaprenyl diphosphate
Peak:m/z	Relative Intensity
346.1259766	0.06
347.2568359	0.07
399.0186157	0.25
422.9076538	0.10
445.2633667	0.19
452.4959106	0.09
453.4971924	0.19
461.3292236	0.28
473.4893188	3.42
481.6669312	0.08
489.5559692	0.24
491.4230347	100.00
492.1257935	0.23
507.7408447	0.15
509.5148315	0.16
526.3172607	0.06
527.6104126	0.09
529.3281860	0.24
533.3303833	0.15
544.8801880	0.25
556.9490967	0.07
581.1636963	0.17
601.3263550	0.05
604.9374390	0.07
607.2047729	0.09
613.2185669	0.08
615.6254272	0.13
617.2437134	0.06
627.4389038	0.13
629.7647095	0.08
631.2427979	0.22
639.3786621	0.17
643.4275513	0.39
653.6372070	0.51
657.1148682	0.15
659.3211670	0.13
671.2998657	0.71
672.9767456	0.08
674.2819824	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	479.3727
Annotation	Clathriol
Peak:m/z	Relative Intensity
158.8534241	0.14
172.7789154	0.11
184.6924133	0.07
195.1090088	0.26
203.4849701	0.11
214.9878693	0.25
233.2178955	0.11
246.9667206	0.13
258.4013672	0.31
271.9333801	0.32
273.1627197	0.05
276.9399109	0.12
280.2709656	0.12
281.3356628	0.09
288.7772827	0.07
305.2514343	0.17
313.3363647	0.29
319.4619141	0.22
321.3696289	0.13
335.3594360	0.14
337.4140625	0.43
353.1084900	0.18
357.2834473	0.05
360.8287964	0.08
364.3105774	0.15
369.1455078	0.11
373.5446472	0.08
380.2890320	0.14
391.4704895	0.12
393.0610657	0.21
393.8340149	0.16
396.7541199	0.23
398.7914429	0.11
402.2556458	0.47
405.1190796	0.09
406.5099182	0.57
411.0236206	0.25
420.3229065	0.22
429.7511597	0.28
430.5299377	0.35
433.1882935	0.83
438.0511780	0.19
442.3661804	0.15
443.3878784	0.56
445.4103394	0.14
448.0187988	0.43
449.3748779	0.06
461.3786316	100.00
462.4057312	0.75
478.6571960	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	432.1706
Annotation	Unknow
Peak:m/z	Relative Intensity
126.9691391	7.39
129.8384552	1.04
144.8260193	4.08
148.2976990	0.31
154.6818237	0.61
157.0208435	0.46
162.8347626	8.74
177.0830383	0.25
180.8014526	1.04
189.0442047	0.66
200.3777313	0.35
204.2219543	0.50
210.4372253	3.03
213.0065308	0.29
214.7644348	0.73
218.0654602	0.69
224.3256836	0.48
228.8321838	0.55
240.0921631	0.55
246.9867554	0.88
251.9378052	50.04
252.6271973	0.96
258.7911377	10.44
269.9040222	100.00
271.0811157	0.48
276.6554260	6.10
277.3061829	1.07
288.8077698	40.27
289.5055847	0.24
300.1368713	1.49
306.7587280	8.85
324.8259888	87.88
325.5050354	0.29
342.2354126	2.28
342.9303589	13.75
345.1285400	0.94
396.0981750	0.44
414.1924438	10.60
415.3854065	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	445.1172
Annotation	Sissotrine
Peak:m/z	Relative Intensity
161.1061096	0.16
163.0455017	0.06
167.848999	0.02
171.1339569	0.05
179.0050659	0.10
184.9475403	0.05
194.1238403	0.05
194.8602448	0.05
199.9151459	0.09
226.9784546	0.03
233.1935272	0.03
235.0772705	0.12
236.9973145	0.04
238.7022705	0.05
244.6655579	0.10
247.2618408	0.08
249.1081543	1.38
266.1676636	0.03
273.1150818	0.06
283.0535889	100.00
284.1784973	0.12
285.4067078	0.10
288.108429	0.04
290.937561	0.03
295.9556885	0.05
306.0827942	0.08
313.9163818	0.05
317.1179199	0.07
319.2653198	0.09
323.1987915	0.06
324.1432495	0.05
325.2255859	0.19
333.1107178	0.19
335.6503601	0.06
339.6425171	0.11
345.9509583	0.08
351.2376099	0.04
353.0850525	0.07
355.2603149	0.07
356.111145	0.10
358.2058716	0.05
359.906189	0.08
363.9082336	0.04
367.9729919	0.13
371.1058655	0.16
372.7238464	0.04
373.399353	0.05
381.1225281	0.09
382.3606262	0.11
383.9599304	0.04
385.3778687	0.08
387.5388489	0.05
396.9682922	0.04
397.8198242	0.11
399.2113342	0.69
400.3570557	0.11
401.2442322	0.16
402.2443848	0.03
406.2047424	0.11
408.0093689	0.38
409.2211914	0.31
410.1301575	0.04
411.2083435	0.22
414.256073	0.02
415.1982727	0.10
416.3755188	0.03
417.2907715	0.05
425.0708313	0.26
427.0838013	0.72
428.296051	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	325.0928
Annotation	6-O-p-Coumaroyl-D-glucose
Peak:m/z	Relative Intensity
92.9877472	0.06
113.1630707	0.02
113.8654251	0.07
119.0172653	6.23
145.1610565	0.18
161.1098175	0.17
162.9495544	100.00
183.0739746	0.25
187.1037903	0.21
189.1826172	0.03
205.1180115	0.19
209.0248718	0.04
218.9371338	0.14
223.1251221	0.04
232.7288208	0.10
235.9821167	0.09
241.4971313	0.06
253.1595459	0.04
261.0567017	0.08
263.1022034	0.11
265.3148193	0.31
277.0460815	0.06
278.8460388	0.33
281.1375427	0.05
283.4441833	0.03
289.3613281	0.03
302.8543396	0.09
306.3113403	0.08
307.1077881	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	182.99
Annotation	Chelidonic acid
Peak:m/z	Relative Intensity
67.0047302	0.28
123.9765778	0.03
138.9085236	100.00
140.4996643	0.02
165.1360931	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.0847
Annotation	Unknow
Peak:m/z	Relative Intensity
148.9977875	0.02
160.9821930	0.07
204.9752808	0.01
206.2021179	0.01
207.1130981	0.07
220.8757629	0.02
224.9768677	0.01
251.2130127	0.01
265.2129517	0.01
274.9601135	0.03
292.8026123	0.03
310.9688721	0.15
322.7658691	0.02
329.0017090	0.01
336.9306641	0.01
341.2553101	5.06
356.2682495	0.01
363.6675415	0.01
373.1889648	0.01
379.5549927	0.02
389.5034180	0.04
390.5228271	0.01
392.2744751	0.02
427.2396240	1.31
439.3285522	0.30
452.4812012	0.02
454.8071899	0.09
473.0941162	100.00
484.3893433	0.01
498.9111328	0.03
500.5682983	0.05
502.5070801	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	277.1322
Annotation	Sudan II
Peak:m/z	Relative Intensity
84.8949051	0.93
87.9335175	0.07
97.0141296	0.49
97.9281921	0.65
102.0066071	0.07
111.9659729	4.09
112.9936066	2.03
114.1934814	1.02
115.2026291	4.30
115.9428558	10.49
117.0244141	0.10
119.7949829	0.07
128.9417572	0.47
131.2170105	0.08
138.9756470	0.15
140.0112457	1.00
144.9565735	29.44
156.0447235	0.07
157.0244904	3.68
158.0274658	4.79
159.1434631	0.17
162.3645020	0.31
165.0792389	0.82
165.8106689	0.18
172.2130585	0.22
174.0763245	0.85
175.1036835	9.82
182.1990662	0.45
183.1371765	5.51
184.1053009	0.18
185.2167511	0.16
191.0913391	0.17
193.2846985	0.23
197.0381165	0.87
198.2458496	0.26
199.1961975	2.53
208.6163635	0.34
209.2635193	0.45
212.9652710	0.12
213.8551941	0.28
215.0182800	0.06
216.1688538	0.70
217.0856934	17.01
218.1001892	18.91
220.8230286	0.13
225.0393677	3.02
226.1511230	67.29
231.1648865	0.75
233.0369568	0.10
235.2043762	5.45
239.8388062	0.41
241.0290527	0.06
243.0332642	100.00
243.6828918	0.31
254.7720947	0.06
259.1111755	32.99
260.1680298	42.13
262.9929504	0.67
267.9385986	1.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	383.1195
Annotation	Quinic acid
Peak:m/z	Relative Intensity
122.7456055	0.10
126.9988403	0.09
128.9017334	0.05
153.0323334	0.17
165.0462646	0.09
172.9559631	0.29
175.0690613	0.03
176.9186707	0.03
179.2603149	0.07
190.9867706	100.00
193.1708221	0.04
196.0313873	0.06
198.0537720	0.03
202.8073883	0.12
204.8411560	0.05
209.1319580	0.38
220.2935791	0.02
224.4482727	0.03
225.0499268	0.04
229.3033752	0.04
240.9662476	0.02
246.1834717	0.10
247.1282349	0.16
253.1232300	0.08
253.7549744	0.06
254.9518738	0.07
257.0339966	0.07
262.0593262	0.15
263.2436523	0.13
266.0094299	0.16
267.2013855	0.14
272.9725647	0.08
279.1656189	0.11
285.2955627	0.13
292.3812256	0.04
293.1751404	0.21
295.1510620	0.13
301.7880554	0.05
322.9997253	0.03
341.1429749	0.02
344.0657043	0.20
346.9710693	0.08
355.2478943	0.12
363.0104065	0.04
364.8949890	0.34
382.7968750	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.0428
Annotation	Unknow
Peak:m/z	Relative Intensity
108.9635162	0.05
109.9368973	0.95
118.9547195	0.09
120.0973511	0.13
121.1678314	0.06
121.9894180	0.28
135.0360718	0.61
136.1255798	0.53
137.0345764	0.62
142.9003296	0.28
154.8519592	0.39
161.1054077	0.53
162.0703583	0.13
173.0320892	1.81
173.9741364	0.25
175.1927948	0.17
179.0590363	5.72
180.0738831	5.66
181.1070709	6.48
191.0883942	16.45
192.1374207	10.22
193.1520081	1.92
200.1471100	0.20
209.3830872	0.06
211.1501007	0.04
216.9737549	0.09
219.9162292	0.09
224.2116394	0.08
232.1236267	0.17
233.0339050	0.20
235.0668030	0.36
239.0798645	0.05
240.9847412	0.06
243.1708374	0.07
252.1052246	0.08
254.2210999	0.10
264.3668213	0.07
265.2012329	0.80
273.2243042	0.04
277.1422729	0.50
283.0304565	0.31
284.9692993	0.09
294.2671204	0.09
295.2801208	0.07
309.3156433	0.16
311.0844116	100.00
319.8486023	0.08
321.2600403	0.29
336.2288818	0.33
337.2265930	0.24
338.2147217	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	588.29
Annotation	Unknow
Peak:m/z	Relative Intensity
175.0677032	0.09
182.2146912	0.09
199.2574615	0.18
200.8871002	0.10
203.1132507	0.08
204.0696716	0.26
209.1125946	0.11
215.0122681	0.14
217.1996460	4.90
234.0703583	0.16
237.9729462	0.45
241.2908630	0.17
242.8946991	1.00
243.8805542	0.06
245.2698975	0.23
259.0377197	0.08
261.5385132	0.21
262.1965942	0.09
276.4162903	0.10
279.1843262	1.00
281.2714233	0.14
284.3804321	0.28
286.8960876	0.37
287.9857788	0.26
289.3800049	0.11
290.3681641	0.24
297.1891174	3.20
302.5794067	0.17
310.0123901	1.11
311.4122314	0.08
314.0907593	0.09
321.0560303	1.68
323.4957886	0.12
326.1160889	0.27
327.1822510	0.12
328.1913452	1.42
330.1388550	0.13
334.3781738	0.07
338.0498047	0.40
339.1131592	3.83
343.2997437	0.50
344.2348022	0.09
345.2841187	0.84
346.2881470	4.21
348.2537842	0.24
353.9363403	0.42
355.3054199	0.21
356.1175537	1.23
357.2155762	0.09
358.0629272	0.09
359.3045654	1.78
360.2462769	0.47
363.0653687	2.61
364.0039673	0.11
366.1007080	0.36
370.2327271	0.14
372.2308350	2.97
373.2947998	0.27
374.9855957	0.59
377.3377075	0.09
380.1347656	0.20
381.2203369	0.28
387.1726685	4.09
387.7855225	0.15
389.2145996	0.60
393.2221680	0.16
394.3930664	0.09
397.1325073	0.21
399.1488037	1.79
403.2166138	0.18
405.1997070	12.77
405.9688721	0.12
406.7833862	0.17
408.0636597	0.30
412.9931030	0.26
415.4445190	0.18
419.8878784	0.13
423.1572876	15.57
426.1730347	2.38
431.1310425	0.56
439.1657715	0.65
441.2359009	73.99
450.1713257	0.28
454.2039795	0.50
455.2184448	0.31
456.0574951	0.60
459.1328735	40.53
459.7993164	0.51
463.1874390	0.48
465.3533936	0.08
467.0834961	2.98
468.1166992	10.69
469.2313843	0.42
471.1237183	0.33
472.2803345	2.46
476.7170410	0.60
477.3501587	3.45
483.8377075	0.14
486.3568726	0.48
490.1496582	13.33
490.7747803	0.27
494.9418335	0.74
495.5687866	0.21
498.3377075	0.36
502.1997681	0.21
512.5720825	0.12
513.2911987	5.21
516.2089233	7.69
525.1904907	0.21
527.8886108	0.11
534.1054077	11.24
534.8122559	0.84
535.9102173	0.43
542.4741821	0.33
543.3389282	0.41
544.8783569	0.11
552.2283936	80.03
553.1184692	0.16
556.7500610	0.30
561.9326172	0.76
570.1355591	100.00
570.8186035	0.99
574.5234375	0.19
578.0032349	1.75
580.0343628	0.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1664
Annotation	Verbasoside
Peak:m/z	Relative Intensity
143.1057739	0.05
148.8981018	0.98
161.0680084	0.25
175.0183411	0.13
177.8355713	0.05
179.2049561	0.10
220.4432983	0.36
221.3612976	0.11
237.7387543	0.05
250.2679749	0.05
254.9635925	0.05
262.0908508	0.29
266.9906616	0.18
280.1735535	0.05
282.8463440	0.13
293.1030884	0.69
295.2579956	0.03
299.2607117	0.17
302.0192566	0.09
311.1476440	0.75
313.1865234	0.04
315.3826294	0.07
327.1502075	0.09
331.2544556	0.19
337.1836243	0.29
365.1102295	0.19
369.0246582	0.18
371.0752258	0.04
381.6505432	0.06
394.4886169	0.05
397.2750549	0.04
398.3919067	0.27
401.5382385	0.14
415.1452942	100.00
415.9675598	0.49
417.3882141	0.56
418.5814514	0.17
424.3874512	0.29
425.4690857	0.22
426.2860718	0.16
431.0750427	0.05
441.3460388	0.21
443.1408081	1.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	319.09
Annotation	Unknow
Peak:m/z	Relative Intensity
112.0411606	0.27
119.0767059	0.18
121.2120667	0.23
124.0321655	0.69
126.0426483	0.03
128.0471649	2.45
131.0757294	0.48
133.0971375	0.07
142.1215820	0.50
146.0755615	0.63
148.0485840	0.32
156.2555542	0.15
156.9655457	0.05
160.9935913	0.78
163.0352325	0.11
164.1967163	0.18
168.0565796	0.17
170.1693878	0.17
179.0487061	0.07
185.2537537	0.12
187.1580811	6.15
190.1424561	7.57
190.8525391	0.05
193.4239502	0.07
196.0903473	0.12
197.9469604	0.16
199.1468201	1.20
207.2252502	5.77
208.2772827	0.50
210.2132263	0.10
213.2726135	2.38
217.2136230	0.70
220.1094055	0.66
221.2354126	0.09
224.2782288	0.23
229.1011353	0.25
238.0656128	0.08
239.1712646	0.35
241.1806641	29.82
242.1857910	0.63
244.2048645	0.07
245.0922546	0.69
247.1647034	0.10
249.2111511	0.07
251.1982422	19.01
253.2352295	0.17
254.2783813	11.44
255.2342529	88.01
257.0590210	0.14
259.3421326	0.11
263.1754150	11.29
267.1637573	0.08
268.1876221	4.29
270.1314697	0.07
273.1214905	100.00
275.1562500	1.14
277.1195679	0.76
280.8982544	0.93
283.1461182	0.04
285.0908508	45.19
288.0609436	1.25
299.2106628	0.07
301.0364990	1.64
302.2944031	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	406.28
Annotation	Unknow
Peak:m/z	Relative Intensity
156.8020172	0.39
165.1387482	0.11
178.8323364	0.10
180.8035583	0.28
188.8499908	0.33
192.6748505	0.15
196.9873657	0.24
263.2673035	0.52
292.3955994	0.11
293.4653625	0.31
299.2467651	0.58
301.0735474	0.22
312.5565796	0.26
327.3422546	0.11
339.2338562	1.04
341.3602600	0.12
343.5237732	0.38
346.4147339	0.25
348.3254700	0.16
357.2845764	2.38
361.2875671	0.16
363.4481506	0.28
366.4959106	1.28
370.1948547	4.53
371.2398376	0.69
375.5394592	1.57
388.2317810	100.00
388.9254456	1.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	290.85
Annotation	Unknow
Peak:m/z	Relative Intensity
122.9112244	1.28
157.9387360	0.12
206.7955627	100.00
230.1415405	0.07
244.0231018	0.03
245.0240173	0.02
245.9699707	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.0316
Annotation	Unknow
Peak:m/z	Relative Intensity
105.0504150	0.29
113.0015564	0.41
118.9519806	0.04
131.1550903	0.03
142.9367676	0.02
145.0189667	0.27
148.9394836	10.03
151.0123596	0.11
156.9028320	0.14
159.1573334	0.04
161.0579834	2.64
163.0018921	2.40
175.0542603	3.35
179.0719910	0.57
190.9427032	3.42
193.1812134	0.05
205.1744080	0.45
207.9750366	0.02
212.7003174	0.05
220.4068909	1.41
221.0281372	6.21
222.8897400	0.23
238.8531799	0.66
251.0429382	6.93
265.0598450	9.42
265.8885498	0.04
267.1597290	0.05
276.0025024	0.03
277.3220825	0.04
293.1450806	0.27
297.1011963	0.04
310.8558350	100.00
311.5317688	0.59
340.2276611	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	442.389
Annotation	Secomahubanolide
Peak:m/z	Relative Intensity
142.9335022	0.36
183.2382965	0.20
211.5775452	0.29
228.7484589	0.53
238.1165466	0.30
253.2697449	0.38
295.1871338	0.17
310.2075195	0.57
317.5516968	0.22
327.3822937	0.17
337.9166260	0.15
361.5647583	1.08
365.3513184	0.53
368.0746155	0.69
369.0015564	0.92
379.1454773	95.15
379.8338013	0.18
385.9192200	0.52
397.1138611	100.00
397.7519836	0.42
401.0275574	0.29
423.5752869	1.09
424.6134033	0.21
442.3841858	0.25
443.2482300	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	855.0399
Annotation	Unknow
Peak:m/z	Relative Intensity
330.8524170	1.54
359.1255188	0.49
386.9320068	0.07
421.0988159	0.09
439.1213379	0.54
440.1741333	0.25
458.3252563	0.24
462.8402100	0.09
474.9446411	1.19
479.4316406	0.14
492.8900757	1.38
507.4061279	0.15
512.6529541	0.10
518.9316406	0.08
540.1477661	0.11
556.9299927	0.66
569.9968872	0.62
574.9414673	5.79
575.8704834	0.45
581.1157837	0.12
593.3101196	0.28
595.0797729	0.23
598.9550781	0.23
605.1435547	0.11
608.8247070	0.10
610.9029541	4.31
612.3351440	0.38
612.9727173	6.57
613.8233032	0.20
615.7531128	0.27
622.5365601	0.07
628.7368164	0.37
657.3726807	0.10
661.0420532	0.14
675.1846313	0.07
681.0815430	100.00
686.3080444	0.08
687.0861206	0.10
692.8240356	6.23
693.8674927	0.12
705.6852417	0.10
708.9943237	0.04
716.6084595	0.20
718.9143066	20.15
720.0818481	1.02
723.2925415	0.07
724.9396362	0.18
734.9054565	1.51
742.8963013	0.79
743.8672485	0.05
770.8610229	1.64
771.5115967	0.03
774.0573120	0.34
779.4063721	0.05
782.9169312	0.24
795.1231689	0.63
798.9454346	0.11
808.8654175	0.82
811.9481201	1.03
813.7784424	0.11
831.4124756	0.17
837.0780640	0.52
854.7499390	0.15
856.5427246	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	380.77
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8249969	0.06
212.8939972	9.37
251.0439453	0.23
289.1934509	0.06
294.1148987	0.10
294.7941284	0.05
296.8404846	100.00
303.2483521	0.04
321.1466675	0.35
334.7393799	36.90
335.3428040	0.14
362.1171265	0.21
363.3027344	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	310.13
Annotation	Unknow
Peak:m/z	Relative Intensity
115.9602203	0.03
117.9894562	0.73
130.0399475	100.00
134.8715820	0.08
138.8898926	0.03
146.9786682	0.20
148.0336761	0.09
149.1860352	0.04
162.0415802	0.17
162.9224548	0.03
164.0250244	0.09
175.2339172	0.07
179.0513000	0.66
180.2583008	0.23
181.0570221	0.64
188.0129852	0.03
190.3381500	0.04
191.1558533	0.03
193.0033722	0.48
196.1780396	0.03
208.9730530	0.06
214.0678101	0.03
217.1062317	0.08
219.7063904	0.03
223.1809692	0.05
232.7313232	0.07
234.2532959	0.26
235.0067139	0.22
237.9131165	0.08
242.0776978	0.05
243.9772949	0.15
245.9720459	0.18
247.1255188	0.29
247.9318542	0.04
250.1496887	0.10
261.2746582	0.09
263.3524780	0.02
267.2618103	0.07
269.1080933	0.27
273.0513611	0.03
275.4777222	0.09
282.0538940	0.04
283.4622803	0.14
291.4745789	0.82
292.2966309	0.95
293.2780151	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	569.3198
Annotation	Unknow
Peak:m/z	Relative Intensity
166.9583435	0.57
173.1022339	0.18
177.0364227	3.31
183.1297760	0.60
186.1952209	0.35
187.0046692	0.30
212.3217163	1.58
212.9606934	0.38
214.7634888	0.30
225.6401520	0.90
232.9806213	0.25
243.1717072	4.79
260.0490417	32.65
261.1467896	2.10
261.8993225	2.09
268.1193237	1.05
283.3502197	1.19
286.1277466	1.67
287.1806030	3.29
288.2882080	2.10
290.0745239	0.69
309.9793091	0.33
328.5709839	0.54
336.3134155	0.60
344.3881836	1.11
355.4149780	0.89
357.1895752	0.94
359.5064697	2.20
360.3118286	1.20
362.2642212	0.56
373.0982666	27.77
374.2066040	5.76
375.1852417	1.51
380.4854736	0.76
383.1904297	0.75
388.2619019	0.65
395.4636841	0.84
399.4142456	0.53
401.2031860	0.45
407.0986328	0.33
408.0750732	0.71
423.5399780	3.91
426.1100464	1.48
427.2096558	1.02
439.6293945	1.16
440.8025513	0.74
442.2031860	0.49
444.3156738	13.16
445.3818359	4.53
450.2778320	0.40
455.6741333	0.41
458.9607544	0.35
462.9782104	1.59
467.4282227	0.74
470.4796143	2.25
471.3546753	0.48
472.3029175	0.37
475.1926270	0.86
478.6242065	1.49
481.5737305	2.52
482.5333252	0.23
486.2167358	0.38
488.3038940	1.57
489.4046631	1.04
492.1818237	1.21
493.1040649	0.26
494.2579956	3.68
501.3374023	2.60
502.2627563	0.66
503.7189331	12.23
506.5930786	0.40
508.0485840	0.50
509.3049927	0.89
509.9298706	0.86
513.6017456	0.38
517.9331055	6.06
518.7505493	2.60
519.5294800	14.50
520.2622681	9.64
521.0983276	1.35
522.7614746	4.20
523.5787964	2.01
525.2395020	1.02
526.1334229	0.33
531.9044189	10.91
532.9757690	1.96
536.8961792	1.42
538.8787231	1.63
539.7268677	0.41
543.8141479	2.44
544.5017090	0.38
545.4113159	0.98
551.8087769	17.77
552.6987915	13.60
553.4194336	2.50
557.7001343	0.28
560.3129883	21.20
561.0535889	22.83
561.9746704	6.39
576.3226929	1.07
589.1081543	1.82
591.3712158	3.26
600.4230347	1.08
602.1220093	6.91
603.3181763	1.56
618.3720703	20.72
619.3778076	19.04
620.2822266	13.44
621.3246460	4.24
672.1674194	1.07
674.6762695	0.71
679.4293823	0.33
681.5476685	1.32
688.2780151	1.23
690.4423218	4.01
691.5914917	0.52
713.2656860	0.38
717.6370239	0.62
734.5780640	0.94
747.4633179	5.92
748.8062134	0.88
761.8912964	0.61
764.0715332	0.58
765.5007935	73.78
766.4868164	16.60
767.5115356	4.12
778.4497681	0.69
803.8187256	1.61
804.7634277	0.55
805.5754395	1.66
815.4904175	0.52
816.4907837	0.25
819.4088745	1.00
833.7590332	0.70
848.5581665	1.68
849.7431030	0.69
850.4057007	0.54
860.7695923	0.93
861.7038574	1.04
878.5856934	100.00
879.5685425	45.87
880.5713501	14.92
915.3264771	0.71
916.5578613	2.22
917.3184204	0.52
918.3971558	0.40
928.2560425	0.38
933.4277954	0.43
934.4230957	3.57
935.3273926	1.47
943.3626099	4.05
944.2853394	3.81
945.5793457	1.00
950.2247925	0.60
961.5632324	27.39
962.4960327	7.74
963.5136719	2.89
990.4821777	1.00
1006.3041990	0.53
1007.9631350	1.36
1008.6123050	1.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1013.87
Annotation	Unknow
Peak:m/z	Relative Intensity
314.4166565	0.17
528.4393311	0.31
532.2077637	0.68
619.5500488	0.56
716.3803101	0.41
728.6792603	0.32
739.2402344	0.62
756.2043457	0.18
797.4985352	0.55
849.1699219	0.69
880.4312744	1.10
896.6668701	0.40
900.7969971	0.35
930.4986572	1.54
965.0727539	4.37
966.8157959	2.07
968.4979248	1.28
972.7209473	5.57
973.6303711	0.51
975.0998535	0.84
987.0644531	2.97
988.0444336	2.53
989.9095459	5.11
991.3583984	0.18
994.8679199	2.17
1034.3552250	0.78
1050.1191410	1.86
1066.8347170	0.35
1070.4812010	0.21
1083.5554200	2.50
1091.3227540	2.63
1100.0252690	3.23
1108.3957520	2.21
1116.1262210	2.94
1118.5318600	2.04
1124.7231450	4.69
1125.5102540	1.54
1131.5458980	3.66
1132.2818600	0.16
1134.1445310	100.00
1134.9493410	3.45
1135.9316410	0.94
1136.9561770	0.21
1137.7437740	1.11
1140.5793460	0.76
1141.3891600	3.87
1144.3978270	2.60
1147.0986330	2.18
1150.0169680	3.31
1152.3569340	8.40
1153.1282960	1.02
1155.8149410	0.18
1158.6064450	3.23
1161.4350590	0.37
1163.9758300	0.28
1171.8608400	1.88
1190.0412600	1.27
1192.4104000	1.33
1199.8883060	2.43
1211.1561280	0.57
1220.8259280	0.42
1241.5522460	0.12
1253.6883540	1.71
1274.9321290	0.28
1290.3834230	0.51
1299.8312990	1.57
1514.8358150	0.52
1538.9465330	0.84
1539.8444820	2.15
1551.1279300	0.12
1600.8946530	0.18
1703.2951660	0.19
1770.8020020	0.67
1851.6545410	3.89
1876.3719480	0.16
1886.3656010	2.11
1905.5538330	0.30
1906.9884030	0.21
1908.3817140	0.25
1910.1550290	14.35
1917.3787840	0.71
1920.2580570	0.24
1925.0201420	26.52
1935.9388430	0.69
1936.6888430	0.50
1942.9830320	0.29
1947.0584720	0.29
1951.2916260	0.16
1956.4573970	15.07
1958.4525150	8.39
1959.4187010	0.18
1966.2254640	2.46
1967.9207760	1.04
1969.8157960	0.62
1970.6833500	0.38
1971.9417720	0.13
1975.6125490	8.74
1977.5202640	0.47
1978.7889400	2.79
1979.9498290	0.69
1982.1817630	55.40
1983.2019040	25.77
1986.3288570	0.34
1987.7746580	7.64
1989.0529790	0.21
1990.4791260	0.29
1993.6239010	0.22
1996.1604000	2.06
1998.2039790	11.17
1998.9202880	9.66
1999.8596190	5.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	617.1079
Annotation	Unknow
Peak:m/z	Relative Intensity
173.0231171	0.02
174.0981903	0.06
178.9379730	0.04
180.9805145	0.04
183.1894073	0.24
184.8744965	0.12
188.8125610	0.06
191.2093506	0.01
193.2430115	0.70
194.0887909	0.07
194.9668884	0.12
197.2492371	0.08
199.1679688	0.25
207.4133148	0.02
209.1028900	0.09
211.3426819	0.03
213.0353394	0.28
213.8192444	0.03
216.2344818	0.02
217.0104828	0.11
219.8414001	0.03
221.3205566	0.04
225.0406494	0.28
226.1234894	0.02
228.3538666	0.06
229.1716919	0.02
231.1234741	0.83
232.2236786	0.08
237.2308350	2.27
238.2965698	0.08
241.1517487	0.22
242.1227417	0.33
243.1920471	0.07
245.0751953	0.03
253.4325562	0.03
254.2199554	0.33
255.2057190	0.09
256.3957825	0.21
259.1569214	1.20
260.2181091	0.20
261.0708618	0.22
263.3320923	0.03
266.0679321	0.02
269.1341248	0.18
271.1978149	2.69
273.1525269	24.22
274.1998291	2.05
277.1768799	0.03
278.6845093	0.02
285.1339111	0.10
286.1680298	0.04
289.2971802	0.15
295.0017090	0.02
297.2392578	0.05
303.1152954	19.41
304.1402588	1.62
305.2525024	2.67
306.1744385	0.22
307.2300110	1.92
308.3111267	0.07
316.4722900	0.02
319.0522156	0.08
323.3468628	0.03
337.0636597	100.00
338.1969604	8.65
338.9284058	0.02
341.2716675	0.69
343.2201538	0.02
349.2915649	0.01
355.2285156	0.03
357.3327026	0.02
360.7169800	0.09
361.8340454	0.04
365.2099609	0.04
371.3076172	0.03
372.7705688	0.03
373.3746338	0.08
379.2818604	0.30
383.3086548	0.11
389.2449951	0.23
390.2807007	0.06
392.1570435	0.13
403.4630737	0.13
409.3452148	0.11
410.1553345	0.07
415.0566406	0.02
416.9522095	0.01
421.2221680	0.10
422.1704102	0.05
423.1821289	0.07
424.3463135	0.02
427.5110474	0.21
435.0976562	0.03
437.1166382	1.58
438.1143188	0.08
442.1685791	0.02
446.5517578	0.02
455.0983276	41.29
456.1470947	4.81
456.7566528	0.02
461.0979004	0.07
461.8596191	0.01
463.0338745	0.05
468.1912231	0.05
469.2983398	0.01
473.2189941	1.19
474.2857056	0.04
479.2122192	0.08
479.8155518	0.02
489.6412354	0.04
492.4290771	0.03
497.0757446	0.30
497.8423462	0.12
502.3208008	0.11
509.1917114	0.14
512.9768677	0.03
515.1126099	0.18
518.6487427	0.01
519.4943237	0.03
521.6369019	0.05
522.6448364	0.02
526.5076904	0.05
527.1503906	1.21
528.1863403	0.26
533.1493530	0.03
539.3247070	0.31
549.1738892	0.05
551.3141479	0.94
552.4011230	0.18
553.1315308	0.03
557.1142578	18.04
558.1577759	1.38
565.3629150	0.02
569.4017944	0.03
571.0327759	0.02
572.6249390	0.02
573.6519775	0.19
575.0842285	0.20
579.0053711	0.12
581.1566772	0.21
582.2316284	0.03
583.0394897	0.34
587.3019409	0.32
588.5462646	0.09
599.1419067	0.96
600.1599731	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	259.0786
Annotation	4'-Hydroxyflurbiprofen
Peak:m/z	Relative Intensity
112.9534912	0.12
113.9321136	0.04
126.0667419	0.04
131.0504150	0.03
140.0483246	1.86
145.1887817	2.97
158.0562897	0.12
167.1853638	0.17
184.2032623	0.07
196.0485687	6.08
198.6313782	0.10
202.2510223	0.17
211.1732025	0.26
213.0801849	100.00
214.0529785	1.24
215.2380524	0.88
225.0956573	0.25
230.9832916	18.43
231.5926971	0.05
232.9865723	0.07
240.1434784	0.06
241.1211548	1.09
242.1810913	1.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	161.1071
Annotation	N-Norgramine
Peak:m/z	Relative Intensity
97.0441742	0.02
114.7729187	0.08
118.1233978	0.05
133.0491333	0.04
143.9682770	100.00
163.4495087	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2777
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
139.9497833	0.12
153.0213776	0.05
166.1258698	0.02
196.1000061	1.75
214.1063538	1.41
223.9568787	0.02
259.3003845	0.06
261.3979492	0.16
279.2840576	100.00
284.7448120	0.02
314.9317932	0.01
393.6238708	0.03
402.0924988	0.02
404.6045837	0.03
415.2738342	0.41
429.4386292	0.03
431.5643616	0.02
432.3234253	0.01
433.6168518	0.02
440.5537720	0.08
448.2379456	0.02
458.4499817	0.10
459.1172485	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
123.2066956	0.21
131.0611877	0.17
143.0775909	0.10
146.8425598	0.31
156.9949036	1.31
159.0978088	0.94
169.1620178	0.45
171.0782166	2.08
173.2211761	0.80
183.1878357	0.62
185.1292725	2.14
187.0717468	0.92
188.9701538	0.29
195.0769501	0.39
199.1438293	2.22
201.1012573	2.60
203.3108063	0.76
211.3494415	0.57
215.1784973	4.61
217.1965027	1.17
221.0665283	0.64
227.2392883	1.42
229.2587585	4.62
231.1075439	0.73
241.2084045	3.46
243.2351074	3.96
251.3152771	0.77
255.2773132	1.40
257.3150024	3.29
259.4358521	1.32
261.3434448	0.19
263.5076294	0.78
267.2232666	0.28
269.2539368	0.98
271.243103	3.05
273.3147278	2.23
277.3273926	0.35
283.168396	1.45
285.2608643	5.45
287.3540649	2.21
288.7943115	0.31
293.3372498	0.41
297.2766113	6.44
299.3215942	7.16
301.064209	0.88
309.4507141	0.57
310.6309814	3.28
311.6062622	0.39
313.107605	4.48
315.3074341	1.84
318.6361694	0.32
319.3445435	0.19
321.2213135	3.69
323.2822266	4.96
325.2091675	0.23
327.0204773	0.32
329.0591125	0.28
337.1674805	0.90
339.2563477	100.00
340.3630981	1.57
341.2808838	27.15
342.2756653	0.63
347.592041	1.81
351.1253052	0.17
355.9812927	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	395.13
Annotation	Unknow
Peak:m/z	Relative Intensity
127.1913452	0.41
132.3179016	0.13
144.1629028	0.35
150.2203674	0.23
158.8739929	0.18
162.1229553	2.90
163.0791931	1.41
172.0151367	0.78
173.0656738	1.11
211.7704010	0.18
227.8716736	0.18
229.9548035	3.41
230.9927673	5.40
246.1019897	0.30
247.2904663	3.75
248.0213013	10.42
248.9767761	13.47
263.3539734	0.90
265.0545959	59.25
266.0209961	100.00
271.3919983	0.24
274.9981079	2.31
282.1149292	0.07
287.2742310	1.35
289.2029419	0.33
290.6737671	0.11
292.0726624	0.28
295.2096558	0.17
297.1002502	0.61
301.8037109	0.17
305.0053406	11.84
306.9239807	0.28
320.0457153	6.04
330.3617554	0.88
331.9163818	0.60
333.3020020	0.19
335.0301514	3.65
348.5555420	0.54
349.2519226	0.19
352.4432373	0.36
359.0216980	1.86
376.5508728	1.06
377.2023315	11.75
378.1773987	0.54
385.8389587	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.0471
Annotation	UDP-glucose
Peak:m/z	Relative Intensity
159.1137848	0.06
175.0644226	0.12
192.837265	0.25
210.9599609	2.35
220.8826599	0.31
222.1583862	0.44
223.0754547	0.09
241.2186432	0.66
241.9518433	0.26
272.9958191	0.08
280.1046753	0.95
280.8959351	0.05
291.3815918	0.11
295.1444702	0.12
305.0394897	0.33
321.1098633	1.54
323.03302	100.00
323.6792603	0.07
334.3967285	0.36
341.12323	0.11
356.1474609	0.28
385.133728	2.84
387.9115601	0.07
389.2855225	0.08
397.1289673	0.10
402.491333	0.25
403.1615601	3.06
411.8369751	0.20
412.8527832	0.08
415.2316895	0.21
417.1595459	0.19
418.8949585	0.16
420.8932495	0.10
428.4061279	0.05
432.0731201	0.05
445.3769531	0.07
446.2232666	0.03
447.2093506	0.05
453.0680542	0.08
461.953064	0.07
467.2346191	0.21
491.7417603	0.04
500.8240356	0.11
517.0419922	0.04
517.8569946	0.18
519.0370483	0.12
521.2632446	0.11
526.8549194	0.18
528.3345947	0.05
545.0568848	0.12
547.1583862	1.05
547.8973999	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.1785
Annotation	Unknow
Peak:m/z	Relative Intensity
118.1668701	0.05
127.0303726	0.03
139.9952698	0.41
145.0382385	15.55
146.0658112	0.03
158.9266815	0.14
167.1518555	0.32
184.9413147	0.17
195.8547974	0.42
204.8316956	0.03
206.3056641	0.03
207.0474091	0.09
210.2697906	0.03
211.1656342	0.02
213.0531921	2.06
214.0487366	0.05
216.0539856	0.08
222.3467102	0.25
223.0575256	1.26
227.1655579	0.16
228.8608093	0.09
230.7352295	0.12
231.3790894	0.04
234.1766663	0.06
240.1238708	5.53
240.8578491	0.17
242.8671570	0.16
245.2606506	0.03
258.1366577	1.24
262.5023193	0.09
263.3182373	0.12
267.2554321	0.26
270.9282837	0.05
277.1232605	0.10
279.2384644	1.89
280.1976013	0.99
285.3576355	0.04
292.8600464	0.05
294.1664734	2.42
295.1955566	0.38
296.2050171	9.35
297.0996704	0.37
298.2014465	0.14
299.1162415	0.18
300.1065063	0.03
311.0065918	0.07
311.8977051	0.34
313.2307739	100.00
314.2127075	2.63
315.2055054	0.16
316.2136841	0.16
324.2050171	0.12
331.0982971	20.72
332.2084961	0.18
333.2308960	0.06
339.3391113	0.07
340.2114258	0.35
341.2789612	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	266.02
Annotation	Unknow
Peak:m/z	Relative Intensity
218.8225861	0.03
221.1163177	0.09
222.0203705	0.18
224.8054810	100.00
225.4266510	0.47
229.0449982	0.02
240.6064301	0.11
242.6507416	17.58
243.3454437	0.13
243.9733734	0.05
245.0483856	0.17
249.1269073	0.06
265.9562073	0.15
268.8673096	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	677.9853
Annotation	Unknow
Peak:m/z	Relative Intensity
211.8144836	0.34
215.6061096	0.16
217.7456665	0.09
233.9613037	0.38
249.1896210	0.55
264.0250854	0.12
266.0919800	0.22
275.8670044	0.11
278.0144653	0.89
302.0470886	0.76
302.6969604	0.15
306.0496216	0.06
306.7166748	0.19
307.8111572	1.21
309.0548096	0.25
321.0377808	0.05
331.9071045	0.23
335.8188477	0.16
344.1920776	0.27
347.7243042	0.81
348.3337402	0.29
349.9186401	1.51
365.8842163	2.31
368.0046387	13.36
375.2178345	0.10
389.9387207	0.09
407.9293213	0.69
413.1252441	0.31
419.9807129	0.59
424.0433350	0.90
425.9533081	100.00
426.5905762	0.20
428.2288208	0.10
437.9874878	11.38
454.7917480	1.28
455.7731323	0.23
467.8444214	0.36
491.4168091	0.10
497.5562744	0.20
508.5561523	0.72
510.0325317	0.42
512.7521973	0.15
515.2437134	0.71
515.8685303	1.54
517.2263794	0.56
520.0124512	0.07
521.0726318	0.87
527.9072876	1.99
531.1207886	0.30
545.4443970	0.14
546.1577148	0.18
548.1677246	0.48
549.1671753	0.40
558.4338989	0.11
571.3656006	0.22
574.7826538	0.31
577.2337036	0.13
587.7971802	4.21
588.5513916	0.23
592.2748413	0.17
593.5281982	0.79
595.2718506	0.09
596.1348267	0.41
602.3392334	1.24
604.9767456	0.41
617.3442993	0.51
618.0927734	0.30
619.0787964	1.59
641.1798706	0.14
644.0206909	0.10
659.4171143	1.07
660.2377930	0.42
669.5169067	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	617.108
Annotation	Unknow
Peak:m/z	Relative Intensity
172.9656982	0.07
176.3831482	0.04
183.1337433	0.11
185.2428589	0.05
187.2160339	0.07
189.0826416	0.04
191.2199402	0.03
193.1688385	1.13
194.2540588	0.06
194.9156036	0.15
197.1440430	0.27
198.1712494	0.05
199.1976624	0.19
200.1664581	0.04
208.0412750	0.58
213.1436768	0.03
216.9938965	0.07
218.6379547	0.04
220.0303345	0.07
221.0748291	0.04
223.0961304	0.02
225.0479584	0.44
225.9329224	0.09
227.2955322	0.03
231.1757812	1.03
232.2027435	0.05
237.1026611	2.31
237.7644653	0.01
241.2450867	0.24
241.9060364	0.15
243.0823364	0.03
244.9629822	0.03
247.8220215	0.05
252.2163544	0.05
252.9719238	0.04
254.1735229	0.77
255.2465668	0.06
256.2140198	0.06
257.3437805	0.05
259.1217651	1.57
260.2448730	0.09
261.1402588	0.21
269.7177429	0.18
271.1857605	2.27
273.1314087	24.60
274.2219238	2.89
275.2393494	0.03
277.2746277	0.02
278.9825439	0.01
285.0753174	0.03
286.9193115	0.03
295.1495972	0.17
296.1991272	0.04
297.2714844	0.07
303.1044312	22.09
304.1988220	2.63
305.2066040	3.14
306.0448914	0.31
307.1855469	1.85
308.3299561	0.32
314.8873901	0.08
319.2721558	0.02
329.5230103	0.02
337.1041260	100.00
338.0775146	10.12
343.9015503	0.04
345.3634033	0.03
346.2878418	0.03
347.1483765	0.02
354.3588257	0.02
357.3878174	0.08
361.0722046	0.02
370.9512329	0.04
374.3027344	0.08
378.2817993	0.18
379.2308350	0.19
380.3956909	0.02
388.9867554	0.08
390.7727051	0.04
402.8038940	0.05
409.0895996	0.04
417.1442871	0.17
419.3236084	0.07
421.1522217	0.07
427.3073730	0.05
430.9656982	0.03
432.2276611	0.03
435.3536987	0.03
436.1113892	0.08
437.1341553	0.81
438.0048218	0.14
439.0655518	0.02
447.5012207	0.04
449.4623413	0.05
452.3644409	0.06
455.0920410	33.09
456.0799561	4.73
461.1164551	0.11
464.2697144	0.06
466.2291260	0.03
469.1476440	0.03
470.7452393	0.11
471.5544434	0.03
473.2167358	0.02
475.9007568	0.03
484.5720215	0.13
486.7597046	0.03
488.4606323	0.12
489.4309082	0.14
492.1343994	0.02
496.6788940	0.28
497.3047485	0.08
501.1957397	0.09
502.4517212	0.52
503.4171753	0.03
509.1375122	0.07
514.9868164	0.07
516.0696411	0.02
519.5817871	0.05
523.3056030	0.08
527.0173950	1.56
528.2201538	0.08
538.6459351	0.07
539.2661743	0.39
540.5157471	0.02
551.3082886	1.01
552.2681885	0.08
552.9331665	0.09
557.1109619	18.09
558.1973877	3.15
563.3213501	0.03
571.3807983	0.43
575.0262451	0.17
575.9569702	0.05
579.8580933	0.08
581.2880859	0.12
582.1921997	0.05
582.9920654	0.38
584.2238159	0.04
587.0423584	0.16
588.0449829	0.16
593.7702026	0.06
594.8840332	0.07
599.1647949	1.60
600.3160400	0.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	260.0234
Annotation	2-methoxyacetaminophen sulfate
Peak:m/z	Relative Intensity
78.9689331	0.06
79.9002228	0.33
80.9352341	0.13
95.6166534	0.05
97.0231171	0.18
113.1454163	0.07
119.0681458	1.97
128.1114044	0.13
130.0838318	0.05
130.9742889	0.04
134.0981903	0.34
139.1009979	0.03
152.2030945	0.11
153.2380981	0.03
157.8958588	0.03
159.8824463	0.03
163.1641693	0.55
168.9160004	0.22
170.0921478	0.03
172.2244873	0.03
180.1275024	11.27
182.2156372	0.03
186.1187286	3.31
187.1122894	0.52
187.9206696	0.04
188.9276123	0.09
190.0467987	0.04
193.1054688	0.03
195.3180389	0.10
196.1838837	0.05
198.9696350	100.00
199.8009186	0.02
205.0430145	0.07
211.9471588	0.05
214.9750519	26.60
215.8509064	0.26
217.2355499	0.06
217.8726044	0.12
223.0443573	0.05
223.8242798	0.13
226.1936798	0.03
230.2278748	0.03
232.1524048	0.11
240.9199371	0.29
242.1407471	2.01
242.9261627	6.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	533.12
Annotation	Unknow
Peak:m/z	Relative Intensity
138.7076111	0.47
156.1531677	1.16
157.2532043	0.77
167.0509033	0.71
169.9574585	0.24
188.0196838	24.54
204.9830017	100.00
208.1392212	0.79
209.1082764	0.99
230.0720978	0.44
282.2720337	0.42
293.0906982	1.21
303.3350525	0.39
311.1190796	0.86
318.1304321	0.32
320.3039551	0.64
322.9695435	1.02
328.8016968	1.38
330.2224731	0.85
342.1384888	1.62
344.5351562	0.37
385.8739624	0.47
400.3182373	0.68
400.9758301	0.24
419.6849365	0.42
471.2116699	1.58
472.1048584	1.71
486.8140259	0.49
504.5338745	0.44
512.0576172	0.47
514.5484009	1.18
515.4208374	1.13
517.3419800	0.65
533.3460693	1.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.109
Annotation	Lactulose
Peak:m/z	Relative Intensity
100.9303207	7.19
113.0041504	16.50
115.0229034	0.18
118.9791794	17.48
125.0229492	1.64
128.8093414	0.26
131.0049438	4.83
143.0039978	21.41
148.8920746	2.79
158.8684387	0.40
161.0249939	21.58
177.1069641	0.24
178.9051056	100.00
182.8341827	0.28
184.0428619	0.37
217.9850464	1.31
220.9468079	0.17
239.1193848	0.59
245.0383301	0.45
262.9127502	0.43
280.8806152	1.67
312.3067322	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1509
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
167.3604431	0.02
169.0292511	0.03
173.0780945	0.07
174.1470947	0.02
179.0921936	0.03
180.1041412	0.05
181.9116211	0.25
183.0314636	0.17
183.9011230	0.09
185.1086731	0.30
187.0649567	0.10
189.2091522	0.32
191.0595093	0.02
192.0463562	0.02
195.1804352	0.15
196.0858765	0.10
197.1438141	0.53
198.0892334	0.08
199.0581055	0.58
200.2140045	0.11
201.0865173	0.07
207.0571594	0.08
209.0698547	0.19
210.1618958	0.09
211.1080170	0.52
212.1946106	0.50
213.1745453	0.80
214.0577850	0.19
215.0369263	0.09
217.3028717	0.25
221.1450653	0.05
223.0317383	0.52
224.2343140	0.04
227.1195068	0.81
228.1314392	0.04
229.1147461	2.50
230.1951141	0.20
231.2674255	0.02
234.1522827	0.06
239.0880127	0.71
240.1931915	1.06
241.1041565	0.90
242.0982666	0.17
243.1360779	0.37
253.2831116	0.07
255.0691376	1.39
256.1393433	0.52
257.1769714	3.04
258.1366272	0.08
259.2743530	0.07
260.0384521	0.02
267.0363770	1.32
268.1269531	0.06
269.0543823	0.04
271.2621155	0.03
273.1452942	0.02
277.2815247	0.02
281.3546143	0.04
283.1229248	0.46
284.2517090	6.10
285.0727539	100.00
286.0588989	14.92
286.8689575	0.03
287.4913330	0.04
297.3519592	0.11
298.2725830	0.14
299.1326294	0.20
305.1294861	0.02
308.0740967	0.01
308.8726196	0.05
313.1147461	0.03
321.0814819	0.02
323.2305298	0.02
325.0104370	0.02
327.2338867	3.53
328.2360229	0.35
337.0481567	0.03
351.1784668	0.02
352.9854736	0.03
357.2487793	0.63
367.2626953	0.05
369.2303467	0.02
371.1394653	0.06
386.1253662	0.03
413.2325439	0.05
414.4036255	0.02
428.7335815	0.07
430.2536621	0.11
432.3779907	0.02
444.3878174	0.05
447.2462769	0.10
448.0578613	0.07
455.2929688	0.03
473.2907104	0.03
478.6513672	0.06
507.3311157	0.07
508.4062500	0.02
521.4069214	0.03
525.6525879	0.12
533.4443970	0.05
546.8907471	0.24
547.8833618	0.03
557.3792114	0.07
558.4584351	0.06
565.2634277	0.26
575.2296143	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	454.2919
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
183.9923859	0.13
198.0372925	0.26
216.0730896	0.08
273.2617798	0.18
282.4285889	1.41
293.2362061	0.27
300.2955322	0.09
313.2677002	41.83
314.0934448	0.06
318.7420044	0.25
351.2235107	0.12
363.6786194	0.12
368.3864136	0.11
369.4655151	0.09
393.2589111	4.75
418.9052124	0.05
426.3048401	0.19
436.1527710	100.00
436.7637939	0.72
446.0989990	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	655.2759
Annotation	Cryptophycin A
Peak:m/z	Relative Intensity
187.7186279	0.19
193.1948242	0.08
195.9092407	0.37
204.1246490	0.08
206.1856384	0.40
208.0792847	0.27
209.1008759	0.07
210.1720734	0.25
211.2464752	0.43
212.2655334	0.10
219.8971863	0.09
221.1426697	0.05
223.1278381	0.23
224.0683289	0.67
225.2634125	0.80
226.1443787	0.45
227.4832458	0.26
230.1791992	0.10
231.2165527	0.05
232.1936646	0.04
234.0911407	0.37
235.1761475	0.33
236.0929260	0.08
237.1645050	0.19
238.8602600	0.36
239.7112885	0.26
240.5733795	0.81
241.4616394	0.41
243.3053741	0.09
246.3831177	0.04
247.3053131	0.07
248.4461517	0.06
249.2134857	0.42
250.2978516	0.27
251.1611023	0.54
252.0140076	0.47
253.2610016	0.36
259.8933105	0.09
262.2761536	0.06
263.1816406	0.20
264.3230591	0.19
265.2911377	0.30
266.2120056	0.13
267.1954651	5.74
268.3221436	0.92
270.1484680	0.14
271.2188721	0.11
271.9035950	0.07
273.2003174	0.07
275.1798401	0.64
276.1095886	0.26
277.9437561	0.08
281.4582520	0.15
283.3458252	0.23
289.1943665	0.35
290.3558960	0.38
291.1024170	0.14
292.1970825	0.06
293.2845154	0.92
294.1654053	0.53
295.0939941	0.06
297.4769897	0.04
302.0628662	0.09
303.1725769	0.95
309.2720337	0.63
310.3634949	0.40
311.1882935	0.23
313.5645142	0.19
314.8218994	0.15
318.1540527	0.18
319.2048340	0.04
321.2265015	7.66
322.3021851	1.20
325.3090210	0.17
327.4189453	0.20
330.3905029	0.34
331.4594421	0.08
334.3682251	0.08
335.4526367	0.09
336.3395386	0.62
337.2358093	0.31
339.2296448	0.04
340.1692505	0.36
342.0321655	0.05
345.7156982	0.11
347.4260864	0.05
348.1200562	0.19
350.5392456	0.07
353.4542847	0.05
355.1911011	0.46
356.4290161	0.20
357.3141479	0.46
358.6889648	0.37
359.5356445	0.05
361.0241699	0.36
362.3500366	0.10
366.3685913	0.30
370.4628296	0.05
371.4052734	0.14
373.0236206	0.36
376.2829590	0.24
383.2743530	0.07
384.0427246	0.06
385.1137695	0.36
386.2937012	0.07
387.1771240	0.17
389.3156738	0.39
391.2478638	0.12
395.1235352	0.60
396.3890991	0.11
397.2279663	0.03
398.2586060	0.26
400.5748901	0.08
401.2701416	0.12
404.4240112	0.04
405.2624512	0.38
408.0299072	0.05
409.7362061	0.25
411.1325073	0.05
412.2198486	0.35
413.2385864	0.38
414.3995972	0.22
415.3775024	0.49
416.1441040	0.26
419.5122070	0.06
420.5480957	0.11
426.5848999	0.37
427.4393921	0.79
428.3654785	0.62
429.8325806	0.14
431.2122192	0.16
436.3593140	0.20
439.1652222	0.06
440.5869141	0.07
442.6128540	0.25
444.5036011	1.37
445.3596802	0.44
446.2546387	0.13
447.4609375	0.06
449.2256470	0.10
453.0853271	0.06
456.2697144	1.25
457.2634277	0.72
458.2994385	0.04
459.2780151	0.06
460.2250366	0.88
469.5202637	0.04
470.5636597	0.17
471.4102783	0.27
472.0328369	0.41
473.0091553	0.13
473.6179810	0.05
475.2537231	0.10
478.0505371	0.34
479.1759033	0.08
481.1397705	0.07
486.5433350	0.28
488.2839355	6.87
489.3446045	2.75
490.3137207	0.20
491.5450439	0.24
493.1156616	0.63
494.1964722	0.18
496.1882935	0.19
498.3991699	0.23
500.0250244	0.24
503.3707275	0.13
505.4232178	0.13
506.4215698	0.06
507.4003906	0.05
509.0654297	1.27
510.1593628	0.53
511.3601685	0.85
512.1987915	0.13
513.3025513	0.09
514.2279663	0.11
515.7415771	0.10
519.3824463	0.18
520.5344849	0.05
521.4420776	0.03
522.4176025	0.05
525.3090210	1.44
526.4791870	0.69
527.4824219	0.09
529.1787720	0.39
532.4398804	0.33
533.3106689	1.03
534.2449341	0.26
535.5878296	0.69
536.3189087	3.46
537.3994751	1.66
538.4738770	0.18
539.3864746	0.85
540.3036499	0.16
542.6690674	0.25
545.4757690	0.28
546.2612915	0.21
547.2343750	0.08
548.8848877	0.51
550.5256348	0.43
551.3457642	0.19
552.5181274	1.35
553.3577881	1.19
554.4174194	1.43
555.5169067	0.43
556.4767456	0.15
559.5417480	0.05
560.3919067	0.09
561.3710327	0.30
562.4824829	0.26
563.4638062	0.74
564.3143921	0.25
565.4438477	0.36
568.2050171	6.84
569.3983765	2.87
570.2557983	0.15
571.2273560	0.06
572.6596069	0.25
574.5460815	0.07
575.1531372	0.09
576.5516968	0.10
577.3643188	0.33
578.3804321	0.45
579.4177246	1.38
580.4201660	2.19
581.3975220	3.22
582.5213013	0.87
583.3991089	0.26
584.4796753	5.01
585.4591675	2.44
586.4274902	0.76
587.2455444	0.12
588.2412720	0.47
591.1364136	0.44
592.5545654	0.45
594.1171265	0.31
595.3306274	9.66
596.4320679	4.64
597.5183716	1.17
598.4895020	0.57
599.4445190	1.14
600.2480469	0.41
601.5457764	0.21
605.3791504	4.18
606.4379883	2.38
609.3632202	3.18
610.4589844	1.33
612.3145142	100.00
613.3383179	78.04
614.3892212	18.34
615.2747803	0.30
619.4222412	0.22
620.2854614	0.18
621.4537964	0.33
623.3166504	76.85
624.3979492	44.71
627.3550415	9.67
628.4024048	4.57
637.3710938	85.65
638.3313599	46.26
639.0195923	0.76
640.3150024	3.75
641.2582397	3.85
642.4155273	0.08
646.1958618	0.10
655.9584351	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	739.2153
Annotation	Guibourtinidol-(4alpha->2)-3,5,4'-trihydroxystilbene-(6->4beta)-epiguibourtinidol
Peak:m/z	Relative Intensity
293.2262268	100.00
390.4019775	0.32
409.0194092	0.52
445.1445312	0.41
510.3273926	2.41
577.0944214	0.63
590.5531616	0.64
607.2800903	0.92
624.5734253	0.73
701.0552368	0.41
704.3250122	3.92
720.4161987	0.65
721.4276123	6.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	188.0702
Annotation	Indoleacrylic acid
Peak:m/z	Relative Intensity
67.4230652	0.04
117.0661163	0.08
117.9383698	0.10
142.0126801	0.28
144.0266571	9.71
145.9491119	100.00
160.0670624	0.45
170.0121460	4.12
170.6786499	0.03
187.8916779	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	873.2114
Annotation	Unknow
Peak:m/z	Relative Intensity
247.0696411	0.07
255.1283417	0.37
270.8915100	0.05
278.8463745	0.21
283.1862183	0.11
299.0612183	0.04
300.0822144	0.05
301.1459656	1.85
323.0676270	0.04
343.0021362	0.22
344.1746826	0.15
344.9700317	0.06
346.2595520	0.05
353.2708435	0.05
354.0808105	0.07
370.0228577	0.16
395.2463379	0.09
410.8000488	0.17
439.5691528	0.12
444.6060791	0.04
487.4481201	0.03
488.9528198	0.02
528.9078979	0.06
530.1623535	0.47
531.2332153	3.15
549.5037231	0.07
559.4186401	0.06
564.1658325	0.25
565.2695923	0.21
571.4735107	0.07
573.3823853	0.14
577.2993164	0.05
587.2768555	0.09
589.2748413	0.18
591.4729004	0.05
593.7926636	0.08
609.3259888	57.29
610.3534546	0.03
612.6845093	0.23
618.4677124	0.11
623.5431519	0.30
624.7076416	0.15
647.2281494	0.09
650.7366333	0.04
651.4321899	0.14
653.4509888	0.04
663.0851440	0.13
671.5778198	0.13
677.1419678	1.01
677.7675171	0.05
680.4338989	0.03
684.7575684	0.09
692.5164185	0.22
693.5305786	0.42
710.3807983	0.44
711.4130249	0.98
719.1679688	0.33
728.3738403	0.26
729.2127075	0.02
752.8401489	0.24
753.6499634	0.05
764.6089478	0.20
768.8712158	0.06
771.1865845	0.26
782.2713013	0.05
785.8553467	0.05
794.4496460	0.16
795.1945190	0.10
797.8555298	0.09
812.3871460	0.16
813.4381714	0.12
826.6210938	0.05
827.9732056	0.18
828.5902100	0.08
829.7341919	0.09
839.2349243	100.00
839.8574219	1.20
842.1975098	0.03
849.6265259	0.32
851.0213623	0.26
854.2803955	0.23
855.3442993	0.19
857.7173462	0.16
863.4719849	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.146
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
171.9850006	0.08
179.0191956	2.07
180.0359039	0.15
185.3084412	0.11
186.9501648	0.04
188.9271545	0.26
190.1308899	0.16
191.0967407	0.28
192.9854736	0.16
199.1526337	0.14
207.0157471	0.10
210.9158325	0.06
212.9903717	0.23
217.2044220	0.08
220.8089447	0.04
221.5237579	0.11
225.8086548	0.30
227.1296997	0.82
228.1847534	0.21
229.1298218	0.29
231.2612000	0.06
233.0724182	0.44
239.8195496	0.77
243.2875214	0.51
244.2587891	0.22
245.0475616	0.17
247.2429504	0.07
255.0083923	3.49
256.0588989	0.77
257.0487061	0.90
258.0035706	0.06
259.0433960	0.08
266.0485229	0.11
267.2328796	0.11
271.0782166	5.31
272.1376648	0.85
273.1605225	1.81
274.1038208	0.25
280.4446411	0.13
281.3512573	0.34
283.1824951	0.60
284.9926453	0.22
287.0824585	0.06
294.9547729	0.32
296.3175964	0.18
297.1169434	1.11
300.0797119	35.45
301.0895996	100.00
302.1293945	17.35
303.1682739	0.19
307.3422241	0.44
313.1324463	0.67
314.2859192	0.08
315.0841064	0.03
325.1652527	1.10
326.0432129	0.48
340.0755005	0.05
343.1447144	8.36
344.0397949	0.88
345.0256958	0.12
354.0953369	0.09
355.0848999	0.28
357.2539673	0.07
366.5712280	0.11
367.2617798	0.06
373.1760254	0.78
374.0703735	0.12
375.9509277	0.12
382.2872925	0.29
385.1033325	0.06
409.2384033	0.52
427.4027710	0.20
430.0336914	0.24
437.2564087	0.06
445.6028442	0.05
446.3002930	0.17
457.3572388	0.37
463.3552856	0.36
464.3587036	0.30
465.3549805	0.37
466.3602905	0.23
473.2976074	0.10
483.3393555	0.06
498.9059448	0.12
500.3538208	0.61
512.0679321	0.10
541.5884399	0.05
547.6996460	0.10
549.3949585	0.19
591.2893066	1.80
592.3281860	0.96
593.2778320	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.2183
Annotation	Excavatolide D
Peak:m/z	Relative Intensity
156.8839111	0.04
161.0064392	0.08
163.1062469	0.16
165.0722961	0.09
165.9814758	0.09
170.9024048	0.07
174.7185669	0.09
178.0241699	0.04
191.1587677	0.28
193.0702057	0.09
207.0637665	0.09
214.1768036	0.12
223.1163940	0.05
226.1388550	0.05
227.9244385	0.08
229.0836487	0.06
271.2198486	0.07
273.2316895	0.17
295.0567932	0.03
298.2157593	0.29
299.1967773	0.77
301.0698242	0.27
311.6774902	0.09
313.1508789	0.63
314.3017578	0.05
315.1661377	0.11
317.4680786	0.04
319.1503906	0.17
324.0736084	0.09
325.1699829	0.18
327.1749878	0.08
328.2812500	0.20
329.2879639	4.66
330.3144531	0.40
331.4779663	0.19
332.2714233	0.26
333.1389160	0.15
337.4433594	0.10
343.2508545	4.97
344.1481934	0.08
346.4149170	0.57
347.2830200	6.66
348.2848511	0.18
349.3294067	0.07
358.4354248	0.31
359.3779907	0.45
361.2437744	100.00
362.1119385	0.74
375.2894897	0.05
376.6397095	0.08
378.0710449	0.04
379.2583008	0.09
387.0688477	0.07
389.0872803	0.26
402.2010498	0.07
403.3919067	0.15
416.7990112	0.04
419.3623047	0.04
421.2957153	0.28
426.7369995	0.07
431.1950684	0.07
432.4382324	0.02
433.2692261	0.03
434.5540771	0.10
435.3797607	0.06
436.9013062	0.12
444.0325317	0.03
445.5061035	0.20
449.1751099	0.03
461.3694458	0.15
463.2391357	0.15
471.3108521	0.06
473.2168579	0.04
477.1958008	0.73
479.0744019	0.06
480.1163940	0.17
485.6155396	0.09
487.2826538	0.24
493.3993530	2.37
494.2813721	0.32
503.3570557	0.19
504.1257935	0.23
505.4451904	1.84
506.6963501	0.09
508.3657837	0.83
515.6333008	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	626.9064
Annotation	Unknow
Peak:m/z	Relative Intensity
182.7917023	0.06
208.7431183	0.11
220.9624329	1.97
222.3928528	0.17
262.2636414	0.10
266.9174805	0.08
277.3118286	0.13
286.3264160	0.09
288.3513794	0.10
304.0744324	0.14
307.2356262	0.06
312.0325317	0.04
341.3407593	0.07
344.9026489	0.18
354.9465332	0.79
374.8408203	0.26
376.1086426	0.40
378.0327759	0.04
382.1868896	0.04
383.0866089	0.03
389.1340942	0.09
394.9375610	0.19
397.1782837	0.06
399.0661011	0.27
403.1497803	1.02
404.2434082	0.04
416.1108398	0.09
419.9468384	0.24
421.8696289	0.05
422.9893188	0.14
434.3265991	0.26
435.8209839	0.09
438.3026733	0.14
441.2541504	0.43
442.8760986	100.00
443.5266724	0.63
444.2805786	0.10
456.8567505	0.17
458.0078125	0.06
465.0510254	0.14
467.2218628	0.19
469.3127441	0.23
473.4067993	0.11
477.2463379	0.06
484.8204346	0.25
495.2192993	0.31
498.3815308	0.26
502.3034668	0.12
505.2736206	0.09
506.1913452	0.07
509.3543701	0.31
510.9818726	0.51
512.6279907	0.17
519.3986206	0.14
528.3463745	0.20
534.9757080	0.09
538.9575806	0.45
557.2045288	0.06
567.0346069	0.07
579.1997681	0.16
583.1382446	1.18
587.4630737	0.13
606.5242920	0.08
608.1348877	0.14
609.3768921	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	330.0672
Annotation	Unknow
Peak:m/z	Relative Intensity
96.8769760	0.05
126.8698807	0.84
145.0145874	0.31
150.8070068	0.17
211.3741760	0.04
212.2582092	0.03
229.1769409	0.04
241.1887817	0.04
258.9210815	1.68
266.9036255	0.03
276.9270630	46.68
277.5895386	0.07
278.5509644	0.05
285.9279175	0.11
290.2673340	0.03
291.5007324	0.09
292.8368225	0.33
294.8738403	100.00
295.5928345	0.23
312.0079651	1.62
313.0921326	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	887.2974
Annotation	Rhamnocitrin 3-glucoside-4'-(3''-dihydrophaseoylglucoside)
Peak:m/z	Relative Intensity
264.9512939	0.06
277.3525696	0.05
289.0700684	0.08
297.0595703	0.08
303.1271362	0.10
307.0156555	0.06
313.4636841	0.06
325.1235962	0.04
327.1604614	0.09
337.1415405	0.12
338.9917908	0.14
343.2160339	3.45
344.3926086	0.52
349.2437134	0.17
352.2731323	0.16
353.2791443	0.06
354.0754395	0.09
357.2837524	3.74
358.1845703	0.87
367.1217041	19.15
368.1986084	2.77
385.0418091	0.25
399.3937378	0.40
421.2662354	0.14
487.1501465	1.26
488.3476562	0.52
501.0907593	0.17
502.3223267	0.21
505.3764648	0.35
506.2256470	0.12
519.2741699	0.07
552.0347290	0.17
571.7670288	0.16
576.2180786	0.11
583.9927368	0.74
611.3020630	0.14
649.4701538	0.24
675.3511963	0.13
678.6566162	0.16
681.5133057	0.05
695.0414429	0.27
716.2820435	0.17
725.2966309	100.00
726.3219604	45.25
737.5805054	0.05
757.0255737	0.07
767.2290649	0.60
768.0917969	0.47
771.7695312	0.21
783.3909912	0.21
789.0916138	0.11
797.1058350	0.12
807.2937622	0.35
814.6301270	0.13
823.1720581	0.17
827.4432983	0.03
839.3820190	0.07
843.7134399	0.07
858.6516113	0.05
864.4490356	0.09
869.3725586	0.44
872.2352905	0.06
873.6673584	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	497.1363
Annotation	Unknow
Peak:m/z	Relative Intensity
157.1907959	0.11
159.1049500	0.05
161.8397522	0.05
169.1195679	0.03
171.0400848	0.05
181.0894012	0.05
183.0433960	0.13
184.9253845	0.03
189.0357208	0.02
190.0446472	0.04
203.1926575	0.14
208.4755249	0.07
211.9119720	0.04
212.8712158	0.13
215.1575317	0.71
217.0166626	0.15
217.7571259	0.03
219.1071472	0.07
226.0693970	0.05
236.0249481	0.07
243.2048645	0.40
244.1038666	0.03
245.0493011	0.14
251.3327637	0.03
253.0735168	0.03
256.1568604	0.09
258.0663757	1.24
259.2004700	0.26
260.2365112	0.03
264.1870422	0.20
265.4779053	0.04
266.9105530	0.08
275.3044739	0.11
276.2050171	0.15
277.2315063	4.30
286.4174500	0.03
292.2190247	0.03
296.1996460	0.10
298.2744751	0.08
300.0232849	0.06
307.5581055	0.28
308.3583984	0.75
309.3089905	0.13
312.5581665	0.09
313.1614380	0.09
315.2112732	0.06
316.3760376	0.03
325.8294373	0.13
329.3372192	0.08
331.1939697	0.04
332.1661377	0.02
333.2198486	0.20
335.2779846	1.29
339.5984192	0.20
340.5423279	0.17
341.3315430	0.13
341.9515076	0.10
345.2473145	0.10
347.2907104	0.10
349.1473389	1.95
350.0694885	0.07
351.3032532	0.20
353.3672485	0.04
356.0056152	0.11
358.2305908	0.25
359.4439087	0.09
375.5775757	0.11
376.6190491	0.27
377.3098145	0.07
382.3340759	0.35
384.2282715	0.08
385.7221069	0.24
389.4319763	0.16
390.9379578	1.44
393.2753296	3.65
394.2577209	0.04
399.7998352	0.13
408.2637634	0.05
409.1385803	0.05
411.2170715	6.40
415.2032471	0.03
418.1298218	0.11
419.0994568	0.18
421.2694092	0.10
423.4450989	0.75
432.1948547	0.09
433.7675476	0.26
435.2812500	0.62
436.0484314	0.11
437.4123840	0.18
439.0263977	0.05
440.6691589	0.05
442.7272034	0.22
448.1770020	0.25
449.7522278	0.05
450.4905701	0.06
453.2193909	100.00
453.8460388	0.30
455.2766113	0.06
456.4583435	0.08
460.0181580	0.09
461.1827393	0.07
467.0751343	0.12
468.0482483	0.06
476.9487915	0.10
478.9919128	2.59
479.8582153	0.34
480.9241333	0.04
484.2947693	0.22
485.5688171	0.06
487.7258911	0.47
488.8670044	0.20
503.7768250	0.03
508.5243835	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	588.151
Annotation	Unknow
Peak:m/z	Relative Intensity
170.8168335	0.30
176.1084290	0.15
194.0620117	0.36
201.1081543	0.10
204.0839539	0.35
220.0883179	0.25
228.2081299	0.15
231.3242035	0.64
238.0990143	0.62
242.7666473	0.11
244.1332397	0.91
262.0472717	0.13
284.0715332	0.13
297.1724854	3.80
301.9767456	0.56
303.1394043	0.19
304.1987305	0.26
311.7997437	0.23
321.1200562	0.95
338.2805786	0.12
339.2302856	3.47
339.9264526	0.27
342.0625000	0.84
345.1025391	0.53
356.0686646	1.64
359.2941895	0.34
360.2703247	0.27
363.1229248	4.47
369.1993408	0.71
373.2294312	0.39
375.4008179	0.44
377.4363403	0.15
387.1970825	2.86
389.2416992	0.21
398.3242798	0.16
405.1543579	11.15
408.3273315	0.36
412.9550171	0.57
422.0200195	0.26
423.1744995	17.47
426.1416016	16.82
431.2669678	0.33
438.0526123	0.34
441.1777344	74.87
444.4474487	0.12
449.6054688	0.90
450.2918701	0.13
453.1728516	0.27
455.2117920	0.14
459.1059570	41.54
466.9995117	2.15
468.1692505	12.94
469.8637085	0.07
472.0732422	1.06
477.0695190	1.47
478.4604492	0.19
488.0117798	0.31
490.1851196	12.77
495.0907593	2.96
500.8505249	0.31
512.2505493	1.08
513.2637329	5.49
516.3161011	5.44
521.9172974	0.33
525.2929077	0.15
528.2421875	0.75
534.2213745	10.21
535.4297485	0.35
545.9129028	0.35
548.2643433	0.26
552.2292480	74.31
558.0037231	2.37
570.2414551	100.00
571.1424561	0.43
579.5306396	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	659.1707
Annotation	Unknow
Peak:m/z	Relative Intensity
189.0893097	0.03
191.1007385	3.90
271.2637634	0.02
275.2779846	0.02
286.3084412	0.04
305.1719971	1.65
309.2582092	0.04
311.9711609	0.02
320.1951904	0.01
325.6539917	0.02
327.4033203	0.06
351.0505981	0.02
353.1193848	100.00
353.9660645	0.03
356.4201660	0.01
374.7518311	0.01
385.3233643	0.13
407.0806885	0.05
409.2646484	0.06
424.8176880	0.06
437.2045898	1.15
448.7644043	0.02
466.7471924	0.04
478.8603516	0.02
487.3167725	0.05
492.3424072	0.03
497.2088623	0.19
498.2106934	0.05
503.3085938	0.01
511.1588745	0.01
526.1509399	0.04
529.6165161	0.03
538.9526978	0.05
544.3795776	0.04
555.3044434	0.02
557.5841064	0.02
568.1260376	0.02
568.8799438	0.03
597.3523560	0.02
599.1149292	0.03
600.2814331	0.09
612.2379150	0.17
613.3501587	0.09
614.4434204	0.06
615.4705811	0.07
624.5078735	0.07
626.6893921	0.03
628.1307373	0.02
628.9900513	0.02
629.6655273	0.05
636.9927979	0.03
640.5042725	0.57
641.3797607	0.49
642.5737305	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0855
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
80.18972778	0.11
80.97612	0.09
83.82307434	0.15
95.0605011	0.04
98.25335693	0.08
102.913559	0.08
104.0233002	0.20
105.1026154	0.10
118.84198	0.05
127.963974	0.08
129.0000916	0.74
130.0307617	0.15
133.04599	0.19
136.0307007	0.11
145.2059174	0.05
146.1888885	0.05
146.9732666	0.34
149.0909271	0.27
151.073349	9.20
152.0953522	2.41
152.8746643	0.20
164.9851685	0.18
167.3271332	0.55
168.1072235	0.09
169.2292023	0.56
172.2311707	0.33
175.068222	0.11
176.1908722	0.25
177.2152252	0.40
178.9812469	0.22
181.1507263	0.09
182.0304565	0.19
182.878006	0.33
184.2682953	0.23
185.2880707	0.41
190.9993744	0.08
192.0805817	0.07
194.1095428	0.18
195.0658875	0.28
196.3209076	0.09
197.0229034	0.99
198.0514069	1.20
206.0795593	2.03
208.3589325	0.35
209.0100098	0.48
210.1925812	0.08
211.1104889	0.60
212.2276459	0.13
217.2761993	0.88
218.2507477	0.91
219.1732941	0.51
224.0566559	0.34
225.1833649	1.03
226.0441284	0.77
235.3110504	3.75
236.1744995	4.80
238.1760406	1.16
239.1525421	1.20
251.2841187	0.08
253.0878448	100.00
254.1988373	3.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	623.2867
Annotation	Swietenin F
Peak:m/z	Relative Intensity
207.1360779	0.04
208.7196503	0.19
217.9012451	0.05
226.8817749	0.05
231.1852722	0.07
248.3341675	0.26
250.8648682	0.05
255.5034485	0.09
259.9203491	0.03
265.2872925	0.10
267.2632446	0.11
272.9184875	0.04
292.0676270	0.08
296.1690674	0.05
307.0764771	0.12
309.5239258	0.12
313.1969604	0.09
323.2250977	0.06
329.1404724	0.09
333.4556274	0.11
353.3789673	0.10
359.3467407	0.07
360.5159912	0.11
380.3949585	0.32
382.8608398	0.12
389.2253418	0.11
396.3986816	0.04
397.2421265	0.11
401.2600708	0.04
405.0722046	0.09
407.4341431	0.30
408.5849609	0.06
415.3843384	0.11
417.4487915	0.17
423.2103271	0.07
433.5512085	0.17
435.0803833	0.20
438.4337769	0.02
440.2058105	0.09
441.6031494	0.13
443.5029297	0.05
444.4108276	0.13
445.3995361	0.04
447.2852173	0.18
448.3663330	1.03
449.2994995	0.35
455.1621094	0.11
458.3969727	0.07
459.1482544	0.07
460.0465088	0.10
466.1079712	0.16
467.5986938	0.06
471.4871826	0.10
473.4899902	0.14
475.4877930	0.14
477.3669434	0.17
480.3794556	0.33
482.5343628	0.29
484.1661987	0.12
486.3018799	0.12
488.2277222	0.15
489.4216309	0.06
493.5515137	0.23
494.4727173	0.15
495.3562622	0.05
499.6268311	0.11
501.0130005	0.06
503.4563599	0.13
504.3265991	0.17
505.5097046	0.18
506.5397339	0.31
507.2540283	0.22
508.3088379	0.22
509.5899658	0.04
515.2355957	0.10
517.4193726	0.35
518.4203491	0.96
519.4535522	0.67
520.4209595	0.13
521.3937988	0.18
522.4714355	0.25
525.2780151	0.09
530.5370483	0.11
532.0441895	0.28
533.3562012	9.17
534.3322144	3.38
535.3837891	2.38
536.3142090	0.88
537.2970581	0.44
541.2103271	0.20
542.2699585	0.05
544.7683105	0.57
545.4767456	1.96
546.2705078	0.22
547.6780396	0.05
548.7061768	0.11
549.4372559	0.24
553.3934937	0.21
555.4705811	0.28
559.0731812	0.48
560.1928711	0.04
561.5470581	1.29
562.3527222	3.32
563.3649292	14.58
564.4085083	3.10
565.5404663	0.19
567.0034790	0.07
568.2592163	0.10
573.4039307	3.43
574.3753052	1.12
576.3385620	0.11
577.4421997	1.96
578.2527466	0.39
579.5673218	0.24
581.0201416	0.16
587.1372681	0.26
587.8009644	0.25
588.5239258	0.17
590.3313599	0.81
591.3838501	4.38
592.7530518	1.57
593.6091919	1.97
594.3809814	2.53
595.3347778	1.17
596.3844604	0.23
605.3580322	100.00
606.3798218	26.22
607.3515015	0.15
608.3187866	0.34
620.7265015	0.08
622.5499878	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	991.4687
Annotation	Unknow
Peak:m/z	Relative Intensity
279.9237061	0.17
296.1662903	0.23
305.8896484	0.28
307.0839233	0.32
323.0785522	0.11
324.1050720	0.18
343.2053223	0.50
351.1301880	0.63
351.9729614	0.41
353.0870667	0.72
358.4859009	0.29
359.3376770	0.17
369.2049561	0.94
370.2615356	0.57
371.4264221	0.15
376.9716492	0.22
396.0617065	0.44
400.1867676	0.53
413.4656372	0.13
414.7088013	0.11
422.3150024	0.43
423.3083496	0.42
430.4335327	0.42
440.2699280	2.49
440.9871826	0.20
441.6606140	0.25
442.5855713	0.67
447.3328247	6.59
448.3303528	0.25
449.3027039	0.21
450.2763367	0.94
452.2761536	0.58
453.2016602	0.57
454.3640442	0.50
457.1605530	0.68
468.1380615	0.39
472.4689331	0.24
477.8942566	0.33
481.1848145	0.53
482.2944336	0.12
487.8810120	0.25
494.9768372	0.50
504.9685974	0.28
511.4254150	0.27
513.3261108	0.56
514.3776245	0.11
518.3829346	2.30
519.1716919	0.38
521.3063354	0.66
525.1951904	1.01
526.2945557	0.56
534.0017090	0.15
539.3746338	3.26
540.4617920	1.55
541.6048584	0.36
544.4512939	0.60
545.8919678	0.54
551.2928467	0.42
552.2224121	0.39
560.5195312	0.34
564.7389526	0.45
569.4564209	4.15
570.5083008	0.78
571.4561768	0.50
572.0718994	0.37
578.3483887	0.17
579.6950684	0.34
582.7482300	0.44
584.3144531	0.30
592.7747803	0.48
600.4544678	0.44
604.4193115	1.04
610.3790283	4.82
611.4166260	2.50
612.3763428	0.83
614.4617310	0.49
621.9061279	0.87
622.6837769	0.77
623.6494141	0.26
624.6745605	0.67
629.4801025	0.42
630.2683105	0.45
631.4468994	1.30
632.2470703	1.14
636.1433716	0.47
637.4317017	0.27
638.2930908	0.26
640.3681641	8.33
641.3995972	0.94
642.4122314	1.99
643.4345093	0.17
647.4576416	4.45
648.2738037	0.58
650.2600098	2.29
651.3095703	0.46
655.4603271	1.35
663.7298584	0.46
664.6250610	0.32
666.3098145	0.68
668.0573730	0.33
671.7576294	0.31
673.2130127	0.21
681.3444824	5.65
682.3292236	1.26
685.6183472	0.25
686.5241699	0.74
687.4006348	0.20
693.2641602	0.21
694.4083252	0.40
695.5729980	0.34
711.4644165	4.81
712.3912964	1.70
713.7294312	1.04
721.3562012	1.91
722.2685547	1.29
723.3972168	0.38
726.1768188	0.80
734.7008057	0.63
737.0698242	0.11
739.3781128	25.13
740.3929443	8.61
741.5471191	2.59
743.3925781	0.28
744.5466309	0.31
752.3806763	4.78
753.5532837	0.79
759.5473633	2.46
760.2867432	0.84
765.2738037	1.94
774.4464111	0.25
776.4377441	7.28
777.4642334	1.15
780.4305420	0.22
782.5133057	2.56
783.3200684	4.86
784.3326416	1.64
786.4152832	1.04
789.4272461	1.15
792.4771729	4.31
793.1011963	0.38
793.9018555	0.50
794.5560303	0.14
797.3605957	0.93
801.8146973	0.73
807.4567871	0.33
810.4035645	47.00
811.3229980	15.03
812.2420654	5.76
821.6837158	0.83
836.6674805	0.66
837.4835205	1.04
841.5478516	0.74
845.4549561	0.20
847.3011475	5.23
848.0321045	1.35
848.9274902	0.34
849.5839844	0.27
853.0527344	1.68
854.4757080	3.59
855.5581055	1.65
856.4410400	0.90
857.6301270	0.84
858.8583984	0.44
859.4764404	0.27
861.3131104	0.16
863.4758301	3.01
864.2525635	3.52
871.8270264	0.81
875.3937988	5.36
876.4259033	0.59
877.3652344	0.29
879.2471924	0.12
881.4244385	77.79
882.4614258	26.07
883.3007812	8.33
884.0036621	1.04
884.6210938	0.17
889.6518555	7.52
890.9520264	8.47
891.7943115	61.74
892.5811768	13.89
893.9584961	0.73
894.8483887	0.24
896.5534668	1.30
898.5604248	0.80
900.6051025	0.07
901.7365723	0.32
907.2807617	0.60
908.5498047	1.05
911.4903564	1.11
916.4902344	0.32
918.8065186	3.52
925.5419922	1.85
928.9782715	0.45
933.9544678	0.18
938.1950684	3.82
939.1898193	4.47
947.2341309	42.12
948.1716309	9.01
949.5532227	0.22
951.8261719	0.65
952.5905762	0.68
957.2304688	0.24
959.2790527	0.18
960.4877930	0.72
965.3569336	0.31
967.4246826	0.31
968.6186523	2.02
969.6667480	1.11
971.2121582	0.40
973.3691406	0.23
974.3861084	6.34
975.0568848	0.83
978.5791016	0.63
995.5511475	0.18
1006.1403810	0.56
1012.6306150	5.10
1013.5877690	0.89
1014.6252440	1.53
1023.3415530	0.76
1024.7424320	0.72
1030.5737300	0.60
1040.7529300	0.31
1046.9296880	0.55
1047.9016110	0.92
1050.5449220	0.90
1066.4410400	1.89
1067.7792970	0.89
1069.5646970	0.25
1083.5814210	6.15
1084.5241700	7.42
1085.4711910	3.46
1086.3654790	1.18
1089.3842770	0.11
1097.7299800	0.20
1100.2370610	0.34
1101.5014650	80.28
1102.5280760	38.13
1103.5290530	9.44
1107.4040530	2.45
1111.6333010	0.76
1112.5683590	0.51
1117.4898680	0.72
1121.0902100	0.94
1126.9528810	0.17
1136.6895750	0.55
1138.8410640	0.45
1139.5059810	0.50
1153.1348880	0.18
1153.8315430	1.40
1154.9163820	3.27
1155.8150630	2.99
1156.8857420	2.02
1168.5747070	0.48
1169.7421880	0.11
1171.4920650	0.76
1172.5698240	53.89
1173.6082760	29.43
1174.6892090	6.47
1178.6643070	0.55
1189.6373290	0.15
1206.6953120	3.58
1207.7760010	4.21
1209.2347410	0.55
1213.5737300	0.17
1225.7883300	0.56
1226.7554930	1.76
1227.5815430	0.69
1240.8306880	0.25
1243.6080320	32.81
1244.6496580	23.28
1245.6237790	4.95
1253.7944340	0.24
1254.9902340	0.63
1264.5954590	0.77
1265.8352050	0.66
1280.6893310	0.36
1284.4984130	1.67
1285.4456790	0.11
1288.3192140	0.59
1290.3599850	0.38
1295.3864750	0.39
1296.5610350	0.93
1297.6512450	0.30
1298.6490480	0.27
1310.5615230	0.36
1311.5778810	0.54
1325.1419680	1.23
1326.1678470	1.05
1335.6243900	9.56
1336.6881100	3.83
1340.0401610	0.40
1342.6115720	6.57
1343.5963130	7.19
1344.4783940	1.78
1345.1169430	0.14
1348.9168700	0.29
1354.7623290	0.31
1355.6934810	1.17
1377.0583500	0.66
1394.6269530	0.26
1395.8345950	0.15
1396.8192140	0.28
1397.8311770	0.10
1411.9067380	0.32
1413.8322750	3.07
1414.8321530	3.94
1416.0463870	0.68
1426.4666750	2.20
1427.3472900	0.33
1428.7352290	0.14
1438.0887450	0.23
1453.5789790	1.13
1464.0611570	1.76
1464.7614750	4.50
1465.6849370	1.39
1466.7520750	0.67
1468.8380130	0.72
1489.1485600	0.60
1508.0628660	0.48
1508.7008060	0.61
1517.8138430	0.31
1524.9201660	1.42
1527.6601560	0.52
1535.6968990	7.48
1536.5511470	2.77
1537.6531980	2.44
1542.5772710	2.91
1543.5679930	1.41
1544.7073970	1.35
1580.0118410	0.19
1595.8118900	0.55
1599.4035640	0.29
1603.8460690	0.20
1609.6373290	0.31
1613.6173100	0.33
1615.3922120	0.32
1663.1475830	0.19
1663.8293460	2.26
1664.9276120	3.68
1665.7521970	0.57
1724.9260250	1.38
1757.4080810	0.17
1825.9290770	0.27
1881.3039550	9.22
1884.7028810	0.14
1888.6903080	0.37
1900.6488040	0.89
1903.2447510	0.43
1904.1667480	0.69
1911.8065190	0.29
1912.6784670	0.26
1918.0623780	0.33
1918.9171140	0.48
1925.1706540	16.21
1930.7590330	1.65
1941.3161620	0.31
1945.1580810	17.43
1950.8499760	16.60
1952.7701420	75.96
1955.6545410	0.20
1960.5511470	0.79
1963.6737060	1.35
1968.3820800	0.87
1973.4865720	0.71
1976.9791260	3.58
1978.0261230	0.11
1980.1021730	0.14
1981.1961670	1.55
1984.3807370	4.03
1985.2235110	22.46
1986.4660640	0.83
1989.5208740	0.16
1990.5344240	100.00
1991.5701900	3.73
1993.4346920	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1173.2468
Annotation	Unknow
Peak:m/z	Relative Intensity
398.0135193	0.08
684.1128540	0.22
867.6394043	0.23
1009.8591310	0.10
1292.9658200	0.81
1295.8507080	0.43
1340.5583500	0.17
1343.3996580	0.52
1482.4920650	0.29
1545.7755130	0.08
1567.3138430	0.12
1597.0737300	0.48
1686.1136470	0.53
1734.5860600	0.13
1744.9978030	21.21
1781.8651120	0.91
1783.0158690	0.22
1787.1936040	0.95
1790.3762210	0.09
1810.4945070	0.60
1812.5787350	2.58
1815.9981690	1.02
1823.0925290	0.19
1824.3094480	0.68
1831.7521970	0.30
1832.9344480	0.34
1843.2948000	0.11
1854.1312260	0.18
1854.7513430	0.39
1861.3692630	0.18
1863.7193600	20.66
1865.3143310	0.17
1871.6838380	2.89
1876.2185060	0.74
1877.8513180	0.20
1880.3156740	0.39
1884.4398190	0.19
1888.3928220	12.52
1889.2423100	38.06
1890.8302000	9.33
1893.7482910	0.63
1898.1331790	0.32
1899.8883060	0.78
1901.7844240	8.52
1905.0440670	0.43
1906.0448000	0.10
1906.7027590	0.44
1907.8211670	2.38
1909.5159910	0.11
1912.8121340	27.91
1914.1013180	3.41
1915.6657710	1.53
1916.6116940	7.37
1917.7604980	0.78
1918.9528810	0.46
1920.1862790	0.24
1922.1649170	5.95
1923.7889400	0.64
1924.7819820	0.13
1926.1729740	25.10
1927.9554440	0.44
1929.4984130	0.26
1930.6345210	0.20
1931.9068600	14.47
1932.8726810	0.33
1937.1555180	2.54
1939.1116940	1.36
1943.4064940	2.68
1945.4484860	0.81
1947.1458740	16.18
1948.1813960	21.09
1949.0364990	0.47
1950.6004640	3.68
1954.4766850	0.95
1955.5838620	25.09
1956.8040770	0.17
1960.9405520	3.05
1962.2232670	15.91
1963.4479980	0.87
1965.5552980	65.56
1966.5208740	0.79
1967.3537600	0.18
1968.0550540	2.84
1969.7415770	47.08
1970.4283450	53.07
1971.5435790	0.98
1972.5006100	54.73
1973.8297120	0.17
1974.7313230	12.81
1976.0872800	5.09
1976.8048100	0.10
1979.1617430	1.32
1980.4886470	4.20
1981.6182860	17.79
1982.8156740	1.10
1983.4606930	0.64
1985.4343260	0.75
1986.3394780	0.20
1989.4592290	9.26
1990.4566650	0.32
1992.1107180	0.08
1992.8077390	0.12
1996.8259280	8.66
1998.0382080	100.00
1998.6473390	98.45
1999.7686770	2.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	794.3503
Annotation	Unknow
Peak:m/z	Relative Intensity
241.2861328	0.43
356.0976562	0.57
359.1018677	0.49
369.2739868	0.28
476.6975708	1.35
515.9897461	1.82
595.4996948	0.81
598.1477661	1.38
650.0138550	0.89
665.1947632	0.94
673.9140625	1.10
692.5494995	3.40
704.3670654	1.07
705.2813110	0.36
707.9972534	2.02
726.4859009	1.19
735.6451416	3.58
737.6282349	1.17
740.0991821	1.35
754.1520996	3.51
757.4732666	1.30
758.6218262	0.48
767.5974731	7.89
773.3601685	16.10
774.1721191	6.22
775.4628296	0.84
776.5869751	2.55
779.0691528	0.61
784.3224487	0.85
814.4357910	0.46
820.4664917	0.69
821.1411743	0.97
843.0032349	0.88
844.1558228	1.51
853.1425171	0.92
875.9092407	1.83
884.7711792	3.91
889.1575317	1.38
905.7172852	0.31
910.6333618	2.23
988.3053589	2.62
997.6359863	0.54
1018.4992680	1.73
1019.4311520	0.84
1052.9401860	3.35
1057.9322510	0.33
1064.3486330	0.82
1072.3291020	3.09
1096.1068120	0.90
1101.7392580	0.84
1104.1217040	1.45
1105.5507810	0.68
1147.7724610	0.72
1192.7977290	2.06
1217.3605960	0.54
1242.7053220	0.38
1293.6451420	0.38
1593.7103270	0.97
1780.7672120	2.81
1781.8815920	0.48
1793.1256100	0.54
1832.6921390	0.28
1837.0738530	1.26
1852.6901860	0.92
1859.0333250	0.96
1863.0684810	0.36
1872.6400150	17.02
1886.0031740	0.31
1891.7755130	0.51
1894.2142330	3.21
1907.2360840	0.38
1918.0754390	0.69
1919.1818850	0.62
1933.5030520	2.03
1939.2413330	0.84
1944.4925540	0.94
1947.0983890	16.93
1951.0914310	8.36
1955.6789550	2.14
1956.4313960	6.05
1960.3287350	0.59
1961.3870850	26.56
1966.1136470	0.20
1970.9891360	14.52
1972.1588130	1.14
1977.4787600	100.00
1979.5954590	0.64
1991.3980710	0.33
1994.6008300	1.70
1996.2559810	0.28
1997.7191160	10.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.1331
Annotation	5'-O-beta-D-Glucosylpyridoxine
Peak:m/z	Relative Intensity
98.7825470	0.09
105.9971542	0.38
107.9927597	1.00
134.0728607	0.15
135.9328308	1.38
152.0780182	3.78
170.0416260	7.87
213.1389771	0.32
233.9062500	0.15
240.1299438	0.13
245.3322754	0.13
257.3308105	0.09
258.1264343	0.12
275.1958923	0.21
286.2962036	0.09
287.8338318	0.27
314.2326050	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.1
Annotation	Unknow
Peak:m/z	Relative Intensity
118.8691101	0.06
120.6803894	0.09
131.1502686	0.05
143.0828552	0.44
148.9939423	0.13
150.1917877	0.06
161.0852051	0.37
179.0392151	2.80
179.9808960	0.15
181.0687103	0.17
196.1176300	0.11
217.3135681	0.10
221.0548706	0.65
223.4182739	0.05
232.9661865	0.12
263.2226868	0.10
264.3776245	0.09
280.8932495	1.62
281.6999207	0.10
283.3744812	0.08
288.2676086	0.05
317.3099976	0.07
319.1122437	0.06
323.0917969	0.30
324.9085999	0.14
339.3668823	0.05
340.9359741	1.39
343.1687622	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	323.0835
Annotation	Unknow
Peak:m/z	Relative Intensity
99.8705597	0.39
100.8183746	0.06
111.7513962	0.55
128.7912750	0.28
130.0905914	0.05
131.0455780	0.13
140.0497437	0.08
141.1639099	0.10
144.0392456	0.11
148.9116821	0.08
157.0942383	0.56
158.0252075	1.54
160.1720123	0.04
162.1384277	0.16
163.1633911	0.11
173.3760071	0.05
175.0537109	0.38
176.0251465	0.96
177.0768585	0.20
179.0682373	0.49
181.0633850	0.20
183.1100922	0.15
184.0773010	0.58
190.1300659	0.31
191.2385559	0.11
192.9189911	0.79
194.1294098	0.56
197.3009186	0.08
198.0485840	0.06
201.2016296	2.26
202.1078186	0.27
207.2023621	0.13
209.3528442	0.14
210.0402222	0.05
217.2565308	0.06
219.4580688	0.14
224.1945190	0.70
225.3066101	1.29
226.2551270	1.37
227.2923889	0.06
232.9663696	0.05
234.1414490	0.15
239.2696228	0.14
242.1325684	100.00
243.1524963	94.70
243.7573242	0.19
245.1801453	0.63
246.0697632	0.18
248.2200928	0.10
253.0444031	0.05
258.4564209	0.11
259.0731201	0.11
259.8090210	0.12
261.0227051	0.05
262.2663269	0.58
263.1605530	1.47
263.9844055	0.88
270.0126038	0.13
273.1701965	0.16
275.2743530	0.50
276.3447266	0.15
277.2465515	0.74
278.1302490	0.19
281.1657410	1.00
285.6716919	0.45
287.9671021	2.57
289.1864319	0.21
291.8538208	0.09
293.0957947	0.06
300.2702026	0.29
304.3475952	0.30
305.1090393	3.34
306.1092834	4.67
313.5260010	0.85
314.3756409	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	464.1041
Annotation	Unknow
Peak:m/z	Relative Intensity
150.0728455	0.41
150.8450623	0.06
151.9379883	2.02
153.4696503	0.08
155.9477234	0.31
165.9082031	0.23
170.0640564	2.31
171.1621399	0.19
177.0140076	0.21
184.0696106	0.16
197.0732727	0.21
197.8259583	0.16
206.3902893	0.14
214.2858887	0.18
217.2755127	0.67
238.4241028	0.36
245.1673584	0.16
258.9277649	0.49
270.0666809	0.15
276.8961182	0.06
278.1638184	0.17
281.3150024	0.09
283.2178040	0.35
308.4327393	0.53
316.0997925	0.13
332.0386658	0.25
332.9928284	0.20
339.0974121	0.41
344.0480042	0.42
374.6742859	0.06
376.8440247	0.40
382.8611755	0.15
400.8092957	0.13
410.1000366	0.56
417.8158875	0.63
423.1507263	1.67
427.0898743	0.14
428.1698608	6.16
432.6809692	0.30
446.1628113	100.00
447.2815247	1.12
453.8359680	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.2648
Annotation	Unknow
Peak:m/z	Relative Intensity
125.1488419	0.10
128.7965851	0.05
130.9777527	0.22
143.0297394	0.62
144.0389709	0.16
152.9211121	0.28
161.0403137	0.19
162.3008728	0.15
166.8975830	0.11
170.9384460	0.07
179.0617371	0.63
180.2284241	0.05
181.8627930	0.06
200.7854767	0.11
208.8048248	0.09
215.3556366	0.07
223.2822723	2.04
224.1395264	0.06
227.9584503	0.09
237.2942810	0.26
238.3100891	0.06
247.3110352	0.06
249.0816650	0.07
251.2524109	3.06
252.3013000	1.17
253.3355713	0.71
254.3475647	0.14
265.2976990	2.61
266.4107361	1.00
267.3327026	0.21
269.2337036	100.00
270.3038025	21.23
272.2648010	0.14
281.3787231	0.16
283.2903137	0.11
284.0565491	0.07
284.9954834	0.32
293.2399902	0.14
294.0683594	0.04
295.5552673	0.12
308.6265869	0.05
311.3275146	6.31
312.2133789	0.78
323.2696838	0.56
324.4467773	0.58
326.3645935	0.07
328.1198120	0.12
329.2084961	0.16
340.9931030	0.61
342.0202332	0.10
343.2082520	0.11
344.2701111	0.05
345.2978516	0.05
346.1134338	0.11
357.8897705	0.05
360.1503906	0.10
368.5376892	0.03
370.3905029	0.08
372.1467590	0.12
378.0000000	0.06
385.0948486	0.15
385.8250427	0.26
387.6453247	0.11
388.2509155	0.19
390.5116882	0.17
394.0909424	0.16
396.1831360	0.21
397.4727173	0.06
399.0160828	0.14
405.3955078	0.08
413.1958923	0.50
414.2302246	0.66
415.2830505	0.33
417.3251038	0.07
425.0060425	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2781
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
140.0278473	0.13
152.9404907	0.22
170.8012390	0.02
196.0426483	2.15
214.1094055	1.17
248.2909851	0.05
255.2458801	100.00
283.4630432	0.02
367.3099976	0.02
391.3882751	0.51
406.2093506	0.03
417.3014526	0.05
433.5884094	0.09
435.0496216	0.01
442.9165649	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
105.0589294	3.16
122.1875	1.74
125.0413971	0.51
131.9412384	0.58
135.0092773	1.80
148.8599243	0.64
156.8364716	0.94
160.7216949	4.23
171.9106903	1.08
179.2291718	0.70
181.3772736	0.88
182.7730255	1.37
184.9221039	1.11
189.3305206	1.92
191.1698608	1.23
194.8749237	3.97
198.1146393	1.13
205.0742798	0.57
206.7921906	8.44
207.4353638	2.58
208.2645721	2.61
209.1923065	22.63
211.0266571	3.61
214.9610138	13.03
222.1305847	5.19
223.0504456	17.23
224.4104462	1.13
233.0337524	10.04
235.0566254	1.25
251.0767975	100.00
252.0256805	16.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	229.1542
Annotation	Leucyl-Proline
Peak:m/z	Relative Intensity
69.9091949	2.53
86.0205383	2.95
112.7754211	0.63
115.9436340	100.00
120.6693878	0.20
125.2323761	0.16
131.7447052	0.16
142.8433380	0.32
147.0817108	0.25
151.1452179	0.60
169.0393829	1.13
170.1767120	0.57
183.2081604	0.78
187.2849579	0.36
194.5376129	0.22
197.2553864	0.33
200.9267426	0.32
210.2707367	0.25
211.1216736	4.42
212.0809784	5.20
229.1566925	0.23
233.5567780	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	429.1186
Annotation	5,7-Dihydroxy-6-methoxyisoflavone 7-O-rhamnoside
Peak:m/z	Relative Intensity
121.0128174	0.07
129.1939240	0.05
131.1109772	0.03
132.0838928	0.69
133.1260986	1.08
133.9886932	4.06
135.1062317	4.73
135.9279938	0.39
136.9822998	0.41
137.9451599	0.11
144.9484558	0.16
146.0044250	0.36
146.8911285	0.14
148.0490570	0.08
149.0564880	0.69
150.1752625	0.04
151.1754761	0.02
155.0040283	0.03
158.0988770	0.07
159.0917053	0.72
160.1908722	2.44
161.0169220	15.47
162.0268555	1.21
163.0850220	0.26
172.5263977	0.44
173.1469116	0.90
174.4288940	0.39
175.0959167	6.69
176.1076355	0.73
178.0027161	0.98
178.9856873	2.80
180.1197205	0.43
187.3510437	0.02
189.0861816	0.04
190.0223999	0.03
191.0325928	0.38
193.0373840	30.06
194.1056671	2.74
201.1582336	0.04
204.0333557	0.08
205.0869751	0.86
206.1380157	0.18
210.9492798	0.10
215.8596191	0.04
219.1655579	0.09
225.0418396	0.04
235.0785217	46.63
236.1422729	6.09
238.2078247	0.02
249.1504822	2.30
250.0862427	0.28
250.7095032	0.03
253.0558777	100.00
254.1641541	10.46
265.9334412	0.10
267.1570129	3.01
268.1571045	0.21
271.3800964	0.08
279.2824097	0.34
283.2806091	0.05
285.0077820	0.03
293.0995483	1.76
294.1428528	0.29
299.1842957	0.03
307.1194458	0.03
309.1843567	0.03
316.3709412	0.04
318.0385742	0.01
325.4936523	0.04
333.9423828	0.05
337.1651917	0.04
340.5320129	0.05
341.4043274	0.06
345.6873779	0.04
348.3703613	0.07
352.0406494	0.04
353.3647766	0.02
355.1446533	0.03
355.9645081	0.04
357.2959595	0.21
362.2023621	0.04
368.1539001	0.08
369.2517395	0.12
370.0293579	0.06
371.5783997	0.12
384.1129456	0.12
385.0303650	0.13
386.1401672	0.17
387.3177795	0.05
392.1822815	0.39
393.1672363	0.26
394.1258240	0.94
396.8612671	0.09
400.1366882	0.01
402.1150818	0.03
409.5124207	0.03
411.3195496	0.39
412.0196228	0.13
412.6694946	0.02
413.3401794	0.10
414.1919250	1.98
415.2742615	0.34
426.8170471	0.03
437.3637390	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.221
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
95.00177765	0.51
99.10977936	0.86
109.1138153	0.51
122.9501953	1.43
125.1753998	1.10
126.885437	1.56
133.2224579	0.24
138.8806763	2.56
141.2291565	2.48
149.1258545	2.55
151.143219	1.00
153.222229	0.82
155.0386963	2.05
163.3510437	1.80
169.3328857	0.35
171.0930176	1.56
177.1148682	1.09
183.0322723	1.11
185.0463562	1.07
193.0258789	1.71
195.1260681	4.98
197.1708374	1.02
206.0457764	1.19
209.2547607	0.92
211.1763916	2.42
213.0915527	0.41
224.9173889	0.45
233.4685669	2.87
235.0953369	0.44
237.1654053	3.64
239.0021057	2.39
241.2348328	2.19
247.2860107	1.00
251.2807007	1.57
253.1360168	6.97
255.1710815	1.87
256.9976807	3.25
265.0383606	2.46
267.2420044	2.84
269.1101074	2.53
275.2155762	28.81
283.0752563	0.72
290.6760254	1.65
293.2094727	100.00
293.9562073	0.36
310.4385986	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	617.108
Annotation	Unknow
Peak:m/z	Relative Intensity
175.0831146	0.07
176.2280579	0.03
180.1419830	0.04
181.7697601	0.02
183.0139923	0.06
185.0875244	0.09
187.1164703	0.02
189.7879639	0.02
191.1825104	0.08
193.1422272	0.59
195.2859497	0.06
197.2274170	0.05
199.2602844	0.40
200.3868408	0.02
205.0407410	0.02
207.2418823	0.04
208.0382996	0.22
209.1345062	0.02
210.1568909	0.02
213.4547577	0.14
217.2203674	0.02
220.2773895	0.04
224.9537964	0.15
226.1551666	0.07
227.2247620	0.11
228.3910370	0.03
229.2661438	0.03
231.1386871	0.62
231.8936768	0.06
237.1383972	1.34
238.1370087	0.11
239.1439209	0.02
241.2642975	1.76
242.1971741	0.30
243.0002747	0.02
247.2142334	0.04
251.2006836	0.02
252.0713806	0.03
254.2995148	0.18
255.2509155	0.06
256.3079834	0.09
259.1674194	1.44
260.1828003	0.24
261.2444458	0.08
262.1211548	0.03
263.0709534	0.13
265.1788635	0.04
269.3851013	0.11
271.2799683	2.54
273.1498108	10.93
274.2339783	1.01
275.1114197	0.16
278.2507629	0.02
279.5229187	0.10
281.3127136	0.01
285.5108032	0.02
288.1021118	0.06
297.1174927	0.08
303.1421509	12.13
304.3497314	1.94
305.1220703	19.48
306.2459106	2.35
307.2445679	7.15
308.3066406	0.84
310.4824219	0.03
311.3456421	0.05
312.3262634	0.04
317.0855103	0.04
320.2405396	0.04
325.2751465	0.03
329.2172241	0.14
330.4080811	0.04
332.2954712	0.03
334.0618896	0.34
335.0796509	0.26
337.1038208	42.91
338.2161255	4.20
339.2940674	0.02
343.1655273	0.05
345.1810303	0.17
346.9128418	0.15
352.1516724	0.03
357.3625488	0.06
359.1855469	0.09
361.3077393	0.09
365.1608887	0.04
371.2374268	0.13
373.2836914	0.03
375.0521851	0.01
378.4086914	0.02
379.3664551	0.04
389.0912476	0.07
390.2077026	0.03
391.2915039	0.03
395.3287354	0.05
397.2313843	0.15
399.1125488	0.02
403.1435547	0.21
404.3306885	0.04
406.8570557	0.01
413.0048218	0.04
417.3131714	0.10
418.2205811	0.02
420.8207397	0.14
421.4855347	0.04
423.2614136	0.04
428.2075195	0.02
429.2095947	0.03
431.0400391	0.09
432.3508911	0.03
434.3070068	0.03
437.1055908	1.69
438.1371460	0.33
439.3298950	0.10
440.3192139	0.06
444.9768066	0.02
451.0618896	0.05
455.1235352	100.00
456.1720581	12.84
461.0507202	0.02
467.2375488	0.03
468.2841187	0.02
473.4230957	0.03
476.2946167	0.02
479.2117920	0.39
480.1604004	0.05
481.2675171	0.02
483.0363159	0.03
485.4871216	0.01
487.1770630	0.03
490.9438477	0.02
493.2495728	0.06
495.4594727	0.10
497.0984497	3.39
498.1104736	0.21
501.3229980	0.03
505.2778931	0.04
509.1105347	0.16
510.3881226	0.10
515.1394043	0.05
516.9719849	0.02
519.1433716	0.03
521.2999878	0.03
527.0195923	2.17
528.1659546	0.38
531.8921509	0.06
533.2083130	0.05
536.1749268	0.08
537.5551758	0.04
539.2340088	0.55
540.2554321	0.14
545.3200073	0.03
546.0601196	0.06
547.0593262	0.27
548.1822510	0.06
549.3345947	0.02
551.2437134	0.50
552.4681396	0.19
553.5593262	0.08
557.1334839	36.70
558.1018677	3.99
563.3370361	0.22
565.2651367	0.07
566.2579346	0.02
569.1331177	0.03
571.6636353	0.05
574.2608032	0.01
575.1516724	0.22
576.2344360	0.05
581.1221924	0.64
582.3490601	0.11
583.2219238	0.13
585.5332642	0.03
587.0839233	0.69
588.3284302	0.28
599.1355591	2.23
600.1926270	0.72
608.4546509	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	664.1143
Annotation	Unknow
Peak:m/z	Relative Intensity
214.2255859	0.07
232.1768799	2.80
239.2440491	0.12
250.2245483	0.27
317.7864990	0.04
320.1712646	0.16
321.1814575	0.10
330.0933838	0.08
335.0985718	0.07
346.2922363	0.12
348.1169434	0.49
366.2855835	0.03
371.1253052	0.15
388.8773804	0.03
404.3141479	0.02
409.9751587	0.41
428.1469727	2.48
444.1838379	0.75
459.3240967	0.03
490.3699951	0.02
497.0004272	0.03
505.9562378	0.02
511.0807495	0.02
513.2848511	0.02
524.0601807	77.05
524.7651978	0.07
529.0220337	0.43
540.1618042	0.05
542.1109619	100.00
550.3585815	0.06
558.4876099	0.10
627.1147461	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	6-Methylflavonol
Peak:m/z	Relative Intensity
95.04290771	2.34
105.0623627	8.36
107.0098419	11.14
129.2266541	4.68
132.8346558	3.53
141.1194916	3.41
148.0591888	4.16
151.0529633	100.00
152.081192	6.31
169.3572083	2.34
177.0287933	1.86
182.3718262	5.55
185.1314545	2.82
192.072052	1.50
193.871048	3.52
196.9680481	3.61
199.2899933	6.03
207.2731781	5.41
219.7793274	1.51
225.187912	10.45
234.7260132	2.15
235.3588409	17.07
238.1223297	40.10
239.276001	6.16
253.0788574	59.54
254.1271515	4.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0561
Annotation	Quinic acid
Peak:m/z	Relative Intensity
56.8606453	0.45
58.8793831	3.49
61.0444145	0.85
70.9954758	4.55
73.1369934	0.17
80.9411850	1.48
82.9539642	3.68
84.9673462	88.66
86.8686371	15.42
92.9579315	55.84
95.8970642	0.49
97.0303802	0.28
99.0758972	2.54
100.9709778	1.14
107.6489868	0.21
108.9329681	20.47
111.0008087	30.27
112.9803314	0.69
114.9609375	2.59
126.9403229	100.00
128.9873352	1.75
131.0494843	0.30
137.0846710	1.31
143.1208038	1.46
145.0206604	1.48
153.0473938	8.17
154.9783783	10.04
161.1079559	0.16
171.0499115	19.53
173.0659180	77.89
190.9924164	0.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	616.9
Annotation	Unknow
Peak:m/z	Relative Intensity
200.2224274	0.04
229.3118896	0.10
272.9832153	8.85
273.9761353	3.89
275.0096130	3.61
386.9767456	16.34
387.9924927	13.87
388.9848633	12.47
500.9042358	43.04
501.8914185	92.02
502.8924561	100.00
503.5858765	0.09
531.0168457	0.06
569.8324585	0.09
570.9787598	0.27
571.6205444	0.21
572.8721313	0.13
578.8425903	0.15
588.8345947	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	686.1586
Annotation	Unknow
Peak:m/z	Relative Intensity
308.9204407	0.13
355.1643677	0.04
361.3992920	0.04
373.3872681	0.05
380.9343872	0.05
385.5352173	0.03
388.1234741	0.03
397.3746338	0.04
402.3535767	0.03
424.4409180	0.05
429.4069824	0.04
436.4617310	0.02
443.2682495	0.03
453.5338745	0.02
461.0739746	0.04
469.3718872	0.07
479.1551514	0.06
487.1751099	0.03
489.4152222	0.01
505.3792114	0.03
523.3082886	0.16
524.0282593	0.03
528.9623413	0.02
556.5368042	0.05
565.3778687	0.19
570.3082275	0.04
589.6802979	0.02
590.4464722	0.06
593.6810913	0.25
596.0129395	0.07
605.2332153	0.03
608.2570801	0.02
609.0874634	0.01
610.3941040	0.04
613.3977051	0.06
623.2199707	100.00
624.2646484	0.04
635.1251831	0.05
639.1196899	0.05
639.8029175	0.05
642.2966309	0.13
650.3402710	0.04
654.5812378	0.05
658.2365723	0.02
664.1107178	0.05
667.2694092	1.61
668.1804810	1.31
675.1878662	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	642.101
Annotation	Unknow
Peak:m/z	Relative Intensity
235.1083679	1.90
259.0229492	4.63
276.9854736	4.50
279.1378174	2.11
294.5666504	3.44
304.3076172	1.51
309.0932617	2.75
321.2544556	0.96
330.8863831	2.35
375.2446289	2.00
385.0413208	1.88
402.9536743	9.93
408.6628418	4.03
421.1685181	1.73
461.2282715	4.70
486.9124146	0.63
499.1421509	1.23
534.9120483	24.57
547.0965576	1.47
553.0092773	90.55
561.3031616	3.05
569.2505493	2.02
570.9744263	100.00
588.9848022	43.62
590.0615845	2.75
606.7233276	3.66
624.2234497	1.12
649.8220825	1.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.0476
Annotation	UDP-glucose Disodium Salt
Peak:m/z	Relative Intensity
158.8034973	0.08
164.3019409	0.04
177.0185699	0.06
183.1216125	0.06
190.9727783	0.04
192.961853	0.17
196.9823914	0.06
211.0023499	2.42
220.9867554	0.66
222.0718384	0.32
223.0090637	0.48
241.0903931	0.76
261.9873352	0.32
280.1040344	0.66
282.8449097	0.06
287.0950317	0.05
294.0541382	0.05
294.8530884	0.04
296.0354004	0.23
305.1686401	0.20
307.1931763	0.04
321.1427612	0.59
323.039856	100.00
329.2457886	0.04
341.1039429	0.19
344.2664185	0.05
360.8909912	0.05
366.3682861	0.05
368.2312622	0.04
371.7388916	0.66
372.4085693	0.40
373.27771	0.14
376.3932495	0.21
380.3248901	0.17
381.0873413	0.06
384.9762573	2.35
388.857605	0.06
391.9241333	0.08
398.3388672	0.10
401.5527344	0.03
403.1713867	2.12
404.9942627	0.07
419.1243896	0.22
423.0064087	0.03
430.0446777	0.46
431.0993652	1.16
432.3495483	0.07
434.8379517	0.18
446.1950073	0.05
449.3447876	0.12
466.6375732	0.34
467.4140015	0.28
482.3874512	0.13
518.9000854	0.11
520.6190796	0.30
522.2008667	0.10
530.012146	0.10
546.4902344	0.28
547.2439575	0.73
564.8905029	0.11
568.3300171	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	731.88
Annotation	Unknow
Peak:m/z	Relative Intensity
229.1536560	0.03
231.2069397	0.03
272.9934692	10.04
274.0108643	3.39
275.0856323	3.71
276.1213989	0.12
369.2957764	0.06
386.9860840	8.19
388.0921021	6.55
389.0043335	8.19
390.0094604	1.84
429.0021362	0.07
500.9806519	23.86
502.0404053	24.20
502.9611816	55.31
503.9097900	18.71
504.6987305	0.06
575.7615356	0.03
577.9080811	0.03
587.7559204	0.05
596.8493042	0.04
597.7802734	0.10
611.1766357	0.14
612.0101318	0.12
613.2395630	0.04
614.8142700	15.72
616.0682983	31.13
616.8701172	100.00
617.8370361	42.36
618.8546143	0.34
628.9771118	0.32
629.8580933	0.19
635.1198730	0.06
638.8682251	0.04
642.7446899	0.14
647.1026001	0.15
655.7720337	0.03
656.9464111	2.12
657.9585571	1.17
659.0366821	0.12
674.8389893	0.78
675.6821899	0.20
684.8488770	0.77
686.0981445	0.35
687.2508545	0.08
689.3447876	0.06
701.7603149	0.08
703.1129150	0.03
712.9692383	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	395.3175
Annotation	Secomahubanolide
Peak:m/z	Relative Intensity
145.2036285	0.03
163.3399353	0.04
183.0651550	0.04
185.1887360	0.02
201.0464478	0.03
223.4170532	0.02
225.3056030	0.76
237.3200378	0.03
239.0703735	0.37
251.3288269	0.03
253.4858093	0.02
255.2505188	0.02
263.2734985	0.12
265.4552307	0.13
271.3674622	0.08
277.3545227	0.06
279.3070374	0.24
281.3325806	0.02
293.4913330	0.02
301.3892517	0.03
311.3392334	0.09
315.3296509	0.12
319.4335022	0.11
321.3121338	0.14
327.6752319	0.07
331.0894775	0.40
333.3824463	100.00
334.0620728	0.36
335.4359741	0.06
336.8635254	0.03
337.5043335	0.03
349.2604675	0.06
351.3923950	10.96
352.3361816	0.04
353.4539185	0.10
359.4086914	0.61
366.6838684	0.02
367.4556580	0.13
374.9034119	0.03
377.4703064	20.58
378.4216309	0.02
379.1022034	0.03
395.4826965	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.2079
Annotation	Unknow
Peak:m/z	Relative Intensity
126.0969086	0.06
143.0281677	0.20
161.0763092	0.25
161.8325806	0.06
179.0498657	1.94
180.0554199	0.41
181.1027222	0.56
193.3797455	0.05
194.9738007	0.03
209.0976868	0.32
211.2721863	0.04
223.9538422	0.17
225.0545044	0.76
226.1031799	0.69
227.0847168	0.18
234.9113770	0.10
242.1374817	0.07
247.0989075	0.07
248.0256653	0.03
252.1165771	0.09
253.2872620	0.64
265.3299561	0.03
266.0711975	0.05
268.3198242	0.09
271.1221008	1.39
301.2658081	0.13
311.1742554	0.08
312.8551941	0.04
317.1347656	0.04
341.2805481	0.09
347.1360168	0.09
355.9002075	0.03
359.3926086	0.04
379.6637268	0.05
385.3611145	0.66
387.2846069	100.00
388.1307373	0.04
389.0617065	0.16
397.7677917	0.18
402.4015198	0.09
404.9974060	0.14
415.3302917	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	641.2599
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9116974	0.79
254.3275757	0.54
265.2647400	0.47
269.0537109	1.09
321.1724854	0.44
373.3056030	1.79
389.0476074	0.68
390.2064819	0.64
400.4049072	1.83
424.4453735	0.37
435.1716309	2.06
444.2745361	4.12
461.2208252	1.50
481.9858398	0.40
492.4694214	1.90
504.3353271	1.76
507.3157349	1.43
514.7932129	0.30
521.4605103	0.34
524.9887695	1.01
528.1206665	0.75
530.9806519	1.73
533.3062134	2.32
539.7726440	3.35
541.6592407	1.19
551.6902466	0.85
553.3456421	1.15
564.3526001	1.33
565.4739990	1.46
567.2881470	6.79
568.5643921	1.11
569.5385132	0.30
573.6629639	4.68
574.7832642	0.54
575.4906616	1.39
578.3063965	1.46
580.2444458	1.86
581.2447510	3.41
582.5535278	0.27
591.2903442	5.45
592.4673462	1.67
595.3489380	1.48
596.5126343	0.75
597.3672485	1.09
598.2876587	0.68
600.4590454	0.71
607.6919556	7.76
608.3292847	100.00
609.2846069	18.62
612.3720093	7.10
613.2266235	8.12
613.8463135	0.32
614.5291138	0.37
619.1262817	0.56
622.0693970	0.58
623.2810669	22.32
624.2393188	6.65
654.5093384	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0855
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.2194519	0.20
97.03317261	0.12
103.0737	0.08
105.0334167	0.07
108.1766357	0.11
120.7041779	0.52
121.7607727	0.22
123.1081696	0.55
128.2883453	0.49
129.006012	0.87
129.9776306	0.57
131.0442352	0.28
133.0710907	0.16
135.910202	0.09
137.1091461	0.16
137.8443298	0.28
140.0897675	0.46
142.2073822	0.07
146.9283295	0.25
147.9455566	0.10
150.9888916	10.61
151.8912201	1.50
153.0736084	0.49
154.0039825	0.21
155.1381836	0.33
158.2063141	0.10
161.135849	0.45
165.2563629	0.18
167.1257477	0.10
168.887085	0.51
170.2397614	0.17
171.0789642	0.53
175.2192841	0.09
176.0103912	0.06
177.1629791	0.15
178.1255646	0.75
179.2541962	0.49
180.248703	0.13
181.1690216	0.42
182.1618958	0.67
183.0297089	0.04
185.1418762	0.36
186.9972076	0.16
190.0685272	0.33
194.1252747	0.25
195.3139801	0.41
197.1531219	1.12
198.1678314	0.38
206.0727081	5.10
207.9941559	1.31
209.3393402	0.12
210.3380127	0.16
211.0865479	0.07
212.3032837	0.19
217.396759	0.95
218.204834	1.47
219.1732635	0.19
223.3186493	0.08
224.0567322	0.07
225.1534576	2.13
226.1031647	1.00
231.0648193	0.34
235.0917206	2.42
236.1601105	6.38
236.9483795	0.19
238.1420746	3.47
238.9672089	1.29
251.2451782	0.30
253.0827026	100.00
254.1282501	5.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	394.1267
Annotation	(gamma-Glutamyl-gamma-glutamyl)-S-methylcysteine
Peak:m/z	Relative Intensity
115.7628937	0.02
127.1085815	0.04
129.9070740	0.08
143.9913635	0.53
162.0227509	2.57
171.9178162	0.50
228.8179016	0.02
229.9042969	5.57
230.5161743	0.03
247.2344666	3.58
248.0644226	10.32
265.0497131	100.00
265.6722717	0.10
273.7741089	0.02
279.3430481	0.04
290.2059937	0.14
290.8870239	0.32
301.1430664	0.20
319.1254883	3.42
319.7665100	0.04
330.8875122	0.16
358.3973999	0.21
376.2458801	1.14
377.0539551	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1142.889
Annotation	Unknow
Peak:m/z	Relative Intensity
503.1785278	0.85
962.4859619	0.89
1113.7604980	0.40
1494.8240970	0.28
1609.0989990	0.25
1700.2438960	0.42
1706.5461430	0.26
1769.1214600	0.22
1774.2160640	0.29
1783.2923580	0.30
1811.1470950	0.95
1839.8856200	0.83
1842.3659670	0.15
1848.5762940	0.55
1849.3883060	0.19
1851.5754390	13.68
1856.2551270	0.42
1859.9027100	0.24
1875.4445800	0.16
1881.6236570	0.24
1884.4992680	0.36
1898.2020260	19.29
1900.9979250	1.50
1908.3563230	0.27
1911.5567630	1.17
1919.1037600	2.29
1924.4991460	1.24
1928.8436280	0.24
1930.1658940	8.83
1932.7565920	0.32
1937.2694090	0.20
1943.0748290	0.90
1950.3221440	0.70
1951.2933350	5.86
1952.6368410	1.62
1960.2170410	0.43
1964.2987060	0.32
1966.3751220	5.91
1969.6810300	1.68
1972.2481690	8.25
1973.6143800	1.52
1974.5750730	86.17
1979.4968260	100.00
1980.9826660	19.38
1981.9196780	8.37
1983.6856690	5.01
1984.5433350	0.63
1987.2059330	2.07
1988.7735600	35.95
1989.7139890	6.03
1990.6658940	0.37
1991.8953860	0.16
1993.4854740	0.19
1997.7354740	0.62
1999.2178960	8.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.1606
Annotation	Rhamnocitrin 3-glucosyl-(1->2)-galactoside
Peak:m/z	Relative Intensity
182.0590668	0.01
184.0845947	0.03
189.0627136	0.04
189.8812408	0.01
192.1307526	0.02
197.2885742	0.03
198.1718903	0.01
200.2418365	0.05
200.9540710	0.04
202.0164490	0.03
204.3024902	0.01
205.2675476	0.02
211.1711731	0.03
212.2665253	0.04
213.1816101	0.05
214.0519562	0.02
214.9912415	0.02
219.2233276	0.07
225.0936584	0.02
225.9706879	0.05
226.8940430	0.19
228.2647552	0.02
228.9205017	0.02
230.0936279	0.03
233.2039032	0.01
237.0303040	0.02
239.0053711	0.11
243.1466217	0.39
244.1110535	0.39
245.2718506	0.04
247.2631226	0.01
254.1190186	0.17
255.1105499	3.05
256.1851196	0.34
257.1409912	0.02
259.2275085	0.23
268.2119751	0.03
269.2503052	0.01
271.0906067	5.27
272.0781250	2.55
273.1161499	0.19
282.3049927	0.03
283.2045288	0.06
285.4089355	0.07
287.2396545	0.94
288.4571533	0.16
289.3476562	0.03
297.0422668	0.03
298.9034119	0.34
300.0947876	18.57
301.1967163	3.31
302.3980103	0.03
303.4975586	0.02
311.1941223	0.03
313.1506653	0.73
315.0786743	100.00
316.0897217	16.63
323.2206421	0.02
324.0138550	0.02
325.1434326	0.02
326.2876587	0.06
327.1101074	0.03
329.0755005	0.15
357.1884155	1.13
358.0755005	0.24
372.2232666	0.02
387.3010864	0.05
388.1518555	0.02
398.3670654	0.05
399.4746094	0.02
422.9457397	0.02
424.1723633	0.01
443.2307129	0.01
447.3740234	0.02
452.0513916	0.02
459.3600464	0.02
471.4207764	0.06
473.4821167	0.07
477.1874390	0.12
491.2916870	0.01
499.0129395	0.03
502.2224731	0.04
507.7457886	0.02
523.1126099	0.04
555.3305664	0.09
563.9898682	0.03
577.0315552	0.03
578.9570923	0.02
580.1628418	0.04
586.1461792	0.04
588.0270386	0.01
591.3107300	0.15
592.5366211	0.03
595.3538208	0.27
596.1397095	0.08
605.3887939	0.02
606.4627075	0.06
608.2433472	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	406.16
Annotation	Lissoclin A
Peak:m/z	Relative Intensity
225.8809509	1.42
247.0061646	1.70
261.1823120	4.28
272.2307129	1.84
288.8808594	14.33
290.1524048	2.41
307.1400146	100.00
308.1872253	1.06
340.3935547	1.47
346.3537598	2.94
347.5082703	2.15
357.1278992	3.62
388.2007141	4.16
389.4006958	5.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	644.0475
Annotation	Unknow
Peak:m/z	Relative Intensity
209.2198486	0.10
235.3150330	0.09
239.0624542	0.29
243.1416016	0.10
256.7579041	0.06
258.9192810	0.13
261.1403198	0.08
261.9058838	0.24
271.2790527	0.15
276.9204102	0.24
279.2067566	0.20
281.2637329	0.07
294.9512939	0.22
297.4302979	0.09
312.3994141	0.13
313.3246460	0.07
316.1439819	0.12
326.2434692	0.10
327.8244019	0.26
332.0799561	3.04
332.8858643	0.16
335.0499268	0.04
339.1544800	0.09
343.3497314	0.19
348.3522339	0.08
359.0619507	0.18
368.2113647	0.35
373.2767334	0.03
381.4730835	0.11
383.3930664	0.09
386.1880493	0.14
398.5205078	0.07
402.6483154	0.08
405.3054810	0.06
408.2485352	0.14
413.4252930	0.13
415.5941162	0.07
426.3975220	0.88
438.4887085	0.08
445.1872559	0.09
446.1027222	0.08
446.9271240	0.28
457.3080444	0.12
462.4559326	0.03
465.7643433	0.06
473.3773804	1.12
474.4172363	0.28
486.3158569	0.86
488.0370483	100.00
496.4654541	0.24
500.6571655	0.09
511.2566528	0.12
521.5824585	0.71
536.1173706	0.89
536.8291626	0.11
538.2646484	0.09
539.3564453	1.05
553.2222900	0.23
554.1896362	1.53
555.0305786	0.83
563.6332397	0.18
571.7235718	1.26
572.9689331	2.90
582.0285034	0.08
582.7019653	0.11
583.5423584	0.28
588.8912354	0.20
590.1790161	2.02
590.9072876	1.07
603.8528442	0.27
607.6177979	0.35
608.6592407	0.23
610.3875122	0.13
615.5657349	0.10
619.4646606	0.09
620.5521851	0.06
624.0050659	0.57
625.3121948	0.60
626.3704224	1.46
628.5829468	0.26
668.4729004	0.08
688.0814819	0.21
703.3519897	0.17
779.7680664	0.06
780.5994263	0.12
797.0833740	0.47
821.3546143	0.21
827.7477417	0.19
841.5285645	0.21
850.6323242	0.24
947.6089478	0.18
973.6647339	0.05
995.7866211	0.14
1022.2567750	0.07
1026.7001950	0.07
1075.3638920	0.31
1080.3732910	0.07
1110.5708010	0.08
1279.7398680	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
99.08576965	0.92
108.9897308	0.53
140.8717957	0.46
143.016571	0.64
154.9298859	2.18
164.9660034	0.64
169.1991882	0.69
170.9991913	0.53
173.443222	0.96
177.2692566	0.28
179.7772675	0.74
181.2628326	2.37
188.948288	1.32
193.1870422	2.51
195.0031891	1.87
196.9986877	1.36
201.221344	0.49
205.196106	1.38
209.1185303	2.12
210.0756531	0.35
210.9976501	1.62
213.1486816	2.42
223.1856689	1.72
225.0986938	2.05
227.1097717	5.97
235.8657837	1.51
239.1248474	1.71
241.0970154	0.28
245.255127	0.47
247.1595764	1.38
249.0904846	0.99
250.9945679	0.94
253.1382446	4.88
256.994873	1.95
261.3638306	1.30
263.1311035	0.62
265.1635742	0.73
265.9942322	1.46
267.2612915	0.49
268.5970154	1.31
275.2607727	11.87
283.4199219	5.81
287.6696472	0.53
293.210968	100.00
296.1611938	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0878
Annotation	Scopolin
Peak:m/z	Relative Intensity
107.0324097	0.02
111.1086426	0.04
117.2293167	0.05
126.7342682	0.11
133.0779114	0.05
133.9293060	0.37
135.0652771	6.68
137.1301270	0.04
155.0397034	0.11
160.9832458	1.00
164.9940033	0.02
170.8754578	0.15
173.0873108	2.36
179.0056000	41.08
191.0117493	100.00
271.1602783	0.03
304.9689941	0.06
306.7947388	0.04
309.1619263	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	659.17
Annotation	Unknow
Peak:m/z	Relative Intensity
191.0451202	3.65
305.1686707	0.12
306.8735962	0.09
353.1094360	100.00
354.7405396	0.06
371.5186157	0.08
425.0447998	0.03
484.3883057	0.23
485.3367920	0.03
496.2877197	0.15
611.9084473	5.24
612.9088135	0.79
613.5131226	0.03
614.2879028	0.06
642.3292847	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1136.2089
Annotation	Unknow
Peak:m/z	Relative Intensity
385.2932739	0.04
422.7230835	0.06
427.1752014	0.11
458.5641479	0.10
526.6017456	0.04
536.1510010	0.11
556.3842163	0.07
601.7471924	0.11
613.1916504	0.13
638.5375977	0.04
674.8886719	0.17
686.6241455	0.04
696.2934570	0.17
719.3162231	0.03
726.3720093	0.11
727.2095947	0.19
731.5525513	0.16
733.5540771	0.28
744.4980469	0.11
745.7211304	0.15
748.5101929	0.03
753.9162598	0.96
759.5293579	0.17
760.2162476	0.12
775.2463989	0.21
776.5899048	0.21
784.5242310	0.62
785.3021240	0.09
789.1038818	0.13
793.5950317	1.36
794.3582153	0.37
797.2281494	0.16
804.1098633	0.19
805.8125000	0.13
811.5787354	0.04
817.4738770	0.31
828.4144287	0.03
829.0578613	0.14
832.5417480	0.19
834.6972656	0.20
837.4604492	2.88
838.5676270	1.68
839.4780273	0.28
845.9197998	0.03
850.5334473	0.17
855.1947021	0.27
862.9721680	0.31
866.8197021	0.52
879.6445312	0.07
885.2819824	0.05
887.2874756	0.06
897.9099121	0.62
899.0644531	0.18
902.3997803	0.13
906.4730225	0.61
907.6943359	0.32
911.3769531	0.18
916.0775146	0.74
919.4732666	0.32
920.3713379	0.09
924.8638916	0.59
928.7604980	0.79
929.6370850	0.06
933.2009277	0.05
937.4486084	0.26
938.6417236	0.13
939.2597656	0.06
944.5323486	0.17
945.8111572	0.28
946.9046631	0.18
947.7513428	0.09
949.3582764	0.09
950.2244873	0.27
956.0196533	0.36
961.3049316	0.52
966.4310303	0.78
967.2886963	0.22
968.6247559	0.22
969.8170166	0.10
976.5109863	0.25
985.7485352	0.90
987.6523438	0.28
990.3731689	0.20
991.2276611	0.78
992.0354004	0.21
993.9372559	0.10
996.1572266	0.20
1000.2283940	0.31
1001.5151370	0.23
1005.9594730	2.33
1008.4108890	0.14
1011.6336670	0.10
1014.7958980	0.88
1015.5157470	0.04
1016.8037110	0.16
1020.6220700	2.26
1021.4681400	0.48
1024.0468750	0.10
1031.4544680	0.10
1036.0043950	0.36
1038.3269040	0.21
1044.8676760	0.10
1047.5405270	0.30
1049.1138920	0.24
1050.5745850	0.15
1057.2352290	0.45
1058.3671880	0.81
1060.0092770	0.51
1060.6226810	0.19
1062.3937990	0.29
1063.7569580	0.88
1066.2849120	0.53
1067.2255860	0.79
1067.8328860	0.19
1068.8576660	0.10
1071.7564700	1.80
1073.0305180	1.15
1074.7940670	0.03
1076.4519040	0.61
1077.7414550	0.80
1078.3870850	1.15
1080.9665530	1.38
1082.0250240	1.86
1082.9089360	0.67
1083.5224610	0.08
1084.1625980	0.07
1085.4851070	0.82
1086.6547850	3.86
1087.5197750	3.19
1088.7700200	0.45
1089.4039310	0.05
1091.2384030	4.27
1092.5373540	6.46
1093.5698240	0.71
1095.2954100	6.16
1097.0697020	4.59
1097.8625490	1.20
1098.7885740	0.12
1099.9882810	1.28
1101.0411380	11.67
1101.6979980	5.78
1102.5378420	0.14
1103.6289060	0.62
1104.4329830	0.10
1106.2139890	5.38
1107.2595210	36.33
1108.3599850	0.09
1109.9431150	9.29
1111.8581540	15.67
1112.7058110	0.88
1113.6774900	0.07
1114.7860110	1.25
1115.3968510	2.13
1116.0028080	49.81
1116.9851070	0.63
1118.5158690	0.79
1119.5051270	0.35
1120.5345460	4.24
1121.8751220	100.00
1122.8094480	1.86
1124.1503910	0.40
1124.7919920	0.38
1146.0677490	0.08
1147.3022460	0.12
1149.7550050	0.29
1151.0364990	0.04
1153.0200200	0.12
1159.0874020	0.57
1159.7781980	0.06
1166.4355470	0.53
1168.5632320	0.78
1169.4522710	0.32
1170.6173100	0.49
1171.3397220	0.10
1173.1638180	0.09
1173.9515380	0.05
1181.2731930	1.81
1182.1121830	0.52
1190.1745610	1.93
1191.0778810	0.25
1194.6989750	0.18
1199.2646480	0.07
1202.1940920	0.05
1203.3485110	1.43
1204.1558840	0.16
1206.5092770	0.26
1210.1560060	0.15
1212.5485840	0.23
1213.1672360	0.18
1217.5046390	0.11
1218.5125730	0.02
1222.7677000	0.22
1233.1254880	0.69
1233.7338870	0.29
1239.4372560	0.27
1240.1221920	0.04
1245.6137700	0.51
1246.2260740	0.02
1246.8599850	0.08
1251.7872310	0.05
1253.2304690	0.03
1254.8098140	1.79
1255.6605220	1.37
1257.4672850	0.06
1262.1848140	0.03
1263.5368650	0.08
1267.5621340	0.46
1268.5859380	0.25
1276.6550290	1.47
1277.7116700	0.05
1290.4630130	0.12
1294.8175050	0.03
1295.6972660	0.05
1306.6528320	0.07
1323.8374020	0.10
1324.6790770	0.06
1341.1430660	0.19
1343.6217040	0.03
1349.0742190	0.12
1352.9746090	0.07
1354.8994140	0.11
1358.7387700	0.03
1359.7410890	0.03
1361.7694090	0.16
1362.4847410	0.06
1367.9403080	0.16
1368.6458740	0.37
1370.8210450	0.05
1376.7083740	0.12
1382.0280760	0.06
1385.9953610	0.34
1393.6916500	0.12
1395.8549800	0.13
1399.7965090	0.05
1410.9941410	0.14
1412.5448000	0.03
1418.8414310	0.12
1426.3275150	0.06
1437.6351320	0.21
1454.5745850	0.44
1455.5130620	0.18
1457.5989990	0.05
1465.6489260	0.11
1507.8597410	0.11
1508.6043700	0.09
1522.6080320	0.25
1526.9288330	0.03
1527.5461430	0.04
1533.6346440	0.10
1534.8126220	0.42
1551.9205320	0.31
1552.6708980	0.54
1570.0484620	0.06
1622.8872070	0.13
1631.6242680	0.17
1637.5163570	0.20
1656.9992680	0.32
1674.7921140	0.09
1702.7357180	0.14
1753.8640140	0.09
1756.6456300	0.06
1778.4670410	0.04
1788.5148930	0.19
1795.7449950	0.14
1796.8253170	0.04
1813.3068850	0.03
1814.8292240	0.11
1815.6231690	0.12
1821.7941890	0.04
1839.5660400	0.16
1840.6654050	0.09
1856.5217290	0.18
1857.5603030	0.25
1882.5281980	0.09
1901.6199950	0.04
1905.6071780	0.03
1916.2233890	0.09
1937.7532960	0.09
1939.1223140	0.05
1948.2254640	0.15
1948.8651120	0.12
1972.0081790	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	445.1483
Annotation	Daidzein G 2
Peak:m/z	Relative Intensity
127.1575317	0.10
141.0842896	0.17
144.9087219	0.43
147.0648804	0.18
157.8905792	0.13
162.9823303	0.15
177.0228882	5.38
179.3052979	0.09
183.0439758	0.11
195.1135559	0.23
201.0539856	0.09
202.8492889	0.14
209.2944336	0.21
213.1070404	0.21
215.3290405	0.12
220.8883362	0.06
225.0394897	0.28
226.9313354	0.07
228.4503784	0.12
230.7299652	0.06
234.3338623	0.11
237.0256653	0.25
239.9568787	0.05
241.3164673	0.22
242.0015259	0.29
247.1933594	0.51
249.5033875	0.40
251.1186523	29.82
251.9624329	0.12
255.1486206	0.10
256.0846863	0.16
259.1452026	0.11
273.0697327	0.10
276.9808350	1.26
278.2067566	0.15
281.8475342	0.24
283.0915222	0.17
285.1346436	0.24
287.2725220	0.41
288.1062622	0.45
290.8546753	0.19
293.3421326	0.20
294.6564941	0.15
296.1449585	0.08
296.9409790	0.25
298.1884766	2.23
299.2530823	1.25
300.2750244	0.13
301.0981140	0.27
303.1260986	0.07
308.1291504	0.16
309.2074585	0.31
311.4404907	0.18
313.2038574	0.23
315.2902222	0.62
317.3684082	0.18
321.1218872	35.98
323.4257812	0.41
324.2957153	0.34
325.2260742	0.13
329.2000122	7.36
329.9554443	0.37
331.1852417	0.14
336.3996277	0.06
339.2872620	0.27
341.0878601	0.07
342.9382324	0.10
349.3496094	0.18
352.9379578	0.87
355.1611328	0.06
360.2615967	0.28
360.9859009	0.13
364.4439392	0.42
369.8995056	0.10
371.3508911	0.34
372.0118103	0.47
373.5036926	0.28
381.4931335	0.24
382.4361877	0.07
385.3304749	0.71
387.1468201	0.05
389.1602478	0.16
394.4574890	0.15
395.1807556	0.17
397.2760315	0.06
398.2690735	0.49
399.2329407	1.50
400.3722839	0.46
403.3452454	0.57
409.2842102	0.62
412.9663086	0.35
416.0777893	2.91
417.2080078	0.90
421.1893921	0.37
424.1841431	0.10
427.1492615	100.00
427.7668762	0.57
428.9277649	0.84
433.3471985	0.14
435.9472961	0.40
444.1987915	0.11
445.1822815	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	721.9479
Annotation	Unknow
Peak:m/z	Relative Intensity
227.8387451	0.14
282.2248840	0.27
356.9747314	0.11
385.7491455	0.27
396.6777954	0.22
505.6344604	0.10
508.1491699	0.17
522.2127686	0.41
524.2817993	0.18
564.0114136	0.16
567.0799561	0.25
581.6956177	0.43
584.5729980	0.12
591.0350342	0.14
603.8401489	0.36
629.1895752	0.87
650.0220947	0.67
659.2818604	0.12
660.5491333	0.24
666.0390015	0.08
695.1729736	1.20
695.8450317	0.17
708.6841431	0.17
711.3538818	2.30
752.2396240	0.73
753.3594360	0.54
755.3333130	0.96
757.8624878	0.72
764.6450195	0.35
780.8820801	0.74
785.5744019	0.68
786.4155273	0.10
793.9596558	0.79
811.6959839	1.53
813.4531250	0.55
831.8386230	2.91
837.1970825	0.83
841.4337769	1.89
845.5612183	3.68
846.2164917	1.39
847.6137085	0.47
854.2216187	0.13
855.5902100	0.76
863.4599609	0.55
869.3756714	0.67
872.5852051	0.77
873.8120117	0.21
893.1000366	0.35
903.0378418	0.82
910.8420410	0.21
912.6414185	0.69
913.4463501	0.10
918.2763062	0.78
942.5097046	0.18
960.3030396	0.79
977.8960571	0.30
1000.2385250	0.49
1003.3132320	1.33
1011.8368530	0.07
1014.3813480	0.15
1015.8125610	0.07
1032.3281250	0.84
1041.2469480	1.28
1042.4914550	0.09
1059.6064450	0.61
1075.6810300	0.30
1085.3813480	0.55
1099.3945310	0.25
1181.9028320	0.46
1241.4296880	0.10
1281.7792970	0.08
1685.7835690	0.22
1726.9193120	0.09
1748.6267090	2.08
1756.2938230	0.13
1763.0640870	0.07
1766.9906010	0.07
1788.3206790	0.20
1793.4432370	0.49
1805.4031980	2.10
1808.4295650	0.07
1817.2043460	1.00
1819.2052000	0.20
1825.3127440	7.05
1841.6148680	0.13
1847.8645020	1.16
1851.9439700	0.15
1853.2653810	0.12
1869.4354250	0.16
1877.1779790	2.84
1880.5759280	23.21
1884.9849850	0.10
1886.1131590	9.19
1891.6154790	0.14
1895.2711180	1.77
1896.0699460	1.43
1897.9510500	1.02
1899.4766850	0.07
1905.6278080	0.28
1911.8458250	0.12
1918.4119870	0.20
1922.9293210	0.21
1925.2008060	2.02
1932.0770260	0.81
1933.5477290	0.08
1936.2520750	12.69
1937.3743900	0.13
1938.8083500	0.27
1943.5247800	2.49
1944.5340580	0.54
1946.2728270	100.00
1949.5539550	4.22
1951.4051510	0.07
1952.4681400	4.00
1954.7521970	0.35
1956.9593510	0.11
1959.8990480	0.44
1960.9566650	0.81
1963.2795410	0.13
1964.4847410	0.59
1965.7103270	0.22
1968.9276120	0.20
1970.0812990	3.10
1971.2526860	8.24
1972.3942870	0.09
1973.9874270	1.24
1975.7288820	0.08
1976.5915530	0.51
1978.4107670	0.14
1980.5350340	0.82
1983.6970210	9.60
1984.9289550	9.77
1985.8470460	2.13
1986.7144780	12.01
1988.8830570	0.14
1989.5338130	0.57
1991.1453860	3.46
1993.6685790	1.98
1995.1505130	0.24
1996.0064700	1.29
1997.5054930	4.07
1998.6712650	2.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	323.0833
Annotation	Unknow
Peak:m/z	Relative Intensity
99.9870758	0.25
111.9446869	1.28
112.9981308	0.49
114.0604172	0.03
115.0136795	0.05
126.8281860	0.07
128.9296112	0.55
140.0895996	0.08
141.1471558	0.23
149.0918427	0.30
150.2139893	0.12
156.7672424	0.54
157.9877930	1.87
158.5960083	0.02
159.2162476	0.12
162.1741943	0.08
165.2122345	0.06
165.9187927	0.30
175.0373993	0.55
179.9170837	0.15
181.1651306	0.18
184.0341339	1.70
190.9070740	0.14
198.2083588	0.05
201.1300049	2.88
203.0068970	0.09
207.0061340	0.17
207.8861084	0.31
210.1399536	0.05
211.1553650	0.06
212.0264282	0.10
218.1757507	0.06
222.1681213	0.06
224.2182007	0.14
225.1617737	1.50
226.1867676	1.51
227.0072632	0.09
234.7643127	0.05
239.1938171	0.12
242.1253052	100.00
243.2171326	76.95
244.9368896	0.44
248.1552734	0.16
257.2266235	0.06
258.9356384	0.04
263.0460205	3.41
264.0706787	0.57
270.0269470	0.27
271.0851440	0.29
272.8175964	0.09
275.2097778	0.44
277.0432739	2.12
281.2550354	1.22
286.9804077	0.66
288.0813599	3.89
288.9487610	0.25
305.0399780	5.97
306.1047668	9.44
313.8676758	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	323.0833
Annotation	Unknow
Peak:m/z	Relative Intensity
97.9731750	0.08
100.0276489	0.97
100.8026352	0.56
111.8860168	18.11
112.9729462	2.68
113.9962616	0.20
115.9134750	0.29
124.1295471	0.33
128.4270325	0.64
129.0885315	6.59
130.1244965	0.08
131.0593872	0.15
132.0482941	0.10
138.2010345	0.12
139.7196198	0.35
141.1154480	0.24
145.2737732	0.09
148.2565002	0.77
148.9019775	5.65
152.2682800	0.20
156.9961090	3.67
158.0838013	24.27
159.0760193	0.42
165.0106812	0.19
165.9868164	1.40
169.0697174	0.07
175.1816101	0.74
179.2584534	0.08
180.1653900	0.13
181.1704712	0.35
184.0307465	10.21
188.0755463	0.11
189.9662628	0.52
193.9437866	0.12
195.9982758	0.43
199.1965942	0.25
201.1436310	30.49
201.9876709	0.09
203.1081848	0.12
207.1693726	1.68
208.1004944	0.08
209.3457947	0.18
210.1809998	0.63
211.0996704	0.69
217.0945435	0.10
221.2792664	0.34
222.0536804	0.61
223.2127380	0.88
225.1696472	12.91
226.2138672	11.59
227.1638489	0.94
231.2403259	0.17
239.0845642	5.17
240.2916260	0.23
242.0994873	68.97
243.1275940	18.99
244.9656982	13.43
246.2443848	0.25
257.0207520	0.47
259.3032837	1.28
260.2079773	0.29
261.1379700	0.20
263.1001282	33.31
263.9625854	7.45
270.1424255	1.48
271.0404358	0.38
272.6406860	0.18
273.4080811	0.12
275.1226501	2.18
277.1293030	5.29
278.1699524	0.31
279.2269287	0.28
281.1114807	11.60
288.0014343	34.37
289.0541077	1.67
291.4697876	0.26
295.3230591	0.29
305.0655212	35.26
306.1344910	100.00
314.2867737	0.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	277.1228
Annotation	Pantetheine
Peak:m/z	Relative Intensity
84.8284607	0.06
86.9382553	3.57
99.0488357	0.13
113.0730972	0.36
115.0675430	0.22
115.8970108	0.20
128.9195404	0.68
129.9385681	9.75
142.7462311	0.05
145.9938354	49.61
146.9581909	28.09
150.9435883	0.05
156.9730835	0.57
160.9231567	0.10
172.2514343	0.09
175.1710052	0.26
177.1426086	0.15
185.0834045	0.10
187.0791321	0.24
190.8150940	0.05
200.0217590	0.72
210.8409119	0.07
213.1661377	0.29
217.0468445	100.00
231.1406860	0.43
232.9413452	0.03
243.1702271	5.14
259.1966553	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	606.25
Annotation	Unknow
Peak:m/z	Relative Intensity
222.3566589	0.05
227.0476379	0.03
258.3800049	0.02
261.3110962	0.09
279.2168579	0.05
293.3947754	0.05
307.7110901	0.02
314.3930969	0.23
316.3369446	0.03
319.1462402	0.04
324.4376221	0.05
328.6779785	0.06
357.3668823	0.11
385.1474609	0.05
395.4687500	0.04
397.3861694	0.04
398.0787354	0.03
401.0199585	0.06
402.2825317	0.11
403.2967529	0.08
426.6258545	0.06
436.4281006	0.09
438.4133301	0.05
439.2683716	0.04
442.4343872	0.03
444.7102051	0.05
446.7298584	0.25
447.4266357	0.13
459.2449951	0.13
463.5567017	0.20
473.2868652	0.77
474.3917236	0.29
475.4291382	0.49
477.3845825	0.17
478.3176880	0.08
485.3807373	0.14
487.4683838	3.90
489.0726318	0.06
490.4755249	0.13
491.6066284	0.16
492.5512085	0.12
500.2567749	0.15
501.2667847	1.08
502.6714478	0.09
503.4883423	0.15
504.2260132	0.02
505.4941406	0.71
506.4944458	1.27
507.2586060	0.14
507.9058228	0.05
513.3574829	0.11
515.3712769	0.06
517.3328247	0.47
519.3718872	17.04
520.4271851	0.05
521.4828491	0.21
529.2287598	3.14
529.8475952	0.11
531.3399048	0.26
533.3739624	3.19
534.4390869	0.99
536.4103394	0.07
538.1483765	0.04
541.2026978	0.07
545.2987671	0.59
547.3948975	100.00
548.4336548	0.18
550.3241577	0.13
551.2873535	0.28
556.2133789	0.08
557.3234253	0.53
559.7034302	0.06
561.4050293	1.77
562.4496460	0.19
563.4860840	0.06
565.4603882	0.06
570.0917969	0.05
573.5116577	0.13
574.3859253	1.79
575.4097290	3.15
579.4414062	86.40
587.6911011	0.49
589.3455200	5.79
590.9390259	0.34
591.7208862	0.07
605.2432251	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1144
Annotation	Lactulose
Peak:m/z	Relative Intensity
178.5763245	0.12
206.8578491	0.17
237.3784485	0.10
341.2075806	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.1594
Annotation	Rutin
Peak:m/z	Relative Intensity
257.2091064	0.29
258.0021362	0.37
269.9671631	0.45
303.0617981	100.00
304.2305908	47.86
311.3632812	1.30
317.4171143	1.00
318.4585571	0.76
345.0286255	3.06
346.4039307	1.84
356.0748291	0.89
357.1130981	0.79
401.2832031	0.72
413.9540405	1.20
423.5475464	0.73
429.4298096	0.90
431.2039795	1.55
439.6278076	1.06
447.1021729	1.15
448.1960449	1.96
448.9631958	8.72
449.8370361	1.42
463.4760132	0.78
465.1763916	35.62
466.1922607	15.72
470.0343018	1.00
492.2813721	0.62
496.4308472	0.32
515.2043457	0.62
520.0032959	1.32
522.1610718	3.11
557.1255493	0.89
568.1015015	0.26
575.1933594	2.12
576.921814	3.79
578.4473267	3.21
580.4694214	1.32
583.4492188	0.50
589.96698	1.96
593.1622925	2.01
594.2140503	1.09
594.8796997	1.72
599.8198242	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	652.1213
Annotation	Unknow
Peak:m/z	Relative Intensity
281.2877808	0.90
294.9540405	0.60
308.1265259	0.16
356.3470459	0.17
386.3618164	0.64
418.3975220	1.21
419.0750122	0.14
425.0206299	0.39
429.1035156	0.52
432.6012573	0.28
433.3168945	0.97
436.4249878	1.30
437.5383301	0.90
443.2341309	0.17
447.4711914	0.16
459.7596436	0.64
470.5786133	1.60
471.5543823	0.31
473.1248169	0.24
489.3188477	7.70
490.5049438	5.80
491.6583862	0.94
496.0352173	2.04
526.5576782	0.33
528.0670776	0.92
532.0078125	1.61
532.6423950	0.70
541.6141968	0.29
542.7181396	0.37
550.1892090	0.87
561.2485352	0.25
568.4850464	0.75
576.3558960	0.23
584.5883789	4.98
585.7295532	2.11
586.4345093	0.19
590.9151001	1.64
599.6751709	0.16
603.8440552	0.36
613.0936890	3.48
613.8789673	4.59
614.4900513	0.67
615.4721069	0.22
616.3252563	0.15
634.5128784	0.80
636.1040649	0.18
639.7466431	1.79
640.7127686	1.66
643.4827271	1.06
680.1335449	0.10
683.8095093	0.25
696.0444336	0.50
705.0535278	4.26
705.6832275	2.71
713.2770386	0.43
720.1166382	1.07
729.1218872	0.34
739.7753906	0.29
749.3346558	0.51
754.2943726	0.25
761.1931152	0.14
771.6875610	2.89
772.8236694	0.17
794.8167725	0.53
798.7736206	5.08
799.3931274	3.27
800.6729126	0.22
813.2107544	0.79
821.3886719	0.70
824.6439209	0.21
825.6343384	0.40
836.4856567	1.40
854.7073364	0.24
868.0336914	0.44
872.3165894	0.62
874.7307129	0.50
918.7331543	0.35
963.4277954	0.85
976.4519653	0.34
978.2420044	0.24
983.9364624	0.45
985.7495728	0.38
996.6000366	0.46
1040.6561280	0.45
1050.9936520	0.33
1055.9227290	0.36
1069.6701660	0.27
1070.8220210	0.21
1084.9566650	0.62
1098.6926270	0.59
1121.4393310	0.27
1126.8758540	0.31
1177.0976560	0.87
1197.6339110	1.43
1198.4198000	1.62
1235.7337650	0.28
1283.8684080	0.25
1293.7198490	0.38
1381.7935790	0.36
1438.6071780	0.15
1440.2302250	0.13
1451.9233400	0.07
1512.4339600	0.29
1620.5045170	0.14
1623.8878170	0.36
1631.2780760	0.07
1652.0460210	0.13
1678.3685300	0.09
1684.7053220	4.00
1706.9053960	0.28
1723.7213130	0.14
1741.1140140	0.45
1749.1457520	0.12
1750.5080570	2.45
1762.6042480	0.11
1790.1090090	0.29
1796.8142090	0.13
1802.2764890	1.14
1808.8087160	0.43
1810.3797610	0.31
1814.4102780	0.12
1822.5184330	0.12
1832.5119630	2.21
1841.4581300	2.94
1851.7164310	0.16
1857.5299070	0.77
1861.6737060	0.32
1862.5426030	0.09
1864.8573000	0.36
1866.0162350	0.17
1870.8103030	0.30
1875.0189210	2.75
1879.0718990	1.19
1879.8363040	0.09
1890.0003660	12.75
1892.6658940	1.31
1894.0158690	6.11
1897.2105710	2.45
1898.3273930	4.70
1900.9592290	0.23
1904.5638430	2.68
1915.3200680	5.00
1917.8996580	5.39
1919.2052000	1.06
1924.5030520	0.31
1926.2386470	0.56
1927.9387210	0.36
1932.2551270	0.62
1933.1263430	0.39
1936.2779540	0.85
1937.0255130	0.62
1938.3687740	1.56
1941.4925540	1.15
1944.7066650	0.15
1945.5993650	4.52
1946.5548100	5.47
1949.7341310	0.63
1950.6177980	1.22
1955.2471920	8.87
1957.2650150	2.67
1958.5994870	0.15
1960.5577390	1.25
1962.3815920	0.71
1963.0023190	0.67
1965.7316890	2.95
1966.6546630	1.45
1967.4735110	0.30
1968.4508060	0.44
1969.3831790	0.63
1970.1218260	100.00
1972.6652830	43.80
1974.6507570	4.74
1975.8292240	7.06
1979.8192140	5.02
1980.9094240	1.88
1981.6516110	3.77
1982.6639400	2.92
1985.3233640	0.64
1987.4010010	0.72
1990.3825680	0.57
1993.1721190	18.52
1993.9097900	11.28
1995.5025630	14.72
1996.6314700	2.17
1998.9954830	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.0264
Annotation	Unknow
Peak:m/z	Relative Intensity
94.9883728	0.31
96.7283478	0.12
101.0883331	0.42
104.8635864	10.17
113.0460205	1.74
114.2602692	0.09
115.0267792	1.30
116.9575882	0.21
119.0325241	0.43
124.9474182	0.11
126.8950195	0.32
128.9213867	0.51
130.8795471	0.25
138.9597015	1.21
140.8720245	0.41
142.9466553	0.85
145.0361633	2.21
147.0248718	1.10
148.8617859	55.24
150.9909058	1.15
152.8907471	0.63
154.9066162	0.41
156.9798279	1.71
159.0682068	1.01
161.0362549	3.94
162.9705200	10.27
165.0954895	0.19
175.0301514	24.18
178.9866638	3.46
180.2694092	0.22
187.0581512	1.83
190.9744873	7.06
193.0789337	0.41
195.0197144	0.27
199.0509644	0.39
203.1576233	0.27
205.0710449	2.28
209.2221680	0.19
213.2241821	0.41
215.0079346	0.34
217.0932617	0.46
220.8424988	26.72
221.5422058	0.29
225.2279053	0.24
233.1703796	0.20
235.1315308	0.07
238.6517029	0.66
243.0819702	0.38
245.0297852	0.93
246.0120850	0.14
247.1142578	1.52
250.9135132	12.82
251.8695984	0.09
253.0914612	0.14
259.1253052	0.14
265.0347290	100.00
267.0765381	1.34
275.0165100	0.45
277.0654297	20.36
280.9485474	0.59
292.9483032	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	262.0569
Annotation	Ascorbalamic acid
Peak:m/z	Relative Intensity
85.0785065	0.43
95.9045105	24.28
110.0972748	0.13
111.0758057	0.07
115.8277893	0.48
116.5234375	0.14
126.0615082	0.96
128.0343170	7.02
128.9625397	0.83
132.8177185	0.18
135.1584473	0.09
138.0408173	3.30
139.9157257	0.67
141.9818573	48.81
146.0864410	0.65
147.2048340	0.61
156.1150665	2.63
157.9442291	94.22
159.1486816	0.46
170.0378723	0.52
172.0510101	4.67
173.9552155	1.28
175.3079071	0.91
182.1900177	0.62
183.0831909	0.13
187.9441986	1.87
198.0561371	0.06
200.0940247	16.70
201.9519196	100.00
217.9581146	19.27
218.9877930	5.70
232.1350098	0.56
243.2677765	0.92
244.1399384	8.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2875
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
153.1158752	1.65
155.3960114	3.25
156.0810547	3.92
167.1856689	2.29
173.2941742	1.48
187.3128052	12.42
189.2985535	4.16
194.9433746	3.08
198.9684753	2.44
200.1790619	4.21
205.2169189	2.60
207.1512756	5.89
229.1743774	4.68
242.4216919	6.81
245.3366089	5.45
263.678833	4.72
281.1732788	9.77
285.3633728	8.65
295.0263367	9.87
298.0462341	2.89
301.4393311	19.30
311.3056946	5.29
326.0782166	1.65
333.6524963	3.89
339.6243286	5.61
344.7870483	5.29
357.0955811	14.77
359.2767334	3.91
366.0749207	4.85
367.2147217	8.44
367.9172058	5.47
369.8564758	7.74
379.5527954	4.49
380.3561096	3.87
385.156311	5.18
385.9994507	2.76
390.5983887	16.40
391.3520508	4.97
395.4612122	5.79
396.17453	3.44
397.0830383	10.28
398.2096863	6.41
400.3815613	6.23
407.469574	40.35
408.2865295	100.00
409.3939209	31.97
417.0826416	4.05
419.2243347	2.56
426.4218445	10.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	367.1033
Annotation	3-O-Feruloylquinic acid
Peak:m/z	Relative Intensity
107.8084183	0.07
109.0216675	0.04
110.2989655	0.06
111.0896072	0.28
112.9135284	0.27
115.9903107	0.09
118.9720306	0.04
125.1548615	0.06
133.9989014	1.28
136.9484253	0.70
141.9287109	1.74
143.1510925	0.19
144.4151917	0.03
149.0949707	0.49
152.9652405	0.04
155.0617981	1.92
158.1486511	0.28
172.9589233	100.00
179.1400299	0.04
186.0249176	5.74
186.9878540	0.56
187.9400482	0.04
191.1804352	0.09
193.0108337	21.42
200.2259827	0.11
204.1308899	4.33
205.1233368	0.65
217.8443756	0.32
237.2347412	0.07
246.1169128	0.73
247.1666260	0.04
248.8483887	0.03
270.6652222	0.06
272.1231995	0.02
276.9921570	0.06
285.2011719	0.03
307.0463562	0.19
310.1502991	0.18
321.1446533	0.04
323.0908203	0.16
328.2232056	0.07
347.1423340	0.29
349.1936951	0.06
350.0929260	0.12
351.9316406	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1014
Annotation	Scopolin
Peak:m/z	Relative Intensity
117.0310516	0.23
135.0756836	0.47
144.9509277	3.07
147.0325165	0.04
162.9504700	100.00
165.0524597	0.02
169.0670166	0.01
172.8010254	0.02
180.9069824	0.17
193.1026154	0.39
205.1644745	0.03
298.0572510	0.03
307.4695435	0.02
308.7686768	0.04
313.6916504	0.06
323.1712952	0.05
326.7558594	0.18
337.1304321	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0562
Annotation	Quinic acid
Peak:m/z	Relative Intensity
56.8532982	0.59
58.8979721	3.18
61.0444870	0.35
69.0090332	0.19
70.9397125	6.38
72.9848633	1.24
81.0834503	0.86
82.9632874	2.76
84.8813477	82.37
86.9321747	18.15
92.9642334	47.32
96.0743713	0.34
99.0193787	3.37
101.0392914	1.55
108.9558258	20.68
110.9421997	59.88
112.9129639	0.39
115.1106873	1.86
119.0574951	0.22
126.9969330	100.00
129.0946045	1.80
130.9503021	1.28
135.0231781	0.40
136.9994354	1.54
142.9942474	1.86
144.7999420	1.74
147.1307831	0.86
152.9347839	6.94
155.0064545	10.75
171.0276947	19.00
172.9586792	84.79
176.0130768	0.46
191.2326660	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	530.1339
Annotation	Unknow
Peak:m/z	Relative Intensity
157.0324860	0.57
174.8387451	0.11
183.3349915	0.30
186.7366333	0.17
190.9804993	0.23
197.2177734	0.11
205.2190857	0.55
206.4634552	0.22
207.1388550	0.07
212.0870972	0.13
215.0454712	0.19
217.0825500	0.12
220.1337280	0.06
226.0932770	0.25
229.1885071	4.91
230.2843933	0.18
242.0598145	0.53
243.2024536	0.29
245.2007904	0.11
245.9149170	0.08
247.1083679	1.10
248.3392181	0.28
259.1914062	0.20
260.5910645	0.33
272.8633423	0.19
274.1121216	0.33
275.0377808	0.15
277.0823364	0.20
288.1366577	0.07
290.0167236	0.13
291.1650391	0.21
292.6339111	0.15
299.3215942	0.08
301.3506775	0.07
302.2249756	0.07
307.2211304	12.29
308.1069336	1.03
313.9751587	0.39
314.9613647	0.08
316.2924805	0.15
319.6615601	0.67
323.1609497	0.30
327.5217896	0.17
329.4948730	0.19
330.1799927	0.09
331.3396606	0.29
332.4021606	0.15
333.2821655	0.23
339.1329346	2.23
340.2305298	0.27
342.0223389	0.10
343.2869263	0.24
344.4712524	0.10
350.3341064	0.47
352.9084473	0.06
355.3255005	0.15
356.1458740	0.08
358.2593994	1.75
360.2188721	0.20
363.4273071	0.06
367.2281494	0.61
370.5978394	0.70
373.0667114	0.18
374.4278564	0.13
380.3153076	0.07
381.2078857	1.55
382.3062744	4.96
383.8174438	0.19
386.1459351	0.06
387.5367432	0.08
388.9005737	0.28
394.9870605	0.60
395.9953003	0.79
397.1256714	0.19
398.1015625	0.67
399.2208252	0.47
400.0866699	0.10
401.0403442	0.34
403.4421997	0.79
411.2915649	0.34
412.6634521	0.25
414.1010742	2.37
415.1801147	2.44
416.1220093	0.40
418.3676758	0.91
422.3944092	0.20
423.4390869	0.15
424.8710938	1.89
427.1292114	1.01
429.4465332	0.10
433.3367310	5.07
434.1237793	0.13
435.3756104	0.19
436.4266357	12.42
437.1920776	5.31
441.3837280	0.21
443.1998291	0.05
444.2346802	0.19
445.5316772	36.97
446.2227783	9.09
446.9378052	0.08
449.2344971	0.54
454.3035278	100.00
455.1198120	4.20
461.7203369	1.16
463.3886108	1.10
464.3187866	0.57
466.9411011	0.14
470.6243286	0.23
471.9885254	0.62
473.7124634	0.46
479.1967163	0.11
480.5438232	0.16
483.1520386	0.16
484.3690796	0.33
486.4577026	0.18
492.3093262	2.34
493.0759888	0.06
494.3639526	1.47
497.2688599	0.46
501.3471680	0.10
503.2670288	1.24
505.9997559	0.16
507.8519897	1.02
510.3552246	0.37
512.1774902	14.84
512.9473267	0.53
514.4790039	0.28
517.7427368	0.17
520.0969238	0.59
521.3287964	9.16
522.9387817	1.18
545.2994995	0.09
546.2927856	0.08
547.1173096	0.15
549.2376099	0.11
566.4141846	0.47
569.6190186	0.41
578.3306274	0.22
581.4022827	0.20
584.2915039	0.19
585.2438354	0.31
587.4149170	0.17
595.3801270	0.27
597.8200684	0.57
599.1571655	0.16
601.0643311	0.66
606.7428589	0.20
607.9163818	0.38
613.0892944	0.76
613.8076782	0.44
616.2374878	0.18
621.4927979	0.31
630.4028320	0.35
631.0888062	0.37
631.8552246	0.58
633.7120361	0.62
639.4531860	0.59
643.4660034	0.59
644.3697510	1.24
648.9208374	0.43
650.0228882	0.26
650.6846924	0.20
655.0794678	0.55
656.2469482	2.25
657.0275269	0.37
659.2151489	0.52
671.0568848	0.20
672.2425537	0.41
681.1056519	0.28
682.5067749	0.25
688.5302734	0.89
691.2065430	0.26
692.7969360	0.17
695.5830688	0.10
703.3413696	0.16
707.2698364	0.11
709.3941040	0.31
713.0682373	0.35
715.4609375	0.19
718.1359863	0.10
728.6384888	0.31
729.6157837	0.82
734.1781006	0.83
735.4204712	0.17
737.3010864	0.43
746.2753906	0.67
747.3755493	0.66
748.1755981	0.08
751.3002930	2.04
752.4521484	0.65
753.1781616	0.21
764.2857056	0.15
769.3136597	0.13
785.2134399	0.55
787.3863525	0.06
789.7169189	0.05
806.7526245	0.11
813.5156250	0.09
826.5388794	0.33
827.7343750	0.29
828.8515625	0.37
830.3789062	0.50
831.1902466	0.06
832.7742310	0.10
847.4633789	0.87
848.4884644	0.66
853.1531372	0.20
854.6000977	0.08
855.5121460	0.40
859.5751343	0.06
864.9658203	0.15
868.6058960	0.07
872.4503784	0.21
873.2494507	0.61
885.3715820	0.17
886.2944336	0.18
887.9292603	0.10
889.1058960	0.76
890.3578491	4.20
891.2868652	2.02
892.1769409	0.86
903.2503052	7.03
904.3265991	1.87
905.2244263	1.08
907.3157349	4.92
908.3928223	1.90
909.3086548	0.13
928.6254272	0.50
1042.7786870	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	651.1127
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
215.2872925	0.22
218.9375305	0.06
233.2839661	0.03
235.9617767	0.18
249.0385895	0.15
285.2288818	0.12
294.1165771	1.53
295.0982056	0.25
300.4676819	0.08
307.4335938	0.12
312.0883484	1.11
318.0591125	0.04
324.9632874	0.09
326.0420532	0.37
326.8867188	0.11
328.2598877	0.04
336.1444702	0.30
343.0674438	0.23
344.1177979	0.21
346.0212402	0.58
350.8551636	0.09
359.9595947	0.27
362.7717285	0.08
370.1624756	0.17
378.0671387	7.29
393.0414429	17.54
393.6459351	0.27
398.5250244	0.05
404.4609375	0.06
409.3820801	0.03
428.0194702	0.13
429.2091064	0.31
430.5380859	0.06
432.8788452	0.41
439.1017456	0.09
439.7341919	0.08
446.2607422	0.04
447.2243652	0.13
449.2866821	0.12
462.3663330	0.07
465.1368408	2.95
467.3073730	0.05
478.2023926	0.05
479.5157471	0.21
484.9213867	0.06
486.3663330	0.07
495.3535767	0.16
498.9479370	0.09
500.9436035	0.06
504.1639404	5.00
505.0037231	0.78
517.3309937	0.07
522.1363525	100.00
522.7640991	0.38
527.2315674	0.16
531.4422607	0.04
534.3899536	0.11
536.7570190	0.03
540.1938477	0.08
553.0357056	0.04
558.1683350	1.57
562.7348633	0.19
569.7426147	0.19
572.2417603	0.06
576.2821655	0.50
587.4066772	0.09
593.8901978	0.03
606.0077515	0.09
614.1685791	0.79
615.1207886	0.87
616.0586548	0.61
616.6965332	0.04
620.5352173	0.23
633.1608887	27.06
634.3841553	1.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	619.1218
Annotation	Unknow
Peak:m/z	Relative Intensity
179.2048492	0.07
180.0208740	0.18
181.0944214	0.04
181.7123260	0.08
182.9378510	0.04
184.1441345	0.11
194.2673798	0.03
199.1202240	0.02
200.0183258	0.18
205.0718689	0.03
211.2619781	0.03
214.1338654	0.04
215.0184631	0.06
220.1638336	0.16
221.7109985	0.08
226.1105652	0.52
227.2142792	0.15
229.0539093	0.32
239.0111847	0.07
240.8127441	0.04
242.0998840	5.86
243.1877136	3.60
243.9004669	0.03
245.0888672	0.13
246.9826508	0.62
247.9865570	0.40
250.2453918	0.05
254.0925751	0.05
256.1835327	0.16
258.0414734	0.05
259.1345520	0.09
260.0064392	0.06
261.0076294	0.12
265.2207031	0.07
266.3786621	0.16
268.2088928	0.04
273.0899048	0.24
274.2049561	0.11
275.2388611	0.14
276.3002319	0.06
277.0950317	0.07
278.0056763	0.03
279.0944824	0.74
280.0961914	0.32
282.1642456	0.17
285.0259705	0.03
289.3241577	0.12
290.1015625	0.33
291.1028442	0.28
296.8946228	0.32
298.2241821	0.19
299.9910889	0.03
304.8445435	0.15
306.0497437	0.83
307.2600708	2.17
308.1977234	0.04
309.2687988	0.14
310.2491455	0.28
313.9641113	0.14
315.4277954	0.14
316.4357910	0.07
319.3188171	0.04
321.9768066	0.71
323.0767212	0.16
323.9521484	0.09
325.2095032	0.10
330.3358154	0.14
332.1677246	0.34
333.0921631	0.09
337.0976562	0.43
339.1561890	12.89
340.1369019	0.09
344.0416260	0.56
344.8367920	0.02
355.2719727	0.11
356.2225342	0.11
357.1840210	0.03
361.2525024	0.02
363.9943237	0.26
365.0297852	0.03
366.3461914	0.03
369.9951172	0.08
370.9791870	0.54
371.6726685	0.05
374.0272217	0.17
376.2476807	0.08
379.0574341	0.16
380.0308838	0.12
383.1246338	0.05
384.1554565	0.20
388.9404297	0.11
391.1266479	0.18
392.7866211	0.32
396.2001343	0.61
397.3536377	0.28
398.5656128	0.15
399.4349976	0.05
403.1437378	0.07
405.9030151	0.16
408.8115234	0.09
411.3013306	0.16
414.3391113	0.18
422.2469482	0.20
423.4804688	0.02
425.2576294	0.02
426.1519775	0.25
427.3792725	0.07
433.2913818	0.03
436.2737427	0.18
437.1469727	0.31
438.2623291	0.06
439.1535034	0.31
440.2316284	0.34
441.0225830	0.08
446.2195435	0.17
450.9964600	0.03
454.2108154	0.08
457.1984253	15.91
463.5422974	0.15
464.2506104	0.46
469.0483398	0.10
470.2385864	0.25
471.4126587	0.17
472.4694214	0.02
473.3623047	0.37
477.4155273	0.27
482.0765991	0.38
484.1349487	0.21
485.8710938	0.20
486.4851074	0.07
487.2922974	0.06
488.0183105	0.04
489.2299805	0.04
492.2408447	0.10
493.1384888	0.47
494.2811279	0.38
499.1848145	4.27
500.0802002	0.41
501.2147827	0.11
502.2113037	0.30
504.1130371	0.03
505.2440796	0.93
506.2463989	0.41
507.1572266	0.10
508.8417358	0.06
511.3036499	0.24
512.2503662	0.34
517.2566528	0.15
518.3180542	1.13
520.1619263	0.48
521.3191528	0.35
523.1847534	1.11
524.3349609	1.52
525.2120361	0.36
529.2180786	20.12
530.1686401	0.59
531.2251587	0.09
532.0509644	0.09
535.2601929	1.78
536.2256470	0.08
537.0819702	0.26
537.9692993	0.54
539.2357178	0.23
540.4149780	0.39
541.3198853	1.19
542.2348022	0.80
543.1885376	0.16
545.7965088	0.16
548.0798950	2.30
549.0134888	0.15
550.2896729	0.29
552.1624146	0.02
553.3407593	10.50
554.1575317	0.16
557.5851440	0.12
559.1932373	100.00
560.2568970	2.03
561.1455688	0.08
565.0876465	1.62
566.2544556	17.45
567.2168579	0.24
571.1822510	0.15
573.2354126	1.24
574.0178223	0.04
575.4932251	0.08
577.0921021	0.40
578.7850952	0.52
583.3164673	15.57
584.2088013	31.72
585.0847778	0.78
587.6777954	0.19
589.2011108	0.64
591.0239868	0.04
601.2064819	49.15
602.1764526	2.24
609.2925415	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	705.1826
Annotation	Lactulose
Peak:m/z	Relative Intensity
200.9757538	0.15
272.6036987	0.02
346.1636353	0.09
362.2026978	0.36
363.1018677	5.00
364.1862793	0.02
381.1922607	8.48
453.1859131	0.17
483.1791382	0.14
502.6271973	0.05
525.2076416	21.70
533.4425049	3.22
543.2100220	100.00
544.3296509	0.11
555.5700073	0.10
615.5697021	0.42
645.2474365	0.66
669.3214722	0.10
687.2717896	0.98
704.8777466	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	274.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9152374	5.37
115.9687653	2.84
116.8693542	3.27
130.9849701	0.04
131.8431091	0.05
133.0479126	0.17
158.9413757	100.00
159.9649963	52.32
160.8907013	63.38
174.0436554	0.05
198.8040161	0.02
199.8719482	1.57
200.9567566	3.12
202.8805847	0.04
217.1759644	0.05
217.9618225	0.48
219.0675354	1.58
229.9095154	20.83
230.9722290	30.25
246.0117188	0.45
247.0467834	0.90
257.0213623	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	941.4553
Annotation	Unknow
Peak:m/z	Relative Intensity
326.7612915	0.19
366.2507324	0.67
395.2449951	0.32
397.9600830	0.29
407.1808472	0.43
437.5471191	0.40
440.1613159	0.41
481.0552368	0.39
493.2844849	0.68
530.8873901	0.38
537.3450317	0.30
555.4083862	1.94
556.4558105	0.24
559.2082520	0.38
567.1293945	0.36
571.4144897	0.49
580.9915771	0.65
587.3266602	0.09
616.6808472	0.21
618.2543945	0.15
619.9378052	0.26
627.3086548	0.54
652.7767334	0.38
653.9898682	0.44
655.8464966	0.23
658.3466797	0.13
666.4183960	0.64
668.2489624	0.22
684.3325806	0.70
685.4852905	0.27
695.2948608	0.18
698.7064819	0.56
700.0380249	0.28
700.8078613	0.44
705.5379028	0.39
714.6591187	0.29
723.5408325	0.07
729.3701782	0.71
735.5105591	0.24
741.3092651	0.23
742.6809692	0.14
747.6618652	0.16
753.4895630	0.15
762.5508423	0.32
769.8014526	0.38
771.3184204	1.80
777.4816284	0.13
783.0653687	0.16
784.6500854	0.23
794.3619385	0.18
798.5811768	0.26
812.5781860	1.87
813.3839722	0.46
836.2014160	1.41
837.2484741	0.18
839.6372070	1.25
842.5460205	0.95
845.7228394	0.49
849.6743164	0.26
851.5283813	0.83
852.5985718	0.12
853.4592896	0.60
854.4105225	0.35
856.1911011	0.42
856.9363403	0.67
858.6511841	0.17
861.4525757	0.87
862.8551636	1.91
863.5002441	0.07
865.7780151	3.51
867.0735474	0.54
868.1677856	0.81
869.0048218	2.15
869.8411255	0.24
870.8548584	0.13
874.3301392	0.31
877.6704102	1.84
881.4542847	0.16
888.5082397	0.88
894.4298706	0.39
896.8802490	2.61
897.6751099	0.72
898.6986694	1.69
899.8770142	0.84
901.6875000	4.92
902.9428101	1.55
904.6571655	0.18
906.7904053	0.20
907.9738770	0.12
910.7730103	0.11
912.2581177	0.09
918.1868286	0.23
919.4926758	12.03
920.1337280	1.43
921.2418823	0.49
923.6929321	0.12
924.5325317	0.06
927.1817017	0.86
956.0735474	0.52
956.7681274	0.33
959.2310181	0.32
960.1287231	0.32
963.3955688	0.29
967.7419434	0.45
968.3429565	0.51
972.3759155	0.25
976.4140625	1.22
978.5517578	0.48
984.6088867	1.99
985.5388794	0.67
1012.2337040	1.50
1017.2167970	0.28
1019.3463750	0.91
1020.2824100	2.54
1021.8195800	0.34
1023.0256960	0.57
1035.3747560	0.18
1036.6428220	0.22
1045.8034670	0.57
1047.7604980	0.58
1068.0209960	0.80
1068.6220700	0.07
1070.6942140	1.37
1071.5135500	0.75
1072.6906740	0.32
1085.3919680	4.86
1086.3549800	0.14
1103.3226320	0.41
1111.9069820	0.53
1112.6557620	0.71
1113.3582760	0.28
1122.4890140	0.19
1125.9102780	0.24
1139.1959230	0.52
1139.9663090	0.10
1140.8494870	0.28
1145.9495850	5.39
1146.7268070	0.89
1148.1596680	1.55
1149.8374020	2.46
1150.5292970	0.47
1154.8547360	1.19
1158.5747070	0.22
1159.6550290	1.52
1160.5972900	0.79
1161.6580810	0.57
1163.7664790	1.52
1164.4833980	0.17
1165.1485600	0.10
1169.5924070	100.00
1170.6226810	3.06
1171.5834960	1.16
1172.7397460	0.60
1173.3891600	0.19
1175.7065430	0.40
1176.5051270	0.27
1177.3422850	0.15
1178.5454100	1.85
1179.3867190	0.18
1183.5864260	0.48
1187.5397950	0.16
1193.3779300	0.79
1208.8044430	0.84
1209.7064210	0.37
1211.9338380	0.21
1213.5588380	0.78
1219.2358400	0.11
1225.7194820	6.44
1231.6098630	0.91
1258.3581540	0.15
1262.1320800	0.26
1262.9458010	0.42
1288.6690670	0.87
1297.7401120	0.22
1298.4353030	1.03
1303.0300290	2.07
1311.9984130	0.12
1337.6998290	0.51
1339.7209470	0.20
1347.4007570	1.80
1348.2166750	0.49
1353.4848630	0.41
1381.9016110	0.10
1399.0638430	0.26
1411.6964110	1.75
1412.6844480	0.74
1431.7742920	0.33
1448.5718990	0.53
1466.4876710	0.38
1467.2879640	0.28
1470.6141360	0.13
1476.2646480	6.03
1477.3881840	1.49
1523.3129880	0.16
1530.7908940	0.40
1556.1289060	0.09
1577.3680420	0.14
1596.6318360	0.09
1635.7152100	0.40
1669.9622800	0.38
1695.1141360	0.21
1695.7160640	0.11
1726.9113770	1.75
1732.5147710	0.15
1750.1905520	0.59
1767.2625730	0.39
1771.6041260	0.74
1800.8679200	0.07
1822.3029790	0.11
1826.8272710	8.12
1829.6441650	0.20
1830.9737550	0.45
1839.5545650	0.08
1848.3057860	0.07
1849.4998780	0.48
1855.6190190	0.35
1862.1602780	5.37
1869.6859130	0.38
1872.8785400	8.19
1882.1456300	0.14
1884.1759030	0.89
1887.6612550	14.56
1897.8905030	0.12
1902.4011230	0.05
1908.9471440	4.38
1913.5694580	0.12
1914.3024900	0.62
1924.9167480	0.09
1927.6726070	0.95
1930.7443850	0.23
1942.0726320	2.97
1942.9971920	1.03
1949.7908940	0.76
1950.7076420	2.30
1951.5206300	0.12
1954.4783940	0.10
1955.8215330	1.27
1957.4525150	1.77
1964.3746340	0.46
1967.1353760	0.23
1968.6799320	2.94
1969.7801510	1.84
1970.8552250	1.09
1971.8524170	1.41
1973.2037350	0.32
1978.4787600	48.63
1979.3327640	8.52
1981.4095460	5.58
1986.5665280	0.11
1991.5125730	0.27
1993.7014160	0.13
1995.2366940	0.12
1996.9971920	1.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	193.0508
Annotation	Speciosin D
Peak:m/z	Relative Intensity
85.9379578	0.03
104.9606628	0.12
106.1729889	0.02
106.9490356	0.14
116.9830780	3.48
121.1828461	0.06
133.9563904	100.00
134.9696503	0.03
145.0316620	0.03
147.0876617	0.24
148.9794159	34.13
157.0302124	0.11
158.8354645	0.03
165.2739563	0.03
175.1340942	0.02
177.9878845	2.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	158.98
Annotation	Unknow
Peak:m/z	Relative Intensity
70.8343506	0.06
92.9951935	0.05
113.0280762	0.04
114.8570404	100.00
115.6798096	0.02
128.7711945	0.23
130.9384308	5.02
140.9363556	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	277.1024
Annotation	C20912
Peak:m/z	Relative Intensity
83.9160995	1.35
84.8951492	0.24
101.8770447	3.18
129.9185791	13.45
130.9204712	0.29
142.9102478	0.05
147.9945984	100.00
150.1783600	0.11
158.8890991	0.52
167.0216217	0.08
175.0286865	0.15
184.1074524	0.25
196.8907776	0.09
202.3321533	0.43
206.1666870	0.15
214.0745239	3.94
216.7389221	0.23
221.2857666	0.22
222.8099670	0.06
231.0269470	0.96
233.2574158	0.25
235.2399902	2.53
236.1522522	0.10
238.5589294	0.50
239.9841919	0.08
240.9049683	0.11
242.1948547	0.06
247.1713867	0.13
248.9919434	0.28
259.0706787	8.07
260.1121826	8.86
267.7474365	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	475.0729
Annotation	Unknow
Peak:m/z	Relative Intensity
132.7048035	0.02
148.1571655	0.06
196.4467163	0.09
201.9141846	0.04
202.8124542	0.04
206.9625854	0.08
209.1798859	0.03
213.1515656	0.11
214.4757996	0.05
220.0292053	0.10
220.9294128	0.04
226.4580688	0.04
227.1012268	0.05
235.8143463	0.15
237.5663757	0.10
241.9210815	0.08
244.1326752	0.08
245.1486969	0.08
258.3756104	0.03
262.1431274	0.20
263.9158936	0.30
265.0493164	0.18
278.2735596	0.06
281.9871826	3.72
283.0526123	1.53
285.0239868	0.03
293.8403931	0.46
294.7195129	0.23
306.1013184	0.11
307.3460388	0.03
310.3402710	0.03
319.0617981	0.04
324.1282349	0.21
325.2215881	0.13
328.5188293	0.08
332.0711670	0.05
332.9454956	0.08
337.3105469	0.05
342.2610779	0.61
343.5739746	0.25
344.2030029	0.03
347.0045776	0.03
350.0769958	2.67
351.1291809	2.12
360.3396606	0.02
361.6647339	0.16
362.9593506	0.16
368.9689636	0.07
379.9508057	0.24
380.7551575	0.03
382.2306213	0.06
385.3598633	0.13
394.3339233	0.04
397.2710266	0.03
403.2799988	0.07
410.7820740	0.09
412.9436951	0.02
415.0376892	0.05
420.3823853	0.04
424.9109802	0.12
430.7896729	0.07
437.1785583	0.19
439.0584106	100.00
439.6862488	0.47
440.5171814	0.06
447.0587463	0.10
455.9857788	3.71
457.0840759	11.94
458.3744202	0.23
470.0062866	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	562.3147
Annotation	Unknow
Peak:m/z	Relative Intensity
213.2887573	0.11
231.4183502	0.15
242.0374756	0.08
244.9644012	0.03
263.0477600	0.08
275.1272583	0.04
277.2784424	1.41
279.1425781	0.04
282.1660767	0.06
286.0057983	0.07
291.2168579	0.07
332.1291504	0.05
335.1359863	0.03
349.0822754	0.08
377.3810425	0.05
392.0905151	0.22
406.3955078	0.13
410.5625000	0.19
414.5393066	0.13
416.5375977	0.10
428.1220093	0.24
432.3318481	0.06
448.4868774	0.09
459.3382568	0.13
465.4677124	0.03
466.4194946	0.35
472.3588257	0.38
476.3026733	1.05
476.9448242	0.05
477.6541748	0.45
478.2967529	0.51
481.5065308	0.21
488.5484009	0.08
500.2219849	0.14
501.8052368	5.57
502.4345093	100.00
503.4651489	0.80
516.2504883	1.57
524.2130737	0.39
526.1183472	0.20
540.5117798	0.07
542.5457764	0.20
543.3519897	0.25
544.3466187	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	474.06
Annotation	Unknow
Peak:m/z	Relative Intensity
141.9419708	0.19
145.0314484	0.21
169.9989319	0.34
185.1369324	0.21
199.8467102	0.18
210.9586182	1.16
212.0518036	0.28
212.9726257	0.37
213.6856842	0.16
220.1600189	0.20
226.1538544	0.73
230.1175232	1.65
235.9228516	1.86
237.4515076	0.30
244.2533722	1.08
245.3379364	0.34
250.1599731	0.29
260.0603027	0.14
262.0825500	0.11
263.8777771	6.85
276.2733154	0.68
279.8886414	0.63
281.9767456	86.01
288.8316956	0.19
291.6416931	0.19
292.8883057	1.56
293.8319397	10.82
304.9882812	0.16
307.8932495	1.09
308.8114929	0.39
316.6222534	0.19
318.0266724	0.46
324.1739197	7.02
326.1390381	0.57
326.8803711	0.33
331.0902710	0.75
332.0878906	3.49
337.0374756	1.47
341.1733398	0.92
342.1590881	3.81
343.8335876	6.06
350.0626526	79.27
350.6676025	0.25
352.2012939	0.18
357.3075562	0.33
359.3075562	1.04
361.8637085	3.93
368.0417175	0.40
368.8960571	0.48
374.6708374	0.94
375.8743286	0.51
380.0797729	1.62
384.0606384	0.25
393.1507874	1.68
395.7714539	0.50
398.9650879	0.40
410.4939270	0.81
414.6679993	0.44
426.2745972	0.09
430.6068420	0.58
432.6127014	0.55
437.1246338	4.22
438.0989990	22.66
439.2631836	0.78
445.5291138	0.19
454.1598816	0.16
455.9731750	100.00
456.7143555	0.99
457.5027466	0.72
483.3595886	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	676.8519
Annotation	Unknow
Peak:m/z	Relative Intensity
222.1091003	0.49
239.1506348	0.18
256.0985718	0.48
257.1672363	0.31
282.3989868	0.38
283.9667664	2.14
302.2521667	0.20
317.0393677	1.78
317.6670532	2.73
318.3765869	0.54
334.3918152	0.61
335.4145508	1.14
351.4490356	0.12
353.1546021	0.38
358.3054199	0.22
368.2969971	0.54
368.9847412	0.24
370.4622192	1.81
380.9813843	0.20
397.7467651	3.15
399.4904785	0.52
414.0610962	0.87
427.4218750	0.43
428.1864624	0.22
431.1169434	0.32
442.0293579	1.80
445.4540405	3.23
446.1828613	0.30
454.2736816	0.18
463.8488770	0.92
472.8555298	0.20
478.7531128	2.44
479.3823242	1.77
482.4016113	0.38
488.5663452	1.05
497.7289429	0.98
499.6190186	1.74
505.3607788	1.19
506.4793091	0.23
511.5879517	0.22
515.8474731	0.45
517.1462402	0.15
518.5667114	2.28
521.4578247	1.35
526.7355347	2.91
529.9993896	0.92
532.0274658	0.61
534.3014526	3.03
535.2647705	1.68
536.1077271	3.03
554.4802246	0.68
555.5240479	0.24
557.4727173	1.28
574.0105591	1.08
575.9937134	1.88
583.0446167	4.26
584.1043701	1.35
591.8710327	0.42
597.5138550	1.08
602.9159546	1.18
608.4065552	0.45
617.2495117	1.86
620.7802734	3.23
621.6429443	0.96
622.7667847	1.17
625.4843140	13.99
626.3272095	12.01
628.8804932	0.36
630.5780029	32.47
631.5510864	7.34
632.1614380	1.03
633.5065308	0.34
634.1472168	0.74
639.5863647	100.00
640.5673828	12.89
641.5464478	0.52
648.3558960	3.23
649.4880981	1.45
659.2649536	2.36
666.4110107	1.67
668.0736694	6.19
668.8132935	3.25
669.7302246	0.37
687.5413208	0.22
705.2549438	1.48
706.3231201	1.17
744.5623779	2.01
745.5891724	2.12
748.9257202	1.40
749.6569214	0.31
752.2305298	0.85
753.4996948	0.82
762.2993164	0.19
768.3740845	2.52
770.3650513	0.36
779.4280396	4.46
780.4904785	3.64
781.7489014	1.01
795.1372681	0.72
796.2408447	0.32
797.3319702	0.20
798.3933716	0.48
804.9669800	1.17
819.5264893	7.81
820.4942017	0.70
844.2285767	3.68
863.4589844	0.62
864.5271606	0.69
880.1460571	0.44
881.4411011	5.19
883.5046997	1.69
891.4495239	0.55
906.5305786	1.19
908.4961548	12.82
909.5507202	4.10
910.4934082	2.13
928.6932983	0.45
939.7507935	1.87
956.4774780	9.27
957.4592285	2.16
958.7013550	1.56
978.1836548	2.18
994.2161255	0.62
999.4348755	0.71
1001.7976680	0.68
1008.4594120	0.70
1019.8850100	3.96
1020.5293580	0.18
1036.5156250	30.25
1037.5228270	8.17
1038.6812740	4.88
1053.6279300	0.90
1054.7082520	1.29
1069.7919920	1.86
1070.6571040	0.42
1071.4877930	0.89
1149.6347660	1.01
1164.0450440	0.90
1164.7418210	14.97
1165.6606450	6.24
1166.6486820	0.92
1314.1396480	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.0582
Annotation	Unknow
Peak:m/z	Relative Intensity
175.1379852	0.07
178.9057465	0.10
187.1469116	0.05
213.2443237	0.07
217.8020782	0.11
237.0676575	0.07
250.7473145	0.07
255.2019348	0.08
273.4114380	0.09
278.1373291	0.05
282.9570312	0.05
284.2821045	0.16
287.3248901	0.11
295.1333008	0.06
299.1571045	0.27
301.1492920	7.90
302.1937256	1.05
303.1793823	0.07
307.1209717	0.05
313.1848145	0.07
317.2773438	0.16
323.0668945	0.20
327.3083496	0.07
365.2212524	1.13
382.9795532	0.05
395.4078979	0.13
397.3638306	0.05
399.1668091	1.47
400.2683716	0.74
407.1757812	0.08
412.9398804	0.08
423.2986450	0.14
425.2790527	0.39
437.3010864	0.08
438.1623535	0.09
445.1503296	4.65
446.2036133	1.15
448.4605713	0.14
451.0054932	0.04
451.7192383	0.04
463.1830444	25.60
464.2524414	5.52
467.5418091	0.03
469.2272339	0.07
471.3229980	0.08
474.2053223	0.28
475.0236206	0.49
477.6125488	0.09
478.4273682	0.30
490.0986938	0.05
495.2282104	0.33
496.4363403	0.13
498.2850952	0.08
499.3104858	0.07
506.9667969	0.07
511.4563599	0.10
517.1671753	0.09
518.3152466	0.40
519.9453735	0.06
524.1628418	0.12
527.2652588	1.93
528.1693115	0.30
529.2939453	3.96
530.6649780	3.37
531.2723389	36.86
532.2050781	12.76
535.3256836	0.13
549.2845459	1.55
550.1519165	0.10
551.1727905	0.07
552.5947876	0.24
558.3923950	0.08
559.4714355	0.08
561.1712646	100.00
562.1876831	30.60
563.1563110	0.07
564.0315552	0.20
575.0662842	0.03
575.8511353	0.12
577.1787720	0.38
577.9756470	0.42
582.0848389	0.05
595.7025757	0.04
596.9168091	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	490.0766
Annotation	Unknow
Peak:m/z	Relative Intensity
143.0673370	0.05
159.9734344	0.16
167.1549072	0.04
170.9754333	0.06
176.9689026	0.15
179.0574341	0.19
183.0003204	0.29
185.1297302	0.03
192.0084534	0.03
210.0338593	0.25
213.1445618	0.05
254.1683350	1.49
258.2075195	0.01
272.0934753	1.61
288.1076050	1.36
306.1003418	100.00
374.2171631	0.03
375.3182373	0.02
383.0391846	0.02
409.4894714	0.02
472.3233032	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.0987
Annotation	Unknow
Peak:m/z	Relative Intensity
129.9945831	4.32
159.0039368	0.51
176.9655304	1.10
193.8191071	3.32
203.9650574	0.08
237.9273071	0.15
244.7857056	0.22
261.1576843	0.07
261.9706421	0.23
277.2769775	0.10
279.0744019	2.18
283.1192017	0.15
289.2909851	0.22
297.0180969	100.00
314.8901978	0.09
322.8537598	0.32
344.0620422	0.14
351.1372070	7.36
351.8592529	0.57
361.7701721	0.89
363.1136780	0.10
380.9605408	0.37
383.9969177	0.07
390.3445435	0.58
398.5021667	0.09
407.4067078	0.15
408.1370544	1.02
409.2595825	0.55
417.2381287	0.19
417.8871765	0.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	657.1614
Annotation	Unknow
Peak:m/z	Relative Intensity
191.0963745	3.55
295.0070190	0.06
305.2214966	0.26
307.1773376	0.05
308.2693481	0.07
314.0226440	0.24
335.0112000	0.14
337.2776489	0.13
342.9716797	0.17
353.1495972	100.00
396.2449951	0.05
399.4970703	0.21
411.5041504	0.08
423.0674438	0.13
450.6398315	0.19
459.7244263	0.21
479.2684937	0.27
483.2815552	0.08
496.3059692	0.19
509.5374146	0.38
516.5250244	0.09
523.2004395	0.07
528.7002563	0.28
539.4725952	0.22
542.0574341	0.06
554.6437378	0.05
558.0737915	0.19
564.5314331	0.11
580.2822876	0.06
583.9194946	0.14
597.2329712	0.06
599.0797729	0.27
610.6419678	0.25
611.9812622	0.59
613.0325317	0.22
614.6671753	0.52
616.9533081	0.07
623.5455933	0.33
624.2780151	0.13
639.4353027	0.15
640.5858154	0.34
641.4556885	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	464.6801
Annotation	Unknow
Peak:m/z	Relative Intensity
178.8842468	3.18
202.2242737	0.41
232.0690613	3.50
233.1172180	2.66
234.0262756	1.55
251.3460693	0.90
275.1717834	0.57
289.0836792	7.45
306.9509888	19.33
308.1286011	39.61
309.2492981	3.29
341.1447754	0.83
384.7315063	0.46
427.4529419	0.74
447.3538818	1.12
448.9440002	1.84
621.3392944	100.00
622.4540405	61.60
623.4024658	20.23
624.4418945	3.63
910.0871582	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	786.1584
Annotation	Flavin adenine dinucleotide (FAD)
Peak:m/z	Relative Intensity
267.9840698	2.30
315.4851685	0.59
344.1980591	0.89
348.0645752	100.00
359.5352173	0.89
379.2572632	2.47
383.8199463	1.57
395.99823	1.30
407.5835571	1.50
421.3204346	1.89
422.3093262	1.84
439.1481323	84.22
456.7834473	1.19
460.4667969	1.24
461.4324951	0.77
470.055542	2.47
486.3330688	8.34
492.4115601	0.71
524.4759521	0.65
539.6222534	0.59
543.9542236	0.95
572.1702881	1.26
582.0502319	0.71
587.0316162	1.35
589.2556763	3.52
601.4282227	3.01
641.7866821	2.70
656.1473389	3.71
657.503418	0.72
663.0548706	2.47
671.7545776	5.86
673.3651733	3.23
724.3445435	1.60
725.8435059	1.25
732.0245972	2.25
732.6335449	4.16
738.5877075	0.71
740.0151367	7.51
748.5897217	4.45
750.4343262	3.02
761.0626831	1.26
765.2822876	1.76
767.3607788	4.11
768.1755371	4.62
773.1595459	9.16
777.2612915	5.42
780.0891724	1.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	319.1332
Annotation	Abbottin
Peak:m/z	Relative Intensity
96.9443283	0.03
117.8973541	0.29
127.9986420	0.27
129.8335419	0.78
136.1514587	0.05
146.1412964	0.14
148.1808777	0.04
164.2902527	0.11
167.1650696	0.09
178.9344788	0.10
185.1702271	0.04
189.0917969	2.99
190.1814117	0.33
195.1152496	0.11
199.3318024	0.05
200.0287170	0.58
203.1684265	0.04
207.1157227	0.07
214.9557800	0.06
223.3306885	0.17
229.2759094	0.09
233.1285095	0.09
235.0574646	0.08
239.2032166	1.07
241.0438538	1.08
254.2159424	0.06
255.3215637	0.31
257.3720703	0.19
259.1573486	8.16
265.0281067	0.06
268.0281677	0.06
273.2356262	0.52
275.1106567	0.40
277.1319580	100.00
283.2859497	0.04
285.1343689	0.28
289.0546875	0.07
301.1266174	1.07
302.3186035	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	682.93
Annotation	Unknow
Peak:m/z	Relative Intensity
212.9679871	0.85
215.0726013	0.32
255.0179443	0.26
270.7825012	0.07
276.8207397	0.07
289.2138367	0.71
290.0451355	0.21
291.0290222	1.18
292.6946411	0.40
294.6824951	0.32
318.9634399	8.56
320.0197754	1.76
321.0375366	6.94
339.1411438	0.26
340.2430420	0.08
353.0762329	0.04
358.0583496	0.22
359.0726318	0.36
360.1197510	0.15
371.3242188	0.28
376.8567505	0.11
378.4610596	0.15
380.4323730	0.05
382.9885254	3.96
383.9843140	1.54
385.0095825	3.62
391.1418457	0.16
395.7687378	0.08
396.9434204	0.12
401.0433960	13.09
402.0844116	7.43
403.1337280	17.81
406.9687500	1.67
407.9490356	0.47
408.8969116	3.15
410.8630981	0.09
414.0448608	0.11
421.0164185	0.57
422.2276001	0.31
422.9846802	1.99
431.0710449	0.10
435.0863647	0.17
437.0282593	6.15
437.9863892	6.19
439.0155029	27.06
440.0753784	3.02
440.9380493	8.78
448.2446899	0.12
454.9772339	0.57
455.6377563	0.05
457.0128784	2.68
471.2423096	0.20
478.3456421	0.05
486.9745483	0.13
500.7881470	0.75
502.9425659	5.49
504.3155518	0.11
506.3269653	0.09
507.0286865	0.07
508.2564087	1.38
508.9890137	0.95
510.2152710	0.13
512.6213379	0.03
519.0018311	20.24
519.9910889	25.79
520.9435425	100.00
527.7914429	0.07
531.1829224	0.23
532.2309570	0.58
533.1216431	0.19
542.9226685	0.09
544.5038452	0.04
546.3181152	0.80
547.0317383	0.36
553.2183838	0.17
563.0535278	0.72
568.0197754	0.05
568.9458618	2.22
569.9894409	7.43
571.0494385	13.70
571.6624146	0.22
595.3153687	0.23
598.8846436	9.40
599.5217896	0.06
601.5830688	0.10
604.5300903	0.27
636.9355469	0.75
638.8876953	7.68
640.0028687	13.43
640.8776245	0.48
647.0824585	0.05
659.3727417	0.48
661.7803345	0.06
663.9159546	1.34
665.1300049	3.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.34
Annotation	Unknow
Peak:m/z	Relative Intensity
193.0721283	0.24
199.1364594	0.07
219.0042572	0.08
223.2579498	0.07
245.1521912	0.06
255.3522949	0.64
258.3331909	0.15
291.4106445	0.13
330.3585815	0.15
347.5516357	0.25
348.2820435	0.04
355.4513550	0.10
374.9044189	0.12
379.5089111	0.06
397.5045776	0.09
399.7268066	0.15
409.3555908	0.06
413.3593140	0.54
423.7719116	0.14
435.8057251	0.14
451.6259155	0.08
455.3250732	0.11
467.3882446	0.06
473.3542480	0.17
479.3327637	0.30
505.5839233	0.11
509.6884766	0.16
516.2760620	0.28
517.4229126	100.00
518.0309448	1.05
519.0468140	0.55
525.2898560	0.13
527.3283081	0.46
528.3118286	0.21
530.7418823	0.24
534.8772583	0.14
535.8947754	0.08
544.9984741	0.76
546.4614868	0.14
548.1545410	0.14
549.4576416	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.2213
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
98.49008179	0.22
102.9912109	0.15
106.9107056	0.29
109.1438141	0.60
111.0578613	0.33
116.963028	0.36
128.919693	0.62
136.8563995	1.03
141.039978	0.69
143.0911255	2.49
146.9463196	0.69
151.0935974	0.83
155.1878967	0.60
159.088974	0.18
163.2096863	0.47
167.2060852	0.67
168.0399628	0.15
169.0688171	3.27
170.8988342	0.13
176.690979	0.15
177.3108063	0.20
179.9734955	0.37
181.1411591	0.74
182.9224548	0.50
187.0883179	0.35
191.3272095	1.65
193.2601776	1.48
194.7701111	0.68
197.1170654	1.93
198.1592255	1.08
198.9013367	0.40
209.2502136	0.57
211.0831299	3.47
213.2434082	1.11
215.4373474	0.49
217.1403198	0.44
223.2180481	0.29
225.1879578	0.78
227.083313	3.83
229.0718689	0.44
233.2845764	0.62
235.2269592	1.94
236.9045105	0.26
238.7537842	0.22
239.5887146	0.42
241.2716064	1.35
247.2846069	0.67
249.2233582	0.31
251.1726074	2.41
253.10672	7.73
254.9806213	0.94
257.1737976	0.33
265.1975708	3.18
266.1656799	0.77
266.9734497	1.28
269.0389404	0.45
270.1704712	0.19
271.1991577	0.45
275.1818542	13.24
279.0639954	0.58
281.3253174	1.83
283.1988831	1.97
293.204834	100.00
294.1798706	0.57
302.0622559	0.58
302.9376831	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.2212
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
95.22009277	0.27
122.5486145	0.19
125.0513153	0.23
128.9855347	0.30
130.6811523	0.76
133.1452484	0.84
137.0044708	0.43
138.769043	1.74
140.8839111	0.23
142.9814148	0.30
144.6842346	0.28
147.0784607	0.53
153.081604	0.15
153.9164429	0.34
155.0797119	2.11
157.0909119	0.90
163.1430817	0.17
164.9298401	0.71
166.9603271	0.82
169.2641602	0.34
170.9673767	0.48
177.1519165	1.30
179.1607056	0.60
181.2276917	1.66
183.0593567	0.89
185.0333099	1.49
190.7878265	0.36
193.0965576	0.64
195.1377411	1.85
197.1456757	1.50
209.2066956	0.25
211.0896912	2.32
213.1428223	0.45
217.009552	0.55
219.3338928	0.39
223.1036072	0.75
225.2917786	1.25
226.1164246	0.72
226.9810181	1.28
228.3309631	0.25
233.1897583	0.81
234.0581055	0.37
237.0927734	2.08
239.2091064	1.65
241.1546631	0.98
247.0743713	0.97
251.2404785	1.11
252.1956787	0.60
253.0087585	4.07
255.0118713	1.15
257.0610962	1.13
258.1808472	0.53
263.1474609	0.23
265.2858276	1.54
267.144165	1.03
269.3031921	1.43
270.3615723	0.30
275.230896	18.40
281.7558289	0.60
283.0206299	1.15
290.1861267	1.77
293.2079773	100.00
294.0664062	2.30
310.4317017	0.64
311.1893921	0.26
312.3018494	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1135.6188
Annotation	Unknow
Peak:m/z	Relative Intensity
388.3717346	0.07
430.2036743	0.11
457.3059998	0.12
473.4280396	0.11
503.5225220	0.05
517.3873291	0.04
518.4672852	0.04
528.6624756	0.44
572.5399170	0.36
598.4073486	0.08
600.8775635	0.18
604.3856201	0.41
616.6414795	0.10
625.4063110	0.48
634.4638672	0.25
651.6453857	0.06
675.7722168	0.33
684.9991455	0.20
698.6520996	0.31
719.3601074	0.11
728.6137085	1.61
731.4766235	0.28
745.7924805	0.11
754.7866821	0.09
757.5225220	0.19
763.4340210	0.82
772.6223145	0.27
793.4500122	0.25
801.5505371	0.17
802.4108276	0.22
817.4685059	0.03
819.5980225	1.72
827.5742188	0.12
830.5034180	0.04
832.4676514	0.90
858.4560547	0.05
863.5753174	1.02
874.3835449	0.16
876.5866699	1.03
887.6270752	0.17
897.3498535	0.16
915.6346436	0.07
928.7633057	0.06
931.3339844	0.08
933.5588379	0.19
957.6914062	0.05
960.8262939	0.25
972.4899902	2.78
973.9742432	0.16
976.6750488	0.17
998.5280762	0.53
1005.7142330	0.09
1015.6333010	0.25
1016.5175780	1.51
1029.6408690	0.12
1033.3293460	0.12
1042.5355220	0.29
1044.5908200	0.07
1047.5554200	29.24
1048.2177730	0.32
1073.6010740	2.28
1074.3818360	0.35
1091.0839840	7.26
1091.6888430	100.00
1092.5822750	0.04
1093.5541990	0.03
1094.5020750	0.11
1099.1080320	0.04
1100.7879640	0.21
1105.4946290	0.04
1116.2048340	0.09
1116.9730220	1.16
1117.6149900	3.77
1118.9501950	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	626.69
Annotation	Unknow
Peak:m/z	Relative Intensity
206.7222595	0.07
232.2593994	0.04
290.7496948	1.31
292.8078003	0.02
371.0659790	0.07
374.5895996	0.71
380.4094849	0.07
419.0026245	0.09
422.9865723	0.05
430.8052979	0.05
433.3234863	0.04
436.2003174	0.02
446.1348267	0.03
458.5997314	12.99
460.6361084	2.60
461.2716675	0.04
462.6183472	0.06
463.2360229	0.03
464.5391846	0.02
466.8623657	0.05
472.0093994	0.08
479.9895020	0.07
482.8109131	0.30
490.7324829	1.27
496.7162476	0.05
499.0154419	0.07
506.7994995	0.27
508.7368164	0.04
520.0532837	4.02
520.7021484	8.21
532.5391235	0.02
542.5337524	100.00
543.3200684	0.98
544.4082031	0.04
549.1196899	0.03
550.8015137	0.27
562.5582886	0.48
566.7435303	2.34
580.4226685	8.21
581.4157104	0.03
603.5320435	0.16
609.1840820	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	680.2172
Annotation	Unknow
Peak:m/z	Relative Intensity
211.3673096	0.07
226.2738037	0.21
234.0059204	0.33
265.0017700	0.18
286.0823059	0.45
303.1343079	1.40
317.0541992	0.14
326.0745850	0.17
327.1416626	0.21
329.8957520	0.13
337.1264038	0.66
342.9468994	0.16
344.2125244	0.39
354.2313843	4.66
355.1199341	16.76
356.2565918	5.32
367.2797852	0.47
368.1055908	0.16
369.3049316	0.26
372.1315308	100.00
373.1863403	35.94
373.8353882	0.06
396.0726318	0.33
414.3391724	0.60
415.1461182	0.78
417.3688354	0.24
426.9440918	0.15
427.7163086	0.83
429.0957642	0.74
431.5476685	0.29
432.2258301	0.25
433.1385498	0.09
438.4103394	0.71
439.1299438	0.14
444.2897949	0.22
448.9580688	1.12
454.3853760	0.06
463.6256714	0.29
464.4380493	0.16
465.2977295	0.97
470.0347900	0.36
470.8163452	0.07
480.3119507	0.23
482.3208618	0.53
483.4091187	0.29
491.3079834	0.20
492.8836060	0.46
498.2301636	0.83
499.1243896	0.49
500.5919189	2.10
501.4465332	0.08
516.3069458	2.50
517.2123413	2.00
518.1665039	4.53
519.2937622	4.37
520.3339844	0.30
524.1984253	0.77
525.2676392	0.11
534.1458130	38.44
535.1126709	22.50
536.6278076	0.84
542.0300903	0.11
548.1721802	0.23
552.0231323	0.32
556.9125977	0.38
560.1433105	0.53
576.6204224	0.28
598.5597534	0.12
605.3293457	0.89
606.5724487	0.19
618.7796631	0.10
620.2659912	0.35
621.1873169	1.22
626.4183960	0.76
627.2778320	0.62
628.0131226	0.54
635.8558350	0.31
637.9827271	0.19
641.2864380	0.95
644.2207642	0.25
645.3262939	1.41
646.8112183	0.20
654.4365234	0.16
662.2816772	5.89
663.2965698	4.88
671.7517700	0.81
681.5295410	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	655.2755
Annotation	Coproporphyrin II
Peak:m/z	Relative Intensity
219.0940857	0.03
230.2009583	0.03
232.5748444	0.03
247.1695709	0.02
266.4511719	0.02
267.3070068	0.02
269.1806641	0.03
280.0729675	0.08
283.2293091	0.02
285.0094604	0.02
291.6000061	0.01
293.2677307	0.04
301.2283325	0.05
307.3085938	0.03
311.2740479	0.05
313.3096313	0.05
324.2622070	0.06
326.1947021	0.03
327.2347412	0.06
329.4076233	0.05
335.0945435	0.03
343.5222778	0.04
355.3480835	0.06
356.6315308	0.02
361.2636719	0.07
370.6138916	0.08
372.4138794	0.05
383.1835938	0.04
387.7318115	0.03
389.1911621	0.02
390.5322876	0.06
402.6115112	0.04
403.6359863	0.02
411.3707886	0.02
416.5912476	0.15
417.4290161	0.05
427.4605103	0.04
429.2506104	0.08
430.4932861	0.21
432.3716431	0.18
435.4249878	0.11
440.3540039	0.06
441.3537598	0.05
443.1503296	0.03
444.4816284	0.14
445.3851929	0.06
448.7355957	0.05
449.3401489	0.02
455.4339600	0.04
456.3902588	0.06
458.7882690	0.05
460.4488525	0.08
462.2945557	0.07
473.8287354	0.02
479.5444336	0.01
488.3895264	0.03
492.2137451	0.02
501.5005493	0.06
509.2827148	0.12
519.1450195	0.09
520.3988647	0.02
521.2623901	0.44
522.1535034	0.04
522.7694702	0.07
524.3493042	0.02
525.2239380	0.03
529.5584106	0.07
532.9471436	0.02
534.6248779	0.04
535.4992065	0.09
536.1588745	0.05
536.7987061	0.05
538.7713623	0.06
540.6094971	0.01
542.0769653	0.03
547.4747925	0.03
549.1725464	0.11
550.7416382	0.06
551.5516968	0.19
553.2481689	0.42
554.5972290	0.09
558.3851929	0.10
561.6233521	0.12
563.3350220	0.52
565.4133911	2.56
566.4872437	0.16
567.3302002	0.89
568.4480591	0.39
569.2235107	0.03
573.6114502	0.05
577.2695312	0.05
579.3656616	1.90
580.4436646	0.09
581.4468994	0.72
582.7632446	0.10
583.5158081	1.63
585.3291626	88.56
586.0209351	0.18
588.8044434	0.05
591.3263550	0.15
593.5681152	0.27
595.4046631	14.38
596.4638672	1.22
598.2891846	0.04
599.4815063	0.35
600.6310425	0.07
601.6606445	0.04
604.2813110	0.08
605.2251587	0.54
608.6831665	0.23
609.3331909	2.96
611.3633423	3.92
612.0662231	0.06
613.3078003	6.14
614.2378540	0.13
618.5361938	0.10
619.4090576	0.09
622.5723877	4.77
623.4021606	15.57
624.5497437	0.59
627.3065796	100.00
636.7290649	2.15
637.3547974	4.48
638.3510742	0.84
639.4127808	0.05
656.0686035	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	687.3016
Annotation	Mombasol
Peak:m/z	Relative Intensity
245.2554474	0.26
305.2792969	1.70
359.4644165	0.32
366.7628174	0.66
381.2006226	0.29
416.1933594	0.29
427.1173096	0.44
435.6947632	0.27
471.4179688	0.72
511.6846924	0.24
525.5295410	0.44
535.6348267	0.22
539.8329468	2.07
550.9903564	0.64
552.6185913	0.62
562.1654663	0.38
567.0740356	1.15
579.6135864	0.31
582.2470093	1.35
585.1112671	0.44
593.4089966	1.87
597.0125122	0.27
599.4039917	24.52
601.2561646	0.67
605.2344360	0.43
611.2542114	32.34
614.4566040	0.55
622.3439331	0.76
625.2007446	1.82
626.5683594	0.65
627.3386841	1.27
637.4633179	1.17
641.2854614	0.48
643.3971558	100.00
649.6177368	0.35
650.2985229	0.56
651.3302612	0.41
655.1525269	87.84
655.9456787	0.38
658.5401001	0.74
659.6637573	0.86
668.4351807	0.52
669.1830444	1.65
670.5944214	0.54
672.3696899	0.18
678.4368286	1.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	784.71
Annotation	Unknow
Peak:m/z	Relative Intensity
299.8665466	0.23
319.5047302	0.19
343.1469421	0.09
345.5002747	0.27
359.2680664	0.18
371.4406433	0.12
390.3942871	0.26
423.9829712	0.12
429.3882446	0.46
436.7573853	0.29
442.3190308	1.14
447.4434204	0.26
501.4385376	0.27
505.4503784	0.41
509.9436035	0.19
518.1914062	0.43
542.9255371	0.41
543.5775146	0.18
551.5072632	0.42
553.1245728	0.34
557.2853394	0.38
562.2991943	0.09
571.3956909	1.60
584.4819946	0.28
590.7793579	2.55
598.5572510	0.16
623.6459961	0.11
626.2772217	3.22
631.3833008	0.66
647.4036865	0.52
649.5288696	0.20
655.4289551	1.28
669.8284302	0.64
680.8875122	0.47
685.7305298	0.75
695.3145142	0.10
709.6428223	0.49
713.5442505	0.19
722.8298950	0.64
725.6199341	0.61
727.3632202	0.28
739.6291504	0.93
745.5170288	0.24
748.2946167	0.47
749.1199951	1.05
749.8546143	0.12
750.8333130	0.50
755.2660522	3.72
758.7263184	0.12
766.0388794	0.13
767.6746216	0.19
770.1415405	0.90
771.4671631	0.24
772.9116821	1.76
776.1354370	0.27
788.9669800	0.52
797.4732056	0.35
807.5445557	1.20
810.4573975	1.02
826.9451294	2.56
847.3355103	0.45
853.4749756	0.28
854.6565552	1.30
862.4397583	0.16
865.2304688	1.11
868.7018433	5.28
879.1984253	0.15
881.5360718	0.36
882.3842163	1.47
883.1000977	0.42
891.4977417	5.06
892.6852417	1.83
897.9863281	3.54
898.9130249	1.54
901.1315918	0.50
906.8508911	0.76
908.4567261	0.21
909.4470825	0.23
911.4678345	0.66
912.2773438	0.33
923.5452271	1.55
930.5795288	0.97
932.1062012	0.08
934.3801880	0.45
938.0988770	0.92
944.5698853	0.32
953.7041016	1.54
956.1187134	1.18
962.2182617	0.11
967.3604126	1.14
974.3478394	0.51
976.1513672	1.31
980.2556763	0.27
982.2257690	0.49
991.3867188	0.85
992.1906128	0.38
1006.3880000	0.16
1010.7703250	0.15
1012.5358280	1.31
1017.9207150	1.90
1026.8657230	3.28
1038.2819820	0.29
1049.9431150	0.73
1051.5415040	0.60
1052.5947270	0.28
1065.4842530	0.28
1066.8022460	0.15
1067.5136720	0.11
1074.5225830	0.79
1076.8100590	1.99
1083.7458500	0.61
1084.8651120	0.53
1101.1799320	1.66
1101.8995360	0.43
1108.7185060	0.51
1109.4528810	2.52
1122.5852050	0.11
1132.1319580	2.47
1143.2111820	0.28
1172.4616700	0.49
1180.1436770	1.28
1180.7827150	1.80
1213.7421880	0.66
1251.5957030	1.91
1252.4942630	0.57
1258.9031980	0.20
1277.8665770	0.38
1288.3275150	0.64
1318.5655520	0.73
1342.3829350	0.36
1355.1621090	0.19
1477.7534180	0.38
1504.8024900	0.18
1663.8011470	0.27
1694.2337650	0.30
1698.7230220	0.16
1740.6866460	0.09
1742.2023930	0.61
1761.7161870	2.91
1798.1916500	0.75
1819.4024660	0.11
1821.8289790	0.45
1843.7523190	0.12
1849.7073970	0.16
1856.2728270	0.77
1867.1364750	0.47
1882.7249760	3.17
1884.0667720	0.60
1887.4261470	0.10
1893.5832520	0.53
1905.7828370	0.87
1906.7747800	0.09
1909.0993650	0.10
1909.9168700	0.09
1913.3005370	0.40
1914.9503170	0.28
1916.7912600	0.14
1919.1124270	1.14
1920.8270260	17.56
1924.2467040	4.54
1925.4772950	0.52
1928.7503660	4.54
1929.5452880	0.30
1930.6511230	0.40
1932.2331540	0.19
1933.5118410	13.90
1934.9422610	0.27
1937.0284420	1.05
1939.0031740	0.35
1940.4660640	0.69
1941.7244870	2.20
1943.2965090	56.01
1944.8010250	1.12
1947.3482670	0.79
1954.4982910	45.42
1955.4224850	4.62
1960.4577640	2.99
1964.9976810	10.52
1966.1612550	10.43
1966.9309080	1.13
1969.8643800	43.40
1971.6986080	100.00
1974.0084230	0.19
1975.2708740	0.62
1980.1658940	0.20
1980.9178470	0.24
1985.1846920	3.81
1987.3156740	88.54
1989.4410400	1.84
1990.1800540	0.10
1993.3068850	1.29
1995.0369870	0.21
1996.3892820	8.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0852
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
104.9045105	1.63
106.6659241	1.56
122.8931732	2.46
128.806839	7.15
130.2351074	1.75
132.8718414	1.78
141.0260162	0.75
143.1053314	1.34
151.0160217	100.00
151.8862762	6.13
154.0922394	3.18
155.1710663	3.47
161.0494843	1.11
167.0548859	7.09
168.9536743	4.35
172.2551575	3.77
179.0655365	6.32
180.4327545	0.79
182.8228302	1.67
185.3082733	1.05
188.0415649	1.96
189.2593689	0.84
190.174881	0.98
194.1686707	1.20
197.2048492	7.21
224.9984894	7.08
226.3943634	0.75
238.0705566	23.18
239.1981659	2.48
251.2241669	3.87
253.0812988	53.54
254.1243286	5.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.2708
Annotation	Epoxypheophorbide a
Peak:m/z	Relative Intensity
251.4669495	0.27
253.1786499	0.42
273.2125244	0.08
285.2600708	0.17
296.1466675	0.26
301.0888672	0.09
303.1421509	0.13
310.9794312	0.15
312.0918579	0.17
313.2824707	0.12
322.4489136	0.08
325.2026978	0.26
327.4505005	0.23
328.3397827	0.17
330.1979980	0.35
331.6581421	0.24
337.3939819	0.31
342.2725830	0.13
343.4311523	0.10
350.9074097	0.23
356.8830566	0.11
357.5366821	0.10
365.3689575	0.08
367.6157227	0.16
368.3103027	0.20
369.5539551	0.19
374.3491821	0.10
379.1773682	0.24
403.6964111	0.20
409.3955688	0.11
421.3038330	0.38
449.5642090	0.11
454.2638550	0.29
464.2816772	0.12
465.2595215	0.15
472.8738403	0.08
473.5463867	0.37
478.5314941	0.25
485.5027466	0.26
487.2054443	0.52
489.0531006	0.15
493.6088867	0.46
499.7871094	0.19
502.6748657	0.37
503.4319458	0.57
504.4941406	0.26
505.2787476	0.29
506.3366089	0.27
509.0669556	0.41
509.8198242	0.21
512.9782104	0.83
513.8175049	0.14
515.3491211	5.39
516.6300659	1.23
517.6770630	0.77
519.3234253	0.31
520.8658447	0.26
521.5302124	0.11
522.3313599	0.33
523.5695190	0.17
529.8034058	0.23
531.3359985	25.33
532.4104004	1.88
533.4490967	0.72
536.0209351	1.72
537.3209839	0.59
541.1765137	2.20
542.1541138	0.71
545.3124390	0.80
546.3110962	0.18
547.2185669	0.35
548.3786011	16.20
549.3860474	6.94
550.3142090	1.76
559.3399048	12.60
560.5537720	0.75
562.4693604	0.72
563.4809570	3.66
564.4595337	0.81
565.2652588	0.89
568.2346802	0.79
571.9567261	0.10
573.1560669	1.09
576.2015991	0.86
577.4027710	8.75
578.4835815	0.38
579.2359009	0.09
580.4061890	2.50
581.4418945	1.11
591.3518677	100.00
592.3195801	7.54
593.4791260	0.50
594.7908325	0.16
599.7297974	0.12
607.0434570	0.10
613.8024292	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	285.21
Annotation	Hexadecanedioic acid
Peak:m/z	Relative Intensity
94.94994354	0.28
112.260498	0.44
113.0441284	0.20
161.1942596	0.27
167.0397034	0.80
169.1473236	3.03
170.6751709	1.07
171.3023987	0.81
175.0197754	0.46
183.1036987	0.17
185.8770447	0.18
191.3158417	0.20
195.0674744	0.14
197.3753967	0.32
199.1560364	0.46
201.0305176	0.34
210.3856812	0.26
211.2287598	0.29
213.2461243	0.36
219.5227051	0.63
223.2544556	28.37
225.1017456	1.78
237.3086548	0.30
239.2008057	2.51
241.0684204	5.45
241.9212646	1.66
247.8205566	0.55
249.1788025	1.12
249.9352417	0.26
255.2966919	0.38
256.9324341	0.67
260.0859375	0.25
266.0377197	0.65
267.1947021	100.00
268.0022278	2.67
269.2855835	1.99
269.9090576	0.12
284.9604187	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	651.0549
Annotation	Unknow
Peak:m/z	Relative Intensity
255.2357635	0.05
323.2260742	0.05
334.1173096	0.13
377.2417603	0.19
382.1403809	0.04
397.1658325	0.12
413.3992310	0.05
427.1401367	0.09
438.5772095	0.33
441.2795410	0.08
443.3898315	0.03
445.1869507	0.07
450.2161865	0.07
473.0751343	3.47
481.7555542	0.07
489.0878296	0.24
492.8857422	0.07
493.5060425	0.29
494.4526367	0.03
501.3138428	0.04
504.6638184	0.04
507.3488770	4.39
516.1557007	0.12
518.3676147	0.26
523.3643188	0.09
525.2404785	0.13
531.4028320	0.04
537.2008057	0.04
538.2631226	0.14
539.2977295	0.77
540.9107666	0.46
542.6564941	0.03
549.5524292	0.48
554.1205444	0.19
555.1230469	0.04
557.0673828	0.08
559.1404419	5.15
563.3504639	0.24
565.2575073	0.03
571.2296753	35.26
581.5791626	0.03
583.9788818	0.04
589.4390259	0.41
592.5205688	0.08
602.7069092	0.08
605.0103760	100.00
605.6759033	0.27
606.5905151	0.16
607.3890991	0.05
609.3704224	0.10
612.7131958	0.04
629.0938110	0.07
630.4652100	0.06
631.2387085	0.09
632.7431641	0.80
633.5433350	0.12
650.4510498	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	220.1176
Annotation	Trans-Zeatin
Peak:m/z	Relative Intensity
71.0186615	0.36
71.84545898	0.31
86.81780243	0.79
89.90910339	20.94
93.00782776	0.29
94.84260559	0.22
99.0650177	0.29
115.8657532	3.74
123.9644318	0.52
130.8841553	0.62
156.1966248	0.38
166.1795807	0.31
172.8343201	0.66
174.116394	2.46
175.9388885	0.38
183.9865417	30.09
192.0131683	0.36
192.9189911	0.75
202.1067352	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	586.1379
Annotation	Unknow
Peak:m/z	Relative Intensity
168.9123383	0.08
170.0187683	0.07
175.1371155	0.04
178.9259033	1.94
184.9041901	0.08
197.1212463	0.26
197.9266510	0.15
201.1163025	0.15
203.1063232	0.25
208.9848480	0.07
210.1385498	1.29
211.1401215	0.29
212.0996399	0.21
213.2663269	0.16
217.2455902	0.07
226.2414093	0.19
247.1880035	0.36
252.0810852	0.20
254.1383057	10.34
255.1864777	0.90
262.9003906	0.66
264.3005676	0.13
270.1726990	0.32
272.1212769	27.84
273.1372681	2.88
275.1616821	0.08
276.2710571	0.13
282.4926758	0.09
286.1857605	2.50
287.4709473	0.25
288.1677246	0.81
289.2332764	0.28
295.2777710	1.06
296.1187134	0.06
302.3512573	0.16
304.1481323	32.61
305.1502075	3.91
306.1728516	7.64
307.3766174	0.98
309.1188049	0.06
314.1303711	0.62
316.3319092	0.14
320.0906372	0.52
321.4257812	0.07
325.7711182	0.05
335.9285889	0.07
338.1060791	13.51
339.1354370	1.31
344.6622925	0.11
346.0625000	0.43
353.1466675	0.12
354.9378052	0.10
367.1483765	0.60
368.1345825	0.06
370.2067871	0.14
376.0823364	0.07
380.0537720	0.36
380.7758179	0.06
390.2432861	0.30
395.3074341	0.14
397.2119751	0.39
398.3412476	0.07
400.0892944	0.07
404.2565308	0.12
406.0634766	7.81
407.1100464	0.36
409.9967041	0.10
414.1659546	0.07
416.3538208	0.11
421.1018677	0.10
422.0404663	0.31
424.1295166	100.00
425.2393188	16.35
434.0390625	0.19
436.5182495	0.08
443.2612915	0.07
448.1077881	0.44
448.9827881	0.30
452.1182251	0.15
453.1989136	0.12
454.1509399	0.09
454.7809448	0.05
457.2775879	2.75
458.2058716	1.27
459.3739624	0.25
460.5629883	0.14
463.5954590	0.08
466.2159424	11.36
467.3566284	2.49
468.3345337	0.28
471.2058105	0.26
472.6208496	0.85
477.0054932	0.19
478.1959839	1.64
479.4913940	0.14
482.3546753	0.08
482.9750366	0.07
484.1392212	0.09
489.3417969	0.20
490.9811401	0.57
491.5960693	0.06
493.2366333	0.07
495.5313721	0.79
496.1878052	10.73
497.3061523	1.35
499.2628784	0.26
506.4874268	0.28
508.0956421	4.28
509.2939453	0.81
511.3924561	0.09
524.3179321	2.80
526.1160278	32.69
526.7233887	0.72
527.3263550	5.51
538.1463013	0.04
539.1930542	0.07
540.2564697	0.07
541.7543945	0.41
542.4134521	0.84
543.4159546	0.51
545.5152588	0.07
548.7858276	0.37
549.9461670	0.28
550.8136597	0.79
551.8588257	0.31
552.4667969	0.12
556.4397583	2.02
557.5626831	0.27
559.9291382	0.21
563.9141235	0.28
568.1791382	39.77
569.2417603	10.42
570.4938965	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.0927
Annotation	Veranisatin B
Peak:m/z	Relative Intensity
111.0237350	0.15
119.0703430	4.78
137.0067444	0.05
143.0171509	0.04
154.9489441	0.49
162.9684143	100.00
173.0068207	4.91
191.0274353	8.49
191.6873016	0.03
219.0483704	0.09
239.0209656	0.02
257.3535156	0.02
266.9934692	0.03
273.1232300	0.03
295.1195679	0.02
303.4350586	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	606.07
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
174.9949951	0.04
176.8519135	1.03
193.1017761	0.20
197.0068054	0.04
211.0945740	1.56
212.0702515	0.19
213.0538940	0.25
222.0535278	0.28
240.1322632	0.76
241.1076202	0.99
241.8978577	0.16
243.0758209	0.19
245.9416351	0.25
254.9591064	0.39
258.9981384	0.20
260.9559937	1.77
264.2570190	0.37
271.0205688	0.04
273.0242920	12.99
278.7295532	0.03
279.9926147	0.11
282.0916138	31.84
287.1005859	0.17
291.1381226	0.28
300.1493530	4.48
305.0681763	6.85
311.0445557	0.06
320.1416016	0.11
323.1304932	30.61
324.0242920	1.82
325.1549683	4.16
326.1593018	0.64
329.1558838	0.30
331.0681152	0.48
332.1647339	0.40
334.0628052	0.31
342.8837891	0.20
344.1185303	2.62
351.9821167	0.10
359.2946167	0.13
361.0466309	0.59
362.1537476	19.66
367.4340820	0.11
373.0015259	0.23
374.0526123	0.05
376.9064331	0.07
378.0523682	0.19
379.0867920	0.89
380.0195312	0.29
382.0792236	0.21
383.1796875	0.08
385.0653687	100.00
392.3466187	0.09
393.1813354	0.14
394.0950317	0.46
403.0717163	55.34
403.8452148	0.06
407.1371460	0.08
411.1495361	0.08
419.1613159	0.08
420.9423828	0.56
424.0479736	0.49
425.3034668	0.20
426.8622437	0.04
430.9600830	0.19
433.9696045	0.05
441.1102295	0.78
442.1810913	0.54
443.0825806	3.13
444.3250732	0.34
451.0315552	0.13
451.9279785	0.04
454.1896973	0.09
460.1793823	0.10
464.3358765	0.19
469.1278687	0.11
469.9064331	0.06
471.0759277	0.10
472.0809326	1.21
473.1597290	0.18
483.1426392	0.75
484.0711670	0.41
485.0029907	5.02
485.9414673	0.65
489.9371338	0.22
490.9695435	0.13
492.2985229	0.09
494.2738037	1.88
502.2890015	0.17
508.2671509	6.60
520.7888184	0.23
521.8472900	0.65
526.2474976	0.58
559.2486572	0.14
560.0979004	0.22
561.3495483	0.87
562.1528931	10.07
563.2478027	2.58
585.0703735	0.14
587.1080933	5.37
588.3007202	0.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	392.1132
Annotation	(gamma-Glutamyl-gamma-glutamyl)-S-methylcysteine
Peak:m/z	Relative Intensity
125.8262787	0.05
127.4243317	0.62
128.1217651	1.99
135.0964813	0.23
143.0579376	3.31
145.1715851	0.05
146.0707092	0.46
148.0989685	0.02
153.2117004	0.25
160.0910797	0.30
166.3291168	0.25
167.1909027	0.32
170.0755920	0.18
171.1148834	0.77
177.1240540	0.62
179.0106201	8.10
179.6373901	0.13
181.1803589	0.12
184.0311127	0.05
185.0003967	0.44
191.3565674	0.04
191.9621582	0.08
197.0588684	0.44
200.3271942	0.04
210.1178894	4.05
210.8404236	0.22
211.7867432	0.07
212.9069519	0.06
228.1703796	0.47
230.9914856	0.07
236.1137695	0.84
242.2911682	0.09
245.1038818	0.07
246.2738037	0.20
251.2467651	0.03
254.1633606	71.47
257.0385132	0.12
258.2333679	0.16
259.4051514	0.20
260.1534119	0.22
260.8564148	0.15
262.5377197	0.29
263.1771240	7.39
272.1363831	100.00
277.2526855	0.06
288.1984558	4.69
294.2489014	0.09
299.3373413	0.07
304.7619019	0.06
306.2031555	47.04
316.2858887	0.13
329.2191772	0.07
330.0526428	0.06
347.7742004	0.17
348.9804993	0.09
350.8565369	0.06
356.9640808	0.05
364.0986938	0.16
374.1266785	18.13
376.4687195	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	619.1215
Annotation	Unknow
Peak:m/z	Relative Intensity
175.2894745	0.23
203.1601868	0.05
206.2528381	0.16
214.9753113	0.11
215.8135681	0.06
221.2598267	0.06
224.3252563	0.05
225.1765137	0.24
226.1267700	0.61
228.9677582	0.55
242.0773315	6.63
243.1785278	3.36
244.3309021	0.61
247.1061859	0.98
250.2236023	0.13
256.1668701	0.20
258.9616699	0.16
266.4881592	0.04
275.0453491	0.07
277.3842163	0.07
278.5306396	0.09
279.3851624	0.27
280.1299438	0.26
282.0547485	0.10
284.2180176	0.57
289.1202393	0.14
290.0607605	0.17
290.9741211	0.28
298.0834961	0.08
304.7417603	0.29
305.9780884	0.34
307.0965576	2.65
309.9992981	0.12
313.9896240	0.24
319.1112061	0.04
321.9120789	0.20
322.9180908	0.04
327.1714478	0.26
332.9508057	0.07
337.2221069	0.05
339.1784058	12.20
340.2429810	0.15
342.2698975	0.54
344.0984497	0.90
345.5434570	0.30
353.7880859	0.10
355.4886475	0.39
356.3056030	0.04
366.0764160	0.30
368.0632324	0.08
370.2796021	0.09
371.2361450	0.53
372.1242065	0.04
374.3193970	0.17
376.3048096	0.13
378.9371338	0.10
384.2360840	0.17
388.1222534	0.22
396.2224121	0.76
397.0921021	0.15
398.4262695	0.18
405.5795898	0.10
406.3051758	0.18
407.8441162	0.04
409.2444458	0.04
415.0273438	0.09
422.0255127	1.07
422.9397583	0.20
429.2889404	0.28
430.5324707	0.06
437.9310303	0.22
438.6493530	0.22
440.3059082	0.15
440.9736328	0.09
446.0601807	0.44
448.0654297	0.16
457.1583862	25.11
458.3356323	0.17
463.2966309	0.35
464.0651855	0.19
468.2980957	0.11
469.1590576	0.31
472.7250366	0.06
473.5258789	0.04
482.0255737	0.05
484.2669678	0.04
486.9343262	0.04
489.3243408	0.12
493.4537354	0.55
494.0815430	0.20
496.4144287	0.09
499.2504272	4.32
500.2324829	0.54
502.2155151	0.66
504.0717163	0.08
505.5078735	0.29
506.1522827	1.46
509.1950073	0.14
512.1457520	0.29
514.0402832	0.14
518.2073975	0.67
519.6795654	0.24
520.3689575	0.66
521.0891724	1.05
523.2024536	0.95
524.2369385	0.71
525.1536255	0.30
529.2114868	19.48
530.3466797	0.59
535.1901245	0.76
536.2380981	0.09
537.1841431	0.24
538.3378906	0.72
539.2810669	0.50
541.1773071	1.66
542.2947998	0.59
543.2814941	0.13
548.0984497	2.11
548.7548218	0.20
550.2860107	0.12
553.2902832	10.91
559.1596069	100.00
560.1647339	4.81
565.0615234	1.63
566.1431274	17.89
567.1421509	0.89
573.3280640	1.11
574.9391479	0.05
577.5307007	0.17
583.3375854	12.82
584.1937256	29.26
585.1352539	1.50
589.3571167	0.20
601.1924438	49.72
602.2684937	3.67
609.9099731	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.2806
Annotation	Fontaineine
Peak:m/z	Relative Intensity
140.9504547	0.79
143.1841736	0.42
160.9569092	0.07
179.1369019	0.03
183.7190247	0.08
204.7469482	0.21
207.8529968	0.12
218.0124817	0.13
219.1348419	0.06
231.2876892	0.14
247.4860840	0.15
249.1807861	0.37
250.2204590	0.31
258.1122131	0.17
259.6058044	0.20
263.2663879	0.06
264.1616211	0.15
265.0567627	0.26
275.4531555	0.12
276.1815796	0.07
277.2632141	5.02
278.3550415	0.52
279.1775818	0.31
280.1812134	0.08
291.2777100	5.76
292.3550415	0.72
295.2771606	100.00
296.2465210	26.21
296.8508301	0.05
297.4697876	0.30
305.4825439	0.11
307.2149353	0.60
317.2653809	0.22
319.1376953	0.46
327.8635559	0.13
333.3835754	0.09
337.2902222	3.35
338.3245850	1.30
340.0858154	0.08
349.3139954	0.34
351.3621826	0.14
351.9714966	0.10
367.4620361	0.22
368.1779175	0.09
370.5570374	0.09
383.4624634	0.27
387.2127991	0.16
389.6370850	0.55
395.8016663	0.14
397.7441711	0.06
401.1201172	0.07
402.0281982	0.28
412.2102356	0.17
413.9830627	0.46
414.9040833	0.50
420.3156433	0.64
421.5660095	0.41
422.2435913	0.47
430.5621033	0.07
439.5538025	1.23
440.4057922	1.13
441.0127258	0.06
443.2085266	0.16
453.2591858	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	213.0745
Annotation	Methyl syringate
Peak:m/z	Relative Intensity
122.0112000	0.06
137.9249420	0.03
153.9586945	0.17
171.2800446	0.04
178.0726471	0.17
195.0699005	21.80
195.9629822	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	528.0938
Annotation	Unknow
Peak:m/z	Relative Intensity
162.1125946	0.10
173.8843079	0.06
177.1015015	0.10
186.8903809	0.07
197.1944580	0.25
201.2273102	0.17
209.1124115	0.05
217.2563324	0.05
228.0146790	0.03
229.7373199	0.04
230.3821564	0.28
231.0924988	0.03
233.0644226	0.06
233.6768188	0.06
238.2669983	0.10
243.1168671	0.09
251.9996490	0.67
256.0061646	0.03
259.8663940	1.10
261.9930420	0.68
269.2744751	0.30
273.3830566	0.05
278.0264282	1.55
279.5875244	0.14
280.2620544	0.07
284.2543030	0.03
288.9525452	0.31
295.2520752	0.94
296.0382080	8.62
298.1430664	0.19
299.9703979	0.16
306.0592041	1.54
308.2629395	0.08
313.2042236	2.64
318.5308228	0.16
329.3093262	0.03
342.1247559	0.07
343.1433105	0.10
349.2697144	0.37
355.1797485	2.80
356.3974609	0.21
358.1513062	0.05
362.3874512	0.12
363.6877441	0.10
365.2902832	0.09
366.1309814	0.14
367.3643188	0.29
377.1706543	0.07
381.3424072	1.12
382.0738525	0.35
383.8781738	0.06
391.2893066	0.08
393.9564209	0.04
399.0765381	100.00
407.0789795	0.11
409.2996216	0.11
413.2133179	0.04
417.8980103	0.03
421.3036499	0.04
423.1400757	0.03
424.0221558	0.17
434.9837036	0.39
437.4804688	0.04
438.9616699	0.07
439.9432373	0.07
441.0441284	0.03
442.1557617	3.09
445.1033325	0.34
445.7521973	0.17
452.2433472	0.42
453.2304077	1.66
458.7770386	0.14
465.1312256	0.32
465.9387817	0.13
467.0512085	0.27
468.4697876	0.13
483.1183472	0.29
484.0805054	0.98
490.1455688	0.15
494.3530273	0.15
495.3040161	0.10
498.4285889	0.17
499.5441895	0.09
503.1453247	0.09
505.7963867	0.36
507.3363647	0.23
509.3877563	1.09
510.1900024	1.73
511.1514282	0.59
515.9769897	0.26
519.3638306	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	273.96
Annotation	Unknow
Peak:m/z	Relative Intensity
115.0065308	5.39
115.9836884	1.54
131.1192932	0.19
132.0653381	0.02
139.1126099	0.01
145.1876221	0.01
158.9519348	100.00
159.9446411	24.37
198.9180908	1.35
199.9721375	1.00
201.0628052	0.02
201.9569092	0.02
217.0346375	0.64
217.9361572	0.49
228.9127197	19.75
229.9116211	11.71
244.9768982	0.30
246.0443115	0.31
256.2051086	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0715
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
153.1094513	1.89
155.1829681	1.00
160.9645996	2.22
165.0579529	1.37
167.0805511	2.01
168.7757416	1.84
169.9445038	2.61
173.7862854	3.12
179.1180115	8.57
189.1496429	6.63
193.2625732	3.61
195.2623138	8.09
197.2119598	4.76
206.0150452	3.00
207.1883698	12.33
209.1499634	16.40
213.1396332	1.37
214.909256	57.05
222.1869812	1.38
222.7998962	7.18
223.53685	1.19
233.3398285	20.82
251.0653534	100.00
252.1140594	10.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	360.15
Annotation	Lactulose
Peak:m/z	Relative Intensity
117.1884232	0.27
144.9220276	1.58
163.1234741	0.46
175.0073547	0.77
179.9992981	10.99
180.8583984	0.33
198.0624237	3.33
199.0016327	0.22
206.0646973	0.24
209.2208099	0.21
212.0607147	0.87
221.2346802	0.36
239.0671997	1.71
244.2550659	0.22
245.2887878	0.29
246.0844421	1.00
257.6623535	1.07
258.8084412	2.57
262.1032104	0.30
265.0516357	0.47
276.4104309	1.43
277.0799561	1.66
288.8299866	8.49
303.1409912	0.52
306.1216431	1.07
306.9092712	4.58
314.7196045	0.82
324.4084167	29.70
325.0852051	100.00
340.1789551	1.25
342.2482605	23.81
342.8918152	22.43
350.6603699	0.26
373.2045593	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	569.2234
Annotation	Excavatolide D
Peak:m/z	Relative Intensity
243.2689514	0.03
269.0140381	0.06
284.1442261	0.13
285.1581421	0.03
293.1724854	0.05
300.2896118	0.03
318.2970581	0.06
332.1310425	0.03
341.2609863	0.10
350.9985352	0.05
370.9219360	0.32
372.2160034	0.03
375.2985229	0.07
377.5534668	0.03
378.9774170	0.02
388.3158569	0.07
396.4990845	0.07
406.0904541	0.03
407.2233887	0.05
411.9453735	0.07
426.5840454	0.16
433.2177734	0.06
447.2330322	0.05
462.9273071	0.07
464.8588257	0.03
481.4873657	0.06
483.3879395	0.09
504.8555298	0.09
506.1129150	0.05
507.6554565	0.03
508.3748169	0.06
509.3370972	0.11
523.3025513	100.00
523.9175415	0.20
532.9299927	0.96
538.2993774	0.05
546.1575928	0.06
549.2846680	0.08
550.4635010	0.89
551.3339844	0.28
554.3878174	0.06
560.4777222	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.2077
Annotation	Unknow
Peak:m/z	Relative Intensity
142.9817810	0.03
161.1368256	0.03
179.0149536	0.11
180.0238037	0.08
184.2769775	0.02
187.2592773	0.03
219.1089478	0.04
225.2624969	0.06
235.1487732	0.03
253.2796021	0.12
269.1173096	0.01
271.2142639	0.01
284.1670837	0.01
313.2681885	0.02
337.3960571	0.06
340.2162476	0.04
341.4797974	0.02
346.2245178	0.01
347.2431030	0.03
348.3554688	0.02
352.8524170	0.02
358.4235229	0.11
373.4725342	0.01
376.9673767	0.01
384.3367615	0.04
387.2648621	100.00
388.2607117	0.06
389.3711853	0.04
395.0256653	0.03
397.2461243	0.02
399.2167969	0.02
402.3126526	0.03
404.1828918	0.01
412.3409119	0.04
414.0331726	0.04
415.2276306	0.15
427.0819397	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	339.1069
Annotation	1-Caffeoyl-4-deoxyquinic acid
Peak:m/z	Relative Intensity
118.9172287	2.04
146.9848938	100.00
156.3355408	0.11
208.3528137	0.14
219.4209595	0.10
246.3733215	0.04
263.9569702	1.42
269.1242371	0.09
270.1607056	0.17
292.8781128	0.18
295.1676331	0.12
310.5738220	0.30
321.1997986	0.38
322.2223511	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	306.08
Annotation	Glutathione
Peak:m/z	Relative Intensity
98.8867188	0.39
115.9762115	0.07
119.8722534	0.10
125.1592865	0.14
125.8902893	0.14
128.0144806	8.52
129.9729767	0.05
135.0638123	0.06
143.0441284	11.12
143.9463654	0.24
145.9444580	1.14
153.0717163	0.14
158.8539734	0.06
160.0342102	11.82
166.4746399	0.27
167.1789093	0.22
170.0404663	0.11
171.0481873	1.87
177.0819397	8.53
178.9873352	9.00
179.6909790	0.06
183.1034851	0.12
184.9898376	1.26
197.1111145	1.69
203.1280518	0.26
210.1481323	5.79
211.3605957	0.05
213.0734863	1.07
215.2496338	0.06
224.3676147	0.08
228.1963806	0.55
231.0734253	1.17
236.0910339	0.43
242.1292114	0.96
244.2568054	0.27
254.1214294	96.78
261.1428223	0.06
270.1638794	0.07
272.1873169	100.00
288.0640259	67.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	145.06
Annotation	3-Ureidoisobutyrate
Peak:m/z	Relative Intensity
72.2250214	0.02
73.5144272	0.03
74.1366119	0.07
84.1220398	0.05
97.9648895	0.04
99.1786652	0.04
100.8988800	0.69
109.0221863	6.75
125.0418549	0.03
126.9438171	100.00
127.9975281	14.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	279.1237
Annotation	Villosin B
Peak:m/z	Relative Intensity
83.0990601	0.05
95.0575943	0.29
96.7676468	0.36
107.2978210	0.04
109.0340424	0.10
111.0129395	0.03
122.2800674	0.13
123.3330765	0.08
124.0711441	0.60
131.0578613	0.05
137.0471802	1.04
138.9977112	100.00
142.9140320	0.04
147.0561523	0.63
149.1308899	0.04
150.3665466	0.08
151.0971375	0.35
160.2034454	0.11
161.0710297	0.08
162.9595337	0.34
164.9936066	0.10
166.2003021	0.03
168.1799774	6.63
169.0382080	11.60
172.9356689	0.12
177.0684357	0.54
179.4660034	0.17
183.1850891	0.10
187.1226959	3.41
190.0462341	0.12
193.2744751	0.19
193.8984070	2.39
195.3109741	0.04
199.0257263	0.07
200.1985168	0.06
201.4171143	0.14
203.1450806	0.12
205.0559692	27.31
207.1700745	0.03
213.0620728	0.11
215.1402283	0.11
217.0390320	2.10
219.8107910	0.04
221.3527832	0.14
225.0671997	0.09
231.1009827	0.70
233.1854858	0.07
235.0374451	24.72
236.8906555	0.23
238.0437927	0.38
243.1812744	0.04
244.2161865	0.07
249.0963135	25.27
250.6494751	0.05
259.2149353	0.03
260.2029114	0.14
261.0554810	2.41
262.0361328	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	445.0843
Annotation	Unknow
Peak:m/z	Relative Intensity
142.8763885	0.12
148.9379272	21.21
151.1094666	0.33
160.3831787	0.06
161.1350098	0.04
163.1122894	0.22
175.2268677	0.19
179.0241699	2.58
179.9423828	0.17
181.3652649	0.04
190.8524780	0.10
204.8878937	0.20
216.9667969	0.32
220.9344330	0.13
251.0042419	0.24
257.0335999	0.12
259.1585999	0.07
265.3164368	0.19
283.2399902	0.12
295.2363281	2.01
301.2592773	0.23
310.9272461	0.17
313.1485291	100.00
316.0822754	0.14
321.1626587	0.12
343.0863647	0.29
379.1978455	0.71
383.3054504	0.05
399.1376648	33.02
399.7617493	0.10
400.8485413	0.09
411.1694946	38.32
427.0598450	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	366.994
Annotation	Chelidonic acid
Peak:m/z	Relative Intensity
125.1795502	0.08
138.9224854	19.94
163.0543671	0.23
174.9086456	0.11
179.0167389	0.05
182.9815826	100.00
186.2318115	0.05
216.9784546	0.09
220.8946533	0.66
221.8841553	0.07
253.1828308	0.16
282.9973755	0.09
294.9533691	0.05
304.1869812	0.07
322.0880127	0.15
323.3320312	0.14
332.0351562	0.07
339.1496582	0.06
347.0744324	0.56
348.1449280	0.03
350.2904358	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1516
Annotation	Unknow
Peak:m/z	Relative Intensity
167.2073059	0.06
169.0649109	0.07
170.8927765	0.19
173.0998383	0.39
174.0309143	0.12
175.0189362	0.61
176.4994507	0.21
177.2246704	0.54
178.0462646	0.22
179.0418396	0.19
182.1350403	0.13
183.0658569	0.43
185.1943054	0.44
186.0604706	0.06
187.0680542	0.05
188.0421753	0.07
189.1165161	0.51
190.8397675	0.18
193.2341003	0.07
194.1174316	0.08
195.2210388	0.27
196.2752380	0.10
198.0084839	0.17
199.1099548	0.40
199.9013214	0.42
201.0745544	1.45
202.2048950	0.47
203.0914459	0.14
203.9087219	0.07
207.0673676	0.11
208.9999695	0.21
210.2709961	0.06
211.1762695	0.64
212.1407471	0.90
213.1817627	1.04
214.1370087	0.53
215.0346069	0.26
216.1907654	0.23
217.1243439	2.12
218.0052490	0.31
218.9781799	0.09
222.2572327	0.05
223.0315247	0.16
225.1094055	0.41
225.9139709	0.08
227.1798706	0.58
228.0465698	0.35
229.1618195	0.95
230.1697235	0.13
231.0797729	0.26
232.1280212	0.42
233.0987549	0.11
235.1694641	0.04
236.4270630	0.10
237.1897278	0.42
238.1221619	0.09
239.1963043	1.10
240.1083832	1.71
241.1083069	3.49
242.0986023	1.16
243.1251221	1.45
244.0440369	0.13
245.1897125	0.13
247.3715210	0.09
253.2599945	0.26
254.0484009	0.09
255.1118469	1.53
256.0386658	2.42
257.1231995	4.07
258.2881165	0.42
259.1900635	0.31
259.9950562	0.04
264.4664307	0.22
265.2817383	0.26
267.0971680	1.63
268.1992798	0.19
269.1426697	0.83
270.1526489	0.24
271.2047729	2.41
271.9707031	0.25
273.0432129	0.14
275.2028198	0.12
276.4528198	0.06
280.2249146	0.37
281.3057861	0.99
282.1028748	0.08
283.0532227	3.37
284.0487976	31.73
285.0871277	100.00
286.2098083	12.37
287.5713501	0.08
290.1670532	0.11
291.1574707	0.14
293.2008057	0.20
294.1227417	0.17
295.1960144	1.88
296.1118774	0.90
297.1869507	1.43
299.0950928	23.42
300.2178040	2.65
301.1906128	0.21
307.2734070	0.08
308.0712280	0.08
309.1773682	4.19
310.2224731	0.90
311.2929688	0.38
313.3311157	0.13
314.1143799	0.08
321.1062622	0.49
324.0288086	0.04
325.0966797	0.16
325.8663940	0.15
327.1607056	10.95
328.1901855	1.75
334.2846069	0.18
339.1093140	5.32
340.1197510	0.50
349.0957031	0.06
351.1649170	1.11
352.3049927	0.61
354.1420288	0.14
357.1904907	3.46
358.1708984	0.46
367.4305420	0.11
369.0606689	0.48
370.0565796	0.09
375.3991089	0.09
381.6409302	0.11
383.2137451	0.13
384.2589111	0.04
393.0919189	0.26
393.9841309	0.03
407.3466797	0.10
411.2387695	1.23
412.3085938	0.12
421.2533569	0.04
431.2565308	0.30
432.3925781	0.21
438.2065430	0.07
447.1939697	0.08
449.3768921	0.32
450.1423340	0.15
452.1759644	0.07
456.4643555	0.06
457.3088379	0.13
458.3015747	0.05
464.4338379	0.13
465.2283325	0.21
467.2503052	7.83
468.3483276	1.33
473.5523682	0.09
474.3668213	0.10
478.3417358	0.05
483.2916260	1.87
484.3789673	0.26
490.1392212	0.19
497.1724854	0.04
504.2373047	0.42
507.3167725	0.11
511.1618042	0.18
515.2350464	0.23
522.4108887	0.24
526.3071899	0.08
529.3540649	0.14
531.0754395	0.04
533.3419189	0.24
535.5855713	0.09
540.2140503	0.05
547.1430054	1.64
548.2460327	0.32
549.2715454	0.25
550.2824097	0.39
552.5565186	0.24
557.2028198	1.10
558.2271729	0.04
559.6253662	0.18
575.2465210	3.46
576.3244629	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	603.0026
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
193.0086823	0.02
204.9834442	0.22
211.0512390	3.62
212.0029907	0.09
214.9215698	1.06
219.0498047	0.04
232.8959656	0.15
238.7964172	0.07
241.0054474	3.92
242.0300751	0.38
244.1351471	0.07
257.1236267	0.85
257.9784546	0.19
259.0615234	0.24
262.2316895	0.25
263.0521240	0.09
268.9934082	0.12
269.8323975	0.04
280.0830688	1.37
283.0433044	0.17
287.0033569	0.10
300.1353149	0.06
305.3120117	0.06
308.0573120	0.04
311.1336060	0.10
312.0751953	0.17
317.1260376	0.40
318.0493469	0.30
319.1290894	0.04
323.0611572	100.00
324.1869507	9.91
324.9541626	0.10
328.9549561	3.91
330.1542969	0.39
334.1298218	0.43
340.5714722	0.04
346.2464600	0.08
352.2783813	0.25
353.6049194	0.45
359.0887451	3.76
360.1137695	0.60
361.1665649	0.23
371.0943604	0.24
372.0424805	0.09
377.0518188	8.09
378.2288208	0.64
378.9577026	0.10
379.9831543	0.52
380.8870239	0.53
382.0121460	0.16
385.2449951	0.20
388.2595825	0.04
389.8898926	0.05
390.9344482	0.04
392.0599976	0.21
398.1223755	1.07
399.2336426	0.06
406.1651611	0.50
407.2996826	0.39
416.2938232	0.30
419.0736084	2.06
420.2576904	0.10
422.9837646	2.70
424.1419678	1.04
425.1879272	0.16
426.1918945	0.10
427.0493774	0.16
429.0682983	0.13
430.0669556	0.09
431.0365601	0.12
432.1855469	0.11
440.0996094	1.75
441.0165405	30.92
442.0107422	3.48
446.1558838	0.04
448.9774780	0.86
450.1853638	0.04
452.2550659	0.37
453.1260986	0.32
458.1439819	0.14
462.0802002	0.45
463.1104126	0.05
466.9405518	0.04
468.3593140	0.04
470.0253906	8.71
471.0972900	1.50
475.2449951	0.11
483.0050049	28.69
484.0573120	3.87
486.2037964	0.05
488.1059570	0.83
489.1447144	0.35
491.0287476	4.02
492.0965576	0.15
499.8872681	0.24
505.9035034	0.14
519.0708618	0.09
520.0552979	0.11
524.2391968	0.79
525.3807373	0.11
542.1207275	1.59
543.1772461	0.19
557.3075562	0.11
560.0704956	51.86
561.1068726	9.63
562.2596436	0.38
567.1193237	0.09
585.0599976	22.72
586.1885986	2.77
587.3810425	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	218.1034
Annotation	Pantothenic acid
Peak:m/z	Relative Intensity
70.9946747	0.49
87.9719849	100.00
100.0244293	0.15
102.9724884	0.04
115.1663208	0.17
116.9961090	0.32
119.9002075	0.80
126.0032196	0.07
130.6771545	0.91
140.1150513	0.42
144.0547028	0.11
146.0468597	9.38
147.3578339	0.07
155.8981171	0.27
158.0531921	0.13
166.2438354	0.05
172.2362823	0.08
174.0790100	2.90
184.0685425	0.46
199.1854401	0.22
199.9656525	1.09
203.1681061	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2874
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
173.1438599	29.31
177.5032043	9.98
184.0770874	10.08
187.1059875	14.09
203.2552185	18.55
229.1319122	12.61
261.3651123	12.38
322.1364746	17.39
329.9280396	19.28
339.058075	18.20
347.3389893	13.27
351.2747192	24.21
363.5472412	39.33
371.8537292	12.41
380.3978271	30.60
384.8463135	14.09
390.4899902	43.57
392.0309753	12.39
408.2844543	100.00
411.1852417	8.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0369
Annotation	Triazolam
Peak:m/z	Relative Intensity
104.9106293	8.73
111.2064209	0.04
114.9694824	0.22
128.8277588	0.48
143.1107483	0.10
148.8839417	43.42
159.1639709	0.33
165.0757141	0.74
172.9977417	0.38
177.0571442	0.10
179.0479126	0.20
188.9101562	0.05
191.0848236	59.12
209.0644836	100.00
209.7579956	0.09
213.2386475	0.03
218.1781616	0.16
221.2547607	0.08
232.0726013	0.06
234.1811523	0.10
242.9898682	0.04
245.7673340	0.13
250.2554932	0.05
251.1007690	0.26
253.2852173	0.08
254.9153442	0.04
263.0558167	0.39
265.1224365	0.03
273.4452820	0.13
277.1931763	0.84
278.2946472	0.19
281.6850586	0.17
294.9830933	0.43
297.0599976	0.27
304.2684326	0.06
305.4454956	0.07
307.2670898	0.07
309.1508484	0.31
311.1245422	0.20
313.1298828	0.07
322.5131836	0.04
323.5577393	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0876
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
107.1538162	0.07
109.1458664	0.07
110.7793808	0.05
113.0806503	0.01
117.1832581	0.01
127.1078491	0.11
133.3500519	0.02
135.0176392	6.43
136.0414429	0.79
137.0057983	0.03
143.0518494	0.05
153.000412	0.01
155.1017303	0.18
161.1230164	0.91
162.0895996	0.09
171.2121277	0.04
173.0351868	2.83
174.144989	0.19
179.0577545	40.16
180.0839233	5.54
183.0491028	0.01
191.0571899	100.00
192.0443115	9.21
204.164917	0.01
232.9559937	0.01
243.2656555	0.02
286.2744141	0.01
291.9041138	0.02
294.0907898	0.02
307.1870117	0.01
309.2793579	0.13
310.3880005	0.01
335.3470459	0.11
336.2154541	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	199.9874
Annotation	Unknow
Peak:m/z	Relative Intensity
92.2048035	0.29
93.1061401	0.09
95.9955292	0.45
130.3256073	0.24
158.9421082	100.00
164.2800598	0.15
175.1408844	0.63
176.1545868	0.25
176.9934845	0.34
182.0291901	0.47
182.8373718	0.29
186.9927063	0.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	761.1248
Annotation	Unknow
Peak:m/z	Relative Intensity
213.1024017	0.11
226.2078247	0.12
229.3545074	0.18
230.9839172	0.03
236.0328674	0.38
240.1993256	0.02
242.1988525	0.28
243.0506744	0.11
252.1949768	0.41
254.1512146	7.02
255.2592621	0.75
259.9741821	0.09
261.3286133	0.06
272.2142029	12.81
273.1998291	1.01
286.1185913	1.55
287.0970764	0.28
288.1520386	5.97
289.1331787	0.51
293.0241699	0.19
302.2871704	0.03
304.1193237	9.82
306.1311035	100.00
307.2025757	8.36
308.1354980	0.04
318.9862366	0.10
325.0170898	0.18
326.9616394	0.10
338.0583496	6.83
339.1307983	0.80
352.2206726	0.04
359.0128784	0.18
363.3557739	0.04
378.1826172	0.82
386.0204468	0.03
390.2526245	0.03
404.0759888	0.69
405.2775879	0.39
422.1676636	36.67
423.1209106	4.21
436.2044067	0.06
437.1522217	0.07
447.0986328	0.11
454.1050415	6.84
455.1036377	0.69
455.7536621	0.88
456.3554688	0.22
478.9454346	0.06
487.7919312	3.13
488.5135498	0.54
489.1282959	0.16
503.1840210	1.27
504.2914429	0.12
518.5704346	0.04
559.3313599	0.15
562.1464233	0.07
586.6168823	0.04
594.4019165	0.28
596.3118286	0.05
596.9696045	0.04
612.0604248	0.09
614.1740112	1.24
615.1246338	0.13
625.1154175	0.03
626.2030640	0.04
632.1131592	49.21
633.2040405	7.30
637.0583496	0.08
647.0562134	0.06
686.1685181	0.11
698.9194336	0.06
717.7242432	0.27
725.0742798	0.57
726.4597778	0.12
727.4348145	0.07
743.1244507	14.39
744.2553101	4.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	413.1405
Annotation	N6-Carbamoyl-L-threonyladenosine
Peak:m/z	Relative Intensity
120.1011124	0.28
129.4361725	0.09
135.9918365	0.46
158.7126160	0.26
162.0469666	0.78
171.1285706	0.25
189.1701965	0.25
201.0832672	0.23
202.0713654	0.21
213.1538086	1.12
218.1742401	0.08
219.0203400	0.15
221.2719879	0.43
226.8938293	0.27
229.1477966	0.14
233.2213135	0.11
242.2201843	0.19
247.9443054	0.50
250.7764893	0.21
257.2194214	0.11
263.4082336	0.14
268.1355286	3.67
268.7718811	0.07
279.1937256	0.15
281.1603394	100.00
290.3684387	0.12
294.0882263	1.33
297.8105469	1.10
315.0465088	0.08
325.4744263	0.31
327.4435425	0.14
329.9519043	0.34
331.5608826	0.78
332.9602051	0.10
338.8649597	0.33
339.4896545	0.14
341.4733887	0.38
352.2015381	0.10
358.1980286	0.76
359.4966125	0.30
360.9317322	0.21
367.8832397	0.12
369.4046936	0.14
377.1029053	0.19
379.3808899	0.14
384.2925720	0.17
385.6043396	0.57
392.5188904	0.24
394.4093323	0.62
395.4085083	3.23
403.6866150	1.52
404.7658997	1.40
406.6045532	0.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.114
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
113.0681992	0.37
114.8748932	0.07
121.1147156	0.14
128.8531952	0.06
135.9242859	0.13
138.0049133	0.19
142.9867554	0.09
148.9530640	1.04
153.1116028	3.31
161.1266479	0.44
162.0762634	0.23
164.0426331	4.70
175.1947632	0.18
177.1223450	0.58
179.1364441	1.44
181.2647400	0.07
188.1912537	0.04
190.0713196	4.50
190.9813232	0.05
203.2603302	0.40
205.0854645	56.36
206.1891785	0.05
207.1014252	0.08
208.1244354	0.75
219.0205994	0.25
221.1230164	2.08
223.1258850	100.00
232.0107727	0.43
233.1101685	0.44
237.1691284	0.29
239.4549866	0.06
245.0528259	0.15
247.0482788	59.90
249.3825989	0.34
251.2793579	0.42
255.1041870	0.13
263.1669617	0.47
265.1238403	10.83
267.2798767	0.07
271.3841858	0.16
277.2284851	1.19
287.3106079	0.15
288.5817871	0.18
289.2001648	1.37
295.0877686	4.13
299.1568604	0.05
305.1714478	0.08
306.2160950	0.31
307.0946655	0.07
325.2437439	6.33
339.2498779	0.48
364.9943542	0.07
367.2434082	1.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	293.1705
Annotation	Unknow
Peak:m/z	Relative Intensity
101.3118134	0.19
112.8458862	0.15
148.8192139	0.33
166.9130096	1.23
168.9194946	0.20
174.9350433	0.25
177.3266907	0.26
179.2406006	0.30
183.3711243	0.19
184.0246582	0.17
185.0009155	0.14
187.0356750	10.25
190.7695312	1.00
193.0397949	0.40
201.2086487	0.31
202.8455200	0.10
210.9089355	0.95
213.2517700	0.11
214.9553223	60.85
215.8485107	0.24
220.8500366	0.18
226.2007446	0.26
226.9724121	0.25
227.8762817	0.82
229.1385193	0.29
233.8526306	0.26
234.5000305	0.63
237.0762329	0.31
243.2176514	0.12
247.0102844	0.09
248.1770325	0.62
251.2522583	0.19
253.3260498	0.07
257.2508240	1.57
260.2895813	0.14
262.2830200	0.11
263.2352295	0.12
264.9738159	0.57
268.0623169	1.15
269.1344604	0.67
272.2008057	7.20
273.3638611	0.65
274.3233948	0.59
275.1723328	2.79
275.9426575	0.41
284.1626587	9.43
284.9550781	0.14
286.0323792	0.41
295.9124451	1.52
297.8707886	0.15
314.0145874	3.83
325.2882385	0.25
356.0289612	0.33
359.5522156	0.07
371.3162231	100.00
372.4547424	2.29
385.5696106	0.34
410.7868652	0.16
469.7128601	0.27
487.4306335	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.1139
Annotation	Bluensidine
Peak:m/z	Relative Intensity
81.0976944	0.27
82.0068817	0.13
87.0227814	0.58
89.1049881	0.24
109.8116913	0.05
114.8164825	0.20
122.0245972	8.27
132.9446259	100.00
139.6314697	0.20
141.6903381	0.28
143.9780273	6.91
149.1783295	0.13
155.9682922	1.69
218.8778839	0.15
247.0407104	0.23
248.3686066	0.17
256.3276672	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	665.1178
Annotation	Unknow
Peak:m/z	Relative Intensity
187.1699982	0.12
208.7984619	0.37
229.2401428	0.33
254.0843658	0.18
259.2497864	0.12
268.2150269	0.34
272.2757874	0.26
277.0127563	0.57
278.8934326	0.52
281.8515930	0.33
294.0920410	0.23
300.0532837	0.39
356.1743164	0.75
363.9703979	0.35
377.3982544	1.19
380.7295532	0.65
383.3361816	0.68
385.9873657	0.71
398.5849609	0.62
401.3717041	4.35
402.3140869	0.16
403.1536255	3.51
419.3128662	1.23
429.1742554	3.59
430.2949829	0.63
434.1942139	0.38
437.1731567	0.77
441.1463623	0.49
442.1705933	0.28
447.2986450	0.75
447.9245605	0.18
449.5239868	0.99
450.2088013	1.07
454.7206421	1.49
456.2868652	0.16
459.3202515	0.32
463.3539429	1.21
464.2501221	0.51
472.5932617	2.69
479.0413208	7.98
483.0468140	0.44
486.0540161	0.28
497.3403931	1.41
498.3908691	1.91
499.4148560	0.61
502.0227661	0.71
503.1362305	3.04
505.6447144	0.42
507.8051147	2.93
511.4701538	0.15
513.4880981	2.23
522.3930054	8.28
522.9938354	4.13
528.8938599	0.63
532.3203735	0.53
537.2117310	1.33
540.3189087	0.77
542.3834839	0.36
543.3654175	0.89
546.7944336	0.30
549.2232056	0.36
552.4865723	0.36
553.5162964	0.41
556.9579468	0.66
561.0756226	0.33
562.1577759	0.66
563.1986694	0.40
567.8042603	0.22
571.0238037	0.25
578.5200806	0.47
583.1786499	1.84
585.7638550	0.46
589.3211060	1.36
590.2169800	0.30
591.0791016	0.67
595.4274292	4.70
596.1801147	3.45
598.0543213	0.48
603.0311279	1.77
604.1307983	43.72
604.8860474	4.80
605.6480103	0.17
606.7296753	1.21
620.2437134	2.87
621.3472290	2.39
622.0048218	0.30
622.6541748	1.21
624.8582764	0.45
625.7542725	1.11
626.4940186	0.50
628.4022827	13.13
629.4087524	1.73
630.3474121	0.73
631.5680542	0.60
632.5036011	0.35
636.9008179	0.60
643.3121948	0.78
647.0814819	1.26
647.8274536	2.59
650.6792603	1.02
651.6266479	1.84
652.4611206	1.74
653.1293335	0.48
653.8145142	1.57
654.7473755	0.41
676.4062500	0.38
677.7386475	0.27
685.4887085	2.08
691.2543945	2.44
692.6802368	1.07
694.4880981	7.85
695.2168579	2.72
697.0947876	0.54
699.7922974	0.20
700.3943481	0.68
701.6543579	0.19
703.0581665	0.52
704.9953003	0.46
706.3869629	3.91
707.0997925	0.91
708.7366943	0.14
711.2553711	1.89
713.2669067	0.60
715.2929077	6.11
715.9478149	16.28
717.5930786	0.27
719.4650269	2.27
720.0962524	32.02
721.2288208	1.04
721.9864502	0.15
723.2444458	0.42
724.4978638	1.19
734.1077271	0.25
737.3338013	0.42
739.5557251	0.40
748.2658081	0.80
750.9683838	0.54
752.3712769	11.44
753.6614990	8.35
754.7367554	1.87
755.5256958	0.33
756.5165405	25.60
757.1190186	29.02
757.9526978	2.09
758.6610718	0.52
759.6947021	0.88
760.9910278	7.48
761.8736572	1.44
762.4842529	0.76
770.0575562	6.74
771.3969116	1.00
772.4931030	0.96
776.9710083	0.63
777.6685181	0.71
780.5883179	12.12
781.1934814	0.39
784.9454956	28.66
785.6516724	5.97
787.0205688	0.88
788.3489380	1.46
789.1399536	0.66
789.9414673	1.34
794.0558472	15.14
794.6594849	2.05
795.9444580	0.81
797.7314453	1.30
799.2069702	0.45
802.5662231	1.06
804.4702148	0.29
806.1755981	0.60
807.4962769	0.21
810.9797363	3.75
811.7813110	1.83
813.7564697	1.23
815.9426880	2.11
817.4136353	3.36
821.1370239	0.70
831.4510498	2.76
834.4899292	0.47
835.3655396	1.81
838.4402466	0.59
843.6455688	0.30
851.6105347	2.90
858.6384888	0.74
865.0606079	0.63
869.6163940	1.38
870.5261841	0.15
873.6262207	0.51
875.2686157	0.14
878.9768677	0.37
884.5941772	0.61
892.7881470	15.91
893.6666870	1.98
900.2013550	1.35
900.8353882	0.72
905.2111206	0.11
909.0773926	5.57
909.9316406	2.49
917.6360474	0.44
925.6838379	0.39
926.5585327	0.68
937.4963989	0.37
942.2058105	4.20
943.3701172	3.58
944.4955444	1.53
956.4562988	0.71
957.6853027	0.48
965.5112915	0.49
976.2567749	0.64
977.6668091	0.16
979.7098999	1.27
984.6812134	4.15
985.6465454	2.42
988.5215454	1.60
989.2526245	1.29
992.8738403	2.35
993.8232422	6.31
994.7743530	0.64
998.1304321	1.51
1002.2897340	12.44
1003.0578000	3.72
1003.8301390	0.96
1009.0529790	1.79
1010.0239870	1.59
1014.5665890	0.51
1026.4930420	0.29
1032.2828370	1.80
1033.1909180	1.05
1041.2593990	3.06
1042.2752690	0.69
1049.5256350	1.93
1050.6035160	3.11
1055.9444580	0.26
1056.8802490	0.44
1057.7465820	0.41
1058.7424320	1.52
1059.9387210	0.72
1069.6135250	0.57
1085.4737550	2.16
1091.6983640	1.33
1093.5817870	0.42
1099.7951660	0.41
1100.7957760	0.87
1113.5721440	0.65
1117.3267820	0.16
1128.2916260	0.56
1131.3154300	1.27
1140.1508790	0.72
1145.5041500	0.42
1146.5810550	0.27
1156.4074710	0.18
1163.7260740	0.52
1211.8464360	0.27
1229.7292480	0.44
1237.0690920	0.84
1237.8090820	0.50
1240.9913330	0.43
1293.9538570	0.28
1335.7561040	0.43
1347.0229490	0.86
1353.0621340	0.40
1389.3250730	0.36
1391.1036380	0.26
1428.7683110	0.46
1434.7915040	0.29
1595.9528810	0.23
1606.6107180	0.48
1610.2536620	0.22
1692.6789550	0.15
1703.5588380	0.22
1705.2917480	0.19
1736.6844480	0.30
1766.0994870	0.88
1799.7585450	0.53
1816.6180420	0.37
1822.4901120	0.20
1840.2009280	0.14
1843.9012450	32.82
1847.7003170	1.90
1860.8638920	0.47
1871.0969240	0.39
1876.4738770	0.30
1884.3015140	2.99
1895.6510010	0.54
1903.5524900	0.18
1917.2305910	0.50
1921.2663570	0.65
1926.9171140	0.19
1930.7442630	0.11
1934.6053470	0.16
1936.3304440	0.99
1941.5245360	27.55
1946.9460450	0.27
1948.6334230	0.16
1949.5432130	0.99
1958.4036870	0.98
1966.1003420	100.00
1970.1370850	12.33
1971.0482180	2.82
1972.7303470	0.35
1973.5020750	0.12
1975.3366700	15.11
1978.0261230	0.20
1980.2580570	12.15
1983.3864750	15.57
1985.8726810	0.55
1987.0128170	3.51
1990.8835450	27.18
1993.2254640	15.58
1993.9486080	0.31
1994.7650150	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	481.06
Annotation	Unknow
Peak:m/z	Relative Intensity
148.8819275	2.52
151.1646881	0.04
160.9792786	0.04
179.1051331	0.20
221.1184082	0.08
227.1905670	0.07
254.1793518	0.02
256.4945068	0.02
259.1029968	0.10
265.0158997	0.02
276.2166748	0.01
288.8513794	0.02
291.3533936	0.02
295.1750793	0.21
298.3890381	0.03
313.1364746	17.96
314.0358276	0.03
315.2605591	0.06
319.1042480	0.07
323.3476562	0.06
331.2063904	0.30
333.1286011	0.05
337.0918579	0.05
338.1550598	0.04
379.4172363	0.24
384.4821777	0.04
393.4744568	0.06
394.3077698	0.02
399.2517700	4.64
404.3830261	0.05
411.2928162	4.74
416.2692871	0.04
417.1756897	0.03
427.2691345	0.03
430.4662781	0.10
432.4866333	0.08
434.7518616	0.13
435.4476013	0.01
436.3359680	0.08
437.4426880	0.32
439.4694519	0.14
442.0445862	0.05
445.0836487	100.00
445.6848755	0.50
452.1170349	0.03
462.8621216	0.24
463.4746399	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	587.91
Annotation	Unknow
Peak:m/z	Relative Intensity
202.9188843	0.13
238.1655273	0.04
245.0695038	0.06
273.0499268	1.01
274.0549316	0.34
311.1514893	0.09
359.9213867	0.03
387.1463623	0.54
388.1256714	0.11
427.0813599	4.20
428.1286011	2.63
429.2266846	0.34
430.1472168	0.10
431.1730957	0.10
433.0945435	0.07
445.1511230	0.06
455.9885254	0.05
472.0361938	0.54
472.9937134	3.28
473.8054199	2.47
485.1820068	0.10
486.2003784	0.08
492.0618896	0.03
501.1668091	0.05
503.9419556	0.06
513.0359497	0.35
514.2314453	0.07
515.1834106	0.20
520.2359619	0.08
540.8970337	100.00
541.8486938	47.30
542.9163208	0.56
543.9283447	0.39
557.9412842	0.04
559.6205444	0.04
568.9754639	0.17
569.8483276	0.17
570.9403687	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.1375
Annotation	Unknow
Peak:m/z	Relative Intensity
188.9442139	0.03
189.7851105	0.11
191.0496216	0.08
192.2278900	0.06
193.1838684	0.10
198.0818176	0.14
203.1421204	0.28
211.1072083	0.03
213.3349609	0.04
217.1794891	0.22
218.0789337	0.08
219.4608154	0.26
220.1871185	3.17
221.1579285	0.72
222.1785889	0.04
225.0370636	0.23
229.0154419	0.05
230.7178802	0.03
232.0925293	0.39
233.2883606	0.03
233.9754333	0.09
237.1245880	0.03
238.0200043	0.07
239.9482117	0.16
241.0457458	0.14
245.0667572	0.46
245.9341736	0.03
248.1340790	3.18
249.1074371	0.22
250.3272247	0.08
254.2386780	0.05
255.0596924	0.11
257.1240234	0.07
259.2071838	0.02
260.1865845	0.36
261.2028503	0.12
262.2457886	0.28
265.3785706	0.06
266.4113770	0.19
268.3558350	0.05
269.2581177	0.08
270.1508789	0.23
270.9850159	0.09
272.1229553	0.09
276.8988037	0.11
279.1342468	0.17
280.1295166	0.32
280.8579712	0.03
282.2892151	0.17
283.0421753	0.20
285.0082092	0.04
287.3330688	0.05
295.3184204	0.04
296.2997131	0.13
297.1779175	0.09
298.1317444	0.12
299.4728088	0.06
300.3740540	0.26
301.1877747	0.12
303.7790527	0.03
306.1678467	0.11
307.1864014	0.04
308.0376587	0.11
309.3072510	0.05
309.9984741	0.04
311.1583252	0.36
312.0422974	0.14
313.2491455	0.20
314.1929321	0.48
315.2582703	0.19
316.4772339	0.03
320.3344727	0.06
321.0604553	0.11
321.7911377	0.06
322.5004883	0.02
323.2322388	0.25
324.3658447	0.32
325.0927734	2.10
326.2009277	1.52
327.0659790	0.64
328.0281677	0.03
334.2308960	0.07
336.1093140	0.10
337.2579346	0.16
339.2164917	0.16
340.1497192	0.80
341.2246704	0.72
342.1476440	0.98
343.5923767	0.07
350.0863037	0.08
351.0924683	0.03
352.3323975	0.72
353.2095337	2.14
354.2697754	0.41
355.2581177	0.13
363.0311890	0.04
364.0800781	0.06
365.1669922	0.05
366.2167969	0.30
367.1486206	0.33
369.1038208	22.70
370.1978149	100.00
371.1890259	14.94
372.1210327	0.06
379.5998535	0.02
380.3305054	0.04
381.3171387	0.07
382.2131958	0.30
383.3020020	0.18
384.2299194	0.10
394.3831787	0.24
395.0718384	0.06
397.1846924	0.20
400.4113159	0.07
401.2854004	0.11
403.2512817	0.05
406.1226807	0.12
409.2788696	0.06
410.1749878	0.06
412.2170410	5.66
413.3054810	0.63
421.5379639	0.04
423.2874146	0.05
424.1158447	0.48
425.2180786	0.08
426.0494385	0.11
427.0761719	0.09
428.6188354	0.03
436.2334595	0.05
437.1701050	0.05
440.0886841	0.06
442.2452393	0.71
443.4364624	0.31
453.5687866	0.04
454.5366211	0.08
457.3092041	0.06
460.2208862	0.04
461.5972900	0.07
465.0692139	0.12
467.4163818	0.03
473.2030640	0.12
478.2716675	0.11
479.2314453	0.05
483.1461792	0.06
486.9871826	0.04
497.2321777	0.03
500.5468140	0.10
505.9508667	0.04
507.2790527	0.05
514.3965454	0.08
515.6687012	0.14
516.6381226	0.12
523.3291626	0.10
525.1239624	0.12
526.1058960	0.04
532.5070190	0.34
533.3333130	0.02
534.2677612	0.04
543.4024658	0.10
546.4143066	0.03
547.3804321	0.03
557.5311890	0.05
558.7565308	0.12
560.8787842	0.03
564.2401123	0.18
565.2736206	0.06
566.2019043	0.04
568.2072144	0.05
569.4734497	0.03
589.0870972	0.03
591.3047485	0.20
592.2417603	0.14
599.0408325	0.06
609.0844116	0.99
610.2609863	0.09
614.1835327	0.04
617.7036133	0.03
618.3139038	0.08
619.2035522	0.29
632.2482300	0.05
634.5692139	0.05
635.3963623	0.39
646.6834717	0.04
648.4450073	0.08
660.3148804	1.26
661.4011841	0.30
663.7534790	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.1769
Annotation	Lactucaside
Peak:m/z	Relative Intensity
161.1735687	0.13
164.8340454	0.90
178.0322418	0.60
191.2717285	0.10
193.0978546	14.94
195.0437012	2.52
201.8915100	0.15
207.4257507	0.13
217.1081543	0.23
226.3620605	0.15
235.0649872	1.53
243.4499512	0.25
247.0800476	0.15
254.9978027	0.28
257.0238647	0.32
258.7543335	0.19
272.2337952	0.07
279.1669312	0.26
281.2379150	0.25
282.3728638	0.14
283.5375366	0.14
284.1730347	0.09
285.1536255	1.97
287.0545654	0.11
295.4976807	0.10
299.4618225	0.22
319.1524658	0.06
325.1136475	0.09
327.1398926	1.55
328.2500000	0.09
329.0807495	0.12
333.3643188	0.28
336.9022827	0.13
341.2782593	3.36
345.4431152	0.06
355.2784424	1.19
357.3184204	0.08
363.3765869	0.09
371.1812744	0.76
375.0874634	0.13
383.0108032	1.06
385.3074341	0.11
387.4144287	0.09
389.1014404	100.00
393.9354858	0.25
394.9903564	0.11
397.2287598	0.22
399.1458130	0.11
402.7863159	0.32
403.4414062	0.53
407.4805908	0.12
411.3090820	0.18
413.0879517	0.22
418.8778687	0.09
421.2773438	0.45
431.2121582	11.86
432.1398315	0.38
434.4568481	0.05
435.3409424	0.18
437.1913452	0.26
442.3825684	0.50
443.0283813	1.18
445.2537231	0.22
447.3413086	0.26
450.5539551	0.31
454.9552612	0.10
459.2338257	0.21
460.5161133	2.69
461.1350098	25.60
463.3457031	0.04
470.3986816	0.04
473.1557007	0.38
475.2152100	0.12
482.4686890	0.12
485.2863159	0.06
487.3366089	0.33
488.6397095	0.08
489.4829102	0.22
490.9801636	45.16
491.6721802	0.13
497.6511841	0.12
501.3948364	0.19
504.1833496	0.16
505.2792358	0.34
507.3151855	0.46
514.6249390	0.35
515.2998047	0.21
516.3881226	0.15
519.4611206	0.16
520.3875732	0.16
521.2689819	2.15
529.0695190	0.52
531.4595337	0.16
532.5894775	0.66
533.2833862	6.75
534.2697754	0.11
534.8988647	0.06
541.7860107	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.3387
Annotation	Lanceolitol B4
Peak:m/z	Relative Intensity
255.4194336	0.11
277.1707764	0.20
280.7042236	0.23
283.9024658	0.21
307.2962952	0.07
323.2911377	0.14
344.3175659	0.24
371.2108154	0.10
385.1719971	0.16
402.9879150	0.26
404.2344360	0.12
415.3696899	0.11
416.5967407	0.41
417.2149658	0.52
429.1857910	0.31
431.1449585	0.06
438.1742554	0.07
444.7767944	0.08
447.0870361	0.08
451.6077271	0.10
452.6856079	0.57
457.7086792	0.30
458.4928589	0.29
483.1583862	0.27
484.3875122	0.06
489.4282837	0.15
494.4977417	0.13
495.1542358	0.23
495.9354248	0.34
499.4110718	0.06
502.9711914	0.11
504.9912109	0.13
512.5187378	0.09
515.4693604	0.57
519.2753296	0.46
533.4131470	100.00
534.1528931	0.43
541.2861328	0.09
542.8111572	0.63
546.2739868	0.17
548.4513550	0.19
560.1245728	0.21
561.0776978	0.76
561.8191528	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1072.4517
Annotation	Unknow
Peak:m/z	Relative Intensity
343.4862061	0.26
481.3042297	0.40
629.6239014	0.28
776.2711792	0.20
872.3864746	0.54
930.2113037	0.19
931.5815430	0.08
933.9449463	0.17
954.9384766	0.23
961.8343506	0.48
967.9443359	0.16
982.1386719	1.12
986.7509766	0.69
989.3889160	0.92
991.5006104	2.08
995.9042969	1.51
999.5058594	0.35
1002.0159910	0.19
1002.8601070	0.24
1005.3691410	0.92
1014.7113040	0.35
1016.7575680	0.98
1020.1437990	0.97
1022.3791500	0.52
1023.2763670	0.49
1025.6166990	0.95
1029.1357420	2.12
1029.7409670	0.65
1034.5949710	6.88
1037.0573730	0.73
1039.0571290	0.41
1040.1860350	1.23
1041.0021970	0.63
1043.3707280	0.43
1047.7078860	1.11
1049.3192140	1.45
1052.0130620	0.12
1054.0019530	0.74
1054.8344730	0.55
1055.7636720	0.92
1057.7465820	3.62
1058.5389400	1.26
1060.9772950	7.28
1199.0305180	0.27
1203.2575680	0.70
1207.2199710	0.41
1280.6324460	0.37
1310.7930910	1.23
1318.9432370	0.43
1321.7420650	0.43
1328.1290280	0.30
1337.6005860	0.17
1338.2390140	0.45
1345.6608890	1.17
1353.8101810	0.27
1368.7868650	0.15
1377.7530520	0.26
1379.6688230	0.32
1401.8038330	1.07
1411.6495360	0.32
1417.3281250	0.65
1418.1623540	0.35
1420.2126460	0.46
1421.7147220	0.24
1438.0130620	0.22
1470.8111570	0.40
1475.7159420	0.49
1498.6343990	0.69
1507.9056400	1.76
1508.8173830	1.01
1542.4239500	1.01
1543.9458010	1.29
1551.5279540	1.55
1658.0814210	0.28
1666.9591060	0.09
1678.7144780	0.47
1690.9373780	0.31
1691.7062990	0.07
1697.8612060	0.13
1710.6248780	0.11
1722.8612060	0.10
1732.5369870	0.46
1745.1218260	0.40
1746.2862550	0.16
1749.0513920	0.11
1753.8050540	0.07
1758.2697750	2.28
1765.1378170	0.34
1770.8029790	0.35
1772.5671390	0.79
1792.0531010	3.58
1794.6359860	0.25
1798.8048100	0.17
1799.8753660	1.44
1801.1009520	0.13
1811.9045410	0.97
1812.8693850	1.04
1814.8039550	1.03
1818.1711430	0.09
1821.8470460	3.33
1826.2146000	3.03
1830.3587650	0.22
1832.7409670	0.57
1835.2269290	0.14
1836.8719480	1.94
1847.1685790	12.29
1853.7535400	2.69
1864.0587160	0.73
1867.0583500	0.61
1868.3107910	0.73
1871.6373290	1.97
1873.9216310	7.44
1878.7390140	1.73
1879.8770750	1.52
1880.5939940	1.23
1881.2210690	1.24
1884.2520750	1.06
1886.1304930	1.26
1889.5555420	0.60
1891.8626710	0.13
1895.0159910	0.48
1897.3463130	0.59
1897.9841310	0.17
1902.9837650	0.69
1903.6934810	0.18
1904.8625490	0.65
1907.5496830	1.87
1908.6451420	2.19
1910.6242680	1.08
1911.3094480	39.16
1913.4122310	0.98
1916.9857180	0.31
1923.4739990	0.40
1925.6779790	0.25
1927.7969970	2.15
1928.6610110	1.44
1930.8106690	0.11
1931.7777100	3.75
1933.9720460	0.24
1935.2658690	0.45
1936.1849370	18.72
1937.0780030	0.68
1938.0847170	6.22
1939.7960210	1.54
1942.3889160	7.80
1943.7067870	0.27
1948.8703610	1.47
1949.5264890	0.11
1953.5729980	3.57
1955.3905030	100.00
1959.6853030	2.12
1961.3845210	0.21
1963.4108890	0.13
1964.8824460	0.54
1965.7032470	0.52
1968.9302980	1.11
1969.6091310	0.60
1971.4127200	3.17
1972.1234130	1.43
1973.0183110	0.31
1974.1500240	12.79
1978.6481930	17.87
1979.4368900	0.84
1981.1599120	0.17
1982.2083740	4.93
1983.3713380	5.54
1984.1442870	1.09
1985.5412600	0.23
1986.9035640	0.09
1988.0866700	0.34
1988.7891850	10.70
1991.3966060	13.18
1992.3093260	44.58
1993.3035890	45.80
1994.6203610	6.38
1996.1724850	0.26
1997.4556880	10.56
1999.7346190	3.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.2918
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
198.1586761	0.18
221.2937622	0.03
245.2023621	0.04
263.2546692	0.06
283.3289795	0.02
292.1732788	0.07
306.3659058	0.21
319.5061951	0.03
324.5500793	0.07
332.2033691	0.02
337.2964478	100.00
337.9313354	0.19
435.1737976	0.14
460.2720032	6.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
97.03394318	0.49
100.8758087	0.49
111.1345444	1.66
123.9114838	1.06
127.184906	0.47
135.0942688	2.14
136.79216	0.69
138.8535156	2.39
141.1551208	1.06
143.0191345	0.54
145.1141357	0.56
155.000061	1.84
157.101532	1.03
165.0545807	1.06
167.1086426	0.96
169.1576691	1.39
171.1478882	0.82
177.0042267	1.01
180.8800964	1.72
182.3119812	1.01
183.1348114	0.53
184.2840424	0.57
185.2545471	0.54
190.9851685	0.80
193.0953217	0.87
195.0236511	3.06
197.1896515	1.88
199.3711243	0.76
203.2203979	1.63
207.3012695	0.47
209.0426331	1.14
211.3192139	0.65
214.8386536	0.84
225.2009888	0.89
227.1312561	0.63
231.1737976	0.50
235.2431946	1.55
237.2213135	3.00
238.0506897	1.46
239.3599854	3.10
241.449646	0.77
242.131073	0.37
251.3659058	4.96
253.067627	10.74
255.1277161	0.95
256.9907532	1.26
263.9883423	1.88
264.9250793	2.07
267.2793579	6.60
269.2625122	0.70
275.2884827	19.86
277.1844482	0.44
280.774292	0.90
282.3657837	0.80
283.0301208	2.99
293.2079773	100.00
294.2718506	1.20
296.0650635	1.07
310.0594482	1.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	523.3409
Annotation	Unknow
Peak:m/z	Relative Intensity
158.1879425	0.22
175.1294861	12.52
196.9037323	0.12
212.7069244	0.08
307.8286743	0.24
315.3353271	0.08
332.2868652	0.21
349.1317749	100.00
359.9526367	0.23
368.2221680	4.80
377.2601318	0.68
378.2885132	0.36
387.0500488	0.21
415.0468750	0.25
417.3040161	0.09
439.0670776	0.24
442.1828003	0.11
476.9059448	0.51
486.5531616	0.49
488.2045898	0.61
505.0263672	0.32
505.7495728	0.95
506.4642334	0.45
507.5909424	0.62
514.3016968	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.3382
Annotation	Lanceolitol B4
Peak:m/z	Relative Intensity
171.1462250	0.05
194.9630585	0.04
203.8789825	0.02
222.1991730	0.03
236.7542725	0.04
239.0561218	0.04
241.3527527	0.11
255.3391418	0.04
277.0778809	0.04
279.7868042	0.03
295.3767700	0.04
299.9399414	0.03
307.7972717	0.14
333.3064575	0.03
336.0195312	0.04
348.1280518	0.03
349.2242432	0.03
368.9656372	0.02
371.2857056	0.08
383.1339722	0.02
407.2238770	0.09
417.3699951	0.43
418.1594849	0.77
428.2327271	0.04
429.3096924	0.03
430.0125732	0.03
432.3217163	0.04
435.3120117	0.02
451.3027344	0.20
455.0869141	0.10
458.5367432	0.08
459.4959717	0.36
462.1912842	0.03
463.4290161	0.03
466.1798706	0.03
483.3389282	0.10
484.3401489	0.08
499.2166748	0.08
507.2655640	0.04
508.3836060	0.09
512.1487427	0.08
517.3023682	0.17
524.8520508	0.02
531.5336304	0.03
533.4446411	100.00
534.5293579	24.00
535.7463989	0.10
536.4556274	0.35
543.0872192	0.04
543.9295044	0.29
555.0459595	0.03
561.5040894	0.22
563.0643921	0.08
570.6207886	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	460.1287
Annotation	Unknow
Peak:m/z	Relative Intensity
157.0872650	1.47
165.8627625	0.05
188.9674072	0.07
196.5381775	0.08
213.2107544	0.07
214.1548767	0.24
214.9361572	0.12
215.9714050	0.24
225.5817413	0.18
226.2633667	0.82
228.1064606	0.10
229.1954193	0.25
231.0523071	0.46
240.8949280	0.11
242.1693115	2.06
243.2346497	3.32
244.3227844	0.29
244.9855652	0.05
247.2004089	1.23
248.0436707	0.09
250.4856262	0.05
257.0942383	0.13
258.2004700	0.18
260.3785400	0.26
261.2233887	0.34
261.9910889	0.09
263.1549072	0.07
272.1255188	0.16
273.1611633	1.89
275.1382446	14.07
276.1441040	0.55
289.0402222	0.31
290.1604004	0.55
293.2721863	0.26
296.1025391	0.10
299.2634888	0.40
305.2731323	1.04
307.1155090	48.61
308.2189331	5.54
309.2689819	3.02
310.7921753	0.07
321.3013306	0.14
322.2584229	0.62
326.1245117	0.28
327.1782227	0.17
339.0991821	39.18
340.3173523	3.41
341.2393799	3.44
342.2557678	0.23
344.0610352	0.25
365.9930420	1.13
369.2438354	0.21
370.4730225	0.12
373.2491760	0.46
379.1111755	0.18
382.3367615	41.46
383.2381897	2.09
386.1301880	0.18
394.7556763	0.44
404.0107117	0.23
405.6272888	0.32
407.0153198	0.31
409.0977783	0.22
411.9319153	0.26
415.4941101	0.22
417.2284851	0.08
419.1704102	0.07
421.1342468	1.97
422.1581116	0.24
422.9388123	0.23
423.9937744	0.32
425.2055969	1.90
426.1392517	0.25
427.2759094	2.97
428.0406189	0.51
430.3380737	38.37
431.3103638	0.89
433.6822510	0.20
434.5487976	0.40
437.8016357	1.51
439.3092957	0.72
440.0270691	0.69
441.3541565	0.70
442.6267395	8.57
443.4065552	11.72
444.1800842	0.04
449.2898254	0.11
451.4532776	100.00
452.3399963	9.72
453.7974243	0.05
475.3591919	0.04
483.4945374	0.26
489.2150574	0.11
492.3146057	0.09
530.4766235	0.08
539.5719604	0.15
545.5922241	0.08
547.3560791	0.95
549.5783081	0.16
553.1545410	0.29
554.3547363	0.11
559.4711304	0.12
563.1686401	1.01
564.2686157	0.57
577.2904663	0.07
579.1428833	1.94
581.2570801	13.93
582.3036499	4.69
585.2809448	0.19
588.7687378	0.28
595.3858643	0.89
596.1720581	0.31
597.4866333	0.11
607.3518066	1.51
608.3273315	0.09
610.4984741	0.28
611.4168091	0.51
613.2832031	14.90
614.3552856	3.50
625.6364136	0.29
627.2412720	0.22
629.3778687	0.18
631.5698853	0.07
645.1231079	1.28
646.2916870	0.32
647.2827148	1.00
648.0118408	0.33
658.8301392	0.07
662.4347534	0.10
674.6400757	0.22
675.6196899	0.07
685.2678833	0.26
703.0991211	0.56
704.1407471	0.09
729.2598267	0.26
730.5454712	0.31
740.7316895	0.18
745.3316650	2.21
746.4096680	1.84
763.2714233	17.17
764.3582764	4.21
771.7777100	0.16
799.2140503	0.19
843.0448608	0.13
868.2117310	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	373.13
Annotation	Glycosmisic acid
Peak:m/z	Relative Intensity
121.9667435	0.55
137.0695801	0.70
148.8768921	0.31
168.5678101	0.85
169.1713867	0.46
200.9581146	0.35
205.0802917	0.46
206.8918152	1.22
210.9602814	0.41
217.1778870	0.42
218.9476929	18.17
224.9955444	1.33
281.4324341	0.53
299.0588989	1.66
302.3433838	1.94
307.2336426	2.17
309.2298584	2.68
310.9664917	0.31
313.3715210	0.28
325.1981201	7.35
327.2848816	1.45
329.2239075	0.32
330.2799072	1.36
337.1383667	1.54
343.0783386	100.00
344.1413574	0.69
355.1922913	74.62
356.0652161	1.05
363.2153015	0.65
365.1564026	2.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	630.0789
Annotation	Unknow
Peak:m/z	Relative Intensity
181.1240082	1.74
186.2149963	0.40
248.2641907	0.76
258.8976746	6.89
276.0105286	1.86
276.9527588	2.00
287.1452332	1.32
288.1442261	0.90
291.2584839	0.44
294.9318848	0.99
300.1039124	3.46
314.3367920	0.17
318.1807251	41.34
336.1559448	100.00
338.0653076	0.80
359.3012085	0.52
361.0640259	0.26
369.0888672	0.29
378.1375732	2.42
382.4595337	0.40
401.2304077	0.51
408.2000122	0.86
414.1423340	0.43
420.2607422	0.93
429.2712402	0.73
449.0695190	1.19
449.9994507	0.15
459.4513550	1.06
470.3159180	0.33
473.2301636	1.01
481.0850220	0.55
482.4379272	0.90
487.5839844	1.23
495.2925415	1.35
496.2844849	0.37
500.0607300	0.67
516.5267944	2.47
522.0219116	3.27
543.1226196	2.15
544.7155762	0.32
551.3253174	0.26
569.9622192	1.01
595.3201294	2.19
606.2590332	0.35
620.7153931	1.75
639.7714233	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	164.07
Annotation	Homomethionine
Peak:m/z	Relative Intensity
55.9580803	0.08
62.9974060	0.05
73.9120789	0.61
90.0469131	0.03
101.9094543	100.00
102.6865997	0.04
147.2037964	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	527.1743
Annotation	Deoxyloganic acid tetraacetate
Peak:m/z	Relative Intensity
149.0472260	0.01
151.4194489	0.02
154.2874756	0.02
161.0903320	0.07
162.9462128	0.02
167.2816010	0.46
168.2350159	0.17
169.1852875	0.63
171.1754456	0.41
175.0405273	0.40
178.9855347	0.02
183.1447449	0.02
191.1090546	0.21
193.0599976	0.03
195.0035400	0.02
197.1010742	13.97
205.0371094	0.09
215.1155396	100.00
220.8871155	0.21
239.0087280	0.03
250.9658356	0.49
265.1088257	0.56
275.1126099	0.05
276.8745728	0.02
293.2124023	0.04
306.8574829	0.05
310.9613647	1.37
324.8585815	0.02
362.8969116	0.02
377.4092407	0.03
406.8806152	0.05
408.1627808	0.03
411.3391724	0.05
419.0266724	0.04
425.4185791	0.05
431.1269531	0.02
466.0317993	0.01
466.7607422	0.03
480.6559448	0.04
481.3632812	0.08
482.3453979	0.04
507.1642456	0.04
508.5570679	0.07
527.0170288	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	777.1147
Annotation	Unknow
Peak:m/z	Relative Intensity
323.0397339	1.16
358.9064331	1.49
361.2594910	0.62
388.9800415	4.74
458.7579956	0.48
472.6625366	1.27
497.0863647	0.30
503.0239258	0.66
532.9304810	41.11
534.9927368	2.18
541.9702759	1.92
592.6661377	0.88
603.1344604	100.00
613.8541870	0.34
614.9345093	4.14
622.8291626	2.72
626.1712036	1.32
641.0496826	28.84
642.1840820	0.83
643.8839722	2.54
645.1520996	0.92
656.7142944	1.95
657.4116821	1.08
665.0446167	3.17
685.2861938	0.36
689.8821411	2.98
692.7516479	5.25
698.1893311	2.57
716.1484985	0.80
730.9817505	1.71
734.0219727	32.69
734.9827271	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.1821
Annotation	Geniposide pentaacetate
Peak:m/z	Relative Intensity
182.9508820	0.05
245.4266357	0.07
247.1287994	0.11
254.3343811	0.18
270.2941284	0.06
301.1198730	0.08
301.8320312	0.28
306.0039062	0.16
315.0978394	0.70
325.2558594	0.29
327.0629272	0.19
329.9077759	0.15
337.3104248	0.24
338.9867554	0.18
343.2987671	0.18
345.2554932	0.93
352.2520752	0.09
353.0351562	0.05
357.1927490	100.00
357.8301392	0.66
359.1353760	0.21
361.4128418	0.18
369.2514038	1.45
372.4786987	0.08
373.3994751	0.32
379.2900391	0.06
385.3287354	0.06
387.1893311	82.35
387.8549194	0.16
391.3122559	0.10
393.4303589	0.10
394.4307861	0.05
396.1102295	0.18
397.1862793	0.05
399.3164062	2.68
400.4718628	0.09
413.2431641	0.16
417.3084717	26.57
421.3220215	0.09
422.4223022	0.49
429.1343994	0.82
429.8069458	0.13
430.4761963	0.22
434.3163452	0.52
435.3598633	0.37
438.0438232	0.22
441.3703613	1.95
443.2396240	0.27
444.2161865	0.47
445.2878418	0.44
447.3955078	0.87
452.3659668	0.62
453.3999634	0.04
459.2463379	19.34
471.3836670	0.68
473.2866211	0.21
475.0941162	0.56
477.2182617	86.47
489.2293701	17.08
493.2807617	0.13
497.3820190	0.32
500.9624634	0.33
507.2277222	5.77
508.5230103	0.07
509.6470337	0.45
514.6926880	0.11
516.0625610	0.18
519.3403320	0.12
520.6586304	0.20
531.4719238	0.08
533.4925537	0.14
534.4013672	0.08
537.1802368	0.12
543.2631226	0.31
549.4135742	0.22
550.4111938	2.53
551.2356567	0.32
552.3391724	0.85
553.2843628	0.08
559.4452515	0.08
560.6183472	0.58
561.3178101	2.78
562.3342285	0.22
564.3482666	0.19
567.1053467	0.10
574.3864746	0.52
576.2865601	0.07
579.1913452	14.80
580.0900269	0.41
597.3226318	0.12
601.2351685	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.92
Annotation	Unknow
Peak:m/z	Relative Intensity
155.1539154	0.03
155.7761993	0.02
158.9638824	3.16
160.0416107	0.33
199.0560455	0.65
200.1142883	0.12
217.0295258	0.14
217.9750061	0.09
228.9731445	0.60
230.0366516	0.31
248.1166077	0.01
272.9902649	48.95
274.0135498	11.99
362.0621338	0.02
385.3227844	0.03
386.9669189	100.00
387.9425049	32.62
413.9420776	0.02
426.8502502	0.07
454.7624207	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
114.7748718	0.95
119.2175217	0.66
124.7806625	0.54
142.9469604	0.71
155.0686493	0.68
183.039032	0.51
187.014328	0.75
197.1626282	3.10
203.3057556	0.41
205.1796265	1.23
211.1947327	0.44
217.272644	3.26
223.1800842	0.75
225.1102295	2.31
229.0648193	0.85
231.0889893	0.38
235.3452148	2.10
236.9967651	13.23
239.1323853	0.68
241.1734619	0.41
247.3201904	1.12
249.0584412	0.71
251.0261536	0.96
252.0964966	1.83
252.936554	0.88
255.0592651	19.00
269.3620605	3.00
275.2699585	5.34
277.0498047	0.54
283.2583618	0.41
293.2070923	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	443.1342
Annotation	Daidzein G 2
Peak:m/z	Relative Intensity
131.1485138	0.21
132.8680420	1.07
133.9578247	5.27
135.0308380	5.34
136.9170685	1.06
143.0595551	0.08
145.1042175	0.10
146.0874939	1.05
147.0205994	1.45
148.2640381	0.44
149.0790100	2.99
150.9763641	0.17
155.0597839	0.10
158.9505615	3.45
159.9869537	2.16
161.0612335	16.83
162.4015198	0.26
163.1136017	0.07
172.0439911	0.52
173.0732422	1.89
174.0822754	0.18
175.0232239	6.18
175.9458923	0.10
177.9630432	3.75
179.0473633	2.20
186.8206177	0.31
190.0671997	0.74
190.9844666	1.72
193.0931702	52.92
194.3775635	0.16
203.8529510	1.27
204.9902039	3.74
207.0407562	61.80
216.1391296	0.13
219.5419769	0.10
234.4879150	14.06
235.1554871	100.00
236.3088074	0.42
249.0807495	27.40
250.2810669	0.18
253.2121887	1.90
255.2052612	0.13
267.1304932	5.47
293.2152710	2.04
307.1172180	0.24
309.2225952	0.14
325.9837341	0.12
342.1018066	0.24
355.9560547	0.14
370.2203674	0.10
380.3659973	0.62
384.0353088	0.13
396.8915710	0.25
398.6634216	0.31
401.0228882	0.34
404.8820496	0.13
406.1991882	0.22
410.4291687	0.09
421.9962463	0.18
425.1978455	0.27
428.1779175	10.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	600.4162
Annotation	Unknow
Peak:m/z	Relative Intensity
172.0085907	1.86
174.2208405	0.88
176.1343079	0.76
181.1380768	0.88
183.1896362	1.85
185.1132507	2.45
187.3261261	1.14
190.1106873	1.12
193.3447723	1.82
203.1163177	2.89
207.1900330	1.24
207.8328247	0.60
211.2817841	2.99
215.1569519	4.07
216.9076080	0.70
219.2545624	7.44
221.0796204	21.36
222.2198486	1.06
223.4686584	2.17
231.3827057	1.36
232.0078583	1.06
233.2771606	0.52
234.2882690	2.75
235.3865204	2.99
237.1336975	23.43
239.2194214	2.20
243.3162994	1.67
246.8500671	5.63
248.0646820	16.16
250.2940521	5.65
251.1099854	9.46
253.1634827	2.36
255.3993988	4.13
256.4135132	3.64
257.3010864	0.61
259.1676025	1.19
259.9577026	4.43
260.9328308	2.53
263.0536194	2.93
264.1296387	1.96
265.2667847	0.82
269.6490479	4.53
270.2691650	1.17
273.2314148	0.94
274.3945923	2.26
277.1383972	0.70
279.1086426	3.50
280.6572266	0.59
285.1595459	2.25
286.3704529	5.20
287.3100281	5.79
289.0864868	1.43
291.1610107	1.06
293.4943237	1.14
294.1878052	2.76
296.5577393	1.24
297.4650879	2.61
298.2590942	0.94
299.2877808	9.92
300.2205811	1.71
301.0612183	1.67
303.2400513	4.64
305.3779907	1.72
309.3146973	0.52
310.2206421	1.78
311.2916260	5.80
312.3386841	4.42
313.3748779	3.34
319.2920532	0.82
321.5917969	1.42
322.3059692	1.72
324.3819580	1.42
325.2064209	8.81
326.2949829	5.67
327.2044067	0.94
330.9226685	0.90
334.5956421	1.25
339.1583252	4.21
341.3262939	1.43
343.5833740	3.00
345.4329834	1.13
346.5163574	0.71
347.3756714	1.36
351.5591431	11.92
352.2770996	50.71
353.1653442	5.28
355.2272949	0.64
356.1145630	2.27
360.4781494	4.96
362.3178711	1.97
364.4356689	1.73
365.4328613	9.94
366.3263550	2.39
369.1614990	2.57
375.2157593	4.64
377.2589722	3.74
378.3814697	1.11
379.3881226	7.09
383.3848267	4.30
388.3521118	1.00
391.3252563	9.31
392.3549805	3.20
401.6144409	7.44
402.3765259	0.58
412.0679932	1.99
413.3848877	2.26
414.5212402	0.94
415.4293213	3.44
418.5859985	0.82
419.5368042	0.52
420.3028564	9.25
424.3940430	1.18
425.5740967	3.49
429.5561523	1.44
431.4165649	1.79
433.3768921	2.75
436.6146240	2.74
437.2651367	3.49
441.2944946	2.04
443.6976318	2.95
444.3466797	1.73
445.6759033	4.99
450.3762207	0.58
454.1798096	7.54
454.7839966	3.16
460.2607422	1.42
463.4020386	3.83
467.6461792	2.91
476.3864746	3.72
481.2712402	3.07
482.2651978	0.88
485.4205322	0.94
492.7205200	3.89
497.3262939	2.53
500.4461060	2.03
502.5212402	5.81
504.2219849	3.41
505.2887573	8.10
506.9324341	6.27
507.6104126	37.51
508.5466919	20.54
518.6875610	2.22
520.2904053	100.00
520.9671021	3.08
525.1323853	1.12
531.3604126	2.28
536.4212646	4.59
539.3556519	1.36
541.5909424	1.72
542.5435181	1.61
549.2732544	3.78
554.6250610	2.31
557.5762329	2.40
564.4896851	4.21
567.4032593	3.64
568.8171997	3.82
571.6799927	1.90
581.4774780	35.16
582.4919434	50.55
583.3693237	12.32
585.6792603	12.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	423.179
Annotation	Ugonin P
Peak:m/z	Relative Intensity
229.0489502	0.49
272.8810730	0.20
278.9675293	0.85
283.3456421	0.20
293.1080017	100.00
308.1472473	0.53
309.1809692	0.73
316.8828125	0.35
333.0789185	1.48
348.7586670	0.45
371.4205017	0.26
376.8869019	0.95
381.4620667	2.69
395.3879700	0.36
405.2445374	24.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.1594
Annotation	Rutine
Peak:m/z	Relative Intensity
177.0688324	0.06
182.9950562	0.08
195.0744324	0.12
206.7906342	0.11
245.0154877	0.20
247.2056122	0.40
257.2915649	0.10
273.2690125	0.08
303.0451355	100.00
314.909668	0.32
327.3873291	0.28
345.0483398	0.32
360.5853882	0.47
381.039917	0.17
398.850708	0.06
411.1204224	0.07
429.3891602	0.14
431.171875	0.13
446.9038696	0.55
448.1999512	0.92
448.9021606	2.96
449.5175171	0.96
465.0534668	43.30
481.1786499	0.49
489.2652588	0.42
491.0924072	0.66
511.1490479	0.56
520.394104	0.06
531.7713013	0.21
542.9760742	0.11
549.8257446	0.56
591.9863281	0.33
593.0106812	0.88
601.5719604	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.0775
Annotation	L-Ascorbic acid-2-glucoside
Peak:m/z	Relative Intensity
97.0665970	0.08
99.0173798	0.32
100.9470215	0.36
110.9461365	0.50
112.9491730	1.11
115.0194092	0.73
117.0263443	0.09
125.1241531	0.04
126.9561386	0.80
128.9860992	0.58
130.8503571	0.05
139.0567932	0.21
140.9607849	0.09
143.2106934	0.04
145.0762787	0.03
149.0427704	0.02
151.2926788	0.02
153.0893555	0.02
155.1082764	0.06
156.9660339	1.98
161.1100464	0.03
167.0551147	0.01
169.0205078	1.58
173.2789307	0.07
173.9533691	0.95
175.0606537	1.29
179.0956268	0.04
181.3418732	0.02
183.1656799	0.05
189.1073151	0.01
199.0137634	0.08
201.0502014	0.04
203.1637268	0.04
209.0481567	0.03
211.1967773	0.01
214.3071594	0.03
215.2769165	0.03
217.1287231	0.02
219.2802124	0.08
228.8216553	0.08
237.4058533	0.03
247.0400085	0.12
255.0756836	0.03
257.0667114	0.01
265.0197144	0.09
274.1699219	0.02
277.0779419	100.00
278.2920532	0.02
293.2813721	0.03
306.0242004	0.06
307.8401489	0.02
316.7554321	0.02
318.0728149	0.07
319.0379028	0.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.1769
Annotation	Lactucaside
Peak:m/z	Relative Intensity
153.9527893	0.26
155.0420532	0.12
165.0054626	0.25
167.9275970	0.71
178.0277405	0.40
181.0002441	0.04
186.1056671	0.95
186.9737091	0.07
193.0396423	6.95
195.0743408	1.21
201.2180176	0.08
204.7469025	0.03
206.2606201	0.10
207.1705627	0.04
231.9435577	0.10
235.0694580	0.03
239.2302399	0.17
249.1756897	0.43
251.2919769	0.07
253.9143372	0.10
257.4263916	0.11
258.9435120	0.08
267.2945557	0.15
268.2241211	0.06
279.5403137	0.16
280.1476440	0.10
281.3441162	1.81
282.2951660	0.12
285.2210693	0.36
299.3056335	3.97
300.2312317	0.20
301.5432129	0.07
309.9183655	0.04
327.1731567	0.44
328.2699585	0.15
336.2521362	0.23
341.2666016	6.80
345.3928223	0.19
353.3168945	0.04
355.1117554	0.02
355.9139404	0.24
357.1408081	0.20
358.4295044	0.09
365.1599731	0.12
367.0104370	0.10
371.2355347	0.25
372.1398926	0.09
380.3969116	0.56
383.1996460	0.43
385.1809082	0.10
387.3555298	0.03
389.0731812	100.00
389.7744751	0.28
393.6066895	0.30
402.2924194	0.11
403.8225098	0.08
406.3868408	0.24
413.2897949	0.05
417.3517456	0.20
421.1531372	0.05
422.5015869	0.15
431.1555176	0.47
437.3135376	0.88
438.2023315	0.20
442.8515015	0.15
443.4932861	0.08
446.4570923	0.08
447.3094482	0.09
448.3906250	0.08
450.6457520	0.02
452.1928711	0.05
455.0488892	0.03
461.0155640	0.80
464.4045410	0.12
470.2200317	0.03
472.4132690	0.03
475.2365112	0.04
488.3914795	1.04
489.5211182	0.09
490.9928589	1.28
492.0548706	0.05
504.6657104	0.03
505.2710571	0.95
506.3994751	0.97
507.6077271	0.22
508.3906860	0.52
509.4553833	0.11
512.1959229	0.23
514.4970703	0.27
515.2134399	0.06
519.2360229	0.03
523.1464233	0.02
532.2385254	1.65
533.4746094	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0877
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
98.9520111	0.04
108.0582047	0.95
120.9781876	0.12
122.9628754	0.83
133.9906006	0.07
145.0393372	0.05
146.9200592	0.03
152.0082092	3.15
153.9823608	0.05
161.1172485	0.10
164.9405518	0.13
166.9716187	100.00
167.7643433	0.06
169.3208771	0.11
178.9023743	0.07
182.4556732	0.03
191.1162872	0.03
192.7886658	0.03
196.2530365	0.06
199.0235443	0.19
202.6730042	0.05
209.0196228	0.44
212.9893494	0.09
223.0115051	0.13
233.0208740	0.59
238.0189819	0.11
239.0372620	0.22
240.4647522	0.56
246.3021240	0.07
251.0700684	0.16
260.9691772	0.07
262.7800903	0.03
266.5007324	0.04
267.1175232	0.10
269.0479736	0.39
271.2427368	0.08
279.1181946	0.03
282.6937866	0.28
283.5988159	0.33
284.2295532	3.47
285.2729492	1.11
292.9580688	0.07
295.3311157	0.06
301.4305420	0.04
311.2005615	0.92
312.8468933	0.07
319.2015686	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1139.35
Annotation	Unknow
Peak:m/z	Relative Intensity
322.9651489	0.10
343.1771851	0.25
463.0681763	1.41
609.2006836	2.61
625.2437744	0.75
638.8675537	0.10
651.5399170	0.16
652.5551758	0.07
655.3420410	0.13
669.2348633	1.45
769.4317627	0.12
771.4520264	2.20
787.2812500	1.13
797.3531494	0.14
815.1973877	0.05
828.0528564	0.04
830.3277588	0.36
831.2087402	2.11
839.4560547	0.06
873.6542969	0.09
880.1821289	0.24
885.2935791	0.28
922.0451660	0.19
923.4840088	0.11
933.3244629	3.36
950.5460205	0.20
959.3275146	17.96
959.9779053	0.08
965.0972900	0.10
976.1220703	1.68
977.3096924	100.00
978.0037842	0.22
979.7700195	0.08
1019.3420410	3.53
1031.3127440	0.13
1049.4079590	0.46
1077.4348140	0.23
1078.1422120	0.11
1079.0183110	0.27
1089.4882810	0.13
1095.3421630	1.81
1102.6486820	0.08
1103.3203120	0.14
1120.5998540	0.18
1121.2592770	0.88
1124.2890620	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	293.12
Annotation	N-gamma-Glutamyl-S-propylcysteine
Peak:m/z	Relative Intensity
83.0299606	0.08
90.0098724	0.21
99.7736053	0.12
101.9644623	9.68
111.1009369	0.19
111.9952087	0.06
113.9983673	1.96
114.8915710	0.58
115.9232483	0.23
119.9771423	1.70
121.9829330	0.15
126.0105438	3.05
131.0024719	14.38
131.9647217	3.60
141.0212708	0.63
144.0123291	0.26
144.9600372	0.41
148.9584656	100.00
151.9265594	0.38
154.0155487	7.72
156.2027283	0.09
157.9067383	0.57
159.0859528	0.13
159.8625641	0.14
162.1396332	0.08
166.8881683	0.19
170.9645233	0.05
172.8751526	0.85
174.0609131	1.07
175.0542297	5.54
180.0176086	38.46
185.9834747	0.68
191.0425720	5.72
197.9746552	36.61
201.0213623	0.13
202.3152771	0.35
204.1437378	1.28
212.8687744	0.44
216.0978088	23.61
222.0986023	3.37
227.8702087	1.42
229.3116760	0.20
231.1427917	63.57
233.0655518	7.02
237.1992493	0.27
239.1220093	0.75
243.2359314	0.22
246.1210327	1.36
246.9350586	0.85
250.0935059	0.10
257.0330811	29.16
258.0203857	0.95
264.0330200	2.16
264.9851990	0.05
275.0881958	53.31
276.1172485	2.90
277.5383301	0.06
284.1259155	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	477.3586
Annotation	Clathriol
Peak:m/z	Relative Intensity
151.0743408	0.12
166.6596069	0.08
189.9160767	0.03
223.0661316	0.10
234.0321503	0.04
238.3000946	0.03
240.0022583	0.06
249.6755981	0.07
267.0186768	0.41
279.8424988	0.06
281.0960388	0.04
309.4996338	0.03
312.1484070	0.05
335.4551392	0.05
336.3588562	0.09
337.3359985	0.05
352.4754028	0.11
373.3147583	0.07
378.4754944	0.04
381.8671570	0.12
389.7484741	0.34
390.5620728	0.20
393.2548523	0.20
394.2373962	0.03
395.8424988	0.09
397.6057739	1.59
398.5186768	0.54
404.6362305	0.12
407.0145874	0.04
408.1352844	0.16
411.8000793	0.03
413.6157227	0.07
415.4893494	7.45
416.5738220	6.92
417.6846619	0.12
418.6892395	0.23
420.2679138	0.05
423.3890991	0.10
431.5187683	0.22
432.4518127	0.11
433.4468689	3.76
434.5250549	4.78
435.4317322	0.30
436.6321411	0.21
441.4643860	11.81
442.4483643	11.08
443.4476624	0.42
457.3290405	0.07
459.4493713	100.00
460.4750366	67.18
461.4387512	3.33
462.4367981	0.79
463.6005554	0.06
471.1642151	0.12
475.4371948	0.04
477.7024231	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	413.1238
Annotation	2beta-Hydroxysalvigenolide
Peak:m/z	Relative Intensity
116.9842224	0.10
118.4721298	0.51
119.1936951	0.53
120.8550110	0.20
129.2943878	0.08
130.1521149	0.16
132.8651123	3.60
134.0200500	2.48
134.9706726	5.67
136.8715668	1.00
143.0787659	0.34
145.0087891	2.14
146.0648956	0.11
146.8767242	0.58
149.1310272	0.78
150.9346161	0.08
155.0734558	0.46
156.0963440	0.76
159.0390167	2.18
160.3051758	1.82
161.0904999	15.80
161.9895020	0.10
163.0331116	5.91
163.7756958	0.44
172.9746094	2.78
175.0324402	2.98
177.0904541	33.05
178.0901794	0.68
179.1064148	1.94
189.0341492	0.39
189.9486084	0.28
191.0885162	0.96
193.0804443	22.38
204.1029663	0.22
205.0444946	2.52
211.0769653	0.27
217.0910645	0.14
219.1038513	6.77
234.0357666	1.28
235.0569763	100.00
237.0102234	1.55
242.2381592	0.09
243.4534912	0.15
246.0270996	0.15
249.1530457	8.34
253.0894775	1.49
255.3435669	0.23
257.3984680	0.21
263.3046265	0.08
267.1416626	2.14
271.4980164	0.10
278.0900879	0.09
293.1102905	2.35
297.1640625	0.07
299.2850647	0.18
309.2022095	0.08
327.4616394	0.06
329.0752258	0.21
337.5960388	0.08
339.5972900	0.09
345.0978394	0.08
351.2545776	0.27
357.0316772	0.03
366.9046326	0.08
368.1620789	0.34
370.5209351	0.19
377.5450134	0.37
393.4013367	0.06
394.3894348	0.09
395.2228699	0.79
398.2897034	2.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	420.1859
Annotation	Unknow
Peak:m/z	Relative Intensity
126.8566589	1.25
127.9735260	0.12
129.0120544	0.48
130.9018555	0.16
132.7021179	1.96
144.9743652	2.68
149.9659119	1.13
156.9385376	2.46
159.0212097	0.56
160.8787537	2.70
162.8959656	6.99
169.2637329	0.46
171.2042847	0.32
175.0605011	4.44
180.9571838	0.52
186.8734283	3.23
189.0390015	0.23
198.9165344	0.67
205.0224152	6.22
207.7243652	0.84
213.8376770	1.35
216.8075714	7.15
221.3600159	0.53
222.8825836	5.65
229.0325012	1.34
230.9306641	0.25
235.0100098	5.19
240.5131836	7.52
241.1916809	2.43
245.2111511	0.31
246.0878601	0.25
252.1799011	4.32
252.9020386	6.60
258.3510437	3.16
259.0367737	35.49
261.9644165	0.47
269.9970703	0.54
270.7446289	20.12
275.0489807	0.45
276.9332886	14.58
287.9401550	2.98
291.4275513	0.25
292.3611450	0.27
293.1715698	0.25
294.9725342	100.00
300.4731445	0.79
306.8688660	0.78
312.0194092	0.25
313.9044495	1.62
345.5066833	0.75
348.8834229	0.46
366.3701477	0.35
367.2055664	0.44
374.0820618	1.15
377.2025146	0.27
382.9862671	1.35
384.7662964	1.93
398.3137512	0.98
400.7057190	0.34
402.2042236	5.37
402.9649353	4.54
411.2115173	1.88
428.5560608	0.39
431.2135315	1.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	773.2119
Annotation	Kaempferol 3-glucosyl-(1->2)-gentiobioside
Peak:m/z	Relative Intensity
248.8697510	0.09
253.9137573	0.04
254.8193970	0.34
272.8676147	0.34
291.2019043	0.12
301.9580078	0.07
303.0550537	24.11
307.2733459	0.07
315.4983521	0.02
327.3073730	0.15
330.1502991	0.07
345.2207031	0.91
346.3928833	0.08
351.2009888	0.12
354.4234619	0.04
369.1884155	0.75
387.0852051	0.13
395.3336792	0.13
411.1339722	0.09
412.8960571	0.69
413.5072632	0.20
417.1947021	0.14
428.9135132	0.09
431.1170044	1.06
447.2135010	1.43
449.2061768	7.27
463.2440186	0.03
465.0795288	100.00
465.7539062	0.13
473.1041870	0.29
489.1810303	0.32
491.0303955	0.79
497.3187256	0.05
506.9781494	0.76
513.3206787	0.17
539.4281616	0.11
546.3325806	0.10
557.4713745	0.32
559.4729614	0.22
575.0685425	0.57
588.8271484	0.04
590.8511353	0.21
593.2329102	1.10
609.1770020	0.26
610.4900513	3.63
611.0955200	43.33
626.9895020	60.26
627.6763306	0.18
635.1394043	0.08
652.8460083	0.21
653.8241577	0.09
664.8486938	0.36
669.0558472	0.78
673.8867188	0.15
683.5965576	0.24
688.6317749	0.21
691.8120728	0.13
694.0157471	0.06
719.0471802	0.77
736.8303223	0.13
754.9003296	1.31
755.5226440	0.36
756.6206055	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.0405
Annotation	Unknow
Peak:m/z	Relative Intensity
100.7894821	0.09
104.7966309	0.04
110.0624619	0.05
110.8340912	0.40
119.7908096	0.08
120.7409058	0.03
126.8706360	0.10
138.6582947	0.05
142.9089966	0.03
146.9462280	0.24
166.1371765	0.06
170.9018250	0.04
175.0678101	0.51
177.2774353	0.15
180.1063538	0.13
184.0815582	0.34
184.9340363	0.06
191.2977905	0.04
195.1597900	0.04
196.9820251	0.04
201.1302948	0.29
205.0260620	0.17
207.9575195	0.13
212.1017151	1.98
213.1897278	0.33
224.1622620	0.13
237.1611633	0.06
239.3910828	0.04
240.1705322	0.17
241.2459106	0.06
241.9410095	0.02
246.4528809	0.09
247.2184448	0.04
249.2120361	0.05
251.1418457	0.21
252.0979004	0.13
261.3860474	0.11
262.4002075	0.17
263.5289612	0.14
265.1678467	0.17
268.1384888	100.00
269.1343689	21.05
269.7583008	0.06
272.4258118	0.04
275.5598755	0.07
278.1392822	0.12
279.0556030	1.84
280.2979736	0.15
281.6232910	0.05
283.8259583	0.06
293.1853027	1.02
296.2644043	0.02
297.2171936	0.08
306.3688965	0.58
307.0473938	7.43
308.1480103	0.26
310.1635437	0.21
315.2547607	0.09
324.7249146	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	651.0546
Annotation	Unknow
Peak:m/z	Relative Intensity
225.0191803	0.08
265.6606140	0.13
267.0864563	0.06
272.0407715	0.05
283.2306824	0.05
311.2454834	0.18
381.4301147	0.06
433.2756958	0.12
441.6484985	0.09
442.9684448	0.07
445.3632202	0.07
465.2350464	0.04
473.2344360	1.51
483.3438110	0.17
488.3776855	0.13
489.4299316	0.37
501.2785645	0.09
502.2317505	0.06
505.4920654	0.07
506.6015625	0.19
507.4932251	0.80
513.3944092	0.04
519.8584595	0.05
524.9400024	0.04
534.4797974	0.07
539.0559692	1.51
540.6367798	0.21
549.5562744	0.64
555.2410278	0.14
559.1651001	1.12
561.1388550	0.45
564.3938599	0.12
571.1607056	7.66
572.2595825	0.19
576.6291504	0.16
590.1473999	0.05
591.0792236	0.10
605.0315552	100.00
605.6776123	0.31
607.0794678	0.05
614.3737793	0.14
615.3290405	0.10
629.0860596	0.24
630.3114624	0.45
631.7244263	0.04
633.2318115	0.62
636.4888306	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	728.88
Annotation	Unknow
Peak:m/z	Relative Intensity
228.9846802	0.06
265.0387573	0.07
272.9358215	9.82
273.5381775	0.03
289.1397400	0.04
296.9934387	0.05
384.1135254	0.12
387.0032959	13.54
498.9982910	0.35
500.8492432	61.01
501.5158691	0.18
597.8762817	0.14
607.5824585	0.08
608.9633179	0.80
609.8518066	0.11
611.0267334	0.20
613.1515503	0.70
614.7998657	100.00
615.4724121	0.78
616.2479858	0.07
625.8427124	0.41
626.8261108	0.12
628.0762329	0.13
638.4944458	0.06
645.0175171	0.10
653.9083862	2.67
654.9938354	4.00
655.9743042	0.86
657.2315674	0.07
671.7611084	0.59
673.0511475	1.49
673.9840698	0.55
681.9786377	1.48
682.9646606	1.72
683.9529419	0.34
696.3668823	0.14
700.0379028	0.34
700.8187866	0.31
702.1311035	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	342.9835
Annotation	Unknow
Peak:m/z	Relative Intensity
128.7440338	0.17
130.6600189	0.15
173.2583923	0.27
178.0357361	0.08
199.2532959	0.09
205.9717102	0.07
207.0056763	2.13
222.4152832	0.10
223.2202148	0.13
236.9762268	16.56
249.0047607	0.19
257.1034851	1.30
259.0150757	100.00
259.7733765	0.20
266.2844849	0.87
266.9046021	0.68
278.9517822	0.35
283.0108032	0.32
296.8569641	42.54
313.3751526	0.09
324.3957825	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.0473
Annotation	UDP-glucose
Peak:m/z	Relative Intensity
190.9489288	0.20
193.0115967	0.04
194.1817169	0.07
211.0267334	2.79
222.0290833	0.15
222.8982849	0.44
241.1193542	1.09
273.2510986	0.20
280.1107178	0.78
305.2180786	0.15
321.0898438	0.52
323.0333252	100.00
327.1421509	0.10
355.0855713	0.06
364.3058472	0.08
373.1658936	0.04
376.9560547	0.07
380.2396851	0.24
383.8123169	0.09
385.1355591	2.06
392.2865601	0.07
403.1108398	2.43
415.0878296	0.04
416.2564087	0.05
418.8659668	0.26
421.3676758	0.09
430.1625977	0.67
431.046875	0.16
433.1088257	0.05
436.5604858	0.07
449.3560791	0.04
467.043396	0.39
473.0248413	0.07
475.0333862	0.16
480.4943237	0.07
502.7785034	0.08
518.0505981	0.04
518.9481812	0.17
545.3145142	0.47
546.1712646	0.13
547.2627563	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	380.76
Annotation	Unknow
Peak:m/z	Relative Intensity
212.8872070	1.56
234.2495422	0.16
243.9710693	0.18
251.0030518	0.19
259.6467285	0.07
263.4343262	0.05
276.2322388	0.09
288.2879028	0.15
290.2739258	0.21
294.9111328	0.09
296.8041077	100.00
305.1637878	0.32
308.0561829	0.04
318.1566162	0.09
324.1686401	0.04
334.1729126	0.13
334.9151306	0.04
337.9639893	0.14
362.2123413	3.13
363.1926575	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1442
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
170.9011383	0.06
175.0441284	0.19
177.1290741	0.07
179.1155090	2.37
180.1816406	0.11
181.0478973	0.04
184.7901611	0.15
192.0103760	0.26
197.1535950	0.40
202.7734070	0.22
210.0514679	3.58
210.9661255	0.21
212.9598389	0.11
217.1482544	0.08
220.8413544	0.05
228.2391968	0.12
236.1509247	0.44
242.0830231	0.19
252.1037750	0.14
254.0642395	11.71
255.2088013	0.73
260.3583984	0.05
272.1215820	35.80
273.1032410	2.96
286.0573730	0.90
288.1149902	4.10
289.3048706	0.20
295.9238892	0.03
304.1189575	14.30
306.1098633	100.00
307.1192017	10.00
320.0477295	0.32
321.1470337	0.03
338.0798950	40.80
339.0418701	4.56
353.0839233	0.25
354.2003174	0.06
361.1305542	0.12
374.2553101	0.03
395.9867554	0.03
408.4766235	0.09
426.3001099	0.02
426.9094849	0.03
427.9916992	0.11
464.0854492	0.84
464.9367676	0.14
470.4907227	0.03
482.1884766	35.50
483.1713257	4.96
495.9772949	0.10
519.0363159	0.10
527.2807007	0.04
536.4204102	0.17
551.6303101	0.09
575.1680298	0.38
576.2799683	0.12
593.1536255	15.52
594.2580566	3.72
595.1560669	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	298.15
Annotation	Unknow
Peak:m/z	Relative Intensity
121.9569244	0.54
131.1210785	0.19
151.8279419	0.35
162.8393097	6.52
234.0797424	49.56
235.2985840	8.60
236.0230103	100.00
237.1203613	0.77
251.9197998	0.95
257.0863037	1.81
262.9133606	1.43
274.9724731	0.41
279.0176392	0.65
280.7648926	56.05
281.4308472	0.65
289.1667786	4.14
289.8037415	0.94
291.6893921	4.53
309.1284790	1.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	598.25
Annotation	Unknow
Peak:m/z	Relative Intensity
182.1052856	0.97
210.9133911	0.17
227.0366516	0.18
231.2299805	0.08
233.0371857	0.17
242.3125916	0.28
253.0733643	0.90
255.1490479	0.13
257.1071167	0.48
261.1974182	0.09
270.1189270	0.34
272.3408203	0.09
275.0775757	0.51
279.0653687	0.12
280.1122437	0.32
283.0822144	0.30
284.5513306	0.10
287.9577332	0.21
289.2646484	0.40
296.1308594	0.13
297.2164307	0.12
300.2081299	0.64
304.1405029	0.04
307.1106873	0.04
308.1490479	0.10
312.2353516	0.13
324.1514893	0.39
328.2108154	1.61
337.1375122	0.12
346.0703735	1.90
350.0134888	0.84
371.1518555	1.56
373.0068359	0.27
379.4843140	0.07
399.1875610	13.49
400.4044800	0.07
402.7311401	0.23
414.1437988	0.10
414.8438110	0.25
417.3120117	0.69
421.2041626	0.08
421.9066772	0.08
424.3700562	0.10
425.2257080	0.27
433.4694214	0.22
436.3358765	0.11
441.8395386	0.05
448.2489624	0.07
448.9687500	0.18
450.4727783	0.20
456.3164062	6.08
476.1345825	0.07
477.0650024	0.07
481.8659058	0.13
483.6646118	0.10
490.1414795	0.12
491.3590088	0.17
493.3947144	0.05
498.0349731	0.06
505.1712646	0.23
508.0469971	0.20
510.4136353	0.26
515.7385254	0.27
519.2637329	0.19
523.4721680	0.17
525.7144165	0.08
527.3350220	0.24
530.1103516	0.35
530.9700317	0.29
534.2042847	1.20
535.1209717	0.35
536.9031372	0.21
539.2431030	0.05
547.3388062	0.10
549.9612427	0.33
552.1092529	0.85
554.6370239	0.16
559.3302612	0.21
560.8441162	0.26
562.2011108	2.93
566.5553589	0.30
574.6846924	0.18
578.5905762	0.71
580.1726074	100.00
580.9184570	0.43
582.2085571	0.55
587.2335205	0.41
588.4141235	0.20
589.3995972	0.37
595.3760376	0.06
601.6076050	0.05
604.6118774	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	537.9341
Annotation	Unknow
Peak:m/z	Relative Intensity
183.0630188	0.10
282.8647461	0.04
298.1806030	0.07
299.1622314	0.40
309.1829834	0.05
314.8105469	0.10
326.5770874	0.18
337.7184448	0.16
352.7214355	0.18
385.2785034	0.10
422.0271606	0.31
422.9862671	2.15
424.0789795	1.90
425.0297852	6.95
425.8811035	0.67
441.3803101	0.33
442.7784424	1.51
443.4319458	0.09
450.8554688	0.04
453.9561768	0.04
462.9871216	0.12
465.0237427	0.10
465.8695068	0.19
467.1271973	0.32
482.2238770	0.19
491.9642944	26.59
492.9747925	100.00
494.0789795	3.03
495.9000854	0.60
501.2225342	0.10
509.9723511	10.89
510.9598999	31.76
511.8374634	1.60
512.6428223	0.05
513.6576538	0.07
515.5425415	0.31
521.0109253	0.50
527.9676514	0.95
528.6892700	0.11
533.4985962	0.41
539.5452271	0.16
547.3434448	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	673.335
Annotation	Gypsin B
Peak:m/z	Relative Intensity
193.4978943	0.02
196.1858215	0.02
197.9035645	0.03
202.1951599	0.34
207.0829010	0.07
210.0334778	0.07
213.2499695	0.14
214.1171417	0.03
217.2311554	0.05
217.9544983	0.02
222.3242798	0.02
224.0783844	0.02
225.2632904	0.08
226.3592834	0.03
228.2553406	0.34
229.3200226	0.13
230.1556396	0.07
231.2950439	0.07
234.2549133	0.06
239.1609039	0.02
243.1614532	0.02
244.3760986	0.03
245.3071899	0.11
247.0743408	0.17
248.5077820	0.04
252.2475281	0.04
254.5646362	0.18
257.1800537	0.12
258.2136536	0.54
261.2816772	0.10
270.2095337	0.21
271.2182922	1.00
272.5216675	0.11
273.3067627	0.04
275.1683960	3.37
276.1661377	0.56
277.3691711	0.04
279.3485718	0.04
281.3386230	0.03
283.3204041	0.18
284.0932617	0.02
286.5270386	0.08
287.3177490	0.10
288.3341980	0.63
289.1283569	0.12
289.8983765	0.13
292.3106079	0.33
293.2886353	0.14
297.3540955	0.04
301.3985291	0.11
302.2150269	0.05
305.1723633	0.04
306.3908691	0.13
307.4206543	0.03
312.2009888	0.06
313.6836548	0.10
314.2853394	1.45
315.4562378	0.28
316.5639038	0.02
318.3499756	0.03
324.3145142	0.03
325.3328857	0.06
326.2146912	0.03
327.0782776	0.04
328.1983032	0.07
330.1162109	0.12
331.2604675	2.49
332.2298584	3.05
333.3414917	0.56
343.1864624	0.39
344.2956543	1.34
345.3428650	0.27
347.4938354	0.04
348.3710327	0.77
349.2978516	1.68
350.2019043	0.36
352.3388062	0.02
356.5253296	0.03
357.4920044	0.08
360.2073975	0.22
361.4531250	0.04
365.5101318	0.03
368.9948120	0.03
372.1286621	0.11
373.2717896	0.05
374.3314209	0.23
375.3556519	0.06
382.5771484	0.22
383.3630981	0.13
386.1578979	0.23
387.3514404	0.07
389.4258423	0.02
391.1639404	0.10
392.2731323	0.14
393.7066650	0.05
396.3532104	0.03
399.2617798	0.23
400.4989014	0.77
401.4535522	0.07
403.3925781	1.41
404.2595215	0.35
406.5128174	0.06
412.3861694	0.02
413.4508667	0.11
414.4899902	0.10
415.2499390	0.36
416.3347168	0.15
417.3902588	1.60
418.2781372	0.48
425.4144287	0.33
426.5327148	0.90
427.5729980	0.07
428.3866577	0.05
429.5311890	0.02
430.7050781	0.12
431.3732300	0.05
433.3580322	0.29
434.3831177	0.24
435.4568481	0.43
436.5231323	0.05
439.4024658	0.16
442.7258301	0.42
443.3936768	4.03
444.4456177	2.00
445.3576660	0.30
446.3402710	0.04
448.4561157	0.03
452.3760986	0.02
454.6502686	0.05
455.3958130	0.02
456.5014648	0.39
457.4754028	0.24
458.5148926	0.06
461.2940063	25.75
462.3545532	8.03
463.4046021	0.05
465.4726562	0.15
468.2285156	0.04
469.3782959	0.07
470.2597656	0.05
471.5941162	0.18
472.4857788	0.28
473.6407471	0.02
474.4205933	0.10
475.2536621	0.08
478.3479614	91.45
479.3723755	28.46
481.5509644	0.03
482.7114258	0.17
483.5534058	0.04
484.4677124	0.02
485.6559448	0.25
487.3359985	6.39
488.4270630	2.36
489.3182373	0.13
492.4747925	0.08
494.2147217	0.03
495.4962769	0.06
497.6881104	0.02
498.4016724	0.22
499.3919067	0.44
500.4207764	7.15
501.4544067	2.55
502.7660522	0.16
503.4669800	0.02
504.8956299	0.04
507.3389282	0.05
511.5585327	0.07
512.5702515	0.21
513.5220947	0.23
516.3848877	0.17
517.5355835	0.09
525.2902222	0.20
526.5413208	0.06
527.4486694	0.50
528.5236816	0.10
532.5015259	2.10
533.4970093	0.50
534.4703979	0.05
537.3584595	0.02
539.4835815	0.47
540.7095337	0.03
542.3498535	1.48
543.6768188	1.11
544.5870361	1.68
545.4423218	4.23
546.4703979	2.49
550.5239258	0.06
553.5247192	0.07
555.2459717	0.06
556.4185791	0.26
557.2926636	0.26
558.5635376	0.74
559.5366821	0.22
568.3975220	0.12
570.2908325	0.05
571.6328125	0.02
577.8764648	0.08
581.7687378	0.04
584.2846069	0.02
585.5908203	0.83
586.5951538	0.62
587.4589233	0.24
588.8275757	0.03
593.1770630	0.06
599.2510986	0.14
600.5717773	0.03
601.6130981	0.31
602.7949829	0.04
611.3300781	0.96
612.4130859	0.77
613.3264771	0.10
624.3969727	0.03
628.0935669	0.10
629.4669800	100.00
630.4553223	48.26
631.3771973	0.31
636.2351685	0.24
645.6066284	0.35
646.3427124	0.01
655.3994751	10.20
656.4905396	5.02
657.2355347	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	715.3671
Annotation	Gingerglycolipid C
Peak:m/z	Relative Intensity
282.7497559	0.05
359.2807617	0.10
371.0468140	0.29
376.9891357	0.07
434.5696411	0.08
475.5299683	0.22
482.7593994	0.19
501.2985840	0.11
517.4052734	2.14
535.5610352	0.05
571.7459106	0.30
574.7515259	0.10
586.9995728	0.13
596.4227905	0.08
627.7361450	0.09
633.9915161	0.11
635.2410278	0.07
637.8081665	0.54
639.1372681	0.09
651.2172241	0.18
655.0922852	0.05
670.8381348	0.25
679.4251099	100.00
680.0945435	0.38
697.0326538	0.71
697.7102051	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	468.1826
Annotation	4-Hydroxytamoxifen sulfate
Peak:m/z	Relative Intensity
148.9725494	0.05
186.1577148	0.14
189.1432190	0.05
206.0657806	0.07
210.1816711	0.23
213.1953888	0.09
237.0119781	0.18
251.2921143	0.08
257.0704346	0.31
258.4736328	0.32
293.0853882	0.13
299.2722473	0.31
303.2203674	0.22
306.1693420	0.29
321.2623901	0.23
324.1998901	0.08
325.6094055	0.52
327.2090454	0.10
334.2428894	0.08
338.1620483	100.00
339.1045532	0.08
360.3288879	0.21
366.4115906	0.26
385.8647156	0.05
387.3670654	0.15
391.2705994	1.83
391.9259338	0.10
392.9949951	0.05
404.0598450	0.05
409.6339111	0.28
418.4259949	0.07
426.7236023	0.35
432.2050476	0.09
436.4433289	0.52
437.1656799	0.25
437.9882507	0.22
449.1345215	0.28
450.3097229	11.33
451.4100647	0.04
452.6739502	0.36
456.6979065	0.32
458.2308960	0.05
459.2545776	1.47
460.4228821	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.18
Annotation	Lactucaside
Peak:m/z	Relative Intensity
164.8778076	0.28
178.0140533	0.33
193.1083832	6.56
195.0872345	1.59
197.0435486	0.11
202.3487549	0.04
227.1902161	0.39
232.9916077	0.03
234.0393066	0.08
235.2988892	0.09
238.9321289	0.07
241.9901276	0.07
255.5240784	0.02
281.2079468	0.04
285.1962280	0.24
294.3901978	0.20
299.3845215	0.05
303.1444702	0.10
306.9420776	0.05
315.3617554	0.11
322.3246460	0.18
323.2150269	0.11
327.2830811	0.21
333.6058350	0.06
335.1661377	0.06
336.0214844	0.08
338.8516235	0.03
339.4823608	0.18
341.1956177	9.27
344.8444214	0.04
345.5337524	0.07
355.0605469	0.04
357.2292480	0.13
359.2465210	0.13
365.0698853	0.07
368.8661499	0.03
370.9977417	0.10
383.1597290	0.11
389.0941772	100.00
393.3087158	0.10
419.4965210	0.14
431.1849976	1.00
436.4344482	0.02
437.4594116	0.02
443.2226562	0.09
447.0809937	0.05
459.1621704	0.07
461.0052490	0.53
474.1530762	0.09
491.1586914	1.28
505.4147339	0.20
506.5646973	0.32
507.6826782	0.12
515.1126099	0.05
515.8135376	0.07
529.0233154	0.26
533.4512329	0.26
542.3836060	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.1333
Annotation	Ciprofloxacin
Peak:m/z	Relative Intensity
107.9239807	1.48
124.1470261	0.10
133.0075378	0.04
134.0170746	0.13
135.9281311	1.10
138.1196442	0.02
144.8265076	0.02
147.8133087	0.01
152.0261688	4.66
154.059433	0.14
156.9746094	0.10
163.0776672	0.05
166.8983612	0.06
168.010376	0.02
170.0058899	6.17
175.1778259	0.04
184.9593201	0.19
186.1917725	0.04
190.1774902	0.08
210.2521667	0.03
213.1873169	0.44
214.0045166	0.05
215.4801025	0.04
216.0856628	0.04
217.0334778	0.09
228.8081055	0.05
232.155304	0.06
232.9891968	0.07
234.0046997	0.13
236.1719971	0.04
245.1876831	0.12
254.8388672	0.02
255.9884033	0.08
270.1090088	0.07
272.0843506	0.11
275.336792	0.13
278.1152954	0.17
291.296875	0.08
296.0770264	0.30
302.153717	0.03
314.1379395	100.00
315.0292969	0.16
323.2269897	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	540.2285
Annotation	Unknow
Peak:m/z	Relative Intensity
162.8401184	11.36
175.4205322	0.47
180.9174805	19.14
198.9154968	43.46
213.3261414	0.30
215.1864929	1.23
219.4387512	0.37
261.5526733	0.95
270.7393799	0.35
276.7994995	0.91
284.4674683	0.75
288.9422607	1.75
307.1100464	1.68
310.1921387	0.62
312.1051025	0.48
315.8212280	0.14
316.8829956	0.19
324.9606323	21.96
325.7006836	0.75
342.5147705	8.38
343.1373901	15.19
344.5166626	0.51
347.2140503	0.62
355.7944946	0.19
359.6171265	1.66
360.6835938	100.00
361.5011597	0.14
377.9746704	0.88
378.5748901	1.38
383.9104614	1.58
398.2673340	0.32
407.3646851	0.57
423.5075073	0.31
436.8210449	0.83
447.8873901	1.53
461.4230957	2.60
468.8168945	0.61
469.5057373	0.68
477.3154297	0.80
481.2784424	0.23
482.7157593	0.29
487.3390503	1.28
505.0770874	1.92
506.9821167	1.93
517.4901733	0.43
519.5905151	0.39
521.0639038	1.08
522.0736694	2.06
523.0493164	5.87
530.4754639	2.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.192
Annotation	Unknow
Peak:m/z	Relative Intensity
125.0034943	0.19
125.9728470	0.06
130.2488708	0.10
131.1272430	1.00
132.1632843	0.03
143.0391541	3.78
149.0117188	1.12
153.0691071	1.53
154.2937927	0.17
159.1708221	0.05
160.9490051	3.20
161.8106384	0.15
178.9376221	41.56
179.9454651	0.63
205.0968628	2.15
207.1691132	0.12
221.1000366	0.08
223.1250305	6.17
225.0544739	19.18
226.0630493	0.59
229.1836395	0.18
235.1068115	0.27
237.0719299	0.29
241.2386169	0.05
247.0664368	0.40
261.2745361	0.05
265.2512512	0.97
266.2849731	0.05
269.3588867	0.09
270.2073059	0.17
301.2916870	0.08
304.1319580	0.06
307.0904236	1.27
315.2405701	0.30
316.1521301	0.51
316.9662781	0.19
319.2006836	0.11
326.2276001	0.08
352.0639038	0.07
354.1741638	0.13
365.6408997	0.05
369.4535217	0.20
383.4572144	0.13
385.1717224	100.00
386.1678772	4.43
387.3215332	0.08
396.2279968	0.14
399.5702515	0.12
401.4449463	0.06
405.1586609	0.21
413.0435486	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	617.1079
Annotation	Unknow
Peak:m/z	Relative Intensity
172.8714752	0.04
183.0715027	0.02
187.2300720	0.02
189.2053833	0.04
191.2272644	0.12
193.2839508	0.40
194.1495667	0.15
194.8145447	0.02
197.0384674	0.06
199.0657501	0.32
200.0751343	0.06
208.3378296	0.08
209.3693542	0.03
213.2701874	0.08
214.2428284	0.05
215.4012451	0.03
217.1797180	0.03
219.3202057	0.04
221.0895691	0.03
223.2104187	0.03
224.1688843	0.02
225.0879974	0.03
226.8860016	0.06
228.1441193	0.14
231.1120453	0.57
232.2224121	0.03
237.2304688	1.00
238.3070679	0.19
241.2214355	1.98
242.2538757	0.34
246.2916870	0.07
252.2947083	0.04
254.1696930	0.33
255.0836487	0.08
256.0596924	0.11
259.1166382	1.45
260.2737732	0.30
261.7112732	0.03
263.1929932	0.32
265.3988342	0.03
269.2226562	0.04
271.1754456	2.00
272.1250000	0.33
273.1453247	9.29
274.1987915	1.08
283.6170654	0.03
286.0491638	0.16
287.3279724	0.03
289.8508911	0.02
291.3561401	0.08
292.2630615	0.02
294.9776306	0.06
296.0269775	0.03
303.1882935	12.31
304.0867920	1.68
305.1184692	19.65
306.1546326	3.36
307.1394043	8.73
308.2189331	1.03
309.6221313	0.03
311.2575073	0.03
315.2017822	0.04
317.5175476	0.05
319.1069336	0.06
325.0880737	0.03
327.2403564	0.06
329.3482056	0.09
330.2933960	0.05
331.3939819	0.14
337.1376343	46.35
338.1274414	4.87
345.2679443	0.43
346.2266235	0.07
347.3014526	0.07
349.1627808	0.02
353.5830078	0.03
359.4940186	0.04
361.2095947	0.19
367.4234009	0.02
369.2940063	0.03
372.3289795	0.12
373.3570557	0.03
374.0031738	0.03
389.2260132	0.04
395.9019775	0.03
399.3038940	0.03
404.3369141	0.05
408.2918701	0.02
413.6296387	0.06
416.0789795	0.02
422.0157471	0.05
430.8439331	0.04
437.1243896	1.16
438.3016357	0.12
439.2156372	0.20
445.2302856	0.21
446.2254639	0.03
452.2496948	0.05
455.0933838	100.00
456.2318726	13.56
463.1393433	0.03
467.4757080	0.10
469.3332520	0.01
471.3901978	0.02
479.1437378	0.52
480.2872314	0.09
487.2608032	0.06
489.5923462	0.10
491.3767090	0.01
493.5012207	0.01
497.0781860	3.13
497.9757080	0.45
499.2044678	0.02
502.3833618	0.03
509.1818237	0.09
510.1434937	0.09
513.5687866	0.10
515.1793823	0.07
515.9434814	0.02
517.2257690	0.05
519.0652466	0.02
521.0979614	0.05
522.2287598	0.10
523.3403320	0.02
525.4607544	0.02
527.1235962	2.15
528.1628418	0.36
529.2992554	0.03
530.5985718	0.02
532.4289551	0.02
539.1508789	0.67
541.9260864	0.05
545.1820679	0.08
547.2337646	0.36
549.2109985	0.07
551.0811157	0.35
552.1668091	0.23
552.9041138	0.16
557.1094360	40.99
558.1732178	5.31
563.0217896	0.08
565.2336426	0.07
566.0990601	0.07
571.7581787	0.04
573.6154175	0.12
574.5362549	0.23
575.4784546	0.04
576.2973022	0.14
581.2428589	0.46
582.1814575	0.20
583.1649780	0.16
584.4169312	0.12
587.1436157	1.08
588.1003418	0.15
589.1834106	0.03
594.9381104	0.06
595.6539917	0.06
597.1149902	0.04
599.2349243	1.86
600.3020630	0.81
601.5745239	0.03
602.7639771	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.16
Annotation	Unknow
Peak:m/z	Relative Intensity
172.8557587	0.11
175.8772278	0.04
177.4017334	0.05
185.1039429	0.14
193.2564392	0.83
199.1884155	1.69
206.1250916	0.07
207.1090698	0.32
208.1309967	0.16
217.1907806	0.20
224.3614197	0.11
225.2734375	0.06
229.3122101	0.32
237.1547852	1.21
241.2085876	5.24
242.1982269	0.05
245.1285095	0.04
254.3058624	0.43
259.1393433	4.08
263.0956726	0.37
271.1600342	1.40
272.3516235	0.04
285.3905029	0.11
288.2677002	0.09
303.2550659	0.34
305.1083984	100.00
306.0723877	0.07
329.2590332	0.05
491.1580200	0.07
517.6502686	0.03
521.1212158	0.12
548.3728638	0.42
566.4497070	0.06
574.4717407	0.10
592.2355347	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	429.07
Annotation	Unknow
Peak:m/z	Relative Intensity
143.0220947	0.26
165.8218994	0.58
176.8758240	1.84
190.2332458	1.20
199.2691803	0.36
216.2033691	0.81
220.0706177	0.83
230.2676086	0.79
238.0544739	4.03
253.9209290	0.19
275.2577515	0.55
276.8068237	0.19
300.5120544	0.82
306.1081848	0.69
307.1515503	0.85
309.8428955	0.63
312.2869873	0.14
323.3954163	0.56
328.5404663	0.45
339.4047241	0.56
345.4503784	0.36
346.7755127	0.46
348.1988525	4.82
349.1669312	0.43
351.6899719	0.89
355.9915771	2.13
364.4651794	2.39
369.0501099	4.68
369.7095337	0.43
382.7680969	2.86
401.3742065	0.24
402.0954285	5.46
402.7972717	6.32
404.9925842	0.49
409.9444885	0.79
411.2198181	31.89
420.1264343	100.00
420.8329163	7.08
423.0226135	0.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	771.1976
Annotation	Kaempferol 3-glucosyl-(1->2)-gentiobioside
Peak:m/z	Relative Intensity
245.4756470	0.02
255.2130737	0.02
271.2472534	0.04
283.0741272	0.02
289.3988342	0.01
297.3669434	0.01
299.0419312	0.05
300.0935059	0.19
301.1038818	3.11
324.9148254	0.01
341.1156616	0.02
343.3159485	0.15
462.1979370	0.48
463.1445312	2.04
504.7966919	0.02
565.4396362	0.02
591.0833130	0.01
609.2194824	100.00
609.8435669	0.30
633.3600464	0.03
651.2827759	0.39
681.4699097	0.03
689.7074585	0.01
693.2409058	0.05
753.0748901	0.11
761.9691162	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	654.3687
Annotation	Unknow
Peak:m/z	Relative Intensity
189.0457611	0.36
197.1255188	0.37
198.2400818	0.04
206.1661224	0.05
207.0766144	0.03
211.3271179	0.05
222.1475067	0.26
222.9188232	0.10
224.5706329	0.05
225.3554993	0.09
230.9825439	0.03
239.1286163	1.46
240.1752014	1.23
241.1487122	0.18
242.1295166	0.04
251.2232819	0.31
252.3677826	0.10
256.0942688	2.00
257.1180725	0.72
258.0824890	0.76
258.9506226	0.05
260.3102417	0.12
267.2176819	0.02
269.5389709	0.14
271.0837097	0.12
284.0923157	5.85
285.1479492	1.31
287.1659851	0.04
290.2932434	0.11
299.1532593	0.11
300.3007202	0.21
305.3650513	0.07
310.0057678	0.07
317.3347473	2.42
318.4514771	0.49
319.5592651	0.26
324.2970581	0.24
328.0007629	0.25
330.3950500	0.14
334.3080750	0.06
335.2530518	0.40
338.4177551	0.06
342.1824951	0.08
342.8501587	0.04
351.2917480	0.62
352.4478149	0.76
353.4408569	0.84
354.2966309	0.08
355.3842163	0.08
357.3606567	0.08
364.4582520	0.05
368.0791626	0.59
369.2399902	1.61
370.2377930	1.87
371.4159546	0.59
379.3112793	0.03
380.0752563	0.12
386.2812500	0.73
388.4307861	0.06
390.0800171	0.02
395.3129272	0.03
397.1926270	2.20
398.3438110	0.96
399.1733398	0.06
404.6849976	0.08
407.1262817	0.03
409.3402710	0.18
410.3302612	0.72
411.2192383	0.17
418.8434448	1.18
420.2667847	0.32
421.2120972	0.20
422.3937988	0.13
427.5885620	2.37
428.3897095	2.99
429.4101562	0.50
430.3176270	0.11
430.9232178	0.03
432.5008545	0.07
439.2474365	0.39
440.4558105	0.47
441.0880127	0.03
445.3417969	6.74
446.4152832	0.95
447.6113281	1.90
448.8461914	0.11
451.5648193	0.06
456.5456543	4.80
457.4810791	0.21
458.4183350	0.20
459.4323120	0.16
463.4332886	0.41
464.5973511	0.19
465.6390381	0.05
466.6809082	1.18
467.5451660	0.60
468.5699463	0.04
469.4919434	0.14
470.8505859	0.10
475.7087402	1.16
476.5635986	0.11
477.3893433	0.15
480.2875977	0.16
481.4557495	0.59
482.4376221	0.25
483.1978149	0.12
484.3704834	0.08
486.2658081	0.33
486.8945923	0.08
487.9593506	0.06
494.8025513	0.27
495.6157227	0.16
496.4718018	0.62
499.3851318	0.99
500.2698364	0.21
503.9917603	1.56
504.9971924	0.79
506.4956055	0.64
507.4722900	0.17
508.5829468	0.08
511.6455688	0.10
513.0989380	6.28
513.7741089	0.72
514.8833008	0.08
516.4304810	0.06
523.1610718	0.37
524.4566040	0.03
528.8558350	0.15
532.5504761	0.29
534.2641602	8.77
535.2797241	2.84
536.1688232	0.18
537.8619995	0.42
538.7362671	0.17
541.4122314	0.05
542.7018433	0.05
547.1979980	0.13
548.0891724	0.09
551.7977295	2.97
552.8660889	0.76
553.6804810	0.23
554.5215454	0.15
555.3715210	0.06
556.3075562	1.43
557.4506226	1.48
558.2526245	0.04
560.5935669	6.29
561.4425659	0.82
562.6270142	0.13
563.2613525	0.16
564.9613647	0.17
567.9293823	0.15
569.7113037	1.46
570.7171021	0.11
571.4279785	0.12
573.4711304	0.78
574.4500732	4.74
575.3706055	1.22
576.5216064	0.19
577.7123413	0.06
580.1951294	0.28
580.8924561	0.45
583.7422485	0.06
584.9202271	0.08
586.2111816	1.52
587.3308716	1.03
588.2719727	0.08
593.1332397	0.37
594.4039307	0.53
595.4284668	0.49
596.6665039	0.10
598.2454834	5.31
599.2268677	3.26
600.1386108	1.12
603.1553955	15.34
604.1219482	2.01
605.1419067	0.32
608.2367554	57.13
609.1084595	10.42
610.1280518	0.27
610.9119873	0.25
611.5935669	0.10
612.5939331	0.40
613.6983032	0.05
614.3863525	0.39
617.2128296	100.00
618.0904541	12.66
619.4982910	0.78
621.3319702	4.59
622.3646851	1.89
623.0772095	0.96
623.6826782	0.21
626.2366333	0.40
626.9783325	0.08
628.9079590	0.06
631.2933960	0.13
632.0737305	0.27
636.7405396	0.73
637.3905640	0.36
638.0685425	0.36
639.7151489	0.05
640.7115479	0.05
643.8573608	0.18
645.7885742	26.17
646.6621704	4.53
648.1373901	0.14
663.0700073	0.11
670.2183228	0.38
671.5518799	0.24
672.5939331	0.03
681.5321655	0.67
682.5487671	0.34
683.4470825	0.11
687.4613647	2.11
688.5878906	1.96
689.4724731	1.07
691.0663452	0.13
695.5955811	0.19
697.5347900	0.11
699.5233765	1.84
700.5166626	0.76
701.4171753	0.17
705.4247437	0.40
706.4577637	0.81
707.4588623	0.30
708.5399170	0.83
709.5817871	0.45
710.4657593	0.07
716.4170532	10.63
717.4456787	3.96
718.4097290	0.69
723.5062866	1.35
724.5613403	0.40
725.3400269	0.13
726.9546509	0.05
731.5719604	0.48
734.4214478	7.32
735.4063110	4.02
736.4826050	0.41
737.5565796	0.06
738.5430908	0.03
739.4855347	0.04
750.4324341	0.05
751.3373413	0.20
756.5351562	0.09
757.4907227	0.32
758.6879272	0.09
774.4462891	10.16
775.5056152	4.27
776.6517944	0.51
777.6755371	0.06
783.5436401	0.07
795.5055542	0.10
800.6825562	0.17
801.5635376	0.72
802.5415649	0.12
818.5539551	2.48
819.6885986	2.22
820.7296143	0.75
822.7526245	0.08
823.9747925	0.05
835.7138062	0.56
836.5150757	2.41
837.3336792	1.44
837.9354858	0.04
838.6314697	0.37
839.3591919	0.09
842.4193726	0.18
845.6035767	0.76
846.3418579	0.13
847.7642212	0.30
861.1604614	0.08
863.4453125	26.05
864.5142212	9.58
865.4976196	2.73
866.4495239	0.12
868.7933960	0.10
875.4899902	0.10
878.5763550	0.65
879.8248901	0.14
880.6023560	1.04
881.6416016	0.46
882.8537598	0.03
893.6817017	0.72
895.3794556	0.36
895.9894409	0.25
911.5036621	13.29
912.5471802	9.68
913.5658569	2.20
914.5908813	0.07
920.7988892	0.08
928.4802856	0.05
931.6877441	1.18
932.6190796	0.63
934.5591431	0.03
947.4927368	0.05
949.3925171	0.98
950.6909790	0.96
951.7769165	0.09
959.5817871	0.13
963.5100098	0.57
964.8942871	0.17
965.5776367	0.05
971.8832397	0.08
973.5632324	0.67
974.4118652	0.83
975.4269409	0.43
989.6133423	0.11
991.4895630	27.18
992.5072632	14.87
993.5862427	5.06
994.5504761	0.23
996.4965210	0.10
1006.4164430	0.23
1007.5000610	0.52
1008.5112300	2.90
1009.5798950	2.48
1010.5918580	0.64
1011.4897460	0.14
1024.5419920	7.13
1025.5372310	4.33
1026.7006840	0.81
1027.5537110	0.20
1074.6778560	0.16
1087.5227050	0.10
1101.9233400	0.38
1102.6890870	0.86
1103.6545410	0.43
1105.1145020	0.08
1119.6229250	18.13
1120.6462400	10.78
1121.6561280	3.44
1122.7246090	0.19
1137.8566890	0.11
1147.4208980	0.24
1148.2790530	0.12
1149.6889650	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.2213
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
100.9606934	0.42
105.1596146	0.33
108.9164429	1.20
116.5984344	0.62
124.9961472	0.56
127.1902924	0.82
139.1767883	0.52
141.072464	0.98
142.9400482	1.72
149.2101288	0.33
153.1278076	0.48
155.2023163	2.59
163.1550293	1.61
169.0833435	0.49
170.8897705	0.62
172.7561646	0.36
175.2438507	0.84
177.0663452	1.13
181.058548	1.65
182.7704773	0.65
191.3635864	1.97
192.8751831	2.60
193.4935608	1.15
195.1538086	3.48
197.0080566	2.73
199.0894928	0.84
199.9737091	0.46
205.1192322	0.71
207.219574	1.07
211.1683655	2.34
215.1416321	0.46
220.0568848	0.49
222.9841003	2.62
225.3180847	0.53
227.2814331	1.77
237.1732178	6.86
239.3275452	1.42
243.1820679	1.20
251.3673096	1.00
252.0126648	1.09
253.2818604	8.32
255.1357422	1.25
257.4153442	1.12
265.3128662	1.75
269.3321228	1.15
275.2478638	18.74
281.8259888	0.55
282.9569092	3.11
283.6437683	0.52
290.2457581	1.36
291.0162354	1.58
293.2070923	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	686.9641
Annotation	Unknow
Peak:m/z	Relative Intensity
375.3457031	0.09
513.0360718	0.09
518.4472656	0.08
550.9747925	0.20
589.1454468	0.09
594.7974243	0.35
603.0413208	0.61
605.1297607	0.37
641.0186768	100.00
641.6828003	0.24
670.0053711	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
139.0601807	18.60
200.2221985	42.32
207.4747467	54.75
338.1946716	57.42
408.2804565	100.00
426.2574158	26.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	208.0633
Annotation	S-(2-Hydroxyethyl)-N-acetyl-L-cysteine
Peak:m/z	Relative Intensity
85.5308838	0.01
118.9487000	0.60
148.2914886	0.01
162.0953827	1.75
171.9492188	0.03
172.9654694	0.02
190.2393036	19.55
190.9194946	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	738.9259
Annotation	Unknow
Peak:m/z	Relative Intensity
211.0878601	0.08
241.0573273	0.75
280.1770630	0.06
323.1663208	14.01
328.9505920	0.02
350.8375244	0.08
359.1036377	0.95
361.2870483	0.06
376.9803467	0.71
418.9797974	0.04
441.1463623	0.72
458.8922729	3.06
459.5168457	0.03
460.2376709	0.06
476.8197021	0.02
479.0972900	0.04
483.1192627	0.88
488.2297363	0.03
491.1762085	0.02
494.8546143	1.00
496.9720459	0.27
513.2836304	0.05
524.7296143	0.02
560.0584106	0.86
564.9861450	0.23
576.9010620	0.42
585.0405884	1.76
603.0423584	100.00
603.6765747	0.28
618.9180298	0.23
626.9579468	0.03
651.8029175	0.21
652.6963501	0.04
654.5211792	0.37
696.0688477	0.28
721.0292969	1.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.92
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9948730	2.70
160.0517578	1.05
161.0082550	1.02
162.1186829	0.08
199.0442810	0.16
200.0858307	0.02
201.0205231	0.30
218.8022766	0.10
229.0120850	0.73
230.0565491	0.31
231.0227051	0.39
232.3076324	0.13
245.8775330	0.05
272.9927979	29.00
274.0297852	17.75
275.0104980	30.67
276.0882263	5.37
289.0935059	0.02
373.2085266	0.06
387.0004883	24.46
388.0014648	26.86
388.9342957	100.00
389.9488525	30.06
390.7609253	0.02
421.4436340	0.02
429.0639343	0.23
429.9787292	0.11
441.9128723	0.05
457.0650330	0.02
458.8793335	0.67
460.1955872	0.03
485.6156616	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	784.1483
Annotation	FAD
Peak:m/z	Relative Intensity
241.1639099	0.94
242.1579895	0.06
242.9331970	0.05
255.1612396	0.44
261.0762329	0.06
273.1227112	0.07
275.0725708	0.10
307.0922241	0.13
328.1054077	0.11
346.1687622	45.24
347.2137451	5.59
375.8865356	0.05
395.3018188	0.05
408.1252441	1.42
409.1651611	0.33
419.3713379	0.32
420.2843018	0.11
426.1821899	0.43
427.0333252	0.11
430.2292480	0.03
437.1575317	100.00
438.2229004	16.98
452.0652466	0.06
455.4620361	0.07
456.3098755	0.16
468.1556396	0.23
479.0695801	0.09
508.1509399	0.07
517.1620483	3.54
518.0852051	0.24
526.1850586	0.13
528.2942505	0.14
542.2405396	0.79
543.3480225	0.08
581.0299683	0.18
593.0471802	0.08
623.5265503	0.25
639.2744751	0.02
669.4893799	0.22
684.7071533	0.03
686.1519165	0.19
703.4407349	0.20
723.3425293	0.05
736.6112671	0.06
740.6387329	0.08
741.7559814	0.08
755.5899048	0.04
766.1724243	0.40
766.8908081	0.08
767.5419312	0.14
768.4972534	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.0468
Annotation	Griseophenone B
Peak:m/z	Relative Intensity
101.0149460	0.04
102.9841232	0.18
151.0369110	0.10
157.0148621	0.09
159.9574280	0.23
162.4668884	0.37
163.1768799	0.41
169.1896973	0.03
173.0927887	2.76
175.0443726	0.40
176.1981964	0.08
179.0984955	0.13
181.0534058	0.14
186.8915100	0.04
191.0773773	0.22
193.1542511	1.11
194.8275146	0.12
199.2247620	0.05
203.2926025	0.09
204.9890747	0.09
208.1294250	0.05
213.1936035	0.05
215.1924744	0.03
217.0539551	0.16
225.1024475	0.12
233.0598145	0.05
235.1282654	0.23
237.1575012	9.65
239.1458130	0.05
242.8221741	0.21
245.0094910	0.08
250.8871460	0.14
252.1641541	0.10
254.1589966	2.44
257.2548828	0.08
261.0339050	0.14
265.1193237	0.71
267.0433960	0.08
269.0881958	0.25
271.1411438	13.41
273.1172791	19.25
274.0771484	0.06
277.0582581	0.08
278.9760132	0.07
283.1739502	0.16
285.0879517	0.12
286.1993713	0.12
289.1286926	0.05
291.1527710	0.61
293.2485352	0.25
295.1791077	0.17
300.4620667	0.02
301.1713562	0.08
303.1073608	100.00
303.7567749	0.15
316.5846252	0.18
317.4793396	0.05
318.2801514	0.17
319.1308899	0.65
321.3188477	0.03
322.1705933	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	591.2617
Annotation	Pheophorbide a
Peak:m/z	Relative Intensity
169.0011292	0.01
195.3826599	0.02
199.3889160	0.02
279.3253784	0.03
281.4674683	0.02
311.2036743	0.01
330.8934937	0.01
343.0429688	0.02
363.6089478	0.01
366.6374512	0.01
381.5218506	0.01
433.1182251	0.03
461.4003296	0.01
463.3872070	0.03
464.3370361	0.01
471.4271851	0.03
472.6995239	0.02
491.3381958	0.08
492.6436157	0.03
501.5737915	0.01
503.5944214	0.01
511.4143066	0.01
513.6299438	0.01
515.4227905	76.08
516.3420410	10.16
517.2887573	0.03
518.4562378	0.07
519.4379272	0.08
531.5874634	0.03
533.3702393	0.04
535.5770874	0.03
537.4033813	0.37
538.3377075	0.03
545.7628784	0.10
547.3842773	2.14
548.4796143	0.45
554.0769653	0.03
555.1823120	0.11
559.2200317	100.00
560.1903687	11.79
560.9176636	0.01
563.8029175	0.01
565.1146240	0.02
573.3808594	0.07
574.9766235	0.05
576.5232544	0.03
577.6084595	0.05
591.3759155	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	655.2755
Annotation	Coproporphyrin II
Peak:m/z	Relative Intensity
206.7438354	0.06
210.9541321	0.10
226.2161102	0.13
239.3535461	0.05
247.1586304	0.08
253.2189636	0.12
266.2188416	0.07
295.2701416	0.14
297.4130249	0.31
299.4296875	0.19
303.3605347	0.07
316.4455566	0.15
323.0868530	0.06
325.2413635	0.09
335.1816406	0.06
347.3412476	0.07
365.4696045	0.07
369.2426758	0.20
372.4288330	0.17
373.3335571	0.07
375.3809204	0.15
376.2134399	0.07
377.8976440	0.04
381.1204224	0.12
383.4312134	0.29
385.3249512	0.17
386.9241333	0.26
389.3888550	0.32
391.8836060	0.06
395.1629639	0.22
401.7350464	0.21
403.2084351	0.12
406.9857178	0.08
417.1934814	0.15
419.2988892	0.07
425.5789795	0.16
426.4548340	0.21
428.3648682	0.06
432.0429688	0.13
434.2528076	0.23
438.0073242	0.05
439.3157349	0.19
440.5347290	0.28
444.0585938	0.12
445.3843384	0.13
446.8084717	0.06
447.4760742	0.12
449.0639648	0.05
454.3154907	0.04
457.1948242	0.13
458.5045166	0.19
459.3847656	0.06
469.3968506	0.16
473.4198608	0.11
477.2354126	0.10
478.4261475	0.08
482.1500244	0.05
483.2890015	0.12
499.0441284	0.05
501.9031372	0.11
507.5172729	0.15
508.5170288	0.18
509.3823242	0.07
510.2263794	0.08
513.5064087	0.18
514.5744019	0.15
521.3856812	0.27
524.2261353	0.17
525.4413452	0.23
526.6646729	0.10
528.4419556	0.12
532.0087280	0.11
537.2775269	0.05
539.2604370	0.32
541.4523315	0.14
542.4378052	0.04
543.4048462	0.08
545.1475220	0.06
546.3602295	0.04
547.4193726	0.13
549.4708862	0.19
550.4635620	0.36
551.3568726	0.05
552.1806641	0.16
553.3233032	0.14
557.2035522	0.24
559.6575317	0.24
566.4867554	0.15
567.5498657	0.24
569.4685059	0.37
570.5142822	0.18
573.9872437	0.22
579.4720459	0.42
581.6115112	0.26
583.2073364	0.27
585.3855591	4.27
587.3660278	0.15
591.5834961	0.30
592.3237305	0.15
595.4094849	36.24
596.2922974	0.17
597.7466431	0.13
599.3292847	0.17
600.1145020	0.27
601.7761230	0.20
604.7811890	0.41
605.5232544	0.86
606.4353638	0.10
609.3532104	0.18
611.3575439	1.82
613.3139038	16.35
614.2142334	0.14
616.7645874	0.16
619.2505493	0.87
622.3588257	100.00
623.3857422	6.33
627.2614136	5.74
628.0851440	0.19
636.4867554	2.95
637.3071899	5.29
638.0811157	0.96
639.9503174	0.55
641.5695801	0.07
657.7619019	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	406.1636
Annotation	6-Acetonyldihydronitidine
Peak:m/z	Relative Intensity
130.0403595	0.05
145.1199341	0.09
154.7851410	0.03
156.0023804	0.39
161.7959442	0.18
173.7608032	0.13
178.9985657	0.67
184.7503967	0.05
199.1817780	0.03
210.2756042	0.07
213.1823425	0.09
213.9338989	0.05
216.7261353	0.08
242.1961670	0.09
244.2324524	0.21
251.0488892	0.02
255.6833496	0.11
259.1146545	100.00
259.9927368	0.06
262.9736023	0.06
265.2098694	0.22
271.3901978	0.04
272.4647522	0.13
275.2378540	0.18
277.0299683	3.19
279.1472778	0.23
284.4912720	0.52
285.1144409	2.10
288.8075562	0.11
290.0117798	0.08
290.8567200	0.09
298.9302979	0.09
301.3173828	0.10
302.4210815	0.03
305.2933960	0.05
308.0524902	1.39
313.1062622	2.17
313.7266846	0.12
317.1617432	0.14
331.1816406	1.27
333.4987793	0.21
334.2551575	0.08
343.4227295	0.10
344.8566284	0.34
350.3690796	0.64
351.5308838	0.10
353.0696411	0.07
355.0598450	0.04
356.2020569	0.06
359.3178406	0.07
362.3672180	0.15
363.9874573	0.12
371.0112305	0.07
372.7651062	0.20
375.2798462	0.13
376.3503113	0.07
379.2002869	0.09
381.8792114	0.15
383.9312439	0.32
387.1526489	0.27
388.2876282	11.97
389.3645935	0.53
390.3812256	0.12
396.5722351	0.36
397.5732117	0.18
400.6313782	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	264.9845
Annotation	Unknow
Peak:m/z	Relative Intensity
86.9344635	0.08
97.0440979	0.03
104.9329071	10.00
114.8214874	0.41
132.8643188	0.15
148.8490143	100.00
151.1822662	0.06
186.1004028	0.11
210.0424652	0.03
230.1046143	0.09
246.2823944	0.17
247.1942291	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	238.02
Annotation	Unknow
Peak:m/z	Relative Intensity
107.9525146	0.07
116.8990021	16.65
119.9995117	51.31
123.9152679	0.04
125.9763947	0.12
127.9728088	0.08
129.9426117	0.21
146.1437073	0.85
150.8993530	1.67
154.1388397	0.12
159.9123840	0.37
164.1558380	0.10
165.1694031	0.06
166.0360107	0.05
172.1183319	0.11
174.1314240	0.23
176.9618988	0.29
181.1911011	0.06
191.8686371	0.04
193.0840759	0.19
193.9500885	0.32
202.1336212	0.12
203.9921417	100.00
209.0755157	0.09
218.2523193	0.19
220.0169678	1.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	361.1657
Annotation	(+)-Jurinelloide
Peak:m/z	Relative Intensity
107.8957062	0.25
108.8901367	1.96
111.0748596	0.11
118.9376678	0.08
121.3256989	1.88
121.9963837	6.87
123.1011963	1.40
124.1203308	0.15
129.0683289	1.55
134.9759979	1.13
136.0227051	3.68
136.8806152	0.21
138.0154266	0.05
141.0863647	0.07
143.0835419	0.53
145.9662323	0.62
147.0046692	3.78
148.7589417	0.93
149.8484192	0.15
151.1859131	0.06
155.2101135	0.24
157.1716766	0.08
158.0646667	0.23
159.2118530	0.08
161.1112671	1.54
162.2025452	0.82
163.2228088	0.19
164.0224304	0.11
165.0136719	44.74
165.9203644	1.18
167.0376587	0.05
171.9784851	0.29
172.9544678	0.08
173.9395447	0.29
175.0633545	0.62
176.0482178	0.29
177.2417603	0.28
178.2339935	2.00
179.0458527	25.26
181.8560028	0.14
183.9961548	0.08
185.4214172	0.05
187.1754150	0.16
188.0810699	0.13
188.9380798	0.20
190.0779572	0.08
191.0111084	1.65
191.9745636	0.67
193.1353149	1.22
194.0677490	0.09
199.1503143	1.75
199.7866211	0.07
202.0719604	0.25
202.9620972	0.08
205.1209106	1.27
206.1333160	0.44
207.1481934	0.39
208.2140198	0.07
209.1878357	1.27
210.2412720	0.11
210.8443909	0.10
215.2152710	0.15
217.0546875	0.19
219.2832642	0.08
220.9357605	0.67
222.2599182	0.28
223.1105042	5.25
225.2574768	0.48
229.2644653	0.07
230.9716187	0.43
235.1664429	0.05
236.0718384	0.08
237.2561035	0.40
239.1638794	0.10
243.1665039	0.05
244.3228149	0.07
255.1287231	0.06
256.2086792	0.05
263.4539185	0.10
265.0103149	0.07
266.2786255	0.79
269.3868713	0.64
270.2485962	0.09
271.2843933	0.37
272.0430908	0.16
276.0556641	0.23
279.1085205	0.15
280.0583496	0.08
281.2058105	3.74
282.0089722	0.09
283.4285278	0.32
284.0651245	0.19
285.1270447	0.24
286.1629028	1.05
287.1401978	0.15
289.2005005	0.33
295.4925537	0.31
298.2731018	11.86
299.3306580	0.84
300.2091064	0.13
301.1403809	1.05
301.9810791	0.20
303.2693176	0.20
311.3133240	0.49
313.2812500	31.10
314.1884155	0.34
315.2392273	6.53
316.2305298	2.92
317.2537537	0.53
319.3430786	1.00
321.0617676	0.11
325.4149170	0.27
327.1395264	0.45
328.2404785	1.03
329.3401489	2.03
331.3066711	17.11
332.2705688	0.06
333.2597351	0.13
341.1314392	0.70
343.2196350	24.16
344.0564880	0.41
346.1721191	100.00
347.3262024	0.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.0879
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
132.2648773	0.01
137.0611877	0.01
138.9268036	0.01
145.1802673	0.01
147.0289764	0.00
149.0080566	0.01
150.9828339	0.84
152.0356293	0.11
153.0556641	0.03
160.8378754	0.01
162.0149078	0.01
163.0306549	0.04
165.1079254	0.01
168.9336853	0.05
170.0410919	0.01
173.1466217	0.01
174.1370087	0.01
175.5975189	0.03
179.0725403	0.92
180.1356964	0.10
183.1434937	0.01
187.1949158	0.03
188.0057373	0.02
188.9799957	0.14
190.0810852	0.10
190.9932556	0.10
192.0766754	0.01
193.1493225	0.05
197.0366516	0.04
199.1893311	0.03
201.2127686	0.02
206.4133301	0.03
207.0546722	0.03
207.9964752	0.02
209.1854858	0.04
211.1255798	0.01
212.0457611	0.02
213.1407318	0.03
214.2327881	0.02
215.3849182	0.01
217.0997620	0.06
218.1484833	0.03
219.1595154	0.03
221.2024384	0.05
223.1633759	0.01
227.2356415	0.01
229.1760406	0.06
230.2575989	0.05
231.1744080	0.01
233.2491608	0.02
234.1278839	0.04
235.2172546	0.04
237.0667419	0.03
238.2985535	0.01
239.7163391	0.01
240.6429901	0.02
242.1912079	0.01
243.0160522	0.05
244.3088074	0.02
245.0556946	0.03
247.0841675	0.02
248.1989136	0.01
249.1467590	0.03
251.1427002	0.01
254.2200928	0.09
255.2303772	0.35
256.2113037	0.08
257.0885925	0.06
258.0197449	0.03
259.2390747	0.03
261.0178223	0.01
263.3377380	0.02
267.1719666	0.01
269.5010071	0.01
271.1194458	0.48
272.2526550	0.16
273.2720642	0.16
274.2743835	0.08
281.6254883	0.02
282.4210510	0.00
283.3118591	0.03
284.2763977	0.04
285.2339172	0.05
287.1399536	0.01
292.2521362	0.01
295.0878296	0.03
296.2178650	0.00
297.3869629	0.05
300.1669922	21.11
301.0988464	100.00
302.0996094	20.09
303.2806396	0.01
308.1636353	0.02
309.3146973	0.01
310.9458008	0.02
312.2063599	0.04
313.1139526	0.08
314.0290527	0.03
315.3563843	0.05
319.1831970	0.03
321.0056152	0.01
323.3674927	0.01
324.1998901	0.01
325.1269531	0.08
326.1670532	0.04
327.3659973	0.04
329.4584656	0.00
330.1105957	0.05
331.1750183	0.01
335.0876160	0.01
337.0543213	0.10
338.4190369	0.01
341.1511841	0.03
342.1212463	0.00
343.1092834	2.19
344.1863403	0.37
347.2651672	0.01
353.1643066	0.04
354.2158813	0.01
355.3880615	0.06
356.5538635	0.02
360.2031555	0.01
362.2763062	0.01
366.5998840	0.02
367.2598877	0.03
373.0025330	0.10
374.1195679	0.01
380.1671143	0.01
386.3471069	0.03
395.0394897	0.03
396.4449768	0.01
399.1436157	0.01
401.2530823	0.03
403.3212280	0.03
404.1557617	0.02
409.5860901	0.02
417.3721008	0.01
419.2994385	0.09
420.0293884	0.02
425.1655579	0.01
445.2650146	0.27
446.1301880	0.10
447.0641174	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	627.2812
Annotation	Red chlorophyll catabolite
Peak:m/z	Relative Intensity
186.9878387	0.13
197.0411530	0.07
210.8312225	0.19
222.9759979	0.09
229.1082764	0.10
248.7719421	0.05
257.0377808	0.09
277.3475037	0.10
281.1021118	0.11
283.6224976	0.13
289.0582886	0.14
299.2299194	0.12
312.5094604	0.04
343.0810547	0.12
345.2893677	0.05
348.2301636	0.06
355.3585815	0.17
356.6355591	0.10
360.8087158	0.09
367.5839233	0.26
373.2789307	1.32
374.2658691	1.42
375.2031860	0.51
381.3099365	0.18
385.2379761	0.05
389.2757568	0.04
390.9820557	0.12
392.0906372	0.23
393.3676758	0.23
400.9603882	0.08
403.1851807	0.18
409.1491089	0.20
414.7083740	0.17
419.0400391	0.10
421.5416260	0.13
423.2502441	0.46
424.0068359	0.23
433.3026733	0.19
436.5256348	0.17
438.1863403	0.09
451.1304321	0.02
455.5330200	0.05
468.5255127	0.12
469.3200073	0.13
477.2885742	0.03
478.6049194	0.18
489.6796875	0.14
493.2535400	0.05
496.3325806	0.67
497.3473511	2.29
505.8610229	0.07
508.5770874	0.05
510.4098511	0.14
511.2836304	0.18
513.5947266	0.20
517.3362427	0.09
519.0791626	0.04
523.5150757	0.33
525.0433350	0.10
527.4859009	0.24
533.2074585	0.05
535.4441528	0.25
538.3438721	0.43
539.5108643	0.12
541.3528442	6.39
541.9662476	0.21
543.1126099	0.05
545.2307739	0.18
546.5502319	0.11
549.3635254	0.21
551.6533203	0.51
552.4849854	0.09
553.6062012	0.11
555.4049072	0.35
559.2233276	0.05
561.3428345	0.11
563.4328003	0.46
564.6673584	0.25
565.4911499	0.28
566.6835327	0.19
567.4507446	0.30
569.1557007	0.13
570.4094849	0.06
577.6710815	0.42
581.2260132	0.52
582.2731934	0.58
583.3973389	41.33
585.3489380	100.00
591.3927612	0.67
592.0807495	0.10
595.2789917	1.31
596.7449341	0.14
599.4546509	2.21
609.1552124	1.58
612.3903198	0.24
613.7595825	0.07
618.0486450	0.07
627.2139282	0.05
631.0762329	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	261.14
Annotation	Glu Leu
Peak:m/z	Relative Intensity
150.9145966	3.12
160.1568756	4.65
200.0397339	4.74
219.8651886	6.11
225.1490936	1.25
243.1316986	100.00
244.3329315	3.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	487.1727
Annotation	Gemichalcone B
Peak:m/z	Relative Intensity
144.0312653	0.60
146.0406342	4.48
150.9555817	0.08
153.1634064	0.18
159.2299347	0.31
169.9830475	0.51
186.1338959	0.20
188.0186005	29.43
204.9752502	100.00
205.5847778	0.12
241.5705719	0.09
247.0184631	0.08
254.0799866	0.43
257.3467102	0.13
263.9914246	0.39
268.0311890	0.36
274.1786194	0.09
275.1330261	0.11
281.6436768	0.37
283.2102661	1.25
286.3076477	0.28
289.0826416	0.38
300.1194153	0.19
303.2003784	0.23
304.2077637	0.25
307.1438904	0.22
311.9532776	0.08
313.1439514	0.09
341.3607788	0.07
345.6168823	0.11
353.1276245	0.19
354.3322144	0.18
355.5398560	0.27
360.7869263	0.21
367.4157715	0.07
369.1633301	0.08
370.5021057	0.41
371.3779297	0.16
372.2490845	0.06
380.4934998	0.10
382.2366943	0.15
387.1236877	0.22
396.0935364	0.41
398.2598877	0.22
401.2230225	0.11
406.2087708	0.20
412.3759766	0.24
415.6891479	0.37
421.2622986	0.30
427.3366089	0.22
429.7630920	0.19
437.3726501	0.14
439.3962708	0.05
441.3057251	0.34
456.3433533	0.23
457.8916626	0.45
464.3569641	0.38
466.4197693	0.07
468.6535339	0.42
469.4382019	0.91
470.0766296	0.46
476.2207642	0.47
478.3262329	0.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.328
Annotation	Dolichosterone
Peak:m/z	Relative Intensity
156.9036560	0.06
172.0133209	0.05
183.2832642	0.30
192.9761353	0.32
194.0975494	0.11
197.1737213	0.07
204.9338837	0.10
206.1974182	0.24
206.9367981	0.07
209.0200043	0.46
209.9686737	0.11
223.3212738	0.05
225.3339691	0.05
235.1610107	0.34
238.0888977	0.13
241.0203705	0.12
247.1748352	0.13
249.2738647	0.11
251.4526672	0.07
255.1989136	0.05
257.2760010	0.48
263.2151794	0.07
265.6228027	0.23
269.1049500	0.07
272.1902466	0.06
278.9816284	0.35
290.9765015	0.22
292.9053650	0.11
293.5814209	0.12
297.5462036	0.06
299.1239929	0.17
305.3319092	0.30
310.2692871	0.14
319.5252686	0.10
321.4933167	0.06
329.2374573	0.13
331.2188721	0.23
333.4353638	2.82
334.5152588	0.07
337.3492737	0.37
339.1483765	0.08
343.3063965	0.20
347.1727905	0.05
353.5713501	0.24
354.9870605	0.25
356.1439209	0.24
357.4867249	0.10
361.3524170	4.29
362.1993408	0.42
363.2055969	0.07
367.3048401	0.11
371.4804077	0.07
373.4053040	7.57
375.3850098	28.52
376.4582520	0.97
377.4138794	0.36
380.9428711	0.09
387.1153259	0.28
389.5254211	0.45
390.5779724	0.19
391.3985901	0.30
393.4853821	0.20
398.0666809	0.10
399.4814148	2.06
400.6894531	0.25
401.3927002	0.17
402.7842102	0.16
404.3199158	0.40
409.1149597	0.07
415.3499451	1.84
417.3947449	100.00
418.3731384	1.39
419.5608826	5.27
421.4493713	0.11
423.2296143	0.30
425.4104309	0.92
428.4539795	0.09
433.3914490	0.28
434.3601990	0.09
443.2583923	3.19
444.4291077	1.19
445.4458618	3.11
446.4725037	0.69
453.4590149	0.06
455.3077698	0.24
461.3886108	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1038.7684
Annotation	Unknow
Peak:m/z	Relative Intensity
280.1857605	0.32
296.0827637	0.21
316.0670166	0.33
342.2141113	0.47
343.7604980	0.12
344.5935364	0.49
412.3016357	0.31
427.1200867	0.22
444.2194824	0.12
451.0258179	0.14
453.3967896	0.15
462.2141724	0.12
464.2730103	0.56
474.4165955	0.31
542.3634033	0.26
544.3237305	0.39
632.0283203	0.39
634.5042114	0.25
681.3697510	0.34
695.4652100	0.50
697.2873535	0.33
757.4350586	0.20
759.4224854	0.19
766.1925659	0.15
787.0460205	0.90
789.5714111	1.20
799.2966309	0.11
831.0107422	0.13
847.6129150	1.36
860.7252197	1.30
868.1434326	1.44
874.9951172	1.03
875.7014160	0.16
876.9558105	0.71
879.9552002	0.45
881.6317139	0.13
883.3767090	0.16
884.6127930	0.33
885.8183594	1.85
888.5966797	2.00
896.1069336	1.19
898.3800049	0.87
899.2507324	1.09
900.8200684	0.95
901.4755859	0.71
902.3685303	0.67
902.9822998	1.01
905.1640625	0.65
905.8974609	0.87
910.5490723	1.02
914.7525635	0.33
918.5101318	0.87
919.4705811	1.66
920.2518311	1.62
921.1662598	0.52
921.9104004	1.60
923.6597900	5.86
925.1357422	4.39
926.2503662	1.37
927.4501953	1.57
928.1237793	1.78
929.0904541	1.38
930.2559814	2.67
931.2832031	1.99
933.7445068	5.72
934.8194580	2.41
936.8763428	0.50
938.6932373	2.12
939.9003906	4.12
940.7354736	1.82
941.3500977	0.29
943.1700439	2.76
944.1995850	2.57
946.3315430	2.14
947.3531494	2.39
948.4658203	2.26
949.8651123	1.40
951.0812988	1.70
951.8906250	0.67
952.9027100	5.27
953.5495605	3.32
954.1713867	0.34
955.3400879	1.27
956.2542725	1.76
958.1269531	1.20
959.5007324	0.97
961.7731934	14.43
962.6407471	6.71
964.5694580	1.46
965.3901367	0.49
966.5103760	4.69
967.8920898	7.53
968.7446289	2.72
969.4274902	0.13
970.3813477	1.20
972.1605225	12.44
973.0236816	10.05
974.7441406	1.65
975.6933594	3.09
977.9226074	0.83
979.0572510	1.16
980.1358643	9.72
980.9350586	11.07
981.9068604	1.78
982.8310547	2.04
983.4436035	2.37
984.5318604	3.69
986.2037354	15.02
987.1307373	10.65
989.2929688	37.04
990.0834961	4.77
991.0021973	5.48
992.0195312	16.36
992.7092285	1.57
995.0510254	47.50
995.8055420	28.89
996.7661133	0.58
997.4110107	0.41
1000.1618650	12.30
1001.0812990	27.83
1001.7838130	40.14
1003.0283200	1.86
1003.7437740	1.06
1004.5286870	0.74
1005.8846440	9.92
1006.7565920	7.52
1007.5439450	1.55
1008.4460450	1.13
1009.1596680	0.34
1009.8601070	1.51
1011.1711430	0.16
1012.6452640	6.59
1013.4061280	7.23
1014.2509770	1.93
1015.4669190	6.19
1017.3471680	0.80
1018.8171390	27.39
1019.7565920	5.54
1021.3449710	1.77
1021.9495850	16.25
1022.7154540	0.62
1024.4846190	21.93
1025.4913330	5.48
1027.6964110	77.33
1028.7067870	1.07
1029.7580570	1.08
1030.7126460	1.18
1032.9029540	0.47
1038.8792720	0.73
1049.8522950	0.50
1061.0876460	0.44
1076.2836910	0.20
1113.5949710	1.00
1118.1829830	0.14
1119.0285640	0.33
1121.2906490	0.08
1147.3150630	0.63
1148.8066410	0.43
1150.6881100	0.23
1156.5908200	0.40
1157.2065430	0.18
1158.0844730	0.55
1159.9887700	0.28
1161.6525880	0.37
1165.9475100	0.40
1169.5686040	0.84
1174.2292480	1.34
1175.5560300	0.47
1176.1955570	1.48
1182.1597900	0.89
1183.7636720	1.52
1185.0687260	0.36
1189.3144530	0.59
1195.1630860	0.19
1201.2390140	0.88
1203.7507320	0.63
1213.9750980	0.37
1217.6203610	0.48
1219.1647950	0.66
1219.9630130	0.07
1221.7451170	0.31
1227.2600100	0.43
1228.6049800	0.92
1230.4951170	1.51
1231.2235110	1.35
1233.9235840	2.31
1239.0632320	0.16
1241.7644040	0.61
1243.9107670	0.52
1244.7427980	0.43
1253.7203370	1.49
1259.1968990	0.67
1260.9927980	0.68
1262.1528320	1.38
1263.5705570	0.31
1264.5473630	1.26
1270.3856200	0.37
1272.2944340	0.41
1274.1081540	0.63
1276.9609380	0.92
1278.1683350	4.84
1279.3977050	2.33
1281.0216060	1.19
1284.1641850	0.70
1286.8159180	0.77
1293.7257080	0.36
1294.8503420	0.71
1297.4221190	1.10
1298.6638180	0.32
1300.5397950	0.58
1303.7340090	0.44
1306.5754390	0.27
1309.5715330	0.81
1310.2299800	3.70
1310.8312990	0.24
1314.3858640	3.01
1315.3673100	0.65
1319.3979490	0.57
1321.0081790	1.46
1321.9729000	2.96
1323.0972900	1.53
1326.4119870	1.09
1327.4056400	8.60
1328.0562740	3.90
1328.6629640	1.14
1329.9481200	1.21
1331.6781010	0.20
1332.5395510	1.28
1333.2296140	0.52
1334.4116210	0.31
1335.4096680	0.39
1336.6228030	0.85
1338.0177000	3.52
1338.8270260	0.43
1340.5010990	0.98
1342.9954830	0.61
1344.0045170	1.84
1344.7890620	2.10
1345.6494140	2.06
1351.5718990	1.23
1354.1224370	1.84
1354.9986570	0.52
1356.3394780	0.72
1358.0655520	0.52
1361.4099120	1.70
1362.5784910	2.03
1363.2102050	0.83
1364.2110600	0.64
1368.5798340	0.69
1369.5876460	1.93
1370.2386470	2.50
1372.3269040	0.71
1378.0632320	5.89
1379.1185300	5.00
1380.2739260	1.97
1383.3543700	0.23
1384.7697750	0.43
1385.6496580	1.73
1388.1118160	5.98
1388.8339840	1.39
1389.5225830	0.73
1390.1336670	0.37
1391.8144530	1.48
1393.5007320	4.79
1394.8089600	2.19
1400.1087650	2.38
1401.2761230	5.02
1402.0882570	7.65
1403.2269290	1.60
1404.3363040	0.63
1406.5750730	0.61
1408.3375240	0.88
1410.6127930	0.81
1411.3743900	20.54
1414.9681400	1.47
1415.9051510	1.47
1417.2725830	2.61
1417.9305420	0.23
1419.6490480	0.63
1421.0877690	0.11
1422.6910400	1.02
1424.1456300	0.86
1424.7989500	0.14
1425.4124760	0.60
1426.6981200	0.88
1427.8732910	1.50
1428.7825930	5.36
1429.6077880	1.84
1433.2401120	1.13
1434.5728760	1.34
1435.5982670	4.15
1436.4349370	2.20
1437.9310300	0.39
1441.9530030	0.71
1443.3339840	1.80
1445.6190190	0.68
1446.6566160	1.37
1448.6851810	1.55
1449.5880130	0.89
1451.3800050	3.97
1452.3588870	3.53
1453.2293700	0.28
1457.5814210	7.35
1458.6650390	4.95
1459.6104740	0.86
1465.8563230	2.84
1469.0308840	0.26
1475.6842040	1.12
1478.8363040	0.73
1479.8386230	2.18
1481.0711670	1.05
1483.0070800	1.13
1484.0227050	2.86
1485.0230710	0.77
1487.7073970	0.66
1488.3511960	0.37
1490.5006100	1.28
1491.9447020	6.38
1492.7443850	8.03
1493.5469970	0.24
1494.2749020	0.43
1496.6613770	0.65
1500.7170410	9.70
1501.4335940	27.74
1502.5225830	5.29
1503.5880130	1.47
1509.3005370	2.92
1510.1362300	1.54
1510.7817380	0.88
1549.7866210	0.30
1565.0749510	0.17
1569.0656740	0.20
1592.3116460	0.14
1599.6619870	0.10
1645.8848880	0.28
1671.9439700	0.93
1685.7619630	0.39
1689.2076420	0.22
1699.3859860	0.22
1701.9434810	0.14
1709.5886230	0.20
1715.6639400	0.23
1726.3934330	0.55
1727.4237060	0.44
1736.5655520	0.42
1744.7917480	0.11
1769.8488770	1.38
1788.8513180	0.13
1795.4149170	0.26
1796.0583500	0.67
1796.7097170	2.10
1798.3321530	0.65
1818.8878170	3.77
1820.2601320	0.33
1827.3366700	0.12
1828.0921630	2.59
1839.5480960	0.49
1840.7972410	0.80
1841.8728030	0.30
1842.5562740	0.21
1843.2385250	1.06
1844.0281980	0.64
1850.2185060	4.45
1855.1778560	4.22
1857.2083740	18.98
1858.3560790	3.16
1860.6746830	0.29
1866.6163330	0.29
1868.1441650	0.62
1869.3065190	0.37
1873.7014160	0.24
1879.1700440	2.06
1883.9392090	0.27
1885.0262450	0.23
1888.3913570	1.25
1889.8656010	0.45
1890.8133540	0.21
1891.8602290	2.88
1892.6480710	0.14
1896.0017090	0.11
1901.0440670	1.07
1902.7982180	0.16
1903.7789310	2.91
1904.7825930	2.05
1905.9532470	0.31
1908.5393070	0.18
1910.0189210	0.13
1912.2005620	0.56
1914.5389400	1.78
1915.4591060	0.41
1916.7761230	73.08
1918.1627200	1.89
1919.4093020	1.69
1920.5871580	28.72
1921.8497310	0.32
1923.0821530	1.09
1925.0062260	0.16
1926.6820070	1.05
1927.2932130	7.06
1930.6413570	9.52
1933.0452880	0.21
1933.8104250	0.45
1939.3472900	3.09
1940.5311280	28.67
1941.1688230	0.70
1942.8739010	0.26
1943.9664310	0.57
1945.2181400	0.14
1946.0587160	0.76
1947.5050050	7.79
1948.6829830	0.34
1950.2205810	0.20
1954.7498780	2.72
1956.5667720	1.72
1958.1148680	2.17
1959.8068850	9.44
1960.4151610	11.84
1961.4395750	6.90
1963.5372310	0.21
1966.3653560	0.24
1967.6804200	9.44
1968.7746580	8.25
1969.4617920	9.75
1971.0535890	1.32
1971.7908940	1.30
1972.6339110	3.09
1974.4210210	0.25
1976.5174560	2.19
1977.2806400	0.12
1978.6002200	58.24
1982.0236820	0.37
1985.9554440	3.42
1987.1331790	100.00
1989.1527100	26.13
1991.7723390	0.28
1992.5516360	15.26
1993.3304440	0.99
1994.2272950	0.14
1995.9068600	0.51
1997.1568600	20.14
1998.0679930	23.41
1998.7401120	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1315.3584
Annotation	Unknow
Peak:m/z	Relative Intensity
445.3166504	0.24
463.4468994	0.51
477.4788208	0.41
478.4325256	0.06
489.1331177	0.31
499.1903687	0.04
507.5243225	0.08
517.1973267	0.79
541.4330444	0.08
543.4549561	0.08
609.2523193	27.18
610.2966309	4.66
610.9329834	0.05
621.3531494	0.59
622.3750000	0.19
623.2619629	0.45
631.2225342	0.46
639.1962891	44.91
640.3080444	5.99
651.2275391	0.36
653.2551880	0.10
669.2817383	7.27
670.3206787	1.16
680.8151855	0.13
681.4708252	0.35
683.2279663	0.20
691.4058838	0.30
699.6508789	0.10
705.1782837	1.01
706.2340088	0.63
753.5045166	0.27
771.2180176	0.69
772.4847412	0.16
783.3870239	0.77
785.0036621	0.90
786.3314209	0.13
801.0599365	3.00
802.0817261	0.99
815.1051636	0.28
845.4346924	0.12
846.4449463	0.04
858.0013428	0.43
875.8884277	0.21
915.6621094	0.10
947.2919922	100.00
948.3458252	18.46
959.2503662	0.12
977.2723389	5.20
978.3183594	1.05
988.6784668	0.10
989.4930420	0.06
992.3525391	0.05
1007.1782230	23.94
1008.2064210	4.37
1008.8432620	0.04
1030.7941890	0.07
1069.1496580	0.08
1091.3774410	0.51
1109.2156980	23.38
1110.3272710	6.26
1121.1481930	0.39
1153.2363280	2.31
1154.1303710	0.56
1157.8587650	0.18
1170.0814210	0.07
1171.0755620	0.19
1275.4072270	0.24
1277.0838620	0.11
1279.9837650	0.08
1297.8208010	0.19
1298.7769780	0.05
1301.0595700	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	605.1873
Annotation	Pinocembrin 7-O-neohesperidoside 3'''-O-acetate
Peak:m/z	Relative Intensity
180.6844177	0.07
199.1663208	0.17
206.8988342	0.06
284.9287109	0.07
305.9383545	0.19
306.9898376	0.19
327.0061035	0.08
328.2138672	0.04
341.2761230	0.08
351.1011353	0.16
355.3630371	0.25
362.1470337	0.36
391.3769531	0.08
399.1997070	0.06
405.5395508	0.09
443.1978760	100.00
443.8470459	0.30
461.3269653	0.18
485.2620239	1.04
489.4771729	0.14
491.1226807	0.14
492.6175537	0.06
494.9505615	0.04
509.1520386	0.33
519.1195068	0.15
527.3552856	0.06
532.2957764	0.18
537.0488892	0.19
539.3213501	0.15
541.1630859	0.29
542.6860962	0.31
543.9111938	0.15
544.8230591	0.15
552.2885132	0.12
557.2784424	0.25
559.0476685	1.16
561.9204712	0.07
563.0663452	0.17
568.6200562	0.10
569.5296021	0.25
570.5012817	0.18
574.6849976	0.22
575.7250977	0.11
586.9130249	0.76
590.3698730	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0852
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.91644287	0.45
103.1080322	1.19
104.981842	1.28
107.2385406	0.35
109.0745697	0.64
128.9821472	7.55
143.026535	0.70
145.2868347	0.62
150.9764557	100.00
151.9660034	3.86
154.0828247	0.45
155.1845856	1.31
166.0985413	1.07
167.2344055	1.37
178.0073395	1.99
178.8830414	2.55
180.4106598	1.12
181.1268158	0.45
182.0240173	1.51
182.9821625	0.86
185.2068024	1.14
186.016098	1.52
190.0002289	2.46
191.0789337	0.35
193.8997955	2.14
197.2155609	11.30
198.1018677	1.51
206.9410706	3.19
210.3213959	1.12
217.4178772	0.88
225.2862549	13.25
235.141037	0.63
237.6876678	4.43
238.2906342	6.61
239.0692139	2.50
253.0908051	68.50
254.2772217	8.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	146.0458
Annotation	3-Aminopentanedioate
Peak:m/z	Relative Intensity
100.1518707	0.04
102.0157013	8.51
109.0006409	0.01
127.9746399	100.00
129.1189728	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1096.803
Annotation	Unknow
Peak:m/z	Relative Intensity
410.8021240	0.16
432.3363342	0.05
458.5021973	0.06
520.4990234	0.08
526.2148438	0.09
560.4886475	0.07
621.3590088	0.04
707.6135864	0.06
799.6661987	0.16
846.8187256	0.16
872.1439209	0.52
880.8026123	0.16
890.6679688	0.57
902.8675537	0.21
931.8182373	0.34
933.2615967	0.17
935.6662598	0.04
961.6130371	0.45
964.5756836	0.10
969.2867432	0.60
978.0000000	0.10
997.2489014	0.31
1006.2060550	0.06
1007.5722660	0.69
1013.9567870	0.16
1019.0837400	0.11
1027.1466060	0.08
1028.5104980	0.09
1039.2062990	0.52
1043.1103520	0.43
1043.8361820	0.36
1046.9865720	0.49
1047.6887210	0.34
1048.6539310	1.46
1049.4514160	0.19
1050.9299320	0.38
1053.7329100	0.07
1056.0698240	0.09
1058.2458500	0.64
1061.7661130	0.28
1066.3090820	3.62
1067.0225830	0.98
1067.7901610	0.04
1070.3762210	0.22
1071.0141600	0.55
1076.4565430	0.82
1078.5902100	0.65
1081.3085940	0.34
1082.9274900	1.52
1083.8399660	2.76
1084.5058590	0.04
1085.6262210	1.52
1086.3914790	0.59
1119.3552250	0.04
1134.5336910	0.12
1140.2604980	0.25
1145.4780270	0.12
1147.8842770	0.23
1149.0051270	0.20
1164.3840330	0.05
1180.0302730	0.29
1181.1646730	0.72
1187.0692140	0.64
1190.3779300	0.40
1198.4062500	0.08
1208.4187010	0.32
1209.8518070	0.18
1214.0208740	1.01
1214.6732180	1.15
1216.8055420	0.32
1217.8441160	0.88
1219.6977540	0.22
1223.6638180	0.35
1224.2847900	0.03
1225.4180910	0.19
1227.0679930	0.80
1227.8424070	1.83
1228.5100100	0.25
1231.8839110	0.54
1235.2398680	0.25
1237.7531740	0.24
1238.5761720	0.09
1239.6292720	0.81
1240.8049320	0.65
1243.0471190	3.45
1243.6657710	1.34
1246.4692380	7.31
1247.2111820	1.63
1249.0980220	0.60
1250.7243650	3.47
1251.6901860	0.33
1252.4273680	0.77
1254.3890380	22.18
1255.0710450	8.40
1255.9162600	0.20
1257.9995120	100.00
1258.9553220	2.21
1259.8243410	1.10
1260.8063960	0.24
1261.4541020	0.09
1262.1207280	0.26
1264.3321530	0.23
1266.1159670	0.08
1267.6823730	1.13
1271.9158940	0.10
1273.6730960	0.58
1274.6599120	0.93
1276.9929200	2.77
1277.6508790	1.46
1278.9517820	0.30
1279.9433590	4.15
1280.8059080	2.58
1283.6706540	2.54
1284.4265140	0.47
1285.3415530	0.57
1285.9470210	0.84
1287.0604250	0.86
1290.4816890	1.33
1293.3936770	0.80
1298.2261960	0.15
1303.2502440	0.50
1323.5766600	0.54
1336.7257080	0.32
1347.8673100	0.57
1370.8228760	0.10
1405.0093990	0.18
1410.2078860	0.66
1422.4632570	0.34
1447.9492190	0.31
1454.0736080	0.48
1474.0404050	0.44
1488.2667240	0.12
1490.5427250	0.71
1498.8154300	0.05
1502.5780030	0.07
1505.5485840	0.23
1506.4927980	0.16
1509.1546630	1.05
1518.9002690	0.26
1525.2824710	0.07
1550.8697510	0.41
1564.4724120	0.09
1567.2910160	0.64
1596.8881840	0.08
1599.8309330	0.12
1609.3021240	0.07
1619.0343020	0.13
1639.4276120	0.14
1656.4528810	0.12
1670.6290280	0.08
1682.7486570	0.18
1691.7213130	0.20
1706.8947750	0.31
1757.5306400	0.04
1814.3708500	0.70
1816.8638920	0.28
1836.0823970	0.18
1860.9168700	0.13
1869.3470460	0.08
1873.1199950	0.10
1892.4200440	0.17
1905.3697510	0.12
1909.1179200	1.16
1921.2427980	0.13
1922.1041260	0.34
1924.5677490	0.25
1930.6864010	13.70
1943.7879640	2.45
1950.0653080	0.25
1951.3441160	0.33
1957.0920410	0.65
1969.5118410	2.91
1974.4617920	2.83
1993.2872310	1.27
1995.3201900	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	400.2172
Annotation	Unknow
Peak:m/z	Relative Intensity
114.6528625	1.96
126.7995758	1.10
132.9470520	0.33
144.9202118	3.01
149.8026733	0.73
161.8237610	0.87
162.9563599	11.14
167.0725250	0.28
175.0677185	0.61
180.7975616	0.72
182.9455566	0.65
184.7238312	1.84
189.1379547	0.77
190.8565521	0.22
201.0408783	0.60
207.3616791	1.23
211.1650543	0.31
217.0748901	2.04
219.0831299	0.63
220.6596375	4.09
221.4144745	0.46
222.9967957	1.27
233.0681458	0.38
239.9885559	0.70
241.0178528	3.24
250.8426819	59.14
254.7590637	0.42
257.7877502	0.99
258.9561768	30.49
268.0140381	1.17
273.2872620	0.51
274.7243347	0.61
276.8397522	9.33
285.1033936	0.44
286.1350708	1.31
287.2012329	1.77
289.2738647	1.04
294.8746338	100.00
295.6067505	0.65
318.7955017	0.25
324.2342529	2.27
325.1953735	0.22
328.9456787	2.17
332.0824890	0.56
346.4231567	5.43
347.1022339	0.21
356.0893555	0.87
365.1733398	0.54
368.9351501	0.22
369.6665955	0.88
371.2333069	0.45
373.3008728	0.34
382.0442505	6.48
382.8739624	20.86
383.6597595	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	369.1173
Annotation	3-O-Feruloylquinic acid
Peak:m/z	Relative Intensity
117.0017624	0.19
129.8870239	0.04
134.8341980	0.07
144.9451599	5.73
149.0106201	0.04
159.1069946	0.06
177.0591125	100.00
190.9676666	0.03
192.0939636	0.02
194.0079651	0.43
195.2161255	0.21
206.8468170	0.06
209.0899048	0.06
273.3146667	0.03
289.1681519	0.09
291.0407104	0.02
293.5565186	0.05
294.4345093	0.13
327.1406860	0.05
340.6773376	0.07
350.7221375	0.23
351.4000244	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1509
Annotation	kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
167.1026764	0.08
168.9789581	0.03
173.0501404	0.02
174.8467102	0.02
181.9139557	0.16
183.2983398	0.04
183.9189758	0.04
184.9581604	0.34
187.0344849	0.38
189.0325623	0.27
191.9354553	0.04
194.8928986	0.29
196.2061768	0.11
196.9649048	0.31
198.2205048	0.08
199.0314178	0.60
201.228302	0.06
208.1641846	0.13
209.9225922	0.04
211.1609497	0.96
212.2576752	0.07
213.0908966	0.57
214.1970062	0.02
215.1195068	0.15
215.7405396	0.04
217.3908081	0.12
219.1687317	0.11
223.1408234	0.18
223.901123	0.04
227.0395813	0.68
229.1324463	1.85
231.1699982	0.02
237.2116089	0.04
239.1599884	1.28
240.2555695	0.13
241.1340637	1.01
243.1199341	0.16
255.0700989	2.03
256.1425476	0.43
257.0668335	2.73
259.045166	0.04
267.1038208	1.14
268.4262085	0.02
269.2744141	0.08
270.0018005	0.02
271.2907715	0.05
273.2113037	0.05
275.4006348	0.03
282.986145	0.83
284.2866211	8.11
285.0388794	100.00
286.0903931	1.01
287.2075195	0.08
293.2889709	0.07
297.5014038	0.14
298.1337891	0.03
298.9210205	0.18
301.1546021	0.05
309.034668	0.03
310.0259094	0.05
325.3497314	0.04
326.0736694	0.05
327.2008057	3.30
328.3812256	0.20
339.1386108	0.05
351.640686	0.03
352.2752075	0.03
355.0258789	0.05
357.2441406	0.96
358.0615234	0.03
365.9580078	0.08
369.2784424	0.05
381.3999634	0.03
385.2728271	0.32
393.2571411	0.03
401.0516968	0.04
429.1465454	0.06
430.4476318	0.03
447.232666	0.89
448.421875	0.36
449.5460205	0.04
463.2055664	0.04
471.4908447	0.31
472.7387695	0.04
487.3648071	0.04
497.3412476	0.03
501.9384766	0.08
525.5178223	0.02
547.1868896	0.62
554.2045898	0.04
555.0098267	0.05
556.8894653	0.09
558.3654175	0.05
565.413269	0.23
575.2000122	0.38
583.0580444	0.11
583.7338867	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	698.8371
Annotation	Unknow
Peak:m/z	Relative Intensity
225.2153320	0.06
307.0133972	0.07
329.1090698	0.04
345.2045288	0.07
352.2840576	0.20
437.1867676	0.13
438.2567139	0.08
461.8680420	0.67
471.2344971	0.12
491.2028809	0.13
501.6173096	0.06
502.9617310	0.30
509.2510376	0.10
518.5383911	0.04
519.6119385	0.19
531.1569824	0.07
532.8832397	0.12
537.2221069	0.67
554.3109131	0.18
556.7800903	0.27
578.3713379	0.13
603.2100220	0.15
609.4848022	0.15
611.4896851	0.04
612.3912964	0.10
615.6098633	0.16
618.6904907	0.26
622.4568481	0.16
633.1139526	8.70
634.0264282	0.84
634.9440308	0.26
638.8644409	0.09
651.4448853	0.49
653.1719360	0.30
655.0731812	58.20
656.0228882	3.13
659.3853149	0.17
661.2361450	0.72
662.4004517	0.57
663.1915894	0.45
664.0504761	0.34
667.9484253	1.87
668.9512329	0.05
669.6948853	0.18
671.1771851	0.24
677.0393677	100.00
678.0394897	7.57
679.4011230	0.09
680.4962769	1.77
681.3466187	0.27
689.8833008	0.49
698.8513184	0.31
699.6922607	0.18
777.3810425	0.15
795.6044312	0.12
797.2837524	0.13
839.6351318	0.12
928.5488281	0.08
1077.5523680	0.23
1091.5856930	0.08
1106.4549560	0.06
1149.1760250	0.10
1193.6254880	0.46
1194.5878910	0.14
1195.7922360	0.18
1237.6756590	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	369.1173
Annotation	3-O-Feruloylquinic acid
Peak:m/z	Relative Intensity
116.9092255	0.22
133.9719391	0.04
144.9207458	4.49
149.1517029	0.10
176.9796753	100.00
194.0603485	0.30
195.3416443	0.08
200.7621460	0.02
241.8427124	0.02
270.0461731	0.04
323.3157043	0.02
327.1776428	0.05
333.3493347	0.06
340.7419739	0.03
350.1798401	0.12
351.0773621	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1109.2965
Annotation	Peonidin 3-[6''-(4-glucosylcaffeyl)sophoroside]-5-glucoside
Peak:m/z	Relative Intensity
315.4201050	0.09
316.1899414	0.03
323.3009644	0.06
324.1982117	0.11
343.0441284	0.21
344.1450500	0.07
345.4134521	0.05
446.2681885	0.02
463.1663513	1.26
464.2584839	1.06
465.4263306	0.08
477.0121460	0.04
478.3052063	0.02
487.4744263	0.04
489.3799744	0.05
490.3754272	0.03
518.1319580	0.06
518.9489746	0.03
609.3139648	3.31
610.2958984	3.87
611.3225098	0.79
621.2354736	0.05
622.4603882	0.07
623.8609619	0.27
631.2308350	0.08
637.8012695	0.06
639.2206421	12.01
640.2629395	18.82
641.2613525	2.88
641.8727417	0.18
651.2263794	0.07
652.4455566	0.18
664.1336670	0.05
680.2123413	0.01
681.3330078	0.28
682.3588867	0.44
683.4645996	0.04
703.4826660	0.05
753.1939697	0.07
771.2474976	1.19
772.2597656	1.27
773.2800293	0.32
785.4770508	0.22
786.4063110	0.10
801.2066040	3.12
802.2055664	8.53
803.2105103	1.61
803.8363647	0.01
871.3966064	0.03
890.3027344	0.03
947.5119629	30.11
948.2697754	100.00
949.2739258	23.85
949.9345703	0.17
989.2615967	0.05
990.2852783	0.04
1019.2674560	0.05
1024.6594240	0.01
1042.2980960	0.02
1081.6491700	0.01
1092.7805180	0.09
1093.6988530	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.1613
Annotation	Stereospermoside
Peak:m/z	Relative Intensity
149.9332428	0.17
151.1917419	0.19
152.0212402	0.05
165.1318359	0.32
167.1064758	2.91
180.9617615	0.10
191.0089722	0.13
195.0839233	1.54
209.2334747	0.04
223.9128571	0.06
225.3583679	0.05
239.3113403	0.04
242.9995728	0.09
244.2788086	0.13
254.3005066	0.04
260.6712036	0.09
278.0495605	0.04
280.2947388	0.05
281.2166748	0.22
301.2709351	0.14
305.2833252	0.11
313.1917114	0.34
315.1689453	9.70
324.1161499	0.05
328.3015747	0.04
329.1045532	0.21
344.0314941	0.10
345.2879639	2.34
357.2976685	0.22
359.3446045	0.40
363.1112061	100.00
383.3134766	0.08
387.2688599	0.08
395.4694214	0.04
402.3044434	0.17
404.1972656	0.17
404.9608154	0.47
410.2239380	0.05
417.0874634	0.33
419.1751709	0.04
425.2078857	0.24
427.2495117	0.05
435.0629883	0.08
437.3370972	0.07
445.2830811	0.06
448.0350952	0.17
462.5286865	0.38
463.5281982	0.16
464.9299316	0.15
471.2791138	0.06
477.9469604	0.10
479.0747070	0.19
480.9301147	0.57
481.6891479	0.08
482.6135864	0.06
483.3190308	0.07
484.6755371	0.31
486.8793335	0.05
488.2804565	0.28
489.2758179	0.43
494.3663330	0.24
495.0741577	0.08
504.3518066	0.15
506.2893677	2.12
507.3069458	1.29
509.9640503	0.42
515.8428345	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.11
Annotation	Anthocerodiazonin
Peak:m/z	Relative Intensity
121.9818420	1.94
135.0197296	0.32
158.9697266	0.11
178.9334106	0.39
191.1636505	0.93
217.2418213	0.43
247.3750916	0.07
253.1537170	0.08
255.3023987	0.05
256.9794922	0.10
260.2885437	0.09
262.7915344	0.07
265.2827759	0.11
275.0908813	0.22
280.1812134	0.42
289.4082642	0.07
291.0537109	0.20
292.9025574	0.08
294.3163757	0.06
303.1681519	0.06
306.1058350	0.24
307.1360779	0.57
309.1473999	100.00
309.9326782	0.39
315.1379700	0.07
316.2555542	0.10
317.1719971	0.20
318.0804443	0.08
322.1490173	0.06
325.4257202	0.09
327.1984863	0.24
332.1046143	0.13
333.3208618	0.21
335.1889343	0.39
337.1042480	0.08
338.0620117	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	439.0855
Annotation	9,10-dibromo-stearic acid
Peak:m/z	Relative Intensity
160.7439880	0.99
259.0330200	96.29
277.0160522	33.84
280.9588928	1.87
313.2697144	7.85
341.2225647	100.00
421.2384338	65.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	589.0526
Annotation	Unknow
Peak:m/z	Relative Intensity
175.3256989	0.15
181.0557861	0.23
191.1899261	0.67
216.9708252	0.56
241.1660767	0.19
252.9595184	0.12
258.3649597	2.76
259.0286865	22.47
276.9679871	17.22
291.2604370	0.20
293.4767761	0.24
294.9207764	27.37
295.5247803	0.71
296.9182739	0.12
305.1383057	1.76
313.0813599	0.16
315.2836914	0.18
317.4077454	0.12
319.0016785	4.55
329.0233765	0.38
336.1458130	0.18
341.0678711	0.30
342.2556763	0.13
347.0941772	0.29
348.9536133	0.47
353.4045410	1.23
359.2264404	0.55
361.3854980	0.13
366.8858643	1.47
384.6690063	4.25
385.3972778	0.63
397.1301270	0.56
398.1094360	0.34
402.9868164	6.06
410.3046875	0.12
411.2661743	0.15
421.1572876	1.69
426.1704712	0.79
431.9816895	0.99
433.9671021	0.70
442.3119507	0.40
446.4255981	0.81
448.3665771	0.37
450.0243530	0.25
456.0124512	0.70
458.0233765	0.81
459.3450317	0.18
462.7312012	0.10
472.2893066	1.25
490.8597412	0.33
492.5742798	0.44
496.3151245	0.37
497.1795044	0.42
511.4644165	0.95
512.4465942	0.52
514.0765381	0.29
517.2010498	0.88
525.2167969	0.28
529.3876343	0.95
534.9298096	17.13
535.7871094	0.84
537.1041870	0.42
539.7992554	0.34
542.6080322	0.49
545.2640381	0.11
549.0802612	0.33
550.8807373	0.35
552.7930298	55.52
553.6989136	0.73
556.1647339	0.33
559.7110596	1.01
570.9942017	100.00
571.9173584	0.27
572.5231323	0.52
576.4995117	1.19
579.6713257	0.46
580.8931274	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	784.3787
Annotation	Unknow
Peak:m/z	Relative Intensity
283.1554565	0.49
298.0859070	0.06
306.1063232	0.16
308.1987305	0.18
313.2528076	0.10
314.4413452	0.10
346.2766724	0.55
378.2095337	0.04
380.1918335	0.36
385.1090088	0.04
398.4804077	0.08
399.5227051	0.09
403.3165283	0.08
410.3518677	0.67
428.2377930	1.77
429.0994263	0.21
437.1660156	0.87
441.7694702	0.09
450.3965454	0.24
462.9727173	0.06
482.3016357	0.11
487.8662720	0.59
496.8630371	0.94
498.0095215	0.42
512.2158203	0.08
528.4726562	0.12
534.3817139	0.17
538.4971313	0.23
539.4636841	0.16
545.9304199	0.36
546.9877319	0.10
547.8972168	0.13
553.4679565	0.28
554.5615845	0.05
555.2794189	0.06
565.6109009	0.10
576.1183472	0.13
577.7244263	0.29
578.7415161	0.12
581.6911621	0.07
587.0337524	0.20
596.2053223	0.54
601.9347534	3.12
603.0018921	0.11
603.6063232	0.11
611.1033325	8.06
620.4921265	0.06
621.4948730	0.39
626.0951538	0.05
639.1260986	0.07
652.3662109	0.08
654.6864624	0.15
659.6535645	0.56
662.3610840	0.36
669.7485352	0.39
672.5397339	0.06
674.6148071	0.26
675.5438843	0.06
678.4790649	0.04
679.3227539	0.06
681.5073853	1.54
683.9226074	0.81
687.2962036	0.10
688.5557251	0.23
690.4860840	0.14
691.4644165	0.38
694.3755493	0.12
695.8992310	0.60
696.9121094	1.31
701.9882202	1.49
702.7115479	0.10
703.5834961	0.06
705.1345825	8.22
709.4653320	1.48
710.9097900	4.13
711.5770874	2.29
712.5088501	0.94
718.2313232	2.16
718.9465942	0.07
720.9390869	0.14
722.9824219	1.03
724.0165405	0.14
726.9760132	10.83
727.6067505	3.51
728.8113403	0.15
729.5794678	0.08
730.6316528	0.05
731.9060669	2.87
732.5479736	2.11
738.5203247	2.38
739.5767822	0.38
740.6557617	0.65
741.7623291	0.03
744.5159302	2.81
745.1585693	0.37
746.0444946	0.61
747.4130249	7.12
748.0280762	3.26
750.4476929	0.38
751.6797485	0.98
752.3064575	0.17
753.6693726	37.78
754.5814819	2.42
755.2588501	0.13
756.0581665	0.25
757.5156860	0.14
760.4246826	4.39
761.0778198	2.85
762.5899048	100.00
763.7600098	0.43
764.6621704	0.23
765.4764404	0.69
766.6785278	11.64
767.5800171	0.23
768.4412842	0.29
769.4363403	11.34
770.0483398	4.14
775.3955688	9.07
776.0182495	0.88
777.7994995	0.27
816.8371582	0.05
818.5386353	0.07
883.8027954	0.08
979.1174927	0.29
980.0105591	0.08
994.4416504	0.17
1004.6704100	0.09
1018.8547360	0.05
1023.3193360	0.15
1035.3471680	0.08
1048.5051270	0.09
1049.5563960	0.10
1050.5356450	0.15
1054.9368900	0.05
1062.5506590	0.07
1066.4919430	0.13
1072.4362790	0.06
1078.5942380	2.28
1079.6054690	0.31
1086.4797360	0.09
1096.4201660	0.14
1104.6567380	0.08
1109.5478520	0.17
1111.7651370	0.41
1122.4857180	5.01
1123.5369870	1.65
1133.6549070	0.11
1139.4809570	0.04
1174.3658450	0.09
1180.8024900	0.13
1207.5922850	0.27
1208.3261720	0.10
1217.4531250	0.04
1220.7084960	0.25
1222.6242680	0.44
1232.8619380	0.13
1233.7117920	0.13
1251.7786870	0.29
1252.4676510	0.09
1278.5925290	0.05
1306.5963130	0.07
1308.3245850	0.13
1315.4630130	0.21
1332.5770260	0.09
1350.5533450	0.28
1351.5881350	0.11
1403.6903080	0.12
1419.2792970	0.05
1420.8026120	0.05
1422.6333010	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	589.2464
Annotation	Swietenin F
Peak:m/z	Relative Intensity
183.3365936	0.02
195.2992249	0.06
206.8740082	0.03
209.8101501	0.02
216.1387329	0.03
226.8413696	0.03
251.1782532	0.03
253.1236115	0.06
259.1314392	0.04
291.3667908	0.03
305.2037964	0.03
307.2239990	0.04
311.3324890	0.04
341.5206299	0.03
355.2423706	0.07
371.4070435	0.04
377.2779541	0.03
388.5631104	0.14
397.6687622	0.07
459.6324463	0.03
460.4530029	0.02
469.6333008	0.03
471.8114014	0.04
479.2083740	0.02
486.4214478	0.06
493.0933228	0.05
495.4501953	0.04
500.5324707	0.02
501.6573486	0.06
513.3717651	39.81
514.3467407	15.42
515.0243530	0.10
517.7914429	0.12
518.6298828	0.09
519.4707031	0.01
521.4838257	0.04
527.6161499	0.02
528.7154541	0.07
529.6366577	0.17
533.4782104	0.06
534.6406250	0.28
535.4844971	0.18
536.3795776	0.04
543.4725952	0.05
545.3562012	100.00
546.3833008	34.88
547.0144043	0.13
549.1635742	0.02
551.7492676	0.18
553.2474976	0.06
554.4139404	0.05
556.5872803	0.32
557.2711792	1.20
558.2681885	0.47
560.6985474	0.03
562.3842163	0.03
563.2457886	0.06
570.2313843	0.07
571.5221558	0.21
572.6071167	0.16
573.2164917	0.03
575.4478149	0.08
576.4345093	0.02
581.5299072	0.04
590.6324463	0.02
591.2715454	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1018.0374
Annotation	Unknow
Peak:m/z	Relative Intensity
299.2952271	0.11
375.9937134	0.08
377.3249817	0.37
394.3870239	0.37
403.3244019	0.11
412.2402344	0.08
460.1005859	0.08
480.5837402	0.15
494.2205811	0.09
504.3614807	0.17
523.2532959	0.22
541.1489258	0.51
547.7829590	0.06
549.4322510	0.05
555.1009521	0.44
558.8538208	0.07
621.5194092	0.63
628.3416138	0.15
653.9180908	0.44
660.0201416	0.09
667.5338135	0.39
675.4945679	0.22
677.5853271	0.14
679.2271729	0.08
680.3357544	0.12
689.7092285	0.26
704.2545166	0.09
711.2364502	0.30
719.3634033	0.17
732.7463989	0.15
738.2745361	0.86
741.1970215	1.27
744.5787964	0.62
745.9799805	0.19
748.0559692	0.08
753.5111084	0.41
755.0607910	0.64
763.5285645	0.20
769.2059326	0.14
771.6452026	0.11
777.7019653	0.45
780.5552979	0.39
790.5753174	1.07
791.8076172	0.11
793.1132812	0.34
796.5302734	0.52
799.9639893	0.32
802.2165527	0.27
804.5020752	0.08
807.1262207	1.12
811.9903564	0.16
813.6300049	0.16
815.6110840	0.14
824.1934814	0.24
826.5203857	0.08
828.7875977	0.08
830.6120605	0.26
834.0548096	0.95
837.3118896	0.20
839.1005859	0.32
839.7856445	0.08
842.5142822	1.70
844.0117188	0.11
847.7242432	0.47
855.5213623	0.75
857.6447754	0.10
858.4216309	0.34
862.8349609	0.06
870.5410156	0.59
871.4278564	0.14
874.6232910	0.29
879.7231445	0.85
883.2130127	1.77
885.5228271	0.22
888.6452637	1.56
889.3724365	0.37
890.2239990	0.21
891.6398926	0.71
892.6787109	1.08
893.4547119	0.39
896.9805908	0.14
901.6860352	1.10
906.9436035	0.40
915.1448975	0.94
919.0012207	0.09
924.0593262	3.00
929.0250244	1.09
938.9224854	0.23
951.2669678	1.41
955.9304199	1.55
959.6005859	1.39
962.5839844	0.07
964.7702637	3.39
966.0942383	0.20
973.6398926	7.84
974.3680420	0.31
975.1179199	0.15
977.0356445	0.40
981.8952637	0.14
983.3033447	0.13
984.6623535	0.11
992.5551758	0.08
994.0830078	0.77
999.6506348	0.21
1000.3099370	0.20
1002.5876460	0.07
1018.2775880	0.10
1042.7646480	0.08
1084.7807620	0.16
1125.8225100	0.28
1129.7307130	0.09
1138.3695070	0.26
1140.7919920	0.18
1141.6813960	0.21
1143.4816890	0.17
1146.7724610	0.07
1150.4785160	0.07
1191.1604000	0.15
1236.0722660	0.49
1254.6027830	0.25
1257.6861570	0.08
1271.6541750	0.16
1279.3812260	0.36
1279.9838870	0.24
1280.9057620	0.48
1290.7114260	0.04
1298.8448490	0.91
1300.3040770	0.10
1306.7896730	0.10
1307.7860110	0.37
1319.0025630	0.24
1319.9074710	0.06
1356.1049800	0.27
1360.9227290	0.08
1370.8469240	0.66
1375.2460940	0.36
1386.2543950	0.28
1389.0515140	0.11
1397.8553470	0.17
1399.7352290	0.90
1406.1071780	0.75
1435.8953860	0.05
1470.6069340	0.94
1471.4022220	0.29
1502.9890140	0.43
1541.9162600	0.47
1542.8934330	0.05
1579.8746340	0.10
1613.1915280	0.76
1614.2181400	0.12
1631.8741460	0.35
1642.1921390	0.20
1667.3079830	0.08
1707.2570800	0.08
1755.8752440	0.31
1780.2803960	0.07
1793.5081790	1.49
1831.6226810	0.52
1842.1672360	20.37
1854.4401860	1.24
1859.2156980	0.08
1862.6744380	1.41
1876.5528560	14.98
1882.5545650	0.14
1892.4906010	0.78
1899.3184810	0.14
1904.5032960	0.25
1906.8551030	0.08
1907.9263920	3.59
1911.2780760	0.08
1915.6356200	0.16
1923.5148930	6.39
1925.9407960	1.15
1931.0982670	2.14
1933.5220950	0.60
1945.7030030	0.20
1946.6463620	0.68
1947.7008060	1.40
1948.9191890	0.06
1951.9595950	15.70
1959.8371580	0.05
1961.3332520	1.93
1965.8616940	0.17
1967.7425540	1.45
1970.5026860	0.05
1983.4274900	0.12
1985.6737060	2.37
1987.5905760	0.06
1991.9674070	0.31
1992.6229250	0.73
1993.2701420	2.80
1993.9022220	2.66
1994.7640380	0.06
1998.7969970	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	166.0858
Annotation	Gentiatibetine
Peak:m/z	Relative Intensity
92.9851685	0.07
120.0265045	100.00
130.9160767	0.24
143.0339355	0.03
148.0654449	1.48
148.8880768	8.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	463.11
Annotation	Farnesyl triphosphate
Peak:m/z	Relative Intensity
139.8283844	0.05
151.1335144	0.16
153.0950317	0.35
157.0236664	0.19
160.9659271	0.12
175.1348724	0.09
183.0999451	0.16
184.6839905	0.11
187.8762512	0.16
201.2140961	0.25
209.9647522	0.14
216.9131622	0.18
220.2435760	0.17
222.2485657	0.08
226.1380615	0.51
229.0101624	0.09
233.1398315	0.22
237.8882446	0.25
239.9622803	0.62
241.0433044	0.13
242.3200378	0.09
243.3692322	0.09
247.1736145	0.65
248.1947937	0.57
253.2907104	0.13
254.2583313	0.13
259.1093140	0.23
260.1314697	0.10
264.0407715	0.41
266.1797485	0.42
270.6976624	0.49
272.2279053	0.12
274.8879089	1.16
275.5775452	0.10
279.1150818	0.78
284.4620361	0.15
288.1281738	0.07
289.2598572	0.10
290.1688843	0.30
290.9722290	0.05
292.6575623	0.48
293.2644653	0.33
294.3231201	0.17
298.9567261	0.12
302.2326660	0.38
302.9984741	0.09
307.1552124	17.23
308.1201782	1.52
309.1339111	1.01
310.9576721	4.02
311.6177673	0.30
314.1668091	0.31
315.2181396	0.12
316.1079712	0.19
323.2308960	0.27
328.9490051	0.11
330.3658752	0.05
331.4694824	0.53
332.1658325	0.50
333.2700195	0.09
339.1605225	2.45
339.8538208	0.08
341.1577148	0.34
343.1820679	0.21
344.6263123	0.12
350.1878052	0.16
351.6660156	0.39
356.3606567	0.62
357.3309937	0.61
358.2424622	0.22
359.2198486	0.20
361.4143066	0.18
366.3986206	0.31
370.3772583	0.53
371.6675110	0.28
372.8930969	1.08
373.7704163	0.64
375.9798889	0.09
377.1919250	0.26
380.2654419	0.14
382.1584167	100.00
382.7716675	9.28
384.1341553	0.46
385.2892151	0.31
388.2313232	0.09
389.1678162	0.09
390.9915466	0.68
391.6881409	0.95
393.2746887	0.34
397.2298279	0.21
398.5550232	0.16
399.6211853	0.33
401.5765991	0.25
403.2515564	4.64
406.0634155	0.57
407.2401123	0.25
409.0851135	1.28
411.3900452	0.41
413.2891235	0.10
414.2089539	0.75
415.6310730	0.83
416.4330139	0.38
418.1388245	10.54
418.8345337	3.11
421.2949829	0.12
422.6258240	10.29
423.4203796	0.22
424.6147766	0.65
426.1209412	0.96
426.9360657	1.33
427.8206482	0.81
431.5356140	0.46
432.2544861	0.22
433.3215027	60.71
434.2519226	0.30
435.2864075	0.36
436.5840759	7.70
437.2574463	1.49
438.2728577	0.22
439.7546387	0.87
441.1440735	2.16
442.8461914	0.70
444.2124329	4.15
445.4129944	48.08
446.3034973	4.59
448.4319153	8.27
449.2829895	1.55
450.1133118	1.27
450.8556213	0.88
454.1601868	53.74
454.8476257	18.94
457.0470276	0.10
457.7398376	1.20
469.3210144	0.42
470.7422485	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
82.87450409	0.32
131.7472382	0.23
140.8029633	0.34
143.1371155	0.99
149.0728455	1.27
150.0868073	0.30
152.9488068	0.34
160.6850281	0.32
165.1462097	0.55
179.0180969	2.43
181.1409149	0.67
182.3461304	0.36
182.9718323	0.94
185.019043	0.47
193.1295929	1.08
195.0794067	0.84
206.2836761	1.75
207.0745087	11.27
208.0320892	7.89
208.985733	1.04
212.9035797	0.34
214.8665771	4.27
218.8495941	0.85
220.9278717	0.76
222.1695099	5.80
223.0552673	8.02
224.0167236	1.23
233.2349091	0.27
236.3604889	0.32
251.0680084	100.00
252.0976105	17.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.2026
Annotation	Acetylchapliatrin
Peak:m/z	Relative Intensity
148.7038879	0.08
161.1004944	0.31
167.2362061	0.05
182.0612030	0.08
197.1135254	0.05
233.0531921	0.11
245.1550751	0.14
251.2803650	0.09
262.3416748	0.16
277.2171631	0.14
289.0574951	0.18
295.0665894	0.23
304.2728271	0.07
315.2421265	0.12
324.1606445	0.12
325.1826782	0.05
327.2902832	0.03
329.1908569	100.00
332.0159302	0.09
341.3952637	0.31
343.2457275	0.08
347.4609375	0.07
354.9873047	0.19
358.9810791	61.54
359.7069702	0.87
368.2886963	0.11
371.2391357	0.15
375.1917725	0.07
376.1586304	0.67
377.3291626	0.24
389.2740479	0.50
390.1871338	0.32
391.4323120	0.93
395.4687500	0.05
399.3958130	0.20
401.1392212	1.10
403.3735352	0.18
405.4495850	0.05
419.0486450	0.49
422.0100708	0.05
424.8032227	0.14
429.8415527	0.25
431.2197266	0.38
433.3849487	0.77
434.2668457	0.89
435.2039185	1.11
441.4403687	0.17
448.1439209	0.23
457.0493774	0.17
459.4221191	0.05
461.3615723	0.98
463.1517334	0.09
475.2149658	8.01
476.3345947	1.33
477.2914429	0.74
485.1420898	0.60
486.1166382	0.30
491.1653442	0.35
492.2255249	0.07
502.3534546	0.18
503.2416382	1.71
503.8443604	0.03
504.7399902	0.75
505.3572998	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	535.037
Annotation	UDP-D-Xylose
Peak:m/z	Relative Intensity
192.6303101	0.07
211.0826416	2.29
261.8928528	0.11
273.1026001	0.19
280.1476440	1.05
290.9328918	0.25
293.1732178	0.04
305.2141113	0.22
308.8539429	0.17
323.0921021	100.00
359.3703613	0.09
385.0565796	2.52
390.8588257	0.06
396.1339111	0.04
403.1510620	2.41
422.8966675	0.09
436.2538452	0.02
437.2572021	0.47
450.8809204	0.09
489.0259399	0.09
491.9667358	0.06
517.2265625	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	267.01
Annotation	Unknow
Peak:m/z	Relative Intensity
71.4853363	0.04
123.8740997	0.06
181.1046600	0.02
220.8291473	0.02
221.7686768	0.13
223.0004120	0.07
223.7961884	0.08
225.8283997	100.00
228.7281036	0.04
243.1223755	2.13
243.7905884	13.61
246.2389984	0.03
248.9423981	0.03
257.9802246	0.24
258.6243896	0.10
266.9131470	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.0265
Annotation	Unknow
Peak:m/z	Relative Intensity
101.0899506	0.21
104.9276428	10.97
113.0116577	2.99
115.0351410	0.66
117.1767426	0.52
118.8576889	0.83
125.1248169	0.08
126.8691940	1.47
128.9787598	0.48
130.9603271	0.35
133.1638031	0.16
134.7620697	0.17
139.0114136	0.89
143.0340271	0.84
145.0549622	2.16
146.9460907	1.05
148.8685913	56.01
151.2843323	0.13
152.9041443	0.11
154.9636536	0.67
156.9941101	1.64
158.9414368	0.86
161.0549927	4.43
162.9871216	11.39
165.0798187	0.09
167.0765686	0.15
175.0086060	22.83
177.9664307	0.36
179.0056915	4.26
182.9734650	0.14
186.9491730	0.92
191.0106506	6.19
193.0664673	0.90
198.9869690	0.14
202.9524078	0.18
205.1217041	1.86
213.0354004	0.09
215.0966187	0.53
216.9845886	0.20
220.9106750	26.60
223.0677490	0.33
227.2810669	0.08
233.1917419	0.34
235.1043091	0.08
238.4914551	0.13
240.1003418	0.22
242.7104492	0.19
244.8954773	0.24
247.0796509	2.09
250.9097900	13.24
251.5258789	0.05
265.0903320	100.00
267.0462646	1.28
277.1090088	15.65
280.6453857	0.35
295.0121155	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.2078
Annotation	1-Octen-3-yl primeveroside
Peak:m/z	Relative Intensity
121.2756348	0.13
124.9974594	3.34
125.9053574	0.68
127.1237259	0.25
129.0247345	0.27
130.8947449	14.30
132.0028076	0.88
137.0061340	0.46
138.1327209	0.09
138.9333801	0.87
140.0230408	0.11
142.9715118	2.64
143.9204712	0.34
145.0388336	0.15
148.9115601	17.53
149.9733582	0.66
151.2608490	0.21
155.0587463	0.35
158.8681641	3.04
160.0001068	0.60
161.0809937	22.51
161.9909058	1.12
167.1655426	0.44
173.1445312	0.27
174.2977295	0.32
178.2232666	0.14
178.9327087	0.21
184.7803955	0.76
185.8739319	0.09
187.0645752	0.34
191.1166687	10.19
191.9848633	0.86
193.2141418	0.33
201.1298523	0.20
203.1856384	1.01
211.2254791	0.49
211.9929504	0.11
214.9802551	2.13
216.1945648	0.31
221.3605347	0.24
223.1569214	0.26
232.4049988	0.76
233.1256409	7.61
234.0796204	0.40
245.0382080	0.11
248.8059387	0.23
257.1963196	0.25
267.8873596	0.09
271.2670593	3.93
272.2281494	0.33
272.9640808	0.36
275.0606689	0.13
289.1282043	100.00
290.1376953	16.66
291.0544434	0.68
293.1032104	17.35
293.9643860	2.51
303.3344116	0.08
309.4372559	0.10
310.1624146	0.35
331.1314087	1.58
337.0207825	0.39
339.4216309	0.21
341.6573486	0.50
344.2550049	0.08
348.3206177	0.17
357.2212219	0.09
358.2864380	0.34
359.1415405	0.11
359.9782104	0.33
365.2560730	0.17
375.5749207	0.16
376.3730164	0.22
377.9353333	0.15
379.3340149	0.08
385.3868713	0.51
386.2217102	2.11
388.8528137	0.15
403.3825989	0.37
404.1789551	0.41
405.2062073	0.12
407.0439758	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
94.95879364	0.98
114.0856323	1.58
166.7598724	2.64
181.0444183	1.11
185.3774414	1.33
186.9897919	1.89
195.2695007	5.22
196.7032623	1.98
211.2278137	1.98
212.9112854	4.30
217.3909302	5.83
227.0660095	4.41
233.3305969	7.35
234.9664917	1.21
235.6243591	2.21
247.5935059	1.55
253.3493347	6.05
264.8647766	3.30
267.0805664	3.10
268.1065063	2.97
275.2125854	6.28
283.2629395	4.63
293.2054443	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1156.572
Annotation	Unknow
Peak:m/z	Relative Intensity
715.5439453	0.42
786.2236328	1.22
831.9888916	2.14
844.3215332	0.96
877.9644775	1.26
959.4171143	0.60
979.5079346	0.40
1073.1488040	0.80
1109.4915770	1.37
1158.8815920	1.29
1180.4812010	2.11
1312.6564940	1.09
1313.5568850	1.42
1317.3315430	0.31
1318.3172610	1.17
1321.3731690	0.31
1511.0965580	1.71
1609.7967530	0.68
1630.6126710	0.34
1761.5311280	0.50
1806.0264890	0.63
1835.0388180	17.28
1837.0543210	0.26
1846.9377440	3.86
1848.5778810	20.44
1862.3746340	1.34
1863.7600100	1.11
1868.3371580	0.26
1869.8157960	10.55
1878.8063960	3.85
1903.2235110	43.10
1909.5006100	0.85
1912.8420410	12.99
1915.5494380	5.44
1919.5427250	7.93
1923.4537350	1.74
1924.5954590	0.20
1925.8635250	2.08
1936.2976070	0.36
1941.2825930	8.40
1942.7288820	3.10
1946.7508540	0.31
1949.9302980	1.20
1958.7072750	6.51
1967.2513430	0.62
1969.0423580	0.63
1969.7127690	0.34
1971.5699460	64.13
1975.2652590	2.75
1977.4813230	16.43
1978.4870610	0.34
1979.6101070	1.76
1980.9436040	10.33
1983.4031980	16.84
1987.0700680	0.60
1992.2370610	0.84
1992.8834230	7.66
1996.0656740	0.31
1997.0935060	0.98
1998.0448000	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	373.1276
Annotation	Glycosmisic acid
Peak:m/z	Relative Intensity
126.8987122	0.58
130.7774963	0.46
136.8594666	7.42
140.7541809	1.38
166.1693268	2.48
167.0405273	0.50
201.2640991	2.20
207.0971680	2.73
218.8991089	15.97
225.3532715	1.65
231.1423035	1.01
238.9554138	0.92
241.8472595	3.40
284.0992737	1.55
302.1719666	1.47
306.8053894	1.18
311.3202820	0.54
312.1744385	0.88
313.2592773	0.93
319.3937988	0.81
321.5673523	0.86
322.9277344	1.21
325.1251221	10.28
326.9443359	3.19
330.1702881	1.93
331.2789307	1.78
336.0682068	1.66
337.1793823	1.28
342.4699097	4.46
343.1097107	72.69
355.1885986	100.00
359.4857483	0.91
363.6064148	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	612.64
Annotation	Unknow
Peak:m/z	Relative Intensity
268.7524719	0.12
307.4945068	0.06
355.5303955	0.04
356.4979858	0.22
383.3129272	0.09
385.0575562	0.50
450.7891235	0.03
452.8984985	0.52
454.0492554	0.06
454.9758301	0.34
459.4000854	0.14
469.6171875	0.23
483.2537231	0.11
496.1905518	1.62
497.1537476	0.32
498.0364990	1.71
499.0480957	1.69
499.7033081	0.16
508.2240601	0.08
510.0679321	0.18
511.7266235	0.05
513.7345581	0.20
515.0272827	0.42
516.3800659	0.38
522.6273804	0.08
524.8147583	0.41
525.7269287	0.08
532.9760742	0.04
537.0309448	0.20
537.9130249	3.10
539.0191650	2.06
539.9867554	0.18
542.7729492	0.06
546.8256226	0.21
555.9050903	0.68
556.9687500	0.14
565.8745117	81.89
566.9162598	100.00
567.9371948	0.45
568.6243286	0.15
570.8679199	0.06
581.5037231	0.94
582.5850220	4.99
583.3831177	22.75
584.3423462	27.03
585.8418579	0.80
586.9080200	0.45
587.8692627	0.04
589.5988770	0.08
593.8858643	0.07
597.9595337	0.05
606.5071411	0.62
607.7581177	0.42
612.0355835	1.03
612.8402710	0.12
619.0211792	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	277.12
Annotation	Pantetheine
Peak:m/z	Relative Intensity
86.9618225	1.99
99.0113907	0.34
113.0604401	0.94
114.6816788	0.10
116.0182800	0.62
119.0655365	0.20
125.9141235	0.71
127.0066376	0.94
127.9371948	0.52
129.3070374	1.03
130.0081482	9.25
130.9101257	0.23
139.2751770	0.10
142.9784088	0.18
144.2403564	0.63
145.1250763	4.25
146.0044556	55.22
146.9920502	24.94
153.0581512	0.13
171.1139221	0.37
174.4844513	0.06
180.9958496	0.18
186.9703979	0.77
191.0769958	0.08
195.1081543	0.32
197.1788025	0.30
199.0874023	0.35
200.0107727	1.10
203.0992432	0.20
206.0143127	0.11
208.9259644	0.21
213.1740417	61.19
214.7821045	0.24
217.0776367	100.00
219.0408630	0.19
225.0288696	4.03
231.0213013	56.58
233.1372986	0.16
233.8473816	0.08
241.3492126	0.50
243.1391907	38.15
245.2552185	0.07
258.9773560	23.26
260.0823975	1.28
277.5209961	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	440.2482
Annotation	1-Octen-3-yl primeveroside
Peak:m/z	Relative Intensity
126.8787537	0.94
127.9152527	0.19
132.9617767	0.15
136.9067383	0.09
143.4732971	0.28
144.8391724	3.49
145.7458496	1.01
147.6021271	0.50
149.2345276	0.43
149.9891968	0.14
153.8710022	0.13
159.1062622	0.51
160.2467346	0.21
162.8098602	10.67
163.7956085	2.00
165.3313599	0.12
166.1054382	0.31
168.9925995	0.09
171.0324402	0.13
174.0683289	0.24
177.6477509	0.24
178.8760681	0.26
180.0799561	1.63
180.8778381	1.85
181.6201172	0.13
189.1318665	0.48
190.9201355	0.12
192.9857788	0.91
195.0535278	0.42
196.0419006	0.40
199.0658417	1.57
199.9180298	0.15
205.5322418	0.09
207.1280212	0.85
208.1638336	0.90
213.2744751	0.12
216.2947388	1.00
216.9130402	6.10
217.8960876	0.81
218.7926331	0.25
220.1855164	0.82
222.9476166	1.41
223.9243469	1.85
225.0344696	4.38
226.0361938	1.24
229.9631653	0.13
232.2298126	0.18
237.0358276	2.21
238.0615234	0.23
238.9668579	0.12
241.0122681	8.33
241.9069519	3.22
243.1000671	9.51
244.0219727	4.00
247.1070557	0.50
248.2641602	0.10
255.0169373	2.66
255.9338989	1.35
258.8517761	40.49
259.9620361	18.91
262.2830200	0.32
269.3167419	0.19
270.9539490	0.16
272.3415833	1.35
273.0159912	6.92
274.0987244	6.81
274.9240112	0.14
276.8903503	14.32
277.8887939	6.60
286.0975342	0.16
290.3877869	1.35
290.9999084	0.77
291.9453735	0.39
293.1956787	0.41
294.8350830	100.00
295.9932556	43.22
303.0953979	0.33
307.9624023	2.01
309.1149597	0.78
312.7500610	7.78
313.8278503	2.88
315.2117310	0.27
329.0249634	0.41
334.1076660	0.37
351.1386719	0.23
352.0117493	0.17
360.1171875	0.08
368.1102295	0.29
368.9335022	0.34
369.6544800	0.38
370.2786255	1.18
380.3220215	0.37
381.3899841	0.26
383.1080017	0.37
385.4786072	0.22
386.5886841	0.84
389.3181458	0.41
394.7254944	0.31
402.8740234	0.45
404.6802673	4.30
405.4230652	4.09
406.0921936	2.74
408.6119995	0.32
413.9665222	0.36
420.2137451	0.21
421.7540588	0.10
422.7349243	4.94
423.7016296	7.15
424.5662231	0.37
432.4749451	0.47
433.5935059	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	615.16
Annotation	Heme
Peak:m/z	Relative Intensity
183.1095734	0.50
201.9682617	0.23
203.1651001	0.15
212.4405212	0.55
225.9187164	1.33
226.5198059	0.14
227.3306274	0.10
229.1494751	1.57
230.3752747	0.89
231.1827698	0.25
240.2648926	0.09
243.1475220	0.22
247.0671082	1.73
248.0579224	0.86
248.9148865	0.82
250.1684723	0.50
263.0436707	0.17
265.0932922	0.30
272.2030029	0.53
275.1721191	0.44
289.1900635	0.21
290.1656494	1.29
291.1884155	0.53
292.2052002	0.48
302.3475342	0.19
307.1306152	100.00
308.1313171	61.05
309.1249695	51.03
309.7651978	0.16
331.3499756	0.12
332.1953125	0.08
336.9523315	0.38
343.2106323	0.47
348.2119141	0.15
350.1081543	0.13
352.9487915	0.10
356.4909668	0.34
368.3622437	0.18
373.3477173	0.07
384.4996338	0.35
387.1770630	0.19
400.1401978	0.09
417.3248901	0.21
451.7221680	0.53
453.1743774	0.36
457.1292725	0.13
458.0163574	0.35
459.3765869	0.52
461.3298340	0.20
462.3015747	0.11
469.1988525	0.44
482.4260864	0.49
484.3901367	0.14
485.3227539	0.13
500.2836914	0.45
505.4573975	0.43
511.3212280	0.16
516.3353271	0.31
525.0148315	0.99
526.0518188	0.12
529.0658569	0.19
534.4291382	0.27
537.2930298	0.45
538.9759521	0.08
540.7752075	0.23
543.7160034	0.95
549.6182861	0.24
550.7780151	0.13
552.9241333	0.37
554.6854248	0.33
555.4822998	0.10
569.0778198	0.20
570.5014038	0.14
571.8817139	0.51
578.2063599	0.08
582.3916016	0.40
583.5416870	0.76
584.2080688	0.13
589.4363403	0.18
596.2743530	0.77
597.2141113	0.97
599.4006958	0.62
605.4373169	0.25
606.3208618	0.17
606.9830322	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	360.21
Annotation	Unknow
Peak:m/z	Relative Intensity
116.1825638	0.05
117.5907593	0.03
132.0517273	1.50
168.9298401	0.06
171.7973480	0.05
175.6753235	0.04
183.0951233	0.46
187.3250275	0.32
188.9637604	0.20
191.2644348	0.04
197.0057220	0.06
201.1412048	14.14
205.1278687	0.09
206.7735596	0.08
212.1711121	0.22
226.7640686	0.33
228.9754639	100.00
229.5842590	0.15
232.5595093	0.09
242.9113464	0.22
247.1450500	0.71
251.0398560	0.09
261.1883850	0.09
272.1259155	0.30
278.9101562	0.17
293.0001221	0.52
296.0597229	0.19
297.2637329	0.57
301.1856995	0.04
305.2017517	0.06
306.1600952	0.06
307.1585693	0.96
311.1845398	0.32
313.1941833	0.07
314.6845093	0.27
316.2452393	0.19
316.8915100	0.07
324.3097229	1.13
324.9747314	6.00
326.8725281	0.05
328.2687378	0.14
331.2850037	0.10
342.0419617	14.13
343.0911560	1.25
346.1068115	0.05
347.1800537	0.16
350.1820374	0.06
350.8620911	0.21
351.8245239	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	532.2451
Annotation	Unknow
Peak:m/z	Relative Intensity
167.9210205	0.03
186.2095032	0.41
187.9911041	0.02
222.9753113	0.09
225.2508240	0.05
230.0885315	0.11
231.1315765	0.04
245.0023804	0.03
257.0972900	0.15
281.0733032	0.07
284.3619385	0.04
299.0219116	0.05
306.2617798	0.04
313.1118164	0.03
318.2858887	0.17
322.0237427	0.05
326.4293213	0.05
339.0786743	0.10
344.2109985	0.06
352.1768188	0.13
370.0623779	0.23
393.3973999	0.02
401.2849731	0.34
410.0472412	0.09
427.0548096	0.03
428.2081909	0.07
436.5126953	0.04
441.4130249	0.14
444.5245361	0.04
470.6559448	0.03
475.1015015	0.09
486.0441284	0.75
488.3041382	100.00
488.9609985	0.56
493.9522095	0.13
496.2760620	0.17
498.2897339	0.03
502.5360718	0.16
504.2570190	0.04
509.3188477	0.07
513.5946655	0.12
514.3899536	2.16
515.2803345	0.15
517.3831787	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	148.97
Annotation	Asparagusic acid
Peak:m/z	Relative Intensity
63.7767029	0.39
83.0343552	0.02
104.8540192	100.00
105.6287842	0.05
112.6899109	0.02
114.9028931	0.06
130.8295898	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	651.1566
Annotation	Tricin 7-rhamnosyl-(1->2)-galacturonide
Peak:m/z	Relative Intensity
191.0930023	0.06
203.8308411	0.02
221.2116699	0.15
227.0102234	0.10
233.2505798	0.03
239.3012238	0.07
240.0970459	0.10
245.1796570	0.04
255.1278992	0.44
262.7083435	0.05
271.1679993	1.71
273.2083740	0.61
283.0878906	0.38
287.1518555	0.08
297.1455688	0.79
300.0794373	5.16
301.1695557	28.09
301.8148193	0.07
307.1080933	0.31
309.1726379	0.05
315.0604248	0.20
325.3862305	0.04
337.1194458	0.31
343.1017456	1.19
344.1627197	0.17
348.2282104	0.13
349.1291504	0.16
352.2254028	0.04
355.3359985	0.46
357.2849731	0.18
358.1787720	0.05
366.4895630	0.03
372.8974609	0.04
410.5885620	0.06
418.2308350	0.05
422.4761353	0.05
447.1931152	0.17
451.5353394	0.06
453.7272339	0.03
457.3792725	0.09
459.2451782	0.11
460.9710083	0.13
463.2789917	2.20
470.6315918	0.04
471.3771362	0.12
488.5220337	0.17
489.3837891	0.31
490.9421387	0.16
499.1069336	0.08
507.5128784	0.06
513.5110474	0.03
515.0033569	0.07
518.5458374	0.11
527.3590698	0.06
531.2634888	0.08
536.4274292	0.10
547.2135010	0.10
549.1248779	0.10
558.5761719	0.03
564.4943237	0.09
566.2272949	0.04
570.2158813	0.13
573.2296753	0.41
574.2555542	0.13
587.0977783	0.11
588.8258667	0.04
591.3051758	5.21
604.8500977	0.30
606.4295044	0.21
607.3704834	0.18
609.2441406	100.00
610.2296753	1.05
612.5925903	0.03
615.0717773	0.04
620.4191895	0.39
621.0419312	0.12
625.2623901	0.09
630.0063477	0.18
633.2066040	0.57
635.4191284	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.2212
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
108.960556	0.75
121.0737228	1.51
123.0704041	0.95
124.9599152	1.49
126.6779022	0.57
135.3286438	0.70
137.141922	0.63
138.9815369	1.26
142.7888947	1.44
145.3180847	1.65
151.0774231	3.36
165.1865387	0.63
172.9329376	1.63
176.756134	0.93
180.1878052	0.81
183.002594	1.75
192.8022003	1.49
196.6247711	1.07
199.1369934	0.70
209.2342529	6.58
211.4646912	0.93
214.8995361	1.70
224.9893494	1.70
239.0621033	7.54
251.3546143	0.89
253.1733398	4.61
257.2359619	2.37
265.0205078	8.63
267.4326172	2.72
269.161438	1.31
270.1467285	2.14
275.1855469	20.86
283.3238831	2.05
284.0135193	0.57
293.2108154	100.00
294.2745361	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
98.88449097	0.61
100.8504562	0.57
112.9455414	0.53
124.1656418	0.84
124.8721085	0.35
126.9453964	0.32
129.034729	1.61
136.9519653	1.17
139.0091095	0.45
143.0963135	1.25
159.0259094	0.44
161.1701965	0.25
163.3187561	0.55
165.0339203	0.32
167.2368164	0.84
169.1075592	1.35
170.8920288	0.46
172.9286194	0.54
175.1542969	0.18
177.1004028	1.18
179.0674591	0.51
181.0932465	1.56
183.1394653	1.64
185.0084991	0.80
193.0805359	0.29
195.2694092	0.95
197.0904236	1.65
199.2818298	1.07
207.1882019	0.57
209.3606567	0.99
210.9942322	2.54
213.1904297	0.43
215.006012	0.53
216.7939758	0.35
218.9911804	0.46
221.2782593	0.37
223.2599792	0.69
225.194458	2.17
229.1834412	0.66
233.151947	0.71
235.1191711	1.35
237.2393494	1.58
238.991394	2.35
243.1715698	0.52
247.1134644	0.76
249.2845459	1.65
251.151123	1.66
253.0518799	9.82
255.2050476	1.20
257.2063293	1.27
264.2502441	0.34
265.271637	2.78
267.1619568	3.12
267.8658752	1.51
269.1957397	1.72
270.1403198	0.68
275.2633972	17.94
283.4084167	1.26
288.4593506	0.42
293.205658	100.00
294.2723389	0.98
302.3590088	1.29
310.4912109	3.57
311.5587158	0.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	457.0698
Annotation	Tjipanazole B
Peak:m/z	Relative Intensity
129.7656860	0.18
131.8183746	0.06
136.0346069	0.15
137.0255585	0.09
137.8295898	0.47
139.9340820	0.29
141.1657257	0.10
143.1707764	0.19
148.1123352	0.20
150.0073700	2.03
155.0437927	0.06
157.1679993	0.49
158.0767212	3.02
159.1978455	0.53
160.1225586	0.30
162.2215424	0.15
164.8870544	1.66
166.1191711	0.44
168.8769989	1.13
170.2265930	0.17
173.1945190	0.15
175.0852051	1.24
176.1058350	0.25
179.0793304	0.08
180.2008057	1.43
181.1892700	1.08
182.1082458	1.66
183.1065216	5.51
184.1028137	1.34
185.1932678	0.07
185.9360962	0.08
191.9628296	0.09
194.9928894	0.46
197.1913910	0.41
198.3345032	0.07
199.1765747	0.28
200.0294342	0.05
200.9324341	0.30
202.0411072	0.46
207.3075867	0.40
208.1458435	0.78
209.0819244	0.15
210.0311127	0.26
212.1777954	0.23
213.1252136	0.86
215.0874481	5.01
216.1370544	0.64
219.3525391	0.06
220.1281891	0.07
224.1880493	10.61
225.2842560	3.38
226.0910034	7.74
227.2262878	1.45
229.1202850	3.40
229.9867249	0.54
233.0606079	0.16
239.0888824	0.38
240.0971985	0.91
242.0829163	97.89
243.1682129	36.59
244.1388855	2.70
245.0574341	1.28
247.1112671	20.01
248.0484314	9.96
249.1080322	1.07
255.0821838	1.13
256.1965637	3.57
257.9338684	11.91
259.0887146	0.94
260.9051208	0.39
262.3076172	0.07
263.0628662	0.14
264.2011414	0.28
265.1988220	0.54
272.0597229	4.11
273.0565491	5.06
274.1135559	0.51
275.2083130	9.94
276.1206360	1.90
277.2980347	0.47
279.1521606	0.87
280.0586548	0.46
283.0303345	3.38
284.0299377	0.55
284.7442627	0.20
288.1173096	1.12
289.0465698	3.68
290.1453857	11.68
291.0786133	2.09
291.9747314	0.11
295.1049500	0.39
299.9778442	0.61
304.1076660	1.09
305.0368652	1.78
306.1388550	3.61
307.0923462	18.99
308.1293335	1.55
313.3850403	0.17
316.5797729	0.21
319.2572021	0.07
322.0793152	0.68
322.9205627	0.62
325.1201172	0.31
326.2790222	0.51
327.1908569	0.34
331.0844727	0.26
332.0794678	0.07
334.2474060	0.13
336.4539490	0.18
339.1562500	47.11
340.2120972	5.49
341.1651611	1.15
347.2710266	0.17
348.4461365	0.06
351.0349121	0.42
354.2852478	0.08
356.3796692	0.19
358.1997986	0.42
359.5394287	0.07
361.2825928	0.10
367.0728149	0.21
369.5845032	0.26
371.1943054	1.16
372.2470398	0.17
373.2245483	0.48
374.1725464	2.01
375.1768494	0.67
376.0356750	0.25
377.0957336	0.22
378.4934387	0.88
379.1485596	3.49
380.0750427	1.39
380.8676758	0.31
383.1315613	0.08
384.8431091	0.22
385.5723572	0.41
387.9953918	0.20
389.2376709	0.24
391.1850891	25.17
392.1783142	3.76
393.1325073	0.65
394.2685242	0.31
397.1002502	50.80
398.0861816	46.31
399.0870361	9.16
400.1096497	0.36
404.0486755	1.88
405.2507019	0.44
411.2454529	3.19
412.2149353	0.31
413.1809998	0.99
415.0926819	4.38
416.1460876	0.25
422.1065369	26.25
423.1311646	5.12
424.2509460	0.33
439.1189880	36.52
440.1304321	100.00
441.1112366	23.90
442.0625305	0.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	652.3537
Annotation	Unknow
Peak:m/z	Relative Intensity
206.7571411	0.07
231.0226898	0.11
231.9931488	0.13
239.3031006	0.07
249.2387238	0.17
250.3757172	0.13
255.1088715	0.29
281.1906738	0.67
282.1616821	0.09
299.3169250	0.56
300.2721252	0.10
301.3262634	0.25
302.2878418	0.13
309.1788330	0.06
312.3696289	0.09
315.2906494	0.39
318.1620483	0.08
321.3911133	0.06
326.3695984	0.16
340.0723877	0.08
346.4729004	0.07
368.4246216	0.09
370.9323730	0.07
372.2379150	0.07
379.4067993	0.16
393.3753052	0.17
398.0913696	0.07
426.2397461	0.41
427.2264404	0.10
436.2971802	0.53
439.4395752	0.25
447.2853394	0.05
450.9274292	0.13
454.3245850	0.17
473.5321045	0.12
477.3628540	0.10
479.1589966	0.10
487.8977661	3.65
488.5468750	1.31
489.9012451	0.16
490.5027466	0.09
493.5991211	0.21
494.3782959	0.55
496.3838501	0.30
502.8369751	1.16
503.4757690	1.14
504.2974243	0.06
507.9983521	0.30
509.6496582	0.09
510.5981445	0.52
511.2272339	0.28
516.6417236	0.13
523.1179810	0.07
531.3417969	0.55
532.2732544	0.91
533.0679321	0.31
537.8323975	0.13
539.7169189	0.41
544.4678955	0.15
545.1454468	0.06
549.3471680	18.86
550.3506470	6.35
551.3526001	0.37
552.4901123	0.10
554.4447632	21.07
555.4282227	3.06
556.0507812	0.26
558.4840088	0.13
560.4620972	0.13
564.1932983	0.14
567.4105225	0.13
572.7482300	0.26
574.2526245	0.10
584.2454834	0.14
589.4744873	0.47
591.2504272	0.08
592.2487183	1.19
593.5040283	0.14
596.6951904	0.06
602.4833984	0.09
606.2822266	0.22
609.2883911	0.07
610.2710571	0.80
611.4154053	0.24
614.7114258	0.06
615.4666138	0.62
616.4224243	0.39
617.2313232	0.24
618.2883911	0.09
619.2581177	0.36
620.7837524	0.08
621.7485962	0.17
623.0892944	0.11
628.4080200	0.23
629.5784302	0.15
631.3746338	0.18
632.1072388	0.13
633.3645630	1.01
634.4806519	1.38
635.4669800	0.10
637.6253052	100.00
638.6211548	0.33
643.6940918	4.71
645.5758667	0.21
658.5950928	0.07
659.7896118	0.09
661.6716919	0.10
667.6588745	0.36
685.6272583	0.18
690.6463013	0.05
702.3442383	1.25
703.5201416	0.38
711.5861206	0.24
714.6813965	0.33
715.5670776	0.58
719.5965576	1.59
720.6196899	0.42
731.3356323	0.09
732.2398071	1.29
732.9776611	0.06
736.0828247	0.13
737.4347534	9.08
738.4325562	2.14
740.7258911	0.15
754.5461426	2.06
755.5747681	0.42
772.4725342	2.18
773.8158569	0.75
782.5436401	0.09
831.3222046	0.21
909.5065308	0.21
959.4533081	0.08
988.4382935	0.09
989.7283325	0.09
1065.5026860	0.07
1088.5704350	0.18
1118.6376950	0.07
1174.1105960	0.08
1186.4982910	0.31
1189.6270750	0.11
1200.8072510	0.51
1201.6214600	0.59
1213.6611330	0.15
1230.5285640	0.23
1231.8977050	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.04
Annotation	Unknow
Peak:m/z	Relative Intensity
212.7654419	0.37
223.0527039	0.57
251.0490112	100.00
281.2658081	1.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	276.1184
Annotation	Glutamyl-Gamma-glutamate
Peak:m/z	Relative Intensity
83.9019775	0.78
85.3078003	0.02
101.0006714	0.49
101.9311905	0.09
129.9697266	22.98
132.9471436	0.06
146.9502869	100.00
162.2799530	0.05
199.1357422	0.10
213.0890808	0.56
215.2195740	0.04
228.0942383	0.15
229.6240845	0.06
240.1959839	0.36
241.1493835	0.75
258.0861511	1.27
259.1062012	3.73
266.6751404	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	755.2039
Annotation	Orientin 4'-O-glucoside-2''-O-rhamnoside
Peak:m/z	Relative Intensity
209.8126526	0.05
211.1378632	0.27
211.8876495	0.33
213.0890198	0.12
214.3354187	0.13
215.2968445	0.50
220.4332428	0.06
221.1427155	0.09
223.3454132	0.14
225.1682739	0.18
225.9584961	0.33
227.1809387	1.40
228.1293030	0.16
229.1503906	2.07
230.1141357	0.03
233.1800385	0.13
235.2782593	0.06
237.3243103	0.27
239.1424866	0.15
240.9084778	0.54
242.0899048	0.80
243.0605164	1.53
244.2315979	0.40
245.1949463	0.12
246.2187195	0.27
247.1660767	0.14
249.0192413	0.11
251.1473083	0.13
253.5081787	0.33
255.0424805	10.31
256.0988770	2.21
257.2179871	0.66
258.0556946	0.15
259.0842590	0.19
263.0115967	0.07
265.3060303	0.04
267.1139221	0.05
268.0999756	0.09
269.0509033	0.28
271.1431274	20.38
272.1340332	3.73
273.1478271	3.41
274.2048645	0.39
277.1863708	0.12
279.0001831	0.27
280.1067505	0.14
281.1202393	2.29
281.9571533	0.18
283.2034302	0.32
284.6626587	0.30
286.9583130	0.33
293.3140564	0.25
295.1167603	0.34
297.1596069	1.93
298.1710510	0.33
299.1423950	5.13
300.0884399	100.00
301.1101074	48.08
302.1824951	7.07
303.3001099	0.05
305.1594238	0.08
307.2111206	0.07
308.0399780	0.22
309.2260742	0.47
311.2225647	0.64
312.0701599	0.23
313.2646484	0.52
314.0694580	0.50
315.0178833	0.26
319.0668945	0.04
320.9750671	0.16
322.2261963	0.09
323.3208618	0.04
324.1142883	0.13
325.1669312	7.25
326.1144409	2.14
327.3081665	0.21
328.2646484	0.11
329.1005859	0.29
335.4410095	0.03
336.3136902	0.04
337.1517334	1.04
338.1494751	0.54
339.1346436	0.39
340.2730103	0.11
341.5422363	0.90
343.1049194	17.49
344.2390137	3.30
347.0581665	0.32
349.2019348	0.06
350.2474365	0.06
353.1697998	0.85
354.1621704	0.25
355.1424561	3.26
356.1683350	1.23
357.2072144	0.12
358.3820190	0.06
363.2210999	0.13
363.8911133	0.04
365.3151855	0.41
366.4237671	0.45
367.1732178	3.29
368.2105713	0.51
371.1875000	0.16
372.2827148	0.04
373.1056519	2.21
374.1738281	0.29
376.1604004	0.05
379.1446533	1.17
380.2936401	0.37
381.1881104	0.28
382.2392578	0.05
385.2330933	0.97
386.2379761	0.69
387.4884644	0.04
391.0941772	0.39
391.9942017	0.04
393.2218628	0.07
397.3873901	0.25
399.1388550	0.15
401.8059082	0.12
403.1160278	0.37
404.5421753	0.07
409.1474609	4.19
410.1730957	1.12
411.3961792	0.11
415.2055664	0.06
419.2167969	0.16
421.3577881	0.41
427.3702393	1.35
428.3621826	0.09
429.3596802	0.11
431.1008911	0.14
437.2487793	0.23
439.2226562	0.69
440.2539673	0.22
443.2825317	0.32
444.1494751	0.13
445.1402588	1.30
446.1215820	0.34
447.0635376	1.01
448.3663940	0.14
450.3242188	0.04
456.2072144	0.09
457.3308105	0.45
459.1855469	0.16
461.3635864	0.37
463.2755127	0.09
464.2564087	0.21
465.2232056	3.40
466.0097656	1.25
481.2149048	0.53
482.3431396	0.53
483.3779297	0.43
484.0953979	0.13
485.3540039	0.03
486.1383057	0.07
487.2052612	0.19
489.1611328	31.29
490.1864624	8.37
501.2246094	0.37
503.3209839	0.08
505.4141846	0.36
509.2208862	0.09
511.4596558	0.08
512.3582153	0.07
513.3751831	0.13
519.3480835	0.10
520.2270508	0.12
522.6899414	0.17
523.3810425	0.04
527.0380249	0.08
529.1350098	0.86
530.0694580	0.03
531.2256470	0.09
545.2101440	0.65
546.1649780	0.17
547.2401123	3.01
548.2219238	1.58
549.1730347	0.44
550.1467285	0.24
555.2692871	0.43
556.3479004	0.44
563.4036255	0.06
573.2435303	5.85
574.1897583	2.22
575.4152222	0.64
591.2172241	52.63
592.3106079	17.13
593.3693237	0.34
594.4342041	0.15
603.4016113	0.35
605.2371826	0.18
606.4234009	0.12
608.6167603	1.99
609.3194580	24.98
610.2770386	9.27
611.2285156	0.33
612.5087280	0.05
618.2786255	0.11
619.4523315	0.67
627.2177734	0.10
628.2606812	0.22
629.4345703	0.36
630.4505615	0.12
633.2174072	0.14
635.4644165	0.06
641.6390381	0.13
645.3479614	0.90
646.4420776	0.50
647.2106934	0.04
648.3158569	0.06
651.3995361	0.25
652.3795166	0.44
655.4036255	0.30
665.0455933	0.28
666.3155518	0.11
669.4304810	0.43
670.4402466	0.22
671.2180786	0.15
681.1032104	0.07
687.4782715	0.29
688.5237427	0.16
692.1950073	0.03
695.0014038	0.12
700.6788940	0.11
709.0722046	0.04
711.2201538	1.34
712.3507690	0.38
713.0344849	0.08
713.6675415	0.31
714.5032959	0.17
719.3396606	0.12
720.2107544	0.24
725.5317993	0.24
727.2439575	0.06
737.2858276	10.81
738.3136597	4.08
739.0668335	0.11
740.3087158	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	303.05
Annotation	Bracteatin
Peak:m/z	Relative Intensity
94.9153442	0.34
106.8605347	0.13
109.1011658	0.43
111.0059052	2.72
120.9015045	2.08
126.9233475	0.50
136.9992523	7.33
139.1111755	0.49
147.0136414	0.47
149.0098114	6.59
149.8873291	0.40
152.9937134	9.50
161.0432587	1.41
162.9375305	3.67
165.0030670	44.06
165.9177246	4.68
167.0449677	0.16
170.8524170	0.30
173.2456512	0.12
177.0224915	1.09
178.3959656	0.57
182.8837738	0.29
186.8939209	1.64
188.0533447	0.37
191.0355682	0.87
192.0188599	0.30
193.0889893	0.32
195.0407715	5.61
199.1688538	0.53
201.1186218	6.51
202.1446838	0.33
205.1455994	1.93
212.9538879	8.52
214.1778259	0.21
215.1300659	2.79
217.1950989	1.36
219.1719971	7.17
223.1672668	0.40
229.0069580	63.82
230.0931091	5.86
233.2264099	1.19
239.1105042	1.24
240.0152588	0.64
241.1435547	1.28
242.3915710	0.51
243.0702515	0.45
247.0256042	37.81
248.1236267	2.37
257.0330200	100.00
258.1477051	10.35
261.1200867	0.22
262.4331360	0.12
267.1488342	0.32
274.0662231	11.66
275.1270752	11.69
275.8879395	0.15
285.0410767	60.77
286.1087036	4.80
303.2026367	14.32
304.1065674	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	724.9187
Annotation	Unknow
Peak:m/z	Relative Intensity
291.0388794	0.01
309.3031006	0.01
323.3637390	0.01
324.1699829	0.05
325.3010254	0.05
333.5430298	0.01
343.0071716	0.01
351.1720581	0.01
361.1632080	0.01
377.2077026	0.03
378.8602295	0.07
395.1130371	0.01
399.1343994	0.01
402.0953979	0.03
408.6351318	0.03
414.7448730	0.04
415.3565674	0.03
434.8515015	0.01
438.5925903	0.02
443.0604248	0.10
443.9202271	0.03
445.1415405	0.04
452.8958130	0.01
457.2921143	0.01
458.8496704	0.02
470.8618774	0.02
473.1865845	0.01
474.5541382	0.01
479.0752563	0.06
479.9783936	0.02
480.9228516	0.07
486.2014160	0.02
486.9655151	0.05
491.1799316	0.05
495.7691040	0.13
498.1832275	0.02
499.0601196	0.06
506.9749756	0.01
508.0985107	0.37
512.8911743	0.03
516.9252319	0.62
519.8615723	0.02
521.5349121	0.11
525.9645386	0.02
526.6918335	0.01
528.2722778	0.07
528.9830933	0.30
529.8385620	0.02
531.6056519	0.04
532.9774780	0.10
539.7035522	0.02
545.9263916	0.66
549.9794922	0.01
551.1332397	0.04
554.4884644	0.07
556.5306396	0.26
559.0054321	0.02
562.9294434	0.13
564.0088501	0.22
567.1475830	0.02
569.0162964	0.04
575.0391846	0.28
577.0714722	0.02
580.0424194	0.36
587.1669312	0.36
588.2290649	0.24
589.0221558	0.09
591.8634644	0.22
598.1023560	1.43
601.0440674	0.02
603.3410645	0.01
604.0999146	0.03
604.9260864	0.09
606.8804932	0.03
609.9512329	0.03
611.3878174	0.04
612.8804932	0.05
617.8815308	0.06
619.0763550	0.01
636.0013428	0.24
638.5993042	0.19
641.0273438	100.00
641.6873169	0.23
647.0834351	0.03
663.7935181	0.06
666.7913208	0.01
678.9182739	11.36
681.8911743	0.64
705.9130249	0.03
706.9308472	0.08
721.8307495	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	613.17
Annotation	Unknow
Peak:m/z	Relative Intensity
182.8900909	0.04
201.1116638	0.12
226.1809387	0.26
229.2778931	0.48
230.0006409	0.09
242.8110809	0.10
247.0726624	1.75
248.1134033	0.76
272.1670837	0.27
272.9182129	0.38
275.0628662	0.05
289.2637329	0.83
290.0588989	0.48
307.1010437	100.00
308.4215698	0.21
332.9959106	0.06
347.0595703	0.06
357.0319824	0.03
357.8436890	0.05
372.1860962	0.06
402.7616577	0.07
448.7409668	0.30
457.4519653	0.17
460.7532349	0.18
462.3680420	0.18
484.5081787	0.12
489.5445557	0.17
509.0192261	0.14
514.2474365	0.04
515.6249390	0.05
530.9546509	0.22
547.2873535	0.14
553.2002563	0.24
576.4277954	0.10
577.9573364	0.05
591.0220337	0.11
592.4478760	0.60
594.4697876	0.06
595.3622437	0.13
601.0103149	0.03
603.7603760	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	252.04
Annotation	Unknow
Peak:m/z	Relative Intensity
87.0225220	0.17
104.0478821	0.27
116.9247437	0.62
130.9320526	80.89
144.4912872	0.20
153.9897308	0.59
159.9719086	3.65
163.0914764	0.92
163.9989471	0.65
174.7741547	0.20
175.4357605	0.49
185.8282166	4.00
188.9943542	0.23
189.7860260	0.20
195.0795135	0.45
197.2956085	0.32
204.0002899	42.21
206.0392303	3.98
212.9249878	0.78
214.9291382	0.35
216.1584167	0.36
219.7075195	0.41
224.2489319	0.40
232.5768585	0.66
234.0329437	100.00
234.7771149	23.86
238.1168365	0.77
242.1443481	0.64
242.9024658	0.62
253.3720093	1.24
260.0052795	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.0471
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
162.9583588	0.05
174.9248962	0.02
177.1169739	0.01
193.1477814	0.05
211.0624695	2.31
212.0273132	0.09
223.2166748	0.08
236.2414551	0.02
239.0892944	0.03
241.0970001	1.09
259.1206360	0.07
262.1324463	0.02
272.5182495	0.04
280.0816650	0.76
281.1646729	0.07
290.9143066	0.05
305.1128540	0.16
306.1343079	0.05
321.1255493	0.69
323.0946045	100.00
324.1708374	9.94
385.0910034	2.37
386.1885986	0.13
403.1275024	2.32
404.0833130	0.33
449.1307983	0.01
452.9229126	0.02
467.1522827	0.22
468.1538086	0.14
480.1176147	0.01
482.7846069	0.05
529.2997437	0.02
547.0258789	0.36
548.2130737	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	286.0325
Annotation	AminoDAHP
Peak:m/z	Relative Intensity
127.1219940	0.04
148.7355499	0.12
154.0680847	4.35
164.9734650	0.03
170.2983704	0.03
173.1766052	0.05
174.0747681	0.50
178.3074646	0.07
179.9454193	4.27
184.1404724	0.33
190.2072449	0.06
191.9166260	0.10
196.2132568	0.25
197.2925720	0.07
199.0478210	0.04
202.0749207	0.18
208.0804138	0.74
209.1412048	0.07
211.2446594	0.07
213.3829041	0.19
218.1991882	0.13
222.1022644	100.00
224.0750122	0.32
238.1799011	0.03
240.0422974	26.38
242.0180359	0.43
252.0312500	39.88
252.6717529	0.08
255.1198730	0.07
258.0093384	0.08
266.9992065	0.13
268.0375977	1.98
268.9979553	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	409.19
Annotation	Vernoflexuoside
Peak:m/z	Relative Intensity
138.0513153	0.10
139.8511810	0.72
143.3385010	0.22
146.0332336	1.12
155.1862640	0.19
157.0594177	3.21
158.1588135	0.33
162.1122894	0.48
166.3356323	0.18
168.9401703	0.11
175.0963135	0.19
182.1354675	0.22
183.0044250	0.35
188.0122070	5.13
198.9286804	0.24
201.0191650	0.15
205.1004028	21.64
209.1379395	0.23
219.0475616	0.14
223.0344849	0.11
225.0805359	0.22
226.3394775	0.30
228.0614624	0.66
237.1435242	0.25
242.1563110	7.41
243.1687927	0.37
244.1671753	0.96
244.8489685	0.34
246.9997864	0.14
248.1155090	0.45
251.5940247	0.09
255.2464905	0.32
260.5642395	0.59
261.1819153	0.05
262.5777283	0.32
273.1650085	3.39
274.4129944	1.46
275.2392883	5.87
276.1429443	0.22
279.3327637	0.38
280.3457336	0.31
287.4460449	1.07
289.3401489	0.74
290.3298645	2.05
291.2239380	0.74
296.1370850	0.27
301.6500244	0.32
305.0760498	0.61
307.1254883	93.32
308.1764221	12.35
309.2413025	9.84
310.2615051	0.45
322.0740356	0.54
323.5556030	0.67
324.4276123	1.62
334.0599365	0.24
338.5213928	1.49
339.1833801	38.70
340.2011414	3.38
341.2178345	4.17
342.2535706	0.57
343.3561401	0.56
347.1682739	0.49
350.3107910	0.63
351.8201294	0.98
352.5357361	0.23
357.1418152	10.12
357.8839722	5.03
358.9227600	0.28
359.8716736	0.35
363.4667053	0.06
364.1993713	0.45
366.2866211	2.99
367.1241150	0.13
368.9102783	1.31
369.7225647	1.08
371.3903503	0.41
372.8705750	0.68
373.9325256	0.66
377.3542786	0.32
380.2539368	0.21
382.2974854	2.05
383.1470032	7.89
383.8739929	8.64
387.2485962	2.20
388.0429688	0.16
389.5044250	100.00
390.3061218	1.16
391.2417297	3.70
392.4216919	2.03
394.4381104	8.65
395.8321838	1.67
397.6027832	29.74
398.3102112	16.46
399.4289551	2.09
400.2241516	0.96
403.2573242	50.44
404.0308838	1.95
408.1536255	0.61
413.3380432	0.41
414.3453979	0.41
414.9606934	0.53
416.2349548	0.46
418.3724060	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	604.1722
Annotation	Unknow
Peak:m/z	Relative Intensity
172.2195435	0.05
172.8607178	0.13
175.1529541	0.05
176.8353882	0.06
182.0369568	0.07
182.8012543	0.03
189.1315613	0.07
195.0651398	0.03
200.0992584	0.41
200.9956512	0.08
202.0153809	7.33
204.8713226	0.26
214.9592896	0.44
217.9918823	1.33
219.0228729	0.49
221.4031982	0.05
232.1665649	0.05
233.1510620	0.19
237.2488556	0.10
239.1175079	0.06
244.2792969	0.29
244.8948212	0.16
246.4440918	0.09
247.1574402	0.03
257.1494751	0.14
259.0936890	0.08
259.6950989	0.05
262.0368958	100.00
263.1615295	0.27
264.1132202	0.13
265.1892700	1.26
269.3298645	0.14
274.9543762	0.22
282.0903931	1.12
283.2260742	0.92
284.7530518	0.07
290.0966797	0.06
303.0993958	0.09
306.9868164	0.11
317.4512329	0.08
318.0688477	0.07
320.9674683	0.45
323.1586304	0.06
329.3170776	0.15
339.1502686	0.12
341.2108154	0.22
341.8822021	0.12
344.0358276	0.33
344.9213867	0.11
345.9898682	0.04
359.0283203	0.21
361.6567993	0.28
362.6666870	0.32
368.8026733	0.11
380.3145752	0.10
383.2258911	4.80
384.2210693	0.11
394.0284424	0.03
397.0579834	0.43
401.1055298	0.94
413.0637207	0.07
415.2786255	1.82
424.2118530	0.15
441.2610474	0.14
442.2763062	0.45
446.6307373	0.09
457.9483643	0.08
465.1181641	0.13
467.3192139	0.04
471.0604248	0.06
472.1359863	0.25
473.4063110	0.10
478.4213257	0.35
479.0878906	0.18
485.1906738	0.44
494.1506958	0.05
506.4119873	0.22
507.1213989	0.13
510.0531616	0.14
511.5259399	0.06
514.1316528	0.15
515.2882690	0.08
526.2376709	0.06
528.6163940	0.06
529.5150757	0.26
543.2723389	0.37
544.4791260	0.60
545.2271118	0.08
561.2399292	0.09
573.3468628	8.72
586.2514648	0.53
587.2781982	0.86
587.9353638	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
96.83804321	0.94
105.0623016	1.26
121.1273956	0.21
130.9143677	0.27
132.7691193	0.38
137.8792419	0.16
147.0007172	0.21
149.1143036	1.72
152.9628448	0.33
154.1658173	0.51
155.2337036	0.39
160.9690399	1.24
165.2561188	0.89
174.3192902	0.27
175.929184	0.53
177.0560913	0.38
178.4147797	0.58
179.1430511	1.01
180.0467377	0.90
181.1248932	1.50
182.2698822	0.35
182.9974365	0.80
185.010025	0.25
193.2790833	1.79
194.9892426	1.40
201.9971313	0.54
204.9444275	1.95
206.1656342	2.73
207.003418	12.83
208.1568451	8.81
209.1719666	4.81
214.8992767	4.23
219.9504395	0.56
222.0703735	7.68
223.0250092	10.22
224.1908112	3.53
232.3014526	1.64
233.1365356	3.17
251.0802612	100.00
252.122757	22.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	182.0808
Annotation	4,6,7-Trihydroxy-1,2,3,4-tetrahydroisoquinoline
Peak:m/z	Relative Intensity
118.7375793	0.03
136.0061493	18.86
147.2673798	0.02
159.0249176	0.05
164.9411163	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	627.1543
Annotation	Myricetin 3-neohesperidoside
Peak:m/z	Relative Intensity
179.2762604	0.11
188.1085815	0.42
190.9676208	0.12
235.0514832	2.48
245.4188232	0.35
247.0422974	0.62
249.2918701	0.16
260.2102051	0.57
263.1829224	0.48
275.0940552	0.76
285.3366089	0.19
303.0870361	17.64
308.5306396	0.70
310.2729187	0.24
311.9737549	0.26
313.1093750	0.15
315.2410889	0.20
319.0861206	0.19
322.2939453	0.41
328.4741821	0.29
330.2028198	0.34
338.1691284	1.03
339.1243286	0.24
343.1978760	0.24
345.2999878	0.46
347.0914307	0.48
354.3287964	0.94
360.2922974	0.15
365.0100098	3.02
366.9642944	0.41
368.1751099	1.52
369.2504272	0.78
382.2231445	0.17
388.3190918	0.89
393.1465454	0.40
399.1971436	0.49
409.1190796	0.09
413.2634888	0.31
416.3866577	0.37
424.2778931	0.58
426.1881714	0.41
427.0050659	0.23
434.1885376	0.19
442.1665039	0.54
446.8974609	0.26
451.4146118	1.48
452.2722168	5.42
454.5895996	0.19
465.1344604	100.00
468.7493286	0.29
471.4649048	0.53
473.4414062	0.24
479.0362549	0.38
480.8292847	0.85
485.3878174	0.16
490.8954468	1.71
493.2415161	0.64
494.3252563	0.23
495.0264893	1.70
504.4323120	0.13
507.3999634	0.88
511.3665161	0.36
512.7718506	0.56
517.7219849	0.35
518.3601685	0.19
525.3203125	0.79
538.1330566	0.38
542.0381470	0.73
542.8165283	0.68
545.1337280	1.70
546.2593384	0.16
547.2901001	0.29
549.0497437	0.61
549.9200439	0.91
551.2627563	5.07
552.2938843	0.56
554.7887573	0.84
558.2630005	0.21
559.9331055	0.33
561.2923584	0.92
562.4735718	0.21
564.3101807	0.45
565.3177490	0.16
567.9835815	0.32
568.6491089	1.87
570.1406250	1.24
574.8801880	2.16
579.4666748	1.07
582.9288330	0.85
583.8543701	0.92
587.0354004	0.95
590.3453979	0.47
591.5950928	1.16
592.5965576	0.16
597.6390381	2.32
598.6554565	1.14
601.3745117	0.73
602.5809937	1.12
608.3795776	3.59
609.2620850	2.95
610.5031128	1.18
613.5966187	0.35
615.0196533	1.74
618.5624390	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.0023
Annotation	SC-58125
Peak:m/z	Relative Intensity
128.9180298	0.32
133.0429993	0.05
155.0951233	0.06
173.0065308	1.43
190.9727478	100.00
199.0116577	0.10
213.0500641	0.08
240.9998779	0.07
257.1141357	0.04
258.1701355	0.08
260.9578247	0.06
273.0575867	0.21
283.3214722	0.04
292.2767029	0.07
299.2187805	0.08
306.1123657	0.05
316.5750427	0.33
317.1967163	0.54
321.9024658	0.16
323.2429199	0.08
330.0200500	0.03
341.4143372	0.08
343.3833313	0.03
357.2976685	0.11
368.2241516	0.04
369.1877441	0.03
374.0886841	0.07
377.0647888	0.21
384.8790588	0.35
386.2796326	0.07
389.2618103	0.07
403.0931091	4.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	504.92
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9474030	3.44
160.0265808	1.46
160.9344025	1.76
162.0976562	0.19
163.0596924	0.12
199.0971985	0.19
199.9814606	0.40
200.9655304	0.50
202.0313263	0.07
203.2872314	0.04
217.9155273	0.09
219.1702881	0.24
228.9559937	0.45
230.1395874	0.43
231.1461334	0.97
231.9890594	0.33
232.7821808	0.10
247.1901398	0.09
273.0133972	21.73
274.0274048	27.88
275.0001221	59.07
276.0311890	20.23
277.1036682	9.81
346.0057983	0.10
387.1429443	5.03
388.0168457	33.49
389.0000610	100.00
389.9751282	99.12
390.9385071	54.99
397.2417603	0.03
430.3095703	0.42
431.0161133	0.05
432.5824585	0.24
442.3285217	0.04
458.9842529	4.88
460.0148315	0.34
460.9564209	0.06
474.3230591	0.22
476.4215393	0.07
486.3561707	0.04
487.0217896	0.76
504.3744812	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	589.9
Annotation	Unknow
Peak:m/z	Relative Intensity
231.1572571	0.05
246.9778442	0.03
273.0551453	1.95
274.1297607	0.51
274.9879150	0.33
335.2633667	0.03
359.1267700	0.09
362.0463867	0.06
387.1916504	0.22
390.1043701	0.03
415.1807861	0.08
427.2059326	0.32
428.9364624	2.97
430.0819702	0.89
431.1109619	0.18
443.0733032	0.08
456.9522095	0.05
458.7066040	0.05
473.0120850	0.24
474.4425049	1.14
475.1632690	3.59
476.0797729	1.74
476.9443359	0.06
487.3020020	0.07
501.9563599	0.03
502.7799683	0.07
505.1517944	0.03
515.6663208	0.03
517.1870728	0.04
535.1716309	0.09
540.9550171	0.16
542.8307495	100.00
543.8268433	26.16
544.4984741	0.21
545.1132202	0.06
546.0917358	0.22
547.3958130	0.14
560.8263550	0.60
561.7854004	0.17
562.4250488	0.10
571.2662964	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	639.28
Annotation	12-Ethyl-8-isobutylbacteriochlorophyllide d
Peak:m/z	Relative Intensity
201.1902313	0.06
214.8195801	0.02
217.0955200	0.05
219.1868286	0.05
228.3741302	0.03
235.9333801	0.03
241.3104858	0.05
243.4141235	0.04
251.0382996	0.17
275.0924072	0.05
283.3404541	0.03
299.2111816	0.03
302.9252930	0.03
313.1567383	0.04
323.7430420	0.08
336.5375977	0.03
341.0473022	0.05
354.5273438	0.25
359.2439575	0.18
360.3815918	0.04
366.4833984	0.04
369.3593140	0.28
371.0795288	0.22
373.3076782	0.18
385.3657227	0.06
387.2901001	0.13
389.2610474	0.70
390.8732910	0.04
403.8942261	0.04
406.6886597	0.65
407.3491211	0.22
410.0833130	0.05
411.5148315	0.02
412.4981079	0.04
425.5652466	0.05
429.4796143	0.03
430.3637085	0.05
437.4584961	0.07
439.8079224	0.05
444.7026367	0.09
453.2083740	0.03
464.0841064	0.04
472.0137939	0.24
481.3225708	0.16
483.1343384	0.06
491.4699707	0.05
493.2969971	0.44
494.3334351	0.07
497.2935181	0.13
506.3134766	0.17
507.2178345	0.03
514.4204712	0.04
515.5970459	0.02
516.4078979	0.11
517.0551758	0.05
517.9344482	0.12
521.5985107	0.10
526.8895874	0.04
527.7705078	0.04
533.5494385	0.08
534.7677612	0.14
535.4406738	0.50
536.2793579	0.05
536.9797974	0.03
537.5917358	0.19
539.5253906	0.12
541.2841797	0.13
542.2404175	0.04
546.1575317	0.04
547.5670776	0.34
550.1135864	0.06
551.4177856	0.45
553.3044434	0.46
554.6869507	0.06
561.4306030	0.13
562.4768066	0.03
563.4732056	0.80
564.5417480	0.54
565.3772583	1.06
566.6035767	0.36
567.3770752	2.67
568.2481079	0.25
569.2959595	0.47
571.5890503	0.05
575.3937378	0.28
577.9716797	0.08
579.3197632	2.61
580.4692383	0.21
581.4768677	0.12
583.2962646	0.18
589.4033813	0.46
590.5360718	0.12
591.2734985	0.08
592.4183960	0.04
593.4262695	0.72
595.3438721	3.96
597.2749634	100.00
598.0299683	0.23
603.6084595	0.03
605.4740601	0.09
607.2977295	18.33
608.4549561	0.46
611.3527222	16.21
612.4147339	0.07
620.7842407	0.86
621.4444580	8.79
622.4072876	2.15
624.4072876	0.82
625.5199585	0.20
640.3162842	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	473.0793
Annotation	Unknow
Peak:m/z	Relative Intensity
142.9628601	0.08
148.9417114	1.53
150.9014587	0.05
158.9225769	0.04
161.2255096	0.06
175.2258301	0.04
178.0314636	0.02
178.9211121	0.63
187.0522766	0.04
194.6441345	0.04
195.3163452	0.11
205.8353729	0.04
209.0013885	0.04
213.4638672	0.06
223.2399597	0.03
242.1653442	0.09
257.4436646	0.19
258.3223877	0.02
263.1700439	0.15
265.1635132	0.03
266.4178467	0.07
277.1894531	0.15
279.1593323	0.12
293.0370483	0.04
310.8498840	0.26
321.0599365	0.05
323.0209961	0.15
323.6911011	0.02
329.0875244	0.05
334.0399780	0.04
337.1601257	0.04
339.4457092	0.11
341.1524658	100.00
343.2157288	0.03
344.3064575	0.11
355.2321777	0.11
356.5889893	0.10
357.2929993	0.65
358.2393799	0.24
367.2666931	0.05
368.2092896	0.07
372.4185181	0.04
381.3558044	0.09
383.2178345	0.06
401.2232666	0.06
406.2993469	0.02
407.2718201	0.62
411.8397217	0.03
413.1156921	0.08
427.1780090	37.46
428.3665466	0.15
429.1008911	0.03
437.3027039	0.54
439.1880188	23.47
443.7657166	0.03
454.3159485	0.15
455.3089294	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	290.1495
Annotation	Imazethapyr
Peak:m/z	Relative Intensity
88.8973465	0.19
143.9856262	100.00
150.4804993	0.83
160.9870300	69.01
169.1186829	0.38
184.8665771	0.15
211.2703857	0.47
227.0742798	6.51
241.1569824	0.84
245.3341980	0.19
249.2240601	0.26
260.0939941	0.12
272.0610046	1.88
273.1134644	38.84
275.9737549	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	227.9822
Annotation	Unknow
Peak:m/z	Relative Intensity
121.8151550	0.75
167.9281158	0.41
186.8774414	100.00
191.1616821	0.19
199.1707001	0.32
200.2100372	0.26
204.5161438	2.00
211.3842621	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	599.41
Annotation	Isomytiloxanthin
Peak:m/z	Relative Intensity
168.9456940	0.22
169.8708344	0.26
173.1355743	0.28
174.0046234	0.18
175.0096283	0.40
176.9403839	0.21
178.1031189	0.35
179.1018372	1.10
180.8444061	0.26
182.0544434	0.09
182.8102875	0.17
184.4268494	0.20
185.2384033	0.46
186.9415741	0.45
189.0493774	0.66
190.5113068	0.46
191.1235809	0.97
193.0397949	0.51
195.1139526	1.13
195.8966522	0.33
197.0274658	1.05
198.2542877	0.07
199.0770874	0.69
200.1496887	0.22
201.2693787	0.35
203.2032928	0.86
205.3384705	0.57
206.7905121	2.04
207.4935913	0.48
209.1856079	2.84
211.2177734	1.27
213.2453003	0.53
215.1930084	0.13
217.6295776	0.18
218.3377686	0.32
219.3074036	0.45
219.9877930	0.14
221.0100555	10.16
223.1388245	2.15
225.2478943	2.22
226.1977386	0.25
228.1405029	0.11
229.2575531	0.40
233.1505890	4.08
235.1727753	1.15
236.1533051	0.19
237.2812653	2.69
238.8560791	0.63
240.1993103	0.11
241.0950012	1.16
243.2380371	0.77
245.1983795	0.53
246.3123474	0.13
247.1444702	0.93
249.2407227	0.99
251.2410126	1.19
252.3099518	0.23
252.9561157	0.13
255.2837372	0.10
257.2951660	0.60
258.0267029	0.18
259.1696472	0.86
260.1859741	0.12
260.7940063	0.21
261.4169922	1.44
263.2229919	1.05
265.1785583	0.94
267.1630859	0.66
269.2773743	0.66
270.6319275	0.36
271.3489990	0.44
273.2220459	2.16
274.2768860	0.40
275.2424011	0.75
276.0812073	0.07
277.2476196	0.60
278.2553406	0.37
279.2662354	1.03
281.2313843	4.94
283.2042847	1.55
285.1923523	3.06
286.1877441	0.55
287.3259583	2.79
289.1684570	2.03
290.2510071	0.90
291.2731934	0.11
293.2487183	0.75
295.1931152	0.55
296.1965637	0.14
297.3355713	0.72
298.3162842	0.33
299.3156738	3.14
300.3145142	0.21
301.1246338	0.93
302.3325500	1.03
303.2286987	1.65
304.1854248	0.10
305.2501221	0.48
307.3036499	0.07
308.3751831	0.34
309.4603271	0.13
311.2709351	2.33
312.2348022	0.94
313.2830811	2.19
314.1534729	0.15
315.3250732	0.48
317.3358154	2.07
319.2904358	0.67
321.2611084	1.81
322.1690674	0.28
323.1363525	1.44
324.1841125	0.18
325.3081665	1.78
326.2116699	0.14
327.0705566	0.96
329.3070068	0.31
330.3901367	0.28
331.3060303	0.79
332.4120483	0.10
333.3435059	0.97
335.3173828	1.44
336.2744751	0.36
337.2565308	1.57
338.3070068	0.59
339.4052124	1.00
340.5859375	0.13
341.3757935	1.33
344.3332520	0.26
345.4743042	0.13
347.3270874	1.76
349.2540894	1.84
350.3229980	0.34
351.4693604	0.32
352.4199219	0.47
353.2987671	0.07
354.4548950	0.75
355.4028320	1.47
356.8071899	0.61
359.2194214	2.83
361.3486938	1.84
363.5445557	1.14
364.4255371	2.57
365.4162598	1.86
367.3624878	0.21
368.2137451	0.30
369.3995361	0.81
371.4403076	1.13
373.2243652	4.39
375.3099976	1.15
377.3577881	6.72
379.2733765	3.03
381.4390869	1.27
383.3473511	0.77
385.4153442	0.38
387.4917603	0.76
388.3972778	0.17
389.4025879	1.61
390.1985474	0.47
391.3205566	4.23
392.4142456	0.41
393.2931519	0.64
394.7439575	0.23
395.4976196	1.07
396.5044556	0.36
397.2745972	1.17
399.3803101	0.43
400.8822632	0.71
401.4857178	1.09
402.1945190	0.11
405.3677979	0.39
406.5344238	0.50
407.3416748	0.42
409.5266724	0.36
410.5416260	0.19
411.4174805	0.64
413.5736694	0.22
415.4195557	3.52
416.3960571	0.31
417.3687744	2.63
419.4077148	1.09
421.3409424	0.23
423.4483643	1.56
425.3740845	1.06
427.4752808	0.70
429.6527710	0.08
430.4021606	0.16
431.2514648	0.44
433.4345093	1.09
434.3805542	0.09
436.8112183	0.30
437.5729980	0.27
439.1630249	0.82
441.4482422	5.28
442.4570923	0.22
443.5596924	0.77
444.3898315	0.52
445.4257202	0.77
446.4080811	0.22
450.3911133	0.13
451.3599243	0.34
453.8566895	1.02
455.0041504	0.40
455.7388916	0.54
457.2827148	0.34
459.4339600	0.12
461.5842896	0.59
463.4649658	0.19
465.4132690	0.21
467.4904785	1.07
468.3292847	0.38
471.3784180	1.00
475.5869751	0.81
479.5537720	0.45
481.4796753	1.23
483.2764282	0.19
485.3436890	0.45
489.4343262	5.40
493.3149414	5.09
494.5374756	0.32
495.5154419	1.00
498.5547485	0.34
499.6863403	0.49
501.6260376	0.24
503.3381348	0.18
505.4149170	0.21
507.4706421	100.00
509.3249512	0.14
511.3134766	0.11
512.7123413	0.26
513.3169556	0.19
515.4807129	0.96
517.4589844	0.95
519.5183105	0.93
520.4949341	1.62
521.4112549	0.58
523.3326416	3.36
525.4389648	4.05
526.3319702	0.49
527.5739136	0.12
531.6998901	0.17
532.5228882	0.13
533.4829102	0.10
534.7166138	0.85
535.5816040	0.27
537.4320679	0.55
538.4566040	0.25
539.5957031	2.67
541.5398560	1.47
543.5033569	1.73
544.9060059	0.47
545.5520630	0.84
547.7120361	0.35
549.0736694	0.23
550.2539673	0.26
552.0397949	0.25
553.2014160	0.79
555.5766602	0.35
556.5765991	0.24
557.2857666	0.18
563.3904419	10.55
564.0466919	0.19
566.9660034	0.36
568.2702637	0.27
568.8759155	0.17
571.4086914	0.99
581.4265137	54.40
582.3728027	0.95
583.7470093	0.38
584.3788452	0.33
598.6826782	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	641.29
Annotation	Crooksiine
Peak:m/z	Relative Intensity
178.8149109	0.07
187.0584259	0.21
187.9855042	0.06
202.1202240	0.07
205.1150818	0.14
218.8107910	0.37
220.3028717	0.14
223.2341309	0.30
225.8760223	0.07
238.1568756	0.10
249.4095459	0.08
250.1418152	0.22
260.1385193	0.24
260.8890991	0.25
266.2268677	0.09
269.1866760	0.18
275.2478638	0.16
279.0597839	0.25
289.4627991	0.30
301.1780396	0.10
302.4097900	0.15
304.7745972	0.26
315.0960693	0.31
320.0195923	0.28
325.3288879	0.11
328.4739380	0.10
331.1574097	0.17
342.1444092	0.25
344.1923218	0.13
348.7315063	0.14
351.3362427	0.43
352.2671509	0.05
353.2773438	0.08
354.1236572	0.17
355.0164795	0.12
357.3165894	0.10
359.1536865	0.34
361.1578369	0.14
365.3508301	0.34
366.1444092	0.35
368.3654785	0.08
369.6719360	0.37
370.3150635	0.74
371.0574341	0.58
372.3392944	0.91
373.8159790	0.77
374.9309082	0.27
377.2707520	0.30
380.5469360	0.13
385.0028076	0.30
389.3131714	0.69
390.4385376	2.34
391.4878540	0.78
401.1228638	0.15
406.6990356	0.33
407.8469238	1.02
413.3471680	0.30
414.6131592	0.19
416.2876587	0.07
421.2918091	0.16
431.1967163	0.54
435.3307495	0.25
438.0249023	0.31
443.1749878	0.08
445.1931152	0.07
447.8973389	0.10
453.3918457	0.15
454.4564819	0.08
461.5787354	0.34
472.3521118	0.13
474.5143433	0.10
478.5372925	0.33
481.3629150	0.21
482.3266602	0.19
485.4577637	0.14
487.1373901	0.17
488.1273804	0.13
492.2621460	0.48
493.3643188	2.62
494.3497314	0.79
495.5332031	0.41
496.9437256	0.22
500.4028320	0.12
502.4602661	0.28
505.2483521	0.17
507.3932495	0.52
508.3904419	0.23
512.5264282	0.21
517.3363037	0.14
519.5997925	0.26
520.7364502	0.47
521.5730591	0.91
522.3639526	0.05
523.3058472	0.17
524.3435669	0.35
525.4290771	0.39
528.8829346	0.07
529.6516724	0.18
531.4266968	0.16
534.3626099	0.23
536.2357788	0.93
538.3367310	0.17
539.3685913	1.93
540.3848267	1.62
541.5475464	0.95
549.2825317	0.30
550.4362183	0.22
551.1954346	0.05
552.2761230	0.79
553.4273071	5.44
554.3618774	3.00
555.2729492	0.68
559.5718384	0.31
560.5831299	0.14
563.5405884	0.69
564.6136475	1.10
565.3850098	2.12
566.3916626	0.15
567.3967285	0.76
568.5599976	1.96
569.4254150	1.03
570.4904175	0.98
571.3165894	0.14
573.6280518	0.06
576.6205444	0.15
577.7305298	0.23
578.9279175	0.38
579.7368774	0.67
580.3379517	4.37
581.3729858	100.00
582.3354492	0.43
583.3839111	3.65
584.5557251	0.81
585.3685303	0.15
590.5919800	0.91
591.3317871	0.89
592.6755981	0.57
593.4696655	1.74
594.5236206	2.54
595.3682251	1.85
596.3262329	2.96
597.5463257	21.55
598.3826904	72.58
599.3796997	56.70
605.4599609	0.40
606.5286255	0.63
607.5632324	2.14
608.3197632	20.51
609.4068604	17.73
610.3864746	0.22
611.7923584	1.71
612.4470825	14.55
613.4393311	11.17
621.2939453	1.64
622.4276123	17.30
623.3821411	16.78
624.4615479	3.83
625.4264526	1.39
626.4730225	1.67
627.2955322	0.17
637.8247681	0.18
640.7684937	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	205.0968
Annotation	Indoleacrylic acid
Peak:m/z	Relative Intensity
99.1195984	0.02
131.9964600	0.04
132.7890778	0.02
159.1504669	0.11
163.0134888	0.01
164.0355225	0.03
167.1667938	0.02
177.0310822	0.01
188.0015259	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	445.1173
Annotation	Sissotrine
Peak:m/z	Relative Intensity
143.9140625	0.14
148.8682556	0.07
151.9455109	0.17
161.0163269	0.12
163.1167297	0.05
179.0945129	0.10
179.9051514	0.18
195.2268524	0.11
202.9363708	0.20
217.3375549	0.15
219.3067322	0.12
223.4399719	0.28
235.1602325	0.17
238.2965088	0.07
239.1012573	0.10
242.3005371	0.07
248.9654541	1.63
254.0667114	0.06
261.1750183	0.28
263.1193237	0.11
273.0322571	0.11
274.2616882	0.29
279.4522705	0.05
281.4282227	0.17
283.0683594	100.00
291.0713806	0.06
296.1420593	0.12
299.0662842	0.09
301.111908	0.14
312.5846252	0.07
317.2752991	0.22
325.456665	0.17
328.1135864	0.11
333.0186157	0.18
348.8832092	0.10
351.1053467	0.14
355.0187988	0.09
363.0149536	0.08
368.222168	0.09
368.9706421	0.18
371.250824	0.05
372.3983765	0.21
373.1192627	0.16
378.1005249	0.11
380.8003235	0.08
382.081604	0.15
383.5069275	0.07
384.4694519	0.10
385.2990417	0.28
398.3166809	0.62
399.2542114	0.82
400.5674744	0.20
401.3540649	0.72
407.0777283	0.24
409.2025757	0.20
410.216156	0.05
410.9886169	0.06
413.131073	0.14
417.0649719	0.10
425.0003967	0.20
427.2746277	3.02
430.7841797	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	540.93
Annotation	Unknow
Peak:m/z	Relative Intensity
311.1578369	0.12
313.0128174	0.28
367.1174316	0.12
375.7126465	0.10
383.1134644	0.16
385.2165527	0.06
400.5342407	0.09
401.3919678	0.18
410.8533325	0.18
412.2340698	0.13
422.4660034	0.13
424.0353394	0.66
425.1408081	1.28
426.9274292	100.00
428.0391235	0.77
430.3504639	0.07
442.1028442	1.22
443.0749512	0.49
444.0517578	2.50
445.0845337	0.78
445.8900757	0.07
450.0693359	0.07
454.9847412	0.10
464.8281860	0.22
466.4720459	0.11
467.0980225	0.31
468.8355713	0.41
481.2872925	0.17
483.0421143	0.15
489.1737671	0.03
492.1800537	0.22
493.9351196	14.14
494.9816284	37.52
496.0710449	0.38
497.0012817	0.05
497.7444458	0.22
499.1744385	0.10
511.3338013	1.38
511.9853516	5.28
512.8857422	9.29
514.0671997	0.08
517.9016724	0.35
519.6994019	0.07
520.3709717	0.25
522.1948242	0.14
525.3082275	0.07
527.7811279	0.05
528.5018921	0.04
529.6670532	0.19
530.4503784	0.10
532.1926880	0.22
535.8579102	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.06
Annotation	Unknow
Peak:m/z	Relative Intensity
173.0388641	0.02
189.1204071	0.02
193.1984863	0.01
197.0790710	0.03
198.7230225	0.18
200.2554016	0.06
201.8482361	0.13
211.0732727	0.05
212.1541443	0.02
216.1467133	0.07
224.9132080	0.02
226.0463715	0.02
227.0608063	0.13
228.2037354	0.13
229.2500305	0.02
231.3679810	0.02
233.2489014	0.04
243.1432190	0.46
244.0559387	0.19
247.1148224	0.02
253.0035248	0.02
254.3310242	0.26
255.1177368	3.35
256.0711060	0.21
257.0444336	0.05
259.1514893	0.27
269.2297974	0.03
271.1663208	5.54
272.1107788	1.95
280.2549438	0.02
281.1560059	0.05
284.3139954	0.06
285.4221802	0.04
287.2715454	0.85
289.0760498	0.07
297.1783142	0.06
298.9846802	0.77
300.0791016	19.10
300.6793213	0.08
309.3546143	0.04
312.1676636	0.02
313.1941528	0.55
315.1071167	100.00
316.0496216	0.10
324.1100464	0.09
325.3535156	0.03
329.3790283	0.05
330.9829102	0.04
338.9835205	0.02
342.3033447	0.16
343.1085205	0.01
355.1224976	0.09
357.2404785	2.09
368.8282471	0.08
387.2875366	0.15
399.2171631	0.04
417.1510010	0.02
441.4381714	0.04
463.1539307	0.17
473.7150269	0.02
499.1171265	0.04
518.1669312	0.03
537.2667847	0.02
563.2979126	0.12
577.9019775	0.06
587.2033691	0.07
588.8676147	0.03
589.4879761	0.08
591.3952026	0.30
592.2747192	0.05
595.2649536	0.60
608.2290649	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	827.7938
Annotation	Unknow
Peak:m/z	Relative Intensity
228.3662872	0.24
268.1994934	0.19
300.0862732	1.92
337.2589111	0.14
377.4129028	0.15
410.3124390	0.22
413.4117432	1.99
500.1611328	0.53
590.2832031	0.11
643.2405396	0.23
658.6089478	0.75
662.9065552	0.08
672.1038818	2.19
681.1192017	0.16
684.3420410	0.27
711.6892090	0.13
722.3167114	3.57
725.3000488	0.39
728.0193481	0.10
729.0691528	1.73
733.5513916	0.29
738.3576050	0.46
743.4354858	0.19
755.2189331	0.74
757.2798462	0.96
757.9823608	0.53
760.8791504	7.76
761.6319580	0.21
781.5665894	0.43
789.2599487	2.02
791.8623657	0.36
792.7975464	2.13
794.0137329	0.15
798.5703735	7.12
799.2768555	0.19
799.9713745	0.40
805.3966064	0.91
810.3220215	1.94
817.5947876	0.12
898.3892212	0.37
969.7522583	0.43
970.9335938	0.18
991.8306274	4.59
992.6193237	0.36
993.3866577	0.16
1024.4552000	1.19
1026.4445800	1.22
1027.4194340	0.37
1035.1260990	0.68
1035.7464600	2.51
1078.0579830	0.44
1082.5336910	0.78
1083.6903080	1.47
1084.4182130	0.58
1086.7465820	0.58
1091.6492920	20.73
1092.4006350	30.00
1093.1997070	2.77
1140.0800780	0.34
1147.9969480	0.69
1154.7675780	0.36
1171.2600100	0.08
1197.6877440	0.55
1636.1735840	0.11
1799.2071530	0.17
1851.2030030	5.61
1875.8321530	5.65
1885.7717290	4.11
1888.9652100	0.23
1890.4123540	75.03
1899.7619630	2.91
1903.7318120	0.09
1906.2569580	0.17
1908.8034670	2.43
1910.0930180	0.19
1914.3786620	0.12
1929.5998540	0.26
1930.2254640	0.51
1932.7214360	7.82
1950.0257570	0.79
1950.9025880	100.00
1953.1317140	0.14
1956.8782960	7.25
1958.4294430	18.63
1963.9417720	0.29
1965.7175290	0.42
1967.0383300	0.27
1968.5793460	9.98
1969.7423100	4.29
1972.8155520	1.13
1975.5880130	6.52
1978.8040770	0.64
1979.6101070	1.20
1982.6799320	0.50
1984.0250240	0.76
1984.6890870	3.99
1986.3919680	0.34
1987.7982180	0.12
1993.2125240	0.62
1994.0787350	0.25
1996.5438230	10.46
1997.2740480	4.32
1998.4631350	0.14
1999.9421390	6.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	392.113
Annotation	(gamma-Glutamyl-gamma-glutamyl)-S-methylcysteine
Peak:m/z	Relative Intensity
128.0473938	2.79
134.7988586	0.05
142.9829712	5.12
144.9890137	0.33
145.9786224	0.57
149.0875549	0.04
153.3538208	0.12
155.0845642	0.05
159.9963074	0.21
166.1842651	0.38
167.1649323	0.40
169.1113892	0.05
170.1167145	0.12
171.1805725	0.18
176.8678589	0.81
179.0001221	10.67
184.5554504	0.05
185.2088776	0.36
192.1389771	0.13
193.3350372	0.03
197.0961151	0.81
210.1242371	4.59
211.1726227	0.32
213.0525513	0.10
228.2475586	0.32
230.2726135	0.10
236.1825562	0.46
254.1759338	85.07
254.9517212	0.05
263.1458435	7.03
272.1043396	100.00
275.8894043	0.04
277.2197571	0.23
288.0720215	6.00
306.1087036	51.85
317.1548462	0.05
320.1551514	0.03
336.4769592	0.04
345.9380493	0.03
356.4517517	0.08
369.5670471	0.05
374.1248474	20.87
375.2854309	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.2212
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
95.10939026	0.26
98.9036026	0.47
100.9745712	0.12
111.1566772	0.17
123.1325989	0.26
124.8752136	1.69
127.1300735	1.12
129.0281219	0.61
139.0932465	1.31
140.9126129	0.62
142.9936829	1.50
149.07901	0.31
153.0050659	0.13
154.9295349	1.89
157.0590515	0.65
160.7937927	0.82
162.9484863	0.41
165.0631866	1.10
167.0977173	0.39
169.0859375	0.12
171.1700745	0.48
173.1681061	0.24
177.075531	0.30
179.3034363	0.48
180.9954834	0.39
183.0778656	1.18
194.9883728	0.32
197.149704	2.40
205.2762146	0.12
207.0844727	0.16
209.0606384	0.48
211.1842651	1.09
213.1456604	1.33
214.14151	0.32
219.2425537	1.15
225.271698	0.39
227.384552	0.93
233.2693787	1.12
235.2669373	0.27
236.1813354	0.73
238.8960571	0.58
240.084198	1.06
240.863739	0.43
247.2769165	0.47
249.310791	0.30
250.0405579	0.72
251.0311279	2.31
253.1901855	6.53
254.9826355	1.57
256.8877258	0.13
263.861084	1.12
265.1496582	2.42
267.2376709	1.78
268.2970581	1.62
269.2081299	2.66
270.0164795	1.18
273.1290588	0.21
275.1580505	9.97
275.8998413	0.46
283.1914062	1.77
288.0711365	0.25
293.2026062	100.00
296.2521362	0.41
302.0953979	0.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.1094
Annotation	Falconensin D
Peak:m/z	Relative Intensity
179.2097321	0.15
182.9732361	100.00
183.7569580	0.11
209.3148041	0.09
211.1170044	0.11
221.1365967	0.18
259.2649536	0.09
311.0253906	0.06
315.3541260	0.06
323.3123779	0.08
339.0674438	0.36
340.4447632	0.26
341.1773071	0.62
344.3128052	0.21
364.2948608	0.08
377.2276001	0.10
378.1143799	0.20
389.3598633	0.06
392.8536987	0.18
403.1309814	1.48
404.1309814	0.07
426.9504395	0.61
435.2192383	0.03
463.2279053	0.08
479.0396729	0.05
479.9631958	0.09
480.9988403	0.54
497.4325562	0.18
507.1444702	0.54
515.8422241	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	471.0852
Annotation	Tjipanazole A1
Peak:m/z	Relative Intensity
137.0522003	0.29
137.9702759	0.61
149.9045715	1.29
157.0588074	0.36
158.0759125	5.15
158.9241180	0.27
163.8957977	0.50
165.0124207	2.29
169.2049103	2.46
170.1955109	0.55
175.1931915	0.56
178.1397552	0.33
180.0222473	1.26
181.2445374	2.09
181.9895325	0.13
183.0592346	4.01
184.1809998	1.01
195.0714111	0.82
196.8613281	4.86
200.2724152	0.36
201.0217896	0.85
207.1466522	0.64
208.3508911	0.12
211.1617889	0.28
212.1100159	1.60
214.1482239	1.87
215.0708160	6.00
216.0861359	1.22
220.1768646	0.88
224.1495056	6.91
225.0848236	2.42
226.1092377	11.54
227.1152344	0.44
229.1141968	1.46
230.2373352	0.84
240.5362549	1.34
242.0455933	74.03
243.0929260	22.46
244.1800842	1.24
245.2159424	0.73
247.0337524	15.38
248.0726318	11.61
249.0494995	0.18
256.1100464	8.20
258.0981750	8.03
261.1746216	0.68
261.8167114	1.31
268.9110413	1.60
272.0414429	1.79
273.1219482	8.52
275.0600891	3.84
279.2320251	1.10
288.0903320	2.16
289.0390015	1.11
290.1425171	12.23
296.8776550	6.94
304.0063477	0.58
305.1691895	0.15
306.0047913	4.63
307.0532837	3.72
308.1602783	0.51
313.3245850	0.81
314.2440186	0.35
322.3490601	0.44
323.3570557	0.96
326.7659912	0.26
328.8104858	0.26
331.4959106	0.63
339.1043396	36.12
340.3044128	3.42
342.4810791	0.72
343.3524780	0.21
345.3004150	0.75
348.7924805	0.47
355.8518677	0.31
358.1475830	0.47
359.2158813	0.16
366.7031860	0.69
370.8251038	0.25
380.1260681	0.65
385.1142883	0.21
388.4512634	0.37
391.7772827	1.26
393.0626526	1.54
394.1694946	0.36
403.2300110	0.47
405.2963562	22.40
406.2768250	1.34
407.4240112	0.13
408.1001282	0.13
409.1995239	0.70
411.0880127	55.84
412.1345215	41.95
413.0546570	0.38
422.1650391	2.00
423.1672058	0.39
424.2666321	0.59
425.0152893	3.15
429.2586365	2.76
430.1477966	0.52
436.2519836	2.11
437.1696167	1.50
439.4726257	1.28
452.1228333	0.33
453.1841736	37.68
454.1126404	100.00
455.3668518	2.55
461.9841919	0.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
95.03933716	0.34
112.9603271	0.71
124.2162476	0.44
126.8576431	0.44
134.9698944	1.84
139.0822754	0.68
143.0488586	1.82
148.7095032	0.80
151.2554016	0.45
152.571106	0.47
155.0498657	0.66
156.211792	0.53
156.8143921	0.37
160.7485352	0.28
163.0689392	0.44
164.1144104	0.44
166.8292542	0.32
169.0999603	1.44
173.0827332	0.33
175.2522278	0.27
179.075592	0.73
180.999527	3.13
183.0195312	0.39
186.0524902	0.25
195.0356598	2.37
197.0761108	0.71
198.8210602	3.40
205.0236816	0.44
209.3260803	1.10
210.9749756	2.31
221.0943298	0.35
222.2437439	0.47
223.3156433	1.97
225.0836792	2.58
227.2034912	1.15
233.1376343	1.95
235.0801086	0.49
236.8899231	0.35
240.6141968	1.67
241.3536682	0.86
247.2114258	1.41
248.4338989	1.05
251.0807495	1.37
252.1637268	0.68
253.0405884	4.67
254.9934692	0.20
265.0530701	1.94
267.1297913	3.21
275.2388306	14.22
277.2153015	2.12
279.4380798	0.86
283.3233032	4.49
285.1095581	0.81
290.637146	0.80
293.2122803	100.00
294.0666504	1.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	931.1136
Annotation	Unknow
Peak:m/z	Relative Intensity
301.0740356	0.27
308.2932739	0.35
311.1050110	0.14
319.2732239	1.57
326.1358643	0.83
368.9153442	0.39
412.1167603	0.09
416.9124146	0.55
424.3871460	0.25
429.3321533	0.54
430.4854126	0.43
440.3808594	0.71
443.3388672	0.56
447.1829834	2.17
448.2969360	1.68
454.9922485	0.52
456.2427368	0.67
493.3847046	1.02
512.3119507	0.15
518.1004028	0.61
538.1630859	0.58
539.5556030	0.51
542.3666992	0.27
551.5268555	2.60
552.1745605	0.70
558.3874512	0.27
569.2399292	0.29
575.1164551	0.24
578.0675049	0.69
584.2378540	0.60
587.1496582	3.38
597.3337402	0.73
610.5055542	1.12
613.6433716	2.07
622.5047607	1.57
625.5422974	0.20
627.2326660	0.73
636.4611816	0.19
640.6190186	0.31
647.4616089	1.83
650.5415649	0.31
655.2307739	1.92
656.3588867	0.54
663.2268677	0.35
668.2644653	0.57
672.1469116	1.32
680.5983276	0.41
681.3971558	0.79
685.2150269	0.43
687.4100952	1.42
690.1919556	1.96
690.8613281	0.84
694.2155151	0.77
703.2471313	0.16
708.0880737	0.78
710.8220825	2.52
711.5665894	1.46
716.7631226	0.46
717.6527710	0.18
721.4189453	2.12
722.2550049	0.17
724.8545532	1.78
725.7065430	4.99
726.4419556	0.36
736.8239136	0.17
739.2880859	5.61
740.4434814	1.02
741.5187378	0.23
746.0759888	2.79
752.5581665	0.44
753.1618042	0.79
759.0820923	0.13
760.2528687	0.39
771.7478027	1.03
774.7794189	13.97
775.4311523	8.30
776.4979248	2.24
779.5275879	0.71
782.4134521	0.66
783.4630127	2.96
792.0990601	0.92
792.8256226	0.86
797.2164917	1.95
798.6688843	0.15
801.3963013	3.30
807.6249390	1.19
810.3489990	31.51
810.9860229	8.93
811.6329956	2.20
812.4948120	0.62
834.9744873	0.54
837.5578003	0.53
842.3557739	0.11
846.0345459	22.22
847.5554810	1.58
854.5650635	2.05
858.9539185	0.60
861.7600708	0.17
863.6294556	1.04
864.6102295	4.30
869.1290894	0.43
871.3269043	0.58
875.4923706	0.93
881.4136963	8.34
882.3162231	1.68
882.9629517	1.82
891.3961792	6.70
892.0214844	5.56
893.1453247	0.80
895.7349243	0.55
896.6037598	0.59
897.4328003	0.38
901.7174683	15.14
902.6057739	0.48
903.2481079	0.31
904.0246582	1.21
911.5747681	0.22
914.1495972	0.13
919.3818359	0.44
938.3974609	0.70
939.6965942	0.31
947.2978516	1.28
948.1237793	2.45
950.8656616	0.29
952.3510132	1.95
953.4752808	0.57
956.3618774	9.82
965.3463745	1.07
968.6411743	0.45
969.6654663	0.40
974.6408081	0.26
982.3947754	1.90
987.1091919	0.97
991.8024902	7.41
992.6301270	0.62
996.1254883	0.72
996.7514038	0.36
1004.4897460	0.26
1006.5062870	0.52
1008.4308470	4.46
1010.3402710	11.53
1011.2798460	1.73
1012.5059200	4.81
1013.5310060	1.00
1017.9224240	0.60
1018.5463870	1.16
1020.4078980	0.44
1022.6626590	0.12
1024.5423580	0.65
1027.3137210	6.20
1028.0236820	0.36
1038.8551030	0.73
1040.4394530	0.82
1051.6083980	0.69
1066.0703120	0.16
1068.6431880	0.21
1073.1009520	1.02
1076.6896970	3.07
1077.4500730	0.22
1082.1384280	0.29
1083.5662840	5.02
1084.5297850	3.70
1085.4079590	1.95
1095.7276610	0.10
1096.3525390	0.55
1101.6291500	17.15
1102.4995120	4.60
1111.0573730	0.15
1132.3349610	1.46
1135.9617920	1.36
1141.0397950	0.10
1143.7517090	1.39
1154.5969240	4.05
1155.5910640	1.66
1172.6729740	12.42
1173.7619630	8.44
1174.5800780	1.10
1177.2619630	0.50
1178.5645750	1.04
1180.4365230	0.47
1212.2185060	0.85
1225.1171880	0.61
1226.7142330	0.32
1237.0957030	2.11
1237.7427980	0.13
1243.5740970	6.24
1244.7340090	3.14
1249.4697270	1.05
1250.5892330	0.53
1264.7917480	0.14
1281.1373290	0.30
1294.3740230	5.29
1295.4185790	0.80
1326.5164790	0.63
1335.5770260	0.98
1336.9510500	0.45
1339.7220460	0.83
1343.6812740	0.39
1351.8374020	1.79
1352.6265870	0.37
1354.6627200	0.15
1378.5621340	0.96
1407.3809810	0.22
1413.9187010	0.15
1420.8873290	0.15
1449.8142090	1.14
1450.4549560	0.34
1463.6735840	1.48
1464.5941160	1.10
1465.9328610	0.15
1479.5827640	0.39
1490.3828120	0.15
1535.5069580	0.44
1537.0754390	0.32
1548.6613770	3.04
1549.4790040	0.62
1561.7873540	0.15
1567.2028810	0.25
1592.5998540	0.28
1599.5706790	1.09
1600.9375000	0.11
1607.9027100	0.45
1617.3573000	0.18
1619.6975100	3.16
1620.6276860	1.70
1672.1434330	0.85
1689.5648190	0.50
1690.7420650	7.26
1691.7634280	5.45
1701.3977050	1.01
1705.9382320	0.79
1719.1418460	0.07
1722.3306880	0.10
1744.7043460	4.07
1766.0618900	0.66
1769.1623540	0.44
1771.9439700	0.18
1773.1960450	0.41
1779.1632080	0.77
1796.4447020	2.71
1806.2146000	0.11
1811.7800290	1.56
1828.1770020	2.54
1830.0357670	0.28
1834.8394780	1.29
1840.6527100	1.19
1843.8250730	1.27
1848.5513920	0.86
1851.3127440	7.93
1857.8737790	1.03
1866.1436770	1.00
1867.0256350	0.48
1872.0716550	1.09
1873.6135250	0.58
1874.5432130	1.14
1877.5109860	0.45
1878.3680420	1.43
1879.2757570	0.26
1880.5987550	0.43
1883.7507320	0.31
1886.8900150	0.20
1889.1915280	3.32
1891.5479740	0.53
1893.9880370	0.09
1895.3914790	0.10
1900.4478760	8.12
1907.5125730	0.43
1908.6335450	0.53
1909.4196780	8.82
1911.3114010	4.42
1912.3348390	0.32
1913.5914310	0.69
1915.2528080	0.18
1916.9056400	0.65
1920.2122800	0.26
1923.5089110	0.80
1929.7130130	5.43
1931.2642820	58.43
1932.4108890	0.28
1934.6820070	0.35
1935.6053470	2.07
1937.4403080	1.39
1940.1496580	0.92
1944.4229740	0.70
1947.1414790	0.63
1949.4322510	0.11
1951.0501710	1.70
1951.9327390	100.00
1953.6846920	0.19
1956.6048580	0.54
1958.1644290	0.27
1960.3944090	21.34
1962.3640140	16.91
1964.0379640	0.81
1965.8786620	0.52
1966.5714110	0.23
1970.1195070	0.79
1973.3322750	1.78
1974.4411620	2.56
1976.3162840	5.62
1977.7169190	1.15
1979.1317140	4.76
1980.4377440	9.61
1981.6784670	17.75
1982.9056400	15.01
1983.7990720	0.69
1985.7170410	0.61
1986.8845210	84.23
1987.6170650	0.32
1988.5222170	15.76
1989.1417240	13.76
1990.1213380	0.18
1992.2669680	5.60
1993.8575440	1.27
1995.7585450	3.42
1997.2215580	0.51
1997.9005130	1.28
1999.8406980	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.1594
Annotation	Rutin
Peak:m/z	Relative Intensity
303.0617676	100.00
304.1673889	56.69
355.2263184	2.48
357.3917847	5.91
387.30896	4.61
459.4470825	9.90
465.1605835	8.30
465.9868164	34.82
490.4140015	4.68
496.81073	5.02
509.7785034	5.16
540.7925415	7.15
556.8605347	22.92
569.5319214	2.00
593.2593384	2.00
593.9055786	7.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	600.4159
Annotation	Unknow
Peak:m/z	Relative Intensity
169.0080566	0.87
173.1287689	1.40
174.8544617	0.83
176.1881256	0.44
177.7119904	0.27
179.2917633	1.46
181.1960297	1.43
182.0861969	0.40
182.9888306	1.21
184.8807373	0.56
186.3238525	0.49
189.1804504	0.53
189.9899292	3.68
192.0186462	0.33
193.2058868	2.01
194.3470154	0.67
196.2367401	0.76
196.9983215	1.99
199.0568695	1.62
200.1852722	1.44
201.2041779	0.99
202.4409180	0.84
203.0843658	1.34
205.2171173	1.96
206.9971924	1.37
208.1707306	1.00
209.0863342	5.91
210.1689453	1.68
211.0166321	0.94
215.1613464	0.31
217.4313202	0.44
219.2719727	0.74
221.1195831	24.82
222.2865753	0.33
223.2197723	2.47
225.0986176	1.60
227.2854004	0.25
229.2592773	2.56
230.2134399	1.64
231.0633392	0.25
233.1494446	5.78
234.1949158	4.55
235.3307190	1.32
237.1563416	20.35
239.2720490	0.60
241.3154755	0.67
243.1730652	0.36
245.3062744	1.18
247.3562317	1.46
248.1872864	7.40
249.2035828	1.73
251.1194458	3.76
255.1360474	2.99
259.0718384	3.00
261.2846069	1.15
263.2046509	3.22
264.0988464	0.50
265.4770508	1.35
266.3956299	1.56
267.2938538	0.31
268.1766357	1.24
269.3817139	0.29
270.2792664	0.64
271.2249146	2.21
273.1893311	0.96
274.2260132	7.62
275.1721802	1.21
277.3863220	2.24
279.1914368	3.17
281.1244812	1.96
282.0663757	0.90
283.2119141	1.09
285.2635498	2.21
286.3226929	5.62
287.2480469	10.30
288.5833130	0.27
289.3130493	1.45
292.3739624	0.60
294.2261353	0.71
296.2169189	0.63
297.3104248	0.52
298.2384644	1.26
299.2108154	9.85
300.4037476	1.84
301.1338806	2.02
303.3843994	6.54
304.2932129	0.27
305.4192505	0.44
306.4664612	0.31
307.2695312	1.84
309.4687500	0.50
311.3059692	1.45
312.4118347	3.59
313.3098145	2.15
314.1379395	1.10
315.2787476	3.24
316.1421204	1.46
317.3866272	0.65
318.4890747	0.42
319.4832764	1.05
321.1834106	1.78
322.3533936	1.15
323.6817017	0.48
325.3261108	19.05
328.2039795	0.66
329.2943115	0.49
330.0888672	0.75
331.3536987	1.39
332.2910156	0.49
333.2186890	2.67
334.2695312	0.78
334.9702759	1.73
337.1981201	2.91
340.2016602	0.18
341.5192871	2.05
343.4342651	1.84
345.3085327	0.33
347.3726196	2.90
349.2749023	3.59
351.2463989	1.15
352.4299316	35.01
353.2789917	0.82
355.3301392	2.84
357.4161987	0.37
359.2932129	6.19
360.4811401	0.73
361.3682861	2.55
363.2716675	0.16
364.4190063	2.60
365.3557129	7.31
369.4369507	0.61
371.7715454	0.59
373.2214966	4.14
374.2934570	2.60
375.3286133	2.11
377.2646484	3.34
378.4479980	3.89
379.3008423	1.53
381.3627930	0.82
383.3939209	5.37
384.6004639	1.37
385.5220947	1.32
386.7727661	0.79
387.4003296	0.50
388.1860962	1.12
389.1741943	1.27
390.6209106	1.50
391.3482056	6.77
392.0928345	3.76
392.6956787	0.32
393.5979004	0.35
395.1899414	0.39
399.3433228	1.71
400.5308228	0.42
401.4683838	2.41
402.2185059	0.72
403.2996216	2.40
404.4805298	0.27
405.5263672	2.58
406.4999390	0.56
407.3610840	1.56
409.3466187	0.23
411.9620361	0.54
413.2849731	1.41
414.4951172	0.79
415.1823120	2.45
415.8151855	0.44
416.6064453	1.93
417.5937500	1.01
418.7955322	5.75
419.5257568	4.10
420.5269165	1.90
423.3540649	5.02
425.3375854	0.20
427.7827759	0.83
428.4182739	0.71
429.3491211	3.30
430.6923828	0.61
431.8012695	1.43
433.2525635	0.71
434.3427734	0.52
435.7596436	0.27
436.9969482	1.22
439.7049561	1.49
440.3444214	0.61
441.2631226	7.83
442.4276123	1.66
445.3186035	1.85
446.4767456	1.34
449.7395630	1.47
450.3578491	0.42
454.4000854	11.85
455.4668579	2.94
456.4309692	0.48
457.0934448	0.44
457.8434448	0.59
460.5258789	0.89
461.4506836	2.78
462.2262573	0.29
462.8368530	0.37
463.4775391	9.40
464.3807373	0.59
465.2315674	0.40
469.6586914	0.50
472.4008179	0.36
473.2598877	1.39
474.9707642	1.93
475.5747070	1.16
476.4826660	0.67
479.5308838	0.65
480.4641724	2.06
481.7677612	1.04
484.2827148	0.65
485.1820068	0.71
488.8469238	1.03
489.5087891	2.81
490.5660400	4.54
492.4377441	1.24
493.3923340	1.21
494.5716553	3.10
495.4371948	0.18
496.7823486	0.31
498.4266968	0.61
501.2257080	0.83
502.5184326	8.39
505.2235718	2.54
507.3613892	78.81
508.4901733	26.38
513.0110474	1.27
513.8590088	0.43
515.4959106	1.52
520.4152832	100.00
521.4881592	2.08
523.6602173	1.20
525.3361816	2.67
526.9201050	3.21
527.6354370	0.48
530.4607544	0.73
536.3410645	0.29
537.5918579	0.72
539.7646484	0.18
541.3197632	0.97
542.4022827	0.32
543.0885620	0.40
543.8474121	1.14
549.6414795	0.27
552.2444458	0.90
554.4298096	0.62
557.4506226	0.29
563.4359741	7.48
564.6215210	4.27
565.7124023	0.39
567.5238647	8.60
571.5533447	1.26
580.2317505	0.31
581.5003052	36.89
582.5171509	37.80
583.5154419	2.32
585.5112915	7.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	295.03
Annotation	Unknow
Peak:m/z	Relative Intensity
96.9276962	0.85
98.8767242	1.05
108.8466110	2.82
126.9274902	21.36
132.7713165	1.50
144.3405457	0.47
146.8752594	0.40
150.8934021	7.67
205.0002136	1.49
217.1354980	0.56
219.0448914	0.51
246.4416504	1.14
248.0758362	0.36
249.2462769	5.70
253.3654175	0.69
258.9252625	37.80
264.8254700	0.65
267.2913818	0.62
276.9825439	100.00
476.4087524	1.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0232
Annotation	Unknow
Peak:m/z	Relative Intensity
176.9530640	4.09
201.0382996	1.02
220.9203949	100.00
234.9107056	0.13
239.2745972	0.13
247.2245483	0.64
322.8826599	0.76
332.9880371	0.99
342.9751587	0.23
344.0884094	0.17
387.4545593	0.11
412.3246765	0.23
413.0850830	3.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	473.1589
Annotation	Neocalyxin A
Peak:m/z	Relative Intensity
140.0797424	1.18
145.0959015	0.35
153.9289856	0.12
157.8395996	0.04
159.0284119	2.77
169.1276093	0.07
184.1000671	0.05
193.0248718	0.06
194.1696625	0.14
195.9299164	1.61
208.8798523	0.15
213.0662384	9.56
214.1217651	0.42
221.1810913	0.06
226.1802216	0.05
231.0636292	1.45
241.2326202	0.06
251.2287903	0.07
256.0712280	0.34
257.1505127	0.08
259.0946655	100.00
281.4139709	0.22
294.1619568	0.09
298.3665161	0.15
299.0532227	0.06
299.6800842	0.06
326.1084595	0.19
327.1981201	2.63
328.2031860	0.13
328.8143311	0.04
358.0711365	0.06
359.3027649	8.48
372.1351624	0.15
375.3384399	0.11
377.3048401	0.32
383.1766663	0.06
389.4503174	0.26
394.3215942	0.10
395.8381348	0.19
399.0349731	0.23
409.2002258	0.16
410.3638000	0.08
411.1507263	0.05
425.6748962	0.35
427.2065735	8.37
428.1253662	0.23
429.1538086	0.77
432.4772034	0.09
437.4480591	0.09
438.5737000	0.05
442.4814758	0.19
443.2690125	0.05
455.2568665	3.02
455.9700928	0.51
464.0143433	0.54
473.1605835	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	307.42
Annotation	Unknow
Peak:m/z	Relative Intensity
98.0219269	0.30
111.8911285	8.13
112.9440231	5.51
114.1847229	0.79
115.0597305	2.21
116.0248718	0.21
125.0882339	0.24
127.1703339	0.06
128.9522400	0.95
129.9848175	0.09
140.1606750	0.07
149.8532104	2.10
156.9449615	1.80
158.0498199	2.15
159.0464325	0.38
165.0420532	0.21
168.0484772	0.15
169.1098328	1.10
170.2135773	0.04
171.5156250	0.05
175.1452942	1.61
175.7868958	0.11
182.1003876	0.65
183.0908203	7.78
183.9360962	0.57
185.3255615	0.30
201.0663147	0.13
201.8987732	0.08
204.0585632	1.33
207.1657104	0.06
209.0677185	0.84
212.0246277	2.53
213.0496521	0.61
218.8266296	0.12
220.1953430	2.00
221.1120300	0.09
224.2383728	0.60
226.0886230	70.49
227.1799622	5.78
229.1074829	34.73
230.1578064	2.48
242.1109009	0.15
243.2120667	4.27
244.1925964	0.52
245.0634460	0.36
247.0013733	100.00
248.0111084	48.35
249.0245972	3.21
261.1504517	0.72
263.3036499	0.10
265.0958252	4.50
266.1026001	0.46
272.1269531	6.26
273.0613098	24.12
274.2164307	1.17
275.1763611	1.33
278.9337158	0.13
286.1071472	0.22
287.4441223	2.24
289.0847168	30.14
290.0326843	55.74
291.0155945	5.38
291.7979126	0.20
292.6850586	0.85
293.9588013	0.78
298.4112854	0.21
301.2156982	1.77
309.2619019	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2875
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
135.8704834	5.10
161.0801392	3.29
163.1388245	5.93
168.0058746	2.87
169.2679291	7.22
185.2037506	13.13
186.7081146	7.56
189.2453308	4.96
195.5944061	5.59
204.1540527	8.41
224.8615417	2.70
232.0084229	6.59
245.7993469	4.69
258.186676	3.32
268.0200806	3.51
291.2615051	12.52
294.2386169	8.67
298.3380432	6.17
303.5068359	5.55
314.2672119	19.05
323.3208923	4.55
327.348999	2.72
336.4638367	12.18
339.302948	27.72
340.3953247	14.37
352.3784485	1.66
356.5402832	8.58
359.1408386	9.62
360.1438293	2.90
366.556488	5.30
369.2827148	34.56
370.0551453	3.87
372.3035583	4.69
375.3283081	11.66
377.4212341	15.81
380.283844	9.03
381.1665344	9.85
384.3250427	1.87
388.54245	3.72
390.3297424	9.93
391.091156	12.31
395.1880188	8.30
396.1235352	4.75
397.9250488	9.02
407.5185547	36.97
408.2689819	100.00
416.3620911	13.60
426.8475037	3.89
427.7828369	7.60
436.9311523	13.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.17
Annotation	Verbasoside
Peak:m/z	Relative Intensity
135.1418457	0.48
146.0324402	2.86
150.9399719	0.04
159.0373230	0.07
161.1490479	2.22
163.9521484	2.67
179.0100861	45.93
185.9254761	0.15
191.0397491	0.17
196.2493286	0.05
213.3608093	0.06
221.2554016	0.31
232.3586731	0.08
235.1798248	1.10
238.4031830	0.11
242.9524384	0.09
253.2739258	0.16
255.0704956	0.04
259.2672729	0.15
261.3449707	0.18
262.4834595	0.08
263.1837158	0.09
267.2595215	0.11
268.1687927	0.18
283.3316650	0.36
296.2774963	0.05
299.2686157	0.76
306.1351929	0.13
313.2443237	0.04
314.3277893	0.07
326.6086426	0.19
327.2954712	0.04
339.0585632	0.36
341.1172180	0.36
344.1148682	0.16
345.1965027	0.16
350.3377380	0.14
355.3131104	0.15
359.3353882	0.17
360.5391235	0.08
369.1448059	0.38
372.8735657	0.08
379.2974548	0.42
381.1753540	0.20
393.0084534	0.20
395.5398560	0.06
396.3206482	0.24
397.1655273	0.28
398.3441467	0.27
399.1728821	0.09
412.3517151	0.25
413.3261108	0.09
415.0829773	100.00
415.6848450	0.76
416.3489380	0.17
417.2159729	0.32
424.3046570	0.05
425.3829041	1.80
426.3797607	0.26
427.6120300	0.11
430.1213074	0.12
431.4189148	0.15
441.3290100	0.06
442.3972473	2.14
443.2519836	1.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.08
Annotation	Didymocalyxin C
Peak:m/z	Relative Intensity
100.7399368	0.04
113.1365814	0.16
113.8740616	0.02
119.3059692	0.04
143.2377777	0.05
160.9978943	0.12
163.1654968	0.02
178.9364319	1.12
179.8440247	0.22
181.0645447	0.02
197.0794067	0.23
198.0799255	0.14
198.9719238	0.97
215.0442200	1.65
216.1790619	2.70
217.0062866	9.67
221.1672974	0.05
251.9629517	0.09
341.1821899	100.00
342.1555176	34.41
343.1769409	10.32
345.1610107	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	642.1008
Annotation	Unknow
Peak:m/z	Relative Intensity
235.2354736	0.90
258.9594727	0.68
264.8198547	0.50
271.3522339	0.74
276.8844604	6.79
294.8678589	8.24
302.9872742	0.26
304.7811890	0.19
318.9210510	0.13
330.0032349	0.52
331.2763672	0.64
340.0670776	0.28
343.9636230	0.37
347.2362671	0.65
360.6988525	0.17
361.5032959	0.13
367.0348511	0.49
384.1876831	0.16
385.1458740	1.61
393.1938477	0.26
403.0756836	2.47
409.1205444	1.59
415.3746338	0.37
421.1266479	0.19
426.5598145	2.99
427.1649170	2.52
432.1243286	0.82
433.1585083	0.58
437.7055664	0.26
438.6936646	0.35
443.7539673	3.37
444.8012085	24.33
450.1258545	0.12
456.3257446	0.35
457.0541382	1.28
460.2022095	6.41
461.1803589	0.98
461.8751831	0.25
469.3022461	0.86
480.0330200	1.44
483.4370728	0.57
486.4837036	2.53
487.1587524	1.72
494.2322998	0.39
502.2421875	0.13
511.4776001	0.32
519.2299194	0.27
523.6654663	1.19
534.8923340	17.48
535.5991821	0.27
537.0827637	0.78
540.3931274	0.35
551.2426147	1.11
552.3450317	9.85
552.9738159	44.78
560.5523682	0.37
570.2502441	7.00
570.9528198	74.32
572.0337524	0.60
586.1955566	0.63
587.2465210	2.51
588.7484741	100.00
589.5449829	0.89
596.4282837	0.33
597.7152710	0.69
604.0007935	0.13
606.4490356	9.49
607.1511230	0.63
614.1209106	0.19
614.8037720	0.23
616.2532959	2.40
623.3991699	2.40
624.4187622	1.02
642.2537231	0.17
645.2689209	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	266.9789
Annotation	Unknow
Peak:m/z	Relative Intensity
78.8806763	0.28
86.9305878	0.03
89.0631714	0.05
95.0051956	0.87
96.8524475	2.72
113.0236053	8.34
113.9869080	1.75
130.9317932	100.00
222.8585663	0.03
249.0608368	1.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2777
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
140.0459290	0.13
152.9853210	0.08
170.9822083	0.01
195.8846436	0.14
214.1841125	1.12
245.9635162	0.01
259.3678894	0.02
261.4947205	0.16
275.0649719	0.01
279.2575073	100.00
280.0878296	0.00
392.8610535	0.01
398.5071106	0.01
419.9733582	0.02
429.5724792	0.04
430.2137146	0.01
431.1990051	0.03
432.3431396	0.01
437.2467346	0.03
440.2747498	0.04
453.8129883	0.02
456.1983948	0.01
457.2946472	0.05
458.0182800	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	630.1328
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9884186	0.12
229.2301636	0.44
252.1286163	0.97
277.1884155	0.48
286.1265564	0.43
287.2303467	0.39
299.1949158	0.52
303.1871338	7.15
304.2885132	1.48
312.2431641	0.87
325.1504211	9.45
325.7839050	1.09
328.1481934	2.80
341.0249023	0.46
346.9276123	0.27
397.1778564	1.23
397.9550171	2.62
398.8007812	0.45
406.5136108	3.07
428.5379639	0.21
442.7647095	0.36
444.7388916	0.30
447.0623169	0.17
450.4448242	0.24
451.3345337	0.72
461.8080444	0.95
465.0593872	0.98
467.2097778	1.83
468.2417603	1.27
469.2739868	1.92
473.2254028	0.97
476.2619019	100.00
477.1090088	1.55
478.0334473	0.39
479.1715698	43.56
479.7988281	15.29
480.9151001	0.26
485.3132324	0.66
486.6300049	2.50
497.0462036	0.97
498.4931030	0.95
500.0257568	0.70
504.0535889	0.62
508.5011597	1.48
512.0392456	0.85
521.0211792	1.91
525.3632812	0.32
539.2996216	0.63
548.1776733	4.90
549.5039673	2.00
556.2097778	1.07
557.3798828	18.34
558.3201904	0.87
567.2272949	0.30
570.1027222	0.92
576.5755005	0.21
594.1989136	0.50
611.1298218	1.33
612.2669067	0.86
613.6036987	0.61
621.2019653	0.45
630.2177734	5.30
631.1030884	7.39
632.2991333	0.33
649.0614014	11.36
649.9726562	0.72
708.7135620	0.78
768.4304199	1.53
804.9895630	0.99
806.0535278	0.80
951.0610352	87.68
952.2553711	35.10
967.2041016	0.39
993.4078979	0.17
995.7868042	0.41
1071.5150150	0.86
1095.3414310	0.55
1096.1193850	0.77
1113.2666020	7.20
1114.1466060	3.87
1144.4190670	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	497.2239
Annotation	Unknow
Peak:m/z	Relative Intensity
263.2615662	0.09
274.5825195	0.06
289.4166870	0.09
309.5479126	0.06
316.2634277	0.07
317.1077271	0.15
323.1641846	0.31
330.9254456	0.05
333.0567627	0.06
341.2911987	0.08
378.2852478	0.08
401.3771057	0.17
434.1789856	0.09
451.2765198	100.00
451.9254150	0.30
453.0440369	0.13
453.8889771	0.07
454.7821655	0.10
457.8616943	0.07
460.2292480	0.05
461.1403503	0.18
462.2725525	0.13
467.3283997	0.19
474.2352905	0.07
476.3358765	0.45
477.2429810	0.03
479.2219543	0.36
482.2348328	0.24
496.8739319	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1752
Annotation	Rhamnocitrin 3-glucosyl-(1->2)-galactoside
Peak:m/z	Relative Intensity
201.1978607	0.05
236.0432434	0.05
247.1551056	0.06
253.6434631	0.07
254.5081787	0.02
255.1207886	0.05
260.7420044	0.07
285.2071533	0.44
287.3626709	0.06
302.1830750	0.31
309.2186890	0.05
317.1135254	100.00
318.1323853	0.12
328.9561157	0.03
345.0991211	0.02
358.9534912	0.27
374.3367920	0.18
383.2423096	0.10
392.2336426	0.03
413.4078979	0.04
425.3587646	0.08
444.2772827	0.04
445.0494385	0.23
453.2575073	0.07
459.1927490	0.02
461.1568604	0.80
462.3957520	0.85
463.0566406	3.42
468.4105225	0.09
478.9587402	31.60
479.6790771	0.11
482.1663818	0.07
503.2279663	0.23
505.2458496	0.16
509.2410889	0.03
520.8702393	0.04
533.9758911	0.07
535.4124146	0.14
538.9624023	0.05
545.3224487	0.03
565.4906006	0.13
571.3020630	0.20
589.1718750	0.16
604.7736206	0.20
606.5278931	0.11
607.3372803	0.26
615.8994751	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	600.416
Annotation	Unknow
Peak:m/z	Relative Intensity
169.3077393	0.23
171.1549988	1.80
172.8982391	0.64
175.4026184	0.40
176.1910248	0.16
177.3682098	0.57
178.2320862	1.09
179.1655426	0.99
181.1129608	1.07
182.1221924	0.40
182.9955750	0.36
185.2086792	0.53
187.0855255	0.72
189.3700867	1.13
190.1488037	0.85
191.1513977	1.86
192.0698242	0.37
193.3916626	0.24
194.8349609	0.96
197.0297394	2.00
197.9080811	0.48
199.1287079	2.29
200.1647797	0.27
201.1515350	0.19
203.2063599	4.70
205.0488739	1.00
206.1558228	0.78
207.0070190	1.30
208.2127686	2.30
209.1720123	4.08
210.2214050	1.18
211.1277466	0.57
212.5701294	0.90
213.2361145	0.77
214.2057495	0.60
215.1514282	1.27
216.1350250	0.39
217.0817871	0.32
218.1700745	1.32
219.1267090	1.12
221.0915070	25.23
222.2944183	0.54
223.1197662	3.88
224.2864685	0.12
225.3302765	2.22
226.1851196	0.24
226.9952240	0.24
228.6565857	0.37
229.5492249	0.24
230.7389374	0.41
231.5083313	0.15
233.0734558	6.80
234.2229614	3.73
235.1872253	2.52
236.5638428	1.03
237.1862793	15.34
238.1574554	0.23
239.1651917	0.08
240.0721283	0.74
241.3187714	1.04
243.1852417	1.29
244.1335449	0.42
245.2794800	1.65
246.5250244	1.17
247.2708435	2.72
248.1753235	5.97
249.3173523	2.38
250.3037720	2.27
251.3229218	3.33
252.0072327	0.26
253.3565063	1.37
255.2045288	1.64
256.3707275	0.17
257.2177429	0.61
258.1655273	0.40
259.2689209	4.04
260.2703857	1.28
261.3115540	1.49
262.3062439	1.58
263.2814331	3.57
264.2081909	0.80
265.2129517	4.37
266.1981201	0.38
267.1184998	1.73
268.5254211	2.09
269.3205566	1.30
270.2475891	3.44
271.2119751	1.30
272.2595215	0.23
273.2214355	4.40
274.2415466	6.34
275.3046875	4.65
276.3377686	0.27
277.0758057	1.61
279.3424683	0.68
280.8102417	1.63
281.7339478	0.71
282.3624268	0.95
283.1914062	0.60
284.2279663	1.39
285.3637085	2.37
286.3792114	9.30
287.3611450	4.30
288.4404907	0.60
289.3206787	2.89
291.2225342	1.55
292.0763550	0.35
293.2904968	2.02
294.2353516	1.63
295.1481628	2.32
296.3138428	0.11
297.0921631	0.96
298.3498535	2.75
299.3031006	13.00
300.4044189	2.03
301.1948242	1.99
303.1523438	6.41
304.5064087	0.14
305.4586487	0.93
306.2119751	0.90
307.1726074	1.73
309.2442627	0.85
311.1856079	8.12
312.3767090	1.35
313.3471985	4.40
314.3237915	0.99
315.2950134	2.62
316.5739441	0.78
317.3374634	1.75
318.1424866	0.32
319.3822021	2.31
320.1592102	0.33
321.3300171	2.24
322.2607727	0.46
323.3341980	1.61
324.6995239	3.02
325.4146118	12.39
326.3655396	0.11
327.3493652	1.63
329.2200317	1.32
330.2401123	0.33
331.3009033	0.15
332.1798706	0.11
333.2689209	2.70
335.3092651	1.27
337.3140259	2.34
338.5417480	2.30
339.3757324	1.40
340.5744019	0.77
341.3487549	1.84
342.4357300	0.48
343.2641602	1.62
345.2789307	1.82
346.4302368	0.72
347.4222412	1.78
348.2955322	0.31
349.3073730	0.57
352.2278442	52.31
353.0851440	1.84
354.3103027	1.30
355.3214722	4.43
356.2528076	0.51
357.1299438	0.40
358.4783936	0.30
359.1267090	3.08
360.2445068	1.93
361.3305054	2.84
362.6174316	1.66
363.4529419	3.43
364.3378296	3.36
365.3374634	10.47
366.0939941	0.53
367.3276367	2.16
368.1766968	0.27
369.4096680	1.86
370.3585205	0.33
371.3073730	0.49
373.3767090	4.07
374.3515015	3.43
375.3556519	1.13
376.4408569	2.59
377.4218140	10.38
378.4829102	1.80
379.4426270	1.77
380.6945190	0.70
381.7578125	1.46
383.3869629	4.74
384.3771973	1.04
385.1151123	0.36
387.3235474	4.03
388.3706055	4.37
389.3678589	2.95
390.1802979	0.79
391.2479248	10.30
392.3082275	2.75
393.3958740	1.30
394.4117432	0.34
395.3309937	2.12
396.4653931	0.57
397.5301514	0.17
399.0509644	0.92
400.0119019	0.84
401.3292236	5.67
402.0852051	0.55
403.1207886	1.55
405.3855591	2.73
406.3469238	0.56
407.0458374	0.62
408.2957153	1.07
409.3622437	0.45
410.4713135	1.70
411.5052490	0.84
413.4708862	3.28
414.8750610	0.43
415.4825439	2.82
416.3613281	1.32
417.5729370	1.15
418.3732910	2.27
419.3796387	4.93
420.3336792	0.47
421.1851196	0.27
422.4124146	0.18
423.5228882	0.64
425.7586060	1.78
426.5166016	0.47
427.5546265	1.81
428.4628296	1.16
429.4013672	3.50
430.2932739	0.72
431.4735107	4.22
432.4318237	1.81
434.3568115	0.24
435.4713135	1.09
436.3862915	0.72
437.4003906	1.63
439.4616699	2.87
440.7219238	0.26
441.3453979	6.96
442.4121704	1.21
443.3588867	2.26
444.3278809	0.80
445.3585815	0.94
447.5132446	1.46
448.2457275	0.42
450.3074951	0.49
451.4608765	0.22
453.4489136	1.31
454.4346924	8.16
455.2957153	0.95
456.6610107	1.43
457.5083008	0.91
458.5169678	0.58
459.4140015	3.60
460.8709717	0.53
461.6987915	0.76
462.6585693	1.16
463.4793091	11.03
466.6571045	0.42
467.7442017	1.47
468.5126343	0.32
471.4909668	1.16
473.3163452	0.48
474.2509766	1.80
475.3436890	0.90
476.6376343	1.53
477.2482300	0.40
479.2744141	1.67
480.3619385	1.09
481.3275757	4.39
482.0589600	0.88
483.6216431	0.32
484.5935059	0.16
485.1937256	0.54
486.4608765	0.19
487.4036255	0.60
488.5969238	0.20
489.3311768	2.18
490.4310913	5.70
491.0890503	0.16
492.4423218	1.09
493.5249634	4.94
494.7510986	1.70
495.4104004	0.11
497.3887939	1.23
499.3530884	1.46
500.6734619	1.23
501.4181519	0.95
502.3617554	10.76
503.5095215	2.48
505.4475708	1.92
507.3760376	89.72
508.4483032	30.55
509.5447388	0.31
513.5343628	0.72
515.6238403	0.80
516.9210815	0.44
518.7595215	2.28
520.3515625	100.00
521.1948853	0.54
522.2575684	0.16
523.2112427	1.00
525.1586304	2.10
526.3775024	1.29
527.3157959	0.19
528.9970093	0.17
532.7141724	0.45
536.4909668	0.20
537.8500977	0.46
539.3418579	0.69
540.3786011	0.48
541.4895630	3.11
542.6063843	1.58
543.3320923	3.09
544.5969238	0.42
546.2577515	0.20
549.4976196	3.01
550.5878296	0.49
551.5215454	0.27
553.4390259	0.37
554.5127563	0.81
555.6637573	0.44
557.6646118	2.17
558.8292847	0.60
563.4537354	7.00
564.5274658	5.67
567.4794312	8.86
568.5327759	1.61
571.0194702	0.12
572.5463257	0.39
574.7681274	0.42
581.4931030	51.80
582.5547485	45.41
583.5052490	3.95
585.4741821	5.16
586.7804565	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	531.7716
Annotation	Unknow
Peak:m/z	Relative Intensity
170.3174133	0.21
186.0152588	0.20
187.0295715	0.20
199.1569366	0.09
204.3001404	0.45
254.4456787	0.20
258.0693970	0.26
274.1942749	0.73
281.2459717	1.75
283.3052368	0.27
284.2838745	0.39
285.1748657	0.28
299.3862915	0.79
300.0418091	0.23
301.1626587	0.71
302.3292847	1.08
321.4659424	0.12
325.0789185	0.16
353.3616943	0.27
367.7782593	0.83
369.3278809	1.10
380.2089844	0.80
381.2410889	4.96
382.4472046	0.29
398.2850952	20.18
399.3197021	2.84
400.2031860	0.70
416.4660034	1.06
418.5640259	0.58
425.3690796	0.44
435.6027222	0.41
438.1429443	0.18
443.9733276	0.86
450.2301636	0.35
453.4476929	0.22
456.0888672	2.57
457.2341309	3.79
461.8007202	0.24
476.4886475	0.66
477.2235107	2.30
481.1232910	7.35
481.8995361	0.58
485.1441040	1.98
485.9494019	0.89
488.7157593	1.60
491.2944946	2.55
495.5410767	3.81
496.2471313	0.27
499.4724731	5.16
500.1196899	2.42
500.9382324	0.23
502.3569336	0.57
506.1517944	2.27
513.3555908	0.35
514.1712036	0.40
515.8607178	2.09
516.4835205	1.45
517.3137207	1.02
518.8885498	4.70
520.7752075	2.61
521.4183960	1.02
522.1437378	0.24
522.9013062	5.43
523.5540161	6.72
536.7672729	1.09
540.2861328	0.87
542.8123779	3.93
549.4105225	0.31
553.3475952	0.60
562.1155396	0.57
568.4275513	0.32
570.6685181	9.97
571.3609009	2.07
576.5888062	100.00
577.4255371	5.82
578.1250000	0.45
579.3415527	0.20
583.5162964	0.19
590.2091675	0.26
592.8490601	2.20
594.2862549	5.13
598.8095093	1.38
599.5453491	0.94
603.2078857	5.94
604.1491089	1.32
608.9124146	9.66
609.6769409	5.58
613.5221558	0.61
619.1308594	0.24
626.1549683	2.62
627.3062134	2.07
628.4412842	2.75
635.0643311	5.15
635.7119751	3.27
636.6109009	0.13
637.9070435	0.76
639.9699097	1.18
641.3327026	41.97
642.0928345	1.68
642.7504883	0.74
644.3940430	0.47
645.4130859	0.94
646.2249146	3.79
647.6250610	5.60
648.9766235	0.24
651.5626831	1.74
654.3171387	10.91
655.1413574	1.02
655.7952271	1.37
660.2332764	63.57
660.8906250	20.04
662.1884155	1.35
663.4151611	0.30
664.4531860	0.30
665.0558472	1.16
665.7911987	2.58
666.8540649	0.59
668.1938477	0.16
671.7265625	0.41
686.8690796	0.36
699.7401123	0.25
703.4618530	3.07
705.9607544	0.58
714.9399414	3.31
715.9989014	0.22
726.4558716	0.36
728.6435547	0.61
738.2798462	0.20
744.5381470	0.40
754.5906372	0.24
755.6293335	0.64
763.8269043	2.79
771.7595825	8.95
772.4378052	1.02
777.1401367	0.57
802.8251343	0.74
812.3651123	0.54
820.2560425	0.67
822.6829224	0.31
825.0590820	0.46
831.3806152	1.47
840.5563354	5.19
841.2991333	1.05
846.5510864	0.18
847.6198730	0.80
860.5862427	0.46
863.2229614	0.68
866.4276733	0.16
869.2562866	1.16
875.0153198	0.82
877.2767944	0.40
889.0276489	0.85
891.1884766	0.86
897.4306641	0.81
925.5542603	0.16
930.5674438	0.22
937.0114746	0.56
941.6624146	0.93
956.6152344	0.30
1036.4199220	1.01
1045.8719480	0.33
1112.8909910	0.46
1187.6666260	0.60
1208.7602540	0.17
1225.8043210	1.27
1375.6870120	0.30
1638.8201900	0.15
1769.0887450	0.13
1804.9763180	0.28
1824.4139400	0.54
1827.9791260	2.98
1833.5152590	7.56
1848.5584720	0.24
1860.5949710	0.22
1868.3465580	0.16
1877.5764160	13.78
1884.1236570	1.10
1889.4080810	5.37
1894.6638180	1.39
1896.2756350	2.69
1906.3431400	0.16
1907.3111570	2.56
1908.6055910	0.19
1909.3835450	32.19
1911.8229980	4.58
1912.4659420	0.94
1913.6014400	0.25
1915.3995360	1.35
1922.2033690	5.31
1925.4338380	0.26
1926.2048340	2.38
1933.7476810	3.83
1934.4180910	2.50
1938.5692140	0.43
1939.2706300	0.12
1942.3819580	9.74
1945.2033690	1.16
1949.0173340	1.94
1950.1890870	2.12
1954.1437990	2.37
1955.0062260	0.41
1956.4661870	0.23
1962.4152830	1.06
1963.0587160	5.87
1965.4168700	78.15
1966.5469970	0.77
1969.8585210	0.33
1970.7888180	0.26
1972.3684080	13.62
1974.8050540	2.52
1976.4320070	0.28
1977.3469240	0.16
1978.1434330	10.26
1978.7766110	0.50
1980.0080570	0.81
1985.0001220	1.18
1990.7590330	1.32
1997.4532470	0.22
1999.6745610	3.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	516.8975
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9106903	0.32
160.8570099	0.04
174.8887787	0.47
198.8472900	0.01
200.8676758	0.03
215.0861511	0.03
229.0347443	0.18
244.8613281	0.17
273.0352173	6.22
274.8425598	0.03
288.9526367	9.10
346.7225952	0.06
363.1390991	0.01
386.9577637	0.76
399.7105713	0.02
402.9084473	100.00
403.5140991	0.32
426.1892090	0.04
426.8757324	0.06
443.0137939	0.04
459.8070679	0.03
461.0096436	0.02
468.7266846	0.02
469.8304443	0.72
470.8918457	4.32
472.7144165	0.06
489.0597534	0.01
499.5775757	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	179.035
Annotation	(E)-3-(2,3-Dihydroxyphenyl)-2-propenoic acid
Peak:m/z	Relative Intensity
79.0486450	0.01
88.8755798	0.10
90.9595337	0.18
106.7062225	0.06
131.3166656	0.01
134.9728088	100.00
138.9822845	0.01
142.9540710	0.03
148.9137573	0.01
152.1431427	0.03
160.9202271	0.19
178.9420319	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	465.1021
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
150.9738312	0.18
177.9904633	0.04
266.1739807	0.04
268.0647888	0.04
277.0540771	0.04
293.1842041	0.07
297.0781860	0.19
300.0972595	0.09
303.0897217	100.00
304.7128906	0.05
316.1490173	0.10
344.9463806	0.11
347.3490601	0.05
355.3655396	0.05
382.9158020	0.07
384.3296814	0.16
390.8427429	0.03
399.2077942	0.23
399.8943176	0.09
411.0781860	0.12
415.0849915	0.09
420.1313782	0.05
420.9910889	0.04
433.4786987	0.04
446.2503357	0.09
447.1792603	0.95
455.8436890	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1721
Annotation	Unknow
Peak:m/z	Relative Intensity
155.2191162	0.05
170.8624878	0.18
173.0930023	0.64
176.8330994	0.21
189.1099396	0.04
190.9931335	100.00
191.7769318	0.03
202.0193787	0.03
203.1871948	0.04
218.1231384	0.15
220.9526978	2.66
250.9651489	0.03
258.8947144	0.03
262.0816956	0.03
263.3019104	0.04
263.9328308	0.05
278.2326050	0.03
291.1347961	0.05
321.1586914	1.22
321.9735107	0.09
323.1243896	0.69
340.7570190	0.10
346.3741455	0.07
347.1804199	0.20
349.2497559	0.16
350.0883179	0.07
351.2018433	0.02
383.2396851	0.03
386.4348755	0.05
387.2546997	0.03
392.1333618	0.09
395.0526123	0.03
397.2633057	0.02
402.1367798	0.03
413.5259399	0.12
416.7950439	0.03
421.2383423	0.04
427.0151367	0.04
434.0683594	0.02
434.9920654	0.11
441.0196533	0.07
444.0319214	0.14
461.5971680	0.03
472.8724976	0.12
487.3506470	0.19
489.1210327	0.05
497.3133545	0.36
514.6332397	0.25
515.5392456	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.2041
Annotation	Unknow
Peak:m/z	Relative Intensity
110.6140823	0.60
137.1426392	0.48
183.1904907	0.43
205.2151794	0.43
210.1704102	100.00
210.7823181	1.84
225.0718384	0.52
238.0255127	0.50
242.2239075	2.00
243.2590332	0.73
255.1025696	0.52
279.4548340	0.59
285.3505859	5.79
286.2127075	0.73
300.4688721	0.50
301.7045898	1.05
312.8607178	1.71
314.2995605	16.94
321.7711792	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	927.7991
Annotation	Unknow
Peak:m/z	Relative Intensity
346.3074646	0.12
509.2975464	0.14
515.8695679	0.69
556.1485596	0.14
632.0802612	0.06
633.0787964	0.09
644.8287354	0.20
655.8848267	0.48
682.1227417	0.71
718.2622681	0.15
723.6812134	0.17
755.4573364	0.69
762.2630005	0.47
765.1869507	0.43
771.8918457	0.48
778.8028564	0.26
780.9739380	0.19
846.9061279	0.40
880.3515015	0.13
888.0049438	1.53
888.6936646	0.16
903.9630737	0.14
905.9179688	0.32
912.6293945	0.70
913.2463379	0.08
918.5751343	0.22
949.6374512	0.10
1004.5109250	0.49
1021.1329960	0.65
1028.7828370	0.19
1032.5072020	0.16
1051.5751950	0.35
1060.7585450	0.25
1069.1166990	0.20
1070.2204590	0.77
1078.6281740	0.18
1123.9312740	0.25
1133.5925290	1.49
1137.7519530	0.12
1139.5251460	0.59
1199.4344480	0.42
1248.8535160	0.17
1322.0714110	0.66
1326.2073970	0.22
1346.9652100	0.08
1540.1226810	0.06
1637.9952390	0.17
1642.7723390	0.42
1646.2521970	0.19
1671.8265380	0.09
1686.8753660	0.22
1688.4426270	0.32
1701.1950680	0.11
1709.4364010	0.10
1718.6263430	0.05
1737.7723390	0.10
1760.3778080	0.14
1768.0960690	2.84
1778.2427980	0.71
1797.3397220	22.16
1801.3035890	0.10
1815.2984620	0.12
1827.5321040	0.38
1829.5250240	0.09
1832.7327880	0.29
1858.2762450	0.45
1859.7554930	0.14
1870.1500240	3.85
1877.7878420	0.24
1888.1717530	0.09
1891.8088380	13.76
1893.3205570	0.30
1893.9981690	0.55
1894.7971190	1.11
1900.0212400	0.96
1901.6223140	11.52
1903.8236080	2.07
1912.5540770	0.21
1914.3885500	0.29
1917.1004640	0.06
1918.3907470	45.55
1921.9967040	1.88
1922.9138180	0.12
1930.0784910	4.48
1931.7625730	0.10
1936.2786870	0.11
1937.0153810	0.65
1938.7419430	0.12
1941.9666750	5.75
1946.6595460	0.06
1949.9996340	1.10
1951.2296140	0.34
1953.4484860	5.19
1954.2756350	3.42
1955.0432130	0.74
1956.2171630	11.82
1958.9984130	0.04
1962.9943850	3.70
1963.9044190	0.13
1966.9254150	0.30
1969.3172610	100.00
1970.6890870	1.92
1971.8795170	0.42
1974.0694580	0.59
1977.6434330	0.06
1978.4720460	29.08
1980.2941890	0.27
1981.8200680	3.05
1986.9088130	0.15
1988.9211430	4.72
1989.9660640	61.72
1993.6949460	26.06
1995.4010010	0.14
1997.4665530	56.07
1999.6854250	1.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	241.999
Annotation	Unknow
Peak:m/z	Relative Intensity
182.9245148	5.90
185.9275818	0.25
196.0001984	2.03
201.0360718	4.57
214.0953522	1.08
218.8803406	0.68
223.9484253	100.00
225.2355804	0.91
241.7560577	6.48
244.0504761	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0195
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
84.8608551	0.43
86.9793701	1.16
101.0674744	0.02
110.9090729	100.00
128.9282379	2.38
130.9148407	0.72
147.0828552	0.06
154.9843903	0.27
173.0033722	20.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	605.241
Annotation	Phaeophorbide b
Peak:m/z	Relative Intensity
256.2450256	0.01
282.4703064	0.01
283.4205322	0.01
289.2102661	0.01
297.3466492	0.03
305.4911804	0.02
311.3685913	0.05
319.2592163	0.02
323.6328735	0.01
340.4381714	0.01
351.3376465	0.01
359.3686523	0.01
380.3045044	0.01
405.2313232	0.01
410.7707520	0.02
419.4544067	0.02
423.4987793	0.05
425.7226562	0.01
429.4631958	0.05
430.5700684	0.01
431.5270386	0.03
433.4821167	0.01
448.8251953	0.03
454.4366455	0.01
475.1126099	0.02
477.5693359	0.02
483.5574951	0.01
485.4428101	0.05
488.3966675	0.01
491.3842163	0.05
492.0644531	0.02
493.3568115	0.03
501.5455933	0.02
502.4463501	0.02
503.4199829	0.02
505.4411621	0.01
507.5443726	0.02
508.4083252	0.01
510.0889282	0.03
517.3469238	0.01
519.2947998	0.03
520.4650269	0.02
521.7308960	0.01
525.5301514	0.02
529.3634644	100.00
530.3246460	27.17
531.1412964	0.08
532.1162109	0.07
533.3142700	0.75
534.3080444	0.21
535.2667847	0.01
536.5765991	0.02
537.8958740	0.04
543.0032349	0.01
546.6519165	0.12
549.4384155	0.03
551.2732544	0.10
552.7797241	0.02
559.4733887	0.04
561.3370972	2.04
562.3897705	0.54
563.2951050	0.01
564.1688232	0.04
564.8599243	0.04
567.4816284	0.02
569.2606812	0.13
570.4639282	0.06
571.4960938	0.04
573.0916748	35.92
574.1566162	7.25
574.7787476	0.12
576.2369995	0.01
577.4431763	0.04
587.3693237	0.26
588.2402344	0.20
589.2528687	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	607.2543
Annotation	Phaeophorbide b
Peak:m/z	Relative Intensity
198.2036438	0.08
218.2243500	0.02
239.2429199	0.05
241.0358124	0.06
251.0829163	0.03
267.0661621	0.03
283.7922974	0.03
286.4044189	0.08
290.9432068	0.10
292.3552856	0.04
305.2555542	0.15
327.5721436	0.08
335.2897949	0.08
339.1372070	0.04
368.0393066	0.07
387.5086060	0.04
394.2133179	0.05
395.4389038	0.17
397.2421875	0.09
398.3900146	0.03
403.3868408	0.07
405.2591553	0.04
419.1438599	0.03
426.2987061	0.05
427.1638184	0.07
441.2376709	0.04
442.5002441	0.62
443.3789062	0.05
445.2821655	0.26
447.0413818	0.03
447.7125854	0.05
454.2745972	0.07
459.2941895	0.10
462.2875977	0.18
463.3254395	0.11
473.5168457	0.20
474.5196533	0.75
475.4959106	0.88
476.4614258	0.09
477.2857056	0.16
478.3936157	0.02
479.3203125	0.04
480.0587158	0.26
487.3341675	3.44
488.3444214	0.83
489.5979004	0.24
490.5816650	0.16
491.3284912	0.25
492.4243164	0.17
494.5126953	0.04
497.1403198	0.02
499.6720581	0.02
501.2814331	1.25
502.1475220	0.69
503.5277710	0.44
504.2820435	0.07
505.3385620	0.07
506.2731323	0.74
507.4572754	0.21
512.9149780	0.61
513.6331787	0.05
514.3928833	0.04
515.3299561	0.08
517.4365234	0.31
519.3444214	17.55
520.3857422	6.17
521.3441772	0.82
523.5413818	0.19
529.2894897	3.22
530.3541870	1.73
531.3576050	0.12
533.3171997	0.44
534.3295288	1.04
535.3203125	0.40
536.3219604	0.28
538.2956543	0.14
539.3801270	0.11
545.3263550	0.60
547.3378296	98.68
548.3822632	34.47
549.4942017	3.90
551.3911743	0.73
552.3158569	0.47
556.3198853	0.05
557.2567749	0.75
559.7736206	0.07
561.3937378	3.81
562.4691162	1.20
563.5037842	0.25
564.5665894	0.16
571.1888428	0.30
573.4716797	0.03
574.3039551	0.06
575.3450928	3.62
576.4395752	1.48
577.4653931	0.62
579.3829346	100.00
580.3867798	36.93
581.3305054	3.87
589.3244019	6.70
590.3227539	2.90
591.2576294	0.39
592.3788452	0.06
607.4299927	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	544.73
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9141693	0.16
245.8471222	0.03
258.0402832	0.06
287.2594604	0.07
290.7332153	3.41
292.8182983	5.97
296.5198975	0.02
301.2343750	0.09
336.1162720	0.03
339.0953979	0.03
340.6896362	0.02
368.7830811	0.04
370.3120117	0.22
370.9242554	0.33
374.7732544	3.08
376.1202393	0.74
376.8001709	4.38
382.4966431	0.29
389.1018066	0.02
398.5638428	0.13
400.0571289	0.03
400.8189697	0.47
408.7804565	0.05
423.0434570	0.04
424.6187134	1.32
430.4929810	0.06
436.8425903	0.62
437.9370117	0.55
438.7471313	3.38
439.3560791	0.02
450.5429688	0.02
452.5505371	0.14
454.7211914	0.66
458.6118774	16.62
460.5364990	100.00
461.2734375	0.42
462.5869141	0.03
468.8331299	0.14
472.9055786	0.11
478.7686157	0.11
479.7005615	0.22
480.7458496	1.54
482.8161011	0.20
483.8159180	0.71
484.7188110	4.54
486.7409058	0.22
496.8855591	0.11
497.8895874	0.96
498.7261353	2.38
509.7993774	0.11
513.9670410	0.06
514.9291382	0.07
526.5806885	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1113.3312
Annotation	Unknow
Peak:m/z	Relative Intensity
463.0970764	0.96
514.8677979	0.14
599.6382446	0.04
609.2453613	1.38
610.4746094	0.14
643.3635254	1.27
644.3620605	0.27
651.3632812	0.17
656.5453491	0.06
685.4509888	0.19
727.2930908	0.05
761.0036621	0.05
771.2813721	0.64
787.2116699	0.09
805.3682251	0.32
806.0975952	0.18
832.0917969	0.07
847.3536377	0.04
857.1188965	0.06
859.0156250	0.09
907.4432373	0.26
908.5115967	0.07
915.4692383	0.10
933.2819824	14.91
934.3924561	1.78
951.3016357	100.00
952.3156738	11.05
980.5567627	0.11
993.4506836	5.61
994.3720703	0.66
1022.4694820	0.09
1023.2457280	0.49
1024.5648190	0.27
1035.3718260	0.13
1037.7316890	0.11
1049.3471680	0.48
1053.2498780	1.84
1054.2102050	0.22
1069.6311040	0.24
1074.3088380	0.13
1077.3155520	0.07
1083.3226320	0.39
1084.5402830	0.06
1088.0965580	0.20
1095.3743900	1.56
1096.2905270	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	247.13
Annotation	Leucyl-Aspartate
Peak:m/z	Relative Intensity
85.9939270	0.76
104.0926208	0.64
116.1439362	0.30
132.1690063	3.33
149.8004150	0.19
168.9418945	2.17
182.9808655	4.10
187.0677643	3.47
201.1372375	47.48
202.0642700	0.50
202.8916168	0.46
205.9467010	2.08
210.9075775	24.83
212.0793457	14.93
229.0151825	100.00
230.1627197	5.64
246.0360565	0.55
247.1725464	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	642.1004
Annotation	Unknow
Peak:m/z	Relative Intensity
217.4055328	0.10
244.1919250	0.08
258.9560547	2.42
277.0101929	4.10
290.9723511	0.23
293.0939331	0.09
294.9808960	3.77
299.3116455	0.18
301.0680542	0.18
305.1508789	0.06
308.9592896	0.07
311.0573730	0.12
327.2898560	0.10
329.5749512	0.12
330.7662659	0.80
339.3640747	0.05
348.7352905	0.43
360.8207397	0.05
363.0746460	0.31
367.1716919	0.63
373.2805786	0.09
376.0185547	0.05
378.4435425	0.10
382.3470459	0.28
385.0916138	1.60
396.9615479	0.29
398.9965820	0.08
401.4535522	0.08
403.0268555	4.20
407.2194214	0.16
408.8226929	3.01
421.0142212	1.01
425.7566528	0.22
426.9346313	4.45
429.2800903	0.18
430.6360474	0.08
433.0864258	0.10
434.9588623	0.54
436.1856689	0.10
438.9197388	0.20
444.0913086	1.04
444.8569946	12.74
445.5919189	0.07
450.8713989	0.45
454.1582031	0.05
456.9494019	0.09
462.5657349	0.11
465.4137573	0.08
469.0269775	1.71
470.1408081	0.19
475.2838135	0.07
476.2028809	0.14
479.8981934	2.74
480.7655640	0.34
486.9025879	2.56
490.2518921	0.32
493.0888062	0.16
494.4382324	0.21
496.0884399	0.05
497.8372192	0.32
498.9611206	0.69
514.6237183	0.04
516.8571167	1.78
518.5690308	0.27
520.9414062	0.12
525.0639038	0.49
526.1519165	0.23
529.4184570	0.10
531.5360718	0.09
533.4122925	0.04
534.9822998	23.48
535.8325806	0.07
538.4188843	0.17
550.6073608	0.19
552.3093872	10.58
552.9673462	71.20
553.6737061	0.19
559.1741333	0.08
560.5448608	0.16
566.9197998	0.08
570.8308716	100.00
571.7485962	0.28
577.3885498	0.21
580.5206909	0.14
581.1982422	0.09
585.6682129	0.10
586.6045532	0.20
588.8166504	83.14
589.5850830	0.07
591.5717773	0.15
597.5715332	0.13
601.1085205	0.08
604.2195435	0.11
605.1642456	0.99
606.5612793	5.47
607.3547974	0.14
608.6989136	0.08
609.3756714	0.08
610.5330200	0.51
614.5368652	0.08
623.0083008	0.22
624.3452759	3.11
625.5366821	0.96
627.5265503	0.17
628.7437744	0.40
632.3568726	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	261.1439
Annotation	Leucyl-Glutamate
Peak:m/z	Relative Intensity
86.0403748	10.74
102.0849304	0.09
113.8715057	0.11
130.1005402	3.26
147.9261932	100.00
171.0108643	0.49
172.1096649	0.14
183.2706146	0.18
187.1083832	0.22
188.1545715	0.52
196.9881287	0.30
202.2406311	0.24
215.1963348	6.88
218.9810028	0.41
220.0391388	1.17
224.8948212	0.69
226.0801849	2.17
231.1222687	0.21
232.8665619	0.48
243.0424957	29.06
244.1043243	0.44
244.9323578	0.30
247.1643524	0.16
251.6929779	0.35
253.1471100	0.49
268.6524658	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	631.2307
Annotation	Unknow
Peak:m/z	Relative Intensity
245.0704651	0.24
253.1071472	0.03
276.0408325	0.13
277.4423218	0.11
284.9012146	0.07
327.1940308	0.39
335.2666016	0.09
337.0883789	0.06
353.2692261	0.19
369.4212646	0.06
416.4374390	0.17
425.5299072	0.09
457.2633667	0.09
466.6225586	0.13
470.4200439	0.21
483.2298584	0.20
486.4818115	0.16
495.2822266	0.36
497.5270386	0.12
499.4364014	0.07
527.3460693	0.17
545.5612793	0.07
547.4493408	0.06
553.4899902	0.22
555.3744507	100.00
560.9685059	0.10
564.2839966	0.07
567.1234741	0.13
567.7584229	0.06
568.6209106	0.12
571.3312988	0.19
572.5241089	0.10
580.9395142	0.17
584.8281250	0.12
585.5881958	0.16
586.3995972	0.23
593.5267334	0.11
596.1165161	0.06
598.2249756	0.79
599.0462036	3.71
612.0125732	0.16
613.2105713	0.83
614.6068726	0.07
617.1990967	0.52
622.1813354	0.14
632.0433960	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	277.0329
Annotation	Unknow
Peak:m/z	Relative Intensity
78.9369583	6.91
96.8175354	100.00
97.6719818	0.20
108.9411926	0.11
128.0306091	0.25
130.7986755	0.13
144.8616943	0.18
147.0027161	0.40
149.0359497	0.26
155.1398773	0.23
157.1353912	0.14
187.0720673	0.50
197.1621094	0.12
203.3148193	0.19
214.9557495	0.07
217.0355225	0.16
227.9566650	0.85
229.1510925	0.65
239.1967468	0.59
240.1441040	0.15
241.2837219	0.29
258.1300659	0.61
259.0612183	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	182.0808
Annotation	4,6,7-Trihydroxy-1,2,3,4-tetrahydroisoquinoline
Peak:m/z	Relative Intensity
135.9898529	18.03
146.8426208	0.04
154.3188477	0.04
164.9682922	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1663
Annotation	Verbasoside
Peak:m/z	Relative Intensity
142.7770844	0.02
148.9319458	1.23
154.2126770	0.10
160.9539642	0.29
178.9408264	0.02
191.1018982	0.42
204.1983643	0.05
220.8185272	0.77
238.9707947	0.12
242.2210693	0.03
243.0224457	0.03
245.0171204	0.02
249.3569641	0.05
251.0561218	0.02
253.9785767	0.07
256.8851624	0.03
259.1414490	0.02
261.9832764	0.06
262.9804077	0.02
267.2671509	0.05
272.3556519	0.02
281.1458740	0.09
283.2287598	0.18
288.1988831	0.04
293.1384888	0.22
297.2073669	0.04
298.3646851	0.04
299.1567383	0.02
301.3034668	0.04
306.0208435	0.24
307.1749573	0.03
309.2133789	0.07
310.9950562	2.09
312.1879272	0.15
315.1049500	0.02
318.9553833	0.05
322.3258057	0.04
326.5198364	0.03
337.1255188	0.09
340.0770569	0.07
367.5253906	0.04
368.2604980	0.11
373.1540222	0.09
374.2177429	0.02
375.7117920	0.03
377.4068298	0.09
384.9407043	0.12
386.5685730	0.07
389.3136902	0.11
396.3744812	0.16
397.1908875	0.02
399.3385620	0.10
401.0233459	0.24
409.2911987	0.22
415.1448059	100.00
415.7818909	0.53
416.4360046	0.05
417.2226257	0.05
425.1644287	0.11
427.2824402	0.09
428.1379089	0.04
430.5364685	0.05
432.2026672	0.03
435.4014893	0.04
442.2966003	0.11
442.9317017	0.03
443.5639343	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	375.0203
Annotation	Unknow
Peak:m/z	Relative Intensity
139.0228271	18.83
153.1204834	0.29
154.1252441	0.16
182.9508820	100.00
213.0589600	0.06
214.9339600	0.07
215.9815216	0.11
221.0602722	0.04
229.3544312	0.26
238.8200378	0.13
242.0272522	0.08
246.2830505	0.04
248.8043823	0.06
255.2264709	0.04
258.8668823	0.22
260.8507690	0.76
285.0044250	0.13
286.0388184	0.20
286.9234619	0.15
288.2531738	0.20
313.1873169	0.03
326.8627625	0.07
328.5998840	0.07
329.3335266	0.07
330.8350220	0.40
331.8335876	0.20
339.2081604	0.13
340.3991394	0.14
343.9859009	0.06
347.0752869	0.35
354.1968384	0.08
356.9616089	16.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.0897
Annotation	Unknow
Peak:m/z	Relative Intensity
146.7053223	0.03
148.8506165	0.01
164.9701843	0.01
244.3044434	0.03
259.2836609	0.01
261.2434082	0.02
263.1008301	0.01
272.1868591	0.01
277.1247253	0.02
313.1533203	0.60
318.3921509	0.01
339.2220764	0.01
340.0995483	0.05
341.4842529	0.01
359.1722412	0.01
376.3750610	0.16
384.5065918	0.01
393.4054871	0.01
395.1823730	0.01
399.2881775	0.06
411.2706909	0.16
425.3574829	0.02
426.5151978	0.03
445.1032715	100.00
447.4501648	0.06
448.2791443	0.02
456.2910156	0.01
472.2902527	0.03
473.3460388	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	406.1981
Annotation	Unknow
Peak:m/z	Relative Intensity
120.2124634	0.02
125.2841797	0.04
128.0574341	0.11
130.1449585	0.03
137.0639648	0.10
138.2097778	0.14
140.1773071	0.17
146.9222870	0.27
147.9783630	0.07
152.1253662	0.91
153.0993958	0.15
154.0882568	0.02
164.0774536	2.65
165.1367493	0.30
170.1387939	0.37
170.9507751	0.03
172.0794983	0.07
173.1217804	0.04
181.9985046	3.21
183.1205444	0.68
187.0503387	0.04
189.0801544	0.02
199.1778259	0.07
201.0679321	0.05
204.0432129	0.04
206.0416412	0.11
210.1472778	0.03
211.1283875	0.13
215.1022034	0.07
216.0500183	0.08
217.2007904	0.14
223.1022339	1.47
224.0999451	0.61
226.4731140	0.02
228.5058594	0.12
234.7463989	0.02
241.0693054	1.65
242.1517334	0.98
243.1815186	0.23
244.4035339	0.09
245.3851624	0.12
257.1230164	0.07
258.2920532	0.10
259.2496948	0.13
260.9283142	0.04
273.1246338	0.02
274.8879700	0.02
276.0679932	0.04
277.2763062	0.56
278.3656616	0.18
279.0014038	0.11
285.2884216	0.09
286.1892395	0.19
290.4143066	0.16
291.2318115	0.06
293.3011475	0.14
301.0687256	0.07
302.1671753	0.16
303.9709167	0.03
310.8983765	1.20
312.2431030	0.10
314.0546265	0.08
315.4332886	0.05
316.1837769	0.04
319.4808350	0.16
321.2842712	0.04
326.0157166	0.08
327.5111694	0.01
328.1914062	0.04
329.2080078	0.34
330.2804871	0.04
332.2819824	0.92
333.4044189	0.38
344.2119751	0.28
346.2626648	3.35
347.3091125	0.76
349.3076477	0.06
351.1004639	0.03
353.3638306	0.04
354.1997070	0.04
359.6456604	0.06
361.0528870	0.32
363.3383484	0.08
364.3662720	0.27
365.5484924	0.04
366.2757874	0.02
370.1779175	0.08
371.2071228	0.18
371.9583130	0.06
376.2904358	100.00
377.2904968	33.68
386.1918640	0.02
388.2502136	32.09
389.2050476	10.01
389.8497925	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	321.1044
Annotation	Unknow
Peak:m/z	Relative Intensity
97.1572800	0.08
97.8669281	0.04
112.1077118	0.29
112.9228745	0.68
114.9687500	2.30
115.8998184	0.04
125.9287033	2.62
127.0371628	0.94
139.1886292	0.12
142.9142456	0.43
146.0049133	2.18
147.4055481	0.11
148.1529846	0.66
149.9458313	0.90
151.1032410	0.12
153.8116760	0.24
158.2144470	0.24
159.0468140	0.06
164.8859100	0.18
169.1441498	0.65
171.1959534	0.25
172.1484070	1.74
183.0613098	3.15
189.0776672	0.73
195.7594757	0.05
197.1186523	0.08
198.2887268	0.40
199.1338501	0.12
201.1455536	0.27
201.8655701	0.59
203.3609619	0.10
204.2069397	0.96
211.9328613	0.10
213.2080994	0.06
220.1169739	0.83
221.1694336	0.40
222.2203064	0.03
226.1920471	18.89
229.1255493	8.06
230.2713013	0.17
240.1007690	13.85
240.7017822	0.10
243.1522217	26.37
244.0399170	0.09
245.0376282	0.06
247.0394897	100.00
248.0765381	28.49
251.1773682	0.03
257.2385254	3.62
258.0942688	0.32
259.9704590	0.46
261.0419617	0.34
265.1156616	22.91
272.3353882	0.46
272.9936523	5.80
273.6452637	0.10
275.0543823	0.13
277.3046265	0.84
279.0284424	0.38
286.1894226	1.29
290.1760254	14.77
303.0787354	10.82
304.1366577	33.90
314.5537109	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	619.1214
Annotation	Unknow
Peak:m/z	Relative Intensity
180.3423004	0.10
183.0201111	0.18
184.2776947	0.07
193.1202393	0.07
194.0556488	0.15
197.1311646	0.07
203.0719452	0.07
209.1519775	0.31
213.0291595	0.03
215.1712952	0.13
221.0467377	0.12
222.0469818	0.04
224.2718506	0.35
225.2435608	0.06
226.0966949	0.52
229.0377808	0.05
238.9662476	0.09
242.0573273	7.12
243.1179199	5.36
244.3944550	0.15
246.9223938	0.57
247.9922028	0.82
249.1215515	0.12
254.7142334	0.05
258.6386414	0.35
261.2952576	0.05
266.1326294	0.06
267.4207153	0.14
268.1574097	0.05
272.8967285	0.34
274.1996155	0.12
275.0712280	0.33
275.9894409	0.11
278.9586487	0.27
280.1487122	0.21
281.2927246	0.04
282.2811279	0.61
283.0722961	0.06
290.1181641	0.09
291.1386108	0.19
293.1558838	0.06
298.1367798	0.10
299.8752441	0.08
305.2512207	0.30
305.9644775	0.16
307.0905151	2.15
308.2474365	0.22
309.9332886	0.14
311.8886719	0.21
314.1890869	0.40
316.4124146	0.05
322.0819702	0.51
322.8546753	0.21
323.9556885	0.21
326.2510986	0.05
327.1876221	0.04
328.1026917	0.05
332.1383057	0.14
339.1463623	16.12
340.1367188	2.68
341.3508911	0.16
341.9547729	0.05
344.2427979	0.75
344.9468384	0.03
346.0470581	0.25
352.5804443	0.18
354.8583984	0.63
356.0366211	0.04
359.0943604	0.07
364.1974487	0.12
364.8698730	0.04
366.3790894	0.17
369.7884521	0.14
371.2368774	1.07
372.2743530	0.17
374.3324585	0.05
378.9397583	0.09
381.1976318	0.11
384.2618408	0.04
387.2078857	0.20
389.2723999	0.15
391.2420654	0.10
396.3518677	0.04
397.0823975	0.15
398.1984863	0.25
406.4149780	0.21
407.1346436	0.05
414.0165405	0.04
416.1082153	0.17
423.0385742	0.30
427.0690918	0.06
437.3829346	0.06
439.0794678	0.21
440.6079102	0.15
441.2382202	0.14
449.0004272	0.11
455.7453613	0.07
457.1802979	4.27
458.2965088	0.46
459.4539795	0.37
463.1704712	0.19
464.3516846	0.17
465.2746582	0.09
469.3726196	0.17
473.4696045	0.52
481.5131836	0.33
482.3416748	0.22
483.1023560	0.08
484.4749756	0.39
485.2868042	0.05
486.3386230	0.24
487.1416016	0.07
489.4858398	0.11
491.2058105	0.14
493.3344116	0.22
494.1318970	0.18
499.2868652	5.81
500.2448730	1.21
501.3281250	0.20
502.2816772	0.34
503.2495728	0.23
504.3195801	0.03
505.7442627	0.70
506.4282837	0.02
507.3643188	0.18
510.4732666	0.22
513.2480469	0.04
515.5256348	0.04
517.0718994	0.15
518.3677979	0.83
520.3618164	0.60
521.3540649	0.32
523.2202148	0.97
524.0584717	1.57
525.2793579	0.45
526.0803833	0.12
527.2619019	0.25
529.2384033	19.65
530.1758423	4.18
531.1479492	0.68
531.9110107	0.02
535.2748413	1.22
536.3231812	0.18
537.0579834	0.34
538.0787964	0.45
539.2406006	0.55
540.1988525	0.17
541.2631226	1.36
542.0429688	0.90
543.0948486	0.32
544.2551880	0.23
545.2510376	0.23
547.3568726	0.35
548.1544800	2.58
549.1090088	0.42
550.1503296	0.08
550.8465576	0.07
553.1686401	13.13
554.2937622	5.08
555.3195801	0.41
556.1399536	0.08
557.3919067	0.11
559.1982422	100.00
560.1997681	23.91
561.3290405	1.38
562.6654663	0.13
565.1936646	2.19
566.1995239	21.34
567.2109985	6.06
568.5039673	0.29
571.1570435	0.50
573.1531982	1.05
574.4816284	0.72
575.4697876	0.18
577.2332153	0.34
577.9880981	0.13
579.2140503	0.09
583.2032471	12.24
584.1979370	39.46
585.2130737	9.92
586.1426392	0.60
588.9733276	0.19
590.0261230	0.44
593.2566528	0.25
597.7165527	0.27
601.1870728	54.39
602.2377319	13.71
603.1569214	1.34
610.5867310	0.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1136.1504
Annotation	Unknow
Peak:m/z	Relative Intensity
727.5051270	0.54
806.0284424	0.29
1011.0532230	1.02
1019.6059570	0.69
1020.4393310	0.73
1022.8397220	0.66
1058.5938720	0.78
1074.1434330	0.65
1075.4340820	0.50
1078.5798340	4.46
1087.6281740	6.60
1088.5388180	0.85
1093.0134280	0.39
1095.5943600	3.57
1105.8547360	2.96
1107.6701660	0.97
1109.7105710	4.47
1114.0743410	1.33
1117.1314700	1.39
1121.0874020	3.54
1125.8748780	2.00
1127.7593990	0.47
1141.4421390	4.19
1232.8728030	0.26
1234.9299320	1.74
1241.0446780	0.42
1246.8881840	1.23
1254.4318850	2.38
1260.5936280	3.51
1262.9643550	0.48
1274.9554440	4.32
1282.7404790	2.06
1286.3466800	5.10
1290.3135990	3.74
1291.4472660	0.17
1292.7653810	12.59
1294.1059570	13.91
1299.1302490	3.86
1301.4592290	6.13
1302.0812990	3.15
1302.9060060	1.58
1304.8657230	14.97
1305.5529790	100.00
1306.6152340	1.43
1308.1010740	2.01
1309.5891110	0.38
1314.2904050	2.22
1315.1732180	0.75
1315.9201660	3.46
1316.8608400	0.97
1321.2119140	1.44
1327.5834960	13.79
1328.1966550	0.63
1330.8057860	4.36
1397.5753170	0.71
1509.7645260	0.26
1544.2659910	1.09
1551.7269290	1.35
1590.8183590	1.27
1598.8277590	0.34
1720.8829350	0.20
1783.3582760	0.38
1880.9378660	0.43
1889.4410400	1.06
1898.1859130	7.73
1928.5109860	0.62
1942.2618410	2.80
1943.4114990	1.83
1950.0028080	1.68
1958.8184810	5.30
1963.9114990	0.11
1964.9598390	0.91
1972.1354980	0.51
1979.8776860	0.17
1982.5393070	1.38
1984.2457280	0.42
1985.9304200	28.57
1989.2415770	0.11
1992.6490480	0.21
1994.2858890	2.95
1999.3332520	7.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.1825
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9984283	0.20
168.2379608	0.03
174.9630127	0.04
177.1888428	0.03
183.0534515	1.47
183.9727020	0.13
204.8816986	0.06
209.0442505	100.00
223.1672974	0.06
236.8864441	0.06
238.1846771	0.13
252.9650879	0.04
259.0650940	0.12
270.9257202	0.23
275.3203735	0.31
311.3763428	0.12
313.1633301	0.03
323.1754761	0.09
324.0759888	0.13
325.2651367	0.11
328.2476196	0.09
329.1987915	0.04
339.2109375	0.03
341.0687256	1.37
343.1104126	0.12
349.4549561	0.03
356.9233398	0.07
358.1476440	0.02
360.5119629	0.13
364.0921631	0.07
367.2414551	1.06
368.0969849	0.03
371.0326538	0.07
387.0343018	0.09
388.2145996	0.17
398.2070923	0.37
402.9032593	0.03
410.1311035	0.05
413.4084473	0.03
414.3034058	0.05
415.0164185	0.04
415.6725464	0.20
422.0523071	0.58
425.3477173	0.03
429.9091797	0.03
435.2200928	0.04
436.3178711	0.07
446.4871826	0.09
452.0656128	0.07
453.1398926	0.84
462.9406128	0.13
464.1983643	0.04
474.6013184	0.03
488.0859985	0.12
490.7304688	0.03
507.1331787	0.32
513.1038208	0.09
515.0674438	0.34
523.9276733	0.09
531.5010376	0.04
532.4864502	0.39
533.2407837	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.14
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
175.0630188	0.11
178.9573822	2.79
181.2361755	0.06
183.1193542	0.07
185.1350403	0.35
192.2563934	0.34
197.1603699	0.49
203.1140137	0.16
208.0633698	0.06
210.1226196	3.59
213.9448395	0.05
218.1410065	0.12
226.1611328	0.08
229.1837769	0.07
231.0698700	0.11
236.0793915	0.24
242.1173706	0.36
251.8267212	0.37
254.1387177	10.02
255.2962494	0.07
272.1922302	30.73
286.1721191	0.78
287.1074219	0.20
288.1854858	4.01
304.2106934	14.69
306.1824951	100.00
320.0561218	0.43
327.9368286	0.09
329.3483887	0.11
338.1367798	42.10
364.1858521	0.25
384.1013794	0.08
398.4887695	0.08
417.2222290	0.11
418.1184692	0.06
419.2597656	0.16
425.2170410	0.29
426.2006836	0.32
435.8686523	0.19
464.3058472	0.96
482.2134399	32.55
512.2839966	0.07
565.1825562	0.09
575.2268677	0.21
589.9835815	0.15
593.1523438	13.50
593.9923706	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	490.18
Annotation	Unknow
Peak:m/z	Relative Intensity
148.0185547	100.00
175.2567444	0.17
184.0273743	0.31
269.1395874	0.59
288.8368835	0.31
309.1855469	0.41
310.2019653	0.27
324.8523560	0.49
327.7232971	0.36
342.5534668	0.12
357.0898438	0.16
361.2003174	0.76
373.3989868	0.25
374.1061707	1.11
374.7120667	0.16
378.4981995	0.19
384.3304138	0.25
392.3782349	0.72
471.3425598	0.86
472.2726440	1.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.1289
Annotation	Psilostachyin C
Peak:m/z	Relative Intensity
97.0513306	0.18
109.0532227	0.18
110.9691010	1.56
123.0389099	0.10
137.1193848	0.10
137.9641418	0.10
142.9054413	0.10
149.1319733	0.17
150.9501038	0.23
153.0045319	100.00
161.1298523	0.41
163.1579437	0.31
165.9103546	0.08
171.1508636	0.10
174.9702606	0.23
176.0314178	0.18
179.2143555	0.14
185.9697113	0.10
186.9315948	0.09
189.1734924	0.27
191.2225494	0.17
201.1513519	3.14
203.3453827	0.62
204.1935577	1.55
208.1270752	0.07
217.1247406	0.74
219.1711731	33.48
220.0621490	0.21
220.9061432	0.22
224.7959137	0.07
226.9899750	0.29
234.2565155	0.13
235.8509064	0.13
243.2810669	0.18
244.2491455	2.10
245.2205658	3.59
246.3341522	0.12
247.1454315	0.15
248.3336792	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	991.2733
Annotation	Unknow
Peak:m/z	Relative Intensity
283.2731018	0.09
286.9278259	0.04
298.9252319	0.16
300.1129761	4.45
301.1903076	1.09
311.0618286	0.06
313.0731201	0.36
315.1382446	27.81
316.1828308	3.92
318.6441040	0.16
327.2944031	0.06
329.1245117	0.98
330.1214600	0.06
339.3196716	0.07
353.2120056	0.57
357.2026367	0.42
358.3895874	0.04
367.3661804	0.51
368.2291870	0.06
422.2681274	0.06
477.2830811	0.30
494.5325012	0.11
499.4576416	0.03
569.0087891	0.03
592.1436768	0.04
609.3131714	0.14
610.2820435	0.05
623.2211304	100.00
624.3081055	14.83
635.1263428	0.05
637.4627686	0.03
648.1413574	0.05
661.3263550	0.12
662.5122681	0.05
665.2369385	0.07
681.7678833	0.03
683.1481934	50.48
684.1751709	8.42
707.7023926	0.11
720.1641846	0.07
725.4849243	0.27
726.3985596	0.04
730.8383179	0.03
737.5532227	0.02
748.6004639	0.04
783.3558350	0.03
784.1574707	0.05
801.4689941	0.30
817.1270752	0.28
829.4082031	1.26
830.4180908	0.22
839.2137451	1.32
840.2672119	0.30
842.5141602	0.12
862.2751465	0.05
871.1333008	0.10
873.4215088	0.11
877.1778564	0.07
887.2633057	0.06
916.2821045	0.04
917.4488525	0.07
945.4782715	0.08
947.3000488	0.11
948.4284668	0.15
949.7888184	0.08
956.1667480	0.03
960.5283203	0.18
963.2708740	0.10
972.3851318	0.14
974.6812744	0.09
992.6162109	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.3907
Annotation	Gingerglycolipid C
Peak:m/z	Relative Intensity
202.8376923	0.18
291.5079041	0.09
309.5529785	0.10
337.5271606	0.57
353.2065430	0.22
355.3858643	2.36
356.4502563	0.21
379.4710693	0.21
396.3869019	0.05
397.4524536	0.16
417.6661987	0.09
441.3187256	0.07
455.4575806	0.24
469.2731934	0.12
477.3085938	0.20
481.3883057	0.36
492.2824097	0.05
492.9948120	0.09
499.5114746	8.83
500.6259155	0.39
511.5889893	0.19
515.2402954	0.09
517.3826904	100.00
518.4010010	3.21
526.9689331	0.06
529.5363159	0.11
534.3348389	1.31
535.3963623	1.31
541.4353027	0.20
549.2316284	0.16
553.6260376	0.24
559.5756226	1.21
560.5340576	0.10
569.2312012	0.17
571.6170044	0.31
583.5216675	0.11
587.5686646	0.08
591.5206299	0.06
592.1807861	0.29
593.3203735	0.12
595.4701538	0.13
601.4400024	0.07
607.4658813	0.34
613.5661011	0.06
616.4242554	0.17
617.8938599	0.12
620.1660767	0.21
625.3247681	0.12
626.5459595	0.19
631.1642456	0.78
632.0064087	0.07
633.2305298	0.42
635.4288330	0.73
640.8751221	0.06
643.4227295	2.47
644.5883179	0.48
646.9463501	0.28
651.2140503	0.38
659.5018311	0.15
661.4849243	47.00
662.5215454	5.46
679.8289185	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	755.2035
Annotation	Orientin 4'-O-glucoside-2''-O-rhamnoside
Peak:m/z	Relative Intensity
279.1069946	0.08
280.0321045	0.10
285.0548096	0.52
311.4337769	0.04
315.1622314	0.05
320.3624573	0.02
338.2573242	0.02
352.0999146	0.03
400.1428223	0.04
413.9631348	0.03
416.3280029	0.06
417.0881958	0.03
419.0450439	0.03
428.8368530	0.03
447.4709473	0.08
454.8644409	0.03
471.5223389	0.07
477.2124023	0.03
479.6137695	0.02
511.4317017	0.03
554.3181763	0.17
574.5385742	0.02
575.4435425	0.11
593.2467041	100.00
593.8588867	0.69
618.6467285	0.02
623.4530640	0.02
625.5079956	0.02
634.0743408	0.02
635.1687622	0.15
640.1326294	0.02
677.5255127	0.03
689.7577515	0.04
692.1596680	0.03
702.3162231	0.02
710.4347534	0.11
711.4922485	0.03
718.5350342	0.03
719.3066406	0.04
724.5205078	0.18
725.4795532	0.10
736.6548462	0.55
737.4874878	0.09
738.4087524	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	645.19
Annotation	beta-D-4-Deoxy-Delta4-GlcA-(1->4)-beta-D-Glc-(1->4)-alpha-L-Rha-(1->3)-D-Glc
Peak:m/z	Relative Intensity
189.1570129	0.04
207.1640472	0.43
214.9923706	0.46
226.9967804	0.27
233.2100830	0.05
242.0224915	0.05
245.1408081	0.23
249.3169556	0.29
251.2607269	0.10
254.0717010	0.15
256.1290283	0.05
257.0041199	0.06
262.9685669	0.12
272.0706177	0.24
273.0409241	0.12
275.2545776	0.05
277.3258362	0.03
287.0561523	0.07
288.9827881	0.27
291.1876831	0.08
300.2218018	0.23
303.1358948	0.07
304.4818726	0.42
305.2852783	0.71
306.1065063	2.07
307.0683594	0.50
317.2077026	0.76
318.9333801	0.08
321.1254883	2.77
331.0210266	0.09
335.1697083	0.42
337.1319580	0.84
338.0578003	0.14
349.3071899	0.09
358.7910156	0.56
359.4157104	0.10
361.0546265	0.09
363.2205811	0.30
371.3327026	0.07
375.3049316	0.17
377.1354980	0.85
379.0018921	0.07
381.2261353	3.18
382.4591675	0.04
389.3006592	0.13
391.3852539	0.04
393.2139282	0.42
400.0730591	0.08
403.2240601	1.60
411.2255859	0.24
417.2205200	0.15
419.0823364	0.27
421.1546021	1.15
423.2518311	0.14
427.1620483	0.15
435.1674194	3.48
445.0158691	0.07
453.2414551	13.34
458.7147827	0.06
460.2020874	0.12
463.3850098	0.46
470.3110352	0.06
471.2436523	2.64
475.1906738	0.05
476.9686279	0.07
479.4216919	0.21
481.2995605	1.16
489.1050415	0.09
493.1555176	0.32
495.1876831	1.32
504.9817505	0.14
507.2539673	1.01
513.2241821	42.25
514.0053101	0.27
516.4121094	0.13
525.2510376	2.42
526.0277710	0.11
529.6021729	0.05
535.2875366	2.48
543.2862549	1.52
547.2040405	0.08
549.2236938	0.60
553.3435669	1.35
555.3671875	0.35
567.2846069	26.78
571.5525513	0.21
578.4194336	0.05
582.2443237	0.05
585.2171021	100.00
585.8534546	0.43
591.5173340	0.40
595.6447144	0.08
597.3046265	0.09
599.3054810	0.06
600.5119629	0.11
603.3735962	7.63
609.3082275	0.24
611.5609741	0.10
613.2289429	2.72
626.3222046	0.28
627.3001099	0.45
628.2927246	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	193.0507
Annotation	Speciosin D
Peak:m/z	Relative Intensity
104.9550018	0.02
107.0889435	0.12
117.0551453	3.12
121.1960754	0.06
129.1558838	0.03
133.9514923	100.00
146.4240875	0.03
148.9031830	32.73
157.0362701	0.03
158.7759552	0.11
177.2650909	0.09
177.9476776	2.56
193.0307465	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	688.1713
Annotation	Unknow
Peak:m/z	Relative Intensity
210.9499054	0.28
239.0752411	0.05
241.2178345	0.18
262.1146240	0.09
263.2185059	0.21
273.2908325	0.03
287.9308167	0.02
322.9393311	0.08
325.2641907	0.14
326.3171387	0.09
344.8819275	0.49
346.1357422	100.00
387.5139771	0.04
390.5576782	0.06
422.6144409	0.07
424.1660767	0.20
425.3728027	0.49
436.1715088	0.03
450.3323975	0.15
486.1013794	0.03
500.0867310	0.03
503.5460815	0.05
515.3524780	0.10
531.7946167	0.06
533.9324341	0.03
537.3815918	0.10
538.1703491	0.32
541.1657104	0.02
550.7934570	0.27
552.9240112	0.05
554.0672607	0.04
555.8637695	0.08
575.1431885	0.07
589.1837769	0.02
590.1688843	0.21
609.9325562	0.04
613.4703369	0.08
627.1879883	0.08
628.2848511	0.24
648.9292603	0.11
657.6012573	0.15
670.3649292	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.9716
Annotation	Unknow
Peak:m/z	Relative Intensity
146.9694824	0.02
155.1042786	0.03
179.0280151	0.03
186.8134155	0.02
198.9623718	0.02
200.9215546	0.01
201.8466187	0.02
213.1561890	0.06
215.9879761	0.02
226.1588440	0.02
242.1531372	0.02
254.2919922	0.05
275.1379089	0.06
283.4844055	0.06
285.8057251	0.02
291.0403748	0.06
293.1533508	0.03
303.4397888	0.09
304.1390991	0.12
308.0903931	0.03
310.2989197	0.39
317.0782166	0.04
319.8467102	0.01
323.3312683	0.01
330.1763306	0.09
331.7966309	0.48
347.8495789	1.06
350.0451050	0.06
351.4561157	0.02
357.8357239	0.14
373.1674805	0.12
375.0180969	0.05
376.0530701	0.20
383.4809265	0.02
392.0262451	0.09
393.9508667	100.00
400.3607483	0.02
401.3069763	0.08
402.3586121	0.08
406.2195740	0.02
409.0885925	0.02
419.0419617	1.79
420.1007385	1.25
421.2888794	0.03
428.3749084	0.05
429.3328552	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.0898
Annotation	Unknow
Peak:m/z	Relative Intensity
146.1325073	0.05
148.9844971	0.10
188.1949921	0.05
208.4386597	0.04
227.1335144	0.02
238.1726074	0.09
251.1995392	0.09
256.2192078	0.06
257.3888855	0.06
260.4331665	0.03
272.4769592	0.04
288.3812866	0.04
299.0745850	0.04
300.1229858	0.07
306.0913086	0.39
307.1941528	0.10
313.1967163	0.58
314.2967529	0.12
328.1951294	0.13
329.1647339	0.05
331.3618774	0.18
339.2407837	0.05
340.1304321	0.04
342.2417603	0.17
355.1666260	0.05
358.3161926	0.04
361.4829712	0.07
362.4415894	0.12
368.2251282	0.05
374.3104248	0.02
375.3006287	0.23
376.2923584	0.19
377.1751099	0.04
386.9751587	0.09
389.5266418	0.16
390.4814453	0.09
393.2962036	0.03
395.1965637	0.02
398.7671204	0.05
407.2342834	0.14
411.1917114	0.17
413.2021484	0.10
416.0279541	0.04
420.5017395	0.14
423.1238708	0.06
425.3611755	0.22
427.3563843	0.03
428.3574524	0.04
429.4925232	0.04
430.4929504	0.11
445.1264954	100.00
445.9263000	0.14
447.0357971	0.43
455.2330017	0.32
456.1817322	0.09
457.3133850	0.10
471.5635376	0.03
472.2696838	0.49
473.1183472	0.62
473.7225037	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	420.1729
Annotation	Unknow
Peak:m/z	Relative Intensity
127.0130005	0.63
132.2094269	0.22
145.9624939	0.31
151.1483154	0.92
185.0989685	0.45
203.0948486	0.58
222.7399445	0.45
225.3487854	1.17
246.9885864	2.13
253.0565796	0.43
258.4071655	0.92
271.3475037	0.72
272.1025696	1.81
273.2546692	1.11
275.1449890	0.55
289.2052002	15.38
290.0743713	1.39
307.0960083	100.00
308.2639465	3.53
335.3938599	0.43
342.3401489	0.56
346.9901428	0.57
353.8800049	0.79
356.6082764	0.27
357.3631897	0.73
360.3279114	1.55
361.2921448	6.62
370.8862305	0.35
378.9347534	0.93
384.9550476	5.24
385.5806885	0.74
391.9014587	0.77
402.3587036	5.79
403.3834839	1.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
119.0600204	0.44
126.0839386	0.32
126.9047699	0.45
127.776123	0.73
140.9992676	0.67
155.1255493	0.80
157.2829437	0.21
158.9847107	0.68
171.3506165	0.31
173.1510315	1.12
183.1119385	0.46
184.8929443	0.64
186.985672	1.55
191.3692627	0.36
199.2680054	0.25
201.2053223	1.19
213.1235352	0.68
215.0787659	2.10
217.3594971	0.21
224.1225281	0.44
227.1709595	0.38
229.1806335	4.02
241.3115234	0.50
243.2915039	1.04
244.1798401	0.27
244.9497681	0.33
245.5828857	0.25
255.1529846	1.54
255.8912964	0.46
257.3544006	0.86
259.2976074	2.40
261.3010864	0.92
263.5139771	0.31
268.8682861	0.66
271.5450439	0.66
273.3932495	1.46
283.097229	0.80
284.5462036	1.42
285.3003235	3.30
289.2782593	0.46
295.3612366	1.09
297.414856	1.83
299.3307495	2.17
299.9642944	0.36
301.3872375	1.45
311.1334229	2.60
312.8149719	3.31
313.8210449	3.37
315.2786255	3.47
321.1182861	1.89
323.2664795	11.39
325.1187744	1.82
329.0603027	1.11
339.2574463	100.00
339.9604187	0.84
341.3198547	12.32
342.2652283	0.74
353.4316711	0.46
360.9875183	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0851
Annotation	6-Methylflavonol
Peak:m/z	Relative Intensity
77.12667084	0.03
91.06474304	0.08
94.82287598	0.10
103.1352844	0.10
103.937912	0.07
105.028595	0.06
106.7211609	0.05
109.0440826	0.03
118.9003143	0.02
122.9131012	0.07
129.0269623	0.99
146.9614716	0.05
147.8898926	0.03
149.499588	0.04
150.969162	10.99
152.0010376	2.13
153.9052582	0.09
156.2541656	0.08
157.1038208	0.08
165.0972443	0.03
166.0799103	0.10
167.0632629	0.20
168.2437592	0.05
169.0946503	0.12
170.0379181	0.17
177.116684	0.07
178.890625	0.03
180.1446533	0.15
182.25177	0.20
182.9344177	0.33
184.0276031	0.09
184.9938049	0.18
186.2094574	0.15
186.9195862	0.03
197.1381989	0.34
198.0696106	0.25
207.257309	0.10
207.8968201	0.02
209.2537994	0.09
210.16745	0.06
210.9488983	0.06
225.1387787	1.22
226.1380768	0.84
227.1500092	0.10
238.0706024	1.76
239.1516876	1.09
240.0450439	0.14
251.2016602	0.30
253.076828	100.00
254.1170197	3.20
254.9308472	0.17
262.3078003	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	614.9
Annotation	Unknow
Peak:m/z	Relative Intensity
198.9530029	0.04
217.1302948	0.02
228.9514160	0.05
272.9739990	7.94
274.2576599	0.03
314.3546143	0.02
385.0901489	0.10
386.9519653	18.22
387.6171265	0.02
425.2899780	0.03
459.7381592	0.09
478.6685791	0.05
498.1477661	0.09
498.8782959	0.23
500.8731079	100.00
501.5132446	0.39
513.3002319	0.03
524.0949097	0.10
541.1610718	0.07
542.2100830	0.03
546.0844116	0.01
546.9590454	0.02
557.9634399	0.03
568.1470337	0.14
569.0523682	0.23
573.1140137	0.05
582.8993530	0.03
595.9328003	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.05
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
159.1020050	0.10
163.9923706	0.02
176.8667145	0.08
178.8861694	0.02
191.1220703	0.10
192.9971771	0.13
195.1434021	0.06
197.1580200	0.03
201.0786285	0.07
202.1616211	0.05
211.0284576	2.44
220.9930115	2.69
222.0439758	1.70
223.0469055	1.42
231.8838654	0.03
239.0416870	0.05
241.0782471	1.94
245.1256866	0.04
247.1372681	0.02
259.2474976	0.04
261.9197998	0.13
263.2969666	0.13
264.9542236	0.06
266.3914795	0.06
273.0732422	0.11
274.3473511	0.02
280.1175537	0.91
282.8938599	0.03
284.5556335	0.03
286.1744385	0.02
290.1428528	0.03
291.9177246	0.04
300.1015930	0.09
303.1813965	0.05
305.1118164	0.29
313.1964111	0.06
316.8607788	0.04
321.1818848	1.06
323.0763550	100.00
324.0493164	0.03
327.2328491	0.06
328.7149048	0.09
334.1323242	0.05
336.0111084	0.03
339.2803955	0.03
341.1193848	0.16
346.0388184	0.39
360.6789551	0.03
362.1542969	0.04
372.8752441	0.34
374.0048218	0.10
379.3662109	0.06
380.2591553	0.11
381.3598633	0.06
384.0269165	0.05
385.0325928	2.13
386.9476929	0.04
391.1006470	0.05
403.1938477	2.54
407.0272827	0.15
418.1004028	0.03
421.0934448	0.43
427.1315308	0.28
428.0109253	0.34
436.1061401	0.17
437.1995850	0.02
443.8683472	0.08
444.9480591	0.06
448.1957397	0.03
449.1971436	0.07
451.7835083	0.04
453.2096558	0.06
458.9734497	0.05
466.0867920	0.14
467.2369385	0.64
472.9569702	0.05
474.3661499	0.04
475.8947144	0.09
478.1296997	0.02
486.0410767	0.02
503.5133667	0.13
504.1740112	0.08
505.1572876	0.14
511.2614746	0.11
519.1904907	0.03
521.0349731	0.03
522.2448120	0.10
528.3690186	0.26
529.1939697	0.08
546.4285278	0.64
547.1696167	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0856
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
82.91096497	8.53
95.12147522	2.92
105.1534424	2.44
111.0901642	9.01
121.072464	10.77
129.1269684	2.97
141.0453339	4.56
147.0498047	5.18
151.0445099	98.18
153.136322	4.87
166.0936127	3.53
168.0960541	6.30
175.2743835	2.98
183.2337799	27.65
189.4112854	4.65
193.2898254	8.70
195.0301666	13.55
208.2595825	4.84
209.259201	2.43
211.0175629	11.75
211.9082184	9.27
217.1744232	14.92
221.3207703	9.79
225.1864166	15.60
231.8965912	7.57
234.1190338	2.15
235.147583	67.86
237.1328278	13.36
238.0748749	31.20
239.1906128	12.00
253.0866089	100.00
253.9277954	2.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
121.179924	0.68
135.1431122	3.45
158.8891907	1.03
175.0054932	1.94
183.2213745	0.62
212.1297913	1.55
212.9687805	2.45
215.3903503	1.29
217.0156555	0.63
221.4438477	2.41
229.2133179	1.05
230.276062	0.57
241.1389771	0.94
255.3291321	3.43
257.1490479	1.26
259.2939453	2.00
261.1030273	1.03
261.8570557	1.35
262.5241394	0.68
263.2211914	1.46
264.7414551	0.88
267.1445007	1.33
268.8560181	4.39
271.3022461	3.92
284.9753723	1.01
285.6066589	0.68
295.3569336	1.70
297.0847778	3.10
299.2294006	1.74
311.0180969	4.74
311.8185425	2.35
313.1809998	10.81
315.4494629	0.89
319.9217529	1.58
321.2402954	3.03
322.0331421	4.30
323.2883606	8.39
339.2524414	100.00
340.0023804	2.90
341.4927673	15.77
342.2960205	1.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1109.94
Annotation	Unknow
Peak:m/z	Relative Intensity
801.1118774	0.17
814.6356201	0.13
907.2010498	0.06
1091.2734380	1.04
1094.1931150	0.04
1095.9853520	0.09
1238.3378910	0.62
1256.7919920	0.95
1260.5947270	0.05
1266.9860840	1.26
1272.7691650	0.54
1274.8216550	0.07
1275.8487550	3.02
1276.7344970	0.45
1278.3073730	0.35
1360.5472410	0.07
1422.7247310	0.78
1434.5606690	0.14
1439.0623780	0.88
1453.3104250	0.51
1457.4910890	0.45
1468.3438720	0.14
1603.1934810	0.24
1647.0667720	0.08
1664.3548580	1.14
1674.8848880	0.14
1684.2023930	0.15
1749.4396970	0.04
1757.7237550	0.07
1788.5733640	0.03
1793.9664310	0.06
1803.6822510	0.17
1814.4056400	0.05
1828.0902100	0.14
1831.5631100	0.27
1832.8819580	0.12
1835.1422120	0.11
1853.9539790	0.51
1858.5552980	0.22
1869.2135010	0.06
1871.9573970	0.07
1879.7452390	0.37
1885.9445800	5.50
1888.0313720	0.16
1901.3228760	0.61
1903.2923580	0.14
1907.0057370	0.06
1920.7502440	0.58
1922.7274170	0.14
1924.4420170	0.15
1926.4246830	0.19
1928.9343260	0.17
1930.3892820	0.10
1933.5338130	0.10
1934.8641360	0.18
1935.5823970	0.06
1936.5412600	0.40
1938.0921630	1.42
1938.9094240	0.06
1942.0106200	0.18
1952.3485110	2.64
1954.6966550	0.07
1956.0638430	1.27
1959.0631100	0.04
1961.1276860	0.05
1961.9930420	0.04
1963.4927980	0.62
1965.4559330	2.30
1970.5333250	24.56
1972.1041260	0.09
1973.4914550	3.27
1976.5856930	0.04
1979.7000730	0.43
1980.8492430	5.28
1981.7872310	6.08
1982.7823490	0.05
1985.7178960	0.19
1986.7634280	0.13
1989.6970210	100.00
1992.8905030	1.15
1996.0885010	10.25
1997.1779790	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	742.2902
Annotation	Unknow
Peak:m/z	Relative Intensity
269.2832642	1.06
335.1574707	0.36
412.3929443	0.31
415.2540894	0.30
442.1781006	0.34
469.4291992	0.36
476.7764893	0.18
487.8314819	0.53
506.4299927	0.37
511.4290771	1.03
512.3083496	1.93
519.7122192	0.59
529.4857178	0.47
531.3754883	0.15
548.6117554	0.52
576.2742920	0.58
580.7554321	0.29
620.6051636	0.29
621.5042725	0.67
629.6732788	0.41
636.3590088	0.42
638.3742065	1.33
643.5281982	0.56
653.5510864	0.91
655.7208862	0.23
657.2427979	0.23
660.1433105	0.30
665.3906860	0.55
667.5643921	0.47
668.4374390	0.26
670.2626343	0.15
678.2969971	0.41
681.8759766	1.19
682.5779419	0.35
688.6636963	0.35
695.4712524	0.47
696.1994019	1.29
699.2752686	100.00
700.4319458	6.92
706.3537598	0.36
710.3089600	2.18
724.2929077	1.53
725.6212769	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.2647
Annotation	Unknow
Peak:m/z	Relative Intensity
143.0034180	0.52
161.0287323	0.65
173.9745483	0.06
178.9423218	0.49
197.1177673	0.28
202.0431213	0.12
215.7449951	0.17
223.1536865	2.60
224.3860474	0.43
233.4918518	0.13
239.4850159	0.12
248.1617126	0.07
249.0718079	0.08
251.2595825	2.79
252.2798462	1.69
253.2407227	1.36
254.3525696	0.37
265.2093811	2.62
266.8715515	0.51
269.2373962	100.00
270.2993774	15.72
271.3866272	0.13
279.5795288	0.14
281.1934204	0.36
289.0070496	0.10
293.4310303	0.26
294.1027527	0.23
300.1174927	0.10
311.2528076	4.35
312.1693726	1.34
323.4400940	1.19
324.0762329	0.14
335.2425537	0.12
341.1171265	0.08
342.3254395	0.13
344.5692139	0.15
365.2915344	0.08
373.3119507	0.15
376.1606750	0.30
378.7553406	0.16
386.4538269	0.12
387.8583679	0.10
388.4730530	0.06
389.2255859	0.48
390.5111389	0.16
392.1129150	0.43
392.8390808	0.09
396.0701599	0.29
397.3389282	0.06
401.5633850	0.14
403.2605591	0.24
406.7322693	0.21
414.2308350	1.01
414.9390259	0.33
433.3501892	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	697.4009
Annotation	Unknow
Peak:m/z	Relative Intensity
206.4357147	0.08
253.2491455	0.04
323.4232788	0.07
341.2288208	0.16
355.4792480	0.91
356.4848633	0.35
358.5600586	0.08
370.1405640	0.06
373.6464844	0.21
377.2286377	0.17
390.3289795	0.14
400.3752441	0.05
403.5331421	0.03
420.3069458	0.13
433.4736328	0.07
434.3267822	0.09
456.4849243	0.04
462.3839722	0.07
469.4534912	0.04
473.4395142	0.10
498.0908813	0.04
499.5863037	2.54
500.5464478	0.65
505.4874878	0.61
506.3166504	0.16
517.4422607	100.00
518.5348511	24.78
531.0639648	0.03
535.4352417	15.83
536.4186401	4.15
549.8051758	0.16
577.6486816	0.07
578.4182739	0.05
584.9154663	0.25
601.8655396	0.04
605.5901489	0.04
612.7063599	0.09
616.7489014	0.14
620.5271606	0.13
624.0704956	0.19
634.0167847	0.14
636.1730347	0.12
636.8396606	0.03
639.4498901	0.13
651.9127808	0.11
655.1565552	0.08
661.9395142	0.77
662.5972290	0.03
663.3787842	0.06
665.1065063	0.10
666.3003540	0.16
667.5158081	0.23
668.3170776	0.20
679.4320679	11.10
680.5673828	5.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1081.74
Annotation	Unknow
Peak:m/z	Relative Intensity
358.2951660	0.10
365.5036011	0.16
376.1576233	0.51
394.0724792	0.62
394.8448486	0.34
458.3943176	0.05
511.1610413	0.40
512.0886230	0.22
525.8109131	0.12
540.1830444	0.02
557.2174072	0.53
558.0001221	0.28
559.3111572	0.09
574.3663330	0.08
579.2832031	0.06
640.6409912	0.05
646.5773926	0.13
659.1041260	0.24
667.3244019	0.37
685.1854858	1.32
686.3471069	0.72
742.2178955	1.15
743.3370361	0.21
790.3164062	0.21
805.0507812	0.06
829.9761963	0.08
907.5567627	0.09
908.6118164	0.04
967.2751465	0.23
984.1411133	0.05
1013.8021240	0.21
1034.8962400	0.56
1036.1009520	0.09
1037.1107180	9.73
1038.2626950	0.95
1039.3791500	0.12
1040.0543210	1.10
1041.3864750	1.47
1043.4952390	0.39
1044.3747560	0.22
1046.6132810	0.30
1047.3848880	0.09
1048.8233640	0.67
1049.6890870	0.09
1051.2630620	0.46
1053.5340580	2.73
1054.1933590	0.68
1055.0964360	1.58
1055.7661130	0.02
1056.6733400	0.48
1057.4860840	1.08
1058.7103270	2.87
1060.0893550	0.11
1061.5610350	0.18
1064.9865720	3.93
1065.9936520	2.28
1067.5043950	55.18
1068.8823240	4.07
1070.0134280	18.73
1071.1887210	2.09
1071.9903560	0.91
1072.8815920	0.76
1073.8686520	0.44
1074.6635740	0.39
1075.7558590	0.50
1077.0158690	0.26
1081.4354250	0.40
1082.4052730	0.47
1108.7644040	0.92
1124.4968260	16.22
1125.5908200	0.48
1127.2292480	0.44
1130.8930660	0.33
1132.6281740	0.47
1134.0440670	52.05
1135.2058110	0.94
1136.0275880	0.08
1137.1252440	0.04
1138.0421140	0.33
1138.7111820	0.18
1140.3480220	0.43
1143.3762210	0.05
1144.9556880	0.25
1152.5377200	11.86
1153.6347660	0.62
1155.4056400	27.58
1156.0434570	0.18
1158.1287840	0.53
1158.9495850	0.20
1163.7570800	0.19
1170.6060790	0.13
1172.2239990	1.49
1172.8527830	0.12
1176.9500730	0.82
1181.0585940	0.33
1182.5827640	58.34
1183.8966060	3.00
1185.1816410	1.62
1186.6948240	0.89
1187.9333500	0.13
1189.1810300	0.52
1193.8153080	0.50
1196.4447020	0.63
1199.7042240	1.34
1200.7507320	0.07
1206.9555660	0.94
1209.7724610	100.00
1211.5588380	1.52
1212.5932620	0.45
1213.2911380	0.56
1214.6385500	1.05
1215.6287840	0.32
1216.9187010	0.09
1218.0621340	0.46
1218.9921880	1.41
1220.2067870	0.59
1221.1827390	0.13
1223.4819340	0.54
1224.6965330	0.14
1226.5683590	1.24
1227.2971190	0.18
1228.0987550	0.31
1229.1130370	2.80
1230.4409180	2.59
1231.1264650	0.44
1232.8420410	0.10
1237.1215820	0.89
1242.3692630	0.24
1243.1605220	0.08
1307.1132810	0.40
1308.6408690	0.21
1315.2835690	0.33
1318.4924320	0.57
1338.1115720	0.17
1350.6871340	0.17
1360.6986080	0.50
1364.7692870	0.03
1367.6429440	0.07
1368.2734380	0.23
1370.4373780	0.23
1383.1851810	0.91
1393.5216060	0.09
1399.6833500	0.06
1409.4777830	0.34
1413.6839600	0.07
1419.4674070	0.10
1428.0078120	0.30
1430.1527100	0.25
1442.6563720	0.31
1450.6654050	0.43
1453.4725340	0.30
1468.6680910	0.07
1487.6929930	0.05
1494.0966800	0.28
1506.5332030	0.34
1529.1884770	0.17
1534.1986080	0.05
1534.8591310	0.11
1540.7247310	0.18
1563.5584720	0.04
1574.3426510	0.34
1576.5213620	0.17
1593.2272950	0.07
1612.1097410	0.30
1624.9865720	0.15
1638.7603760	0.90
1645.9566650	0.07
1650.8121340	0.09
1651.5162350	0.50
1653.2576900	0.14
1657.8337400	0.08
1659.8868410	0.16
1667.7220460	0.13
1687.6945800	0.21
1712.5255130	0.31
1719.7015380	0.07
1737.0423580	0.07
1755.3494870	0.34
1792.9263920	0.17
1804.1105960	0.20
1815.5450440	0.52
1820.2010500	0.66
1836.9000240	0.14
1848.9768070	0.39
1854.9329830	0.05
1859.3570560	0.28
1869.4857180	10.38
1876.2769780	0.08
1887.1491700	0.16
1892.5499270	0.70
1896.0681150	3.52
1902.9680180	0.05
1904.1146240	0.10
1907.6895750	0.09
1913.5544430	0.38
1915.8581540	0.08
1922.1276860	0.58
1922.7689210	0.10
1936.8050540	1.00
1944.1838380	0.16
1952.5998540	0.06
1956.8145750	0.05
1957.8278810	0.12
1960.3015140	5.20
1969.6428220	0.11
1970.7864990	1.52
1983.9361570	0.12
1985.2796630	0.59
1986.7955320	0.21
1987.8532710	0.04
1988.7142330	0.08
1993.5518800	0.12
1998.1075440	0.50
1999.8166500	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	494.1129
Annotation	Unknow
Peak:m/z	Relative Intensity
148.9945374	2.70
165.9953461	100.00
166.9745636	7.83
209.0598450	1.90
228.5354919	0.70
237.8399658	1.17
239.3210602	0.51
245.1539764	0.44
266.1116943	0.17
274.8870850	7.46
283.0090942	0.41
293.0204163	18.38
299.1440735	0.53
310.9188232	66.85
328.8834534	13.09
379.5558472	1.61
401.3685608	0.89
426.3451538	0.58
430.8376770	2.71
446.0065918	0.77
458.0959778	3.67
476.1982727	2.61
484.9814148	0.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.0964
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9260406	0.52
141.1766663	0.33
158.1383972	0.09
158.9840240	0.92
187.0886230	0.07
191.0475769	0.19
209.0413361	100.00
210.0608215	0.09
235.1051178	0.07
242.0810089	0.12
249.0094604	0.06
254.0052490	0.12
263.9853210	0.08
264.9835815	0.22
272.3750610	0.37
273.1702881	0.10
297.1120605	0.07
304.0572510	0.16
310.0734253	0.05
315.2474060	0.14
319.1004639	0.18
321.3889771	0.12
324.0851746	0.12
326.7107544	0.08
327.7057800	0.17
328.3780518	0.05
330.0965881	0.14
332.3094177	0.14
341.3536987	0.60
344.9946594	0.09
354.1617126	0.20
355.2307739	0.24
358.6815491	0.65
359.4387512	0.05
367.1470337	0.42
395.1628113	0.16
407.1812134	0.35
412.0660706	0.89
413.0049133	2.03
414.0268860	0.42
421.1317444	0.14
426.3191833	0.16
427.1351624	0.14
435.8884583	0.10
438.1952820	0.67
439.2228699	1.19
440.3075562	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.1242
Annotation	Ethyl (S)-3-hydroxybutyrate glucoside
Peak:m/z	Relative Intensity
84.8854370	1.78
87.0464325	0.26
88.9534302	4.05
95.1317291	0.03
96.8335724	0.08
98.9432221	0.12
100.9001923	4.96
106.9798584	0.11
113.0136185	6.85
114.9535675	0.45
118.9707031	3.76
125.0834961	0.47
127.2181473	1.45
128.0590057	2.94
129.0713348	0.37
130.9329834	100.00
140.8402100	0.14
142.9865417	2.33
145.0146179	0.38
146.2445984	0.05
147.1255798	0.04
148.9156799	0.58
152.0066528	0.12
155.0017090	0.05
159.0721893	0.35
161.0545502	0.96
164.1018677	0.09
173.0783691	6.26
174.3148956	0.17
178.8359680	2.26
180.0129547	0.63
185.0175629	0.68
186.9696198	0.66
190.8380127	0.04
197.1590271	0.05
203.1146851	0.47
205.0673828	0.15
207.1861267	0.09
213.2030334	0.11
214.9978027	0.07
217.0299683	0.13
227.2067871	0.42
229.1320801	0.51
232.3834229	0.16
233.0647888	0.19
238.7834167	0.09
247.0787659	0.51
249.2156067	0.60
251.0532837	0.05
257.1837769	0.17
257.8943481	0.07
259.0383911	0.61
263.0093079	0.04
265.1967773	0.17
272.9791260	0.09
274.5279846	0.90
275.2456665	2.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	947.2463
Annotation	Kaempferol 3,4'-diglucoside 7-(2-feruloylglucoside)
Peak:m/z	Relative Intensity
263.2313538	0.06
271.1235962	0.20
272.0212708	0.14
273.2749329	0.08
274.1700134	0.07
280.4367065	0.07
283.0714417	0.13
284.1285706	0.04
285.1379700	0.07
297.1177673	0.08
300.0478516	3.36
301.0830078	14.96
302.2579041	1.79
312.9140320	0.09
315.1114197	5.84
316.1911621	0.94
323.2831421	4.06
324.2560120	0.33
325.1471863	0.06
327.1939697	0.05
337.2770386	0.08
339.5831909	0.04
343.1597595	0.57
344.2786560	0.02
352.9896851	0.03
357.3039551	0.05
373.4511719	0.08
385.1252441	0.08
399.1162109	0.06
445.3671875	0.16
446.1298828	0.02
448.1138916	0.05
457.4130859	0.03
460.1254272	0.07
463.1793823	0.07
464.3674927	0.06
465.3300171	0.02
469.2946167	0.04
471.3228760	0.03
475.2587891	0.07
476.9912720	0.02
478.3174438	0.03
489.2454834	0.75
490.1683350	0.14
507.6829224	0.04
509.1528320	0.05
511.9880981	0.06
517.0903320	2.74
518.1642456	0.61
559.1731567	0.05
565.4257812	0.03
579.1506348	0.05
591.4426880	0.15
592.1185303	0.07
595.4054565	0.03
605.9657593	0.17
609.2378540	67.79
610.2409058	15.99
610.9829102	0.16
621.3008423	2.97
622.3250122	1.13
623.2512817	0.57
624.1958618	0.07
625.5211792	0.11
631.4242554	1.10
632.4072876	0.04
633.1260376	0.02
637.2385864	0.02
639.1861572	100.00
640.2222900	28.80
640.8446655	0.13
651.2529907	0.14
652.2907715	0.02
664.6553345	0.04
681.1971436	0.49
682.5536499	0.04
691.0964966	0.02
693.3794556	0.03
711.1894531	0.10
712.2333374	0.01
750.0490112	0.05
753.1958618	0.20
753.9291382	0.04
767.2284546	0.04
768.3472290	0.03
771.3465576	1.45
772.2639771	0.34
782.1058350	0.03
783.9704590	0.04
785.1929932	2.10
786.1495972	0.91
787.4126587	0.04
793.6903076	0.03
801.1889648	0.06
808.6254272	0.05
861.5744019	0.05
896.1481323	0.05
903.7045898	0.02
911.2536621	0.05
917.6120605	0.06
927.3152466	0.02
929.3234863	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	441.18
Annotation	[3aR-(3aR*,5E,7R*,9Z,11aR*)]-2,3,3a,4,7,8,11,11a-Octahydro-7-hydroxy-6-methyl-3-methylene-2-oxo-, beta-D-glucopyranosyl ester cyclodeca[b]furan-10-carboxylic acid
Peak:m/z	Relative Intensity
180.7026367	1.18
184.1088257	11.85
198.0117493	1.92
202.0108185	0.35
206.4487152	0.57
210.3155212	1.19
240.1742249	65.17
258.1551514	58.52
269.2909546	0.39
272.2821350	5.95
287.1633301	100.00
291.8853149	1.48
322.2115784	0.67
382.3571167	0.61
423.1719360	8.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	295.03
Annotation	Unknow
Peak:m/z	Relative Intensity
96.8261185	2.33
99.0323715	0.94
104.8479004	0.60
108.8794708	3.28
110.5144501	0.20
115.8915863	1.77
126.9668732	23.17
132.7881622	0.66
133.9912720	28.79
136.0339355	3.73
144.8448486	3.50
150.8869019	6.89
153.4218140	0.88
162.0037079	7.33
163.0031128	0.14
169.0559387	1.49
174.9635620	0.25
177.0829010	0.17
182.0571136	0.52
193.1394653	0.45
199.1716309	0.25
211.2398376	0.15
217.1330261	2.05
230.8155212	0.10
234.9499207	0.30
245.4359131	0.48
246.4248047	0.77
249.1363525	5.79
258.2687378	4.03
258.9511414	24.89
260.8813477	0.18
263.4468384	0.51
267.2651367	0.22
274.8336487	0.64
276.9990540	100.00
278.1524658	1.08
286.1358032	2.17
373.1801147	0.24
441.0939331	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	374.1071
Annotation	DIMBOA-Glc
Peak:m/z	Relative Intensity
107.9630890	0.33
116.0653458	0.39
122.9660416	0.84
128.9026642	0.75
134.9045105	0.30
136.0085449	4.63
147.0517273	0.91
155.1566467	0.21
161.1448669	0.19
164.9532776	10.47
174.8974152	0.13
182.0719299	100.00
186.9354706	0.36
199.1782532	1.81
200.2345428	0.19
207.7839813	0.33
209.0614014	0.40
212.0134583	0.17
217.2180634	1.11
225.2593689	0.50
226.2217407	2.86
227.1195068	1.90
232.2138977	0.19
233.0352478	0.28
238.0298462	0.34
240.4723816	0.28
241.7178955	0.15
243.1842041	0.72
245.9169312	0.50
250.0278625	5.84
251.2145691	1.70
258.1024475	1.72
267.8682251	0.73
269.1663208	0.19
274.6206055	0.21
275.5720825	0.13
279.2711792	0.26
297.1477966	0.13
308.1909790	1.23
309.8651428	1.07
314.2491455	0.21
320.5965881	0.38
329.7089844	0.70
337.2985840	0.24
338.4626465	1.21
355.4797668	4.28
356.2409363	4.81
357.3126831	5.05
364.7361450	2.98
365.7944641	0.79
382.3151550	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	687.3019
Annotation	Mombasol
Peak:m/z	Relative Intensity
183.9866791	0.24
305.1007080	0.29
335.2367249	0.23
352.3217163	0.45
376.2253418	0.23
431.3510742	0.59
432.2954102	0.31
456.2305298	0.64
468.6415405	0.79
475.2055664	1.76
567.2737427	1.17
583.5039062	2.85
587.3795776	0.39
596.4918823	0.62
599.3993530	28.94
611.3330688	17.98
614.4998779	0.95
623.4988403	1.52
625.5402222	1.21
627.4298706	0.48
637.3960571	0.54
643.3668213	100.00
655.1236572	27.75
655.7256470	2.37
669.0923462	0.75
670.1693726	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	330.0672
Annotation	Unknow
Peak:m/z	Relative Intensity
126.8922882	0.23
136.0140381	0.34
137.2071838	0.13
144.6956787	0.10
150.9618988	0.53
163.0800476	0.10
166.0708618	0.05
175.8721161	0.10
179.9772644	0.15
213.1977539	0.79
258.8124390	1.71
276.9761353	36.53
280.7189941	0.15
284.1644592	0.04
285.3037720	0.04
289.0072937	0.07
290.0032349	0.11
291.2422485	0.20
292.8096008	0.23
294.8439026	100.00
295.5317993	0.48
311.0650635	0.56
312.0705872	3.16
313.1763000	0.46
320.6268311	0.26
321.3123169	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	250.15
Annotation	Unknow
Peak:m/z	Relative Intensity
80.8777466	0.08
87.9542694	0.24
100.5754547	0.30
101.5743408	0.10
107.0425568	0.06
110.6762848	0.55
114.8888245	0.14
115.8789215	0.07
118.1531372	0.20
121.0131531	0.05
121.8569946	0.04
134.6284332	0.09
143.3180237	0.06
148.8688812	0.06
155.1359711	0.15
158.2440948	0.04
160.9857788	0.94
167.1033020	0.13
173.1206970	0.33
174.0352020	0.69
174.6474457	0.07
176.3745270	0.05
179.9982605	0.12
186.0264587	0.76
186.9894867	0.07
188.2664795	0.34
190.2713776	0.10
191.1200562	0.10
192.4716034	0.08
193.2130280	0.16
204.1132660	0.35
207.9861145	0.35
209.0860748	0.47
211.2441559	0.17
214.3075714	2.01
214.9872742	9.42
232.0852814	36.37
233.0254974	100.00
234.2781982	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	6-Methylflavonol
Peak:m/z	Relative Intensity
100.9919739	0.26
102.9476013	0.25
107.0062561	0.21
109.0681458	0.31
117.4792938	0.08
118.099762	0.10
120.9191742	1.05
122.9796143	0.30
128.4924469	1.16
129.1154938	0.99
130.048645	0.33
133.3504333	0.22
136.1043549	0.97
138.7881317	0.27
141.1618042	0.15
147.2302399	0.15
150.9016266	13.30
151.9689178	3.27
155.148941	0.29
159.2454834	0.31
160.2702637	0.25
166.1308289	0.22
167.0029144	0.77
169.0978546	0.48
172.0648499	0.39
175.4465942	0.19
176.4538422	0.15
179.5123444	0.55
182.8414154	0.76
184.1427917	0.43
184.9420319	0.14
186.1732483	0.22
188.0631104	0.32
191.3817444	0.08
192.064682	0.06
194.9028168	0.07
196.3072357	0.53
197.1272278	1.08
201.1093292	0.35
206.0715485	3.66
207.2614136	0.12
208.0386505	1.42
209.2466125	0.08
209.9800415	0.12
210.9828796	0.27
211.9673309	0.35
212.8480072	0.29
217.2558289	0.07
218.078125	2.86
225.1182098	1.30
226.0754547	1.24
235.3317871	2.08
236.0939331	5.63
236.8800049	0.35
237.9922943	1.20
238.9707031	1.05
253.0787811	100.00
254.1782227	5.83
255.3686676	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	282.0843
Annotation	Crotonoside
Peak:m/z	Relative Intensity
106.9069061	0.17
107.8142090	0.07
114.0512161	0.03
128.0178375	0.02
132.9601440	3.51
149.9555359	100.00
157.1438446	0.04
167.1715546	0.04
180.0812683	0.03
190.0761719	0.05
191.2001648	0.07
192.8350220	0.03
194.1555481	0.03
194.9324036	0.07
223.2994385	0.03
235.8752441	0.10
238.0252991	0.20
239.3009949	0.09
263.9799194	0.07
282.2105408	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1102.3147
Annotation	Unknow
Peak:m/z	Relative Intensity
428.8591919	0.08
455.2135620	0.14
880.1206055	0.12
884.5566406	0.05
918.9951172	0.20
990.5714111	0.17
1000.8861080	0.31
1008.1016850	0.44
1009.1612550	0.09
1018.5541990	0.13
1024.5512700	0.66
1033.0532230	0.49
1033.7523190	0.27
1063.4993900	0.37
1065.6826170	1.36
1070.1096190	1.70
1080.9794920	0.27
1122.1257320	0.39
1160.3032230	0.22
1178.6311040	0.49
1245.0039060	0.24
1252.2692870	0.35
1255.1968990	0.37
1292.5793460	0.25
1312.4537350	0.38
1327.9141850	0.41
1358.2435300	0.62
1371.1174320	1.10
1376.9014890	2.56
1377.7343750	0.53
1378.6556400	0.25
1414.6729740	0.24
1426.0845950	0.62
1443.2308350	0.33
1448.6838380	0.09
1517.3730470	0.13
1529.7396240	0.12
1543.2943120	0.49
1580.4337160	0.05
1620.8841550	0.37
1628.9035640	0.07
1674.7142330	0.12
1679.3284910	0.38
1694.5096440	0.08
1735.1485600	0.12
1741.9215090	6.70
1742.9323730	0.37
1744.1453860	0.06
1744.9899900	0.92
1746.0749510	0.09
1760.0440670	0.20
1770.8150630	0.95
1779.0305180	0.10
1783.4442140	13.80
1785.2303470	0.11
1789.3880620	1.44
1794.0433350	1.45
1797.6315920	0.12
1815.0404050	0.12
1822.4010010	0.14
1831.5426030	0.08
1835.9698490	0.70
1849.7056880	0.40
1855.5533450	0.10
1858.2565920	0.10
1859.6734620	0.48
1873.2561040	0.14
1875.8958740	0.30
1879.8439940	0.10
1881.5701900	0.14
1887.8665770	0.40
1888.8929440	1.45
1890.6412350	0.32
1897.4268800	0.60
1903.9661870	0.06
1909.2032470	1.01
1922.0515140	0.09
1924.1339110	0.07
1925.9466550	0.10
1927.3294680	4.31
1928.8248290	18.38
1931.0301510	21.88
1931.7591550	0.98
1936.5577390	0.22
1937.2100830	29.48
1939.1639400	0.10
1942.5686040	53.34
1943.3753660	0.12
1946.5059810	2.44
1950.8068850	0.82
1951.5714110	0.96
1953.6228030	0.13
1954.7814940	0.22
1957.6799320	0.14
1958.6848140	0.18
1959.5197750	1.26
1963.4616700	12.67
1967.8980710	0.07
1969.1951900	3.01
1973.9835210	0.05
1974.5867920	0.08
1975.5509030	0.62
1976.8702390	100.00
1977.6296390	2.01
1981.8020020	0.28
1982.9508060	0.79
1986.5609130	1.94
1987.4024660	1.39
1988.3670650	0.27
1989.4576420	4.87
1991.8806150	0.59
1993.4339600	0.28
1995.4172360	1.69
1996.8875730	44.50
1997.7879640	0.74
1998.9460450	88.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.16
Annotation	Rutine
Peak:m/z	Relative Intensity
213.8013916	1.98
303.0478821	100.00
304.2774353	2.83
305.1302185	1.30
309.1821899	2.53
344.7474365	8.83
412.895874	1.58
429.2918091	2.56
449.1080322	2.67
461.5603027	1.21
464.9825439	62.50
525.3034668	1.80
530.6621704	3.20
537.0689087	2.29
574.0609741	5.67
575.4387817	6.02
580.2044067	1.50
585.1417847	1.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	360.2124
Annotation	Unknow
Peak:m/z	Relative Intensity
126.8370972	0.06
132.0791321	0.58
137.0892181	0.16
143.9783020	0.68
177.0902405	0.07
186.9566193	0.07
192.0741577	0.13
201.0965729	12.57
207.0207062	0.08
212.3489685	0.14
227.4223633	0.24
229.0004883	100.00
231.1855164	0.15
234.1652832	0.16
236.3068237	0.24
238.0286865	0.10
240.3663330	0.11
245.4735718	0.17
247.4148560	0.13
253.0168152	0.33
262.3182068	0.20
275.4011230	0.10
282.2866211	0.19
284.1196899	0.09
289.0422974	0.07
297.1433105	1.22
309.5308838	0.79
310.9638062	0.38
314.2700806	1.41
315.2312012	0.17
316.2563477	0.48
324.3784790	0.16
325.0486755	0.43
328.8108826	0.19
342.1335144	23.24
343.2298279	0.42
345.7073364	0.35
351.2171936	1.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	455.0556
Annotation	Tjipanazole B
Peak:m/z	Relative Intensity
131.1131287	0.11
142.1205139	0.03
154.1694336	0.14
157.8956909	0.04
173.0586548	0.60
178.0453796	0.02
179.1746826	0.02
180.9369812	0.04
184.1242981	0.02
187.1448364	0.14
189.0886230	0.06
197.2073212	0.55
199.0433655	0.13
201.8243103	0.02
209.9600677	0.03
212.1828308	0.07
213.1959229	0.19
222.3111877	0.03
227.4222412	0.03
231.1170349	2.24
234.2907562	0.02
237.2177124	0.10
239.2067413	0.13
241.1922302	0.19
253.2149353	0.02
255.2129517	0.05
256.1690674	0.28
259.2253113	0.14
260.0315247	0.02
263.3295288	0.03
265.1170349	0.03
269.7659912	0.02
271.1801453	0.39
273.1392822	100.00
289.1151123	0.09
289.8657837	0.03
291.1305542	0.09
292.3747559	0.14
294.1339417	0.09
303.1822205	2.53
305.1522522	7.41
307.1221619	6.49
307.7624207	0.04
322.2180176	0.02
324.6351318	0.03
330.7488098	0.05
333.6896973	0.04
335.9470215	0.08
337.0971680	43.40
345.2833862	0.07
349.3547058	0.10
354.2291565	0.05
356.0864563	0.04
361.0087280	0.05
363.3946533	0.20
367.0849609	0.02
370.0374756	0.02
371.3348999	0.01
375.2635193	0.14
376.1763000	0.04
377.9358521	0.07
383.0945740	0.05
384.3439941	0.02
385.3129578	0.02
389.1225891	1.05
393.9374695	0.15
407.1183777	0.08
408.1540222	0.04
409.1257629	0.97
410.2621765	0.29
411.0413818	0.07
416.1002502	0.10
416.8750000	0.02
418.0697937	0.07
419.0226440	0.07
421.0478210	0.57
423.5355530	0.02
424.4885864	0.03
427.0306091	0.23
434.4293518	0.04
435.4817810	0.21
437.3319397	0.36
438.0967102	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.9719
Annotation	Unknow
Peak:m/z	Relative Intensity
112.6130676	0.08
133.9073029	0.11
136.0236816	0.03
159.1308899	0.06
174.7103271	0.06
179.9141388	0.14
202.9386597	0.17
207.9255676	0.03
211.1645050	0.10
213.1180725	2.62
214.5428162	0.06
226.9465637	0.09
228.8937683	0.08
233.1382751	0.03
238.9367676	0.03
242.9411621	0.08
244.8554993	0.56
258.1018066	0.10
271.0099487	0.39
276.8011475	0.06
286.2078247	0.03
287.0689087	0.07
288.7529907	0.06
297.2072754	0.03
303.2980957	0.03
303.9037476	0.08
305.0430298	3.05
306.1290588	0.14
307.2097168	1.37
308.1305237	0.32
310.2028198	0.59
315.0697021	1.93
317.1301575	0.22
321.0719604	0.16
323.3082581	0.12
327.0935669	0.06
330.9385986	0.10
332.9678650	4.96
334.9926147	1.61
338.1103210	0.13
342.0792847	0.05
343.1085815	0.20
345.0704041	0.09
346.9990234	0.14
348.8199463	1.59
349.4275513	0.07
358.9697266	1.74
362.0272217	0.16
362.8871765	0.23
365.4033813	0.04
366.1729431	0.26
374.7137451	0.27
376.9308167	4.85
378.3645935	0.17
382.1662292	0.05
385.1204529	0.16
388.0174866	0.04
390.0152893	0.07
394.0066223	14.70
394.9876099	15.76
402.9363098	10.10
403.7865906	0.09
408.0531921	0.18
411.5108948	0.11
420.9209900	100.00
422.3385315	0.43
430.2536011	0.05
435.5447998	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	647.13
Annotation	Unknow
Peak:m/z	Relative Intensity
198.8768616	0.04
206.9915161	0.09
207.6650696	0.10
237.0953217	0.21
241.2227783	1.46
242.3507080	0.11
259.0284119	0.29
271.3177490	0.07
305.1755371	18.39
306.3847046	0.10
323.2034912	0.22
337.1020508	0.04
339.1135864	0.72
340.9250488	7.26
358.0354004	0.04
372.9295044	0.17
386.2102051	0.10
457.2415161	0.04
473.3409424	0.37
484.2339478	0.05
485.3939819	0.14
517.1616821	0.20
518.2875366	0.06
520.2113647	0.15
532.6095581	0.03
556.0538330	0.06
575.1680298	0.09
598.2800293	0.09
601.7623901	0.39
602.5195923	0.35
603.5181274	0.11
605.6876831	0.10
610.9331665	100.00
611.6862183	0.16
613.2556763	0.08
617.7123413	0.08
628.2577515	0.57
629.1453247	0.77
630.4019165	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	357.2492
Annotation	Unknow
Peak:m/z	Relative Intensity
123.9743347	1.26
125.9970474	0.11
129.0572510	1.54
129.9914093	0.08
141.9813843	3.50
151.9664307	4.26
153.1981812	0.12
155.1860352	0.23
156.3203430	0.13
161.1120605	0.07
169.2759399	1.04
170.0617676	2.93
171.2535706	0.10
173.2129211	0.05
174.9856415	0.20
179.1951599	0.11
182.1692810	0.13
191.1372833	0.07
197.2700195	0.37
201.1939850	0.14
206.9946747	0.29
209.1790771	0.09
211.1623688	0.08
211.9725952	0.07
212.6998444	0.78
215.0892944	1.89
224.0686340	0.26
226.2508545	0.97
227.3715210	0.05
229.1701355	100.00
240.2033691	0.74
242.1163330	1.89
252.2111511	0.21
254.3921204	0.05
258.2303162	9.47
262.2578430	0.56
263.0192871	0.17
270.3475952	0.78
272.1533203	0.60
272.8201599	0.10
280.2054443	2.99
281.1951599	0.20
282.5885620	0.28
285.8019409	0.11
294.8380737	0.24
298.1777649	34.03
306.9984131	0.17
311.0737305	0.12
312.4017639	0.21
313.1594238	0.09
338.3653870	0.44
339.3269043	3.29
340.0765686	0.82
343.4936829	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	249.139
Annotation	brasilidine A
Peak:m/z	Relative Intensity
97.0652771	0.05
100.5207977	0.07
114.6574860	2.38
115.3430939	0.19
116.7456818	1.21
133.0574188	0.20
135.8446198	0.10
147.8760529	0.12
149.9812164	0.20
150.8729706	0.96
155.9212189	1.27
158.8289948	0.08
169.0025635	0.20
171.0048218	0.37
172.9553680	5.92
175.0287018	0.49
183.0402985	0.27
184.8206024	0.15
191.0938110	0.06
191.7328796	0.49
193.2221527	0.53
197.9328461	0.07
201.1224670	26.88
203.3299713	0.47
207.2092590	0.06
207.8368378	0.09
210.9781647	0.27
212.1228027	0.32
212.9736176	0.09
219.1830902	3.96
220.1903687	0.16
221.0995941	0.28
223.3149872	0.48
227.1464691	0.58
229.0307617	82.29
231.4488068	12.80
232.2188263	0.19
234.3018036	0.36
235.5186920	0.06
238.0857544	0.40
240.1148224	40.06
240.7859039	0.96
241.4098358	0.18
242.0867920	0.05
251.1877899	0.32
259.6312866	0.21
269.1204529	100.00
270.2327576	0.66
282.0725403	0.10
296.4262695	0.16
297.0591431	0.07
314.3171387	0.43
324.2298889	0.04
325.5149231	0.16
342.1490173	1.02
365.4761047	0.10
379.2342834	0.10
382.3947449	0.68
384.2961731	0.25
421.1004333	0.07
462.3381958	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	260.09
Annotation	Unknow
Peak:m/z	Relative Intensity
78.9272461	0.64
96.8767700	2.88
97.7441711	0.09
112.9392700	2.29
113.9654999	1.27
115.0691528	0.06
127.9220123	20.12
130.9451599	28.59
138.8795929	0.27
144.1363678	0.21
145.1119995	3.77
155.0484772	0.06
161.1255035	0.19
169.0053864	0.21
180.0998230	0.20
181.1597748	0.28
199.0923004	1.58
200.0819244	0.29
215.0163879	0.15
216.1946564	0.11
224.0409393	20.91
225.1813202	1.45
230.1686554	0.08
242.0666504	100.00
243.0195465	8.61
245.0510406	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	642.9739
Annotation	Unknow
Peak:m/z	Relative Intensity
289.1115723	0.18
319.0546265	1.04
368.7496338	0.40
383.0643311	0.91
391.0744629	0.65
401.0184326	37.92
403.8046875	0.14
438.0964966	0.18
463.1715088	0.12
474.9154663	1.26
481.1165771	100.00
545.1275024	0.63
558.8218994	8.49
600.2682495	0.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.16
Annotation	Rutin
Peak:m/z	Relative Intensity
187.4590912	0.45
193.1827393	0.34
232.8227539	0.37
261.1295776	0.18
263.0934448	0.69
267.2706604	0.61
273.2998047	0.47
286.107666	0.65
291.2157593	0.26
296.1266479	0.37
298.9640503	0.41
303.0615845	100.00
317.1159668	0.49
342.9737549	0.87
345.24646	0.35
353.2642212	0.59
355.112793	0.90
369.3057251	0.20
393.1530762	0.33
442.8805542	0.33
448.8011475	2.58
455.3383179	1.28
464.9686279	29.34
465.5910034	0.12
468.289856	0.78
473.0721436	1.21
481.5657349	0.30
490.6286011	0.43
494.6680908	0.76
497.8770752	0.51
513.7454834	0.62
525.7564087	1.09
529.3255615	2.42
531.4473877	0.51
540.5605469	0.33
545.637146	0.37
556.9710083	1.17
566.1758423	0.45
567.6332397	0.59
573.649353	0.66
576.5814209	0.30
578.4032593	0.34
581.5631714	3.10
592.9519653	4.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	445.1172
Annotation	Sissotrine
Peak:m/z	Relative Intensity
130.0378723	0.02
145.172821	0.02
151.2236633	0.02
162.7144928	0.02
178.4746704	0.03
179.0986023	0.17
181.046463	0.03
182.0985107	0.03
195.1248169	0.33
235.1064148	0.07
238.0051422	0.12
243.3644104	0.06
249.1237488	1.11
250.0715027	0.18
261.0606079	0.08
275.4481201	0.02
277.5897217	0.06
280.4494324	0.02
283.0648499	100.00
284.1416626	12.75
288.1105652	0.05
295.8389282	0.05
314.1847839	0.03
317.3374634	0.04
324.833252	0.02
328.0272827	0.02
329.3520203	0.04
337.1904907	0.04
340.5527954	0.07
341.324707	0.07
345.1593933	0.02
349.9395142	0.06
353.1413879	0.03
355.4664307	0.02
358.1363831	0.05
359.193634	0.13
361.5882263	0.11
369.1103516	0.05
370.0661316	0.08
373.960083	0.02
383.2782898	0.07
397.4118958	0.04
398.9655762	0.06
400.2805176	0.22
401.3331909	0.12
402.1932068	0.05
403.4031677	0.04
407.3258362	0.04
408.0932312	0.02
409.927124	0.46
411.4165955	0.07
426.1266174	0.08
427.4634094	0.41
428.2452393	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	464.6799
Annotation	Unknow
Peak:m/z	Relative Intensity
157.6828156	1.70
232.2383423	2.58
274.3662109	3.15
289.1001282	3.98
307.0255127	29.07
308.2340698	23.33
394.3024597	2.58
405.9605408	2.48
448.4403992	14.85
449.3539124	5.26
450.0507202	2.55
450.7464905	1.62
480.7665405	2.43
589.3090820	8.78
590.3889160	10.15
621.3775024	52.78
622.3670044	100.00
623.4497681	14.48
624.4976196	2.54
739.7128906	1.77
787.7134399	1.48
799.1939087	6.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.1611
Annotation	Stereospermoside
Peak:m/z	Relative Intensity
150.0632935	0.15
151.2283630	0.20
151.9483795	0.28
164.9163818	0.86
166.9711914	4.94
181.0242767	0.37
195.1204224	0.55
201.0685577	0.11
208.8153687	0.06
211.0590820	0.04
213.0976562	0.05
217.1050568	0.05
226.0305481	0.10
236.1206818	0.15
257.1433105	0.19
259.2604370	0.06
269.0979614	0.11
272.2458496	0.06
281.3042603	0.17
299.8460999	0.09
306.0422974	0.06
313.3700562	0.08
315.1914673	6.28
324.2966919	0.05
329.1360474	0.92
331.9616699	0.08
332.5726318	0.04
336.8632812	0.07
345.6981812	0.72
360.3025513	0.21
361.5982666	0.67
363.0708618	100.00
364.1097412	0.10
368.1325073	0.06
369.1279907	0.05
374.9808960	0.32
403.3134155	0.40
403.9725952	0.18
404.9520264	0.44
409.2327881	0.49
410.4757080	0.06
419.3609619	0.16
421.1513672	0.17
422.5842896	0.47
429.2863770	0.37
430.0692139	0.12
431.1827393	0.07
432.0366211	0.26
433.1990356	0.18
434.0145264	0.10
435.0783081	0.60
437.3722534	0.22
438.2854614	0.04
462.8770752	0.26
464.9505615	2.04
472.0778198	0.07
478.3507690	0.59
479.2039185	0.88
481.1121826	0.86
489.1030884	0.81
490.4227295	0.05
495.3646240	0.43
496.8309326	0.48
504.2267456	0.10
505.1676025	0.51
506.7152710	2.16
507.4792480	1.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	467.21
Annotation	Ebracteatoside C
Peak:m/z	Relative Intensity
137.0111542	1.33
145.1072693	0.13
158.8381653	0.39
172.9121246	0.12
191.2759094	0.20
192.9149475	0.44
195.4667969	0.08
205.1429443	0.19
219.3472900	0.17
235.0130920	0.13
247.1037903	0.18
249.2786255	0.11
259.1347046	0.10
263.2412109	0.06
264.4281311	0.18
267.0803528	0.39
274.6786804	0.10
277.3591919	0.08
289.0095215	0.33
293.0494690	2.95
295.1198730	0.09
303.3677979	0.10
304.0939941	0.31
307.9854126	0.12
309.1576538	0.11
311.8894958	0.10
315.4346924	0.06
317.1644287	1.50
329.0993652	0.40
341.1029968	0.22
348.5741882	0.08
366.2890625	0.16
369.0426025	0.10
371.3133850	0.08
373.2491150	0.19
375.2797546	0.07
377.4397278	0.16
379.2120972	0.16
381.2248230	0.94
383.2556763	0.64
389.1953430	0.13
399.0816650	0.89
400.9131165	0.29
403.5973511	0.08
407.0813293	0.13
411.1518250	0.15
419.0816345	0.05
421.1928406	100.00
422.0686646	0.05
423.0075378	0.54
423.9703674	0.57
425.2554321	0.17
429.2177429	0.21
430.8448792	2.16
431.5299988	0.07
447.0137939	0.05
448.9452820	2.70
450.1766052	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	486.8822
Annotation	Unknow
Peak:m/z	Relative Intensity
163.0859375	0.05
210.2215881	0.05
221.1424561	0.02
223.1697235	0.03
225.0932922	0.04
234.1949158	0.04
238.1183167	0.03
239.0204163	0.04
264.0558167	0.10
279.3515015	0.09
281.4215393	0.04
284.0215454	0.05
285.0115051	0.04
291.1551208	0.04
292.7576294	0.07
295.3267212	0.05
304.9519653	0.07
313.1687012	0.13
316.0207520	0.08
317.2930908	0.05
319.1252441	0.07
320.0880737	0.12
323.4768066	0.11
324.3131714	0.12
325.0148315	0.04
336.0090027	0.14
337.0281372	0.73
343.3404846	0.24
349.3130493	0.09
354.4246216	0.03
355.9429932	0.04
357.2504883	0.06
361.4447327	0.06
366.1251831	0.09
369.1439819	0.15
371.1095886	4.30
372.2356567	0.10
372.9650879	0.02
388.3118896	0.17
390.3020325	0.02
391.0648499	0.06
395.1325378	0.05
396.8130188	0.09
399.0378723	0.08
401.9302673	100.00
403.0752869	5.80
404.2644958	0.06
409.0588074	3.65
412.1769714	0.14
417.2489929	0.06
421.3581543	0.03
422.9593201	0.06
425.6713257	0.12
426.9554749	0.28
429.5052185	0.03
431.2836609	0.10
433.1070557	0.06
435.3327942	0.05
440.4916077	0.38
442.8688965	16.00
443.9331970	1.31
448.1889648	0.37
449.3548889	0.64
450.2165833	1.03
453.3351135	0.12
468.1882935	0.34
468.8729858	0.20
469.6471558	0.04
471.9380188	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	725.3958
Annotation	Gingerglycolipid C
Peak:m/z	Relative Intensity
277.8608704	0.15
329.1316528	0.42
340.1757812	0.05
344.5437012	0.05
367.2026978	1.64
369.2994995	0.09
399.8368530	0.14
432.3075562	0.06
469.3612061	0.21
495.5949707	0.05
498.2776489	0.04
523.3627319	0.08
550.3960571	0.16
562.3632202	0.10
568.9965210	0.10
576.6524048	0.06
579.6126099	0.09
581.1173706	0.12
593.3771362	0.04
595.1847534	0.29
629.7111816	0.11
643.0384521	0.04
649.2818604	0.13
653.3883057	0.12
661.5797729	0.21
665.5023804	0.35
666.3283691	0.71
668.0214233	0.08
677.7438354	0.09
679.4151611	100.00
680.1039429	0.50
681.2600708	0.23
689.2399292	0.18
691.1771851	0.71
704.5463257	0.40
706.4037476	0.26
707.8767090	0.15
710.0416870	0.05
715.6627808	0.07
720.9537964	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	290.85
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8308792	1.52
140.0383911	0.03
175.0910034	0.05
176.1524658	0.04
201.2009583	0.02
203.2870483	0.07
206.7479248	100.00
207.3602295	0.34
222.8738403	0.30
231.0332947	0.11
245.1276855	0.03
272.4454041	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	323.0286
Annotation	UMP
Peak:m/z	Relative Intensity
96.8602982	10.68
98.9284668	0.09
110.9333878	0.26
112.9166489	0.03
119.8324127	0.05
127.0569763	0.04
130.8348846	0.08
134.9872131	1.07
138.9296722	2.89
139.9554901	0.07
145.8062744	0.05
148.9330444	0.04
150.9662170	4.01
152.0315857	0.30
153.0295105	0.07
154.1801147	0.04
160.0234375	0.32
161.0342712	2.03
162.9959106	0.20
164.0177307	0.14
175.0268860	0.05
178.8110352	0.03
182.1327057	1.10
184.9290771	0.07
187.0100250	0.20
192.9858704	2.72
195.9763641	0.08
196.9858856	0.06
200.1737823	0.13
201.9997864	0.23
203.0216370	0.09
205.3254395	0.19
208.9213562	0.04
210.9625854	100.00
212.0140381	0.20
215.0507202	0.27
218.3571777	0.11
220.0152893	0.09
223.0762024	0.12
225.1042480	0.42
232.1863098	1.42
233.0541687	7.96
236.2385254	0.11
244.2939453	0.08
249.1922302	0.06
262.1398621	1.51
263.0995483	1.47
280.0438232	34.51
280.6749878	0.05
287.2922363	0.03
293.2235718	0.21
304.9271851	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	366.1296
Annotation	Unknow
Peak:m/z	Relative Intensity
108.4814529	0.47
109.0931015	0.18
109.8576584	0.18
118.0819016	0.22
135.9594421	1.25
136.9849091	2.22
154.0054321	100.00
155.0921326	0.21
155.9948730	0.10
168.0723877	0.14
173.0794983	0.99
191.1400452	0.10
191.9351196	0.16
234.1497192	0.12
282.1536255	0.47
288.0557251	0.04
298.1466064	0.07
321.3592529	0.07
324.2806396	0.14
337.4310913	0.14
349.3955688	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	382.0724
Annotation	Unknow
Peak:m/z	Relative Intensity
130.2006073	0.93
161.8758240	1.63
177.0282898	1.98
178.8344116	1.44
184.8618469	0.24
213.2517700	0.61
220.1851807	0.80
244.9573669	1.22
247.9445190	0.35
252.8888245	0.26
266.0754395	12.20
266.7217407	0.57
271.8954773	0.95
276.5567932	0.47
278.2148438	0.81
279.6785889	0.35
305.9076538	5.97
308.1657410	0.89
309.2883911	1.09
317.7425537	100.00
321.8212891	1.10
322.9398804	0.43
330.2912292	1.60
344.5821228	9.18
345.2211304	1.60
346.0727539	0.71
346.8892822	0.31
360.5618591	0.55
363.4920654	0.67
364.1802673	2.19
370.1549988	1.49
372.7101135	0.63
373.7431030	2.62
374.3523560	0.65
458.0984497	1.70
465.9817810	0.30
471.9778442	1.69
505.2221985	2.43
505.9475403	1.65
514.3828735	0.91
558.9985962	0.20
562.3200073	0.20
615.9479980	1.24
634.1100464	5.26
635.1724854	1.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	586.91
Annotation	Unknow
Peak:m/z	Relative Intensity
202.0722809	0.04
224.2670593	0.03
229.0686188	0.13
273.0419006	0.82
274.1547852	0.06
290.0150146	0.04
316.0557861	0.05
357.0863647	0.14
359.0816650	0.13
387.3364868	0.10
388.0716553	0.06
427.0802612	6.28
428.5786133	0.24
429.1854248	0.29
430.8238525	0.28
431.8521729	0.08
443.0454712	0.11
445.1575928	0.06
454.0522461	0.06
456.1451416	0.11
457.0109253	0.16
470.7772827	0.15
472.8870850	4.85
473.5075684	0.03
484.6110840	0.05
486.8401489	0.05
491.0742798	0.12
501.2797241	0.18
512.7949219	0.10
522.0723877	0.06
527.6641235	0.14
539.3259888	0.20
540.8441772	100.00
541.4729004	0.32
542.8726807	0.42
543.8175659	0.04
559.1525269	0.07
563.4716187	0.39
568.3242188	0.10
570.4890747	0.06
577.0199585	0.11
586.1939697	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391.1284
Annotation	SN-38
Peak:m/z	Relative Intensity
139.9484406	0.02
145.1043091	0.41
154.1672516	0.09
155.2747955	0.05
159.0209656	0.02
171.0238953	0.06
171.9013062	0.06
174.9889221	0.39
175.9367065	0.18
187.0911713	0.07
193.0518799	0.05
195.3888550	0.05
199.1701965	0.09
201.0163116	1.65
202.1284180	0.09
205.1024933	0.08
218.2958832	0.08
230.1225891	0.06
243.1095886	0.36
244.4621277	0.76
245.0791931	9.88
246.0718689	0.61
246.7582092	0.29
256.2484131	0.04
259.0905762	0.04
260.8941650	0.14
269.0845947	0.03
271.1258240	0.10
273.2686157	0.22
274.1803589	0.18
275.1955261	0.29
276.3758850	0.08
285.1020508	0.05
289.2352600	0.12
301.1593323	0.11
302.2243042	0.02
307.0761108	0.06
313.3784180	0.03
316.5415649	0.14
328.1826477	0.08
330.5833740	0.03
343.2741089	0.17
345.1576843	100.00
346.5751648	4.43
347.2177429	19.90
353.2172546	0.10
354.4685059	0.20
358.1848450	0.03
360.2368469	0.47
361.5607605	0.08
363.0651245	0.76
372.2905579	1.02
373.1821289	0.22
374.2565002	0.06
382.8818054	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	349.09
Annotation	Unknow
Peak:m/z	Relative Intensity
111.9632568	0.03
112.8326569	0.02
118.9554443	0.02
142.9492493	0.19
151.2063293	0.13
161.0068054	0.09
162.7124329	0.02
175.1766510	0.04
178.9731750	0.58
193.1547852	0.10
287.4573975	0.07
305.1200256	0.07
311.3098755	0.04
313.1110840	100.00
330.2102661	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1619
Annotation	Safflomin A
Peak:m/z	Relative Intensity
170.2503967	0.10
174.9294281	0.37
177.0102081	0.22
180.8467255	0.11
186.9995728	0.05
195.0932770	0.21
197.0761719	1.37
198.0143585	0.28
199.1069946	3.04
200.0764771	0.33
201.1867065	0.47
206.1721802	0.05
207.4160614	0.06
209.0829163	2.56
210.0033875	0.40
211.1069489	0.34
211.9532318	0.20
213.1814117	1.50
214.1676331	0.12
215.0708923	0.08
217.0639343	2.56
218.2067719	0.43
219.3881531	0.31
221.0356445	0.04
223.1212463	0.44
224.1968842	0.41
225.8282166	1.12
226.4783478	0.12
227.2975464	0.06
235.0010071	0.31
239.2123108	1.55
241.1140747	16.33
242.2045593	2.98
243.0652618	2.45
244.0491333	0.33
257.3623657	0.24
258.3152466	0.17
263.3820190	0.04
264.6500244	0.20
267.0236816	0.64
269.0751648	1.39
270.3747559	0.22
276.4476929	0.15
277.1843262	0.17
281.2103882	0.46
282.1841431	0.10
283.2114868	0.04
285.0950317	100.00
286.2111816	13.80
298.0470581	0.05
299.0127563	0.26
300.1795044	0.08
301.1290283	1.11
302.0580139	0.54
303.1448364	1.57
303.9093018	0.27
306.1220093	0.22
307.1523438	0.62
308.3992920	0.17
311.1695557	1.38
312.2161865	0.07
318.8026123	0.03
319.4284668	0.04
323.1273804	0.08
324.3051147	0.07
325.1881104	0.15
329.1624146	3.36
330.1396484	0.21
337.2354736	0.22
338.1249390	0.22
339.2572021	0.05
340.0382690	0.08
341.2529907	1.80
343.1251831	0.17
343.9360962	0.09
345.1766357	0.13
354.1743164	0.05
359.1058350	1.09
360.0513916	0.18
364.0857544	0.18
371.1047974	39.39
372.2108154	6.49
373.1566772	0.17
379.1163940	0.15
380.1333008	0.05
383.1691284	1.54
384.2569580	0.06
389.3798218	0.10
391.3447876	0.12
392.5537109	0.06
395.0899048	0.20
397.1795044	0.17
401.2105713	34.92
402.1990356	5.93
403.2219849	0.40
407.2958984	0.10
411.3140869	0.20
413.3535767	0.92
414.5661011	0.06
421.6235352	0.09
424.2179565	0.04
425.4876099	0.16
427.2702026	0.05
431.1388550	12.21
432.2041626	2.35
437.1644897	0.13
439.1931763	0.14
443.4402466	0.13
444.3929443	0.05
449.2169189	5.00
450.2410278	0.74
455.2706299	0.29
456.2711792	0.32
461.2197266	0.42
463.2186890	0.08
464.1390381	0.41
466.9666138	0.15
473.2258301	13.10
474.2542114	4.02
475.3485107	8.33
476.1859741	2.19
477.3013916	0.09
481.2542725	0.26
482.4093018	0.37
485.1759033	18.63
486.2257080	5.01
486.8360596	0.02
491.1106567	79.18
492.2283936	12.88
496.4015503	1.76
497.2496948	0.34
497.9329834	0.13
501.2268677	6.65
502.5837402	2.66
503.2525635	7.42
504.1886597	2.46
517.3488770	0.04
519.4867554	0.04
521.1686401	8.31
522.2032471	1.30
524.3927612	0.10
525.6137085	0.05
528.7313843	0.09
543.2193604	1.34
544.1763306	0.33
551.5049438	0.36
557.1135864	0.31
558.2123413	0.09
559.3146973	0.14
563.2898560	0.16
565.8854370	0.12
567.4624634	0.86
568.2451782	0.36
569.3408203	0.05
570.2347412	0.04
575.1841431	2.89
576.4299316	0.48
582.4407959	0.05
593.2042847	13.24
594.3009033	3.42
595.2540283	0.16
602.4591064	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	548.2738
Annotation	Unknow
Peak:m/z	Relative Intensity
197.1890564	0.29
216.1896667	0.06
220.0328979	0.15
258.0074463	0.49
261.2821045	0.16
263.0464783	0.48
268.0887451	2.64
269.0985718	0.11
272.1944885	0.11
286.0250854	15.23
309.3139038	0.13
310.2593994	0.17
311.9583130	0.25
333.8502808	0.39
344.3234253	0.43
356.6174927	0.84
357.4481812	0.08
358.3933105	0.08
367.2939453	0.09
375.0680542	0.19
381.0586548	0.20
385.0656128	100.00
385.9416504	0.57
408.2061157	0.15
415.2893066	0.32
417.3692627	0.14
418.2272949	0.43
427.1051025	0.29
430.5104370	0.28
432.4037476	0.19
435.3756714	0.46
442.8911743	0.30
457.7595215	0.72
466.6229858	0.55
467.5463867	0.76
468.5490112	0.21
473.4080811	0.07
475.2282715	0.67
483.8898926	0.65
485.4160767	0.62
487.1450195	0.34
488.5070190	0.22
491.1075439	0.26
496.8563843	0.16
501.8240967	0.26
503.4616089	0.10
513.1753540	0.09
516.0879517	4.71
529.7096558	0.97
530.4068604	1.21
531.3724976	0.55
538.5716553	1.16
539.4483032	0.09
548.1222534	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	305.0748
Annotation	Unknow
Peak:m/z	Relative Intensity
115.9333954	0.05
123.0944290	0.03
130.9868317	0.62
136.1663208	0.12
150.5416565	0.02
151.1558533	0.75
154.0573730	0.04
155.2097015	0.07
156.1204987	0.28
164.2530212	0.04
173.1141052	5.27
176.1045227	0.06
184.6784668	0.05
185.3699646	0.07
189.2219543	0.18
190.2809448	0.09
193.1705322	6.44
194.4264374	0.24
195.0574188	1.10
199.1151428	3.71
206.3807068	0.03
207.3711243	0.41
208.1069336	0.74
210.0810852	0.20
211.1492310	0.11
217.1856079	0.87
218.9979553	0.09
220.5229797	0.09
224.1277771	0.22
225.1550903	0.90
227.1914062	0.90
237.0727234	33.06
237.6744690	0.04
241.1563416	94.90
242.2528076	0.14
245.0073242	1.20
254.1203003	5.90
259.1130066	100.00
263.0962524	12.98
271.0642700	34.38
287.1454468	0.35
288.0989685	0.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	399.1441
Annotation	S-Adenosylmethionine
Peak:m/z	Relative Intensity
118.9652863	0.05
135.9711304	0.94
145.2441559	0.13
163.0729065	0.11
175.1221924	2.44
177.0357666	0.12
178.7933960	0.07
184.0753784	0.18
185.9833069	0.24
212.7731171	0.10
225.1975098	0.79
244.1321411	0.09
250.1147766	100.00
253.2701111	0.49
264.1700134	3.66
271.5909424	0.22
298.1201172	49.63
301.0239868	5.28
325.7535706	0.29
327.0909424	0.25
338.0302124	0.13
354.4414062	0.19
363.4625854	0.52
381.6275940	0.42
382.2486572	0.19
389.7135620	0.73
398.7644958	0.47
549.4868164	0.17
715.0368652	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	475.1821
Annotation	Phenethyl rutinoside
Peak:m/z	Relative Intensity
137.1792145	0.03
144.8744965	0.21
161.0566559	0.10
162.9736023	7.55
168.1092529	0.06
169.0784607	0.03
193.2373962	0.07
205.1018982	0.57
230.3082275	0.06
231.2155762	0.04
233.1696472	0.03
234.1613312	0.84
234.9104004	1.92
252.3475952	0.14
255.1701050	0.07
264.8997803	3.84
274.6781921	0.06
277.0598755	0.12
289.2483215	0.26
290.4963074	0.04
293.6396179	0.03
295.0462036	0.16
307.1934814	1.49
311.6378479	0.07
312.4142761	0.10
313.3595581	0.06
315.2802734	0.02
325.0382080	5.39
327.2482300	0.05
331.1351929	0.03
333.4066467	0.03
339.4822998	0.10
340.2625732	0.06
343.0844116	0.06
352.2167358	0.04
360.3417053	0.05
361.2482605	0.02
371.6408081	0.05
379.4741516	0.06
389.1065979	0.03
395.4656677	0.03
403.5664673	0.02
409.2551270	0.06
411.1744995	0.27
412.4332581	0.05
414.4372864	0.03
429.1958618	100.00
430.3664856	0.08
431.3434143	0.15
437.2548523	0.07
438.5278320	0.06
441.5747375	0.03
455.3928528	0.08
457.0660400	0.28
457.8566895	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1571
Annotation	Unknow
Peak:m/z	Relative Intensity
173.0117493	0.09
176.2826843	0.04
180.0764618	0.01
183.0352325	0.04
185.0591736	0.15
189.2049866	0.01
193.1455383	0.69
194.1252747	0.02
195.0652161	0.01
199.1320038	1.42
207.1543884	0.35
208.3039856	0.19
210.0086823	0.01
217.1951904	0.23
220.0467834	0.04
222.0038757	0.01
224.1069336	0.27
225.1628113	0.27
227.2023010	0.12
228.8857422	0.03
237.2026825	1.51
241.1648407	6.64
242.1835327	0.03
245.2190857	0.06
254.1922913	0.28
259.1956177	5.07
263.1728210	0.51
271.1655884	1.56
286.9737854	0.02
288.2151489	0.02
303.0039673	0.01
305.0837097	100.00
423.2926025	0.02
439.3516846	0.01
447.1187134	0.07
483.1876221	0.02
483.9996948	0.02
563.4992065	0.02
567.1360474	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	671.3068
Annotation	Moluccensin E
Peak:m/z	Relative Intensity
190.8389893	0.60
247.2303009	0.48
251.2769165	0.49
387.0778198	0.13
403.2687378	0.39
438.1302490	0.51
467.5793457	0.18
495.6435547	0.38
507.6171875	0.39
509.3637085	0.20
516.1735229	0.26
518.1829224	0.34
545.4805908	0.13
547.5336304	0.34
551.2078857	0.18
559.7033081	0.38
565.3493042	0.96
566.4527588	1.23
567.4159546	0.72
569.7129517	0.14
578.9289551	0.30
580.4534302	1.20
582.3776245	11.21
583.4042969	41.35
584.4971313	1.24
585.7463989	0.31
593.3838501	5.28
595.5316772	0.15
598.3084106	0.15
607.4382935	0.15
611.5275269	2.89
612.3738403	2.29
621.1631470	0.91
622.3606567	0.21
623.6607056	0.13
624.4316406	0.34
625.4420776	0.82
629.8201294	0.10
632.3521729	0.13
633.1567383	0.23
637.1064453	0.25
639.2050171	0.43
653.4388428	100.00
654.5524902	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.3303
Annotation	Unknow
Peak:m/z	Relative Intensity
171.0297852	0.03
193.2910919	0.01
219.8018799	0.06
242.2686462	0.05
256.3874512	0.01
279.3309937	2.07
325.5474243	0.07
363.4135132	0.04
403.9687500	0.05
408.3270264	0.06
409.4303589	0.08
433.4169922	0.16
438.9442749	0.03
459.4677124	0.03
460.5170288	0.02
468.1688232	0.10
478.3884277	0.03
483.6027832	0.05
496.3895874	0.10
504.3318481	100.00
505.3041382	0.61
518.5603638	0.02
521.5314331	0.02
527.1238403	0.03
528.3090210	0.08
530.4203491	0.06
546.0908813	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	326.21
Annotation	Unknow
Peak:m/z	Relative Intensity
97.7469025	0.07
112.0638504	0.47
114.9537506	0.07
115.9998093	1.13
122.1469955	0.11
125.8151398	1.50
130.2720642	0.16
141.8865051	0.13
142.9635925	0.13
149.7190247	0.13
151.0323181	0.10
155.0558167	0.17
158.3510742	0.14
159.2605591	0.69
161.9853973	0.13
167.4620361	0.57
183.0876465	10.46
185.1463470	0.44
186.5087585	0.05
201.0183258	0.20
202.1870270	0.34
204.3945312	0.20
206.0331421	0.14
211.0630798	100.00
213.1621704	34.12
214.9590149	0.65
226.1444397	0.42
228.0648193	0.09
229.3341980	0.64
233.1671448	0.31
236.3064880	0.19
237.4154358	0.32
238.9704895	0.09
240.3406372	0.05
243.1641235	5.16
244.1420288	4.93
245.3482056	0.49
246.3155823	0.60
246.9942627	0.27
251.1967468	0.42
253.2474365	0.38
259.7366333	0.51
266.1566162	0.26
268.5270386	1.66
269.2941895	6.83
270.2498779	2.70
271.6343384	0.63
273.8571167	0.09
279.9190979	0.24
281.1510925	0.62
283.3037109	0.10
284.0714111	0.13
284.8972168	0.58
287.4985657	0.48
290.2147827	0.13
291.0358276	0.27
298.3853149	0.16
307.0086060	0.81
308.2166443	2.35
309.1116028	2.95
310.5393677	0.95
314.9224854	0.38
316.7724915	2.22
326.2004700	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	903.1699
Annotation	Unknow
Peak:m/z	Relative Intensity
271.1483765	0.11
299.0439453	0.10
300.1375122	0.44
301.1557922	3.09
343.0877991	0.27
345.2189941	0.03
362.8583984	0.08
365.5189209	0.05
373.1774292	0.06
399.1412659	0.18
407.1589355	0.06
424.9606934	0.05
441.4280396	0.09
444.2099609	0.09
445.4159546	0.19
449.2940063	0.05
457.4011230	0.02
463.2250366	0.74
467.2092896	0.08
527.2395630	1.38
529.1281128	0.07
531.3024902	0.77
561.2205811	1.21
565.2041626	0.09
571.2561646	0.06
577.2484741	0.07
579.2212524	0.12
591.4469604	0.15
595.1806030	0.84
596.1272583	0.06
609.3389282	100.00
619.0942993	0.05
625.0879517	0.50
625.7326050	0.06
633.5197144	0.03
635.4895630	0.07
647.5097046	0.03
651.3199463	0.34
673.3692017	0.78
675.2527466	0.18
677.3424683	1.33
689.2457886	0.36
691.5037231	0.03
693.3460693	0.23
695.3772583	0.03
707.2554932	8.24
709.3176880	0.02
723.2996216	0.05
725.5446777	0.07
733.4290161	0.57
735.1843262	0.13
741.2724609	7.45
749.6792603	0.09
753.1629639	3.00
753.7683716	0.29
759.3143311	0.04
771.3297119	24.42
773.0664673	0.04
803.3079224	0.03
813.1890259	0.04
817.3617554	0.22
825.0564575	0.06
835.2705078	23.68
837.2540283	3.84
839.2482910	94.06
840.1783447	0.11
852.3792114	0.02
856.6473999	0.08
857.3251953	0.81
869.2324219	79.49
869.8389282	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	502.92
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0319214	3.80
160.0526886	1.18
161.0231018	0.71
199.0806885	0.60
200.1504517	0.26
201.0797119	0.30
202.0883484	0.04
217.0247498	0.14
218.0517426	0.04
218.8803406	0.03
228.9535675	0.87
229.9756470	0.63
230.9902649	0.49
272.9974976	52.48
274.0309448	31.57
275.0160217	28.72
275.7568665	0.02
387.0396118	54.30
388.0144043	100.00
388.9438477	84.22
428.1110840	0.20
429.0431213	0.06
430.8153381	0.06
456.4663696	0.03
457.1637878	0.14
457.8583679	0.03
485.4815979	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	460.13
Annotation	Unknow
Peak:m/z	Relative Intensity
132.0275269	5.06
148.9403229	1.39
157.1364441	0.46
166.8883514	8.32
173.0066376	0.22
175.0836334	0.10
180.8044739	0.30
186.1997986	0.13
194.2218018	0.09
195.1091461	0.37
201.0552368	0.16
209.1877747	0.25
210.9421539	0.25
213.1626434	0.58
214.3756409	0.12
215.1678925	0.08
220.9081421	0.35
224.8618774	0.42
229.2774963	0.35
231.8941956	0.28
233.0013275	0.27
238.7977905	2.63
242.1019592	0.12
243.3692932	0.23
245.1309509	1.06
246.1042480	0.72
247.2460327	0.87
248.2184143	0.11
265.2731934	0.21
269.1864014	0.19
272.2341003	0.13
273.1375122	0.34
274.8835144	6.14
276.6398315	0.15
279.5299988	0.59
281.6637573	0.06
285.9782715	0.44
287.6069336	0.08
292.9524536	34.34
297.5072327	0.33
300.0330200	0.45
304.8409424	0.09
307.1824341	5.10
308.4061890	0.61
309.2366638	0.71
310.9405518	100.00
313.1750488	10.06
314.2667847	0.06
320.0873413	0.16
325.1881409	0.37
327.1574097	1.26
328.2283936	3.49
328.9633179	5.64
330.1072388	0.13
331.2999878	5.87
339.1448364	2.44
339.9747314	0.58
341.1687317	0.57
343.2207642	0.12
344.3942871	0.14
345.3176270	0.27
346.4981689	0.31
351.8162842	0.09
353.3454895	0.12
362.1337280	2.06
365.2041626	0.25
369.3984375	0.46
371.1104431	3.37
382.4659424	2.51
385.4992981	0.36
395.5686951	2.52
396.1828308	1.57
398.1076965	0.08
400.1483459	0.25
405.9537048	0.09
412.0024109	0.06
413.8423462	0.55
415.1665955	0.22
415.9913025	0.08
419.0361938	0.07
421.7733459	0.15
422.8773499	0.65
424.3974915	0.36
425.3311157	0.68
426.2568665	0.97
427.4413452	0.75
430.2009888	1.49
430.8870850	0.71
437.8353271	0.49
441.0958557	2.33
442.1988220	7.13
443.4347229	1.42
447.2804871	0.41
451.3647766	10.32
452.3431396	2.72
453.2626038	0.13
458.7612610	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	440.2092
Annotation	Unknow
Peak:m/z	Relative Intensity
130.8535767	0.34
154.7820435	0.21
166.0393066	4.18
167.1143646	0.37
172.7229919	0.23
181.8939514	0.34
183.2298889	0.40
211.0608826	0.20
213.1502075	0.18
221.3260803	0.11
223.8910980	0.23
229.0411377	1.49
230.2158813	0.45
234.9467163	0.65
238.2724304	0.33
241.2035217	0.67
243.1295471	0.11
249.5790405	0.50
250.9976501	0.44
258.1481323	0.55
267.1992188	0.17
269.0511169	0.51
275.0672913	2.00
277.1632080	0.51
279.2283630	3.99
282.2214355	0.26
291.2667847	0.27
293.0493164	0.40
295.5193481	0.20
307.0998840	0.21
308.9783020	0.27
309.8010864	0.11
311.2689819	1.29
313.3489990	0.17
314.5876465	0.13
323.0954285	0.78
323.9630127	0.18
325.2989807	0.83
327.3011169	0.96
331.2057190	0.30
334.2680359	1.28
335.2033997	1.21
336.7110901	0.99
341.0610962	0.65
343.8998108	0.21
345.7413635	9.03
346.6213379	1.11
347.3529968	2.67
347.9794617	0.31
353.7602539	1.73
355.3149414	0.48
359.3813477	2.06
360.1051025	0.76
365.6026306	0.62
370.0936584	1.43
372.0913391	0.14
373.0270081	1.10
376.0234680	8.28
376.7125549	0.12
377.6118164	0.23
379.4109192	1.69
383.6091614	3.71
385.2447815	8.81
388.1765137	0.72
389.1844177	0.53
390.9582520	4.04
391.8567810	1.86
392.6283264	1.30
394.1801453	1.24
395.0900574	0.23
396.1595154	3.05
396.7734375	36.61
397.4632263	2.81
398.7154846	0.31
400.3457336	0.17
401.9458923	0.97
402.7483826	8.03
410.9330750	0.48
412.3653564	0.24
416.2510071	3.84
417.3162231	0.38
420.6271057	0.71
421.4541931	1.29
422.4315491	2.62
423.4059753	0.65
425.2282410	9.01
426.2816467	2.00
428.4487610	7.17
430.5816650	2.77
431.6068115	2.40
432.9037781	1.08
434.4796143	0.27
447.4891052	0.45
455.5231628	2.70
464.3749695	0.38
465.7841492	0.71
474.3497925	4.78
475.0962830	3.21
484.3054504	0.33
495.3607483	0.67
496.7093811	0.43
497.7427673	1.03
498.5405579	1.73
499.6191101	0.67
502.7677612	0.47
503.7812805	0.23
506.9784241	4.58
507.8193665	2.53
511.9944458	16.29
512.9262695	2.59
518.2123413	3.06
519.3707275	0.45
521.0042114	57.90
521.9652710	4.88
523.3984375	0.65
524.1310425	0.42
529.8469849	12.55
531.0492554	2.34
532.4066772	1.05
539.0347900	20.36
540.0197144	1.22
540.8466187	0.24
541.4542847	0.53
543.6824341	0.24
553.2794189	2.75
554.1000977	0.73
556.8870239	0.48
560.3590698	1.57
563.5935669	9.89
564.4044189	1.47
568.4476929	8.50
569.3739624	3.95
574.1744995	0.48
577.5784302	100.00
578.5161743	5.48
579.1973267	0.63
583.7179565	0.71
585.8032837	8.64
586.5946655	47.81
587.5131226	1.30
588.2406616	0.57
592.6484985	0.30
594.6505737	47.55
595.5245972	3.28
597.2985840	0.50
601.3032837	0.86
603.6376343	65.40
604.4805298	2.84
605.3185425	0.11
611.3571777	0.76
629.4042358	3.98
630.6775513	0.30
635.4164429	0.54
651.7744751	0.57
661.5008545	0.49
669.2994995	0.59
672.5364380	0.72
688.5275879	0.27
691.4743652	0.71
709.1211548	0.33
729.4829712	0.52
730.2238159	0.53
738.3743896	0.79
760.7989502	0.17
766.4112549	1.10
767.5320435	0.38
772.4876709	0.35
782.5001831	0.99
798.5395508	0.84
799.4722290	0.54
819.0648804	0.27
820.2020874	0.77
868.7266235	0.42
875.5603027	0.63
879.6120605	0.62
882.5409546	0.24
884.8916016	0.44
885.4974976	0.48
887.8237305	1.48
893.6517944	0.21
1017.6955570	0.81
1040.5706790	1.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	277.0685
Annotation	Unknow
Peak:m/z	Relative Intensity
110.0049591	0.01
119.0967102	0.05
120.1803055	0.03
126.0025787	0.12
127.7405167	0.02
128.9889221	0.02
145.0992432	1.30
146.1441650	0.02
147.1651154	0.01
161.1227570	0.05
171.0290375	1.07
183.0708160	0.01
187.0107727	0.02
189.1411285	0.02
191.0273743	0.03
197.1191406	0.13
199.2020569	0.39
204.9511108	0.05
209.1215515	14.46
213.1414490	8.92
217.3291626	0.17
231.0610657	100.00
232.2687683	0.11
233.0518799	0.12
233.9582214	0.02
237.2595215	0.02
241.0962219	0.04
243.0566406	21.12
249.1756287	0.02
259.1758118	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	520.2675
Annotation	PS(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
151.0959473	0.18
153.0197906	10.69
154.0123291	0.36
159.2486572	0.05
171.0131683	1.14
192.2382355	0.04
218.2308807	0.02
222.9853516	0.04
232.1466827	0.03
240.1384583	0.34
255.2526550	0.02
258.0101624	0.04
259.1597900	0.04
266.3527832	0.12
293.4627075	0.03
328.3162842	0.04
333.5759888	0.25
368.9606934	0.16
372.4716797	0.05
389.1718750	0.08
407.0839844	0.03
407.8868408	0.04
409.2973633	0.11
414.3999023	0.03
415.5942383	0.05
433.2825317	100.00
434.2805786	26.57
434.9238281	0.06
445.5113525	0.03
447.2901001	0.04
449.1320190	0.07
463.5767822	0.03
467.3211670	0.84
475.1387329	0.08
477.6066284	0.26
479.4182739	0.04
482.4135132	0.17
483.1833496	0.64
484.1365967	0.09
485.0989380	0.79
486.1281128	0.08
498.2619019	0.03
500.9267578	0.03
502.4638062	0.10
503.4630127	0.41
504.1956787	0.11
505.3865967	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	214.25
Annotation	Tetradecylamine
Peak:m/z	Relative Intensity
71.08283997	10.03
173.0587616	12.31
185.8106842	17.19
196.2341003	32.83
214.2496643	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	445.1172
Annotation	Sissotrine
Peak:m/z	Relative Intensity
126.0083008	0.01
142.8810425	0.05
148.6390686	0.01
150.9976196	0.02
159.2792664	0.08
161.1421814	0.10
166.1930847	0.04
172.3999634	0.05
175.2507935	0.02
177.875946	0.02
179.0779724	0.21
183.0437622	0.01
192.0446167	0.01
194.0257416	0.04
199.0042725	0.02
200.9189453	0.02
203.1192169	0.03
205.0101013	0.10
213.2016907	0.04
235.0996094	0.01
240.0803528	0.02
249.1036072	1.31
265.2228394	0.05
268.9120178	0.04
283.0645752	100.00
283.838501	0.01
295.1589355	0.03
299.6905823	0.03
300.9259644	0.02
309.1660461	0.02
312.99646	0.07
314.4386902	0.02
316.2807617	0.11
324.5454102	0.04
325.3166504	0.05
326.0249329	0.02
326.9736328	0.03
330.0925293	0.02
338.2121582	0.02
341.3318787	0.03
344.183197	0.02
344.9503479	0.01
348.4036255	0.10
349.1771545	0.06
353.330719	0.07
354.1604004	0.01
354.960907	0.02
356.2845764	0.01
359.1564636	0.01
361.1669312	0.03
365.2054443	0.01
367.2897034	0.07
371.3569031	0.02
381.1725159	0.06
383.2944031	0.06
387.2187805	0.01
398.6598206	0.10
400.3882141	0.12
401.195282	0.11
403.6653137	0.04
406.7929993	0.12
408.1920471	0.20
409.5428162	0.05
410.59375	0.05
411.2002869	0.10
412.3551331	0.03
413.289093	0.11
425.9133911	0.37
427.2701416	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	289.0409
Annotation	Unknow
Peak:m/z	Relative Intensity
83.7727966	0.30
108.8790283	0.15
110.0099640	2.78
111.0638885	0.82
112.5127029	0.38
119.9695206	6.95
121.9256134	4.07
129.9270630	4.13
131.0928345	0.23
132.7943420	0.96
138.1214905	0.36
146.0763245	0.66
150.2019653	1.03
151.0142670	0.85
153.5621338	0.61
156.1083069	1.36
157.2035522	0.33
166.9524841	0.44
170.1254883	0.14
171.3887177	0.20
177.0448303	16.38
177.9661255	0.44
179.0883484	0.72
180.2012939	0.63
184.0598602	0.09
202.8330994	0.79
207.0954895	0.27
210.0683594	0.28
212.9844666	5.35
214.0570984	3.10
215.9221497	0.43
224.2984924	0.49
225.0007935	0.21
227.1601562	0.36
228.5490417	100.00
229.9818420	2.49
231.0591431	0.85
242.0728760	4.90
243.1090698	4.95
244.1244812	0.27
245.0802612	0.56
247.1684570	0.54
251.8018799	1.24
253.0894470	0.37
257.6683350	1.11
259.3526001	0.20
266.0416565	11.52
266.7227173	0.57
269.9377441	9.47
271.0250244	6.03
271.7881775	0.84
273.1732483	0.38
274.1906128	0.12
274.9257202	0.22
280.2921143	6.74
281.0601196	0.71
281.9833984	0.22
288.7330017	0.52
298.3605957	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.2212
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
105.03508	0.95
143.0431061	3.21
181.2070465	1.76
183.1683197	2.81
195.1499634	6.11
223.5492249	1.02
239.2602539	5.55
247.1733398	2.20
251.226532	12.97
253.1040649	8.67
255.0744324	3.25
265.9150085	1.95
268.8955078	4.82
275.1724854	17.03
283.3579712	1.81
293.208252	100.00
293.8948975	4.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	617.9
Annotation	Unknow
Peak:m/z	Relative Intensity
190.4143677	0.05
199.1786652	0.16
199.8719177	0.03
228.8702698	0.08
230.9724274	0.06
234.1587524	0.04
236.0047607	0.07
272.9600220	4.85
274.0142517	2.32
275.0278931	4.26
276.1138306	0.63
382.8158569	0.05
386.9680176	8.37
387.9896240	6.10
388.9581909	15.29
390.0341187	3.18
473.3657227	0.04
482.9220581	0.01
500.9570923	18.74
502.0981445	31.20
502.9498901	100.00
503.9099731	36.06
504.6060181	0.05
508.2852783	0.02
515.1586304	0.04
542.6892090	0.10
562.1425171	0.10
571.1630859	0.28
571.8927612	0.34
572.9223633	0.05
589.4063721	0.10
599.7027588	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1586
Annotation	Formononetin 7-O-beta-D-apiofuranosyl-(1->6)-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
162.8805695	0.02
175.1190491	0.08
188.2741547	0.01
191.1433105	0.01
201.0843353	0.03
203.2489014	0.03
205.1926880	0.07
221.1326141	0.06
222.8953552	0.01
228.1138916	0.01
231.0346680	2.37
249.1212158	100.00
250.8117065	0.01
263.1495361	0.03
265.1366577	0.16
277.2164612	0.02
308.8542175	0.01
311.0021973	0.35
314.2932739	0.02
361.2194824	0.13
367.3779297	0.06
387.3887329	0.06
390.5462646	0.11
403.7106934	0.01
411.5373535	0.02
414.9508057	0.02
416.3163452	0.02
424.0618286	0.01
425.3237915	0.05
431.2713013	0.03
439.2142944	0.03
445.5123291	0.02
467.5514526	0.03
470.4258423	0.09
471.1196289	0.03
474.1796265	0.09
480.6282349	0.06
484.4385376	0.02
486.9757690	0.01
497.3718872	0.02
499.2922974	0.06
500.8408813	0.01
501.5964355	0.02
516.1327515	0.01
517.4202271	0.04
523.8320312	0.02
524.4992676	0.03
541.1958618	0.10
542.7349854	0.04
543.3362427	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1081.59
Annotation	Pithecelloside
Peak:m/z	Relative Intensity
301.9898682	0.18
331.1355591	0.41
348.9673462	0.70
369.3940430	0.51
394.1585693	0.18
476.0359497	1.43
504.2938538	0.96
544.1381836	0.17
557.3918457	0.33
558.1392822	0.28
592.0338135	0.87
668.2504883	1.40
685.1799927	2.47
686.3045654	0.39
772.5590210	0.50
817.8096924	0.44
919.6090088	0.75
1034.5306400	4.17
1037.3701170	10.10
1038.1002200	0.92
1041.1198730	5.46
1045.1427000	1.32
1050.9616700	0.24
1053.5809330	0.91
1054.3254390	0.96
1055.6276860	0.91
1058.7611080	8.59
1065.0351560	25.90
1066.0898440	6.36
1067.3211670	63.52
1068.1306150	7.93
1069.2126460	13.39
1069.9294430	44.23
1070.5664060	2.63
1071.3168950	7.45
1072.6015620	5.58
1074.3387450	1.84
1075.2840580	0.74
1075.8950200	2.34
1124.4246830	31.90
1133.9495850	83.50
1134.8067630	1.62
1135.5000000	0.74
1137.3940430	0.94
1138.4604490	1.19
1140.1678470	5.30
1147.8127440	2.32
1152.5253910	24.77
1154.5244140	0.35
1155.3824460	23.82
1158.9265140	0.65
1176.5908200	5.47
1179.7733150	3.24
1182.6235350	82.77
1183.6562500	6.60
1186.0628660	0.66
1190.9106450	3.60
1195.9925540	4.67
1209.7325440	100.00
1210.6840820	7.84
1211.5953370	0.76
1214.5600590	3.57
1230.4656980	8.72
1231.5091550	1.88
1237.2299800	5.38
1257.0823970	2.07
1265.9833980	5.16
1333.3074950	3.76
1339.2347410	1.20
1341.9024660	0.59
1360.7896730	8.32
1383.6262210	3.60
1391.0909420	2.62
1431.3280030	2.62
1463.6673580	0.55
1660.1682130	0.86
1707.2393800	0.26
1738.6343990	0.59
1763.1833500	0.61
1766.2097170	0.74
1778.2042240	0.20
1779.6986080	4.82
1807.5684810	1.56
1827.3350830	0.64
1843.7989500	0.31
1846.3001710	3.38
1848.4232180	0.29
1850.1765140	3.47
1862.3353270	1.34
1870.2467040	0.94
1882.6243900	1.20
1898.7569580	0.24
1905.1804200	1.59
1906.6623540	0.63
1926.1633300	5.31
1927.0559080	0.24
1930.4104000	23.25
1947.2730710	1.04
1948.2008060	22.41
1951.8148190	2.09
1953.0476070	1.35
1957.8157960	7.23
1959.3804930	0.35
1960.2614750	0.26
1963.3394780	1.61
1966.3763430	7.15
1968.3020020	4.43
1970.3336180	1.65
1971.6994630	0.29
1972.4426270	5.27
1974.1188960	1.39
1975.6881100	6.00
1978.4866940	0.28
1979.1497800	1.81
1983.2974850	0.33
1986.6956790	1.46
1987.9167480	28.94
1990.3634030	0.50
1993.2976070	4.77
1996.2722170	0.37
1998.0189210	6.90
1999.3233640	2.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.2626
Annotation	Cryptophycin A
Peak:m/z	Relative Intensity
205.2035828	0.03
207.9064331	0.04
229.1552429	0.09
236.8365479	0.02
241.6259613	0.12
253.6694794	0.04
255.1848755	0.03
257.3311768	0.03
265.3565979	0.07
266.0473328	0.17
279.2890930	0.08
281.2138672	0.06
293.2888794	0.16
296.2543640	0.12
297.4826050	0.05
299.5711060	0.14
307.2421875	0.03
312.2344971	0.06
319.3322754	0.10
326.5050659	0.02
327.3690186	0.05
329.6357422	0.12
330.5527344	0.03
335.2872925	0.19
337.2592163	0.24
339.1669922	0.09
342.5264893	0.07
357.4472656	0.02
371.2064819	0.03
373.5423584	0.04
375.2211304	0.07
383.3186646	0.07
387.2647095	0.35
389.2862549	0.15
393.3556519	0.07
399.2082520	0.05
400.1721802	0.05
409.7113037	0.10
413.7118530	0.03
423.3257446	0.28
426.5563965	0.03
448.3884277	0.06
475.3601685	0.24
477.3995972	0.03
479.8994141	0.12
484.3709717	0.07
488.4706421	0.07
490.2981567	0.37
491.2868042	0.46
492.2165527	0.21
493.3547974	0.03
501.4046021	0.03
502.2756958	0.04
507.3655396	0.07
509.4229126	0.11
514.1356812	0.09
521.7059326	0.03
523.3516846	0.75
532.9815674	0.04
534.4048462	1.29
541.4144287	0.04
545.3869019	0.59
549.4693604	0.20
553.4352417	0.06
556.6981812	0.06
559.5915527	0.07
560.4411621	0.03
562.5447388	0.18
565.3373413	0.82
566.4097900	0.45
567.3972778	0.30
575.4118652	0.11
577.3418579	10.76
578.2596436	0.10
579.4323120	0.60
580.5506592	0.19
581.3421021	0.26
582.3570557	0.19
583.4765625	0.04
589.2438965	0.04
593.4244385	1.10
594.4639893	1.91
596.8156128	0.49
597.5410156	1.64
598.4367065	1.72
599.4756470	0.92
606.3683472	0.04
607.3104858	0.15
609.3486328	100.00
610.0293579	0.47
610.7365112	0.04
611.5199585	0.08
612.4295044	0.05
614.3923340	0.09
616.1968994	0.31
616.8886719	0.06
617.5374146	0.34
620.3768311	0.23
621.3112793	0.41
622.3905640	0.08
623.4435425	0.34
625.4543457	9.82
627.4072266	0.09
632.5291138	0.12
635.2062378	3.32
635.8508301	0.03
637.4542847	0.36
638.3598022	0.22
647.0772095	0.04
650.2603149	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	293.2106
Annotation	13-epi-12-oxo Phytodienoic Acid
Peak:m/z	Relative Intensity
90.89967346	0.19
98.99600983	0.07
100.8126144	0.05
105.0569458	0.13
107.0749817	0.17
121.1581268	0.18
123.1373749	0.09
131.0725403	0.47
133.0208282	0.12
135.1515808	0.40
140.927887	0.03
143.1370544	0.15
145.0229187	0.45
147.0215149	0.45
149.1316223	0.26
151.0741272	0.99
153.2305298	0.41
154.89534	0.08
159.3373413	0.09
161.0704956	0.20
163.0499268	0.11
165.0898743	0.29
166.9676666	0.18
169.4151306	0.08
171.1747437	0.13
173.0758362	0.18
175.1693268	0.40
178.8694153	0.22
180.9472046	0.11
183.1322632	0.11
187.2151184	0.44
189.125351	0.11
191.1490173	0.63
193.1454773	0.29
197.3650055	0.12
199.0070496	0.15
201.1422119	0.44
205.0189819	0.19
207.0893555	0.39
208.5390625	0.09
211.1703491	0.14
213.1751099	0.08
215.0987854	0.75
217.1210632	0.22
219.1337891	0.92
222.3098145	0.28
223.3473511	0.23
229.1219177	0.45
231.1660156	0.28
233.2362976	0.65
235.1321411	0.96
236.0687256	0.16
237.2593689	0.63
238.5124512	0.07
239.1606445	0.38
241.9956665	0.08
247.0217285	0.47
249.2111511	0.17
250.2459106	0.10
251.2668457	0.74
257.1921082	5.11
258.783905	0.10
265.414978	0.14
266.1410828	0.06
275.2076721	100.00
276.0249634	0.18
288.4981995	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	613.16
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
176.7389679	0.05
188.9553070	0.14
204.2512817	0.04
205.6528320	0.04
208.7572021	0.29
211.0275879	0.39
231.0926971	0.32
235.1919556	0.12
262.0621338	0.15
272.0825500	0.10
275.8934631	0.05
279.8312378	0.04
292.2948608	0.06
298.0139771	0.05
301.3010864	0.07
304.3457642	0.05
305.8460693	0.13
310.2166443	0.21
330.1817017	0.05
331.1971436	0.15
332.5062866	0.04
334.9863281	0.14
337.1760864	0.29
337.9714355	0.07
343.9755859	0.07
355.0977783	67.17
363.2348022	0.10
378.7509155	0.08
381.2014160	0.04
383.4869995	0.10
391.2530518	0.09
403.0475464	0.12
405.3574219	0.03
409.1953125	2.81
410.6074829	0.11
419.8050537	0.05
421.0839844	0.19
425.5007935	0.04
426.3546753	0.03
429.3510742	0.11
432.1376953	0.11
452.2184448	0.07
454.3538208	0.17
457.3725586	0.11
466.2067871	4.30
467.3150024	0.10
479.4727173	0.35
480.9039307	0.06
481.6286011	0.05
484.1614990	100.00
484.7780762	0.52
496.7789307	0.04
498.3524170	0.16
519.9761353	0.06
538.2349243	3.20
550.4910278	0.05
559.1506958	0.06
577.5125122	0.19
578.2923584	0.06
595.2008667	23.77
596.2293701	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	420.9132
Annotation	Unknow
Peak:m/z	Relative Intensity
131.9134521	0.24
133.2373047	0.01
138.0381165	0.02
138.8770752	0.07
144.0838013	0.03
159.9700317	1.14
161.0207825	0.24
171.1770020	0.14
171.9217682	0.26
183.0567627	0.33
188.0003662	0.99
188.9113770	0.14
189.9939575	0.03
191.9401855	0.03
200.0488892	0.55
201.0767365	0.02
202.0250854	0.03
204.0980530	0.10
205.0933838	0.05
206.1808167	0.06
211.1103363	0.02
214.0030060	0.02
215.9386444	5.03
216.9798126	1.41
219.4396973	0.04
220.7699432	0.07
228.3782654	0.02
231.9974518	2.39
232.9839172	0.28
234.0008850	0.09
234.9875793	0.03
235.9920044	0.02
236.9329224	0.04
240.0372620	0.02
241.1730347	0.14
243.9914856	1.76
245.0860596	0.34
246.2284851	0.03
256.2111511	0.04
257.2718201	0.04
259.9858704	2.70
260.9872437	0.50
262.0854492	0.05
263.0865784	0.15
264.8339539	0.02
270.3843384	0.03
274.0844421	0.01
276.0465698	0.11
276.8417358	0.02
279.0294495	0.15
281.7666626	0.03
287.9940186	3.21
289.0286255	0.67
290.0249939	0.05
291.2293701	0.02
304.0410156	0.46
305.1146240	0.47
306.0707703	0.11
315.9705811	0.05
319.6499939	0.02
322.9551086	0.07
330.3375854	0.07
332.0415649	3.33
332.9590149	7.69
334.2993774	0.07
337.2097473	0.02
345.0433350	0.04
350.0164490	0.04
359.0393372	0.03
361.0108337	0.04
368.1869812	0.23
374.1219788	0.08
375.0744629	0.07
377.0272522	100.00
382.3042297	0.02
386.0731506	0.32
400.3223267	0.06
401.1188354	0.03
402.1195984	0.51
403.2159119	0.47
404.3966064	0.03
421.1380005	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
135.2601624	1.17
143.2264404	1.83
145.9995728	3.30
169.1012878	5.77
182.1968231	2.86
183.3456116	1.60
185.040863	3.59
190.8539734	0.96
196.976532	2.37
207.1373901	2.77
223.1714478	0.86
224.9988403	1.07
237.0059814	6.56
243.0372009	2.22
244.5625305	5.59
247.0570984	3.28
253.1090088	1.71
255.4310303	0.86
265.0658875	1.59
270.1394043	5.18
275.2045898	10.04
280.1354675	3.91
290.6503601	1.12
293.2029419	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.1924
Annotation	Unknow
Peak:m/z	Relative Intensity
193.0831909	0.19
204.0374298	0.06
217.0391693	0.12
225.2945251	0.10
234.1702576	0.18
235.7740326	0.11
239.0471039	0.06
257.7621460	0.10
264.9677734	0.16
266.3122559	0.05
273.3433838	0.06
295.2131958	2.32
296.2222900	1.17
318.6424561	0.05
321.1863403	0.09
337.3283081	0.23
345.1712036	0.11
353.1475830	13.38
353.7620850	0.08
355.2680054	1.78
356.2664795	0.47
357.1828003	0.07
383.4756470	0.07
395.3345337	0.06
396.4855347	0.26
399.0924683	19.66
399.7734985	0.12
426.1380615	0.06
427.0259399	0.12
440.0669556	0.09
452.3089600	0.06
455.2200928	0.09
456.8345337	2.55
457.8459473	0.95
480.0267944	0.26
480.9741211	0.09
501.4710083	0.23
517.5034790	9.59
518.1453247	100.00
518.9650269	0.48
520.0249634	0.56
521.4199829	0.09
530.4962769	0.04
533.0216675	0.06
545.5401001	0.37
546.4230957	0.27
554.2474976	0.18
554.9437256	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2875
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
120.8107376	39.71
171.298645	14.17
182.9267273	11.05
223.0473633	14.72
232.9550781	18.41
239.4552917	12.61
245.3343201	7.86
246.8352051	21.31
255.4892883	21.16
256.7512817	13.26
270.0849915	15.88
279.0312805	10.50
285.1939392	9.43
297.039093	33.56
320.2722473	8.38
351.0983887	15.90
354.5135498	11.03
363.1469727	6.25
366.0592957	7.26
373.2823181	4.66
380.3197632	4.66
384.8031921	26.93
390.9924622	25.67
408.2680054	100.00
409.3252869	36.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1181.82
Annotation	Unknow
Peak:m/z	Relative Intensity
667.7287598	0.22
694.2103882	0.36
706.7320557	0.09
799.3921509	0.70
855.4787598	0.05
962.6037598	0.30
1084.9929200	0.26
1118.6285400	0.66
1130.3236080	1.76
1135.0537110	0.11
1149.4230960	4.63
1153.5981450	0.07
1154.2100830	0.28
1154.8319090	0.31
1156.1726070	1.64
1161.2476810	1.60
1163.6312260	3.00
1165.6313480	8.54
1167.1768800	1.00
1168.5412600	100.00
1169.6572270	3.22
1170.5919190	3.47
1171.4113770	1.33
1172.7406010	0.69
1175.4162600	0.24
1176.2225340	0.09
1179.1613770	0.11
1226.1315920	0.70
1293.8233640	0.53
1313.3660890	1.17
1323.6987300	0.66
1336.6882320	1.05
1355.7757570	1.78
1362.0469970	1.22
1362.9790040	0.67
1365.7160640	1.16
1378.7728270	1.34
1423.7576900	0.05
1466.2434080	1.34
1497.7708740	0.09
1568.4117430	0.08
1600.3748780	0.08
1688.4515380	0.24
1697.8006590	0.32
1698.8937990	0.17
1700.9831540	0.09
1728.1270750	0.19
1763.2388920	0.09
1781.2025150	0.17
1806.3648680	1.73
1817.6614990	0.21
1825.1760250	0.31
1837.9041750	0.51
1855.8485110	0.33
1865.6824950	0.12
1871.3962400	0.10
1878.0539550	0.09
1885.7774660	0.27
1888.3714600	4.45
1890.9655760	5.79
1892.7355960	0.09
1895.8858640	0.62
1905.9073490	0.10
1912.2464600	0.24
1921.2828370	0.09
1922.6556400	0.09
1924.8044430	1.24
1925.8016360	5.24
1927.1511230	0.08
1929.3864750	0.15
1931.8781740	0.11
1938.3795170	0.30
1939.2453610	0.14
1942.9998780	0.11
1946.7966310	0.41
1951.5124510	0.53
1957.1750490	1.12
1958.6315920	0.37
1959.9407960	0.09
1962.1370850	3.12
1963.5217290	0.05
1971.3323970	1.42
1974.8399660	0.17
1981.8020020	1.08
1982.7340090	0.17
1983.6916500	7.60
1985.7803960	0.28
1988.1495360	0.16
1989.0533450	1.87
1990.6163330	14.33
1993.2357180	4.20
1994.9566650	0.10
1996.2208250	1.18
1997.7619630	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	257.0658
Annotation	1D-1-Guanidino-3-amino-1,3-dideoxy-scyllo-inositol
Peak:m/z	Relative Intensity
131.1225128	0.45
155.9807434	0.06
173.0381012	100.00
215.2614899	0.03
239.2407379	0.03
240.4711304	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	288.0464
Annotation	AminoDAHP
Peak:m/z	Relative Intensity
82.9502869	0.23
92.9933472	0.97
110.0328598	16.83
117.1342316	0.02
118.9472504	0.09
124.1557312	0.12
137.8872223	1.79
147.1392365	0.07
155.1271667	0.04
156.0628662	2.74
158.1038361	0.06
166.0856476	0.03
168.9080353	0.06
178.0673218	0.29
185.1136475	0.12
199.8440552	0.07
205.8521423	1.55
210.1135559	0.51
213.0797424	0.99
224.1549072	4.86
225.9843140	0.26
242.0373230	79.36
244.1518555	0.15
252.0559692	0.06
255.2253723	0.04
270.0736694	100.00
272.9687500	0.08
279.3216858	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	394.1267
Annotation	(gamma-Glutamyl-gamma-glutamyl)-S-methylcysteine
Peak:m/z	Relative Intensity
129.8317108	0.06
130.4362488	0.04
133.0536957	0.02
143.8663025	0.58
162.0295105	2.93
171.9584351	0.63
198.8584747	0.03
219.0582886	0.07
227.0129089	0.02
229.9204407	5.35
239.3858643	0.02
243.0628662	0.05
244.9472046	0.04
247.2220764	3.96
247.9863586	10.98
262.9490356	0.02
265.0399170	100.00
274.1141052	0.05
289.9540405	0.05
290.7625122	0.47
291.4069519	0.03
301.1116638	0.19
319.1644287	4.41
331.0413818	0.51
347.8668823	0.03
358.0090027	0.31
359.8484192	0.03
365.9043579	0.02
376.2027283	1.86
377.1743469	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1625
Annotation	Safflomin A
Peak:m/z	Relative Intensity
173.0953674	0.04
174.0639801	0.12
175.1201782	0.17
177.0227509	0.09
178.9817657	0.25
179.9540558	0.28
181.8307953	0.14
182.9184265	0.10
185.1484222	0.36
187.0774231	0.06
190.3097687	0.05
191.1031799	0.10
193.0297546	0.05
195.1114655	0.15
197.1636505	0.43
198.0553436	0.62
199.0497589	2.10
201.1654816	0.42
203.0487671	0.04
205.0933838	0.27
208.2050781	0.07
209.2713776	0.07
211.0537872	0.34
212.2973175	0.14
213.1211853	0.57
215.1337128	0.26
217.1378479	2.16
217.9903717	0.04
222.9386292	0.57
226.1028595	0.50
227.5187836	0.10
228.9335632	0.28
230.2091064	0.05
234.9015503	0.02
239.1028290	0.12
241.0554810	19.30
241.9275208	0.87
243.0120392	3.68
243.7832336	0.08
245.4239197	0.05
254.0098572	0.07
255.1440125	1.02
256.0414124	0.23
257.2189941	0.79
258.2037354	0.23
259.2814941	0.07
264.9346619	0.05
267.0934753	0.37
269.1530762	0.04
271.0356445	0.57
272.1660767	0.95
273.1324463	0.44
273.9724121	0.05
275.0387573	0.06
281.1923218	0.03
283.1366272	0.05
285.0596313	100.00
289.2272949	0.04
297.1884766	0.41
298.1196899	0.20
299.9826660	4.17
301.0809937	15.49
302.0447083	12.02
303.1786194	6.10
304.1359863	0.11
306.1589355	0.08
307.2481079	0.05
311.2266235	0.10
313.0912781	0.19
315.1333618	0.36
324.6389771	0.22
325.3127441	0.10
326.1940918	0.12
329.1320801	0.18
330.3120728	0.09
332.2718506	0.05
341.3349609	0.12
343.1112671	1.18
344.2279053	0.84
345.1484985	1.00
345.9291992	0.02
347.3629150	0.03
357.0823364	0.05
359.4359741	0.06
361.1663208	0.13
368.1589355	0.05
369.0765381	0.05
371.2484131	0.67
374.2426147	0.11
381.2755127	0.52
383.2186279	0.06
386.2526855	0.11
389.2108154	0.12
401.1646118	0.54
403.1707764	0.10
405.6076660	0.04
406.2097168	0.15
407.0744629	0.03
413.0239868	0.06
420.3734131	0.07
425.2540894	0.22
429.3949585	0.04
431.4374390	0.10
435.2789917	0.24
443.1672974	0.13
445.1052856	0.14
447.2263184	0.14
449.2385254	0.03
464.5893555	0.04
465.2011719	0.11
466.1942139	0.03
473.2067871	0.05
474.1262207	0.05
475.2272339	14.97
475.8502197	0.05
485.2667847	20.57
489.1651611	0.04
491.0290527	1.06
491.6953125	0.08
495.1864624	0.26
501.2573242	7.52
503.0258789	0.02
511.2211304	0.04
514.1743164	0.04
524.3671265	0.05
525.3028564	0.04
527.3567505	0.39
529.8140869	0.10
543.3313599	1.31
551.3618164	0.05
553.1372681	0.06
557.4735718	0.02
559.2279663	0.14
563.0966797	0.06
564.0640259	0.20
566.3576050	0.53
567.3186035	1.76
574.9531860	0.05
580.4479370	0.12
581.5457153	0.19
592.1997681	0.96
593.2473755	0.89
593.8816528	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	677.9849
Annotation	Unknow
Peak:m/z	Relative Intensity
263.3183594	0.40
273.8979492	0.23
289.8119507	0.35
291.0066528	0.39
302.0063477	0.48
307.8765259	0.91
308.8200684	0.83
327.4310303	0.41
347.8775024	0.55
350.0852051	0.80
353.0417480	1.11
365.8953247	1.80
367.9404907	19.66
370.3223267	0.35
405.9090576	0.72
408.2249756	0.48
420.1365356	0.61
424.0162354	1.41
426.0086060	100.00
438.0130615	12.59
455.8674927	3.29
461.1530762	1.54
467.9872437	1.86
472.8730469	0.52
509.1268921	0.34
515.7614746	1.06
520.4758911	0.88
522.8408813	3.42
527.9824829	1.76
540.4227295	0.30
544.4181519	1.41
546.3554688	0.16
557.1945801	0.55
558.5388794	1.02
569.4986572	0.69
579.2625122	0.46
587.7898560	0.48
597.4293823	2.06
598.3306885	0.41
615.1458130	2.83
617.7332764	1.39
618.7426758	0.64
668.6484375	1.26
670.2626343	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0712
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
104.8719025	0.38
116.9674988	0.65
122.8926086	0.09
132.1028137	0.09
141.1998444	0.10
146.0397644	0.39
148.971405	1.15
150.0902405	0.52
153.0166321	0.07
155.0541229	0.12
160.8553925	0.06
163.9840546	0.12
165.1289368	0.34
167.0294037	0.62
168.0249329	0.08
169.3361206	0.21
173.8675537	0.19
178.1613617	0.38
179.1021576	1.34
180.1050568	1.03
181.2179871	0.47
183.138382	0.06
184.2971344	0.07
185.1026611	0.10
193.1064758	0.37
194.0044403	0.47
194.963913	0.48
196.3294525	0.21
206.2117157	2.06
207.1797943	7.89
208.0757904	6.84
209.1753082	2.42
210.1593018	0.41
211.1201324	0.11
215.8963776	0.33
220.8649292	0.21
222.1361694	6.00
223.1439209	13.08
224.2268982	2.97
233.2680664	0.84
234.8424225	0.13
236.2850189	0.09
237.0526276	0.11
249.2364349	0.06
251.0790405	100.00
252.1175995	38.15
253.0992432	5.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	917.2418
Annotation	Unknow
Peak:m/z	Relative Intensity
258.9961548	0.79
263.0204468	0.13
271.1623840	0.70
305.1893311	81.35
306.1592407	0.24
308.2519531	0.06
396.5783691	0.06
611.0150757	100.00
613.3866577	0.15
656.8842163	0.09
658.6030273	0.08
771.0012817	0.18
872.6976929	0.05
886.4133911	0.07
898.9208374	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	229.1542
Annotation	Leucyl-Proline
Peak:m/z	Relative Intensity
69.0463104	0.27
69.8513641	1.50
86.0079956	4.48
101.0720825	0.08
115.9144897	100.00
132.0391693	0.11
134.9907684	0.07
144.2877045	0.11
154.9323120	0.10
167.0005646	0.06
170.0756073	0.08
172.9706116	0.09
182.9781952	0.23
185.0224152	0.11
185.7199097	0.07
193.0130463	0.04
200.1325836	0.24
201.0244446	0.45
211.0890656	0.41
212.1768951	0.51
214.3081207	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.1033
Annotation	Veranisatin B
Peak:m/z	Relative Intensity
107.0468140	0.03
111.1177521	0.05
112.9848022	0.38
127.0499878	0.05
132.0671082	0.05
134.0379639	4.33
143.1916199	0.02
146.9291992	0.03
148.9768677	0.81
159.9679565	3.93
161.1136780	0.12
173.0007629	0.11
174.9930115	43.99
175.9271393	0.39
178.0164795	0.85
189.2156067	0.15
191.0858002	1.99
193.0302429	100.00
201.0967560	0.04
201.9586487	0.91
202.9341278	0.39
207.1071167	1.49
214.9908752	0.06
217.0395203	62.25
219.1214905	0.13
221.1266785	0.34
231.1580505	0.08
233.0638733	0.17
234.5421448	0.88
235.1614075	9.82
245.3091736	0.12
247.0377197	2.16
257.0466309	0.13
259.1368408	1.63
262.9552002	0.02
265.1000977	3.83
275.2018433	0.19
277.2053833	0.27
289.4116211	0.03
295.0487366	5.95
319.4664307	0.02
335.6073303	0.03
337.0755920	2.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	335.1201
Annotation	Unknow
Peak:m/z	Relative Intensity
114.4043274	0.37
115.0631409	2.35
116.1578369	0.05
126.9625397	1.26
128.0086060	0.11
128.9132996	0.20
139.5028839	0.24
140.4876556	0.07
145.9825134	2.20
149.9807129	0.18
153.9912109	0.11
157.0007629	0.20
164.1654053	0.14
166.1524353	0.07
169.0268097	1.10
170.0536652	0.27
172.1436157	1.82
182.4250183	0.39
183.1946869	1.37
184.9852600	0.17
187.1608887	0.22
193.2175446	0.05
195.2113953	0.05
195.9134979	0.17
201.3240967	0.05
202.0402679	0.28
203.0314789	0.48
203.9689026	1.43
204.9233093	0.06
206.2445526	0.06
206.8750610	0.06
213.3303528	0.60
219.1635437	0.05
219.9979248	0.32
221.1509399	0.78
226.1179810	0.23
227.2247314	0.05
229.1264038	6.07
230.1099548	0.39
233.0724182	0.09
238.2372131	0.30
240.1924744	12.23
241.8923035	0.41
244.2397766	0.13
245.2398071	0.08
247.0505981	100.00
248.1205444	22.45
254.1557007	0.08
257.1875610	13.54
258.0986633	0.18
259.9743652	0.53
263.0821533	0.04
265.0973816	54.23
270.5336304	0.32
271.2343750	1.32
272.5005493	0.60
273.1081848	2.33
275.3370361	0.24
285.9476013	0.81
288.0438232	0.07
289.0504761	0.50
290.0100403	0.13
291.3128662	0.28
292.3916016	0.08
293.9721375	0.05
299.2228394	0.19
301.0540161	0.12
304.1379089	49.16
304.9772339	0.08
307.1104126	0.94
310.0461731	0.19
316.1080933	1.87
317.1956787	5.47
318.3690796	0.10
325.7495117	0.26
326.6729736	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	429.0752
Annotation	Unknow
Peak:m/z	Relative Intensity
125.5665283	0.10
130.8951111	0.08
134.8973083	0.04
152.0259399	0.08
152.8202820	0.04
164.5059052	0.19
175.1870117	0.04
184.8941345	0.09
203.0122986	0.13
214.9663086	0.09
217.9269562	0.13
218.9604797	0.06
220.1135712	1.08
223.9503784	0.06
226.2676697	0.05
227.2290344	0.06
236.9270630	0.07
243.0828247	0.03
249.3321228	0.06
254.6440735	0.34
264.0057068	8.77
265.2672119	1.05
266.3545532	0.71
267.2239990	0.20
274.9979553	0.13
282.0577393	0.50
283.8482666	0.12
290.2626953	0.04
291.0481567	0.97
292.9939880	0.23
307.6057129	0.07
310.8748779	0.04
314.3194580	1.45
331.0970459	0.30
337.1685181	0.06
341.2366943	0.61
350.1842346	0.13
356.3509216	0.04
361.3479919	0.05
366.0489807	0.11
367.1707458	0.24
368.5999451	0.11
369.2552795	0.16
380.3354187	0.03
383.1195068	100.00
384.2253113	2.04
385.1231079	14.81
390.0322571	0.11
393.2461548	0.08
398.2940979	0.15
400.7899475	9.28
401.5125427	0.10
408.4801941	0.05
410.5887146	0.46
411.4141235	0.81
412.3078308	0.22
418.4482422	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	549.2183
Annotation	Kunzeaphlogin F
Peak:m/z	Relative Intensity
167.2747498	0.20
187.9232941	0.09
204.1685638	0.52
205.1259918	2.41
213.2605743	0.42
260.1411743	0.35
271.4252930	0.12
284.3340454	0.21
286.8921814	0.35
301.2886658	1.12
327.0869751	14.25
330.4169312	0.15
341.4078979	0.27
345.1767578	100.00
359.1902466	0.31
372.2033691	0.26
393.4574585	0.27
400.1327515	1.30
401.3940430	0.09
402.4182129	0.14
415.2239990	0.67
417.0186157	0.19
418.2037354	0.55
434.3792114	0.13
457.3132935	0.18
467.5514526	0.61
469.3071289	0.14
469.9902344	0.61
474.9893188	0.60
476.1868286	0.40
482.7956543	0.54
484.9816284	0.58
486.3230591	0.16
493.1125488	0.39
496.1685181	0.10
497.4215698	1.04
503.5108032	0.29
504.7886353	0.27
506.3630981	0.59
507.2349854	0.90
513.3170776	0.32
514.2235718	0.48
522.6786499	0.17
530.1068726	0.99
531.3126831	2.59
532.1220093	0.19
539.5635376	1.16
540.2005005	0.71
540.8008423	0.34
542.6120605	0.49
550.4161377	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	494.1134
Annotation	Unknow
Peak:m/z	Relative Intensity
146.2002258	0.15
147.0863037	0.18
148.7490540	2.58
165.9869537	100.00
167.0110168	6.29
175.1100769	0.40
176.1924744	0.17
207.3341064	0.37
208.9122925	0.42
213.2874451	0.12
214.9312744	0.16
231.9591370	0.18
237.8623657	0.09
238.9236908	2.18
242.8998566	0.20
248.9896393	0.28
261.1062622	0.34
265.9296570	0.36
274.9679871	4.66
282.8925476	0.07
292.9765320	21.49
310.9895325	64.10
316.2081909	0.54
328.6005859	5.92
329.3246460	0.63
332.1138306	0.22
365.5115051	0.13
374.1398926	0.57
420.6982422	0.49
426.3157043	0.49
427.0957336	0.29
439.8362427	2.25
447.8873901	0.30
450.8662109	0.46
458.2637634	0.23
475.1812134	1.66
476.0235291	4.94
476.6346130	0.92
477.6235962	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	657.1614
Annotation	Unknow
Peak:m/z	Relative Intensity
191.0681763	4.94
244.0030518	1.20
350.0793457	1.35
353.2022705	100.00
429.2305908	0.82
544.4110718	0.86
613.0391846	32.21
622.6810913	1.40
640.4859009	1.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.9394
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9176331	0.07
159.0361328	0.66
229.1926880	0.10
247.0621033	0.01
272.9353638	100.00
312.9776001	0.10
340.2232056	0.01
341.0255737	0.07
341.9037476	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1664
Annotation	Verbasoside
Peak:m/z	Relative Intensity
144.8106842	0.07
147.0469513	0.03
148.9897766	0.29
150.8465576	0.08
160.9788055	0.18
164.2544556	0.04
175.0740814	0.04
178.7762909	0.02
180.9962158	0.54
183.0693359	0.03
188.9983521	0.03
205.2425232	0.05
221.0284729	0.08
245.0629883	0.03
252.8756714	0.04
261.5852356	0.18
265.0471802	0.02
267.2314148	0.02
269.2129211	0.08
279.0917969	0.21
294.3713379	0.03
299.2517700	0.04
309.2344055	0.01
311.0716248	0.30
313.2265625	0.15
330.3079224	0.03
342.9921265	0.15
358.9953613	0.10
370.8952637	0.02
395.0501404	0.02
398.3523865	0.08
400.9956665	1.01
415.1993408	100.00
416.3073730	0.05
417.2722473	0.03
431.5361328	0.02
442.0874023	0.02
443.4658813	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	490.0768
Annotation	Unknow
Peak:m/z	Relative Intensity
138.8299866	0.02
143.0990295	0.05
159.9384460	0.07
166.9871216	0.10
177.0053406	0.15
178.9987335	0.23
183.0510254	0.30
185.1072083	0.10
210.1535034	0.20
228.2666016	0.01
231.0374451	0.04
242.2054596	0.03
254.1340027	1.51
271.1315002	0.02
272.1636047	1.79
288.1575623	1.30
304.1618042	0.03
304.8679810	0.02
306.0964966	100.00
323.8068848	0.02
340.8184204	0.04
343.2467346	0.01
374.5020752	0.02
409.9977722	0.07
427.8011169	0.05
436.2345276	0.03
471.3103333	0.02
472.1906433	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	707.1824
Annotation	Patuletin 3-rhamnoside-7-(3''',4'''-diacetylrhamnoside)
Peak:m/z	Relative Intensity
254.2935486	0.13
260.9962769	0.08
271.3971252	0.05
303.2406006	0.11
304.0046692	0.05
305.2901001	0.05
306.0242615	0.05
313.9970093	0.09
337.0682983	0.39
340.8965149	0.16
353.1270752	100.00
353.8956909	0.43
356.6159058	0.15
357.3440552	0.19
358.9678345	0.28
361.5026855	0.08
379.3452148	0.25
385.2019653	0.28
392.1799927	0.08
397.2689819	0.12
398.3829956	0.43
399.2749023	0.29
400.1910400	0.05
401.4502563	0.17
403.2048950	0.21
404.1309814	0.05
418.2910156	0.09
422.1730347	0.06
424.2566528	0.53
433.3465576	0.10
442.3628540	0.08
458.1126709	0.14
489.2191772	0.15
514.0728149	0.05
533.2417603	0.12
544.2546387	1.62
545.3114624	0.64
550.3452759	0.04
554.4416504	0.17
555.2266235	0.05
563.6145630	0.05
575.0040894	0.19
586.2005005	0.34
586.9214478	0.47
593.2887573	0.42
607.2694092	0.05
609.1410522	0.06
613.6740112	0.26
616.3405762	0.23
627.3345337	0.13
640.0986938	0.12
640.8796997	0.25
644.7315063	0.24
646.0955200	0.50
650.2294922	0.11
661.1154785	0.04
662.6204834	0.08
663.6527100	0.26
670.2892456	0.16
675.9705200	0.45
676.7214966	0.29
678.9436035	0.04
683.7011108	0.34
688.3558960	1.30
689.2780762	0.53
696.7396851	0.07
697.5046997	1.15
698.5637817	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.1803
Annotation	Spinosin
Peak:m/z	Relative Intensity
202.0172119	0.07
214.0964355	0.11
225.0733795	0.13
229.3044128	0.23
231.0835419	0.16
235.0218353	0.27
250.9993286	0.08
258.1049194	0.49
260.1317139	0.14
263.2401733	0.12
268.0508118	0.27
286.1515503	3.91
287.0838013	0.85
295.2495728	0.03
301.0962524	100.00
302.1816406	19.34
346.2149048	0.10
356.2958984	0.04
363.1137695	0.05
376.3269043	0.07
385.2659912	0.13
398.2653809	0.06
399.7431641	0.18
403.1715698	0.12
410.3421021	0.11
411.1755981	0.38
417.2179565	0.12
419.1229248	0.16
421.1832275	0.05
425.1702271	0.12
426.4338379	0.05
428.0226440	0.11
429.3288574	0.28
447.0722656	1.58
448.2947998	1.08
458.4354248	0.13
463.0973511	26.47
464.1464233	6.34
472.3776855	0.16
473.2711792	0.31
473.9369507	0.12
479.4542236	0.14
480.3029785	0.02
489.7466431	0.04
495.6240234	0.11
506.9158936	0.20
516.4067383	0.06
520.9615479	0.20
545.5571899	0.24
549.4745483	0.10
557.0064697	0.03
559.1726685	0.16
562.8456421	0.10
570.7280273	0.10
573.5419312	0.12
576.6989136	0.66
577.4776001	0.21
587.8799438	0.24
591.4844971	0.86
592.3864136	0.18
593.0933228	0.06
597.9939575	0.15
598.7340088	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	763.2142
Annotation	Unknow
Peak:m/z	Relative Intensity
273.1237488	0.09
289.2864380	0.05
307.1820679	2.34
325.2313232	1.51
331.1284180	0.13
357.1391602	0.06
379.1047363	0.13
386.3175049	0.04
421.1904907	0.24
439.1398926	2.09
449.3825073	0.21
467.5437012	0.15
475.3327637	0.06
479.0786743	0.10
481.1860352	0.33
491.2945557	0.19
493.2801514	1.96
499.2227783	1.54
509.1952515	0.12
511.1232910	1.45
520.9605103	0.09
529.2542114	0.57
535.2494507	0.24
536.9677734	0.06
540.5573120	0.32
541.3464355	0.78
543.9703979	0.13
553.3400879	9.66
569.5175781	0.05
571.3124390	16.55
578.4909058	0.06
589.3278198	0.95
595.3526611	0.22
607.3560181	0.27
613.3224487	2.32
625.2376099	1.29
631.2378540	39.34
643.3022461	1.99
661.3946533	1.07
664.5993652	0.50
665.3433228	0.59
666.9601440	0.34
667.6425171	0.10
673.4317627	0.98
674.9040527	0.06
685.2094116	36.28
685.8624268	0.14
703.2525024	100.00
703.9624634	0.26
715.3994141	0.07
719.7776489	0.06
721.3918457	5.04
727.4472046	0.07
733.4503784	0.08
745.3926392	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	542.2592
Annotation	Unknow
Peak:m/z	Relative Intensity
162.8588257	1.45
168.9093018	0.16
182.9270172	0.44
189.1410370	1.49
200.9340515	1.72
215.0615387	0.73
221.0809631	0.37
226.7297363	0.55
229.1587982	0.81
276.1177368	0.11
295.1267090	7.08
298.8777466	0.27
312.3964844	0.56
327.1689453	64.37
344.5233765	15.54
345.1257935	100.00
346.0653076	0.33
348.6085815	0.25
357.1996460	1.04
358.5474243	0.62
360.5090332	0.70
362.0047607	19.63
362.9122314	76.90
369.2207031	0.76
380.3187866	0.34
383.1243896	0.19
385.1730347	0.75
391.1310425	0.19
401.2225952	0.33
404.8466797	0.25
411.2084961	0.92
418.8218384	0.38
425.3177490	0.54
434.7869263	0.59
447.2070923	0.40
452.3336792	0.12
453.1559448	0.37
456.4619141	0.79
471.2733154	0.70
488.3338013	1.62
491.4646606	0.66
499.6015015	0.57
507.1391602	0.67
510.3611450	0.18
512.0671997	1.13
521.7645264	0.24
523.8082886	9.32
524.7071533	12.32
525.5256958	0.22
532.8571777	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	308.0903
Annotation	Glutathione
Peak:m/z	Relative Intensity
89.9818268	0.04
115.8072510	0.31
116.7803345	0.12
117.9681778	1.06
130.2093048	0.19
143.9078369	1.31
144.8447571	0.68
145.9896545	2.41
147.8002930	0.12
152.1588135	0.22
152.9592590	0.07
162.0505066	8.32
163.0712891	8.51
164.0071106	25.01
176.1394501	0.11
179.0030060	35.23
180.0259705	40.95
180.9477539	100.00
185.0465088	0.07
188.1757355	0.05
189.2131653	0.06
205.0677185	0.21
206.3779907	0.05
207.0780334	0.09
215.1516418	0.28
215.9020691	0.12
217.0248413	0.52
229.0558777	0.09
232.9777527	3.79
233.9953918	10.01
235.0228577	21.89
244.1611633	0.08
245.0481567	0.35
246.1977844	0.86
247.1337280	1.21
256.5096130	0.09
263.7106018	0.10
272.3286133	0.02
273.1405334	0.96
274.0549927	1.55
290.2858887	0.74
291.1448364	4.32
292.0615845	10.10
293.1689453	2.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.3388
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
166.2536621	0.19
184.0016479	80.69
206.8256226	0.07
258.0276489	0.25
291.1851807	0.04
296.6119385	0.23
335.1882935	0.08
337.5137939	0.12
341.2915649	0.10
443.4953613	0.03
453.5662231	0.06
459.3101196	0.04
463.3199463	0.11
473.7020264	0.06
488.1151733	0.19
492.2819824	0.19
499.7235718	0.18
502.4345093	100.00
503.0869141	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0875
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
106.9906464	0.04
107.9369888	0.07
109.2157822	0.02
111.0025711	0.02
112.1666718	0.05
113.2242432	0.02
114.109024	0.02
127.0245514	0.07
128.0130005	0.07
134.0389862	0.23
135.0274658	7.20
136.0349274	5.56
137.0586548	0.60
138.0741272	0.04
143.0831909	0.05
145.1842346	0.03
155.0453339	0.11
156.0932922	0.12
157.1266785	0.01
161.0461731	0.88
162.1032867	0.75
163.3081055	0.06
171.2854919	0.02
173.0791931	3.54
174.1343384	2.02
175.1492767	0.39
179.0671082	35.68
180.0767517	42.84
181.0263367	5.66
185.2183533	0.02
191.0523682	100.00
192.0493469	76.95
193.0382538	13.62
196.1844788	0.05
218.2945557	0.01
221.207489	0.09
225.1541748	0.03
233.1794739	0.02
251.3158569	0.02
265.2246704	0.03
268.1087646	0.02
274.2451782	0.01
308.993988	0.03
310.1938171	0.10
311.5353394	0.01
336.1676025	0.10
337.34375	0.03
368.1438904	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	619.1218
Annotation	Unknow
Peak:m/z	Relative Intensity
174.8876495	0.41
181.3214264	0.08
183.2169800	0.13
191.2020721	0.12
205.2111053	0.16
210.2468719	0.22
214.0983734	0.11
221.1938629	0.11
223.1488342	0.51
226.2081299	0.25
229.1034546	0.12
238.1347046	0.08
242.0953979	3.08
243.0570679	2.72
244.1361084	0.39
247.1492310	0.42
257.9230042	0.27
259.1160889	0.26
260.1997986	0.20
268.5223389	0.13
273.1304321	0.09
274.1543274	0.06
275.1928711	0.95
277.0793457	0.05
280.0465088	0.32
282.1560059	0.09
284.3577881	0.15
288.8635864	0.05
289.4675598	0.16
290.2215576	0.06
290.9679565	0.23
294.1627808	0.32
301.4522400	0.05
304.1597290	0.07
305.9685669	0.37
307.1634521	0.90
308.0167236	0.18
309.1513062	0.07
312.1362305	0.13
314.1159668	0.43
320.0487061	0.06
321.2725830	0.22
322.1516724	1.06
324.1892090	0.36
326.8743591	0.45
331.1020508	0.10
332.2334595	0.12
339.1571655	8.52
340.2680664	0.14
344.2388306	0.43
345.0498657	0.06
348.4310913	0.13
355.0870972	0.13
363.0197754	0.22
365.2373657	0.14
370.0033569	0.05
371.1429443	0.16
374.1076050	0.90
377.0870361	0.08
380.0861816	0.26
385.0681152	0.12
391.4253540	0.24
392.2172241	0.08
397.2369385	0.39
398.1276855	0.46
403.9430542	0.20
414.3167114	0.04
415.2381592	0.33
418.8812866	0.18
422.0159302	0.06
426.0747681	0.13
433.1793213	0.09
435.3549805	0.23
438.2830200	0.33
439.1516113	0.55
440.1213379	0.18
446.3145142	0.05
447.9722900	0.07
454.3629761	0.05
457.1933594	36.87
458.1827393	0.16
460.2171631	0.14
463.4862061	0.06
464.1287231	0.31
466.3437500	0.14
469.2077637	0.50
473.3732910	0.48
477.1716309	0.30
482.1361084	0.74
484.2956543	0.14
487.5001221	0.09
490.4032593	0.07
493.2993164	0.49
499.1932373	7.08
500.3295898	0.87
502.5354614	0.12
503.4326172	0.06
505.0625000	0.26
506.2250366	1.08
511.0142212	0.27
512.3280640	0.70
513.0441284	0.17
517.5638428	0.07
518.3543091	0.75
520.0227661	0.27
521.3601685	0.80
523.1921997	1.01
524.2789917	1.58
525.2361450	0.52
526.6635132	0.22
529.2053223	16.78
530.1821289	1.55
535.1831665	0.81
537.0202637	0.36
538.0711060	0.28
539.3088989	0.16
541.3220825	1.09
542.2594604	0.23
543.3031616	0.49
548.0744019	2.47
549.2605591	0.44
553.2155151	3.01
553.8815308	0.05
559.1878052	100.00
560.3229980	3.75
565.1875000	1.74
566.1596069	13.79
566.8613892	0.34
571.2301636	0.09
573.1497192	0.38
575.2860107	0.39
577.3305054	0.14
581.0215454	0.13
583.2407837	18.30
584.2875366	38.25
585.3229980	0.95
590.8305054	0.27
595.7792358	0.05
601.1837769	74.23
602.2436523	3.96
610.9091187	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.1442
Annotation	Unknow
Peak:m/z	Relative Intensity
210.8945312	6.30
280.4231567	2.05
322.0241089	2.04
323.1054688	100.00
335.1730347	0.35
345.8841553	0.60
395.1636963	1.50
567.0390015	0.44
574.7850952	1.71
629.3083496	1.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	457.0696
Annotation	Tjipanazole B
Peak:m/z	Relative Intensity
150.0129089	0.44
157.0965881	1.08
157.9734802	0.51
159.1035767	2.01
162.8472595	1.16
164.8897552	1.87
172.1166382	1.36
175.1102142	1.16
178.1522217	2.05
182.1139374	2.91
183.1539307	0.67
211.9610138	2.92
213.2798767	0.29
214.1399231	0.75
215.1182556	2.83
216.2020874	6.66
224.1622314	8.21
225.0760193	1.22
225.9681091	8.14
229.1438599	5.28
231.2008514	0.86
239.9579163	1.16
241.2586823	0.59
242.0668335	66.70
243.2354126	32.32
244.3637390	1.65
245.0691223	0.63
247.0485229	12.10
248.0986938	6.87
256.1919861	1.45
257.2664490	0.85
258.0648499	4.42
261.0575867	1.59
272.3099976	3.42
273.1567993	1.17
275.0521240	7.55
276.1994019	0.63
276.8332520	0.33
280.1039124	0.46
285.2946472	0.76
286.2866516	1.07
288.9334412	0.98
290.2226868	11.20
294.3938904	0.70
304.8562622	2.40
305.7148743	2.15
307.1149902	9.51
308.1681824	3.96
315.2082825	0.94
316.4511108	2.98
321.9769897	0.47
325.3219299	0.43
327.1688538	0.50
339.1318359	69.67
340.2038574	5.75
341.4437866	1.90
350.3045654	0.42
369.5687866	0.33
371.3970642	1.68
376.0038147	0.37
376.8964539	0.78
378.8958435	11.24
388.1590881	1.88
391.1692200	22.82
392.2165222	3.03
393.2131653	0.80
395.4951172	0.95
397.0441284	31.22
398.0400696	31.04
399.4193115	1.86
404.4321594	0.37
410.6734314	4.95
411.3432312	0.80
415.1825256	5.10
422.1733704	13.52
423.0992126	6.60
428.2406921	2.11
429.1708984	1.61
439.2268982	38.36
440.2078857	100.00
441.1477966	2.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	617.1081
Annotation	Unknow
Peak:m/z	Relative Intensity
173.0703430	0.18
183.0252686	0.12
193.0271912	0.69
197.2366028	0.13
199.0504761	0.47
208.1353760	0.10
210.2359467	0.13
217.2878418	0.15
220.9975281	0.12
224.9626465	0.06
231.1680908	0.85
233.0159302	0.13
237.2454224	0.89
241.2795258	2.61
241.9011230	0.05
244.2011871	0.08
247.0369263	0.17
254.2439270	0.54
259.0805054	1.59
260.7184143	0.05
266.4012451	0.10
269.0608521	0.18
271.0628357	1.69
273.2282715	7.21
285.1564331	0.17
297.6112671	0.05
300.9047241	0.12
303.1976318	12.14
305.1519775	21.22
307.1671448	8.60
315.0702515	0.07
319.1573486	0.78
325.3839722	0.12
327.6560669	0.15
329.2438354	0.06
331.1684570	0.41
333.9854736	1.30
335.2142944	0.17
337.1449585	37.99
338.7053223	0.29
345.0209961	0.05
347.0421143	0.17
349.5046387	0.11
353.3167114	0.39
355.0181885	0.11
361.2579956	0.13
363.3121948	0.07
367.3743896	0.20
368.3583374	0.05
369.3244019	0.16
372.0279541	0.06
373.0084839	0.08
379.2387695	0.13
393.8510132	0.24
398.6351929	0.07
402.9089966	0.08
408.1864624	0.23
410.9385986	0.06
412.1514893	0.45
414.2677612	0.06
415.1679077	0.08
421.0529175	0.24
425.4054565	0.07
435.2828979	0.15
436.4038696	0.28
437.1466675	1.09
446.3845825	0.06
451.1219482	0.14
455.1865845	100.00
463.1640625	0.04
467.3823242	0.05
467.9962769	0.11
469.3132324	0.21
471.3208008	0.21
473.0308228	0.07
479.1708374	0.09
480.0626221	0.18
484.0275269	0.08
485.2525635	0.06
488.2670898	0.09
494.5617065	0.11
495.1633911	0.19
497.1312256	2.60
499.4494019	0.09
500.4005737	0.36
509.3408813	0.24
514.2368774	0.33
515.4568481	0.08
523.0656128	0.12
526.8668823	0.66
527.6660767	0.09
530.1101685	0.08
533.2296143	0.14
535.7522583	0.47
537.3886108	0.08
538.3407593	0.15
547.0919800	0.14
548.3895264	0.05
551.2004395	1.21
553.2730713	0.33
555.3738403	0.11
557.1095581	30.27
563.1720581	0.20
565.2403564	0.11
569.7286987	0.11
571.1630249	0.23
572.2511597	0.25
573.4886475	0.48
579.1440430	0.11
581.2440796	0.75
582.5345459	0.13
583.7691040	0.12
584.4246216	0.11
585.4315796	0.07
587.2285156	0.36
594.3803101	0.34
598.2312622	1.56
599.2670288	2.25
617.8027344	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	340.03
Annotation	Unknow
Peak:m/z	Relative Intensity
149.8695374	0.05
165.0232849	0.07
173.9670563	0.17
183.1710205	0.34
188.9405060	0.35
197.0573120	0.13
199.2848511	0.09
208.0397797	0.13
209.0456848	0.33
210.0784912	0.07
220.0578613	0.40
227.3631897	0.26
236.0628052	0.49
246.4526367	0.05
253.8998108	0.09
263.1350708	0.04
276.0550842	0.21
277.3043823	0.49
280.1698914	0.05
285.2229919	0.06
291.7570496	0.14
294.1160278	18.27
295.2270508	0.25
296.4080200	0.21
303.2601013	0.33
304.8640747	0.10
306.8604736	0.11
308.1054382	0.31
312.1493530	0.11
321.9571533	100.00
322.8462524	0.17
325.5824585	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	351.0801
Annotation	Unknow
Peak:m/z	Relative Intensity
127.0001373	0.22
130.8366699	0.06
135.0420532	7.72
155.1588898	0.34
160.9771118	0.65
173.0522614	2.71
178.9926147	44.03
180.8836365	0.05
190.9984894	100.00
219.2364807	0.17
232.1358948	0.04
237.3315125	0.06
239.0982361	0.10
241.0362549	0.03
247.8010864	0.04
255.2555237	0.04
262.8954163	0.11
275.2048645	0.04
304.1126404	0.09
305.8231812	0.07
309.3173218	0.11
316.4912109	0.13
334.1505432	0.05
335.2466431	0.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1094.5225
Annotation	Unknow
Peak:m/z	Relative Intensity
375.3056030	0.30
410.1610107	0.11
474.6784058	0.52
512.6409912	0.24
527.6964111	0.25
587.4785156	0.10
593.3487549	0.10
601.6950684	0.57
618.1522217	0.26
667.9078369	0.31
673.2556152	0.58
674.2766113	0.16
675.3215332	0.20
734.1986084	0.26
741.0779419	3.16
741.7839966	1.30
752.4146118	0.62
769.3414307	1.26
787.3675537	0.62
788.3116455	0.16
798.4587402	0.72
799.2187500	0.45
800.5376587	0.40
801.5097656	0.33
834.5758057	0.52
856.1928711	0.63
866.7115479	0.14
875.4223633	0.19
876.8524170	0.18
882.8618164	0.29
884.4278564	0.36
887.9978027	0.26
897.0721436	0.07
901.1029053	0.32
903.6593018	0.12
904.6813965	0.07
913.6328125	1.83
946.7204590	0.12
952.7202148	2.62
953.3937988	0.49
955.7268066	0.26
962.2612305	0.08
970.8830566	1.74
990.3121338	2.85
990.9826660	0.68
995.5764160	0.24
1008.1159670	0.70
1010.9926760	0.26
1012.2070310	0.85
1013.8946530	0.38
1019.9279790	0.39
1023.5124510	1.61
1026.3623050	0.24
1028.2456050	2.62
1029.9860840	0.28
1036.1496580	0.13
1046.2329100	1.32
1047.5875240	0.12
1051.6813960	0.43
1057.0943600	2.78
1068.2904050	0.82
1074.9252930	0.70
1077.3652340	0.64
1078.1076660	0.91
1095.1147460	0.53
1098.1457520	0.18
1112.5554200	0.74
1119.6926270	0.13
1126.0389400	0.30
1127.1625980	0.11
1130.2292480	0.34
1131.1406250	0.30
1135.4315190	3.27
1136.3056640	1.04
1140.4007570	1.59
1154.9440920	0.41
1191.6975100	3.61
1192.7344970	1.03
1228.3297120	0.33
1230.9033200	0.22
1235.9191890	0.80
1244.8222660	0.27
1248.4141850	2.61
1249.0263670	0.27
1305.6140140	0.49
1345.9283450	1.54
1374.5989990	0.66
1379.2259520	0.48
1379.9781490	0.36
1411.4976810	1.11
1418.9122310	1.12
1421.4389650	0.08
1428.1179200	6.97
1429.0020750	4.63
1454.5509030	0.80
1460.2126460	0.20
1467.4122310	0.80
1470.6049800	0.24
1473.0853270	0.17
1476.4656980	3.29
1477.5157470	1.46
1481.0167240	0.94
1483.8883060	0.31
1484.7481690	1.78
1485.4101560	5.68
1486.2108150	0.77
1486.8935550	0.21
1488.0064700	0.29
1490.3189700	0.45
1506.4241940	0.50
1534.5239260	0.41
1535.5926510	0.81
1574.4403080	0.18
1596.0531010	0.29
1685.5549320	0.17
1759.9368900	0.41
1768.0679930	0.10
1771.4581300	0.23
1773.3316650	1.17
1777.8127440	2.28
1791.0451660	0.14
1792.7873540	0.06
1814.3868410	0.45
1824.8465580	5.73
1826.1898190	0.13
1834.3504640	0.86
1842.1932370	0.76
1858.5758060	0.35
1866.4655760	0.24
1870.3928220	6.67
1871.6643070	0.25
1872.3070070	0.68
1878.7352290	0.10
1880.8502200	0.80
1885.9222410	0.82
1893.9969480	0.33
1898.5837400	11.18
1903.2432860	0.17
1904.4559330	0.46
1907.2855220	0.23
1909.2849120	0.21
1917.3853760	1.93
1920.3415530	0.38
1923.4102780	12.55
1925.0916750	11.99
1928.1927490	0.41
1934.7799070	0.28
1938.8360600	0.13
1939.7678220	0.74
1942.1096190	0.17
1944.5052490	0.57
1948.5340580	0.10
1950.7266850	1.11
1952.6944580	0.38
1955.4434810	15.10
1956.4229740	3.87
1957.7930910	0.84
1958.9050290	20.69
1959.5413820	22.34
1962.9244380	0.47
1963.8890380	0.21
1965.5367430	0.86
1966.6276860	6.53
1969.8519290	0.19
1971.4185790	0.12
1973.6662600	3.49
1975.2078860	1.31
1978.1373290	17.98
1980.1138920	1.56
1981.2630620	0.22
1982.4958500	1.19
1985.4864500	3.15
1990.2735600	0.30
1990.9084470	0.21
1991.8800050	0.07
1992.6179200	1.56
1995.2926030	0.82
1996.3643800	10.45
1998.6990970	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	755.2036
Annotation	Orientin 4'-O-glucoside-2''-O-rhamnoside
Peak:m/z	Relative Intensity
285.2489929	0.05
286.3106079	0.51
332.0823975	0.06
427.6664429	0.04
428.5274658	0.11
447.3547974	0.20
455.2585449	0.03
462.1461182	0.12
463.1787720	0.03
468.5149536	0.20
491.1212769	0.10
520.1548462	0.05
522.1201172	0.10
547.6058350	0.21
563.2886963	0.06
579.6580811	0.06
580.3878784	0.05
593.2435913	70.64
594.3126831	100.00
609.3899536	0.18
610.9641724	0.24
624.4896240	0.24
626.6255493	0.10
635.4946289	0.15
636.5618286	0.09
639.8165894	0.05
647.2748413	0.06
647.8915405	0.19
658.8427124	0.05
678.2943115	0.10
695.9839478	0.33
697.3799438	0.06
711.1947021	0.07
712.4794312	0.22
718.5749512	0.08
719.9226685	0.06
725.4157104	0.18
732.1359253	0.32
734.0972900	0.03
736.8811035	0.43
738.1875000	0.32
740.8214722	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	851.1063
Annotation	Unknow
Peak:m/z	Relative Intensity
261.3029480	0.19
270.1494141	0.31
288.0181885	0.68
365.0150146	0.46
445.6080322	0.59
450.4150391	0.52
508.2229004	0.25
547.2933350	0.34
601.4534302	0.19
689.4705200	0.75
744.8954468	0.44
747.9967651	0.22
777.9286499	1.00
780.6046753	0.35
784.9185181	1.46
785.7008667	1.63
787.4321899	0.42
792.6493530	1.32
793.4505615	1.56
795.8863525	2.62
796.4904175	4.85
798.4418945	0.73
800.2081299	3.58
800.9005737	0.70
802.4675903	1.64
804.8775024	2.96
808.3719482	0.24
809.3453979	2.64
809.9760132	0.75
811.3894653	0.60
812.2326660	1.06
813.6499634	2.66
815.3971558	0.15
817.2247925	1.07
817.8507080	4.33
818.5372314	0.30
819.5545044	1.34
820.8236694	0.62
822.6950684	1.40
823.3931274	2.45
824.2442017	0.62
827.0328979	5.66
828.6757812	3.65
831.1762695	3.75
833.6566772	16.55
835.4937134	9.25
836.0997925	0.08
836.8500366	3.52
837.9447632	66.81
838.7733765	1.81
840.1172485	2.32
840.9470825	1.65
842.2025757	2.72
861.8753052	0.49
891.7979126	0.65
912.6283569	0.32
916.5046387	1.49
934.7301636	0.20
935.6530762	1.32
962.3879395	1.38
974.2924194	5.60
974.9412231	0.75
980.3167114	0.38
985.8786011	0.48
987.7690430	0.45
993.3685913	1.59
995.2638550	0.44
999.2994995	3.33
1002.8849490	1.64
1004.2009280	1.32
1005.3271480	4.78
1007.1115720	1.28
1009.9450070	1.39
1015.1577760	0.63
1022.5504760	1.59
1023.9744260	1.45
1027.1308590	0.84
1027.7409670	0.52
1028.4377440	3.49
1029.7263180	0.18
1030.5573730	0.12
1033.0545650	7.03
1034.7333980	3.53
1036.5052490	1.15
1039.2191160	8.63
1040.1754150	0.16
1040.8291020	0.37
1042.1917720	3.19
1043.3063960	0.39
1044.5366210	2.26
1045.1572270	0.66
1048.0727540	4.34
1048.8791500	0.25
1053.3546140	1.98
1054.8559570	1.08
1055.8466800	0.95
1057.0321040	0.36
1057.6394040	0.97
1060.8479000	6.44
1061.5534670	5.58
1063.0573730	1.06
1063.8209230	1.24
1066.6452640	6.79
1067.4245610	7.74
1068.5590820	1.22
1072.7536620	16.34
1073.4440920	5.43
1075.1040040	1.53
1075.8879390	3.62
1077.2528080	0.87
1079.1184080	2.68
1082.0010990	1.80
1083.1131590	0.70
1084.3482670	4.41
1085.1192630	9.33
1087.5009770	0.19
1088.8261720	0.27
1090.0805660	5.31
1090.8383790	4.20
1095.3254390	2.96
1096.3671880	4.69
1097.5050050	0.75
1100.0433350	1.81
1101.0195310	2.99
1102.5214840	2.07
1103.7362060	1.53
1121.2802730	1.05
1122.6092530	0.48
1127.7813720	0.39
1165.7873540	0.96
1202.9833980	0.28
1253.6136470	0.66
1259.8426510	0.34
1335.2802730	0.61
1396.5030520	0.77
1411.0028080	0.16
1419.1378170	0.60
1422.5557860	0.80
1467.1461180	0.68
1483.7785640	0.91
1486.9758300	1.21
1493.8243410	0.12
1508.9572750	0.45
1527.7396240	0.32
1550.6317140	0.90
1562.8643800	0.70
1564.4525150	0.80
1578.5994870	1.17
1619.4669190	0.09
1681.5324710	0.23
1692.9844970	0.15
1726.4449460	0.16
1738.7467040	0.50
1739.8314210	1.21
1752.3781740	1.13
1761.6641850	0.18
1763.7512210	0.12
1795.3557130	0.12
1808.1571040	1.09
1818.0733640	0.22
1824.7679440	14.77
1826.8880620	0.33
1834.5251460	0.14
1843.0710450	0.29
1853.5875240	2.16
1854.9268800	0.33
1858.0294190	0.21
1870.2155760	0.17
1872.3590090	1.78
1884.4837650	0.41
1890.9447020	3.92
1895.4021000	0.26
1897.5666500	2.48
1900.3133540	7.08
1905.8527830	0.30
1910.1369630	0.58
1916.7419430	3.27
1918.9454350	2.94
1920.8770750	0.12
1922.9766850	2.12
1925.2614750	0.12
1926.7943120	10.16
1928.1698000	15.82
1929.7824710	0.08
1934.2678220	5.06
1936.6065670	4.18
1939.1018070	11.04
1941.4991460	24.74
1942.9246830	0.74
1944.4364010	0.31
1945.7653810	0.10
1947.5098880	0.17
1948.2238770	0.24
1953.7956540	0.26
1954.7448730	0.20
1957.7286380	0.22
1959.4002690	0.56
1961.3107910	7.25
1962.8406980	2.63
1963.4759520	0.26
1965.4215090	0.40
1966.7647710	7.57
1968.7468260	1.26
1969.6893310	3.21
1972.1916500	3.25
1975.8205570	93.94
1980.0109860	8.72
1981.7047120	6.21
1984.2545170	0.71
1985.8913570	1.66
1986.8913570	15.73
1987.6062010	49.35
1988.7692870	100.00
1989.9405520	0.31
1991.1248780	0.45
1992.0729980	0.43
1993.2786870	0.23
1995.3145750	0.31
1998.8504640	0.58
1999.8415530	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	771.1978
Annotation	Kaempferol 3-glucosyl-(1->2)-gentiobioside
Peak:m/z	Relative Intensity
255.1906128	0.10
265.0582886	0.01
269.1700439	0.01
271.1978760	0.04
283.1630554	0.01
285.2062988	0.03
286.0613403	0.01
297.2526245	0.02
299.1429749	0.11
300.1135254	0.19
301.1941528	2.42
302.1132812	0.36
302.7699585	0.01
307.3450623	0.02
315.3262939	0.01
325.2495117	0.05
341.0974121	0.01
343.2117920	0.13
344.2459106	0.05
366.9907227	0.01
373.3560181	0.01
385.1287842	0.02
387.0646973	0.01
396.4310303	0.01
445.2633667	0.03
457.3910522	0.01
462.2706909	0.46
463.1921387	2.17
464.1896973	0.56
465.3977661	0.02
484.5659180	0.01
500.4546509	0.01
506.4640503	0.01
535.3763428	0.03
549.1806641	0.02
591.2616577	0.03
592.1886597	0.03
609.2857666	100.00
610.2269287	23.59
610.8583374	0.13
651.4073486	0.24
652.4202271	0.05
681.3151245	0.01
693.2317505	0.01
693.9994507	0.02
700.4687500	0.01
711.2809448	0.01
727.2935181	0.01
728.1801147	0.01
740.2815552	0.02
744.8654785	0.01
753.3718262	0.12
754.3713989	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1081.45
Annotation	Caucasicoside D
Peak:m/z	Relative Intensity
357.8217773	0.35
485.8157959	0.76
505.3026123	0.58
511.2924805	0.42
539.3062744	0.21
557.4550781	1.66
558.3438721	0.63
647.7139282	0.32
685.4204102	0.96
686.0327759	0.54
690.2933350	0.67
725.3844604	0.89
918.1195068	0.14
922.4160156	0.57
968.6906738	1.00
1013.5146480	0.26
1018.7573240	1.13
1020.1452640	1.19
1034.7639160	0.79
1037.0350340	8.14
1038.1611330	1.51
1039.6508790	1.40
1040.4116210	0.76
1051.4125980	2.56
1054.1348880	0.32
1055.7276610	2.89
1058.7365720	8.44
1063.2435300	1.75
1065.2392580	0.36
1067.2656250	43.81
1068.1029050	9.29
1068.8989260	3.21
1069.5991210	15.23
1070.5808110	4.83
1071.4676510	0.77
1081.8057860	0.68
1124.5477290	16.05
1131.3315430	5.51
1132.4431150	0.58
1133.8547360	51.99
1134.8503420	2.13
1138.0585940	0.83
1139.4914550	0.43
1140.4421390	3.31
1145.7115480	0.32
1152.2963870	12.54
1155.3160400	24.79
1157.3029790	0.25
1166.4775390	0.39
1175.0739750	0.39
1182.4829100	70.26
1184.2348630	0.69
1206.8286130	3.40
1209.4967040	91.24
1210.2761230	1.96
1210.9792480	0.17
1212.0434570	0.96
1212.7584230	1.15
1213.6673580	1.01
1214.7879640	3.39
1217.2839360	3.67
1222.7480470	0.93
1225.1639400	0.60
1228.9564210	7.73
1258.8809810	0.81
1284.8266600	0.42
1303.7142330	0.24
1304.8227540	0.25
1307.3741460	0.61
1330.7891850	0.46
1343.2991940	0.61
1344.7780760	0.98
1367.8708500	1.96
1386.4437260	1.39
1431.6063230	2.88
1493.7806400	1.03
1517.2155760	0.54
1521.6124270	1.40
1538.6024170	0.25
1602.5523680	2.62
1624.0740970	2.61
1639.7390140	1.03
1665.5506590	0.24
1701.7767330	1.35
1703.4061280	0.14
1714.7580570	1.03
1736.9320070	1.03
1762.0479740	0.64
1792.4644780	0.62
1818.5377200	20.32
1834.8571780	1.93
1840.2076420	0.24
1870.0769040	0.26
1875.9034420	0.34
1882.5452880	0.62
1889.0794680	4.60
1893.6068120	1.23
1896.0007320	0.36
1902.2098390	0.73
1907.4127200	0.41
1914.8200680	1.31
1918.0179440	24.90
1924.2355960	1.07
1926.0006100	5.36
1935.4857180	1.01
1940.7681880	0.52
1941.9606930	0.15
1948.8673100	3.58
1950.2593990	0.23
1951.1564940	0.64
1952.0510250	0.73
1962.3675540	1.99
1966.2969970	5.10
1967.3328860	0.19
1968.8592530	14.80
1970.9055180	24.95
1972.8026120	0.16
1973.5679930	0.27
1974.9699710	14.17
1977.9293210	9.70
1979.3557130	0.37
1983.0616460	0.15
1987.6857910	100.00
1989.6754150	26.16
1990.8503420	3.38
1991.6232910	0.34
1993.8131100	13.16
1994.5261230	13.89
1995.4788820	7.91
1999.8669430	16.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2625
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
139.7591400	0.18
153.1188965	0.31
167.1135559	0.07
196.1376648	2.00
196.9854431	0.38
199.0444946	0.11
214.0061035	1.01
215.2585449	0.10
216.0592346	0.22
222.0217285	0.09
227.7184906	0.05
231.3225098	0.08
233.2107391	0.29
234.3013916	0.16
235.7493591	0.27
255.4787903	0.17
259.3590698	0.18
265.3471375	0.05
275.6202087	0.40
277.2840271	100.00
278.2815247	39.77
278.9222107	0.07
291.1804199	0.06
325.0773010	0.13
328.2111206	0.10
329.3977051	0.05
331.0586243	0.08
333.2136230	0.18
342.8406372	0.05
345.1590881	0.17
347.3319397	0.25
358.9703674	0.06
360.1719666	0.25
366.9831543	0.15
371.0992737	0.07
390.4489441	0.30
391.1640320	0.11
401.2961731	0.07
403.2035828	0.54
411.4560242	0.12
413.3075867	0.27
414.5034485	0.15
429.2934265	0.33
431.2170410	0.12
432.2162781	0.16
437.1884460	0.44
438.4244385	0.29
439.1673584	0.20
439.9905701	0.22
447.3732300	0.72
448.4432068	0.11
455.6708679	0.14
457.1889648	1.77
458.0152283	0.65
460.3238831	0.87
475.3518677	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.1951
Annotation	Excavatolide D
Peak:m/z	Relative Intensity
172.9309998	0.14
205.0847473	0.03
235.0201721	0.09
279.0837402	0.05
297.3999329	0.05
309.7003479	0.03
311.0064697	0.07
314.4083252	0.05
345.0187988	0.18
347.2739258	0.06
355.3160400	0.15
359.3317871	0.15
361.2305908	48.21
361.8423462	0.10
362.8192749	0.05
363.8870239	0.05
365.3181763	0.15
367.3385620	0.25
371.9044189	0.22
378.2237549	0.25
379.2934570	0.05
391.1970825	0.17
394.7984009	0.04
396.3853760	0.25
399.4880371	0.04
403.4502563	0.11
409.3130493	0.04
413.0666504	0.07
423.6071167	0.04
426.2648926	0.20
427.6732178	0.09
431.5973511	0.06
442.2988281	0.19
443.1791992	0.11
444.1593018	0.13
463.4233398	0.06
467.4220581	0.11
469.9262085	0.04
478.0463257	0.06
487.1626587	0.14
495.1430054	0.04
497.2123413	0.10
498.3132935	0.07
499.2378540	0.04
505.4574585	0.07
509.3502808	0.13
513.1231689	0.84
514.2723999	0.85
515.5027466	0.34
523.1070557	100.00
524.4886475	0.16
525.5431519	0.04
527.1608276	0.07
528.3009644	0.09
539.7637329	0.19
540.5988159	0.95
541.4071045	0.11
542.4934082	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	709.4009
Annotation	Unknow
Peak:m/z	Relative Intensity
349.2122803	0.15
359.4078369	0.06
378.3148193	0.07
381.6516113	0.17
385.0467529	0.13
390.9857788	0.26
426.9229736	0.12
441.4625244	0.06
463.4813232	0.32
469.1289673	0.28
479.8485718	0.06
487.1769409	0.10
495.2060547	0.52
501.4477539	0.32
511.2572021	0.16
525.3735352	0.19
531.2640991	0.06
577.2238159	0.19
594.8577271	0.30
607.2119751	0.27
618.5240479	0.14
621.3224487	0.13
622.6242065	0.27
624.8364868	0.24
626.4298096	0.16
630.4108276	0.35
637.1266479	0.20
638.0031738	0.15
645.7473755	0.08
663.4010620	100.00
664.0944214	0.51
665.1240845	0.12
673.2308960	0.27
681.4440918	0.11
683.8239746	0.08
690.7614136	0.50
691.6024780	0.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	215.03
Annotation	2-C-Methyl-D-erythritol 4-phosphate
Peak:m/z	Relative Intensity
70.8828201	0.15
87.0540161	0.16
88.9123535	1.27
100.9457703	0.59
106.5397491	0.14
107.2057343	0.05
113.0290527	1.05
117.0976257	0.09
118.9719543	2.21
124.9995270	0.40
130.9732666	0.74
142.9912262	3.18
149.0210266	0.67
159.6695404	0.04
160.9779968	4.62
176.9768524	0.11
178.9185028	100.00
196.7477112	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	638.3378
Annotation	Unknow
Peak:m/z	Relative Intensity
269.4692078	0.14
302.5342407	0.09
328.0157471	0.19
328.6758423	0.10
346.2272339	1.40
362.3110962	0.35
455.9876709	0.16
474.1138306	1.54
492.1514893	100.00
592.6328125	0.17
620.4033813	1.60
621.4048462	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	307.08
Annotation	Unknow
Peak:m/z	Relative Intensity
115.0743256	0.19
127.0547180	0.24
129.9053802	58.19
130.9678497	1.68
143.8866272	0.44
152.0644531	0.11
156.5518646	0.15
162.0265350	0.79
172.3700409	0.17
175.0379028	0.65
176.9685059	0.50
179.0692291	4.37
182.0647888	0.36
190.0968323	0.47
199.1504517	0.80
208.7980957	0.47
211.0283203	0.39
216.1669006	0.37
217.0587158	0.21
231.2123413	2.19
232.0285950	0.54
233.2228394	0.58
234.1005554	0.17
235.1790161	0.40
238.0803833	0.96
242.5996704	39.18
243.2689209	3.25
244.6021118	1.38
245.3936768	0.15
246.7422180	3.01
248.2426147	0.32
249.6084900	0.11
260.4798889	2.08
261.1875916	1.59
261.9805908	0.99
265.2218628	1.08
269.5600586	42.70
270.5875854	1.03
271.3728333	0.46
272.1882324	0.31
274.0468750	0.85
275.5724182	56.61
276.2573242	3.42
277.3121643	0.33
278.9955444	3.43
279.7009888	0.58
288.2196960	2.96
289.0288086	0.86
289.9814453	0.52
292.4161682	0.61
297.2088318	1.29
298.5683289	100.00
299.2461243	8.21
300.6697693	0.53
301.3023071	0.44
308.1915283	1.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1014.01
Annotation	Unknow
Peak:m/z	Relative Intensity
294.0871277	0.13
314.2456360	0.29
349.2189941	0.61
468.6188049	0.34
499.6397400	0.30
532.3594971	0.26
646.6934814	0.50
657.2166748	0.13
702.0372314	0.08
720.5274048	0.53
815.5493164	0.19
816.1517334	0.40
851.6594238	0.10
892.9001465	0.51
915.4631348	0.23
943.6052246	0.63
960.1479492	1.65
961.8752441	0.61
967.6790771	2.94
968.5871582	0.17
972.3088379	1.67
978.0871582	0.57
984.1215820	2.44
984.9395752	0.20
987.7593994	3.85
990.3988037	1.32
995.7691650	0.12
998.1248779	0.83
1001.4392090	0.39
1002.3869630	2.87
1003.6522220	0.45
1029.1250000	2.39
1068.1755370	0.71
1072.2447510	0.14
1073.9340820	0.07
1075.6303710	0.41
1081.1789550	3.64
1084.8160400	2.19
1086.8292240	2.98
1091.3092040	1.14
1094.8078610	1.50
1108.7884520	1.75
1110.2009280	0.08
1115.8364260	4.06
1120.6829830	0.43
1124.8571780	16.38
1126.7406010	1.67
1127.8718260	1.26
1129.7778320	3.29
1131.4614260	8.48
1132.2530520	0.83
1133.9379880	59.69
1134.5798340	79.33
1135.3536380	2.03
1136.5579830	1.14
1137.4522710	0.83
1141.8637700	2.19
1142.9180910	2.94
1143.6281740	0.14
1145.3369140	0.54
1146.2402340	0.27
1147.7291260	2.30
1148.8492430	3.74
1149.6326900	1.95
1151.0095210	0.52
1152.6820070	18.70
1153.5225830	3.39
1155.5913090	2.75
1157.8967290	0.83
1159.3212890	3.98
1161.2525630	3.49
1162.2557370	2.03
1163.5664060	0.37
1196.4558110	0.09
1224.4766850	0.12
1240.0749510	1.60
1252.0771480	0.09
1254.5732420	0.35
1255.9846190	0.13
1260.9653320	0.23
1274.4233400	1.16
1287.1107180	1.32
1293.3272710	0.33
1302.6442870	1.57
1312.3861080	0.52
1323.2110600	1.41
1328.3240970	0.12
1329.9504390	0.85
1331.1766360	1.17
1336.6677250	0.25
1340.7908940	1.56
1345.0582280	0.13
1345.7105710	0.34
1347.2845460	0.36
1411.1087650	0.14
1463.8128660	0.13
1478.5874020	0.37
1493.9136960	1.30
1560.9289550	0.54
1598.7960210	0.54
1609.3946530	1.07
1634.6741940	1.77
1658.9451900	1.20
1659.7056880	0.37
1661.8103030	0.26
1709.1837160	0.17
1710.9906010	0.37
1720.9313960	0.25
1747.7086180	0.42
1754.5369870	0.12
1771.0496830	0.28
1772.1094970	0.13
1786.4875490	0.38
1794.8978270	0.07
1830.4862060	0.19
1845.4210210	0.20
1847.9132080	0.13
1853.4031980	0.07
1855.3713380	10.16
1859.4451900	61.59
1860.1228030	0.79
1865.0606690	0.07
1873.6115720	0.59
1874.3229980	1.17
1878.9783940	0.17
1882.9010010	0.54
1888.9202880	0.08
1891.9705810	2.94
1907.8870850	0.17
1912.5383300	0.38
1919.7862550	0.77
1923.8781740	0.23
1933.4479980	0.25
1936.5935060	0.08
1940.1500240	0.84
1941.1776120	31.13
1941.7795410	0.15
1943.8273930	8.20
1945.5921630	0.47
1946.7371830	1.16
1947.6678470	1.02
1949.0064700	0.41
1951.7902830	19.24
1952.4771730	0.11
1953.1632080	0.43
1954.7600100	0.18
1962.5013430	100.00
1964.0416260	3.68
1969.1348880	0.09
1971.0822750	0.97
1972.1583250	0.13
1975.6314700	0.16
1976.5821530	2.58
1978.2025150	0.90
1981.4366460	1.34
1982.0423580	2.33
1986.3084720	0.12
1987.4963380	2.51
1989.8775630	2.35
1991.0744630	1.89
1994.3360600	0.53
1995.8493650	0.79
1997.1457520	0.10
1998.3858640	1.53
1999.5812990	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	306.0762
Annotation	Glutathione
Peak:m/z	Relative Intensity
99.1453247	0.12
99.8692932	0.05
110.9919281	0.14
115.9350433	0.37
120.1313400	0.15
127.9687500	8.28
142.9833984	9.76
143.9479675	0.05
145.0588379	0.49
146.0811462	0.80
153.2720337	0.03
155.0357056	0.04
159.9508972	9.21
166.2296753	0.36
167.2074738	0.45
170.0814667	0.12
171.1183624	1.54
177.0780029	8.21
178.9817810	7.70
182.3399963	0.07
185.0250397	0.30
192.2185364	0.14
193.2322998	0.12
197.0484924	1.12
210.1413879	5.53
213.1556702	2.48
224.1723938	0.05
226.1521606	0.12
228.1868286	0.96
231.0596313	1.06
236.0780945	0.29
237.2087402	0.04
242.1817627	1.13
254.0783081	85.57
254.9599915	0.08
270.1712036	0.15
272.1208496	100.00
288.1105957	66.82
289.1336670	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	614.74
Annotation	Unknow
Peak:m/z	Relative Intensity
200.9798737	0.13
201.9868927	0.07
208.2285004	0.17
209.2271118	0.06
211.2168579	0.09
212.2403870	0.12
225.9804382	0.94
227.0596924	0.28
228.8916931	0.81
229.7534790	0.57
243.2412720	0.07
247.0443115	1.56
248.0877686	2.36
249.0534821	0.65
262.3310852	0.20
272.2322388	0.31
273.0791321	0.45
274.2549438	0.34
283.4649048	0.06
289.1507568	0.13
290.2797241	1.03
291.1480103	0.19
307.1216431	100.00
308.1293945	88.98
309.1495361	3.61
323.1608276	0.03
330.0554810	0.19
348.1576538	0.13
371.0914307	0.06
381.9655762	0.15
384.3262329	0.08
398.2577515	0.04
420.8845215	0.10
438.1172485	0.15
442.2304077	0.07
456.8183594	0.08
464.9226685	0.05
469.5127563	0.06
475.5025635	0.06
482.3544312	0.03
490.3682251	0.15
535.6683960	0.14
540.5720825	0.09
541.7551270	0.24
543.6320190	0.05
552.9801636	0.17
554.1627808	0.20
559.3299561	0.56
564.0418701	0.43
568.9125366	0.10
570.3588867	0.22
576.3549194	0.46
584.9093628	0.50
594.6067505	0.12
595.2120972	0.22
596.4595337	0.85
597.3936157	0.50
598.0095825	0.16
598.6428833	0.26
602.2812500	0.12
604.7717896	0.06
605.5954590	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	367.1032
Annotation	3-O-Feruloylquinic acid
Peak:m/z	Relative Intensity
109.0158997	0.04
110.9609528	0.44
117.1246490	0.03
127.1098480	0.07
128.9789429	0.06
134.0740051	0.90
137.0098572	0.29
149.1193237	0.13
152.8931274	0.06
155.0071716	1.68
172.9828186	100.00
179.0534668	0.01
187.8017273	0.06
191.1070099	0.12
193.0882721	13.26
200.3380737	0.05
201.2579651	0.03
203.1946716	0.06
223.3584290	0.02
239.1706543	0.03
246.3950500	0.02
280.3141479	0.23
287.3244019	0.03
305.3070679	0.07
307.1640930	0.31
312.9742432	0.03
322.1923218	0.09
330.7015686	0.04
331.3644409	0.08
347.1487732	0.03
349.1287537	0.02
367.2662964	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	710.75
Annotation	Unknow
Peak:m/z	Relative Intensity
290.8920288	3.36
374.4010010	0.80
412.0722656	0.25
458.5063477	21.13
459.3790894	0.56
460.6805420	1.23
464.0745239	0.20
482.6181641	0.70
490.4775391	0.41
496.8419800	0.57
499.0784302	0.13
502.7213135	5.41
520.6741943	2.10
530.9525146	0.21
535.1705933	0.42
535.9857788	0.92
537.1981201	0.34
542.5406494	100.00
543.4019775	1.36
544.5288696	12.40
546.8581543	0.93
548.5670166	0.95
562.8583374	0.45
564.0579224	0.42
566.7794189	3.01
573.9252319	1.24
574.5433350	3.87
580.6358032	4.44
585.8287964	0.33
590.5808105	9.07
601.9053345	0.71
602.9387817	0.64
604.4661255	55.66
605.2499390	0.44
611.9309692	0.43
616.4308472	1.23
624.6711426	0.36
626.0968628	17.57
626.7836304	47.90
634.4940186	1.92
646.4677734	10.53
650.5770874	20.83
651.3548584	0.44
663.9137573	6.26
664.6531372	12.55
665.9929810	0.33
680.7474976	1.04
689.9694214	0.18
691.3298950	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1134.4717
Annotation	Unknow
Peak:m/z	Relative Intensity
318.3920898	0.39
353.2567444	0.40
411.2265625	0.39
428.1614380	0.28
482.4711914	0.25
484.3906250	0.90
524.5118408	0.90
543.4020996	0.37
565.6938477	0.42
583.4706421	0.96
584.5472412	0.37
595.2266235	0.33
611.4670410	0.59
651.6417236	0.23
655.1049805	0.24
664.3024902	0.22
717.6697998	0.18
750.7091064	0.53
780.2701416	0.42
832.6702881	0.37
842.7266846	0.84
850.1390381	1.23
873.6483154	0.53
916.9130859	0.34
926.8398438	1.73
931.8724365	0.96
942.2817383	0.79
949.1690674	1.03
960.9854736	0.83
963.1649170	1.13
975.5362549	1.09
976.6759033	2.52
979.2119141	1.97
980.5169678	1.38
988.2067871	1.94
992.4013672	2.04
999.7119141	0.88
1003.2034910	0.66
1009.1362300	1.22
1009.8481450	0.28
1011.4713130	0.21
1012.8914790	1.00
1013.5800780	1.55
1014.3107910	0.55
1015.5113530	1.21
1018.3919680	1.50
1019.2615970	1.79
1021.5933840	1.97
1022.8560790	2.68
1023.9370120	1.89
1025.1452640	0.15
1026.6323240	1.72
1029.0375980	4.01
1029.6561280	3.55
1030.5178220	1.42
1031.9431150	0.36
1033.1772460	2.55
1034.6134030	1.65
1036.2517090	0.49
1038.4875490	0.35
1039.6125490	3.09
1041.4440920	1.62
1042.4106450	0.09
1046.5118410	1.43
1047.5045170	2.83
1048.4040530	1.32
1051.2542720	4.13
1053.9006350	3.05
1055.4987790	1.39
1056.6079100	2.97
1057.2780760	4.44
1058.1970210	3.13
1060.6048580	1.75
1061.6666260	0.96
1062.8438720	10.66
1063.5434570	5.17
1064.2321780	1.27
1064.9354250	0.24
1067.0300290	8.03
1067.7087400	9.13
1068.6951900	2.88
1070.2858890	4.98
1070.9870610	1.13
1072.9572750	9.25
1073.7030030	3.98
1075.1220700	2.47
1075.8985600	5.80
1076.5200200	3.93
1078.8248290	7.36
1079.4310300	0.49
1081.1356200	2.98
1082.1531980	2.73
1084.5378420	42.05
1085.2894290	14.11
1086.1854250	0.48
1087.2446290	5.88
1087.8851320	5.02
1089.3537600	2.39
1090.0515140	2.30
1090.8045650	67.77
1092.2849120	1.16
1092.9978030	1.67
1095.5083010	8.85
1096.1500240	27.47
1096.8433840	63.57
1097.9769290	4.23
1098.7602540	0.82
1099.4123540	0.76
1101.5092770	5.64
1102.4384770	0.38
1103.0998540	0.25
1105.5892330	0.90
1106.6579590	0.47
1108.4621580	6.17
1110.7572020	4.34
1111.3703610	4.38
1113.9987790	12.60
1114.8256840	5.08
1115.6815190	0.28
1116.9638670	17.81
1117.6794430	3.36
1119.5760500	12.64
1120.6057130	12.82
1121.5167240	12.55
1122.5646970	10.01
1123.3063960	21.14
1123.9440920	3.61
1125.0627440	0.92
1126.3187260	0.13
1139.5111080	0.54
1198.0263670	0.63
1229.8944090	1.30
1236.3945310	1.08
1239.5445560	0.22
1242.5756840	0.87
1243.9219970	1.09
1267.0458980	0.49
1268.6623540	0.93
1269.5512700	0.43
1277.5131840	1.60
1278.3747560	0.94
1279.3079830	0.77
1280.7292480	0.99
1289.4908450	0.66
1296.1136470	0.58
1300.5891110	0.72
1310.2086180	0.31
1317.9851070	0.17
1324.3763430	0.72
1328.1166990	1.75
1338.9415280	1.30
1345.6575930	1.10
1346.9827880	1.79
1352.5743410	1.74
1357.9107670	0.15
1361.7974850	0.57
1362.6942140	0.50
1364.2861330	1.64
1371.9814450	0.41
1374.2790530	0.63
1377.4896240	0.48
1388.2698970	0.86
1392.4549560	1.38
1394.3012700	0.24
1396.0682370	1.67
1396.7193600	0.99
1397.9294430	1.74
1400.2342530	0.49
1401.4763180	3.20
1402.3150630	2.57
1404.5300290	0.76
1405.5111080	0.28
1406.4240720	1.37
1410.6409910	6.44
1411.2779540	4.31
1412.8221440	0.66
1421.6770020	2.24
1422.5416260	0.86
1429.8209230	0.41
1435.5286870	0.87
1438.9158940	0.61
1442.8426510	0.45
1451.9893800	1.15
1454.3817140	0.28
1457.6735840	1.99
1459.0097660	0.41
1461.8480220	1.25
1462.7923580	1.56
1463.8271480	0.43
1466.9434810	0.87
1470.3260500	2.10
1471.7906490	1.92
1473.8734130	0.67
1475.4877930	0.84
1478.5283200	1.21
1479.3573000	0.60
1480.4833980	1.23
1481.1379390	1.17
1495.2948000	0.50
1497.3658450	0.75
1498.3710940	1.96
1499.2985840	1.28
1500.1389160	0.34
1504.4909670	0.85
1507.4005130	1.81
1508.3148190	2.95
1509.9947510	2.26
1511.7138670	0.20
1512.9127200	2.23
1514.2998050	0.12
1515.2468260	0.97
1517.7633060	0.33
1521.3380130	0.82
1522.0885010	0.65
1522.8415530	0.25
1528.0582280	0.98
1531.3651120	0.86
1533.2355960	0.37
1534.6413570	0.37
1536.5709230	1.65
1542.4927980	0.86
1543.6103520	1.63
1544.5510250	1.91
1547.7066650	0.15
1550.0300290	1.35
1551.8038330	0.72
1552.4124760	0.41
1555.2047120	0.92
1558.7545170	5.15
1559.4271240	1.89
1561.2572020	0.53
1561.9704590	0.58
1562.7230220	1.91
1569.2591550	0.86
1572.2291260	1.15
1577.7352290	0.58
1586.6978760	0.44
1588.4941410	0.81
1589.3258060	3.01
1592.6964110	1.74
1593.5079350	0.36
1594.6673580	1.64
1595.4794920	2.83
1599.6037600	0.68
1600.7347410	4.95
1602.7512210	1.01
1608.8995360	5.47
1609.6956790	1.69
1612.8056640	0.20
1620.1420900	0.21
1622.0871580	1.59
1626.3724370	0.92
1627.0958250	0.20
1630.2326660	0.24
1632.8007810	0.69
1633.7723390	0.41
1634.7113040	2.08
1635.5815430	2.92
1636.4187010	1.78
1644.1712650	13.87
1644.9904790	16.65
1645.9620360	0.95
1647.4052730	0.37
1700.8283690	0.73
1703.4110110	0.76
1744.5606690	0.48
1756.0301510	0.18
1761.5230710	0.22
1778.7614750	4.60
1779.8277590	0.18
1788.5271000	1.87
1798.7899170	3.50
1805.2796630	0.76
1811.2420650	0.12
1825.8543700	0.35
1832.1115720	4.98
1841.5235600	1.12
1848.3863530	5.80
1853.3231200	3.68
1857.0437010	0.34
1857.6818850	0.52
1858.7102050	0.19
1873.2921140	0.15
1874.6016850	2.28
1875.4700930	0.95
1880.3912350	0.12
1882.9260250	0.13
1888.5357670	0.18
1890.7985840	0.18
1891.4632570	0.30
1894.2980960	1.10
1895.0266110	9.21
1896.6252440	4.18
1901.9256590	40.88
1905.9998780	2.09
1906.9903560	0.40
1909.8719480	0.16
1911.4421390	5.73
1912.7413330	18.48
1913.3854980	0.23
1919.0662840	0.48
1923.5721440	1.59
1925.2298580	0.24
1929.0037840	0.64
1933.4381100	3.11
1938.5559080	0.55
1939.1805420	0.12
1942.7015380	4.51
1946.7581790	0.10
1949.2530520	10.80
1953.3465580	11.08
1954.5041500	0.39
1956.9147950	3.50
1957.8875730	12.23
1962.7056880	1.15
1968.8186040	4.59
1969.6751710	2.16
1970.4310300	16.10
1971.0880130	0.87
1972.8072510	0.09
1975.6529540	0.59
1976.6419680	0.41
1977.7941890	4.44
1978.7420650	0.58
1981.0423580	2.73
1982.6257320	11.24
1988.2663570	100.00
1989.7913820	0.18
1990.7170410	0.33
1991.4027100	6.14
1994.4162600	7.48
1995.6208500	2.14
1996.3428960	78.32
1997.4440920	2.18
1999.6405030	1.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	855.2577
Annotation	Sesaminol glucosyl-(1->2)-[glucosyl-(1->6)]-glucoside
Peak:m/z	Relative Intensity
254.9564514	0.07
257.1871033	0.04
265.6442261	0.05
271.1367493	0.18
273.1054077	0.07
283.0194092	0.04
285.0726013	0.04
287.1246033	0.04
299.0961304	0.14
300.1405640	1.27
301.0795288	7.96
313.1252136	0.14
314.3103638	0.07
325.1266785	0.08
329.1234131	0.02
337.3949280	0.02
343.2440491	0.50
367.0541382	0.02
396.2946167	0.01
427.4133301	0.07
445.2828369	0.11
462.1207275	0.05
463.0272217	0.03
464.4569092	0.10
477.6516724	0.03
490.0634155	0.04
491.1617432	0.02
495.2803345	0.02
505.2226562	0.08
509.5551147	0.05
519.4495239	0.03
525.4106445	0.01
531.2189331	0.02
533.5734863	0.07
534.5087891	0.06
543.3760376	0.01
546.3050537	1.60
547.3148193	6.77
573.1738892	0.02
589.1892700	0.08
591.1596680	0.11
594.1980591	0.06
609.2056885	100.00
609.8726807	0.26
619.6162720	0.02
623.2261353	0.22
624.1549683	0.03
633.3904419	0.03
649.8230591	0.03
650.7872925	0.02
651.4242554	0.50
668.3798218	0.06
693.1729736	1.53
697.7890625	0.03
708.1117554	0.04
735.0658569	0.02
739.8137207	0.03
747.2640991	0.08
751.6947632	0.03
753.2650146	0.11
756.5580444	0.08
763.0023193	0.07
771.2000122	0.25
779.6726074	0.02
808.0436401	0.06
810.5570068	0.03
812.2996826	0.03
823.8174438	0.17
836.3007202	0.03
837.4408569	0.18
840.1470337	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.0475
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
164.0865021	0.05
176.9698181	0.07
191.0124207	0.12
192.9745483	0.13
205.0874634	0.04
211.0469818	2.63
212.0278015	0.03
220.0410767	0.01
220.9540710	0.23
222.1088562	0.06
223.0006104	0.06
241.1241455	1.19
242.2475891	0.07
259.0710449	0.22
272.9447632	0.16
280.1765442	0.64
305.0166016	0.26
306.1608276	0.06
309.0609131	0.05
310.3126831	0.06
311.0164795	0.08
315.9223633	0.04
321.0140381	0.78
323.0978394	100.00
324.1976318	10.42
326.9895020	0.03
328.8795166	0.02
341.2536011	0.09
342.2061768	0.03
344.3040771	0.05
357.2322998	0.02
359.8906250	0.04
374.1127930	0.07
381.9753418	0.04
385.1226196	1.63
386.3620605	0.15
392.9261475	0.02
394.1879883	0.11
396.3011475	0.02
403.1213989	2.03
403.9797974	0.16
416.2836304	0.11
421.4462891	0.07
430.2913818	0.12
431.0364990	0.12
434.6861572	0.02
436.3097534	0.03
446.3611450	0.05
461.1983032	0.05
464.2752075	0.03
467.3205566	0.39
468.2089233	0.42
469.3839111	0.04
476.3148804	0.05
482.0055542	0.04
504.2238159	0.02
521.2708130	0.08
522.0609131	0.02
527.3186035	0.02
543.4288330	0.06
547.1558838	0.78
548.3263550	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	207.08
Annotation	Glycyl-Methionine
Peak:m/z	Relative Intensity
86.1724701	0.17
88.7594223	0.29
102.0296326	0.04
102.9274750	0.04
110.2749939	0.24
117.9865417	100.00
120.0185089	0.40
132.9327393	0.28
137.6331787	0.12
141.0160980	0.08
143.8869629	35.49
144.9195709	0.56
147.9646606	0.22
151.0350952	0.84
160.8932343	30.05
162.0016632	3.46
174.9859161	0.08
177.4546356	0.14
178.2334900	0.21
184.2476044	0.15
185.3689880	0.17
186.9528351	0.17
188.0724030	0.25
189.1605682	5.69
189.8047791	7.22
198.0118866	1.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1513
Annotation	kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
166.8594818	0.03
168.9207306	0.04
171.2428589	0.16
173.1394958	0.09
183.1421204	0.10
185.1370544	0.18
187.0786285	0.25
189.0043182	0.05
195.097168	0.45
196.3699951	0.20
197.2200623	0.29
199.0819702	0.34
211.1438751	0.83
212.3370667	0.22
213.233017	0.30
214.9868164	0.03
217.2258606	0.07
219.0765076	0.02
220.9555206	0.02
223.1305542	0.25
225.0392761	0.03
227.0838013	0.35
228.074234	0.14
229.0913239	1.66
237.2147827	0.15
239.171814	1.43
240.1856995	0.23
241.1725769	0.74
243.0945892	0.04
255.1344299	1.26
256.321991	0.59
257.1778564	2.74
258.9187622	0.10
266.2056274	0.06
267.1726074	0.74
269.0194092	0.26
271.3972778	0.09
278.1612854	0.05
281.1635742	0.05
283.4700317	1.13
285.046875	100.00
285.6677246	0.11
286.2833557	0.24
298.0568848	0.12
299.1380615	0.27
300.1759033	0.04
309.0682983	0.15
310.1222534	0.11
313.4771118	0.03
325.1792603	0.13
327.196167	3.10
332.9682617	0.04
338.1342773	0.07
344.119751	0.03
356.4952393	0.05
357.2810669	0.72
369.3170776	0.20
385.0858765	1.04
387.2382202	0.02
393.2891235	0.24
408.279541	0.10
410.4024048	0.07
411.3543091	0.08
413.2746582	0.08
429.9936523	0.05
430.9641113	0.27
438.467041	0.05
443.1564941	0.06
445.6102295	0.03
447.4231567	1.89
448.3647461	0.27
460.1353149	0.07
463.2026367	0.41
467.5554199	0.04
469.3659668	0.07
471.401062	0.65
473.5308838	0.05
478.041687	0.04
478.6724243	0.02
488.3617554	0.04
489.5378418	0.03
491.1866455	0.12
496.1478882	0.03
501.1769409	0.09
503.6638184	0.11
505.1576538	0.04
507.0007935	0.03
511.119812	0.04
512.7133179	0.05
518.1372681	0.02
525.5159302	0.10
527.2147217	0.18
529.1689453	0.04
529.9807739	0.03
532.3607178	0.16
533.5526733	0.02
540.6091919	0.05
546.6363525	1.16
547.2435913	2.98
548.1271973	0.29
554.3878174	0.28
555.1851196	0.51
556.4389038	0.13
557.1443481	0.03
557.7626343	0.02
558.4849854	0.04
559.1553955	0.02
560.7454224	0.05
562.4157715	0.16
565.3200073	0.30
572.3781738	0.03
573.2757568	0.29
574.4119263	0.19
575.1664429	0.58
575.8762207	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	324.13
Annotation	Unknow
Peak:m/z	Relative Intensity
100.1066513	0.18
110.8182220	0.09
111.9419250	2.93
113.0005875	3.55
114.0610123	0.96
115.0574341	0.46
119.0233917	0.17
120.9835510	0.10
126.9228516	0.05
129.1591644	2.38
130.0658569	0.68
132.0586090	5.97
137.2486877	0.12
139.1554413	0.15
140.7510681	0.12
148.8617859	1.23
149.7939148	0.81
153.1195374	0.13
157.0709839	0.27
158.1025848	4.30
159.0915222	1.69
161.1820526	0.10
162.3778687	0.07
163.3845215	0.12
165.9859619	0.24
166.8677673	0.36
175.0647888	2.35
176.2735596	0.82
177.1398621	0.18
178.1026459	0.08
179.9708557	0.22
181.1953735	0.57
182.0578156	0.20
184.0352173	1.37
185.0915222	1.23
188.9148254	0.08
190.9756622	0.09
191.9767761	0.14
193.1878510	0.81
201.1080322	4.73
202.1755371	4.78
202.9057312	0.13
207.1416016	0.48
208.1726379	0.22
209.0865784	0.07
212.2036438	3.95
223.0974426	0.43
223.9728699	0.06
225.1139526	3.08
226.2508240	4.16
227.2453003	2.88
229.6522827	0.13
230.8815308	0.15
233.6985168	0.19
238.1479797	0.27
239.0810242	0.49
240.0868225	0.63
242.3297424	7.22
243.2494507	15.48
244.2272949	2.51
245.1458740	0.97
246.1045837	2.84
249.9964905	0.21
252.1905212	0.53
259.3250122	0.07
261.1699219	0.22
263.1080017	1.59
264.1504517	9.19
265.2348022	1.69
268.2545776	100.00
270.1687927	0.34
271.0411682	1.09
272.0682983	0.07
274.9571228	0.13
276.2541504	0.45
277.0856323	0.41
278.1223755	1.21
281.0408936	2.71
282.1281433	2.57
287.1643982	0.26
288.0568848	4.34
289.0619507	7.81
289.9152527	0.66
290.9176636	1.08
296.1235046	0.48
305.0846558	5.48
306.1238708	17.46
307.1652832	19.72
308.2926636	0.36
311.3630066	0.11
314.9100342	1.48
318.1811218	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0855
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
98.0381012	0.13
110.778244	0.42
115.0349121	0.12
121.1810913	0.15
122.1201324	0.19
125.1135101	0.32
128.9849243	1.15
129.7979736	0.28
135.0612946	0.92
137.049057	0.12
141.5439301	0.25
142.8347015	0.13
147.9937592	0.23
151.0668945	9.07
152.0488281	1.84
152.9988708	0.08
154.8471222	0.50
156.1143951	0.24
166.2015839	0.20
167.056015	0.65
168.9976959	0.87
175.1346588	0.21
176.8566284	0.40
179.2638855	0.44
182.0987701	0.16
185.2285614	0.68
185.9718475	0.20
192.843277	0.48
194.0883942	1.05
194.9900055	0.34
196.9563446	0.32
198.1057129	0.92
205.5292816	1.11
206.1480255	3.86
207.5815582	0.35
208.4005585	0.65
210.0324249	0.27
211.1291046	0.74
213.0326233	0.85
218.0842133	2.42
225.1571198	2.68
226.0677338	1.44
230.7745819	0.78
235.8769073	13.56
237.078598	0.57
238.0096893	2.21
238.9985504	1.85
251.2511749	0.10
253.091507	100.00
254.2147675	5.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.1978
Annotation	(+)-Cycloolivil 4'-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
161.2186279	0.16
165.1090851	1.09
176.9825592	0.05
179.0056915	1.99
191.1498566	0.29
194.9877014	1.93
206.9708557	0.21
219.8622589	0.20
223.0342407	0.09
225.0935059	0.15
226.9646912	0.11
253.2123260	0.07
254.1442413	0.26
264.8980408	0.13
272.2381897	0.53
274.0156860	0.17
277.0886230	0.12
283.1178894	0.09
304.9465332	0.34
306.2191162	0.05
307.3647461	0.13
308.3572998	0.19
311.4144287	0.19
312.1516724	0.65
315.0479126	0.23
323.2095947	0.07
327.1753540	100.00
331.1385498	0.05
333.1284180	0.07
339.2112427	0.32
346.6600952	0.12
348.4417114	0.48
350.2926025	0.06
353.2768555	0.14
355.4387817	0.17
357.2502441	2.00
363.2787476	0.18
364.3380737	0.10
371.3823242	0.06
375.1831665	7.88
378.4646606	0.06
382.3909302	0.07
385.2180786	0.12
391.7424927	0.22
392.3850098	0.46
393.2283936	0.09
399.1809082	0.14
405.1585693	0.22
407.2640991	0.18
414.3524170	0.10
417.3024292	0.05
419.0644531	0.83
421.4848022	0.06
429.3505249	0.44
441.0644531	0.07
443.1746826	0.35
446.9383545	0.34
449.5466309	0.04
451.3467407	0.19
453.5712891	0.09
468.5920410	0.29
470.2213135	0.06
473.3571167	0.18
474.2152710	0.28
475.7819214	0.90
477.1406250	1.53
489.1744385	38.95
490.4780273	0.36
491.2777100	0.03
492.2154541	0.41
493.0034790	0.05
493.7951050	0.11
501.0845337	0.10
502.2362671	0.76
503.4052734	0.55
504.2810669	0.48
505.4119263	0.38
507.4057617	0.29
508.6698608	0.12
509.3463745	0.08
518.3046875	0.78
519.0825195	2.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	267.1334
Annotation	gamma-Glutamyltyramine
Peak:m/z	Relative Intensity
120.9730682	54.19
132.9475403	0.98
138.0738373	77.32
221.0014343	17.03
226.1566315	0.78
231.0932007	2.69
249.0211945	8.26
250.1231537	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	731.3621
Annotation	Bismurrayafoline C
Peak:m/z	Relative Intensity
267.3339539	0.08
299.1794434	0.06
315.0986328	0.05
335.0886230	0.11
368.3222046	0.12
369.4829712	0.10
375.3491821	0.13
377.1420288	0.04
400.3583374	0.23
407.3012695	0.09
415.4568481	0.32
423.0873413	0.25
425.2796021	0.09
437.2020874	0.05
445.2915649	0.05
461.2177124	0.13
472.2268677	0.54
482.5328369	0.12
503.2235718	0.07
513.2390747	0.06
514.7681274	0.42
515.4648438	2.16
525.6604614	0.14
532.3825073	0.16
533.4948730	5.20
534.6256714	0.10
549.3973389	0.10
551.1063843	0.09
552.3269653	0.07
569.1787720	0.59
573.5624390	0.13
582.1787109	0.13
608.2993164	0.10
615.1238403	0.05
629.3353882	0.05
633.3297729	0.08
639.1965942	0.03
653.4553833	0.08
658.9660034	0.21
668.2438965	0.06
677.5349731	0.19
684.4199829	0.12
686.3894043	11.12
687.3801270	3.67
688.0961304	0.05
693.2190552	0.45
694.9348755	10.61
695.5466919	100.00
697.6752930	0.22
699.8356934	0.05
701.3208618	0.40
712.4180908	0.23
713.4006348	0.33
716.6907959	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	588.9
Annotation	Unknow
Peak:m/z	Relative Intensity
245.1406250	0.07
273.0147095	1.04
273.9767151	0.46
275.1519775	0.54
276.1357422	0.08
333.5314331	0.24
361.0302124	0.24
386.9655762	0.17
387.9263916	0.32
414.3984375	0.07
427.0479736	1.46
428.1018677	1.06
429.0527344	4.27
430.3215332	0.23
430.9445801	0.23
433.9550781	0.04
443.0734863	0.17
444.1353760	0.14
456.3052368	0.06
472.9373169	1.45
474.0082397	3.11
474.9642334	4.29
500.9816895	0.27
502.6043091	0.06
503.8096924	0.20
505.0963135	0.08
511.7847900	0.08
517.3650513	0.08
532.8313599	0.19
541.9113159	73.00
542.8278809	100.00
543.8358765	0.16
557.9700317	0.10
560.6757812	0.40
578.8751221	0.15
587.9947510	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	472.92
Annotation	Unknow
Peak:m/z	Relative Intensity
199.1522827	0.03
201.1530457	0.06
245.1825562	0.15
344.3389893	0.02
357.2318115	0.12
358.3166504	0.32
359.2001343	0.11
386.8500671	0.03
399.1508789	0.06
408.4255066	0.04
416.9670105	0.16
426.9953613	100.00
428.9424744	0.88
429.8680115	0.02
433.5473328	0.08
445.0082703	0.11
449.5140076	0.05
454.4522400	0.03
455.4293823	0.09
457.3464661	0.06
463.4954529	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	238.0213
Annotation	Unknow
Peak:m/z	Relative Intensity
72.9438858	0.20
85.9677734	0.05
86.9366379	0.10
116.9915466	18.61
119.9070892	54.47
126.0405273	0.04
129.0060577	0.05
133.2021790	0.04
137.1348877	0.04
146.0453644	0.08
147.1785889	0.11
151.0684814	1.83
154.1023102	0.05
160.0036469	0.11
163.8573608	0.05
167.3745270	0.02
168.0443726	0.06
170.0228271	0.14
174.2086334	0.05
177.2388458	0.02
189.9887848	0.02
193.0733337	0.13
194.0443573	0.12
203.9783936	100.00
208.0714111	0.03
208.9957733	0.05
210.1167755	0.06
220.1727142	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	649.0318
Annotation	Unknow
Peak:m/z	Relative Intensity
195.0908813	0.27
205.8735809	0.17
214.1264954	0.10
217.0574646	0.16
223.0707397	0.30
234.9709015	0.33
240.9065094	2.76
247.1366577	0.48
258.9361267	1.74
265.0371094	0.60
278.2341614	0.24
279.2093811	0.13
295.1481934	0.73
307.3058777	15.18
308.2636719	1.16
318.8077393	1.82
319.9724731	0.39
325.1406860	0.19
331.0698242	1.30
336.8234253	5.24
339.2384033	0.74
340.2677612	0.27
341.3270264	0.23
345.1273193	0.16
346.9642944	0.24
349.0490723	3.66
355.1307983	1.43
360.6406860	0.37
366.8749390	0.57
373.2113647	0.34
378.9627075	0.80
383.3771362	0.84
390.4106445	3.54
391.0300293	16.03
396.8853149	9.71
408.9402466	100.00
421.1176147	0.62
426.9073486	32.66
427.5108032	0.35
433.0462036	0.66
439.1145020	5.45
452.5684814	0.25
453.5113525	1.49
457.0146484	0.75
462.0855103	1.79
462.9063721	0.61
466.2597656	0.92
468.9270020	0.37
476.8919678	0.17
481.1392822	1.99
484.9340820	0.49
486.7874146	6.21
490.1430664	0.28
491.3247070	0.25
492.6405029	2.28
496.8435669	0.59
498.8663330	3.32
516.5248413	0.82
528.4066772	0.36
529.0444946	0.68
529.7754517	1.44
536.0708008	0.56
541.1218872	1.41
552.7326660	1.31
558.6954346	14.55
559.3938599	0.50
571.2263794	1.90
573.9364014	0.57
576.6242065	2.77
581.1445923	0.28
582.5547485	1.48
583.2238770	1.06
588.8925171	27.85
589.9374390	0.95
594.8079224	0.86
600.3097534	0.65
600.9537964	0.23
602.4422607	0.31
604.9544067	0.72
610.0982666	0.67
612.9688721	3.88
613.5928955	0.11
630.4048462	12.29
631.1030884	8.50
640.3887329	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	614.74
Annotation	Unknow
Peak:m/z	Relative Intensity
347.6345825	0.08
356.1998291	0.54
384.9522095	0.28
385.8750000	0.50
386.5139771	0.26
387.3656616	0.85
403.6876221	0.14
453.0998535	0.45
454.3201904	0.26
455.0675659	0.63
456.1712036	0.34
467.9557495	0.08
469.7915039	0.14
498.0806274	0.72
499.0450439	1.63
499.9035034	1.17
501.0713501	0.64
516.8025513	0.99
518.0384521	0.40
519.1723022	0.12
528.9750366	0.15
538.6874390	0.31
540.3638306	0.58
541.0304565	1.11
542.0073242	0.16
556.8141479	0.52
558.0764771	0.10
565.5901489	0.25
566.9904175	7.29
567.9087524	100.00
568.8540039	93.37
569.4633179	1.43
571.3314819	0.17
573.5304565	0.55
584.2623291	8.17
585.2932739	33.70
586.4223022	25.82
587.8251953	1.78
588.5078125	0.67
589.1911621	0.29
591.0938721	0.24
592.0172729	0.42
596.8578491	0.54
605.1137695	0.08
614.0256958	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	404.9498
Annotation	Unknow
Peak:m/z	Relative Intensity
127.8803864	0.06
138.9557495	0.54
146.1624451	0.03
177.0164795	2.05
183.0359497	0.21
194.8449249	0.03
199.0995483	0.02
200.8957977	0.03
220.9102020	100.00
221.7651367	0.02
239.1478271	0.04
254.9798889	0.03
257.2066956	0.10
271.8990173	0.07
275.1210327	0.04
292.3911743	0.01
305.1380005	0.01
306.1542053	0.07
306.9571533	0.07
314.2502441	0.02
316.9877319	0.79
318.7899170	0.01
319.4216309	0.01
335.0465088	0.02
348.2835083	0.05
356.2851257	0.02
358.3273621	0.04
359.1503601	0.04
361.0188904	0.88
368.0802917	0.03
369.7145081	0.03
374.1219177	0.02
383.1069031	0.01
386.2322693	0.09
387.1298218	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.2181
Annotation	Excavatolide D
Peak:m/z	Relative Intensity
161.1981812	0.05
163.0937958	0.02
193.2073212	0.01
196.9196320	0.02
199.1363068	0.06
209.2838745	0.01
222.8977966	0.02
227.0921783	0.01
245.0740051	0.01
247.2874756	0.01
273.2216187	0.03
281.0049438	0.04
299.1738586	0.03
329.3536987	0.04
330.2847290	0.06
331.0847168	0.01
343.3833008	0.02
346.4275513	0.01
347.2096558	0.04
347.9143066	0.01
356.2061157	0.01
357.3220215	0.02
359.2490845	0.05
361.2561035	100.00
375.2865601	0.01
379.4703369	0.02
391.3700562	0.02
403.3484497	0.18
427.4218140	0.05
431.6367798	0.04
435.2558594	0.04
449.4808960	0.01
451.5417480	0.02
462.4504395	0.01
463.2069702	0.02
477.1933594	0.13
478.6624146	0.04
479.4183960	0.02
489.1222534	0.03
489.8624268	0.01
492.3554077	0.01
493.3223267	0.02
502.3223267	0.01
503.1812744	0.02
504.0772095	0.06
505.2669067	0.16
513.3742676	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	402.9168
Annotation	Unknow
Peak:m/z	Relative Intensity
126.9533844	0.02
133.0103607	0.04
158.9958496	0.14
159.9206238	0.05
174.9931030	0.50
212.1595612	0.02
237.8068848	0.06
238.4250793	0.02
241.1764526	0.02
242.8035278	0.06
243.9017639	0.05
244.9963379	0.31
246.6373596	0.03
249.0977478	0.12
256.3877563	0.22
272.1002502	0.15
273.0592041	3.95
274.2854004	0.09
275.1653748	0.03
286.0268555	0.05
286.9967346	0.30
288.9938354	100.00
291.1795654	0.03
298.1302795	0.05
313.8769531	0.20
315.2668762	0.07
325.1505737	0.04
329.1064453	0.23
330.4840698	0.04
339.3948669	0.04
347.2328186	0.07
353.8964233	0.03
356.2866516	0.69
357.0062561	0.55
358.3164978	0.61
359.0279846	0.38
360.7007141	0.14
366.1430359	0.03
367.2737732	0.02
370.9490051	0.04
373.2895508	0.20
374.8406982	0.12
376.7377319	0.14
384.4257812	0.56
385.1556702	0.88
403.0580750	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	663.0472
Annotation	Dictazoline A
Peak:m/z	Relative Intensity
193.2151489	0.19
197.2622681	0.07
207.9502106	0.11
210.9615784	2.03
212.0531158	0.31
216.9483795	0.04
218.6032410	0.11
221.0720825	0.05
232.0940704	0.06
235.1096497	1.65
236.1162109	0.32
252.1415558	0.17
254.1223145	0.15
272.1577454	1.03
273.1216431	0.97
279.0459900	0.21
280.1906738	0.91
281.1702881	0.09
291.0767822	1.04
291.9677734	0.14
297.2558899	0.08
300.0948486	0.06
305.0006714	3.19
306.2257080	0.64
309.2705688	0.20
317.0676880	0.14
320.9415283	0.11
323.0506592	100.00
324.0874023	13.11
328.0609436	0.04
334.2753296	0.04
335.2957764	0.08
338.0906982	4.62
339.1174927	4.58
340.0778198	0.72
346.1493530	0.35
357.1464233	0.06
358.8981934	0.08
360.2211304	0.04
377.3614502	0.07
385.0803223	2.48
386.2123413	0.51
389.3504639	0.05
397.1699219	0.92
400.2337036	0.09
403.0391235	66.94
404.1313477	9.39
408.0924072	0.67
415.0343628	0.12
419.1721802	0.16
420.0281982	0.09
426.2805176	0.06
455.1189575	0.09
456.3780518	0.19
461.2548218	0.24
470.2138672	0.09
479.2705078	0.16
481.0955200	0.05
484.4903564	0.08
492.2107544	0.13
493.8567505	0.07
497.1131592	0.17
499.2536621	0.13
500.3411255	0.44
501.3299561	0.21
522.4831543	0.12
524.2850952	0.17
529.0818481	0.13
530.0687866	4.71
533.4423218	0.13
542.3571167	0.30
543.1705933	0.28
544.3084106	0.04
548.1565552	0.09
559.1835327	0.26
565.3218384	0.52
566.3601685	0.42
568.2078857	0.11
570.2717896	0.04
572.2343140	0.07
584.2014771	1.01
584.8536987	0.10
600.4634399	0.38
603.1262207	5.60
604.0685425	1.13
619.4467773	0.05
626.8385620	0.06
645.1383057	0.71
646.0656738	0.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	319.1
Annotation	Antibiotic CJ 12371
Peak:m/z	Relative Intensity
100.9529572	0.11
109.9868393	0.12
112.9196472	0.19
118.8822479	0.88
121.0492401	0.12
124.2147751	0.29
126.0659485	0.04
127.9845734	7.89
130.9645081	0.25
132.1138000	0.05
139.8770752	0.07
142.0557098	1.20
142.8284302	0.03
146.0561218	1.03
148.0633240	1.16
156.2458801	0.06
157.0827332	0.08
161.0932465	1.47
163.0510864	0.13
172.1036377	0.08
179.0139923	0.07
187.2311859	1.14
190.1170959	30.77
191.1618805	0.13
193.0777283	0.10
199.0918579	0.78
202.9447174	0.16
205.2887878	0.04
207.2181396	1.60
208.0620117	0.05
208.7508545	0.05
213.1336975	0.34
215.1139221	0.12
217.1082458	0.25
220.0054932	0.04
220.7974854	0.04
222.0475464	0.03
222.9297791	0.05
231.0572815	0.16
239.4299927	0.07
241.1285095	100.00
242.0673218	0.13
245.2965393	0.03
246.4513245	0.08
247.0676270	0.24
251.1252747	4.88
254.0220337	1.65
255.2014771	17.61
256.2776489	0.05
257.3131409	0.08
259.2276917	0.63
263.0473328	2.85
268.0558777	0.68
273.1623535	17.38
275.1068420	3.64
275.8038330	0.10
280.9492188	2.03
283.1803589	0.47
285.1467590	7.89
286.4041748	0.10
288.2142944	0.79
301.0280151	5.49
302.1595459	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	209.0667
Annotation	Sedoheptulose
Peak:m/z	Relative Intensity
68.9267120	0.43
70.9012299	0.80
73.0628967	0.09
82.9757919	1.05
84.9319763	10.28
86.8839264	13.11
88.9053955	1.24
97.0124359	3.25
98.9954071	4.83
101.0398865	0.27
110.9083557	11.73
112.0655518	0.06
112.8975525	0.20
113.5136566	0.11
114.9192200	2.85
116.9333496	0.03
128.9174347	100.00
129.6724243	0.04
130.9088287	0.24
132.0719604	0.09
141.0170441	8.43
143.5890045	0.08
144.5242310	0.20
145.1907196	0.12
158.9392548	49.56
162.8425140	0.50
165.1501465	0.78
173.0558929	0.07
175.1876984	0.09
177.1345825	1.04
190.9904175	2.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
129.8809509	0.24
143.1246643	0.36
148.8890381	0.47
155.019989	0.29
173.0564728	0.59
183.2537994	0.31
183.9620361	0.39
185.2316132	0.86
187.0879974	0.83
213.2646179	0.41
215.3793945	1.42
216.9185791	0.33
217.5775146	0.47
223.2411194	0.63
227.3766174	0.28
229.1035156	1.48
243.1570435	3.72
245.1850586	1.27
247.1904907	0.56
253.4190979	0.27
255.2497864	3.38
257.0745239	1.73
258.153595	0.49
259.9678345	0.57
261.1334839	0.41
263.3453064	1.30
267.498291	1.34
269.1479797	1.15
271.1650391	4.25
277.5300903	1.75
283.1471863	1.28
285.3435364	3.35
287.4485779	0.38
288.1305237	0.66
289.105896	0.40
295.3783569	3.80
296.2290344	0.53
297.2728271	3.92
299.3209534	4.60
300.0487976	0.68
301.5458069	0.96
309.426178	0.24
311.0291138	1.11
313.1643677	2.67
313.8054504	0.26
315.2203064	0.78
319.2261353	0.73
321.2663574	2.95
321.9585571	1.57
323.2712708	9.16
325.0958557	1.00
327.257843	0.50
329.2137756	0.26
333.0853577	0.49
337.1802368	0.35
339.24646	100.00
340.3709412	2.33
341.3520508	13.78
342.2047424	0.42
347.0354614	0.74
356.9765015	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	230.99
Annotation	Unknow
Peak:m/z	Relative Intensity
101.1614990	0.75
106.1312866	1.16
114.0247345	2.64
114.9719086	0.21
115.8746796	6.11
122.4282837	0.42
124.1097107	3.15
124.9841309	1.64
129.8424835	0.87
135.0310669	0.88
142.0618134	6.14
143.0814056	13.33
143.9475403	1.10
148.0563812	0.36
151.9760284	0.47
167.0023956	0.21
169.4565887	1.42
170.3233490	0.49
171.0831451	4.39
184.1241455	0.92
185.1065216	10.02
186.9400787	0.67
189.3863831	0.65
190.0623627	0.73
191.0942535	0.47
194.0147858	0.49
195.0544128	12.17
196.0411530	11.72
196.7436981	0.43
198.7234955	0.23
202.9166718	1.16
204.8849335	1.13
212.9481354	100.00
214.0974274	12.43
215.0594330	0.29
216.3119659	0.27
221.9399261	1.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	931.1563
Annotation	Unknow
Peak:m/z	Relative Intensity
307.1836853	1.95
313.9800415	0.66
332.2416382	0.56
380.2695923	0.78
425.3826904	0.43
474.1876221	0.50
492.4394531	0.44
584.0536499	0.35
598.1257935	0.37
615.6274414	0.31
619.1010132	0.31
620.3248901	1.11
653.2875977	0.48
709.0430298	0.31
716.1773682	0.49
720.9575195	0.33
733.2873535	0.46
757.8031616	0.82
758.4825439	0.35
767.4976807	0.56
769.1901245	36.15
776.3562622	0.22
779.0814819	0.41
781.1865845	1.33
783.5188599	0.14
793.3103638	0.33
799.7905884	0.50
805.4854126	0.29
811.1488647	6.97
835.3402100	0.78
836.3592529	1.50
837.3455811	0.22
841.3505859	4.59
842.2839966	1.38
850.5364380	1.53
853.3927002	2.35
865.2883301	1.83
871.3251343	100.00
872.2074585	1.56
877.3889160	0.79
878.2275391	5.12
883.3291016	1.09
887.4258423	0.22
895.1181030	8.22
896.1248779	6.08
896.9746094	0.96
913.1835327	35.38
913.8427124	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	349.1865
Annotation	Sachaloside VII
Peak:m/z	Relative Intensity
101.0516510	1.11
101.9711304	0.03
104.9860840	0.02
111.9365158	0.02
113.0856934	1.71
114.1164474	0.06
115.1759491	0.05
119.0176773	0.98
120.0712280	0.04
124.9762878	0.05
126.0796738	0.01
129.0311127	0.02
130.8866272	0.38
132.0321655	0.02
137.0226593	0.08
139.1221008	0.13
141.0908508	6.49
142.2068024	0.71
143.0641327	0.48
144.0641632	0.08
147.1212921	0.02
148.9805450	0.18
149.6236877	0.04
151.1395721	0.02
152.8498383	0.01
155.1059265	0.07
156.3451843	0.09
157.1585541	0.10
159.2541809	0.02
161.0799866	0.45
162.2758484	0.03
169.1182556	2.28
170.2229309	0.30
171.2424927	0.94
172.1349945	0.15
173.1588135	0.02
175.2407379	0.01
175.9189453	0.03
178.9693909	0.64
183.1932526	2.07
184.2587433	0.36
185.0715790	0.45
187.1224060	100.00
188.1953125	12.19
194.0951538	0.03
195.3429565	0.02
199.2483978	0.07
200.4140625	0.14
201.0769958	0.28
202.0695801	0.07
211.1941223	0.23
212.1599426	0.05
217.9938049	0.02
222.9724121	0.03
224.9506531	0.03
229.2381287	4.41
230.1922913	0.64
237.1321106	0.02
241.2168579	0.58
242.2962036	0.07
243.0433350	0.03
244.1604614	0.04
247.0169678	0.01
253.8512268	0.02
255.2121887	0.08
259.2525635	0.33
260.3800659	0.03
268.1777954	0.02
270.7319641	0.04
272.0652466	0.12
273.8387451	0.02
283.3598938	0.07
289.1654663	0.07
293.0274048	0.01
295.2125854	0.06
303.2664490	0.03
305.1745911	0.10
305.9887085	0.05
307.8441467	0.02
309.0545044	0.02
312.0917664	0.03
313.0848694	0.03
314.1137695	0.76
315.1370239	0.04
320.1105347	0.03
322.3487244	0.02
329.5247803	0.09
331.2852783	0.22
332.1357422	0.07
333.0524292	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	277.0321
Annotation	Unknow
Peak:m/z	Relative Intensity
116.0545044	0.37
126.0065918	0.28
127.0057526	1.11
128.0973358	0.30
144.0928955	0.26
145.0876465	4.21
145.8185272	0.03
147.1443176	0.16
153.0631409	0.40
157.0468597	0.07
168.9218445	0.04
171.0397491	0.43
179.1491089	0.13
181.2517242	0.14
187.1718750	0.46
190.6395264	0.26
193.1249695	0.43
195.1357422	0.31
196.9098206	0.03
199.0429993	0.50
208.9442444	0.14
213.1805725	100.00
215.1185303	0.13
215.9813232	0.06
217.1091614	0.27
225.1181641	9.27
226.0958252	0.19
231.0734558	79.56
233.0634155	0.12
233.8747864	0.04
241.1279297	0.05
243.0999146	57.36
259.0292053	28.06
260.1760254	0.88
262.2826538	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	441.1977
Annotation	Unknow
Peak:m/z	Relative Intensity
154.1070099	0.02
165.0232697	0.03
175.9308472	0.01
185.0141907	0.03
213.0013733	0.02
216.1190491	0.02
228.9839935	0.03
232.9484558	0.02
235.4601288	0.01
247.1318054	0.03
249.1807861	0.28
250.8515625	0.03
259.2980042	0.03
277.3138733	0.04
278.2869873	0.02
279.1455688	0.19
285.1446228	0.04
293.8958740	0.04
299.2102661	0.04
304.1392517	0.02
308.7877808	0.02
312.1846313	0.05
320.9763184	0.02
323.2308960	0.02
325.3704834	0.02
326.6372070	0.02
331.6250305	0.04
336.2402039	0.01
343.3493347	0.01
345.1914062	0.03
348.9819946	0.04
350.1571350	0.02
363.7935791	0.02
378.3932495	0.06
385.2919006	0.01
395.2161560	100.00
396.0916138	0.01
397.1876221	0.01
401.8121643	0.03
402.9681091	0.07
403.8725281	0.03
405.0836182	0.03
406.1189575	0.02
421.2207947	0.04
422.2535095	0.09
423.3744812	0.20
424.5146790	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
64.44149017	10.05
94.90553284	6.40
104.9801636	2.26
109.1699982	4.32
114.9771576	3.93
118.8958893	3.44
121.2055054	1.41
129.1066437	9.68
129.8056793	3.27
132.993576	4.01
147.0750885	3.56
149.2644043	8.11
150.9824677	100.00
152.0791016	11.44
155.0372467	1.15
161.1912079	2.07
164.8729401	5.10
167.1012421	7.92
174.9695587	2.20
178.1365509	1.31
179.4159241	3.53
181.8413696	5.76
183.1060638	5.03
185.2241669	2.48
186.1563873	1.68
190.876358	7.24
197.0395813	11.43
211.1470184	1.71
217.2414246	4.39
217.9508972	4.58
225.2271271	26.31
235.2736664	31.41
238.0528564	16.35
253.0884552	72.12
254.2391815	17.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	675.2639
Annotation	Unknow
Peak:m/z	Relative Intensity
279.2307129	0.13
343.1535645	0.12
359.3250122	0.07
382.3082275	0.15
397.5223389	0.30
414.3204956	0.07
449.3853149	0.08
467.7736816	0.15
497.3183594	1.46
498.2926636	0.80
499.4624023	0.98
504.1878052	0.19
508.5341797	0.08
511.2921143	0.19
512.1698608	0.16
514.3806763	0.16
516.2730103	0.45
517.4788208	0.05
528.2655640	0.95
530.2306519	0.13
539.3897095	0.55
542.0736694	0.27
549.3115845	0.08
553.3037720	0.20
556.2638550	2.23
557.3641968	6.40
558.3560791	2.93
559.2156982	0.83
569.1446533	0.09
570.5529175	0.84
571.2519531	0.49
572.1182251	0.92
572.8146362	0.30
573.5250244	0.07
580.2656860	0.06
585.3652954	0.73
586.0994263	0.44
587.1751099	0.17
587.9197388	0.08
589.3054199	0.82
590.4411011	0.47
591.1701660	0.42
597.3919678	0.11
600.5003662	0.10
601.4856567	0.30
602.3781128	0.15
611.1832886	0.32
613.3419800	0.52
614.5290527	1.21
616.2722168	8.66
617.3765869	4.22
618.3850708	3.27
619.5061646	0.19
625.2772217	0.23
626.4413452	0.08
629.2764282	0.39
630.3843384	1.76
631.3073730	0.66
632.3977051	0.40
633.4234009	0.26
643.3776245	38.02
644.4090576	100.00
645.3890991	94.21
646.3806763	30.90
647.3866577	3.15
648.6673584	0.19
649.4028931	0.27
657.3783569	78.30
658.3587036	64.87
659.4112549	18.19
660.2656860	0.32
661.4078369	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	272.96
Annotation	Ribose-1-arsenate
Peak:m/z	Relative Intensity
114.9316330	5.28
131.0099182	0.31
158.9304657	100.00
159.6990356	0.02
198.9164734	2.07
201.0872192	0.01
216.9488525	0.80
228.9056396	25.02
229.5088501	0.05
245.0707092	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2877
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
141.0555267	4.51
149.1832886	8.14
169.1297607	2.96
174.1922302	3.55
189.2529907	3.74
197.0421143	6.90
199.257843	5.32
214.0941772	3.55
225.1965942	5.09
227.2508087	2.78
234.3826904	6.39
244.9755554	8.35
249.3544312	5.86
254.9606018	5.63
263.3012695	8.51
268.2411499	4.51
281.0518799	26.78
282.3544922	6.39
290.0780029	12.04
300.2111816	2.93
314.0542603	8.74
315.1098938	4.72
328.2008667	18.39
332.3996582	1.82
335.1279602	2.00
339.3656311	11.21
344.5460205	5.24
346.1846619	7.82
356.1155396	6.05
358.1767578	2.79
363.0579529	3.16
365.3639221	27.93
366.2895203	30.86
367.0809631	6.21
368.7929993	14.64
370.0971985	2.59
372.6947327	6.38
380.4295959	3.91
381.2401428	9.18
385.0967102	2.39
389.3866272	5.05
390.8216858	34.10
394.8840637	5.74
398.3406677	6.12
403.1416626	7.53
406.945343	9.74
408.2742004	100.00
409.2549133	23.56
426.1114807	9.04
427.4900513	4.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	639.28
Annotation	Cryptophycin 46
Peak:m/z	Relative Intensity
205.0422058	0.08
219.2217560	0.15
247.0152588	0.22
248.9700012	0.07
252.0956573	0.13
254.4045868	0.16
275.0990601	0.11
278.7259521	0.07
284.2597046	0.05
294.1420593	0.14
316.9570923	0.26
325.2283936	0.08
351.2052002	0.21
359.1080322	0.11
364.2916260	0.19
367.6243286	0.03
369.2573242	0.80
370.3679199	0.09
371.3251953	0.30
373.1943359	0.28
380.0189209	0.09
383.3543701	0.16
384.1918335	0.31
386.3514404	0.25
387.2661743	1.04
389.2703857	1.43
397.6081543	0.18
400.2408447	0.12
406.1497803	0.14
407.1194458	0.35
418.4746094	0.54
421.5153809	0.29
423.6185303	0.51
426.3177490	0.16
427.2653198	0.50
430.1126099	0.31
436.4283447	1.06
440.2198486	0.26
441.4968872	0.12
444.5360107	0.22
451.2844849	0.45
456.2548828	0.26
463.2520752	0.14
464.4245605	1.35
465.2998047	0.22
470.2868042	0.62
472.5268555	0.22
479.4578247	0.27
481.6950684	0.41
483.6095581	0.20
485.3000488	0.10
491.4060669	3.53
492.4368896	0.87
493.4901733	0.22
497.3654175	0.84
498.2518311	0.57
505.2559814	0.19
507.5664673	0.10
509.5555420	0.50
511.4236450	0.12
514.5164185	0.28
517.0518188	0.25
519.3671265	1.22
522.1248779	3.52
523.3901978	1.77
524.3648682	0.25
525.1675415	0.46
527.4571533	0.21
529.3229980	0.09
530.0384521	0.09
533.2632446	0.78
534.3739624	0.08
535.3423462	0.74
537.3778076	1.02
538.2956543	0.64
541.2200317	0.17
542.3988647	0.11
544.1667480	0.26
547.2347412	0.68
548.5178833	0.17
549.2400513	0.59
550.4124756	3.10
551.3523560	9.77
552.3512573	2.98
553.3040161	0.69
556.7536011	0.10
560.2921753	0.09
561.4115601	4.45
562.4907227	1.50
563.4422607	1.05
564.4685669	1.36
565.3392944	0.57
566.3164673	0.24
567.2418823	0.12
571.4572144	0.07
575.6019287	0.35
577.7312012	0.76
579.3278809	100.00
580.4213257	12.59
581.9777222	0.33
582.6492920	0.24
583.3615723	1.34
587.5624390	0.45
589.2362671	1.13
590.3350830	0.24
591.4741211	1.20
592.4572144	1.43
593.4776001	0.89
594.3119507	0.63
595.5842285	1.43
596.3234863	3.08
597.4019165	3.21
598.3586426	0.48
603.2449951	0.48
606.4707642	7.82
607.3750610	13.36
608.2910156	0.88
609.4149170	9.73
610.3855591	24.56
611.3606567	12.12
612.4589233	0.69
621.3367310	62.90
622.4010620	8.39
623.4154663	7.86
624.3423462	35.44
625.4592896	2.85
END