#DEFINITION	Reference Metabolome for Abelmoschus esculentus
#IDENTTFIER	RefMeta-Abelmoschus esculentus.R1
#FORMAT	msr
#VERSION	1.0/R1
#KEYWORDS	RefMeta
#ORGANISM	Abelmoschus esculentus
#CREATION	31-MAY-2024
#PUBLICATION	CropMetabolome: a comprehensive metabolome database for major crops cross eight categories
#JOURNAL	The Plant Journal
#AUTHORS	Shi H, Wu X, Zhu Y, Chen P, Xu X, and Li X.
#COMMENT	Reference metabolome for Abelmoschus esculentus was generated from multi-tissue LC-MS/MS data with redundance removed
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	344.0808
Annotation	p-Hydroxybenzyldesulphoglucosinolate
Peak:m/z	Relative Intensity
99.8783112	0.03
100.7558899	0.02
102.1021347	0.10
112.9864883	0.04
118.8379898	0.08
119.9201050	13.87
127.2368011	0.05
127.9569702	0.15
133.1183167	0.05
138.2160339	0.27
141.1925964	0.03
143.2316895	0.06
145.0593872	0.03
148.6886292	0.03
149.9511871	0.69
153.1478271	0.06
156.1030579	0.02
159.9095459	0.17
161.1171875	0.12
164.0757294	0.24
167.0781555	0.10
177.1896515	0.04
179.0536346	0.11
180.0820312	0.07
180.9554901	0.44
182.1462708	0.35
183.0282288	0.04
184.0308838	0.02
197.1755676	0.16
203.1905365	0.14
205.9367676	0.02
207.1848145	0.11
208.0750427	0.51
209.1739197	0.27
211.1797791	0.16
212.1798706	0.40
213.0387573	0.15
215.0603943	0.07
223.0365906	100.00
224.8973999	0.04
227.2919006	0.11
228.3597717	0.04
229.2539673	0.08
231.2145691	0.03
235.1685791	0.27
237.1837463	0.03
239.1125488	0.07
240.1869812	0.26
246.0516052	0.05
250.2208557	0.25
252.0975342	0.06
254.0847168	0.08
260.3907471	0.07
265.4898071	0.15
266.1718140	0.78
269.0665894	0.77
274.0428467	0.11
277.1238403	0.03
281.7409363	0.05
283.2113953	0.11
291.2952271	0.17
292.1398315	0.09
297.0286255	0.04
298.2681885	0.44
299.0839844	0.14
300.2587585	0.41
307.3539734	0.05
308.2872314	0.03
310.1396484	4.21
314.1215820	0.02
315.1289673	0.09
316.0746765	0.05
323.3189697	0.18
325.1559448	0.44
326.1099548	0.90
327.1477966	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.0476
Annotation	UDP-D-galactose
Peak:m/z	Relative Intensity
159.1435242	0.05
164.1621094	0.05
175.0873718	0.03
176.9705811	0.03
182.1074219	0.02
193.0996399	0.05
210.9864044	2.81
225.1699066	0.06
241.0333557	1.38
261.890564	0.03
273.0632935	0.02
280.0708618	0.60
303.2658081	0.04
305.1733398	0.16
321.1368408	0.73
323.0379028	100.00
323.8406982	0.01
325.4610596	0.05
350.2407837	0.01
385.1026611	2.01
391.2313232	0.02
403.1547852	2.56
409.3618774	0.25
410.22052	0.14
452.814209	0.04
467.3331909	0.11
518.1306152	0.18
519.213562	0.04
520.2909546	0.02
521.1699219	0.05
522.0710449	0.02
547.1412354	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.2814
Annotation	Dictamnoside G
Peak:m/z	Relative Intensity
179.0142517	0.23
185.0575256	0.21
191.0405273	2.28
209.2482605	0.29
213.2225800	0.11
218.0166016	0.04
223.0057831	0.07
227.1581421	0.06
233.8166504	0.15
237.3083649	0.17
254.1266937	0.07
255.2402954	0.30
257.1160889	0.14
270.9202271	0.09
281.3513794	0.17
283.1098938	0.15
284.1224365	5.36
285.0463257	1.20
295.4049683	0.22
301.4539185	0.16
305.1723022	0.30
305.9097290	0.13
307.1740112	0.06
309.3743286	0.35
317.1682129	0.20
319.3026123	0.25
327.2930908	0.49
328.3059692	0.19
329.2680054	0.11
341.3056030	0.48
343.4152832	0.09
352.2184448	0.05
353.2332153	0.17
357.1775513	0.15
361.0138550	0.21
365.5101318	0.06
369.1709595	0.18
383.3038940	0.70
389.4378052	0.22
393.2957153	0.26
394.0924683	0.07
399.4785767	0.06
409.1224365	0.22
411.2561035	0.68
413.3814087	0.24
415.1343994	0.25
417.6912842	0.14
422.5046997	0.11
423.3839111	0.09
429.2066040	4.71
430.2163086	0.35
431.2820435	1.01
437.9943237	0.10
439.2208252	0.08
447.2965088	1.46
460.2788086	0.06
463.1361694	0.08
467.2280884	0.29
472.2948608	0.24
473.3416138	0.49
485.3046265	0.13
486.8461914	0.07
491.3820801	0.34
495.3558350	0.47
496.2243042	0.35
497.3308105	0.05
507.1618652	0.06
508.9895020	0.37
517.4182129	0.08
519.3327026	0.06
525.3338013	0.26
531.2182617	0.43
533.1879272	0.08
534.4583130	0.14
535.3261108	0.15
545.6730347	0.12
547.3127441	100.00
548.6750488	0.73
549.3834839	0.89
550.2084351	0.57
555.2849121	0.31
557.5108643	0.28
560.3910522	0.17
562.3808594	0.55
563.2356567	0.57
563.9519653	0.11
570.7766113	0.69
571.4360962	0.38
574.2704468	0.84
575.4233398	1.84
576.4224854	0.10
578.1224365	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	613.16
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
199.1592102	0.06
209.0002289	0.32
210.3362122	0.05
211.0484619	0.21
231.0735779	0.23
235.1455078	0.17
256.0236816	0.30
261.8362427	0.12
262.9484558	0.07
274.1262207	0.07
279.9609375	0.02
287.2246399	0.06
288.2721558	0.34
290.2887573	0.05
298.0697937	0.04
299.2157593	0.02
307.1511536	0.08
308.2903748	0.13
309.0924683	0.07
317.2192383	0.05
318.2124634	0.01
321.0478516	0.05
322.1567383	0.19
323.1126099	0.01
337.1324463	0.27
338.0006714	0.15
340.3593750	0.08
341.2298584	0.02
347.8576050	0.15
355.1146851	57.54
355.7637329	0.12
357.8095703	0.03
361.0083008	0.01
367.3276978	0.04
377.2902832	0.07
380.3490601	0.01
391.0383301	0.12
409.2684937	3.30
419.9925537	0.12
421.1103516	0.17
425.9424438	0.04
427.3782959	0.11
430.9146118	0.12
438.2064209	0.03
443.0328979	0.14
444.6466064	0.32
445.2827148	0.04
466.2711792	4.76
467.4926147	0.01
471.3518677	0.06
480.4344482	0.12
481.2659912	0.07
482.0324707	0.03
484.1606445	100.00
484.7709351	0.38
497.0765991	0.02
511.7335815	0.02
520.2605591	0.18
528.3776855	0.06
538.2576294	2.44
550.4739990	0.02
577.4153442	0.07
578.5482788	0.04
595.2854614	19.79
596.5612793	0.04
603.7443848	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.093
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
145.3622284	0.19
146.1430664	0.06
147.2025452	0.13
151.0635986	3.07
152.1706848	0.03
152.9799500	0.90
156.9657288	0.04
161.0022278	0.35
162.9131317	0.32
164.1936035	0.04
165.0622101	0.11
168.9963989	0.30
171.0788422	0.09
173.0532532	0.03
173.9891968	0.78
175.1234741	0.35
178.9328308	1.66
179.9959106	0.06
180.9805145	0.12
183.1510925	0.05
185.0705719	0.30
186.1404114	0.08
187.0544128	0.42
189.8750305	0.06
190.6806641	0.08
191.8793335	0.22
193.0883179	0.20
199.0584106	0.07
201.0799255	0.13
203.0805054	0.21
205.1103210	0.28
209.0464172	0.08
211.2023010	0.04
213.1387482	0.28
215.1054993	0.28
217.1964417	0.11
219.4228821	0.18
225.0743713	0.18
227.0905457	2.15
228.1066437	0.19
229.2854004	0.24
231.2598724	0.34
237.1375580	0.18
239.0057373	0.65
240.2344360	0.18
241.0650024	0.32
243.0700684	2.75
246.2430115	0.17
248.8917236	0.06
251.3979187	0.06
252.1910400	0.03
253.3128662	0.27
255.1242676	13.58
256.1018982	1.88
257.2214355	1.83
259.1729431	0.85
261.2608337	0.14
263.1395569	0.03
264.1475220	0.06
265.0298462	0.18
266.2605896	0.11
267.2766113	0.24
269.1870422	1.39
271.1105042	0.26
274.3609009	0.11
275.0995178	0.02
279.1966858	0.12
281.2100830	0.45
284.0563965	96.07
285.0606689	100.00
286.1424255	1.05
293.1975403	0.21
295.2489319	0.07
295.9514771	0.12
297.0895996	0.64
297.9235840	0.12
299.1347351	3.06
300.1616211	0.08
301.2922363	0.32
302.1165466	0.27
307.2698059	0.31
309.0821838	0.40
311.2346802	0.36
313.3038025	0.30
314.1549072	0.15
317.5014038	0.07
325.2440186	0.31
325.9156494	0.13
327.1865540	21.97
328.1936035	0.05
351.1139221	0.08
353.9879761	0.03
357.0639038	2.22
367.3782959	0.07
380.2712402	0.05
381.2203674	0.15
383.1190491	0.24
386.6042786	0.05
388.4785156	0.03
393.4283752	0.06
399.4664917	0.21
400.9191284	0.13
402.1777039	0.24
403.4471130	0.04
405.2384644	0.11
411.1131897	0.06
414.2087402	0.08
417.0718079	0.07
419.3071594	1.68
420.1539612	0.14
428.6264038	0.15
429.3645020	0.14
432.4025574	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	615.9
Annotation	Unknow
Peak:m/z	Relative Intensity
198.8810425	0.04
200.1888275	0.01
217.2458038	0.03
218.0656433	0.06
229.0650330	0.16
230.0743103	0.06
273.0074158	8.48
273.9604797	2.47
385.1104126	0.02
386.9500122	18.35
387.9976807	7.27
427.3580933	0.05
439.5721436	0.03
458.6142578	0.07
484.8445435	0.05
491.0964966	0.08
497.6641846	0.02
499.3026733	0.09
500.9685669	100.00
501.9391479	51.91
502.5715332	0.23
513.9869995	0.08
523.1831055	0.03
531.0579224	0.04
531.7085571	0.01
541.2084351	0.13
541.9644775	0.17
555.6855469	0.03
568.6996460	0.13
570.1140137	0.25
571.1022339	0.08
572.2022095	0.13
572.8822021	0.08
583.1378784	0.10
587.0608521	0.03
596.9737549	0.02
597.8016968	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	570.3257
Annotation	Unknow
Peak:m/z	Relative Intensity
182.8288574	0.02
205.2295227	0.04
207.1325989	0.03
208.2069092	0.48
209.2750397	0.03
221.1826324	0.02
224.7022705	0.18
244.2090454	0.05
245.2047729	0.06
258.4386597	0.09
275.1186523	0.02
277.2696228	0.04
286.2069092	0.44
287.1505432	0.04
308.4691162	0.04
310.1810913	0.25
311.1743774	0.07
318.0897827	0.04
322.0676270	0.03
323.2935791	0.09
327.2579346	0.15
328.3405762	1.02
329.1548462	0.12
334.4599609	0.07
343.2752686	0.05
346.2600708	1.04
347.1685181	0.23
364.3599854	0.14
370.4021606	0.09
376.9843140	0.11
379.4699097	0.03
388.4580078	0.15
390.4556274	0.06
406.3024902	2.46
407.3883667	0.41
408.5504761	0.12
409.3981323	0.14
420.2361450	0.02
422.9755249	0.06
424.3373413	100.00
425.4039917	23.95
431.6356201	0.06
432.3765259	0.18
436.6835938	0.04
438.3827515	0.25
441.4887085	0.31
442.1300049	0.18
448.5313721	0.11
455.2831421	0.17
456.0664062	0.07
457.0137329	0.10
457.6455078	0.12
466.5093994	0.61
467.4039307	0.09
474.6242676	0.34
475.6680908	0.08
480.6544800	0.05
490.4653931	0.23
491.3450317	0.09
492.4888916	0.05
493.6766968	0.06
496.1350708	0.13
504.9220581	0.08
515.7502441	0.21
516.4937744	0.34
517.2791138	0.07
524.4652100	0.06
525.4446411	0.24
527.1317749	0.13
529.2824097	0.06
534.3710327	2.80
535.3206177	0.79
535.9255371	0.14
542.0056763	0.13
552.4567261	3.06
553.4179688	0.52
554.2708130	0.04
555.2114868	0.03
558.4175415	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	207.16
Annotation	Unknow
Peak:m/z	Relative Intensity
63.0335693	0.17
72.9475403	0.14
82.8132782	0.28
87.0310288	0.26
88.9527130	12.26
95.0458374	0.17
100.8135376	2.17
107.0067139	0.32
110.9287109	0.12
117.0004730	0.60
118.9226074	2.08
123.0106964	0.15
125.0154877	0.09
133.0114594	50.06
135.0697937	0.03
135.9540558	0.15
136.9618378	0.05
142.8234253	0.12
144.9557343	36.25
147.2297974	0.17
151.0455322	100.00
153.2138824	0.04
161.2699127	0.05
163.0898132	0.88
165.7609558	0.11
170.8596191	0.15
174.8700409	0.11
179.0077362	0.32
186.3479156	0.22
187.2704163	0.08
189.0911255	3.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	423.1784
Annotation	Ugonin P
Peak:m/z	Relative Intensity
133.0978851	0.57
135.9169159	0.28
147.2213898	0.38
149.8930664	0.07
152.0814056	0.37
161.0666504	0.21
163.2487183	0.12
170.0222778	0.17
178.8315735	0.17
189.0877686	0.44
189.9877319	0.17
197.0608826	0.60
201.2467651	0.11
207.1573334	1.20
210.0253448	0.47
224.5106201	1.23
225.2803955	0.23
227.3179626	0.40
228.3159180	0.42
228.9976196	0.14
242.2099304	18.82
243.2726135	3.10
246.1601562	0.33
257.8444519	0.20
260.2532654	100.00
261.2363281	15.53
261.8383179	0.07
265.1032104	0.06
275.5960083	0.56
284.1638184	2.18
285.1719666	0.42
290.2893677	0.21
293.2044983	37.14
301.4497681	0.19
302.3809814	4.89
303.3377380	0.78
304.8320923	0.35
308.1173706	0.98
320.6415100	0.44
322.0968018	0.09
323.3682861	0.48
326.3710327	2.75
327.1565552	0.41
332.1937866	0.49
333.1274414	0.58
333.8296204	0.16
338.2432251	0.58
341.3168945	0.91
342.0665283	0.07
347.9921265	0.67
350.1936035	0.67
351.2928467	0.44
356.5116272	0.46
358.9791260	0.76
365.2272949	0.08
368.2165527	2.24
369.3020020	1.23
375.1076355	0.41
386.3577271	7.49
387.2732239	2.38
400.3475037	0.61
404.3896179	19.52
405.2485352	16.42
406.4651794	0.94
407.3463440	0.14
408.8721008	0.59
413.7940063	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	536.3205
Annotation	Unknow
Peak:m/z	Relative Intensity
207.9287415	0.02
238.2710571	0.04
260.1790771	0.04
289.0822144	0.08
291.2713013	0.02
312.0609131	0.51
313.3249512	0.29
330.4245605	0.21
331.2950439	0.34
338.1879883	0.06
345.1041260	0.05
353.3817139	0.08
355.4764404	0.05
357.3236694	0.45
358.2932739	0.04
364.4888916	0.03
369.3707886	0.07
373.2882690	0.14
375.4006348	0.69
376.5377808	0.06
379.0443726	0.07
388.3555298	0.09
390.3430176	100.00
391.3502808	52.49
391.9594116	0.62
395.2775269	0.02
402.2333984	0.25
403.4214478	0.12
405.3665161	0.03
414.4829102	0.19
415.4836426	0.13
417.0482788	0.13
424.3101807	0.08
425.0790405	0.16
430.0731812	0.06
432.4383545	0.29
433.4719238	0.09
455.5654297	0.10
457.3806763	0.10
458.5728760	0.07
463.1299438	0.05
474.6307983	0.06
475.8540649	0.07
476.5048218	0.02
477.5092773	0.04
479.2351685	0.02
483.1145630	0.08
483.7554321	0.01
484.4608765	0.07
493.3217163	0.14
500.4252319	2.09
501.4536743	1.41
503.9716187	0.02
505.2808838	0.11
506.6240845	0.01
507.2913818	0.12
514.1891479	0.08
518.3994141	2.37
519.4993286	1.93
520.1846924	0.01
521.6740723	0.19
523.3917236	0.03
526.1233521	0.15
528.3281860	0.07
531.0987549	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0711
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
106.1623383	1.85
148.9712372	2.31
150.1367645	0.74
168.9484863	1.25
170.4266815	0.36
173.7209015	0.71
178.0295563	1.58
179.1169434	1.28
180.1277618	1.17
180.9448395	0.40
195.1558228	1.80
206.3235626	3.12
207.2287598	12.97
208.2484589	10.40
209.1743622	4.15
210.1703033	3.25
222.0605774	7.02
223.008316	16.32
224.171463	6.76
232.8242035	1.02
234.0366974	0.44
235.0276947	0.52
249.2807617	0.17
251.0792694	90.09
252.1230927	100.00
253.1819916	1.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	223.06
Annotation	5-(3',4',5'-Trihydroxyphenyl)-gamma-valerolactone
Peak:m/z	Relative Intensity
85.0458145	0.25
106.9613647	0.10
110.9880371	0.43
120.0730896	0.05
122.9282532	0.03
129.2510681	0.03
132.8786926	0.03
135.1791534	0.07
147.0612030	0.30
148.9688873	0.42
150.9475250	0.12
160.9725037	0.07
162.7783813	0.05
164.0894165	16.07
177.2444611	0.12
179.0348663	38.34
180.2552948	0.03
186.9920807	0.18
191.0483246	0.75
193.0342102	0.11
195.0354156	0.06
205.1179962	5.16
208.0518951	100.00
208.6673431	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	560.31
Annotation	Unknow
Peak:m/z	Relative Intensity
253.2132568	0.40
265.9839478	0.06
273.0325317	0.07
275.8856201	0.06
291.1975708	0.42
296.4332886	0.06
310.3339233	0.45
314.2599487	0.43
315.1777344	0.31
325.2775879	0.16
326.2325439	1.39
328.5967407	0.18
332.2739258	0.13
340.0407715	0.29
342.1276245	0.39
344.5006104	0.77
362.0614624	1.15
368.4159546	0.09
377.0473633	0.17
378.2669067	0.93
380.2380371	10.27
384.9489746	0.08
387.7968140	0.34
391.5229492	0.05
392.4413452	0.16
396.7664795	0.78
398.4042969	100.00
399.2417603	0.14
404.4315796	0.16
410.3851318	0.12
411.4772949	0.11
413.1579590	0.28
422.4391479	1.43
426.4585571	0.12
427.2788086	0.39
428.6098022	0.10
429.3839722	0.33
431.4631958	0.25
434.3353882	0.15
440.3878784	2.42
441.2329712	0.56
452.3757935	0.19
454.2921143	0.53
455.0873413	1.40
464.5099487	0.31
471.1040649	0.19
478.6754761	0.12
488.2274170	0.31
488.9887085	0.60
498.8556519	0.31
506.2024536	1.45
507.1198120	0.55
514.4187622	0.23
515.4467773	0.98
516.4677124	0.36
524.4354858	5.10
531.9051514	0.15
541.5096436	0.34
542.4987183	6.05
545.7567139	0.21
551.1398315	0.78
571.6449585	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1281
Annotation	Unknow
Peak:m/z	Relative Intensity
206.1668549	0.12
235.4628296	0.12
239.3843384	0.14
277.4251404	0.06
284.2565918	0.25
293.6338196	0.06
300.9366150	0.14
303.3010254	0.03
308.2415466	0.03
309.0545654	0.11
313.2903442	0.07
319.1904907	0.11
324.9816895	0.07
332.2659912	0.13
336.6946411	0.12
347.1981201	100.00
352.3596802	0.14
354.3611450	0.03
356.2901611	0.15
362.3079224	1.23
363.2873535	0.33
367.3557739	0.16
369.0349121	0.06
373.0200806	0.10
378.4214478	0.08
384.0120239	0.10
389.1828613	0.39
407.5065918	0.11
413.1586304	0.34
415.1089478	0.11
417.1486816	0.16
420.0390625	0.06
425.7496338	0.04
432.4124756	0.18
433.2411499	0.25
438.3875732	0.07
446.8562012	0.08
454.9715576	0.39
461.1762085	0.13
462.0939331	0.06
463.5397339	0.73
472.4690552	0.03
497.1855469	0.15
504.6799927	0.78
505.2888794	0.21
508.7550049	0.20
533.1085815	0.10
540.9321289	0.25
558.6450806	0.64
559.2621460	0.62
559.8683472	0.04
576.4353638	1.01
577.3134766	2.28
592.4382324	0.15
603.4771729	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	649.1967
Annotation	Esperamicin A1
Peak:m/z	Relative Intensity
210.5121155	0.11
257.3128662	0.13
258.9095459	0.84
267.2671814	0.08
271.2835083	0.15
276.2598267	0.33
276.9414062	0.13
288.8966675	1.35
298.5978394	0.14
305.0071716	0.52
307.1428223	12.06
324.8627014	3.90
333.7369995	0.03
338.7791138	0.63
341.8948364	0.91
342.9490967	8.16
355.0485840	0.15
359.5831909	0.14
360.8013916	2.93
368.6887817	0.08
381.2337036	0.50
427.2174683	0.09
446.3350830	0.33
449.7796631	0.33
456.5541992	0.31
458.9191895	0.17
469.1628418	0.75
477.9826660	22.72
478.7260742	0.81
479.7299194	0.27
480.5273438	0.12
482.6906128	0.12
484.0413208	0.48
486.6419678	0.62
503.1515503	0.12
504.5251465	2.22
505.1363525	1.07
520.3936157	0.32
521.2025757	0.14
522.2646484	1.68
544.9317017	0.10
551.2015381	0.18
558.8106689	0.32
590.1409912	0.13
595.3157349	0.62
613.1836548	100.00
614.3244629	0.50
615.3798828	0.18
616.5200195	0.16
617.1366577	0.55
619.7820435	0.27
631.1720581	0.59
680.5625610	0.17
682.9990234	0.09
684.4580688	0.77
711.0010376	0.05
958.6940918	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.0933
Annotation	5,4'-Dihydroxy-3,3'-dimethoxy-6,7-methylenedioxyflavone 4'-glucuronide
Peak:m/z	Relative Intensity
162.8892059	0.11
172.9523621	0.26
179.1163177	1.03
188.8673706	0.16
190.9463348	2.94
192.8790283	0.06
203.2148590	0.14
209.0291748	12.05
216.7692261	0.13
217.4007263	0.05
221.2799683	0.06
241.3876953	0.08
253.3692627	0.15
259.2864380	0.07
306.1703491	0.31
308.1340332	0.37
309.2111206	0.34
315.2779541	0.08
319.1876221	0.20
323.9022827	0.09
329.0794678	0.22
333.2450562	0.08
335.1645508	0.61
338.4379272	0.07
340.4006348	0.06
347.4378662	0.12
349.2164917	0.08
350.0241699	0.09
353.1735840	7.85
357.0845337	0.13
361.5883179	0.05
371.1534424	100.00
385.2557983	0.03
387.0430298	0.03
389.3826294	0.17
398.3307495	0.06
401.3225098	0.43
403.5263062	0.07
407.2564087	0.19
411.2673340	0.21
413.2177124	0.06
417.1230469	0.07
420.8823853	0.15
423.9182129	0.06
428.5499878	0.29
430.6169434	0.17
441.1082764	0.07
442.5064087	0.58
443.6094360	0.13
445.1032104	0.28
449.3486328	0.05
451.2434082	0.48
453.3137817	0.15
456.0895996	0.05
457.1842041	0.07
458.9996948	0.40
467.2786255	0.16
469.5730591	1.02
479.4012451	0.08
487.1603394	2.62
489.0153198	0.10
494.3201294	0.05
495.9679565	0.48
496.8088989	0.16
500.1807251	0.30
503.7347412	0.12
510.3120728	0.25
514.6974487	1.36
515.3189087	2.15
516.3068848	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	223.05
Annotation	Unknow
Peak:m/z	Relative Intensity
74.8757019	0.03
82.8362732	0.02
84.9490051	8.65
101.0724792	0.27
110.9828796	9.01
124.9404907	0.11
128.9604034	2.07
133.0131683	0.09
142.9685974	0.06
146.9729767	0.39
148.9685974	0.03
159.0213165	0.07
161.0077515	0.45
163.0618591	0.02
163.8581848	0.09
166.8872528	0.09
173.0624847	0.29
176.9811554	0.15
177.9384003	0.04
179.1287689	0.24
180.3524017	0.10
181.2823639	0.05
186.9875641	2.70
191.1368256	0.44
195.0651398	0.14
205.0000610	100.00
205.7930603	0.03
207.9777374	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
125.9673462	3.30
151.0500488	1.84
162.9012146	5.94
170.0323639	1.20
196.9006348	2.73
198.1921844	14.93
211.1886902	1.59
226.3443909	1.94
239.3166504	1.20
251.0976868	2.35
271.0784607	1.12
275.3015137	2.49
278.236908	4.30
280.6922302	7.46
281.4205933	9.62
291.1014404	7.24
292.2377625	7.59
293.5527954	2.52
305.7339478	5.95
308.0385437	1.68
309.2383118	17.47
310.2895813	1.87
314.4511108	1.11
322.2672729	8.19
323.8082275	0.73
325.8235474	2.44
327.8596191	8.26
331.2908936	2.30
335.2709961	1.47
337.1914673	10.90
338.3676758	1.58
339.3452759	4.30
340.8779907	5.81
352.1777344	1.94
353.4333496	1.11
357.2223511	6.71
362.4047546	2.16
365.4702454	7.44
373.5441589	9.44
382.5957336	10.17
387.5958557	2.32
391.4125671	2.16
395.3017578	7.56
396.3135986	2.25
408.2724609	100.00
409.3056946	20.52
425.7240906	5.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	796.61
Annotation	Unknow
Peak:m/z	Relative Intensity
290.6456909	2.24
292.8978271	1.96
374.4197998	0.19
376.8319092	0.29
424.3180542	0.19
425.2217407	0.07
458.5592651	6.09
459.5928955	3.28
460.4888916	10.46
461.3257446	0.52
542.4929810	33.73
543.9246216	18.79
544.5989380	55.73
564.6430054	0.19
580.6888428	0.07
588.5380249	0.21
620.3419800	0.23
625.7890015	0.24
626.4378662	6.07
627.7879028	18.37
628.4896851	40.68
629.4280396	1.01
630.5665894	1.05
658.4136353	0.46
659.5410156	0.45
666.2714844	0.30
670.7514038	0.29
675.5326538	0.41
688.7630005	2.74
689.5225830	3.81
690.5028687	2.57
710.2956543	13.40
711.5059204	25.62
712.3977661	100.00
713.1425171	0.28
718.7778931	0.24
730.3721924	0.85
731.7355957	1.32
732.8131714	0.57
734.9879150	0.35
749.1488647	2.72
749.9661865	1.00
750.6187134	1.87
758.1632690	0.86
777.9992065	0.32
795.7963257	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	268.1034
Annotation	Zidovudine
Peak:m/z	Relative Intensity
118.8318329	0.04
135.9470673	100.00
137.1651764	0.06
195.1387482	0.04
212.2065582	0.06
223.3010559	0.10
224.2157745	0.16
249.7636261	0.23
250.7578278	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1459
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
176.1974640	0.02
176.9592438	0.10
179.1561432	0.28
180.2332001	0.03
183.2370758	0.01
187.9010010	0.04
197.0543671	0.03
198.8723755	0.06
200.0906372	0.01
201.0934143	0.02
202.0473785	0.01
204.2358093	0.03
206.2385254	0.05
211.3901215	0.02
213.1936340	0.03
215.1191559	0.10
216.1229706	0.09
217.2061615	0.01
220.2370453	0.02
222.8028259	0.04
225.0511932	0.07
225.9645691	0.14
227.1380157	0.14
230.0825500	0.05
232.2453766	0.03
233.1632385	0.01
235.3579712	0.07
236.0803833	0.10
236.7721405	0.02
238.2491455	0.01
242.0805359	0.02
243.1140137	0.38
244.2769165	0.07
245.1836090	0.03
248.9854736	0.03
251.1564941	0.07
252.3600159	0.11
253.3454285	0.22
254.1802521	0.13
255.1522064	2.16
256.0362549	0.87
257.1574097	0.16
258.4436646	0.11
261.0134277	0.10
268.1983643	0.05
269.1091003	0.05
271.0666504	5.90
272.0977173	1.56
273.1488647	0.15
274.1515503	0.03
279.1651001	0.05
280.1551208	0.23
281.9135742	0.16
283.3088379	0.14
284.1803284	0.17
285.2086182	0.66
286.2062073	0.10
287.4398804	0.01
288.1927490	0.06
289.2517700	0.18
290.3923340	0.11
291.2351685	0.05
292.2473755	0.03
293.2398071	0.07
294.8989258	0.12
296.3181152	0.41
297.2402954	0.07
299.2192688	12.53
300.1233521	53.18
301.1852722	9.21
302.0796509	0.10
303.2860413	0.05
305.5920410	0.08
306.6339722	0.05
307.3989868	0.09
309.1763611	0.04
310.2268066	0.36
311.1955566	0.38
312.2933350	0.09
314.2792358	15.32
315.1222534	100.00
316.1929321	16.08
317.1715698	0.09
322.1445923	0.11
323.3836670	0.09
324.1011963	1.60
325.0289307	0.43
326.2287598	0.26
327.2821655	0.59
328.2387085	0.52
329.1652832	0.17
330.3089600	0.11
331.2070312	0.01
335.0939941	0.01
338.1254272	0.15
339.1507568	2.72
340.1427002	0.87
341.1256714	0.41
342.1266479	0.49
343.2679443	0.26
344.2443237	0.07
349.1453247	0.05
351.2732544	0.30
352.4744263	0.07
353.2846069	0.09
354.1773071	0.20
355.0748291	0.29
356.1825562	0.32
357.1443481	6.95
358.2189941	1.88
359.5644531	0.01
360.2331543	0.08
363.2429810	0.04
366.3041992	0.25
367.1177979	0.12
368.2777710	0.06
369.1076660	1.49
370.1860962	0.19
372.0325317	0.09
373.1040649	0.12
374.6890869	0.04
377.3028564	0.07
378.3336792	0.09
379.4012451	0.05
381.2623291	0.72
382.1947021	0.16
383.0643921	0.18
384.1102905	0.12
385.2363892	0.12
386.2232666	0.04
387.2244263	2.02
388.2957764	0.29
391.2287598	0.13
393.2345581	0.02
395.2514648	0.02
396.2045288	0.04
397.2597046	0.03
399.3038940	0.66
400.2796021	0.20
401.2113647	0.09
404.3251343	0.04
405.2821045	0.02
408.1907959	0.15
409.2233276	0.08
411.1264648	0.41
415.3528442	0.21
417.2873535	0.18
418.3123779	0.10
421.4784546	0.12
422.0972900	0.01
423.2241821	0.30
424.3146973	0.22
426.2826538	0.05
427.2485962	0.02
429.0997314	0.22
431.4616089	0.01
432.2705688	0.02
433.2739868	0.07
441.1398926	0.26
442.3735352	0.02
444.0383911	0.05
445.1419067	0.08
446.1419678	0.08
447.2689209	0.17
448.3315430	0.08
449.0974731	0.36
449.8526001	0.03
457.4260864	0.13
459.1845703	4.85
460.2493286	1.37
461.3111572	0.26
462.1956177	0.12
463.1854248	0.10
464.1105957	0.02
465.0908203	0.04
473.0015869	0.11
474.2500610	0.11
475.2437744	0.01
477.2456665	1.66
478.2935791	0.49
479.3024292	0.09
483.0469360	0.11
489.2247314	1.38
490.1205444	0.38
519.4833984	0.19
523.9626465	0.08
525.4741211	0.03
529.2399902	0.01
531.3375854	0.04
541.4130249	0.21
542.3175049	0.05
549.5974121	0.12
550.5587769	0.12
564.2348022	0.07
565.3375244	0.20
566.0434570	0.06
567.3767700	0.06
574.1002808	0.03
581.3584595	0.99
582.4097290	0.28
589.3681030	0.02
590.2327271	0.02
591.4149780	0.09
594.3247681	0.52
595.4942627	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	305.0666
Annotation	Leucocyanidin
Peak:m/z	Relative Intensity
93.0484619	0.45
97.0161362	0.18
106.9612274	0.27
108.9414673	1.06
111.1638870	0.32
113.1524429	0.22
120.9107590	0.15
123.0258789	0.94
125.0171356	17.06
132.9863892	0.61
135.1042023	1.34
136.9075012	14.27
139.0401459	8.90
147.1495361	0.92
149.1761169	0.18
151.0764160	1.71
159.1204834	0.54
160.9806671	5.19
163.0432587	1.01
164.0458069	5.84
165.0279236	29.59
167.0699463	10.48
172.9982147	0.60
175.1586609	1.61
177.1132202	6.54
179.0665588	100.00
179.8967285	0.22
181.1230011	0.40
182.7787170	0.18
185.0118103	0.14
186.0853271	0.13
189.0833740	2.51
191.0788727	2.77
192.7226410	0.15
199.0081787	0.75
201.1087341	2.57
202.0238647	0.07
203.0899048	2.71
204.0876160	4.77
205.2122803	0.12
206.9630127	0.09
215.1972046	1.04
217.1838989	3.14
219.1157227	83.33
221.0636292	88.74
225.0643311	0.19
225.8430481	0.11
226.9813538	0.14
228.0022278	0.66
231.1266174	0.17
233.0727539	6.05
234.8228760	0.14
237.2486572	0.84
243.1249390	6.80
245.1091919	0.94
245.8937378	0.17
247.0312500	14.71
261.1628418	45.13
262.1357117	0.11
263.1635742	8.66
269.0481873	0.72
277.2080078	0.30
287.0407410	11.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
149.083374	0.94
161.164444	9.78
181.2481079	4.99
190.8931885	2.46
207.0291901	3.15
207.9941711	2.27
215.2555389	0.94
216.288681	7.14
221.1598053	2.67
226.4554749	1.35
244.8553467	2.01
246.3662109	8.30
258.4542847	4.27
263.3731689	6.52
265.2147827	1.83
271.9456787	2.11
276.828064	3.10
281.1266785	18.03
311.5989685	1.14
312.3168945	6.80
322.4837952	1.74
332.3656006	6.45
341.0740356	3.39
343.0425415	10.43
349.1956482	3.76
357.3992615	3.09
359.0035095	6.51
367.197998	1.49
370.1167908	3.14
372.7915344	1.96
376.9996643	6.77
377.6402283	6.32
381.1947021	1.39
384.3017273	8.69
390.7355652	20.86
395.1353455	7.64
396.5151062	1.04
408.2833557	100.00
409.3244019	6.80
410.9444885	13.52
417.544342	3.85
425.1369934	1.46
426.2008057	8.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	395.1921
Annotation	Creoside IV
Peak:m/z	Relative Intensity
126.9318085	0.15
143.1453705	0.08
161.0646667	0.25
179.2147217	0.05
184.4998779	0.14
187.3156586	0.18
203.0481720	0.11
213.2102661	0.13
217.3418274	0.06
218.1419067	0.10
222.3108673	0.27
230.1541138	0.31
232.1913452	0.08
233.0353394	0.63
244.3894958	0.43
260.4020996	0.17
261.2414856	0.34
262.3073425	0.81
263.2091370	0.03
271.4796753	0.21
275.5022278	0.06
287.4036255	0.31
288.2556152	0.87
289.3309021	0.12
297.2400513	0.13
302.3427429	0.17
303.2480164	0.35
305.5211792	1.01
306.4031982	1.12
307.2277527	0.65
313.2570190	0.19
314.1912842	1.67
315.2329712	10.58
316.4359741	1.11
320.3895569	0.09
321.4062805	0.20
322.3240356	0.04
331.1609497	0.58
332.2467041	7.39
333.2810669	2.01
336.0000000	0.37
349.2206421	100.00
350.2978821	2.30
351.0221558	0.38
357.0724182	0.12
358.1552124	0.30
358.8950195	0.29
365.7811890	0.30
367.3180847	0.18
372.4579773	0.09
376.2449036	4.74
377.2931213	2.89
378.0539246	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	266.98
Annotation	Unknow
Peak:m/z	Relative Intensity
78.9090500	0.21
79.5635223	0.04
95.0210724	0.57
96.8457489	5.10
113.0016174	8.33
114.0053711	2.11
131.0063629	100.00
131.9862213	0.24
145.0675659	0.04
146.1492767	0.04
165.8879852	0.06
180.8242950	0.13
205.9438782	0.09
248.2376709	0.29
249.0059052	1.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	804.4855
Annotation	Antibiotic X 14667A
Peak:m/z	Relative Intensity
219.7397919	0.09
225.1922302	0.30
226.1705780	0.16
234.2799072	0.08
235.1576996	0.08
235.9763336	0.23
237.2247314	0.05
238.9198151	0.11
249.2794495	0.18
251.0255585	0.96
252.2168884	0.10
253.9055481	0.13
255.1537628	0.10
259.3160706	0.03
260.6885986	0.08
262.9485779	0.16
265.0975647	1.04
265.9182129	0.08
267.2672729	0.13
268.6243286	0.06
269.2599182	0.51
270.0583496	0.26
271.4503784	0.03
277.3113403	0.07
279.1173401	0.09
288.1505432	0.03
295.2553711	1.05
296.1948547	0.06
296.9294434	0.12
298.9931030	0.28
305.2376099	0.14
308.6888428	0.44
309.3190308	1.37
310.1613770	0.13
311.2104797	0.90
312.6495056	0.43
313.2887573	0.81
314.5673828	0.14
315.2242432	0.22
315.9145813	0.02
323.3970947	0.04
327.2526245	0.21
328.4296570	0.17
329.3898010	0.21
330.3358154	0.07
331.1700134	0.07
333.1849976	0.07
337.1862488	0.06
339.2552490	0.27
341.2682495	0.14
351.2699585	0.04
353.1915283	1.66
354.6296387	0.58
355.3135376	0.59
356.0088501	0.03
357.2074585	0.37
358.1209106	0.12
359.2568970	0.39
367.1693420	0.04
370.7828369	0.03
371.8541870	0.26
373.2321167	5.79
374.2671509	1.48
375.2684937	0.51
376.0192261	0.09
383.0205078	0.21
388.7017212	0.19
397.0841064	1.22
398.0726318	0.08
399.2862549	0.16
401.1227417	1.00
402.5985107	0.36
403.4119873	0.09
409.2224731	0.05
411.1430054	0.06
415.1784058	0.25
417.0982666	2.81
418.1143188	0.70
419.2828369	0.84
420.2579956	0.21
425.2634277	0.11
426.2403564	0.04
427.1678467	0.07
441.1665649	0.71
442.2932129	0.16
442.9894409	0.05
445.3420410	0.59
446.5398560	0.04
447.4750977	0.17
459.2290649	0.08
460.9660034	0.39
462.6248779	0.18
463.3779297	0.61
464.3829346	0.14
471.2254028	0.19
472.5457153	0.05
474.6809692	0.06
479.4989014	0.13
485.1336670	0.42
486.7459106	0.16
489.1179810	0.74
490.2785034	0.26
491.2265625	0.08
505.0422363	1.64
505.9674683	0.34
506.5904541	0.09
507.3818970	0.61
508.3967896	0.18
515.4369507	0.02
517.2786255	0.08
523.0344849	0.24
524.3121948	0.30
533.1544189	0.17
534.4451294	0.09
535.3824463	0.01
547.3566895	0.03
549.2293701	1.02
549.9606934	0.34
551.3189087	0.49
552.5590210	0.15
559.0369263	0.15
567.1485596	0.92
568.4179688	0.15
575.6703491	0.06
577.1918335	0.41
577.8649292	0.03
593.1602173	1.79
594.1275635	0.56
595.3186035	0.79
596.3821411	0.14
611.2705078	0.34
612.0601196	0.20
621.5540161	0.04
637.1525269	1.33
638.1090698	0.40
639.4400635	0.32
640.4721069	0.28
655.3043823	0.54
656.3429565	0.46
662.5772095	0.03
665.3336792	0.59
665.9584961	0.05
681.2123413	1.11
683.2514038	13.62
684.2476196	4.07
684.9514160	0.20
699.3523560	3.21
700.3706665	0.67
725.3953247	0.51
726.5557251	0.03
743.2756348	3.34
744.2374878	1.36
746.1827393	0.02
746.8571167	0.05
769.1597290	1.06
770.1925659	0.52
787.3424683	100.00
788.2937622	32.10
788.9456787	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	781.5667
Annotation	Unknow
Peak:m/z	Relative Intensity
218.9797058	0.10
233.0998230	0.09
235.0360260	1.27
236.1493530	0.21
236.9278412	0.04
249.1276855	0.02
251.0708160	0.21
263.0592957	1.81
264.1437988	0.19
265.2353516	0.05
321.3328857	0.03
332.3967285	0.02
350.2873535	0.20
365.7920227	0.01
380.0987549	0.07
395.5819092	0.06
405.9381104	0.10
413.9030151	0.14
419.3646851	0.02
485.5646973	0.03
494.4880981	0.04
495.2649536	0.07
500.4049683	0.02
505.1077271	0.02
507.6627808	0.01
510.5545654	0.10
525.4452515	0.02
574.3411255	0.04
575.2643433	0.07
587.9730835	0.19
598.2442017	0.17
630.4369507	0.05
646.2981567	0.06
648.2459106	0.11
651.7654419	0.03
669.3059692	0.10
678.5572510	0.31
682.3064575	0.11
682.9959717	0.35
684.0767822	0.06
686.1759033	0.40
689.2022705	0.21
690.2055664	0.17
691.8449707	0.22
693.6611328	0.06
694.6250610	0.22
696.2942505	0.29
698.3024292	0.10
700.9598389	0.05
703.6299438	0.58
704.5482788	0.25
707.8902588	0.66
709.0126343	0.17
709.8098145	0.34
711.6651001	1.81
712.4716797	0.37
713.7108765	1.16
714.7276001	0.50
715.8113403	0.99
717.2864990	0.42
718.2586060	0.19
719.5613403	0.27
720.6188354	0.41
721.6336060	0.14
723.4145508	0.20
725.8316040	0.89
726.7444458	0.22
728.9042358	0.21
730.6135254	0.08
732.3563843	1.45
734.7495728	0.28
737.3858032	0.47
738.0997314	0.30
739.7511597	0.19
740.9729004	0.58
742.9978638	0.47
743.6935425	0.19
745.8185425	1.05
746.8367310	0.32
748.4044800	2.03
749.3630981	0.66
750.9935913	2.73
752.0944214	0.53
752.8716431	2.46
753.6950073	0.25
755.2622681	6.13
756.0015259	1.03
756.7288208	0.11
757.6401367	1.58
759.7771606	4.45
760.8052979	0.61
761.5484619	0.15
762.3960571	0.21
763.9351807	0.26
764.8330688	0.03
766.2037964	1.14
767.2177124	0.22
768.6882324	1.95
769.6942139	1.02
770.6705933	2.80
771.5069580	0.47
773.1071777	4.02
774.4542847	0.02
785.2766724	0.08
787.6466675	0.15
788.3878784	0.09
804.7002563	0.07
817.3258667	0.05
818.7239380	0.02
821.1828003	0.28
826.8652344	0.18
829.8335571	0.26
832.5944214	0.06
836.4949951	0.10
842.2844849	1.08
844.3261719	0.16
855.1986084	0.03
857.1934204	0.03
858.0382690	0.10
859.8473511	0.29
861.9323730	0.35
864.6393433	0.06
867.4788208	0.07
868.7427979	0.20
871.6862183	2.56
872.5272827	0.87
875.0945435	0.19
876.5034180	0.31
878.8282471	0.27
880.5912476	0.21
881.5115356	0.08
883.2999878	1.02
884.2455444	0.34
886.2858887	0.41
887.7315674	0.15
890.2094116	0.43
891.7287598	0.93
892.6641235	0.87
893.8217163	1.08
895.2028809	0.42
896.7988281	0.51
898.1337280	0.13
899.2813110	0.02
902.6680298	0.21
904.2758789	0.17
905.2522583	0.36
906.9906616	0.02
908.8823242	0.24
909.8678589	0.22
910.6950684	0.39
913.6458130	0.49
914.8270874	0.15
916.8765259	0.39
917.6179199	0.06
919.2542114	1.84
920.0875854	0.92
920.6881714	0.20
921.6010742	0.12
923.4376831	0.25
925.0906372	3.16
925.8464355	6.54
926.5957031	2.01
928.3594360	1.04
929.4946899	1.06
930.3765259	0.04
932.3378296	0.07
933.5578613	0.32
934.7595215	0.75
936.5961304	0.16
937.3890991	0.08
938.8399048	0.18
940.1124878	0.67
941.1335449	0.53
942.0437622	0.36
943.0696411	2.58
943.8642578	0.56
944.7150269	0.66
945.8022461	1.93
946.7229004	0.44
947.5444336	0.44
948.8168335	6.05
949.6689453	6.44
950.4060059	0.12
951.1651001	0.26
952.1167603	1.53
953.0975952	1.08
954.2809448	4.45
955.1493530	100.00
957.3328247	2.93
958.3748169	3.26
959.5540161	1.42
960.4542847	0.37
961.9604492	0.14
963.1627808	0.52
963.9033813	0.50
964.6909790	0.20
966.0248413	0.93
968.2370605	0.70
969.9547729	1.24
971.2167358	0.39
973.6538086	1.34
975.3898926	0.05
976.1788940	0.31
977.2816772	0.32
978.1243286	0.43
979.6605835	4.28
980.5251465	0.10
981.7109985	0.84
983.1619263	0.85
985.2080688	0.28
987.2276001	0.11
988.5951538	0.64
990.9360962	0.65
991.6497192	1.92
992.5146484	0.47
993.5886230	0.87
994.3582153	0.09
995.2877808	0.27
996.2631226	0.17
997.3502808	0.48
998.2985229	0.60
999.5208130	0.36
1000.5634770	2.09
1001.2868650	0.07
1002.9392700	2.50
1003.6005860	4.19
1004.5215450	1.38
1006.4611210	3.61
1007.1789550	1.80
1008.5581670	2.33
1009.4250490	13.44
1010.4252320	2.83
1011.3403320	0.38
1012.7429200	3.59
1013.5038450	1.39
1014.4457400	0.02
1015.6382450	0.48
1017.3687130	0.27
1019.2377320	0.62
1019.8499150	0.14
1027.3441160	0.12
1030.3808590	0.34
1046.5290530	0.19
1047.4617920	0.13
1051.4859620	0.01
1054.0688480	0.06
1054.9042970	0.18
1055.6710210	0.12
1062.2197270	0.12
1063.9785160	0.28
1070.7895510	0.34
1078.6270750	0.03
1098.8735350	0.20
1102.1132810	0.10
1102.7733150	0.21
1109.8559570	0.11
1111.1530760	0.26
1114.4307860	0.12
1115.8303220	0.03
1122.2014160	0.30
1123.8659670	0.24
1124.8919680	0.14
1129.8928220	0.08
1133.8264160	0.17
1136.7957760	0.07
1140.6776120	0.02
1145.2025150	0.07
1146.5061040	0.07
1153.7083740	0.15
1154.4953610	0.10
1162.0327150	0.29
1164.8157960	0.07
1171.0358890	0.15
1176.9154050	0.18
1178.1545410	0.69
1179.0908200	0.05
1193.3270260	0.08
1203.1610110	0.16
1208.4726560	0.12
1209.5419920	0.14
1215.5312500	0.11
1218.3266600	0.14
1227.7270510	0.34
1229.4498290	0.10
1235.0654300	0.19
1240.1217040	0.18
1250.7198490	0.03
1253.6893310	0.09
1262.0369870	0.27
1262.8583980	0.43
1267.6776120	0.11
1275.0271000	0.06
1281.8925780	0.19
1285.4971920	0.08
1286.3573000	0.05
1292.5975340	0.08
1298.0269780	0.14
1300.1000980	0.14
1304.2246090	0.13
1306.6506350	1.24
1307.5845950	0.79
1308.2854000	0.14
1310.7080080	0.17
1313.1180420	0.23
1313.8458250	0.30
1314.6802980	0.20
1326.5380860	0.29
1337.2774660	0.45
1338.3607180	0.47
1339.0761720	0.09
1341.7946780	0.44
1342.7187500	0.07
1343.3286130	0.08
1346.4383540	0.04
1348.5104980	0.05
1356.9260250	0.17
1360.7969970	0.24
1363.4892580	0.08
1364.8099370	0.06
1367.7364500	0.05
1369.8321530	0.12
1371.1182860	0.07
1376.3035890	0.24
1380.0157470	0.30
1387.1154790	0.12
1388.2231450	0.48
1388.9764400	0.05
1399.4802250	0.03
1409.9705810	0.08
1418.9271240	0.23
1438.9805910	0.09
1447.0645750	0.08
1458.5384520	0.04
1464.7939450	0.10
1581.8171390	0.02
1613.1336670	0.07
1630.2037350	0.08
1648.3288570	0.04
1723.1013180	0.12
1748.1060790	0.04
1786.6574710	0.08
1866.6358640	0.03
1874.7218020	0.08
1959.0643310	0.07
1965.4660640	0.11
1990.0739750	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	405.05
Annotation	1-O-p-Coumaroyl-(b-D-glucose 6-O-sulfate)
Peak:m/z	Relative Intensity
118.8337784	0.04
120.7057266	0.04
126.9515915	0.05
127.9745178	0.53
132.0275269	0.21
135.1478271	0.03
138.7907715	0.11
140.0623932	0.04
143.0557251	1.17
145.1474304	0.04
145.9829865	0.20
146.7758942	0.04
155.2125244	0.06
159.3881531	0.07
160.3796692	0.02
161.2868042	0.04
163.0940552	2.16
165.1224670	0.02
167.0215149	0.50
170.9830322	0.02
177.2203979	0.06
179.1206360	1.43
183.0064697	0.03
184.8768616	0.34
196.1259766	0.08
197.1992035	0.06
208.8718109	0.06
210.1276855	0.64
211.0221558	0.03
213.0438690	0.01
224.1615601	0.13
224.9065704	0.05
226.1575317	0.09
227.1284180	0.17
228.3450928	0.13
235.0903931	0.02
236.2389832	0.06
241.0103760	100.00
242.1092834	1.82
242.9875183	0.48
249.2124634	0.07
254.1649475	10.59
259.1395874	0.94
265.0072021	0.05
268.1573181	0.04
269.2205505	0.25
270.3923340	0.03
272.1988220	35.84
274.1738586	0.03
276.2987671	0.07
285.0803528	0.08
288.1461487	3.04
292.8918457	0.08
294.0929871	0.06
303.0874023	0.05
306.1972351	38.83
316.8898621	0.17
325.2020874	0.35
342.8857117	0.04
351.0427246	0.03
357.0953064	0.04
359.1352844	4.82
360.1337585	0.36
361.1601257	1.58
376.0859985	0.12
376.8487854	0.34
386.1310120	0.08
387.2507324	1.54
389.3325195	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	296.8
Annotation	Unknow
Peak:m/z	Relative Intensity
196.9829102	0.18
198.7592468	0.04
210.8909607	0.18
211.7063904	0.02
212.8066101	100.00
233.2634277	0.04
251.0740356	0.27
278.1492920	0.07
279.3910522	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	491.3078
Annotation	Unknow
Peak:m/z	Relative Intensity
165.0819702	0.11
176.2180786	0.08
177.1074219	0.24
184.1271667	0.04
192.8816833	0.06
195.1187134	0.16
199.2360535	0.08
205.6519623	0.16
207.0642700	0.12
208.2111053	0.04
221.0583496	0.16
221.7226715	0.20
224.8120422	0.06
229.5299072	1.18
230.3697052	0.08
235.2507019	0.09
243.5478363	0.34
250.7233276	0.12
251.5769806	0.93
253.1447144	0.04
265.1528931	0.27
267.3147583	0.17
269.0589905	1.37
270.3721924	0.07
272.3784790	0.14
273.5953674	2.01
274.3912659	0.35
275.9048462	0.09
279.3435974	0.07
287.0776367	0.08
289.6606140	0.26
295.4873352	2.94
296.2676392	0.14
297.6642456	2.33
299.9076233	0.07
310.1919250	0.12
311.8725891	0.23
313.0683289	0.89
313.8496399	0.27
319.5528259	0.68
323.1176758	0.07
333.7611694	0.11
338.7063599	0.24
339.7313232	1.01
341.6090393	1.34
342.2457886	0.90
348.5150757	0.09
352.2869568	0.06
353.3296509	0.32
355.7729187	0.06
357.0319214	0.37
357.7315979	0.13
361.7059937	0.30
363.4507446	0.62
364.3408813	0.53
365.5788269	0.12
367.1189270	0.15
383.5800476	0.51
385.1460266	0.34
385.7502136	3.44
392.0473938	0.09
407.4598999	0.06
409.1171570	0.21
419.2062683	0.03
422.2377625	0.45
430.9209290	56.63
432.0023804	0.66
433.6001587	0.18
434.9960632	0.10
438.8257751	0.48
440.5543213	0.11
441.4870605	0.04
442.4824829	0.29
443.8404846	0.90
445.1216125	0.06
445.8423157	0.08
452.0223083	0.20
454.7843323	0.03
460.3637390	0.14
461.1667786	0.43
473.9365540	1.64
474.8070679	1.04
475.6868286	0.08
476.5952759	0.06
482.8460999	100.00
484.4241028	1.21
485.5818787	1.54
486.6074524	0.37
487.6442566	0.24
488.5114441	0.34
489.9443054	0.14
493.4288940	0.13
503.3020935	0.36
520.1901245	0.33
521.2778320	0.07
530.4651489	0.04
533.4552002	0.08
534.2225342	0.20
547.5049438	0.24
552.6663208	0.06
563.8107300	0.18
564.4882202	0.46
565.1961670	0.44
568.2765503	0.07
577.2546997	0.03
591.3423462	0.27
595.3812866	0.11
597.5142212	0.09
608.3229980	1.49
609.4505615	0.45
617.4186401	0.11
622.2554932	0.04
623.3569946	0.11
635.2622070	0.21
636.4705811	0.05
638.6419067	0.13
640.4345093	0.11
641.3646240	0.06
652.5029907	0.46
653.6419067	0.17
656.4752808	0.47
657.5434570	0.28
667.1236572	0.10
679.6524048	0.13
682.7096558	0.12
684.4307861	0.23
696.4910278	0.86
697.2043457	0.07
700.6193237	0.52
701.5147095	0.42
727.5402222	0.07
728.7797241	0.07
744.5436401	1.47
745.5845337	0.30
773.1909180	0.10
773.8104858	0.16
787.7747803	0.36
789.0200195	1.06
789.6739502	0.02
816.5536499	0.18
817.3815918	0.11
832.3281860	0.50
843.3616333	0.81
844.4890137	0.19
860.4580688	18.18
861.4495239	9.73
862.1918335	0.05
862.8372192	0.22
942.7016602	0.04
964.4174194	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	568.3105
Annotation	Unknow
Peak:m/z	Relative Intensity
189.1777344	0.04
191.2602844	0.05
211.1405945	0.15
225.9995422	0.03
237.0354309	0.03
238.3756104	0.01
249.1269226	0.02
258.2169189	0.39
259.9357910	0.06
281.7557983	0.02
282.4938354	0.02
283.3666382	0.09
286.1572266	0.92
287.2761230	0.07
294.0705566	0.04
306.2390137	0.03
308.3893738	0.26
309.5470581	0.08
313.1806030	0.01
316.2186890	0.13
326.4476318	0.07
328.4041138	0.03
343.1886597	0.06
344.2615967	0.05
370.1539307	0.02
373.1471558	0.11
374.0660400	0.06
380.0540771	0.05
383.1287231	0.03
386.3953857	2.91
387.9952393	0.04
399.2882690	0.76
400.3425903	0.57
404.3444214	7.07
405.0488892	0.15
406.1579590	0.05
422.4044800	49.11
436.4261475	0.10
437.1343384	0.01
439.2169800	0.03
445.0653687	0.06
446.0509644	0.06
446.7778931	0.07
463.1790771	0.20
464.3585205	0.15
465.4666748	0.02
472.3869629	0.07
474.1990967	0.04
488.1875000	0.02
488.9995728	0.02
490.1268921	0.09
492.4009399	0.22
493.7573242	0.12
496.7190552	0.07
502.1249390	0.09
506.0131836	0.05
508.5662231	0.14
509.1860962	0.04
514.3251343	0.29
524.5603638	0.07
532.4140625	2.23
533.0886230	0.01
550.3668823	100.00
551.0139771	0.40
551.6867065	0.07
554.2720947	0.04
558.1278687	0.07
562.6427002	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	369.0826
Annotation	Isoferulic acid 3-O-glucuronide
Peak:m/z	Relative Intensity
110.9517975	2.35
129.0041351	8.09
129.7848511	0.23
137.1199036	0.26
141.2120056	0.06
147.1968842	0.06
149.2380371	0.05
156.2007751	0.05
159.2032776	0.05
161.0170898	0.67
163.0270996	0.95
167.0521545	0.10
171.4686279	0.03
173.0085754	0.51
179.3060150	0.08
181.1396027	0.05
183.2219238	0.20
185.0933075	0.06
186.9836273	1.79
187.9219360	0.12
188.8333435	0.06
191.1427917	0.10
193.0865021	0.09
194.1463013	0.05
199.0016785	0.06
201.1304932	0.51
205.0525360	37.57
206.7356873	0.12
207.3547058	0.24
209.3108521	0.11
216.7702026	0.11
219.2920837	0.03
223.0686035	100.00
231.2844849	0.10
235.3335266	0.04
239.1713867	0.09
241.2537231	0.07
242.8970947	0.10
246.1330261	0.05
247.0348511	0.21
249.2386475	0.08
255.0847168	0.04
256.8940430	0.09
257.8879089	0.22
259.2304993	0.14
269.1019592	0.17
273.7570190	0.07
278.9543457	0.14
280.6229858	0.07
287.6364441	0.07
288.5543518	0.09
289.5593567	0.15
291.3783569	0.14
293.1992798	0.10
306.3094788	0.26
307.3944092	0.40
308.4576111	0.03
312.7740479	0.10
315.4572754	0.06
322.6208496	0.24
323.2835388	0.65
324.5025635	0.42
325.2074585	0.28
330.0171509	0.31
331.9940796	0.19
333.2996216	0.55
341.3387451	0.31
351.1086731	5.74
351.7526550	0.02
353.3126221	0.14
354.3763733	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	477.1612
Annotation	7-Methoxydiderroside
Peak:m/z	Relative Intensity
178.8290405	0.15
182.2342224	0.20
199.1633606	0.21
226.9677429	0.06
229.1782532	0.17
251.9119873	0.14
259.4011841	0.27
267.1888123	0.31
287.2115173	0.23
293.4714661	0.09
296.0652161	0.14
297.1649780	0.22
299.3984985	0.23
300.8442993	0.19
305.3655090	0.58
313.1054077	0.11
314.0466003	0.37
315.1825562	1.45
316.0182800	0.06
327.3182983	0.11
338.9930115	0.06
343.3720093	0.19
344.0544739	0.19
345.4446411	0.21
347.1242676	0.15
354.0670776	0.04
357.2889404	0.19
360.9334106	0.18
362.2263184	0.21
369.3128052	0.56
381.1405945	0.21
387.0899963	0.98
387.7539978	0.10
390.2843018	0.67
392.3940430	0.05
393.0364685	0.06
401.2727966	0.09
402.2916260	0.10
413.3406982	0.25
416.2968750	0.19
417.2871399	0.16
429.9626465	0.06
431.2746887	100.00
433.1782227	0.73
433.9829407	0.13
436.3985901	0.18
439.1324768	0.09
441.3359070	0.12
447.0939941	0.16
449.1387634	0.14
459.1242981	2.22
460.5129089	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	416.1824
Annotation	Naltriben
Peak:m/z	Relative Intensity
132.9166870	0.01
133.7937775	0.01
141.2301788	0.07
148.2132568	0.02
159.0526123	0.01
168.9250946	0.11
176.0720215	0.05
178.9092102	0.01
184.9954376	0.01
187.1664124	0.31
194.0471191	0.05
201.2204742	0.03
207.3669434	0.02
209.2732239	0.04
210.0884705	0.01
222.3309784	0.08
227.1923218	0.05
244.2857361	1.39
253.2698059	0.04
256.3939819	0.01
258.8881226	0.05
262.2654419	17.35
263.2631836	0.03
264.1506042	0.08
266.9703979	0.06
270.2245483	0.45
271.3772888	0.06
274.0704956	0.07
282.2771606	0.33
296.3767090	0.02
300.2598572	4.75
307.3794556	0.04
312.2033081	0.03
316.2632446	0.04
318.1945801	100.00
318.8434448	0.26
326.5726013	0.04
327.2497559	0.31
334.6532593	0.06
336.2546082	3.04
343.5773621	0.10
352.9156494	0.06
363.2586670	0.04
372.0782166	0.03
380.3632507	0.02
381.0101013	0.03
385.4378052	0.02
398.4170837	0.48
399.2203674	0.05
407.2741089	0.03
418.9432678	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	637.3439
Annotation	Unknow
Peak:m/z	Relative Intensity
197.1039886	0.10
207.0560760	0.05
237.7374268	0.11
245.1695557	0.17
281.4582214	0.04
295.1455994	0.06
313.3121338	0.16
333.4657593	0.06
342.7542114	0.22
344.3177490	0.09
349.6896362	0.09
361.4539795	0.27
377.3931885	0.13
379.2219238	0.16
383.3999634	0.04
389.2925415	0.05
395.2111816	0.09
398.7352295	0.11
403.3521118	0.05
407.2684326	0.10
413.3369751	0.51
415.3375244	37.90
416.3378296	0.59
417.5125122	0.11
433.2160645	0.27
439.4270630	1.05
445.6585693	0.22
457.3753052	1.18
459.3102417	0.08
461.2791138	0.19
463.4815063	0.22
475.3544312	4.26
479.4586182	0.09
481.4250488	0.37
483.1040649	0.08
484.9424438	0.18
495.4984131	0.09
535.3265381	0.16
539.3856201	0.07
550.6360474	0.55
551.4706421	0.16
552.5474243	0.21
553.1887207	0.09
555.0526733	0.15
559.3609009	1.44
569.4378052	0.18
574.2227783	0.12
575.4113159	1.00
577.3259277	34.44
578.5571899	0.27
591.2656860	0.86
592.0027466	0.33
593.2901611	0.32
601.3890991	5.65
617.3399048	0.05
619.4481812	100.00
620.1807861	1.69
621.2396851	1.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1814
Annotation	(-)-11-hydroxy-9,10-dihydrojasmonic acid 11-beta-D-glucoside
Peak:m/z	Relative Intensity
112.9861603	4.03
114.0455704	0.55
114.8834076	0.03
115.6464310	0.08
118.9768219	5.59
120.0581894	0.53
124.8973236	0.24
126.0920639	0.17
130.9115906	2.42
131.9705353	0.21
134.1148987	0.06
141.0535278	0.04
142.0289612	0.10
143.0370483	5.19
143.9831085	0.08
147.0551605	5.45
148.1608887	1.34
149.0316620	0.52
149.9788055	0.19
160.0466003	0.05
161.0575562	1.54
162.0152893	0.27
163.1748352	0.19
165.1620483	1.99
173.0823669	0.15
178.9613647	2.42
179.9310303	0.12
181.0068970	0.63
182.0947418	0.09
183.3466949	0.07
187.0555573	0.05
191.0852814	1.22
192.1131744	0.10
193.2525940	0.14
205.5039978	0.04
206.3301697	0.10
207.2409515	0.62
209.0875702	100.00
210.1389160	14.62
211.1026917	0.54
223.2707520	0.58
227.1649170	10.33
228.1720581	1.93
233.0807800	0.03
235.4378967	0.09
241.2834167	0.20
251.2264404	0.67
261.1720886	0.31
265.3780823	0.04
269.2576904	0.24
279.4275513	0.06
286.0892334	0.02
293.2746582	0.11
302.4092407	0.13
303.1950378	0.11
311.5183716	0.06
314.2583008	0.07
315.3139343	0.22
330.4705200	0.03
343.1580811	0.52
344.3280640	0.22
345.2967834	0.19
346.3311768	0.17
353.2556458	1.50
354.4412231	0.20
360.4248352	0.26
371.2406921	57.88
372.3406372	13.12
373.2535095	0.13
375.1618958	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	438.0841
Annotation	Unknow
Peak:m/z	Relative Intensity
139.1933289	0.08
150.0234070	0.31
152.8609924	0.25
175.7704163	0.18
184.1692505	0.20
189.7064972	0.03
193.0335693	0.03
194.1176453	0.29
195.0031128	0.05
208.1724396	0.41
226.2566681	0.03
227.3807831	0.09
231.1886749	0.13
238.9722595	0.06
240.1369019	1.11
244.8546753	0.24
254.0736389	90.95
254.9400024	0.08
258.0063171	0.09
258.8813477	0.12
266.1110535	0.04
268.0665588	0.19
268.9672546	0.06
271.7005920	0.08
273.2263184	0.26
274.1839294	0.08
279.0153809	0.12
286.1451416	2.61
291.9730835	0.05
293.1628418	0.19
296.8922729	0.17
301.2249756	0.06
304.9921265	0.16
308.1818237	0.82
311.9313354	0.13
313.2202759	0.09
316.1458130	0.04
318.1455994	0.10
319.3496094	0.07
321.0966797	13.83
322.2135620	0.07
331.2005615	3.23
333.0969543	24.23
348.3282471	1.25
348.9720459	5.39
355.2991943	0.03
356.2412720	0.63
357.1671753	0.35
359.1572876	0.79
359.8391113	0.04
362.4859619	0.05
371.3664856	0.06
374.4413147	0.55
375.2767029	0.10
384.3246155	0.11
385.2230530	0.30
389.3062439	0.04
392.0350037	2.22
393.2930603	0.41
402.0473938	1.24
403.0169373	2.03
418.0038147	0.06
420.1286926	100.00
421.1081238	18.06
429.1731567	0.10
438.6012268	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	343.29
Annotation	MEDICA 16
Peak:m/z	Relative Intensity
107.0524902	0.18
108.3140335	0.23
109.0091553	0.28
123.0144119	0.33
130.9674988	0.25
145.2739258	0.11
147.0611572	0.36
151.0141907	0.20
152.1125488	0.22
153.1483765	0.42
159.1017456	0.10
162.7016907	0.26
164.7613373	0.22
169.198288	0.31
173.008728	0.27
174.3200073	0.57
183.2409821	0.15
185.1080933	0.15
191.0229797	0.23
196.8796844	0.17
202.8466034	0.14
207.9263	0.09
215.1901245	0.88
228.383606	0.30
229.2048035	0.16
240.2541809	100.00
241.2077332	0.14
243.2749023	0.63
244.9458008	0.23
247.3540955	1.25
249.1016235	1.43
252.9609375	0.35
259.1193237	0.36
262.9554443	0.18
265.251709	0.17
268.2324829	1.35
269.0148315	0.44
271.2872314	0.30
273.1227417	0.23
283.1803894	0.51
283.8388977	0.31
285.0451965	0.30
293.790802	0.50
295.0050659	0.47
297.3511658	1.25
301.2949219	0.62
302.4049377	0.19
307.3103638	3.73
308.0920715	1.14
312.6793518	1.44
315.1181946	0.33
325.2671814	75.81
326.033783	2.52
331.3113403	0.55
333.5307007	1.13
343.1560059	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	182.0807
Annotation	4,6,7-Trihydroxy-1,2,3,4-tetrahydroisoquinoline
Peak:m/z	Relative Intensity
136.0419617	17.36
147.0356598	0.12
164.9582825	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	610.13
Annotation	Unknow
Peak:m/z	Relative Intensity
177.1004333	2.76
178.0544128	0.23
179.0324707	0.48
180.0898438	0.06
188.1703491	0.05
189.1837006	0.06
193.2510071	0.04
201.2831879	0.03
203.2445374	0.09
204.0713501	0.03
207.0924072	0.06
215.0004730	0.04
217.0213928	0.18
217.7703857	0.04
219.1144104	0.63
220.2715149	0.27
221.1300812	0.49
222.1728973	0.06
227.2912903	0.09
232.7563171	0.07
235.3430939	0.06
238.3659058	0.04
241.2297974	0.11
243.1591339	0.15
245.1450806	0.10
249.2442322	0.08
255.0989380	0.57
258.1578064	0.04
259.0931702	0.20
261.0071411	1.39
261.9768677	0.45
263.2243958	0.18
268.5799255	0.14
271.2056885	0.15
272.0980835	0.03
273.0980225	4.03
274.2100830	0.71
285.2516785	0.43
286.3378296	0.32
287.3801880	0.67
288.1046448	0.08
289.1734619	0.04
297.0955811	0.17
299.3890381	0.06
301.2033081	0.19
303.2280273	5.95
304.2642212	1.56
305.1035156	41.54
306.1902466	8.20
307.1240845	0.47
311.1191406	0.04
315.0570679	3.56
316.1505127	0.85
317.2419434	0.73
318.3529053	0.08
327.3271484	0.04
329.3772583	0.21
331.1571655	0.05
337.1454468	0.08
339.2445679	0.11
340.3060913	0.04
341.0581665	0.25
341.7590942	0.07
343.2702026	0.52
345.1983643	0.39
346.3102417	0.17
347.2082520	0.88
348.5505981	0.05
355.2114868	0.62
356.1342163	0.29
357.1188965	0.43
358.2684937	0.08
360.3928223	0.04
363.3245850	0.27
366.2800903	0.26
368.4273682	0.04
369.1893921	0.12
373.3462524	0.35
378.4305420	0.07
384.2734985	0.33
385.2930908	0.11
397.3273315	0.85
398.3936157	0.09
399.3390503	0.09
406.3618164	0.08
409.1181641	0.20
411.2145386	0.09
412.1980591	0.23
413.4343262	0.03
415.2841187	0.04
418.3275146	0.16
419.4710693	0.02
423.1959229	65.68
424.2063599	40.68
425.1970215	0.15
426.0962524	0.12
426.7843628	0.11
427.4248657	0.88
428.3657227	0.56
429.2654419	0.36
430.0604858	0.38
431.0910645	0.03
432.8587646	0.51
435.3770752	0.16
439.2940674	0.49
441.1738281	100.00
442.1387329	42.41
443.2581177	0.26
447.2127075	0.65
448.4425049	0.35
453.2064819	1.35
454.0117798	0.29
455.3936768	0.09
456.9039307	0.05
458.1687012	0.03
459.5609131	0.04
462.0078125	0.20
462.7103271	0.19
465.2182007	1.28
466.2431030	0.69
469.1328735	0.03
470.1595459	0.16
471.0592651	0.50
472.4794312	0.04
476.3117676	0.07
477.0957642	0.08
479.3069458	2.76
480.2006226	0.49
481.0375977	0.10
483.1522217	28.67
484.1978149	10.77
485.0422363	0.27
489.4561768	0.62
494.0189209	0.10
498.3884888	0.07
499.8664551	0.03
503.2775269	0.10
506.5004883	0.14
507.4066772	0.25
510.9860229	0.06
514.3480835	0.11
516.1522827	6.58
516.8095093	3.13
518.1328735	0.13
518.9460449	0.11
519.6417847	0.03
521.2349243	0.03
523.3579102	0.08
524.4739380	0.71
525.1014404	4.08
525.8179932	1.48
526.7509155	0.08
527.9952393	0.06
529.2861938	0.06
531.9490356	0.09
537.1343384	0.39
538.2189941	0.09
542.3598022	0.03
543.2835693	0.32
545.3054199	0.42
546.2469482	0.51
547.3768921	0.07
548.2747192	0.29
550.4312744	0.04
562.5241089	0.07
563.5423584	0.10
565.2279663	2.40
566.2312622	1.02
572.3528442	0.12
573.0900879	0.05
578.2221069	0.10
579.3070679	0.19
580.4426880	0.03
581.4531250	0.54
582.1846313	0.06
591.1991577	14.26
592.3178101	9.50
593.3626709	0.08
594.2514038	0.30
600.1593628	0.49
603.5297852	0.03
612.2321777	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.1032
Annotation	Veranisatin B
Peak:m/z	Relative Intensity
123.1483078	0.13
135.0312653	0.06
136.0737305	0.82
139.0543518	0.08
143.0649414	0.31
151.1577454	0.12
153.1997681	0.53
161.9738770	0.14
177.2029877	0.36
181.3118286	0.26
191.0269470	0.12
191.9721069	0.24
193.1755066	1.00
195.0055237	100.00
209.2248077	0.20
210.0873566	0.24
211.0893707	0.80
213.0376434	0.16
219.2785645	0.14
227.1354980	0.44
228.3160400	0.32
231.3208008	0.31
235.1394043	0.13
237.0270996	0.85
261.0026550	0.72
266.4814758	0.07
267.2732544	0.27
269.4513245	0.30
271.5540161	0.14
276.0689087	0.04
283.3031921	0.07
285.1474915	0.21
286.0306396	0.08
289.1359863	0.07
295.2534180	0.04
297.1470337	0.42
298.9436646	0.17
311.0355835	1.04
313.1768188	0.79
319.1792908	0.03
322.3145752	0.08
325.0097351	0.17
329.0160522	0.08
338.2000732	0.47
339.1159058	0.58
340.2414551	0.04
342.2819519	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	238.1294
Annotation	Unknow
Peak:m/z	Relative Intensity
68.8901291	0.91
87.1021271	0.45
117.0427551	0.08
119.5451660	0.11
123.0291138	0.20
124.8840942	0.22
135.1702423	0.14
136.1390533	0.13
138.9575348	0.06
152.0085297	100.00
153.0494690	1.20
160.1143799	0.09
163.9846344	58.17
169.7660675	0.05
178.0394440	0.26
179.2831879	0.26
182.0871582	0.75
184.1035309	0.19
190.0244293	0.16
192.1195984	1.57
193.0582581	0.18
196.7936859	0.15
202.0649872	0.23
207.2499695	0.74
209.9875031	0.44
211.1862335	0.09
218.1395874	0.48
220.1444702	74.23
221.0838776	1.35
223.2865448	0.10
228.9912109	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	913.1823
Annotation	[Gallocatechin-(4alpha->8)]2-gallocatechin
Peak:m/z	Relative Intensity
255.1096649	0.54
257.3593140	0.27
259.1225891	0.22
261.0457153	1.17
272.9920959	0.23
280.9844360	0.09
283.2506714	0.26
284.9774475	1.37
285.5859375	0.21
286.7632751	0.45
295.3328857	0.04
297.4379578	0.52
301.1344299	0.41
303.0824585	4.97
305.1584473	6.67
306.5873718	0.12
315.0935364	0.60
316.1907043	0.36
317.2219238	0.15
327.3375549	0.14
331.3971558	0.14
333.5986633	0.48
339.1398926	0.54
345.1597290	0.39
353.4161072	0.04
355.5919189	0.12
357.2448730	0.98
365.3942871	0.17
373.2246094	0.10
379.1235352	1.24
380.8482056	0.12
385.6170044	0.10
387.3560181	0.66
391.2560425	1.60
395.1568298	0.21
397.2687683	1.07
408.9673462	0.13
411.2330322	2.63
413.0292969	0.38
414.1174927	0.34
421.2599487	2.03
423.1547852	17.62
423.8431396	0.04
425.5162964	0.06
427.1815186	0.74
429.1137085	4.06
433.2619629	0.62
438.3413086	0.47
439.1989136	2.48
440.6416626	0.67
441.2533569	9.21
451.0428467	0.41
453.3769531	0.56
455.5379639	0.81
463.3195190	0.56
465.2395020	1.73
467.4697876	0.16
469.3361206	0.19
471.4548950	0.47
477.5048828	0.18
481.1212769	3.63
482.0978394	0.08
483.2286987	11.14
485.1126709	0.25
489.2301025	0.22
493.4089966	0.45
507.1975098	0.17
515.3939209	0.18
521.3632202	0.07
523.4250488	0.58
525.2935181	0.27
533.2532959	0.55
541.1601562	11.83
543.5914307	0.24
545.6119995	0.04
547.3464966	0.69
549.3535767	0.07
551.1275024	0.24
557.4755249	0.31
559.1961670	28.55
561.1063232	0.05
563.2836304	0.36
565.2214966	3.48
571.2976074	0.21
575.2514648	0.11
576.0576782	0.48
577.2427979	7.10
581.1862183	0.05
583.2107544	0.36
584.0372925	0.17
586.9665527	0.08
587.8417358	0.05
589.3084106	0.79
591.1909180	4.96
592.3882446	0.11
593.2776489	0.46
601.2077026	2.86
602.2308960	0.13
604.9926758	0.13
606.0321655	0.13
607.1403198	7.98
608.1897583	1.09
609.2155151	16.64
610.2177124	0.28
619.1801147	8.34
620.1775513	0.08
621.2573853	0.38
631.0658569	0.33
632.4634399	0.27
641.2289429	0.26
643.4670410	0.12
648.3091431	0.64
649.3418579	0.80
651.2695923	2.10
653.3717651	0.13
661.2991943	0.79
661.9097290	0.07
665.1823120	0.17
666.5942383	0.33
675.7658081	0.16
677.1476440	0.24
683.2314453	1.66
691.1896362	0.11
697.5630493	0.15
701.0449829	0.81
707.4906616	0.04
709.2282715	6.79
709.8738403	0.21
713.4680786	0.08
715.4087524	0.30
725.0169067	0.71
727.1461792	100.00
727.7701416	0.74
729.2228394	0.10
734.1536255	0.24
735.6828003	0.43
739.4249878	0.11
743.4411621	1.24
745.0862427	28.53
745.7059937	1.43
747.4733887	0.84
751.9712524	0.15
756.7675171	1.48
765.1494751	0.65
768.0670776	0.08
769.2615356	1.24
772.3062134	0.24
775.4596558	0.82
785.0075073	0.09
785.6231689	0.23
787.1775513	21.59
788.9381714	0.40
810.2427368	1.31
819.3875122	3.99
820.1682739	1.30
828.7833252	1.93
840.6152954	0.16
849.2057495	0.29
850.0125732	1.13
851.2645874	0.35
853.3281860	0.21
869.1981812	1.00
870.0540161	0.07
877.2554321	1.94
893.0820312	0.08
895.1894531	15.18
896.4957886	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	581.2809
Annotation	Unknow
Peak:m/z	Relative Intensity
178.7738953	0.31
191.0979004	0.19
196.8557129	0.77
220.6715393	0.11
228.1585388	0.06
241.2227173	0.22
242.1304626	0.25
254.2798157	0.54
257.1293335	0.10
269.2485352	0.21
271.1401978	0.14
274.2880859	0.20
287.3466797	1.32
296.0399170	0.11
299.4234009	0.27
300.1196289	0.17
315.3026123	0.25
321.1298218	0.09
329.3355103	0.11
341.2210693	1.28
355.0878906	0.17
357.2307129	2.62
359.3265991	100.00
360.4656982	1.85
361.2637939	0.44
371.2229614	0.09
373.3742065	0.71
375.2931519	0.45
376.4793701	0.17
377.1724243	0.13
383.1718140	0.46
385.3153687	0.24
391.5625000	0.08
399.5724487	0.24
401.2109985	0.40
403.4158936	0.17
404.9859619	0.21
412.4254150	0.06
413.2887573	0.49
417.1401367	0.55
418.4155273	1.20
419.4916382	8.62
424.9869995	0.17
431.2937622	0.47
433.2736206	0.09
434.3961792	0.15
443.5703735	0.67
447.3394165	0.10
448.2747803	0.69
449.3134766	13.56
449.9351196	0.38
455.5915527	0.98
485.3789673	0.64
491.5392456	0.26
501.5899048	0.20
503.3729248	4.87
505.0786743	0.19
508.3324585	0.15
509.2653198	0.81
519.4276733	13.62
521.3245239	68.78
522.6060181	1.08
534.7734985	0.57
535.4918823	0.34
536.6810303	1.07
537.3585815	2.16
539.5884399	0.77
545.3273315	1.62
563.3501587	11.83
570.1745605	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	540.32
Annotation	Unknow
Peak:m/z	Relative Intensity
165.3526001	0.02
177.1547699	0.05
195.0891418	0.03
198.7642822	0.04
208.0048218	0.04
246.2988586	0.10
247.0659180	0.02
265.1660156	0.09
278.3663330	0.08
294.2550659	0.02
311.3035278	0.43
312.3075562	1.17
319.2766113	0.03
322.2791748	0.07
323.1361084	0.16
330.2733765	2.96
331.1105347	0.77
332.1286621	0.10
333.2840576	0.10
336.5825806	0.04
342.4464722	0.17
346.2918701	0.03
347.1720581	0.03
348.5133667	0.15
352.3363037	0.07
353.3821411	0.06
360.5749512	0.04
361.4465332	0.09
371.2941284	0.02
374.5113525	0.02
378.4169312	0.21
384.2141113	0.02
388.4313354	0.42
389.4100952	0.67
390.3031616	2.62
394.3893433	0.08
395.1931152	0.24
406.3887939	0.45
408.3384399	100.00
409.0130005	0.21
418.9132690	0.18
420.3928223	0.10
425.1615601	0.03
425.8491821	0.20
426.4790039	1.99
429.2287598	0.04
435.3309326	0.02
444.3403320	0.67
444.9418945	0.01
445.8090210	0.10
450.4909668	1.89
462.4151611	0.07
474.5505371	0.02
479.3612671	0.03
480.3153687	0.39
485.5809937	0.31
486.4694214	0.66
494.1281738	0.06
504.5070801	7.60
509.6621704	0.13
510.3676147	0.03
511.3954468	0.06
513.1071167	0.04
514.4703979	0.03
521.4849243	3.05
522.4479370	4.39
523.2481079	0.30
524.6436157	0.33
531.3369751	0.09
540.4846802	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	401.145
Annotation	Benzyl beta-primeveroside
Peak:m/z	Relative Intensity
112.7886276	0.15
117.0264893	0.06
118.8774261	0.06
125.0169220	1.12
129.0109711	0.36
130.9712524	0.79
142.9052582	0.77
148.9061432	1.42
154.5517273	0.14
155.1622162	0.23
157.1315308	0.09
158.2869568	0.11
159.0127106	0.61
161.0376892	13.11
171.2866821	0.04
175.0582428	0.07
191.1628418	0.56
197.1032257	0.10
203.1645508	0.37
233.1548157	3.30
239.1259460	0.10
250.9886475	0.10
269.0516357	100.00
293.1964111	5.26
311.1664429	0.34
383.2170410	0.05
385.9187927	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	275.9924
Annotation	Unknow
Peak:m/z	Relative Intensity
97.0704651	0.36
98.6494522	0.11
114.0540390	0.55
115.8846970	0.45
125.9013062	0.33
126.8365173	0.90
127.8988647	1.20
130.8956451	0.21
131.9836731	0.69
137.8557434	0.37
139.8235626	0.24
140.9974670	0.11
143.8842926	1.33
144.8302612	0.51
151.7710266	0.48
155.8197021	0.31
156.9404297	1.04
157.9603882	0.10
158.8430328	0.29
165.9296722	0.43
169.9057159	28.61
170.9686127	0.52
171.9572906	2.15
173.9234619	59.91
174.8596497	0.74
181.9109955	8.05
183.8907928	1.25
185.8991699	5.01
187.2222290	2.72
187.8365936	2.04
189.7441406	0.18
191.7846375	0.20
195.2456970	0.92
196.0570068	0.25
197.9539490	20.01
199.9233704	43.98
202.0051880	0.45
203.9253845	4.90
209.9837036	22.85
211.9753113	29.54
214.0036926	0.98
215.9347229	30.14
216.9577942	3.04
217.9571228	9.15
219.9521179	0.33
221.7692261	0.35
226.2267151	0.71
227.9199829	100.00
229.0864868	3.58
230.0004272	18.21
231.1820679	1.55
231.9601746	3.35
233.1452332	0.52
233.9557495	0.74
234.8510437	38.69
235.8480835	0.54
236.6354980	0.18
237.7595825	0.18
238.7508850	0.16
240.0140991	9.55
240.9678955	0.18
243.3839722	1.11
244.1559753	0.35
245.8906250	21.14
246.6002197	2.12
247.7989807	1.94
252.7044983	10.73
253.6599731	0.68
254.8380127	1.34
255.6442261	2.89
256.5947266	0.27
258.0040283	83.53
258.9353638	0.38
261.1838074	2.76
262.4763184	0.66
264.2820435	0.70
264.9152832	0.43
266.8638306	3.27
269.9027100	0.60
275.7396851	1.40
284.4311523	0.48
288.9418945	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	630.8773
Annotation	Unknow
Peak:m/z	Relative Intensity
201.2896423	0.05
203.1232605	0.03
215.1075439	0.01
245.1334381	0.14
246.1267548	0.02
246.9756622	0.33
273.0146790	1.40
274.0779114	0.05
289.0706787	3.72
386.9652100	2.00
401.1284180	0.07
402.9459839	17.39
403.5952759	0.05
500.9037476	0.43
502.1589355	0.02
514.1727905	0.10
514.9493408	0.22
516.8533325	100.00
519.3546753	0.01
540.0806274	0.02
549.2566528	0.02
558.8724976	0.03
583.9341431	0.17
585.0483398	0.23
586.9180908	0.12
613.1287842	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.0629
Annotation	Unknow
Peak:m/z	Relative Intensity
184.0936279	0.02
191.0701294	0.53
193.0527649	0.13
203.1785889	0.06
206.8264465	0.03
209.0491333	3.19
211.1250000	0.17
223.0809326	0.12
246.3193817	0.05
251.8743591	0.09
255.3183594	0.05
260.1217651	0.12
273.3136597	0.18
285.2318115	0.37
287.1630249	5.44
299.1721191	0.04
305.0011597	0.29
309.4591675	0.16
311.1264648	6.76
314.9411011	0.06
318.1103516	0.03
323.1628418	0.11
324.0054321	0.11
327.1988525	0.30
329.2369385	0.48
345.2582397	0.06
371.1104126	0.04
372.9496460	0.32
380.3807373	0.52
381.2619019	0.09
384.2148438	0.20
387.3835449	0.12
400.8413086	0.05
402.4510498	0.12
403.1769409	0.18
411.4234009	0.18
416.1050415	0.03
417.0829468	0.02
422.3363037	0.05
423.1885376	0.22
431.3159180	0.29
433.4562378	0.06
438.2352295	0.12
447.1870117	1.42
448.0966187	0.12
449.0534668	0.33
451.7919922	0.18
453.4612427	0.19
456.3460083	0.08
457.5147095	0.09
459.1486816	0.08
460.6029663	0.03
463.2187500	0.54
464.1187134	0.09
473.4799194	0.28
491.1704712	100.00
491.7748413	0.58
492.9962158	1.30
497.6094360	0.06
514.2201538	0.06
516.2218018	0.05
517.3778687	0.19
518.4281006	0.17
519.2253418	0.17
520.2654419	0.11
532.0675659	0.54
533.1060181	0.33
534.4982910	2.10
535.1298828	51.33
541.3204346	0.09
542.0767212	0.12
558.1538696	0.05
560.5435791	0.24
561.1806030	1.02
570.1917114	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	682.2581
Annotation	Unknow
Peak:m/z	Relative Intensity
270.4163513	0.09
273.3500977	0.07
316.0411377	0.05
326.7350464	0.02
342.3383179	0.06
354.2449951	0.06
355.0548096	0.21
357.4151611	0.06
366.3972778	0.04
371.3767700	0.08
374.3184814	0.02
378.2575684	0.02
380.5108032	0.05
381.2951660	0.04
388.4213867	0.02
399.3638306	0.04
407.4776001	0.02
442.6079712	0.07
452.1428223	0.12
455.1381836	0.28
461.3949585	0.05
464.8505249	0.02
467.7330322	0.03
471.4930420	0.05
474.0726318	0.09
478.3761597	0.13
481.2305298	0.09
485.3750610	0.33
487.3408203	0.20
488.4399414	0.18
489.2887573	0.05
491.3106079	0.31
493.4893799	0.03
497.2949219	0.17
499.5429077	0.12
500.5196533	0.08
501.5406494	0.17
506.3270874	0.08
512.4263916	0.02
516.6234131	0.07
519.2696533	0.23
520.3303223	0.50
526.4124146	0.08
529.2905884	0.33
541.3607788	0.04
542.3261108	0.05
543.1721802	0.03
544.6395264	0.04
545.3376465	0.07
548.4959717	0.15
550.3761597	0.19
562.3916626	0.09
570.4148560	0.07
578.5985718	0.07
580.2665405	0.61
581.5466309	0.22
586.3995361	0.35
588.4678955	0.07
592.4686890	0.25
596.3616943	0.09
601.2298584	0.15
602.0849609	0.03
602.6992798	0.03
604.5370483	0.21
606.4601440	0.06
609.4372559	8.94
610.2521973	0.06
612.9999390	0.38
614.3253174	2.77
615.3297119	0.10
618.2424927	0.31
622.3394775	2.17
626.0488892	0.11
628.5274658	0.13
632.3722534	1.63
636.2460327	0.95
637.0391235	0.21
640.3048706	0.13
645.6858521	0.66
646.3541870	1.35
650.2917480	100.00
651.1895142	0.03
652.3527222	0.31
654.3328247	2.93
663.7541504	1.20
664.4280396	3.57
665.2007446	0.40
681.2155762	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	639.28
Annotation	Cryptophycin 46
Peak:m/z	Relative Intensity
189.0404053	0.11
191.0665741	0.03
205.3014526	0.05
214.7185516	0.15
229.0486145	0.06
230.9037170	0.14
233.0077820	0.09
239.1173553	0.04
242.3285828	0.05
243.0400696	0.12
245.2698822	0.11
247.1740417	0.03
249.3428650	0.17
250.1427460	0.07
251.3101501	0.12
269.0609131	0.11
275.1819153	0.07
277.2248840	0.06
282.3208008	0.07
283.2703247	0.10
287.0019531	0.05
289.1011353	0.07
297.0535278	0.10
301.4306030	0.09
304.9626465	0.23
309.1602173	0.08
315.1863403	0.06
316.9887085	0.04
325.0838013	0.03
328.8039246	0.03
331.1246948	0.19
337.3406982	0.03
340.8819580	0.40
341.6069336	0.04
356.6419678	0.04
359.2306519	0.07
360.2730713	0.06
369.2922974	0.92
371.2219238	1.11
373.2827148	0.29
374.3338623	0.02
382.5042114	0.02
384.1240845	0.18
385.1548462	0.34
386.6501465	0.65
387.4415283	0.04
388.4755249	0.45
389.3609009	3.01
397.4082031	0.11
399.7227173	0.04
403.1480103	0.08
404.8908691	0.03
406.9739990	1.35
421.3571777	0.08
422.1426392	0.04
425.2283325	0.16
429.8980713	0.08
433.6601562	0.20
435.6472168	0.14
440.4448853	0.08
443.1212769	0.02
448.6462402	0.05
450.7327271	0.05
453.3602295	0.12
454.6667480	0.09
463.5390015	0.09
471.2827148	0.19
473.4272461	0.20
475.2897339	0.07
479.4011841	0.15
481.3093872	0.05
488.3768921	0.11
493.4747925	0.04
499.9466553	0.25
509.3574829	0.17
510.2291260	0.16
519.5451050	0.05
521.3165283	0.16
523.4906006	0.11
526.3386841	0.09
527.6542358	0.11
533.4605103	0.21
534.6303101	0.18
535.3961182	0.28
537.2841187	0.55
539.4490967	0.09
540.1801147	0.12
547.5171509	0.09
549.3706055	0.04
552.1130371	0.05
553.3211670	0.47
557.5311890	0.09
561.0661621	0.07
563.3904419	1.94
564.9784546	0.77
565.6038208	0.50
567.3218384	4.15
568.4066772	0.33
569.6232300	0.39
571.3068237	0.20
572.4060059	0.15
575.4982300	0.33
576.3247070	0.11
577.2330933	0.06
579.2835083	1.36
580.0273438	0.24
581.6318970	0.37
582.5444946	0.18
583.4570923	1.09
589.3770142	0.47
593.3157349	0.46
595.3231812	4.18
597.3369751	100.00
598.3502197	0.19
602.7170410	0.13
603.5211792	0.17
604.4201660	0.10
605.6525879	0.03
607.3767700	14.74
608.6583862	0.14
611.3849487	20.11
612.0928955	0.09
621.4226685	13.36
622.4774780	0.63
623.1760254	0.14
624.4371338	0.75
625.5239258	0.05
639.4104004	0.16
640.1745605	0.02
649.4587402	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.0603
Annotation	Unknow
Peak:m/z	Relative Intensity
131.9794159	0.05
134.0794067	0.94
139.1838379	0.06
143.3162842	0.29
144.1511993	0.04
146.2072754	0.27
148.9623260	0.07
160.1242065	0.58
160.9544373	0.08
175.0208130	2.78
186.8203735	0.05
191.1211548	0.06
193.0927582	12.93
199.0195923	0.02
202.1422729	0.07
206.0823059	2.45
207.1739655	0.21
209.0070038	0.03
210.2861176	0.16
217.0946960	6.87
220.5204773	0.08
227.1474457	0.14
228.0826721	0.71
229.1544952	0.15
235.1793518	1.61
238.2473755	0.03
241.1169128	2.92
244.2974854	0.03
247.1261902	1.60
250.3201294	0.07
259.0929871	6.45
265.2267151	2.80
270.2616272	0.83
271.2297668	0.10
273.1028442	6.39
277.1885986	0.05
287.3374023	0.76
288.0586548	0.03
295.1597900	1.03
300.4105530	0.06
305.0802002	0.15
315.4341431	0.08
320.1510010	0.08
331.3868103	0.07
334.2952576	0.04
337.1981506	0.36
345.3795776	0.24
347.0880127	0.11
355.2415466	100.00
356.3266907	0.07
356.9567261	0.04
359.4533997	0.07
360.9747925	0.04
363.0780334	0.28
372.0238342	0.03
372.9451599	0.12
374.0864258	0.73
375.0669250	0.58
387.9986877	0.17
389.1368713	0.71
390.3451233	0.82
391.1569519	0.10
398.9123535	0.28
415.2270508	0.03
416.8316040	0.13
417.9260254	0.17
426.0784607	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	426.2496
Annotation	Unknow
Peak:m/z	Relative Intensity
128.1177216	0.04
133.9650421	0.03
145.0172729	0.06
149.6430359	0.05
160.9664154	0.02
180.2337036	0.09
183.9662476	0.03
185.2958374	0.02
187.1786499	0.04
201.2574463	0.04
210.1671295	0.04
226.4563904	0.03
236.0454712	0.02
243.1306763	0.08
243.9377136	0.02
247.1623840	0.08
262.0523376	0.03
263.2743530	0.15
279.8990784	0.06
283.0838318	0.04
287.0391235	0.04
288.2451782	0.41
291.1940308	0.05
300.3458252	0.02
307.0610046	0.04
328.0510864	0.14
331.0377502	0.07
340.2290649	0.05
345.4757080	0.02
346.6092834	0.01
348.2407837	0.03
362.3320923	2.52
364.0116882	0.09
365.8820801	0.03
377.8257141	0.03
380.2264099	100.00
380.8467102	0.44
382.0291443	0.04
384.5171814	0.03
390.2084045	0.19
391.3411255	0.03
394.6600342	0.05
397.1961975	0.02
398.2467041	0.05
405.3708191	0.03
407.2728882	0.18
408.1073914	0.41
409.2450562	0.11
411.1432800	0.05
412.2177429	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	352.2108
Annotation	Dipivefrin
Peak:m/z	Relative Intensity
112.0220871	0.06
120.0816269	0.02
121.0366669	0.02
125.9552307	0.06
130.0310211	0.02
132.0500793	0.77
134.3035889	0.03
146.2951050	0.11
157.1712646	0.04
163.9901733	0.02
168.1518402	0.02
173.3228149	0.08
176.0518646	0.02
183.2177734	0.42
195.2797546	0.04
199.1070251	0.05
201.2151184	0.22
202.0913696	0.12
209.2395172	0.06
215.3487244	0.13
218.2359009	0.07
222.2606201	0.03
227.0645142	0.04
230.5058594	0.02
232.3280334	0.05
237.3772583	0.02
242.1922913	0.03
245.9980774	0.03
250.2536316	0.48
251.1480103	0.07
256.3878479	0.03
258.1486206	0.05
260.0965271	0.01
262.3216248	0.17
263.4179688	0.08
268.2644043	2.12
270.8218994	0.20
274.3158569	1.96
280.2812195	3.05
286.2266235	1.88
288.2355347	0.04
298.2464600	8.21
298.9700928	0.08
310.9801941	0.02
316.3166809	16.18
334.2330017	100.00
334.8461914	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	370.2216
Annotation	Pramanicin
Peak:m/z	Relative Intensity
117.1251068	0.02
118.6877518	0.03
131.9745941	0.08
140.9631042	0.04
146.1306152	0.02
147.2930450	0.15
150.1972046	0.02
155.0506592	0.02
156.9715424	0.04
173.0243073	0.28
178.1733398	0.05
183.1173096	0.33
191.2248840	0.02
196.7937622	0.06
201.8560638	0.02
202.8946533	0.03
205.1275940	0.14
205.7673187	0.02
207.4099121	0.05
211.2588196	0.12
212.1855774	0.05
213.4242859	0.04
218.1920166	0.07
223.1101379	0.06
229.9638367	0.11
230.8821106	0.01
232.1752625	0.22
233.1687927	0.09
234.2392883	0.05
238.0856934	0.05
241.3302307	0.04
242.1246033	0.05
243.1210022	0.02
244.1177673	0.05
245.2232666	0.04
248.2482605	0.29
250.2337646	0.03
252.0473938	0.06
256.3374634	0.07
260.2063293	0.04
262.0827026	0.16
268.1979370	0.97
270.3673706	0.20
272.3722534	0.06
274.3464355	0.94
276.4685059	0.09
277.9836731	0.26
280.2368164	1.58
281.2164307	0.03
283.9976196	0.20
286.2789917	1.06
288.3609009	0.18
291.9530334	0.10
296.3417969	0.02
297.6038818	0.14
298.2893066	3.89
299.4752197	0.06
304.2914429	0.04
308.9404907	0.07
311.4983521	0.10
316.2925415	9.99
318.0012207	0.08
324.4086304	0.03
326.7035217	0.05
327.4631348	0.05
328.3120117	0.09
329.2044983	0.03
334.2559204	38.75
335.1292114	0.11
339.4635925	0.04
352.2158508	100.00
352.8908386	0.42
360.5110168	0.04
370.5166321	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0877
Annotation	Grevilloside F
Peak:m/z	Relative Intensity
113.0336380	0.04
119.1240692	0.05
125.9888611	0.09
130.9851379	0.04
133.0250702	0.86
133.8595734	0.03
135.0290985	6.03
160.9896545	29.71
163.0802460	0.09
175.0373077	0.16
177.1105957	0.12
179.0146942	100.00
193.1161346	0.14
196.0993652	0.05
199.3639832	0.06
203.0235748	7.65
217.0731201	0.10
219.2578125	0.09
221.0708008	1.39
225.9986267	0.02
227.2623901	0.12
231.2598877	0.02
232.9671631	1.07
245.2392883	0.06
249.0715332	0.01
251.0642700	2.15
260.8566895	0.12
262.8836670	0.04
267.2799683	0.07
277.2633972	0.03
281.1159668	5.87
292.9810181	0.08
297.1905823	0.05
305.2192688	0.44
311.1868286	0.12
313.0811157	0.03
323.2005005	0.84
323.9729614	0.02
340.9948425	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	913.1825
Annotation	[Gallocatechin-(4alpha->8)]2-gallocatechin
Peak:m/z	Relative Intensity
255.0302124	0.06
257.0610657	0.30
261.0706177	1.15
262.2311401	0.57
265.2765198	0.22
269.2879028	0.05
273.0199585	0.18
283.2712402	0.48
285.0987854	0.78
286.9388733	0.22
296.9916687	0.11
298.2477417	0.04
301.2030945	0.31
303.1871338	8.59
304.1903076	0.76
305.2078552	7.37
306.1504517	0.89
307.1703491	0.05
309.2285156	0.20
312.8917847	0.06
315.1719360	0.94
316.4288940	0.03
321.1609497	0.23
324.8901367	0.10
330.2853699	0.15
331.0951538	0.22
338.4627686	0.04
341.4583435	0.17
343.0741577	0.08
343.9334412	0.10
345.2353516	0.27
347.4343262	0.49
349.3197021	0.18
355.0034180	0.05
357.2938843	0.49
361.2756348	0.13
369.1821899	0.07
370.0753784	0.05
374.2381592	0.18
379.0789185	0.93
380.0274658	0.23
383.2031860	0.28
385.0969849	0.41
386.3060913	0.03
387.3031006	0.17
391.1148682	1.24
392.1253052	0.76
393.0715332	0.10
395.2470093	0.06
397.2250977	1.29
399.1395264	0.20
400.0600586	0.15
403.2111816	0.12
405.2887573	0.06
408.2415466	0.04
409.1706543	0.14
411.1938477	2.11
412.3754272	0.72
413.2377930	0.58
414.4054565	0.10
419.2598877	0.29
420.0888672	0.07
421.1284180	2.48
422.3505249	0.48
423.1789551	18.65
424.1990356	3.16
425.1281738	0.13
427.3875122	0.48
429.2425537	5.72
430.2416992	1.11
433.2255249	0.17
434.3805542	0.12
437.6587524	0.41
439.1954346	3.16
441.1578979	8.17
442.2097168	1.99
449.3348999	0.24
451.2747192	0.69
452.3500977	0.21
453.2952271	0.13
454.1282349	0.10
463.2219238	1.08
464.2897949	0.33
465.1988525	2.58
466.1759033	0.50
467.1054077	0.22
468.1608276	0.04
469.0753784	0.47
470.1524048	0.20
471.0909424	0.04
479.0532837	0.20
481.0974731	6.33
482.1369629	1.69
483.1321411	14.06
484.1237793	2.13
485.1425171	0.06
491.0658569	0.06
495.2926636	0.14
500.0457764	0.04
507.2680664	0.11
515.1998901	0.26
516.5307617	0.14
519.4577637	0.12
521.2111816	0.16
523.1237183	0.26
525.2564697	0.22
526.3056641	0.05
527.1447144	0.54
533.1624756	0.49
541.2734375	10.17
542.2188110	1.44
542.8506470	0.03
545.2753906	0.07
547.1997681	1.44
548.1541748	0.54
549.1159668	0.10
550.3319702	0.09
559.1691895	32.49
560.1464233	5.65
563.1832275	0.23
565.2176514	3.11
566.1397705	0.35
567.2728271	0.15
568.2396851	0.16
570.3001099	0.10
571.3911133	0.04
574.2886963	0.55
577.1087646	5.94
578.1398926	1.47
579.0400391	0.26
583.3695068	0.48
584.3699341	0.08
587.2667847	0.03
589.2149048	3.07
590.4458618	0.44
591.2705078	2.51
592.3378296	0.77
593.3110962	0.46
599.0955811	0.31
601.2201538	3.53
602.2274780	0.77
603.0216675	0.16
605.0577393	0.12
607.1718750	8.08
608.5438232	5.51
609.2560425	18.86
610.3062744	4.96
611.4052734	0.19
612.1549683	0.07
617.0065308	0.31
619.1699829	7.37
620.2210693	2.77
626.4271240	0.09
631.4400024	0.25
633.2888794	0.10
634.5375366	0.18
643.3083496	0.14
645.2987671	0.36
646.1043701	0.24
648.2877808	0.66
649.3027954	0.60
651.0681152	3.14
652.2973633	1.51
655.2279053	0.04
661.1459351	0.88
662.0918579	0.23
663.8035278	0.12
667.7069702	0.88
671.3317261	0.07
683.3743286	2.03
684.2668457	0.20
697.7136841	0.43
699.1330566	0.19
701.1781616	1.30
702.2758179	0.43
708.1469116	0.26
709.2346191	6.06
710.3461304	1.63
724.9893188	0.09
727.2056274	100.00
728.2592163	28.36
733.1611938	0.14
735.8393555	0.09
743.2990112	0.90
744.4903564	1.76
745.1172485	38.96
746.1573486	7.49
747.3601685	0.04
756.8467407	0.91
757.5239258	0.16
758.4998779	0.07
759.3746948	0.57
760.8820801	0.55
761.5562134	0.17
766.2887573	0.13
768.0488281	0.19
769.1480713	1.69
770.2208862	1.30
774.5664673	0.57
775.4443970	0.25
776.4985962	0.05
785.3577271	0.14
787.1596069	25.73
788.2915649	10.26
810.8384399	0.44
811.6177979	0.06
820.1377563	0.80
820.8150024	0.56
829.1381226	1.80
829.9212646	0.55
840.2941284	0.10
850.0858765	0.20
851.1995850	0.34
852.2245483	0.09
859.6610718	0.16
863.2431030	0.14
869.1865845	0.40
870.2948608	0.24
877.3887939	0.07
893.7514648	0.29
895.1571655	11.82
896.1693726	7.32
898.5683594	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.09
Annotation	Lactulose
Peak:m/z	Relative Intensity
125.0517502	0.05
143.0377655	0.19
161.0740051	0.17
165.3062592	0.03
179.0482788	0.89
189.8785095	0.03
197.1284332	0.43
209.0641785	0.24
215.0281982	8.07
271.0627441	0.04
285.0034790	0.07
291.1715698	0.02
293.1635132	0.03
316.9784546	0.07
341.1666260	100.00
347.1897583	0.04
359.1573181	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.1613
Annotation	2''-Epifraxamoside
Peak:m/z	Relative Intensity
161.0786591	0.07
172.9971313	0.34
179.1089172	0.07
180.2590942	0.10
183.1836548	0.24
190.4646606	0.16
191.0928192	5.00
196.9116669	0.06
203.0795593	0.16
209.2204437	0.20
218.7945862	0.06
225.7958984	0.21
281.2354126	0.14
289.1963501	0.10
293.1202393	0.17
309.2198486	0.98
313.2952271	0.50
325.1837158	0.07
330.0401001	0.31
335.1068726	1.69
339.2131348	0.09
346.9286499	0.07
353.0891724	2.65
355.1508789	0.06
357.1604614	7.21
361.5288086	0.31
371.6685791	0.13
373.2050781	0.16
375.1453857	100.00
375.7909546	0.52
381.0444946	0.10
381.8872681	0.09
387.4106445	0.36
388.6439819	0.40
391.6843872	0.04
405.2832031	0.35
407.4321289	0.26
411.1282959	0.09
413.4496460	0.05
415.2159424	0.09
417.2485962	1.89
429.0770874	1.18
440.9479370	0.51
447.0527344	0.05
451.0418091	0.07
456.6083374	0.51
457.2822876	0.35
463.2841797	0.62
465.2982788	0.15
475.0476074	0.61
477.3616333	0.20
491.0872192	0.14
492.1795044	0.11
493.2041626	0.30
494.4772339	0.34
495.2529297	0.17
500.0896606	0.12
503.3672485	0.05
504.0632935	0.08
505.8672485	0.41
509.3223267	0.17
515.0382690	0.46
518.2232056	0.21
519.2858887	2.81
520.2831421	0.46
522.5102539	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	390.1383
Annotation	Unknow
Peak:m/z	Relative Intensity
119.0024948	1.03
122.9277802	0.31
128.9236450	0.08
135.9707947	3.95
137.2526398	0.04
146.9521484	1.50
158.0763245	0.04
163.0133057	0.44
165.0292664	11.49
182.0070648	100.00
182.8962097	0.05
190.8285980	0.12
208.0970459	0.13
211.1699829	0.28
214.7873688	0.10
219.1418457	0.13
222.1271057	0.09
225.2730408	0.10
228.0806885	1.19
239.0495300	0.15
240.0557251	0.06
242.4503174	0.25
243.4532166	0.33
254.9859314	0.04
255.9855652	0.18
257.2714844	0.27
258.1636658	0.12
259.0918884	0.13
261.1857300	0.05
262.2780457	0.14
269.1492920	0.07
273.9805908	0.07
276.1660767	0.25
283.9953918	0.07
289.3829346	0.10
301.3565063	0.08
302.4608765	0.13
303.2029419	0.10
308.2612305	0.28
310.1087646	0.05
315.0631104	0.27
325.9561462	0.06
327.3183899	0.05
330.1436157	0.18
332.5374451	0.18
345.4436340	0.11
347.9984741	0.14
353.3389893	0.04
355.3178711	0.09
358.3086243	0.04
371.3799744	1.69
372.3519287	1.56
373.3487244	0.09
380.4332581	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	307.0804
Annotation	Leucocyanidin
Peak:m/z	Relative Intensity
122.9108276	1.11
127.1261749	0.24
129.2318726	0.09
130.0057678	0.07
132.7355652	0.11
139.0444489	95.49
140.1560669	0.04
150.9519043	74.75
151.5686951	0.16
153.0843811	1.83
163.0925903	1.50
168.9985657	7.50
179.2780762	0.11
180.9849091	10.46
182.1006622	0.16
187.1317596	0.15
201.1126099	0.12
214.7889099	0.24
237.2089844	0.10
243.4907532	0.51
244.5868225	0.10
247.2902222	0.13
259.9669189	0.11
261.0081177	0.61
262.5262451	0.10
265.0567627	0.10
265.9623413	0.14
270.9033508	0.07
289.1035767	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	848.5118
Annotation	Unknow
Peak:m/z	Relative Intensity
236.0936432	0.08
247.2143860	0.08
249.2257690	0.24
251.1038513	1.04
253.1437073	0.24
253.9079895	0.02
255.2821655	0.22
256.0837708	0.13
263.3370056	0.08
265.0367126	1.23
267.0758057	0.31
269.1750488	1.61
270.2015991	0.09
271.2868347	0.26
277.2937927	0.05
278.2879639	0.03
279.0065002	0.10
281.1656189	0.04
287.2213135	0.07
293.1287231	0.09
294.2253113	0.05
295.0729675	1.66
296.3106689	0.12
297.2759094	0.45
297.9060364	0.02
299.3256836	0.12
303.3755188	0.06
306.1983032	0.04
309.0004883	1.26
309.7925415	0.30
311.2156067	1.06
312.6124573	1.07
313.2951050	0.76
314.1553955	0.31
315.2993164	0.38
323.4498901	0.12
324.8894043	0.04
327.0625000	0.13
328.4197388	0.31
329.3080139	0.66
330.2301636	0.10
337.1909790	0.12
339.1872864	0.27
340.0927124	0.06
342.2237854	0.02
343.3474121	0.15
351.0840149	0.21
353.0875244	1.80
354.1620483	0.40
355.0797729	0.75
355.8739014	0.31
357.0838318	0.67
358.0980530	0.13
359.0676880	0.14
371.3568726	0.20
373.2007751	7.03
374.1651611	1.56
375.1855469	0.41
375.9859619	0.02
379.2552490	0.06
381.2681274	0.22
383.2592163	0.11
384.3631592	0.36
395.3039551	0.09
397.2628174	0.85
398.1603394	0.07
399.2663574	0.19
400.6614380	0.73
401.3676758	0.94
402.2474365	0.11
403.0603027	0.32
415.2863159	0.98
417.1027832	2.56
418.1664429	0.33
419.4235229	0.41
422.3382568	0.08
427.2244263	0.18
433.1386108	0.15
441.2373657	1.55
442.2440796	0.19
443.3650513	0.34
444.4000244	0.23
445.3040161	0.83
446.6480713	0.20
447.5712280	0.13
459.2756958	0.63
460.4886475	0.63
461.1583252	0.56
462.3669434	0.14
463.1891479	0.48
464.2038574	0.12
470.8746948	0.04
475.6007080	0.04
476.2769165	0.20
479.2919312	0.15
485.2566528	0.79
486.3260498	0.04
489.1626587	0.70
489.9375000	0.03
491.3381958	0.17
501.2207642	0.07
503.2348022	0.10
504.2719116	0.26
505.1377563	0.84
506.1347046	0.32
507.2326050	1.28
508.0913696	0.27
508.7896118	0.21
522.1072998	0.05
523.2559814	0.26
524.6626587	0.32
529.1117554	0.22
532.5191650	0.16
533.2420044	0.16
547.4061279	0.35
549.1422119	1.51
550.3369751	0.24
551.5164185	0.32
567.2645874	0.66
568.0123291	0.01
568.6525269	0.02
577.2487183	0.20
578.4891968	0.03
593.2017212	1.51
594.2698364	0.45
595.2137451	0.46
596.3090820	0.28
611.3168335	0.78
612.3079224	0.20
621.2433472	0.30
623.3430176	0.30
637.1620483	1.82
638.1586304	0.62
639.3184814	0.60
640.2332764	0.23
655.4794312	0.66
656.3552856	0.27
665.1890259	0.03
668.3297119	0.06
681.0903320	0.74
683.2280884	1.13
684.3867798	0.35
699.2585449	1.62
700.2420044	0.15
708.7489624	0.14
709.5491943	0.17
725.4257202	1.19
726.1870728	1.05
727.2951050	14.14
728.3509521	2.85
743.2894897	2.92
744.3327026	1.32
767.4733276	0.06
768.9796143	0.12
787.3419800	3.66
788.4867554	0.98
812.9006958	0.61
813.5465698	0.41
814.1854858	0.19
831.3018188	100.00
832.3255615	31.31
832.9445190	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	409.0445
Annotation	Unknow
Peak:m/z	Relative Intensity
138.8293915	0.01
150.1232452	0.03
167.0475159	0.58
179.1052856	0.02
181.0704041	0.01
199.5595398	0.05
203.1040039	0.14
209.0519409	0.82
210.3131561	0.08
225.2755127	0.03
239.1535339	0.19
241.0506592	1.12
247.0592041	2.91
259.1106262	6.58
269.1740112	0.43
270.5997009	0.02
271.2215881	0.04
273.1141357	0.07
277.0741577	0.06
285.0788879	0.04
287.2318115	0.05
293.4679260	0.05
305.1490479	0.05
314.2423096	0.04
325.0193787	0.02
329.1533813	100.00
329.7620850	0.26
344.9867249	0.05
361.1034851	0.02
363.2003479	0.29
365.1809998	0.12
373.1058044	0.02
381.0730286	0.06
391.1947937	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.0984
Annotation	Quercetin 3-(6''-ethylglucuronide)
Peak:m/z	Relative Intensity
151.0796509	0.77
151.9358978	0.05
153.0354462	0.19
157.0062561	0.04
162.9585571	0.14
164.0246887	0.18
165.1573944	0.07
168.9796753	0.10
173.8916626	0.05
174.9992676	0.03
179.1000061	2.76
180.0788116	0.48
181.3325348	0.02
187.1348877	0.04
189.2027283	0.12
189.9584808	0.16
191.2784729	0.17
193.0423431	0.24
197.1164093	0.06
198.0942383	0.03
201.2545776	0.11
205.1319885	0.05
207.2684326	0.04
209.0513916	0.14
211.0925751	0.05
212.1363983	0.05
213.2048645	0.10
214.8716736	0.11
216.9802246	0.19
217.9699097	0.01
219.2059479	0.13
221.3401489	0.04
225.9214935	0.05
227.0702209	0.23
228.3144989	0.07
229.1932220	0.28
230.2651672	0.04
231.0902100	0.12
232.1260986	0.03
233.2215729	0.05
237.0910339	0.02
240.4838409	0.03
242.0922089	0.07
243.2013397	0.04
244.3704529	0.02
245.2572327	0.18
246.1259918	0.01
249.1635742	0.02
251.5720520	0.03
253.2891235	0.03
255.2380371	1.72
256.2784424	0.64
257.0950928	0.29
258.0329895	0.02
259.1623535	0.02
263.0582581	0.03
264.9859924	0.07
269.3197021	0.06
271.1231384	2.50
272.1158447	0.78
273.1521301	0.67
274.2843628	0.06
275.4945374	0.01
281.1916504	0.14
283.3405151	0.17
284.1899719	0.07
285.0817871	0.04
287.1798096	0.05
291.1091003	0.09
292.1092834	0.03
293.0278320	0.01
294.1718750	0.06
296.3165283	0.08
297.2310791	0.30
298.6185913	0.44
300.0780640	65.75
301.0951538	100.00
302.1954346	14.07
303.2559204	0.08
307.8658447	0.06
310.3000488	0.03
311.1402588	0.22
313.1861267	0.37
313.9550476	0.05
319.8635864	0.22
323.4298096	0.05
324.1282043	0.11
325.2359314	0.36
326.2376404	0.02
327.2694702	0.02
329.1588440	0.04
330.2905273	0.01
335.2009888	0.13
336.0590820	0.06
337.1826172	0.05
338.1188049	0.03
339.6378784	0.13
341.1967773	0.12
343.1473083	3.49
344.2199707	0.52
351.2289429	0.10
353.1662598	0.15
355.1425171	0.18
356.3544617	0.17
357.2649841	0.13
359.1390076	0.04
360.2092590	0.04
367.2740173	0.03
369.3109131	0.06
373.0643311	0.02
377.3514709	0.03
379.2093811	0.33
380.1124573	0.05
381.5343323	0.01
385.1159973	0.33
395.2279358	0.19
396.3831482	0.04
397.1982727	0.07
401.3117981	0.16
402.2812195	0.06
409.2090759	0.15
410.1415100	0.03
415.1382446	0.14
417.3191833	0.03
418.6812439	0.02
420.3115234	0.03
422.2783508	0.04
427.1540833	0.26
428.2720947	0.09
442.9492188	0.04
445.1523743	67.31
446.1889038	19.27
463.2092285	13.38
464.2214661	3.53
469.2951050	0.03
487.1955872	0.71
488.2763062	0.10
492.0427856	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	382.1142
Annotation	1H-Indol-3-ylacetyl-myo-inositol
Peak:m/z	Relative Intensity
112.3918304	0.21
112.9982910	0.16
118.7766800	0.05
128.8645325	0.15
130.0655823	0.24
142.9240723	0.41
161.0526733	2.35
173.0511475	0.18
174.0644531	11.07
178.9512024	0.07
188.0729523	0.26
198.0710754	1.96
206.8760071	0.44
216.1089630	3.26
224.1210632	0.03
226.3964539	0.02
228.2272644	0.22
240.1921387	1.10
246.0544434	5.18
263.7692261	2.29
273.0741577	0.15
274.4884033	0.14
276.0272827	22.35
277.3613586	0.09
286.0796509	0.11
288.3179932	0.03
291.2663879	0.03
293.2197571	0.28
298.0286255	0.12
301.3359985	0.04
307.1304016	0.07
309.1408997	0.22
312.3955688	0.13
317.6121826	0.22
318.2849426	0.25
319.1956177	0.53
322.0028992	0.05
323.2541199	0.02
324.1262817	0.13
325.2409973	0.08
333.0771484	0.05
334.1133423	0.03
335.9671021	100.00
337.2259521	2.22
338.2140503	0.57
345.3699646	0.03
346.1536255	0.15
349.5548706	0.03
361.3449707	0.24
363.1302795	0.70
364.2930603	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.927
Annotation	Unknow
Peak:m/z	Relative Intensity
148.9332733	1.36
150.7961121	0.56
158.9576721	0.15
162.9196167	0.10
165.2967224	0.04
168.0134430	1.10
171.9487000	1.26
172.9832764	0.84
174.2066956	0.22
178.9268188	0.10
179.8664856	0.12
184.1690826	0.06
189.6798401	0.39
200.9672546	0.14
208.0792236	0.10
209.0268250	1.36
209.9352722	0.92
210.9206848	0.39
212.0601196	49.90
216.1822052	0.10
216.9016418	0.22
224.2063293	0.10
226.9863281	0.24
228.0292053	0.19
238.0332642	0.95
241.0747375	0.08
241.8093567	0.21
242.9412231	0.44
243.9377441	0.23
244.8662415	0.21
251.0633240	0.24
251.8632812	0.15
254.1941223	1.29
255.9515381	100.00
256.5925293	0.14
259.9689026	6.45
261.1941833	0.05
265.1233521	0.05
267.4401245	0.39
268.1398315	0.20
269.0734863	0.15
269.9876709	3.56
272.0166626	2.63
274.8686829	0.20
275.8323669	0.36
280.2948303	0.03
281.0158081	0.42
281.8936462	7.36
283.0403137	0.09
284.1029358	0.08
285.2201843	0.12
286.0783081	0.69
288.0971680	0.50
292.0291443	0.38
294.8361206	0.23
295.4391785	0.26
297.9131470	5.00
299.9112244	12.50
300.5259705	0.26
302.0619202	0.77
304.3111877	1.03
306.0699768	2.42
306.9231262	0.11
310.4984741	0.31
311.1268005	0.76
313.1685791	0.14
314.2171631	0.58
315.9656982	17.33
316.9692993	0.29
317.8522949	0.05
325.8763123	6.72
326.8858032	0.18
328.3359985	0.08
330.2650757	0.08
331.1984253	0.35
333.0222473	0.57
335.1402893	0.36
340.9798279	1.52
342.0503845	2.68
342.9731445	1.59
343.9988098	3.20
359.1253357	0.45
360.1301270	0.62
367.0348816	0.14
369.6054382	5.09
370.3565063	0.13
371.0016174	0.19
372.2366638	0.66
384.7182312	0.36
385.3763733	1.57
386.1846313	0.23
387.9729004	26.32
393.9800110	0.19
395.0635986	3.96
396.1543274	0.20
411.8017883	0.08
413.2165833	4.18
413.9181824	13.09
433.1862183	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	680.9279
Annotation	Unknow
Peak:m/z	Relative Intensity
208.7885437	0.05
212.8566284	0.72
232.0303345	0.20
240.2023315	0.08
271.0325317	0.19
275.0648193	0.11
279.1378784	0.16
289.0373535	1.03
292.8354492	0.51
301.0873718	0.60
308.8148193	0.05
315.7355347	0.05
319.0588989	13.45
321.1015015	0.05
324.2958374	0.17
325.2579651	0.14
332.9151001	0.26
337.1310425	0.12
338.8280029	0.12
340.2059326	0.08
347.9741821	0.07
350.9170532	0.11
356.9517212	0.14
357.9990234	0.39
360.8203125	0.05
368.9634399	0.35
370.6463013	0.08
382.9832764	6.68
396.3182373	0.17
401.1024170	27.68
406.9703369	3.90
410.2237549	0.10
419.0239868	1.21
421.0333862	1.41
427.9389648	0.02
431.1632690	0.21
436.8928833	20.30
438.9746704	8.87
442.9865112	0.03
444.3402100	0.05
448.1473389	0.02
449.0894775	0.10
454.9380493	1.58
468.8712769	0.09
472.8997192	0.12
476.1817017	0.30
500.9826660	4.35
502.0424194	0.15
502.7202759	0.07
504.9840088	0.12
506.8513184	14.13
507.6248779	0.18
509.1018066	0.13
512.7768555	0.27
517.5646362	0.16
518.9373169	100.00
519.5977783	0.30
524.8253784	0.42
526.0335083	0.12
531.0186157	1.39
544.7507324	1.77
548.9302368	0.21
551.3348999	0.07
560.7831421	0.37
562.6385498	0.08
568.9600220	18.50
569.5887451	0.04
582.9067993	0.29
585.3834839	0.19
594.8921509	0.23
596.0767212	0.43
596.8288574	1.20
602.7270508	0.09
621.0137329	0.29
634.6250610	0.16
638.0320435	10.68
638.7028198	0.37
644.9746704	0.15
656.4834595	0.16
657.5564575	1.04
663.0888062	3.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	350.1972
Annotation	Dipivefrin
Peak:m/z	Relative Intensity
106.9937363	10.95
108.2094879	0.59
114.0226593	0.20
122.9312897	0.28
130.0684967	0.38
133.0798340	0.85
134.3856354	0.13
135.0753479	0.57
136.0491333	0.25
136.7699890	0.17
147.1574402	0.18
149.0113525	1.04
153.0216370	0.51
160.0422974	0.12
161.3558044	1.36
162.0605469	0.10
163.1333618	0.77
165.9078674	0.59
170.0997009	0.13
174.1826477	0.46
176.1437073	0.90
178.1162262	1.71
179.9748230	0.32
182.0326233	0.37
183.0988159	0.29
186.0982666	0.96
187.1911926	0.30
188.0392761	1.14
189.1689301	0.12
192.2599182	0.58
194.1924744	0.32
196.1623535	0.35
197.3003693	0.14
201.1247253	7.51
204.1290894	6.37
206.2236938	0.58
210.2200012	0.12
211.2881775	0.36
213.3272095	0.54
215.1456909	19.04
216.0261536	0.50
222.4144287	0.35
226.2636414	0.10
228.0200195	0.85
229.1875000	0.27
233.0231934	0.45
242.2654114	2.52
244.3243103	4.88
245.1932678	1.30
246.1682129	9.12
247.1040649	0.57
254.1442261	0.32
258.5305786	0.35
260.6647644	1.94
261.3541260	15.45
262.1695862	0.53
266.1079712	0.16
269.0900574	1.02
270.2319946	1.52
271.4349365	1.38
272.4650269	0.84
274.2548218	12.71
275.2244263	1.81
276.2567139	0.70
277.7426147	0.50
278.6747742	0.30
282.1970215	7.01
284.2723694	48.85
285.2406616	1.77
286.2357178	54.53
287.3730774	1.51
288.2210693	5.66
289.2221680	1.19
290.2099609	3.31
291.2548828	7.28
294.2005615	2.06
296.2863770	10.03
297.1226196	1.07
300.3031006	78.26
301.3852234	4.50
302.2661743	6.83
304.1656189	3.72
305.0258789	0.29
312.3395386	71.74
313.2785034	4.52
314.2766113	5.29
315.4969788	0.86
316.1355896	0.87
318.3088989	67.86
319.2543335	4.19
320.1970825	1.12
322.1422119	1.00
330.2500305	100.00
331.3148193	7.85
332.2483826	11.55
333.3926392	0.26
335.2825317	0.47
350.6116028	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.14
Annotation	(+)-Abscisic Acid
Peak:m/z	Relative Intensity
81.03386688	0.67
108.9706421	3.32
110.8756561	1.41
112.947464	0.61
123.2213135	0.78
131.0826721	0.51
132.6652069	0.70
137.0838928	3.71
145.0523376	0.67
149.1902924	5.20
150.875	1.47
152.9061127	4.13
160.1343689	2.87
165.095047	2.80
171.2016296	0.74
179.9747467	1.81
181.0265503	1.98
187.1227264	6.35
188.6109009	1.45
191.3250732	3.23
204.9799652	3.02
207.4361267	4.50
208.9638214	7.82
211.164917	3.08
217.9525604	4.49
218.9397125	16.68
221.0473175	0.74
223.015274	4.56
229.0629578	6.87
232.6870117	3.63
235.2715607	2.21
236.7675629	2.13
244.7481079	2.94
247.1290283	100.00
248.2337799	6.91
251.64888	3.56
265.0531921	3.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	787.3185
Annotation	Correolide
Peak:m/z	Relative Intensity
255.3950806	0.03
278.7586365	0.08
293.1224365	0.04
295.2427063	0.09
311.3708496	0.06
321.3369141	0.02
337.2561951	0.09
342.2107544	0.01
353.4008179	0.06
357.4434814	0.01
368.0453186	0.04
372.4353638	0.03
374.4907227	0.02
384.1394043	0.02
386.0397949	0.04
395.9690552	0.02
400.4080811	0.11
402.4600220	0.02
412.3814697	0.03
415.4492188	0.04
417.9727783	0.02
424.4890137	0.02
426.2686768	0.02
429.2354126	0.12
430.5595703	0.03
440.5272827	0.06
442.4898071	0.03
454.4461670	0.07
457.0278931	0.01
458.5336914	0.15
460.2559814	0.04
462.5389404	0.02
463.3295288	0.09
469.4047852	0.05
474.4190674	0.04
478.3492432	0.03
488.1776123	0.07
490.4097290	0.27
493.4317627	0.18
499.2619019	0.04
501.2085571	0.02
507.4137573	0.17
516.1561890	0.02
517.3146362	0.09
519.4624023	0.08
521.4261475	0.06
522.4304199	0.19
525.3987427	0.02
527.5137939	0.06
528.8684692	0.05
543.1815796	0.03
546.5313110	0.02
549.6858521	0.23
553.6856079	0.02
560.7822876	0.05
565.4902954	0.02
566.2339478	0.01
571.5324097	0.19
574.1178589	0.03
575.4115601	0.60
578.4730225	0.08
579.6766968	0.02
588.4537964	0.07
589.8167725	0.03
590.6174927	0.08
591.4721069	0.24
592.3710938	0.39
593.3864746	1.58
594.5154419	0.25
596.3197021	0.06
604.6089478	0.01
607.3046875	0.26
611.4293823	0.34
613.6959839	0.01
617.4943848	0.07
618.4846191	0.14
619.3988647	0.38
620.3811646	0.07
623.0695190	0.11
624.3666992	0.06
625.2980957	0.57
625.8986816	0.17
632.2960205	2.50
633.1998291	0.17
635.5028687	0.49
636.3880005	0.03
639.1468506	0.02
650.1298218	0.21
651.2895508	0.60
652.4827881	0.61
653.3845215	0.25
662.4923706	0.05
664.3351440	23.71
665.5429688	0.33
667.2448120	0.74
669.4486694	0.16
677.5817871	0.07
681.3268433	0.01
683.4340210	0.40
685.8429565	0.04
687.4676514	0.53
695.4766235	0.13
697.4889526	0.01
700.0671997	0.02
710.1265259	0.03
711.4231567	1.34
713.3822021	19.83
714.4241333	1.43
715.3764038	0.62
725.3496704	0.11
727.4386597	0.72
737.4210815	0.48
745.2166138	0.17
755.3593140	100.00
756.0062256	0.25
759.4170532	1.19
769.4270020	0.40
773.5711060	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	339.0722
Annotation	Aesculin
Peak:m/z	Relative Intensity
133.1759033	0.13
139.2068176	0.08
166.7708282	0.05
177.0006409	100.00
177.7597961	0.01
182.9441223	0.46
205.2763977	0.07
224.8901062	0.01
235.1407776	0.02
249.1412659	0.05
250.0284424	0.05
251.2835999	0.08
292.9081421	0.03
294.0691528	0.02
295.1040955	0.06
303.1146851	0.06
320.7642517	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	550.76
Annotation	Unknow
Peak:m/z	Relative Intensity
212.6168976	1.27
213.2627563	0.02
213.9048462	0.28
214.9831848	1.88
216.7370300	0.08
245.2198792	0.21
279.3311462	0.21
295.1132202	0.15
296.7557678	9.67
298.6480103	5.94
299.3408203	0.06
324.3061523	0.32
335.9605713	0.10
336.9833374	0.38
340.2158203	0.18
378.3226318	0.13
380.6043091	19.91
381.8589478	12.23
382.6942749	47.74
383.3505859	0.66
388.6666870	0.13
420.7884521	0.44
428.9931030	0.08
434.8444214	0.26
442.9570312	0.09
443.8932495	0.05
459.9959106	0.11
460.6907959	0.15
464.4965820	18.45
465.7924194	31.02
466.6987305	100.00
478.8156738	0.10
491.0598755	0.09
501.6662598	0.09
503.4528198	0.55
504.5842285	5.54
505.5088501	0.03
514.0213013	0.06
521.0801392	0.11
531.8509521	1.25
532.9296265	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	322.11
Annotation	S-Methyl GSH
Peak:m/z	Relative Intensity
103.9324036	0.11
115.1338043	0.20
115.9535980	0.47
118.9685822	0.18
122.0411530	0.25
129.9094086	0.35
132.6348724	0.24
143.8997650	2.59
160.0921936	0.38
161.0176086	1.07
164.2479858	0.22
175.9916534	15.80
190.8512573	0.21
193.0964203	100.00
201.2766113	0.09
206.1259155	0.03
208.9154663	0.37
211.0987244	0.22
215.0652466	0.18
216.0948792	0.53
216.7415771	0.07
233.1160583	14.79
233.9270935	0.45
235.1653442	0.61
238.2965698	0.15
241.2565002	0.39
248.0776367	0.56
249.1087952	0.32
250.3916931	0.42
258.0751343	0.23
259.1726685	1.17
259.9655151	0.28
262.0349731	0.63
265.9507446	0.17
267.1907349	0.11
276.0754089	1.85
278.0700378	2.87
279.2490234	0.07
280.8098145	0.38
281.5251465	0.38
286.0385132	2.73
290.3763428	0.39
293.5231018	0.27
304.1053467	10.44
305.1468506	2.14
312.9444580	0.47
322.2239075	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	913.1827
Annotation	[Gallocatechin-(4alpha->8)]2-gallocatechin
Peak:m/z	Relative Intensity
254.9638977	0.41
261.1000977	1.15
269.2904968	0.06
273.0457153	0.11
277.3247375	0.15
279.1755676	0.12
281.1372681	0.29
283.3688965	0.19
287.2934265	0.05
296.9425049	0.03
303.2236938	2.94
304.1953125	0.68
305.1943970	5.45
306.1322937	1.16
315.1503906	0.61
318.2087708	0.09
319.0310669	0.22
333.3275146	0.05
347.1288452	0.06
349.2215271	0.13
357.2557068	0.08
365.1838684	0.33
371.2656860	0.13
373.9739075	0.34
379.2694092	0.35
380.2530212	0.21
381.3692932	0.07
382.2943726	0.28
387.6347656	0.08
391.2016602	2.40
392.2452698	0.44
395.2628479	0.07
396.9378052	0.78
398.8930054	0.30
409.1139832	1.01
409.9859009	0.27
411.2605591	0.81
413.3033447	0.11
419.4795532	0.37
421.2614136	1.77
423.2784424	17.35
424.1516724	3.16
425.1358643	0.13
427.1287231	0.13
429.2465210	2.75
430.2189331	0.31
433.3626709	0.05
435.4370117	0.07
437.4660034	0.14
439.2313232	3.07
441.2043457	10.06
442.1041260	0.69
451.2201538	1.09
452.2042236	0.22
453.3064575	0.59
454.2312622	0.10
455.3078613	0.16
463.1614380	0.77
465.3483276	2.53
466.0958862	0.12
469.1878662	0.26
481.3428345	1.76
483.1758423	9.06
484.0914307	1.20
485.3533936	0.21
492.8993530	0.23
494.2144165	0.10
496.3018799	0.15
509.5877075	0.28
515.2890015	2.62
516.3762207	0.35
523.3994141	0.09
525.3900146	1.13
526.2789917	0.28
533.3678589	1.49
534.6193848	0.18
541.2422485	27.71
542.3267822	7.51
547.2738647	0.59
549.1625366	0.09
559.1307983	43.54
560.2326660	6.58
563.4699707	0.24
564.7239380	0.51
565.3995972	0.77
570.8092651	0.07
575.2282715	0.48
577.0928345	41.25
578.2418823	5.24
583.4018555	0.10
584.3510132	0.09
589.1655273	0.13
591.1262207	5.25
592.2672729	1.44
599.5120239	0.11
601.2280884	6.27
602.2023926	2.90
603.0833740	0.43
607.2180176	4.77
609.1588745	20.49
610.2734375	4.72
615.4748535	0.32
619.2158813	6.79
620.1843872	1.28
631.3870850	0.11
633.1411743	0.55
643.2337036	0.64
649.4278564	0.43
650.3283691	0.12
651.4016724	1.83
652.5187378	0.45
661.2391968	0.91
661.8572998	0.29
662.4677734	0.19
663.3205566	0.71
667.4155273	1.27
683.4640503	1.60
684.4484863	0.57
687.2582397	0.40
691.8977051	0.85
701.2599487	0.91
702.0303345	0.38
709.3012085	5.40
710.4061890	1.16
725.2455444	0.43
727.1261597	100.00
728.2200317	24.93
735.0875244	0.12
743.4909668	0.06
745.1064453	42.01
746.1299438	7.14
757.3799438	0.69
760.6527710	1.22
769.1077271	2.09
770.3259888	0.67
771.0838623	0.10
787.1296997	24.88
788.3272095	6.31
789.3076782	0.15
811.5078125	0.33
820.0477295	1.60
828.9020386	0.08
849.7755737	0.18
851.2269897	1.09
869.4689941	0.23
877.1508179	0.43
878.6828003	0.08
895.1380005	4.96
896.1622925	2.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.1825
Annotation	Geniposide pentaacetate
Peak:m/z	Relative Intensity
177.1475830	0.18
191.0498505	0.12
219.0717468	0.36
227.1243439	11.45
228.9612427	0.11
238.1374207	0.05
242.9530640	0.09
255.1573792	0.06
259.3026733	0.10
261.3801880	0.04
276.2961731	0.23
285.0183105	0.15
291.1730347	0.04
293.0252686	0.05
297.0804749	0.03
303.1270142	0.45
305.1301270	0.76
329.2062378	0.16
339.3813477	0.10
345.2667236	0.06
349.3634644	0.12
367.3018188	0.41
369.5227661	0.09
373.2741089	0.03
375.3323975	0.32
386.9357910	0.06
389.1618652	100.00
389.8373413	0.09
394.9188232	0.13
407.1381226	0.08
409.1751099	0.23
410.7262573	0.75
411.4373779	0.15
420.4277344	0.11
423.3747559	0.86
427.2438354	0.36
428.9354858	1.47
431.4151611	0.08
434.3932495	0.11
447.3226318	0.65
450.1550293	0.21
451.1981812	0.29
453.4558716	0.12
464.6369629	0.28
465.5212402	0.35
467.4063110	0.17
468.3582153	0.06
470.2769165	0.11
471.1110229	0.26
477.1892700	0.09
482.6755981	0.20
499.3370972	0.20
500.3377075	0.36
511.7006836	0.08
517.5090332	0.25
534.8792114	0.66
535.4939575	0.41
537.2788086	0.26
550.3240967	5.94
551.1190796	85.89
553.1787720	0.36
561.4241333	0.05
579.3085938	1.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	148.06
Annotation	3-Aminopentanedioate
Peak:m/z	Relative Intensity
83.9492340	0.76
98.2186737	0.03
101.8932343	16.94
129.9363098	100.00
130.9103546	7.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	788.4752
Annotation	Linckoside O
Peak:m/z	Relative Intensity
221.0308533	0.08
225.1166077	0.30
225.8185883	0.05
234.7806244	0.20
236.0537415	0.05
237.0848694	0.13
243.0668640	0.14
245.1569214	0.08
248.4351196	0.05
249.1181641	0.20
251.1560211	0.67
252.1062775	0.13
253.1934967	0.09
255.2668457	0.30
256.4008789	0.13
261.3214417	0.03
261.9859924	0.03
263.2048950	0.29
265.0272217	1.78
266.0566711	0.37
267.2186279	0.26
269.1990662	2.52
270.2362671	0.38
271.1389465	0.28
272.1227112	0.03
277.1859131	0.40
278.2633667	0.15
279.3517151	0.31
281.2583008	0.08
283.4385376	0.07
287.0885620	0.04
293.2562866	0.03
295.1533203	0.98
296.1755981	0.51
297.2243652	0.34
298.2355042	0.02
299.2208557	0.79
300.0339355	0.07
305.0155945	0.21
307.1224670	0.15
309.0737610	1.51
310.2171021	0.12
311.0720825	0.36
313.0787964	3.37
314.0285645	0.26
315.2724304	0.16
321.3055420	0.10
323.1686096	0.73
323.8961182	0.04
331.3164062	0.04
337.0596008	0.10
339.0905151	0.75
340.7341309	0.13
341.3803101	0.28
343.0377808	0.68
344.4030457	0.21
349.1390991	0.22
350.2617798	0.07
351.0773926	0.09
352.0974121	0.04
353.1274414	2.60
354.3221436	0.21
355.4896851	0.22
356.9248657	0.91
358.5206299	0.33
359.1845703	0.26
365.2876587	0.14
366.3921204	0.02
367.2599487	0.12
368.2863770	0.11
383.3359985	0.18
385.1867065	0.21
387.3171387	0.38
388.1026001	0.02
392.3817139	0.02
393.5208740	0.04
395.0750732	0.05
397.2281494	1.96
398.1462402	0.18
399.4220581	0.06
401.0241699	2.27
402.2315063	0.34
403.1315308	1.14
404.4851685	0.03
411.4641113	0.28
415.2450562	0.23
419.1469116	0.28
426.8596802	0.03
429.1224976	0.15
429.9277344	0.04
431.2943115	0.23
432.3071289	0.10
441.2262573	1.23
442.2854614	0.19
443.3685303	0.05
445.1913452	2.48
446.1109619	0.40
447.3060303	0.95
448.3126221	0.05
453.1869507	0.03
455.4375000	0.07
459.2794800	0.06
463.2421265	0.89
464.2745361	0.03
471.1367798	0.05
472.1085815	0.02
473.1651611	0.12
475.3689575	0.10
476.0964355	0.02
485.1715088	0.69
486.2359619	0.04
488.8015137	0.70
489.4113159	1.92
490.4854126	0.52
491.3732910	1.04
492.2728882	0.10
503.2597046	0.10
507.1117554	0.42
508.2816162	0.07
514.9830322	0.02
516.3969727	0.05
517.0307617	0.08
518.3390503	0.06
519.4246216	0.14
529.2099609	0.36
530.2654419	0.11
531.3838501	0.03
533.0915527	1.22
534.1268311	0.35
535.1041870	0.73
536.0632935	0.26
551.2728882	0.98
552.4458008	0.15
560.7086792	0.11
561.3087158	0.07
563.1345825	0.09
573.3353271	0.03
574.3936157	0.13
577.2526245	1.15
578.4838257	0.12
579.3336792	0.71
580.1511841	0.11
595.1956787	0.62
596.6525269	0.06
606.4805298	0.02
621.3175659	1.37
622.2855835	0.13
623.3112183	0.29
626.2615967	0.04
627.7513428	0.08
639.3073120	1.26
640.2911987	0.12
650.1814575	0.09
659.5518799	0.15
665.1723022	0.89
666.3168335	0.75
667.2772827	2.05
668.0949097	0.61
683.2710571	1.94
684.3458862	0.53
709.3855591	0.19
721.3045654	0.04
727.3301392	3.70
728.3060913	0.48
752.3073120	0.03
753.2814331	0.82
754.3651733	0.33
763.1207886	0.06
771.3383789	100.00
772.3206787	25.24
773.0414429	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	643.1482
Annotation	Myricetin 3,3'-digalactoside
Peak:m/z	Relative Intensity
189.1084442	0.04
209.2612000	0.03
227.1289368	0.06
231.1687317	0.05
245.1136169	0.03
271.0464172	0.05
273.0896301	0.33
288.7354126	0.03
290.2424011	0.17
301.0520630	0.21
306.8596191	0.04
319.1115112	100.00
325.0562744	0.07
331.1468201	0.03
343.2628174	0.12
348.3932495	0.01
361.2073364	1.18
385.2576294	0.37
409.2595215	0.06
415.2999878	0.26
427.1868286	0.28
445.0321655	0.59
463.1582031	4.06
463.7630005	0.07
468.8760986	0.03
472.7833252	0.01
475.3120117	0.01
479.6422119	0.01
481.0916138	27.54
481.7537231	0.07
505.2735596	0.14
522.9683838	0.03
545.5565186	0.03
553.0618286	0.02
563.5512085	0.04
571.1866455	0.01
583.9066772	0.02
607.0361938	0.16
625.0686646	0.44
626.8255005	0.04
634.3492432	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.09
Annotation	Delphinidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
187.0587158	0.01
201.2140198	0.01
205.1655884	0.21
219.3100891	0.01
223.1585388	0.83
224.1270905	0.33
225.1011963	0.07
247.2770996	0.02
273.1367493	0.01
274.2212524	0.01
301.4863281	0.01
325.1201172	0.02
367.0215454	0.06
368.0492554	0.07
369.3599243	0.02
385.0809326	1.43
386.1048584	3.25
387.1801758	0.79
463.2333374	0.04
505.1986084	100.00
530.0983887	0.05
531.1277466	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	440.229
Annotation	Unknow
Peak:m/z	Relative Intensity
165.0447235	0.10
180.1909180	0.58
186.1803589	0.10
244.3868408	0.07
260.2758179	0.06
273.8909912	0.68
278.2763062	0.11
292.1373291	0.08
297.4076843	0.08
308.1755371	0.31
313.9591064	0.28
323.8743896	0.12
332.2036438	0.98
334.1515503	0.13
340.3298645	0.12
341.2581787	0.23
346.2507935	0.05
350.0773926	0.20
356.0835571	0.09
360.3091125	0.14
374.3373718	0.60
377.1435852	0.10
378.1572876	0.20
381.3201599	0.70
392.6123962	0.11
394.2835388	100.00
394.9299622	0.14
396.2673035	0.49
397.1378479	0.43
404.0685425	0.27
419.8224182	0.09
420.5576172	0.28
422.1548157	0.48
423.2708435	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.224
Annotation	Linalool 3,7-oxide beta-primeveroside
Peak:m/z	Relative Intensity
199.3085785	0.16
222.0292358	0.12
233.1556702	0.13
239.2593079	0.20
240.2311096	0.15
243.3383331	0.07
261.3414001	0.05
266.8663940	0.03
285.4246826	0.23
301.2840576	0.06
302.9520264	0.03
310.9974365	0.08
317.2429199	0.02
319.2363281	0.28
325.3516235	0.04
329.0728149	0.31
345.5895386	0.11
347.4445801	0.49
354.1931763	0.03
359.4711914	0.08
374.3359985	0.04
375.2276611	0.12
383.2760620	0.04
387.2156372	0.03
392.3543091	0.02
395.1428833	0.07
419.4707031	0.12
423.1406860	0.22
433.2746582	0.21
444.4861450	0.11
448.2419434	0.25
449.1423340	0.15
449.7426758	0.10
463.2869263	100.00
465.3028564	0.11
466.3676147	0.09
472.6802979	0.07
479.3720093	0.11
490.4016724	0.13
491.3817139	0.04
493.5435181	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	589.1558
Annotation	Cassiaoccidentalin C
Peak:m/z	Relative Intensity
172.9739380	6.42
191.1288452	0.02
193.1617584	0.06
207.0798492	6.21
216.3202209	0.04
221.2068024	0.29
229.1845093	0.04
232.3962402	0.11
233.0934753	0.04
247.3519592	0.26
265.1060181	0.07
275.3064880	1.12
313.9718018	0.12
318.6154785	0.42
319.2528076	0.55
337.2265015	28.23
345.2035522	0.11
362.9088135	1.28
366.5512085	0.13
381.1414795	100.00
395.2330933	0.04
401.9995728	0.06
415.0919189	0.09
422.2244873	0.20
431.0679932	0.02
482.8731079	0.03
484.4880981	0.05
493.3574829	0.11
509.3598633	0.26
526.9833374	0.29
528.4666138	0.09
541.3638916	0.10
543.4360962	0.40
551.8006592	0.15
553.4401245	0.15
559.2719116	0.40
570.9045410	3.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	189
Annotation	Oxalosuccinic acid
Peak:m/z	Relative Intensity
72.9866257	0.42
82.9554825	4.19
98.8152313	0.27
101.0719147	0.06
104.9993134	0.06
126.9072418	100.00
145.2867737	0.01
146.2146912	0.02
147.0179443	0.03
155.0688629	0.03
170.9506531	0.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.11
Annotation	Pratensein 7-O-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
159.4370728	0.12
164.1551208	0.12
179.0413361	0.92
187.0082397	0.29
189.3738861	0.06
201.1806183	0.28
203.2390289	0.26
205.0867004	0.66
206.8344269	0.32
219.0606689	0.29
223.0866089	11.26
244.4468384	0.14
247.3692322	0.38
272.1937866	0.06
273.2477417	0.41
291.0064697	0.37
294.8543701	0.17
303.2855835	0.10
306.1317749	0.11
307.4696655	0.91
320.3430176	0.11
323.1661987	0.36
325.4295044	0.46
341.3397827	0.23
343.3182373	0.03
344.3724365	0.22
349.0764771	1.41
353.0617676	0.36
367.1612549	2.43
371.0115356	0.06
383.3384399	0.40
385.0866089	100.00
385.7998047	1.38
392.3070679	0.30
393.5408325	0.05
395.2251587	0.31
401.2138672	0.09
408.2974854	0.48
409.2870483	0.11
413.4644165	0.24
415.2806396	0.83
416.2217407	0.14
417.5306396	0.25
421.6537476	0.31
430.2963257	0.35
443.7960205	0.61
450.3431396	0.11
451.1289673	0.12
455.2647095	0.19
456.6063232	0.29
463.2698364	0.18
466.3792725	1.15
467.4948120	0.58
469.3912354	0.49
470.3189087	0.32
473.3129883	0.26
479.4161377	0.43
482.2872925	0.12
483.4860229	0.07
495.7167358	0.20
500.1964722	4.95
501.3147583	1.24
502.5795288	0.66
503.4848022	0.25
510.2003784	0.74
511.2684326	0.80
511.9479980	0.14
519.1222534	0.28
527.2566528	0.12
528.2989502	0.06
529.1746216	3.77
530.2180786	0.40
531.0853882	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.0605
Annotation	Unknow
Peak:m/z	Relative Intensity
133.8766327	0.31
166.8738098	1.55
177.8535004	0.23
180.7376099	0.04
192.9957886	3.53
217.0213470	0.45
223.0905151	0.04
229.2225952	0.05
234.7203979	0.18
241.0150146	100.00
254.0253296	0.08
254.9916992	0.35
259.1356812	0.66
271.1914673	0.12
273.1382751	2.70
277.3733215	0.10
294.1490784	0.07
303.1172485	0.07
319.3094482	0.05
320.8825989	0.08
338.8464355	0.13
343.8681335	0.06
344.9246826	0.09
347.3267822	0.38
348.2749023	0.20
353.0759888	0.09
355.2707214	0.13
361.6113892	0.16
363.0357971	0.05
370.3225098	0.12
372.2426453	0.23
388.4676819	0.10
389.1741638	0.41
389.8511658	0.05
390.4640198	0.05
391.4189758	0.42
393.3787842	0.05
397.4280701	0.24
398.3904724	0.67
399.2002258	0.06
400.1865845	0.08
406.3031616	0.26
414.0864563	0.24
416.2268372	0.58
417.3755798	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	376.1381
Annotation	Tiagabine
Peak:m/z	Relative Intensity
120.9264603	0.09
132.2259521	0.03
139.0705566	0.09
145.0266876	0.06
147.1500854	0.04
148.2241974	0.10
151.1806946	0.15
153.1928253	0.05
158.9279480	0.09
161.0887756	0.20
162.0441589	0.04
162.9819794	0.35
165.0039978	0.20
169.1808472	0.13
173.0282593	0.42
175.1101227	0.06
176.7594604	0.05
178.9582062	0.63
181.1630707	0.14
184.9924622	0.13
187.1774292	0.02
188.4408875	0.13
189.2879639	0.12
190.0691528	2.48
191.1285858	3.38
193.0116272	0.04
196.0266876	0.10
201.3390961	0.15
203.0402679	1.34
205.1084900	0.02
208.0856476	100.00
214.2024231	0.04
215.5196838	0.11
220.0745544	1.77
220.7947693	0.16
230.9264526	0.04
232.3644104	0.11
233.2112122	0.03
238.0410156	0.01
245.4737549	0.10
249.2466431	0.02
254.7261658	0.04
260.2647400	0.03
263.0872192	0.09
271.3045349	0.10
278.9392090	0.11
288.0666504	0.17
289.2253113	0.02
299.8986816	0.07
304.2911377	0.06
307.0336609	0.07
311.2597046	0.05
313.3205566	0.08
320.2843628	0.19
322.2639465	0.19
323.2333374	0.41
330.1479797	0.15
330.9204407	0.09
332.6408691	0.04
334.8795166	0.06
340.4142151	1.30
341.2395935	16.20
347.1464844	0.20
349.4108582	0.08
358.1723328	29.79
359.1931458	10.20
366.8132935	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	801.298
Annotation	Kotschyin C
Peak:m/z	Relative Intensity
242.2346802	0.06
252.6096497	0.05
257.3018494	0.18
266.3318176	0.04
269.2529602	0.07
278.1011353	0.11
281.0889893	1.08
283.3081665	0.52
300.0515747	0.20
302.4218445	0.16
314.3327026	0.08
315.1753845	0.05
326.3091736	0.10
328.0964966	0.18
334.1584778	0.11
334.9426880	0.17
337.2488708	0.46
338.2774048	0.28
339.1658936	0.58
343.2442017	0.51
347.3428955	0.17
350.3638916	0.28
363.1970215	0.33
363.9646301	0.09
373.4043579	0.27
375.1574707	0.16
377.2271118	0.25
387.2604370	0.06
398.2238159	0.04
399.3703003	0.11
403.2673340	1.75
404.3114624	0.35
409.1818237	0.22
449.3032227	0.08
463.1203613	0.29
470.5220337	0.24
471.3510132	0.04
474.2472534	0.39
478.4444580	0.06
480.4972534	0.11
481.3844604	0.14
484.4096069	0.46
485.3720703	0.52
486.3308105	0.53
487.3508911	0.96
488.3054810	0.37
489.5811157	0.07
490.3916016	0.09
491.5482788	0.09
497.4482422	0.09
499.2583618	0.46
500.0247803	0.38
501.4255981	0.58
504.1663818	0.10
506.3193359	0.10
512.5889893	0.15
515.3144531	0.29
517.3496094	3.10
518.3344116	0.96
519.3823853	3.13
520.2490234	1.85
520.9259033	0.03
527.3176270	0.31
531.3696289	1.00
532.3771362	0.05
534.4316406	0.17
536.0389404	0.13
539.6488647	0.08
541.4390869	0.28
543.2656860	0.81
544.4951782	0.26
545.4710083	0.26
547.0092773	0.18
551.3585205	0.27
557.2805786	0.07
559.9244995	0.77
563.3993530	0.09
567.3026733	0.03
568.4611206	2.21
569.3997192	0.41
571.3190918	1.14
572.2352295	0.21
573.2673950	0.68
577.2738647	0.10
578.7222900	0.37
579.5274048	0.28
582.3801880	0.07
583.4459839	0.42
584.2723389	0.04
585.2153320	0.34
586.0743408	0.32
587.5621948	0.14
589.2395020	0.07
593.5831909	0.15
594.3306274	0.25
595.3029175	0.10
598.5420532	0.08
603.4721069	0.05
604.3967896	0.04
606.3449097	0.07
608.3398438	0.24
609.4751587	0.20
611.4169312	0.18
620.6165771	0.03
625.1347046	0.15
627.2765503	0.14
628.4326782	0.09
634.3399048	0.39
638.3733521	0.35
639.3089600	0.65
640.4186401	0.41
647.0401001	0.15
650.3297119	0.18
652.9244385	0.49
653.5415649	0.37
658.5722046	0.15
663.2313232	0.14
664.2803345	1.22
665.3504028	1.15
666.3624268	0.18
672.4179688	0.18
679.0280151	1.06
681.1613159	1.28
682.0227661	0.16
686.3897095	0.10
688.4555054	0.07
691.4766235	0.07
697.5333862	0.13
698.6093750	0.05
714.5413208	0.06
716.6235352	0.32
723.8767090	0.21
725.4945679	5.84
726.5113525	5.46
727.4901123	0.67
729.2927856	0.31
730.2210693	0.85
741.6681519	0.43
742.4310913	0.19
745.7786255	0.10
751.6057739	1.46
752.3856201	0.44
756.0203247	0.07
758.2774048	1.83
759.3525391	0.96
760.5532837	0.18
767.0202026	0.05
769.3662720	100.00
770.4533691	52.22
773.3703003	1.36
774.4051514	0.80
778.7236938	0.03
783.4587402	3.06
784.5099487	2.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1099.183
Annotation	Delphinidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
325.0649719	0.19
343.2577820	0.10
366.6748657	0.45
367.3435059	0.07
385.0374451	0.30
386.0605164	0.24
387.0595703	0.27
395.4728394	0.16
445.3190002	0.31
463.0798950	1.28
505.2685547	100.00
507.2600403	1.18
547.0543823	1.27
548.8409424	30.47
549.5726929	0.33
635.5064697	0.14
667.2247314	0.10
714.0476074	0.24
719.5531616	0.09
935.8624268	0.06
938.3869629	0.22
959.1359863	0.06
1009.3785400	0.20
1012.1312260	0.09
1015.5989990	0.08
1017.4855960	0.33
1055.5627440	0.27
1080.5690920	0.13
1081.1929930	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	156.08
Annotation	L-Histidine
Peak:m/z	Relative Intensity
82.9507446	0.45
92.8710632	0.07
94.9939728	3.10
109.9147797	100.00
110.8215179	0.04
111.9989777	0.44
137.9997406	1.44
139.0727692	0.32
156.1695099	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.14
Annotation	Cyanidin 3-(6''-caffeylglucoside)
Peak:m/z	Relative Intensity
177.0310822	0.07
179.0746918	0.48
180.3466339	0.03
188.9806061	0.15
193.3768768	0.08
198.9636383	0.06
201.3963318	0.05
203.3981171	0.07
213.2644043	0.08
219.3132019	0.14
221.1241760	0.02
223.8262329	0.21
227.1881409	0.17
231.2206421	0.14
232.9797821	0.03
241.1538239	0.13
243.0746460	0.09
245.1283417	1.42
246.9115143	0.11
252.9600983	0.14
257.2592773	0.11
259.1954346	0.28
263.0537720	6.13
264.4271851	0.16
268.9966431	0.79
274.9940186	1.03
277.1687317	0.88
279.8987732	0.03
281.3651123	0.05
287.1749268	11.64
288.5938721	0.24
289.1997681	2.66
290.0494385	0.05
299.1539917	2.49
300.9147339	0.27
305.0412598	15.58
307.0753174	25.83
307.7296448	0.11
311.2730713	0.28
313.3816528	0.25
317.0935669	23.83
318.1366577	0.29
319.3982544	0.21
329.1790161	0.50
335.4273071	0.04
342.2413330	0.18
349.0946655	0.58
359.1903687	0.06
361.9822388	0.24
384.3259277	0.08
391.5553589	0.14
399.3981934	0.13
407.0938721	0.13
417.0342407	0.02
419.4519043	0.15
425.1140747	28.15
425.7528076	0.06
431.3936157	0.26
433.8909302	0.74
436.5861816	0.07
437.1998291	0.69
439.0876465	0.10
443.0915527	100.00
443.9630127	0.26
448.3120728	0.12
449.0968628	0.25
453.3312988	0.14
454.5227051	0.21
455.1994019	0.93
458.0069580	0.04
460.6930542	0.22
463.5365601	0.41
464.3932495	0.07
465.3816528	0.13
467.1744385	6.46
477.3771362	0.04
478.1770020	0.10
478.9053955	0.06
482.3785400	0.29
483.1471558	0.28
485.0571289	1.86
490.4979858	0.33
493.1737061	0.08
495.8609009	0.02
507.4423218	0.11
513.2625122	0.10
517.5443115	0.04
526.3136597	0.48
527.0584717	0.42
532.9066772	0.03
538.2799683	0.11
549.4149780	0.13
557.1134644	0.11
566.5600586	0.21
574.9178467	2.01
575.5414429	0.35
591.5015869	0.26
592.5807495	1.74
593.2477417	5.20
594.0479126	0.11
598.1616821	0.06
621.1638794	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	408.2947
Annotation	Unknow
Peak:m/z	Relative Intensity
123.0577927	0.02
128.1252289	0.05
132.0731201	0.02
137.0556030	0.25
141.0553589	0.07
144.0068512	0.05
151.0245514	0.09
151.8977509	0.06
172.1385345	0.09
182.2149048	0.08
186.4658661	0.03
193.1967163	0.17
210.2862396	3.95
211.3711548	0.15
212.9865723	0.08
215.3053589	0.08
228.3078003	16.34
231.2695007	0.10
232.0717163	0.06
233.2464600	0.05
235.0973816	0.05
240.0783997	0.89
241.9202881	0.12
243.3180542	0.23
246.2193604	100.00
249.1771545	0.12
250.1214905	0.10
252.3548889	0.71
258.2259521	0.07
259.9738770	0.25
263.2778320	0.05
265.9113159	0.15
267.3648987	0.17
270.3252563	1.69
272.0904236	0.03
275.2965088	0.03
276.9000549	0.02
282.8223572	0.16
288.3560486	5.04
290.9595642	0.25
294.3280029	0.80
301.1751709	0.25
302.0359192	0.24
303.1094971	0.10
304.1499023	0.04
306.6260986	0.08
310.0540161	0.02
312.2884521	3.39
312.9429321	0.12
318.5692444	0.09
323.0672913	0.06
324.3110962	1.81
327.0547485	0.33
328.2187500	0.04
330.4353943	0.23
331.1386719	0.06
335.3491821	0.40
336.4384460	1.41
342.1328125	0.48
344.0122681	0.10
348.8066711	0.03
354.3884888	5.07
355.2716064	0.07
362.2200012	0.06
364.2081604	0.09
372.3634338	10.32
377.1864319	0.12
378.3187256	0.03
387.2940979	0.05
390.3078308	15.97
391.3753357	0.22
398.7933655	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	610.13
Annotation	Unknow
Peak:m/z	Relative Intensity
209.0657349	0.60
225.1629639	0.39
233.1876678	0.50
256.7611694	0.15
289.0750732	0.13
297.1188965	3.97
300.2543030	0.63
307.0407104	1.17
311.1824951	0.26
314.4356689	0.30
315.0802612	0.30
316.9042358	0.44
329.3273926	0.54
334.7431030	0.35
337.3348999	0.06
338.9625244	0.48
342.5789185	0.49
346.1342773	0.48
355.3210449	0.13
360.8660278	1.08
361.4833984	0.15
362.1106567	0.36
371.7424927	0.10
378.0197144	2.51
388.1246948	0.39
395.0795898	0.13
405.8167114	1.82
412.3464966	0.25
413.7644653	0.36
421.9437256	0.17
423.7396851	0.29
428.4675903	0.13
439.8105469	0.11
441.0437012	0.54
442.3945312	0.47
444.3362427	0.21
446.2476196	4.88
447.0431519	0.31
449.3588257	0.33
458.2430420	0.31
459.1558228	0.20
463.1636353	7.36
464.1251221	3.70
471.8990479	0.19
476.5827026	1.14
479.3435059	0.34
481.2121582	100.00
488.4618530	0.32
517.1897583	0.28
535.2700195	18.89
537.4899292	0.05
543.5503540	1.03
546.6640015	0.47
564.6052856	0.25
566.2615967	0.42
569.2722778	0.26
583.3666992	0.11
591.2358398	0.61
592.1189575	2.40
593.1989136	0.43
595.4359131	0.56
598.0885620	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	550.1541
Annotation	6,7,3',4'-Tetrahydroxyaurone 6-(4'',6''-diacetylglucoside)
Peak:m/z	Relative Intensity
203.1420898	0.24
213.2618713	0.63
221.0703735	0.25
239.0176086	0.30
240.8855743	0.18
248.9633484	0.12
252.3774719	0.16
255.1831360	0.07
271.3441162	0.44
273.3432007	0.48
283.1837158	0.23
285.3004761	0.19
296.4466553	0.54
303.0897827	100.00
307.2151489	0.16
308.0785522	0.06
310.2349854	1.17
321.3710327	0.10
327.1290283	0.91
329.0023804	0.28
333.0090942	0.06
335.3786011	1.04
336.1871948	0.73
337.3344116	0.12
339.0764160	0.16
340.4976807	0.12
345.0964355	2.72
346.4428711	0.24
351.2770996	1.03
352.0279541	0.24
353.5255127	0.81
357.2391968	0.29
359.6892090	0.57
365.2338257	0.36
369.0161133	0.87
370.2146606	0.26
371.3999634	0.06
387.9212036	0.14
389.1332397	0.05
404.3355103	2.16
405.2982788	0.61
411.2949219	0.50
416.5062866	0.06
418.1913452	0.30
421.2629395	0.82
422.1773071	0.09
430.3521729	0.07
431.2401123	0.24
432.8999634	0.27
443.6354980	0.31
445.3392944	0.23
447.2004395	0.46
460.3900146	0.23
462.8918457	0.15
463.9970093	0.15
465.1823730	0.39
471.2687988	0.32
473.4699097	0.11
476.1962891	0.16
479.6420898	0.34
482.5913696	0.30
483.4060669	0.15
484.8829346	0.11
490.3457031	0.27
491.0267944	0.41
491.7080688	1.13
497.4666138	0.07
505.3567505	0.22
506.0674438	0.09
507.6245728	1.03
509.7229614	0.08
513.3918457	0.59
515.2109985	4.74
516.0179443	1.29
519.0031128	0.17
519.7078857	0.18
521.6209717	0.47
527.3004761	0.36
531.4236450	0.63
532.5039062	3.10
533.2907104	9.27
534.1171875	1.81
541.7799683	0.32
550.5498047	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1221.5233
Annotation	Unknow
Peak:m/z	Relative Intensity
350.4009705	0.64
358.2843323	0.84
368.4268799	0.41
384.2579346	0.16
398.1455994	0.36
413.1338196	1.55
417.1261597	0.24
418.8013916	0.43
420.4960938	0.95
427.1586304	1.54
431.1641235	0.33
435.5288696	0.32
443.4857178	0.43
445.3839111	0.42
451.3850098	0.19
471.3323669	0.62
477.3535461	0.23
487.4350891	0.36
493.4039917	0.16
499.0885620	0.65
514.3023682	0.67
516.4660034	0.47
521.0878906	1.24
526.2263184	5.15
527.3321533	3.47
528.4981689	0.19
529.3184204	0.10
543.4020996	0.25
544.3094482	3.47
545.2263184	0.90
546.2091064	1.44
563.7805786	0.16
565.2042236	0.48
566.4519043	0.93
576.3299561	1.64
577.3634033	0.59
578.5627441	0.24
580.4168091	0.33
581.9771729	0.78
590.5093994	2.44
594.2227173	1.15
597.0979004	0.16
601.1682739	0.27
603.3511963	0.20
608.2479248	0.39
615.7782593	0.61
646.4884033	0.45
648.7620239	0.28
651.1495361	0.27
659.1595459	1.42
661.1689453	1.31
662.0749512	0.30
663.5714722	2.03
664.4049072	0.19
667.8562622	0.58
670.4830322	0.87
672.5158691	0.56
677.8435669	1.19
678.7373047	0.13
680.5155029	0.48
685.2612915	0.29
689.5697632	2.44
690.5245361	0.91
693.9240112	1.60
695.5291138	0.17
696.3114014	0.54
697.2220459	0.69
706.1051636	0.14
707.4341431	6.47
708.4321289	4.23
709.8546143	0.67
715.0313110	0.77
725.1768188	0.86
734.6315918	0.42
741.3172607	0.52
745.7080078	0.19
750.2336426	0.26
758.4794312	4.41
759.6693115	0.14
765.5565186	0.36
766.4710083	0.86
771.3642578	0.59
772.5982666	0.20
776.3932495	2.17
777.3608398	0.76
778.8701782	0.31
793.5794678	1.34
794.4377441	1.68
795.3880005	2.76
796.7551270	1.11
798.3573608	0.17
802.2076416	0.36
803.0579834	0.39
804.6826172	0.49
809.3385010	0.12
821.4808960	0.82
822.0830078	1.29
827.0584717	0.44
840.1662598	0.42
859.4310303	0.90
864.2260742	0.30
875.9023438	0.39
882.4061279	0.75
895.4005127	0.58
912.9774170	1.00
921.6221924	0.17
922.4598389	1.21
926.1458740	0.43
931.3437500	0.54
939.3105469	2.36
940.4342041	1.73
941.1094971	0.96
941.8951416	0.12
957.4631348	1.60
958.2696533	2.67
959.5109863	1.49
960.5902100	0.92
976.4399414	0.67
983.5321045	0.55
986.4519043	0.30
987.5969238	0.64
991.9877930	0.76
1001.1280520	0.22
1006.3322750	0.62
1007.6562500	0.67
1011.2050780	1.46
1017.5146480	0.57
1021.5802000	0.62
1022.7116700	1.03
1023.8623050	1.67
1026.8249510	0.84
1027.8854980	1.57
1032.3071290	0.10
1033.1091310	0.42
1035.8192140	1.04
1040.4493410	1.29
1041.5173340	2.81
1043.4899900	1.64
1050.0114750	5.83
1053.3328860	0.81
1054.5112300	0.73
1060.6242680	1.32
1061.4842530	0.45
1062.5784910	1.46
1063.4023440	0.94
1065.3984380	2.11
1067.2257080	0.66
1071.6335450	2.67
1073.6308590	4.42
1075.8048100	2.30
1077.1125490	3.91
1078.2904050	0.87
1079.1982420	1.94
1082.6535640	1.60
1084.0261230	2.02
1084.9191890	1.42
1087.8596190	0.84
1088.7385250	0.84
1092.1751710	1.75
1093.4395750	2.94
1095.6740720	1.69
1097.4173580	6.26
1099.1796880	3.55
1103.3386230	0.40
1104.3236080	1.05
1105.8701170	7.25
1106.4771730	3.16
1107.0861820	1.71
1110.5758060	0.44
1112.0510250	4.56
1113.3604740	2.39
1114.7719730	3.03
1115.7630620	5.34
1116.4381100	1.92
1117.2651370	0.45
1118.1843260	2.21
1119.5731200	3.80
1120.6293950	2.57
1122.1761470	8.59
1123.0097660	8.16
1123.7924800	0.45
1125.6192630	7.41
1126.4250490	2.23
1127.2102050	1.71
1128.3937990	4.07
1129.2501220	1.20
1130.8284910	10.68
1132.0372310	3.72
1133.2343750	3.27
1133.9654540	2.94
1134.7294920	0.67
1135.7856450	3.94
1137.1250000	1.36
1137.8677980	2.29
1138.8568120	3.14
1139.5909420	7.11
1140.5090330	7.47
1141.7946780	4.34
1143.0229490	4.40
1143.8588870	4.04
1144.8098140	2.16
1145.4825440	4.65
1146.0886230	0.31
1147.2602540	4.06
1148.4167480	6.58
1149.2572020	5.11
1150.4636230	11.70
1151.5946040	9.11
1152.5273440	0.58
1153.8282470	14.61
1155.1905520	22.33
1156.0864260	6.93
1158.4270020	2.29
1159.9384770	29.89
1160.8551030	27.28
1161.5335690	28.32
1162.4301760	11.04
1163.3858640	2.86
1164.1538090	2.71
1165.1782230	2.46
1165.8862300	1.05
1168.1677250	2.33
1168.8428960	6.90
1170.0905760	8.20
1170.9938960	1.34
1171.9638670	4.00
1173.5009770	9.41
1174.4729000	2.00
1175.4318850	4.15
1176.0864260	1.27
1177.7456050	13.15
1178.7446290	6.38
1179.5671390	3.61
1181.0249020	13.18
1181.8723140	4.21
1183.0598140	12.85
1183.6931150	35.64
1184.7758790	33.37
1185.6948240	3.03
1186.6893310	21.92
1187.3304440	18.82
1188.2585450	1.71
1189.2884520	5.44
1191.1032710	1.02
1192.7802730	100.00
1193.6213380	15.43
1196.3009030	2.65
1197.3791500	0.97
1198.6412350	2.06
1199.2789310	0.13
1201.4733890	5.30
1202.1358640	8.32
1202.7832030	0.43
1203.5281980	0.37
1204.8410640	15.42
1205.6645510	5.46
1206.7165530	0.64
1207.3739010	24.15
1208.1464840	6.96
1208.8571780	0.23
1210.5386960	11.98
1226.3061520	4.05
1227.0992430	0.78
1239.9342040	0.60
1245.3576660	1.53
1246.5760500	0.30
1252.2387700	2.90
1254.1192630	2.40
1259.9864500	2.26
1261.1743160	0.30
1263.0041500	0.85
1264.9245610	0.23
1267.3532710	1.88
1268.9885250	0.12
1270.0993650	1.85
1275.1055910	1.91
1275.8498540	0.56
1276.8807370	0.58
1280.0899660	0.87
1281.8825680	0.69
1286.5784910	0.38
1290.5253910	0.79
1295.8087160	2.78
1296.8161620	0.85
1298.7843020	2.51
1301.1285400	3.08
1301.9688720	0.99
1303.2003170	1.02
1305.2675780	1.08
1308.9741210	5.50
1310.0479740	5.57
1310.6727290	4.31
1312.4559330	0.53
1317.7185060	0.66
1321.5922850	1.05
1327.4201660	0.94
1331.1669920	1.62
1332.7456050	0.61
1335.0507810	1.47
1336.0546880	0.54
1336.9425050	0.40
1338.1467290	2.47
1340.4101560	3.32
1341.9569090	0.81
1343.7135010	1.09
1344.4594730	2.13
1345.3740230	6.63
1346.3383790	4.03
1346.9500730	4.14
1348.1469730	1.16
1354.0093990	8.52
1354.9007570	20.02
1355.6840820	1.91
1356.5743410	0.53
1359.3072510	0.52
1360.9829100	0.60
1362.9576420	0.48
1364.0482180	1.89
1365.1942140	1.11
1367.5904540	0.46
1368.8662110	0.66
1370.2309570	2.10
1372.4710690	1.86
1377.7766110	1.07
1378.5804440	0.82
1381.6000980	0.63
1383.7241210	0.99
1386.2580570	2.06
1388.0284420	2.02
1390.6572270	1.91
1392.0697020	2.87
1392.8400880	2.51
1395.3690190	0.41
1398.4686280	0.71
1402.0758060	1.37
1404.4785160	3.62
1405.2954100	4.41
1406.1392820	2.40
1409.0457760	0.11
1412.8021240	0.58
1414.4149170	0.71
1415.5352780	2.95
1416.3229980	0.82
1418.4490970	0.96
1421.6968990	2.36
1423.5047610	2.63
1424.1143800	1.11
1425.0570070	1.06
1426.4886470	4.39
1427.2875980	4.25
1428.2276610	3.09
1429.1080320	1.60
1432.3272710	1.45
1434.1126710	1.96
1435.4390870	8.26
1436.3813480	29.23
1437.5040280	2.53
1439.7403560	0.78
1440.3515620	1.85
1443.0222170	1.03
1447.3937990	0.85
1448.4852290	1.71
1450.4473880	0.56
1451.6152340	0.97
1452.5858150	2.43
1453.3050540	2.03
1454.9216310	1.50
1455.9941410	1.36
1457.1885990	0.65
1459.5538330	2.40
1460.4948730	2.78
1461.7154540	5.09
1463.8182370	0.86
1465.1197510	0.84
1466.2689210	0.56
1467.2192380	1.52
1468.1143800	2.74
1468.9390870	1.99
1470.3796390	9.81
1471.3082280	7.48
1472.3255620	3.64
1475.2742920	0.53
1476.5777590	1.73
1477.3027340	2.33
1479.4572750	47.14
1480.2879640	26.32
1481.0009770	4.38
1482.1274410	0.93
1482.7637940	0.87
1484.2653810	1.25
1485.0948490	1.56
1487.0091550	2.02
1487.9508060	2.13
1489.4279790	0.63
1493.1265870	1.16
1494.1522220	0.83
1494.7789310	2.07
1497.1270750	2.27
1498.6417240	0.94
1500.1428220	1.44
1501.0806880	1.30
1502.1951900	1.05
1503.2032470	2.43
1504.6823730	6.45
1505.5148930	2.79
1506.8693850	3.42
1508.0213620	4.97
1508.9019780	7.08
1509.7835690	0.34
1510.8052980	1.04
1513.9644780	0.79
1515.5723880	3.62
1516.5975340	13.88
1517.3394780	5.23
1518.2857670	1.31
1520.7271730	0.17
1521.7108150	2.53
1523.4343260	2.90
1524.2379150	1.25
1525.8044430	0.79
1528.7130130	1.74
1532.8990480	5.72
1534.0085450	6.35
1534.8737790	2.13
1537.4869380	0.81
1538.3234860	1.66
1542.9201660	0.20
1543.7015380	1.95
1544.5028080	2.21
1545.4030760	4.64
1546.9444580	4.79
1547.7832030	4.31
1548.4781490	1.68
1549.7207030	0.16
1551.4029540	2.02
1552.0440670	6.05
1552.9857180	24.76
1553.7465820	2.42
1554.5003660	1.15
1555.4885250	1.65
1556.5529790	2.32
1557.2963870	0.74
1558.0773930	1.26
1559.8182370	4.98
1561.0758060	48.95
1561.9390870	37.94
1562.8397220	3.40
1563.6003420	4.22
1564.4196780	1.31
1565.6214600	2.67
1566.5297850	2.43
1567.4156490	0.89
1569.8664550	0.23
1571.0028080	2.02
1572.5877690	0.47
1574.4288330	2.40
1576.3497310	0.34
1578.9198000	3.18
1580.2769780	2.41
1581.9658200	0.79
1588.3566890	2.13
1591.9935300	3.68
1592.7928470	1.97
1594.4952390	2.10
1597.5007320	6.88
1598.6336670	0.52
1601.0628660	2.18
1602.1812740	6.59
1603.0175780	0.32
1603.6328120	0.18
1606.1893310	0.77
1607.7017820	1.39
1608.3402100	0.20
1609.5607910	10.42
1610.5906980	8.93
1611.3167720	10.07
1612.0162350	4.94
1612.9826660	1.73
1614.5255130	3.07
1615.6968990	3.37
1616.8049320	1.11
1617.6285400	2.70
1618.3675540	2.02
1619.2303470	0.18
1619.9331050	1.00
1620.6363530	0.82
1622.0838620	0.59
1622.8282470	1.28
1624.3138430	1.60
1625.5411380	1.18
1626.5135500	1.22
1627.1898190	1.00
1628.2114260	2.38
1629.2352290	1.52
1630.8375240	0.68
1632.3232420	3.74
1633.1960450	1.50
1634.7901610	3.08
1636.8446040	8.22
1638.0898440	2.10
1638.8157960	0.88
1639.5819090	2.62
1640.4732670	3.22
1641.1118160	0.37
1644.7517090	5.78
1645.7001950	13.61
1646.5404050	6.51
1647.2586670	1.16
1648.9510500	1.92
1649.7994380	1.36
1653.0460210	1.53
1654.1705320	27.63
1654.9722900	26.54
1655.9824220	5.35
1658.6624760	12.39
1659.6446530	1.75
1660.4108890	1.19
1666.9366460	6.21
1667.6906740	2.09
1668.6229250	1.84
1670.8302000	2.07
1672.6968990	0.34
1674.4417720	1.51
1676.9021000	0.64
1677.8563230	1.03
1681.4241940	0.67
1682.8862300	2.87
1684.1954350	2.08
1685.1766360	2.03
1686.9976810	1.04
1688.4726560	1.33
1690.0362550	0.26
1693.3895260	1.49
1694.1700440	2.08
1695.3610840	5.42
1697.0189210	2.92
1697.8576660	0.97
1699.2990720	1.88
1701.5729980	5.52
1702.2161870	4.30
1702.8342290	2.16
1704.7786870	2.91
1706.0643310	0.17
1708.6434330	2.18
1710.4930420	12.76
1711.3626710	20.88
1712.2545170	4.55
1714.5723880	2.60
1716.7873540	2.24
1718.9968260	1.59
1721.2481690	2.86
1723.9382320	1.89
1725.4743650	2.37
1728.3381350	6.25
1730.8767090	1.60
1731.7180180	1.96
1732.7575680	3.55
1737.8370360	1.31
1739.1448970	8.90
1739.9011230	1.36
1740.6439210	2.58
1741.7784420	1.91
1743.0300290	0.68
1744.0777590	0.94
1749.7266850	2.27
1751.3939210	1.06
1755.8776860	0.55
1759.9406740	1.94
1761.3697510	0.31
1766.3939210	0.38
1767.9700930	1.96
1775.0754390	1.23
1775.9099120	2.29
1777.1146240	0.45
1783.1945800	1.85
1784.8175050	8.23
1785.6585690	1.33
1793.5113530	0.16
1803.8404540	0.48
1870.5223390	0.27
1888.8128660	0.52
1925.5588380	0.30
1950.0169680	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	318.2995
Annotation	Phytosphingosine
Peak:m/z	Relative Intensity
94.8153000	0.13
103.9926758	0.06
109.0467377	0.11
111.1391144	0.09
112.9264145	0.06
114.6846085	0.08
122.7811661	0.06
130.8253174	0.03
135.1109924	0.24
137.0538025	0.29
140.9046021	0.12
154.9861145	0.17
161.1047668	0.07
170.9945831	0.04
175.0469818	0.05
179.2026367	0.19
183.0350037	0.14
185.3048401	0.03
191.2908020	0.10
194.4042511	0.09
195.0846863	0.07
197.0051575	0.12
199.0138092	0.08
203.1123657	0.04
207.3985291	0.11
211.1290894	0.20
221.0803528	0.11
225.1358948	0.11
227.2502441	0.08
229.2988892	0.10
235.2619934	0.18
238.0872498	0.12
238.9821777	0.66
246.1469116	0.07
247.1597290	0.12
252.3684692	1.07
253.1725159	0.50
256.5045166	0.12
257.9751892	0.06
264.2568665	1.10
265.2908936	2.79
267.2664185	0.05
268.6747437	0.07
269.4117737	0.04
270.3842163	0.91
271.4678345	0.05
272.5537415	0.03
282.2847900	38.21
283.0852356	1.13
286.9981079	0.23
294.9993591	0.05
300.2878418	100.00
301.0516357	0.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	366.2841
Annotation	Unknow
Peak:m/z	Relative Intensity
106.8693771	0.03
109.0590363	0.09
114.9390717	0.02
118.9774475	0.03
121.0976715	0.11
131.3050690	0.05
133.0881653	0.07
135.2048035	0.23
136.1815338	0.08
137.9480286	0.04
138.7209473	0.14
145.2383728	0.07
147.1079712	0.22
149.1344604	0.16
156.0218811	0.04
156.8009033	0.03
159.1185760	0.01
161.1054688	0.26
166.9794006	0.04
171.3063660	0.09
173.0670166	0.04
177.2489624	0.11
179.9320068	0.06
185.0639954	0.11
186.9721985	0.05
190.8851624	0.02
193.1289368	0.03
199.2187347	0.05
201.0872955	0.19
201.9824982	0.03
203.1201782	0.09
204.1895752	0.05
205.4147797	0.09
213.1599884	0.02
215.1871033	0.15
216.4034729	0.04
217.2931824	1.08
229.1235657	0.09
231.0790405	0.08
234.7269287	0.04
237.2147217	0.20
239.0592346	0.30
241.2694092	0.78
247.0974731	0.06
248.3919067	0.08
253.1773682	1.37
258.1774902	0.12
259.1495361	0.41
261.0128174	0.03
264.4900208	0.02
265.2647705	0.11
268.1831665	0.07
270.8877869	0.05
273.8742065	0.03
276.3221130	0.63
277.2661133	0.38
282.2801819	0.26
285.3620605	0.06
286.1926880	0.07
294.2805786	1.70
295.0213318	0.08
298.7418518	0.04
301.8638916	0.06
303.2095032	0.03
304.3565369	0.17
308.0504456	0.01
312.3019409	9.53
312.9257812	0.03
320.1020203	0.06
321.1863403	0.33
330.3707886	32.77
336.4027405	0.09
338.1866760	0.11
343.0347595	0.07
343.6736450	0.07
345.2406616	0.23
346.4067078	0.03
348.2876892	100.00
349.3211365	0.10
351.2993774	0.16
354.5064392	0.05
364.8994141	0.09
366.2393494	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.192
Annotation	(6R)-9,10-Dihydroxy-4,7-megastigmadien-3-one-9-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
131.0592346	0.09
143.1394043	0.33
145.3387756	0.02
153.0691223	0.80
154.1547241	0.16
155.0885010	0.04
159.0644989	0.17
161.0175171	1.59
162.0014648	0.40
171.2660522	0.08
175.0265198	0.16
179.1860199	0.37
186.0134888	0.02
189.9015808	0.05
191.1658173	0.02
203.1095276	0.15
205.1718903	1.80
206.2465210	0.24
211.0137634	0.04
223.1011658	3.09
224.0508728	1.12
239.1757202	0.02
245.3269043	0.07
249.0809937	1.37
250.1687622	0.34
251.2206116	0.06
268.9786072	0.05
270.9591980	0.09
283.2042847	0.05
292.1350098	0.02
301.3059387	0.10
306.2786255	0.08
310.1229858	0.03
315.3915405	0.03
316.2607117	0.24
317.4757996	0.50
333.3003845	0.01
343.3180847	0.08
345.2004700	0.14
357.8968811	0.17
362.3663635	0.08
371.1730957	0.03
380.2542419	0.02
385.2120056	100.00
386.2777710	23.02
387.3428955	0.35
388.2890930	0.51
394.2603455	0.11
395.4036560	0.17
396.3718262	0.18
399.2842712	0.04
413.3648682	0.34
414.1236877	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
122.8797455	0.54
126.7067108	0.84
129.0090942	0.23
143.112915	0.36
143.8253784	0.40
145.2974243	0.32
155.1717529	0.42
158.7864685	0.67
162.8178711	0.38
169.0688782	0.22
171.1773376	2.08
180.7962036	0.25
185.1861877	2.05
198.9736023	0.28
201.3194275	0.18
203.1017914	0.66
215.2292786	2.29
216.8317261	0.31
227.032196	0.83
229.1522522	1.42
234.9434814	0.17
241.1138	1.36
243.1923218	0.61
245.1069946	0.46
255.360321	0.52
257.1355286	0.99
261.1512451	1.86
263.5005798	1.13
265.119873	0.44
267.1422729	0.42
267.8743591	1.26
269.0001526	0.32
271.2436523	4.89
272.3676147	0.86
273.2285767	1.06
280.12854	0.24
283.4579773	0.26
285.3879395	2.72
287.1490784	4.17
295.31604	1.28
297.2243042	3.23
299.2663574	1.18
301.3081055	0.40
311.1071167	1.18
313.3807983	4.83
314.2022095	0.11
315.3985596	3.83
319.2263794	1.29
320.9819336	2.56
322.0683594	3.02
323.3434143	13.69
328.9554138	0.43
339.2537842	100.00
340.1781311	1.93
341.3703613	17.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	542.1412
Annotation	Acrinathrin
Peak:m/z	Relative Intensity
144.8986053	0.03
162.7718658	1.82
177.1408386	0.42
180.6320648	0.09
188.9181519	0.04
198.4585266	0.13
200.2134094	0.55
209.1362457	1.24
229.0217896	0.12
247.0874329	0.30
252.7696838	0.09
258.8242493	1.28
259.9990845	0.19
270.6411133	0.10
271.2986450	0.08
272.2175903	0.31
276.7327271	0.49
279.1926270	1.01
281.0913696	3.39
282.0199585	0.45
288.9451904	5.75
290.0578613	39.20
291.1613159	1.20
292.0311890	0.05
294.0014038	0.23
295.6946106	0.12
296.9246216	0.71
299.8216858	0.10
301.7550659	0.05
302.6679382	0.16
306.8865356	0.62
308.8812866	0.03
309.8361206	0.38
310.5166016	0.37
319.8773804	0.51
320.7650146	0.28
324.8428955	3.34
325.5088501	0.04
327.1900024	0.37
338.9035645	0.98
342.2702026	0.24
343.0135498	0.57
344.3812256	0.16
354.0997314	0.56
354.7234497	0.07
356.8683472	0.74
358.5624390	0.12
360.9767456	0.09
361.9614258	4.63
369.9781494	17.14
371.0616455	87.73
371.9718628	1.71
373.0392456	1.65
374.4369507	0.37
375.2483521	0.04
377.0350952	0.24
377.8953857	0.13
379.2744751	0.22
379.9571533	1.08
380.9526978	0.24
384.0436401	0.39
387.9699097	0.04
390.3040161	0.28
397.1583862	0.21
399.0924683	1.23
401.9300537	0.70
412.1223755	0.06
414.0516357	0.40
416.9381104	0.73
424.6018066	0.15
441.3963013	0.49
442.5581665	0.08
444.0509033	0.14
451.9598999	7.10
452.5873413	0.04
456.9912720	0.59
458.8711548	4.27
459.8367310	0.42
461.0422974	1.14
471.0181885	0.41
477.8846436	5.03
480.3226929	0.08
481.6362915	0.14
487.7571411	0.61
489.0284424	6.15
490.3846436	0.73
496.0253296	12.66
497.0937500	0.14
498.6766968	0.13
499.8855591	0.17
500.8910522	1.76
501.7628784	0.22
505.7962036	1.22
516.0983276	0.52
518.4190674	1.38
519.1231689	1.66
523.3051147	0.26
523.9589233	1.06
525.3209229	0.23
527.4923706	0.23
529.2302856	0.13
531.0093384	0.14
560.9746704	4.05
576.3640137	0.45
577.1458740	1.07
578.9459839	19.37
650.9898071	0.46
680.9448242	0.42
737.9953003	0.19
739.1326294	1.91
740.9908447	100.00
742.0556030	1.01
744.9061279	0.12
847.8727417	0.11
878.0585327	0.13
918.8945312	0.27
920.4511719	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	474.2536
Annotation	Unknow
Peak:m/z	Relative Intensity
144.7979431	0.80
162.9310608	100.00
169.2911377	0.06
175.0561523	0.13
187.2246704	0.14
190.9313965	0.09
203.1844788	0.08
210.3639221	0.08
221.9902496	0.09
228.7255249	0.20
241.1539917	0.25
244.1985168	0.14
247.2843628	0.06
264.7127991	0.22
285.0357056	0.37
288.7569885	1.37
294.6437988	2.10
295.2692261	0.37
301.0511475	0.09
308.1438599	0.17
308.9118347	0.34
311.3923645	0.09
319.6812744	0.12
322.7313538	2.02
324.0045776	7.72
324.8012695	41.09
327.3989258	0.20
342.3370056	0.26
356.9856873	0.56
358.3156128	0.12
365.3209839	0.14
371.1281128	0.13
385.0985413	1.19
393.4916687	0.09
398.0420837	0.17
402.8366699	0.13
411.1475220	0.14
420.6846619	0.09
427.8536072	0.16
432.9623108	0.35
438.2814941	0.55
439.2117615	0.52
442.0654297	0.28
443.1855164	0.39
455.4698792	0.80
456.4720459	6.97
457.2595520	1.02
464.6074524	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	235.1647
Annotation	Unknow
Peak:m/z	Relative Intensity
101.1374664	0.12
117.9465332	100.00
118.7601776	0.03
131.9687042	5.21
145.1228180	0.02
146.9770203	0.04
154.8457184	0.03
176.0815277	1.07
179.0329590	0.37
206.9840240	0.08
216.8606873	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391.1609
Annotation	Unknow
Peak:m/z	Relative Intensity
112.9682846	2.14
116.6089172	0.21
118.9871521	1.52
123.1294403	0.21
125.2192993	0.16
131.0739746	0.05
134.7410736	0.14
139.1586304	4.34
142.9726410	1.80
146.9491882	1.30
148.6340332	0.27
158.8871155	0.18
160.9350739	4.65
167.1045837	0.25
178.9470215	2.97
183.0544739	78.04
185.2901459	0.29
186.1731720	0.34
197.3189392	0.06
207.0621338	27.71
211.0917053	0.16
213.0898438	0.23
225.1292725	7.18
228.8051147	0.71
237.1508484	0.26
246.1598816	0.18
255.0539551	7.91
267.4857788	0.36
271.1163330	0.19
272.5480042	0.86
273.3727112	0.22
282.1214600	0.04
284.7874756	2.59
285.5019226	0.15
295.6826172	0.13
315.2476196	0.30
315.9692993	0.34
327.1349182	0.06
344.9959717	100.00
345.6725464	0.30
371.1252747	0.09
372.2054443	0.06
373.3771667	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	369.0828
Annotation	Isoferulic acid 3-O-glucuronide
Peak:m/z	Relative Intensity
107.0769653	0.03
110.9731140	2.42
118.8503113	0.03
127.0466614	0.19
129.0061798	9.79
132.9568634	0.04
134.0211945	0.05
134.9951935	0.14
143.1675262	0.05
160.9959106	0.38
163.0952454	0.57
165.1263733	0.04
173.1114807	0.24
174.0325623	0.07
180.9225769	0.09
187.0665588	1.41
189.0653839	1.91
191.0623169	0.23
192.0163574	3.56
204.9733276	37.25
207.1475067	22.33
216.2581635	0.16
217.3974915	0.11
223.0436096	100.00
231.0794983	0.31
232.2404480	0.07
233.1083984	1.90
234.1366272	0.78
235.2094727	1.64
236.3215637	0.10
237.0714722	0.05
266.4646606	0.04
269.0558167	0.04
272.8841553	0.08
274.2229004	0.05
277.3397827	0.05
279.3068848	0.11
280.3801880	0.12
284.1758118	0.11
286.2533264	0.18
293.1036377	0.08
296.1856384	0.23
298.1015930	0.10
300.1763000	0.50
301.5844727	0.06
303.4195557	0.09
307.3229370	0.33
311.0201416	0.04
312.2380371	0.25
314.1677246	0.06
318.1545105	0.21
322.4479675	0.19
323.2784424	0.61
324.2036133	0.19
325.1276550	0.26
328.3082275	0.12
330.3068848	0.06
332.9591675	0.04
342.0579224	0.09
349.0821228	0.11
350.0845032	0.55
351.1154480	4.50
354.2884216	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	569.2236
Annotation	Excavatolide D
Peak:m/z	Relative Intensity
163.2252350	0.04
196.9420471	0.07
215.1860962	0.02
231.0691528	0.01
238.1669312	0.03
259.8874817	0.01
274.0531921	0.04
275.5882568	0.01
279.2805176	0.08
299.1638184	0.04
303.1246033	0.09
305.4507446	0.03
312.4300537	0.02
313.5111694	0.01
319.4715576	0.04
320.2586060	0.03
323.2576904	0.01
325.2752686	0.01
341.2185669	0.06
344.4556274	0.09
346.1909180	0.02
347.3447876	0.44
363.3833618	0.08
368.4841309	0.06
369.3977661	0.34
371.3765259	0.36
374.7832031	0.03
381.3338013	0.02
382.2965698	0.05
387.4223022	0.01
388.2680054	0.04
389.3999634	0.09
395.4324341	0.02
397.4541016	0.03
399.1487427	0.12
400.3682861	0.20
401.0778809	0.11
405.5639038	0.04
407.2391968	1.05
418.2104492	0.06
419.5640259	0.02
431.3345337	0.03
437.1673584	0.26
437.7725830	0.04
447.5135498	0.02
455.1992798	0.01
470.9590454	0.05
472.2756348	0.03
473.1259766	0.01
475.2508545	0.02
476.6278687	0.06
477.4740601	0.04
481.2883911	0.17
482.3485718	0.06
497.3764648	0.03
505.2548828	0.05
509.4553833	0.73
518.3513794	0.01
523.2988892	100.00
523.9465942	0.32
526.6157837	0.02
533.3697510	0.41
538.1054077	0.10
539.2567749	0.02
544.3445435	0.02
549.2193604	0.05
551.3248901	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3143
Annotation	Phyllanthoside
Peak:m/z	Relative Intensity
272.5120239	0.05
286.4515991	0.04
287.3039856	0.03
292.1856995	0.04
316.3644714	0.09
358.4306030	0.07
362.3029175	0.02
384.4495850	0.09
456.6414185	0.07
457.2811279	0.04
462.0084839	0.04
463.5253296	0.02
479.3419189	0.06
488.1537476	0.03
499.4376831	0.05
505.2116089	0.11
507.1401978	0.04
517.8628540	0.02
536.3593750	0.08
539.6568604	0.02
551.4653320	0.03
555.2980347	0.09
561.3971558	0.03
564.4070435	0.07
569.1854248	0.10
584.6208496	0.03
590.6057129	0.02
592.3092651	0.02
593.2835083	0.29
600.4047241	0.02
606.4179077	0.03
610.6542969	0.05
613.2745361	0.03
619.2866211	0.07
620.4622192	0.04
624.6744385	0.04
637.2812500	0.04
641.5883179	0.10
642.2537231	0.42
643.2882690	0.75
648.6513062	0.01
650.4546509	0.90
651.4287720	0.95
655.5654907	0.14
661.4038086	0.15
669.0175781	0.08
670.6867676	0.03
673.8617554	0.03
682.1774292	1.79
683.2289429	0.34
685.0725098	0.03
687.4451904	0.15
692.6641846	0.03
705.7348022	0.16
715.2944946	0.06
717.9440918	0.07
727.7809448	0.23
728.4871216	0.28
729.5805054	0.44
733.6459351	0.02
745.6225586	0.25
751.3786011	0.14
755.3696899	0.38
757.4365845	0.04
758.7803955	0.02
760.5488892	0.30
761.5011597	0.13
762.5753174	0.04
764.7095947	0.20
768.8704224	0.02
773.3732910	100.00
774.1031494	0.19
776.3290405	0.09
777.3568115	0.09
782.8479614	0.16
784.7907104	0.03
786.3488159	0.58
787.5636597	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	821.3568
Annotation	Unknow
Peak:m/z	Relative Intensity
234.2697296	0.09
296.2967529	0.36
341.1591492	0.05
348.9799805	0.09
353.4615479	0.09
373.3985596	0.15
386.3984375	0.19
445.3778076	0.08
446.4941406	0.27
462.4033813	1.04
474.3972778	0.43
480.2666626	0.10
494.2064819	1.35
506.1918335	13.95
507.2427979	0.31
520.4177246	0.06
536.3393555	0.31
537.3360596	0.30
537.9815063	0.08
554.9398193	0.12
573.0520630	0.07
615.3680420	0.28
619.6766968	0.37
625.7866211	0.17
627.3115845	6.53
641.2818604	1.20
642.5052490	0.33
652.3895874	0.41
658.6304321	5.28
659.3164673	100.00
666.2675781	0.14
667.2401733	0.29
673.0280151	0.28
682.9061279	0.42
686.0526123	0.84
698.1723022	1.28
698.8578491	0.29
699.7000732	0.31
700.4034424	0.94
702.4315796	0.05
715.0090942	0.23
757.3359985	0.28
760.7774048	0.15
763.4060059	0.32
775.2905884	0.60
776.9241333	0.75
787.8512573	0.66
788.6070557	2.05
789.3621216	17.23
791.5957642	0.22
793.2670288	0.94
797.3648682	0.28
802.4550171	0.60
803.4195557	2.18
823.2638550	0.08
825.4423218	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.063
Annotation	Unknow
Peak:m/z	Relative Intensity
191.0752106	0.31
205.3002014	0.08
209.1035461	2.50
210.9227448	0.08
222.9380188	0.14
239.0783234	0.05
251.0063477	0.03
256.9816284	0.26
259.1321716	0.23
272.1411133	0.02
273.0548706	0.10
281.0402527	0.06
285.1597290	0.43
287.0689697	4.03
289.4774170	0.06
299.3250732	0.05
303.4163208	0.07
304.1091309	0.04
304.7588806	0.15
311.1605225	4.33
322.9642944	0.27
327.1324463	0.03
329.0935059	0.90
337.3870850	0.23
343.4964600	0.51
364.2920532	0.04
370.9487305	0.06
373.2662964	0.12
384.8009033	0.03
387.0454712	0.18
397.3070068	0.03
398.7908325	0.03
403.0996094	0.28
405.1381226	0.04
411.2848511	0.08
417.4206543	0.14
421.0821533	0.04
423.1250610	0.39
427.4000244	0.09
429.5219116	0.04
431.2735596	0.36
443.3903198	0.03
446.4736938	0.17
447.2783203	1.38
449.4185181	0.27
455.2933350	0.09
457.1588745	0.13
458.4565430	0.04
463.1726074	0.56
473.2877197	0.09
485.3496094	0.15
488.5471191	0.20
491.1693726	100.00
491.7824707	0.33
492.9340210	1.36
496.3853760	0.06
497.8140869	0.14
502.3709106	0.15
511.2568970	0.12
517.3643799	0.03
531.2151489	0.07
532.3497314	0.39
533.1974487	0.52
535.0059814	50.73
535.6192017	0.55
541.1232300	0.10
542.2623901	0.06
542.9942017	0.15
544.3111572	0.04
554.4030762	0.12
555.9067993	0.08
556.8880615	0.09
558.2344971	0.16
559.5025024	0.17
560.9958496	1.38
579.2011108	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.1379
Annotation	Galactotriose
Peak:m/z	Relative Intensity
161.0095825	0.13
162.1576538	0.02
174.9556580	0.01
179.0813293	1.14
180.0294800	0.16
221.1221313	0.19
222.0196838	0.08
250.1279907	0.05
250.8428040	0.06
263.7601929	0.03
280.9017334	0.15
282.2236023	0.04
310.8667603	0.01
311.8707886	0.02
323.3063965	0.55
324.1572266	0.07
341.0405884	2.61
342.0080566	0.81
356.4912720	0.22
357.2230835	0.04
359.3737793	0.19
360.3853760	0.02
376.1062622	0.02
377.1925049	13.77
378.2799072	2.62
383.2258301	0.52
384.2249756	0.15
407.0940552	0.03
413.1930542	0.11
441.8759766	0.07
443.1076660	0.20
443.9930420	0.07
501.6093140	0.03
503.2871094	100.00
504.2429199	29.33
504.9188843	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1296
Annotation	Robinetinidol-(4alpha->2')-robinetinidol-4beta-ol
Peak:m/z	Relative Intensity
169.1388550	0.03
171.2287903	0.06
179.0350647	0.04
183.1288452	0.05
185.1585541	0.21
187.0663147	0.35
189.1326599	0.02
198.8982391	0.05
201.2035217	0.03
204.0111694	0.04
205.0633392	0.11
207.5671082	0.02
208.9749451	0.11
211.1418762	0.16
212.2718811	0.03
212.9962921	0.24
219.0888672	0.04
223.1505890	0.11
224.1651917	0.02
227.2875061	0.20
229.1870575	0.87
238.9765778	0.33
241.1169128	0.45
242.9492340	0.19
246.9129486	0.29
251.2185822	0.06
255.1348877	1.32
256.0504761	0.20
257.0986938	1.24
265.3904419	0.07
267.2326050	0.15
269.1788635	0.18
280.7140503	0.05
283.9965820	6.26
285.0765381	100.00
286.3275757	0.36
296.8659668	0.05
299.1423950	0.35
307.1137085	4.38
327.3214111	0.81
337.1411743	0.06
339.1243896	0.18
340.2485352	0.03
347.5850220	0.07
348.5772095	0.11
357.1561279	0.49
359.2798462	0.13
361.0904541	0.21
369.3070679	0.18
371.2708130	0.14
381.4574585	0.15
382.0776978	0.05
383.9299927	0.14
387.3972168	0.13
389.4486694	0.04
393.0231323	0.07
428.2377319	0.09
429.1931152	0.63
429.9079590	0.14
431.4180908	0.37
447.2604370	11.26
473.3441772	0.14
484.3992310	0.06
492.2307739	0.03
506.9225464	0.11
509.5597534	0.05
531.9002075	0.04
533.2619019	0.04
536.3453979	0.14
546.2226562	0.28
547.2363892	0.38
554.7002563	0.02
555.6714478	0.04
557.1538086	0.50
562.0127563	0.04
563.0814819	0.08
565.3859863	0.05
567.1057739	0.08
574.4189453	0.13
575.6305542	0.23
576.2749634	0.03
580.5476685	0.21
593.0847168	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1454
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
173.1108704	0.06
179.0368500	1.96
183.1575623	0.10
187.1502686	0.19
189.1438904	0.13
191.0337830	0.16
192.9913330	0.49
198.6722260	0.13
203.2236328	0.23
207.1204224	0.32
209.1558838	0.23
211.0383606	0.29
213.1483154	0.33
215.0962830	0.04
217.0999146	0.66
220.9669495	0.08
226.9391174	0.20
228.2084961	0.13
229.1361389	0.63
235.0293579	0.07
239.3596802	0.57
240.0821533	0.15
241.1278076	0.07
242.1058044	0.09
243.1933594	0.22
245.2315369	0.21
246.0938416	0.11
246.9574280	0.14
253.1586304	0.18
254.1172180	0.38
255.0865479	3.23
256.2209778	0.23
257.1262207	0.51
265.1244202	0.03
267.0785522	0.11
269.1909790	0.18
271.1646118	3.73
272.0205078	0.17
273.0634155	0.75
274.0717773	0.11
281.3970032	0.32
283.0656128	0.47
285.1444702	4.03
286.2006226	0.07
287.1915283	0.06
290.2784424	0.04
297.1704712	1.08
299.1243896	1.03
300.0855103	33.88
301.1690063	100.00
302.0964966	0.78
308.9624634	0.22
312.8590698	0.41
322.9459839	0.05
325.1968079	0.36
327.2264404	0.17
337.3651733	0.08
343.1418457	8.65
344.0254517	0.10
349.3197632	0.05
355.1157837	0.68
355.8101196	0.23
365.2318115	0.10
366.1994019	0.21
367.3215942	0.08
368.9667969	0.04
372.9920044	0.33
385.0166016	0.74
409.2776489	0.16
419.1529541	0.10
427.3735352	0.07
439.4243164	0.11
443.1731567	0.02
444.8663940	0.04
445.5691528	0.07
446.5609131	0.06
456.9609375	0.14
463.1865234	0.74
464.1399536	0.15
465.2876587	0.40
473.4710083	0.12
483.5028687	0.05
493.4016724	0.15
523.2880249	0.08
549.3308716	0.18
565.3944702	0.09
566.5368652	0.09
581.5787964	0.06
591.2540894	1.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	573.26
Annotation	Nudifloside D
Peak:m/z	Relative Intensity
170.0774078	0.01
175.0784760	0.02
178.9816742	0.14
191.1382751	0.10
197.0901489	0.08
207.2164459	0.04
231.2369690	0.02
239.1546783	0.02
254.3200989	0.03
274.6952515	0.13
275.3621216	0.71
279.2241211	0.06
289.4527588	0.01
299.9507446	0.02
301.3444519	0.17
303.1815491	0.11
306.2783203	0.07
307.1861572	0.02
334.9773560	0.01
343.2622681	0.01
345.3627930	0.03
347.3602905	0.01
361.3792114	0.01
365.2407227	100.00
365.8416138	0.16
367.3004761	0.01
373.4385376	0.05
375.3652954	0.01
388.3129272	0.03
389.4387207	0.13
393.0850220	0.02
407.2978516	0.34
411.0551147	0.84
411.8171387	0.01
413.5872803	0.04
419.4786377	0.04
436.9070435	0.03
442.4370728	0.03
445.1428833	0.02
448.8746338	0.03
449.5603638	0.09
463.2564087	0.52
477.2864990	0.03
485.6339111	0.11
492.2088623	0.07
493.2653198	0.01
498.3255005	0.04
499.5662231	0.01
509.1618652	0.01
510.5729370	0.18
519.2223511	0.03
525.1876221	0.04
526.9114990	11.41
527.5917358	0.06
528.9367676	0.09
535.4519653	0.33
536.4262085	0.18
537.4670410	0.20
544.1771240	0.04
554.5892334	0.09
555.2325439	0.08
572.7805786	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	307.0826
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
117.7378693	0.27
130.0098877	44.80
130.9903717	3.20
137.1086731	0.10
143.9934387	0.40
159.8109589	0.18
161.8870087	0.66
177.0434570	0.05
178.9028015	1.44
187.2441711	0.24
199.0472717	0.49
210.9678955	0.77
215.0201416	0.08
218.6057129	0.25
219.8601685	0.12
231.1626282	3.54
232.0469055	0.27
233.0535583	0.15
234.1321716	0.50
235.1029663	1.27
236.3403320	0.08
242.6560669	25.14
243.9491882	1.98
244.9781799	0.06
246.9436035	1.62
252.0898438	0.09
255.6574097	0.10
257.0948486	0.94
258.2327576	0.13
260.7317505	1.68
262.9692993	0.28
264.1786499	0.20
265.3783569	0.10
267.3723755	0.27
269.6260376	20.37
270.3217468	5.46
272.3454590	0.12
273.5980530	0.07
274.3695068	0.11
275.6927185	46.32
276.6273804	2.55
277.7269897	0.15
278.7526550	0.50
280.0579834	0.11
289.2235718	0.72
290.3655701	1.24
290.9869080	0.49
298.5462646	69.86
299.1673279	16.43
299.7755127	2.36
306.3020020	0.30
308.3378296	0.76
309.1302185	0.48
337.0543518	0.79
337.9717102	0.29
340.2688904	0.21
355.1425476	100.00
356.1365051	11.77
357.1518860	4.59
364.0000610	0.55
381.0557556	4.55
382.1074219	1.06
383.1201477	0.16
391.2359619	0.80
401.2222290	0.30
409.2349548	11.31
410.1084900	1.42
411.2781677	0.08
421.3690796	0.17
421.9941101	0.15
423.1282654	0.18
437.2238464	0.24
445.5814514	0.28
458.8005066	0.23
466.1716614	2.01
467.2173462	0.97
468.0141296	0.07
475.1134644	0.08
484.1383972	78.39
485.1277161	13.99
486.1706848	4.06
520.3024292	1.54
521.3068237	1.02
522.3683472	0.12
538.2871094	18.51
539.2763672	5.72
540.2810669	1.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	307.0804
Annotation	Leucocyanidin
Peak:m/z	Relative Intensity
94.9680328	0.25
121.0725708	0.14
123.0318375	0.37
126.8674011	0.16
133.2369995	0.10
138.9630127	86.39
139.7813110	0.10
150.9161987	65.67
153.0954590	1.94
163.1179199	1.91
169.0456238	6.76
173.9919739	0.23
180.9179993	11.80
193.3359222	0.05
226.1803894	0.88
247.1251221	0.09
256.9072571	0.26
257.9620056	0.29
261.0551147	0.25
262.8896484	0.18
265.2167358	0.49
266.1143799	0.41
271.1112061	0.47
278.6127319	0.51
279.2593079	0.31
289.0600281	100.00
289.6668701	0.15
297.6891785	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	487.18
Annotation	Unknow
Peak:m/z	Relative Intensity
144.9489288	53.18
154.7821045	0.32
157.1284637	0.18
161.1148376	0.51
175.1841125	0.60
179.0194550	2.96
250.3240051	0.20
280.2131042	0.34
280.9234924	0.40
303.1018677	0.10
323.0251770	0.25
341.1867981	100.00
399.5339050	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	524.1959
Annotation	Herbicidin E
Peak:m/z	Relative Intensity
146.8725586	0.47
163.0779419	0.14
165.0402527	12.39
181.9707031	100.00
226.9515076	0.04
231.1422424	0.08
253.0123291	0.21
263.0390625	0.04
275.9804077	0.20
282.1376648	0.14
288.7562256	0.23
297.1942749	0.23
306.5475464	0.12
309.2087402	0.07
311.1920166	0.06
316.3629761	0.38
325.0935669	0.34
326.1107178	0.20
332.2194824	0.41
340.3038330	0.09
342.6420288	0.57
343.4945068	1.05
344.0953369	3.43
361.3649902	1.22
362.0307007	4.41
363.9938354	0.06
370.8378296	0.16
377.2828369	0.46
391.5653076	0.08
392.3863525	0.18
393.4289551	0.17
395.0695190	2.85
419.1123047	0.63
420.3712769	0.04
426.3953857	0.14
433.9672241	0.23
449.1817017	0.04
464.3461304	0.11
478.1639404	0.19
479.7106323	0.10
488.0510864	0.25
497.4801025	0.18
505.0952148	0.07
506.1453247	0.80
507.2108765	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.0622
Annotation	8-Hydroxytricetin 7-glucuronide
Peak:m/z	Relative Intensity
143.4531250	0.04
148.8755951	0.03
151.0699463	0.04
155.0305634	0.11
158.1525879	0.11
159.2139893	0.07
161.0236206	0.04
162.8658295	0.16
167.1236725	0.20
168.9348755	0.10
171.0749054	0.07
175.1142273	0.25
176.1691437	0.12
178.9501801	0.41
182.3227234	0.08
187.0358887	0.73
190.2467346	0.15
190.9328613	0.31
197.0283203	0.09
198.9841309	0.24
202.1089478	0.05
203.1536560	1.11
211.1914368	0.07
213.0194092	0.13
213.9085236	0.04
214.9546051	1.62
217.0242004	0.91
218.8438873	0.04
224.2991028	0.08
225.1995850	0.07
226.9754791	0.10
229.0613708	0.03
230.0530853	0.24
231.1886292	1.26
233.1620789	0.17
235.0762024	0.22
241.1436310	0.70
241.8888855	0.09
243.1469269	2.16
243.9921417	0.07
245.2410278	0.12
247.0737305	0.20
253.2996826	0.22
254.4762878	0.40
255.2078857	0.06
256.0579834	0.04
257.2055359	0.79
257.9938049	3.21
259.1255493	24.81
260.1189880	0.12
263.0742798	0.13
269.1671143	1.63
271.1815796	0.23
272.2296143	0.31
273.2812805	0.78
274.0263062	0.17
283.1372986	1.32
285.0257874	1.63
287.0540771	100.00
288.1255188	6.11
289.2724609	0.81
295.3067017	0.47
297.0591431	0.31
298.1521606	0.35
299.1253052	0.10
301.1046143	3.32
304.1429749	0.20
305.9226379	1.57
306.8564148	0.06
309.3845825	0.17
311.2203369	0.52
312.2528076	0.26
313.2626953	0.45
315.0720215	0.47
316.0410767	0.08
317.0945129	0.03
318.5032349	0.07
323.0634766	0.11
327.1129761	0.03
329.0642700	3.38
330.1734314	8.84
331.0977783	56.48
332.2294922	0.18
337.2544556	0.28
342.4675903	0.14
343.3504028	0.33
345.2745972	0.27
347.2061157	0.03
350.1543274	0.20
351.3001099	0.17
353.7136536	0.05
355.2012634	0.06
356.3036499	0.13
357.2861023	0.04
359.0950928	0.29
361.2333984	0.80
363.2816772	0.11
364.3692627	0.29
367.2571106	0.09
371.0120239	0.45
372.1690063	0.12
373.2530518	0.22
377.7746582	0.24
387.1588440	0.50
387.9291077	0.07
395.2778625	0.04
397.0673523	0.07
398.9861755	0.05
402.2485962	0.17
402.9830017	0.35
404.3479004	0.06
405.0901794	0.42
408.5027771	0.12
419.2297363	0.07
421.2640686	2.33
425.2123718	0.05
431.2245178	0.15
432.2738342	0.57
433.2705078	0.97
446.3779602	0.44
447.0517883	0.37
449.1325989	8.07
449.8714294	0.06
456.1357727	0.26
457.2042236	0.16
460.4874573	0.09
463.4617004	0.25
465.5845032	0.03
467.4459534	0.09
470.6549377	0.17
473.0458679	0.07
474.3983459	0.67
475.3026428	1.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	850.3171
Annotation	Unknow
Peak:m/z	Relative Intensity
462.3125610	0.13
471.2575684	0.19
478.5176392	0.10
481.3878784	0.04
510.4672852	0.06
549.0592651	0.16
553.4439697	0.17
572.5637207	0.48
584.9035034	0.11
623.6102295	0.12
645.5115967	0.24
662.2112427	0.14
664.5131836	0.49
682.4164429	0.08
687.3150024	0.19
688.3283691	0.18
695.5305176	0.03
697.2558594	0.11
702.3878784	0.05
705.4985962	0.07
714.3812256	0.20
726.5245361	0.06
728.4486084	0.08
755.3198853	2.35
755.9425659	0.09
772.1657104	0.11
773.5200806	0.08
774.7494507	0.15
785.4108276	1.12
787.3605347	100.00
788.0286255	0.60
789.2412109	0.08
790.4934692	0.32
800.6003418	0.07
803.2509766	0.15
804.2133789	0.05
805.4223022	0.12
806.4195557	0.17
811.3717651	0.09
817.4349365	0.59
818.2622681	0.54
831.6566772	0.20
832.2724609	0.19
849.7818604	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.0878
Annotation	Spiraeoside
Peak:m/z	Relative Intensity
136.8077393	0.01
145.1905212	0.04
151.0873718	0.83
153.1914978	0.06
161.1521912	0.03
174.1534271	0.03
175.066864	0.07
178.9857483	1.16
182.9733887	0.02
187.3544006	0.03
189.089447	0.11
189.9937439	0.06
191.1715088	0.08
192.0653992	0.10
197.0933838	0.02
199.2015381	0.01
205.079483	0.02
206.9481201	0.03
209.2580109	0.01
212.3876343	0.04
214.9559784	0.13
216.6786346	0.08
217.2893982	0.08
219.1669617	0.01
221.0943756	0.12
222.0312195	0.02
227.0618286	0.04
229.1442871	0.02
231.0193176	0.02
233.0475464	0.02
240.9465637	0.04
243.0745239	0.04
246.9795227	0.02
251.1591492	0.03
252.8175659	0.02
254.1448364	0.12
255.1192017	0.41
256.1770325	0.03
257.0562744	0.10
259.0111694	0.03
261.3045044	0.03
269.1699524	0.08
271.0879211	0.42
272.1539917	0.03
273.1069336	0.26
275.324585	0.01
277.3819885	0.02
281.2142029	0.03
283.2626038	0.12
285.3371277	0.05
295.2707825	0.02
297.1047363	0.14
300.0606689	22.70
301.0434875	100.00
301.9196777	0.26
302.5255127	0.02
309.2900391	0.10
311.3672485	0.05
313.0037231	0.15
315.1030884	0.11
316.3699036	0.01
319.4722595	0.12
322.9326172	0.09
325.1838684	0.12
329.3435059	0.02
331.3618164	0.06
337.1430359	0.19
338.0316162	0.02
343.1342163	1.86
347.2351685	0.02
353.2120972	0.04
355.0826416	0.16
357.1281433	0.03
359.291626	0.05
365.2408752	0.02
373.374054	0.07
375.0660706	0.03
381.1180115	0.02
390.9954529	0.06
401.2657166	0.02
409.3878174	0.06
415.5728455	0.02
416.3240967	0.08
417.4390259	0.01
419.3587036	0.05
426.0784912	0.07
445.0113831	0.44
445.7722778	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	246.9918
Annotation	Vanillic acid 4-sulfate
Peak:m/z	Relative Intensity
79.8950348	3.42
96.9020233	7.76
108.1650543	0.14
122.9795380	1.33
129.2657166	0.04
132.0853271	0.03
138.8654022	0.24
152.1146240	0.24
167.0752869	100.00
168.1493988	0.04
184.9771576	0.03
188.3007050	0.04
189.3453064	0.03
203.0172729	45.76
211.5362091	0.05
219.3001251	0.04
228.1044312	0.03
229.2425537	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	338.1606
Annotation	Aucherine
Peak:m/z	Relative Intensity
100.1343231	0.08
102.2020264	0.10
126.0162888	0.12
127.9711914	60.42
129.0377808	6.22
130.0701904	1.38
131.1546021	0.13
144.2379761	0.15
146.0308838	5.64
147.1228638	0.79
164.1371307	0.06
165.1738586	0.20
172.2849426	0.31
183.8757019	0.03
191.2971649	0.05
209.1600952	24.18
210.1369934	8.14
224.4776611	0.05
225.2833557	0.07
232.2332458	0.04
236.2531433	0.11
237.6095886	0.04
245.0403442	0.02
259.0288391	0.17
261.4549866	0.03
268.2243347	0.05
276.2111206	0.30
277.2366638	0.21
279.1934204	0.04
281.2542725	0.06
284.6756592	0.03
293.2359619	0.03
294.2696533	6.82
295.3665161	3.54
300.9976501	0.02
320.2180786	100.00
321.1764526	41.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	744.1442
Annotation	Unknow
Peak:m/z	Relative Intensity
224.9870148	0.04
240.4049377	0.10
241.3011322	0.08
299.1488037	0.17
300.0491028	0.09
303.0321655	0.10
305.2235718	0.15
305.9240112	0.04
307.1759644	0.06
333.3140259	1.62
345.2610474	0.05
355.3005371	0.08
361.9263916	0.19
373.4302979	0.04
420.1875000	0.70
428.0299072	0.04
449.3774414	0.04
471.7062988	0.08
473.3049316	0.12
498.0968018	0.51
512.4381714	0.05
536.4046631	0.07
552.2782593	0.18
557.1779175	0.05
568.1616821	0.07
576.3914185	0.10
578.1513062	0.12
582.2087402	0.15
586.2456665	0.08
591.2562866	0.13
623.5189819	0.46
625.3612671	2.02
651.7857056	0.09
657.2904663	100.00
659.4024658	0.69
660.3912964	0.06
662.7535400	0.54
672.2737427	0.41
693.2048340	0.46
699.9165649	0.05
700.5399170	0.13
707.5309448	0.04
710.3969727	0.28
712.0346069	0.05
723.9225464	0.08
725.2207031	0.77
726.3171997	0.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.0727
Annotation	Melicitrin
Peak:m/z	Relative Intensity
127.9627914	0.04
147.1280823	0.04
150.9599915	0.14
152.9320068	0.02
157.1927795	0.02
169.0261536	0.15
172.8903809	0.02
174.6777039	0.01
177.2612610	0.01
178.9690247	0.33
185.0997620	0.04
187.2242432	0.01
191.2569885	0.02
203.0720825	0.08
205.1790466	0.04
207.0657806	0.11
211.0116425	0.03
214.7204285	0.01
215.3379517	0.01
216.8449554	0.03
219.3793640	0.05
221.0527496	0.03
227.2446899	0.08
231.1913910	0.02
232.0987396	0.03
233.1013184	0.62
241.2226562	0.04
242.1826782	0.04
243.1824951	0.21
244.2836304	0.02
245.0735474	0.11
247.2360229	0.03
250.1948242	0.07
253.3395691	0.03
255.2020874	0.09
257.2714539	0.05
257.9894104	0.05
259.1272583	0.71
260.0787659	0.18
261.1080322	0.41
263.0704651	0.02
268.3463135	0.03
269.2279358	0.04
271.1782532	0.05
272.1577148	0.03
273.3078308	0.02
277.3593445	0.04
281.2318726	0.01
283.1397095	0.03
285.2106323	0.16
287.0636597	100.00
288.1331177	0.30
289.1770630	0.36
291.2359619	0.03
293.1376038	0.03
297.0417175	0.11
299.2116699	0.14
301.2803955	0.10
303.1275024	0.34
307.0515137	0.09
309.1920776	0.11
310.1560974	0.07
311.2195435	0.13
315.4247131	0.11
319.2398071	0.02
327.2317505	0.11
328.2504272	0.02
329.1417847	0.77
331.2078857	0.04
333.0924072	0.11
339.0537720	0.04
345.2102051	0.05
347.4304199	0.01
349.2706299	0.10
353.1651917	0.26
359.1436157	0.03
361.2489319	0.01
362.9851685	0.10
365.4287415	0.03
367.1088867	0.03
374.7421570	0.05
377.4316101	0.05
379.1039734	0.32
387.0424500	0.03
389.3027039	0.03
392.9940796	0.17
402.1993713	2.62
403.2353210	0.91
405.1098022	1.47
407.0383606	0.03
411.3564148	0.04
412.2940979	0.02
420.9748230	0.21
429.1253357	0.02
431.2042542	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	222.1345
Annotation	Dihydrozeatin
Peak:m/z	Relative Intensity
68.9636993	0.40
85.9637756	0.06
86.9688568	0.34
110.0011902	0.05
120.0045319	0.21
122.9133606	0.04
135.9733124	100.00
136.9874573	5.66
139.1968231	0.01
148.0388641	27.27
149.4035797	0.04
152.1227875	0.07
154.1683350	0.06
155.0597687	0.12
161.1271210	0.07
162.0318146	0.16
166.0731964	3.59
175.0638885	0.08
176.0507050	0.61
177.1812134	0.04
178.0306244	0.03
180.8584442	0.12
186.3617096	0.08
187.0884552	0.12
190.0470428	0.07
191.0656128	0.13
192.4999847	0.11
194.4597015	0.10
195.1909180	0.23
200.8572998	0.17
201.6683350	0.11
204.1049194	36.75
205.1988220	0.22
209.6692352	0.21
210.3685455	0.08
222.1748657	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	230.2473
Annotation	Xestoaminol C
Peak:m/z	Relative Intensity
68.9968491	0.13
70.7775803	0.06
80.9582138	0.06
82.9880829	0.17
85.1255951	0.08
97.0541382	0.45
99.0281525	0.08
111.0040741	0.65
112.9690247	0.14
124.9525909	0.53
128.2209167	0.03
138.9197540	0.11
152.2153625	0.02
153.0052185	0.04
156.3897095	0.04
170.2322540	0.16
171.0009003	0.07
174.1226654	0.05
181.8130188	0.07
183.8730316	0.03
185.2009735	0.09
188.9522400	0.07
192.2089539	0.06
194.1749420	0.04
195.1681671	0.09
201.6532135	0.07
212.2137299	100.00
213.0467377	2.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.1241
Annotation	Ethyl (S)-3-hydroxybutyrate glucoside
Peak:m/z	Relative Intensity
84.9531555	2.86
86.6780014	0.31
88.9434052	2.79
94.9114990	0.19
98.7355423	0.10
101.0078049	2.46
111.9500046	0.10
113.0368576	4.94
114.9812088	2.76
118.8950195	3.28
122.8406219	0.09
124.9706116	1.65
127.1323013	1.34
127.8830566	0.99
129.0567474	0.58
130.9730530	100.00
142.9158783	2.41
144.9307861	0.13
149.0969238	1.13
154.9713745	0.24
156.8674011	0.10
160.9606476	1.70
163.1114197	0.12
163.9150696	0.10
167.0311737	3.26
173.0458069	4.38
174.0635986	0.10
177.0639954	0.16
178.8884583	0.48
180.8560791	0.11
185.0383759	0.30
187.1587219	1.53
188.9015656	0.16
203.0616455	4.89
205.1639404	2.48
206.9616394	0.52
219.3599243	0.09
221.0491943	4.71
226.9907837	0.24
231.0856934	6.08
233.0201111	0.09
237.1987305	0.13
247.0405884	0.73
249.1575317	2.80
255.2822876	0.53
257.0496216	0.35
263.2114563	0.51
275.1518555	7.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
81.04755402	2.77
95.15094757	1.01
96.89640808	0.33
104.9956818	0.33
106.9861298	0.54
109.8878937	1.10
111.2153015	2.76
120.9403229	1.93
123.2049713	0.71
124.9870605	0.83
128.995224	10.73
130.0702515	1.82
132.9703827	1.93
139.0149841	1.03
143.1288605	0.65
151.0607147	79.61
152.0500793	3.86
153.0604248	1.76
159.3321686	2.37
161.0590363	1.67
163.2279053	0.36
165.0778656	1.42
167.0198822	1.06
169.1025696	1.67
171.1166382	3.48
175.0892639	1.56
179.0560455	3.26
180.0786285	0.50
180.8787537	1.06
182.093399	3.41
182.9846344	1.00
185.1086273	4.42
191.1249237	3.37
193.263382	0.29
194.0675507	2.67
195.4049225	1.11
197.139389	7.78
199.2724457	1.82
207.2230988	6.78
208.7902985	0.92
210.3595734	1.27
211.2020111	3.54
216.7246094	2.51
217.3663177	7.31
223.0899811	0.50
225.0620728	20.02
226.2473145	2.32
234.3869629	0.49
235.2120819	46.92
236.2833252	2.55
238.0391235	21.10
239.0077667	3.56
244.927063	1.63
253.0939331	100.00
254.1473846	14.77
259.8192749	1.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	477.14
Annotation	4'-O-methyl-(-)-epicatechin-7-O-beta-glucuronide
Peak:m/z	Relative Intensity
179.0261688	0.06
199.1896667	0.02
208.8912964	0.03
239.2931671	0.08
243.3727722	0.06
251.1806030	0.08
253.4579163	0.03
266.4334717	0.24
267.2071228	0.25
271.2000122	0.15
274.9296570	0.17
276.1289062	0.07
281.2483215	0.07
283.4408264	0.12
294.1650696	0.05
297.3335266	0.37
300.2529907	0.02
301.1175232	0.26
311.1732788	0.11
312.8560791	0.10
313.6763306	0.21
315.0871277	3.85
316.2112122	0.09
317.1198425	0.03
327.1925964	0.13
327.8692017	0.03
331.2705994	0.08
333.0464478	0.02
335.2854309	0.03
338.1373901	0.03
341.2536926	0.10
343.4065857	0.05
355.3400269	0.22
357.1860962	100.00
358.3973389	0.07
360.4200134	0.03
361.3678589	0.33
363.2381592	0.06
369.1517029	1.42
373.1327515	0.06
373.7940979	0.05
380.6091614	0.07
381.2485962	0.05
383.2724915	0.04
387.1886292	58.31
389.1599121	0.40
390.3190002	0.38
393.5527649	0.08
396.3468323	0.11
399.2920837	1.53
404.3064270	0.06
413.3521423	0.13
414.1605225	0.05
415.1760559	0.12
416.1071472	0.15
417.2070312	1.58
423.2263184	0.13
429.3723450	0.43
430.3247986	0.30
431.3824158	0.60
432.6020813	0.13
433.2934875	0.19
437.5292053	0.05
439.0252075	0.07
441.1938171	1.58
447.2483521	0.34
449.1357117	0.25
457.8719177	0.38
459.1846924	12.49
459.8493347	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	614.9
Annotation	Unknow
Peak:m/z	Relative Intensity
199.1542969	0.09
217.2303162	0.02
229.0072632	0.11
273.0565796	7.65
386.9898682	16.39
458.9727783	0.11
461.1780396	0.06
496.7321777	0.04
499.2230835	0.42
500.8791504	100.00
501.5142212	0.41
530.3403320	0.02
539.7838745	0.21
568.0307617	0.12
568.9506226	0.26
571.0013428	0.06
582.6032104	0.02
596.6231079	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
135.1170197	0.51
143.1880493	0.67
153.2339478	0.76
159.0517578	0.49
171.0417786	3.04
172.8450317	1.04
185.0299377	2.28
194.2649536	0.59
198.0349884	0.67
199.2560883	0.29
201.3287811	1.04
203.3241272	1.06
213.2172852	0.28
215.0914612	2.45
217.3431396	0.48
227.250061	1.51
229.2210999	4.94
230.1298218	1.33
231.0113525	1.10
237.2449341	1.01
239.3380432	0.26
243.1929932	5.29
253.1239624	0.51
253.7640381	0.75
255.2416687	0.91
257.262146	8.42
259.1427917	0.35
263.2325439	2.31
265.3663025	0.76
269.2709656	2.77
271.3318176	6.73
273.2188721	1.20
274.212677	1.04
277.2437134	1.56
278.3929443	0.59
283.1298218	3.70
285.4292603	5.08
287.2597046	1.31
295.2447205	0.57
297.3004761	12.08
299.3108215	4.28
301.0575562	2.40
309.270813	0.18
311.020813	0.65
313.1062012	3.78
313.7816162	0.71
316.3750916	0.33
319.2965698	2.09
320.2243652	0.67
321.229248	3.65
323.4045715	4.07
325.3906555	1.59
339.2576294	100.00
339.8661499	3.15
341.4228821	19.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	360.1494
Annotation	Lactulose
Peak:m/z	Relative Intensity
127.0058441	0.21
130.0934143	0.21
144.9459381	1.40
146.9361877	0.35
162.7975159	2.58
179.9916077	7.93
181.0431061	0.74
198.0282440	3.88
227.1994324	0.21
228.0887146	0.27
228.9298706	0.18
250.0405579	0.23
255.0158081	0.15
258.4010010	0.37
259.0531006	1.60
271.2429504	0.14
276.7131348	1.95
277.3792725	0.19
281.8540344	0.13
287.6081543	0.30
288.8223267	8.81
289.5643311	0.20
305.5069580	0.45
306.5699158	5.46
307.1851196	3.64
315.1650391	0.24
319.1604004	0.25
322.7299805	0.28
324.9021912	100.00
333.4079285	0.23
341.3680115	2.18
342.1474915	14.05
342.9268799	43.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	913.183
Annotation	[Gallocatechin-(4alpha->8)]2-gallocatechin
Peak:m/z	Relative Intensity
254.1675415	0.17
255.1288757	0.16
261.0522461	0.47
261.9867859	0.11
282.4832153	0.18
283.2144775	0.32
285.2183838	0.27
289.0125122	0.37
299.2990417	0.24
301.1753235	0.41
303.1644287	6.12
305.2148438	4.64
313.0474854	0.18
314.9901123	0.59
316.3043823	0.10
317.1569214	0.07
333.0187988	0.15
338.1106262	0.21
343.1734924	0.66
345.0362549	0.39
347.3317871	0.07
355.0148315	0.27
357.3872375	0.46
365.2314453	0.47
367.2061462	0.22
369.2606812	0.35
379.1204834	2.26
379.8108826	0.11
391.1296387	2.98
395.4174194	0.12
397.1652832	1.12
399.6041870	0.20
408.9656372	0.15
411.1716919	1.30
421.1719360	2.16
423.2427979	19.03
429.1324463	5.27
430.3470459	0.41
430.9772949	0.06
437.0050049	0.42
439.1605835	4.34
441.2501831	6.82
449.4326172	0.12
451.4747314	0.09
463.1492920	0.87
465.1312256	2.86
467.5733032	0.46
469.3941650	0.10
470.2728882	0.34
471.4409790	0.18
479.1945190	0.19
481.1135864	2.01
482.1773071	0.32
483.1616821	10.01
484.9803467	0.35
515.3832397	1.20
523.2853394	0.30
525.1848145	0.22
529.3883057	0.20
533.2128906	1.32
538.3329468	0.07
541.2763672	11.41
543.4516602	0.12
547.3198242	0.90
548.4729614	0.28
549.2471313	0.41
559.1467285	26.40
560.2271729	0.06
561.1359253	0.31
563.3167725	0.29
565.0322876	0.89
567.1316528	0.62
573.2308960	0.27
574.2935181	0.17
575.4479370	0.36
577.1811523	9.95
578.6750488	0.21
583.1845093	0.86
584.2838135	0.09
586.2297363	1.70
587.3995972	0.15
589.2178345	1.41
591.3255615	2.11
591.9396362	0.39
593.3069458	0.99
599.1867676	0.71
600.3054810	0.31
601.3182983	3.87
602.3179932	0.33
603.6487427	0.19
607.1712036	8.71
608.1009521	1.21
609.2490845	14.21
610.2351685	0.43
617.1878662	0.06
619.1753540	5.16
633.2922974	0.26
647.8181152	0.21
649.5386353	1.38
651.0923462	3.03
661.3742065	0.35
667.6443481	0.97
672.2220459	0.30
683.3587036	1.12
690.2414551	0.30
695.0333252	0.37
696.3473511	0.67
701.0665283	1.34
704.0947876	0.51
709.2362671	4.75
717.3948975	1.68
721.5697632	0.08
724.9039307	1.13
727.1157227	100.00
727.7855225	1.51
728.4616089	0.04
733.4513550	0.21
735.1599731	0.45
735.8248901	0.55
737.2980347	0.22
742.9070435	0.18
744.4699707	3.25
745.2214966	17.95
746.1959839	0.15
747.4667358	0.25
750.2093506	0.69
754.4545288	0.44
756.2745972	1.21
757.1170044	0.19
759.1535645	0.10
760.3894653	1.06
761.2056274	0.22
764.2200317	0.25
768.2071533	0.23
769.5255737	2.38
775.0646362	0.79
785.0029297	1.22
786.0910034	0.82
787.1841431	18.86
788.8001099	0.12
801.5157471	0.30
810.0238647	1.61
810.8477783	0.38
819.3365479	7.57
820.3126831	1.42
828.2443848	5.33
837.5173950	0.26
840.8383179	0.09
849.3150024	2.60
850.2528687	2.19
851.0471191	2.11
853.2061157	0.11
869.3233032	1.17
870.1127319	0.34
872.8023682	0.15
877.2764282	0.61
883.8364258	0.48
885.0646362	0.36
892.8391724	0.07
894.4364014	1.68
895.2198486	4.11
896.2208862	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2778
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
153.0102386	0.12
183.0224457	0.03
188.8605957	0.03
196.2322388	0.37
205.9370575	0.04
214.0212402	1.48
261.3514709	0.31
279.2937317	100.00
279.9452209	0.20
313.3507996	0.01
316.0609131	0.01
328.1873169	0.02
365.0614014	0.01
375.3962708	0.04
403.2595215	0.04
427.8883972	0.03
437.4872437	0.06
440.1026611	0.06
458.0553894	0.11
462.0829468	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.2498
Annotation	Valtrate hydrine B3
Peak:m/z	Relative Intensity
179.0212250	0.10
203.2517242	0.10
207.2673035	0.03
215.1847839	0.04
227.0335388	0.09
229.0923767	0.04
243.2087097	0.02
244.8827820	0.04
259.2668152	0.15
261.3069458	0.06
266.5410156	0.15
268.4515381	0.11
281.5308533	0.07
292.3646240	0.04
293.1154175	0.06
299.1940918	0.11
314.1049805	0.10
331.3245239	100.00
349.1667480	0.04
368.8999023	0.04
373.1434326	0.05
377.2343140	0.17
388.2037964	0.09
395.1203003	0.05
399.4210815	0.11
403.0693970	0.12
406.3785400	0.25
407.2371826	0.03
411.1713867	0.07
413.2463989	0.04
430.8948975	0.13
436.7842407	0.03
441.1250610	0.05
446.6156006	0.27
448.4412842	0.02
459.2954102	0.05
463.3545532	0.10
464.2136841	0.10
465.1959839	0.03
467.4372559	0.04
475.3718872	0.05
477.2560425	0.09
478.4003296	0.21
479.4768066	0.35
481.0822144	0.03
483.5032349	0.45
484.2192993	0.06
491.0028687	0.07
493.1519165	11.16
494.9381104	0.95
495.6765747	0.01
497.4177856	0.29
500.3354492	0.11
501.4168701	1.65
502.4426880	1.01
503.4509888	0.41
509.8579712	0.04
511.4777832	0.14
519.4271851	0.08
521.1373901	0.38
521.9098511	0.10
525.2168579	0.06
530.4699707	0.04
537.2185669	0.04
539.3452148	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	913.1821
Annotation	[Gallocatechin-(4alpha->8)]2-gallocatechin
Peak:m/z	Relative Intensity
255.0067596	0.28
257.2673035	0.13
259.2166443	0.08
261.0332336	2.29
270.2685547	0.07
271.1855774	0.06
273.2164917	0.11
274.0920105	0.12
279.7522583	0.20
283.1277771	0.38
285.2791748	0.23
286.0836182	0.10
293.2188110	0.10
295.1415100	0.21
297.3805847	0.09
298.1878967	0.12
299.1665955	0.08
301.1164246	0.11
303.0122375	5.65
304.1398315	1.49
305.2285461	8.10
306.1805115	0.47
315.2213135	0.50
330.3618164	0.03
333.2116089	0.13
335.4417419	0.32
338.0664368	0.33
343.2275391	0.07
347.1999512	0.32
349.4353638	0.16
350.1138306	0.12
353.2279663	0.48
354.2660522	0.12
355.2626038	0.11
357.3822327	0.08
358.3515930	0.14
365.2161865	0.06
368.5020752	0.25
373.2369385	0.17
379.2448730	2.40
380.1426392	0.28
385.2776489	0.65
386.3421631	0.12
387.1806641	0.38
391.1867676	2.78
392.1434937	1.51
395.5937500	0.28
396.4041748	0.27
397.1530151	0.08
398.2126465	0.52
403.2796631	0.56
404.0806580	0.18
405.3103027	0.20
406.1029053	0.04
409.4010925	0.10
411.1412964	1.20
412.3586426	0.55
413.1097412	0.35
419.5836182	0.22
421.2036743	2.57
423.1889648	17.88
424.1114502	3.68
429.1677856	6.86
430.3907471	0.92
433.0530396	0.12
434.0112305	0.28
439.1453857	2.61
439.9987183	0.87
441.1568604	8.28
442.0896606	1.31
450.9268799	0.17
452.1213989	0.15
455.3991699	0.08
461.3623657	0.21
463.1719971	0.55
465.2313232	1.31
466.2241211	0.52
468.2501831	0.40
469.1071777	0.06
471.1959229	0.09
475.2818604	0.27
476.3568726	0.13
479.0036011	0.32
481.1638794	4.40
482.3350830	1.52
483.2337646	8.47
484.2793579	2.23
495.0440063	0.72
504.7231445	0.20
507.0513306	0.05
511.2041626	0.20
513.3771362	0.17
515.3226318	0.81
523.2785034	0.13
525.1968384	0.17
533.1437988	0.34
534.3602295	0.15
535.3624268	0.11
539.3845825	0.16
541.1610718	11.21
542.1520386	2.89
543.2590332	0.32
544.3739014	0.09
547.1512451	0.46
548.9889526	0.44
552.2796631	0.08
557.4714355	0.15
559.1675415	25.79
560.2619629	10.23
563.4848633	0.08
564.7206421	0.65
565.5345459	0.93
566.3845215	0.18
568.1859131	0.05
575.2941895	0.24
577.1412354	10.70
578.2138672	1.97
580.4103394	0.39
583.1253052	0.59
584.0042114	0.47
589.3189087	1.74
590.2662354	0.87
591.1994019	2.10
592.3031006	1.37
593.4147339	0.55
595.1412354	0.12
599.0307007	0.10
600.7245483	0.71
601.3358765	2.82
602.3607178	1.02
603.3554688	0.37
604.1582031	0.04
605.2981567	0.27
607.1101685	12.83
608.3200073	2.46
609.2602539	14.59
610.3251953	2.87
617.2597046	0.16
619.1590576	5.01
620.3038940	1.27
625.1505127	0.55
626.2824707	0.30
632.2383423	0.09
633.4132080	0.14
648.1143188	0.08
649.1850586	0.81
650.1846924	0.29
651.1190796	1.51
651.9955444	0.39
657.4409180	0.17
658.3598022	0.07
659.3189087	0.80
661.3203735	1.63
662.5403442	0.11
665.2827759	0.08
667.3507080	1.21
676.5444946	0.27
682.7041626	0.24
683.4336548	0.17
684.3148193	0.20
695.4773560	0.10
701.1212769	0.73
702.3640747	0.48
709.1488647	3.76
710.2794800	1.44
713.9120483	0.30
716.4148560	0.08
717.1914673	0.10
717.8782959	0.20
718.5771484	0.08
726.0230713	0.30
727.1769409	100.00
728.2734375	34.91
729.3978882	0.58
731.0635986	0.39
735.3922729	0.13
736.4165039	0.28
738.4706421	0.27
743.2434692	0.56
745.1029053	27.90
746.2249146	6.39
748.9733276	0.28
751.2017822	0.13
752.1033325	0.26
757.1583862	1.63
757.9577026	0.25
761.3059082	5.94
762.4111938	1.97
766.1794434	0.37
766.9131470	0.55
769.1189575	1.98
770.2205811	0.85
773.5720825	0.12
774.8586426	0.43
786.0629272	0.20
787.2074585	14.62
788.2901001	5.00
789.1838989	0.18
798.7047729	0.15
803.0244751	0.05
806.8816528	0.06
809.5221558	0.29
811.0288696	0.70
811.9482422	0.22
820.1788940	6.61
820.8744507	2.89
821.5127563	0.12
829.1843872	1.17
829.9066162	0.62
832.5220947	0.27
834.7447510	0.08
841.0469360	0.98
850.2564697	1.66
851.3328247	0.15
852.0767212	0.11
860.3221436	0.28
869.0852661	0.42
870.4150391	0.36
877.9305420	0.23
891.2916260	0.25
893.2190552	0.20
895.1173706	5.94
896.1154785	3.53
896.7755737	0.03
898.3637695	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	620.1597
Annotation	Unknow
Peak:m/z	Relative Intensity
178.0619049	0.03
190.1164246	0.13
207.0489502	0.19
208.0701599	0.08
214.1208496	0.20
220.1445007	0.37
238.1894989	2.24
240.2928162	0.19
256.1937561	2.10
263.8569336	0.07
274.1918945	16.66
299.9963379	1.07
301.1800537	0.23
303.1504517	8.47
308.1757507	0.19
317.2177124	1.42
318.2461853	3.02
324.9540405	0.39
326.1809387	0.21
422.1787720	0.33
424.0327759	0.05
465.0169678	0.74
473.4132690	0.04
478.3862305	0.08
487.4888916	0.10
488.1486816	0.12
502.5482788	0.17
522.5011597	0.14
531.7186279	0.24
533.3344727	0.43
551.0352173	3.79
558.4039307	0.44
565.4844360	0.10
576.2504883	100.00
588.2155151	0.26
601.6414185	1.46
602.3054810	7.00
603.8490601	0.28
610.9838257	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	541.071
Annotation	Unknow
Peak:m/z	Relative Intensity
180.9217834	0.62
200.3061676	0.20
215.2499084	1.00
218.1152954	0.09
231.0447083	4.51
234.1512604	0.18
237.2940521	0.31
242.8064270	0.58
245.2150421	0.92
247.1602936	0.07
259.0804443	0.43
260.4500122	1.19
261.0719604	7.66
269.3797607	0.16
270.8590088	0.18
276.7454834	0.11
289.1047974	1.27
290.9895020	0.18
302.9030151	0.44
306.5011597	0.70
310.1982422	0.11
311.9078369	0.15
317.0302734	0.05
318.0007935	0.14
320.2800293	0.45
325.3306885	0.47
333.0956421	7.55
342.0247192	0.46
345.2725220	0.40
346.7536621	0.09
349.0568848	0.51
351.0131836	100.00
352.1027832	0.83
359.6566772	0.21
361.1383057	0.07
362.2183228	0.54
370.2796631	1.58
379.1124268	0.75
389.2030640	0.86
392.6132202	0.18
404.9885864	0.32
405.9140015	0.59
411.0662231	0.46
414.4758301	0.18
420.8859253	0.59
422.6360474	0.36
423.8633423	10.64
424.5501099	0.54
425.1680298	0.31
426.1291504	0.23
432.9070435	1.21
436.9680176	0.19
447.2109985	0.21
450.7459717	2.97
460.6908569	0.13
466.4376221	0.20
472.9124146	0.45
476.1902466	0.21
479.7926636	0.06
481.0801392	0.71
493.0083618	0.16
495.1825562	0.90
497.2801514	1.01
514.0013428	0.71
517.5402222	0.22
522.7545776	6.08
523.5969238	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2863
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
139.1268463	0.56
141.121521	1.79
155.0895691	0.55
161.2543945	3.87
162.8201599	0.70
171.1341248	1.42
197.1829376	3.55
198.3942566	3.04
214.2792511	6.21
219.1894531	0.92
227.9033203	5.50
244.3352356	1.64
245.1007385	1.04
247.1350098	1.15
252.0699768	2.70
256.3600464	0.67
259.3747864	4.78
263.9849548	4.03
265.2290955	2.90
267.2212524	0.49
281.4546509	2.39
296.4240417	0.80
297.1311951	1.85
305.0458374	2.76
308.420105	5.28
312.0812683	1.17
314.0761414	2.96
325.9419861	1.89
327.341217	0.68
339.1046143	4.49
340.329895	0.77
346.2587891	3.53
354.0177002	3.65
354.9708862	1.69
355.8370056	2.48
358.1695557	0.74
364.3703613	1.98
366.4721985	6.56
368.3340149	1.37
372.2586365	1.57
377.433197	0.61
380.0716858	5.01
381.1036072	0.98
388.6506348	1.89
389.562439	0.98
390.6669312	3.41
395.285675	2.52
397.3123474	0.91
402.7006531	1.25
404.410553	3.45
407.662262	2.73
408.2779236	100.00
409.1167297	27.34
411.049408	3.85
427.5816345	7.23
435.1302795	2.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	913.1815
Annotation	[Gallocatechin-(4alpha->8)]2-gallocatechin
Peak:m/z	Relative Intensity
257.5441895	0.03
261.1436157	1.33
263.8617554	0.05
268.1433411	0.06
269.1941833	0.41
272.8236694	0.10
275.0901489	0.06
282.0396729	0.15
283.2087708	0.23
285.1573486	0.67
293.4393616	0.31
295.2053223	0.45
297.3773804	0.10
299.3021851	0.11
303.0679321	8.98
305.1978760	8.22
312.8884277	0.04
315.2761841	0.99
317.0605469	0.21
327.4097900	0.34
335.2508850	0.07
341.1559143	0.08
341.9271240	0.23
345.1556702	0.25
347.3305359	0.22
349.2351990	0.22
353.3542480	0.43
355.3362732	0.13
357.0433960	0.09
361.1882019	0.15
362.1401062	0.18
365.1018066	0.12
367.1964722	0.38
373.3144531	0.09
379.1541748	1.36
381.2452393	0.05
383.2487793	0.11
387.3228455	0.50
391.2160645	3.06
394.6653137	0.07
395.4379883	0.10
397.2104187	1.18
403.1530151	0.86
405.0465698	0.29
409.2061768	0.42
411.2120972	2.37
413.4029541	0.17
419.4857178	0.15
421.2205811	2.66
423.2668457	19.86
425.4033203	0.23
426.1754761	0.12
429.1022339	3.70
431.2470093	0.03
433.1257935	0.23
437.0421143	0.04
439.2158813	3.39
441.1532593	9.29
441.7547607	0.03
449.1431885	0.07
451.1854858	0.49
453.3356323	0.08
463.0935669	1.59
463.9586182	0.06
465.3411255	1.53
469.1496582	0.71
471.2588501	0.12
479.2353516	0.24
481.2608643	5.72
483.2309570	12.41
484.2274170	0.10
485.2603760	0.46
493.1978760	0.14
501.5570679	0.11
505.2028809	0.03
507.4272461	0.05
510.0641479	0.06
511.2774658	0.13
513.3403931	0.18
515.3135986	0.17
520.9421997	0.18
523.1759033	0.73
525.4080200	0.29
527.5806885	0.11
531.2443237	0.09
533.2288818	1.54
541.2879028	12.06
545.3938599	0.06
547.2296753	1.15
547.8823853	0.16
549.3565674	0.06
551.2150269	0.37
557.3192139	0.27
559.2169800	36.27
563.0568237	0.42
564.2894287	0.15
565.2850952	4.06
567.1184082	0.16
569.1967163	0.08
571.4168701	0.10
575.3436890	0.59
577.0546875	7.57
581.9904785	0.44
583.2676392	0.60
587.3840942	0.15
589.2825317	2.61
591.2191162	3.25
593.1360474	0.07
599.2095337	0.17
601.1824951	3.63
601.9743042	0.17
605.2262573	0.28
607.1986694	12.27
609.2473145	26.13
619.2466431	11.82
631.4372559	0.30
633.3804321	0.08
644.1806030	0.06
647.3821411	0.05
649.2021484	0.14
651.2348022	2.23
659.2136841	0.39
661.1554565	0.67
665.1141968	0.09
675.1734009	0.07
683.2390747	0.82
695.3989258	0.09
701.2223511	1.17
709.2713013	7.45
727.2273560	100.00
733.3018799	0.26
735.3400269	0.31
743.2706299	0.41
744.6777954	8.87
745.2911987	23.27
751.1132812	0.15
756.3578491	0.25
759.0608521	0.27
760.3496094	0.16
769.1858521	1.22
770.3508911	0.14
775.3588867	0.12
785.2541504	0.38
786.6688843	1.75
787.2923584	24.10
789.1494751	0.09
802.8040161	0.10
809.0958862	0.30
810.0153198	0.45
819.1920776	0.98
828.3704224	0.47
844.4382324	0.45
845.0739136	0.27
849.5166016	0.30
851.1239624	0.33
851.7401733	0.13
856.0512085	0.13
859.3375854	0.20
869.0896606	0.91
876.2865601	0.23
895.2333374	15.11
896.5687866	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	525.1203
Annotation	4-O-Methyl-a-D-glucosyl-(1->2)-b-D-xylosyl-(1->4)-D-xylose
Peak:m/z	Relative Intensity
164.1423340	2.03
182.2652893	0.35
190.9635773	0.18
192.0524445	0.13
227.3103790	0.22
244.8369141	0.65
264.0532837	0.44
271.3088989	1.09
271.9525146	1.39
273.0641479	5.04
293.0212402	0.57
326.3602905	0.56
327.5543823	0.32
328.2292480	0.39
354.0720825	28.11
363.1028442	100.00
364.2642212	2.36
420.5900879	0.36
425.0077515	1.09
464.4143066	0.56
484.9657593	0.52
495.1351929	0.25
506.4651489	0.70
507.0917358	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.2234
Annotation	Javanicoside C
Peak:m/z	Relative Intensity
196.2657166	0.19
200.9203186	0.08
203.1172791	0.14
211.1934814	0.48
221.3034973	0.12
226.0589905	0.06
246.8051910	0.09
249.4348907	0.12
260.9670105	0.08
274.1016235	0.21
287.1467590	0.19
303.2371826	0.25
305.1679688	10.04
341.9323730	0.19
345.2763062	0.08
358.0628052	0.10
373.2033691	100.00
374.3165283	0.24
385.3728638	0.40
391.1867676	0.09
398.1340942	0.09
417.8901978	0.08
423.1195068	1.49
435.1303711	0.04
439.1791992	0.04
441.3229980	0.51
453.3562622	0.05
487.4085083	0.09
492.1937256	1.03
493.0070190	0.41
498.0976562	0.07
499.4365845	0.13
503.4000244	0.15
510.4233398	0.56
539.4546509	0.08
546.1098022	0.04
550.5060425	0.07
564.2037964	0.06
590.5214844	0.25
592.5906982	0.42
599.1890259	0.61
600.4190063	0.10
607.2955322	0.49
608.6542358	0.27
609.4995728	0.24
610.3347168	0.23
615.2406616	0.13
616.5774536	0.03
624.6572876	0.33
632.3627319	0.13
633.2495117	0.63
635.3780518	0.25
648.8973389	0.05
659.4747925	0.36
660.9020996	0.61
661.7282104	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	404.154
Annotation	Perphenazine
Peak:m/z	Relative Intensity
123.9742126	0.32
127.9292297	0.40
129.1828461	0.09
129.9780426	0.16
142.7633362	0.23
144.0366669	0.12
145.9848938	0.32
160.0389252	0.39
160.6875000	0.47
163.0309448	3.05
164.1246643	0.21
174.7403870	0.61
175.9456329	0.26
177.0738678	0.21
179.9534912	1.41
189.1336060	0.22
189.7676392	0.11
200.0982361	0.08
206.9012756	22.27
207.5030823	0.09
210.7572937	0.25
216.2993011	0.06
223.1020050	0.48
225.0403137	100.00
232.0736084	0.27
236.2742310	0.20
239.0406799	0.05
241.3957214	1.12
242.0375061	6.68
242.6772461	0.09
245.3234558	0.05
246.8941345	0.13
257.2064819	0.26
269.3018799	0.10
270.1170959	0.22
272.2210693	0.17
273.9677124	0.26
279.2450867	0.20
286.1348877	0.17
287.5026245	0.11
290.6821289	0.27
291.8651733	0.29
296.4138489	0.15
300.6579590	0.32
307.1468506	0.13
309.5643005	0.32
311.2842102	0.39
327.4181213	0.17
329.0541992	0.73
331.7328491	0.19
332.4385986	0.18
338.3323975	0.94
341.0537720	1.36
344.1005859	0.15
348.4812927	0.09
351.2812805	0.24
354.3662720	0.17
355.2875671	0.15
358.1357727	0.73
359.4324646	0.08
363.0322266	0.26
368.6676941	9.66
369.3617249	0.45
375.0253601	0.27
375.6989136	0.14
376.3710022	0.07
383.1066589	1.15
385.0947876	2.19
386.4449158	20.87
387.4001770	0.52
392.6148682	0.72
397.3719788	0.27
405.1491089	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	643.1729
Annotation	Unknow
Peak:m/z	Relative Intensity
216.9647064	1.47
259.0050354	0.05
262.0592651	0.17
282.3519897	0.13
293.8845520	0.22
300.1386719	0.49
300.9503174	0.02
303.1207581	11.31
307.1604309	0.08
321.1053467	9.31
339.1791382	0.05
340.3106079	0.09
353.0629883	0.10
360.1002808	0.04
360.9490356	0.03
381.2042236	0.31
393.5175171	0.17
395.3689575	0.25
418.9749756	0.09
419.6149902	0.09
433.2453613	0.22
437.2178955	2.09
440.9949951	0.05
461.1312866	0.03
463.1788940	0.20
467.3097534	0.08
469.2005005	0.03
471.4119263	0.05
479.2589111	22.28
484.9971313	0.29
493.1311035	0.29
495.5270996	0.35
497.2368774	9.13
504.9356689	0.04
506.0761719	0.27
510.1734619	0.46
539.2771606	31.45
542.1265259	0.34
544.5651245	0.32
545.4749756	0.22
580.2186279	0.27
581.0795288	0.91
596.9950562	0.06
601.2678833	0.03
606.4862671	0.10
607.3054810	0.49
625.2298584	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	504.3098
Annotation	PE(20:2(11Z,14Z)/0:0)
Peak:m/z	Relative Intensity
152.8920441	0.03
167.6739960	0.06
179.0023193	0.33
204.8715057	0.06
224.2279816	1.59
242.1674805	2.19
243.1730042	0.14
244.0722504	0.16
250.1378021	0.26
251.8161011	0.18
252.9761353	0.16
261.1856384	0.24
268.5202026	0.18
270.7071838	0.06
272.2369080	0.11
279.2800293	100.00
299.9736023	0.56
301.0974121	1.13
307.1354675	0.30
354.6870728	0.19
391.1710815	0.23
398.6040039	0.13
414.3037415	0.16
415.4985352	0.12
427.6855774	0.17
430.4874878	0.36
432.2971802	0.12
437.3425903	0.07
442.3163147	0.16
445.3534241	0.09
447.3735657	0.22
450.1522827	0.57
458.3613586	0.33
460.0905457	0.38
462.1933899	0.21
463.3419495	1.08
464.6741638	0.24
466.1260681	0.58
468.2165222	3.84
469.2461548	0.37
473.5718689	0.19
475.1004944	0.06
485.7863464	0.48
486.6699829	0.31
487.5665894	0.33
488.2727661	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	521.3262
Annotation	PIM1(19:0/18:1(9Z))
Peak:m/z	Relative Intensity
174.7705841	0.19
177.2695007	0.09
184.0129395	0.16
185.3325195	0.06
195.1021423	0.32
207.3401337	0.32
208.9956970	1.43
221.1483917	0.42
222.2241669	0.24
223.2111206	0.32
224.1751404	0.25
225.2304688	0.38
229.8560181	0.10
237.1072388	0.13
239.1624146	0.05
251.4304047	0.92
252.3036499	0.11
256.0592957	0.15
269.1689453	0.24
273.7160950	1.69
279.1792297	0.28
295.6679688	0.83
297.6434631	0.19
309.1658325	0.05
311.2177124	0.27
313.0393677	0.19
317.4360962	0.71
320.4282837	0.40
327.2742310	0.16
329.0581055	0.08
335.5581055	0.07
340.3253784	0.38
341.5462646	0.17
348.2888794	0.37
349.8359985	0.14
357.3175049	0.18
358.1373291	0.14
362.0007324	0.38
363.6519165	0.47
371.9589844	0.73
373.2901001	0.17
374.3237305	0.40
375.1256714	0.10
376.1737671	0.23
377.6062012	0.14
393.8084717	0.19
400.1062622	0.38
401.3609619	0.38
408.7456665	4.46
409.4384766	3.27
415.6397095	1.24
416.2938843	0.58
417.9912720	0.32
421.6919556	1.51
422.4624634	0.15
423.2473755	0.09
427.3316040	0.22
434.9542236	0.24
451.7495117	0.42
452.6622314	0.24
456.6830444	0.16
460.2831421	9.07
460.9149170	100.00
461.8572998	3.24
462.9024658	2.35
463.6411133	0.65
464.9796143	0.34
466.2557373	0.29
468.8438110	0.92
470.2871704	0.32
476.5404053	0.19
483.0962524	0.09
503.4636841	2.12
504.2539062	0.51
505.7266846	0.20
512.7411499	8.50
513.7981567	0.91
516.4572144	0.15
525.8204956	0.26
532.7594604	0.15
547.2974243	0.29
549.1138916	0.33
564.4390869	1.20
565.5689697	0.62
574.5001831	0.15
578.2214966	0.16
584.4800415	0.24
593.2388916	0.08
608.3339844	0.59
609.5339355	0.62
635.0712280	0.06
637.3075562	0.35
638.3001099	0.64
652.6779175	0.48
673.3458862	0.19
681.8984985	0.13
683.8988647	0.24
696.5214233	0.30
700.6201782	0.13
745.3495483	0.06
788.4140625	0.07
799.4695435	0.37
804.4656372	0.60
805.6070557	0.23
816.4802246	8.49
817.3560181	2.50
848.3975220	0.33
876.2788696	0.18
892.2831421	0.26
893.5876465	0.17
903.0493774	0.31
904.1604614	0.12
920.4718628	94.44
921.4869995	38.72
922.4954224	0.25
937.6527710	0.49
1024.7634280	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	366.192
Annotation	Isariotin D
Peak:m/z	Relative Intensity
107.0053558	2.33
107.8241425	0.04
111.8761292	0.15
112.9878082	0.04
114.2153397	0.06
119.0894165	0.05
124.9472809	6.35
125.9987869	0.23
130.0494843	0.28
132.9538574	2.37
134.1184387	0.07
135.0434875	0.98
136.0525208	0.06
144.9010468	0.04
145.9467468	0.84
147.0261536	0.22
148.3279724	0.29
149.0003967	0.45
155.0624695	0.04
156.3099518	0.05
159.0976257	0.09
159.8809509	0.05
161.0865173	0.21
161.9085999	0.04
167.0365295	0.07
171.2885590	0.07
173.0574646	0.33
174.1014099	0.52
175.3080444	0.04
178.2620239	0.23
180.1085358	0.28
181.9742737	0.14
186.1856995	0.40
187.1246948	0.34
189.2826080	0.09
190.1919861	0.38
191.2657776	0.05
192.2009125	0.44
196.1876068	0.21
197.2707825	0.30
198.1115875	0.03
199.1436768	0.07
201.1458435	3.11
202.3088989	0.67
204.1585083	1.17
205.2971191	0.13
212.2482300	0.11
213.2249756	0.27
215.2190399	4.55
216.3954163	0.10
220.1327515	1.15
221.0090332	0.17
222.1715393	0.13
225.1838684	0.72
229.3192444	0.24
231.1625671	7.13
233.1395874	100.00
234.2207642	1.04
235.1776733	0.12
241.0757446	0.30
242.0581665	0.20
243.0932617	1.30
245.1165466	0.12
246.2611084	0.84
247.1072083	0.69
255.2223816	0.15
257.1491699	0.35
258.1452332	1.77
259.1694946	0.06
260.7472534	0.59
262.1679077	1.73
263.2476501	1.66
264.3576660	1.38
265.3733215	0.07
266.1160278	0.12
270.1449890	0.59
271.2107544	0.06
272.2593689	1.44
273.4825745	0.50
274.2067871	1.48
275.7478027	0.21
276.3831177	0.38
277.2102051	0.18
278.4270020	0.08
280.0695496	0.18
282.1947632	5.19
284.0689392	1.73
286.3179932	0.96
288.3051758	0.88
290.3148804	0.39
291.1523743	0.07
292.1811829	1.81
294.2384338	4.83
298.1808472	12.55
300.2872925	5.18
308.2619324	0.40
310.2369995	10.30
312.3226624	4.55
316.2894287	9.88
318.2370911	0.35
320.1512146	0.10
320.9566345	0.04
328.3029785	9.28
330.1409912	1.32
333.3192139	0.09
334.2432556	0.13
336.1668396	0.17
346.0798950	0.12
348.2543030	14.18
349.3797302	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.92
Annotation	Unknow
Peak:m/z	Relative Intensity
155.6268005	0.01
158.9685669	3.37
159.9558411	0.29
199.0027618	0.23
199.9820557	0.12
217.2114868	0.01
229.0708618	0.85
230.0441132	0.22
272.9979248	53.06
273.9732666	12.72
385.1931152	0.11
386.9573669	100.00
388.0031128	39.11
399.2957764	0.02
411.1097107	0.03
412.0777893	0.03
415.3976746	0.03
428.1567993	0.05
455.1418152	0.09
456.2608032	0.10
456.9023743	0.05
457.6392517	0.02
458.8731995	0.03
482.9974060	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	514.2634
Annotation	DAMGO
Peak:m/z	Relative Intensity
179.0237427	0.10
180.0718536	0.02
193.1800385	0.02
200.3829651	0.01
205.3498993	0.02
207.2305756	0.08
229.1696472	0.21
233.2068176	0.04
242.1831665	0.02
246.7807465	0.04
274.0147705	0.04
280.3793335	0.04
282.0028076	0.02
288.3805542	0.02
290.7753296	0.04
298.0639038	0.14
308.2865601	0.02
311.2918701	0.02
315.0834961	0.03
316.2789307	0.09
328.1288452	0.04
334.3291016	1.95
335.4487915	0.06
344.1954346	0.01
345.7703247	0.16
349.5433350	0.05
352.2963257	100.00
367.6190186	0.14
368.2894897	0.24
369.4625244	0.02
385.1580811	0.95
391.0729370	0.02
410.6517944	0.02
422.2415771	0.03
424.1177979	0.01
426.3607788	0.03
427.4418945	0.01
433.3257446	0.02
439.3480835	0.25
440.2661133	0.12
442.1830444	0.02
454.1455078	0.11
454.7606812	0.01
460.3968506	0.02
467.0811768	0.03
469.0632935	0.04
470.1083984	0.06
472.9205933	0.03
478.2111816	0.03
484.2933350	0.04
489.4218140	0.04
496.1919556	0.70
497.0937500	0.15
506.4817505	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.12
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
160.9988098	0.22
171.9781952	0.07
172.9789276	1.35
178.9946442	0.95
191.0431519	19.16
193.3798218	0.02
203.0484924	0.03
207.3134155	0.08
216.3047333	0.05
229.4195862	0.04
231.9014740	0.10
247.3762360	0.11
275.0717163	0.11
291.1015320	0.12
307.0477600	0.09
309.1828308	1.95
318.9846191	0.04
335.1753540	4.46
335.9997559	0.06
337.0961304	1.72
344.9188843	0.06
353.0249023	17.29
362.9962158	0.29
367.2803345	0.16
381.0460815	15.20
381.6823120	0.09
386.4304199	0.03
387.1499023	0.05
399.2006836	100.00
418.1147461	0.08
426.2533569	0.06
429.1316528	0.19
431.2742310	0.05
482.3535767	0.06
498.4531860	0.03
499.5880127	0.23
500.3981323	0.59
515.2053833	0.13
542.9273071	4.67
543.6045532	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.08
Annotation	Didymocalyxin C
Peak:m/z	Relative Intensity
118.9431610	0.04
127.2538986	0.09
144.2076874	0.03
144.9117889	0.06
162.0825500	0.03
178.9884949	1.02
179.9984894	0.06
197.1212463	0.11
199.0205994	0.61
215.0979767	1.55
216.2007904	2.74
217.0936279	11.59
221.1060181	0.05
281.2247620	0.06
311.0257568	0.02
319.1899719	0.19
341.1640930	100.00
342.1138916	35.97
343.1746521	8.97
343.8442078	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	586.9052
Annotation	Unknow
Peak:m/z	Relative Intensity
273.0338135	0.90
357.3515015	0.33
359.1719360	0.34
360.1743774	0.16
387.1468506	0.17
388.1817627	0.25
427.0750732	2.86
428.1173706	2.15
429.1281738	0.12
472.1834717	0.46
473.0180664	3.09
474.0731201	1.61
484.8766479	0.30
486.1075439	0.09
504.0861206	0.56
515.0057983	0.06
516.1650391	0.06
529.0185547	0.55
531.9259644	0.25
540.8787231	100.00
541.9275513	61.06
543.1701660	0.84
544.1133423	0.27
546.9807739	0.06
558.3265381	0.13
560.1301880	0.03
568.9053345	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	918.4288
Annotation	Unknow
Peak:m/z	Relative Intensity
271.4456787	0.44
276.2409668	0.40
292.2792664	0.21
310.3949280	1.30
318.4983826	0.16
328.3079834	4.32
346.3350830	3.93
364.4044189	1.35
380.1738892	0.09
388.4390869	1.18
404.2974854	0.50
406.4107666	100.00
418.0202637	0.11
438.4588013	0.19
440.3014526	0.21
448.5993652	0.32
454.1790161	0.19
456.4505005	0.31
478.4683838	0.17
498.6473389	0.26
516.3821411	3.56
532.4866943	0.24
534.3368530	1.13
536.3870239	1.03
552.4469604	15.84
568.4488525	0.27
600.7280884	0.33
610.5785522	0.56
636.1168823	0.15
672.2325439	0.20
678.1920776	0.30
678.8204346	0.09
696.7245483	0.40
714.1338501	1.65
740.6273804	0.12
755.3165894	0.38
756.1511230	0.26
772.5248413	1.59
773.4095459	0.09
776.3705444	0.42
789.7266846	0.05
794.2140503	1.04
882.5419312	0.26
888.4013062	1.22
899.7185669	0.10
900.5471802	0.75
904.4686890	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.1608
Annotation	3-Methyl-3-butenyl apiosyl-(1->6)-glucoside
Peak:m/z	Relative Intensity
113.0198212	8.91
115.0091553	0.45
118.9394684	5.02
124.9803467	4.99
130.9455109	25.09
142.9840393	10.75
146.3641205	0.26
148.9089050	100.00
160.8598328	8.22
167.0922852	0.44
172.9779358	0.14
178.9675751	17.04
190.9763794	28.76
196.1781311	0.28
196.9868469	0.17
198.2286987	4.43
205.9683533	0.24
207.0097809	0.44
212.7743988	0.12
216.3418121	0.20
216.9423065	0.92
219.0465393	0.39
220.4581604	4.64
221.0655823	11.55
233.0580139	2.06
247.0446167	38.94
249.9798584	1.37
251.1239014	14.05
263.2417908	0.16
273.2937622	0.27
275.1026611	4.27
277.2051392	0.47
281.0420532	0.77
283.2018127	0.40
287.4755859	0.21
289.5321350	0.58
291.1457214	0.83
293.0956726	16.48
311.0185242	5.39
331.9830322	0.38
333.1080017	1.71
335.4577637	1.52
336.2601929	0.67
341.2240601	0.63
360.2130127	1.39
361.3524170	1.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	392.24
Annotation	Purpuride
Peak:m/z	Relative Intensity
109.9685364	0.08
125.2722778	0.22
144.5487061	0.06
149.0818787	2.30
150.0225372	1.45
150.8829498	0.19
152.8999481	0.12
161.2826080	0.09
163.0119934	0.07
166.9602356	1.67
167.9463806	0.07
181.0636597	0.08
185.1784973	0.21
198.6041260	0.11
199.4285583	0.08
229.0448914	0.04
233.1447144	0.31
235.3591003	0.21
237.2841492	0.07
251.3637695	0.11
253.8443604	0.10
255.8349609	0.25
256.9199219	0.11
258.1631470	0.05
259.6241760	1.33
260.6549072	0.41
261.5035706	0.06
262.3807068	0.10
271.2580872	1.18
277.0546875	0.21
278.8411560	1.76
280.0136108	2.00
282.2234802	0.05
283.4674988	0.21
285.6283569	0.11
300.2519531	0.06
303.0543823	0.24
304.1656494	0.10
311.6033325	0.27
324.1265259	0.07
325.4604492	0.18
329.2940063	0.16
330.2823792	0.22
332.2358704	0.30
337.6282959	0.03
342.3323975	1.60
343.3588867	3.38
346.3324280	0.16
350.3988037	0.37
351.3328857	0.11
357.2462158	0.08
360.1888123	0.38
361.3237610	0.83
375.1672058	100.00
383.4178772	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	348.07
Annotation	Adenosine monophosphate
Peak:m/z	Relative Intensity
118.8019791	9.67
136.0587921	100.00
147.1583405	0.44
180.7527466	0.40
184.3428192	0.46
186.0973358	1.19
198.4036255	0.45
228.0045166	0.90
229.9684753	0.74
232.0041199	3.07
243.3577271	1.24
246.0188599	0.22
257.4141235	0.48
258.0419617	1.07
275.8926392	1.80
281.1865234	2.95
284.9434814	0.38
289.0395813	0.44
302.3227844	1.19
304.1376953	1.51
306.9943237	1.65
312.1392822	1.16
312.786499	2.28
315.0141296	0.47
318.1581116	1.26
319.2506714	0.51
320.0298767	1.52
321.4053345	0.30
330.109436	2.22
331.3898926	1.26
338.840271	2.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.0938
Annotation	5,4'-Dihydroxy-3,3'-dimethoxy-6,7-methylenedioxyflavone 4'-glucuronide
Peak:m/z	Relative Intensity
154.9902802	0.03
172.6423187	0.07
173.2600708	0.02
179.0550385	0.49
191.0658722	4.10
203.1246338	0.05
209.1266327	15.32
241.1799011	0.04
247.2403717	0.06
254.2850189	0.03
270.8571777	0.04
280.1877136	0.16
291.1851196	0.09
309.1443481	0.66
334.9661865	0.31
353.1542358	9.05
355.0840454	0.02
367.1146240	0.14
369.2153931	0.07
371.1436768	100.00
387.2179565	0.90
388.4191895	0.06
401.2349854	0.27
411.5463257	0.02
439.3605957	0.05
442.2613525	0.05
469.4425659	0.12
470.3234863	0.15
486.3657837	0.03
487.4472046	0.29
488.9374390	0.05
496.5230103	0.18
514.9313965	2.16
515.5935669	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
124.9451294	4.22
147.1369171	1.83
153.1528168	2.66
195.9459686	4.32
198.8997955	1.41
203.106369	8.47
209.108429	1.51
239.315033	11.02
253.4526367	3.26
262.2176514	0.98
270.158844	5.42
281.3688965	23.19
290.5310059	4.96
295.0612183	2.04
300.4146423	1.21
302.2642517	7.82
309.2025146	0.98
309.9016113	4.91
315.2803955	1.51
322.2203979	2.64
327.3700867	5.74
328.3150024	12.27
329.3743286	1.40
332.0071106	1.46
336.0922546	8.47
339.8371582	1.57
348.9328003	2.11
353.5615234	13.32
357.3432922	2.32
358.5596619	2.30
364.3853455	6.87
367.2961121	3.68
368.3607178	4.23
369.901886	1.21
380.4467468	4.72
381.4985046	9.19
387.1891174	3.50
390.2095642	21.21
391.2903748	6.86
397.8231812	7.84
400.2705383	4.77
403.5741272	3.64
407.6238098	15.24
408.2790222	100.00
409.5115662	16.21
410.1911011	6.30
411.1541443	10.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	415.1244
Annotation	O-Acetylgeniposidic acid
Peak:m/z	Relative Intensity
131.1918945	0.26
133.0325165	0.26
134.7917938	0.04
149.2433167	0.10
158.7786407	0.18
160.8852844	0.19
164.9355469	0.06
190.8616486	0.30
198.1747131	0.43
199.0477295	0.28
201.2183380	0.09
204.1603394	0.11
207.1242676	100.00
221.2369080	0.50
232.9080811	0.09
235.1698608	0.07
241.0472107	0.04
245.9413757	0.10
247.3948975	0.05
248.9895935	1.12
253.0309448	0.86
271.1753540	0.05
275.2015076	0.17
277.3485718	0.09
278.8428040	0.45
281.0671997	0.08
285.4374695	0.04
286.1969910	0.07
287.0779419	0.18
291.2362671	0.16
293.4603882	0.68
294.3875732	0.87
295.1004639	0.46
296.9435425	0.09
308.7263489	0.14
323.3946533	0.62
324.2523193	1.27
325.1577454	0.48
340.9717712	0.09
342.4069519	0.04
351.2343445	0.17
355.3135376	0.19
356.1158142	0.14
368.2841492	5.25
369.0009155	57.87
371.9730835	0.17
382.7764893	0.05
383.5708618	0.07
385.8780212	0.06
396.2699280	0.38
397.2908325	0.62
416.2092896	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	616.9
Annotation	Unknow
Peak:m/z	Relative Intensity
198.9859619	0.05
201.0622559	0.03
229.2671661	0.16
273.0674438	7.11
274.0119934	2.44
275.1149292	2.93
387.0119019	12.33
388.0643311	11.63
389.0023804	11.15
428.4243774	0.04
458.8796997	0.03
500.9343262	34.18
501.9264526	56.49
502.9058838	100.00
503.5304565	0.31
511.8793335	0.03
514.8652954	0.08
528.8748779	0.03
530.8273926	0.02
560.1369629	0.03
570.2393799	0.25
571.0618286	0.08
573.0963745	0.37
583.7762451	0.05
589.1401978	0.12
589.7504272	0.19
598.8922119	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	711.2439
Annotation	Boehmenan
Peak:m/z	Relative Intensity
261.2224731	0.06
279.1254883	0.02
280.1054688	0.46
309.1745605	0.21
339.2983093	0.03
343.1006470	0.21
368.0759888	0.05
371.3812866	0.03
379.6754150	0.02
413.0537720	0.07
449.5535889	0.08
450.4861450	0.02
456.4166870	0.07
465.1046753	0.05
473.3350830	0.18
485.2231445	0.05
502.3694458	0.77
503.3128052	3.27
504.2778931	0.22
504.8823242	0.04
511.3120117	0.05
517.2994385	100.00
518.3196411	40.46
528.2131958	0.07
533.1723633	0.31
535.4119263	0.36
536.4271851	0.06
579.1150513	0.10
586.3108521	0.04
607.7031860	0.06
624.0290527	0.02
665.4609375	0.05
667.4113159	0.27
668.1896362	0.27
676.1150513	0.03
683.1340942	0.11
684.0821533	0.04
685.8153687	0.08
692.2877808	0.12
693.4996338	0.19
694.3540649	0.07
699.6293945	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.84
Annotation	Unknow
Peak:m/z	Relative Intensity
128.8962402	6.83
198.9477234	0.17
212.7931824	3.16
222.2317505	0.17
260.9866943	0.22
268.2251282	0.92
270.1449585	3.40
271.3970642	0.95
291.1976624	0.62
296.7572021	100.00
297.4766541	2.68
349.9092102	0.10
350.5092468	0.39
360.8843384	0.35
362.8610229	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	688.52
Annotation	Unknow
Peak:m/z	Relative Intensity
227.3097229	0.12
247.3305359	0.11
249.0045624	0.21
251.1231995	0.14
253.3979645	0.12
256.5391846	0.03
257.1809692	0.28
263.2332153	0.24
264.1847839	0.07
265.0421753	0.16
269.1221313	0.09
301.2102661	0.37
309.5029907	0.07
313.1332397	0.26
315.5516968	0.15
327.3404846	0.09
329.2418823	0.71
344.9834290	0.19
353.1514893	0.41
355.1738892	0.44
357.3105469	0.16
358.5067139	0.06
359.3140259	0.11
363.1730957	0.05
373.2253418	0.90
375.0813599	0.09
388.7926636	0.12
395.0151978	0.10
397.3183594	0.33
407.1607056	0.04
415.5464478	0.22
425.7610474	0.14
431.4562988	0.04
433.1724854	0.19
445.3432007	0.17
463.2235718	5.57
463.8385010	0.02
472.4229736	0.03
477.3452148	1.09
479.2521973	0.29
484.9548950	0.04
488.9912720	0.12
495.4085693	0.13
497.8809814	0.12
503.0903931	1.02
503.7764282	0.09
504.9397583	0.07
513.5250244	0.10
520.3124390	0.14
521.1598511	0.56
523.1251831	0.44
523.8283691	0.12
529.0136108	0.03
538.2628784	0.06
539.2314453	0.06
549.0573120	0.03
565.0626221	0.16
565.7008057	0.14
567.3020630	66.10
573.0685425	0.08
583.2825317	0.57
596.8021851	0.06
607.2807617	0.14
609.4098511	0.05
617.6078491	0.10
627.3747559	0.43
628.0422974	0.26
629.5996704	0.06
638.5804443	0.19
639.3751831	0.13
642.3975220	0.16
653.4285278	0.53
657.2410278	0.05
668.1985474	0.11
671.2009888	100.00
672.0563354	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	407.0654
Annotation	Unknow
Peak:m/z	Relative Intensity
162.8658142	0.02
165.1183777	0.13
166.9794312	0.29
179.2082520	0.04
180.9834290	0.04
191.1559296	0.05
195.1483765	0.05
199.2614746	0.08
203.3423767	0.06
213.0761108	0.07
221.1969757	0.06
225.9884949	0.07
227.2429810	0.12
228.3140259	0.04
235.2683411	0.04
237.8336792	0.06
241.0243530	100.00
242.4984436	0.06
243.2712708	0.05
245.0516052	0.18
254.0524597	0.07
260.4513245	0.06
269.0511475	0.02
273.1362610	0.02
275.0867920	0.08
276.2520752	0.15
277.3382263	0.14
281.1643677	0.02
285.3389893	0.06
286.2427979	0.06
287.0856018	0.05
288.1191101	0.09
307.1568604	0.08
308.3176270	0.15
309.3117065	0.05
311.0139465	0.03
316.2440796	0.18
319.1901855	0.06
320.8047791	0.08
325.0776672	0.06
327.0772705	0.22
329.1265869	0.02
341.2631226	0.02
345.2710571	0.04
352.0300293	0.05
352.6871338	0.02
360.0191345	0.02
361.3695374	0.38
362.1878357	0.04
363.3597412	0.10
370.0047302	0.03
371.1061401	0.16
377.1420593	0.03
379.4286804	0.06
383.8609619	0.10
386.3302917	0.05
388.1774597	0.11
389.2428284	0.42
389.9694519	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	297.24
Annotation	cis-9,10-Epoxystearic acid
Peak:m/z	Relative Intensity
111.1425323	0.06
119.211586	0.13
141.2232361	0.55
142.2674561	0.39
147.9544678	0.08
156.1936646	0.21
170.044754	2.83
171.0966492	0.28
183.0083008	100.00
183.9874878	10.62
184.8497772	0.11
195.0052643	0.17
197.0945587	4.57
198.0997925	0.88
199.0430908	0.14
211.3964539	0.90
212.1846008	2.01
213.3843994	0.06
221.32724	0.03
225.1636353	1.70
226.1573181	3.34
227.0736389	0.37
233.3026733	4.26
234.1896667	0.42
235.9888611	0.08
239.3287048	1.15
240.1141052	2.27
241.1942139	0.82
249.5651245	0.04
250.3667603	0.45
251.2996216	0.16
253.2357178	4.53
254.015564	0.18
255.4464111	0.09
260.8885498	0.04
261.9099731	0.07
265.2339478	0.10
269.4500732	0.16
279.4024048	2.48
281.0316162	0.16
297.2169189	8.56
298.2519531	1.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.04
Annotation	Unknow
Peak:m/z	Relative Intensity
151.1687317	0.18
155.9522095	0.20
157.9512634	0.03
175.1062927	100.00
175.8765259	0.03
206.0699768	0.03
212.9094849	10.69
223.1981506	0.08
225.0617676	0.14
227.0718994	0.84
228.6337585	0.06
240.2487793	0.04
264.5005188	0.03
265.1876831	0.22
268.8435364	0.03
270.1582642	0.05
292.3712158	0.41
293.1265869	1.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.093
Annotation	5-(3',4',5'-Trihydroxyphenyl)-gamma-valerolactone-4'-O-glucuronide
Peak:m/z	Relative Intensity
128.9277191	15.02
129.9421539	0.66
159.1062775	0.19
161.0714264	1.69
162.0737457	0.11
172.6972504	0.02
176.3478699	0.05
177.8560028	0.16
187.0198364	3.28
188.1096191	0.73
189.4488525	0.15
191.1152649	0.08
193.0650177	0.87
193.9773560	0.46
204.9922333	100.00
206.0116577	13.13
217.4596558	0.06
219.2566833	0.05
223.0753479	61.35
224.0735321	9.94
224.6856842	0.10
233.3309937	0.30
261.2367249	0.08
262.1190186	0.38
270.2852783	0.17
273.2253418	0.02
278.2894592	0.15
294.1208801	0.30
305.8408813	0.12
311.8577881	0.05
319.4665222	0.10
320.4315491	0.05
322.3727722	0.13
323.0911560	0.09
337.1765747	0.27
340.4644470	0.33
341.3428345	0.43
349.0405273	0.11
353.3078613	0.50
354.3309326	0.28
355.2004395	0.38
355.9467163	0.06
357.2635498	0.16
358.3022766	0.15
363.1075134	0.05
364.1027527	0.21
365.2404480	0.09
370.4207458	0.10
371.8119202	0.12
378.3416443	0.13
379.3674011	0.23
381.0308533	5.06
382.1692505	1.86
384.9353333	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.088
Annotation	3-O-beta-D-Galactopyranuronosyl-D-galactose
Peak:m/z	Relative Intensity
103.0132523	0.49
110.7658234	0.11
112.9625854	5.41
125.0846634	0.21
128.9210968	1.62
130.9606018	19.90
145.0453186	3.42
146.7906189	0.22
156.8574219	5.84
162.8818054	0.28
170.8970337	5.39
174.9494781	100.00
193.0702209	1.22
207.0312500	0.19
219.0290833	6.63
222.9341736	0.77
235.0517273	0.91
249.2014771	0.39
257.0010681	0.15
265.0807800	2.94
281.1419678	0.29
295.1204224	4.37
310.3498535	0.11
318.9165039	0.43
325.1159668	0.51
335.8312073	0.19
336.9805908	4.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	382.2578
Annotation	Unknow
Peak:m/z	Relative Intensity
115.9714661	0.60
119.0248566	0.06
127.0125885	0.05
129.6133728	0.11
132.3003082	0.03
133.1640015	0.09
141.5168762	0.10
142.7610779	0.03
149.3917236	0.02
160.2337952	0.07
160.8421021	0.03
182.2634888	0.02
183.3359070	0.02
184.8985748	0.05
188.1788635	0.04
190.1049500	0.05
198.9337463	0.07
203.1641083	0.08
206.1274719	0.33
208.3607941	0.05
210.0029755	0.05
218.8693848	0.03
220.9535828	0.03
224.2910767	0.27
226.2216492	0.14
227.2209778	0.03
237.1264954	0.07
242.1293945	0.32
244.2177429	0.05
246.2717590	0.27
249.0299072	0.12
255.2399902	0.11
257.3346252	0.03
260.2452087	0.73
261.4346619	0.03
264.2821045	0.10
272.3136597	0.08
272.9785156	0.17
276.3847961	0.06
278.4250488	0.08
282.2865295	0.03
283.9775085	0.19
285.2416992	0.06
286.2335510	0.92
287.3475342	0.02
288.5863647	0.01
292.2537842	1.51
298.1951599	0.03
300.3605347	0.35
304.3307495	3.44
308.6010132	0.10
310.3390808	10.75
312.3333130	0.06
315.3898926	0.04
316.3580322	0.10
320.7943420	0.10
322.6870117	0.03
326.1262207	0.05
328.2636719	16.20
328.8703613	0.22
332.8671265	0.12
336.1734009	0.03
337.0454407	0.05
338.1093750	0.58
339.2751465	0.05
346.2976074	20.98
346.9358826	0.19
350.1227112	0.02
354.0568542	0.16
356.2752991	0.04
360.7148438	0.11
364.2962341	100.00
365.3183594	0.04
368.1105957	0.04
373.1654663	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	487.0393
Annotation	Unknow
Peak:m/z	Relative Intensity
152.9140015	0.04
156.8196869	0.02
158.9772034	5.28
189.8865356	0.05
198.9387512	0.94
216.9636841	0.35
228.4236145	0.16
229.0501404	1.53
271.0338745	0.11
272.9660645	100.00
277.3374634	0.07
306.2091675	0.06
306.9522095	0.06
323.1063232	0.09
323.9032288	0.06
325.2897339	0.03
333.3512268	0.28
340.4208374	0.07
341.3044434	0.09
348.2776794	0.13
353.5332031	0.05
357.9956970	0.23
358.9922485	0.26
370.3020630	0.02
371.3262634	0.02
373.0779419	4.45
377.0755615	0.02
378.9991150	0.05
395.2652893	0.11
398.9011536	0.08
409.2545471	0.06
412.8181458	0.32
418.9606628	0.16
421.2080994	0.03
425.3581848	0.04
431.1641541	0.04
431.9591980	0.02
440.1836243	0.69
441.1012268	0.69
442.9526367	0.46
451.2369690	0.06
453.5459290	0.06
458.9767456	0.33
459.8026733	0.21
461.0739441	0.11
468.1907349	0.11
469.1089783	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1247
Annotation	Cyanidin 3-(6''-caffeylglucoside)
Peak:m/z	Relative Intensity
175.0219116	0.01
177.0109100	1.34
178.9335022	0.05
187.0517731	0.08
189.4096069	0.02
200.9514008	0.19
203.0952148	0.05
219.1837769	0.85
221.1239929	0.34
228.2419891	0.03
229.1372528	0.34
233.2138214	0.11
237.1818848	0.22
241.0621338	0.11
242.4785156	0.07
243.1929474	0.19
247.1147614	0.06
255.0543518	0.31
259.2459106	0.21
261.1448975	1.64
263.1805115	0.06
271.1080017	0.06
273.0240784	4.96
275.1035767	0.03
285.1727295	0.57
287.2028809	0.25
294.1718750	0.05
301.2916260	0.03
302.6165771	0.41
303.2507324	4.50
305.1127319	28.30
306.2185669	0.16
307.1859131	0.10
309.1478271	0.07
315.2374268	2.06
317.1378174	0.04
323.9562378	0.05
327.1196289	0.10
329.2872925	0.06
339.0178833	0.04
343.3516846	0.11
344.0812378	0.07
344.9520874	0.19
345.5873413	0.09
347.1189575	0.28
347.8743896	0.08
355.3870850	0.14
357.0205688	0.40
359.4464722	0.07
363.0784912	0.07
373.2396851	0.11
374.4527588	0.05
379.2838745	0.13
389.0883179	0.12
395.3227539	0.24
397.2376709	0.89
399.2827148	0.05
403.1116943	0.02
408.2158203	0.11
409.0687256	0.27
411.3165894	0.12
421.4484253	0.02
423.1718140	81.95
424.1286621	0.07
425.3731079	0.10
427.1552124	0.09
429.3270264	0.32
430.1443481	0.04
431.1506348	0.27
431.8751831	0.26
437.1005859	0.18
439.3513794	0.66
441.1220703	100.00
441.8674316	0.49
443.1550293	0.03
446.4880981	0.08
447.4714355	0.04
452.5980225	0.95
453.3476562	0.80
456.1940308	0.16
462.1084595	0.19
465.2506714	1.90
469.2478027	0.47
470.2486572	0.04
471.1108398	0.13
475.7265015	0.05
476.9810181	0.03
479.0695190	0.54
479.6830444	0.12
481.1703491	0.39
483.1494751	16.81
483.9435425	0.41
493.6054688	0.12
498.3035278	0.06
503.2105103	0.10
507.1462402	0.58
513.3158569	0.04
515.4151001	7.68
516.3512573	1.03
518.2628784	0.09
521.5499878	0.10
523.2730713	0.11
524.3363647	4.73
525.3274536	0.70
528.4810181	0.03
532.4158936	0.33
536.2111206	0.27
537.3264160	0.09
541.2373047	0.11
545.3347778	1.42
546.0991821	0.55
547.5319214	0.15
549.3843994	0.02
551.3710327	0.05
561.0044556	0.09
563.1691895	0.26
565.3281860	1.73
566.4639282	0.17
572.2821655	0.10
573.2343140	0.10
577.1272583	0.04
579.0634155	0.04
581.4263306	0.02
586.5064087	0.08
587.3925171	0.03
589.1694336	0.06
591.1683960	9.98
591.7738647	0.19
599.5680542	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	407.16
Annotation	Isaindigotidione
Peak:m/z	Relative Intensity
117.0268707	0.06
129.9920502	0.06
133.1629333	0.02
144.1036377	0.04
144.9547424	0.41
148.8591156	0.05
159.0923767	0.02
160.0122986	0.04
162.0526886	0.26
164.2085724	0.03
174.1619873	0.04
175.0302734	0.10
177.0302734	1.68
179.2273254	0.06
180.9361267	0.06
188.0105896	0.39
195.0389862	0.10
196.2641754	0.09
197.1657104	0.06
199.0373688	0.60
199.9859314	0.06
203.0768127	0.66
204.0119324	0.01
204.9903412	0.78
206.0205231	0.03
213.0982361	0.17
220.0882721	0.02
221.2604523	0.02
228.8892212	0.05
231.2063904	0.09
235.1802979	0.02
238.2399902	0.08
245.0890808	100.00
256.1111145	0.25
256.9187317	0.12
260.1331177	0.50
274.0788574	1.66
274.9165039	0.09
278.1288452	1.99
286.2087708	0.06
288.1824951	0.91
288.8062134	0.02
299.0697021	0.29
306.0814819	0.35
308.1193542	0.44
314.0304871	0.06
316.0662842	0.06
316.9093018	0.04
318.7600403	0.05
327.4076843	0.09
332.1599731	4.49
333.1376038	0.08
334.1095276	0.16
343.1678772	0.06
344.2050171	0.84
346.3030701	0.05
348.8622742	0.09
353.2789307	0.02
356.3332825	0.04
357.3360291	0.06
359.2756042	0.17
360.9628601	0.04
362.5010986	0.05
366.3109436	0.02
370.3250122	0.08
372.1881714	0.06
373.1805725	0.37
374.3215637	0.04
381.3924866	0.02
388.2519531	0.17
389.1908264	1.36
390.2708435	5.09
398.2199097	0.22
407.2410583	0.17
418.1957703	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	383.2057
Annotation	Cinncassiol A
Peak:m/z	Relative Intensity
137.0796356	0.05
163.3355865	0.04
165.0329590	0.21
177.1134796	0.04
180.1213379	0.09
183.0774078	0.04
191.0995636	0.09
192.6420288	0.01
198.9744873	0.01
206.8518219	0.05
208.8009644	0.03
211.2227173	0.09
219.1162415	0.03
220.9490356	0.06
236.9736023	0.02
239.2784119	0.08
242.7419128	0.02
245.2554321	0.06
255.0706787	0.03
260.9258118	0.36
265.2244263	0.05
272.9594727	0.15
279.1433716	0.02
282.6542358	0.11
283.2720337	0.22
285.2977905	0.21
285.9080811	0.06
286.5523682	0.04
289.2890930	0.03
291.0902100	0.10
292.5878601	0.13
293.2392883	0.06
301.1438293	0.27
303.2655334	0.11
304.5731201	0.04
307.0362549	0.03
310.5325012	0.80
311.2712402	2.37
312.0569458	0.05
319.2055664	0.74
324.7208557	0.03
326.2135620	0.10
327.0826111	0.14
328.5659180	1.41
329.2124634	4.37
337.2770691	1.96
338.0194702	0.05
339.1601868	0.23
346.5333557	1.81
347.2222290	23.29
364.5277405	9.97
365.1353455	100.00
365.8907776	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1088
Annotation	Forsythide
Peak:m/z	Relative Intensity
123.2613525	0.06
125.0443802	0.05
134.2665405	0.11
140.1614990	0.11
142.9532471	0.07
146.9670868	0.08
151.3106079	0.11
152.7229156	0.57
154.8261719	0.14
161.0475769	0.27
162.4006042	0.06
164.9346313	0.81
166.0804138	0.76
166.8916931	0.12
168.0909882	1.72
175.3090515	0.13
181.0365295	1.75
181.9129028	0.07
183.1395264	1.13
191.0545959	0.07
193.2668610	0.55
194.0693054	1.23
195.1815186	0.09
197.2247162	0.05
199.4313202	0.06
205.1660767	0.29
206.9195251	0.12
209.0694580	7.78
212.0310364	33.27
216.7348022	0.04
220.9409180	0.15
225.1900330	0.12
227.0633850	100.00
227.9776611	0.11
232.8930664	0.08
239.3378906	0.06
245.5108948	0.05
254.2197266	0.29
255.0802612	0.08
259.1487122	0.14
269.0083313	2.40
280.9157104	0.03
323.2075806	0.06
326.9349060	0.05
343.1823120	0.65
344.2760010	0.43
345.1158447	0.12
351.0809937	0.13
361.2311707	0.15
370.1756287	0.27
371.2500916	0.89
374.2539062	2.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	327.07
Annotation	Bergenin
Peak:m/z	Relative Intensity
100.8418961	0.43
110.9529800	11.61
120.9428253	2.02
128.9197693	54.66
129.9009552	0.10
146.1080780	0.12
158.7697449	0.12
160.9406433	3.73
165.0626526	0.37
173.0968933	0.30
177.1753235	0.27
186.9687805	12.86
189.2144775	0.50
190.8984222	4.89
205.1097870	100.00
209.0186768	2.30
211.1632080	0.08
213.2789001	0.22
231.3706055	0.22
236.3554382	0.12
237.9593506	0.08
239.8211365	0.38
247.2812195	0.17
251.1943970	0.08
254.9832764	0.34
258.5300293	0.17
264.3447571	0.29
265.1343079	0.43
266.0699463	0.36
268.3164978	0.46
276.7052612	0.14
283.1862183	0.68
291.1664429	0.41
294.9143066	0.14
296.2164307	0.96
297.1679688	0.63
298.2018738	0.22
299.3110962	0.13
307.9400024	0.61
309.1373901	12.28
312.1924744	6.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.1584
Annotation	Cyanin
Peak:m/z	Relative Intensity
189.1924438	0.48
197.0577087	1.20
200.1993256	0.90
279.3839722	0.79
287.0605469	100.00
288.1021118	88.76
289.1452942	82.06
291.2203369	1.23
292.2026672	0.71
302.1940918	0.70
303.1942139	12.36
304.2601318	7.18
305.164917	9.11
313.2345276	2.69
319.1564026	0.18
327.0081177	0.50
329.0960083	2.21
331.2705688	3.35
353.2826538	1.13
355.0281372	1.54
369.1838379	0.20
409.2246704	0.29
431.2782593	0.72
432.2840576	2.46
433.2028809	6.12
447.2376099	0.67
448.0160522	1.32
449.1564331	6.13
450.1620483	19.82
451.1456299	25.50
459.2506104	4.27
465.0310059	0.72
466.5458984	5.45
467.2856445	3.87
468.7545166	0.56
492.3236694	0.86
493.3808594	5.38
501.8370972	1.43
515.4723511	1.42
520.8002319	0.79
523.4915771	0.95
524.473938	0.41
532.0141602	2.02
551.3759155	2.27
552.3087769	0.26
554.263855	1.23
560.3206177	3.01
561.5408325	2.32
577.9671021	1.51
586.2981567	1.22
587.1710205	1.35
595.2140503	2.30
595.9351196	1.20
602.6762695	2.08
613.3970337	2.86
614.0319214	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
79.05072021	1.42
80.83442688	1.12
85.03637695	1.49
96.02790833	0.89
97.17674255	1.25
98.12612915	1.36
98.86630249	0.63
103.0411987	4.06
105.0701141	0.99
106.8332062	1.22
108.9437561	4.31
112.9068909	1.95
120.936142	2.07
122.6318054	0.89
123.324295	1.78
124.1556702	0.82
126.8240509	1.34
129.061264	4.40
130.2234192	1.94
133.00737	8.44
134.0299377	0.93
135.080658	13.46
137.0383911	1.84
137.7523193	0.64
139.0782013	2.45
146.9361725	5.41
150.9655914	79.42
152.1012268	2.28
153.0642853	1.28
155.1660309	2.26
161.1595917	1.26
164.9829407	7.35
167.1217804	1.49
168.9361725	4.05
171.1098328	6.39
175.0945129	2.36
179.1494751	1.99
180.765976	2.06
182.1849213	1.85
183.1063232	5.95
185.1023254	1.70
188.2452698	1.55
189.4602661	1.58
193.182785	2.83
195.0865021	6.36
197.0824432	13.99
198.2374725	2.29
199.1855316	1.85
205.2711334	1.03
206.8419342	4.34
209.1438293	4.63
210.3238373	0.38
211.1271515	7.24
217.1991272	25.12
222.8921204	0.61
225.1953735	25.54
226.0336304	5.55
232.0818024	3.13
234.4007721	3.19
235.1931305	81.67
236.0968781	1.07
238.0947876	18.07
251.1067047	0.56
253.090332	100.00
254.2116089	3.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	307.1398
Annotation	Unknow
Peak:m/z	Relative Intensity
88.9387360	2.04
96.9491272	0.36
99.0036926	4.53
100.9151459	5.11
105.0197144	0.08
106.8265991	0.20
111.9932632	0.23
113.0220184	8.34
119.0124130	4.29
121.9711761	0.07
123.0716934	0.17
125.0224457	0.92
125.8016052	0.10
127.0777893	7.75
129.1544800	1.90
130.8134003	1.84
131.6866760	0.08
141.0813293	1.32
143.0567322	5.10
145.0653687	100.00
149.0082092	1.20
159.0233307	0.47
160.2005005	0.54
160.9701538	2.54
162.0911102	0.07
165.0076752	0.08
169.2299500	0.05
177.1650696	0.12
178.9875793	13.23
187.0266113	3.46
187.6850586	0.05
199.0718994	0.38
201.0286865	0.08
203.0998840	0.14
217.1567688	0.56
219.0802917	0.45
223.1513062	0.28
227.0758972	0.37
231.0794373	0.06
233.3937378	0.08
234.9407654	0.28
241.2342224	0.21
247.1297607	0.36
253.2587891	0.20
254.6194763	0.16
255.2220764	0.29
256.8868408	0.14
261.1223755	0.89
263.1368408	1.07
269.0553894	0.10
270.3006592	0.12
271.0949402	0.30
272.2583008	0.20
278.8343506	0.20
288.3369751	0.48
289.2317810	0.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	319.0935
Annotation	Unknow
Peak:m/z	Relative Intensity
101.9970703	0.49
111.8763123	0.12
128.0226898	78.27
137.2946777	0.10
143.9617310	0.62
145.9636230	39.30
165.0867920	0.08
172.0654297	20.04
177.0664673	0.31
189.5042114	4.55
190.1328735	27.23
191.0337677	0.10
193.1063843	0.09
213.3139954	0.91
214.1978455	0.21
217.0459900	0.23
231.4057007	0.44
232.2523499	0.10
246.9117126	0.12
257.1332397	4.33
258.1503906	0.38
263.2326660	0.15
275.1857300	14.72
277.1346741	1.01
281.0574341	0.21
282.9935913	0.95
288.2465820	0.11
301.0426025	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	592.3514
Annotation	Unknow
Peak:m/z	Relative Intensity
177.0014038	1.22
177.9163513	0.10
198.9856567	2.32
206.0194092	0.17
207.2728882	0.13
209.1461792	0.13
210.7746429	0.17
219.1553955	0.46
221.0700073	5.83
227.0205994	0.30
243.0173035	2.76
245.3904114	0.10
251.3546753	0.23
253.2685089	0.50
255.1688538	0.32
265.1684570	6.12
267.3101807	0.60
268.9386597	0.62
269.6018677	0.12
270.9917603	0.26
272.0187073	0.20
277.3012695	0.61
279.0510254	0.24
283.0617065	0.61
287.0604248	4.98
287.8227539	0.63
289.2377930	0.18
293.1663818	0.12
295.1902466	0.73
296.1086731	0.31
297.3935547	1.07
307.2321777	0.25
307.9336853	0.53
308.8908997	2.01
309.5042114	0.34
311.3459473	0.15
313.0753479	1.39
317.4697266	0.33
321.4816895	0.53
329.1837158	0.96
330.9817505	1.45
339.1267700	0.50
351.1113281	0.80
353.0748901	4.56
355.2833252	0.07
357.2878418	0.32
358.1409302	0.78
359.0897217	0.51
366.8750610	0.21
373.1947632	2.14
374.3715820	0.67
375.1590576	0.77
384.9170532	0.33
397.1285400	2.65
399.1520386	0.57
401.3440552	0.57
406.1846924	0.40
417.2443848	1.53
418.8908691	1.70
419.7736206	1.49
435.0614624	0.45
441.0718994	1.49
441.6792603	1.02
443.1398315	0.22
444.1261597	0.16
458.8742065	0.61
460.8712158	0.18
462.6872559	0.15
467.5477295	0.23
470.9582520	0.17
479.1651001	1.95
485.4046021	0.69
487.5673828	1.47
488.3261719	9.13
489.1987915	0.11
490.0074463	0.10
498.3555298	0.34
503.1234131	3.68
505.1546631	0.08
506.1405640	1.00
507.6132812	0.37
509.9768677	0.24
510.6508789	0.23
517.7185669	0.35
523.3224487	0.85
524.4959717	0.24
525.5291748	0.05
529.4338379	0.57
530.2992554	0.23
533.0789795	0.48
534.8085327	0.63
540.2688599	100.00
541.8916626	1.61
542.9258423	1.55
547.3210449	1.83
548.1105347	0.47
549.1386108	1.67
557.2022095	5.42
558.1275024	0.47
564.5179443	0.19
567.3980103	1.72
568.5172119	0.41
573.4803467	0.74
574.4668579	0.82
575.2324829	1.24
575.8588257	0.82
583.5525513	1.49
604.9629517	0.47
615.7457886	0.11
617.3594360	0.42
635.2805786	3.25
636.2971191	0.16
637.1463013	0.45
641.2391968	0.58
649.0181274	0.11
655.3514404	0.19
661.1538696	0.59
679.3271484	4.39
680.3399658	0.15
681.0916138	1.43
705.3659058	0.85
723.2877808	3.67
724.4401245	0.36
725.3215942	0.06
749.2921753	1.35
767.3717651	2.50
768.3301392	0.16
811.3301392	2.06
855.5400391	0.35
963.6282349	0.19
975.2482910	1.17
976.3473511	0.87
1009.5141600	0.68
1051.6730960	0.24
1079.4139400	5.16
1080.5543210	2.23
1147.8547360	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	817.3301
Annotation	Unknow
Peak:m/z	Relative Intensity
267.2760925	0.07
269.9698486	0.06
283.3763123	0.03
295.2544250	0.12
301.4580078	0.13
305.1364746	0.10
305.9575500	0.14
307.1312256	0.17
309.1654968	0.25
314.3759155	0.16
321.4677124	0.13
326.3093872	0.07
337.3270874	0.86
357.2723389	0.07
385.1627197	0.11
386.2521362	0.28
411.4001465	0.05
441.2230835	0.24
446.4246826	0.17
448.4606323	0.13
451.7355347	0.15
454.3640747	0.30
459.8647461	0.19
462.5004272	0.09
464.4396973	0.06
468.0841064	0.03
472.5083618	0.25
475.0963745	0.14
477.0408936	0.08
485.5900269	0.11
487.1374512	0.77
488.2314453	0.04
489.2086792	0.19
492.1127319	0.36
493.1024170	0.17
501.5261230	0.09
504.3863525	0.53
509.3851318	0.22
517.3668213	3.09
518.4815063	0.18
519.4429932	0.57
520.4247437	0.09
531.5345459	0.18
534.3206787	0.04
535.3646240	0.08
536.4142456	1.17
545.1841431	0.10
547.4480591	0.27
563.5496826	0.11
564.6943970	0.18
565.4958496	0.38
571.9005737	0.22
575.1574707	0.45
577.3762817	0.09
578.3658447	0.79
580.3923950	0.08
583.2858276	0.24
585.3825073	0.20
589.2876587	0.05
592.4950562	0.73
593.4348145	0.46
607.1484375	1.27
610.4855347	0.41
611.2709351	0.31
614.4373169	0.07
620.5060425	0.22
621.7363892	0.04
623.6149902	0.31
624.5283813	0.72
634.6633911	0.18
637.1563110	0.07
639.4292603	2.33
640.4689331	0.15
643.4772339	0.08
647.3218384	0.04
652.6652222	0.13
653.2750244	0.05
656.4704590	0.03
657.3229370	0.38
658.2255859	0.14
660.6259155	0.08
664.3991089	7.97
665.4769897	10.13
666.3164673	0.68
669.1781616	0.10
673.6264038	0.14
677.0602417	0.07
682.4605103	0.50
683.2380981	0.29
687.6079102	0.19
691.0590210	0.06
694.4940796	1.03
695.3724365	2.46
696.5270996	5.27
697.4591064	43.03
698.4386597	0.86
699.4529419	0.15
701.2612915	0.44
713.5789185	0.42
714.2708130	0.34
715.2010498	0.26
719.3215332	0.74
719.9848022	0.10
722.8413086	0.39
725.5585938	0.26
727.4834595	0.37
729.0604248	0.05
731.6652222	0.13
733.2144775	0.04
738.4972534	0.03
742.2867432	0.32
743.3798828	0.66
744.4050293	0.14
745.4564819	2.05
746.3004150	0.88
747.1327515	0.36
755.3429565	18.89
755.9924316	0.29
759.2817993	0.74
769.5677490	0.20
772.9597168	0.21
773.6168823	0.06
774.3413696	0.30
775.4359741	0.23
783.4303589	0.05
785.3264160	1.67
786.3967896	24.65
787.4349976	100.00
791.5457764	0.36
800.3491211	0.18
801.3247681	1.50
821.0615845	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	713.1649
Annotation	Unknow
Peak:m/z	Relative Intensity
227.1646118	0.07
273.0729980	0.54
291.1381531	0.58
309.1363525	2.48
389.3361206	0.07
405.0557251	0.38
434.3465576	0.16
453.1240845	0.26
459.9633179	0.38
469.4547729	0.18
470.9839478	3.82
476.7489624	0.50
534.8235474	0.09
539.3671265	0.86
551.0310059	100.00
551.7667847	0.26
557.1992798	1.88
558.0678101	0.64
565.8733521	0.22
566.9953613	3.47
580.0919800	0.78
581.2518921	2.11
602.2368774	0.39
612.9651489	0.44
613.8930054	0.62
615.0774536	0.83
631.0421753	0.33
632.6893311	0.30
647.4631348	0.41
666.0514526	0.14
667.0067139	1.26
669.0941772	0.65
677.1557617	0.17
695.0722046	1.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	336.2164
Annotation	Dendrine
Peak:m/z	Relative Intensity
96.8538055	0.14
102.8233795	0.20
105.0001526	2.54
105.7715759	0.15
109.8718185	0.43
114.0401230	0.15
115.8565140	0.77
116.9808731	3.58
118.8949127	0.77
120.0982742	0.18
122.0764313	0.44
122.9618835	0.21
127.0484238	0.15
128.1559906	0.63
129.1403198	1.46
130.2013855	0.17
131.0518036	0.27
132.9638367	3.05
134.0108490	1.93
137.0630798	0.06
139.8954315	0.18
140.9979401	1.43
143.0153809	1.31
143.9720306	0.13
146.0220032	0.13
148.0408020	2.46
150.1174164	0.80
150.8364410	0.12
152.1286316	0.17
155.3325806	0.28
157.0347900	0.46
158.0017700	0.82
158.8860931	0.76
160.1095581	0.47
160.9585724	0.71
164.4638977	0.10
166.1449127	0.90
166.9813843	0.09
169.0264587	1.09
170.2729187	2.03
172.0957031	0.15
172.9290466	0.94
174.8163147	0.11
176.1555176	0.41
177.9848022	2.86
179.0332184	0.41
181.9913025	0.06
183.0988770	2.09
184.1926270	0.12
185.8398132	0.42
187.0535278	2.02
191.0502625	0.60
193.8868408	0.63
195.2372437	0.05
196.2334900	0.15
197.1774902	0.77
199.3162231	0.42
200.0775146	0.19
200.9162292	1.45
204.8782196	0.14
206.9014893	0.33
208.9168396	1.76
211.2354431	0.13
214.1679077	1.10
216.2151184	1.94
217.9991455	0.16
219.5172119	0.19
221.0260010	0.22
222.4639587	0.99
223.3552551	0.73
224.1315918	0.17
225.2230530	0.63
226.2183228	1.57
227.2867737	1.54
229.2719727	0.11
230.3643188	0.18
231.3457642	0.16
232.1887512	2.42
235.1542664	0.86
236.3473511	0.12
239.1415710	0.19
241.1685791	0.30
244.3151245	1.51
245.2954102	0.59
246.0166321	0.36
247.0235596	0.36
251.0976562	0.06
252.2039795	1.48
253.9417419	1.38
254.5943604	0.03
256.2996216	0.30
258.1819153	1.46
260.6831360	0.86
262.1759338	11.31
264.2751465	9.69
265.2872314	0.40
270.2236633	20.72
271.1845703	0.09
272.3284302	3.76
273.2561035	0.68
280.3262939	0.25
282.2661133	45.01
283.1420288	0.29
288.1134033	1.27
290.2362671	2.66
291.0932007	0.05
294.0146484	0.40
300.2595520	56.00
301.2920532	0.32
303.6441040	0.17
318.2284546	100.00
319.2190247	2.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	366.1194
Annotation	Unknow
Peak:m/z	Relative Intensity
109.0414429	0.08
112.9862976	0.70
116.0593872	1.77
117.0120087	0.46
119.0479202	0.18
122.9997482	0.17
127.2516632	0.08
131.1645508	0.64
136.9418640	0.23
139.1152344	0.06
142.0821838	28.81
143.0046082	0.10
144.1156311	0.37
154.0728302	0.33
156.8701477	0.62
158.0606384	3.80
160.0774536	0.32
160.9291840	0.11
170.0367432	0.12
186.0927429	100.00
188.1029968	0.34
189.9828186	0.27
199.9472961	1.63
200.8980408	0.80
202.9936676	2.30
204.1538696	77.53
214.0677490	0.26
216.2062225	0.15
218.1117249	1.81
219.3151855	0.57
228.1325073	0.24
231.3530273	0.39
233.1890259	21.33
236.9976807	1.52
238.2218628	0.17
244.0140381	2.41
246.1157227	13.20
249.2103882	0.79
257.2955322	0.19
263.0028076	0.36
264.2547913	0.44
267.3171387	0.05
272.3416138	0.89
274.9796753	0.47
276.0183716	0.10
281.0854797	0.09
282.3930664	1.02
284.4595947	0.76
287.0960388	0.08
288.1112366	0.22
294.3904419	0.24
298.1109009	0.82
300.0860291	0.64
306.2302246	0.15
307.3714294	0.28
310.2922974	2.00
312.3873291	0.08
316.2478943	1.01
319.8861084	0.16
321.2881470	0.49
322.5465698	0.67
328.4805603	1.61
330.1621094	0.51
335.3631592	0.14
336.1947632	0.14
347.2043762	0.37
348.5263367	1.71
349.6333313	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	565.3524
Annotation	Unknow
Peak:m/z	Relative Intensity
177.0792542	0.55
178.1484985	0.08
183.1675568	0.07
185.6074371	0.08
189.0541077	0.11
190.2072754	0.10
195.9430389	0.18
199.0604248	0.32
207.5511169	0.95
208.7601929	0.06
209.3601990	0.31
212.0413971	0.17
219.2586975	0.05
220.9449615	3.30
221.6393738	0.10
223.2840881	0.15
225.2053833	1.10
226.2710419	0.24
229.6466675	1.44
236.0541077	0.06
237.8354187	0.08
239.1001282	0.07
243.2928162	0.51
248.3250275	0.15
251.4562531	2.79
252.1818085	0.47
255.3413391	0.14
264.3008423	0.13
265.3039246	0.44
266.9965515	0.22
269.2991943	0.11
270.1363831	0.24
273.5774536	4.39
275.6181335	0.29
277.5924683	0.05
278.9251709	0.08
283.6426697	0.41
293.3962402	0.18
294.5831299	0.42
295.6216431	2.09
297.6193237	0.12
300.5509033	0.04
301.1997070	0.24
305.5921021	1.75
307.7720947	0.05
309.3320312	0.52
310.3309326	0.07
311.0358276	0.81
312.8201904	1.01
313.7130127	0.07
314.3500977	0.09
317.4646606	4.31
318.2636719	0.54
319.8903809	0.54
327.6674805	1.80
328.8407593	0.68
330.8064575	0.11
339.4123535	0.71
340.0617065	0.48
349.9162598	2.78
350.9556274	0.12
353.2090454	1.15
354.3022461	0.15
355.1224365	0.29
356.4713135	0.03
359.6400757	0.11
361.4727173	1.26
362.4537964	0.02
363.5150146	0.79
364.2416382	0.32
369.4990234	0.24
371.5175781	2.26
372.2182617	0.83
373.2305298	2.02
374.2880859	0.35
376.6348267	0.06
383.9168091	0.10
388.1520386	0.13
392.6657715	0.14
393.5861206	1.24
395.1201782	0.17
397.0322876	0.29
398.1849365	0.10
399.3779907	0.07
401.2419434	0.08
405.5861816	1.57
406.2222900	0.16
407.4853516	0.05
408.2367554	0.12
409.5764771	0.11
415.5596313	1.03
416.5746460	0.42
417.1926270	1.51
418.3896484	0.13
419.3052368	0.08
429.7185059	0.06
430.9342651	0.07
434.9874268	0.21
436.2319946	0.03
437.7938232	0.99
442.3099365	0.20
444.5722046	0.42
452.1538696	0.65
452.8905029	11.92
454.1616211	0.51
455.0617676	0.06
459.4109497	0.16
460.7844238	0.25
466.2169800	0.10
475.0341797	0.04
476.3791504	0.25
477.7005615	0.04
481.9302368	0.34
482.7385864	0.44
488.6216431	0.12
489.3424072	0.03
490.6972046	0.03
493.1954956	0.08
496.2453003	2.44
498.0786743	0.17
504.1245728	6.06
504.9396362	100.00
506.0722046	2.82
506.9838257	0.84
507.8591919	0.96
508.5491943	0.14
509.6949463	0.23
511.1761475	0.34
512.7996826	0.54
513.5938721	0.17
516.1738892	0.03
517.7686157	0.40
519.1039429	0.16
520.3951416	0.33
521.5245972	0.18
523.4498901	0.17
525.3283081	0.33
529.0914917	0.37
530.2095337	0.15
535.3189087	0.58
537.2292480	0.12
537.9207153	0.07
539.8828735	0.08
541.5073853	0.07
546.6432495	0.13
547.4067993	2.04
548.2736206	2.69
549.2983398	0.42
550.3551025	0.09
556.7079468	5.99
557.5957031	0.43
558.4754028	0.07
560.3321533	0.05
562.2725220	0.17
574.2319336	0.03
591.4100952	0.08
592.2083740	0.02
593.0326538	0.67
608.4213257	2.52
609.5404663	0.28
615.3728638	0.07
634.6138306	0.04
637.7693481	0.21
640.0671997	0.12
650.4266968	0.06
652.3683472	2.57
653.4003296	1.94
654.2987061	0.24
655.4755859	0.15
660.0858765	0.09
661.0086060	0.28
662.3019409	0.07
679.0035400	0.41
679.7708130	0.40
680.4636841	0.13
682.4298706	0.06
684.4058838	0.12
694.3975830	0.03
696.5285034	3.12
697.4738159	0.58
700.3962402	0.50
701.2939453	0.04
709.6526489	0.06
711.0039673	0.03
723.9578247	0.20
724.5689087	0.09
726.6229248	0.32
740.4635620	1.20
741.5305176	0.26
742.5670166	0.12
743.3400269	0.06
744.3778687	0.32
754.7780151	0.02
758.4595947	0.06
760.7218628	0.33
761.3835449	0.08
767.5130005	0.20
768.7357788	0.10
769.5403442	0.16
779.4769287	0.09
784.4594116	1.22
785.5939331	0.38
786.5164185	0.02
787.7686157	0.03
788.5108643	0.85
804.5070190	0.72
805.5210571	0.74
813.4383545	0.14
814.0474243	0.15
814.8278198	0.36
816.4763184	0.10
830.6550293	0.02
832.5592651	0.38
833.2843628	0.20
844.4690552	0.03
848.3801270	1.34
849.4902344	0.34
857.2350464	0.06
874.6325684	0.06
875.5321655	0.09
876.5014038	0.27
887.5410767	0.24
888.2772827	0.06
889.1303711	0.05
892.5108032	1.32
893.4833984	0.53
903.7871704	0.25
904.4380493	3.25
905.3910522	1.68
906.0101929	0.04
907.5221558	0.06
918.9572144	0.03
920.6999512	0.42
921.3783569	0.06
936.3955078	0.48
937.5834961	0.38
964.7080078	0.12
965.7284546	0.14
980.6431274	0.49
981.5585327	0.66
991.5162964	0.66
992.4230957	0.11
1008.4909060	26.55
1009.5148320	12.49
1010.4363400	0.32
1024.9829100	0.03
1112.5788570	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	216.07
Annotation	3-Methylindolepyruvate
Peak:m/z	Relative Intensity
70.8797531	0.02
74.8078003	0.02
96.8917236	0.04
98.9247894	0.35
108.2573853	0.03
110.0890045	0.02
113.1477203	0.05
115.9565277	0.78
118.2057648	0.14
129.0728607	0.06
130.0859833	0.02
138.9795074	0.01
142.0598602	0.05
144.1137695	0.61
144.9399872	0.11
154.1021881	34.46
155.9983673	14.16
158.0559845	1.53
160.0477600	1.36
165.9861298	0.04
169.0084534	0.18
170.1042938	1.76
171.1510162	0.60
172.0674438	6.36
172.9446259	0.06
174.0294647	0.08
178.9938660	0.05
184.2740326	0.02
186.1569366	0.41
188.0135803	100.00
196.9877167	0.56
197.9907074	6.25
199.0557098	0.08
200.8085175	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	308.0902
Annotation	Glutathione
Peak:m/z	Relative Intensity
116.0497742	0.14
117.0775528	0.09
117.9000626	0.15
129.9712524	0.35
130.8492432	0.32
136.1185455	0.09
143.9534149	0.64
145.2171326	0.59
145.9902344	2.03
147.2451324	0.14
151.9337006	0.06
162.0183411	7.87
162.9518127	6.62
163.9379883	21.62
178.9808044	30.24
180.0260315	26.07
180.9605713	100.00
186.7705841	0.05
205.6382141	0.15
207.1589661	0.04
214.8027954	0.25
216.0709229	0.16
217.1771545	0.08
221.2788086	0.21
222.2394714	0.25
233.0695801	3.18
234.0562439	5.81
235.0748596	20.35
245.0729065	0.52
246.0826111	0.29
246.9528809	1.17
256.1475830	0.10
263.9446411	0.18
266.2851562	0.08
272.9421997	0.67
274.0421753	1.64
291.2086182	2.96
292.1413879	8.83
293.2070007	2.41
295.0203552	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.0775
Annotation	Avicularin
Peak:m/z	Relative Intensity
133.9729767	0.01
137.1412964	0.00
151.1379547	0.27
151.9436493	0.01
153.1253357	0.01
160.9850311	0.01
162.0213318	0.01
163.0311432	0.02
165.3360596	0.00
167.1327820	0.00
169.0535583	0.02
173.1677856	0.00
175.0702515	0.01
177.2131500	0.01
179.0289917	0.34
180.1357117	0.04
180.8896179	0.03
182.1932678	0.01
187.1596375	0.01
188.0767517	0.01
189.0399475	0.04
190.0280762	0.05
191.0784607	0.03
193.0305481	0.05
194.7723541	0.00
197.0594025	0.04
198.2463379	0.02
199.2043457	0.01
203.5049896	0.00
204.9114075	0.02
207.2322998	0.00
208.1543884	0.00
213.1719818	0.00
214.2800598	0.02
217.1782074	0.00
218.1779633	0.00
219.1744080	0.03
220.9035339	0.06
222.4925690	0.00
227.1177826	0.03
228.5652161	0.00
229.1938477	0.04
230.5045471	0.00
233.1290588	0.04
234.2667847	0.01
237.3450928	0.01
240.0959167	0.00
241.0497437	0.04
247.0642700	0.04
248.3150635	0.00
249.1262512	0.00
251.2630615	0.05
253.2896423	0.03
254.2151489	0.06
255.2308960	0.05
256.2092590	0.03
257.1478882	0.01
257.9338074	0.01
259.1214600	0.01
260.1750793	0.00
261.2741699	0.02
269.3439636	0.02
271.1627197	0.37
272.1850891	0.05
273.1209106	0.06
274.1901550	0.02
275.5156250	0.01
277.4768677	0.00
281.1195679	0.03
283.0891113	0.04
284.9710083	0.04
286.7207947	0.02
288.0625000	0.01
289.3388672	0.03
290.3104553	0.00
293.1551208	0.01
294.3914795	0.00
296.3493652	0.01
297.2004089	0.02
298.2658081	0.01
300.2762756	18.04
301.1116943	100.00
302.0770264	11.20
304.1234436	0.01
306.0429993	0.02
307.0642090	0.07
308.1423950	0.03
309.4540710	0.00
310.2213440	0.00
310.8990784	0.00
312.4832764	0.00
313.1950073	0.04
314.2897949	0.03
315.1605835	0.01
323.3431702	0.03
325.1064758	0.06
326.1810913	0.01
327.2172852	0.02
329.5357056	0.00
333.0014954	0.01
334.1711731	0.00
335.4486694	0.01
337.2047424	0.01
341.2730713	0.10
343.2016602	0.79
344.2498779	0.21
345.3304443	0.01
347.1966248	0.01
348.1635742	0.01
350.1083679	0.00
354.9844360	0.02
356.3360596	0.03
358.3173523	0.00
359.2871094	0.09
360.4642334	0.00
364.8861389	0.00
365.5344543	0.00
371.2176819	0.02
373.2464294	0.11
374.0700989	0.03
375.1908264	0.02
379.2067261	0.00
387.1822815	0.03
388.1463013	0.02
389.2377625	0.07
390.0502625	0.01
391.0436096	0.01
392.0434265	0.01
394.9556580	0.01
396.9860535	0.02
398.1511536	0.03
400.2015686	0.00
415.2306213	0.22
416.1936340	0.04
417.0556335	0.01
417.7132568	0.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	521.3257
Annotation	PIM1(19:0/18:1(9Z))
Peak:m/z	Relative Intensity
147.1566010	0.24
166.1221619	0.22
169.2465973	0.27
183.9621887	19.81
184.9458313	1.42
186.8489838	0.43
192.9692688	0.13
194.3081512	0.29
195.2715454	0.14
202.7216492	0.13
209.2407684	1.12
212.2857513	0.06
217.0851746	0.15
221.1468506	1.85
223.1778870	0.42
225.2832947	0.68
227.0292206	0.17
229.6287537	3.12
234.9978333	0.43
242.9327698	0.75
249.2869110	0.22
250.8243408	1.07
251.5205841	1.68
255.3063507	0.09
257.0595703	0.14
265.0310364	1.20
266.9996948	0.50
269.0350952	0.04
273.5437622	4.51
275.7320557	0.36
279.1126709	0.55
283.4539185	0.31
287.1937866	1.14
295.5599365	2.30
297.7053833	0.21
299.8978882	0.23
305.8322754	1.85
309.2106934	0.22
311.1497803	0.59
313.4442749	0.19
314.8735962	0.14
316.3550415	0.43
317.6235962	4.24
327.6717529	2.57
332.5468750	0.50
335.8632812	0.36
339.5666504	0.07
341.6987915	0.07
343.1594238	0.04
344.9522095	0.42
349.5767822	2.55
353.0316772	0.42
355.4401245	0.34
361.4297485	1.89
363.5300293	0.99
371.5776367	4.26
373.3062744	1.99
373.9512939	0.06
376.9862671	0.18
378.5955811	0.44
383.4168091	0.09
393.4183960	0.81
399.7203979	0.26
400.7317505	0.10
408.6677856	5.75
411.1376343	0.32
413.3850098	0.09
415.5518188	0.68
416.8126221	0.30
417.4431763	0.22
421.8540039	0.98
423.3615112	0.31
426.4855347	0.09
429.5826416	0.79
431.9458008	0.37
438.7847290	0.35
443.1914062	0.93
446.0067139	0.19
452.2560425	0.78
454.6505737	0.22
459.0245361	0.87
459.7001343	2.73
460.7442627	66.51
461.5606079	2.62
462.4688721	0.21
463.2493896	0.31
464.2625732	0.40
464.9550781	0.06
465.7009277	0.33
468.8392944	0.46
471.1896362	0.31
474.5578003	0.40
476.4108887	0.17
480.3092651	0.18
485.5822144	0.18
488.9274292	0.12
490.5743408	0.99
491.4012451	0.18
492.5102539	0.35
496.4841919	0.25
502.4670410	19.57
503.4122925	8.97
504.2531128	1.90
505.1315308	0.18
512.7548218	5.71
513.6583252	1.41
521.7691040	0.16
547.4928589	0.15
564.4353638	2.11
572.9352417	0.43
591.7391357	0.30
593.2821655	0.21
608.4586792	2.07
628.4373779	0.09
635.5422974	0.05
637.2839966	0.24
639.3563843	0.13
652.4640503	1.03
654.7453613	0.18
672.5928345	0.51
681.3812256	0.42
683.0408325	0.05
696.4657593	1.17
700.6244507	0.34
716.5090332	0.18
744.2786865	0.10
758.7100220	0.05
760.5936279	1.38
799.1483154	0.77
802.3919067	0.40
804.4736938	2.57
814.5457153	0.09
816.3977661	10.82
817.3685913	0.12
819.7586060	0.33
832.6311035	0.70
847.9933472	0.29
848.6150513	1.29
876.1110229	0.41
892.5547485	0.26
903.4403687	1.00
904.6848755	0.19
918.6003418	0.06
920.4892578	100.00
921.4479980	1.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	803.3094
Annotation	Kotschyin C
Peak:m/z	Relative Intensity
241.0349579	0.04
244.0593262	0.11
254.8418427	0.17
256.1910400	0.14
268.1777954	0.18
269.1343689	0.10
280.9757080	0.08
282.4703369	0.08
283.1229858	0.73
285.3133850	0.94
299.3040466	0.21
301.0878296	0.30
303.0679321	0.41
307.2238464	0.42
318.3190613	0.14
325.2283325	0.36
326.3762207	0.14
330.2753906	0.10
339.3157959	0.05
341.2614746	0.39
343.4375610	0.14
345.2633057	0.33
346.0509644	0.19
349.0570679	0.11
359.1179504	0.49
372.9979248	0.09
374.2118530	0.04
374.9729614	0.40
381.3066406	0.10
391.3668823	0.12
393.5754395	0.25
397.2075806	0.18
401.3031616	0.10
408.8494873	0.06
411.3489990	1.06
420.5300293	0.09
421.1810303	0.15
426.9913940	1.20
429.1495361	1.82
439.5009766	0.16
445.1159668	2.33
445.7429199	0.08
446.6960449	0.44
447.2966919	1.92
448.4442139	0.05
456.4089966	0.12
459.1820679	0.15
461.0938721	0.36
462.2385254	0.33
473.3109131	0.05
474.3128052	0.21
489.6647339	0.17
492.3154907	0.15
506.2836304	0.33
524.7012329	0.03
528.0435181	0.62
532.7052612	0.10
544.3939209	0.67
546.3321533	0.26
553.9752808	0.09
556.3821411	0.14
557.6084595	0.04
562.3970337	0.65
564.2879639	0.07
565.5700073	0.43
566.4548340	0.11
570.2943726	0.21
572.2282715	0.04
574.3749390	0.04
576.2485962	0.22
580.1315308	2.20
582.0736694	0.46
582.7538452	0.23
583.7279663	0.37
588.3851929	0.60
590.1232300	0.14
592.3848877	0.78
598.2901001	1.57
599.9808350	0.41
600.5999146	0.57
602.3266602	1.09
604.4022217	0.30
606.4737549	0.64
608.3311768	0.34
609.0485229	0.84
610.2507324	0.56
614.3402100	0.40
618.6080322	0.86
620.2760620	1.69
622.5902710	0.16
623.3283081	0.33
624.4079590	0.37
625.0602417	0.14
627.1665649	0.41
632.4672241	0.66
634.2759399	0.18
636.5720825	0.23
638.2781372	0.36
639.8733521	0.11
641.1712036	1.69
641.8237915	0.29
642.7287598	0.06
646.2265015	0.08
648.2106323	0.38
650.2742310	0.78
651.5714722	0.09
657.5631714	0.26
658.3543091	0.37
659.2887573	1.05
664.4700928	0.08
666.1860352	0.17
668.2500610	0.18
669.4813843	0.25
670.9938354	0.04
678.1672974	0.86
681.4642334	0.37
683.7951050	0.08
689.2876587	1.28
691.4699097	4.24
699.5335693	0.21
701.4291382	1.28
707.4183960	2.33
708.9411011	1.78
709.5830688	3.09
710.2785034	0.07
711.4580688	0.22
717.2648315	2.20
718.4060059	0.04
721.6240845	0.56
725.4851074	1.56
727.4918213	1.81
728.2874146	0.32
735.3689575	34.29
738.5099487	0.07
739.2896118	2.93
741.4809570	0.04
743.3278198	0.71
749.2741089	1.66
753.2471313	16.46
754.1647949	0.81
757.2994385	3.20
758.6914673	0.44
763.3380737	0.04
764.7955933	0.15
767.3228760	36.74
771.2820435	100.00
772.0026245	0.10
774.3032837	0.42
775.3634644	2.03
781.1645508	0.21
785.2777710	26.97
800.9598999	0.09
803.4062500	0.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	700.97
Annotation	Unknow
Peak:m/z	Relative Intensity
276.7030640	0.16
293.9205933	0.09
308.7020874	0.18
322.9640198	1.21
380.7847290	0.18
391.2638550	0.26
403.2237549	0.24
428.8661499	1.18
457.0042114	0.43
458.9523315	0.57
470.8636475	0.55
475.2371216	0.08
482.7853394	0.10
486.7608032	0.60
488.7738037	1.45
520.6130981	0.76
526.1517944	2.94
526.8853149	13.58
528.2011108	0.24
532.7899780	0.14
539.1383667	0.45
545.5133667	0.53
546.1921997	0.06
546.8773193	0.16
565.0448608	100.00
565.7898560	0.79
573.1755981	0.17
599.1025391	0.30
602.6817017	0.19
603.3600464	0.24
612.9543457	0.18
614.3650513	0.99
616.6691284	0.91
617.3803711	0.53
623.2112427	0.09
654.3215332	0.22
658.8867798	0.89
683.7711792	1.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	303.0494
Annotation	Bracteatin
Peak:m/z	Relative Intensity
92.8284149	1.44
104.9713974	0.82
106.8853149	0.58
108.9840698	0.87
110.8818893	3.43
114.8711700	0.55
117.1670074	0.48
120.9775009	3.89
122.0987244	0.92
126.7989807	0.22
134.8377228	0.31
136.9711761	12.27
149.0382690	5.18
151.3061829	0.32
152.9349060	13.79
154.1412811	0.49
156.8762512	0.21
161.0883331	2.43
162.9299774	4.21
163.9638214	0.95
164.9319611	35.91
166.0406799	4.16
173.0096436	1.48
174.0032349	0.20
175.0930634	0.67
177.2659912	0.27
183.2084503	0.45
185.1195068	0.99
186.9985352	1.66
188.0171509	0.46
189.2013702	0.52
190.9693146	0.26
194.0093842	0.12
195.0803833	7.32
196.1385193	0.19
201.0939026	5.40
205.0718384	2.89
207.2587891	0.49
213.0696411	2.02
214.8590393	0.46
216.0980530	0.23
219.1015015	5.62
223.1410522	1.20
229.0847473	61.46
230.0109863	4.92
231.1643677	0.63
231.9768677	0.18
232.8942566	0.70
239.2589722	0.16
239.9779968	0.39
241.1482544	0.34
242.9830627	0.32
247.0963745	29.52
248.1110840	7.36
257.0748291	100.00
258.0795288	9.91
259.1234741	0.26
262.0404968	0.68
267.0448914	1.06
271.2369690	0.29
274.0255127	18.19
275.0823364	12.47
276.0104065	1.01
285.0696106	64.31
286.1510315	6.42
303.1201172	39.78
304.1798096	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	314.1245
Annotation	Unknow
Peak:m/z	Relative Intensity
97.9869690	0.07
109.9436951	0.08
111.1004257	0.09
114.8323822	0.46
135.1736755	0.03
139.3179016	0.20
154.0714417	1.39
155.1910400	6.01
164.1236877	0.18
165.0996704	0.11
180.9752502	0.23
182.7558441	0.04
187.0846710	0.17
194.1704559	0.06
198.1193848	100.00
199.0603790	39.45
208.1347656	1.08
211.3793335	0.12
212.0614319	0.08
225.9867249	0.09
242.3048096	0.04
243.2140808	0.08
247.1744385	0.03
252.0667725	25.39
252.6938477	0.02
253.9962769	0.07
267.3903809	0.16
268.2053528	0.13
269.5126953	0.41
270.2441711	3.12
271.0582886	0.08
278.1098022	0.47
282.2114258	0.49
286.2692871	0.14
296.1439209	89.13
297.0879822	0.39
298.0904236	0.16
298.9750671	0.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	470.1513
Annotation	Unknow
Peak:m/z	Relative Intensity
160.9174194	0.20
169.8828735	0.31
178.9754944	0.40
218.2998505	0.10
231.0148010	0.34
242.3333130	0.25
248.7481079	0.33
262.0666809	0.47
290.2192383	0.21
307.0549927	0.27
308.0508423	0.70
332.0225830	0.28
335.2830811	0.32
339.9314575	0.15
341.1358643	100.00
359.9015503	0.15
371.7904968	0.75
390.4306335	0.11
395.1377869	0.34
407.2505798	0.44
410.0958557	0.22
418.5462952	0.13
423.8682556	0.62
426.2164001	0.71
433.1006165	0.14
452.1602783	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1614
Annotation	Safflomin A
Peak:m/z	Relative Intensity
205.0689697	0.10
207.2076111	0.16
210.0474854	0.06
229.1420898	0.09
244.1804810	0.03
247.0494385	0.09
249.0542755	0.07
254.1892700	0.18
272.2417603	0.06
275.2094421	0.16
286.1508179	0.08
297.3015747	0.05
304.1560669	0.07
305.1329956	0.05
306.3202515	0.17
314.3165283	0.09
315.2123413	0.50
316.0712891	0.06
317.2835083	0.11
320.3991089	0.04
331.0693359	0.08
337.0689697	0.34
338.0253906	0.09
341.0390015	0.05
345.4477539	0.10
354.7962646	0.17
356.1524658	0.32
359.3981934	0.35
363.1550903	0.32
371.0567627	0.52
381.1126709	0.86
388.1842651	0.94
403.1616211	100.00
406.2213745	0.10
417.3236084	0.04
434.2075806	0.04
436.6565552	0.11
437.4185791	0.03
447.3137817	0.04
449.6502075	0.04
454.0748901	0.07
465.2003784	0.12
468.9524536	0.16
470.3958130	0.19
475.4685669	0.08
479.4912720	0.07
480.6271362	0.11
486.3591919	0.06
487.4229736	0.31
489.4498901	0.25
491.1668701	0.03
492.1848145	0.09
515.1385498	0.04
515.8519287	0.09
516.5477905	0.18
519.1309814	0.39
524.4567261	0.17
549.7596436	0.72
552.4052124	0.12
561.2962646	0.04
564.5017700	1.34
565.3500366	0.35
566.4160767	0.28
567.2830200	0.90
568.4453125	0.03
569.5452271	0.09
574.8876343	0.19
575.6188354	0.04
591.3272095	0.04
592.5475464	0.38
593.5537720	0.08
611.1709595	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.1505
Annotation	Benzyl beta-primeveroside
Peak:m/z	Relative Intensity
139.1322937	0.01
154.1180115	0.04
157.0848389	0.04
165.3119965	0.04
167.0763245	0.04
175.0158997	0.04
181.9740295	0.08
183.0347595	0.01
192.0320740	0.04
193.2115479	0.10
197.1720734	0.13
200.8019714	0.01
203.4523926	0.05
212.1816406	0.02
219.2214355	0.04
221.0428314	0.04
223.1698456	0.08
224.1893921	0.10
228.1425323	0.04
230.9945374	0.08
237.2279358	0.04
239.1278687	0.04
243.3176270	0.04
249.1865234	0.59
253.0295410	0.09
255.0458679	0.03
257.1887512	0.24
267.2143555	0.27
271.2076416	0.39
275.3153381	0.07
284.0184326	0.02
285.3627014	0.01
293.2855225	0.02
296.3882141	0.03
297.2132568	0.04
299.0005798	0.10
300.2765808	0.01
301.3160095	0.08
303.3323669	0.05
311.2901611	0.03
315.1837158	0.03
327.2658691	0.06
335.9707947	0.02
351.3068237	0.03
358.5960083	0.24
359.4143677	0.38
360.4633179	0.24
375.7004395	0.01
383.3070984	0.02
385.1778259	0.11
386.2463074	0.03
387.3771057	0.05
389.1170349	0.01
401.2759705	100.00
402.4847107	0.02
403.4601135	0.02
405.3440247	0.03
410.3424988	0.14
411.4042664	0.23
415.1220398	0.20
428.5691528	0.21
429.2075500	0.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	209.0303
Annotation	Glucaric acid
Peak:m/z	Relative Intensity
84.9858551	8.19
87.1926575	0.01
89.0448608	0.02
100.9430389	0.08
102.9604034	0.16
114.8856354	0.04
129.0476532	0.87
133.0560913	0.24
145.1273041	0.03
146.9549103	1.44
162.7530670	0.03
172.9657135	1.31
190.9755402	100.00
193.2458649	0.08
193.9399719	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1686
Annotation	N-Undecylbenzenesulfonic acid
Peak:m/z	Relative Intensity
111.1190567	0.10
112.9201050	0.03
119.1004639	0.12
133.3395081	0.05
134.2650299	0.02
155.9541321	0.27
162.9645844	0.04
169.9902191	4.93
171.0714722	0.25
182.9958801	100.00
184.0038147	17.71
185.0622711	2.17
186.0381165	0.09
195.2284546	0.06
197.0315552	88.59
198.0353699	20.22
199.0673828	1.89
199.6858215	0.06
206.5223999	0.02
211.1168518	2.71
212.0657654	2.59
213.1416626	0.42
213.8179932	0.08
216.7771301	0.05
225.1472778	3.51
226.0326538	3.56
227.0844116	1.14
228.0934143	0.06
234.9428406	0.02
239.1331177	4.72
240.1156921	3.39
241.0382080	0.62
241.9362793	0.10
245.4553528	0.02
247.1923218	9.68
248.2355042	2.71
249.2268982	0.19
250.2544556	0.06
253.0787048	2.43
254.1642456	1.71
255.1692505	0.71
256.2111206	0.12
267.3325806	0.81
268.2179871	0.65
269.2358704	0.26
270.2648315	0.06
281.2079468	0.31
282.2660522	0.14
283.2071838	0.14
284.3675842	0.11
285.9929199	0.09
293.2760620	1.07
294.2229309	0.72
295.4672241	0.18
296.1810303	0.11
311.2555237	16.60
312.2507935	4.80
313.3142700	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	373.1502
Annotation	Deoxyloganin
Peak:m/z	Relative Intensity
112.9733734	1.62
115.1097641	0.21
118.9979477	2.17
121.0908813	0.12
124.9882507	0.97
130.8754883	0.60
133.0087128	0.47
136.7734528	0.09
143.0715179	2.61
149.0419159	100.00
158.8749695	0.56
160.9378357	0.82
167.2894897	0.11
175.2825928	0.17
179.2336121	0.11
190.9488983	0.39
193.0579224	0.38
195.1326294	0.38
196.0918884	2.59
208.8166809	0.33
211.0870819	10.87
237.2967834	0.26
252.9227295	0.07
273.2899780	0.72
315.1087646	0.22
327.1823425	0.40
329.1574707	0.32
355.2996521	21.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
120.9634552	0.23
128.7941589	0.28
134.0437317	0.85
142.979248	1.78
155.0043335	0.75
156.9519196	0.81
158.899353	0.77
163.277832	0.40
169.2683105	0.95
171.0176544	2.60
173.0660248	1.02
174.8645782	0.64
180.8045807	0.22
185.2919769	0.50
187.1058807	2.82
194.9248962	0.37
199.3565369	3.51
200.9081421	3.78
203.1387329	1.55
211.2283478	0.65
213.1088867	1.01
215.1868591	2.48
217.3690491	1.18
227.2728577	1.87
229.2154541	2.04
231.2359009	1.47
239.3217163	0.32
243.1190491	6.75
245.0646362	0.60
255.3052063	1.96
256.1224365	1.58
257.2193909	3.80
259.2324829	1.34
263.3287964	3.06
269.4068298	0.79
271.1375732	7.84
273.3121948	2.21
277.1107788	0.73
283.2660522	2.39
285.2892151	8.33
287.3424683	1.23
289.0127258	0.16
295.1977539	0.61
297.1817932	8.12
298.3580322	0.71
299.3384399	5.54
301.2321167	3.42
304.692749	0.24
309.1065369	0.50
311.4405823	3.82
313.2428284	4.05
315.1963806	6.91
318.9075623	0.54
321.2234802	2.08
323.2615356	12.18
325.0935059	0.89
339.2577209	100.00
341.231842	32.29
342.0063477	0.10
356.9288635	1.34
359.1828918	0.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.2078
Annotation	Symlandine
Peak:m/z	Relative Intensity
145.0333862	0.01
145.9778748	0.01
162.6334839	0.04
190.0078430	0.08
227.5268860	0.01
265.0265198	0.04
273.2452698	0.04
274.0415955	0.04
275.3787842	0.10
276.4424133	0.03
282.3018799	0.03
285.0926514	0.02
290.0904236	0.23
292.0855713	0.09
299.4426575	0.04
300.4215698	0.06
313.2596130	0.23
315.2589111	0.23
318.3193054	0.09
319.1631470	0.06
320.3852234	0.06
325.4760742	0.03
327.2440186	0.06
329.6180420	0.22
331.2503662	0.09
334.2758179	100.00
336.3565674	0.05
341.2892456	0.15
347.1321716	0.07
359.4261780	0.03
361.4681702	0.38
362.3744202	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	227.1273
Annotation	1-Acetoxy-7-hydroxy-3,7-dimethyl-2E,5E-octadien-4-one
Peak:m/z	Relative Intensity
66.9771805	0.04
84.9746323	3.91
99.0304413	0.28
108.9614105	0.08
110.8906403	0.19
119.1152802	0.22
121.1343536	0.36
124.9038239	0.12
126.9907990	0.21
131.0016022	0.26
139.0890198	0.05
143.0034027	0.71
145.1628876	1.34
148.9815674	1.54
162.9654999	1.95
165.2473602	0.08
167.1316223	3.77
169.0723419	0.06
172.9284363	0.09
179.1358337	0.56
181.0016022	0.03
182.5901642	0.13
189.2463684	0.07
191.0355988	35.78
191.6745758	0.08
195.0211334	0.09
197.1537628	0.44
205.8661346	0.04
209.0621033	100.00
215.1257782	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
118.9878693	0.23
166.9472656	0.39
171.2576599	1.50
185.1950836	1.31
187.3208923	0.20
195.0920715	0.46
199.3623047	2.02
201.1197205	0.95
215.0333557	1.15
225.2324829	1.58
239.1345215	0.50
241.208252	0.11
243.2018433	2.67
257.3338623	0.26
260.2221375	0.57
260.9111938	0.60
263.1344299	0.97
269.0980835	0.28
271.3081665	0.30
280.0673828	0.74
285.401062	5.61
295.2558594	1.22
297.4689026	1.03
299.4359741	1.28
303.855957	0.25
309.2050476	0.88
310.6607056	1.60
311.3052979	9.51
313.2365723	7.63
313.9655151	0.82
315.274231	1.23
321.2719421	1.88
322.3932495	1.86
323.322876	6.83
325.3153381	0.43
329.2223511	1.03
331.0817871	0.82
335.4710693	0.56
337.3328857	0.62
339.2404785	100.00
339.9967651	1.61
341.1967468	13.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1142
Annotation	Lactulose
Peak:m/z	Relative Intensity
128.0400543	0.02
161.1149292	0.02
179.9853516	0.04
183.0445099	0.04
191.1054382	0.04
195.0909119	0.07
209.3701172	0.03
224.9403076	0.03
242.2332458	0.05
244.9816895	0.06
251.4216919	0.07
258.1086426	0.07
269.1518860	0.05
270.1208801	0.08
271.1227417	0.02
281.1403198	0.13
282.2891235	0.05
286.3072205	0.02
297.1408386	0.04
297.9488525	0.07
299.0051270	0.23
315.2301331	0.03
325.1438293	0.01
327.0513306	0.23
341.1386108	100.00
341.7512207	0.08
343.1037598	0.09
350.2264709	0.04
369.2982483	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	554.3311
Annotation	Unknow
Peak:m/z	Relative Intensity
224.7895355	0.03
260.4385986	0.01
274.7396851	0.01
278.5446777	0.01
294.1068726	0.02
296.3108521	0.02
310.4312744	0.01
311.3442383	0.19
312.3808594	1.02
327.1382446	0.02
330.3627319	2.10
348.2961426	0.04
354.2785645	0.04
366.1196289	0.02
372.3877563	0.07
376.4226685	0.08
378.2171021	0.04
388.4002075	0.20
389.3742676	0.87
390.4158325	1.59
392.5056763	0.06
403.3861084	0.02
404.4193115	0.02
406.2825317	0.67
408.3275757	100.00
408.9537964	0.73
412.6276855	0.02
420.0058594	0.05
420.9035034	0.03
422.3918457	0.11
431.7815552	0.03
440.3152466	0.47
448.3315430	0.06
450.3179932	0.53
450.9368286	0.01
474.4982910	0.06
476.0678711	0.03
477.5154419	0.03
492.9229736	0.04
494.5547485	0.11
499.2482300	0.07
500.4524536	0.10
512.1612549	0.02
512.8017578	0.02
518.0108032	1.08
518.6129761	2.88
535.3515015	1.13
536.3970947	2.80
537.0860596	0.01
555.3103638	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	639.3593
Annotation	Unknow
Peak:m/z	Relative Intensity
205.0471191	0.06
221.2007446	0.23
227.1409302	0.03
253.2702942	0.05
254.9818878	0.32
257.4553223	0.07
258.4106445	0.06
292.0392456	0.07
297.2229004	0.24
310.2114258	0.21
315.9874268	0.21
317.2992554	0.19
325.5552368	0.11
327.4888306	0.15
345.2777710	0.05
347.4708862	0.11
351.4660034	0.14
352.2741699	0.17
359.4891357	0.09
363.2362671	0.22
369.3105469	0.04
393.2744751	0.08
399.6958618	0.14
409.9866943	0.13
415.3197632	0.88
417.3499146	29.54
418.4022827	9.31
420.4421387	0.08
432.4178467	0.05
433.7526855	0.10
441.2124634	0.72
442.4550781	0.36
446.2231445	0.17
447.5574951	0.06
455.8150024	0.40
459.4103394	1.73
460.5316162	0.43
462.3499756	0.05
463.4609985	0.12
466.8045044	0.07
470.5232544	0.05
477.3822021	3.72
478.4414062	0.97
482.6688843	0.14
483.5911865	0.14
484.2738647	0.09
502.4398193	0.07
511.4074097	0.06
513.7241211	0.04
520.4584351	0.14
525.3654785	0.06
554.3678589	0.49
556.1065674	0.14
561.5045776	1.43
562.4340210	0.29
566.7742310	0.09
568.4096680	0.08
577.0884399	0.73
578.0350342	0.20
579.4023438	38.98
580.5182495	14.34
581.7270508	0.03
583.8474121	0.16
585.0592041	0.13
593.9301758	0.25
596.6123657	0.13
597.4658813	0.10
603.3955688	5.34
604.3613892	2.95
605.0242310	0.07
608.6273804	0.11
621.4713745	100.00
622.4929810	39.01
623.2627563	0.32
624.9988403	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	520.2678
Annotation	PS(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
151.0253754	0.12
152.9675751	8.12
161.8023376	0.20
170.9920654	0.42
175.9104767	0.16
197.8862610	0.10
240.1159821	0.10
246.0233765	0.26
249.2573547	0.23
263.0922852	0.10
265.2194824	0.04
290.8912964	0.10
296.0769653	0.07
342.9403687	0.19
371.4602051	0.15
374.4976196	0.25
380.0264282	0.08
392.4563599	0.09
399.1860962	0.17
407.8889771	0.07
410.1837158	0.04
412.5620117	0.20
420.2689209	0.19
425.6592407	0.20
427.2678833	0.15
428.7012329	0.06
433.4058228	100.00
434.1466675	0.05
441.4076538	0.17
443.5759277	0.35
444.3836060	0.12
446.2816772	1.49
447.4837036	0.05
448.3297729	1.32
449.3445435	0.09
452.4006348	0.44
456.9594727	0.12
459.4128418	0.07
465.6673584	0.25
472.5520630	0.06
474.1111450	1.45
475.5973511	0.28
476.2911377	0.19
477.0233765	0.06
477.8043213	0.17
478.8964233	0.21
482.2088623	2.60
484.1992188	10.41
485.0679932	1.09
489.5618286	0.11
501.3673096	1.10
502.5818481	1.16
503.5715942	0.39
504.5648193	0.14
520.1067505	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.1357
Annotation	Herbacetin 8,4'-dixyloside
Peak:m/z	Relative Intensity
169.2045593	0.10
178.9276733	3.98
191.0376587	1.02
195.0933685	0.25
197.2500305	0.66
198.9989929	0.32
209.0221252	0.54
210.2270508	0.17
213.3248291	0.41
215.0349426	0.09
217.0450287	1.66
223.1756592	0.42
224.4188232	0.29
227.1791992	1.42
229.1083221	2.34
237.0701294	0.38
239.0880127	1.50
240.0943451	0.34
240.9380341	1.45
253.1047211	0.56
255.0637817	24.77
256.0540466	2.73
257.1555176	13.49
259.0889282	0.22
267.1091919	0.61
269.3001404	0.23
271.1369324	0.30
277.2092896	0.33
281.1657104	4.48
282.1748657	0.71
284.0485229	100.00
285.0538330	87.26
286.1640625	1.66
287.3262329	0.35
295.1071472	0.90
297.3129578	0.57
298.4417725	0.77
299.3068237	0.50
305.0894775	1.40
306.1691284	0.32
307.0443726	0.17
309.1668091	3.72
311.2322388	1.48
313.4075623	0.41
319.0652466	0.22
323.3997803	0.49
326.1127930	3.41
327.1405640	13.92
333.3046875	0.97
335.8257446	0.19
337.1930542	0.17
338.6644897	0.11
339.2796631	1.19
341.2480469	1.21
349.0895996	2.24
351.1154175	3.95
353.1811523	2.35
355.1926270	0.17
357.3303833	17.34
358.9649658	0.11
365.1414795	0.78
369.2971191	1.00
371.2011719	0.80
373.0142822	0.38
375.0447998	0.16
381.3261108	1.79
383.4975586	0.49
385.1489868	0.59
387.4370117	0.72
393.2675781	3.75
399.2493896	1.71
400.2789307	0.13
401.2431641	0.41
402.9561157	0.65
404.5072021	0.19
405.5228882	0.14
410.6555176	0.31
411.2737427	2.71
415.1290283	1.90
416.2080688	0.85
417.3447876	2.22
418.7915649	0.34
423.2001953	0.12
427.9823608	0.14
429.1925049	95.35
430.1250610	0.72
431.1213379	1.95
441.3773804	0.52
447.1781006	26.42
459.2385254	7.05
465.2173462	0.36
475.1661987	0.45
490.9915771	0.36
491.6283569	0.88
501.1521606	0.86
511.1301880	0.46
517.3499146	3.80
518.0050659	0.72
519.3215332	13.08
532.3377686	0.32
533.2659302	1.21
543.1793823	0.79
551.2672729	0.36
559.9317017	0.15
561.4097290	6.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.2391
Annotation	14,15-Dihydro-15-hydroxy-3-epicaryoptin
Peak:m/z	Relative Intensity
143.1590881	0.07
160.9134674	0.16
178.9072266	1.12
273.3803711	0.02
285.7496948	0.10
299.2687683	0.13
303.1637573	0.03
309.0339966	0.04
314.1105957	0.04
316.8889771	0.04
329.2746582	1.15
342.4593506	0.01
345.6408691	0.04
347.3488770	100.00
348.1470947	0.04
361.4723511	0.31
365.4434204	0.10
373.1983643	0.01
377.3583374	2.12
379.8525391	0.09
389.2944946	11.49
393.3274536	0.11
399.3702393	0.01
419.2996216	0.45
421.1959229	0.09
422.6986084	0.05
429.5462036	0.09
431.1073608	0.05
434.7890625	0.01
439.0822144	0.08
449.2082520	1.27
451.4096680	0.02
462.0411377	0.06
463.0313110	0.35
464.3788452	0.03
465.3985596	0.11
467.1513672	0.05
470.3555298	0.06
471.2332153	0.04
472.9494019	0.43
473.9187012	0.01
490.6317749	0.13
491.5001221	0.09
493.3289795	0.10
494.2201538	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	641.1689
Annotation	Nervilifordin C
Peak:m/z	Relative Intensity
198.2162933	0.06
243.2618408	0.05
255.4163971	0.16
256.7810974	0.18
261.1275024	0.20
268.2670288	0.04
271.0428467	0.13
274.0651550	0.57
284.9684143	0.08
288.9919128	0.17
297.5746460	0.16
302.2201538	0.43
315.9253540	0.15
317.1528625	100.00
320.8313293	0.05
329.4683228	0.07
331.2242432	0.11
333.3356323	0.48
341.0266113	0.30
355.9064331	0.02
359.1376343	2.11
361.0168457	0.14
375.3427734	0.03
383.1751099	0.24
396.4713135	0.03
413.1812744	0.56
424.1921387	0.17
425.4224243	0.19
429.2052002	0.22
442.4385376	0.05
443.1926880	0.47
444.0817871	0.13
458.2407837	0.16
461.2221069	2.03
476.4821167	0.05
478.5305176	1.98
479.1326294	16.93
485.3894043	0.15
495.2198486	0.08
503.6480103	0.03
505.3323364	0.08
507.4472046	0.04
509.4701538	0.03
521.0252075	0.04
522.3536987	0.06
526.5317993	0.10
533.3261719	0.33
548.3269653	0.14
551.0533447	0.47
552.5548706	0.04
558.1657715	0.08
559.3682251	0.10
564.1220093	0.30
578.2756958	0.42
587.2931519	0.07
596.5559692	0.13
605.1682739	0.42
622.3277588	0.59
623.2644043	1.04
624.3338623	0.06
632.4668579	0.13
636.2402954	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.219
Annotation	Unknow
Peak:m/z	Relative Intensity
151.8410645	0.02
187.3278503	0.04
193.1254272	0.03
198.1054993	0.04
207.8044434	0.01
211.0490265	0.01
214.4312897	0.02
232.2554932	0.02
241.1430664	0.25
254.1408691	0.11
272.1970520	0.37
288.0428162	0.09
294.1049500	0.05
306.1640930	1.61
307.2609863	0.70
308.8287659	0.03
314.2477722	0.06
323.0968628	0.15
338.1520996	0.03
339.2221375	0.24
354.5195923	0.16
373.2858276	0.07
376.2347412	0.05
381.4353638	0.12
397.1231384	0.03
409.3121643	0.02
411.3447571	0.09
425.2119446	0.07
426.1192322	0.08
427.7283936	0.03
437.3437805	0.03
438.3078613	0.13
447.1899719	0.03
453.2855530	0.02
455.3060608	100.00
456.3772583	0.14
457.4599609	0.10
458.0675354	0.06
462.5428162	0.04
463.3326416	0.52
465.0009460	1.00
465.7682190	0.08
467.5389709	0.08
481.0877380	0.04
482.7707825	0.32
483.4606323	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.1093
Annotation	Pratensein 7-O-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
172.8967133	0.61
179.1531067	0.37
191.0883484	15.46
193.0881805	0.56
203.3102264	0.06
209.0630341	1.16
219.2951050	0.24
223.0718842	0.29
229.1105347	0.12
240.9238586	0.16
261.2810974	0.28
275.1910400	0.12
291.1154480	0.04
293.2900085	0.23
305.0376587	0.45
309.1529541	2.21
311.2215576	0.08
313.4682007	0.10
319.1152344	0.07
323.2379150	0.71
327.3557739	0.26
328.3065796	0.19
335.0772095	4.53
338.1505737	0.06
339.0071411	0.29
342.3150635	0.13
344.3696899	0.05
348.1945190	0.24
349.2229004	0.29
353.0974731	13.60
355.0177002	0.16
367.1047363	13.42
371.0651245	5.90
371.6825562	0.07
373.5145264	0.51
383.3433228	0.20
385.1195068	100.00
386.0786133	0.23
387.4927979	0.14
397.3990479	0.04
401.8324585	0.25
403.2216797	0.48
409.2759399	0.06
413.4512329	0.11
414.4270630	0.22
415.9224243	0.10
424.9581909	0.14
431.3179932	0.52
432.3375244	0.18
449.0755615	0.20
450.8759155	0.08
451.5352173	0.16
454.0685425	0.18
461.4619751	0.62
467.0563354	0.10
468.4496460	0.13
473.4306641	0.28
481.3406982	0.18
484.4613647	0.19
485.2764282	0.17
495.3782349	0.10
499.9310303	0.09
501.2078247	1.50
503.0941772	1.85
508.4138794	0.11
511.5803833	0.07
516.4569702	0.20
517.2706909	0.05
529.0206299	3.67
529.8227539	0.06
532.2654419	0.21
537.2837524	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1658
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
112.9912491	1.21
119.0703812	2.33
129.0894775	0.20
131.2167969	0.09
142.9807587	1.71
144.8274994	0.49
146.9916840	0.22
148.4526367	0.40
149.0684509	0.23
161.0345764	1.48
163.1343079	63.41
178.7790070	0.38
181.6075592	0.30
191.0941772	1.23
192.1941223	0.52
207.1040955	100.00
211.0787354	0.40
222.9876404	0.26
224.3375244	1.74
225.2102051	5.28
237.0152588	0.26
249.1340637	0.27
251.1217041	0.32
267.2093201	0.60
287.2189941	1.14
315.3814697	0.09
341.3753052	0.28
343.2369690	0.35
350.0289917	0.36
355.1084595	0.29
369.3136902	21.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	678.477
Annotation	Unknow
Peak:m/z	Relative Intensity
193.1182556	0.03
209.0314026	0.06
211.0104370	0.26
217.3332825	0.17
221.0968018	0.98
223.2427673	0.12
235.2268982	0.41
237.1172180	0.13
243.2075500	0.26
245.0866089	0.05
247.1084900	0.71
253.0736389	0.02
255.1344299	0.82
259.2583313	0.09
262.6211243	0.56
265.0242004	1.19
267.2228699	0.03
270.9931641	0.28
273.2734070	0.22
278.9641724	0.78
281.1726074	0.04
289.1277466	0.14
291.1661987	3.86
297.0335083	0.25
299.0875244	0.75
305.1549377	0.23
306.6864624	0.14
309.0374146	2.38
310.9308167	0.20
315.2407227	0.10
317.2685547	1.49
319.2510681	0.17
320.0055542	0.10
323.0364380	0.54
327.6000366	0.06
333.3569031	0.08
335.1408691	3.02
341.1785889	0.17
343.2863770	0.05
349.1112061	0.07
352.1759644	0.17
353.1223145	1.54
359.2492065	0.17
361.3472290	0.37
367.3790283	0.24
379.1192017	1.11
385.4442139	0.03
387.4434204	0.28
397.2449341	0.53
403.1610107	0.12
405.0844116	0.17
407.2677002	0.11
411.3612671	0.54
422.6173706	0.23
423.2456665	0.08
425.2672729	0.29
429.2200928	0.20
441.2014771	0.51
447.3165894	0.25
449.0995483	0.21
459.4710083	0.10
467.0286865	0.90
469.4122925	0.38
485.1417847	0.82
491.2871094	0.24
511.1088257	0.18
513.3336792	0.06
529.1891479	0.88
535.3556519	3.07
536.5730591	0.06
548.8740845	0.05
555.1621704	0.33
557.2212524	0.06
573.3298950	3.08
599.0807495	0.22
599.8156738	0.03
600.4581909	0.11
617.3317261	2.27
625.6304321	0.25
642.8180542	0.51
643.5321045	0.06
647.8339233	0.09
652.3501587	0.07
653.6842651	0.22
661.3091431	100.00
662.0247192	0.57
677.1906738	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	538.93
Annotation	Unknow
Peak:m/z	Relative Intensity
282.2988586	0.10
296.8201294	0.08
311.1862793	0.08
315.6320190	0.19
341.2010498	0.09
353.0322876	0.22
422.8487549	0.30
424.9652100	10.44
425.8865967	1.07
430.0141602	0.07
433.3717651	0.44
437.4444580	0.30
441.9712524	0.23
442.7687378	0.87
443.8877563	0.99
463.1208496	0.35
466.0538330	0.22
467.0523071	0.65
480.3521729	0.43
481.1925659	0.51
483.0704956	0.30
484.0713501	0.07
491.3058472	0.34
492.9713745	100.00
494.0916748	10.30
494.9709473	0.49
503.9539795	0.72
504.8826294	0.08
510.8264160	42.85
511.8949585	5.32
514.0370483	0.12
516.5576172	0.30
524.6280518	0.23
528.1491089	0.16
529.5209351	0.25
530.7214966	0.16
539.4707642	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.114
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
113.0514603	0.25
126.6971359	0.03
129.0378265	0.02
135.0167389	0.06
136.8638000	0.02
147.0870209	0.16
154.8518982	0.01
172.9688721	0.02
174.8273163	0.07
179.2190552	0.08
187.0094604	0.03
189.0742493	0.02
191.0587158	3.37
200.2876282	0.01
202.2803040	0.03
203.3118134	0.03
205.3792114	0.06
206.1416016	0.01
208.9467773	0.53
221.9176025	0.06
223.2169495	0.35
231.2340698	0.20
240.8709412	0.05
245.1485901	0.04
249.1244812	7.14
255.2048645	0.04
257.1181946	0.10
260.3225098	0.05
264.9367371	0.05
267.1762085	100.00
269.1304932	0.19
276.0832520	0.04
278.2120972	0.05
279.3970337	0.02
289.0225525	0.01
291.0657654	0.01
297.1671753	0.08
298.4582520	0.03
303.1763306	0.02
307.3009949	0.15
313.1284180	0.04
323.3489075	0.08
325.5259399	0.03
327.1486816	0.05
337.0827637	0.06
338.1781921	0.28
339.2410889	0.41
340.5273132	0.07
341.2504883	0.11
342.1508789	0.03
342.7700195	0.05
346.3306885	0.03
347.4876709	0.04
348.2828369	0.05
349.2580566	0.02
350.2252197	0.05
353.4917908	0.04
354.3522644	0.02
356.8080750	0.02
364.2416687	0.01
366.1069641	0.19
367.1457214	1.37
370.2839050	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	589.0502
Annotation	Unknow
Peak:m/z	Relative Intensity
173.0797729	0.54
216.9885254	100.00
218.0302277	4.41
223.3099060	0.08
243.2802429	0.03
285.2999573	0.03
287.0470581	0.03
300.1759033	0.08
315.7006836	0.41
367.2515259	0.05
395.0208740	0.07
409.2777710	0.12
411.3058472	0.05
416.3852539	0.17
425.4262085	0.02
427.2854004	0.09
443.2086182	0.30
449.1415405	0.08
451.1658325	0.83
452.0741577	0.15
469.1881104	0.08
480.2543945	0.03
484.1527710	0.03
491.2213745	0.15
496.9424438	0.03
498.0317993	0.14
503.4060669	0.06
518.1610718	0.08
533.1637573	0.13
544.0424805	0.10
545.5779419	0.36
546.5733032	0.33
571.2051392	1.25
572.2728271	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	479.1176
Annotation	Pedaliin
Peak:m/z	Relative Intensity
155.0389099	0.12
171.1654663	0.14
178.7445068	0.03
216.3164978	0.06
218.1947021	0.01
222.1714783	0.02
229.0914154	0.08
231.0667725	0.04
235.1292419	0.07
251.3846741	0.02
261.3074951	0.03
271.1900940	0.19
279.3087158	0.03
295.1130066	0.01
297.2018433	0.05
298.3963318	0.03
299.0720825	0.03
302.9802856	0.05
312.2144165	0.02
314.1290588	0.03
314.9648438	0.03
317.0985107	100.00
317.9511719	0.06
349.1517029	0.03
352.9047852	0.07
359.2667847	0.37
362.9535522	0.03
371.0539246	0.02
375.2191772	0.19
377.1027832	0.17
383.1974792	0.06
390.1502991	0.04
391.1506653	0.07
393.2683411	0.01
397.5125427	0.27
400.3732605	0.13
401.1617126	0.04
404.2776489	0.11
405.2024536	0.02
406.5205688	0.04
413.1642151	0.20
415.2066040	0.06
417.3679199	0.05
418.5837402	0.21
424.4464111	0.02
425.2752991	0.18
433.2568970	0.10
434.1755981	0.07
434.9777832	0.13
436.9510193	0.10
442.9414978	0.16
447.1980286	0.05
448.2078552	0.01
450.7068481	0.02
461.1352844	1.58
462.6958923	0.09
469.2897339	0.27
470.0664673	0.14
479.3296204	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.0826
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
102.9436035	0.05
124.7796631	0.06
136.9814453	1.78
149.9474487	0.05
165.0669250	0.20
181.1285858	0.15
181.9788208	0.18
183.2631073	0.13
193.2064667	0.04
203.0397186	0.12
205.1872406	0.10
209.1774139	0.18
217.1375427	0.13
225.5154724	0.14
229.1095886	0.31
252.8460388	0.05
255.0852356	0.23
261.2405396	0.12
273.2874756	0.05
275.3178101	0.10
277.2997131	0.29
283.0632019	0.55
297.5638733	0.06
299.0693054	100.00
300.3896179	0.60
301.6719360	0.44
302.4643555	0.06
309.0891724	0.07
317.3137512	0.10
327.1250916	0.80
330.5156250	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	584.3567
Annotation	25-Cinnamoyl-vulgaroside
Peak:m/z	Relative Intensity
175.0546417	0.02
177.1495514	0.12
207.0945740	0.01
208.0505371	0.02
219.3054199	0.02
220.9445496	0.04
224.9777832	0.06
227.1953125	0.02
235.3069000	0.01
244.2893066	0.02
251.3896027	0.05
253.3661346	0.02
255.1323853	0.02
256.9239197	0.02
261.2090149	0.01
265.0130310	0.21
266.0483398	0.03
269.1931152	0.16
271.1625061	0.04
273.6017456	0.02
283.3381348	0.01
295.3915405	0.03
296.2648926	0.01
308.1323853	0.01
309.1437988	0.02
311.2655029	0.06
313.1697693	0.07
315.3171387	0.05
327.1533813	0.01
329.3396606	0.02
331.1128540	0.05
337.3823853	0.01
339.2590942	0.01
341.1276855	0.02
350.4158325	0.02
355.2142944	0.09
357.1005249	0.16
359.3680420	0.37
367.2278442	0.02
373.2899780	0.57
375.0837402	0.12
382.3847046	0.02
399.1558838	0.02
401.1195679	0.07
402.8161011	0.03
411.5832520	0.02
417.2033691	0.19
419.2427368	0.05
430.0507202	0.03
445.4623413	0.18
458.2189941	0.04
461.2222290	0.10
463.2052002	11.33
463.8832397	0.11
468.0858765	0.01
473.6137695	0.01
479.0524902	0.46
479.9075928	0.02
489.3708496	0.02
491.4439087	0.03
499.3378296	0.01
505.2678223	0.02
513.6126099	0.03
520.8803101	0.02
521.5291138	0.04
523.1176147	0.06
523.7365723	0.01
525.3170166	0.03
530.9462280	0.02
535.2600708	0.03
537.5791626	0.05
538.6648560	0.06
539.3310547	0.02
540.0085449	0.02
542.7664185	0.06
546.3455200	0.00
547.5015259	0.01
548.9749146	0.38
554.4759521	0.03
565.5050659	0.07
567.2197876	100.00
567.9357300	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	458.77
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9012299	9.30
213.1024780	0.22
285.1131897	0.22
290.7241516	100.00
291.3378296	0.34
338.5687256	0.47
374.0868225	4.43
374.7415466	28.13
398.8707581	3.26
428.8627319	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.1612
Annotation	Maltotriose
Peak:m/z	Relative Intensity
161.0439758	100.00
164.9607086	0.92
179.0287476	6.79
205.2313538	1.38
216.2625885	3.73
221.113678	11.19
222.2636871	1.00
250.5439148	1.58
281.03479	2.85
311.3488159	3.65
315.0249329	1.20
318.2810669	1.14
322.7045898	1.08
340.5934753	1.17
341.2633972	7.67
342.5169983	2.07
348.8909912	2.40
353.1899414	1.47
359.1434021	4.03
363.1590881	0.96
370.3323364	3.20
373.8382874	1.56
378.4753418	4.52
386.2808228	2.91
387.136322	3.71
398.069458	1.02
441.0710144	0.76
443.8300171	1.68
457.0491943	2.52
467.3127136	3.18
471.2780457	1.22
475.1438904	3.85
485.2851257	8.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	275.102
Annotation	(1xi,3S)-1,2,3,4-Tetrahydro-1-methyl-beta-carboline-1,3-dicarboxylic acid
Peak:m/z	Relative Intensity
94.0033798	4.30
137.9362793	100.00
138.5559998	0.72
151.9530792	40.85
155.9467773	0.05
184.9652863	0.11
187.1312561	3.84
199.8854980	0.15
213.0071411	0.20
228.9123840	0.27
231.0386963	17.98
234.0446167	0.10
244.7661438	0.09
248.4617004	0.06
257.1114197	0.08
265.9440918	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	605.2409
Annotation	Phaeophorbide b
Peak:m/z	Relative Intensity
221.9627228	0.03
237.3664856	0.03
239.1568909	0.11
254.8353577	0.06
255.4594421	0.03
274.1752319	0.02
276.9213562	0.02
277.5748596	0.07
286.1298218	0.05
297.3660889	0.02
311.0550232	0.05
313.3104248	0.04
323.4638672	0.02
325.3134155	0.02
334.0632324	0.02
339.7304688	0.10
341.1176147	0.06
343.5329590	0.07
361.3535767	0.05
365.6036987	0.03
379.2512207	0.10
396.2146606	0.06
401.0994873	0.05
406.3419189	0.07
412.7009888	0.05
417.0598145	0.03
420.6372070	0.03
425.4277344	0.02
431.5883789	0.06
432.3944702	0.20
435.9016113	0.03
453.4130249	0.08
467.3101196	0.02
479.5134277	0.04
488.5456543	0.02
491.6230469	0.03
492.8677368	0.06
494.8274536	0.05
498.5087280	0.03
499.5104370	0.03
502.6795044	0.03
504.0314331	0.14
504.9979858	0.01
517.3001099	0.03
519.2059326	0.05
521.3129272	0.14
524.1779785	0.32
525.3667603	0.23
527.7454224	0.07
529.3028564	100.00
530.0209961	0.18
530.7055664	0.03
531.4874878	0.14
532.3769531	0.07
533.3207397	1.14
534.5641479	0.21
536.3943481	0.03
543.4168701	0.17
546.2332153	0.20
548.7404785	0.08
549.5974731	0.12
551.0615845	0.43
551.6666870	0.10
560.4763794	0.15
561.4388428	1.50
562.8303223	0.07
563.7553101	0.11
567.4264526	0.18
568.6671753	0.11
569.3487549	0.29
571.5635376	0.07
573.1514282	33.37
573.7787476	0.62
575.0099487	0.02
577.2080688	0.13
579.9758911	0.03
586.8101196	0.73
587.4747314	0.67
589.9766846	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	405.0496
Annotation	1-O-p-Coumaroyl-(b-D-glucose 6-O-sulfate)
Peak:m/z	Relative Intensity
117.1721115	0.01
119.0298996	0.26
126.1692734	0.02
127.9059448	0.04
143.2148895	0.04
146.2527161	0.04
159.1146240	0.05
161.1736450	0.06
162.9873047	2.37
167.0103912	0.41
177.2487488	0.02
179.0362854	0.11
181.0991821	0.02
210.0980682	0.02
223.0625305	0.05
225.2326202	0.01
226.0723572	0.06
227.0781860	0.02
236.0681152	0.04
241.0391846	100.00
242.0606079	0.40
243.0845947	0.02
251.0640869	0.04
253.2033386	0.02
254.1247864	0.55
259.1069336	0.82
267.0594788	0.13
272.1436768	2.00
280.2005005	0.02
281.3147583	0.03
288.0117188	0.10
306.1466064	3.28
307.2994080	0.01
323.2113037	0.02
325.2492676	0.02
327.4611206	0.01
333.3235168	0.03
344.1118164	0.03
345.1846924	0.03
357.9432068	0.07
359.0316467	4.03
359.8688965	0.09
361.1562195	1.84
370.3220520	0.01
372.3007507	0.07
373.2265625	0.01
376.6795044	0.18
377.3138733	0.05
386.4026184	0.04
387.1871033	0.32
388.9902039	0.07
403.3864441	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1345
Annotation	Olanzapine
Peak:m/z	Relative Intensity
161.1138306	0.58
165.2519989	0.05
170.8305969	0.08
175.0967712	0.57
183.0836029	0.31
184.0765381	0.20
184.9647369	0.05
189.0427094	1.83
216.2119141	0.11
220.9270935	0.42
222.3086243	0.14
225.2695923	0.16
233.1626587	0.17
250.9737244	0.07
258.2859497	0.21
265.1673584	100.00
267.2133179	0.31
292.3023682	0.71
293.2162170	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	333.0233
Annotation	Chlorphoxim
Peak:m/z	Relative Intensity
205.3871765	0.06
217.1215515	0.05
230.7878113	0.17
246.7942810	0.02
256.1952209	0.05
259.3088989	0.07
261.0612183	0.20
263.1671143	0.03
269.1358643	0.01
277.2199707	0.11
287.0531006	100.00
288.0195312	0.24
289.1804504	0.27
297.5218811	0.05
305.1596069	1.30
314.2925110	0.10
315.4696960	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	388.2533
Annotation	Gln Ile Lys
Peak:m/z	Relative Intensity
132.8877258	0.06
170.2866516	0.03
179.2046814	0.09
201.2601624	0.15
207.0866241	0.08
208.3417969	0.18
209.0708313	0.10
221.0177002	0.06
226.7316895	0.07
251.8416748	0.02
264.9316101	0.19
282.4631042	0.09
283.3113403	0.07
304.3273621	0.17
325.4311218	0.36
326.2706909	0.04
327.3148804	0.17
335.2642212	0.03
341.9165039	0.13
344.3864136	0.08
347.0238037	0.21
352.3004456	0.35
353.1620789	0.24
360.4273987	0.09
369.435791	0.26
371.2377625	100.00
371.8396301	0.30
378.7507629	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	417.2633
Annotation	3alpha-Angeloyloxy-18-hydroxy-ent-labd-8(17)-13dien-15,16-olide
Peak:m/z	Relative Intensity
169.3466187	0.12
174.9863281	0.11
176.9794312	0.19
193.9989624	0.08
205.1416321	0.12
206.9745026	0.12
208.9846649	0.21
220.8670044	0.11
221.9487305	0.15
223.5064392	0.10
227.1249695	0.04
237.0246582	0.13
244.1688843	0.20
253.4823608	0.19
255.0033875	0.04
267.5863647	0.10
269.1108398	0.15
273.1599426	0.21
273.9777832	0.16
283.0710449	0.04
288.3027344	0.16
289.1699829	0.15
295.2466736	0.18
296.2971497	0.07
301.0605469	0.11
305.1467285	0.11
309.3432617	0.05
311.3344421	0.16
312.1409607	0.20
313.2216797	0.16
315.1160278	0.10
316.1763611	0.07
316.9122620	0.08
317.5637512	0.92
328.1320801	0.05
329.0618896	0.19
334.0848694	0.17
343.0900269	0.11
343.7381592	0.21
347.3562012	0.07
351.2459106	0.21
354.1591797	0.14
355.4777222	0.37
358.1283569	0.52
358.9862061	0.09
361.2479248	0.10
362.2807617	0.18
363.0543518	0.07
369.1409607	0.08
371.0869446	0.03
371.9454346	0.33
376.4365234	0.09
381.3500061	0.21
382.2257080	0.20
386.1473389	0.07
387.2848816	0.42
389.2531738	0.22
399.4678345	1.33
400.2893372	0.45
402.7284851	0.09
408.8917236	100.00
410.4807434	0.16
411.1362915	0.24
412.8302307	0.24
413.6151733	0.33
414.5365295	0.23
415.3848572	0.13
416.8005676	0.15
417.6126404	0.10
424.8342590	0.22
476.5868530	0.24
503.2812805	0.11
504.4318542	0.08
517.1592407	0.19
518.4112549	0.03
547.5000610	0.34
552.6019287	0.21
564.5741577	0.14
579.6201172	0.04
597.2761841	0.06
608.5168457	0.30
609.4817505	0.06
622.8090210	0.07
640.3461304	0.39
641.5952148	0.63
684.5692749	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	739.16
Annotation	Unknow
Peak:m/z	Relative Intensity
211.1056671	0.07
217.1551514	0.04
241.1704102	0.50
259.1791382	0.03
280.1655579	0.03
299.1931763	0.05
315.3958130	0.08
323.1625366	12.88
324.1627808	0.09
331.3475342	0.02
341.1297607	0.02
350.2461548	0.02
350.9552307	0.02
359.0574951	1.05
365.2092896	0.18
376.9715576	0.55
390.8387451	0.54
430.9123535	0.07
441.1002808	0.65
442.7750854	0.08
459.0167847	2.71
470.2208252	0.03
477.0576172	0.19
482.9943237	0.75
494.2424316	0.20
494.9961548	1.78
497.1482544	0.15
507.9882202	0.05
516.2896729	0.04
521.2898560	0.05
526.3597412	0.03
527.2005005	0.18
541.9744263	0.06
550.7533569	0.01
554.5209961	0.04
558.2721558	0.05
559.0282593	0.06
560.1222534	0.33
562.0293579	0.06
564.3442993	0.94
564.9721680	9.97
570.6238403	0.02
574.8598022	0.02
575.9401855	0.02
577.0678101	0.49
578.9678345	0.04
583.0208130	0.12
583.7813110	0.36
585.2102661	1.28
587.0104370	0.02
603.1528320	100.00
604.2118530	0.54
607.0404663	0.04
619.0886230	0.21
627.3014526	0.05
641.0404663	0.58
646.8348999	0.07
658.4935913	0.09
666.9182129	0.02
692.8656006	0.82
695.9688110	0.05
720.9746704	1.15
721.8593140	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.561
Annotation	Unknow
Peak:m/z	Relative Intensity
96.1111755	0.07
101.0175247	0.06
105.9269257	0.20
122.9692841	23.96
123.9531631	0.11
136.0672913	0.86
168.2900696	0.11
200.0978851	0.16
216.8670349	0.36
230.9706726	0.14
232.1561584	0.53
242.9988403	0.37
246.1595154	0.43
254.9382629	0.10
272.2755737	0.18
273.0773315	0.50
274.0343323	0.23
275.1672363	0.23
285.7413025	0.23
287.6989136	0.55
290.7890625	0.17
297.1017151	0.90
305.3630676	0.15
308.3011475	0.05
314.0429993	3.01
315.1661072	1.70
330.7649536	0.09
347.6261597	0.17
409.9754944	0.11
428.1894226	1.01
444.1488342	0.61
524.0914917	39.02
524.7706909	0.37
529.1646118	0.09
542.0717163	100.00
543.1121216	1.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	283.03
Annotation	Unknow
Peak:m/z	Relative Intensity
81.1045074	0.13
88.9423599	0.08
96.9547424	0.03
98.9457245	0.04
107.1519928	0.19
108.9374542	0.23
110.9388275	0.25
112.8305054	0.05
121.2482529	0.04
123.0208588	0.08
124.0191193	0.07
128.1634979	0.06
129.1071472	0.05
132.3504639	0.16
133.0349426	0.41
135.1351013	0.29
137.0855865	0.08
143.2887878	0.03
148.9890442	0.25
151.2123260	0.17
154.9828186	0.04
156.8507233	0.11
163.0363159	0.08
169.2694092	0.05
170.9002991	0.04
176.9553528	0.30
194.1510010	0.03
199.2233887	0.18
209.0572510	0.03
212.1498108	0.16
213.1015320	0.12
218.2149963	0.10
225.0530396	0.22
225.9746704	0.05
233.0982361	0.10
237.1659851	0.62
238.8628540	0.67
239.5017090	0.05
240.6275940	0.16
241.9435425	100.00
247.2546387	1.06
254.1193542	0.06
254.8864136	0.09
256.0032654	0.12
259.6929321	18.41
260.5266724	0.44
262.3628540	0.34
263.1544495	0.34
263.9776306	0.08
265.1652527	1.83
267.0986938	0.21
268.3252563	0.15
269.5615234	0.03
271.2706604	0.50
272.9274902	0.10
276.3455505	0.51
284.0009766	0.04
287.3830261	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	179.06
Annotation	D-Hamamelose
Peak:m/z	Relative Intensity
59.0176163	0.22
70.9634171	2.60
72.8180542	0.29
74.9528961	5.66
80.8432007	6.51
84.9465027	0.11
86.9504852	2.70
89.0061035	1.66
96.8633728	0.16
98.9396820	22.48
100.9619904	0.21
104.8969421	0.22
113.0693970	0.31
114.9124146	1.08
116.8565063	0.50
118.7909851	0.39
120.7224579	0.04
125.0126648	4.93
128.9140472	0.03
130.8990479	0.53
132.8854980	0.35
142.9428864	100.00
149.0546875	0.83
160.9948273	38.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	442.7354
Annotation	Unknow
Peak:m/z	Relative Intensity
129.0211945	0.17
129.9950714	0.22
143.0065613	1.88
144.7773438	0.28
168.9695129	0.65
171.0813141	0.78
173.1557159	0.57
185.0529480	0.32
186.7370148	1.19
189.0083618	4.61
190.3287354	0.51
216.0224457	0.30
219.9965057	0.33
223.9739685	0.14
234.1546936	0.42
236.4739685	0.17
237.1697235	0.41
241.8659363	1.80
248.1359558	1.65
249.1351013	0.11
254.1415710	5.72
255.2986450	0.74
256.2949219	0.09
264.2231140	0.14
265.6087952	0.37
266.2970886	4.54
267.2778625	0.51
269.2247925	1.62
272.0088806	15.73
273.1235352	2.00
274.9721985	0.79
280.9735107	0.92
281.7376404	0.67
282.5047607	0.08
293.2134094	6.06
294.3059692	0.50
296.1445312	0.55
299.5128784	3.82
300.1442566	25.54
301.1662598	4.85
302.1182251	0.11
311.3211365	0.13
312.4625244	0.62
313.4676819	0.24
317.2826538	12.48
318.2390747	4.99
319.5021362	0.25
323.0325317	0.48
324.9400330	0.64
327.0149536	0.50
330.7498474	0.36
331.8984985	2.12
335.8825073	1.15
339.7034302	0.70
341.2655640	2.98
346.0770264	0.23
348.4099121	0.24
349.7559814	7.81
350.4960632	2.94
351.3627625	0.45
352.9884644	0.72
361.3464966	3.43
362.3285828	0.19
365.3357239	0.63
367.3905945	0.43
369.2143860	2.40
370.3180847	0.25
373.4517517	2.00
374.3898926	0.83
378.5065002	46.92
380.1595154	0.67
380.9144897	0.61
382.2989807	0.52
383.0063477	0.91
383.6417847	0.15
384.8129272	1.35
387.4205627	5.54
388.3300781	0.27
391.2233582	61.04
391.9680481	24.68
392.7939453	0.85
396.4831238	31.95
397.2330627	8.51
398.2770081	2.04
399.3804932	0.16
401.5221252	0.65
404.5233459	2.33
405.4128723	100.00
406.3781433	8.75
408.1232605	0.22
411.1372375	0.69
412.3669739	0.73
413.1971130	1.56
414.7010803	0.57
416.0127869	1.52
418.9985657	2.77
419.8723145	0.81
420.5992432	1.10
421.4570007	2.25
422.5472412	0.76
425.0157166	34.81
425.9257507	4.17
428.2624207	1.09
428.8890076	0.30
431.2136536	5.64
432.3213196	0.53
434.0196838	71.20
434.9827576	6.15
436.5485229	0.60
454.3231506	20.77
455.2605591	4.15
456.4321899	0.73
481.4446106	0.21
482.2465515	0.37
492.4911804	3.25
493.3308716	1.85
494.4453735	0.56
510.3313904	7.62
511.5455933	2.06
520.2321167	0.12
534.2116089	0.07
538.5859375	0.45
540.3669434	1.09
541.4557495	0.59
542.1240845	0.13
550.4779663	3.65
551.2145386	0.51
568.1190186	17.81
569.3139038	5.31
570.3772583	1.38
585.3444214	64.55
586.3443604	17.66
587.3318481	5.23
590.3493042	0.20
606.4891357	0.24
619.3762817	0.92
620.3450928	0.33
624.2191772	0.09
627.6290894	0.19
653.6849976	0.13
660.5260010	0.58
662.6008911	0.72
663.4214478	1.37
670.7490845	0.11
678.3997192	1.52
679.1796265	0.23
680.1770630	1.45
680.8041382	0.96
681.8074951	0.77
682.8190918	0.50
684.5869751	0.58
696.4014282	54.36
697.3933716	23.08
698.4440918	7.02
699.4725952	0.69
722.3404541	0.51
725.6163940	0.07
740.3456421	0.38
755.5974121	1.96
756.4813843	1.51
757.6404419	0.33
785.6743164	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
79.98409271	0.52
84.96453857	0.81
105.1328583	1.06
123.1516571	1.05
124.9154968	2.83
129.9154663	0.36
139.0846252	0.37
143.0471191	0.99
149.0555725	2.31
150.9268036	0.34
152.907959	0.87
160.9262543	0.82
179.1265717	2.82
180.1813507	2.52
181.2494812	3.48
183.063324	7.14
193.1024017	1.38
194.1154022	2.23
195.1807098	0.34
207.2172394	20.71
208.1338348	2.60
209.2474976	0.54
214.9010925	8.44
222.1931305	4.71
223.1638031	11.41
224.4666748	4.36
233.1582489	3.37
235.2693481	0.91
236.3427887	0.61
251.0658112	100.00
251.9920807	11.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	252.0862
Annotation	N-Carboxyacetyl-D-phenylalanine
Peak:m/z	Relative Intensity
96.8526840	0.04
142.8213043	0.01
150.9769440	0.02
166.1071625	0.16
177.2191620	0.07
178.2295685	0.01
188.1865997	0.06
200.9214020	0.07
206.0097809	59.93
207.2485199	0.12
211.0379639	0.04
216.1247711	0.06
220.1104279	0.24
233.9188080	100.00
234.5311432	0.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	271.228
Annotation	2-hydroxyhexadecanoic acid
Peak:m/z	Relative Intensity
93.03772736	0.03
94.86607361	0.02
145.140213	0.04
155.0048065	0.05
164.2191925	0.04
177.3186493	0.06
181.217041	0.02
186.048111	0.04
191.2671204	0.08
193.1396179	0.18
197.1424561	0.10
199.3401184	0.03
201.3103027	0.11
209.1519928	0.40
211.0661469	0.03
212.3174286	0.05
215.0921783	0.05
223.2940369	0.51
225.2229614	100.00
226.3239441	0.07
227.1825409	0.83
231.1356812	0.04
235.0017242	0.08
239.1325684	0.08
241.3159332	0.02
242.5368042	0.11
243.1910858	0.23
251.4131012	0.03
252.1507111	0.19
253.2623749	5.24
254.781189	0.09
255.4009399	0.25
257.3614502	0.02
270.854248	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	182.0807
Annotation	4,6,7-Trihydroxy-1,2,3,4-tetrahydroisoquinoline
Peak:m/z	Relative Intensity
136.0346069	17.73
139.9770660	0.03
147.1196136	0.07
158.4660492	0.09
164.9509277	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.11
Annotation	Herbacetin 8,4'-dixyloside
Peak:m/z	Relative Intensity
173.0739594	0.08
178.9313660	0.22
186.9666901	0.27
190.9195251	0.03
201.0391541	0.10
203.0511475	0.06
204.9599152	3.85
219.1777344	0.10
223.0225372	29.01
223.6920166	0.24
247.0472717	0.43
273.0319824	0.09
290.9651794	0.38
323.1298218	0.54
341.0590820	0.17
348.8935547	0.40
353.0709229	0.09
358.2883911	0.04
367.1627197	3.40
385.0901489	100.00
409.0683594	0.23
411.4189453	0.08
438.9723511	0.10
485.5603638	0.15
497.1422729	0.30
503.2204590	0.29
511.1307983	0.06
525.4087524	0.07
529.1273193	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	581.1509
Annotation	Polygalaxanthone V
Peak:m/z	Relative Intensity
162.8780975	0.15
164.9908600	0.05
167.1359863	0.73
175.0350342	0.04
177.0748291	0.13
178.0878601	0.18
179.0827332	0.40
181.1237488	0.19
188.9617310	0.07
191.0652161	0.13
192.2414856	0.02
193.1254425	0.04
201.2208710	0.06
205.0296936	0.14
207.0473938	0.14
208.2480011	0.05
209.0257568	0.07
217.2023163	0.02
219.1443176	0.27
221.3096924	0.05
223.3749695	0.04
225.1207581	0.05
227.2613983	0.06
230.9969177	0.08
233.3372192	0.08
235.0124817	0.02
236.9979706	0.05
241.2130585	0.09
246.9307861	0.17
249.2027588	0.27
253.1193237	0.09
255.1103821	0.10
256.9921265	0.03
267.1369629	1.78
269.0253296	0.06
281.1555176	0.04
283.2386475	0.04
285.1797485	1.50
287.4018555	0.88
289.1148987	0.03
297.3480835	0.02
299.1962585	0.19
305.2583923	0.05
306.3071899	0.36
314.1370850	0.06
323.2674561	0.04
324.9985352	0.27
327.1445312	0.50
329.2638550	0.04
331.0387573	0.06
341.0835571	0.64
342.0986938	0.22
343.2217407	0.10
344.1945190	0.10
346.3182373	0.07
351.1715088	0.05
353.5722656	0.22
355.0106201	0.02
373.1939697	0.15
375.3187866	0.03
376.2566528	0.21
377.2758789	0.20
381.2136230	1.60
384.3252563	0.03
387.3089600	0.15
388.2684326	0.05
393.0244141	0.11
399.1712036	100.00
400.3037720	0.93
401.5256958	0.17
405.4746704	0.04
413.3101807	2.72
416.1986084	0.02
418.1892090	0.22
419.3410645	0.58
422.4113770	0.02
425.2319946	0.08
431.3920288	0.10
433.3453979	0.02
434.1304321	0.10
435.5474243	0.03
447.2319946	0.02
449.3698120	2.86
456.7763672	0.06
461.3347168	0.04
484.5673828	0.10
485.5494385	0.06
488.3334961	0.17
493.4064331	0.07
494.2053833	0.14
495.4045410	0.04
496.2562866	0.03
499.3632812	0.14
505.3672485	0.01
506.4555054	0.27
507.4458008	0.05
521.0574951	0.11
533.0847168	0.06
534.2027588	0.37
535.2645264	0.20
536.4670410	0.21
537.4876709	0.22
538.2900391	0.23
542.0250244	0.09
544.3185425	0.19
545.1127319	0.03
545.7996826	0.04
548.3121948	0.03
549.2717896	0.02
550.4560547	0.06
562.2356567	0.31
563.4606934	0.30
572.1134644	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.3305
Annotation	Unknow
Peak:m/z	Relative Intensity
168.9888458	0.06
186.9383545	0.06
225.1886749	0.02
243.8589783	0.05
253.0419617	0.01
279.1389160	0.54
285.2125854	0.05
299.0736694	0.08
360.0697021	0.03
391.1586914	0.03
392.6524658	0.04
450.4629517	0.04
468.2736816	0.04
469.5377197	0.04
473.0899048	0.12
474.5847778	0.06
475.2368774	0.08
477.3787231	0.03
480.7373047	0.07
500.2789917	0.03
501.4492188	0.04
504.3768311	100.00
505.3529663	0.30
508.4278564	0.01
511.2899780	0.08
517.4882812	0.03
518.1177368	0.01
519.3770142	0.12
520.5260620	0.01
527.1018066	0.05
528.1207275	0.19
531.2905884	0.09
536.1820068	0.01
541.9868164	0.11
545.9268799	0.11
546.6924438	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	353.2679
Annotation	[10]-Gingerdiol
Peak:m/z	Relative Intensity
105.1129608	0.12
107.1108704	0.46
108.9764481	0.80
111.2286072	0.16
112.9307709	0.11
114.9982452	0.04
117.0712128	0.39
119.2666168	0.38
120.9344864	1.41
123.0838776	2.04
125.4019470	0.04
127.1598434	0.50
128.9779358	0.18
130.9817657	0.61
132.8975677	0.67
135.0446930	1.42
137.0855408	0.37
139.1338501	0.47
145.0057678	0.76
146.9963531	0.70
149.0913391	2.01
150.9795990	1.27
153.1838074	0.78
157.1022644	0.32
159.0928650	1.91
161.1386719	1.54
163.1144867	4.80
164.9409790	0.44
167.0464172	0.21
168.4990234	0.10
169.1790771	0.06
171.1877747	0.31
173.1811676	2.62
175.1756134	0.35
177.1735840	3.61
178.8544922	0.75
183.1956787	0.67
185.0235138	0.10
187.1340485	0.99
189.1231384	0.67
191.1726990	1.10
193.0087891	0.36
194.8215790	0.18
196.9931641	0.27
199.0285645	0.17
201.0065918	0.99
203.4385986	0.60
205.0691528	0.93
207.2506104	0.66
209.1855316	0.78
211.2659607	0.06
213.0670624	0.26
215.2842407	0.58
217.2528381	0.74
219.4129944	0.36
221.8916016	0.10
223.1208191	1.18
225.3463745	0.35
226.5571899	0.12
227.2458801	0.42
229.2603149	0.31
231.1364441	0.68
233.2836304	1.80
237.0137939	0.55
239.3920288	0.04
241.3009949	0.22
243.2577209	27.34
244.1775818	0.21
245.3555908	3.52
251.3389282	0.22
253.1058960	0.29
253.7123108	0.08
255.1210632	0.05
256.9541016	0.19
259.0394592	0.59
261.2491455	100.00
263.1824951	3.68
265.1876221	0.46
267.1253357	0.75
269.0797729	0.13
270.9010010	0.12
273.0391235	0.05
275.3509216	0.06
277.3216553	0.42
279.2709961	8.99
281.2935791	0.48
283.0250244	0.33
287.2775574	0.36
289.5133057	0.29
291.3113098	0.46
292.3449707	0.04
293.0950317	0.04
295.4001770	0.50
297.2109680	2.56
299.2168884	1.10
307.0635986	0.04
309.3689575	0.14
311.2854309	0.83
312.0338135	0.17
317.3720703	5.12
325.1210632	0.21
329.2811279	0.13
335.2987976	59.37
336.1088562	0.81
343.8941956	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	273.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9688721	4.64
116.0037689	1.71
131.0552673	0.21
131.9814453	0.08
158.9190369	100.00
159.9081116	38.49
198.9653015	1.93
199.9869385	1.04
200.9805908	0.08
217.0661011	0.50
218.0235291	0.71
225.7645569	0.06
228.9118958	15.93
229.9877014	18.91
245.0505066	0.29
246.1625061	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	354.2266
Annotation	Cinnabaramide E
Peak:m/z	Relative Intensity
119.9799805	0.01
130.1395874	0.04
131.9544067	0.12
132.9670258	0.09
136.2212982	0.14
144.8854218	0.04
146.9677734	0.11
148.0470886	0.05
150.0191040	0.02
159.1943970	0.09
166.0935059	0.01
169.1845703	0.01
170.7538147	0.05
184.3291931	0.05
187.2180481	0.05
188.9734192	0.01
194.9697113	0.02
197.1329498	0.04
199.7998657	0.01
200.9647980	0.09
202.1434631	0.05
209.0319214	0.05
217.1809998	0.03
218.0552063	0.28
219.3306274	0.37
220.2901306	0.15
223.3433533	0.10
227.2784424	0.06
228.4937744	0.07
232.0087585	0.14
233.2145996	0.05
237.2635498	0.02
240.1411133	0.03
241.2556152	0.03
243.1068726	0.02
245.4884338	0.03
246.4115295	0.05
250.3281860	0.05
256.5039673	0.06
262.2594604	0.52
270.2090454	0.72
271.3386230	0.06
272.1503906	0.15
272.9856873	0.26
273.6300354	0.02
274.3522644	0.16
275.4250488	0.04
280.1505127	0.37
282.2622681	0.96
283.0994568	0.02
287.2210388	0.03
288.1938782	0.03
290.1566772	0.04
300.3560181	2.39
301.0796204	0.04
304.4876709	0.06
308.2923584	0.05
313.5057373	0.04
318.2879639	3.54
319.0261536	0.01
326.1545410	0.06
332.2214355	0.02
333.6110229	0.13
334.6741638	0.20
336.2646179	100.00
337.3305054	0.16
345.6773987	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	312.16
Annotation	Unknow
Peak:m/z	Relative Intensity
126.8987122	0.32
130.3504333	0.16
132.7984314	0.38
136.9177246	0.10
139.1238403	0.14
144.8541870	0.95
147.1373291	0.18
156.0162659	0.31
162.9760132	1.61
165.8553009	0.32
167.2533875	0.05
169.1099548	0.14
171.2057800	0.25
172.9712219	0.19
174.8901978	0.06
179.2207184	0.09
179.8782043	0.51
191.2186584	0.32
194.1680298	0.26
199.1407471	0.10
202.4611664	0.20
207.0540771	0.34
210.9337769	0.11
215.2394409	0.08
222.7002869	0.46
223.3523254	0.10
227.0793152	0.19
241.2508545	0.14
248.7324829	0.39
252.1029663	0.05
254.9436035	0.30
258.8220215	0.86
263.2805176	0.17
263.9794922	0.20
266.1184692	0.49
267.0343628	0.10
268.1872864	0.22
269.3128967	0.09
270.7263794	1.17
273.0558472	0.16
276.2942505	0.79
277.0001221	0.64
279.1535034	0.11
282.4566650	0.52
284.4288330	0.45
286.2743225	0.06
291.2288513	3.54
292.1753540	0.54
293.2160034	0.72
294.8302307	100.00
295.5849915	0.19
299.1720581	0.05
303.5438538	0.53
304.1478882	0.29
311.6110535	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.1194
Annotation	Raltitrexed
Peak:m/z	Relative Intensity
152.8776703	0.06
176.8727417	0.14
178.9373627	1.71
276.4851074	0.04
293.2589111	0.26
295.0464783	0.55
307.0892639	0.15
322.9675903	0.15
339.8205872	0.03
341.1750488	100.00
385.2364807	0.08
387.1663513	0.06
397.1882019	0.31
411.2174683	0.21
412.4021301	0.13
414.2168274	0.03
425.1104431	0.13
438.8033142	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	368.2061
Annotation	Isariotin D
Peak:m/z	Relative Intensity
113.8823624	0.03
115.9529037	0.11
130.1483459	0.01
132.0928650	0.29
132.8300476	0.13
134.8719025	0.05
146.1929932	0.04
156.9521484	0.05
160.1586151	0.09
161.3586426	0.05
171.1510315	0.03
172.9616394	0.17
177.2834167	0.05
185.2396851	0.10
187.0443420	0.04
196.1772614	0.05
197.0065308	0.02
199.1103210	0.94
200.9085846	0.11
203.2131042	0.01
211.2651215	0.13
212.9643250	0.08
214.2241211	0.04
215.0600739	0.05
216.3438263	0.10
217.0330811	1.10
219.2989502	0.04
221.9537048	0.09
225.1818848	0.01
228.9480591	0.01
230.1515808	0.05
231.3659363	0.01
234.2389832	0.05
235.1623230	0.07
236.7793884	0.15
239.0605164	0.03
241.5961609	0.02
243.3592834	0.13
245.0328369	0.03
246.9797668	0.06
248.2284546	0.25
251.2364502	0.04
252.3112488	0.09
253.4309692	0.10
254.5374451	0.03
255.2819519	0.08
258.3961487	0.02
260.1434326	0.06
261.2521362	0.14
264.1584778	0.04
266.3539124	0.41
268.1808167	0.07
271.1103516	0.02
272.3220215	0.22
277.2333069	0.02
278.2955933	0.85
279.1632690	0.14
284.2639771	2.16
286.4087524	0.11
290.1896973	2.05
294.3159180	0.16
296.2656860	3.56
297.0330200	0.05
301.5488586	0.10
302.3074951	1.46
304.3126221	0.13
314.3012695	8.79
315.4841919	0.02
322.1483459	0.01
327.2270203	0.07
332.2152405	16.45
332.8414917	0.05
345.1756592	0.07
350.2299194	100.00
351.2130127	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	716.382
Annotation	Amamistatin B
Peak:m/z	Relative Intensity
260.4533081	0.40
277.2332153	0.41
286.3523560	0.06
294.1597900	0.75
302.2797241	0.05
303.3538208	0.06
304.0988464	0.22
312.2999878	2.92
330.4493408	4.18
372.4793701	0.59
390.3110962	2.35
408.3672485	72.39
409.0100708	0.16
416.9137573	0.18
420.4307251	0.29
422.2935181	0.35
438.3804321	0.20
440.5667725	0.31
446.0153198	0.11
450.3690796	1.15
453.2681885	0.07
456.3118286	0.66
466.7324829	0.19
476.2902832	0.20
491.3318481	0.06
494.5371094	0.15
498.3013916	0.48
500.2377319	0.20
516.5634155	0.29
518.3643188	2.05
521.2189941	0.25
534.5085449	1.18
536.4494629	0.89
552.2177124	0.18
554.4224854	31.30
567.5744019	0.22
570.4555054	100.00
578.3756714	0.16
584.5912476	0.15
594.9900513	0.10
599.4939575	0.11
612.4645386	1.72
619.3954468	0.32
620.2201538	0.39
645.7015991	0.07
653.1892700	0.46
657.1759644	0.56
662.2667847	0.40
680.3904419	4.38
686.2413940	0.08
696.4263306	0.37
698.2777100	2.54
707.0874634	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.3304
Annotation	Unknow
Peak:m/z	Relative Intensity
205.0482788	0.02
232.7852325	0.02
242.2923889	0.05
261.0396423	0.01
271.2186890	0.02
279.2850952	1.84
280.3498840	0.04
357.1010742	0.09
369.4714355	0.02
375.7391968	0.04
379.4140015	0.04
397.2118530	0.02
407.3012085	0.04
419.8450317	0.11
448.1425171	0.04
459.8061523	0.03
462.5655518	0.06
468.6300049	0.03
472.3748169	0.07
473.3884277	0.03
477.1988525	0.04
490.3793335	0.04
504.3390503	100.00
505.1673584	0.53
510.6656494	0.03
518.5620728	0.04
521.1198730	0.09
528.0660400	0.21
546.0584106	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	338.2316
Annotation	Dendrowardine
Peak:m/z	Relative Intensity
114.8503342	0.03
116.1167755	0.07
116.9724884	0.02
131.0507050	0.01
136.0691223	0.15
148.2485657	0.02
152.8793335	0.02
156.1141357	0.02
158.7933960	0.10
174.1912842	0.10
181.0859680	0.09
188.1321716	0.03
200.1773376	0.09
202.0006714	0.04
214.1141968	0.04
216.2814941	0.08
220.3006287	0.04
222.2919006	0.04
232.2518616	0.42
236.1520691	0.03
239.2675781	0.09
240.4237061	0.01
245.5346985	0.02
248.9886780	0.03
253.2118835	0.03
258.3213806	0.03
259.0017700	0.01
266.2847595	0.02
268.0845032	0.11
273.6779175	0.02
275.2849426	0.05
276.1354980	0.07
278.9793701	0.01
284.2790527	1.68
285.1966553	0.21
288.7012329	0.06
290.3106079	0.05
292.0444946	0.12
293.0923462	0.17
297.9025269	0.01
300.6392212	0.07
302.3318481	4.54
303.4315796	0.23
310.9555664	0.03
316.3347168	0.18
318.3768311	0.04
320.2450867	100.00
320.8600769	0.31
323.1345215	0.03
324.2348328	0.17
329.0404968	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	770.7439
Annotation	Unknow
Peak:m/z	Relative Intensity
243.8448486	0.05
257.1554260	0.11
259.0684814	0.06
266.5345764	1.24
267.7539062	0.72
270.2025757	0.52
271.1228027	0.37
275.8466492	0.77
284.7145996	2.73
285.7145081	0.71
287.3682556	0.14
304.9710693	0.24
306.9824829	0.22
315.2177429	0.37
316.3598022	0.08
324.8839722	0.26
336.6356812	0.06
345.6470337	0.20
346.5350952	0.39
347.1362000	0.25
348.1207886	0.69
349.3085327	0.33
356.5441895	0.10
357.7996216	0.49
365.6704407	2.99
366.4338379	0.77
375.9095459	0.34
384.1447144	0.44
391.1495361	0.32
396.1721191	0.95
407.1610107	1.10
407.9433594	0.56
409.4260254	0.39
417.6050415	0.56
426.4767456	3.29
429.2181396	2.03
431.1401978	0.05
437.3773804	0.81
438.2933960	2.86
439.5278931	0.31
446.7913818	16.26
447.6935425	3.51
449.0646973	0.29
462.2863159	0.04
466.9436646	0.93
468.3843384	0.22
469.3740845	0.45
473.4616699	0.11
475.2785034	0.18
477.2780762	1.19
478.2689209	0.44
489.4475708	0.74
491.1613770	1.17
492.1365967	0.75
493.1920776	0.56
495.0116577	0.05
498.1405029	1.27
499.1058350	1.65
507.3770752	3.92
509.1594849	3.12
510.1384277	2.76
510.9050903	0.93
511.5167236	0.06
518.7763062	5.21
519.7650146	6.35
520.6467285	0.20
522.1055298	0.23
527.8931274	35.49
528.8259277	5.63
532.0324097	0.13
535.1965942	0.31
539.6725464	0.56
551.1695557	0.57
551.9700317	0.12
552.8695068	0.59
558.8796997	2.42
569.2664795	2.49
570.9275513	1.04
579.4812622	4.43
580.3581543	0.51
581.2886963	1.35
582.3837891	1.32
588.5241089	12.13
589.4203491	2.57
591.1630859	1.08
592.6161499	0.42
599.2821655	4.19
600.1179810	7.66
601.0222168	1.87
601.9299316	0.06
609.0496826	43.15
609.9766235	6.38
610.9122925	0.96
611.6883545	0.09
615.1129761	0.36
617.9483643	0.07
621.8590698	0.28
624.3425903	0.24
625.5279541	0.19
629.1623535	2.23
630.1992798	0.16
634.5071411	0.13
635.8015137	0.06
639.3167114	2.73
639.9240723	1.95
640.8969116	0.33
642.4478149	0.07
643.1863403	0.31
651.5844116	1.57
653.2854614	0.84
654.1981812	0.23
660.5028687	10.80
661.3472290	3.84
662.2971802	0.15
669.5090942	43.98
670.4093018	11.42
671.2656250	11.44
672.2382202	5.02
673.3041992	1.96
676.2894897	0.05
680.9505005	22.55
681.7911987	7.29
683.4813232	0.20
690.0272827	100.00
690.9080200	24.54
694.6447144	0.18
701.9401245	0.59
704.4888306	0.21
705.4451294	1.47
708.1000366	0.47
710.6221924	0.04
711.5960083	0.18
713.4076538	0.35
720.5878296	6.81
721.4160767	1.16
722.1096802	0.55
725.1066284	0.99
731.1488647	7.14
732.1740112	4.10
732.9308472	0.77
733.6361694	0.34
734.5095825	0.14
743.1390381	1.34
744.1998901	0.42
752.7482910	1.03
753.8247681	0.52
761.9573975	24.65
763.0069580	4.07
764.8307495	0.33
790.9116821	0.64
792.0490112	0.51
797.0531616	0.08
814.9253540	0.71
815.7048950	0.11
816.4591064	0.20
817.4968262	0.10
821.2008667	0.51
823.0304565	0.28
827.1718750	0.18
831.5463257	0.21
833.4776611	2.20
834.3855591	0.65
850.5033569	0.89
851.5040894	0.50
852.3182373	0.30
856.1572876	0.08
869.9130249	0.19
874.1198730	0.20
875.3456421	1.92
876.0386963	1.44
877.3513184	0.61
893.3398438	21.13
894.3150024	7.90
895.3681641	3.53
905.2455444	0.22
923.3646851	0.65
924.0668945	0.55
924.9506226	0.28
936.1135864	0.15
937.4464722	0.32
954.1469727	0.15
955.1040649	0.17
966.1058960	0.29
975.1890259	0.39
976.4912720	0.51
977.3447266	0.68
977.9665527	0.05
983.1189575	0.20
993.2527466	1.34
994.2473145	0.12
995.2021484	0.56
996.2805176	0.72
1000.3715820	0.37
1012.9707030	2.57
1014.0026860	1.35
1015.2961430	0.87
1016.1261600	0.20
1021.5493160	0.04
1036.2812500	0.92
1037.4829100	1.95
1039.1340330	0.15
1040.5477290	0.11
1055.3168950	19.57
1056.3588870	8.93
1057.4364010	3.89
1065.0736080	0.10
1068.5681150	0.28
1079.2742920	0.13
1087.5098880	0.14
1096.6824950	0.25
1097.3116460	0.34
1098.7685550	0.10
1115.2714840	0.23
1115.9826660	0.07
1116.9887700	0.16
1137.3062740	0.40
1137.9179690	1.23
1138.7873540	0.17
1139.7124020	0.36
1140.3916020	0.14
1144.9289550	0.10
1157.0764160	0.74
1158.3907470	0.35
1160.2396240	0.28
1175.1638180	0.42
1176.2453610	0.91
1198.3212890	2.30
1199.2537840	1.81
1199.8721920	0.10
1216.0750730	0.08
1217.3791500	4.84
1218.2430420	1.46
1219.2725830	0.39
1230.2626950	0.15
1247.0689700	0.15
1248.1763920	0.39
1249.1580810	0.50
1259.9813230	0.21
1264.8747560	0.14
1277.6929930	0.14
1278.3326420	0.16
1279.0283200	0.09
1279.6894530	0.08
1300.7216800	0.21
1318.2174070	0.09
1319.1175540	0.17
1319.8863530	0.18
1337.3367920	2.04
1338.1134030	1.39
1339.4871830	1.10
1340.5059810	0.07
1360.0417480	0.88
1361.7479250	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1192
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
125.1558304	0.57
130.9777222	0.19
134.9823456	0.07
147.0166168	0.08
151.2995300	0.08
174.7921448	0.06
179.0498047	0.13
188.2896118	0.08
190.9648743	0.21
192.9228973	0.07
194.0918274	0.45
195.1978760	1.23
206.1141968	0.15
207.1073303	0.21
208.1980133	0.23
208.9640656	0.06
210.1049500	0.17
216.0518494	0.41
221.1117401	0.36
223.1657867	14.14
227.4175262	0.09
233.1160889	0.13
245.2581482	0.10
254.1401062	0.18
259.0816956	0.04
265.2083130	0.21
266.8813477	0.11
269.0959473	0.49
287.1333923	0.14
302.0516052	0.38
310.1356201	0.25
313.0723267	0.32
315.2254639	0.44
325.3455811	0.09
329.0648193	1.40
334.8927917	0.16
355.3207397	0.27
362.2398987	0.13
366.1219177	0.34
367.2690735	0.13
369.4794006	0.22
370.8045654	0.46
371.4436951	0.69
382.4076843	0.14
385.1418762	100.00
385.8089294	0.53
387.0821228	0.67
389.3593140	0.58
394.2676697	0.07
396.6096497	0.09
412.1889954	1.11
413.2961121	1.55
416.0996399	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	697.4293
Annotation	Unknow
Peak:m/z	Relative Intensity
199.2414703	1.35
203.2445374	0.34
207.6112518	1.49
209.1167603	0.37
219.0152893	0.18
220.9978027	1.64
222.6792908	0.19
224.3823547	0.13
225.5483704	0.23
226.2986450	0.18
227.2981720	0.09
229.5858154	1.45
230.4776154	0.93
234.8884735	0.32
237.0807343	0.15
238.1451874	0.56
239.3073425	0.36
240.3953552	0.08
242.4703674	0.10
243.2103424	2.06
244.0000763	0.40
250.7843781	0.99
251.6803741	4.44
252.6250153	0.30
255.7794342	0.22
260.9434204	0.06
263.2706299	0.23
265.0321960	1.74
265.7067566	0.12
268.8812866	1.15
270.1796265	0.18
271.3004150	0.14
272.7065430	0.06
273.4820557	3.74
274.3010559	0.46
275.7368774	0.15
277.1622314	0.12
279.2298584	0.54
282.0778198	1.01
283.3168335	1.25
285.2033691	0.27
289.5555420	0.18
290.3303833	0.12
294.7297668	1.33
295.4707947	3.47
296.7446899	0.73
297.7307129	1.11
299.6160583	0.16
300.2754211	0.09
305.7952881	0.65
309.2025757	1.50
310.0927124	0.14
311.1492615	1.28
312.4006348	0.34
313.2916870	0.40
314.3752441	0.12
315.4307861	0.33
316.1821899	0.89
317.5243530	2.02
319.6948853	2.16
320.8037720	0.72
326.0114746	0.08
327.2266846	1.60
327.8799438	0.56
329.3916016	1.05
330.2698364	0.42
333.6925659	0.48
338.8268127	0.91
339.5517578	1.96
340.3039551	0.25
341.7404785	2.36
342.3574219	0.14
344.1373901	0.35
349.7851562	2.82
350.7732544	0.25
353.0604248	0.32
354.4439697	0.33
355.4481201	0.25
357.2460938	0.42
359.2543335	0.12
360.9137573	0.38
361.7156982	0.16
362.8296509	0.24
363.8143311	1.32
368.5157471	0.28
369.6750488	0.13
371.8341675	3.52
373.2861938	4.13
374.2849121	1.18
375.1713257	0.58
376.6256104	0.36
379.2214355	0.14
383.4562378	0.58
384.5954590	0.56
385.6176758	1.01
386.3854980	0.62
388.6828613	0.14
393.7285767	1.42
394.7799683	0.51
397.2608643	0.24
398.5321655	0.29
399.2365723	0.20
400.2965088	0.13
401.2770996	1.47
403.1361084	0.06
404.4968872	0.23
405.7575684	0.55
406.5553589	0.07
407.7456665	0.51
410.2993164	0.15
415.5769043	1.78
416.9773560	1.28
418.0484009	0.56
419.2205200	0.64
420.0944214	0.25
427.4334717	0.68
428.1690674	1.39
430.6083984	0.37
432.2003174	0.07
436.4077759	0.15
437.5000000	0.76
438.2354736	0.71
441.3813477	0.11
442.2022705	0.05
444.8749390	0.23
446.3638306	0.30
447.3779907	0.30
449.0410156	0.28
452.1694946	0.29
459.5581055	0.65
460.3838501	0.07
461.1355591	0.33
463.2066040	0.61
464.6650391	0.16
471.4826660	0.35
472.4472046	0.59
473.6399536	0.37
475.5169067	0.09
477.3197632	0.42
479.0668945	0.52
481.2506104	0.33
485.2881470	0.91
486.3551636	0.13
488.1869507	0.08
489.0981445	0.46
493.9887695	0.63
496.2860107	0.90
497.0825806	0.18
498.3250122	0.15
502.2453613	0.07
502.9211426	0.79
503.9321899	0.26
504.9218140	1.84
506.0164185	0.51
512.4519043	0.12
514.8482666	0.45
516.0473633	0.10
516.8713379	1.03
518.1771240	0.43
518.8836060	0.04
523.1902466	0.51
524.2545776	0.21
525.6895142	0.60
526.7633667	0.75
527.5939331	0.10
529.1641235	0.40
532.5514526	0.26
533.6590576	0.34
537.8609009	1.07
538.7899780	0.25
539.4334106	0.39
540.3372803	0.63
541.4845581	0.20
546.2901001	0.12
547.5130005	0.61
548.4640503	1.85
549.2313843	0.66
550.3020630	0.71
551.2974243	0.25
552.3580322	0.30
556.3390503	0.23
560.2008057	0.08
561.2967529	0.21
563.0690308	0.43
564.4048462	0.16
565.2897339	0.17
567.9783936	0.68
568.6134644	0.16
569.8008423	1.04
571.0782471	0.44
572.3858032	0.44
573.3012085	0.33
574.3525391	0.25
577.2127075	0.49
584.6089478	5.48
585.3162842	3.43
586.0419312	0.95
586.8464966	0.05
591.6520386	0.85
593.0394897	4.39
594.1830444	0.36
595.4705811	0.66
596.1395264	0.05
597.4375610	0.04
599.7863159	0.65
605.2931519	0.33
607.9589233	0.23
608.5743408	0.47
609.4149780	0.07
611.9099731	0.64
612.5817261	0.05
613.3873901	0.34
615.0853271	2.74
615.8445435	0.84
616.8876953	0.80
618.4304810	0.26
623.4524536	0.03
626.7072144	0.59
628.6812134	2.70
629.5158081	0.12
630.3030396	0.19
635.3778076	1.55
637.0328979	100.00
637.9669189	13.57
638.8550415	0.91
639.8546143	1.04
640.6910400	0.32
641.4755249	0.07
642.1008911	0.07
644.8233032	1.39
645.7091675	0.37
650.3132935	0.65
651.3810425	0.17
652.2786255	1.41
653.4475708	0.34
654.5444946	0.10
658.7725220	0.08
661.6075439	0.08
663.4301147	0.31
667.1613159	1.68
667.9963989	1.39
668.7646484	0.05
672.3992920	0.87
677.5297852	0.36
678.3851929	0.23
679.6001587	2.64
680.4538574	2.60
681.4290161	0.31
682.1162720	0.07
683.6970825	0.35
688.8955078	0.14
703.4686279	0.14
705.1676636	0.12
710.2981567	0.11
710.9840698	0.15
716.9836426	0.10
723.6045532	0.20
724.5261841	0.43
725.8401489	0.14
740.5543213	2.44
741.4375610	1.79
742.6007690	0.14
749.2189941	0.05
749.9179077	0.10
760.4968262	0.32
767.3063354	0.78
768.2494507	0.15
769.0918579	0.11
770.4400024	0.73
771.4321899	0.18
783.9586792	0.35
784.5685425	3.60
785.5018921	1.10
787.3887939	0.04
788.1074219	0.11
793.4337158	0.54
799.1911011	0.45
804.4396973	0.07
805.4399414	0.07
811.2667847	1.31
812.3966675	0.30
814.5048218	0.24
816.2824707	0.26
828.4294434	3.86
829.5775146	1.33
832.6206665	0.21
833.5620728	0.21
834.6235352	0.17
835.5761108	0.08
837.7598267	0.07
840.3416748	0.04
841.4400635	0.14
846.4619751	0.10
848.4465942	0.23
849.3002930	0.04
854.0485229	0.07
855.1651001	0.39
856.4114380	0.68
858.5289307	0.54
859.5502930	0.24
860.7487793	0.09
865.5737305	0.23
872.3258667	4.64
873.4411621	1.78
874.6626587	0.29
876.7150879	1.12
877.6303711	0.37
882.3710327	0.03
885.6003418	0.04
892.4880981	0.94
893.3693237	1.00
899.6555176	0.16
901.6017456	0.15
916.4744263	3.11
917.3992310	0.89
918.7126465	0.21
919.8397827	0.60
920.7051392	0.50
921.5659790	0.27
929.5529785	0.08
930.4736328	0.36
936.5189819	0.97
937.3036499	0.67
938.1188965	0.16
943.4844360	0.58
945.5172729	0.05
946.5209961	0.42
948.2529907	0.04
960.5994263	2.63
961.8117065	1.09
962.5095825	0.56
963.6057739	0.40
964.5642700	1.82
965.6287231	0.55
966.4960327	0.44
978.7722168	0.35
980.5631714	0.98
981.5312500	1.48
982.7517700	0.10
987.7388306	0.22
989.5455933	0.44
1004.6282350	1.00
1005.3566890	0.34
1006.3143920	0.08
1008.3430790	0.55
1009.4717410	0.40
1010.7606810	0.32
1023.7536010	0.71
1024.5296630	1.21
1025.6096190	0.82
1026.5213620	0.07
1033.9940190	0.06
1035.4287110	0.29
1048.5765380	0.08
1052.6542970	1.27
1053.6706540	0.45
1054.7150880	0.67
1067.8884280	0.28
1068.8181150	2.62
1069.6448970	1.74
1070.5800780	0.62
1077.4750980	0.03
1078.1076660	0.04
1082.1805420	0.26
1096.4790040	0.51
1112.3957520	2.50
1113.5533450	2.28
1114.7208250	0.24
1124.7635500	0.51
1125.8654790	0.07
1138.2507320	0.05
1140.2725830	0.53
1141.6967770	0.06
1142.4262700	0.04
1156.6644290	4.02
1157.6031490	1.97
1158.5017090	0.28
1168.5629880	0.43
1169.5144040	0.30
1184.2099610	0.20
1185.2666020	0.14
1200.5991210	2.15
1201.6800540	0.17
1202.6477050	0.31
1210.6275630	0.10
1228.3638920	0.43
1244.3236080	0.63
1245.5533450	1.49
1246.8420410	0.04
1256.4305420	0.05
1272.6446530	4.88
1273.7418210	1.60
1274.7188720	1.25
1306.5856930	0.24
1358.7913820	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	215.03
Annotation	2-C-Methyl-D-erythritol 4-phosphate
Peak:m/z	Relative Intensity
88.8572388	6.61
100.9437103	0.95
106.7977448	0.78
113.0492249	1.68
118.9449158	2.51
139.9051361	1.76
142.9720917	9.11
152.8741302	0.62
160.9673157	9.20
171.2385712	1.38
177.2658844	1.49
178.9799042	100.00
196.4945526	1.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	292.85
Annotation	Unknow
Peak:m/z	Relative Intensity
122.7875519	0.25
124.8866959	0.21
157.8143921	0.03
159.0650635	0.02
166.3706665	0.04
177.0544739	0.04
193.3492432	0.02
199.8770447	0.07
206.8784180	5.29
208.9202576	100.00
221.0693359	0.04
229.0597229	0.28
230.8796387	5.18
231.8795166	0.24
256.3926392	0.05
262.1639404	0.09
263.1285400	0.10
274.1617432	1.24
275.0963135	0.22
276.0932922	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	531.1143
Annotation	6,7,3',4'-Tetrahydroxyaurone 6-(4'',6''-diacetylglucoside)
Peak:m/z	Relative Intensity
161.0450134	0.61
163.0413208	0.39
169.1458740	0.22
172.9394073	0.17
175.2225037	0.16
178.0528870	0.03
179.0247192	0.98
187.0009918	2.20
195.1303406	0.05
201.1245270	0.21
203.2166290	0.75
204.9818420	5.05
213.2703705	0.59
219.0773010	0.23
223.0912933	12.79
228.4980469	0.10
230.9880829	0.50
245.1890106	0.05
247.0497742	1.50
252.9261780	0.07
256.4244995	0.24
257.2154541	0.75
259.3117065	0.06
262.9861145	0.08
273.1531372	0.88
275.1109009	2.38
291.2337036	0.49
305.2289429	0.04
307.1867065	0.71
309.4390259	0.05
316.5174561	0.22
323.0466919	0.33
324.4014893	0.06
325.2648315	0.12
330.1197510	0.46
331.9701538	0.04
333.0501709	0.15
335.3280640	0.09
339.1964722	0.17
341.3580322	0.04
349.1273193	1.63
350.9968872	2.50
351.6110840	0.21
367.1651001	4.11
369.0718994	100.00
369.6893921	0.30
381.3251953	0.11
385.1123657	29.20
399.2864380	0.14
401.1402588	0.05
402.5526123	0.07
408.5529175	0.06
415.1168823	0.05
417.4943848	0.07
440.9899902	0.18
447.1785278	0.20
448.5668945	0.08
454.8858643	0.02
459.9146118	0.12
462.9121094	0.12
469.2832031	0.34
471.4382324	1.24
480.7444458	0.70
481.4212036	0.15
484.2651978	0.14
485.1672974	0.13
486.9314575	0.30
487.6952515	0.27
492.5138550	0.05
493.2443237	0.11
494.8774414	0.07
495.5397339	0.17
512.9976196	2.59
513.6276245	0.23
521.1573486	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	596.1075
Annotation	Unknow
Peak:m/z	Relative Intensity
252.0707703	0.04
272.1231689	0.06
300.0643005	0.06
301.2819214	0.04
304.1517334	0.03
313.3600464	0.27
314.2222900	0.04
329.0585938	8.36
329.6710815	0.04
347.1912231	6.45
354.2972412	0.50
372.1329956	2.19
382.3765869	0.03
386.3375244	0.04
400.2297363	0.06
409.3953247	0.06
417.2904663	0.10
419.0511475	0.02
426.2191772	2.49
427.1625977	0.07
434.0404663	16.10
434.6671143	0.02
451.3900757	0.03
452.1789551	0.02
457.4156494	0.01
462.3900757	0.20
463.3046265	0.12
465.2503662	0.09
476.2318115	0.46
487.4854126	0.03
498.6220093	0.03
499.2494507	0.09
509.1686401	100.00
509.8419800	0.03
511.7323608	0.08
520.5464478	0.07
530.1898193	0.10
534.3343506	0.39
536.0538940	0.13
541.2118530	0.10
548.9308472	0.08
550.3530884	0.05
552.0040894	2.27
558.1227417	0.21
559.3455200	0.23
560.5518188	0.03
562.3232422	0.06
563.1091919	0.04
575.5471802	0.09
578.1813354	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1088
Annotation	Forsythide
Peak:m/z	Relative Intensity
115.0301666	0.05
125.1174545	0.05
126.8970795	0.08
131.4916382	0.08
137.9410400	0.04
144.1804352	0.05
148.7915039	0.03
150.1403809	0.02
151.1721039	0.14
153.0359802	0.08
155.1454315	0.03
159.8589478	0.04
163.0607147	3.79
164.1619263	4.63
165.2160187	0.39
166.3038330	0.04
168.0867310	2.11
174.9241943	0.12
181.0230713	0.46
183.0327606	0.69
187.3115540	0.05
191.0537720	0.41
194.1580811	0.06
204.3370056	0.02
205.0756531	0.03
207.1163940	0.19
208.3231506	0.27
209.1324463	2.44
210.0870819	0.17
212.0556793	22.75
217.2366333	0.10
223.3312073	0.02
224.3835144	0.47
225.2944641	1.50
227.0169983	100.00
230.0259094	0.08
230.7301025	0.02
249.0568237	0.04
250.9246826	0.06
259.1887207	0.18
264.1900024	0.09
266.1180725	0.07
267.4823303	0.08
269.1242676	0.07
280.8893433	0.04
283.1735229	0.04
287.2795715	0.11
288.5189819	0.09
293.1035767	0.03
295.2708435	0.05
297.0509949	0.12
299.3144226	0.06
305.1951599	0.26
316.3387451	0.03
317.1005859	0.18
319.8702393	0.03
327.3826294	0.08
328.3261108	0.22
329.0494995	0.14
330.0677185	0.13
342.0337524	0.59
343.0232544	0.39
344.2741089	0.47
345.2940063	0.28
346.2433167	0.40
352.5710754	0.03
370.4723511	2.90
371.2253113	1.94
374.1386719	9.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	299.0772
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
92.9065399	3.81
121.0678024	0.18
121.9475021	0.16
135.0589294	0.17
136.9092255	100.00
147.0220642	0.20
164.9865570	0.29
166.9490662	0.08
177.2175598	0.14
179.0658569	0.47
181.0487823	0.07
183.0067139	0.15
184.4404907	0.12
209.1206360	0.13
211.0815735	0.03
214.8517151	0.09
227.0625000	0.97
235.3323669	0.13
237.1435852	0.13
238.0053406	0.17
239.2846680	0.35
241.2101746	0.07
253.0549316	1.62
255.1832275	4.27
267.1436768	0.18
281.1250000	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	522.2812
Annotation	PS(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
149.0697327	0.09
173.1976929	0.09
195.1894989	0.24
229.3420715	0.45
242.1224365	0.28
253.0135803	0.13
254.9729919	0.12
260.2465820	0.09
263.1881714	0.08
270.0950928	0.09
271.3492432	0.04
273.9089966	0.16
280.2126465	0.33
293.1712646	0.07
297.6015320	0.18
300.2604370	0.03
301.0990601	0.24
315.1539307	0.16
325.4626465	0.13
335.9826050	0.11
337.3707886	100.00
350.4000244	0.72
355.3544922	0.23
405.1959839	0.03
415.2453003	0.11
416.9069214	0.99
424.0213013	0.39
424.6469116	0.52
436.2860107	0.03
449.1867676	0.08
454.1583252	0.08
459.4479980	0.18
460.8578491	0.04
462.4481201	0.05
474.3643188	0.07
476.1439819	0.22
477.2341919	0.20
480.9863892	0.51
482.2278442	0.35
487.1569214	0.16
503.7722778	1.47
504.3744507	14.50
505.4073486	0.60
513.0044556	0.39
514.3149414	0.08
518.0167847	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.3065
Annotation	Unknow
Peak:m/z	Relative Intensity
143.0611877	1.08
149.0245361	0.25
159.0538788	3.15
161.0405884	3.75
178.9481659	4.05
186.1013794	0.19
191.1524963	0.16
201.4043427	0.06
203.2781372	0.29
215.2716064	6.88
223.3430023	0.43
243.3780212	0.05
249.0881805	6.88
251.2446136	0.05
260.9762573	0.12
279.0637207	0.14
281.3383484	0.28
282.3427429	0.06
285.4602051	0.30
291.1843262	0.11
294.4425964	0.10
303.2343140	0.35
320.6715088	0.26
321.4312134	3.18
328.2529907	0.06
337.4222717	0.28
339.3230591	10.89
354.3242493	0.05
357.3563232	0.77
359.2000427	0.18
367.2572327	0.17
369.3052979	0.19
371.3548889	0.22
376.2493591	0.08
381.1608582	0.11
385.3569031	0.10
387.5867004	0.13
397.2825623	0.06
404.1507568	0.27
405.9890442	0.35
411.2829895	0.14
421.0933533	0.15
423.2692566	0.06
427.3258362	0.14
437.4385681	0.04
441.3013611	7.98
446.6697388	0.19
453.4100037	0.35
455.3495483	0.52
456.5057678	0.04
457.3246155	0.30
462.6264648	0.26
463.3059082	0.45
464.6107788	0.88
465.3897400	13.29
466.1934509	0.25
471.6885376	0.32
481.2827454	0.07
483.3432312	100.00
491.4763489	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.3126
Annotation	Unknow
Peak:m/z	Relative Intensity
179.3035431	0.09
187.2694855	0.03
201.1815796	0.05
207.4364014	0.07
225.3806000	0.12
226.4032135	0.07
237.9936829	0.05
243.0018311	0.21
249.2953186	0.04
262.9570618	0.10
264.0140991	0.07
269.4549561	0.03
285.1199341	0.03
297.4426880	0.23
301.1842041	0.04
302.2545776	0.04
302.9896851	0.05
305.5679932	0.09
307.3058472	0.08
316.2551575	0.15
321.2391968	0.29
323.2800903	0.08
332.4516602	0.10
333.2816162	0.32
339.8485107	0.04
351.4481201	0.13
365.2633667	0.03
369.4632568	0.08
370.4342041	0.26
375.5922241	0.05
385.3041992	0.70
387.3532715	43.74
388.3552856	9.86
389.4246826	0.30
394.1181641	0.12
404.4790039	0.05
411.4219971	0.78
412.4687500	0.21
423.3655396	0.08
429.3379517	1.78
430.4549561	1.20
431.1553955	0.06
435.9552612	0.19
436.5872803	0.05
447.4511719	6.14
448.4578247	2.05
453.3433228	0.12
454.4810181	0.04
467.1132812	0.11
483.3693848	0.09
489.3625488	0.03
506.4595337	0.16
513.3255615	0.12
520.3422852	0.10
522.5891113	0.09
531.4588013	2.00
532.5542603	0.44
537.7828369	0.05
541.2305298	0.13
547.3623657	0.87
549.3255005	44.66
550.4257202	12.77
564.2018433	0.06
564.9580688	0.04
565.5919800	0.16
569.7666016	0.09
572.3673096	0.09
573.3940430	4.33
574.3995361	1.70
580.7060547	0.11
582.4849854	0.08
587.3458862	0.18
591.3833618	100.00
592.4075317	38.25
593.0109253	0.16
611.1730347	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1217.2407
Annotation	[Epigallocatechin-(4->8)]3-epigallocatechin
Peak:m/z	Relative Intensity
342.9878845	0.03
355.1046143	0.05
361.0003662	0.45
365.2950439	0.04
366.0655823	0.05
379.2184143	0.84
383.0849304	0.06
385.1372681	0.08
387.3528137	0.24
392.4430237	0.15
395.2453003	0.31
397.1106567	0.18
403.0363464	0.18
405.2029419	0.28
411.1995850	0.66
412.3441162	0.09
413.2837219	0.14
419.4224548	0.07
421.2208862	2.91
423.1883240	5.58
424.1788330	0.10
425.0790710	0.21
427.3354797	0.34
429.3009033	3.05
432.3074951	0.14
433.2783508	0.38
435.2182007	0.07
437.3519287	0.29
439.2186890	2.50
441.2701416	2.34
442.3019409	0.18
444.9266968	0.07
451.3240356	0.22
452.3505249	0.03
452.9706421	0.24
463.2286987	0.59
465.4221802	0.56
470.9277649	0.11
475.2539673	0.10
479.1783447	0.04
481.1492920	2.90
483.2326050	4.64
484.2595825	0.42
493.0780945	0.18
497.5380249	0.11
503.3533020	0.29
506.4409790	0.18
509.4466858	0.36
513.3210449	0.10
515.2335205	0.40
519.5834351	0.17
521.2451172	0.10
523.3459473	0.53
525.2301025	0.24
526.4537964	0.15
529.2593994	0.18
533.4108887	0.18
539.1948242	0.26
541.1677246	1.30
545.2824707	0.26
547.1150513	4.04
547.9643555	0.31
549.3941040	0.29
551.0954590	0.20
557.1585693	1.51
558.5035400	0.37
559.1883545	2.26
561.1564941	0.29
562.9485474	0.60
565.3356934	2.81
567.0208740	0.49
571.3274536	0.09
575.4304199	0.15
577.1925049	0.36
583.3271484	0.56
587.0092163	0.14
589.0537720	1.73
590.9903564	1.63
591.7085571	0.14
598.8400269	0.22
601.2097778	2.18
602.4864502	0.16
603.1996460	0.07
605.5428467	0.47
607.1725464	11.47
608.6137695	1.30
609.3161621	8.71
610.1856689	0.37
611.2265625	0.14
616.7249756	0.21
617.4128418	0.31
619.2043457	2.25
623.1965332	0.11
631.3656006	0.14
635.1419678	0.04
643.2750244	0.17
644.5057983	0.04
646.4342041	0.06
648.6055908	0.11
649.2752686	0.55
651.2944336	0.94
652.2789307	0.06
659.2382812	0.20
660.1879883	0.07
661.2398682	0.29
662.1322632	0.08
663.2314453	0.30
665.1275635	0.40
673.3104248	0.22
677.1742554	0.64
679.8550415	0.13
683.1057129	0.32
686.6984863	0.11
689.3746338	0.44
693.3219604	0.08
695.3417358	0.31
697.0754395	0.17
699.1551514	0.13
701.1787720	0.62
707.2502441	0.66
708.6344604	0.14
709.3922119	0.98
710.3718872	0.11
715.2001953	1.15
717.1246948	0.12
719.2512207	0.02
725.2408447	4.21
727.1457520	8.26
733.1915894	6.50
734.0123291	0.21
737.4119873	0.39
739.3109131	0.05
741.2650146	0.10
743.1353760	2.46
744.0189819	0.03
745.2232056	1.61
746.9112549	0.13
748.4655762	0.38
749.3216553	0.03
751.4356079	0.10
755.4508057	0.23
757.4558716	0.13
759.5318604	0.11
761.4248047	0.08
765.1870728	0.45
767.2122803	0.16
769.1375732	2.42
770.1466675	0.46
773.1912231	0.10
780.3448486	0.17
785.2260742	2.44
787.1213379	17.06
787.7592773	0.13
788.6159058	0.06
789.2717285	0.43
797.2634888	0.04
798.2269897	0.06
801.4444580	0.05
811.4794922	0.19
819.2404175	0.65
827.2978516	0.11
828.1551514	0.09
829.1595459	0.51
837.1177979	0.62
845.1987305	11.03
846.3729248	0.26
848.9682617	0.14
851.3002930	0.17
853.3455811	0.05
860.9936523	0.26
863.0911865	13.84
864.3807373	0.52
867.2482910	0.10
869.1263428	1.52
870.8059082	0.22
871.4431152	0.12
875.4307861	0.14
876.4249268	0.12
877.6090088	0.15
881.0538330	3.15
881.9105225	0.22
886.9774170	0.50
888.1689453	0.55
893.1898193	0.58
895.1770020	5.80
895.9365234	0.18
897.0688477	0.15
904.0549316	0.04
905.1516113	3.99
906.0179443	1.22
907.4355469	0.27
908.5300293	0.24
909.2838135	0.09
911.1967773	14.95
913.0684814	32.57
914.1695557	0.91
915.4500732	0.13
923.1906738	4.13
924.2055664	0.32
926.1839600	0.13
936.9431152	1.11
943.4169922	0.05
953.2255859	0.32
955.1335449	8.94
955.8079834	0.22
965.2481689	0.47
966.2521973	0.17
971.4129639	0.05
987.2733154	0.31
995.4029541	0.21
1002.1550290	0.35
1005.2432860	2.11
1013.2208250	9.31
1014.2159420	0.42
1029.1992190	0.37
1031.1331790	100.00
1032.1397710	1.85
1032.9956050	0.26
1039.0434570	0.06
1047.2954100	0.21
1049.0936280	30.21
1049.9876710	1.73
1050.7453610	0.19
1052.1649170	0.20
1055.1503910	0.37
1057.1523440	0.25
1063.3388670	0.08
1065.2121580	0.07
1065.8316650	0.13
1073.1574710	3.18
1074.0117190	0.91
1074.7368160	0.07
1079.4428710	0.18
1082.0070800	0.25
1088.9112550	0.36
1091.1110840	28.73
1091.9765620	1.00
1092.5953370	0.42
1102.1108400	0.08
1115.9836430	0.25
1123.9805910	0.95
1132.9975590	0.93
1145.3415530	0.22
1154.6456300	0.62
1155.4504390	0.23
1173.2640380	1.18
1181.3354490	0.50
1182.4985350	0.21
1199.1677250	17.86
1200.1320800	2.18
1200.9895020	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	568.3115
Annotation	Unknow
Peak:m/z	Relative Intensity
163.1148071	0.01
171.1136932	0.01
199.4041595	0.01
208.4232025	0.04
236.5108948	0.04
244.3413086	0.07
286.2319336	0.94
287.2632141	0.02
288.4358521	0.02
292.4199219	0.09
296.7501831	0.01
298.2894287	0.02
309.4498291	0.01
316.4641113	0.01
318.0593262	0.01
320.2271729	0.02
344.3725586	0.30
347.2124023	0.02
359.0770264	0.03
361.1347656	0.03
362.3924561	0.17
368.2516479	0.02
380.5624390	0.04
384.3629761	0.04
386.3060913	0.18
389.0097046	0.05
391.9024048	0.03
393.3244019	0.02
400.9454346	0.02
404.3710327	0.52
405.1791382	0.06
406.1171265	0.10
414.3861084	0.05
420.4542236	0.18
422.3485107	100.00
428.5270996	0.06
432.2480469	0.84
434.0883789	0.03
438.0090332	0.04
439.2899170	0.09
441.3332520	0.02
444.5520020	0.03
453.1942749	0.02
454.3901978	0.09
462.7485352	0.04
464.1222534	0.32
464.8508301	0.07
472.5617676	0.16
482.4222412	0.06
484.1906738	0.09
494.5155029	0.04
504.9783325	0.01
506.7931519	0.01
508.4208374	0.18
514.4412231	0.01
522.1189575	0.02
529.9993286	0.02
532.3772583	1.98
533.0244141	0.07
536.1261597	0.04
550.4797974	4.91
551.3786011	0.02
553.0963745	0.03
554.0627441	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	820.4965
Annotation	PI(14:0/18:4(6Z,9Z,12Z,15Z))
Peak:m/z	Relative Intensity
235.2133484	0.23
236.3168335	0.14
249.0489502	0.11
251.2066498	0.26
253.1510773	0.18
255.0541992	0.14
262.1026917	0.04
265.0388184	0.67
267.3290100	0.04
269.2138672	0.17
271.2173462	0.27
278.9182739	0.07
295.0947266	0.10
307.1654663	0.10
309.1277161	1.03
311.2961426	0.68
313.2665405	0.41
315.1036682	0.08
323.2065430	0.39
327.1336975	0.10
329.3097839	5.25
331.1765747	0.06
334.7716675	0.10
339.2167969	0.10
351.3737183	0.16
353.3191833	0.85
355.0327759	0.43
357.1497803	0.38
365.2972412	0.06
371.1164856	0.99
373.1683350	1.64
375.2092285	0.34
397.1265259	1.51
399.1364746	0.25
401.3488770	0.41
403.4241333	0.09
415.3288574	0.21
417.0816650	0.40
418.2157593	0.04
419.1063843	0.70
429.2917480	0.23
431.2144775	0.13
433.2601929	0.52
434.9836426	0.34
441.0364380	0.06
443.3398438	0.07
445.2810059	0.34
452.1807251	0.03
458.6585083	0.21
459.5479126	0.04
461.2254639	0.38
463.3486938	0.63
474.6683960	0.19
475.3605347	0.02
477.3587036	5.43
479.0465698	0.65
487.3031616	0.31
489.3690796	0.13
491.2833252	0.30
496.5588989	0.03
503.2833252	0.54
505.1035156	0.83
507.2180176	1.20
508.2080078	0.11
520.8447876	2.10
521.4473267	0.65
523.2169800	0.74
525.3196411	0.02
539.5109253	0.04
546.2909546	0.19
547.3539429	0.22
549.0557251	0.29
549.6591797	0.11
551.1652832	0.30
565.2911987	0.04
567.3598633	0.95
572.8916626	0.08
583.3056030	0.63
593.4168091	0.89
595.2933350	6.15
608.7519531	0.48
611.2773438	2.91
618.7168579	0.04
620.8619385	0.06
627.2710571	0.04
637.3536987	0.20
645.5417480	0.06
648.2855225	0.17
653.0648804	0.46
655.3253784	2.13
669.3799438	0.21
671.1791382	0.23
675.3198242	0.04
681.0464478	0.75
686.3524780	0.10
687.6142578	0.18
695.9470825	0.28
697.2628174	1.72
699.3400879	60.14
715.3568726	1.98
729.3217163	0.16
741.4582520	0.58
749.7219238	0.20
755.9060669	0.02
758.7932739	0.13
759.4515381	1.75
761.4728394	1.85
763.5829468	0.05
773.8929443	0.20
777.2251587	0.17
781.7249756	0.09
785.2337036	1.21
787.9147949	0.08
803.2634277	100.00
803.9414673	0.79
819.7666626	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	743.13
Annotation	Unknow
Peak:m/z	Relative Intensity
209.1090240	9.75
335.0640869	0.17
353.1932983	6.55
371.1035767	100.00
372.1942139	0.76
435.1713257	0.22
478.3843994	0.06
532.8013916	0.83
533.4357300	0.25
537.4807129	0.07
547.1305542	0.05
556.9462891	0.04
562.9426880	0.14
574.2882690	0.12
575.0998535	0.25
580.7739258	2.26
581.9071655	0.35
600.3378296	0.08
606.2031250	0.03
714.6751099	0.03
724.9418335	1.63
726.1125488	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	588.9
Annotation	Unknow
Peak:m/z	Relative Intensity
174.8948364	0.09
206.7892303	0.06
273.0371704	1.62
274.4090881	0.16
275.2776489	0.32
358.9606934	0.37
361.0394287	0.48
387.0336914	0.16
388.1170044	0.06
388.8746338	0.17
404.0339966	0.20
427.1361084	1.11
428.0508423	1.63
429.0173340	3.78
442.9992676	0.52
458.1973267	0.05
459.0381470	0.16
473.0750732	1.08
473.9995117	1.24
474.9047852	3.14
487.9447021	0.04
501.1766968	0.18
503.5614624	0.03
520.9367676	0.12
530.4319458	0.27
535.2449341	0.06
541.8275757	73.57
542.9251099	100.00
543.9640503	0.21
544.9773560	0.17
546.6397705	0.08
547.2507324	0.06
556.9737549	0.40
558.3388062	0.17
560.8760986	1.07
570.2984009	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	531.1146
Annotation	6,7,3',4'-Tetrahydroxyaurone 6-(4'',6''-diacetylglucoside)
Peak:m/z	Relative Intensity
154.8776855	0.20
160.9150085	1.08
163.0548706	0.27
167.7486267	0.04
172.9912262	0.62
178.9179993	0.61
183.1790161	0.13
187.0223083	1.13
191.1011505	0.53
193.1591492	0.10
197.1557770	0.14
200.7865906	0.31
203.0811615	0.15
204.9267731	5.58
213.0299530	0.20
223.0611115	12.26
229.0310669	0.46
230.9521484	0.05
241.4171143	0.13
247.1668854	0.52
257.1764832	0.06
265.4550781	0.14
270.4367065	0.22
273.1116943	1.03
275.1463013	0.46
279.0523071	0.19
286.9813232	0.55
290.9462891	0.41
292.9185486	0.13
297.3551025	0.21
305.3455505	0.30
306.7326050	0.18
309.5239258	0.07
322.9751587	1.18
324.4511719	0.18
325.3472290	0.12
327.2094116	0.13
329.9838257	0.09
333.4736328	1.86
335.1203003	0.66
346.8075562	0.11
349.1137085	3.66
350.6673584	2.07
351.3919067	1.61
353.0719604	1.68
361.1770020	0.16
367.0991211	5.73
369.0987549	100.00
370.0437622	0.07
371.5585327	0.05
385.1796875	23.41
389.0358887	0.12
393.4468384	0.28
398.1822510	0.52
399.3330688	0.18
400.3054199	0.23
408.1425171	0.28
409.1032715	0.07
410.5548096	0.08
435.3317871	0.21
439.0393677	0.26
443.2731323	0.22
445.0807495	0.18
456.8787842	0.08
463.0937500	0.61
464.1846313	0.31
467.2352905	0.21
469.4727173	0.17
471.4759521	0.27
476.1286621	0.59
480.7706909	0.60
484.3989258	0.15
485.2559204	1.16
486.5354004	0.41
487.2928467	0.18
488.4342041	0.19
489.6050415	0.13
492.0128174	0.22
493.1315308	0.08
494.5644531	1.27
495.3049316	0.55
496.2732544	0.12
503.4076538	0.05
513.0181274	2.65
513.8693237	0.21
515.8109131	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	423.9533
Annotation	Unknow
Peak:m/z	Relative Intensity
182.8654785	0.15
224.2321472	0.34
230.9870300	0.08
245.2037659	0.11
297.1892090	0.28
307.4946899	0.37
309.9505615	2.00
310.9945374	0.94
312.9020081	0.31
314.9748535	0.20
324.2155151	0.19
326.9930420	0.20
328.0122681	0.36
329.0962524	0.11
336.9033813	0.47
342.0696411	0.10
344.8036194	0.24
350.0676575	0.14
351.1830139	0.29
352.9489136	0.18
366.0169373	0.26
369.0394592	0.07
377.3567200	0.48
378.1180115	0.58
379.1094360	0.06
379.8952942	0.62
382.9972229	100.00
388.0137024	0.06
394.1963806	0.35
396.0883789	0.14
397.1875000	0.17
397.8786316	0.23
398.8050842	0.05
400.3497620	19.31
401.0241394	0.84
403.1324463	0.15
405.1884155	0.14
411.7077942	0.21
413.8625183	0.10
417.2118530	0.14
423.8702087	0.78
427.6235657	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	398.2526
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9152222	0.01
115.9541321	0.11
116.9703445	0.01
119.7690659	0.01
120.9143448	0.01
124.2348938	0.02
129.1936340	0.09
131.4304352	0.04
132.0438232	0.80
133.0523987	0.11
141.1734619	0.04
143.0697937	0.14
143.9922791	0.02
145.0715942	0.12
146.1242065	0.01
149.2837677	0.01
156.1291199	0.01
157.2736206	0.01
157.8811035	0.02
158.8945160	0.03
160.5443115	0.16
161.2630920	0.02
162.2017517	0.03
162.8130188	0.05
164.0186157	0.04
166.2792816	0.01
167.2622375	0.01
169.0997009	0.09
172.1136322	0.02
173.0010376	0.01
174.0330811	0.02
176.1782074	0.17
177.7562256	0.06
179.3889160	0.01
183.1010895	0.10
190.5612793	0.01
192.1940918	0.14
193.7463989	0.14
194.5153503	0.01
198.3187256	0.08
199.1770020	0.04
200.6384277	0.05
204.1504211	0.08
205.3033752	0.01
206.5502319	0.16
207.1929169	0.05
208.4258118	0.04
209.8639069	0.02
211.1524048	0.57
212.0352173	0.08
216.2706299	0.07
217.2988586	0.04
218.1871338	0.11
222.1415405	0.39
223.1967773	0.05
224.1892395	0.13
224.9824829	0.06
226.3673096	0.07
227.1355896	0.04
229.1593018	0.09
230.2956543	0.13
233.3600159	0.03
233.9806519	0.01
237.4320984	0.01
239.3619690	0.01
240.1875305	0.27
241.0967712	0.13
242.2811584	0.17
243.2816772	0.04
244.3455811	0.08
246.2868042	0.04
247.1705017	0.18
248.0870361	0.07
249.1198730	0.05
251.4036560	0.02
254.1466064	0.01
256.4705200	0.03
258.1659546	0.63
259.3054199	0.29
260.2469177	0.30
261.1816101	0.12
262.3227844	0.03
263.0918579	0.08
264.3336792	0.02
266.3077087	0.06
267.3703003	0.02
268.5559692	0.01
270.2032776	0.02
271.1730347	0.01
272.5135803	0.06
273.1475525	0.04
276.3403015	0.89
277.2628784	0.15
278.2893677	0.62
279.5541382	0.15
280.4113770	0.18
282.1726990	0.15
284.2072144	0.10
285.4316711	0.03
286.3530884	0.58
287.3082275	0.09
288.4111938	0.05
289.5002441	0.05
290.2018127	0.25
291.1862183	0.20
292.4816895	0.05
294.4359131	0.01
296.3710327	2.95
297.3511047	1.20
298.3542480	0.46
299.2926636	0.10
300.3399353	0.12
301.8331909	0.22
302.4811707	0.68
303.4671021	0.23
304.2959595	0.23
305.2548218	0.13
308.2493286	3.60
309.2948914	2.07
314.2721252	5.12
315.3789673	1.52
316.5029907	0.15
317.4266663	0.10
320.1997681	1.79
321.3441467	0.67
324.2058105	0.02
325.0167847	0.11
326.2876587	11.63
327.3974915	3.39
332.3172607	0.21
333.4764099	0.15
334.4028931	0.14
335.5339050	0.11
344.3052368	11.96
345.3788452	4.92
353.0929565	0.03
362.3193054	17.84
363.3954163	7.16
378.7887573	0.01
380.3207092	100.00
381.2901306	35.58
381.9201660	0.05
385.3606873	0.02
390.3157043	0.11
394.0471802	0.01
399.0762024	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	365.1814
Annotation	(1R*,2R*,4R*,8S*)-p-Menthane-1,2,8,9-tetrol 9-glucoside
Peak:m/z	Relative Intensity
108.9881668	0.08
111.0883102	0.27
112.0037994	0.07
113.0779266	1.22
114.7721329	0.05
118.9639511	0.56
122.8977737	0.05
126.9517593	0.65
130.9790649	0.32
137.1356506	0.14
139.0299072	0.19
143.0764160	0.52
148.9191895	0.45
154.9324951	0.94
157.1674805	6.07
158.9464722	0.21
161.1407928	1.12
169.2795868	0.21
171.1972046	1.26
173.0497284	0.06
178.8988953	0.42
181.3456268	0.44
185.0951843	2.91
187.1142578	1.72
191.0672302	0.09
193.2569885	0.29
197.9144592	0.11
199.1986542	9.05
201.2918701	0.87
203.1331787	100.00
204.0853729	0.05
205.0280609	0.95
209.9716492	0.07
211.1380920	0.06
215.1076660	0.16
216.9222260	0.20
223.3444214	0.24
227.1017761	0.21
232.3555603	0.05
237.6944885	0.13
238.9656067	0.12
243.1009521	1.75
245.2119446	7.52
247.2289734	0.14
255.1533813	0.09
257.2972717	2.12
258.9173279	0.08
267.1377258	0.05
268.4417725	0.14
275.0722046	0.28
278.1550598	0.06
282.8701477	0.03
285.4682617	0.05
290.8478088	0.05
293.0856628	0.12
297.3154297	0.07
303.1763611	0.15
304.7666931	0.44
305.4002686	0.35
307.2826233	0.08
311.6339111	0.14
319.2247620	0.77
320.2217407	0.08
321.2697754	0.46
323.0239258	0.11
323.8864746	0.11
329.3086853	0.03
332.6040649	0.15
333.6475525	0.11
335.3483887	0.09
337.2583008	0.04
347.2406616	13.73
348.4610901	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	925.1683
Annotation	Unknow
Peak:m/z	Relative Intensity
311.2517700	0.02
319.0682373	0.06
355.3507080	0.24
388.9969482	0.11
393.2296143	0.07
397.2611694	0.02
405.4131470	0.03
406.8698730	0.08
407.6196289	0.06
419.1693115	0.02
421.0238037	0.07
430.2905273	0.09
431.0921631	0.03
433.2477417	0.06
442.2689209	0.04
446.1726685	0.08
451.1768799	0.25
461.0582275	0.03
475.2259521	0.04
479.2526245	0.21
492.2428589	0.03
493.1583252	0.03
511.1331787	0.01
514.3948364	0.05
524.0029297	0.04
533.3205566	0.02
569.1922607	0.34
573.0889282	0.14
581.0645752	0.10
583.2264404	2.98
593.4138794	0.04
597.4539795	0.02
599.8993530	0.25
601.2141724	20.43
608.2312622	0.02
610.9988403	0.07
619.3411865	0.08
620.8578491	0.03
625.1681519	0.04
626.9191895	0.05
627.7034912	0.02
631.3074951	0.11
641.1835327	1.09
642.7463989	0.07
643.3649902	0.07
649.3934326	0.08
653.1350098	0.04
654.2528076	0.03
655.1786499	0.03
657.5241699	0.06
719.2823486	0.05
727.0267944	0.04
745.2454224	1.72
761.3838501	0.24
763.1848755	100.00
763.9016724	0.34
789.4189453	0.19
790.4117432	0.03
805.3912964	0.02
809.2678833	0.03
815.1420288	0.03
823.7896118	0.07
835.5061646	0.04
839.6641235	0.05
850.7725220	0.03
862.4070435	0.02
876.5108643	0.07
881.1997681	0.08
907.2081909	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.9715
Annotation	Unknow
Peak:m/z	Relative Intensity
141.0054626	0.01
179.1631012	0.01
199.0910950	0.02
199.7149963	0.01
205.2380066	0.01
215.2264099	0.04
216.3986359	0.02
219.4336243	0.03
221.0487366	0.01
226.9776459	0.03
228.1796417	0.01
231.0932312	0.01
234.2958984	0.02
240.3392639	0.02
241.1368713	0.03
242.1129456	0.03
245.0997009	0.06
247.1429138	0.02
254.8891296	0.01
257.8044434	0.04
258.5446777	0.03
259.3194580	0.11
260.0848999	0.06
271.9183655	0.01
273.4465637	0.02
275.6524048	0.05
286.2163391	0.06
290.5830994	0.09
291.2932739	0.06
292.1492310	0.02
298.1959839	0.01
303.1905518	0.05
304.0540771	0.09
305.4263000	0.01
308.1945190	0.25
309.2550659	0.12
310.2712402	0.07
313.0528564	0.00
313.9437866	0.01
322.0562439	0.03
325.8782043	0.00
326.9875488	0.03
329.1083984	0.01
329.9686584	0.07
330.9185181	0.17
331.9356995	0.42
333.1090698	0.06
334.0718994	0.04
339.2026978	0.02
340.2509460	0.05
344.0437622	0.09
346.8812561	0.18
347.9603271	0.99
349.9827271	0.01
353.1144714	0.03
358.0151672	0.05
362.1368103	0.02
363.2255249	0.03
364.5275574	0.04
374.9467773	0.08
376.0137329	0.20
376.7956238	0.07
379.0197449	0.01
384.0000916	0.06
391.2053223	0.02
394.0037537	100.00
394.8406677	0.00
401.0259705	0.33
402.3611145	0.10
405.0727844	0.05
405.9711914	0.02
419.0404968	3.60
420.0769958	2.01
421.2991028	0.16
429.2276917	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	401.145
Annotation	Benzyl beta-primeveroside
Peak:m/z	Relative Intensity
112.9460068	0.21
123.0622559	0.21
125.0041199	1.54
126.8842239	0.06
128.9545288	0.20
130.9419861	6.05
136.9471436	1.82
138.8426208	0.20
142.8677673	1.43
148.9649048	6.69
150.9064941	0.24
155.1487274	0.38
159.0146179	0.93
161.0539551	14.90
169.0615082	0.08
171.3030396	0.23
175.4734192	0.10
178.0403137	0.33
187.0641174	0.81
190.9563599	3.79
192.0653381	0.43
193.1831665	0.26
203.1981201	0.45
206.1349030	0.07
209.2512512	0.03
215.2273560	1.04
220.8819122	0.08
222.4164886	0.17
223.1573486	0.86
224.2197418	0.14
228.1403198	0.08
233.1150818	4.95
236.1963196	0.06
237.1333313	0.75
238.0147705	2.31
239.0293579	0.47
241.1704712	0.05
243.4237061	0.36
250.1481323	0.25
251.1995544	2.81
267.0973816	0.51
269.1321716	100.00
285.1627808	0.16
287.0846863	0.11
293.1696777	3.50
309.2755127	0.09
310.4850769	0.13
311.1110229	0.30
340.1579895	0.06
340.9997864	0.74
343.1127625	0.12
345.0141602	0.09
353.4243469	0.09
354.3042908	0.21
355.3577271	0.39
356.1770935	0.33
357.2230530	0.36
359.4134827	0.05
364.2654724	0.44
365.4416504	0.13
366.3126526	0.25
371.5716858	0.25
378.6178894	0.07
383.4576416	1.69
385.2956848	0.12
386.2396851	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
132.9301147	7.05
158.0628357	5.99
173.1394958	8.32
178.0107422	2.81
184.8699646	7.36
227.2253113	2.39
252.4767151	6.20
265.6438904	3.66
276.5380249	3.87
277.3988647	10.86
281.2287292	4.03
284.3529663	11.30
305.2173462	4.63
311.1936951	8.91
319.1295776	7.37
324.3900757	14.51
328.3421936	14.71
332.4331665	3.45
335.1428833	3.87
338.9797058	8.25
341.496521	8.62
352.3625488	11.85
357.3389282	5.69
358.0337524	7.58
362.2973022	2.17
365.2712708	7.42
366.4094849	18.84
367.3359985	28.89
369.3813171	2.39
380.3922424	12.35
385.1255188	21.53
385.9806519	21.61
390.5979004	21.18
391.2648621	1.92
395.2162781	8.82
398.0514221	6.09
402.3679199	3.66
408.2685852	100.00
409.6517029	13.48
410.4123535	9.39
411.211731	14.12
417.4219666	7.77
425.537262	9.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
81.01110077	1.43
83.76839447	1.14
94.90155029	6.35
97.13091278	1.26
98.947052	2.72
102.8481293	5.33
106.0426178	2.29
106.9463806	4.41
108.7919464	1.02
111.138382	4.40
112.0513916	0.84
112.9299316	4.14
124.2172546	1.36
125.8531036	0.96
127.2199707	1.88
127.9572296	0.99
129.0135956	17.19
133.0502014	2.59
135.0214539	0.71
137.0064392	4.70
139.0079803	2.07
140.7001648	1.18
145.1185455	5.20
146.9958801	2.71
149.0609131	6.29
150.9786377	89.52
151.9274292	5.12
153.17836	1.93
155.2590332	4.35
156.1880341	2.75
161.1207123	6.32
165.1427155	8.43
166.9341583	6.00
168.9628296	0.59
174.9365082	2.25
176.548996	5.90
177.4908295	1.82
179.1919861	11.33
182.0672455	1.27
183.0507507	2.10
184.9547882	5.33
189.036972	8.17
193.226593	8.39
194.2599945	3.89
195.212677	8.86
197.1200714	24.05
199.1900024	8.72
204.7676239	3.57
207.1443634	17.57
209.2054291	2.74
211.1009369	10.63
217.2605743	35.33
220.2241669	0.90
222.9830627	0.77
225.0055695	17.43
225.956543	5.19
229.9137421	1.86
234.0305023	1.51
235.1728363	50.62
236.4700775	1.48
238.22229	23.09
239.0093994	6.42
243.9376068	2.50
253.083313	100.00
253.9556274	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	209.0303
Annotation	Glucaric acid
Peak:m/z	Relative Intensity
84.9388580	8.93
102.9519958	0.15
111.0136719	0.02
129.0166626	1.29
133.0161743	0.33
147.0822754	1.92
160.6852570	0.05
162.8959503	0.08
165.1060638	0.10
173.0407104	1.21
178.8280029	0.04
190.9539032	100.00
193.7206879	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	801.2977
Annotation	Kotschyin C
Peak:m/z	Relative Intensity
229.1895599	0.11
241.2093048	0.06
246.9885254	0.04
251.1759033	0.11
254.1673889	0.03
255.3385925	0.09
257.1209412	0.47
267.4014282	0.11
269.2937012	0.04
281.2059937	0.03
283.2717590	0.67
301.3663025	0.26
307.2117310	0.02
309.4795837	0.15
311.1666260	0.19
321.1304016	0.05
321.7683411	0.09
326.4252319	0.06
337.3015137	1.35
338.0648193	0.14
339.3303833	0.30
341.0998535	0.04
343.4584656	0.32
354.9702759	0.06
356.2528076	0.09
359.0208130	0.10
362.4982300	0.04
363.4771118	0.18
364.1492615	0.11
365.3865662	0.21
369.5503540	0.10
373.2229004	0.15
398.3435059	0.22
399.4705811	0.26
403.2229004	1.18
417.4808960	0.04
426.3040161	0.06
433.0993042	0.15
441.2295532	0.12
444.4672852	0.05
454.0338135	0.05
455.0722046	0.12
458.0522461	0.25
463.2120972	0.22
469.2501831	0.05
470.4316406	0.05
473.3894043	0.09
474.2534180	0.13
481.2314453	0.13
483.1784668	0.11
484.1842651	0.02
485.2192383	0.14
486.1881104	0.04
487.2086182	0.69
499.3247070	0.70
505.4395142	0.07
511.5515137	0.03
512.9940796	0.22
513.6292725	0.02
515.2485962	0.04
517.3630371	2.24
519.4136353	3.07
523.2902222	0.07
525.2014160	0.07
527.6603394	0.27
529.0714111	0.07
531.2921753	0.41
541.1773071	0.14
542.5921021	0.38
543.3140259	0.21
545.3277588	0.38
547.4259033	0.06
557.2963867	0.13
561.4220581	0.06
563.3961792	0.12
567.3275757	0.05
568.4544678	2.02
569.1889648	0.13
570.2626343	0.05
571.2304688	1.09
581.4685669	0.10
582.4052124	0.10
583.6221313	0.05
585.5720825	0.23
589.0194092	0.08
591.0761108	0.03
592.3417358	0.10
593.4493408	0.10
594.4371338	0.46
595.4461670	0.04
597.4973145	0.12
598.4574585	0.08
600.4531250	0.19
603.4970093	0.13
606.5618896	0.23
607.4390259	0.03
608.3208618	0.46
611.6052856	0.16
614.2039795	0.12
620.4485474	0.03
621.2650757	0.40
633.3667603	0.02
634.3408813	0.03
635.1663818	0.09
636.4273071	0.08
639.3544312	0.26
640.7822266	0.38
646.3366699	0.32
649.2029419	0.09
653.3297119	0.25
657.5006714	0.04
658.5521240	0.19
659.6617432	0.24
660.5345459	0.04
662.2993774	0.19
663.4664917	0.20
664.6008911	0.49
665.5210571	0.56
666.4079590	0.26
667.1583862	0.14
672.5430298	0.07
678.3493042	0.57
679.3218994	0.48
681.3854370	0.16
683.7670288	0.19
688.7036743	0.11
690.3963013	0.04
697.5861206	0.51
701.5173340	0.18
705.3926392	0.35
706.6215210	0.02
707.5394897	0.08
709.4024658	0.05
713.4998169	0.06
714.6255493	0.09
719.8029785	0.10
724.2669067	0.10
725.4125977	7.30
726.4294434	0.85
727.3741455	0.47
729.3079834	0.69
732.6334229	0.09
737.4113770	0.06
740.8719482	0.30
741.6432495	0.57
751.2442627	1.92
755.1893311	0.05
756.4380493	0.30
757.4060669	0.36
758.3645630	1.89
759.2067261	0.03
769.3093872	100.00
770.2854614	0.07
772.3818970	0.16
773.3976440	1.61
781.1616821	0.17
783.4947510	3.79
785.2004395	0.05
786.2854614	0.06
801.2619019	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	785.3031
Annotation	Unknow
Peak:m/z	Relative Intensity
221.8914185	0.04
239.0439148	0.02
241.3198853	0.02
279.1282654	0.01
285.1849060	0.06
285.8773193	0.01
296.1560364	0.05
305.2591553	0.03
309.2722473	0.01
327.3305054	0.11
328.1763306	0.03
337.3956909	0.05
338.1361694	0.02
340.6251221	0.02
341.2653198	0.02
357.6901550	0.05
358.3641968	0.03
367.7656250	0.05
375.3284912	0.02
384.4299927	0.09
385.0941162	0.02
386.2968750	0.07
387.4372559	0.05
388.2152710	0.09
389.2504272	0.02
391.2705688	0.02
404.4745483	0.03
409.2816772	0.02
412.1921387	0.11
413.4612427	0.02
414.4104614	0.04
415.3134766	0.03
417.5572510	0.03
425.4660034	0.02
428.6376343	0.02
432.1776733	0.06
438.4171753	0.02
439.3929443	0.01
443.6161499	0.04
449.4353027	0.01
454.1810303	0.03
458.1713867	0.06
459.2001343	0.03
467.1037598	0.05
470.2343750	0.07
472.5350342	0.10
477.0918579	0.01
479.5822144	0.01
483.2791138	0.04
499.4758301	0.07
500.2995605	0.06
502.5536499	0.02
503.9642944	0.01
505.4335327	0.01
517.2550049	0.04
520.3893433	0.03
532.0502319	0.07
533.3682861	0.20
534.2719116	0.05
537.2601318	0.03
538.3817749	0.01
547.4517212	0.09
548.5358276	0.01
549.4141235	0.01
550.2755127	0.05
551.3909302	0.07
555.6182251	0.02
556.4295654	0.02
561.3284302	0.02
561.9492798	0.02
563.2515259	0.06
564.1806641	0.01
565.8242798	0.02
566.4756470	0.02
569.5769653	0.02
572.6273804	0.02
573.4371948	0.05
574.3703613	0.10
575.2876587	0.01
577.4273682	0.02
581.7036743	0.02
587.6187134	0.02
589.5639038	0.02
591.3255005	0.93
592.3809204	1.41
593.4016724	0.54
594.4885254	0.11
595.6237793	0.03
605.4357300	0.11
606.2994995	0.07
608.5483398	0.05
609.5991211	0.15
610.3555908	0.01
611.7328491	0.06
612.3457642	0.01
615.4557495	0.09
616.4204712	0.05
617.6457520	0.08
618.5197144	0.04
619.3633423	0.08
623.4703369	0.24
624.4696655	0.20
625.4950562	0.08
631.3051758	0.13
633.4254761	0.23
634.4087524	0.17
644.8419189	0.03
645.8707886	0.03
647.2764282	0.08
649.3562012	0.02
650.4768677	0.05
651.2485962	0.30
652.4486694	0.07
654.6340942	0.01
663.4784546	0.05
664.5266724	0.02
665.4533081	0.33
666.3906860	0.16
667.1577148	0.03
681.4666138	0.46
682.3925171	0.14
684.4335938	0.06
685.3656616	0.92
686.3822632	0.49
691.7444458	0.01
693.1355591	0.04
694.2863159	0.11
695.5174561	0.02
699.4421387	0.01
701.5764771	0.02
709.4198608	0.61
711.2468262	3.17
712.3804321	2.92
713.4727783	1.13
714.5029297	0.26
715.5599976	0.04
724.1549683	0.09
725.3556519	1.06
726.4575195	0.29
731.3618774	0.02
735.3568726	0.53
736.5424194	0.40
740.4484253	0.02
741.5626831	0.13
742.4960327	0.05
750.2904663	0.01
751.4948120	0.02
753.4099121	100.00
754.3567505	43.46
755.0281372	0.16
757.3907471	1.07
758.4508667	0.47
767.5180054	0.42
768.5230103	0.19
770.3287964	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	365.0334
Annotation	Unknow
Peak:m/z	Relative Intensity
118.9925995	3.36
121.0189667	0.04
135.2587585	0.15
137.0706329	0.19
152.0781555	0.03
163.0688477	0.36
183.0283661	0.04
194.2208252	0.10
198.9557800	100.00
214.9960632	25.84
224.2877502	0.05
232.5794678	0.24
241.4092712	0.08
242.9680786	23.64
245.3184204	0.08
248.1731262	0.07
250.0155029	0.05
250.8293457	0.12
267.2417603	0.09
269.1148987	0.03
270.2523499	0.05
281.2231445	0.10
283.1277771	0.06
285.0489807	0.72
286.6866455	0.04
291.0993042	0.12
294.0639648	0.10
297.1844482	0.09
303.3612976	0.11
304.1571655	0.07
305.1365051	0.12
307.0770569	0.04
308.1921082	0.17
311.0873413	0.28
319.2027893	0.10
320.5488281	0.23
321.3684387	0.61
328.2816467	0.12
329.0011902	0.25
332.3077087	0.04
335.4001160	0.07
337.1179504	0.17
344.1791077	0.06
346.1817322	0.10
347.1148376	0.57
349.1346130	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.0778
Annotation	O-Feruloylgalactarate
Peak:m/z	Relative Intensity
110.8896332	0.19
128.9204407	2.99
150.8767700	0.22
161.1983337	0.31
179.0564270	0.21
180.9468231	0.08
186.9417725	0.15
191.0678101	0.76
203.0494690	0.22
205.0590820	9.43
223.0371399	100.00
233.0811768	0.08
246.9994812	1.26
269.3247986	0.09
277.0387878	0.12
298.6011047	0.09
309.2926636	0.09
310.9934082	0.16
323.1907959	0.10
326.4674072	0.15
339.0776367	0.17
339.9246826	0.18
340.9979858	1.08
342.1712952	0.15
348.9575806	0.61
352.7023621	0.15
357.3350220	0.42
367.1896362	7.00
370.1005554	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	680.246
Annotation	Unknow
Peak:m/z	Relative Intensity
215.4264679	0.04
240.2027740	0.06
248.3235016	0.07
265.2438660	0.20
277.3066406	0.20
279.1982727	0.25
281.1918640	0.05
282.1031189	0.04
289.2607422	0.08
291.0226440	0.10
293.0526123	0.08
294.3287964	0.04
295.3303833	0.01
305.2781982	0.06
307.4281921	0.12
311.3000488	0.11
313.0991516	0.04
314.3752747	0.03
321.3721924	0.08
327.1799316	0.07
332.8991089	0.03
334.4390564	0.11
337.2957153	0.08
338.1075439	0.05
339.0655823	0.01
349.3301392	0.04
351.0859985	0.02
353.2890625	0.74
355.2729492	0.09
365.3561401	0.03
370.9682617	0.07
373.4041748	0.06
385.9636841	0.04
396.4174805	0.03
398.2619629	0.08
413.8897705	0.12
415.5473633	0.07
422.4077759	0.03
424.3624878	0.33
426.2564697	0.05
427.3958130	0.04
428.2777710	0.03
440.3786011	0.09
442.2738647	2.80
442.9302979	0.01
444.3018188	0.06
449.8568115	0.20
450.4873657	0.32
452.3095093	0.19
453.0708008	0.10
454.4512939	0.28
456.2697144	0.05
458.1616211	0.04
459.3652954	0.16
460.3757935	0.56
461.0850830	0.08
468.2591553	1.16
469.3721924	0.05
470.3275146	0.21
473.4254761	0.18
474.4669189	0.02
476.3283081	0.04
477.3260498	0.04
482.4005737	0.35
483.2859497	0.29
484.4218750	0.17
485.7155151	0.43
486.3766479	2.11
487.2156982	0.29
494.2658691	0.11
499.3925781	0.03
500.4476929	1.12
504.4547729	0.42
506.1761475	0.05
510.5587158	0.23
517.6115723	0.69
518.3284912	1.07
520.3922119	0.08
527.1840210	0.10
528.3036499	0.63
532.3316040	0.13
536.3272705	0.06
540.4609985	0.09
542.4085083	0.26
546.4306030	0.31
548.5584717	0.06
550.9049683	0.10
552.4744873	0.07
558.0914917	0.18
560.3587646	1.30
561.3669434	0.03
563.2733765	0.04
573.9928589	0.07
576.3933716	0.49
580.0045776	0.59
580.6687622	0.51
581.9551392	0.05
586.3367310	0.24
589.0879517	0.09
598.0856323	0.05
600.4733276	0.05
602.5131836	0.13
604.3526001	1.93
606.6847534	1.09
607.3706665	2.83
608.3256226	0.43
612.6600952	0.10
617.4650269	0.15
619.1780396	0.10
620.4475098	2.76
630.3728638	5.16
632.8650513	0.34
633.5023193	0.45
634.3603516	0.16
636.3279419	0.09
639.1532593	0.08
642.2325439	0.15
644.6449585	0.07
648.2877808	100.00
649.4262695	0.28
650.4198608	0.22
652.3290405	3.66
653.4060059	0.22
662.2907715	2.57
666.0162354	0.05
671.2427368	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	288.9365
Annotation	Unknow
Peak:m/z	Relative Intensity
84.9183502	0.03
103.0224609	0.06
114.8125763	0.57
130.8587341	2.80
146.9540100	0.47
158.9545898	8.99
174.8782654	100.00
215.0911255	0.12
232.9755554	0.48
235.0412903	0.06
244.9132080	25.82
261.0249634	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.1373
Annotation	Cyanidin 3-(6''-caffeylglucoside)
Peak:m/z	Relative Intensity
174.8766479	0.07
179.0365295	0.15
199.0428467	0.09
201.2218933	0.06
202.9811096	0.17
206.8773346	0.09
212.9017334	0.14
217.1304016	0.21
221.3263702	0.05
227.2399597	0.17
229.2308960	0.19
230.9485168	0.06
233.3058624	0.25
235.1277466	0.02
241.0061493	0.63
245.1244354	1.61
247.3840485	0.14
257.1629028	0.29
259.1894531	0.73
263.1085205	3.91
264.1141357	0.04
269.1231689	0.24
274.5396118	0.14
275.2498169	1.42
277.1835938	2.20
287.1719971	10.54
289.0290527	2.11
299.2302856	2.13
301.2609253	0.13
305.0350952	24.83
307.1139832	10.65
307.9110718	0.06
311.2033997	0.77
313.0927734	0.05
317.0853271	12.01
318.0966797	0.08
319.2149048	0.39
327.3668213	0.06
328.0538330	0.15
329.1500244	0.51
345.1558228	0.06
349.1402588	0.28
355.1928711	0.06
356.4487915	0.11
359.3787231	0.03
390.0203857	0.05
407.1170654	0.16
421.0701294	0.11
425.1623535	12.42
425.8460083	0.05
426.5525513	0.24
430.9533691	0.02
437.2181396	0.84
439.3068237	0.31
440.9700928	0.05
443.1118774	100.00
449.2986450	1.06
455.1156006	1.13
457.1110229	0.02
459.0134888	0.08
460.0638428	0.06
467.1608276	5.85
467.8576660	0.07
470.7977295	0.16
473.0890503	0.07
484.9872437	5.06
485.6650391	0.14
507.2224731	0.17
574.0319214	0.16
575.2628174	0.39
581.4505615	0.21
583.4429321	0.08
593.1066284	3.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	807.3412
Annotation	Unknow
Peak:m/z	Relative Intensity
357.0920410	0.07
422.1703491	0.17
446.2747803	0.09
466.1069946	0.04
480.1549683	0.35
490.2002563	0.38
491.4489746	0.19
492.3681641	1.12
508.2482300	0.07
510.3187866	0.20
522.2679443	0.42
523.3339844	5.11
524.2522583	9.52
559.1993408	0.17
569.6546021	0.13
571.1098022	0.11
571.7194824	0.07
585.4187622	0.06
587.3856812	0.79
595.2119141	0.42
611.2399292	0.15
613.3300171	10.09
625.6644287	0.06
627.0466919	0.04
631.2546997	0.04
640.3969116	0.28
642.4249268	0.04
645.2406616	100.00
645.9330444	0.24
652.3511963	0.37
653.4797974	0.25
654.4267578	0.71
661.2520142	0.09
668.9116821	0.10
672.4037476	0.17
673.6478882	0.07
684.3897095	1.28
685.2976074	6.59
686.2905884	6.40
686.9174805	0.02
702.9013062	0.10
706.6959229	0.24
710.3017578	0.04
710.9902954	0.17
721.5297241	0.04
722.5601196	0.27
724.4618530	0.08
731.5615845	0.14
732.9189453	0.54
739.1895142	0.81
747.1947632	0.03
757.2916260	1.22
760.4171143	0.27
761.7210083	0.09
762.6007690	0.04
770.7355347	0.58
771.5140991	0.50
774.6059570	6.85
775.4299927	21.32
788.1481934	0.25
789.3765259	1.03
808.0651245	0.06
809.1113892	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	294
Annotation	Unknow
Peak:m/z	Relative Intensity
99.0064392	0.07
127.9620056	0.06
169.8555298	0.05
173.9241180	2.32
182.1220551	0.57
185.8733673	0.57
187.7764587	0.23
190.2704010	0.09
194.0462799	0.17
197.9087219	1.11
198.8233337	0.06
199.8530579	1.31
203.9839172	4.11
208.9248047	0.13
210.0012512	0.56
210.9902954	0.08
212.3955383	0.12
213.8960571	0.25
215.8962402	1.50
216.7767639	0.20
218.0338440	0.34
219.1598511	0.06
222.2313843	0.08
223.8689270	0.04
227.9238892	0.23
229.7940369	0.08
231.2414551	0.11
231.9901733	0.07
233.9573975	16.22
235.1093750	0.04
235.7353210	0.12
236.3414307	0.03
239.9706421	2.99
243.5237122	0.11
245.8568115	0.46
247.2588806	0.07
249.7356262	0.35
250.4092102	0.03
252.9313965	3.67
256.0066528	0.08
257.9384766	6.39
260.0740356	0.18
263.5541382	0.43
264.1629944	1.06
265.0503235	0.72
265.9792480	0.23
269.7630310	0.34
270.8804932	1.33
272.9358521	1.47
273.7133789	0.42
275.9840393	100.00
276.7703857	0.04
279.0290833	1.18
279.8715820	0.38
280.5904541	0.15
281.8401184	0.10
284.7116394	1.61
285.4188232	0.21
287.6911926	0.34
292.8973999	0.22
293.8865662	0.52
302.4559326	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	443.1472
Annotation	Bequinostatin D
Peak:m/z	Relative Intensity
132.9842834	0.70
135.9536438	0.15
143.0811615	0.10
161.0599213	4.75
168.9984131	0.07
171.0361938	0.26
187.8818054	0.45
193.0093994	18.28
195.0614319	0.08
204.4841919	0.11
205.0960999	0.08
206.0639648	0.11
216.1772766	0.07
227.1090546	0.25
231.2402191	0.35
233.2073212	1.27
234.1681824	3.06
237.3254700	0.16
251.1105347	100.00
263.3240662	0.03
267.8849487	0.15
279.8657532	0.17
281.1741333	0.39
290.4776611	0.08
296.1053772	0.17
303.2608032	0.13
310.5670776	0.10
311.4487000	0.19
312.4755249	0.16
313.3825684	0.27
314.0781860	2.15
317.0574646	0.07
324.0570984	0.29
328.0455933	0.05
341.0445251	0.14
347.8361816	0.64
356.2622070	0.07
367.5923157	0.05
379.1047058	0.12
380.2893677	0.11
384.0527344	0.75
385.3190002	0.17
386.4498901	0.49
396.6972961	0.28
397.3088074	0.23
398.9506836	0.09
402.2776184	0.19
408.2586365	0.10
409.9554138	0.04
413.4897766	0.04
415.2353821	0.33
420.8045959	0.05
422.9868469	0.42
424.1437073	0.48
425.2393799	1.12
426.1865540	1.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	705.1826
Annotation	Lychnose
Peak:m/z	Relative Intensity
201.1194763	0.03
219.3589935	0.06
281.6359863	0.18
361.3815308	0.02
362.2297974	2.70
363.1744385	3.89
381.1691284	9.17
453.1641846	0.35
490.1201782	0.23
525.2105103	25.37
533.0661621	13.62
533.7399902	5.13
534.3781738	0.23
537.2917480	0.09
543.2010498	100.00
543.8889771	0.40
593.1145020	0.28
615.2936401	0.81
645.3593140	0.21
687.1832886	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	437.0874
Annotation	5'-Demethoxycadensin G
Peak:m/z	Relative Intensity
152.9162292	0.05
188.9710083	0.10
196.1148834	0.06
217.0523987	0.08
218.0807648	0.02
220.6528778	0.07
223.1882935	0.05
247.2307434	0.04
254.9952698	0.05
267.4075623	0.03
276.9987793	0.13
296.8201599	0.05
303.1014709	0.03
309.9358215	0.11
341.0765991	0.06
363.2948303	0.08
366.1503601	0.14
375.2798157	0.08
377.7027283	0.11
379.4237976	0.05
384.0564880	0.12
389.0242004	0.15
391.3140564	0.30
392.0025330	0.04
393.0762634	0.27
394.3052673	0.55
395.0983276	0.04
400.3634033	0.13
401.2911072	0.48
402.2793274	0.36
403.4936829	0.09
406.2025146	0.30
407.1919250	0.46
408.2559509	0.30
409.1444397	0.32
410.2872009	0.20
413.0668335	0.03
419.1691284	3.75
420.2345581	1.69
422.1383362	100.00
423.1096497	29.50
424.1988831	2.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.1092
Annotation	Pratensein 7-O-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
161.2131805	0.24
172.8886414	1.56
177.0439301	0.05
178.9997864	0.89
191.0160217	14.11
193.1985931	0.30
209.1549377	2.91
215.3723450	0.08
223.0491943	0.04
243.4186554	0.28
245.0647888	0.11
246.9993286	0.09
259.3926697	0.10
261.3135376	0.11
270.8182068	0.05
275.3364868	0.09
278.1992188	0.06
291.0381470	0.38
292.2359619	0.17
293.1932373	0.29
297.3710327	0.10
299.2305603	0.10
304.8902588	0.29
306.3417969	0.09
309.2247620	2.66
313.4230347	0.08
322.0853271	0.04
323.1511841	0.77
332.2854004	0.04
335.2113037	2.91
337.5621948	0.09
338.9209595	0.10
341.2170410	0.44
347.2191162	0.12
348.6403198	0.27
349.4328003	0.08
351.3462524	0.06
353.1379395	14.62
357.1782227	0.21
367.1004028	13.40
371.1086426	6.74
371.7568359	0.03
385.0767822	100.00
385.6774292	0.38
390.0496216	0.07
391.3259277	0.08
396.0233154	0.12
397.1114502	0.13
398.3144531	0.05
410.2452393	0.09
413.4019165	0.07
414.1637573	0.13
415.3692017	0.08
425.3401489	0.10
428.9094849	0.06
431.1625366	0.19
441.2743530	0.06
444.2407837	0.12
449.2163086	0.32
450.4362793	0.15
451.2003174	0.12
461.4422607	0.12
463.3099976	0.13
467.1391602	0.06
479.2955933	0.20
483.8662109	0.17
484.4756470	0.40
485.4409790	0.12
500.1676636	1.97
501.0845337	2.30
502.4121704	0.04
503.2787476	0.57
508.5715332	0.07
509.9474487	0.64
511.0603027	0.54
512.1670532	0.14
513.9941406	0.10
515.0606079	0.14
528.5505981	0.65
529.2023315	5.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	513.3068
Annotation	Daechuine S7
Peak:m/z	Relative Intensity
153.1275787	0.03
157.0558472	0.05
161.1524506	0.03
168.8139343	0.04
171.2419739	0.03
179.0639954	0.06
200.7267914	0.06
213.2667236	0.13
233.3134918	0.83
235.1717072	1.29
245.5157166	0.04
253.1752625	7.84
259.3621826	0.06
270.9748840	0.04
275.3174744	0.24
277.2583008	100.00
277.8649292	0.51
285.0487061	0.06
297.0770264	0.04
339.3933716	0.22
369.3255005	0.09
382.4152832	0.11
383.4721680	0.13
398.2800903	0.03
399.3781128	0.17
409.9739990	0.06
410.9001465	0.03
418.9077759	0.02
423.7358398	0.03
437.2900391	0.05
438.1765747	0.04
440.4486084	0.04
442.4630737	0.04
448.9639893	0.19
452.4227295	0.79
453.3985596	0.67
455.4623413	0.02
467.2207031	0.44
469.3082886	0.28
475.0895386	0.05
477.1115112	0.25
478.2149658	0.33
483.2173462	0.05
494.9086914	0.52
495.5570679	0.12
496.3314209	0.07
499.2317505	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1245
Annotation	Theviridoside
Peak:m/z	Relative Intensity
122.4312210	0.05
123.0520020	0.10
126.1716003	0.02
131.1156006	0.01
132.8782501	0.03
134.9976654	0.07
138.9017487	0.01
149.1478577	0.24
152.1068115	0.04
153.1255951	0.03
161.2049103	0.18
162.9693909	0.02
165.2150574	0.02
167.1223450	0.41
175.2013855	0.02
176.0514526	0.05
177.2258911	0.05
179.0512085	0.39
180.0903015	0.01
182.0836792	0.61
189.0079193	0.03
190.8616943	0.04
195.0809937	0.43
197.1600800	5.78
203.1300354	0.02
205.0330353	0.11
206.0940552	0.09
206.9706879	0.06
208.1257782	0.17
209.0447388	0.01
221.2199249	0.03
223.0787048	2.14
226.0496216	5.48
235.0788269	0.01
238.9781494	0.08
241.1030579	100.00
242.9378967	0.03
253.1040039	0.03
254.6713562	0.03
259.2586365	0.03
265.1773376	0.13
266.3860779	0.03
271.0711060	0.07
274.8181152	0.02
279.2394104	0.01
283.1137695	1.18
286.2125854	0.09
295.4385071	0.02
299.1826782	0.03
300.1657715	0.12
301.1143799	0.04
305.2679138	0.04
307.3305664	0.06
313.1243896	0.29
315.3897400	0.03
316.0345154	0.04
323.3075867	0.06
325.0166016	0.04
328.4231262	0.03
331.3453979	0.06
334.1870728	0.04
341.2273254	0.02
343.0933533	1.14
343.9827271	0.01
356.8081055	0.37
357.4479065	0.26
359.2598572	0.14
360.0652466	0.02
366.8370056	0.08
367.4416199	0.01
368.5207214	0.02
381.9416809	0.08
384.3360291	0.11
385.2503967	0.80
386.1664124	0.10
388.2488708	0.05
403.1210022	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2256
Annotation	Lactulose
Peak:m/z	Relative Intensity
339.6955566	0.57
341.1510620	100.00
341.7524414	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.09
Annotation	Lactulose
Peak:m/z	Relative Intensity
119.1422348	0.03
142.9533234	0.02
160.2755127	0.03
161.2942810	0.01
179.0373383	0.59
196.9874573	0.72
215.0995331	8.63
221.0596313	0.02
341.2287903	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.1
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
143.0279694	0.11
147.1867371	0.12
151.0704651	8.88
161.1260681	0.25
163.2117920	0.11
164.0637512	0.10
164.8624725	0.03
168.9271088	0.09
174.1742554	0.05
176.8996277	0.34
179.0638428	0.14
185.0184326	0.18
189.0228271	0.05
192.9962158	0.05
195.1880341	0.12
199.1675720	0.06
200.9531555	0.08
202.5639343	0.31
215.4237061	0.12
218.3653412	0.15
220.9959564	0.22
229.1691284	0.20
230.2315216	0.75
231.3608704	0.10
241.4462891	0.11
243.8901672	0.08
252.8361816	0.17
255.1682434	0.04
257.1141052	0.13
258.3343201	0.61
259.1466370	0.15
265.5539551	0.06
267.3619995	0.63
271.1261597	0.10
272.9842224	0.19
276.9936523	0.07
281.1957397	0.15
283.2223816	0.12
284.2238159	0.07
285.1183167	1.56
288.9541016	0.15
290.0936279	0.20
294.0189209	0.05
297.1442261	0.13
299.5456543	0.33
300.1672058	0.19
301.2390137	1.47
303.0651855	100.00
303.6712646	0.24
304.3415833	0.27
307.0483704	0.08
311.0414429	0.09
313.1402588	34.78
318.8896484	0.09
327.1651001	0.09
331.8165588	0.09
333.4129028	0.80
335.4184570	0.20
339.1334839	1.00
342.2489624	0.18
343.3417358	0.16
345.0747070	0.35
348.3045044	0.05
352.1477051	0.07
354.9556274	0.08
363.0134583	0.43
365.2238770	0.07
369.3153076	0.41
375.1714172	0.14
377.2694702	0.78
378.3351746	0.32
379.2333679	0.07
380.5771484	0.09
381.4002991	0.10
393.9057312	0.13
403.3951721	0.61
405.2670593	0.93
409.0081177	0.14
417.2901306	0.47
418.7577820	0.47
419.4036865	0.53
420.5048523	0.23
421.4247742	0.37
423.2000732	0.41
427.2792358	0.98
428.4128418	0.59
429.3829041	0.05
435.9315186	0.12
447.2153625	1.01
447.9355164	0.16
451.2637024	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	415.1244
Annotation	O-Acetylgeniposidic acid
Peak:m/z	Relative Intensity
125.0021133	0.14
130.9198151	0.16
135.0135345	0.69
143.2366791	0.07
146.7756500	0.11
160.9747009	3.03
172.8818359	0.12
178.9458008	0.79
191.0555573	0.25
198.0946960	0.16
203.1988678	0.32
207.1168213	73.49
221.1099701	0.34
233.1356812	0.18
234.9939880	0.18
249.1465759	1.34
252.9923096	1.53
255.3252258	0.14
278.2926331	0.25
279.4679565	0.17
284.2405396	0.17
296.9153442	0.32
303.1697388	0.25
306.9498596	0.11
308.7651978	0.82
309.5302734	0.28
323.3041992	0.49
329.1873779	0.52
335.4580078	0.26
354.1619263	0.58
355.3635254	0.28
356.1459961	0.32
357.0587158	0.79
369.0005188	100.00
371.2358704	4.51
377.3276062	0.12
382.9781799	0.11
385.3612976	0.48
386.0508118	0.45
388.2419434	0.20
395.6208191	0.17
397.3417053	1.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	459.1388
Annotation	5a,11a-Dehydrooxytetracycline
Peak:m/z	Relative Intensity
151.0038452	0.18
162.0209045	0.56
176.9848480	0.23
179.0173645	0.97
233.4505920	0.06
283.1266785	0.70
308.1919250	100.00
308.9812927	0.06
316.8808594	0.75
330.1681519	0.36
331.1052856	0.33
332.1257935	0.33
339.2674866	0.15
339.9179382	0.25
346.2251282	0.22
347.3216248	0.10
355.3341675	0.51
360.6882935	0.68
361.3688354	0.14
362.1310730	0.40
369.0571289	0.33
371.1652222	0.32
409.5951538	0.12
412.9674377	0.15
415.0065308	0.18
415.6456909	0.56
417.7882690	0.32
422.6476746	0.51
423.3244324	0.70
432.8063354	0.61
441.2838135	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.0776
Annotation	L-Ascorbic acid-2-glucoside
Peak:m/z	Relative Intensity
94.7550354	0.04
97.0606689	0.11
99.0066834	0.27
101.0967865	0.13
108.8404541	0.02
110.7653656	0.16
113.0088959	0.97
113.8854218	0.20
114.8520050	0.89
120.1213074	0.07
125.0701675	0.21
126.9081192	0.79
129.0865173	0.43
130.9465332	0.43
134.9922791	0.13
136.9354858	0.05
139.0598755	0.24
140.9732513	0.11
143.0571747	0.06
145.1141968	0.03
149.0193176	0.22
152.9771423	0.03
154.9874268	0.11
156.9913025	1.52
169.0656281	0.78
172.8670197	0.03
174.2106018	1.12
175.1246796	1.65
192.8307953	0.02
195.1326904	0.02
199.2291260	0.12
200.2670593	0.02
205.0085144	0.08
207.1954803	0.25
208.9024658	0.09
217.3082886	0.04
219.1676941	0.28
221.2427368	0.04
229.2580566	0.05
233.0979004	0.06
235.9503479	0.10
236.9859009	0.07
243.0873413	0.71
247.2089844	0.18
259.2731323	0.03
263.2794495	0.10
265.1386414	0.09
273.0705261	0.20
277.1044617	100.00
293.2363281	0.04
305.1321716	0.01
318.1753845	0.02
319.1791382	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	274.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9184113	4.27
115.8523712	1.46
117.0597992	3.64
130.7716370	0.09
131.9032898	0.19
132.7355652	0.13
158.9306641	100.00
159.9310150	39.53
161.0264587	72.35
200.0348511	1.47
201.0108643	2.34
202.9251099	0.23
216.8612061	0.02
218.1217957	0.42
219.0189209	1.48
229.8871765	17.29
231.0163879	43.73
245.0465393	0.08
246.0990295	0.34
247.0445557	0.90
257.2631836	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	281.25
Annotation	Linoleic acid
Peak:m/z	Relative Intensity
80.83777618	1.78
83.31308746	0.70
85.02088928	0.80
93.09174347	0.88
95.0894928	13.37
97.1395874	1.76
98.91782379	1.39
100.8528442	0.23
104.949707	1.97
106.8688049	0.82
109.1323395	2.97
111.0653839	1.85
112.9311829	1.06
119.0526276	2.20
120.992836	4.47
123.0109329	2.99
125.2108459	0.90
127.0423126	1.52
129.0711823	0.53
133.1889954	3.93
135.0261841	4.11
137.0032654	5.22
139.0954895	4.02
141.0330505	1.75
147.1927795	3.85
148.9521484	2.78
151.1168518	5.44
153.2842102	0.32
155.0190125	2.34
155.9546356	1.39
156.9459381	1.54
161.1085205	3.22
162.9382629	4.77
165.0674744	1.88
169.0437317	19.16
171.0094604	0.96
175.0552216	6.01
177.2384796	1.44
179.0487366	0.33
181.133728	0.81
183.0651398	14.74
183.9529877	0.84
187.2494965	0.75
189.1162415	6.89
191.0863953	3.54
195.165802	1.65
197.0486145	3.02
198.9980774	2.64
201.1437683	1.11
202.9387512	1.07
205.0877991	18.94
207.1471863	3.44
210.4839172	0.62
211.2884216	2.06
212.9182434	1.10
217.0569763	2.24
218.1871033	0.59
219.2377625	0.31
221.0387573	5.90
222.3374023	1.22
223.3320312	10.68
225.311676	1.52
226.4475403	1.09
227.3495789	0.84
232.9491882	1.79
235.2041931	3.69
237.2046509	2.67
239.1983643	30.47
240.0936584	0.51
245.2196655	82.31
249.1542664	0.95
250.0930481	0.60
251.272644	0.74
263.243927	100.00
264.2092896	1.48
265.0569458	0.57
266.0542603	1.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	481.1
Annotation	Unknow
Peak:m/z	Relative Intensity
154.1850891	0.16
171.1587067	0.14
176.6849213	0.29
181.1414948	0.19
198.9665222	1.40
231.2147369	0.22
251.3695679	0.37
253.0929871	0.72
265.1406860	0.11
273.3020325	0.33
287.1328735	0.28
302.0675049	0.23
307.0478516	0.50
309.1504517	0.22
316.9338379	0.66
319.2849121	0.76
324.8969421	0.36
333.0809326	0.24
334.1517029	1.77
335.0576477	2.02
337.2091370	0.93
339.4111328	0.16
343.4254761	0.12
348.0431519	0.27
352.0781555	100.00
355.2446289	0.13
360.4326477	0.18
364.2988892	0.08
373.3572083	0.12
375.1177979	0.27
375.9271240	0.13
383.0992126	0.16
385.1885071	0.29
393.4294739	0.17
394.0718689	0.13
399.0120544	0.36
417.3921204	0.07
421.0122681	0.13
427.2771912	1.82
435.2481689	0.34
445.0277405	2.36
445.6447754	0.36
463.2008667	8.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	913.1821
Annotation	[Gallocatechin-(4alpha->8)]2-gallocatechin
Peak:m/z	Relative Intensity
261.1679688	0.83
262.2098694	0.16
264.2734375	0.10
269.1672974	0.13
271.3347778	0.24
273.2639160	0.23
280.9105835	0.10
282.4793701	0.29
283.2399292	0.26
284.7538452	0.17
285.3912659	0.05
286.2192993	0.34
287.1896973	0.18
287.8477478	0.08
296.2579956	0.10
297.0442200	0.06
298.2176819	0.24
301.4370728	0.05
303.1978760	6.86
305.1740417	7.41
315.1837769	0.91
317.3730469	0.17
329.3872070	0.06
337.1730347	0.09
344.1913452	0.22
345.2728882	0.20
347.1634521	1.27
355.3176575	0.06
357.2230225	0.09
362.3582764	0.13
366.7591553	0.06
379.0683594	0.35
380.8903809	0.16
386.8131104	0.13
391.1958008	2.10
392.0559692	0.61
397.1276245	0.70
405.1885376	0.14
409.2717285	1.55
410.1322327	0.27
411.1774292	1.67
413.2939453	0.22
421.2534180	1.13
423.1672974	25.02
424.2208862	1.99
427.2282715	0.09
428.1709595	0.06
429.2420044	2.21
430.1489868	0.52
433.3059692	0.42
434.2482910	0.31
436.9594116	0.48
439.1442871	1.50
440.0798950	0.41
441.2224731	7.76
442.2955322	2.16
451.3000488	1.62
452.1826782	0.56
453.2112427	0.10
463.1126099	1.35
465.2318115	1.22
466.3056641	0.12
469.2434692	0.61
473.2187500	0.48
475.6127930	0.29
481.1547241	3.47
483.2263794	12.47
484.1741943	2.46
485.0531616	0.05
490.0784912	0.07
493.2427979	0.80
494.2111816	0.10
507.2584229	0.14
509.0097656	0.29
509.9892578	0.21
515.3873901	2.58
524.4300537	0.12
533.1906738	1.73
534.5899658	0.10
541.2196045	34.93
542.2476807	6.59
543.2266846	0.18
544.4332275	0.08
547.4251099	0.53
548.3255005	0.05
549.1332397	0.11
550.8740845	0.55
559.1415405	42.94
560.1073608	8.60
561.0563354	0.17
563.4028931	0.03
565.3513794	1.11
566.2542114	0.73
567.1557617	0.95
568.0107422	0.21
571.1810913	0.54
573.5889893	0.07
574.1977539	0.11
575.1166382	0.64
577.1202393	43.87
578.2328491	7.31
583.3364258	0.68
584.1401978	0.04
584.7807007	0.08
587.9701538	0.44
589.1378784	0.22
590.5651855	0.55
591.2536621	3.97
592.1690063	1.74
599.0727539	0.21
600.5593872	1.23
601.2470093	7.67
602.2169189	1.87
605.0870972	0.46
607.0934448	8.14
609.0566406	22.66
610.1296997	5.06
619.1724243	13.42
620.1519165	3.60
621.3211670	0.37
625.9362183	0.56
631.1546021	0.10
631.7786865	0.26
633.1200562	0.38
633.8164673	0.05
638.2509155	0.14
643.3629761	1.05
644.2181396	0.12
648.2775269	0.15
649.2675781	1.00
650.2244263	0.33
651.2293701	2.04
652.0509033	0.07
660.5385132	0.39
661.1516724	2.54
662.3850708	0.27
665.1885376	0.17
666.5957642	0.56
667.5175781	1.16
668.4861450	0.30
672.8784790	0.20
681.2479248	0.76
683.2467651	0.42
684.2166138	0.43
690.5566406	0.09
697.2437134	0.22
699.6068115	1.21
701.1578979	1.14
702.1591187	0.69
709.2723999	4.35
710.1369629	2.51
723.8991089	0.22
724.8859253	0.58
725.5004272	0.32
727.1154785	100.00
728.1578369	20.56
728.7599487	0.10
732.2847290	0.13
733.7507324	0.43
734.4957275	0.17
735.7506104	0.67
736.5487671	0.29
739.1725464	0.10
743.0465698	0.13
745.0764771	53.66
746.1674805	8.60
747.0661621	0.19
751.3290405	0.16
752.0576172	0.27
757.0473633	2.64
759.3438721	0.15
760.3870239	0.62
761.4263306	1.78
766.5797729	0.64
769.1099243	2.74
769.9661255	0.31
775.1845703	0.62
781.2240601	0.07
787.1398315	30.53
788.2025757	10.53
789.2532959	0.23
798.3077393	0.12
802.0046997	0.11
802.8777466	0.11
811.1940308	0.59
812.3468628	0.35
820.2070923	5.59
821.3788452	0.06
825.3678589	0.61
826.0870361	0.15
829.3034058	2.19
830.0120239	0.02
832.2763062	0.04
833.1361084	0.20
836.4839478	0.06
838.1918335	0.15
841.2056274	0.32
841.9647217	0.46
845.3789673	0.44
850.4660034	2.50
851.3897705	0.61
852.5209351	0.14
867.1083984	0.05
868.7518311	0.51
869.3970337	0.33
877.3086548	0.90
881.4426880	0.18
884.6910400	0.36
895.1710815	11.12
896.1228638	5.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.0619
Annotation	2-O-Caffeoylglucarate
Peak:m/z	Relative Intensity
112.9765320	0.22
120.7637711	0.11
127.0994720	0.09
129.0161438	1.03
130.0072327	0.44
131.1962891	0.14
140.5559387	0.06
146.8249512	0.23
161.1456146	0.23
162.0390015	0.13
164.9632874	0.12
172.7694092	0.18
179.0618134	0.16
186.7679901	0.05
190.9846191	9.84
193.0907593	0.07
196.2116394	0.10
201.1348572	0.03
204.9668427	1.19
206.2823486	0.71
207.1803894	0.63
209.0805359	100.00
212.7547150	0.04
223.0013428	3.53
224.1962891	2.98
225.0281067	0.90
230.8962402	0.07
231.9836426	0.22
238.2803040	0.07
239.0203247	0.04
243.0264587	0.16
249.0920715	3.56
250.3501892	0.03
254.1740723	0.04
255.0238342	0.06
261.2911377	0.07
295.2587891	0.08
299.1861572	0.29
308.5929871	0.23
309.2484436	0.11
310.4702454	0.23
315.2138062	0.24
324.0291748	0.10
325.5162964	0.32
326.4545898	0.14
327.0648193	0.06
328.9538574	0.09
335.1245728	0.31
338.2200623	0.05
353.0587463	13.42
354.5815735	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	531.0624
Annotation	Unknow
Peak:m/z	Relative Intensity
229.0398560	0.28
230.9521332	0.19
240.1968842	0.18
247.9192505	0.39
249.0390320	1.93
252.9324188	0.12
256.3016968	0.06
259.0630188	0.88
261.1605835	0.29
263.3267517	0.46
274.9542847	0.23
277.0487671	13.31
278.8056641	1.29
284.7283936	0.19
289.1074829	1.43
295.2097778	0.57
306.8589478	25.58
308.9982300	5.60
315.2371216	0.25
316.1812744	0.28
318.8731689	0.39
324.1942139	0.27
326.3485107	0.17
332.2590942	0.08
332.9802856	0.46
336.8729248	12.26
338.1211548	0.60
348.9246826	0.13
350.2411499	19.50
351.1630859	12.05
351.7775879	0.21
353.1584473	0.05
361.0817871	0.21
366.1304932	0.06
366.9539795	2.22
368.2399902	53.73
369.1758423	28.73
371.8983154	0.83
378.4966431	1.18
379.1956177	0.69
380.3835449	0.35
381.1933594	0.78
383.9716187	0.30
384.7355957	0.07
385.5093384	0.17
393.3767700	0.40
394.8121338	0.57
397.0379028	100.00
399.1478271	0.10
410.4697876	0.13
414.5996704	0.35
415.3710938	0.40
417.2576294	0.08
424.0330200	0.15
428.4899902	0.33
433.2218628	0.12
437.6913452	0.32
440.8969727	0.84
451.3865356	0.22
457.2435913	0.13
458.8148804	0.50
465.3715820	0.45
470.1372681	0.18
471.3894043	0.12
476.3848877	0.73
477.3049927	0.15
484.8411865	0.28
486.9688110	0.31
494.2442017	1.93
495.5136108	0.16
507.9586792	0.27
510.9237671	0.30
512.1719360	2.26
513.3004761	1.12
517.4457397	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	380.2422
Annotation	Ro 09-1543
Peak:m/z	Relative Intensity
109.0091934	0.01
116.2686539	0.09
117.0969696	0.04
120.1465607	0.02
125.3368149	0.01
127.0377502	0.01
129.0744324	0.02
131.0007629	0.09
132.1002808	1.17
133.1151428	0.06
140.9885864	0.01
146.0677948	0.01
153.1447754	0.01
157.2839813	0.02
159.1105957	0.02
160.9380798	0.03
163.0834808	0.04
168.1071014	0.02
169.0531006	0.06
171.1632385	0.08
174.1753235	0.03
175.1068420	0.10
179.2289429	0.01
181.1960297	0.02
188.1999817	0.02
191.1032410	0.01
193.3777618	0.03
194.3000793	0.02
195.0480804	0.05
198.0977783	0.02
199.1305847	0.02
201.2234955	0.02
209.2968903	0.01
210.2182465	0.01
211.2596283	0.05
212.3955994	0.01
213.3592529	0.01
217.0667572	0.01
219.2725525	0.01
221.2250061	0.02
223.2326660	0.03
227.3096313	0.02
229.2784119	0.01
235.2753296	0.07
237.2492981	0.27
238.2601624	0.08
241.3397522	0.03
244.3977966	0.01
245.0493469	0.03
246.5659790	0.24
247.3243103	0.49
248.2935181	0.20
252.6369019	0.02
253.5442810	0.02
255.1480713	0.03
258.4529114	0.01
259.3323364	0.02
260.3052979	0.29
261.3645020	0.10
268.0108337	0.02
270.6715088	0.09
273.2423096	0.51
274.2212524	0.22
274.8536377	0.01
276.5513916	0.01
277.2977905	0.04
278.4414062	0.01
279.3819275	0.04
280.3582153	0.01
282.2818298	0.04
284.3390808	0.26
285.2630615	0.19
286.2401123	0.05
287.1354980	0.04
288.3054810	0.11
290.1645203	0.09
291.2460938	0.14
293.3822327	0.04
296.2713928	5.45
297.3330994	1.99
298.3127136	0.09
299.3065796	0.17
300.1318665	0.01
302.2962952	3.40
303.3690796	1.09
306.3384094	0.27
308.2960205	7.87
309.3302002	3.36
309.9780273	0.01
310.6022034	0.02
313.2483521	0.03
314.2975769	2.10
315.4029541	0.73
316.3295898	0.20
317.2044067	0.07
318.1068726	0.03
319.2517090	0.05
323.5204773	0.01
324.4816589	0.06
326.3143311	16.61
327.3964233	6.17
335.0245972	0.08
344.2968445	23.54
345.3103027	8.40
345.9257812	0.03
353.0357056	0.02
362.2998352	100.00
363.2801208	34.87
364.5259705	0.02
367.3296509	0.02
381.4828186	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	554.95
Annotation	Unknow
Peak:m/z	Relative Intensity
173.0830688	0.06
212.9445190	0.04
257.0423889	0.09
258.7906494	0.05
300.8875122	0.06
302.8759766	0.32
308.6286011	0.05
331.2328491	0.29
341.0675049	0.11
342.2453003	0.14
351.1646118	0.05
375.0473022	2.12
378.1300049	0.31
379.1524048	0.50
380.1740112	1.05
381.3215942	0.24
385.3093262	0.35
386.7893066	4.11
392.9924927	0.32
410.9699707	0.11
433.0744019	0.10
434.1460571	0.10
444.2100220	0.26
445.1970825	0.14
449.1052856	0.03
468.8197021	0.84
470.7007446	100.00
471.3441772	0.57
475.1020508	0.08
494.6892700	0.47
537.1693726	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1089.1125
Annotation	Unknow
Peak:m/z	Relative Intensity
304.3731079	0.80
312.0361328	0.58
324.1071167	0.44
342.1213379	0.49
343.5689087	0.22
345.8054810	0.20
352.9841309	0.44
359.3873901	0.94
360.2713623	0.86
380.9461670	0.43
383.5188599	1.48
395.2241821	1.37
401.4014587	0.30
409.2983704	1.23
414.2900696	0.84
417.1345825	0.42
419.3341064	0.31
422.4572754	0.22
426.1687012	1.03
427.2581482	0.18
431.4251709	0.15
434.2262878	0.11
441.4512329	0.20
442.2758179	0.38
443.1757202	0.35
444.1970825	0.13
445.3776855	0.55
460.2838440	1.09
461.2297058	0.15
462.2749634	1.42
469.4964905	0.61
473.4987183	0.63
474.6086121	0.31
479.5061951	0.28
481.2996521	0.06
482.3107910	0.43
493.6883545	0.14
495.4532166	0.15
497.2982483	0.53
498.1862793	0.38
500.5656128	0.46
512.7821045	0.25
514.0978394	0.40
528.2247925	0.14
537.1472778	0.67
540.7551270	0.64
541.3753052	1.28
553.2071533	0.29
555.4388428	0.69
557.4833374	1.67
561.4735107	0.16
572.6029053	0.38
575.5222168	0.56
576.7233887	0.76
581.2556152	0.50
584.3074951	0.34
595.6954346	0.29
596.4141846	0.48
602.2982178	0.84
606.2619629	0.25
612.5526123	1.14
613.4803467	0.09
621.6674194	0.16
629.0291748	0.40
630.5571289	0.42
631.6901245	0.46
633.6156006	0.42
636.5441895	0.38
643.3917236	0.74
646.2869873	0.14
653.3765869	0.55
654.4321289	1.19
666.8224487	0.28
668.4520264	1.10
672.4445190	0.12
674.5079956	0.59
680.3906250	0.46
681.7166138	0.40
686.3870850	1.92
690.6829834	1.16
696.3864746	0.25
705.4101562	0.22
734.1503296	0.67
743.5069580	0.33
756.3681641	0.27
759.3997803	0.49
767.9324951	0.29
768.6072388	0.69
769.4641113	0.52
774.3156738	0.50
784.1578979	1.00
785.4294434	0.78
786.5794678	1.09
787.4078369	0.18
800.5502930	0.53
803.1767578	1.49
834.2713623	0.60
836.5279541	0.59
842.9888916	0.57
880.8203125	0.33
889.3693848	0.96
897.1604004	1.29
898.4289551	1.18
899.5950928	0.87
900.3769531	0.84
909.8165283	0.35
911.2835693	0.26
911.9239502	2.36
914.1812744	0.16
916.0467529	2.19
919.8483887	0.13
920.8314209	1.78
922.1556396	1.18
924.0622559	0.18
927.6763916	2.19
928.5600586	0.63
930.4565430	0.63
931.6181641	0.58
937.8511963	5.83
939.1901855	1.16
940.8883057	0.34
942.2285156	1.47
944.3758545	0.30
945.2691650	1.10
950.4775391	2.23
951.5599365	1.41
954.1650391	0.83
956.3037109	2.41
957.2740479	1.49
959.3641357	1.47
961.3282471	1.83
962.1386719	0.77
963.7124023	1.05
964.6414795	5.21
966.2283936	2.50
967.4705811	3.00
968.7449951	1.47
970.5162354	3.42
972.0190430	3.62
972.9442139	0.91
974.5791016	1.77
975.6119385	7.68
976.8530273	6.37
977.5910645	1.12
979.6181641	6.52
980.3159180	1.24
980.9501953	0.35
981.9755859	2.11
982.7047119	3.81
985.0944824	4.62
985.8472900	2.31
987.3436279	6.63
988.6247559	2.34
989.5603027	9.12
991.0559082	4.37
992.9689941	0.53
994.1180420	4.10
994.9848633	2.95
995.8999023	0.76
996.6589355	1.19
997.5498047	1.64
998.7624512	3.76
999.7073975	2.92
1000.7724610	2.30
1001.7396240	3.38
1002.8833010	9.21
1003.7932130	2.17
1004.9152830	2.28
1006.4296880	2.83
1007.1363530	3.46
1007.8273930	1.95
1008.9855960	12.78
1009.8181150	2.25
1011.1083980	6.87
1012.3000490	5.97
1013.3452150	8.64
1014.3443600	12.04
1015.2097170	6.14
1015.9989010	2.67
1016.7821040	9.88
1017.7812500	3.58
1018.9968260	7.51
1019.7409670	5.28
1020.4753420	3.89
1021.7058110	11.81
1022.6014400	19.72
1023.7133790	6.20
1024.5932620	0.62
1025.7639160	5.01
1026.6315920	11.69
1027.7026370	8.37
1028.3421630	16.36
1029.3708500	5.87
1030.8737790	8.86
1032.0059810	19.43
1032.7539060	6.83
1033.4377440	3.86
1034.6090090	5.85
1035.3632810	11.79
1036.2336430	7.44
1037.4510500	18.04
1038.2927250	3.28
1039.7436520	6.55
1040.8837890	13.85
1041.7158200	9.42
1042.9122310	7.02
1043.8205570	4.10
1045.0455320	3.96
1045.7426760	23.90
1046.7001950	17.41
1047.8256840	4.05
1048.8271480	10.86
1049.5091550	11.25
1050.6627200	8.96
1051.3092040	23.66
1052.2473140	24.03
1052.9461670	20.37
1054.8884280	42.95
1055.6475830	11.38
1057.1744380	51.33
1058.0041500	41.39
1059.4616700	16.51
1060.7825930	52.26
1061.5356450	7.95
1062.2158200	2.05
1063.3759770	5.74
1064.1472170	10.06
1065.3027340	14.40
1066.5607910	19.19
1067.4808350	5.02
1069.3735350	35.78
1070.2519530	17.50
1070.9675290	3.38
1072.4291990	32.20
1073.0316160	45.56
1073.8245850	5.56
1075.2923580	73.54
1076.1037600	23.80
1077.0384520	2.21
1078.6090090	100.00
1079.5759280	6.04
1082.1193850	0.30
1083.1303710	0.34
1089.1690670	0.11
1097.7468260	2.67
1104.8044430	0.71
1108.5170900	2.11
1109.3754880	0.18
1113.7121580	0.36
1119.0883790	0.54
1120.4648440	0.22
1125.6354980	0.99
1128.0129390	0.62
1129.1323240	1.04
1133.0812990	0.66
1135.8214110	0.57
1136.7310790	1.36
1138.4744870	0.28
1144.6403810	0.45
1152.8222660	0.72
1155.0874020	0.23
1155.9946290	1.89
1156.7747800	0.19
1161.7121580	0.47
1162.9583740	1.10
1163.9438480	0.56
1165.1644290	0.61
1167.4796140	0.28
1168.4765620	1.37
1171.9792480	0.87
1173.5909420	0.38
1177.0081790	3.89
1177.8918460	3.18
1178.9042970	0.89
1184.1723630	0.45
1187.9392090	1.24
1194.6461180	0.75
1199.4516600	0.28
1201.4216310	1.43
1202.2137450	2.22
1205.4559330	2.14
1212.6328120	0.41
1214.6704100	1.65
1216.0429690	1.59
1217.1149900	1.45
1217.7327880	1.19
1219.8664550	0.66
1220.6243900	1.26
1221.5279540	0.31
1223.1881100	0.76
1225.3479000	2.56
1226.1307370	0.51
1227.6983640	1.94
1228.5090330	0.13
1229.6823730	0.32
1230.7393800	0.54
1233.2926030	6.68
1233.9775390	3.64
1234.6694340	7.85
1235.7972410	1.72
1238.9633790	1.83
1239.9746090	0.68
1241.3305660	1.32
1243.4832760	1.15
1245.8500980	1.27
1247.5319820	1.95
1248.2016600	1.64
1254.3238530	0.81
1255.4887700	8.70
1256.2813720	2.84
1263.0827640	1.02
1263.9708250	0.22
1265.8625490	0.93
1267.0769040	0.91
1268.2407230	0.90
1269.0860600	0.40
1271.1862790	0.91
1273.3305660	1.29
1273.9836430	0.84
1274.9869380	0.90
1276.9454350	2.16
1277.6505130	0.65
1278.5981450	0.92
1279.2985840	1.52
1280.5314940	0.49
1281.7681880	0.90
1282.6022950	1.53
1283.6452640	2.57
1285.8275150	2.83
1286.8198240	1.48
1288.0263670	1.33
1289.0279540	1.17
1290.3271480	7.70
1291.0803220	5.63
1291.8068850	1.69
1294.2600100	2.16
1298.4815670	2.79
1299.3110350	9.31
1300.3492430	6.19
1301.1455080	3.69
1302.7652590	4.06
1303.6635740	2.87
1304.3333740	2.93
1306.6773680	1.47
1309.2751460	1.06
1311.4121090	11.61
1312.2473140	24.14
1313.1846920	4.09
1316.2183840	0.90
1316.8355710	0.99
1318.7003170	0.35
1320.3386230	1.03
1322.6102290	0.73
1324.2020260	0.83
1325.9158940	2.33
1330.8176270	2.76
1331.5118410	0.79
1332.3790280	1.62
1333.4725340	3.07
1334.2564700	2.58
1336.1236570	0.63
1337.4178470	0.77
1339.0047610	1.77
1340.3262940	5.03
1341.6949460	1.01
1343.7655030	1.71
1345.0867920	1.93
1346.5643310	5.39
1347.8155520	5.51
1348.8426510	9.57
1349.7955320	3.79
1350.8087160	2.00
1351.6680910	1.46
1352.8886720	1.34
1353.7515870	0.83
1354.9067380	2.39
1356.4549560	12.15
1357.3273930	6.55
1358.3408200	1.13
1359.0916750	1.36
1360.4121090	0.73
1361.2053220	3.58
1362.5532230	1.20
1363.8084720	1.75
1365.2235110	0.97
1366.1116940	0.61
1366.7299800	0.40
1367.9859620	0.92
1368.9610600	4.47
1369.8297120	1.91
1370.7508540	0.20
1372.7955320	0.62
1373.7554930	0.99
1376.8081050	3.03
1377.7720950	19.70
1378.6507570	11.23
1379.4232180	1.20
1380.1796880	0.37
1382.8703610	0.84
1384.4198000	2.79
1385.7615970	4.86
1387.2854000	1.64
1388.2325440	1.55
1390.6677250	2.97
1395.0446780	2.50
1395.9281010	2.96
1396.6698000	4.38
1397.6511230	1.49
1399.0028080	9.22
1399.8507080	4.39
1400.6651610	0.92
1401.2657470	1.53
1404.2915040	7.84
1405.3128660	15.71
1406.1715090	11.34
1407.4626460	0.38
1408.7135010	0.74
1410.3522950	3.92
1411.6912840	4.20
1412.5886230	6.99
1413.2493900	15.40
1414.0139160	2.90
1414.6646730	1.52
1416.1243900	1.40
1417.2124020	0.63
1418.1339110	2.32
1419.1552730	1.84
1420.7935790	3.59
1421.4493410	0.91
1422.0601810	0.72
1422.8842770	0.74
1424.2388920	1.47
1426.1201170	6.59
1427.1024170	1.88
1428.2093510	0.81
1428.9766850	1.28
1430.4633790	0.56
1431.1892090	0.49
1432.7603760	3.27
1433.5831300	2.90
1434.7230220	18.36
1435.7427980	2.50
1437.8521730	0.73
1438.7701420	0.35
1439.6704100	1.17
1441.0234380	3.13
1441.9156490	3.95
1443.1256100	1.70
1444.4019780	1.60
1445.2152100	0.82
1446.3453370	0.64
1446.9560550	5.85
1447.5625000	0.65
1448.4128420	6.09
1449.1290280	0.30
1451.2979740	0.36
1452.3096920	0.53
1453.6373290	1.79
1455.3922120	19.55
1456.3055420	17.56
1457.2567140	1.00
1458.0828860	0.90
1460.3032230	3.21
1461.2088620	0.57
1461.8450930	3.06
1462.9439700	11.89
1463.6451420	11.44
1464.4709470	3.89
1468.3464360	5.40
1469.0960690	0.30
1470.8527830	32.83
1472.0017090	8.60
1473.8560790	3.48
1475.2497560	1.73
1475.9932860	6.40
1476.6923830	1.55
1477.3974610	2.37
1478.5875240	0.13
1481.0992430	0.68
1482.3978270	9.31
1483.3311770	3.28
1484.7572020	0.46
1485.7806400	1.21
1487.7447510	1.25
1489.4923100	3.31
1490.8990480	11.94
1491.5075680	26.82
1492.3267820	13.38
1493.2656250	2.60
1495.1131590	4.93
1496.8018800	4.38
1497.4996340	1.22
1498.2183840	0.83
1498.8424070	0.67
1499.9586180	1.84
1501.4129640	0.94
1503.5690920	7.27
1504.3885500	2.69
1505.4821780	2.12
1506.2849120	1.30
1507.3945310	1.81
1508.3138430	1.02
1509.4239500	0.42
1511.1956790	2.96
1512.0433350	4.18
1512.9266360	24.30
1513.7496340	4.97
1515.1204830	0.39
1516.0145260	1.60
1516.7012940	0.56
1517.8546140	2.68
1519.2141110	6.91
1520.0278320	3.96
1521.3287350	22.35
1522.1416020	5.39
1522.8160400	1.16
1524.3492430	2.36
1525.1842040	0.86
1526.0468750	0.41
1527.5582280	6.01
1528.4439700	2.95
1529.4908450	3.65
1532.5699460	10.27
1533.2835690	11.22
1534.1651610	2.96
1535.3267820	1.68
1536.1195070	0.20
1539.2608640	1.00
1539.9473880	0.27
1541.5781250	12.77
1542.4163820	20.86
1543.3947750	1.45
1544.5899660	1.42
1545.6859130	0.36
1547.3917240	1.85
1548.3122560	2.56
1549.2458500	0.79
1551.3104250	0.15
1552.3149410	0.89
1553.3673100	0.28
1555.0540770	1.82
1556.3919680	3.26
1557.1070560	2.21
1558.1579590	0.96
1560.4287110	4.90
1561.5445560	6.36
1562.2392580	3.96
1564.6795650	0.74
1567.5325930	2.31
1568.1807860	0.46
1569.5496830	5.29
1570.5513920	5.11
1571.5247800	1.78
1573.2469480	0.49
1575.5607910	2.55
1576.7115480	6.16
1578.1063230	11.03
1578.9262700	3.24
1582.7286380	0.75
1583.7991940	4.52
1585.3703610	40.25
1586.3979490	8.94
1587.1341550	0.62
1590.4550780	0.38
1618.5450440	0.64
1632.7050780	0.58
1634.7346190	0.18
1648.1033940	0.52
1678.9820560	0.66
1685.5992430	0.44
1693.5261230	0.11
1713.7946780	0.53
1715.5601810	0.88
1760.8157960	0.39
1762.6656490	0.31
1838.5743410	0.10
1840.0490720	0.10
1847.9152830	0.31
1862.9010010	0.76
1877.7604980	0.85
1892.3052980	0.08
1957.2312010	0.27
1971.0231930	0.34
1992.4777830	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	555.27
Annotation	Unknow
Peak:m/z	Relative Intensity
161.0009766	1.19
173.0835571	0.08
179.0041809	0.14
189.0438538	0.22
191.7948456	0.05
220.9431763	0.16
230.0495300	0.08
233.2052155	0.07
241.1980591	0.07
246.2643890	0.05
246.9627838	0.07
251.1546936	0.30
260.2442017	0.06
267.3276367	0.53
270.9889526	0.40
279.4220886	0.25
306.2006836	0.18
315.3465576	0.14
331.3646851	0.87
333.3026733	32.10
334.3220215	0.27
348.4162598	0.05
355.0504761	0.08
357.2457886	0.50
375.1952515	3.08
389.6189575	0.35
391.5538940	0.65
392.4961548	1.57
393.2792969	6.33
397.3809814	0.10
399.4160156	0.98
417.4794312	0.10
422.2583008	0.17
423.3114624	0.92
427.3773804	0.13
429.5328369	0.20
433.3167725	1.52
440.1785889	0.20
465.2552490	0.12
475.4974976	0.48
477.4635010	0.39
478.1751099	0.15
493.3390503	1.09
495.2857666	45.18
496.1144409	0.17
501.6282349	0.08
508.8762817	0.35
510.3021851	0.56
511.5473633	0.32
517.4723511	0.21
519.3291016	5.04
520.3462524	0.12
525.2972412	0.19
526.3630981	0.13
537.3307495	100.00
538.3449097	1.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.1039
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
132.8507233	0.10
160.6815033	0.04
163.1740112	0.03
177.1193085	2.21
193.0279236	0.13
215.1267090	0.20
217.3277435	0.03
223.0039520	0.18
260.1990967	0.05
261.1963501	0.24
267.0203857	0.13
267.8288879	0.34
275.0505066	0.24
285.1703186	21.97
290.0016479	0.04
303.1302185	100.00
304.1747131	0.09
306.9766846	0.09
309.1297607	0.50
311.3995056	0.05
314.1427917	0.08
319.3062439	0.39
324.5803223	0.07
327.1287842	0.95
331.3640137	0.24
332.3252258	0.09
333.4018250	0.08
334.2161865	0.05
339.1365662	0.14
341.1513672	1.04
345.2414551	0.14
348.2727051	0.03
349.3350220	2.12
350.4400024	0.15
359.2014160	0.22
364.4260254	0.12
369.2721252	0.32
377.3388367	0.22
378.2993469	0.07
385.3747559	0.57
387.1530762	0.07
391.3698120	0.09
393.2405701	0.17
400.3212891	0.08
403.3074036	0.03
419.1638489	0.38
421.2245178	1.51
422.1799622	0.03
427.0897522	0.22
429.1478577	0.80
430.1680603	0.52
434.3180237	0.09
436.2818604	0.23
437.3886414	0.40
444.9034119	0.29
446.2705994	0.98
447.1638489	2.99
448.3381653	0.09
449.8847961	0.19
456.3658752	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	405.1767
Annotation	Unknow
Peak:m/z	Relative Intensity
118.8650055	0.16
123.9736099	0.06
130.8488464	0.02
139.0150452	0.15
166.0105286	0.03
179.7566528	0.03
181.0985107	0.53
182.9836121	1.30
189.0509033	0.04
199.0145264	0.45
207.0536804	0.05
217.0587311	0.08
220.0533447	0.03
225.1656799	1.07
238.3186951	0.05
241.1354980	0.08
243.1011353	100.00
249.0671692	0.37
255.1847229	0.04
267.2442322	0.33
271.1721497	0.13
273.0921631	0.02
274.4349976	0.15
276.2413635	0.09
285.1665649	1.52
288.4373779	0.09
295.2972412	0.06
297.1617126	0.07
307.2302246	0.09
309.2536621	0.05
315.0888977	0.48
325.0737915	0.04
327.4450989	0.12
329.3853760	0.08
330.2254333	0.04
340.2993774	0.03
345.2707520	3.06
357.2173767	0.10
359.1341248	0.16
360.1484375	0.08
361.0090027	0.32
369.2209778	0.09
377.5285339	0.06
386.3455505	0.39
387.3157043	0.86
388.0533142	0.04
391.4556274	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.0775
Annotation	Aesculin
Peak:m/z	Relative Intensity
110.9872589	0.26
128.9966431	3.03
133.2079010	0.05
161.0458221	0.09
173.0079193	0.08
179.0186462	0.21
187.1043549	0.34
191.0058594	3.12
205.0941467	8.46
209.0414581	0.54
223.0382996	100.00
237.0678101	0.03
245.2678833	0.02
247.1803284	0.69
321.2097168	0.01
323.3875732	0.16
335.3231201	0.08
341.0473633	0.03
348.9791870	0.07
367.1591492	4.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.05
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
159.0235596	0.06
175.1311951	0.10
177.1503143	0.08
182.0828552	0.07
193.4062347	0.11
197.0628052	0.09
210.9845123	2.14
220.9300995	0.06
222.0846710	0.07
223.0873413	0.03
241.0823822	1.00
244.9973907	0.28
251.6866302	0.13
258.9749451	0.35
262.0620117	0.07
270.5441589	0.03
273.1181641	0.06
280.1737671	1.19
282.0362549	0.34
282.8899536	0.05
287.5450134	0.17
294.2641296	0.06
305.3718262	0.03
307.0459595	0.12
321.1828003	0.56
323.1771240	100.00
338.1754761	0.18
355.1625977	0.91
356.1047974	0.37
357.0354004	0.04
379.1939087	0.09
380.4812622	0.20
381.2250977	0.72
383.1634521	0.04
384.0640869	0.68
385.0356445	2.05
391.1443481	0.05
392.3029175	0.03
394.9627686	0.32
401.0686646	0.09
403.2451172	3.37
417.8778687	0.39
418.9830933	0.61
420.9776611	0.02
426.7714844	0.07
428.8403320	1.97
429.4763794	0.06
432.8419189	0.58
466.7982178	2.89
467.5561523	0.11
472.9139404	0.06
474.8863525	0.05
481.0091553	0.06
490.9995117	0.19
504.1619263	1.17
505.1762085	0.03
521.8828735	0.11
528.8755493	0.36
534.3505249	0.07
547.1233521	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	543.281
Annotation	Pharboside C
Peak:m/z	Relative Intensity
159.0426178	0.11
161.8935394	0.11
179.1963806	0.09
191.3002014	0.05
191.9977570	0.05
207.0411377	0.50
237.0828247	0.11
282.0753174	0.48
319.4889526	0.36
320.4514160	0.06
328.8643799	0.10
330.2733154	0.28
333.1238403	0.17
335.3039551	100.00
337.4856567	0.06
341.3579712	0.17
343.5515137	0.13
358.3556519	0.04
359.2384033	0.03
377.5297241	0.22
379.2067871	0.61
380.4854126	0.42
381.1450195	0.37
395.2501831	0.35
403.3218994	0.17
405.0387573	0.15
421.2973633	0.15
421.9858398	0.04
427.4680786	0.19
428.1866455	0.10
440.4174805	0.11
447.3684082	0.06
451.3829346	0.28
463.5496826	0.20
468.7177124	0.18
480.1884155	0.11
482.2045898	1.90
483.2999268	0.91
489.1802368	0.11
497.1290894	33.58
498.2709351	0.04
498.9940796	0.11
500.2350464	0.23
501.2355957	0.20
504.9552002	0.21
505.7530518	0.11
507.2888794	0.69
508.0452271	0.11
523.4705200	0.16
524.3667603	0.24
525.1169434	0.21
525.8748779	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	637.1412
Annotation	Isoetin 7-glucoside-2'-(4''-acetylxyloside)
Peak:m/z	Relative Intensity
183.1578369	0.05
188.9465027	0.09
193.0123749	0.17
199.0493164	0.05
200.2554016	0.04
209.1280670	0.06
211.0760803	0.03
212.1228333	0.03
215.0605469	0.14
216.2764587	0.02
220.0783691	0.10
225.9889679	0.07
227.0261078	0.18
228.1618805	0.04
238.9442139	0.06
240.2932434	0.03
242.3237000	0.18
243.0923615	0.85
244.2768250	0.62
245.1771851	0.03
246.2492065	0.05
255.0140839	3.80
256.2050781	0.27
259.3663940	0.08
267.2965088	0.02
268.2810059	0.04
269.0526123	0.02
271.1615601	5.65
272.1612854	1.38
273.1605835	0.19
282.1474609	0.07
283.2294006	0.06
287.1548462	0.49
295.9187927	0.17
297.0678101	0.03
300.0357361	29.32
301.1081543	2.76
302.1985474	1.39
303.3161316	0.19
304.7206421	0.09
313.2335815	0.27
315.1086121	100.00
316.1293335	0.42
319.2729492	0.40
320.1509705	0.10
322.2575378	0.03
324.9074707	0.24
327.3103027	0.07
330.4210815	0.06
331.0675354	0.74
339.0529785	0.18
343.2352295	0.10
344.2783203	0.05
344.9862061	0.07
346.6320190	0.02
352.0623169	0.02
356.2219849	0.13
357.2398071	0.51
360.4829102	0.05
363.2760620	0.05
367.2468262	0.22
369.2288818	0.06
375.5286255	0.11
380.2768555	0.01
381.1409912	0.03
387.2767334	0.08
392.4224854	0.04
399.2564697	0.20
400.4166870	0.15
408.9981079	0.03
410.8916626	0.07
421.2141113	0.02
427.1862793	0.03
428.1832275	0.17
429.2512817	0.05
441.3563232	0.23
443.2083130	0.03
444.6722412	0.05
446.3370361	0.29
447.3995361	0.48
453.1329956	0.03
457.0425415	0.07
459.2669678	0.11
470.0726929	0.09
473.9517212	0.04
476.3905640	0.69
477.3656006	0.41
479.1746216	0.07
480.4744873	0.02
487.2102051	0.20
488.1920166	0.22
489.2429810	0.32
494.6077271	0.13
501.0735474	0.04
504.4179688	0.02
505.2410889	0.27
506.1973267	0.76
507.0612793	0.32
508.5451660	0.03
510.5640259	0.03
515.1495972	0.04
521.3923950	0.05
523.3573608	0.05
529.3464355	0.04
534.3182983	0.03
537.2905884	0.43
544.8305054	0.20
548.2158813	0.07
551.4776001	0.02
553.3796387	0.05
558.6636353	0.05
559.3551636	0.05
566.1827393	0.02
575.4131470	0.07
576.1906128	0.05
577.2927856	0.22
578.2626953	0.50
579.3665771	0.92
593.0269165	0.14
594.0558472	0.25
595.1901245	0.46
596.3584595	2.59
597.2440186	0.75
602.6724243	0.08
603.4762573	0.29
604.2933350	0.03
607.3253174	0.27
609.5529175	0.10
611.2052002	0.20
615.8712769	0.05
619.3549805	0.10
620.8711548	0.51
621.4934692	0.91
622.8256226	0.02
624.0249634	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	373.0587
Annotation	Acetylelatol
Peak:m/z	Relative Intensity
114.8593674	8.64
131.1196594	0.28
145.0912170	0.05
156.7681885	0.13
158.9044495	100.00
213.3664856	0.07
242.1356506	0.12
243.3090515	0.19
244.9306946	0.08
257.0447083	0.17
259.1308899	40.55
260.0412903	0.05
273.6747131	0.12
282.8816528	0.18
285.1764832	0.19
293.2066040	0.07
294.3513794	0.08
299.1173096	0.54
300.4377747	0.03
308.9853516	0.31
310.5865173	0.41
311.3107300	0.12
318.4432373	0.16
327.1069946	11.36
327.8035889	0.02
329.0069885	0.21
336.1874084	0.07
342.5160828	0.04
345.1237488	0.03
346.9527588	0.04
354.8490295	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	300.03
Annotation	Unknow
Peak:m/z	Relative Intensity
106.9589386	0.04
124.2244720	0.06
135.1331482	0.03
150.3824615	0.12
151.0692749	0.55
152.1198425	0.04
152.9519043	0.14
159.8827362	0.04
163.2135162	0.10
164.1548462	0.07
171.1566772	0.05
174.1306000	0.02
179.1329041	0.32
182.9829712	0.03
188.5503998	0.05
190.7073975	0.04
192.1500854	0.08
193.1295929	0.02
199.0033875	0.07
210.1116943	0.10
210.9519043	0.06
216.1839294	0.34
221.4791565	0.02
226.0005188	0.53
227.0550537	0.88
228.1742554	0.26
229.1332703	0.09
230.1159973	0.06
243.0371704	2.27
244.1531677	0.62
251.1896667	0.05
254.0949707	7.56
255.0958252	50.37
256.1062622	0.39
256.9965210	0.07
259.4110718	0.06
271.0712891	100.00
272.1512451	9.07
273.0657043	0.06
281.4355164	0.06
282.2605286	0.10
299.0987549	0.02
300.1672668	0.28
301.4448547	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	591.1799
Annotation	Unknow
Peak:m/z	Relative Intensity
169.9932251	0.50
181.1812592	0.03
188.1015625	33.22
204.9860840	100.00
205.6722260	0.27
224.9432678	0.20
261.2275391	0.06
276.1912842	0.10
279.3264771	0.08
297.0078125	0.14
328.9842529	0.11
332.1213379	0.17
351.0561523	0.19
367.1608276	0.43
369.1749268	1.10
386.3015747	0.11
387.0446777	0.07
397.2271729	0.02
398.1510620	0.11
410.7816162	0.03
411.7860718	0.04
423.2686157	0.23
425.1523438	0.02
429.1972656	0.11
447.3202515	0.07
456.1644287	0.04
457.2244873	0.02
462.7030029	0.11
471.3101196	0.04
475.0360718	0.04
476.6208496	0.02
483.2098999	0.05
485.7265625	0.14
488.1517334	0.05
496.3703003	0.02
530.7284546	0.16
547.4138794	0.07
555.1665649	0.16
561.0442505	0.02
572.4716797	0.20
573.1176147	0.96
574.5147095	0.14
575.2934570	0.09
580.4069824	0.08
581.2081299	0.02
582.6343384	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.29
Annotation	Atractyloside D
Peak:m/z	Relative Intensity
158.9704895	0.05
160.9065247	0.17
172.9227600	0.34
176.9417419	0.08
179.0317230	0.88
187.0350800	3.66
191.1493378	2.43
193.1412659	0.53
199.3304596	0.05
200.2005768	0.14
203.1542053	0.30
205.0570679	6.01
207.1719208	0.19
211.4586945	0.06
216.9747925	0.16
223.1927185	3.26
229.0980988	0.17
245.2240143	0.08
247.0661011	0.13
261.3024292	0.82
273.1222534	0.76
280.7849731	0.08
287.1884766	0.36
291.1364746	0.39
305.2079468	1.00
307.5376587	0.17
309.1671143	0.40
320.9722900	0.03
323.2245483	0.19
331.2747192	0.28
335.2073975	1.40
337.1542358	0.33
345.7692261	0.14
347.2800903	0.14
349.1109009	0.14
351.1736450	0.40
353.3182373	14.63
357.2884521	0.71
359.3127441	0.14
362.5961304	0.08
363.3240967	0.29
366.5939331	0.47
367.2321777	5.36
368.2240601	0.18
371.0627441	0.04
378.2108765	0.05
381.0692139	5.20
385.2114868	9.05
386.1419067	0.11
394.3304443	0.23
395.3631592	0.14
399.1199341	100.00
399.7574463	0.35
401.3802490	0.08
402.9842529	0.13
407.5452881	0.10
413.3624268	0.35
415.5300903	0.14
426.6129761	0.10
427.3341675	0.18
431.2941284	0.05
435.5364990	0.10
445.5050659	0.08
453.5379639	0.09
464.0885620	0.03
465.1980591	0.18
471.1965942	0.29
474.7874756	0.21
475.4234009	0.33
481.7317505	0.53
483.3958130	0.25
484.3859253	0.08
486.1394043	0.20
489.3359985	0.36
493.2795410	0.07
499.4524536	0.16
500.3843384	0.26
501.3508911	0.83
507.5432739	0.06
510.8389893	0.10
513.5111694	0.19
514.6536255	4.73
515.3516235	3.00
517.2218628	0.11
518.2783813	0.40
522.5993652	0.32
523.5309448	0.63
524.7133179	0.70
525.5308838	0.43
537.8211060	0.11
541.0388794	0.33
542.9279175	2.36
543.7451782	0.14
551.9690552	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	306.0763
Annotation	Glutathione
Peak:m/z	Relative Intensity
99.0635986	0.29
126.9836121	0.06
127.9254684	9.52
129.9347839	0.10
143.0420837	8.72
144.9977112	0.32
146.0984955	0.66
152.9228668	0.05
159.9486542	8.81
166.4211578	0.11
167.0235138	1.47
169.0688782	0.04
169.8988953	0.40
171.0932770	1.27
177.0439148	9.44
178.9869385	8.34
179.6082306	0.07
183.2394867	0.06
184.9807281	0.82
197.1165161	1.08
203.1319580	0.25
210.0776672	3.57
212.2008667	0.36
213.0855713	1.27
215.1760254	0.08
224.1370544	0.13
228.1547852	0.40
231.0629578	0.48
236.1343079	0.84
242.0463867	2.73
254.0900574	87.90
260.6098022	0.06
270.2046814	0.20
272.1247253	100.00
273.0057373	0.16
286.8367310	0.07
288.1240845	70.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.1674
Annotation	ADP-Ribosyl-L-arginine
Peak:m/z	Relative Intensity
206.1338501	0.52
233.2472534	0.02
248.0401001	0.03
250.0308838	0.20
294.3181152	0.02
295.4400635	0.03
300.4583130	0.23
301.2005920	1.58
344.4860229	0.01
349.4107361	0.04
363.4978027	0.02
383.2770386	0.07
400.3739014	0.04
411.3928223	0.04
426.4276123	0.04
437.2816162	0.04
461.1942139	0.06
463.1339111	100.00
463.8708496	0.32
485.5257568	0.03
490.4827271	0.20
502.8574219	0.09
509.3121338	0.18
510.3800049	0.06
533.4389648	0.03
544.1876831	0.04
548.4241333	0.04
551.3314209	0.65
552.3016357	0.02
581.5841064	0.29
591.5073853	0.04
594.5192261	0.09
622.5070190	0.04
633.4213257	0.03
637.9569092	0.08
651.2554932	0.06
653.3545532	1.25
654.3844604	0.26
667.4743652	0.02
669.6259155	0.61
671.4489136	1.91
672.5678101	0.11
678.2572632	0.02
678.9166260	0.09
680.8903198	0.08
685.5706177	0.02
694.1803589	0.06
695.3133545	0.50
696.4043579	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	547.1907
Annotation	Paratunamide B
Peak:m/z	Relative Intensity
159.0039825	0.37
161.9386292	0.05
169.9766235	0.70
188.0746155	35.81
204.9742432	100.00
246.8441162	0.08
271.2168579	0.08
308.2463074	0.11
314.1461792	0.14
319.2092896	0.35
327.3135376	0.55
340.2195435	0.05
342.4715576	0.10
343.6190796	0.41
366.8742065	0.67
384.7977905	0.60
392.2067871	0.13
394.7613525	0.45
422.2382202	0.48
428.3869629	0.06
429.4631958	0.18
431.0394897	0.28
442.4635010	0.18
455.9829712	0.18
459.3726196	0.16
483.2205200	0.74
485.4710083	0.11
493.3681641	0.33
510.5807495	0.39
528.0826416	0.16
529.0569458	0.52
530.3226929	0.08
548.2979126	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	580.88
Annotation	Unknow
Peak:m/z	Relative Intensity
216.6736450	0.04
255.0007477	0.32
283.0734863	0.35
285.3892822	0.32
308.9243469	1.18
319.1285400	0.26
320.8540649	0.08
323.2023315	1.11
324.2151489	1.50
325.0439453	0.04
339.2652588	0.23
355.0784302	1.28
356.1690674	0.78
357.3236084	0.42
366.9907837	0.07
367.9208374	1.63
390.6074829	0.13
393.1394653	0.25
399.1150513	0.94
400.1941528	0.72
401.2565308	0.11
403.0473633	1.50
404.1229248	2.65
405.3227539	0.57
406.9204102	64.10
408.0363159	0.11
444.8202515	100.00
445.8957520	1.05
447.8726807	0.08
454.0904541	0.22
467.0648804	0.59
468.8153687	0.08
483.3750000	0.06
496.0198975	0.64
496.7598877	1.16
507.7358398	0.11
533.7667847	6.04
535.0112915	0.08
557.2172241	0.12
562.0033569	0.13
564.2837524	0.48
573.1003418	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	211.0975
Annotation	F 11334A1
Peak:m/z	Relative Intensity
71.0617599	0.02
79.9098358	0.06
123.1924286	0.24
125.0116119	0.02
139.2476654	0.04
142.8675690	0.02
151.1132202	0.04
153.1201935	0.09
154.2721405	0.06
154.9253845	0.06
162.9006348	0.05
167.0931854	100.00
169.2155762	0.03
169.9873352	0.04
170.7251434	0.04
181.2541046	0.01
183.1512604	0.10
185.0498810	0.03
193.1014557	15.75
195.3837738	0.07
210.9188690	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	207.03
Annotation	Isoochracinic acid
Peak:m/z	Relative Intensity
96.9385529	0.02
100.8170776	0.01
103.0006256	0.01
113.0812225	0.01
124.9294281	0.01
127.2513123	0.01
135.0917206	0.02
145.0610199	0.01
161.1818390	0.10
162.9908905	0.42
164.2777252	0.02
165.1390686	0.12
179.1163483	0.05
189.1149902	0.07
191.9776459	100.00
207.1509857	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	785.3024
Annotation	Unknow
Peak:m/z	Relative Intensity
239.0700378	0.05
245.2003784	0.03
284.9877930	0.02
313.0720825	0.03
327.3004150	0.06
335.3589172	0.01
337.1659546	0.09
340.2960815	0.02
344.3219604	0.03
346.1826782	0.02
351.0899658	0.02
382.1292725	0.06
383.9256592	0.07
384.5306396	0.05
386.6438599	0.07
389.3338623	0.04
400.4815674	0.01
404.6967773	0.01
409.4777222	0.02
412.0446777	0.03
412.7705078	0.15
414.1072998	0.02
415.4570312	0.03
430.5004883	0.03
432.4032593	0.12
441.2219238	0.13
454.0950928	0.01
456.3593750	0.03
457.4032593	0.03
458.6501465	0.15
467.6514893	0.04
470.3156128	0.10
472.3938599	0.08
474.0891724	0.05
477.1944580	0.03
479.5164185	0.01
484.1737671	0.03
497.5172729	0.02
502.4272461	0.01
505.3409424	0.01
517.2000732	0.03
519.3723755	0.04
522.2302246	0.02
525.0350342	0.04
529.4550171	0.04
531.2564697	0.06
532.4543457	0.09
533.1234741	0.03
533.7719727	0.08
539.6236572	0.04
547.4238892	0.06
549.3840942	0.03
551.6253052	0.07
555.3772583	0.01
565.4230957	0.02
569.2855835	0.02
571.4953003	0.05
573.3368530	0.14
587.7459717	0.05
591.3563843	0.76
592.4349365	1.35
593.3427124	0.02
594.4602051	0.04
600.2718506	0.05
605.3663940	0.19
606.2991333	0.08
607.3352661	0.03
609.3972778	0.19
615.1822510	0.15
615.7969971	0.02
617.3433228	0.08
618.2405396	0.10
621.0614014	0.08
623.2855835	0.28
625.6194458	0.02
632.1395874	0.04
633.3624268	0.17
639.3864746	0.03
641.4213257	0.04
650.4807129	0.11
651.3049927	0.14
665.3293457	0.29
667.2579956	0.10
681.4140625	0.35
683.4708862	0.01
685.4003296	1.34
693.5229492	0.05
694.3748779	0.02
695.1973267	0.13
708.8882446	0.12
709.5113525	0.61
710.8129883	0.24
711.4133911	2.26
712.3873291	2.51
713.4164429	0.37
717.3569946	0.07
725.4606323	0.78
735.5011597	0.57
739.3338013	0.01
741.6451416	0.04
743.5476074	0.06
753.3563232	100.00
754.0109253	0.24
757.3117065	0.44
758.2548828	0.07
767.3057251	0.43
795.5690308	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.1194
Annotation	Raltitrexed
Peak:m/z	Relative Intensity
131.0787506	0.06
148.8230438	0.04
152.8087463	0.12
160.9699554	0.21
179.0148773	1.35
186.9985352	0.04
234.2049255	0.08
235.1147156	0.12
289.1506958	0.09
295.1966553	0.43
295.9533081	0.08
303.1233215	0.14
323.1185608	0.07
341.2421875	100.00
378.9650574	0.14
394.7084961	0.25
410.9364929	0.73
413.3730774	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.1288
Annotation	Psilostachyin C
Peak:m/z	Relative Intensity
108.8445282	0.16
111.0366058	2.57
136.8245850	0.08
138.0996399	0.23
138.9825287	0.10
151.1776276	0.33
153.0103912	100.00
161.0789337	2.64
162.9594421	0.03
173.1320038	0.05
175.0930634	0.05
178.3211517	0.15
179.2944641	0.07
183.4833374	0.08
186.1467133	0.06
189.0806732	0.12
191.3630676	0.14
201.0388336	2.88
201.6859131	0.08
203.3340454	0.59
204.1901398	2.23
205.5147552	0.09
216.8941650	0.88
219.1642303	35.44
220.0293274	0.02
220.9741516	0.15
224.9759216	0.17
232.9843597	0.03
234.0051270	0.03
235.2549438	0.45
244.3563995	1.14
245.1753387	2.75
248.1791229	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	616.9969
Annotation	Unknow
Peak:m/z	Relative Intensity
174.9088135	0.22
199.2069092	0.33
214.9249878	0.40
245.1390076	0.27
250.2194977	0.05
259.1229248	0.10
273.0482788	9.06
275.0161743	0.74
289.0061035	35.97
289.9922791	0.10
359.2734985	0.21
370.7896118	0.10
373.1756592	0.74
386.1156006	0.30
386.9625244	1.87
388.0686646	1.44
388.9307251	2.22
399.0116577	0.07
401.7199097	0.06
402.9895630	100.00
434.9815063	0.36
442.9196167	0.43
459.2025757	0.22
470.1316528	0.14
471.2545166	0.06
487.1760864	0.18
500.9222412	5.22
502.0285645	6.02
502.9570312	34.99
503.6127319	0.16
523.9691162	0.59
525.1408691	0.87
526.5425415	0.43
527.3576660	0.41
542.9758911	0.21
545.4131470	0.30
553.2199707	0.27
561.1109619	0.03
569.4904175	0.36
570.2570801	1.68
571.2169800	2.74
573.0128784	0.58
589.0504150	0.20
593.6657715	0.15
598.3053589	0.22
599.1380005	0.38
617.0609741	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	323.08
Annotation	Elephantorrhizol
Peak:m/z	Relative Intensity
108.8766327	0.06
120.8352356	0.05
121.8894348	0.14
122.8679352	0.06
127.0252228	1.14
133.0129547	0.34
134.7470703	0.04
139.0166931	0.21
151.0447693	0.67
152.9370422	0.05
154.9966125	6.77
160.0737915	0.21
160.8045044	0.11
163.1203918	0.18
164.8898926	0.10
167.0213928	0.08
169.0815582	6.12
179.0186920	1.72
180.9099884	0.41
183.2236023	0.07
190.9646912	0.02
191.9720154	0.06
193.1398010	0.09
197.0249634	0.98
198.9313965	0.03
201.2506866	0.02
202.1310730	0.06
214.0689087	0.10
215.3430481	0.02
219.1649475	0.03
233.0770264	0.04
234.2237549	0.04
243.1883545	0.57
249.0128174	0.31
255.3576660	0.09
259.0628967	0.11
261.1187744	8.10
264.0737915	0.09
269.0500183	0.55
275.6220703	0.15
277.0902100	0.97
278.1363831	0.43
279.2372742	1.27
287.0780029	49.16
294.3366089	0.13
299.5981750	0.04
305.0074158	100.00
305.6517944	0.13
309.3442688	0.07
314.8063965	0.03
324.4673157	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	535.334
Annotation	Unknow
Peak:m/z	Relative Intensity
161.1471405	0.14
165.4048157	0.10
168.0715485	0.26
177.0869751	1.51
185.3016968	0.07
191.2239227	0.17
193.1289978	0.08
194.2552795	0.36
199.2869568	1.16
207.8225403	1.18
208.8800049	0.13
220.9644318	2.79
221.6062164	0.06
223.3040466	0.12
225.0628052	0.21
226.2205200	0.08
227.5479431	0.24
228.5852661	0.09
229.5897064	3.55
230.2632141	0.25
235.1206360	0.12
238.2288208	0.14
243.0971832	1.85
243.7883911	0.61
245.6682281	0.17
251.5590668	4.55
252.3185577	0.06
253.3053284	0.06
255.1975403	0.11
256.0700684	0.46
262.8703003	0.17
265.0549316	1.01
267.3354797	0.12
268.2217712	0.40
269.0973816	2.33
270.3128052	0.27
271.1375122	0.96
273.6112671	3.50
275.6015015	1.29
277.0632324	0.22
279.1224976	0.41
282.4609985	0.23
287.1506348	0.82
289.4751587	0.23
290.2977295	0.12
295.5675659	7.04
296.4303589	0.14
297.7540894	2.90
299.5834045	0.20
303.1550293	0.20
306.5169067	0.10
309.0965576	0.58
311.9719238	0.07
313.0593872	1.93
317.5142212	3.70
319.5454712	5.47
320.4271240	0.88
321.4846191	0.22
329.4727783	0.06
333.9296875	1.24
339.4952393	3.19
340.1348877	0.32
341.0150757	0.16
341.7658081	8.03
348.3168335	1.22
349.2012329	0.33
355.6708984	0.05
358.6365356	0.17
361.0017090	0.65
362.0757446	1.41
363.4627686	3.56
368.3683472	0.19
370.2071533	0.06
376.2012329	0.21
377.8613281	0.39
382.8041992	0.37
383.6871338	0.69
385.3468628	3.39
386.1803589	0.23
392.0765991	1.06
392.6947021	0.37
393.3973999	0.35
396.9147339	0.27
401.1306763	0.10
405.7780151	0.19
407.7689819	0.77
408.4155273	0.21
409.4046631	0.17
411.2506714	0.05
415.6431885	0.15
419.0800171	0.15
420.1419067	0.06
422.1358032	0.15
424.1397095	0.24
427.4448853	0.46
428.3159790	0.38
429.6752319	2.12
430.4837646	0.20
431.4884644	0.32
436.2368774	0.74
438.7062378	0.08
440.8876343	0.06
443.4246216	0.29
444.7860718	0.40
446.4190063	0.13
451.5319214	0.69
452.5605469	0.53
453.3553467	0.37
460.6668701	0.11
461.3806152	0.32
466.0767822	0.29
466.7026978	0.30
472.5462646	0.10
473.8288574	2.80
474.9902344	100.00
476.3955078	0.75
478.2590332	0.25
479.0507812	0.07
482.8477173	4.10
483.8654785	0.22
485.3076782	0.27
487.8125610	0.34
488.9932251	0.78
489.5966187	0.08
495.8344116	0.46
496.9784546	0.77
502.7421265	0.62
503.6112061	0.04
504.7236328	0.89
505.3524780	1.52
510.2622070	0.08
513.4190674	0.17
515.9801636	0.45
518.3378296	4.81
520.2416992	1.11
521.5108032	0.22
526.2532349	1.60
526.8851929	68.81
528.3995972	1.11
535.6842651	0.33
536.8141479	0.08
547.3090820	0.14
553.5200806	0.14
564.4392700	3.15
565.3616333	0.36
573.3116455	0.28
577.0183716	0.39
590.7384644	0.27
591.4121094	0.07
592.3623657	0.31
594.2644653	0.12
608.3599854	2.63
609.5280151	0.99
611.1997681	0.26
617.3266602	0.38
621.8009644	0.16
634.7045288	0.27
635.5469360	0.17
641.0008545	0.20
652.3217163	4.76
653.5256958	0.52
656.2576294	0.14
664.6273193	0.15
666.3046265	0.05
679.0806274	0.40
682.5502319	0.33
684.5311890	0.24
685.6388550	0.13
696.4042358	2.79
697.3780518	0.47
698.4694214	0.12
700.3486938	1.05
701.3673706	0.20
705.4343872	0.16
708.8810425	0.34
709.5667725	0.09
723.5526123	0.20
726.4049683	0.05
727.2130127	0.32
729.3297119	0.11
740.3702393	2.18
741.4750366	1.22
744.3682861	1.23
745.0814819	0.05
752.9817505	0.24
754.7853394	0.54
772.5119019	0.31
784.5372925	1.57
785.5133667	0.41
788.5332642	2.22
789.4860840	0.48
814.5695801	0.13
816.7510986	0.24
828.6018066	0.04
832.3993530	2.92
833.6203003	1.84
856.8678589	0.11
876.6101074	2.50
877.4633789	1.21
904.8969116	0.04
905.5258179	0.21
920.5639038	0.33
921.5624390	1.37
932.4941406	0.36
948.4285278	10.58
949.4390259	5.03
950.6713867	0.29
1023.8003540	0.33
1034.6191410	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1658
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
112.9942627	1.11
118.9272614	2.61
124.9891586	0.56
131.0847473	3.36
142.8786011	0.78
145.2255859	0.74
146.9153442	0.31
148.7391510	0.65
161.0135651	0.70
163.1416931	49.86
175.0920105	0.17
179.0743103	0.70
189.1064758	0.34
207.0889587	100.00
207.6898346	0.58
209.0438538	1.15
225.1829529	4.11
236.9788513	0.69
251.1221924	0.19
257.3042908	0.13
267.4127197	0.18
279.2559509	0.72
286.7763977	0.33
308.9772339	0.17
311.2962341	0.37
341.1439209	0.24
350.9346008	0.36
369.2851562	19.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.07
Annotation	Melicitrin
Peak:m/z	Relative Intensity
146.8196564	0.05
151.0140076	0.09
163.0083313	0.02
169.2889404	0.01
173.0272675	0.05
178.8640442	0.10
186.9984741	0.08
203.1995850	0.10
205.0982666	0.07
207.1015930	0.09
209.1249390	0.05
214.2011871	0.09
215.1549683	0.11
215.9549561	0.01
217.4133759	0.06
219.2531281	0.04
230.1492920	0.13
231.2996216	0.09
233.1116028	0.48
238.7821350	0.03
241.1949158	0.09
242.1687012	0.01
243.0028687	0.45
244.1175537	0.10
245.1635132	0.05
246.7089233	0.02
255.2867737	0.08
257.1260986	0.15
258.1207581	0.07
259.1328430	0.68
260.1341858	0.14
261.2159119	0.55
262.9385681	0.05
269.1697083	0.09
270.0636597	0.04
273.0982666	0.03
275.0036011	0.08
281.2419434	0.03
286.0087280	1.96
287.1125793	100.00
288.0758057	0.31
289.1467590	0.31
297.0389099	0.23
299.2675781	0.02
301.0969543	0.03
303.0583496	0.06
304.2960510	0.03
306.9016724	0.03
309.2664795	0.03
313.3093567	0.01
319.3897705	0.03
320.4561462	0.01
327.0946045	0.03
329.2074890	0.89
333.0182495	0.07
337.4222717	0.06
341.1475830	0.05
343.5151367	0.01
353.1602173	0.41
358.2371826	0.08
359.0866089	0.02
361.1706543	0.02
363.2866821	0.09
372.1330566	0.01
375.1695251	0.05
377.3114319	0.04
379.2058105	0.43
381.4031677	0.01
387.2010803	0.13
389.1161194	0.09
392.9949036	0.16
393.6294250	0.04
396.2108459	0.10
401.4413452	8.45
402.2245789	83.08
403.2696228	4.35
405.2711182	1.22
407.3672180	0.07
410.3866882	0.06
411.3597717	0.02
412.3133240	0.16
414.5632629	0.02
419.3847351	0.11
421.0354309	0.05
429.2951660	0.05
430.1120300	0.02
431.1714783	0.13
450.4999390	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1296
Annotation	Robinetinidol-(4alpha->2')-robinetinidol-4beta-ol
Peak:m/z	Relative Intensity
173.2877350	0.03
174.2297516	0.06
175.3049164	0.03
182.9921112	0.15
185.3849487	0.07
186.4400635	0.10
187.0556030	0.08
188.0482483	0.03
189.2045746	0.04
195.0014496	0.07
198.1629639	0.14
198.8973999	0.03
204.9379883	0.23
207.0024109	0.04
211.0137634	0.36
212.9659424	0.28
214.0120239	0.14
217.9856110	0.13
219.2693939	0.39
226.9508209	0.10
229.1211548	0.89
230.3724976	0.04
235.2766266	0.07
239.0762634	0.08
240.0346222	0.11
241.3247986	0.88
242.8346710	0.06
245.0725708	0.07
245.7093201	0.10
247.2010040	0.60
255.1932068	1.62
256.2596436	0.44
257.1765747	1.07
258.0687256	0.26
263.3609619	0.07
267.3161316	0.15
282.0639038	0.13
282.9818420	0.14
284.2637939	5.95
285.1019287	100.00
286.1762695	26.75
307.2591553	5.66
308.1718750	1.74
327.2059326	0.99
328.2322998	0.77
351.1584473	0.12
355.0552979	0.04
357.1061401	0.06
370.1607056	0.05
376.3236084	0.07
389.0010986	0.16
390.0024414	0.09
393.6582031	0.11
394.3742676	0.03
399.1765137	0.13
401.3341675	0.12
413.2552490	0.10
418.1557617	0.05
429.2766724	0.27
430.4816895	0.13
443.2447510	0.05
444.0859985	0.14
447.1645508	9.33
448.3013306	4.22
461.4020996	0.11
463.6789551	0.10
474.2310181	0.08
497.5477295	0.07
509.6727295	0.09
514.4884644	0.13
517.4345703	0.08
530.3262329	0.06
534.1229248	0.18
547.1476440	0.34
550.1084595	0.23
557.8875122	0.07
559.6847534	0.22
571.6106567	0.20
572.9142456	0.20
575.4515381	1.06
576.3139038	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1299
Annotation	Bispyribac
Peak:m/z	Relative Intensity
135.0259705	0.39
148.9858704	0.73
150.8729095	0.18
163.2196045	0.28
164.9969482	0.26
165.7932892	0.10
166.9945984	48.24
173.2772064	0.15
174.9932709	0.19
179.0101013	1.02
180.0508423	0.07
181.0601196	0.60
188.9916992	0.18
191.0274963	23.64
193.1222992	0.50
197.1714783	0.50
203.0934906	0.21
205.0957031	0.68
205.8156433	0.36
209.0575867	15.98
217.0671234	0.30
221.0766754	13.54
223.1657715	0.23
233.1041870	2.90
239.0945892	4.58
241.3126221	0.26
249.3060608	0.13
251.0781555	14.16
256.7870483	0.32
259.2815857	0.09
261.2055664	0.21
263.3172302	0.33
269.1544189	12.85
272.2209473	0.19
276.9410400	0.11
281.0904846	4.83
288.8735352	0.05
293.0424194	1.66
299.1218872	49.51
301.1542053	0.09
311.1255493	6.11
313.0923157	0.47
328.2001953	0.13
329.2298889	2.11
335.4865723	0.36
341.2127991	100.00
353.4171143	0.19
365.0577698	0.29
377.5862732	0.44
379.2731628	0.25
381.0379333	0.40
387.1559753	0.06
392.3077087	0.07
395.5174866	0.10
397.2133179	0.13
399.1512451	0.08
400.3176575	0.40
401.2746582	0.05
414.3835144	0.14
415.2344971	1.85
419.1919250	0.54
425.0635071	0.20
433.1867371	0.07
438.3476562	0.15
442.1561584	0.28
443.2698059	4.09
447.3551025	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
144.9517822	0.53
148.783783	0.38
161.0919495	0.85
171.1158142	0.67
173.1137695	0.68
185.0280304	1.00
187.0278625	0.31
199.1777954	0.28
201.2825165	0.67
205.2045898	0.48
206.8997345	0.48
215.3156128	1.02
217.2853088	1.70
229.4217834	1.06
231.2729492	1.06
234.7113647	0.61
239.2687683	0.33
240.8368225	0.78
243.1569519	1.49
246.2071838	0.50
248.085144	0.37
251.1422729	0.26
253.2785339	0.58
254.0862122	0.23
257.1295776	1.19
259.3154907	0.21
261.0982056	0.39
263.2733765	0.97
265.3411255	0.62
267.4154968	0.66
269.2680054	0.78
271.2523193	3.83
273.5432739	0.50
277.2949524	0.76
279.3518372	0.55
281.144165	0.49
284.0979614	1.31
285.3208618	4.12
287.4213562	0.18
294.2017517	0.21
295.1044006	2.30
296.3930054	0.15
297.3595581	1.96
299.503479	1.59
311.2093201	3.33
312.2415161	1.16
313.3488159	2.49
315.0089417	0.56
319.1889954	0.29
321.1306763	5.77
322.2026062	1.90
323.3421631	6.73
325.5304565	0.94
329.1321411	2.63
337.0684509	0.66
339.2508545	100.00
340.5872803	3.69
341.4128723	13.68
342.3167419	3.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	508.3103
Annotation	Broussonetine A
Peak:m/z	Relative Intensity
163.0855713	0.16
164.2833557	0.16
165.3186340	1.00
166.9496460	0.13
174.8779144	0.68
177.1401825	0.69
180.1851807	0.36
185.0115204	0.11
190.9734192	0.19
193.1436157	0.30
209.0122070	1.19
213.1861572	0.17
219.0221252	0.27
220.7911682	0.37
223.2350616	0.17
228.8162231	0.11
235.2284546	0.24
245.2683411	0.28
253.0829468	1.82
255.0617676	0.45
265.2363892	2.04
266.9156799	0.17
279.0492859	0.19
296.9730530	1.39
300.0892639	0.30
304.1923523	0.88
309.2463989	0.82
316.1081543	0.09
325.6356812	0.10
327.1180725	0.15
334.3621216	0.21
335.3647766	0.47
336.0650940	0.14
339.0275269	0.33
340.9089355	0.22
353.0677490	0.67
358.5541382	0.43
359.7141113	0.06
363.1750488	0.09
364.2638245	0.40
366.9426880	0.69
372.1531067	0.39
378.0719299	0.16
383.0497131	0.48
385.1857300	3.08
387.3139343	0.08
395.9763489	0.38
401.2110901	0.14
402.8796082	0.80
403.5103455	0.58
405.7509155	0.48
410.0276794	0.12
413.2043152	0.34
420.8780823	0.59
421.7213440	0.24
429.1119385	0.18
436.2178040	0.39
444.5884399	1.05
445.5741272	0.10
447.2727966	2.13
454.6372681	0.13
459.4114380	0.63
462.1590881	0.38
463.1784668	0.22
465.5101013	0.61
471.5000916	0.12
472.8580017	2.32
473.5421448	0.18
474.2482605	0.09
477.9695129	0.40
486.9434509	1.08
491.1645203	100.00
491.8414001	0.36
499.7468567	0.29
508.2438049	0.06
509.3208618	0.17
516.6469116	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	461.2895
Annotation	Unknow
Peak:m/z	Relative Intensity
132.8055115	0.05
139.0929413	0.03
145.1595612	0.04
165.0974121	0.32
167.5397949	0.09
174.9937744	0.07
177.0304413	0.36
177.9308167	0.02
184.8214264	0.06
193.9761658	0.04
209.0754852	0.22
209.9300995	0.11
211.1316833	0.24
212.6429138	0.04
216.1904907	0.05
221.2575378	0.32
222.9919586	0.02
229.6588440	0.37
235.0576935	0.04
239.2241211	0.17
243.1861267	0.04
244.2845154	0.19
245.4211121	0.21
246.0590820	0.03
251.4858093	0.26
252.1676941	0.10
252.9266357	0.17
254.1047058	0.03
255.3326416	0.06
259.1194458	0.04
263.2386169	0.03
265.0538025	0.18
266.1922913	0.02
267.9338379	0.66
269.2949219	0.04
271.1358032	0.30
272.9942017	0.18
273.6849976	0.82
279.1505737	0.07
281.9715271	0.02
283.1392212	0.14
284.0273132	0.05
287.3167114	0.07
288.1989746	0.08
288.9776001	0.07
289.8380127	0.60
290.6019897	0.05
295.7077332	0.84
300.3395996	0.06
303.5554199	0.07
309.3852539	0.02
311.4840698	1.51
312.2471313	0.47
313.3484497	0.03
317.5457458	1.31
325.5241699	0.09
327.3011780	0.06
333.8074036	1.36
340.2449951	0.07
341.1411133	0.09
343.5271606	0.09
345.3313599	0.02
353.1829224	0.09
354.2782593	0.07
355.6187744	1.44
361.9875488	0.09
369.0434570	0.07
374.1535034	0.15
377.5081482	0.06
378.1803894	0.18
379.1954346	0.08
383.0619812	0.12
384.4309998	0.03
387.5332336	0.07
389.2413025	0.03
394.2569885	0.05
398.2212219	0.04
399.4537048	0.89
400.2393799	0.04
401.2036438	0.04
402.2458801	0.19
403.3348083	0.17
404.1729431	0.09
407.2963257	0.04
409.2031555	0.21
412.1041565	0.03
415.2567444	0.08
416.5118103	0.11
420.1944885	0.16
421.4362183	0.17
424.6459656	0.14
426.6423035	0.04
430.7539368	1.22
431.3805542	0.19
433.3832703	0.07
434.2684631	0.05
443.4542847	0.77
444.4129333	1.63
445.0697632	0.36
452.8434448	100.00
454.0656128	2.94
454.9743347	0.83
455.7554626	0.29
456.6104126	0.22
457.5323181	0.19
458.2609558	0.03
459.1628113	0.09
461.7363586	0.35
462.6548157	0.04
476.3758240	0.05
477.3200989	0.08
484.9437561	0.28
503.4485779	0.02
520.7257690	0.11
521.3776245	0.09
529.0905151	0.22
547.3875122	0.05
564.4732056	0.52
565.1781616	0.26
578.5558472	0.07
590.4792480	0.03
592.5595703	0.03
596.5934448	0.29
597.7388306	0.07
608.5480347	0.24
609.5051270	0.14
617.2954712	0.03
623.4384766	0.13
635.0805664	0.12
640.3717651	0.38
641.4218140	0.03
652.5080566	0.48
653.4464722	0.11
667.6310425	0.05
684.5999756	1.29
685.5841064	0.07
696.3436890	0.12
697.5122681	0.07
712.4059448	0.17
728.5902710	0.27
729.4243164	0.13
755.4032593	0.29
772.2862549	0.06
773.4580688	0.15
845.7015991	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.0622
Annotation	8-Hydroxytricetin 7-glucuronide
Peak:m/z	Relative Intensity
164.1642151	0.02
171.7951660	0.02
178.9934082	0.06
187.1113434	0.03
239.0787048	0.02
248.4409332	0.02
249.1246338	0.03
259.0521851	0.01
266.7984314	0.02
272.1351318	0.01
285.1535034	0.09
287.0650024	4.87
289.3941345	0.04
303.0037842	0.02
306.3556824	0.01
311.3579712	0.02
313.1960449	0.04
328.9979553	0.02
330.8052979	0.05
332.1186523	0.02
333.4520874	0.01
342.1030884	0.01
345.3158875	0.04
354.4517212	0.02
355.1212769	0.03
360.9786682	0.07
363.3093567	0.01
365.0523987	0.02
371.4283447	0.01
375.1506958	0.02
381.4066772	0.01
389.1674500	0.03
396.0851746	0.02
405.3879089	0.06
413.0521545	0.04
421.1730652	2.14
421.7776794	0.04
446.4279785	0.30
449.1462708	100.00
449.7553101	0.15
455.9167786	0.03
463.3944702	0.11
471.2464905	0.02
475.3412170	0.05
478.5340271	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	468.3889
Annotation	Unknow
Peak:m/z	Relative Intensity
131.1839600	0.04
149.1284180	0.05
177.1712036	0.22
192.9941406	0.16
198.9432068	0.14
211.1171570	0.23
217.2450562	0.34
221.1641235	0.07
223.2334595	0.05
225.1247253	0.10
231.1752319	0.33
234.7143250	0.11
236.1365967	0.04
240.2688599	0.08
247.0746765	0.42
249.2111511	0.27
257.1818237	0.92
259.0099182	0.19
265.2716064	0.18
283.2374573	0.72
290.7079468	0.07
294.3457947	0.58
301.2035522	0.39
321.9125977	0.18
325.0753479	0.09
329.2224731	0.24
335.6136169	0.08
338.1603394	0.05
341.4050598	0.47
343.3988037	0.17
345.4183350	0.09
356.3704224	0.24
367.5207825	0.66
376.0645447	0.07
383.3236389	0.18
384.5734253	0.08
386.7664490	0.12
394.2829590	0.16
396.0386047	0.06
400.0821838	0.45
401.2050171	0.22
405.7296753	0.05
407.2390442	0.79
415.2497864	0.73
419.1019897	0.53
422.6302795	0.63
423.5047913	0.09
425.3572693	0.12
432.6693726	0.82
434.3465576	0.16
437.1478271	0.24
446.2049561	0.09
449.6808167	0.29
451.2572327	100.00
451.9271545	0.31
468.2975464	1.02
468.9902649	0.33
469.6277161	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	606.074
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
174.8879700	0.06
176.7996979	0.63
184.2684937	0.05
185.1545258	0.03
185.8769073	0.06
193.0627441	0.32
199.0628204	0.08
200.9854126	0.10
210.9434814	0.77
222.0287933	0.81
222.8963928	0.13
227.9320374	0.05
237.3974762	0.05
240.2012329	0.54
241.2207642	0.05
243.1155243	0.17
246.0666199	0.43
255.2091827	0.05
261.1704407	2.39
262.2137756	0.11
264.1441040	1.10
265.0809937	0.19
273.0780640	14.12
273.8952637	1.28
274.6173096	0.19
280.1097107	0.54
282.0810547	35.44
283.1156921	5.69
291.1171875	0.48
291.9943237	0.25
300.1483154	5.50
301.0989990	1.00
305.1574707	5.35
306.0546265	1.15
307.3632202	0.04
310.8903809	0.36
312.8870239	0.19
323.0792236	21.05
324.1522827	4.62
326.1802368	0.03
327.2410278	0.08
333.5698242	0.05
342.2791138	0.11
344.1207275	2.89
345.2671509	0.25
354.2666016	0.04
354.8854370	0.15
360.1134033	0.08
362.1123047	24.29
363.1367188	3.80
367.4212036	0.07
378.1422119	0.05
379.4889526	0.29
380.2142334	0.30
381.0115356	0.54
385.0540161	100.00
386.1436768	19.73
388.0524292	0.21
392.9044800	0.13
394.7382202	0.71
403.0913696	60.02
404.0782471	11.50
404.6824341	0.10
407.1505127	0.19
411.1690063	0.10
432.7871704	0.61
438.5372314	0.71
443.1165161	0.05
444.0678711	0.03
444.8214722	0.08
448.8650513	0.08
461.3148193	0.07
468.7959595	0.40
470.8858032	1.15
473.9752808	0.20
476.9124146	0.14
478.7395020	0.03
485.1538696	0.30
486.2980957	0.29
487.1286011	0.30
490.1494141	0.03
494.1649170	1.03
495.2426147	0.26
508.2662354	5.86
509.3002319	2.85
521.0119629	1.60
522.8910522	9.17
523.8125000	0.02
526.1295776	0.51
527.5038452	0.12
546.6406250	0.47
561.0156860	0.13
562.4528198	0.22
563.1133423	1.37
564.1354980	1.19
571.1667480	0.08
588.9584961	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	326.1594
Annotation	Boveinine
Peak:m/z	Relative Intensity
94.8330536	0.07
101.9125900	0.43
109.0187454	0.02
118.9902496	0.29
120.9801331	0.04
129.9489136	5.50
133.0988770	0.47
136.9677734	8.61
143.9059753	0.81
148.0197449	3.01
151.0157166	0.04
161.0872040	1.47
171.9977417	6.21
179.1141510	9.50
183.2873383	0.04
185.1150818	0.22
187.0635223	0.07
187.9005890	0.11
189.9436340	0.08
197.1620331	0.46
199.0891876	0.12
200.2019348	0.06
209.0466919	0.04
210.0218201	0.05
211.9768372	0.15
212.9726562	0.06
215.2057495	0.10
219.9787292	0.04
227.2279663	0.30
228.3213501	0.21
232.3202209	0.07
234.2831726	0.24
238.3445740	0.04
244.3618774	0.17
251.2420044	0.11
256.1759033	0.13
258.1965027	0.02
262.1752319	12.21
264.3977661	0.04
266.1314697	0.13
268.3811035	1.69
269.2061768	3.88
270.0026550	0.84
280.1973572	52.21
282.1079712	0.47
290.1422119	13.39
297.0123596	0.06
298.1319885	0.53
308.1119385	100.00
317.6903381	0.04
325.3777771	0.06
327.2017517	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	236.1136
Annotation	Unknow
Peak:m/z	Relative Intensity
85.1728439	0.04
95.0741272	0.01
112.8425751	0.02
120.8200226	0.01
123.0487823	0.03
133.0380096	0.02
152.0376434	6.22
163.9746704	9.10
168.1613312	0.02
171.9502716	0.03
176.3522797	0.05
177.1040802	0.02
179.1427155	0.63
180.0501556	0.37
182.8824463	0.02
186.8501282	0.07
190.2584991	0.05
192.2059326	0.02
195.0062561	0.06
199.8428040	0.05
201.1181183	1.43
205.8823547	0.06
208.0791626	0.01
216.1893463	0.04
218.0991364	100.00
218.9965820	0.08
221.1699371	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1248
Annotation	Myricetin 3-sambubioside
Peak:m/z	Relative Intensity
173.3256531	0.11
179.0286255	2.11
185.0041504	0.03
187.0236664	0.10
189.0993042	0.05
190.3468323	0.06
192.1404572	0.09
193.0710907	0.20
200.0524597	0.06
201.2502899	0.11
203.2345734	0.17
204.0537720	0.17
207.2074585	0.05
211.2545776	0.03
214.0180664	0.25
214.8904419	0.11
216.9548340	0.08
219.2699280	0.09
227.0869141	0.26
228.8995209	0.09
231.1378174	0.10
234.0549316	0.04
241.1540070	0.17
242.1166992	0.62
243.2023773	0.51
244.9351959	0.45
247.0772095	0.30
252.8209839	0.07
255.3882141	0.26
259.1730957	1.12
261.3531494	0.20
266.7790833	0.36
268.3451843	0.02
269.9708252	1.92
271.1171875	8.93
272.0197449	0.04
273.0672913	0.09
280.7440796	0.02
281.3711548	0.14
283.1457520	0.17
285.1791382	0.04
287.0745239	4.32
288.0285034	0.07
289.0825195	1.00
290.8489990	0.21
295.1563721	0.03
297.2201538	0.65
299.0325928	0.10
300.1596069	0.10
306.1250000	0.03
309.3093872	0.48
311.1003723	0.12
311.9719849	0.05
313.2080688	0.28
314.0443115	0.09
316.0663452	100.00
317.0749512	24.24
318.0848083	0.33
321.1909180	0.06
323.0740662	0.13
325.4522705	0.09
327.0135498	0.81
329.3643799	0.06
331.1719360	0.02
335.1480103	1.62
336.0714722	0.04
339.3673096	0.08
340.0906982	0.06
340.9719238	2.25
341.6976318	0.14
343.1204834	0.09
353.3657837	0.09
359.0901489	1.67
363.5053101	0.05
365.0463867	0.09
365.6477051	0.03
369.0424805	0.06
371.2116089	1.93
375.3784180	0.15
376.9182129	0.10
383.2059326	0.89
385.7213135	0.04
387.3785400	0.06
389.1018066	1.59
399.1177368	0.54
401.3061523	0.17
402.9845581	0.08
417.2412720	0.53
418.5660400	0.05
419.2529907	0.15
425.1557007	0.07
429.1090698	0.08
430.2833862	0.04
434.8673706	0.05
443.1924438	1.36
444.9251099	0.23
447.2147217	0.26
448.8521729	0.04
461.1954956	4.63
462.3585205	0.15
463.2086182	0.76
473.1910400	0.12
479.1591797	4.85
480.4769897	0.13
481.1428833	0.06
485.3705444	0.63
491.1520996	4.25
501.3569336	0.54
521.1040649	0.13
531.1959839	0.11
539.1557007	0.04
549.3585815	0.20
557.1714478	0.06
565.2966309	0.25
567.2206421	0.49
575.3804932	0.09
593.2481079	6.52
594.0878906	0.06
623.1882935	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.1301
Annotation	Peltatoside
Peak:m/z	Relative Intensity
172.3029327	0.06
173.1775208	0.06
175.1491089	0.23
179.0177002	4.09
187.0818787	0.06
189.1433716	0.26
191.014679	0.11
193.0711975	0.08
198.0981903	0.11
200.2932281	0.03
201.3451996	0.02
202.9950867	0.10
204.3888245	0.04
205.102417	0.03
211.0333557	0.20
212.1757812	0.19
213.1910706	0.15
214.8299561	0.28
219.1367493	0.20
226.0383453	0.36
227.029541	0.40
228.1700439	0.14
229.0932007	0.83
230.2112122	0.04
231.2162628	0.13
233.0561829	0.13
239.1269226	0.17
240.9890137	0.16
242.1400909	0.08
242.9508667	0.66
244.1642456	0.05
245.0150146	0.16
246.9150848	0.41
251.1269226	0.06
252.1618195	0.20
254.1964722	1.04
255.1342316	7.39
256.3574829	0.06
257.1541748	0.81
261.4315186	0.03
263.1799622	0.07
265.020752	0.03
269.1065674	0.09
271.1626587	14.40
272.2193604	0.03
273.1350098	2.57
281.1764526	0.24
283.0370483	0.21
289.2857666	0.12
291.3729553	0.11
293.2453308	0.36
295.1218872	0.04
295.9349365	0.02
297.0038757	0.51
298.2044067	0.16
300.0224304	100.00
301.0828857	44.63
301.8057861	0.23
305.2831421	0.05
309.1135254	0.04
311.2554321	0.10
313.3132935	0.16
313.9247437	0.02
315.2600708	0.03
319.1589966	1.09
321.2617188	0.28
323.2210693	0.05
325.2244873	2.54
327.1556396	0.34
329.2112427	0.29
335.1437378	0.03
336.4031372	0.28
337.0535889	0.37
339.2169189	0.16
341.2405396	0.58
343.0535278	6.37
344.3024902	0.16
347.3401489	0.05
348.9507446	0.09
349.6403198	0.04
353.5112915	0.19
354.1361084	0.03
355.1582031	2.57
356.3739624	0.13
357.2954712	0.10
361.1390991	0.12
365.2005005	0.49
367.2026978	2.65
367.9386597	0.08
369.2615967	0.15
371.3964233	0.04
372.258606	0.20
373.1646729	0.98
374.3554688	0.10
379.272583	0.03
381.3140869	0.21
383.1896362	0.15
385.2340088	0.58
387.168457	0.25
389.0574951	0.02
390.87677	0.15
397.2474976	0.40
399.1065063	0.14
401.2276001	1.38
403.302124	0.50
407.3074951	0.20
409.2346191	0.86
410.2306519	0.26
415.0883789	0.21
417.2033691	0.23
426.7190552	0.96
427.3471069	2.01
429.4766846	0.06
431.2702026	0.46
432.0803223	0.13
432.8837891	0.23
433.5124512	0.14
441.380127	0.11
445.2057495	26.16
446.0863647	0.05
447.2978516	0.02
459.2991333	0.12
461.0986938	0.11
463.1938477	18.94
464.1089478	0.23
467.4443359	0.04
469.1641846	0.13
475.1936035	11.47
475.9317627	0.08
485.0474854	0.05
486.3909302	0.34
487.2903442	0.09
488.9984131	0.03
497.4978027	0.11
499.3453979	0.10
504.3639526	0.07
505.1707153	0.18
509.3847046	0.08
511.3673706	0.06
523.2949219	0.08
529.4921265	0.03
533.2628784	0.12
535.2061157	0.16
549.2543335	0.35
551.0466919	0.33
553.1489258	0.05
556.4389038	0.15
559.2704468	0.25
565.3226929	0.82
576.1356812	0.19
577.1715088	2.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
151.03125	4.26
152.8013306	3.77
163.1788635	1.86
165.2535095	2.59
171.0154419	11.87
174.8690338	3.55
183.8852234	1.63
190.7467041	2.38
192.1011963	5.84
207.1882629	8.18
227.1038513	1.42
228.73349	1.05
237.2860718	5.15
239.2868958	2.86
272.833313	9.46
274.3010254	14.28
281.4775696	2.84
283.7093811	2.38
285.1414185	2.48
286.4569092	6.68
297.3297119	5.50
305.3829346	4.50
307.0426941	8.73
308.4570923	3.66
314.4191895	6.68
318.3491211	9.48
328.1439209	14.65
334.4541626	8.60
337.491333	2.86
339.3371887	5.40
354.5042419	4.68
357.4586792	4.11
366.6296082	5.21
369.3833923	0.82
377.2452698	8.86
379.634613	5.34
380.3403625	13.29
381.6302795	26.24
382.2472229	3.11
385.007782	4.84
385.8269043	2.50
395.1438599	30.59
397.6253052	4.38
399.2496948	2.87
407.5942688	23.71
408.2807922	100.00
409.1266479	2.26
412.3213196	5.92
424.6607056	6.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	768.1564
Annotation	Unknow
Peak:m/z	Relative Intensity
254.2266235	0.06
271.3521423	0.18
272.1530151	0.22
306.0011597	0.27
315.0858154	4.53
333.1957397	0.05
335.2197876	0.13
340.8084717	0.06
356.1083374	0.36
357.1884766	0.07
361.0928345	0.09
365.5363770	0.08
381.3259888	0.14
386.9281006	0.10
410.9208984	0.36
421.1527710	0.09
440.2255859	0.13
443.4660645	0.48
454.5911255	0.05
461.2737427	0.41
463.1631470	0.48
476.8722534	0.11
495.1074219	100.00
496.0222168	0.85
508.5417480	0.12
510.8906250	0.34
512.3460083	0.10
527.1464844	0.28
535.0651245	0.35
569.7376099	0.06
575.2939453	0.10
586.4087524	0.13
587.3948975	0.11
603.9260864	0.26
605.0065308	0.24
606.1689453	1.53
607.1851196	0.54
610.1356201	0.22
619.1248169	0.15
623.3640137	0.23
629.8865356	0.27
638.0552979	0.13
639.0562134	2.80
640.2421875	0.20
652.2718506	0.13
653.5070190	0.07
658.9624634	0.04
669.2301636	0.28
674.1781616	0.30
682.4514160	0.07
683.2644043	0.15
686.3516235	0.15
687.1468506	0.25
693.3588257	0.22
719.1291504	0.24
724.3147583	0.39
727.2521362	0.11
729.3422241	0.18
741.3118896	0.28
749.3312378	1.19
750.0166626	1.33
750.6259155	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	628.3828
Annotation	Unknow
Peak:m/z	Relative Intensity
198.9082031	0.03
210.9724731	0.07
216.9903564	0.02
220.9931030	0.31
223.1601410	0.02
225.2123566	0.08
235.2100525	0.02
237.1688995	0.02
249.1308136	0.07
251.2144318	0.37
253.2344360	0.02
254.9714508	0.01
265.2895203	0.16
267.0714111	0.02
269.1778564	0.18
271.2603455	0.01
277.0071106	0.05
279.0129089	0.03
295.2810669	0.09
304.2486572	0.03
308.7117920	0.07
309.3312073	0.11
311.0728455	0.23
313.2338867	0.53
315.3218994	0.05
327.2636108	0.02
329.2661743	0.27
331.1056519	0.03
336.6055908	0.06
339.3144531	0.03
354.8929443	0.06
357.1371460	0.14
358.9149780	0.04
360.4224854	0.01
370.9671631	0.04
373.3059692	0.99
375.0451050	0.21
381.2546387	0.05
382.9611816	0.01
385.3881226	0.01
392.3020630	0.03
399.3138428	0.10
401.0447998	0.87
403.2391357	0.15
417.0971069	1.17
419.1876831	0.56
426.2319946	0.03
434.9281006	0.06
440.5496826	0.01
443.2669067	0.04
445.3329468	0.06
447.1542969	0.03
461.0894775	0.26
463.2371826	0.38
466.2619629	0.06
479.3669434	0.08
484.2230835	0.02
489.2905273	0.11
502.6136475	0.02
505.0837402	0.84
507.2124634	13.06
507.9216309	0.04
522.5875854	0.06
523.3355713	0.41
524.2551880	0.05
527.7283936	0.05
533.1755981	0.03
546.1585083	0.05
547.7552490	0.07
549.4485474	0.03
567.1481934	0.68
567.7643433	0.15
569.3523560	0.02
586.5872192	0.03
593.1308594	0.52
611.2232666	100.00
611.8919067	0.16
627.7312622	0.02
628.3760986	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	347.1862
Annotation	Gelomulide X
Peak:m/z	Relative Intensity
127.1144104	0.06
146.9094849	0.09
162.1386108	0.22
162.7802124	0.04
209.2705078	0.03
218.2211304	0.03
228.3688354	0.03
239.0600586	0.14
241.4012146	0.05
247.3638611	0.10
251.9938354	0.06
253.1539917	0.06
255.1863708	0.08
257.2227783	3.02
259.3243408	1.97
262.1398926	0.06
265.6311035	0.02
267.0481262	0.06
269.2677002	0.38
270.0832520	0.49
274.2196655	0.08
274.9438477	0.04
285.3245239	0.64
295.6726990	0.29
301.2547302	2.90
303.2421570	100.00
303.8554077	0.18
304.5434875	0.19
309.2219238	0.28
310.2399902	0.07
311.2339783	0.50
312.0449219	0.17
313.2592773	0.22
317.1862183	0.21
319.2666321	0.14
328.6976318	1.46
329.3495483	6.49
331.4078674	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	303.0497
Annotation	Bracteatin
Peak:m/z	Relative Intensity
92.5314331	0.34
108.9230194	0.36
110.9940948	5.22
111.9946060	0.18
120.6907120	1.35
121.9725342	0.92
126.8779907	1.07
135.0632629	0.70
137.0344543	16.71
138.0728455	0.44
144.9470978	0.47
148.9619141	3.22
150.1120911	0.61
152.9651184	10.81
154.2185364	0.61
161.0117188	3.97
162.8726807	4.58
164.9730377	29.68
166.0135956	4.69
167.2260132	0.51
169.0272675	0.25
173.0158997	2.51
175.3447876	0.41
177.0663910	2.33
187.1546936	0.16
188.9252625	1.16
191.0686951	1.45
193.1965332	3.04
194.2855072	1.19
195.0023956	3.47
195.8576508	0.16
201.2055054	3.28
202.3615723	0.58
204.9810791	3.85
205.9570618	0.32
207.5019226	0.82
213.1809387	3.85
214.0273438	0.21
215.1308594	1.60
217.0481262	0.47
219.0718994	7.14
220.3403625	0.51
223.1890869	0.52
229.0463562	67.06
230.1081848	7.23
231.0065308	0.39
233.0010986	2.49
236.3157959	0.71
239.2586060	1.23
241.3078003	0.83
242.1228333	0.17
246.4216614	2.01
247.1330566	28.14
247.9857178	2.45
257.1192322	100.00
258.1375732	16.31
261.1956177	0.19
267.0934143	1.36
274.1696472	15.64
275.1571655	11.45
276.2205811	0.71
285.0711670	60.64
286.1425781	11.21
303.1824341	30.73
304.2813110	1.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	540.32
Annotation	Unknow
Peak:m/z	Relative Intensity
178.6794128	0.06
209.2654877	0.16
211.2190857	0.02
219.1176758	0.19
220.8512573	0.05
236.8194275	0.07
241.0054626	0.01
248.8082275	0.03
261.1944275	0.06
264.8203735	0.03
268.0665894	0.04
274.3119202	0.01
278.2266846	0.04
283.3418579	0.04
286.2871399	0.02
290.0157471	0.05
292.1520081	0.03
294.3218384	0.16
298.1318359	0.02
307.3541260	0.04
312.4268188	0.76
313.4281616	0.16
318.3975220	0.04
322.2001343	0.02
322.9645386	0.01
326.0317383	0.04
330.3569336	2.58
331.2117920	0.40
332.2763672	0.03
336.3950195	0.12
337.1036377	0.10
340.5435181	0.03
341.2877808	0.01
342.3087769	0.13
346.3128052	0.03
352.3790894	0.04
354.4709473	0.28
359.4312744	0.03
360.6536865	0.07
361.3005371	0.04
362.3671265	0.02
372.3321533	0.22
376.7177124	0.04
378.1434326	0.13
379.2282715	0.02
380.6551514	0.08
381.8612671	0.12
387.0485840	0.01
390.3543701	1.97
392.4299316	0.14
393.0411987	0.05
394.6260986	0.02
396.6384888	0.06
406.5335693	0.30
408.3534546	100.00
409.4519043	0.07
411.4177246	0.05
416.3473511	0.04
418.1215210	0.03
419.1088867	0.03
426.3997192	1.31
432.3311768	0.07
434.0344849	0.02
435.5608521	0.07
444.4115601	0.28
446.2335815	0.02
447.0496826	0.05
450.3020020	1.73
458.6766357	0.09
462.4833984	0.06
474.3692627	0.02
480.3408813	0.39
481.4409790	0.02
486.3209839	0.58
487.3843384	0.05
498.5684814	0.04
504.4060669	6.29
505.0149536	0.04
518.0449219	0.08
519.1940918	0.12
522.3608398	3.71
523.1461792	0.30
531.7114258	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	401.1088
Annotation	Veranisatin B
Peak:m/z	Relative Intensity
137.1297913	0.18
178.1051178	0.33
180.3222046	0.07
193.0543213	23.95
194.3986664	0.07
195.0558624	0.22
201.0787048	0.09
203.2133484	0.13
206.0782318	0.10
206.9458466	0.10
224.2059174	0.22
235.7583008	0.15
236.7309875	0.22
238.1702881	0.42
238.9873962	0.95
240.8115234	0.08
242.3429565	0.10
252.8292236	0.06
264.9722290	0.12
265.8934937	0.10
267.2014465	0.21
268.0202637	0.11
269.1910400	0.08
281.6576538	0.32
283.3831787	0.26
286.2080383	0.24
295.0139771	0.11
299.0051270	0.12
301.1865845	0.37
311.3313904	0.13
313.2300110	0.23
321.2138672	0.24
337.1795044	0.09
338.9465942	0.09
347.0769958	0.08
355.1154785	100.00
355.7274170	0.48
357.2184753	0.97
365.2728882	0.17
370.5991516	0.08
382.2278748	1.64
383.3699341	1.53
386.3549805	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1659
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
112.9075470	2.76
119.0572128	1.56
131.0503235	0.62
143.0235596	2.27
145.0541534	1.78
146.9580688	0.64
159.1354065	0.22
161.0370789	0.78
163.1105042	48.48
164.3269958	0.11
179.0394897	0.66
181.2577820	0.58
207.1858673	100.00
211.1903381	0.21
217.2633057	0.28
225.2468262	2.12
237.3019104	0.12
249.1280823	0.38
287.3054199	1.40
297.0971069	0.20
327.0051270	0.09
341.1362610	0.18
354.3592224	0.28
369.3315735	23.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2779
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
139.9493408	0.06
152.8588104	0.08
163.1379852	0.02
166.1206818	0.01
171.1525269	0.03
186.9936676	0.01
196.0542450	2.08
197.0598755	0.24
207.0782166	0.01
214.1524963	1.37
215.2081757	0.22
229.0663300	0.03
239.0275879	0.02
261.3231812	0.23
262.4054871	0.03
279.2934570	100.00
280.2723083	22.50
291.2102966	0.03
305.4352112	0.02
309.4304810	0.04
315.1286011	0.00
343.3054199	0.03
353.3855896	0.05
390.8172607	0.01
393.3034668	0.02
397.3500061	0.02
403.1325684	0.03
415.2151184	0.25
416.4417419	0.08
417.2907410	0.02
419.4164124	0.02
420.2958679	0.01
421.6710815	0.03
423.4365540	0.02
431.4253235	0.04
432.3690796	0.01
433.2199707	0.12
441.4391785	0.01
442.1398621	0.04
449.2792664	0.02
459.2480774	0.17
460.3441772	0.03
462.3903503	0.02
475.4841614	0.01
476.7046204	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	182.0807
Annotation	4,6,7-Trihydroxy-1,2,3,4-tetrahydroisoquinoline
Peak:m/z	Relative Intensity
119.2406311	0.05
136.0798798	17.69
146.9601898	0.21
164.9474030	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	524.3205
Annotation	Sordarin-1-methyl ester
Peak:m/z	Relative Intensity
163.2594910	0.03
177.0157776	0.13
203.7640533	0.02
220.4592896	0.10
221.0881958	0.13
225.0915527	0.06
226.3782654	0.02
235.4606323	0.04
241.0397186	0.12
251.2004395	0.21
253.0851440	0.02
269.2101135	0.43
271.3199158	0.05
279.1291504	0.05
294.3608398	0.05
295.0895386	0.08
296.4370728	0.07
297.2935181	0.13
299.0850830	0.07
309.2276001	0.39
312.8087158	0.88
313.4668579	0.84
314.9900513	0.12
316.1768188	0.05
344.3033447	0.12
348.0308838	0.08
350.4740601	0.03
355.3493042	0.10
357.4697876	0.05
359.2929077	0.17
367.0784302	0.06
374.5368652	0.08
376.5538330	0.05
380.2445068	0.02
383.3514404	0.08
399.3656006	0.02
401.1381836	0.40
403.2900391	1.70
407.1515503	0.13
419.1589966	0.46
428.6289673	0.08
430.5292969	0.06
435.4039307	0.13
449.5866089	0.02
455.1162109	0.03
463.3457031	0.72
470.4202881	0.12
474.9656372	0.02
478.2052612	0.06
482.7623291	0.23
485.8582153	0.02
489.1359253	0.87
489.7628784	0.02
491.1472778	0.27
493.2517700	0.02
505.0529785	0.15
507.2344971	100.00
507.9326782	0.30
510.1495972	0.09
514.8845215	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	584.0317
Annotation	Unknow
Peak:m/z	Relative Intensity
169.7250214	0.28
170.8784332	0.04
171.8730621	0.56
172.9931183	0.06
184.8815613	0.08
189.0011292	0.78
193.0730438	0.09
198.1685638	0.05
201.9918976	0.05
212.0277100	0.14
213.9997253	1.30
214.9716492	0.05
224.3287048	0.05
226.0397034	0.27
231.7712097	0.28
240.0713196	0.04
241.2229004	0.15
253.0803986	0.10
254.0494995	0.04
260.0655823	0.81
274.1239929	2.51
277.1233215	0.12
278.8560486	0.04
285.9999390	0.08
290.0829468	0.82
300.0673523	1.24
301.9583740	48.23
306.0582886	0.34
312.1718750	0.17
314.2415161	0.14
316.1050415	2.13
318.3233032	0.05
331.9951782	1.99
334.0675659	1.37
337.2611694	0.45
341.6467285	0.34
343.0902100	0.12
359.4777832	0.38
362.1298218	1.20
363.9670410	0.15
373.9285278	0.43
383.3500977	0.05
386.0320435	0.51
387.9622192	0.44
389.1904297	0.20
391.8572998	0.26
393.0621948	0.43
394.1168213	2.23
395.1004639	0.47
396.0333252	0.14
402.2110596	0.05
404.0163574	10.98
405.4882812	0.36
410.0311279	0.20
412.1758423	37.65
420.0922241	0.21
420.9481812	0.26
422.1026611	13.93
431.8369751	0.31
433.0468140	0.05
433.7235107	0.09
437.7885742	0.08
439.1854858	0.28
444.0684204	0.06
447.2537231	0.22
450.4824829	1.17
452.1363525	100.00
453.2551880	0.05
462.4800415	0.05
463.9422607	0.45
467.1533203	0.10
468.0597534	1.27
475.9348755	0.05
478.1115723	3.49
479.1604004	0.21
485.8673096	1.27
492.9274292	0.05
494.2482910	1.49
495.4556274	0.15
496.0871582	5.48
503.3944702	0.03
505.5803833	0.33
510.0350342	0.11
522.2112427	0.25
524.0341797	0.70
536.9554443	0.22
537.9846802	0.14
540.1614990	0.15
545.3772583	0.10
546.2139282	0.21
547.0477295	0.05
548.1754761	0.39
565.3162231	0.46
566.1798096	0.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	388.1593
Annotation	6-(2Methoxybenzylamino)purine-9-beta-D-ribofuranoside
Peak:m/z	Relative Intensity
122.8782196	0.03
126.7930298	0.08
133.0758209	0.04
144.2428284	0.06
155.1314087	0.08
161.0593567	0.07
162.0299683	0.24
163.2372131	0.04
180.0051575	2.37
191.0101318	16.89
203.1200562	0.08
205.2234955	0.06
209.0498352	100.00
209.6699829	0.11
225.8517761	22.31
230.9911499	0.09
241.1966553	0.10
281.8798523	0.03
285.1459351	0.26
286.1893921	0.03
287.1431580	0.05
296.4991150	0.09
298.3955383	0.20
309.2015381	0.03
311.5146484	0.04
313.2196960	0.29
316.2899780	0.06
321.4351501	0.20
322.3970337	0.04
325.7119446	0.10
328.2730713	0.03
329.1898804	0.17
331.1820679	0.06
334.6869507	0.10
339.7568054	0.05
341.6794739	0.10
344.0037231	0.03
347.1936646	0.63
348.2735596	0.04
350.4020996	0.02
352.2483215	0.98
353.0619812	4.49
356.2407227	0.16
359.1900330	0.19
365.2345276	0.05
366.6935120	0.12
368.1861267	0.15
369.3669739	1.52
370.4523010	8.62
371.3642578	0.83
372.9808044	0.03
378.1697083	0.20
379.0561523	0.45
388.6468811	0.24
396.4515076	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	649.1006
Annotation	Unknow
Peak:m/z	Relative Intensity
183.0258179	0.81
185.3814697	0.28
197.0046234	0.25
207.0071411	0.30
208.9276123	0.74
210.0642090	0.24
212.7924500	0.07
217.1039734	0.64
223.1304016	1.68
225.2138214	0.42
235.0154419	2.10
237.2056122	1.15
241.2084656	0.51
247.2019653	0.18
248.2454071	0.34
248.9958344	0.80
251.0386658	0.14
252.0556335	5.58
254.2583771	0.70
257.0227966	0.11
264.1300659	0.52
266.1889343	1.35
268.9911499	0.46
270.2368774	0.36
272.1187134	2.97
280.4540100	0.07
288.1834106	0.27
292.1238708	4.03
301.1184692	1.42
304.0423584	1.45
306.1883545	4.15
307.0879517	0.68
308.0978394	0.15
310.1686707	21.83
324.1234741	0.29
326.1866760	0.35
330.9996338	0.17
338.1289062	2.03
342.1087646	100.00
344.0792847	49.58
358.1286621	0.87
362.9963379	0.38
376.0587158	34.40
385.1192627	0.17
399.5546265	0.13
427.2109375	0.54
431.2835693	0.19
463.2600708	0.25
466.2241821	0.09
468.9957275	0.51
472.2789917	0.07
477.1574707	0.08
483.8144531	0.56
485.1940308	0.27
487.1704102	0.30
502.3055420	1.35
503.1549072	1.56
520.1346436	46.91
532.8613892	0.06
543.1281738	0.13
548.0702515	0.21
565.3048706	0.13
571.2868042	1.24
574.1525879	0.10
586.2008057	0.23
588.0354004	0.06
589.3253784	0.56
597.2185669	0.17
603.0470581	0.48
611.3265991	0.22
612.3614502	0.46
613.1230469	1.63
617.4573364	0.39
630.5953369	1.84
631.2283936	41.55
632.1571045	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	540.3312
Annotation	PS(19:0/0:0)
Peak:m/z	Relative Intensity
176.9020386	0.07
220.8746796	0.36
224.9948578	0.05
226.9699402	0.02
235.3206177	0.12
249.3800049	0.05
278.2528076	0.08
282.4284058	0.02
292.3365479	0.06
295.0420532	0.02
311.0972290	0.24
313.2924805	0.28
315.2673340	0.64
321.3566284	0.05
323.3503418	0.04
327.2714233	0.06
330.9594727	0.07
350.0702515	0.02
355.4362793	0.02
361.0585327	0.03
373.2655029	0.45
375.0560913	0.06
381.1107788	0.03
383.1423950	0.09
387.8995972	0.10
389.4536133	0.05
394.1340942	0.02
395.4655762	0.17
401.3079224	0.02
412.4529419	0.03
413.7733154	0.07
417.0794678	0.42
419.2349854	11.76
425.9954834	0.05
435.1336670	0.07
436.2615356	0.20
440.3970337	0.05
459.1678467	0.03
460.4274902	0.10
468.2574463	0.06
473.6233521	0.07
477.3589478	0.03
478.9896851	0.08
481.6185303	0.05
488.7729492	0.05
495.2001953	0.06
503.5829468	0.01
504.4611816	0.07
505.0687866	0.21
508.5334473	0.04
521.5937500	0.33
523.1889038	100.00
523.8346558	0.23
527.4988403	0.14
531.2930908	0.01
532.2390747	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	655.3539
Annotation	Unknow
Peak:m/z	Relative Intensity
251.0040588	0.07
253.0134735	1.03
266.2874451	0.27
271.4329224	0.53
273.3803101	0.31
277.4421082	0.14
303.5321045	0.11
306.5550537	0.09
309.2624207	0.04
311.2390747	0.18
313.1057434	0.05
318.8831787	0.20
331.1928101	0.16
349.3240356	0.05
350.7095337	0.17
351.9420776	0.05
357.1654053	0.57
359.1670532	0.08
361.2621460	0.13
367.3085327	0.13
381.0026855	0.13
385.2446899	0.15
397.1326294	0.07
404.9714966	0.65
413.3723145	0.24
415.2984619	0.32
417.0680542	0.18
431.1519775	1.50
433.3552856	57.28
434.0753784	0.36
447.3815918	0.09
449.3749390	0.20
457.4080811	0.99
475.3822632	2.23
479.2693481	0.20
481.8214111	0.06
485.4310303	0.34
492.3120117	0.10
493.4856567	5.78
499.5850220	0.51
503.0177612	0.48
513.5046387	0.17
522.0421753	0.51
523.8053589	0.37
529.5606079	0.11
541.4222412	0.24
544.9084473	0.14
546.8803101	0.28
547.7266846	0.39
559.3984985	0.87
563.1382446	0.12
567.4661255	0.31
569.3322754	4.06
573.4699097	0.69
575.4592896	0.61
576.3023071	0.29
577.4421997	4.07
581.1738892	0.20
593.4502563	1.21
594.7623901	2.80
595.3912354	27.59
596.0944824	0.15
609.2310791	0.62
610.4896851	0.25
611.4687500	1.57
619.4640503	5.30
625.4165649	0.57
627.5373535	0.31
637.4322510	100.00
638.3849487	1.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	304.99
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9106293	7.09
125.9069977	0.15
132.9629364	100.00
136.7531433	0.15
160.9391174	0.19
172.8941650	0.05
175.1721802	0.07
178.9105377	0.26
189.0059509	0.27
201.0508118	0.07
219.1933899	0.50
221.2977295	0.25
230.3117065	0.11
231.0390320	0.13
232.2299194	0.18
232.8762207	0.26
235.1420288	0.12
242.9260254	0.46
243.6204834	0.31
244.9758301	18.89
252.9983215	0.20
261.0209351	1.61
261.8183899	0.10
268.8787231	0.08
270.2396851	0.10
286.1688232	1.23
287.1175842	2.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	483.12
Annotation	Unknow
Peak:m/z	Relative Intensity
159.1591187	0.11
161.0977478	0.10
164.1960449	0.06
191.0297241	0.27
209.1508026	1.33
246.9252930	0.10
260.1065063	0.04
271.2904358	0.24
285.3435059	0.03
290.9529724	0.20
293.2262268	0.10
300.3402100	0.20
304.5523682	1.12
305.2172241	5.55
309.2251282	0.06
310.9859619	0.17
314.9414062	0.05
343.1974182	0.15
345.0932007	0.09
357.4183960	0.29
365.1689453	0.18
368.8222046	0.15
379.2240906	0.12
382.3134155	0.02
403.2046509	1.92
407.6323853	0.12
423.2224731	0.06
425.2076111	0.04
437.2111206	100.00
439.5072937	0.08
447.1173401	0.06
465.1786194	1.13
480.0669861	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1087
Annotation	Teuhircoside
Peak:m/z	Relative Intensity
101.0533447	0.06
113.0286560	0.25
113.8873215	0.06
118.9182892	0.32
122.0904770	0.11
124.8493195	0.18
134.8703918	0.38
137.0255127	2.01
140.1996918	0.15
143.1155548	0.33
158.9181213	0.06
160.9732971	1.08
162.9151917	0.07
164.1458435	0.19
166.1094208	0.39
176.9927979	0.05
179.0247650	0.22
180.9790497	91.80
190.8927002	0.20
193.1385498	0.14
195.1330566	0.16
207.0229492	15.54
207.9173279	0.14
209.1481781	0.73
223.3288574	0.21
226.0490417	0.03
226.8037720	0.57
233.9849548	0.13
248.2864990	0.09
249.2607117	0.06
253.1691895	0.07
271.0163269	0.28
273.2480774	0.44
275.1340027	0.18
279.3211975	0.09
282.7748108	0.05
290.9296265	0.05
316.8493347	0.16
341.1264648	0.24
342.9277039	100.00
343.5930786	0.40
344.2539062	0.10
345.2011719	0.86
346.3680115	0.05
350.2592468	0.10
350.9713745	0.09
353.1238098	0.05
356.2187195	0.08
356.9328613	0.20
361.2477112	0.05
370.2262268	0.10
370.9624634	0.13
371.6830444	0.47
374.1490784	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	303.2
Annotation	Prosolanapyrone II
Peak:m/z	Relative Intensity
104.9335556	0.03
106.0486603	0.16
109.0587921	0.04
121.2010956	0.04
136.0607300	0.03
136.8911591	0.09
139.0174561	0.04
147.1697235	0.08
149.1198120	0.36
149.9134216	0.09
151.2389374	0.08
161.0261078	0.04
164.0388184	2.49
164.9500122	0.31
172.9999084	0.06
176.0717926	0.02
176.8875427	0.03
185.0858459	0.04
186.1847534	0.04
188.0419617	0.21
189.2829590	0.05
190.1770172	0.08
195.1482086	0.05
203.1607056	0.54
204.1479492	0.38
205.1195984	0.44
209.2445679	0.01
211.0183411	0.04
213.8577881	0.12
215.4076843	0.07
217.1585388	0.19
219.1170044	100.00
220.2099915	0.23
221.4424133	0.10
223.5034790	0.03
225.2279053	0.02
227.2283936	0.17
229.2119141	0.03
230.2194519	0.07
239.2931519	0.09
239.9947815	0.08
245.1655579	5.43
247.0089722	2.60
248.2996826	0.02
249.4946289	0.06
252.4120178	0.06
256.9482422	0.22
258.0705566	0.04
259.2634888	0.22
259.9791870	0.04
261.1364136	0.15
265.1287842	0.07
267.1801453	0.44
268.1667786	0.09
269.3407593	0.05
271.1570435	0.21
273.4274597	0.04
274.2744751	0.04
275.2572021	0.10
283.2956543	0.09
285.2088318	56.12
285.8629761	0.11
287.2536621	1.33
288.2102051	0.08
296.9568787	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	568.3109
Annotation	Unknow
Peak:m/z	Relative Intensity
209.0310211	0.04
221.2457886	0.02
242.0238342	0.03
251.2515869	0.04
252.0654297	0.05
272.2721558	0.47
286.2164307	0.02
287.2943726	0.04
289.2650146	0.44
302.1166382	0.12
317.1710815	0.29
318.3372803	0.47
319.1507568	2.73
320.2119141	5.29
326.2744141	0.03
330.1368408	0.06
339.9488525	0.03
343.2493896	0.01
344.2855835	0.50
360.9924316	0.17
362.1980591	0.51
371.3057251	0.02
373.3192139	0.03
380.3535156	0.10
383.2583618	0.09
394.1176758	0.01
404.3366699	0.54
406.3983765	0.42
409.0527954	0.06
418.3887329	0.16
420.2728882	0.50
422.3215942	100.00
422.9367065	0.65
428.4392090	0.03
432.2379150	0.09
434.9538574	0.02
436.0835571	0.03
439.1064453	0.16
444.2060547	0.01
445.2012329	0.02
446.0845337	0.04
447.0546265	0.37
448.1705322	0.16
449.2973022	0.02
450.7176514	0.06
454.7468872	0.04
457.8573608	0.06
459.2859497	0.09
463.2896729	0.06
464.2734375	0.61
468.3975830	0.03
473.2838135	0.09
482.1876221	0.02
484.3298340	0.10
493.5961304	0.04
502.2345581	0.24
506.1079712	0.22
507.3425903	0.01
508.4832153	0.05
511.2666016	0.05
512.3209839	0.05
521.2598267	0.09
524.6303711	0.01
532.4481812	2.01
540.3099976	0.08
549.6383667	0.21
550.3549194	4.07
551.2974243	0.15
552.4700317	0.09
554.7276001	0.02
568.7276001	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	535.037
Annotation	UDP-D-Xylose
Peak:m/z	Relative Intensity
150.8986053	0.02
176.7618713	0.03
192.8856964	0.09
194.6575470	0.04
197.0430298	0.03
211.0620270	2.19
229.3175201	0.02
232.1702271	0.04
232.9705353	0.02
276.0366821	0.05
280.1600952	1.09
291.0347900	0.63
305.0435181	0.19
319.7710571	0.04
323.0441895	100.00
328.1826172	0.04
359.0776367	0.03
377.0875244	0.02
385.1796265	1.75
398.9385376	0.10
403.1298218	2.55
404.4666748	0.05
419.8192749	0.02
423.4676514	0.05
437.0234375	0.40
445.2567749	0.03
446.9921265	0.02
448.6445923	0.02
450.8976440	0.16
467.0419922	0.10
486.2351685	0.01
488.0913086	0.04
488.9633789	0.01
492.4171753	0.07
499.1176147	0.03
517.2465210	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.2673
Annotation	PA(19:1(9Z)/0:0)
Peak:m/z	Relative Intensity
152.9513855	0.04
165.1863556	0.07
167.1740723	0.05
182.7183228	0.14
183.8866272	0.06
185.0733337	1.23
210.7903595	0.06
220.0559540	0.03
221.0778809	0.09
231.3066101	0.05
243.2068481	0.05
251.2759399	0.15
274.9041138	0.06
281.3673706	100.00
287.1838989	0.10
291.2067871	0.25
293.2925415	0.03
300.1846924	0.17
300.9852295	0.04
305.1060791	0.15
307.2165527	0.06
313.0791321	0.09
343.4977417	0.08
349.5709229	0.11
359.1172485	0.12
373.2687683	0.24
390.5476074	0.36
391.4742126	0.80
400.6598816	0.07
402.8534851	0.16
403.5743713	0.03
405.2125549	0.53
405.8751526	0.11
407.0135498	0.43
412.5707092	0.17
413.3443909	0.27
421.1988525	0.13
422.3146362	0.09
427.1617737	0.41
429.1606750	0.29
431.3143921	1.22
433.3938904	0.13
440.8253479	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.1016
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
97.1892548	0.29
122.9544678	0.20
163.9274902	0.39
169.0373688	1.04
183.2165833	0.13
184.9327393	0.19
193.1412048	2.15
200.5189819	0.10
211.0428772	16.03
229.0540161	0.09
231.1154175	0.25
233.0489502	0.11
235.0848389	22.12
242.0113525	0.75
247.1274109	2.53
252.8031006	0.33
254.6746216	0.07
258.6012573	0.62
259.4776917	0.36
265.0568848	7.20
271.0071716	0.20
272.1596069	0.23
274.9681702	0.29
277.1359863	18.97
281.9877319	0.13
287.1242676	0.09
289.7097168	0.13
293.0536499	0.42
295.0038757	14.45
295.6099243	0.46
303.2325439	0.09
313.0479126	100.00
314.4921570	0.20
321.5921631	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	310.0916
Annotation	Inodxyl glucuronide
Peak:m/z	Relative Intensity
105.1199417	0.02
109.1571808	0.08
115.0615997	0.06
123.0922012	0.18
133.7601624	0.05
138.8865051	0.07
145.0453491	0.17
156.1036682	0.18
173.0809937	0.07
175.0487366	0.04
176.9776001	100.00
178.1204681	0.08
179.9102631	0.05
181.0528870	0.11
191.1320190	0.05
195.8537445	0.06
202.8061829	0.03
212.2074890	0.08
213.0617676	0.05
228.2280579	0.44
231.1414795	0.26
236.4657898	0.06
247.2953186	0.05
248.0077209	0.04
249.1715393	0.21
251.1167603	0.33
264.2674561	0.04
265.8967896	0.10
267.0531006	0.05
268.9991455	0.49
272.9457397	0.23
274.1386719	0.48
275.0549316	0.05
277.7739563	0.27
279.1995850	0.20
282.2886047	0.09
286.9707642	0.12
288.1067810	0.08
289.6130371	0.03
291.2257996	0.63
292.2291870	1.83
294.2220459	0.15
301.1642456	0.29
310.1944580	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	506.1912
Annotation	Unknow
Peak:m/z	Relative Intensity
227.1700745	0.11
228.3607788	0.04
230.2009888	0.13
237.9061890	0.12
251.0495453	0.23
252.2380676	0.36
254.1501465	1.53
255.0184326	0.03
256.8405151	0.08
269.2282715	0.87
279.9856873	0.09
287.8396606	0.19
298.1373901	1.34
311.1524658	0.07
313.3454590	0.14
315.2588501	100.00
316.3923340	0.15
333.1695862	0.09
336.2593079	0.14
342.6257324	0.07
343.2690125	0.75
344.4243164	0.18
358.2868652	0.14
359.3008423	0.02
371.1533508	1.54
373.1662598	0.31
383.8699951	0.22
392.4959412	0.07
404.2043152	0.19
405.1371155	0.06
408.2356873	0.15
414.1731873	0.14
416.2416687	0.10
421.3125000	0.22
423.2619324	0.23
431.3508301	0.09
432.5914001	0.03
434.3273010	0.14
442.2099915	0.09
443.2983704	0.84
444.1562805	0.02
445.5385437	0.19
460.2351379	10.61
461.2847900	35.42
462.3862610	0.38
469.9879456	0.20
471.0751343	0.23
478.2816772	67.34
484.4205933	0.34
486.6880188	0.05
488.1198120	8.66
489.2579956	74.49
497.4169617	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	319.0934
Annotation	Unknow
Peak:m/z	Relative Intensity
102.0667877	0.72
103.2228088	0.13
122.1274185	0.10
124.1657562	0.03
127.9882126	72.11
129.0789185	6.63
130.2497253	0.02
134.3151550	0.03
144.1437836	0.41
145.9926758	37.73
147.1131287	2.83
149.0066223	0.06
166.9530945	0.08
172.0031433	12.93
173.0729675	2.33
175.2294922	0.04
184.4212494	0.12
186.2438507	0.10
189.9842072	26.27
191.0521545	5.77
192.9212799	0.22
194.0996704	0.32
203.1489868	0.03
213.2134705	1.12
214.2021179	0.27
217.1402588	0.07
231.2087708	0.11
232.3697815	0.05
233.0796814	0.04
234.0289917	0.07
235.1206360	0.04
240.3263550	0.06
246.1972046	0.02
247.1812134	0.10
253.1721497	0.06
257.0787659	2.48
258.0727234	0.63
274.0444946	0.04
275.1837463	13.35
276.1782227	4.60
282.1074524	0.08
283.1759033	0.88
284.1203613	0.32
289.3314514	0.03
291.2961426	0.20
292.2670898	0.02
301.1349487	100.00
302.1062622	24.55
303.1862793	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.14
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
171.1537018	0.60
179.0351562	3.29
191.9792023	0.22
197.0483093	0.44
198.1955872	0.09
201.3215332	0.11
210.1925812	2.86
211.3218231	0.07
225.9716187	0.29
228.4284668	0.09
236.1968079	0.22
251.8704529	0.21
254.1570435	14.30
270.2922974	0.17
272.1757812	35.09
286.1805115	1.51
288.1837158	5.96
304.2059937	16.96
306.1274414	100.00
320.0995178	0.59
329.1458130	0.13
338.1140747	48.27
418.9564209	0.26
421.2846680	0.66
442.1126099	0.10
464.1159668	1.12
482.1550903	39.92
482.7581177	0.17
545.0562134	0.08
575.2279053	1.12
593.2333374	16.41
594.3471069	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.29
Annotation	Pseudomonic acid B
Peak:m/z	Relative Intensity
145.0117340	0.16
156.9518433	0.07
159.2704926	0.10
161.2631073	0.27
163.1270142	1.04
167.0665588	0.07
169.0401154	0.06
178.9580078	0.11
180.9677429	0.11
185.1890564	0.31
187.0281067	2.31
191.2523499	0.06
195.2887878	0.05
198.7847900	0.05
203.2402039	0.54
204.9633636	1.30
213.2341003	0.28
223.1446838	1.62
231.1274567	1.05
241.4275513	0.04
243.3480072	0.11
247.3795166	0.02
255.4901276	0.07
257.1542969	0.17
261.4075928	0.25
265.4748230	0.03
269.1364746	0.05
273.2491455	1.15
275.1369019	3.31
279.1953125	0.10
299.2893066	0.55
307.0855103	3.44
310.9521484	0.02
317.3949585	2.96
325.2730103	0.06
329.2605591	0.22
333.0866089	0.18
335.2769775	100.00
335.9260254	0.15
338.1148682	0.02
351.0853882	6.75
352.0554810	0.14
353.3972168	0.19
356.9271851	0.02
369.0922241	20.23
371.0776367	0.20
381.0333862	0.20
383.2855835	0.06
384.1977539	0.05
411.3018188	0.28
419.4476318	0.16
431.2703857	0.15
432.8090820	0.05
441.7543945	0.03
444.4041748	0.07
450.2863770	0.06
455.2962036	0.20
457.2723389	0.02
459.2371826	0.05
468.9329834	0.29
469.6216431	0.18
471.2141724	0.38
477.3473511	0.08
479.3085327	0.58
480.3557129	0.04
485.5344849	0.19
488.0727539	0.07
495.7918091	0.10
497.2249146	1.50
497.9140015	0.09
516.0877075	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.1194
Annotation	Herbacetin 8,4'-dixyloside
Peak:m/z	Relative Intensity
161.0217285	0.03
163.1633148	0.10
164.1070251	0.03
169.2286377	0.04
173.7531128	0.04
175.0513000	0.12
178.9688568	3.47
180.0535278	0.13
183.2160950	0.05
189.1813354	0.05
190.9828796	0.09
193.0357971	0.02
199.2498474	0.06
203.1878052	0.05
207.1083984	0.08
212.1736145	0.06
217.0775452	0.23
218.2518921	0.02
224.2287598	0.05
226.3709869	0.22
227.2685699	0.08
228.4164124	0.03
229.2254333	0.23
230.2904968	0.05
231.1289673	0.11
236.0753784	0.09
239.2555389	0.25
241.0273590	0.03
242.1655884	0.09
243.2444305	0.21
245.1260376	0.33
247.2178192	0.07
251.0860291	0.10
254.0061340	0.57
255.1338196	3.05
256.1212463	0.35
257.1293335	0.17
257.9077759	0.16
259.2585144	0.05
260.1805420	0.18
265.4107666	0.08
266.9688110	0.03
271.0854797	6.61
272.1408691	1.27
273.2386475	0.78
274.3032837	0.19
280.2207642	0.13
281.2961731	0.07
283.2123413	0.34
287.1774292	0.14
289.0607300	0.78
290.0927429	0.03
297.2154541	0.11
300.0821533	100.00
301.0813599	39.09
302.1125793	3.51
303.1754761	0.04
307.1235962	0.06
308.4551697	0.04
311.2328491	0.41
313.0413208	0.10
314.2459412	0.06
323.3247681	0.05
325.2029419	1.81
326.2950439	0.14
327.1394653	0.30
327.8830566	0.07
329.1025391	0.12
330.2538452	0.02
335.2454834	0.07
337.1426392	0.30
341.1906738	0.12
343.1779785	2.15
344.3077393	0.16
350.4023438	0.04
351.1166382	0.07
353.2407227	0.11
354.0630493	0.12
355.1254883	1.84
356.1464844	0.19
361.5000000	0.02
365.3165283	0.04
367.2947388	0.25
368.1128540	0.10
369.2368774	0.20
370.2221069	0.09
371.2075195	0.50
372.6356812	0.34
373.2373657	0.34
374.2676392	0.13
379.3925171	0.10
380.2788696	0.08
387.1069336	0.30
388.2249756	0.09
397.1666260	1.83
398.2405396	0.36
401.5454102	0.08
403.1001587	0.05
404.3797607	0.06
407.2862549	0.09
415.2117310	12.11
416.2522583	2.15
417.1331177	0.10
422.3464966	0.02
427.9722900	0.02
429.3253174	0.24
430.2547607	0.11
431.2072754	0.31
433.1884766	7.78
434.1478271	0.95
435.3809204	0.16
440.4575195	0.14
455.2021484	0.32
456.3342285	0.15
475.2866821	5.62
476.3335571	1.16
487.4794312	0.07
501.0264282	0.04
506.2514038	0.06
521.2809448	0.46
522.4107056	0.13
523.0670776	0.04
524.8062134	0.10
534.4000244	0.02
547.2135620	1.78
548.2156372	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1089
Annotation	Lactulose
Peak:m/z	Relative Intensity
96.7206650	0.31
100.9868317	6.34
106.4643707	0.81
113.0362854	16.21
113.8763657	0.59
114.9248123	0.46
118.0192108	0.08
118.9590149	15.22
125.0251617	1.75
130.9579468	8.19
142.9894409	18.64
148.9735718	3.52
158.8823395	0.56
160.9335938	22.29
161.6009216	0.12
178.9152374	100.00
179.5460510	0.69
191.3008118	0.45
220.1454468	0.25
221.0771790	0.18
262.7182007	0.58
280.9495239	2.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	605.02
Annotation	Gallagic acid
Peak:m/z	Relative Intensity
175.1774292	0.81
217.0155029	0.17
219.0185547	0.12
280.8771667	0.56
311.3818970	0.08
313.3109741	0.10
330.9165649	0.13
333.1581421	0.09
345.1295776	0.25
348.9183960	0.17
349.5603638	0.13
361.0413818	0.07
363.1109619	0.86
377.2189331	0.71
379.0450439	2.23
387.0518188	0.12
391.7186279	0.29
393.2985840	0.11
394.8103027	0.17
428.2105713	0.07
428.8161011	0.14
430.7947998	1.37
436.7998047	0.03
439.1166992	0.03
443.0186157	100.00
447.2388306	0.18
448.7048950	0.16
449.8275757	0.84
457.1323853	0.10
458.1209106	0.35
459.1593628	0.15
460.5189209	0.24
461.3905029	0.30
462.8833618	0.09
463.9787598	0.05
468.4327393	0.14
469.0830688	1.04
475.0012817	2.79
481.0196533	0.09
491.1157837	0.10
492.2369385	0.06
493.1636353	0.57
504.1072388	0.03
507.2149048	6.85
523.2834473	0.13
525.2084351	0.24
543.6252441	0.17
545.0339966	0.35
545.7334595	0.04
558.8001709	0.73
559.4428101	0.23
562.0543213	0.35
569.0822144	0.04
573.9263916	0.11
587.2001953	0.56
603.7446899	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	608.12
Annotation	Unknow
Peak:m/z	Relative Intensity
173.0016479	0.27
175.1816406	0.09
177.0962219	1.54
177.8513031	0.60
187.0459290	0.29
192.9150696	0.04
201.0180969	0.66
206.9679718	0.09
211.5285645	0.11
215.0149994	0.44
216.9249573	0.31
219.1475677	0.55
220.2644653	0.11
221.0339355	0.18
227.3146667	0.46
229.3396301	0.11
243.1624451	2.23
251.0614929	0.14
255.1796875	0.21
256.0145874	0.20
257.3531799	0.14
259.0153198	0.15
261.1064453	3.92
262.1203918	0.42
263.3889160	0.38
273.1154480	0.67
274.1940918	0.52
275.0961914	0.24
283.1840515	0.11
284.1550903	0.06
285.1741333	1.00
287.3013306	0.36
289.4387817	0.11
299.3402100	0.12
301.1842041	3.91
302.5792236	2.80
303.2070312	8.61
304.4216919	2.56
305.1034851	15.95
306.3018799	0.08
307.4321899	0.08
310.4945679	0.62
315.0010986	0.20
316.4173584	0.23
317.8043213	0.12
327.2637939	0.85
331.2390137	0.23
335.1539307	0.23
338.2837524	0.27
340.0998535	0.09
343.1854248	0.59
344.1942139	1.23
345.2542725	0.74
347.1455688	0.79
357.1523438	0.18
377.2335815	0.21
378.9940796	0.12
383.2904663	0.87
385.3008423	0.33
387.3112183	0.18
392.4287720	0.35
395.2343140	0.13
396.2872925	0.35
397.2849731	0.38
398.2615356	0.05
400.1152344	0.46
403.2585449	0.21
405.3348999	0.06
408.2474365	0.52
409.3055420	0.13
411.2937012	1.61
413.2026367	0.14
417.3814087	0.31
418.0595093	0.55
421.1386108	2.92
422.3196411	9.23
423.1586304	12.03
424.3483887	0.56
427.1700439	1.79
429.0726929	5.23
430.2492676	2.09
431.2496948	6.21
435.2239990	0.49
438.0706177	0.09
439.1594849	11.52
440.0985107	12.20
441.0563354	3.42
443.0938110	0.43
445.5728760	0.65
447.4721680	0.14
449.3347778	0.19
451.3961792	1.40
452.2612305	4.97
453.1461792	0.61
453.8897095	0.34
456.0279541	0.20
456.8247070	0.33
460.1437988	0.47
461.3164673	1.32
463.2946167	1.20
464.2742310	0.96
465.2243042	0.66
466.9127197	0.22
468.0908203	1.38
469.1387939	5.36
470.2478638	0.19
471.2445068	0.90
475.3248291	0.59
476.1811523	0.78
479.2719116	0.07
481.1995239	10.59
482.2073975	2.26
483.1931763	4.27
484.1059570	0.43
492.2170410	0.07
493.2780762	0.77
497.0693359	1.19
502.0115356	2.34
503.2681885	0.17
505.5979004	1.29
506.2846069	3.83
507.2733765	0.44
508.9602051	0.13
511.1179810	0.39
515.1422729	100.00
515.8683472	5.49
516.7960205	1.05
518.5214233	0.31
520.4973145	0.42
521.1373901	0.09
521.7855835	0.12
523.9984131	60.45
525.0037842	2.40
525.6069946	0.09
527.2925415	0.18
528.0324097	0.07
530.1434937	0.19
532.1367798	0.33
535.2545776	0.12
536.3925781	0.85
537.8688354	0.98
538.7328491	0.14
541.0512695	0.71
544.3106689	0.86
545.2117310	8.51
547.0464478	1.61
548.3599243	0.10
554.5089722	0.17
557.5394897	0.17
559.2007446	0.60
562.1334839	0.94
563.2520142	1.03
564.1876831	0.84
565.3458862	0.95
566.2888184	0.10
567.2277222	0.12
571.1280518	2.14
572.1651001	0.13
575.5413208	0.43
576.6113892	0.24
577.5151978	0.70
579.2755127	0.58
585.2365723	0.50
586.6465454	1.35
587.5003052	0.31
589.2631226	2.69
590.1657104	4.46
591.2641602	5.06
592.3369141	0.40
599.2174683	3.14
599.9690552	0.43
601.4484253	0.26
619.2344971	0.34
648.1347046	0.19
651.1069946	1.05
652.2794189	0.45
659.5160522	0.20
661.5599365	1.40
662.3296509	0.39
665.2797241	0.14
682.9124146	0.11
689.0833740	0.23
707.2384644	0.59
709.2669067	0.11
713.2661133	0.23
715.3208618	0.56
719.0614624	0.76
725.4907837	1.03
727.1715698	6.47
728.2992554	0.17
729.5395508	0.19
731.0591431	0.45
731.9193726	0.77
733.1862793	1.28
734.0553589	0.43
737.4694214	0.16
743.0588989	0.68
744.4207153	0.31
745.4213257	2.49
746.1184692	0.47
766.2032471	0.07
767.8457031	0.06
769.1116943	1.47
775.1642456	0.09
776.2238159	0.59
785.1901245	0.37
786.4777222	2.05
787.2820435	5.73
788.2100830	1.26
789.2949219	0.06
836.7083130	0.18
837.5089722	0.15
845.1513672	0.31
851.1181641	0.17
863.1699829	2.68
868.2573242	0.07
869.2262573	1.14
869.8497925	0.29
877.2764282	0.18
879.1040649	0.52
881.1887817	1.91
885.7980347	0.13
887.3168945	0.16
887.9761353	0.16
893.3674316	0.29
894.9755859	1.82
903.3038940	0.49
904.5140991	1.67
905.2332153	7.61
906.1281738	0.31
909.2870483	0.12
911.1288452	16.46
912.2597656	2.77
913.2197266	11.36
914.3584595	1.25
920.8067017	0.15
923.2272949	2.49
925.9319458	0.20
939.2749023	0.05
951.9475098	0.78
953.3672485	0.78
955.2395630	0.74
963.6139526	0.14
965.2365723	1.06
1013.1786500	0.14
1029.2009280	0.28
1031.1718750	2.39
1032.5277100	0.09
1047.1129150	0.87
1048.2279050	0.69
1049.0711670	2.81
1049.7880860	0.08
1055.2897950	0.38
1073.2650150	0.94
1074.0285640	0.20
1089.1674800	0.32
1090.5020750	0.57
1091.1364750	10.51
1091.8688960	0.68
1092.4848630	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	439.2768
Annotation	Unknow
Peak:m/z	Relative Intensity
138.9892273	0.08
145.0883179	0.09
165.0507507	0.26
189.0566559	0.13
191.2239990	0.26
207.8743591	0.02
209.0680847	0.12
221.3930511	0.10
223.4594116	0.08
229.7804260	0.47
235.3019714	0.03
237.2154541	0.06
243.0535583	0.09
243.8495178	0.26
249.4736633	0.12
251.5814514	0.39
252.1943970	0.12
252.9579163	0.17
254.0554504	0.27
262.0648193	0.04
264.1359558	0.10
265.3268127	0.07
267.7351379	0.47
269.7173462	0.02
270.8732605	0.14
273.7615662	0.44
275.4571838	0.08
287.3029480	0.37
289.7315674	0.30
295.4630737	0.62
296.5191956	0.05
297.2369995	0.05
298.0166016	0.11
301.4418945	0.07
307.3948975	0.08
308.8817139	0.06
311.5972900	0.63
312.2227783	0.03
314.1123352	0.02
314.9747620	0.13
318.0109253	0.30
319.1394043	0.13
325.3789062	0.10
331.8586731	0.02
333.5401917	0.13
334.1659546	0.44
339.9686890	0.28
340.9066772	0.12
356.0239868	0.50
357.3952026	0.04
359.6878052	0.23
363.0420837	0.02
365.2904663	0.13
367.3885498	0.08
376.0360107	0.03
377.5148010	0.49
378.1207581	0.16
379.3544006	0.02
381.3291931	0.11
383.2776794	0.27
385.4012756	0.05
386.5112000	0.23
387.3485718	0.30
390.0667419	0.14
393.4210815	0.07
394.3128967	0.32
395.6177979	0.32
396.2751770	0.06
399.7336731	0.17
401.9550476	0.06
404.4519958	0.04
408.6471252	0.10
409.2555237	0.09
416.3773193	0.04
417.3998108	0.03
419.3579407	0.04
421.4072571	0.42
422.2235413	0.80
430.8794861	100.00
432.0242004	2.37
433.6347046	0.72
434.5104675	0.07
472.8771667	0.04
503.1784058	0.12
520.4640503	0.65
521.4447632	0.14
547.5192261	0.08
550.4304199	0.07
564.4380493	0.14
579.3152466	0.18
591.5858154	0.03
593.1742554	0.07
597.6412354	0.07
608.2412720	0.14
609.5761719	0.26
624.2650757	0.04
640.3579102	0.22
641.4434814	0.35
652.4398804	0.14
653.4027100	0.05
667.3606567	0.04
679.2887573	0.06
684.6508179	0.20
685.5571289	0.06
695.3224487	0.06
696.5155029	0.03
697.4776611	0.05
712.0934448	0.03
729.4956665	0.13
740.1961670	0.03
860.5033569	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	807.3401
Annotation	Unknow
Peak:m/z	Relative Intensity
246.0750427	0.03
250.3761597	0.08
253.2135162	0.02
271.4748230	0.02
283.2085266	0.09
284.3831177	0.01
287.5417480	0.03
289.0311890	0.11
292.2835388	0.01
293.0332031	0.04
297.2232666	0.10
299.1174011	0.07
310.3861389	0.02
311.2854004	0.03
325.1082153	0.09
327.0957031	0.02
337.3864136	0.06
341.2582703	0.06
343.1500244	0.03
357.3864746	0.06
367.1880493	0.10
369.2761841	0.01
373.2120972	0.09
399.0545654	0.32
416.6582642	0.02
423.3640137	0.01
425.5258179	0.04
430.4044800	0.10
433.3708496	0.03
442.3026123	0.03
448.3255615	0.46
449.3135376	0.04
450.3311768	0.22
450.9346313	0.02
460.3798218	0.42
461.4409790	0.22
462.4028320	0.02
474.3144531	0.06
476.4588623	0.13
477.3594360	0.06
478.4445190	0.09
480.3074341	0.20
487.1240845	0.15
488.1060791	0.02
490.2156982	1.00
491.1807251	0.05
492.3376465	0.54
494.3215332	0.02
502.4595337	0.01
504.8509521	0.10
505.5378418	0.10
506.6317139	0.04
510.3023071	0.03
519.1882324	0.08
520.4613647	0.04
521.6051025	0.13
522.3752441	0.98
523.3314819	0.12
524.2200928	0.04
568.9902954	0.01
571.2077026	0.03
584.1173706	0.03
585.2426758	0.08
592.4360962	0.03
595.2971802	0.49
597.0494995	0.02
601.2881470	0.04
603.2095337	0.04
608.2676392	0.12
610.1895142	0.05
611.1514282	0.01
613.2808228	22.97
614.0336914	0.07
616.3933105	0.10
627.3279419	0.05
634.4348755	0.09
638.2894897	0.02
645.2418213	17.24
645.9279785	0.09
652.3013306	2.61
653.4443970	0.05
654.3530884	0.21
668.1804199	0.01
684.2254028	5.06
685.3445435	0.30
686.4511719	0.02
694.4982300	0.03
704.4176636	0.02
717.5003052	0.02
721.2495117	0.09
731.2647095	0.48
738.0877686	0.02
739.2733154	0.36
747.5496216	0.06
756.3510132	0.10
757.4510498	1.41
760.5773926	0.02
761.4720459	0.03
763.1197510	0.03
770.1493530	0.01
771.3449707	0.02
775.3137817	100.00
776.0116577	0.22
779.4904175	0.06
788.8519897	0.12
789.5819702	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	996.6008
Annotation	Unknow
Peak:m/z	Relative Intensity
277.9942322	0.25
291.0172119	0.08
293.2343750	0.22
295.3059692	0.42
309.0935364	2.92
311.4269409	0.49
312.7945862	0.93
314.9836731	0.38
325.3431091	0.17
327.1800842	1.75
329.3224792	12.16
339.3118896	0.30
340.9637451	0.14
343.2504272	0.06
350.5712585	0.25
353.1321411	2.99
355.3516235	0.73
357.3566589	0.43
359.3720093	0.10
371.2763977	1.22
373.3751221	2.51
375.2884827	0.63
384.3772583	0.17
397.1640015	1.31
400.6132812	0.25
401.2467041	0.95
413.5606384	0.14
415.2350159	1.77
417.2758789	1.36
419.3732910	1.63
425.5485229	0.07
427.1383667	0.10
431.2453003	0.43
433.2842102	1.53
441.2676392	1.14
442.7400513	0.66
443.3546143	0.14
445.4152527	0.30
459.0685120	0.15
461.1201172	1.07
463.3855591	0.77
477.3229370	12.23
479.2770691	0.44
485.0260925	2.76
486.9496460	0.18
503.2645264	0.73
504.6929932	0.07
505.4324951	0.44
507.2853394	1.29
508.0308533	0.14
521.0472412	4.05
523.2177734	2.35
529.2030029	0.60
531.0885010	0.23
533.3607788	0.11
535.0599365	0.41
547.5622559	0.13
549.3524170	1.01
551.3193359	1.64
565.0878296	0.91
567.3903809	0.70
573.2281494	0.38
577.3943481	0.29
591.5792236	0.21
593.4285889	1.00
595.2557373	0.48
596.0690918	0.09
607.2119141	0.08
608.9462891	1.07
611.1445312	0.82
621.4214478	0.41
627.5582275	0.43
637.0136108	0.14
639.4320068	0.75
652.5499878	0.95
653.5015869	1.01
655.2825317	1.65
671.0935669	0.18
680.7056885	0.20
681.3825073	0.19
683.2648926	1.12
696.1363525	0.25
697.1871948	2.48
699.1770020	0.99
715.4419556	0.82
725.0512085	0.53
727.2827148	0.09
741.4817505	0.58
742.5740356	0.62
743.4082031	1.07
758.7026367	0.14
759.5333252	1.06
767.8731079	0.17
769.0203857	0.50
771.3298340	4.20
785.3940430	1.07
787.4106445	1.14
803.0650635	1.25
813.1174316	0.24
829.4654541	0.63
831.4339600	4.41
847.3317871	1.87
857.0093994	0.20
873.0483398	0.37
873.6662598	0.23
875.3316650	39.97
891.5529785	2.10
935.4438477	3.17
960.9067383	0.61
978.8178711	8.07
979.4868164	100.00
996.0590820	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	436.0706
Annotation	Unknow
Peak:m/z	Relative Intensity
125.0468521	1.23
178.1565094	0.15
178.9605103	0.23
196.2182922	0.06
202.8860016	0.03
204.0447845	0.17
207.9050751	0.49
208.9410706	0.10
216.3277893	0.04
217.1069183	0.34
221.2292633	0.33
223.0842590	7.85
223.9548645	0.08
227.1116028	0.14
232.1829681	4.58
237.1663361	0.09
243.0887756	0.10
245.0747986	0.82
245.9530640	0.33
248.0729980	0.21
256.3575134	0.14
261.0635376	0.04
263.1415710	1.05
265.1122742	0.39
267.7301025	0.03
272.1547241	0.30
273.3084717	0.10
274.8928528	0.13
277.1236267	0.13
287.1344299	0.96
288.3761292	0.17
289.9643860	0.22
297.1794434	3.96
305.1339111	12.82
310.1062012	1.97
312.0513306	0.08
313.2044983	0.46
314.0300598	0.10
315.1995239	1.56
316.0786743	0.70
321.2190247	2.11
323.3861084	0.11
331.1506348	100.00
333.2926941	0.05
334.1966858	0.06
336.7463379	0.09
341.2366638	0.02
343.3666687	0.06
346.1328735	0.22
349.0935974	57.25
350.0555725	0.58
352.1825867	0.58
356.2752075	0.32
356.9916992	0.05
364.0673523	0.05
373.5870667	0.29
374.2281799	0.71
377.2100525	0.12
389.2580566	0.27
391.3454590	0.15
392.1319275	3.59
397.4561462	0.04
399.4896545	0.11
403.1044006	1.38
406.4619141	0.13
408.1787415	2.13
418.1174011	94.97
419.3016052	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	639.1562
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
179.1327362	0.07
190.8606110	0.02
193.0472107	0.05
194.0481110	0.05
195.0527954	0.09
199.0158386	0.06
201.9054260	0.03
206.1751251	0.02
206.9837341	0.03
209.1653137	0.39
210.0258026	0.05
211.0093689	0.04
213.0524902	0.05
215.1767426	0.36
217.2477417	0.07
225.1897583	0.05
227.0370941	0.27
228.0350189	0.22
231.0497131	0.30
233.0280457	0.12
236.1492767	0.06
238.1827087	0.07
239.1340179	0.16
242.1803131	0.53
243.2312927	0.21
244.0881653	0.43
245.2040558	0.26
247.0154114	0.03
249.2418213	0.18
251.1297607	0.08
253.0842133	0.07
254.8066864	0.07
256.1665955	0.19
256.9327393	0.25
258.2186890	0.89
259.1349487	0.29
260.3856812	0.04
266.1692810	0.17
267.2653198	0.08
268.8580933	0.15
270.2030640	0.02
271.1315918	0.47
272.0818481	0.11
273.0888977	0.17
276.3586426	0.12
277.1448669	0.02
281.1444092	0.08
282.3028870	0.29
283.2877197	0.04
284.0922852	0.05
285.3684692	0.60
286.3457642	1.97
287.1011353	11.01
288.1864319	2.39
289.4469604	0.06
293.1976318	0.13
295.2359619	0.19
297.1968994	0.16
298.0394287	0.22
299.2516174	0.12
300.1613770	0.77
301.1566162	1.84
302.1482544	0.27
305.1395264	0.07
309.1524963	1.16
310.0825806	0.12
311.2172852	0.32
312.2867432	0.47
313.5225220	0.83
314.1970215	2.16
315.1163330	17.49
316.2009277	3.66
317.2700195	0.21
318.0495605	0.08
319.6579895	0.17
320.2632446	0.02
322.0469360	0.16
323.3126221	0.17
324.1534424	0.31
325.0419006	0.22
326.1268005	0.69
327.9298096	0.48
329.1443176	19.19
330.1358643	59.35
331.1208191	11.89
334.7170410	0.07
336.1415405	0.08
337.2984009	0.25
338.2979126	0.66
339.0076904	0.35
340.3324585	0.12
341.2053833	0.35
344.2453003	15.47
345.1512451	100.00
346.1743164	17.07
347.0582275	0.08
348.0065308	0.05
351.3121948	0.09
352.4290161	0.06
353.1543579	0.08
354.2347412	0.75
355.1376953	0.43
356.0949097	0.08
357.1525269	0.20
358.2035522	0.25
359.2028198	0.12
361.2888794	0.23
364.2291260	0.04
365.3545532	0.10
367.2083740	0.44
368.2368774	0.11
369.2548218	0.74
370.1168213	0.23
371.2150269	0.08
372.2826538	0.17
373.3997803	0.10
374.9898682	0.18
379.1224365	0.05
380.1646729	0.10
381.9796753	0.20
384.2421875	0.15
386.2518311	0.27
387.2467651	1.17
388.2007446	0.25
389.2672729	0.03
392.1899414	0.20
393.1829834	0.02
394.3807983	0.03
396.3702393	0.11
397.2343750	0.19
398.1322632	0.05
399.2387695	0.58
400.2723389	0.04
402.2382812	0.04
409.3989868	0.07
411.1087036	0.49
412.1618042	0.10
415.2529297	0.05
417.2846069	1.29
418.3357544	0.30
421.1241455	0.37
423.2881470	0.07
427.4188843	0.06
429.2645874	0.10
430.2036133	0.13
431.2020874	0.23
433.4020386	0.06
435.2742310	0.05
441.1582031	0.11
443.3078613	0.06
447.3259888	0.10
449.2462158	0.09
451.3412476	0.13
457.1160278	0.08
457.9329224	0.42
459.2781982	0.54
460.1799316	0.12
461.8739014	0.14
463.2387085	0.16
464.3224487	0.35
469.0365601	0.05
471.0027466	0.12
473.1267090	0.17
474.2097168	0.61
475.2498779	0.38
476.2595825	0.52
477.4090576	0.31
478.4970703	0.12
479.3611450	0.20
480.0104370	0.09
489.1689453	4.55
490.1970215	1.71
491.2812500	0.29
492.3378906	0.30
493.3126221	0.49
494.1759644	0.03
495.0491333	0.05
496.0332031	0.03
501.0657959	0.05
504.2217407	0.18
507.2366333	2.14
508.3170776	0.74
509.3172607	0.04
519.3702393	0.28
520.0225830	0.03
521.4780884	0.05
522.3247070	0.06
525.2268066	0.05
532.2640381	0.13
537.2531128	0.04
538.3664551	0.14
543.4094849	0.11
544.1667480	0.10
549.1213379	0.20
550.2262573	0.15
561.0493164	0.09
565.7219849	0.04
571.5357056	0.18
575.3828735	0.05
576.2907715	0.02
579.5054321	0.63
580.4716187	0.24
581.2144165	0.13
581.8686523	0.14
591.4785767	0.04
593.4465942	0.19
594.7503052	0.02
596.0455933	0.45
597.4604492	0.20
603.5277710	0.08
604.4158325	0.11
607.1928711	0.07
608.2553101	0.81
609.2426147	0.20
611.2460327	1.49
612.1771851	0.24
621.3798218	2.11
622.4315796	0.98
624.1893311	11.57
625.2033691	4.31
625.9574585	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.2028
Annotation	Staphylionoside C
Peak:m/z	Relative Intensity
143.1076355	0.07
156.9445496	0.08
164.9511719	0.13
178.9619446	0.07
233.2452850	0.09
243.1392212	0.08
244.2988586	0.17
247.0957947	0.13
252.9364929	0.21
257.1526489	0.17
259.2284546	0.19
269.1391602	0.13
287.1975403	1.52
302.0279236	0.21
308.9129028	0.46
311.3213501	0.26
314.9923096	0.12
317.3533936	0.10
319.2463379	0.09
324.4344177	0.65
329.2079468	0.15
333.1289368	0.18
334.0324707	0.17
345.3677979	0.29
347.0751953	0.11
359.5263062	0.08
361.2884827	0.16
364.1377869	0.11
365.1965332	0.15
373.1103516	0.33
375.1676636	0.19
377.6817932	0.13
379.2451477	0.29
381.2784729	0.45
385.3299255	8.38
403.2780457	100.00
405.3059387	1.60
407.1511841	0.25
411.1997986	0.22
413.1657410	0.18
419.5227966	0.08
421.3031921	0.15
427.1481018	0.11
429.3582458	0.19
430.5897522	0.24
431.3820496	0.26
440.3819580	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1245
Annotation	Theviridoside
Peak:m/z	Relative Intensity
124.9092865	0.06
130.7261963	0.05
139.3223267	0.05
142.9121094	0.05
149.2028503	0.10
150.1824493	0.07
161.4635925	0.03
165.9144592	0.09
167.0787201	1.36
178.8228607	0.05
182.0776062	1.39
197.0723877	0.56
207.3969116	0.02
208.2546997	0.03
223.0350800	0.39
226.0601349	13.65
233.0983276	0.07
241.0974426	100.00
242.2986450	0.06
264.8331299	0.02
274.3136292	0.02
275.4633789	0.05
283.2238770	0.09
293.1029358	1.16
305.2291260	0.16
326.2749023	0.03
326.9855042	0.03
333.2370911	0.07
357.0869751	0.07
358.2791443	0.11
359.3163757	0.18
371.1641541	0.06
375.2776184	0.04
385.1758118	0.20
388.1367188	5.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.1401
Annotation	Unknow
Peak:m/z	Relative Intensity
135.9210815	0.10
144.8811646	0.90
162.7701111	1.12
181.1346893	0.09
185.0578308	0.03
197.1543579	0.04
225.2422028	0.08
229.1599579	0.04
231.2734528	0.09
243.7706909	0.05
246.5914307	0.14
247.1923218	0.02
250.9458923	0.04
253.1002197	0.09
258.5664673	1.00
259.2072144	0.13
259.9752502	0.02
269.8273010	0.56
270.9147949	0.72
276.8579712	1.02
288.2584839	0.38
288.9280396	2.47
297.2142944	0.17
298.1144714	0.29
298.7890930	0.59
307.1181030	40.86
307.8215942	0.09
308.4589844	0.07
309.7426147	0.06
314.6513977	0.06
315.8903198	0.19
317.2424316	0.12
323.3775024	0.48
324.8725586	10.20
326.7566833	0.06
332.1784058	2.10
332.7894897	0.02
333.4017334	0.23
342.2489624	0.60
342.9465332	3.08
346.3472290	0.10
349.0888672	0.08
355.2424011	0.35
379.5768433	0.09
385.1942444	0.06
388.1554565	0.05
396.8175354	0.05
398.3744202	0.04
409.1574097	0.10
414.9214783	0.13
419.2396240	0.08
434.0393372	0.05
437.2394104	0.25
442.2472534	0.16
447.2959595	0.17
460.1511536	0.19
470.3114319	0.08
484.2579041	0.40
485.5509338	0.10
538.3701782	0.03
571.3694458	0.04
595.1552124	0.09
613.2175903	100.00
614.3488770	2.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.2182
Annotation	Excavatolide D
Peak:m/z	Relative Intensity
154.9239197	0.02
159.1739960	0.08
161.1064758	0.15
162.0403137	0.06
164.1574860	0.01
165.0139771	0.17
166.2033539	0.03
173.2155304	0.02
174.8787079	0.07
179.0338745	0.22
180.5306702	0.02
191.1260986	0.21
192.0141907	0.08
193.1550903	0.21
194.3551941	0.02
205.2368622	0.03
206.1663055	0.05
207.0998840	0.04
211.1264038	0.01
222.0785217	0.04
245.4216156	0.03
251.1398773	0.05
256.3096313	0.02
258.2887573	0.05
269.1662292	0.02
281.0174561	0.06
282.3314209	0.03
283.1962891	0.11
284.2174683	0.21
285.3041382	0.10
287.4718323	0.04
288.4036865	0.10
298.2772827	0.25
299.2073364	1.24
300.1439209	0.15
305.1456909	0.02
311.2695312	0.06
313.2451782	0.76
314.3742676	0.42
315.3286133	0.26
316.2319336	0.07
317.3160400	0.13
318.3333740	0.03
321.4432373	0.02
327.1060181	0.01
328.2019043	0.45
329.2867432	5.70
330.3246460	1.16
331.1643677	0.33
332.1215820	0.21
333.3248901	0.48
334.1669312	0.06
341.1564331	0.08
341.8635864	0.05
343.2929077	4.60
344.3253784	1.48
345.3482056	0.01
347.1793213	9.45
348.3185425	2.16
349.3287964	0.02
355.4637451	0.06
359.2369385	0.03
361.2666016	100.00
362.2503662	25.07
363.2207031	0.10
370.1474609	0.03
371.8648682	0.09
375.5104980	0.05
377.2612915	0.01
378.5164185	0.01
385.3132935	0.07
387.2305908	0.02
389.4513550	0.10
391.1609497	0.17
391.7730103	0.02
397.3026123	0.02
399.2599487	0.01
402.2014160	0.02
403.4402466	0.27
406.9020386	0.06
416.3743896	0.02
417.2048340	0.09
429.3848877	0.02
431.3239746	0.02
432.4156494	0.02
433.5215454	0.03
444.1483765	0.01
447.4723511	0.06
461.1997681	0.03
463.3128052	0.01
469.0600586	0.02
471.3622437	0.01
472.2705688	0.04
477.3754883	0.06
478.4274292	0.02
479.6716919	0.02
480.2835083	0.01
481.0935669	0.01
486.4295654	0.02
491.3606567	0.20
492.6652222	0.10
493.4242554	1.54
494.3115845	0.59
504.3595581	0.04
505.2534790	1.03
506.2826538	0.44
508.2748413	0.53
509.4694214	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	327.072
Annotation	Bergenin
Peak:m/z	Relative Intensity
110.8906174	17.07
113.2384720	0.14
121.0375977	1.90
128.9194183	67.69
147.2038574	0.11
161.0216522	6.22
187.0111237	11.06
189.1470795	1.34
191.2259064	0.10
194.1685486	0.12
204.9738159	100.00
205.6003265	0.36
209.0611572	0.19
241.8442688	0.07
248.0070190	0.29
249.2639771	0.49
251.2998657	0.31
267.3058777	0.43
281.4909058	0.13
283.4017944	0.50
289.1891479	0.19
290.8799744	0.33
295.1778564	0.09
309.1163330	9.51
312.1212769	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0197
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
84.9082031	0.28
86.9414062	1.06
101.0580597	0.16
110.9024658	100.00
129.0068359	2.01
130.8379822	0.76
147.0043793	0.03
154.9105988	0.40
172.9886475	19.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.151
Annotation	Unknow
Peak:m/z	Relative Intensity
148.9618378	1.66
160.9251862	0.26
181.0052795	1.87
191.0665131	1.29
217.0845490	0.24
218.8815002	0.10
220.4238892	0.85
221.0489197	2.00
223.2566681	0.28
231.5393677	0.26
232.8357086	4.04
235.0559387	0.21
238.8349762	0.07
240.8176270	0.29
245.1114197	0.14
246.9457397	0.42
251.0505981	0.68
252.9333954	1.84
264.6311951	0.19
265.2347107	0.16
271.0597534	0.21
275.1829224	13.36
279.3541260	0.69
293.0953979	68.53
297.1808777	0.45
305.7965088	0.12
308.9282227	0.31
312.8240967	8.92
313.4268188	0.10
316.2318726	0.57
329.1998291	0.70
335.3482666	0.21
339.3272095	0.31
341.0553589	2.05
353.2032471	0.06
354.9402466	0.34
357.2646484	0.70
359.1677856	14.20
369.1489258	0.47
371.3811035	0.08
375.3234253	0.23
383.5465698	0.21
384.7384033	4.18
388.3685303	0.41
389.5429688	0.24
391.2691650	0.15
399.3497925	0.08
402.9986572	2.99
413.5720825	0.40
414.9464722	2.46
427.3978882	0.09
428.7047729	0.17
432.2072754	0.17
438.9115601	0.63
445.1838379	0.80
456.4471436	0.84
457.1361694	2.61
461.4764404	0.09
474.8800049	100.00
475.5905151	0.37
476.4107666	0.13
485.0906982	0.33
491.2583618	0.65
502.4509888	1.33
503.3047485	1.05
507.0527954	0.18
512.3124390	0.08
513.2466431	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.2531
Annotation	Elymoclavine-O-beta-fructofuranosyl-(2->1)-O-beta-D-ructofuranoside
Peak:m/z	Relative Intensity
169.9684448	0.12
188.0305481	36.48
195.1127319	0.28
204.9859924	100.00
205.5972595	0.34
212.9070740	0.36
258.1556091	0.08
302.2490845	0.27
303.0368042	0.10
313.0837097	0.07
321.0618286	0.06
357.4179688	0.08
367.2033081	0.14
375.0421143	0.06
381.1599121	0.38
393.3972168	0.12
399.1276245	0.63
410.3762207	0.07
417.0147705	0.06
429.2001343	0.10
432.3267822	0.18
434.9931030	0.14
459.2659912	0.10
460.5585327	0.07
477.1252441	0.13
488.3743286	0.12
489.1390991	0.08
514.7168579	0.06
521.3146362	0.17
532.8844604	0.08
546.4505615	0.05
551.9756470	0.60
555.3281250	0.04
559.6074829	0.23
561.0228882	0.63
562.2200317	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	803.3088
Annotation	Kotschyin C
Peak:m/z	Relative Intensity
255.1386414	0.08
267.4039917	0.09
274.3417053	0.09
283.6040649	0.09
285.1629028	0.16
301.4493103	0.06
303.0660400	0.31
359.0556641	0.15
373.0918579	0.17
381.0408936	0.17
403.3234863	0.23
409.2841187	0.04
411.0932617	0.08
427.4284058	0.12
445.2033081	0.15
447.1102905	0.27
449.5148315	0.20
461.1754761	0.12
465.2422485	0.03
473.1782227	0.04
475.3851318	0.21
488.6868286	0.15
494.3694458	0.04
504.4603882	0.23
508.4035645	0.33
516.4826050	0.11
539.2056885	0.04
544.3068848	0.12
562.2517090	0.31
564.3259888	0.06
576.1737061	0.33
580.3192749	0.41
582.9023438	0.12
583.9760132	0.30
590.2788696	0.04
597.2286377	0.14
598.2181396	0.23
602.2700195	0.13
608.1188354	0.21
609.2611694	0.09
614.1718140	0.33
617.1047974	0.11
618.4984741	0.37
620.2350464	0.35
622.3681030	0.05
627.4442749	0.54
632.3316040	0.17
638.2113647	0.07
640.3848877	0.10
655.1176147	0.04
659.2500000	0.06
661.1728516	0.20
664.2554321	0.20
668.9584351	0.15
676.5119019	0.03
678.4466553	0.12
680.3735962	0.45
683.6331787	0.03
691.6058960	0.09
701.5814209	0.05
706.8630371	0.06
709.3976440	0.98
717.4586792	0.35
721.3972778	0.16
725.3177490	0.32
727.3343506	0.24
731.3909302	0.31
735.3494873	3.73
739.3008423	1.21
743.3512573	1.31
749.3083496	2.15
749.9269409	0.02
753.2111206	2.63
753.8752441	0.15
757.4376831	1.51
758.3299561	0.17
759.6279907	0.25
766.0103149	0.15
767.3485718	5.81
771.3158569	28.53
775.4334106	0.51
785.3656616	100.00
786.0960083	0.48
803.9192505	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.28
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
136.8918610	0.18
147.1880035	0.13
149.3508911	0.16
155.3907776	0.37
157.0228271	0.08
167.0153198	0.20
172.8988800	0.08
177.2704315	0.29
178.1752014	0.33
181.0214539	0.14
187.2074890	0.32
189.3747559	0.78
190.8388672	0.19
195.2068024	0.37
198.0898743	0.14
199.2187500	0.62
201.0687256	0.13
209.9477234	0.54
211.4427643	0.20
216.0929871	0.63
226.9691925	0.23
232.9750366	0.26
236.7556763	0.21
243.1490936	0.88
245.1284790	0.17
255.4040833	0.21
257.9735718	0.18
261.2846375	2.15
269.4057922	0.66
275.1780396	0.33
277.0702820	0.43
299.0383911	0.11
304.4990540	0.99
310.2171631	0.32
316.7824097	0.28
317.5235901	0.25
323.4091187	0.68
330.3373413	0.16
335.2601013	45.63
341.3248596	0.22
346.2404175	0.41
357.1510010	0.10
359.1582947	0.17
368.4480286	0.29
369.3178711	0.13
380.3111877	0.08
395.1893616	0.13
398.6269531	0.26
401.8480530	0.13
409.4396667	0.36
412.1520691	0.14
413.2593689	0.21
415.2336121	6.83
416.0054016	0.04
420.6224976	0.28
423.0320129	1.02
423.7552795	1.49
429.4464417	0.70
433.3330383	1.13
439.8695374	0.27
440.8384094	0.41
441.4871216	0.11
442.4606628	0.33
445.3888855	0.34
447.4112244	0.14
448.5287476	0.14
458.1756897	100.00
459.0203857	2.68
459.6827087	0.68
461.7732544	0.45
467.8856812	0.84
476.5113831	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.31
Annotation	Dendronobiloside A
Peak:m/z	Relative Intensity
173.2001495	0.15
175.2449493	0.06
179.0442505	0.37
190.9284973	0.53
211.0638123	0.16
223.2985229	0.06
235.6661682	0.08
259.2658081	0.13
267.2830811	0.09
305.9232178	0.09
329.3472290	0.05
331.2998047	0.13
337.3010254	0.04
339.3923340	0.13
356.2585449	0.56
357.1127319	0.15
358.9963989	0.03
367.4143677	0.30
371.1510620	0.24
381.2105713	0.06
382.2941895	0.41
383.2392578	0.27
385.1458130	0.35
395.1062012	0.57
399.0731201	0.58
399.9471436	0.25
401.1658325	0.40
414.1538086	0.86
415.2127686	0.79
423.6205444	0.21
426.8474731	0.07
430.0678711	0.25
430.8636475	0.12
441.3507690	0.04
443.1524658	0.06
446.2510376	0.11
465.4598999	0.22
477.4403076	0.26
483.3107910	0.19
489.3632202	0.30
499.3511353	1.28
504.7271118	0.33
505.3546753	0.29
506.4030151	0.14
517.2980957	100.00
518.0209351	0.32
519.1839600	7.77
526.4291382	0.23
527.4852905	0.17
541.1768799	0.26
542.6177368	0.44
543.7725220	0.17
544.8219604	0.34
545.4505005	0.42
546.6040039	0.31
549.2620239	0.24
562.7357788	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	306.0763
Annotation	Glutathione
Peak:m/z	Relative Intensity
87.1355820	0.05
88.2038498	0.07
99.0292587	0.26
108.7637482	0.05
115.8281631	0.37
120.2741165	0.02
126.0023499	0.08
127.3980865	0.91
128.0082245	8.91
130.1038208	0.32
135.1033173	0.07
143.0594940	9.16
145.1043243	0.07
146.0512390	1.05
153.1193848	0.06
155.1176453	0.32
159.9101562	9.80
166.1976013	0.23
167.0870972	0.54
171.0424347	1.20
177.0474701	10.97
179.0177612	10.43
185.1417389	1.65
192.0015106	0.41
196.9931030	1.69
210.1585083	4.06
213.0558167	1.62
228.1385803	0.42
231.0713196	0.90
236.1437683	0.50
242.1182251	1.62
244.1188660	0.10
249.0844727	0.08
254.1383972	93.84
269.7660828	0.23
272.0959167	100.00
288.1535645	70.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	479.12
Annotation	Pedaliin
Peak:m/z	Relative Intensity
135.0565796	0.12
147.2133942	0.16
150.2003479	0.17
162.8626556	0.08
178.7615051	0.05
205.4070740	0.04
207.0541840	0.06
212.9179688	0.11
221.6372070	0.09
227.1219482	0.08
232.7991028	0.09
254.8318176	0.06
268.8999329	0.23
271.3236084	0.14
286.4063721	0.07
299.9307556	0.04
302.3446350	0.05
303.1541443	0.24
307.0871582	0.19
308.1665039	0.05
310.3684692	0.17
312.1420288	0.04
317.1076050	100.00
322.7522583	0.06
331.2794800	0.06
333.1376038	0.02
340.5093384	0.15
344.1296387	0.04
345.1285400	0.15
348.2088623	0.07
353.4244690	0.04
358.3287354	0.05
359.2815552	0.33
367.1941223	0.04
375.1424866	0.83
380.0140076	0.03
383.2459106	0.47
389.3082886	0.42
389.9690247	0.02
396.9903259	0.12
398.2477722	0.16
405.0988464	0.54
413.2813416	0.44
414.7799377	0.12
417.6058960	0.12
419.1965027	0.04
425.3484192	0.20
429.0072937	0.04
433.3358154	0.31
435.3862610	0.04
438.3904114	0.10
441.3835754	0.20
443.0968323	0.49
443.9797668	0.10
445.1746216	0.09
446.2020569	0.19
447.0257263	0.30
450.2035522	0.10
451.4331665	0.24
455.7904358	0.13
460.3349304	0.44
461.2701721	1.91
462.3787231	0.35
463.0658875	0.29
469.6975403	0.13
470.4270935	0.25
479.2914429	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	350.1973
Annotation	Dipivefrin
Peak:m/z	Relative Intensity
99.9802322	9.04
112.1443634	0.24
115.9665527	0.33
119.1776123	1.79
123.1679535	0.72
125.0602875	12.35
130.0346680	6.34
136.2891235	0.10
141.1269531	0.33
142.9105835	0.47
147.2424927	0.15
147.9136353	0.29
154.0448608	0.29
156.1576691	1.25
160.1412964	0.84
166.2564087	0.18
169.4610138	0.10
170.9691467	0.10
174.0601807	0.99
176.0587463	0.41
177.8364410	0.35
178.9867859	0.06
180.1558838	0.98
186.0880737	1.42
187.1794434	1.30
189.9893494	0.21
192.1426392	17.91
199.1803436	0.44
204.1671600	0.60
207.9796143	0.56
210.2633057	0.66
215.1013184	0.33
217.0930176	100.00
222.2603760	1.04
225.0799561	0.19
227.2288513	1.46
228.2075806	0.22
230.6555176	2.14
231.3172302	0.42
243.1353455	0.42
244.2488098	0.81
245.2980042	1.06
246.2338562	4.82
247.2709045	0.20
248.1842957	1.97
254.2501831	0.31
258.1530151	8.59
260.0895691	1.36
264.2225647	0.17
266.3023376	7.20
270.3669128	2.26
272.1364746	2.17
274.0821533	1.12
278.1916504	0.43
282.3143921	5.96
284.1905212	83.74
290.2501221	0.38
296.2826233	14.82
300.1989136	9.24
302.2429810	10.41
305.2460327	0.37
306.2323914	0.50
307.2391968	0.30
312.3126831	3.31
314.2711182	22.03
320.0725098	0.57
330.1623535	0.96
331.3380127	0.43
332.3250427	11.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	381.1765
Annotation	1,2,10-Trihydroxydihydro-trans-linalyl oxide 7-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
101.0861053	0.07
113.1250763	0.57
118.4985046	0.04
125.0261230	0.21
129.0796509	0.13
131.0125275	0.09
137.0283508	0.05
141.1159973	0.04
142.9145355	0.50
145.2910767	0.02
148.8213959	0.12
158.9420471	0.81
161.0943909	5.15
177.0989532	0.28
181.0325165	0.53
191.2637939	0.10
197.0039062	0.14
198.2892761	0.06
199.0693512	0.18
215.1112061	0.11
217.1596527	0.21
218.4512939	0.05
225.4937744	0.03
233.2929993	0.15
238.0111084	0.06
243.1456299	0.02
249.1230774	100.00
251.9405212	0.01
265.6180420	0.04
272.3576965	0.13
273.4786072	0.07
275.1700439	0.02
285.3936157	0.05
289.2247925	0.08
291.1467285	0.53
293.1544189	0.17
294.3407288	0.04
295.2172852	0.02
299.9877930	0.91
301.6871033	0.04
314.2764893	0.06
315.2301331	0.03
334.3572388	0.11
337.0766296	0.06
339.2454529	0.05
340.0949707	0.04
341.4523926	0.05
342.8137512	0.02
344.3159790	0.18
345.2266846	0.08
360.5521240	0.04
362.4185791	0.23
363.2457275	0.26
366.2332458	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.2326
Annotation	Pendine
Peak:m/z	Relative Intensity
179.2574615	0.06
191.1773987	0.15
219.2071228	0.04
221.2225037	0.06
253.1800537	0.04
273.1727295	0.02
283.2257690	0.17
289.1316833	0.02
290.7155762	0.01
301.0768433	0.05
305.1666260	0.03
306.1560364	0.03
317.3499146	0.07
318.8178101	0.07
323.2371826	0.03
325.2843018	0.05
335.4552002	0.11
339.4865723	0.03
342.3472900	0.06
363.2711792	0.03
368.3295288	0.03
369.0851440	0.04
370.0155640	0.06
370.8833618	0.01
371.6664429	0.05
372.3773193	0.05
374.5167236	0.02
377.3602905	0.06
385.4859619	0.06
395.1327515	0.12
396.2429810	0.24
397.3605957	1.01
398.2178345	0.02
399.2714233	0.24
401.4338989	0.04
415.2894287	100.00
416.4394531	0.58
434.7278442	0.02
441.5421143	0.03
445.8227539	0.03
451.5086060	0.07
455.5740967	0.08
456.5607910	0.05
457.4435425	0.09
459.5199585	0.19
460.7738037	0.05
466.6109619	0.03
468.4563599	0.05
481.1089478	0.11
485.3778076	0.12
488.2623291	0.01
490.5413208	0.02
496.4329224	0.03
497.5798950	0.05
501.1857300	0.02
503.4882202	0.11
505.2108154	0.14
515.4682617	0.04
516.4652710	0.15
517.6597900	0.02
530.8466187	0.41
531.6626587	0.17
532.9784546	0.21
533.6811523	0.04
534.4710083	0.02
538.4613647	0.06
539.4287720	0.15
541.5408325	0.04
545.2874756	0.07
551.0364990	0.01
554.5586548	0.05
558.2603149	0.13
559.2968140	0.61
567.8245239	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.07
Annotation	4-(beta-D-glucosyloxy)-3-hydroxy-benzoic acid
Peak:m/z	Relative Intensity
94.9341431	2.55
108.9747086	1.39
112.9954681	11.46
114.0338593	2.73
114.8801956	0.06
127.0367737	8.55
128.0368958	2.08
128.7681274	0.15
130.9413757	57.61
132.1404572	0.20
139.9995728	0.14
144.9794006	100.00
176.9772034	0.11
217.0769958	1.01
224.8432312	0.25
230.9322815	0.26
240.0984802	0.06
241.1272888	0.59
255.0828247	0.07
256.1362915	0.07
271.3577271	0.69
278.9546509	0.28
281.0552673	0.10
296.0561218	1.52
297.0843506	3.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	656.3986
Annotation	26-Glucosyl-1,3,11,22-tetrahydroxyergosta-5,24-dien-26-oate
Peak:m/z	Relative Intensity
190.7893677	0.29
192.0498199	0.20
193.2690887	0.24
196.2421570	0.08
207.9783630	0.21
211.2494507	0.10
217.0889130	0.14
219.3006897	0.42
221.0273743	0.92
221.7694092	0.22
222.4089355	0.07
223.0758362	0.36
225.1615448	0.05
232.9904785	0.06
235.0842896	0.47
236.0337830	0.28
236.9391022	0.06
249.1837006	0.21
251.5135345	0.77
252.3320618	0.11
253.1559448	0.15
255.3422852	1.21
262.2144470	0.07
265.0603333	1.40
265.9358826	0.53
267.2180481	0.44
269.0933533	2.25
270.2497559	1.84
271.1662598	0.59
272.2199097	0.22
277.9899902	0.46
279.2694397	0.24
281.0315552	0.28
283.3874207	0.10
291.1614380	0.17
296.1694336	0.17
297.2619019	0.70
298.1632080	0.21
299.3294678	0.10
300.2609558	0.36
301.1223450	0.18
304.4888306	0.13
305.6500854	0.15
306.9066162	0.08
308.8881836	1.45
310.0077515	1.55
311.1282959	0.12
313.0370483	1.97
313.6674805	0.67
314.2759399	1.63
315.1926270	0.64
323.0073242	0.22
324.2813110	0.31
324.8976440	0.06
339.1452026	0.10
340.0709839	0.42
341.9104004	0.09
343.1005249	0.14
344.3697510	0.12
350.0770874	0.34
353.0203857	0.55
354.3506470	0.79
355.3914795	0.31
356.4010010	0.73
357.1963501	0.39
358.0889893	0.36
359.1443481	0.27
361.0142212	0.07
366.1854858	0.29
367.3778687	0.28
369.1978149	0.20
370.0943604	0.05
375.4160767	0.06
381.9382324	0.10
384.2660522	0.09
385.4479370	0.10
386.2365112	0.05
387.4635010	0.36
397.3122559	0.78
398.3099976	0.21
400.9848022	0.47
402.0934448	1.70
403.1566162	0.94
404.2629395	1.02
405.2915649	0.39
412.2570801	0.09
420.2576904	0.47
421.0391846	0.35
427.2868652	0.09
428.2819824	0.46
430.2773438	0.38
432.2897339	0.04
441.2368164	0.08
441.9248047	0.19
442.6274414	0.06
445.2595825	1.96
446.2615967	1.34
447.4055786	0.75
448.1026001	1.43
449.2532349	0.12
463.3399048	0.05
464.2066650	0.16
465.4172363	0.19
474.4151611	0.14
489.9361572	0.56
491.0260620	1.56
491.9919434	0.70
492.9764404	0.35
507.9915771	0.25
509.3297729	0.52
515.5399780	0.41
516.7767944	0.06
519.2679443	0.07
533.1377563	0.68
534.3654175	2.61
535.2406616	2.43
536.3055420	3.17
537.2881470	1.38
546.9437256	0.05
552.2622681	2.37
553.3080444	1.52
553.9546509	0.06
563.2275391	0.31
578.2060547	0.27
579.3117065	0.31
580.0094604	0.05
584.7904663	0.04
596.3485718	2.31
597.3107300	0.47
614.6470337	0.07
622.3016968	1.97
623.5375366	0.62
633.6033325	0.11
640.2796631	100.00
641.3677368	79.12
650.3233032	0.58
658.1476440	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	223.0459
Annotation	Unknow
Peak:m/z	Relative Intensity
82.8686218	0.06
84.9527435	10.18
100.9517059	0.23
110.9287872	7.18
124.8142853	0.06
128.9359436	1.81
133.0660248	0.08
142.9064026	0.03
146.9852448	0.30
158.9554138	0.14
160.8739624	0.34
164.1513672	0.23
173.0188751	0.94
179.1290588	0.24
186.9788055	1.35
190.9708099	0.05
203.2066650	0.03
204.9756317	100.00
208.0229034	0.10
224.1125946	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	233.98
Annotation	Unknow
Peak:m/z	Relative Intensity
119.6000519	0.15
138.0501556	0.19
145.7805939	0.25
148.9224548	0.12
157.9233246	2.14
170.0429840	0.61
171.5434875	0.16
172.9099884	0.48
173.9970398	7.49
175.7974396	0.43
178.0822906	0.32
185.9498596	13.55
187.2276917	0.21
188.0684967	0.80
190.0328674	0.50
197.9965973	1.61
201.8225861	0.15
203.7447968	24.36
204.8641968	0.19
206.2764587	0.38
211.8850555	1.13
215.9606476	100.00
218.8333588	0.16
219.7233276	1.04
220.3613739	0.10
222.3356171	0.11
224.7702026	8.51
225.4143829	0.78
227.1668854	0.13
233.8035278	1.63
238.6472626	0.40
242.1492157	0.15
242.9262848	0.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.08
Annotation	O-Feruloylgalactarate
Peak:m/z	Relative Intensity
110.9566498	0.42
128.0163269	0.06
129.0029297	6.01
135.1618042	0.36
144.9593201	0.03
146.9761200	0.08
153.1544189	0.05
161.1235657	0.12
166.9939575	0.05
173.0738220	0.12
179.0252075	6.34
186.9906464	0.05
191.0034790	0.94
193.0906067	0.17
194.6632996	0.03
195.9867249	0.17
197.1106262	0.09
198.9661865	0.07
203.1785583	0.16
205.0282898	9.23
206.8578186	0.18
209.2301636	0.18
215.1707153	0.19
221.1464844	0.25
223.0461731	100.00
233.2705078	0.04
237.1979675	0.14
247.0903015	0.54
252.9901733	0.10
264.2586060	0.05
265.1057434	0.71
269.1472168	0.04
279.3149109	0.04
282.9024963	0.04
289.1893921	0.24
294.9892883	0.41
301.1134033	0.06
305.2832031	0.05
307.1863098	0.04
311.1841431	0.03
321.3049011	0.06
323.2623901	0.10
325.0174866	1.07
326.4243774	0.07
334.9124756	0.41
338.3408813	0.25
339.1902466	0.03
340.4795837	0.20
341.2507324	0.37
345.0620728	0.06
346.1159058	0.05
349.0018921	0.15
350.1273804	0.11
352.8220520	0.07
356.8187561	0.07
367.0243225	4.71
367.6803894	0.20
368.3076782	0.08
384.8952332	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	589.0501
Annotation	Unknow
Peak:m/z	Relative Intensity
172.8428802	0.98
190.1091766	0.10
217.0352173	100.00
218.0479126	4.64
247.0720062	0.12
268.0974731	0.06
273.0931396	0.25
276.0797119	0.15
282.8186646	0.07
313.1068726	0.19
318.9866028	0.07
320.3468018	0.18
325.1096191	0.04
371.3884277	0.08
380.7907715	0.06
382.3604126	0.65
383.0649414	0.10
385.1854248	0.28
389.1441040	0.05
406.3278198	0.07
421.3719482	0.09
426.2734375	0.08
427.3847046	0.21
428.4669189	0.10
441.3388062	0.07
450.2120361	0.08
451.0557861	0.32
454.1513672	0.03
458.2315674	0.04
463.2386475	0.75
469.5514526	0.07
475.5051880	0.10
484.2185059	0.16
491.0293579	0.12
504.3897705	0.27
514.3571167	0.06
530.0159302	0.35
545.3126221	0.19
546.2358398	0.54
553.0042114	0.29
554.2707520	0.15
561.8047485	0.08
567.9651489	0.21
571.0691528	1.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	454.2917
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
131.2564545	0.05
144.8976288	0.16
146.9735718	0.15
163.2620239	0.07
175.2456512	0.04
197.2151642	0.04
198.1690979	0.04
207.0411224	0.35
211.1399231	0.09
221.4152527	0.07
223.3076172	0.06
226.2676239	0.38
239.0095978	0.08
241.2477112	0.16
255.0454407	0.05
257.1057739	0.27
259.3883972	0.03
282.3155823	0.92
292.3002014	0.05
295.1122437	0.14
304.2522583	0.04
305.3409424	0.04
308.5108643	0.17
311.6242676	0.10
313.3037415	39.46
314.2453918	0.14
316.2253113	0.05
322.9586182	0.04
324.9863586	0.09
326.2242432	0.09
328.1394653	0.06
329.5530396	0.11
344.0858765	0.06
345.9976807	0.25
351.2050171	0.13
353.0247498	0.06
357.2056885	0.02
360.2753601	0.09
364.4261780	0.15
368.0872803	0.23
369.0524902	0.04
380.1054382	0.05
392.0528259	0.04
393.1697693	4.79
397.3592529	0.04
400.9783630	0.34
402.0737000	0.07
408.1572266	0.28
409.1414490	0.12
411.3387146	0.22
413.0810242	0.44
417.6474304	0.26
418.2778931	0.56
419.3205566	0.21
422.5079956	0.08
425.1926575	0.02
430.8097839	0.13
436.2767029	100.00
437.4776917	0.27
453.2911682	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	598.3229
Annotation	Unknow
Peak:m/z	Relative Intensity
178.1067963	0.05
180.9375916	0.23
182.1211395	0.05
193.0535889	0.09
203.1417542	0.08
205.2989044	0.07
210.1109924	0.13
219.2965088	0.05
220.9678345	0.03
240.9550171	0.07
253.4137268	0.07
255.1410370	0.22
256.2831116	0.06
263.0662537	0.04
271.0819702	0.13
273.1809692	0.41
274.2797546	0.05
283.4098206	0.08
285.1871338	0.06
289.5541382	0.09
295.3468018	0.08
300.4028320	0.05
301.3348389	0.19
302.1956177	0.10
303.2709351	0.53
305.1918335	0.17
306.6845093	0.13
311.2429199	0.06
329.3666992	0.03
339.3995361	0.02
350.4580688	0.15
357.0514526	0.07
371.2717896	0.03
372.1541748	0.12
375.1782227	0.15
387.1199951	0.05
388.1435547	0.23
389.6853027	0.14
391.4858398	0.13
394.3755493	0.05
404.9346313	0.05
405.5675049	0.06
407.3674316	0.16
412.0173340	0.07
415.2730103	1.58
416.2313843	1.02
430.2113647	0.22
434.0032349	0.03
435.1906128	0.64
436.1987305	0.31
438.1257935	0.05
445.0380859	0.04
446.7678223	0.12
448.1837158	0.13
457.0928955	0.20
462.6547852	0.11
463.4657593	0.02
465.4299927	0.61
466.4923096	0.08
468.4608154	0.23
472.4130859	0.06
477.6210938	0.14
478.2980957	0.04
492.2730103	4.93
507.1837769	0.09
510.4273071	0.58
511.7069702	0.04
513.8507690	0.07
521.6320190	0.18
522.5723877	0.07
523.4628296	0.02
536.1832275	0.37
537.4480591	0.16
538.6317139	0.08
544.1365356	0.03
548.3566895	0.14
552.1970215	100.00
552.9171753	0.06
554.1016846	0.56
560.2412720	0.05
561.3093262	0.13
562.3718872	0.03
566.6876831	0.13
567.4298706	0.05
568.3555298	0.09
578.1881104	0.26
579.3916626	0.46
580.2810669	0.40
581.5597534	0.09
589.6131592	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1249
Annotation	Cyanidin 3-(6''-caffeylglucoside)
Peak:m/z	Relative Intensity
177.0575104	1.63
177.8814240	0.04
179.0215759	0.34
187.0534058	0.02
190.9604187	0.09
203.0091858	0.06
204.2158966	0.19
207.0555267	0.03
213.0568390	0.18
217.0687714	0.11
219.2190247	0.58
221.1462402	0.25
228.3119507	0.04
229.1351013	0.08
231.1467896	0.39
232.2973938	0.03
243.1338348	0.15
245.2824249	0.02
247.1291809	0.10
255.0500336	0.34
259.0077209	0.29
260.9475708	1.45
262.1838379	0.06
263.3685303	0.24
266.9562988	0.03
273.1600342	2.46
283.0393982	0.32
285.1847534	0.30
287.0563354	0.13
295.1525269	0.18
297.2086487	0.03
303.0940247	4.34
305.0870667	36.31
306.1032715	0.37
307.0075073	0.19
313.3244019	0.09
315.1309204	1.94
316.2965393	0.03
325.2965698	0.08
326.0701904	0.03
327.2181396	0.10
329.3284302	0.03
341.2286377	0.08
344.0731201	0.07
345.3964844	0.37
347.0730591	0.33
355.3379517	0.31
357.1477661	0.46
359.0681152	0.12
360.2290649	0.02
367.3902588	0.07
373.2171631	0.27
378.1021729	0.05
380.4449463	0.16
386.1491089	0.05
387.3625488	0.07
397.1860352	1.36
399.5437622	0.08
405.1487427	0.03
411.5640869	0.05
413.4382324	0.12
417.2749023	0.40
421.3443604	0.08
423.1271973	92.31
424.0146484	0.11
427.3644409	0.61
429.4208374	0.13
430.0808716	0.09
431.2578125	0.53
439.0594482	0.36
441.1679077	100.00
442.1216431	0.15
443.2630005	0.19
447.3743896	0.07
451.2277832	0.07
453.2067871	0.96
463.3102417	0.10
465.1867065	2.48
466.2041626	0.06
468.2326050	0.04
469.1704712	0.31
470.2198486	0.14
471.4084473	0.54
475.1542358	0.77
481.1666870	0.65
482.3349609	1.37
483.1774292	16.21
483.9715576	0.08
502.0603638	0.13
503.8076172	0.14
506.7463379	0.15
507.3618774	0.07
509.5021973	0.04
515.4268188	3.02
516.2527466	0.33
517.1931763	0.05
524.3939209	2.77
525.2990112	0.49
528.3732300	0.02
529.3960571	0.10
545.7070923	0.11
547.3502808	0.78
549.6967163	0.12
555.6813354	0.09
565.1903687	2.32
567.0542603	0.03
572.3175049	0.22
573.2017822	0.38
579.1706543	0.04
586.2141113	0.03
587.4216919	0.16
590.5668945	1.33
591.2944946	12.69
599.2387695	0.10
600.4138184	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.12
Annotation	Cyanidin 3-(6''-caffeylglucoside)
Peak:m/z	Relative Intensity
177.0402527	0.95
178.9615326	0.65
189.1752930	0.08
201.1365662	0.07
202.6250000	0.05
219.0842590	0.59
221.2833557	0.06
229.2000732	0.15
241.3258057	0.12
243.0472870	0.22
246.3242188	0.08
253.1596680	0.04
259.2209167	0.12
261.1021118	0.86
263.0968323	0.06
273.0457153	2.41
285.0109253	0.03
286.1943970	0.07
287.2222900	0.35
291.5149231	0.09
297.0826416	0.12
302.1256104	0.09
303.1282959	3.19
305.1951294	28.23
315.1202393	1.30
325.3253784	0.13
326.1299438	0.22
327.1699829	0.03
343.3649902	0.06
345.2156372	0.88
347.3333740	0.03
355.3796997	0.65
357.1253662	0.07
373.2308960	0.27
378.0914307	0.05
383.1714478	0.07
387.1435547	0.08
397.3065186	0.77
423.1536255	78.67
423.9625244	0.19
425.4760742	0.04
426.3563843	0.33
427.1105347	0.10
428.3560791	0.08
428.9586182	0.09
429.9990845	0.03
435.3117065	0.15
439.3020630	0.44
441.2229614	100.00
442.1704102	0.19
443.0090942	0.12
447.5036011	0.29
451.2653198	0.03
453.2379761	1.08
454.6078491	0.13
464.7203369	0.81
465.3302002	1.96
471.4050903	0.32
481.4542847	0.22
483.2716064	13.89
484.2047119	0.04
489.1242065	0.21
503.1681519	0.13
506.7271729	0.15
515.0687866	0.12
516.0352783	0.92
519.9595337	0.20
524.6560059	0.10
525.3793335	0.25
536.6776733	0.13
541.3339844	0.03
545.8933105	0.10
547.2125854	0.28
548.1138306	0.11
551.5254517	0.16
564.1205444	0.16
565.1080933	1.83
565.7805786	0.10
573.1298218	0.05
581.5370483	0.05
588.1473999	0.14
591.2582397	10.94
592.5379028	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	217.03
Annotation	Unknow
Peak:m/z	Relative Intensity
70.7667465	0.52
88.7027893	1.04
113.0384674	1.49
131.0426788	1.14
143.0830536	3.75
144.7595062	5.23
157.0196686	0.47
160.9684906	11.39
168.8424530	2.17
178.8748932	100.00
181.1266632	4.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	557.2603
Annotation	Valeriotriate B
Peak:m/z	Relative Intensity
160.9449768	0.46
178.9335785	8.69
225.0192719	1.13
238.3485107	0.20
247.2600098	0.18
280.5839233	0.05
293.2666626	0.14
330.6132202	0.03
335.2729492	0.24
339.1258545	0.03
347.2463989	0.21
349.2780151	100.00
355.1869507	0.08
356.4688110	0.14
358.1434937	0.03
361.0622559	0.40
377.1871338	0.44
391.2037964	0.38
393.5487671	0.04
394.5920410	0.05
397.0803223	0.05
423.4904175	0.13
435.4909668	0.29
437.1265869	0.15
441.3104858	0.08
450.3305054	0.18
451.5199585	0.15
467.4155273	0.08
469.1583862	0.47
474.1392822	0.49
479.1265259	0.85
482.4074707	0.10
495.3124390	0.22
496.3007202	0.73
497.1799927	1.37
508.2219849	0.20
508.8538208	0.08
509.7833252	0.14
510.8314819	5.92
511.5425415	0.73
513.5623779	0.52
515.3145142	0.10
517.9057007	0.40
518.5152588	0.22
521.0717163	0.54
522.0676880	0.04
524.5156250	0.06
534.0906372	0.41
538.0863647	0.46
539.1059570	0.35
539.9087524	0.07
542.4537964	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.0617
Annotation	2-O-Caffeoylglucarate
Peak:m/z	Relative Intensity
128.9947815	0.44
133.1521606	0.05
147.0666656	0.16
150.9960938	0.02
173.1835632	0.05
179.1127319	0.25
183.1758118	0.05
191.0825806	10.65
192.1952057	0.02
204.2275391	0.16
204.9212799	0.01
209.0439453	100.00
209.8418274	0.01
252.9726868	0.02
254.0464478	0.01
281.1141357	0.03
291.3989258	0.04
303.2467651	0.02
309.4262390	0.28
324.2058716	0.02
325.1721191	0.02
328.2685547	0.05
335.0990906	0.14
353.0737305	11.73
362.2070007	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	440.2289
Annotation	Unknow
Peak:m/z	Relative Intensity
146.8844299	0.02
161.7831726	0.02
202.0453491	0.04
205.0769653	0.09
207.9730682	0.05
210.2903290	0.06
215.2063904	0.12
241.2069397	0.13
246.1934814	0.08
257.4551086	0.10
262.1170044	0.30
275.1099548	0.03
278.2000122	0.05
298.3518066	0.02
309.9403381	0.03
311.2700195	0.04
338.2050171	0.08
339.8642883	0.02
342.1203918	0.04
344.2589111	0.11
344.9207764	0.08
348.3312683	0.03
350.3197021	0.10
359.4461670	0.21
360.3932800	0.74
363.2349854	0.06
364.2314148	0.06
368.4043579	0.03
376.4640198	0.02
377.9172668	0.12
379.2792664	0.05
384.3728027	0.03
391.3887024	0.01
392.5549011	0.03
394.2871704	100.00
396.2097473	0.10
397.4175720	0.09
404.1704102	0.32
405.9298401	0.05
421.3728333	0.06
422.2961731	0.44
423.2013855	0.02
425.3811951	0.08
426.0608826	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	602.8826
Annotation	Unknow
Peak:m/z	Relative Intensity
174.8812866	0.65
267.1401978	0.26
273.9082642	0.09
275.0307312	0.09
297.3056946	0.15
404.4521484	0.04
442.9945068	0.38
446.0780640	0.09
459.2977905	0.07
486.9990234	0.46
488.6871338	1.43
489.3411255	0.08
507.4721069	0.13
511.8539429	0.15
529.2534180	0.08
529.8927612	0.25
556.8704224	100.00
557.6901245	0.04
558.6399536	0.10
559.2734985	0.08
572.1517944	0.18
584.3145752	0.35
585.2803955	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.183
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0284576	0.37
174.9460449	0.05
177.0093994	0.08
179.1232605	0.10
190.9750061	0.14
207.3220825	0.33
209.0541534	100.00
271.2473755	0.03
289.3622437	0.04
304.9154053	0.01
306.2520142	0.10
322.1799927	0.02
323.3588257	0.03
325.1780396	0.05
333.2483521	0.10
341.1290894	0.05
377.0897217	0.15
414.0351562	0.04
415.1510010	0.02
435.4959717	0.06
450.2037354	0.11
453.3176880	0.04
490.8090210	0.20
499.1227417	0.04
505.2488403	0.07
507.2922974	0.13
514.8933105	0.04
532.7343140	0.05
533.5347900	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1145.1716
Annotation	Unknow
Peak:m/z	Relative Intensity
327.7478638	0.55
358.1273499	0.70
363.0969543	0.17
375.1278076	0.44
377.4926758	0.10
390.8451538	0.30
397.4104309	0.34
405.3775024	0.23
425.2763367	0.60
433.9052124	1.97
439.2446289	0.60
440.9146729	0.56
441.6098328	0.24
452.1015015	0.31
457.1816406	0.23
458.9254456	0.13
470.3315735	0.75
471.6699524	0.23
478.1856689	0.38
480.1967773	0.30
486.5177002	0.16
487.6337585	0.09
514.0243530	0.73
515.3661499	0.29
516.1859741	0.13
521.4865723	0.56
523.0466919	0.59
523.6673584	0.38
531.4133911	0.16
542.3232422	0.49
546.4456177	0.32
548.0794678	1.09
549.4181519	0.62
551.3277588	1.71
556.7707520	0.41
570.2198486	0.24
574.2487793	0.43
582.1914062	0.21
585.5604248	0.61
588.3419189	0.15
590.3569336	0.20
591.1224365	0.43
596.5897217	0.57
613.3565063	4.40
614.4863281	0.69
626.3155518	0.43
632.4270020	0.25
635.4614258	0.25
636.5467529	0.19
637.2940674	0.65
651.1760864	0.24
652.4512329	1.26
654.4974976	0.57
655.2037964	0.23
656.5337524	0.45
659.2335205	0.37
661.3154297	0.24
662.0960083	0.89
669.7855835	1.31
671.3331299	1.09
671.9938965	0.19
673.9401245	0.15
680.0255127	0.34
682.4898682	1.43
683.4244995	0.87
685.5747681	0.44
690.1870728	0.76
694.2887573	0.33
699.3704224	0.13
700.3321533	1.03
712.4182739	0.80
714.4573364	1.06
716.6475830	0.35
717.6974487	0.27
718.5422363	0.41
722.4039307	0.89
724.6098633	0.88
725.8356934	0.67
728.8992920	0.11
732.3888550	0.21
742.6436768	0.44
755.4675903	0.30
769.3514404	0.41
770.4035034	1.05
781.5360718	0.11
784.0288086	0.43
786.2293701	0.23
787.5950317	0.12
795.6988525	0.73
797.6940308	0.32
799.5593872	1.33
803.4617310	0.32
817.4967041	0.30
818.2886963	0.63
843.5577393	1.39
850.7331543	0.28
854.5631104	0.14
865.0007324	0.22
866.8286133	0.59
867.5200195	1.99
872.1057129	0.66
874.4119873	0.28
892.9954834	0.20
900.2735596	0.45
904.6821289	1.52
907.6945801	0.44
911.2849121	0.16
917.3778076	0.23
919.5717773	0.30
921.1585693	0.64
927.7412109	0.13
929.8746338	0.20
938.3383789	0.39
939.0883789	0.22
948.4526367	0.19
952.3262939	0.68
954.1929932	0.79
956.5573730	2.41
958.6585693	0.26
969.9899902	0.83
970.7060547	0.49
977.5656738	0.31
982.4077148	0.10
983.2432861	0.49
984.1125488	1.69
988.5092773	1.53
993.6243896	3.10
1002.2703860	0.12
1004.6250000	1.55
1010.6345210	0.48
1011.7680660	0.79
1013.4987790	0.88
1015.6329350	3.27
1017.6748050	0.48
1018.9766850	1.61
1019.6153560	1.12
1020.3906250	0.74
1023.7490230	1.75
1024.8432620	6.05
1025.5073240	0.08
1026.2233890	4.96
1028.1865230	1.71
1029.3876950	1.85
1030.5334470	3.78
1031.1434330	3.64
1031.8688960	2.14
1033.6210940	1.77
1034.8376460	0.65
1035.4443360	0.58
1036.6293950	0.48
1037.4377440	0.89
1040.8002930	2.95
1041.7436520	0.25
1043.0650630	0.69
1044.1179200	0.46
1046.0886230	2.46
1048.1654050	0.50
1050.2801510	1.89
1050.9116210	1.10
1051.8747560	0.91
1052.8125000	2.96
1053.4367680	0.83
1054.6643070	1.97
1056.3344730	0.96
1057.2849120	6.71
1058.2550050	7.62
1059.0384520	4.57
1062.9316410	29.00
1063.8840330	14.04
1064.9018550	5.17
1065.9353030	1.31
1066.5384520	4.97
1067.2062990	1.19
1067.9851070	5.40
1068.9851070	24.98
1070.2943120	3.46
1072.2509770	5.98
1073.8033450	5.42
1074.5676270	3.34
1075.6541750	1.00
1076.6090090	1.43
1077.9063720	5.45
1078.6103520	0.95
1080.2586670	0.78
1081.1607670	3.42
1082.1107180	0.27
1083.4781490	4.59
1084.3793950	2.01
1085.4086910	3.67
1086.1386720	4.50
1087.1916500	2.71
1087.9522710	2.31
1089.5548100	9.15
1090.3677980	4.69
1091.3110350	2.61
1092.5202640	5.42
1093.3939210	1.16
1095.2661130	31.13
1096.3734130	94.51
1098.0280760	7.95
1099.0307620	3.13
1099.6607670	3.01
1100.6826170	1.28
1101.6563720	100.00
1102.6984860	14.72
1103.4528810	0.91
1104.6420900	3.03
1106.0811770	3.11
1107.2568360	22.38
1107.9520260	23.33
1109.0382080	3.71
1110.3416750	3.01
1111.0126950	2.86
1112.0681150	4.04
1113.1306150	4.49
1114.3101810	3.48
1115.4448240	0.36
1117.5354000	1.31
1118.6959230	5.46
1119.5617680	5.39
1121.2702640	7.39
1122.0612790	4.03
1124.0031740	12.25
1124.6215820	16.08
1125.2680660	6.60
1127.4846190	46.98
1128.1427000	33.15
1129.0147710	2.68
1130.3852540	37.41
1131.1972660	4.50
1132.2248540	2.87
1133.6081540	74.19
1134.8242190	1.76
1135.7863770	1.52
1136.9619140	0.24
1139.6478270	0.45
1140.4854740	0.83
1144.9823000	0.30
1149.8618160	0.25
1174.1712650	1.48
1178.1711430	0.42
1182.4598390	0.64
1183.4642330	0.60
1186.2658690	1.72
1187.0747070	0.25
1187.8654790	0.11
1195.3662110	0.39
1201.1138920	2.06
1202.5118410	0.99
1211.8980710	4.06
1213.4333500	0.32
1215.2368160	1.28
1215.8780520	0.33
1216.6877440	0.75
1222.9705810	1.17
1224.7041020	0.43
1230.7384030	2.95
1234.6562500	0.76
1236.0791020	1.04
1239.7834470	4.31
1240.6401370	2.00
1242.8154300	0.80
1243.9180910	1.52
1245.5332030	1.64
1250.4523930	1.30
1251.0678710	1.79
1254.5041500	0.61
1256.9001460	1.74
1258.0388180	1.73
1258.7634280	2.29
1261.2556150	0.43
1265.9763180	1.21
1267.2490230	3.50
1268.1037600	0.91
1269.3122560	0.25
1270.3278810	0.50
1273.3527830	0.71
1274.2879640	0.20
1277.6473390	1.15
1285.6300050	3.18
1286.6248780	1.26
1287.2271730	2.39
1288.0366210	1.57
1289.3557130	0.75
1292.2949220	0.80
1293.5944820	0.48
1294.3253170	0.75
1296.5803220	2.64
1298.4909670	2.09
1299.2390140	0.24
1300.5993650	3.66
1302.2156980	0.15
1302.9943850	0.44
1304.4049070	0.73
1305.6772460	1.26
1306.9599610	1.84
1308.5200200	1.64
1309.3364260	1.19
1310.3907470	0.88
1312.2626950	2.24
1313.4147950	2.06
1315.0344240	1.68
1316.1203610	1.89
1316.8084720	4.76
1319.1622310	1.29
1322.5773930	1.26
1323.3532710	0.57
1325.2021480	1.10
1327.6458740	2.63
1329.3138430	0.77
1331.8779300	0.60
1336.0584720	0.28
1337.9345700	0.36
1338.5655520	0.33
1341.2690430	1.20
1342.0543210	3.02
1344.5885010	1.52
1346.5390620	1.57
1348.5015870	0.74
1349.5843510	0.45
1351.4102780	4.11
1353.3870850	0.69
1354.9212650	2.37
1357.3094480	1.25
1358.6207280	0.93
1359.7323000	0.42
1360.6143800	1.22
1363.6131590	2.69
1364.2745360	1.53
1366.2037350	1.68
1367.6861570	3.98
1369.2574460	2.79
1370.6383060	2.66
1371.4794920	0.32
1372.3955080	0.34
1373.7536620	0.79
1376.0853270	0.31
1378.7808840	0.45
1379.6683350	0.61
1382.2052000	1.18
1382.9959720	0.77
1387.1712650	0.43
1389.4710690	0.55
1390.8510740	0.61
1392.3182370	0.98
1393.0528560	1.30
1393.7735600	3.67
1399.3861080	0.22
1400.9031980	2.00
1402.8374020	10.60
1403.5179440	0.41
1404.1965330	0.61
1406.2646480	1.68
1407.0252690	1.13
1407.8525390	1.08
1409.9454350	0.18
1410.9971920	4.97
1411.7672120	0.27
1413.4506840	1.06
1415.3548580	3.29
1416.0621340	1.79
1417.1242680	2.36
1421.7589110	1.17
1423.7539060	3.97
1424.3636470	8.46
1425.1705320	2.76
1425.8962400	0.32
1427.2310790	0.20
1427.9870610	0.23
1429.4188230	1.58
1430.2064210	0.41
1431.3265380	3.94
1432.0130620	0.08
1432.7410890	0.40
1436.8504640	0.58
1439.3013920	1.89
1439.9785160	1.40
1443.6085210	1.24
1448.1215820	1.25
1448.8590090	0.71
1450.3807370	0.17
1452.0266110	1.65
1452.9833980	0.77
1453.7751460	1.34
1455.9923100	1.00
1457.1727290	2.25
1458.4647220	2.19
1459.5548100	0.92
1464.8077390	1.01
1465.4194340	0.97
1468.3489990	0.79
1469.3117680	0.62
1469.9405520	1.58
1471.1486820	1.19
1472.2634280	1.33
1473.5039060	1.46
1474.7196040	0.20
1479.3994140	3.29
1480.2514650	1.80
1481.4528810	3.83
1482.2919920	0.87
1484.4300540	0.23
1486.5214840	1.81
1487.9544680	1.20
1489.0577390	1.94
1490.1636960	5.40
1490.9432370	0.68
1493.0712890	0.57
1494.6257320	4.66
1496.4046630	1.06
1501.8082280	1.15
1503.5806880	1.18
1504.5653080	1.19
1505.5017090	0.33
1506.4311520	0.30
1507.4921880	0.21
1509.4659420	1.99
1512.0140380	1.09
1513.4036870	0.73
1514.4471440	0.95
1515.9669190	0.58
1518.6519780	0.54
1520.0300290	0.28
1521.1636960	1.98
1521.9991460	2.62
1522.8210450	1.43
1524.8315430	0.74
1525.9378660	0.66
1526.9974370	0.85
1528.2242430	1.41
1529.1593020	0.85
1530.1812740	3.60
1530.9195560	1.37
1533.7346190	2.58
1534.7359620	1.53
1537.1778560	5.29
1538.1114500	3.50
1539.3045650	3.87
1540.0130620	0.18
1541.5921630	0.44
1542.3706050	1.89
1543.6560060	0.73
1545.1933590	7.99
1546.1868900	12.73
1546.9593510	4.71
1547.7197270	0.22
1548.7058110	0.56
1550.8824460	2.24
1551.5954590	2.48
1552.6202390	0.67
1553.8409420	1.61
1554.6550290	0.92
1555.5848390	0.22
1557.3494870	1.09
1560.3413090	0.61
1561.0554200	0.31
1562.4686280	0.44
1564.6336670	0.30
1571.6677250	0.51
1572.5230710	1.76
1573.2503660	0.16
1580.1048580	3.07
1580.9884030	1.99
1581.7249760	0.67
1583.7869870	1.27
1584.8105470	0.65
1585.7374270	5.41
1586.7637940	7.83
1587.6285400	0.56
1589.5035400	2.11
1590.5046390	1.57
1593.5765380	3.66
1594.3389890	3.50
1595.5582280	13.65
1596.2808840	2.09
1596.9007570	0.40
1598.4053960	7.01
1599.1322020	8.59
1600.0738530	2.12
1600.9370120	1.13
1602.5411380	11.21
1603.3372800	5.27
1604.9000240	2.10
1607.5749510	12.78
1608.2297360	3.10
1608.8396000	1.86
1610.0258790	1.03
1610.8687740	0.64
1611.8349610	1.22
1612.4870610	0.68
1616.6136470	38.49
1617.9769290	0.29
1619.3392330	0.36
1620.3166500	0.39
1620.9892580	0.70
1623.3843990	0.54
1624.5394290	0.37
1630.4097900	0.90
1633.1439210	0.54
1634.2260740	0.73
1635.1968990	0.29
1637.3554690	0.91
1639.1682130	0.76
1642.0710450	8.51
1642.7354740	11.25
1643.5985110	5.66
1644.2934570	0.74
1647.3426510	0.89
1649.0855710	1.07
1649.9421390	0.13
1650.9665530	19.06
1651.9340820	33.12
1652.9755860	3.20
1654.7197270	0.14
1656.5468750	0.25
1660.0201420	30.95
1660.8101810	19.48
1661.8551030	3.11
1663.5596920	0.21
1666.5092770	0.34
1667.7846680	0.59
1669.0166020	0.58
1698.8594970	0.35
1714.8068850	0.12
1719.0587160	0.55
1735.3288570	0.59
1737.1232910	0.43
1754.8820800	0.28
1763.0953370	0.67
1790.6354980	0.20
1801.3082280	0.43
1835.5480960	0.18
1849.4586180	0.19
1850.7967530	0.36
1863.6989750	0.44
1865.6431880	0.10
1886.7598880	0.28
1892.8809810	0.54
1899.6583250	0.44
1905.8062740	0.37
1913.9927980	0.49
1919.2535400	0.14
1959.0775150	0.16
1962.3792720	0.47
1978.5955810	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	494.3098
Annotation	14-Acetylchasmanine
Peak:m/z	Relative Intensity
146.1449127	0.21
167.1538544	0.15
198.2465668	0.20
213.2391357	0.20
227.9903259	0.07
253.1971130	0.06
265.1248779	0.16
269.0580750	0.36
291.2308044	0.11
308.0631714	0.11
311.1484070	0.17
312.4339905	0.09
314.3622742	0.19
330.4389954	0.22
332.1440125	0.29
348.3481750	100.00
349.4226685	0.79
351.8721924	0.08
360.2565002	0.14
361.3431702	0.24
362.0327454	0.29
364.0662537	0.14
371.4166260	0.39
374.2009583	0.69
378.0089722	0.15
380.9566650	0.11
389.2994690	0.10
391.6449890	0.11
396.9604187	0.33
401.2981262	0.06
403.8124084	0.15
405.1087646	0.47
406.1757202	0.37
413.3127441	0.32
420.2397766	0.12
423.7384949	0.25
427.2563782	0.43
431.2401123	0.36
440.4550171	0.30
441.0717773	0.10
449.0694885	0.24
451.3546753	0.22
453.2539673	0.36
458.8881531	0.57
466.4015198	0.10
476.2489319	3.02
477.3270874	0.99
478.1344604	0.15
492.2337036	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	206.8855
Annotation	Unknow
Peak:m/z	Relative Intensity
122.7835846	100.00
158.8483276	0.02
189.0014954	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	597.1432
Annotation	Quercetin 3-lathyroside
Peak:m/z	Relative Intensity
219.2850800	0.02
229.3433990	0.02
240.7919922	0.01
246.8948059	0.08
274.3566284	0.02
285.1549377	0.03
294.9555054	0.06
303.1094360	100.00
303.9346619	0.04
326.9293213	0.21
345.1835327	0.41
368.9682007	0.25
399.2656250	0.08
411.2506104	0.17
429.2434082	0.38
435.0066528	0.76
447.1325684	1.81
449.5106812	0.01
459.2192993	0.14
464.9752808	40.62
465.7010498	0.11
477.0723267	0.13
483.1820068	0.01
489.2583618	0.05
530.3944702	0.03
532.1994019	0.02
543.4282837	0.01
549.8644409	0.12
550.4834595	0.02
561.1768188	0.34
579.1408081	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	644.49
Annotation	Unknow
Peak:m/z	Relative Intensity
184.0320587	0.12
204.5855255	0.07
212.9102173	0.20
217.1546478	0.07
219.0507050	0.07
220.7341919	0.61
221.3814697	0.07
227.3369751	0.12
243.2219849	0.07
256.9623108	1.11
265.0677185	0.08
301.0258179	1.23
309.3032227	0.60
311.3698120	0.11
315.1813965	0.30
316.0554810	0.08
327.3270874	0.20
329.5696411	0.04
335.4052734	0.11
337.5144653	0.12
344.0269165	0.15
345.1495361	0.23
353.2125854	0.16
354.9942627	0.10
359.0152588	0.08
363.0632935	0.06
371.3870850	0.19
373.1605225	0.13
375.0692139	0.05
389.2695312	0.17
397.3629150	0.41
398.4321289	0.06
399.2120972	0.09
407.4230957	0.32
411.2324219	0.13
416.7718506	0.10
417.5296021	0.09
419.0618896	6.45
433.2740479	0.26
435.1436157	0.26
441.2452393	0.54
451.0214844	0.07
459.3679810	1.04
477.0481567	0.27
478.6349487	0.10
483.1425171	0.12
495.0144653	0.13
498.8758545	0.06
520.7009888	0.09
521.3236084	0.61
523.1239014	50.24
523.8354492	0.09
528.1101685	0.08
538.3181152	0.04
539.3857422	0.68
545.7611084	0.09
549.1245728	0.05
556.5291138	0.24
565.8565063	0.12
577.1384888	0.16
583.4235229	1.71
585.6817017	0.03
598.4144897	0.11
608.0153198	0.09
609.1691284	0.41
610.5831909	0.28
612.3687134	0.15
627.1879883	100.00
627.9406128	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	516.8973
Annotation	Unknow
Peak:m/z	Relative Intensity
154.8957214	0.01
158.9791870	0.30
159.9849091	0.12
175.0322266	0.51
176.1965332	0.01
199.0544281	0.04
199.9064636	0.01
215.0515900	0.02
216.0247498	0.01
229.1635437	0.09
245.0348358	0.07
245.9898682	0.03
273.0009460	5.53
274.1072998	1.67
288.9987183	8.76
289.9792480	1.65
318.1540527	0.01
359.0290527	0.01
387.0630493	0.42
388.0479736	0.12
396.9095459	0.01
401.1439819	0.01
402.9587402	100.00
403.9561157	26.48
429.1618042	0.06
443.2374268	0.02
444.1060181	0.07
457.1291504	0.01
470.7968140	0.05
472.1681519	0.03
499.1302490	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	581.3178
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0598755	0.13
191.0293274	0.14
206.1610718	0.18
221.0538330	0.88
235.2742767	0.16
239.2847443	0.59
257.3209229	5.87
258.2228394	0.24
259.0894470	0.21
269.6503906	0.17
271.3797607	0.37
277.6375427	0.20
281.4635620	0.13
287.4480591	0.15
293.1851196	0.19
299.1810913	0.33
317.3841553	0.15
323.1278687	0.18
325.2233276	0.16
333.2487793	0.15
337.5745239	0.27
342.1661987	0.10
355.4637451	0.42
361.3385010	1.16
363.1947632	0.24
365.1600952	0.13
376.9183350	0.09
385.1308594	0.19
386.1936035	0.11
391.5838013	0.14
399.6210327	0.08
401.3496704	12.21
402.3923340	0.20
405.1677856	0.85
406.7299194	0.36
418.1697388	0.20
419.3995972	100.00
420.3571777	6.47
422.6580811	0.11
429.3293457	0.11
431.2783203	0.23
432.7089233	0.05
433.3995361	0.41
435.4722290	0.31
438.5754395	0.20
443.4478760	2.49
444.4803467	0.10
447.5642090	0.08
448.6913452	0.13
449.5624390	0.21
450.4555664	0.28
454.1120605	1.11
456.1763916	0.15
461.2945557	0.24
471.2451782	0.25
473.5330811	0.16
485.2197876	0.35
486.3794556	0.06
491.5904541	0.05
492.6113281	0.06
497.0523071	0.08
501.4409180	0.76
509.1952515	0.21
514.5475464	0.12
519.3545532	0.28
521.1124878	0.05
527.5456543	0.07
534.6126099	0.49
535.3888550	0.47
536.2726440	0.18
537.4325562	0.22
538.4739990	0.13
539.5272827	0.09
544.1328735	0.07
545.2531128	1.48
549.5401611	0.86
561.0502319	0.06
561.9297485	0.42
563.3598022	20.16
564.3362427	0.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	505.316
Annotation	Unknow
Peak:m/z	Relative Intensity
156.8406067	0.06
162.8749390	0.05
167.0976257	0.06
177.0323486	0.45
178.0987549	0.16
191.0357666	0.04
195.6688232	0.09
199.3764648	1.05
207.4721832	0.55
208.1352539	0.20
209.1487122	1.06
212.2854309	0.34
219.0218658	0.03
220.8045349	0.08
221.7122650	0.38
227.0533142	0.08
229.6924438	1.43
230.8061371	0.51
234.4061279	0.10
237.8250732	0.09
240.2317657	0.15
242.8968811	0.43
243.6201172	0.10
244.2932739	0.04
245.5815125	1.24
246.2190094	0.10
249.7532806	0.23
251.5896912	2.75
253.0426025	0.42
256.1492310	0.08
256.9807434	0.06
261.6580200	0.12
262.7354736	0.15
264.6853333	0.13
265.3043518	0.17
267.4493713	0.57
268.2522888	1.22
272.4299622	0.05
273.5780029	3.12
274.2626953	0.53
279.3528748	0.07
287.9229431	1.24
289.7739258	4.66
295.5553589	3.07
296.2039795	0.51
306.2688599	0.18
309.2197266	0.24
311.4543762	3.59
312.1175537	1.82
313.1055908	0.28
314.5899658	0.52
315.3513184	0.71
317.4636230	0.53
323.2880249	0.09
325.0329590	0.27
328.3369141	0.04
332.2554321	0.69
333.6878052	3.19
339.5448608	1.47
340.2305298	0.79
341.2651367	0.38
353.1826172	0.32
355.6382751	2.74
357.2536926	0.09
358.3138123	0.06
361.4671631	1.59
376.0913086	0.40
377.6964111	0.79
383.4872437	0.84
385.2163391	0.22
389.3457336	0.10
396.8998718	0.32
399.5013123	0.70
407.0709839	0.40
408.5254211	0.15
415.3203430	0.06
416.1775208	0.27
417.1007996	0.04
420.5360107	0.13
421.6151428	1.47
422.5717773	0.25
426.3094482	0.20
427.6822815	0.28
428.7262878	0.25
430.0321960	0.08
431.3290710	0.09
441.2972107	0.31
443.5088196	0.80
444.1543884	0.58
445.7552795	0.32
449.5605164	0.08
450.3235168	0.13
452.6866760	1.60
453.4516907	1.14
454.9816284	0.08
457.0184937	0.22
459.5586853	0.18
461.2173157	0.10
462.2984314	0.15
463.6666870	0.12
466.0972595	0.59
467.3619690	0.20
469.1585999	0.15
470.3169861	0.49
471.4303284	0.21
474.7452698	1.81
475.4344788	1.63
477.0412903	0.10
486.1690063	0.12
487.3101501	2.54
488.0447083	1.26
488.6900024	1.80
489.7216187	0.13
496.8544006	100.00
497.9465637	1.78
498.7148743	0.37
500.1077576	0.45
500.9989319	0.09
501.6683655	0.65
503.8300171	0.07
504.8175659	0.32
507.0984802	0.16
512.6137695	0.10
517.2017212	0.20
521.4424438	0.06
548.1995239	0.13
564.4727783	0.68
565.4535522	0.13
571.4286499	0.12
591.0752563	0.27
594.6835938	0.06
596.9603882	0.09
608.3333130	0.90
609.5661621	0.38
615.2387695	0.06
618.1054077	0.22
634.5283813	0.11
639.5694580	0.12
641.8710938	0.09
642.5420532	0.09
652.5366821	1.56
653.4813232	1.27
666.8013306	0.06
679.6394043	0.11
684.3843384	0.42
685.4750366	0.33
693.1112061	0.06
696.4346924	2.58
697.3680420	1.24
698.3604126	0.12
706.1154175	0.09
726.3847046	0.22
728.4920044	1.14
729.3654785	0.76
730.2459106	0.08
737.0696411	0.20
740.3197632	0.87
741.3938599	0.91
742.2783813	0.07
764.0076904	0.10
772.6767578	0.89
773.5079956	0.13
781.0165405	0.12
784.4165649	1.16
785.6070557	0.14
800.4122314	0.06
815.5579224	0.06
816.4907837	0.90
817.4933472	0.78
818.5146484	0.09
826.5659180	0.17
829.9306030	0.30
860.3022461	0.43
861.5585327	0.38
905.6569214	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	453.7837
Annotation	Unknow
Peak:m/z	Relative Intensity
244.9066162	0.03
249.0811462	0.11
255.7302551	0.07
318.9507141	0.92
319.9083862	1.77
324.2035217	0.13
335.1472168	0.10
336.8370972	0.09
342.1077576	0.12
347.6222839	0.05
349.8932800	0.08
357.4283752	0.04
363.8004761	100.00
364.9946899	0.28
371.3316956	0.08
377.4502869	0.04
379.1562500	0.32
379.7981262	5.43
381.4329529	3.41
385.8729553	0.14
387.8290710	0.06
389.8085632	0.20
393.5013123	0.05
394.9449768	0.02
396.2269897	0.41
397.4338074	0.95
399.6910095	0.06
401.4621887	0.19
404.7166443	0.13
407.9849854	1.02
408.8686829	24.87
409.8521423	0.30
411.0615540	0.05
412.5894470	0.08
415.9060364	0.33
417.4323425	0.03
419.2568054	0.16
421.5905457	0.16
422.3468018	0.54
423.3636475	0.30
424.0170593	0.88
424.9115906	0.89
425.8439636	1.19
426.5955200	0.47
428.4560852	0.13
430.4607849	0.23
431.2716370	0.43
432.7709351	0.97
433.9520569	0.82
434.8067017	0.14
435.6499634	0.39
438.9753113	1.86
440.2773743	0.22
442.1900635	0.07
442.9055481	0.26
444.5733948	3.14
445.3468323	0.89
447.2792053	0.19
447.9349976	0.14
448.5708313	0.03
450.5342407	0.10
453.8540649	1.10
455.9787903	0.13
462.5652466	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1664
Annotation	Verbasoside
Peak:m/z	Relative Intensity
136.9089050	0.06
143.0967102	0.02
145.2749634	0.01
149.0438080	0.79
152.7918091	0.03
161.0300598	0.30
175.0771484	0.02
179.2281494	0.01
191.2591248	0.14
209.0950623	0.04
220.3093567	0.17
220.9400940	0.18
223.0842743	0.02
227.9559326	0.06
244.2475281	0.15
250.8403931	0.04
253.0254822	0.03
259.1882629	0.10
263.0899963	0.02
280.9149780	0.02
282.5731506	0.03
293.1438293	0.29
299.2831116	0.05
311.0242920	0.53
324.3523254	0.04
325.1055298	0.10
328.6240540	0.06
332.1549072	0.06
339.3030090	0.03
340.9615173	0.04
371.4830017	0.03
372.1753845	0.04
373.1330261	0.09
401.4418335	0.01
415.1937561	100.00
417.0314941	0.17
417.9068604	0.04
425.2205200	0.02
433.1213684	0.04
442.5450745	0.10
443.2283020	0.01
445.8955078	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	338.1608
Annotation	Aucherine
Peak:m/z	Relative Intensity
101.8590927	0.15
125.8205719	0.08
128.0246582	42.12
130.2014465	0.07
131.0072021	0.04
137.0908051	0.07
143.4071350	0.08
144.3903503	0.10
146.0759430	3.10
170.0319214	3.02
181.8863983	0.04
209.1742554	25.40
210.5758057	0.12
218.2893677	0.03
222.9125061	0.05
236.0158691	0.03
238.1697693	0.04
249.2043762	0.06
251.1671143	0.04
257.1456604	0.12
265.4812317	0.12
274.9734192	0.15
277.2766113	0.05
282.3747559	0.02
291.8294373	0.10
294.1732788	9.58
295.1193237	0.21
296.2585449	0.14
297.6028748	0.35
302.0834045	0.40
310.2835388	0.21
320.2047119	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1024.616
Annotation	Gordonoside E
Peak:m/z	Relative Intensity
295.2753906	0.47
296.8798828	0.07
308.8654175	1.02
311.2162476	1.49
312.9239807	0.58
321.2124023	0.36
327.3220825	0.59
329.1314087	0.75
339.1744690	0.25
341.4581299	0.79
343.0994568	0.20
351.4179077	0.07
353.1423950	1.38
353.7625427	0.08
355.2206421	1.49
357.0348816	0.88
359.1520386	0.28
371.0056763	0.39
371.6452026	0.16
373.2221069	8.51
375.2914124	0.69
381.4240417	0.24
383.3271790	0.92
395.4020386	0.18
397.1437378	1.32
399.2702637	1.28
401.2338257	1.58
403.2793884	1.08
415.2342529	0.69
415.8724060	0.05
417.1513062	2.90
419.1863403	1.00
439.0998535	0.37
441.2540283	2.10
443.1577148	0.05
445.0884399	0.86
447.2731934	0.10
459.0855103	0.44
460.4050293	0.14
461.2779236	0.19
463.3014221	1.02
467.1605835	0.50
475.0642700	0.18
485.2861328	2.02
487.5302124	0.08
489.0460510	0.57
491.3033142	0.91
503.2774048	0.58
505.1275940	2.00
507.0452271	0.90
523.0288086	0.20
527.1146240	0.06
529.2331543	1.49
533.2418823	0.37
535.4976807	0.05
547.4678955	0.15
549.0577393	1.44
551.2331543	1.03
567.3488770	0.36
573.1909180	1.17
576.9906006	0.41
591.1159668	0.09
593.1998901	2.04
595.4274902	0.23
611.1855469	0.26
617.1512451	0.65
618.6916504	0.38
621.0140381	0.87
631.3229370	0.16
637.2298584	1.66
639.3089600	0.53
655.4308472	0.41
661.3240356	1.13
663.3205566	0.36
665.3977051	0.36
679.1460571	0.04
681.2020874	1.60
683.4647827	0.08
699.1439209	0.39
705.2983398	0.36
707.1989136	0.14
709.0181885	0.13
723.2994385	0.17
725.1610718	2.16
725.7734375	0.04
727.4610596	0.36
742.9384766	0.88
743.5574951	0.65
753.4917603	0.15
769.1567383	0.56
771.6206665	0.74
787.2480469	0.32
797.1848145	0.42
799.5242920	0.42
813.1765137	0.97
813.7944336	0.11
815.6268311	0.28
831.3250732	0.60
857.3868408	1.01
859.3653564	1.89
863.9521484	0.04
873.4377441	0.07
875.3684082	0.36
901.3468018	0.14
902.9195557	2.14
903.5239258	13.20
919.4425049	2.82
944.6162109	0.56
946.8249512	0.16
963.2839355	2.75
963.8850098	0.49
988.1149902	0.18
989.1107178	0.51
1007.3312990	100.00
1008.1081540	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	297.1528
Annotation	Unknow
Peak:m/z	Relative Intensity
93.0979309	0.01
95.2070923	0.02
109.4884033	0.01
119.1330185	0.22
139.3313751	0.01
143.2528534	0.01
156.1882019	0.04
170.0212097	2.87
171.0655670	0.26
171.9675903	0.07
182.9709167	100.00
183.9824524	16.64
184.9822388	0.77
185.9914398	0.07
191.1419983	0.03
194.9828491	0.01
197.0562439	3.55
198.0789185	2.70
199.0978394	0.25
203.2453918	0.04
208.9786682	0.01
211.0826721	1.19
211.9822693	3.08
213.1069641	0.84
214.1632690	0.03
225.0881348	2.05
226.0444336	2.94
227.1181641	0.72
227.8262024	0.02
233.2167053	4.08
234.2862244	1.31
235.4487915	0.02
237.3422852	0.05
239.1378784	1.00
240.1687622	1.84
241.1059570	0.57
242.3843079	0.03
251.3184814	0.05
253.2519836	2.42
254.1838989	1.15
255.1677246	0.22
255.8883057	0.01
260.2700195	0.08
261.9312134	0.33
267.2942505	0.06
268.1809692	0.11
269.2044373	0.02
277.2443542	0.02
279.3272705	1.33
280.3276672	0.21
282.3003540	0.03
295.4109497	0.03
297.2447815	7.34
298.2936707	4.28
299.2777100	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	740.93
Annotation	Unknow
Peak:m/z	Relative Intensity
211.1265259	0.23
216.9830780	0.02
241.1225586	1.67
242.3191223	0.04
242.9929657	0.07
256.9542847	0.15
280.0580444	0.19
282.1542358	0.04
305.0680542	0.06
323.0771484	20.03
324.1154785	8.25
325.1798401	1.57
334.7589722	0.08
352.8401184	0.11
359.1075439	1.02
360.0236816	0.39
361.0319214	0.54
377.1003418	0.79
378.9288940	0.81
417.2745972	0.08
441.1141357	0.81
442.0247803	0.34
443.1428223	0.86
459.0654297	3.69
460.1156006	2.20
461.0755005	1.64
483.2070923	0.47
484.1393433	0.72
485.1162720	0.68
491.1646729	0.07
493.2706909	0.03
494.9685059	2.28
496.0077515	0.58
497.0076294	1.29
498.3436890	0.26
499.0192871	0.56
528.8601074	0.03
560.0659790	0.20
561.2012329	0.41
562.2431030	0.17
564.8926392	0.59
566.0817871	0.56
566.9030151	6.68
572.7209473	0.12
577.0662231	0.43
578.0427246	0.51
584.9515991	0.80
586.1677856	2.31
587.1165771	1.03
603.0963745	70.21
604.1318970	100.00
605.0507202	65.96
605.6842651	0.26
606.3027954	0.03
619.0293579	0.10
620.4378662	0.23
621.1788940	0.22
623.0660400	0.15
636.8054810	0.04
640.5624390	0.09
642.9107666	0.29
652.6732788	0.14
653.3842163	0.26
654.8156128	0.56
656.6693726	19.54
657.2736816	0.18
690.1600952	0.05
695.0397339	0.17
697.0731812	0.20
697.9733276	0.06
721.8862305	1.88
723.0149536	1.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	483.3029
Annotation	Unknow
Peak:m/z	Relative Intensity
161.0444336	0.03
165.0837097	0.40
167.7855835	0.33
177.0492706	0.17
187.5791626	0.11
191.1109772	0.07
194.8062134	0.11
208.8140106	0.53
210.1986084	0.33
212.0209961	0.05
221.1266479	0.69
225.1839600	0.12
227.0900879	0.03
229.3256378	0.42
230.0036774	0.37
237.1640778	0.03
238.2610321	0.02
239.1448822	0.07
245.6189423	0.90
246.3431854	0.03
249.0025940	0.09
251.4812012	0.84
252.7851257	0.19
256.0648804	0.17
263.0152893	0.11
265.1379395	0.53
267.5018311	0.58
268.2331848	0.50
273.7371521	2.35
280.2016602	0.10
282.1762695	0.04
283.0570374	0.11
288.0608826	0.06
289.7138062	4.49
295.4652710	2.08
296.1800537	0.43
296.8576660	0.14
299.2167969	0.84
302.1150513	0.25
303.2546692	0.20
306.9835205	0.07
309.2277222	0.04
311.4854126	2.43
312.2425232	0.99
316.4301758	0.08
317.6400757	0.85
318.2750549	0.09
320.9379272	0.08
325.3502197	0.21
327.1189575	0.14
333.6376038	3.54
334.8482361	0.24
338.1634521	0.15
338.7901917	0.12
339.5768433	0.22
343.1387329	0.05
346.9898987	0.03
352.8652344	0.03
355.5435181	0.53
360.8029785	0.30
361.6555786	0.20
365.2085876	0.05
368.3363953	0.10
376.4186707	0.25
377.4340515	1.00
378.1072083	0.51
381.7113342	0.06
382.9394226	0.13
383.8659363	0.05
385.2435608	0.33
390.4383240	0.21
391.0683899	0.06
395.4322815	0.02
397.4119873	0.11
399.6291199	0.38
400.4530945	0.30
403.1226501	0.04
405.5783997	0.39
409.0777893	0.88
409.7903442	0.22
414.8063660	0.03
417.0502014	0.07
421.6784668	0.42
424.3432617	0.12
430.2881470	0.49
431.3159180	1.18
433.6399841	0.06
436.7042542	0.42
438.3019714	0.25
442.2584839	0.06
447.3751831	0.07
448.3381958	0.03
452.6930237	1.37
453.4289551	0.52
465.3223572	3.13
466.3975525	1.87
468.3981628	0.19
473.1386414	0.04
474.8641052	100.00
476.1608582	1.95
477.2671509	0.73
478.0407410	0.19
479.4282532	0.08
481.2166138	0.11
482.9991150	0.11
484.4893494	0.21
501.7125854	0.10
519.9729614	0.08
520.6730347	0.17
529.4633179	0.04
544.8804321	0.05
547.0346069	0.09
562.1254883	0.03
564.4989624	0.93
565.7796021	0.09
566.4844360	0.13
573.6858521	0.03
590.2772827	0.13
591.4155884	0.03
592.3341064	0.21
596.2097168	0.18
597.3937378	0.12
605.2532959	0.11
608.3549194	0.53
609.4133911	0.66
636.4196167	0.03
640.4106445	0.69
641.5272827	0.26
652.4234619	0.63
653.4650269	0.77
662.3630371	0.17
666.5269165	0.03
667.8187866	0.06
679.3655396	0.11
684.5397339	0.72
685.5193481	0.35
696.5370483	1.08
697.4916382	0.45
700.6694946	0.21
723.1821899	0.13
724.1338501	0.05
726.7029419	0.08
728.3529663	1.89
729.4833374	1.35
738.2222290	0.03
740.4606323	0.14
741.1982422	0.10
741.8273315	0.31
754.7650146	0.10
755.3654785	0.31
772.5335693	0.34
773.4394531	0.67
774.3406982	0.05
784.5963745	0.04
801.9578247	0.06
816.5418091	0.89
817.8374023	0.11
818.9595337	0.17
826.6467285	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2781
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
150.9984131	0.05
153.0323792	0.28
196.0935974	1.50
198.9615631	0.02
214.1479797	1.14
224.9684143	0.05
255.2714539	100.00
256.1459961	0.05
281.3215332	0.12
283.1925659	0.08
356.8013306	0.03
361.4605408	0.11
391.3601379	0.37
404.6753845	0.14
406.3846130	0.13
408.4203796	0.10
414.4687805	0.08
416.1821594	0.02
433.2225647	0.04
434.8800964	0.18
443.2305298	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	338.088
Annotation	6-hydroxyindole-3-carboxylic acd 6-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
113.8972626	4.30
115.0064774	3.19
115.9386063	0.11
119.3344269	0.03
127.2516022	0.03
132.0663910	15.66
133.1269073	1.57
135.1529999	0.14
137.0594788	0.04
137.9573212	0.07
146.0864868	0.05
147.0025330	0.05
148.9723816	0.52
150.1622314	0.04
153.1214905	0.52
154.2623291	0.13
158.1467285	0.16
160.2361603	0.14
164.0845642	3.46
165.0617676	0.84
172.0948486	0.04
174.9764252	0.14
179.0621643	9.17
180.0944672	1.33
183.0459595	0.05
184.1086578	0.06
190.1771851	0.08
192.1203613	0.08
193.2141418	0.03
200.2428131	0.17
205.1410522	0.89
206.1898651	0.47
207.0703888	0.99
208.1757812	0.44
209.0963440	0.23
223.0248718	100.00
224.1650085	23.79
232.2011108	0.13
233.0241699	0.13
235.0112915	0.05
240.1203613	0.36
241.3634644	0.12
242.7626038	0.03
248.0979004	0.71
249.4396362	0.61
250.3124084	1.00
251.2551880	0.11
252.0053711	0.03
254.8876343	0.09
258.1925659	0.31
259.3325806	0.16
261.2335815	0.13
262.2946777	0.10
262.9930115	0.03
268.2973022	0.12
276.1275940	18.29
277.2036133	7.57
278.1543274	0.14
279.6008606	0.09
294.1414185	22.53
295.2427979	6.81
309.5363464	0.03
311.3009644	0.05
320.1255493	6.31
321.2018127	1.00
323.9762268	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	703.3174
Annotation	Unknow
Peak:m/z	Relative Intensity
207.0418091	0.06
225.0045166	0.10
266.2035522	0.04
301.3807068	0.07
315.5853271	0.10
316.3250122	0.04
333.3143921	28.60
334.3818359	6.44
343.1248169	0.09
347.3518677	0.51
348.5184326	0.12
374.0120239	0.06
375.3087769	10.81
376.3649292	2.72
405.3405762	6.97
406.3043823	2.16
417.4549561	0.11
422.1576538	0.09
423.0468140	0.22
424.3615112	0.23
429.2287598	0.20
430.4188232	0.08
435.3186646	10.76
436.4078979	2.14
443.4763184	0.05
447.4099731	0.06
451.1513672	0.03
453.6979980	0.05
460.4069824	0.17
465.3003540	0.03
476.3731689	0.08
477.1315918	0.09
477.8245239	0.11
495.2835693	100.00
496.3806763	19.95
516.3887939	0.03
523.2426758	0.12
524.5217896	0.12
537.2063599	1.38
538.2947998	0.25
541.2286987	15.02
542.1348877	2.50
567.0274048	0.42
567.6483765	0.02
568.3022461	0.03
577.5638428	0.03
579.0912476	0.10
583.9551392	0.06
585.6381836	0.07
589.2524414	0.02
597.0040894	0.69
598.0233765	0.38
609.1317139	0.07
618.3347778	0.08
621.6406250	0.07
629.3495483	0.03
638.4458618	0.02
639.3464966	0.10
642.9310303	0.08
643.6464233	0.04
653.3878784	0.33
657.1071167	20.76
658.1394043	5.63
658.7907104	0.20
659.5405273	0.03
667.2009277	0.11
668.0730591	0.02
676.2916260	0.29
678.2511597	0.04
680.7147827	0.11
686.5290527	0.25
688.0848999	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.2556
Annotation	Unknow
Peak:m/z	Relative Intensity
160.6308136	0.09
164.9197235	0.02
191.2013245	0.02
191.9877777	0.05
222.0192566	0.04
223.0877533	0.02
281.9130554	0.11
294.0411377	0.03
295.5187378	0.06
301.0050964	0.04
311.1478271	0.71
312.0652466	0.34
312.8905640	0.36
317.1136475	0.06
332.9846802	0.04
336.9971313	0.06
341.3792114	0.03
344.8982544	0.09
351.3720093	3.68
352.0116577	0.02
354.1925659	0.11
357.3570557	0.01
367.1400146	0.12
368.4756470	0.05
385.4004517	0.18
386.1652832	0.53
387.1429443	0.30
388.0667114	0.02
398.2491455	0.01
403.4687500	0.14
405.3397217	0.03
416.4462891	0.12
417.5841064	0.01
432.1930542	0.13
433.6195679	0.13
453.1592407	0.04
454.5546875	0.07
459.3654785	0.05
463.2717896	0.27
464.5542603	0.04
465.3555298	0.04
471.3482666	0.02
487.5404663	0.07
502.1119385	0.17
503.3467407	100.00
505.1549683	5.41
505.7824097	0.06
512.2755737	0.09
513.3950806	0.02
517.5832520	0.02
526.7586670	0.03
527.9158936	0.04
530.4328003	0.14
549.2282104	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1816
Annotation	(-)-11-hydroxy-9,10-dihydrojasmonic acid 11-beta-D-glucoside
Peak:m/z	Relative Intensity
113.0389938	0.59
144.0323486	0.23
153.1211243	0.16
155.0387421	0.15
159.0748596	0.09
160.9168854	0.31
165.1116943	1.32
177.1573334	0.15
180.1912537	0.20
180.9072723	0.05
183.0791626	4.71
191.0084229	0.47
198.2320557	0.09
206.3114929	0.07
207.9759827	0.18
209.2024841	2.37
211.2147522	0.09
213.2164612	0.16
225.4901123	0.11
227.1028748	100.00
227.9326477	0.06
237.1455994	0.19
241.1561279	0.19
247.0231628	0.31
249.0718994	0.11
251.2633362	3.07
252.7674866	0.03
261.3532104	0.05
265.2508850	0.48
269.4778137	0.48
276.1138916	0.08
281.4816895	0.21
283.9703369	0.13
287.0616760	0.26
293.1022949	1.18
295.4636536	0.16
299.2286987	0.47
305.1144409	0.17
311.1713562	0.05
312.0664062	0.12
317.3954468	0.14
325.5036011	0.09
327.3329773	0.45
329.2394714	1.66
331.2082214	0.13
342.0148926	1.13
343.2639771	1.22
345.1552734	1.88
346.3654480	0.90
347.1101990	0.42
352.2124634	0.05
353.2638855	2.15
355.0875244	0.07
357.3619385	1.69
358.0473022	0.47
361.2374878	0.15
369.1863708	0.30
370.6155701	2.26
371.4116821	2.62
372.2935181	0.14
373.0436096	0.52
374.1394958	5.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1145
Annotation	Lactulose
Peak:m/z	Relative Intensity
179.9216919	0.04
328.5333252	0.02
341.1632080	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1247
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
158.8949127	0.05
161.0975342	0.06
161.9081573	0.02
173.0052185	0.19
174.0461884	0.04
174.9980011	0.06
179.1560974	0.50
186.9946594	4.85
188.1529541	0.10
191.0910645	1.06
192.1548462	0.04
193.2333984	0.35
199.6192322	0.08
200.9712830	0.08
203.1399841	0.10
205.0961914	5.00
206.0473328	0.25
217.2258301	0.21
218.2967224	0.10
223.1590424	3.30
224.0975494	0.20
232.8856506	0.10
237.2545929	0.03
243.0200500	0.08
247.0969391	0.40
248.3096161	0.05
258.1937256	0.05
261.1886597	0.34
262.1577759	0.08
273.2210083	0.51
287.1959839	0.04
288.1343384	0.16
291.0650635	0.58
305.1155090	0.73
306.2286072	0.17
309.2385864	0.09
319.1478882	0.07
323.2321167	1.07
324.2512207	0.16
328.2306519	0.02
335.0804443	0.81
337.1799316	1.24
349.0969238	0.61
350.2436523	0.11
351.1614380	0.08
353.1539307	1.96
354.0855713	0.10
355.0589600	0.06
357.2470093	0.61
367.1837158	4.85
368.1709595	0.49
381.1353149	3.91
382.3088379	0.40
385.1066895	12.32
386.2117920	0.69
391.3866577	0.05
395.3152466	0.04
399.1113281	100.00
400.1514282	8.06
415.9474487	0.06
417.3402100	0.07
424.3334961	0.08
430.7375488	0.06
432.3893433	0.24
439.5766602	0.05
446.2328491	0.01
454.1006470	0.04
457.1807861	0.04
465.3859253	0.15
466.2259521	0.05
474.0176392	0.03
474.6334229	0.06
475.5187988	0.39
476.5897217	0.12
479.3334961	0.21
482.2987671	0.04
487.2620239	0.06
488.7444458	0.17
490.1610107	0.02
498.7413330	0.05
501.5117798	0.25
502.6016846	0.10
511.0481567	0.49
513.2356567	0.51
514.6953735	0.31
515.3944702	0.74
517.3052979	0.07
519.6068726	0.09
523.4255371	0.03
524.2090454	0.23
525.4188843	0.78
526.2037964	0.07
530.0115356	0.13
541.3283081	0.26
542.9701538	3.56
544.2259521	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	324.1815
Annotation	Awajanomycin
Peak:m/z	Relative Intensity
105.2023468	0.06
112.3487854	0.12
123.0925674	0.22
126.8983917	1.49
128.1136932	0.25
130.0669098	100.00
148.9907837	0.96
149.6351929	0.08
150.9859009	0.05
155.2906799	0.04
164.9876709	0.07
167.0400696	0.09
172.2196808	0.55
177.0220184	0.35
178.0363312	0.06
181.1126709	0.26
183.1600647	0.18
184.1673584	1.77
193.1621246	2.36
196.2056885	0.87
203.0284119	0.11
204.0321045	0.16
214.0046997	0.13
218.2212219	0.57
236.2677002	32.78
242.2898254	0.12
245.2103271	0.09
249.4912109	0.12
251.5286560	0.13
256.3376465	0.42
261.1431885	0.06
262.2507019	1.43
263.2041016	0.06
264.2855225	0.05
278.1863403	1.20
279.2514648	0.62
280.2727051	4.85
281.0740356	0.13
283.6307983	0.30
284.2399292	0.24
287.9789734	0.75
289.4387817	0.15
295.8456421	0.17
305.3194580	0.41
306.2526855	2.65
307.0353088	0.42
309.1088867	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.3392
Annotation	Unknow
Peak:m/z	Relative Intensity
155.1285248	0.04
175.0988312	0.08
177.1853943	0.38
191.1297607	0.05
199.1263733	1.45
207.6510468	1.08
209.2037964	0.99
210.3281097	0.11
221.1629181	2.22
223.1528320	0.17
223.9036407	0.12
225.1899414	0.85
226.5279236	0.35
227.4420776	0.07
228.4879913	0.06
229.5302277	0.31
230.2674561	0.03
233.0392761	0.10
235.1225891	0.54
238.1658020	0.04
242.9768066	1.29
243.5945129	0.28
246.9878540	0.03
248.9986420	0.27
251.5967560	4.68
253.2247314	0.17
256.2351685	0.12
261.3657227	0.06
263.2290649	0.09
265.1939087	0.27
266.1757812	0.03
267.2975464	0.03
268.4865723	0.27
269.1807861	0.94
270.1186523	0.11
271.3828735	0.29
272.5743408	0.11
273.6367798	2.16
278.7843018	0.14
280.2273254	0.09
290.0328979	0.54
292.7811890	0.03
295.4347534	6.05
296.0675659	0.29
300.8649902	0.09
305.7982788	1.57
308.0346069	0.04
309.0302734	0.47
311.2717285	0.54
311.9711304	0.19
313.2220459	0.71
315.4243164	0.11
317.1141968	0.23
318.1370850	0.62
321.2786865	0.20
322.1370239	0.07
327.5717773	1.24
328.2822266	0.33
329.0003052	0.25
329.6373901	0.25
331.0775757	0.68
333.5308838	0.10
339.6051025	2.74
340.2952881	0.15
341.5867920	0.21
344.1694336	0.05
349.8082886	4.97
350.7160645	0.44
353.2280884	0.15
354.9802246	0.09
355.8974609	0.12
359.3057861	0.19
361.4610596	0.67
362.4214478	0.12
363.2125854	0.13
364.0215454	0.14
370.5618896	0.27
371.4767456	3.67
372.1348267	1.42
373.3311768	0.89
374.8211060	0.16
383.6449585	2.12
385.7297363	0.13
393.4920044	2.70
394.3710327	0.31
397.1213379	0.27
399.5905151	0.18
407.2296753	0.04
408.1801147	0.32
411.5523071	0.11
416.4218140	0.24
417.2963867	0.32
418.2122192	0.11
419.2734375	0.06
419.9877319	0.24
422.2119751	0.08
430.8527222	5.98
431.5909424	1.01
432.4536133	0.29
433.2993774	0.21
434.0907593	0.24
436.0480957	0.05
437.4147339	0.68
438.1286621	0.61
439.3635254	0.18
441.2271118	0.13
442.4277344	0.08
443.8026123	0.44
453.3632202	0.25
459.1931152	0.29
469.2149658	0.15
473.8254395	0.15
474.6242065	0.22
475.2402954	0.30
476.5187378	0.14
481.7005005	2.36
482.9046631	100.00
483.9584961	2.69
485.2548218	1.36
486.6536255	0.68
487.3628540	0.08
489.0626831	0.04
490.2911377	0.27
490.9107056	0.52
492.3953247	0.18
493.1989746	0.08
493.8511353	0.44
494.6037598	0.31
496.2515869	0.72
497.5234985	0.15
499.4830933	0.07
501.3834839	0.22
504.3756714	0.18
505.2726440	0.30
507.1605835	0.08
512.5028687	0.21
515.5550537	0.04
516.1925659	0.08
520.2745972	0.85
525.6087646	2.38
526.3378906	1.48
527.1619263	0.04
528.3115845	0.27
529.1475220	0.07
534.7435303	19.41
535.6767578	0.02
536.7719116	0.39
537.7688599	0.57
539.8073730	0.16
542.0540771	0.13
547.0912476	0.12
550.2241821	0.23
564.2413940	2.18
564.8514404	0.05
565.5883179	0.30
592.9452515	0.09
608.4293823	3.20
609.4251709	0.40
634.3344116	0.07
635.4463501	0.57
636.2314453	0.16
637.1956787	0.11
640.4418335	0.23
652.4009399	2.86
653.3787231	0.60
656.2648315	0.04
662.4765015	0.08
672.8851929	0.03
680.1968994	0.15
681.3191528	0.05
687.4695435	0.19
694.5197144	0.07
696.3050537	0.69
698.8538208	0.10
699.6624756	0.13
700.3668213	0.06
711.2359009	0.06
716.1941528	0.42
717.3255005	0.09
723.3566895	0.16
726.5703735	0.22
738.4840698	0.07
739.8553467	0.32
740.6544189	0.72
741.5591431	0.49
743.0465698	0.08
744.4815063	0.21
758.8212280	0.10
760.2846680	0.67
761.7294312	0.02
770.0302124	0.09
770.6307983	0.10
772.4306030	0.46
773.5784302	0.10
789.5089722	0.12
798.7252808	0.06
804.5571899	0.47
843.2064819	0.60
844.0231934	0.05
848.2995605	1.14
849.1274414	0.21
849.7470093	0.26
850.5800781	0.26
859.7626343	1.07
860.6171265	3.92
861.6721191	1.73
876.0436401	0.11
877.3613892	0.42
886.4364624	0.07
887.5618286	0.08
892.5501099	1.35
893.4445801	0.58
920.5935669	0.06
921.2880859	0.14
936.6946411	0.21
937.3517456	0.26
938.9951782	0.14
947.3996582	1.24
948.5414429	0.11
964.5039062	44.04
965.5971680	20.55
966.8752441	0.03
1069.2344970	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1
Annotation	3,5-Dihydroxy-6,7,8,3',4'-pentamethoxyflavone
Peak:m/z	Relative Intensity
187.8132782	0.14
191.9084473	0.05
199.4619446	0.19
202.2462158	0.16
204.7488251	0.09
213.1974792	0.06
215.2714691	0.47
219.0776062	0.25
233.2798767	0.25
235.5764465	0.05
245.0018311	0.06
246.1651611	0.52
247.7715149	0.19
253.3949585	0.08
255.3600769	0.18
261.7594604	0.19
265.4194031	0.31
271.2992554	0.15
276.9736023	0.24
285.3869324	0.20
288.9647522	0.41
296.8043213	0.13
307.1351624	0.05
311.2446899	0.49
312.1900635	0.14
313.3388062	0.70
314.9545898	0.40
317.0014648	0.49
325.3627319	0.34
329.1503906	0.56
339.3298035	0.74
341.3362427	0.27
343.0960999	0.25
345.1245117	0.35
349.2406616	0.06
352.1092529	0.18
356.1439514	19.96
357.3750305	5.49
359.1474915	0.77
365.3665771	0.64
366.4770813	0.71
367.6390381	0.58
368.4290161	0.06
369.6008606	0.13
371.1753540	26.62
372.0112610	0.21
373.5081177	0.47
374.5726624	0.22
376.8179016	0.21
382.3303223	0.07
383.3499451	0.05
385.1987000	2.92
388.2487488	100.00
389.2263489	0.73
395.2114563	0.22
397.0701599	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	380.2423
Annotation	Ro 09-1543
Peak:m/z	Relative Intensity
133.2953644	0.04
169.0305786	0.03
183.1614685	0.02
247.1112366	0.01
256.4515381	0.01
288.9070129	0.03
292.4636230	0.01
300.8505859	0.09
302.4270020	0.04
303.2602844	0.04
306.2431641	0.02
308.1831055	0.02
316.2789001	0.02
317.1593018	0.05
319.2758789	0.02
321.1119995	0.05
325.2683716	0.01
326.2064209	0.10
335.5671387	0.02
338.9880981	0.03
343.3540649	0.03
344.3010864	0.32
349.7745056	0.02
362.3152161	100.00
362.9495850	0.29
366.1699524	0.02
371.3475037	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1087
Annotation	Forsythide
Peak:m/z	Relative Intensity
137.0782166	0.15
140.0738525	0.03
149.0504456	0.27
150.0064392	0.32
151.0771942	0.52
152.7440491	0.23
158.0033264	0.16
165.0920105	0.76
166.0101318	1.20
166.9781494	0.20
167.9967346	2.27
175.1392212	0.07
176.9706116	0.12
181.0870361	2.44
181.9920654	0.25
182.9797516	0.45
185.2572632	0.03
189.2084351	0.03
193.1906738	0.13
194.0245361	1.55
195.1689606	0.05
207.1380005	0.16
209.0493317	8.66
212.0850525	29.17
213.0075226	0.04
224.1879883	0.04
225.1450806	0.31
227.0516663	100.00
228.1111145	0.06
235.8415833	0.05
249.0160828	0.05
251.4651794	0.05
254.1511841	0.60
265.1585083	0.02
269.0813599	1.90
272.9984741	0.03
279.3332214	0.08
295.2217102	0.05
302.1451416	0.06
305.2690430	0.05
317.3014832	0.20
330.1328125	0.08
344.3397217	0.16
345.1650696	0.14
361.3025208	0.12
370.1551208	0.07
371.0596924	0.51
374.2127075	3.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	270.9918
Annotation	(Z)-4-(2-Hydroxy-5-sulfonatophenyl)-2-oxo-3-butenoate
Peak:m/z	Relative Intensity
113.0424805	0.02
129.8898163	0.03
133.0152740	0.03
138.0907745	0.01
147.2838593	0.02
151.0504303	0.15
161.1880341	0.04
163.9600067	0.05
175.9151764	0.17
191.0037079	100.00
191.7595062	0.01
199.0486450	0.02
202.9777679	0.05
205.0715179	0.01
208.3690948	0.01
209.1455841	0.17
210.2110901	0.04
211.1074371	0.04
224.4016113	0.04
225.1995239	0.04
226.1392365	0.12
227.0613251	0.14
228.1288605	0.01
235.2424927	0.03
243.0460358	0.03
244.2332611	0.09
252.1144409	0.06
253.2012482	0.45
255.3327179	0.10
256.2486267	0.11
270.8303528	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.7661
Annotation	Unknow
Peak:m/z	Relative Intensity
211.0359650	0.13
212.9310303	0.46
296.8145447	19.45
303.0265503	0.44
323.1671753	3.91
325.0416870	0.10
335.2120972	0.16
345.1215210	0.40
378.0662231	0.07
380.6088867	73.38
381.3422241	0.11
386.7291870	1.55
400.4786377	0.12
403.3875732	0.06
404.9187012	0.17
421.0441284	0.24
428.7167358	1.14
442.7814331	0.13
446.8814697	0.26
450.8866577	0.09
456.7362671	0.12
457.8187866	0.16
458.7417603	0.54
462.4145508	0.83
463.9636230	18.35
464.6169434	100.00
465.4899292	0.20
476.6882935	0.34
484.8840942	0.22
488.7273560	1.76
501.7759399	0.29
503.0569458	0.31
518.5389404	0.08
531.8661499	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	406.21
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
119.0541840	0.06
120.7327347	0.25
131.1640320	0.60
134.8029480	0.10
135.9119568	0.26
145.0060272	0.76
147.2997742	0.25
149.0812836	0.08
162.3315277	0.10
165.0780640	0.08
167.0477753	0.44
177.1145935	0.21
179.1510315	0.45
180.2263794	0.27
181.3214722	0.14
182.3637543	0.13
191.1501770	3.24
204.8663635	0.25
207.0293427	1.70
207.9457092	0.42
209.1228180	42.20
223.0086365	0.10
224.8275757	5.45
226.3339386	8.20
227.1452026	100.00
241.9271240	0.28
243.1966248	1.13
244.0819092	0.38
247.0355835	0.17
255.1617737	0.46
259.1519470	8.95
266.9347229	0.21
274.7820435	0.23
277.0863342	2.08
280.7921753	0.10
285.1905518	1.55
294.2494202	3.07
294.8608398	0.25
298.9911194	0.38
299.9953003	0.18
301.3765869	0.09
308.0090027	0.08
309.5797729	0.32
313.1782227	0.97
316.2119751	4.49
325.1189575	4.34
327.3962402	0.50
331.2192993	0.42
333.8093872	0.18
346.8129578	0.27
352.2456970	0.19
356.1573486	0.37
360.0820618	0.50
360.9463806	0.28
362.3124084	0.27
368.2213440	0.42
370.3058777	1.13
374.4828796	0.06
375.3114319	0.20
376.3498840	0.10
377.6165466	0.19
386.2347412	0.36
387.5317993	2.56
388.2312317	6.44
388.8968811	21.03
392.2244263	0.14
396.5544128	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.3776
Annotation	Unknow
Peak:m/z	Relative Intensity
181.1952057	0.02
185.4818573	0.09
191.1761627	0.11
194.0703125	0.03
199.2436066	0.14
207.7396088	0.28
209.1524048	0.23
211.0302734	0.07
219.3002319	0.20
221.1248322	0.90
222.0560760	0.17
223.6987915	0.03
225.1102905	0.19
229.5597229	1.35
230.2006531	0.17
238.3967743	0.21
239.1679993	0.14
240.2868042	0.07
243.0366058	0.12
245.0731506	0.02
249.3225708	0.13
250.8281250	0.23
251.5393677	1.81
252.2232361	0.04
255.7668457	0.25
256.5877075	0.04
264.9973145	0.34
266.0228882	0.07
267.0450439	0.27
269.2687073	0.92
271.3160706	0.07
272.4446106	0.09
273.5355225	1.56
274.2176514	0.06
275.8476562	0.22
277.8262329	0.14
278.9902344	0.05
281.0882568	0.15
282.3627625	0.10
283.0736084	0.04
289.7249146	0.04
295.4261475	1.94
296.1098022	0.31
297.4631958	0.43
298.3044434	0.06
299.2265015	0.13
301.5575562	0.03
306.7651062	0.04
309.0946350	0.24
311.4243164	0.31
313.0962219	0.42
314.9757080	0.11
316.9415894	0.06
317.6570740	1.27
319.5270996	0.68
320.7299805	0.10
321.4591064	0.09
323.3701782	0.05
326.3562622	0.03
327.5485229	0.09
328.5765991	0.04
337.1488647	0.05
339.2838135	0.58
341.7857666	1.26
342.5133057	0.05
348.3202515	0.03
349.6430664	1.29
350.2968750	0.13
351.3005981	0.04
353.3500366	0.12
355.2678223	1.15
357.0039062	0.24
360.5762939	0.09
361.9406738	0.14
363.8286133	0.79
364.4424438	0.02
371.7887573	2.17
373.1356812	0.88
373.9673462	0.22
375.4591675	0.06
376.7062988	0.05
383.5047607	0.43
385.3903809	0.48
386.2883911	0.33
392.4776611	0.03
393.6766357	1.51
394.3432007	0.03
395.1825562	0.17
396.7789307	0.10
401.1860962	0.36
402.3540649	0.04
403.3904419	0.07
405.8157959	0.24
407.4837646	0.48
415.6273193	2.01
417.0133667	0.54
418.3790894	0.19
419.4112549	0.08
427.8419189	0.58
429.6837158	0.42
434.8851929	0.21
436.0804443	0.11
436.7178345	0.15
437.8591309	0.60
439.0728760	0.13
441.2274780	0.59
445.3109131	0.29
446.2872314	0.04
449.5186768	0.24
451.9223633	0.26
452.5942993	0.36
453.2318115	0.27
454.0870972	0.07
459.9542236	0.28
460.9668579	0.05
461.8592529	0.04
463.8117676	0.04
473.2302246	0.26
474.0244141	0.03
476.5147705	0.14
477.6004639	0.03
481.5374756	0.38
482.2793579	0.11
488.8671875	0.35
489.5524902	0.03
494.6204224	0.07
496.7171021	6.56
497.3416138	2.76
498.0076294	0.10
502.6621704	0.30
503.3185425	0.33
504.7133179	0.45
505.4019165	0.45
506.1965942	0.02
507.3934326	0.03
508.1635132	0.27
516.0177002	0.11
517.8926392	0.11
520.3769531	0.24
524.4024048	0.10
525.6405640	0.23
526.8217163	0.90
527.5454712	0.18
529.3507690	0.09
532.7797852	0.07
533.4806519	0.07
540.4597778	1.29
541.5581665	0.03
547.0140381	0.16
548.9479370	100.00
550.4937744	1.31
551.8828735	0.39
552.6283569	0.16
553.6672974	0.21
554.9356079	0.04
555.9607544	0.06
556.7439575	0.73
557.9328003	0.06
558.5737915	0.06
564.4304810	0.05
565.4364014	0.34
571.3045044	0.07
573.5394897	0.04
576.6246948	0.20
577.2957153	0.08
578.6667480	0.96
579.3145752	0.51
584.4605103	0.19
591.3967896	0.79
592.3599854	0.94
593.1891479	0.43
595.1007690	0.08
599.6656494	0.10
600.9096069	0.82
618.0999146	0.05
621.0479126	0.27
622.4581909	0.04
629.5059204	0.07
635.2896118	0.17
636.5817871	0.20
637.2055054	0.30
638.2425537	0.08
649.3231812	0.05
652.4098511	1.45
653.2028198	0.39
653.9009399	0.05
659.2033691	0.08
661.4598389	0.07
673.5801392	0.06
679.1119995	0.35
680.9174805	0.18
682.2294922	0.09
696.4870605	2.19
697.5391235	0.70
705.2768555	0.14
710.9768066	0.10
712.3921509	0.03
722.7781372	0.02
723.5229492	0.09
728.6243286	0.08
729.4921875	0.02
740.4926758	1.42
741.5778198	0.15
745.4507446	0.38
748.7867432	0.11
750.1412964	0.11
760.1359863	0.06
767.4838257	0.05
772.2343140	0.22
782.6762695	0.05
784.4728394	0.99
785.4782104	0.49
786.5715332	0.13
788.6742554	0.86
797.8983765	0.05
799.4802856	0.04
805.5531616	0.42
810.6268921	0.02
828.6268921	0.67
830.0863037	0.10
831.2717896	0.13
832.5259399	0.47
833.6801758	0.24
848.2775269	0.30
849.5493164	0.16
857.4672852	0.18
859.2329102	0.28
872.7417603	0.25
876.4943237	0.19
877.6020508	0.17
892.6878052	0.50
893.7029419	0.50
902.3701172	0.11
904.6123657	0.13
919.1976929	0.08
920.5336304	0.32
921.7177124	0.10
934.3501587	0.04
936.4484863	0.92
937.4363403	0.47
964.2732544	0.14
965.6569214	0.02
976.5275269	0.04
980.5289917	0.64
981.5747070	0.30
988.7660522	0.07
992.5661011	1.67
993.6256714	0.54
1007.5612790	0.05
1008.5827640	0.03
1009.7333980	0.04
1024.4621580	0.92
1025.6373290	0.34
1052.5356450	0.04
1053.4726560	0.05
1068.7357180	0.17
1069.3775630	0.04
1079.3631590	0.35
1080.3920900	0.02
1096.4996340	8.80
1097.6643070	5.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	296.88
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9536438	100.00
206.2644043	0.04
211.1608582	0.06
212.7558594	40.82
213.3580933	0.36
253.2326355	0.05
278.8018494	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0712
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
139.0433807	0.94
144.903717	0.82
146.1260834	0.82
149.0460052	1.14
150.1110535	2.34
161.910965	1.26
164.0735626	0.43
167.3771515	0.29
168.8537598	1.98
175.0070648	0.33
177.8857727	0.79
179.0904999	0.76
180.1401672	4.43
182.1722717	3.00
183.2223358	5.99
184.0481873	1.68
186.0762939	0.48
193.2288666	1.53
194.0311127	3.74
195.1773224	0.78
196.0731964	0.90
206.1569366	0.66
206.9812927	3.30
207.9975433	13.44
209.1950989	5.73
216.0538635	3.12
217.0453186	1.48
222.1454926	4.29
223.2441254	12.81
224.2350769	12.12
225.3785553	0.34
232.0783539	0.55
233.067337	0.20
234.3041382	0.62
249.0847778	4.93
251.0632935	68.24
252.1131744	100.00
253.1987305	2.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	925.1678
Annotation	Unknow
Peak:m/z	Relative Intensity
311.2127075	0.04
329.1792603	0.01
341.0634766	0.06
355.0688477	0.24
363.3448486	0.04
373.9358521	0.02
388.8715820	0.03
404.1856689	0.01
405.3561707	0.01
407.5777588	0.01
408.2677612	0.01
409.4779053	0.06
419.2990723	0.09
420.4180908	0.05
421.5114746	0.17
422.3298340	0.04
432.3489380	0.02
433.1247559	0.24
434.3703613	0.03
449.2122192	0.13
450.3712769	0.03
451.1649170	0.04
460.6682129	0.05
461.4773560	0.01
462.1964111	0.04
503.1636353	0.02
517.3223267	0.04
535.3676758	0.01
555.8417358	0.11
569.3646851	0.19
570.5563965	0.06
582.1665649	0.04
583.1589966	2.07
584.2938843	0.55
587.1185303	0.03
588.5817261	0.02
595.1640015	0.29
599.6143188	0.03
601.1551514	17.72
602.2739868	6.48
611.2168579	0.03
612.4340210	0.02
613.2061768	0.11
614.3628540	0.07
623.4187622	0.01
625.1207886	0.13
626.3900757	0.04
627.3281250	0.10
628.0623169	0.02
637.4411011	0.07
641.1834106	0.20
643.1199341	0.45
644.4396362	0.11
652.9784546	0.07
653.6389771	0.02
662.4695435	0.02
665.1357422	0.02
673.1761475	0.07
685.1281128	0.03
718.8268433	0.06
745.2413940	1.68
746.1835327	0.50
749.6279907	0.01
758.1516113	0.02
763.2087402	100.00
764.2951660	33.11
765.3508911	0.03
771.6583862	0.02
773.1608887	0.36
774.2382202	0.10
775.1069946	0.13
789.2623901	0.22
790.3938599	0.10
796.6054077	0.03
803.1238403	0.15
804.9989624	0.32
806.1928711	0.05
815.4592896	0.12
836.6442261	0.03
844.2524414	0.09
848.2023315	0.05
889.2730103	0.07
907.1287842	0.13
907.9202881	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	642.9714
Annotation	Unknow
Peak:m/z	Relative Intensity
212.9696655	0.08
271.8169556	0.03
289.1661682	0.21
319.0822754	2.18
326.9382935	0.03
332.9085083	0.10
335.5170288	0.11
336.2691040	0.03
337.3875732	0.05
344.8706665	0.02
350.9375610	0.13
358.2084351	0.02
369.2355957	0.02
371.2089844	0.19
383.1845703	0.06
398.8342285	0.19
401.0584717	35.66
429.4321899	0.04
434.7589111	0.08
437.9679565	0.16
444.2066650	0.02
450.4951172	0.08
451.6523438	0.02
463.0980225	0.25
468.8637695	12.19
469.6156616	0.14
472.5993042	0.03
475.3599854	0.14
478.8067017	0.03
481.0093994	100.00
484.9178467	0.02
486.6930542	0.10
487.7528076	0.02
488.4065552	0.08
490.6622925	0.08
496.2417603	0.12
497.7791748	0.11
506.9345703	3.44
507.5816040	0.13
513.0892334	0.11
531.0949097	0.02
542.6539307	0.01
544.0458374	0.10
545.1436157	0.35
551.1364136	0.10
555.1253662	0.03
556.5523071	0.30
558.7023926	1.37
561.0390625	0.03
563.7013550	0.20
564.3251343	0.02
564.9644165	0.09
566.4613647	0.13
568.0172119	0.16
595.9025269	0.21
596.8327637	0.32
599.0346069	0.10
599.8916626	0.03
619.4076538	0.12
624.8909302	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	518.18
Annotation	Unknow
Peak:m/z	Relative Intensity
149.2572632	0.13
161.9815063	1.33
166.9820557	0.26
179.0211639	5.14
181.1745911	0.49
192.8725891	0.07
199.2177429	0.14
211.0779114	6.71
213.0969238	0.03
215.3077087	0.24
233.0880890	1.72
245.1707916	0.21
260.9757690	0.05
268.9275513	0.27
278.2420044	0.20
286.0936890	0.23
288.7857971	0.11
290.2052002	0.28
291.1509399	0.40
302.1749268	0.27
305.9592896	0.08
308.0788574	100.00
314.1314697	0.11
318.3132324	0.22
338.8475342	0.20
355.2880249	0.22
356.3054810	0.67
371.2594604	0.26
373.2012939	0.12
376.7615967	0.07
384.2442627	0.27
385.2908325	0.20
388.8725586	3.51
399.2204590	0.31
412.1301270	0.09
415.3544922	0.04
429.0212402	0.04
430.5648193	0.07
432.2775269	0.15
442.5120239	0.10
443.1389160	1.79
447.8414917	0.10
457.3139648	0.27
474.9320068	0.59
500.0804443	1.12
501.1127319	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	787.82
Annotation	Unknow
Peak:m/z	Relative Intensity
252.8290100	0.02
271.0061035	0.06
272.9811707	0.01
295.1576233	0.02
357.0217285	0.02
383.6260376	0.02
457.9737549	0.01
487.2276611	0.03
524.3239136	0.04
556.3620605	0.01
572.0808716	0.02
590.5864258	0.01
591.8831177	0.04
596.7132568	0.07
598.5878296	0.08
602.3618164	0.28
607.4655762	0.02
611.2859497	0.03
616.3303223	0.03
620.5288696	0.03
650.6654663	0.08
669.2289429	0.03
691.5261230	0.04
693.4195557	0.02
705.3279419	0.01
709.4841919	0.01
711.3098755	0.21
713.4990845	0.08
714.5120239	0.03
719.4832153	0.02
727.2975464	0.38
737.3775024	0.11
751.3127441	0.08
751.9810181	0.02
752.6213989	0.01
755.3449707	100.00
756.4317627	2.07
759.4442139	0.31
769.4738770	0.06
770.3320923	0.05
771.2406616	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1159.515
Annotation	Unknow
Peak:m/z	Relative Intensity
352.3359680	0.79
355.1741028	0.23
362.7500305	0.58
387.2484741	0.38
392.2328491	1.98
394.1448975	0.16
396.4350586	0.40
398.9927368	0.56
408.9965820	0.26
425.4316101	0.44
427.0412292	0.29
441.3930054	0.36
443.0928955	0.07
454.4661865	0.43
462.6004028	0.13
467.2513428	0.10
471.1593018	0.39
473.3534241	0.18
477.3973389	0.55
505.4371338	0.26
510.2241211	0.93
511.3858337	0.49
513.6257935	0.20
519.4245605	0.21
522.1245728	0.57
528.3073120	0.24
557.4814453	0.18
560.3111572	0.38
562.5097656	0.08
564.4844971	0.51
574.3195801	0.18
576.3920898	0.67
592.3990479	1.86
593.0324097	0.39
599.5645752	0.11
604.6267090	0.55
627.1049805	0.47
633.0220947	0.19
645.1921387	0.32
661.4002686	0.10
673.5690308	1.06
674.4113770	0.74
684.4608765	0.18
686.4725342	0.10
690.7886963	0.52
691.4140625	0.28
705.2344971	0.44
709.0872803	0.67
727.3214111	0.53
737.2975464	0.30
738.2517090	1.18
749.7131348	0.10
775.7785034	0.25
786.6941528	0.08
817.2722168	0.91
843.6363525	0.17
859.6265869	0.11
907.5168457	0.17
913.6287842	1.01
916.1551514	0.08
919.9249268	0.08
925.3898926	0.27
949.8211670	0.08
964.5782471	0.12
979.2076416	0.67
991.1519775	1.20
997.5075684	0.22
999.7785645	0.29
1004.2862550	2.20
1006.0985110	0.38
1016.9638670	1.28
1020.0461430	0.95
1020.8785400	0.45
1021.9104000	2.14
1025.0439450	1.12
1029.2395020	1.04
1031.8679200	0.58
1033.5888670	1.43
1034.5963130	1.51
1035.7446290	1.62
1036.6385500	0.64
1037.3013920	2.69
1038.0642090	1.13
1039.5897220	1.05
1041.7875980	6.12
1042.4317630	0.66
1043.1070560	0.18
1044.5577390	0.99
1045.6906740	2.90
1046.4724120	0.63
1050.6119380	0.80
1051.6910400	1.65
1052.8203120	0.70
1054.1661380	0.84
1054.8195800	0.23
1056.0543210	3.23
1057.4189450	0.11
1058.0793460	2.86
1058.7587890	0.44
1059.6333010	1.49
1060.5541990	1.51
1061.7932130	0.77
1062.6539310	0.48
1064.4493410	1.33
1065.6297610	19.55
1066.4818120	0.41
1067.7691650	0.56
1069.2883300	1.61
1070.8288570	0.43
1072.2248540	0.08
1073.9196780	2.97
1075.4105220	3.71
1076.3881840	1.01
1077.3149410	1.36
1078.3236080	0.57
1079.2171630	2.04
1082.0219730	7.36
1082.7679440	1.88
1083.7369380	3.75
1086.0023190	1.90
1088.8453370	2.50
1089.6403810	6.96
1090.3468020	0.10
1091.5517580	1.16
1093.7205810	5.21
1094.3920900	5.73
1095.2321780	1.35
1096.1643070	0.51
1097.5379640	6.98
1098.7773440	5.08
1099.4084470	3.27
1100.1611330	0.93
1100.9312740	1.45
1101.6741940	0.92
1102.9173580	12.00
1103.5947270	30.92
1104.3377690	0.55
1105.6677250	16.11
1106.3834230	1.86
1107.7248540	1.09
1108.5799560	2.66
1109.6296390	0.81
1110.7124020	0.86
1111.7780760	1.07
1112.9945070	0.23
1115.4565430	5.17
1116.4873050	3.07
1118.0932620	4.80
1119.2683110	0.84
1121.2628170	13.70
1122.3920900	15.45
1123.1149900	1.38
1124.5716550	2.03
1126.4769290	2.29
1127.1452640	73.98
1128.7551270	4.15
1130.1472170	9.58
1130.9820560	4.66
1133.0097660	13.23
1133.9909670	1.26
1134.8709720	0.43
1135.9409180	1.94
1136.6065670	3.35
1138.6879880	100.00
1139.4003910	20.21
1140.6938480	3.44
1141.6435550	1.00
1142.6733400	1.75
1144.9187010	4.95
1145.5722660	1.55
1146.1813960	0.09
1147.9248050	0.37
1169.9277340	0.55
1177.0800780	0.30
1185.2788090	0.69
1186.8228760	0.35
1192.7952880	0.55
1197.7680660	1.26
1200.5271000	0.84
1212.1689450	0.69
1212.9024660	1.06
1216.8468020	0.77
1218.1414790	0.62
1219.0515140	0.43
1226.8076170	0.42
1233.7304690	3.03
1234.8399660	1.92
1238.2197270	0.13
1241.4434810	0.44
1243.2081300	0.23
1245.2064210	1.43
1247.2221680	0.54
1250.6157230	5.31
1252.8044430	2.47
1261.7679440	0.48
1265.9243160	1.27
1266.5671390	0.82
1267.7874760	0.72
1269.2105710	0.40
1273.7664790	0.75
1274.3835450	0.61
1275.6242680	0.40
1276.9488530	0.51
1277.8142090	1.02
1283.2089840	7.88
1284.2209470	0.65
1289.6423340	0.28
1291.5279540	0.81
1296.7114260	0.45
1297.4111330	0.09
1301.4179690	0.43
1302.2822270	1.10
1305.1716310	0.40
1305.9670410	0.55
1307.3012700	0.60
1309.9580080	0.78
1310.6896970	0.34
1312.4023440	3.12
1313.5268550	0.69
1317.1942140	0.74
1319.8726810	0.74
1323.6800540	0.70
1329.8389890	0.27
1331.1837160	1.44
1338.1422120	0.11
1339.2084960	0.69
1345.2757570	2.70
1345.9708250	1.29
1346.7581790	0.39
1348.3878170	0.77
1351.3140870	0.46
1352.0249020	0.40
1354.1535640	1.93
1358.6640620	4.14
1359.3997800	1.86
1362.0941160	19.97
1362.8367920	2.59
1372.7805180	0.65
1375.6282960	0.23
1379.1082760	0.33
1381.2401120	0.65
1382.2991940	0.24
1383.2131350	0.45
1384.4644780	1.22
1385.5753170	0.57
1386.7199710	0.52
1387.5839840	0.19
1394.0482180	3.20
1395.0545650	0.76
1399.1282960	1.05
1399.7468260	0.15
1401.8699950	5.49
1402.6022950	1.80
1405.0756840	0.09
1408.0628660	0.85
1409.0216060	0.83
1418.5327150	0.42
1420.1451420	1.04
1421.4091800	0.63
1426.3746340	0.33
1428.5019530	1.24
1429.2630620	1.50
1430.8371580	1.13
1433.0736080	0.50
1434.9071040	2.83
1435.6197510	1.36
1436.9759520	1.83
1438.0627440	3.65
1438.7069090	0.45
1440.9241940	0.20
1442.3111570	0.73
1443.6636960	15.53
1444.2926030	7.04
1444.9117430	0.86
1445.8317870	1.02
1447.9526370	1.08
1449.3154300	0.49
1450.3176270	1.03
1451.0440670	0.40
1452.3970950	0.76
1456.5926510	0.48
1459.2177730	1.69
1460.8582760	0.35
1462.0551760	0.47
1464.4388430	0.27
1465.9166260	0.23
1470.1901860	0.71
1472.9345700	4.29
1473.8356930	1.48
1476.1837160	0.33
1478.0714110	2.12
1479.3304440	0.70
1479.9406740	0.71
1482.5689700	0.47
1484.5679930	0.82
1487.0306400	20.31
1487.9807130	14.85
1488.7839360	0.26
1490.4429930	1.09
1492.5286870	2.03
1494.1878660	3.64
1494.9689940	0.52
1496.6341550	1.31
1505.5859380	7.05
1506.5225830	0.36
1507.5428470	0.85
1512.4471440	0.65
1513.4873050	0.46
1521.5750730	2.26
1522.8681640	2.15
1526.8898930	0.70
1529.4763180	1.71
1530.2258300	0.48
1531.0626220	2.94
1532.2878420	3.55
1533.2349850	1.22
1534.3251950	0.53
1535.3101810	2.95
1536.0220950	3.14
1539.6159670	0.20
1542.5119630	1.92
1543.7015380	26.73
1544.5346680	11.23
1548.4831540	0.49
1549.1817630	0.56
1549.8571780	0.25
1553.1436770	1.65
1554.1374510	1.46
1555.8626710	1.16
1557.0958250	0.24
1558.7445070	0.57
1561.8363040	9.63
1562.9128420	7.83
1563.7639160	0.08
1566.4027100	1.93
1567.6158450	4.04
1568.5449220	1.13
1570.4344480	0.53
1572.4346920	0.32
1573.2418210	0.45
1576.7447510	0.58
1577.9671630	0.77
1579.9271240	0.85
1582.4727780	0.63
1585.1458740	10.95
1585.9909670	2.78
1586.9843750	1.60
1588.1254880	0.88
1589.9768070	2.47
1591.1289060	0.69
1592.1507570	0.79
1597.6715090	9.81
1598.5941160	4.85
1602.5520020	2.26
1603.9132080	0.49
1604.6674800	0.56
1605.7578120	0.53
1606.5225830	0.66
1607.8912350	0.99
1608.6927490	2.40
1609.6219480	0.16
1615.7757570	0.70
1617.1129150	9.94
1617.8428960	12.37
1618.7606200	0.57
1620.0911870	0.52
1620.9976810	0.39
1622.5556640	0.82
1623.5125730	0.10
1624.8271480	0.54
1625.7933350	0.18
1632.2996830	0.57
1633.1768800	0.57
1634.3537600	1.31
1635.9803470	0.32
1639.2801510	0.29
1640.5550540	0.50
1641.5187990	1.39
1642.4732670	0.21
1645.8647460	0.38
1646.7720950	0.48
1647.3941650	0.37
1648.3934330	0.70
1652.8074950	0.36
1654.0457760	2.91
1654.8280030	0.90
1656.0562740	0.63
1657.8360600	2.52
1660.0297850	0.39
1667.3576660	0.60
1675.9261470	1.08
1680.5217290	0.21
1681.1973880	1.18
1682.3101810	0.08
1682.9661870	2.16
1687.4376220	0.10
1689.4964600	3.06
1690.6033940	6.74
1691.3558350	0.95
1747.1135250	0.33
1774.9064940	0.22
1792.0622560	2.22
1807.7398680	0.75
1917.6671140	0.07
1924.8052980	0.24
1953.9725340	0.33
1968.9263920	0.67
1970.0323490	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	517.1633
Annotation	Unknow
Peak:m/z	Relative Intensity
158.1938019	0.41
175.0471802	100.00
337.2337036	0.07
340.9780884	1.63
342.3561401	0.62
379.2087402	0.31
380.0699463	0.31
473.8405151	0.24
474.4678955	2.91
498.8510742	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	771.1611
Annotation	Unknow
Peak:m/z	Relative Intensity
223.1138763	16.01
224.5283661	0.05
226.9653320	0.10
273.2686462	0.08
282.7940369	0.06
295.0745850	0.04
321.2724304	0.08
323.3489380	0.26
339.3717651	0.16
342.2468872	0.10
349.4628906	0.18
367.0846558	1.28
367.9018250	0.13
385.0706177	100.00
386.1601562	3.17
397.2461548	0.61
415.2468262	0.07
417.0177002	0.09
423.0784302	0.22
433.1352539	0.08
439.2095947	0.05
441.2490234	0.06
467.1790161	0.09
489.4196777	0.05
524.2248535	0.05
547.0166016	0.75
559.3467407	0.62
567.0781860	0.17
568.1452026	0.35
579.3823242	0.09
590.9129639	0.32
603.4682007	0.19
605.1735229	0.06
607.4236450	0.12
608.9357300	2.98
610.3598633	0.19
624.9982300	0.10
628.0693970	0.20
629.4343872	0.16
631.3220215	0.79
637.0440674	0.08
638.3209839	0.17
639.0366821	0.10
645.1354370	0.47
657.1168823	0.28
681.5390015	0.08
711.3490601	1.14
712.1947021	0.05
727.5728149	0.32
728.7755737	0.14
751.3757324	0.11
752.2475586	0.44
752.9765015	1.38
754.0586548	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	314.1051
Annotation	Amoxapine
Peak:m/z	Relative Intensity
99.1354218	0.05
104.8220444	0.05
132.7487030	0.01
160.9792480	3.30
161.6209106	0.05
168.9214172	0.10
177.2296753	0.02
183.0582886	0.02
191.1498260	0.02
193.0630798	100.00
197.9556580	0.02
205.9815674	0.02
214.0513611	0.03
217.2321472	0.04
221.8247375	0.01
225.1417236	0.11
227.0287170	2.36
233.0729980	0.13
235.2986450	0.04
238.2849426	0.07
241.0930176	0.02
243.1286011	0.09
251.1455383	0.02
256.0747681	0.13
260.4013672	0.05
267.4330444	0.06
268.3051758	0.09
273.0392761	0.10
277.1811523	0.04
280.0748596	0.08
280.9570923	0.09
283.0492859	0.05
285.9543457	0.02
290.7614746	0.11
292.1935730	0.10
295.2062683	0.18
296.1840820	0.89
297.1126404	0.32
305.2402039	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	308.0901
Annotation	Glutathione
Peak:m/z	Relative Intensity
105.9107513	0.22
115.9980164	0.44
117.0197067	0.17
117.9802322	0.81
130.9850769	0.16
131.9400330	0.17
143.9735718	1.25
145.1029358	0.91
146.0385132	2.70
147.1175232	0.04
148.0640259	0.04
151.0654907	0.15
161.9586639	7.87
162.9634399	6.62
164.0099182	19.72
179.0508575	32.59
180.0237122	29.39
181.0569763	100.00
190.0961304	0.05
204.8146667	0.06
207.0953064	0.07
216.1568298	0.23
217.0706177	0.27
221.0826721	0.15
233.0961304	2.59
234.0911255	9.17
235.0622864	19.58
239.3209839	0.11
245.8761902	0.55
247.1715088	0.99
273.0388489	0.91
273.9795227	1.49
291.1225586	3.33
292.1246338	9.56
293.1069641	1.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	698.3719
Annotation	Unknow
Peak:m/z	Relative Intensity
209.1909790	0.08
241.9667816	0.10
253.0423889	0.05
260.2179260	0.97
281.2067261	0.06
300.4705200	0.11
312.3030701	5.25
312.9288940	0.06
330.3611755	2.61
348.2921143	0.13
373.9119873	0.17
375.6363525	0.06
388.2719727	0.31
390.3297729	100.00
391.2937012	0.03
402.6397705	0.09
432.1774292	0.07
440.4772949	0.10
449.4868774	0.12
450.4561768	0.10
458.5570068	0.15
468.3622437	0.02
472.0360718	0.05
474.3861694	0.04
478.0782471	0.11
482.6241455	0.20
491.7511597	0.08
492.4110107	0.03
494.0620728	0.03
499.8624878	0.11
500.4980469	2.48
502.5983887	0.10
518.4144897	0.32
520.3571167	0.18
521.2244873	0.03
536.4271851	5.76
539.4263916	0.11
548.7088013	0.10
555.0343628	0.07
571.2703857	0.20
574.0369873	0.10
574.9277954	0.06
576.2643433	0.05
589.0307617	0.02
594.2256470	0.03
617.0913086	0.23
624.4424438	0.17
638.8440552	0.15
652.3943481	0.09
667.3433228	0.10
678.7507935	0.04
680.2696533	1.99
681.1295166	0.03
684.2686157	0.56
689.0003662	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	925.169
Annotation	Unknow
Peak:m/z	Relative Intensity
269.2875671	0.03
297.2729797	0.03
301.2623901	0.03
419.1535645	0.54
420.3837891	0.01
428.3640747	0.03
449.0921631	0.11
461.7910767	0.03
557.2716064	0.06
581.3826904	0.74
583.2046509	0.02
586.1421509	0.04
592.8171997	0.02
597.2670898	0.04
601.1456909	24.12
611.1895142	0.29
625.3135986	0.09
626.0687866	0.02
630.4417725	0.01
637.3025513	0.02
643.2208862	0.11
649.2183838	0.12
650.4523315	0.02
654.2377930	0.08
673.0456543	0.01
674.9954224	0.04
678.2573242	0.11
743.3046265	0.14
745.0247192	0.12
758.4574585	0.01
763.1712036	100.00
763.8071289	0.14
773.2103882	0.61
790.2865601	0.04
792.7267456	0.08
795.6848755	0.05
805.2984009	0.12
809.4124756	0.01
887.1207886	0.05
889.3085938	0.03
906.4042358	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1873
Annotation	Isosyringinoside
Peak:m/z	Relative Intensity
191.1512909	0.07
194.9532318	0.18
209.1791382	0.37
215.0947266	0.05
239.1419067	0.11
241.8342590	0.19
247.2018585	0.09
249.1625671	0.09
251.0032806	0.58
274.8983154	0.16
281.2338867	0.73
291.2904968	0.35
293.1437378	100.00
297.3673096	0.13
305.1591797	1.83
307.1115112	0.10
307.8050537	0.09
317.3477783	0.10
321.3168945	0.11
323.1928711	69.49
327.3501587	0.09
335.2751465	1.39
341.4149170	0.15
347.0613403	0.13
352.1254272	0.37
353.2539673	23.82
358.9639893	0.14
364.4862061	0.23
365.3002319	1.18
371.1956177	1.19
377.4277954	1.64
383.3026123	0.64
385.3508911	0.32
386.3963623	0.10
388.2845459	0.03
389.1647949	0.40
395.2775269	18.33
401.7961426	0.03
407.3950195	1.22
413.2064209	78.20
425.2134399	15.65
437.4935913	0.15
441.6310425	0.07
443.2579956	6.52
447.3837891	0.19
455.2568970	0.41
467.7098389	0.14
471.3483276	0.03
473.0025635	0.03
479.1133423	0.11
486.9298706	0.45
487.5427856	0.09
489.0659790	0.07
497.1639404	2.64
497.7677002	0.42
503.4222412	0.05
512.0177612	0.19
513.4804077	0.18
515.2770996	16.70
524.2048950	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	771.1613
Annotation	Unknow
Peak:m/z	Relative Intensity
223.0484924	16.99
224.0428162	0.03
227.0513763	0.05
247.0588074	0.31
260.9741821	0.03
311.1726379	0.04
321.4460449	0.09
322.8061829	0.03
335.2919312	0.06
340.1242676	0.04
345.3197021	0.05
367.2580261	1.27
369.4884644	0.30
385.0452271	100.00
386.0996704	0.27
423.2573853	0.05
465.4854736	0.11
479.1339111	0.11
507.4154663	0.06
519.2138672	0.05
520.0183716	0.03
545.0669556	0.11
546.9984741	0.82
553.3558960	0.03
559.5496216	0.20
560.2052612	0.13
570.3748169	0.08
575.8015747	0.17
590.6697388	0.09
595.2379761	0.05
600.8688965	0.12
603.3914185	0.03
607.4227905	0.19
608.8869019	2.81
609.7401123	0.09
627.2019043	0.54
628.5741577	0.04
645.7982178	0.05
656.5454712	0.09
687.2942505	0.07
749.1775513	0.15
752.2789307	0.19
753.1430054	1.04
753.7537231	0.17
754.6074829	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	644.03
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
193.3228912	0.03
204.1882172	0.04
206.0324554	0.16
211.0661011	0.09
214.9663696	0.73
224.2233582	0.21
232.8983459	0.81
235.9429626	0.16
248.0006409	0.15
256.0853271	0.08
257.1625977	0.21
261.0103760	0.13
262.1688232	0.79
264.2481384	0.07
269.1464844	0.09
273.1732788	0.27
280.2343750	0.10
282.1963806	4.68
290.7497559	0.06
294.9478149	0.29
297.0413818	0.11
298.9083252	0.19
300.0897827	2.99
301.0747070	0.11
304.8796387	0.17
310.9605103	1.41
317.0240479	1.58
318.0246582	0.21
323.2172241	2.15
329.0178833	1.44
331.0326538	0.09
333.2950439	0.07
340.1962891	0.06
342.1259155	0.32
344.2097168	0.06
344.9686890	0.14
349.1418457	0.14
350.1063843	0.23
351.2192993	0.04
354.2197876	0.04
359.9996948	0.11
360.9185181	0.11
361.9985352	0.53
364.2898560	0.56
366.9597168	0.16
368.1379395	0.09
369.2930298	0.61
371.1104126	0.60
374.9937134	0.26
380.0042114	0.43
383.9686890	0.12
386.2064209	0.44
387.0851440	0.04
389.1495972	0.09
392.0613403	0.06
393.2490845	2.10
397.5222168	0.03
398.1809082	0.22
400.1680908	1.83
401.1435547	0.05
402.0832520	0.14
403.4953613	0.03
404.9149170	0.10
405.5335083	0.09
410.0057373	0.36
411.8212280	0.25
416.2067871	0.39
418.1456909	24.10
420.7780151	0.49
422.1874390	0.49
423.0887451	1.31
425.9026489	0.17
428.8217773	0.05
429.4323120	0.14
431.1064453	0.32
432.0664062	0.56
434.0580444	0.47
437.1310425	0.57
438.1389160	0.03
441.1441040	9.91
446.2528687	0.07
447.2650146	1.98
449.0355225	0.05
450.8206177	0.50
460.1712646	9.24
464.0286255	0.07
465.2366333	5.03
466.8947144	0.51
467.9423218	0.44
468.8461914	4.67
469.7612915	0.17
470.8956299	3.18
472.1532593	0.74
473.6439209	0.10
474.3575439	0.07
483.4170532	0.15
484.8815918	1.44
487.2764282	0.27
490.1024170	0.90
494.2177734	1.45
499.0417480	0.97
500.1032715	0.40
503.2292480	0.99
511.0521240	30.00
511.6803589	0.15
512.3377686	0.04
513.2128906	0.04
514.2470093	0.18
515.4365234	0.09
518.2242432	0.07
523.8821411	0.25
526.2578735	0.60
527.3057861	0.60
529.2059937	2.73
532.0296021	5.27
532.8639526	0.07
541.2533569	0.38
556.1881714	0.18
557.0965576	0.24
558.0803833	0.11
559.1396484	2.21
560.1742554	0.32
560.8956299	0.34
565.1351318	8.12
572.8301392	0.06
580.6826172	0.05
582.1423950	0.08
583.1307373	3.51
601.1715698	100.00
602.1003418	0.60
603.2841797	0.25
608.9657593	0.03
622.2855225	0.15
626.1752319	0.84
626.7896729	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	432.1772
Annotation	Unknow
Peak:m/z	Relative Intensity
132.8729095	0.06
140.2106171	0.06
146.0014191	0.03
149.9729156	0.02
155.1300964	0.10
160.9840088	0.12
167.0234680	0.06
169.2419891	0.02
170.0130768	0.02
171.1316833	0.19
173.1685486	0.52
181.0311584	0.16
183.1159668	0.66
185.1041260	0.12
187.0970764	0.09
191.0794220	0.07
193.1794891	0.06
193.8835602	0.01
197.2342834	0.04
200.1773987	0.09
201.0248108	1.13
211.9270020	0.13
218.1564178	0.09
219.0761414	0.29
221.2858582	0.03
222.3071899	0.01
223.2373657	0.03
225.2237396	0.04
227.2691650	0.06
230.3655396	0.11
232.4290314	0.20
233.3215332	0.03
235.0848389	0.07
242.2140503	0.23
243.1492615	0.31
244.1789551	0.39
251.2495422	0.22
252.0961304	0.03
257.1177063	0.07
260.2444458	3.32
262.2116089	0.16
268.2620544	0.18
269.2423401	0.20
270.2732544	0.37
278.2131958	8.97
279.6287231	0.28
280.3488770	1.03
282.0576782	0.05
288.1546021	0.07
290.0173340	0.02
298.3339233	10.37
299.2022095	0.11
316.3187256	11.68
322.5123291	0.04
334.2331238	100.00
334.9410400	0.20
350.7086182	0.05
352.2304688	1.56
354.3363342	0.07
360.1700439	0.03
369.1397400	0.17
383.3106995	0.02
388.2889404	0.02
390.0277405	0.02
390.9862366	0.22
396.2855530	0.43
397.3710022	0.02
399.6350403	0.03
414.3173523	30.61
415.4137878	0.22
422.7375183	0.11
431.5667419	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0711
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
133.1089172	0.40
134.0188751	0.53
146.0164337	1.06
166.1355286	0.99
175.2210846	0.87
179.0906219	1.56
180.1752472	2.46
180.9938507	1.09
193.1898956	0.55
194.9522858	1.05
196.4767609	0.55
205.8447113	0.27
206.9693451	2.41
208.1654205	12.02
209.09198	10.31
222.0599518	5.57
223.1131134	15.54
224.2064972	12.44
232.8668671	0.60
251.0826416	62.09
252.1996307	100.00
253.3014984	4.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.11
Annotation	8-Cinnamoyl-3,4-dihydro-5,7-dihydroxy-4-phenylcoumarin
Peak:m/z	Relative Intensity
122.7874908	0.05
134.7297821	0.10
138.0470581	0.05
143.1054993	1.00
155.0930634	2.98
159.0775604	0.07
165.9315491	0.09
166.9988708	0.27
174.8856201	0.25
176.2803192	0.05
181.0246124	0.35
188.0347900	0.16
191.1303711	0.46
193.5496979	0.17
198.2122650	0.17
203.1846008	0.19
204.0834045	0.11
206.0672913	0.21
207.1834869	0.49
208.0170593	0.82
209.2590942	0.30
210.1423492	0.16
210.9296265	0.14
213.1314850	0.49
220.1058807	0.26
221.0808868	0.58
222.0339661	4.90
223.1338196	1.10
231.1725464	0.15
231.8879395	0.47
235.0825806	0.23
241.1767273	1.43
246.2424927	0.29
248.0276184	0.13
249.3902588	0.05
250.1808777	0.15
250.9728088	0.06
252.1444702	0.08
255.0709229	0.05
259.1852112	0.37
263.1945496	1.44
265.4036560	0.52
266.1279297	0.12
268.2607117	0.48
270.3017883	0.07
274.3459473	0.81
276.7227478	0.35
285.4888306	0.41
289.1683350	1.59
290.1176758	0.22
291.5424805	0.32
292.4167480	0.10
293.0222168	0.23
294.0144348	0.04
294.8179626	0.08
297.1407471	0.29
301.0528564	0.09
302.8811646	1.18
305.1610413	0.17
307.1480713	3.21
309.1421814	100.00
310.0144653	0.63
317.0289001	0.24
319.0513916	0.05
320.8787231	13.43
321.5174561	0.07
323.1671753	0.23
325.1683350	0.16
333.2715454	1.74
338.5670776	0.53
339.2487183	1.80
341.0753479	0.36
348.5921326	0.23
351.1616211	0.72
353.3846130	0.31
355.1143494	10.95
367.1387939	17.66
369.9519043	1.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	819.3082
Annotation	(+)-Phyllanthostatin 2
Peak:m/z	Relative Intensity
240.9255676	0.13
301.0900574	0.06
343.2536316	0.15
355.2036743	0.07
359.3930054	0.11
374.2137451	0.06
399.4763794	0.14
441.1879272	0.04
445.4048462	0.04
450.1831055	0.03
476.4133301	0.06
500.5587158	0.20
504.4230347	0.04
517.5003662	0.08
539.2401123	0.10
550.8953247	0.13
565.2783203	0.03
566.6036987	0.03
583.5451660	0.09
586.1309204	0.11
591.3961182	0.08
596.6463623	0.16
597.6210938	0.09
598.6070557	0.08
600.7337036	0.06
602.4451294	0.12
608.3695679	0.58
617.4319458	0.25
618.4094238	0.12
619.5460815	0.03
621.4740601	0.15
626.3410034	1.64
627.3550415	0.17
632.3576050	0.26
649.5193481	0.13
650.5193481	0.15
655.4758911	0.34
657.1820679	0.32
659.4580688	0.06
662.2651978	0.05
663.5753784	0.11
664.6178589	0.14
665.3163452	0.10
667.3948364	0.20
676.6199341	0.05
683.7312622	0.13
685.7180786	0.14
686.5214844	0.15
689.5027466	0.04
690.5761108	0.15
691.1807251	0.05
695.2593384	0.08
699.3508911	0.40
701.4780884	0.17
709.3884888	0.05
713.3607178	0.16
714.3734131	0.19
715.1565552	0.16
716.2424927	0.09
719.3001099	0.23
720.6730347	0.21
727.2846069	2.76
728.4161987	1.47
729.3341064	0.20
730.1680298	0.04
739.6664429	0.05
740.6593628	0.09
743.4348145	0.19
744.5799561	0.66
745.4027710	2.77
746.3769531	1.66
747.4331665	1.25
748.4699097	0.14
751.5652466	0.97
752.4734497	0.15
757.3402710	0.13
759.2816772	3.21
760.3571167	1.43
769.3621826	15.77
770.4701538	8.84
771.3352051	0.02
772.1548462	0.07
773.4129028	0.31
774.3456421	0.04
775.4100342	0.10
776.6107788	0.22
783.3939819	1.86
784.5357056	1.59
787.4414062	92.13
788.4013672	36.47
789.3512573	0.11
790.1320190	0.08
791.3894653	0.77
792.4332886	0.34
797.9254761	0.07
801.3198853	100.00
802.4353027	45.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	420.1855
Annotation	Unknow
Peak:m/z	Relative Intensity
114.8338318	0.36
127.0255890	0.36
127.9689484	0.13
129.0084839	0.42
131.0443115	0.15
132.7655640	0.78
141.1262207	0.10
142.9898682	0.08
144.9335938	2.05
146.7952423	0.04
149.1151276	0.20
150.0866699	1.21
152.9740295	0.19
155.1132812	0.05
156.9216156	0.41
159.0460663	0.41
160.7679138	2.09
162.8153839	2.22
164.6962585	0.15
167.1754761	0.17
169.0724030	0.11
171.1288452	0.65
175.0118713	1.50
178.1315613	0.04
179.9546661	0.17
180.9107056	0.15
187.0145874	0.73
189.1438751	0.45
191.0903015	0.34
194.9732361	0.04
197.2355957	0.13
198.0760345	0.06
198.8641205	0.43
204.8831635	4.11
205.5112610	0.02
209.1137848	0.46
210.7201996	0.17
216.4441376	0.72
217.1144104	2.75
218.0553894	0.04
222.9214783	9.22
223.5518341	0.11
224.4284363	0.06
227.1295929	4.15
231.3875427	0.07
232.8101807	0.14
234.4023132	0.82
235.0978394	3.02
235.9611511	0.03
238.5866394	0.15
240.0516357	2.41
240.9405823	9.42
244.5012512	0.07
249.2249756	0.20
252.2758789	3.49
252.9773560	17.82
253.7711182	0.07
255.2676086	0.09
258.0876770	2.58
258.8295593	22.30
259.4341431	0.27
264.1683044	0.05
267.9874573	0.07
270.2326660	5.39
270.9169617	28.90
271.8482056	0.07
274.8931885	0.04
275.6037292	0.10
276.7919922	0.99
277.4208984	0.17
288.0913696	7.54
290.2592468	0.06
294.9121704	100.00
295.5950623	0.32
297.1187439	0.04
299.8621216	0.09
312.1525269	0.84
331.0491638	0.17
333.2843628	0.10
348.5316772	0.18
349.1823120	0.52
353.7486572	0.04
361.1286926	0.04
366.6395874	0.69
367.4302673	0.02
376.3260193	0.07
384.9006348	3.23
388.9559631	0.36
398.8970642	0.07
399.9854126	0.09
401.3556824	0.55
402.1544495	2.59
402.9035950	17.08
410.8572693	0.22
412.3424988	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	349
Annotation	Unknow
Peak:m/z	Relative Intensity
174.8063049	4.57
195.9243469	4.06
212.9975739	100.00
234.1562805	0.13
234.9826965	0.17
251.0314331	0.32
264.8992004	0.68
280.7148132	0.52
281.3201904	0.50
291.1055908	0.05
328.3372803	1.02
331.1185913	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	612.64
Annotation	Unknow
Peak:m/z	Relative Intensity
384.3109741	0.12
452.0698242	0.26
453.1143188	0.11
454.2309570	0.22
466.9927368	0.08
469.2528076	0.22
470.4754028	0.45
483.0107422	0.22
495.9457397	1.37
497.0152588	2.46
497.9652710	2.68
499.0767212	3.06
500.2492065	0.59
511.1950073	0.13
513.5156860	0.21
514.8817749	1.19
515.9071655	2.03
516.8894043	0.17
517.9610596	0.37
536.9397583	1.40
537.9540405	4.22
539.0116577	3.56
539.8248901	0.50
540.8639526	0.20
555.1600952	0.53
555.9757690	1.28
557.0381470	1.38
558.6787720	0.07
565.9111938	100.00
566.9675903	54.77
568.9735718	0.54
575.6414185	0.42
577.5380249	0.17
580.1689453	0.56
581.2810669	0.23
582.4258423	5.13
583.3776245	30.45
584.5460815	11.61
586.1409912	0.88
594.0562744	0.04
606.3988647	0.15
611.9837646	3.16
613.0688477	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	608.1169
Annotation	[Epigallocatechin-(4->8)]3-epigallocatechin
Peak:m/z	Relative Intensity
175.2794647	0.09
177.0823364	1.68
178.1453094	0.26
178.9852905	0.30
188.9978943	0.16
190.9759674	0.35
203.9609070	0.09
205.1549683	0.18
205.9643707	0.06
207.2065430	0.11
217.1659851	0.12
217.8948364	0.12
219.0516968	1.20
220.0356445	0.19
221.0064850	1.00
229.3283386	0.05
233.0583801	0.10
235.0648956	0.05
241.1029358	0.09
243.3068237	0.85
244.2502747	0.45
245.2168274	0.19
247.1462097	0.11
257.2017212	0.19
261.1299438	3.84
262.0134277	0.34
263.1719360	0.25
272.1455688	0.08
273.1386108	1.53
283.3205566	0.11
285.3461609	0.35
286.4348145	0.06
287.1954041	0.18
288.8478394	0.06
301.3080444	0.16
303.1453857	9.93
304.4016724	4.12
305.1206665	43.88
306.2399902	3.97
307.3387146	0.36
309.3066711	0.04
315.2290039	0.64
317.0710449	0.21
329.0917969	0.08
338.1848145	0.13
344.9949951	0.51
346.5957031	0.23
347.3526001	1.23
348.1127930	0.19
350.3541260	0.15
353.0106201	0.06
355.4219971	0.12
357.2086792	0.08
367.4233398	0.23
369.3645020	0.19
372.1854248	0.10
373.2435913	0.23
377.6616821	0.13
383.2245483	0.36
384.0339355	0.12
385.1476440	0.17
386.4149170	0.32
392.7539673	0.08
396.1538086	0.10
397.1879272	0.69
408.9587402	0.28
409.6802368	0.45
411.2243652	2.20
412.2193604	0.81
413.2468262	0.17
420.2924805	0.11
421.1483154	1.63
423.1007080	64.87
424.2024536	3.04
425.3729248	0.37
426.3970337	0.36
427.2446289	0.15
429.2131958	7.34
430.1981812	0.76
431.3276367	9.30
432.2772217	0.20
435.2015381	0.07
439.0996094	3.24
441.0545654	63.99
442.1000366	0.81
443.4257202	0.23
447.2384644	0.05
452.1563721	1.00
452.8007202	1.55
453.5358276	0.33
455.5286865	1.20
456.3084106	0.16
461.1620483	0.94
463.2752075	0.69
464.1419678	0.83
465.1854248	1.84
466.4863892	0.78
467.3912964	0.53
469.1073608	1.02
470.3423462	2.21
471.2813110	1.54
472.3070679	0.06
473.3750000	0.05
476.5019531	0.07
477.4350586	0.27
479.2189331	0.13
481.2441406	4.16
482.4733887	3.51
483.2196655	16.79
484.1762695	1.34
484.8240356	0.23
486.0277100	0.10
493.2136841	0.78
497.2327271	0.09
502.2163696	0.66
506.3780518	3.50
507.3333130	0.88
508.1453857	0.04
510.3246460	0.23
515.4649658	100.00
516.6939087	1.35
517.3486938	0.04
521.3148804	0.31
524.3754272	60.17
525.4867554	4.71
526.1019897	0.23
529.1537476	0.71
529.8858032	0.34
533.1220093	0.19
536.2209473	2.43
537.2913208	0.22
539.2284546	0.62
540.0305786	0.23
541.2031250	0.16
545.2816162	7.11
546.1880493	1.60
547.3377075	2.27
548.3122559	0.56
549.2681885	0.29
552.3088379	0.04
559.4210815	0.14
562.7902222	0.11
563.6226196	0.19
565.2352905	2.48
566.4619141	0.24
567.1523438	0.22
571.1049194	0.18
573.0906982	0.09
575.4550781	0.14
577.1468506	0.11
578.4024048	0.17
580.2564697	0.50
581.1628418	0.26
581.8125610	0.21
586.1696167	0.19
587.5046997	0.30
589.0476074	1.64
590.5771484	4.35
591.2384644	14.51
592.2494507	1.65
593.4827271	0.40
599.2283936	7.65
600.0355225	1.68
619.6767578	0.30
620.3866577	0.14
632.3285522	0.16
633.2739868	0.31
643.3537598	0.14
649.3104858	0.34
650.1194458	0.10
651.3521118	1.67
652.2811279	0.62
653.4667358	0.27
660.1580200	0.19
681.6172485	0.11
683.1307983	0.28
694.9767456	0.13
697.1165161	0.09
699.9971313	0.60
709.2536621	0.69
710.3693237	0.44
715.0502930	0.36
725.1132202	2.78
726.2915039	0.35
727.1719971	0.37
728.1058960	0.76
733.2352905	5.33
734.2418213	1.26
736.0751343	0.24
743.3914185	0.78
745.0665283	1.16
746.1864624	0.19
747.4848022	0.26
755.2316284	0.13
756.2706299	0.08
758.2575684	0.21
765.4006348	0.13
766.3952026	0.16
767.2203979	0.05
769.2996826	0.65
770.1978149	0.55
771.0700073	0.24
774.1122437	0.25
775.2343140	0.39
785.2037964	1.42
785.9416504	0.13
787.2192383	6.27
788.2125854	2.39
788.8391113	0.02
790.2688599	0.15
813.0948486	0.25
820.3344116	0.12
821.3886108	0.22
826.9868774	0.22
839.1259766	0.14
845.3692017	0.45
846.5938110	0.15
850.8226929	0.33
861.2648926	0.07
863.3024902	0.36
864.3651733	0.33
865.0458984	0.16
867.5336914	0.18
868.9513550	1.28
869.8962402	0.53
872.3733521	0.05
881.2636719	0.19
893.4089355	1.41
894.1638184	0.46
895.3844604	0.82
896.2353516	0.73
897.2963867	0.19
904.9666138	1.37
906.1503296	2.64
907.3562622	0.51
911.1210938	19.03
912.1760864	8.57
913.1811523	8.95
914.2822876	4.79
915.1398926	0.74
923.3010864	0.49
924.1142578	0.31
949.1010742	0.06
955.0676880	2.02
956.2037964	0.88
957.5410767	0.21
965.3151855	0.09
988.1296997	0.21
1012.8809200	0.20
1031.2514650	1.82
1032.0957030	1.95
1033.3322750	0.72
1049.0943600	3.27
1050.1352540	1.67
1051.1704100	0.43
1055.3312990	0.06
1073.1843260	0.49
1073.9625240	0.60
1091.1103520	6.05
1092.1878660	5.86
1093.2075200	1.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.31
Annotation	Unknow
Peak:m/z	Relative Intensity
160.8865662	0.20
179.0325317	0.33
179.9324341	0.18
205.4317322	0.15
215.4059143	0.10
220.9102020	0.11
243.0531616	0.04
245.2582245	0.22
249.3364105	0.55
258.2568359	0.11
261.1539307	0.07
272.1910706	0.50
285.3162231	0.03
288.3829956	0.12
293.1810913	0.19
306.1241455	0.40
311.3016968	0.19
325.3265381	0.16
327.2609253	0.30
331.0270386	0.23
333.4397583	0.15
337.3278809	0.21
339.3912964	0.23
343.3782959	1.68
344.2027588	0.06
347.3394775	0.92
349.3002930	1.29
350.2999268	2.91
351.3100586	0.71
361.2222290	0.91
365.2568970	0.34
366.2678223	0.15
381.5510254	0.07
393.4845581	0.08
397.1960449	0.39
398.5206299	0.06
399.4720459	0.10
411.9336548	0.38
413.5139771	0.06
419.3369751	0.07
423.1486816	0.14
427.2819824	0.14
429.3450928	0.18
431.1634521	0.12
433.4005737	0.04
435.6416626	0.07
437.8664551	0.20
439.3883057	0.48
441.3443604	0.20
445.1362915	0.05
451.3403320	0.31
463.2301636	1.71
464.1527100	0.15
469.1203003	0.15
470.4039307	0.14
471.3367310	0.16
473.3967285	0.15
477.1837158	0.10
478.3608398	0.30
481.4175415	17.86
487.2074585	0.20
499.2539062	100.00
499.9372559	0.56
511.2984009	0.20
512.1150513	0.29
513.0069580	2.43
514.2273560	0.09
515.2612915	0.56
516.2149658	0.08
517.3269653	8.85
520.8546753	0.75
523.2882690	1.83
526.8736572	0.05
539.2936401	0.06
540.3859253	0.41
541.2914429	5.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.0775
Annotation	Aesculin
Peak:m/z	Relative Intensity
110.9533920	0.55
128.9731445	2.62
146.9728088	0.26
149.0080109	0.04
161.0535583	0.02
179.1446533	0.23
181.1004639	0.02
186.9533234	0.46
189.2181702	0.02
191.1099854	4.86
205.0747986	7.46
209.0676575	0.86
223.0241699	100.00
224.0800476	0.06
246.9991455	0.60
303.0395203	0.09
309.5648193	0.02
320.9947205	0.36
323.1323242	0.24
335.1251221	0.10
340.2875671	0.02
349.1238098	0.40
353.2884521	0.03
367.1169739	5.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.0623
Annotation	8-Hydroxytricetin 7-glucuronide
Peak:m/z	Relative Intensity
212.3707275	0.01
243.0390167	0.01
245.0855103	0.01
287.1616516	5.39
292.2495117	0.04
296.8715210	0.02
313.2252808	0.01
317.4955139	0.03
330.2359009	0.04
331.0612793	0.08
333.4095459	0.01
349.0888672	0.02
360.1493530	0.03
360.8849487	0.01
377.7102356	0.01
393.2480774	0.04
421.2136536	2.74
446.3607483	0.04
447.1294250	0.01
449.1727600	100.00
452.6340027	0.05
454.2960815	0.00
465.0293274	0.02
474.2872009	0.02
475.3629761	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	716.382
Annotation	Amamistatin B
Peak:m/z	Relative Intensity
208.5618896	0.01
210.2806244	0.01
226.3463135	0.15
230.1989441	0.02
232.3064117	0.01
256.3003235	0.04
260.3278809	0.38
261.4912109	0.09
270.3047791	0.09
293.4548950	0.07
294.1387329	0.66
304.2861938	0.03
310.6118164	0.05
312.3465881	6.47
315.0116577	0.08
322.4876099	0.04
328.6609497	0.12
329.6519165	0.32
330.4092407	4.03
334.4332275	0.02
348.4262695	0.83
366.4185181	0.14
369.9198608	0.07
372.4711914	0.20
382.4522705	0.03
386.3519287	0.03
388.4614258	1.94
389.4696045	3.06
390.3560181	5.04
392.3949585	0.06
404.5941772	0.11
406.3251343	2.97
407.4721069	7.01
408.3856812	100.00
409.1637573	0.33
410.6729126	0.06
416.0130005	0.03
420.3171387	0.08
421.4507446	0.14
422.3172607	0.02
434.3024292	0.04
440.4111938	0.23
441.0470581	0.03
458.3723145	0.03
460.6173706	0.04
462.4956055	0.11
474.6704712	0.09
475.4246216	0.03
486.3267822	0.04
492.4849243	0.05
498.9317627	0.25
500.3226318	0.25
511.2173462	0.08
516.3172607	0.09
517.9289551	1.30
518.5603027	5.47
520.4650879	0.01
528.1537476	0.03
530.2941284	0.08
534.3250122	0.18
535.4978638	0.73
536.4682007	1.74
537.5215454	0.06
538.5216675	0.08
548.3461304	0.09
551.1138306	0.02
552.5315552	0.57
553.3585205	0.88
554.4863281	10.94
568.6256714	0.06
570.3280640	1.62
579.3710938	0.06
580.0381470	0.03
611.3918457	0.06
612.6262817	0.05
620.5645752	0.15
622.3551636	0.05
626.2796631	0.04
634.6514282	0.04
640.4369507	0.29
641.6274414	0.07
642.6875000	0.10
662.5366211	0.03
663.3329468	0.04
666.7988281	0.06
668.5558472	0.10
672.7001343	0.03
679.3400269	0.17
680.3755493	0.24
684.0270996	0.07
686.4094238	0.05
688.4823608	0.03
694.8279419	0.07
697.3391724	5.19
698.5243530	3.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.12
Annotation	Unknow
Peak:m/z	Relative Intensity
177.0221710	3.48
178.1499634	0.45
179.1606293	0.08
198.9978027	0.17
201.1914673	0.14
214.9573669	0.38
217.3582458	0.56
219.1421967	0.60
220.9598083	0.56
224.9617157	0.08
229.3104095	0.21
233.4453888	0.05
235.2993774	0.05
243.1577301	1.09
244.2409363	0.37
245.1045685	0.15
255.1682739	0.39
259.2780151	0.37
260.1766357	0.10
261.1516113	1.50
262.1792297	0.13
271.0470581	0.68
273.0563354	5.98
274.3377686	0.08
282.9888306	0.06
285.0370483	1.03
286.2116699	0.28
287.1461182	1.61
288.2160645	0.41
301.0756836	0.08
302.4719849	0.36
303.1797180	6.95
304.5155640	1.14
305.1800537	30.01
306.3424988	0.94
307.2839050	0.18
313.3862305	0.23
314.0980530	0.17
315.1756287	6.15
316.1026611	0.81
317.0354614	0.48
335.4606323	0.06
337.2457886	0.09
338.6578369	0.05
339.3511963	0.29
340.1870728	0.09
343.5883789	0.05
345.1992798	0.16
347.4926758	0.20
349.1872559	0.06
354.0100708	0.13
355.2291260	0.20
356.4818115	0.50
358.1726685	0.28
359.4855957	0.15
369.0543823	0.13
371.1452026	0.07
383.2505493	0.09
383.8804321	0.30
385.4761963	0.24
393.4385376	0.11
396.6173706	0.40
397.3733521	0.96
399.1622925	0.65
406.2998657	0.04
409.8988647	0.31
411.1722412	1.11
412.2118530	0.35
414.1953735	0.28
415.1321411	0.32
421.0166016	0.13
422.6965942	13.65
423.3178711	69.77
424.2425537	0.79
427.0424805	1.04
429.2098389	3.54
430.1428223	0.07
431.3793945	4.34
432.1832275	0.33
434.2935181	0.16
436.4842529	0.17
439.3320312	2.99
441.1113892	100.00
441.7755127	0.16
443.0697021	1.21
446.5485229	0.28
447.2749023	0.35
451.2725220	0.22
452.4877319	3.44
453.2379761	1.53
455.4697876	0.27
460.6213989	0.29
461.8178101	0.92
462.9371338	0.06
464.2185059	0.30
465.2385254	2.06
466.4118042	0.35
467.8507690	0.79
469.3376465	1.28
470.2605591	0.90
471.2064209	0.83
473.3200073	0.09
479.2008667	6.11
481.3179932	2.58
482.3129883	3.59
483.2436523	20.47
484.3925171	0.30
486.0098877	0.11
489.1381836	0.29
493.4152832	0.82
502.1637573	0.67
503.0603027	0.83
506.4917603	3.96
507.2579956	0.35
508.3845825	0.09
513.2022095	0.15
515.3900757	45.50
516.2433472	4.72
517.1659546	0.42
518.1152954	0.57
519.1808472	0.20
520.2063599	0.20
524.4128418	33.02
525.2783203	4.68
525.9984741	0.12
529.6229858	0.39
531.7941284	0.31
533.0474243	0.37
535.3681030	0.35
536.3289795	1.67
537.1818848	0.72
538.2423706	0.18
539.8005981	0.08
543.2537842	0.39
545.3779907	4.75
546.0281982	2.05
547.5761108	0.76
548.4348755	0.09
549.4732056	1.11
556.6003418	0.18
559.4011841	0.38
563.3402100	1.97
565.2514648	2.46
566.2287598	0.23
573.4527588	0.11
575.5078735	0.31
577.5432739	0.69
578.9117432	0.42
581.1820068	1.75
583.3330078	0.33
586.3419800	0.17
587.3588867	0.06
589.3225708	0.61
591.1936646	14.43
592.2208862	0.80
599.4910278	4.53
600.1951294	0.24
601.2784424	1.08
602.4533081	0.22
621.5706177	0.33
651.2035522	0.50
652.1431885	0.13
653.3061523	0.24
660.2623901	0.10
661.2105713	0.64
689.6543579	0.17
702.4592285	0.20
715.1328735	0.26
717.0256958	0.27
719.4479370	0.09
720.2678833	0.41
725.1308594	0.20
727.1574707	0.89
728.3265991	0.66
729.0461426	0.26
733.9733276	0.23
741.1715698	0.08
743.2302246	0.21
744.2496338	0.24
745.3994751	0.05
748.3247681	0.49
766.4211426	0.06
767.4144897	0.27
768.1729736	0.39
769.0122681	0.79
770.3241577	0.30
771.3186646	0.08
786.0593872	0.50
787.2168579	3.32
788.1752930	1.10
799.3912964	0.14
813.2847900	0.40
820.2348633	0.07
826.6456909	0.11
828.4790039	0.16
845.1503906	0.79
847.6201172	0.34
862.7890625	0.73
863.4526367	0.29
864.2598267	0.09
864.8828125	0.11
869.4524536	0.09
870.4957886	0.10
871.1914062	0.49
873.5187988	0.08
877.3262329	0.52
880.4284668	0.53
881.3115845	0.09
882.0095825	0.10
885.3939819	0.11
893.1118774	0.26
895.3742065	0.15
896.1437988	0.18
897.2086792	0.30
901.4404297	0.29
905.2441406	2.77
906.1383667	1.71
907.3737183	0.51
909.0947876	0.16
911.1777344	3.49
912.2317505	3.48
913.2556152	5.44
914.3058472	1.48
915.2780151	1.04
922.9746094	0.47
924.2578735	1.13
933.8599243	0.22
937.0629883	0.15
938.3193359	0.12
955.4335327	0.14
956.1916504	0.55
956.9628296	0.08
965.0566406	0.65
966.5095825	0.06
1013.6439820	0.21
1031.0969240	1.11
1032.2244870	1.42
1048.4611820	0.54
1049.2829590	0.77
1050.1528320	0.61
1073.7702640	0.84
1076.1951900	0.48
1091.2628170	4.24
1092.2702640	3.41
1093.3269040	1.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	916.3957
Annotation	Unknow
Peak:m/z	Relative Intensity
263.1480103	0.06
305.2245178	0.04
314.3951111	0.18
315.3722534	0.21
329.6559753	0.15
330.3650208	0.12
331.4205322	0.13
332.2463989	0.13
358.2747192	0.34
359.1400452	0.18
384.8322754	0.16
387.6907959	0.12
396.2270508	0.08
397.7870483	0.91
398.8635864	0.95
405.4256592	0.03
413.2231445	0.32
414.2199097	0.44
415.4746094	0.26
418.1859741	0.13
419.4041138	0.05
424.2687988	0.23
427.4816895	0.23
431.2545166	0.05
433.1307373	0.29
437.3656616	0.06
441.6237183	0.17
445.3427734	0.13
470.2203979	0.18
472.3708496	0.11
479.4996338	0.26
491.6610718	0.04
493.2224121	0.06
513.9357910	0.23
515.2535400	0.33
526.2396851	0.42
527.2695312	0.50
539.1272583	0.24
544.1645508	1.08
545.6821899	0.10
554.6900635	0.21
555.6348877	0.08
563.2465210	1.07
563.8944092	0.71
570.4929199	0.10
573.8526611	0.36
579.6434937	0.20
582.4426880	0.25
590.1746216	0.18
597.2686157	0.07
608.3851929	0.24
609.4456177	0.09
613.2680054	0.47
635.9955444	0.22
640.5276489	0.09
679.3530273	0.39
684.0809326	0.07
689.5145264	0.60
694.7145386	0.47
699.3710327	0.10
707.3442993	1.73
708.7161865	1.00
729.3164673	0.17
735.4973755	0.52
737.3978882	0.13
739.6663208	0.09
745.9793091	0.35
749.3893433	0.27
750.6074829	0.08
758.3506470	0.28
766.4871826	0.19
771.3653564	0.21
776.5112915	0.19
777.6469727	0.35
794.5758667	0.58
795.5490723	0.08
800.3535156	0.39
804.5243530	0.16
805.3570557	0.32
806.4597778	0.40
807.4932251	0.67
817.7805176	1.80
823.3522339	0.15
824.0680542	0.44
825.3970337	0.70
828.1668091	0.37
830.0364990	0.47
831.6348267	0.83
832.7048950	0.54
833.7190552	1.20
834.7445068	0.86
837.2085571	0.22
840.5900879	0.45
841.6948853	1.58
842.6935425	1.80
843.7702637	0.10
847.2479248	1.21
848.9913940	1.50
850.2241821	0.55
850.9335327	2.68
852.1294556	0.91
852.8919678	0.58
854.0583496	0.49
854.8378296	1.28
855.7792358	0.27
857.1195068	1.06
858.7502441	3.56
859.6312256	0.49
861.5696411	2.48
862.3557129	0.49
863.0423584	2.05
863.8834229	1.12
865.7901611	5.90
866.5988770	5.85
867.5202637	0.90
868.6603394	0.47
869.7868652	13.08
870.7987671	7.09
871.7219849	1.22
872.6014404	1.59
873.5725098	1.14
875.2695312	2.71
876.3002930	2.36
877.0930786	0.62
879.1094971	2.34
880.2827148	4.09
881.3847046	1.25
882.4694214	0.77
883.3936157	4.08
884.2759399	1.33
885.3845215	8.16
886.2025757	2.09
887.7723999	18.45
888.8156738	3.73
890.2807617	13.73
891.2037964	1.06
892.2250366	1.03
893.4638672	1.10
894.6797485	24.60
896.1862183	1.55
896.9721680	2.23
897.8778687	0.95
899.2029419	2.27
899.9065552	0.53
901.1137695	4.04
901.9939575	2.40
903.4347534	6.17
904.5056152	1.08
905.7307739	9.37
906.6990967	0.88
917.9071045	0.59
921.5578003	0.06
924.0282593	1.37
927.9079590	0.61
933.5219727	1.71
935.6173706	0.46
938.5453491	0.13
939.3651733	0.31
940.3164062	0.80
943.5607910	0.16
944.4856567	0.05
946.4924316	0.40
947.4059448	0.64
951.5529785	0.37
956.4393921	1.03
957.5154419	2.26
958.7067261	1.08
959.4108276	0.09
964.1862183	0.53
967.8257446	0.20
968.5311890	0.46
969.6513672	0.25
972.2693481	0.40
975.4702759	0.26
980.6472168	1.34
984.9503784	0.90
987.0380249	0.70
988.1541138	0.99
988.8540039	0.37
991.5178223	0.24
992.2656250	0.21
995.9296265	0.45
996.6361694	0.13
1001.5287480	0.15
1002.2407230	0.39
1005.0348510	0.16
1006.0749510	0.78
1008.6117550	0.16
1013.6120000	0.30
1014.4951780	0.04
1017.6553340	0.37
1020.2301640	0.41
1022.7109380	0.25
1026.3952640	0.70
1027.6892090	1.12
1028.3919680	0.20
1029.2126460	0.89
1029.9099120	0.22
1032.9956050	0.24
1035.1845700	1.97
1037.6431880	0.16
1039.4448240	1.28
1041.2199710	3.62
1042.1896970	0.73
1043.8203120	0.52
1048.6618650	0.95
1050.8710940	0.76
1052.3245850	0.47
1054.0218510	0.24
1059.3310550	0.45
1060.4141850	2.47
1063.3349610	0.65
1064.6237790	0.17
1067.2625730	0.85
1068.3111570	1.01
1069.4030760	0.91
1070.8686520	0.31
1072.4963380	0.77
1073.8500980	1.30
1075.0826420	0.38
1076.6387940	0.05
1077.6071780	0.44
1078.7387700	0.61
1079.6649170	0.22
1081.1665040	1.35
1082.1080320	0.24
1082.9876710	0.09
1084.3127440	0.72
1085.6384280	0.32
1087.5953370	0.46
1088.4792480	1.16
1089.7236330	0.18
1091.0500490	1.81
1091.7630620	0.51
1092.4841310	0.04
1093.1883540	0.12
1094.2279050	0.16
1096.5537110	1.08
1098.0693360	2.25
1100.1494140	0.45
1101.6115720	0.62
1103.1237790	10.95
1104.6201170	0.69
1105.8229980	3.44
1108.3129880	0.50
1109.5275880	0.50
1111.8947750	1.17
1112.9284670	1.84
1115.0190430	0.79
1115.8303220	2.22
1116.8933110	1.98
1118.4458010	0.44
1119.6643070	0.43
1122.0158690	6.68
1122.9322510	1.04
1123.7028810	0.13
1124.3713380	0.84
1125.3643800	0.14
1128.9261470	3.03
1129.7680660	0.76
1131.0997310	2.44
1132.3885500	3.33
1133.0875240	0.55
1135.1245120	6.19
1135.8863530	3.41
1136.4976810	2.02
1137.7388920	1.37
1138.3770750	0.97
1139.8663330	0.87
1140.7780760	4.25
1141.8378910	1.83
1142.6486820	1.27
1143.5031740	1.08
1144.4666750	1.78
1145.7210690	0.20
1146.3232420	0.33
1147.5523680	3.85
1148.6785890	2.28
1149.4110110	3.31
1150.3187260	1.66
1150.9299320	0.15
1152.3327640	2.58
1153.5859380	8.85
1154.3801270	5.34
1155.1871340	8.18
1156.1217040	0.97
1156.9630130	0.62
1157.5786130	0.33
1159.4497070	26.24
1160.1770020	10.57
1160.8349610	6.30
1161.6315920	4.50
1162.4376220	1.09
1163.1571040	0.57
1163.9016110	1.01
1166.3592530	0.04
1167.6486820	5.19
1168.3737790	0.75
1169.0438230	1.97
1169.9472660	0.83
1171.9655760	0.18
1173.2663570	1.07
1173.9941410	0.21
1174.8472900	0.71
1175.6513670	0.84
1177.1684570	0.29
1178.5627440	10.37
1179.4637450	1.48
1180.5317380	0.99
1181.3218990	1.20
1182.9440920	6.34
1183.8776860	10.73
1184.5207520	100.00
1185.8405760	2.72
1186.8072510	2.14
1187.6638180	1.02
1188.9019780	0.97
1190.1953120	0.83
1191.4005130	0.15
1192.4158940	9.27
1193.0880130	4.63
1193.7922360	0.65
1194.4750980	0.15
1196.1274410	0.53
1198.6063230	1.36
1200.0583500	0.06
1201.2237550	0.69
1203.4030760	0.32
1207.9793700	0.22
1208.6179200	0.22
1210.0991210	2.20
1211.7374270	0.73
1214.5321040	0.16
1216.3101810	1.21
1217.2849120	2.11
1218.2561040	0.56
1219.3929440	0.44
1225.4030760	6.71
1226.3162840	5.24
1226.9298100	0.08
1228.6794430	0.33
1231.8228760	0.32
1237.2954100	0.57
1238.3784180	1.14
1239.1091310	1.54
1243.5578610	0.28
1246.4781490	0.34
1247.3173830	0.22
1252.8378910	0.67
1253.8127440	0.80
1259.9038090	1.05
1261.3886720	0.36
1262.1103520	0.19
1263.3012700	0.20
1265.6656490	0.38
1272.5981450	0.16
1275.3044430	0.59
1284.9906010	0.60
1287.3936770	0.51
1288.1158450	0.13
1290.4317630	0.21
1293.2376710	0.54
1295.8824460	0.20
1296.7635500	0.13
1297.3742680	0.65
1299.5001220	0.10
1303.2786870	0.44
1308.3181150	0.14
1309.1868900	0.98
1309.9688720	0.61
1310.6778560	0.15
1319.7824710	0.58
1324.6903080	0.08
1328.1700440	0.71
1328.8608400	0.63
1330.6832280	0.35
1332.5455320	0.24
1334.8527830	0.37
1335.5953370	0.80
1336.7285160	0.35
1341.6918950	0.58
1342.7203370	0.15
1345.1905520	0.48
1346.2113040	1.16
1353.8875730	2.69
1355.0173340	1.57
1355.8675540	0.36
1361.7227780	0.36
1368.4874270	0.47
1369.7106930	0.78
1371.9447020	0.91
1374.2607420	0.24
1375.5531010	0.21
1376.6583250	0.67
1378.1175540	0.20
1380.0299070	0.84
1385.7028810	1.07
1386.3931880	0.60
1389.2625730	0.17
1390.2409670	0.12
1391.6677250	0.05
1392.9121090	0.28
1396.7193600	0.25
1397.7498780	0.56
1403.6334230	0.38
1404.8784180	1.02
1405.5931400	0.76
1406.9959720	0.08
1409.2518310	0.29
1411.6750490	0.35
1412.4669190	0.07
1416.0559080	0.21
1418.1658940	0.41
1421.0130620	0.32
1421.6156010	0.08
1423.6002200	0.30
1426.2821040	0.53
1426.9876710	0.97
1431.2473140	0.19
1434.5093990	1.92
1435.4615480	1.86
1436.3232420	1.08
1436.9532470	0.10
1442.6068120	0.49
1444.8568120	0.03
1456.2352290	0.31
1457.5361330	0.17
1460.6883540	0.46
1461.6512450	0.34
1463.0700680	0.35
1465.1608890	0.47
1466.3729250	0.52
1467.7513430	1.68
1469.5997310	1.28
1470.5882570	1.17
1471.2589110	0.35
1472.0028080	0.23
1473.2979740	0.17
1476.3676760	0.23
1479.2546390	2.72
1479.8656010	1.55
1481.3345950	0.23
1484.5029300	0.89
1486.7457280	0.22
1487.4166260	0.73
1488.0168460	0.11
1495.7186280	0.24
1498.3516850	0.35
1506.5567630	0.56
1507.6256100	0.43
1513.9373780	0.17
1516.4034420	0.57
1519.4627690	0.08
1527.9315190	0.08
1533.6612550	0.30
1541.0766600	0.21
1548.0970460	0.16
1550.7395020	0.95
1551.7269290	0.52
1554.0548100	0.09
1554.7005620	0.37
1557.9855960	0.56
1558.8612060	1.11
1560.8385010	0.40
1563.4215090	0.16
1564.2564700	0.70
1568.6671140	0.24
1570.2233890	0.91
1572.9354250	0.27
1575.5252690	0.06
1587.4598390	0.27
1590.7044680	0.47
1596.7250980	0.10
1597.7891850	1.16
1601.6694340	0.22
1602.6810300	0.35
1604.2291260	0.23
1609.4039310	0.40
1616.2608640	0.59
1624.2077640	0.15
1644.2985840	0.13
1649.1878660	0.26
1651.5721440	0.06
1653.8204350	0.64
1663.4792480	0.15
1673.3927000	0.07
1674.0847170	0.56
1682.2271730	0.42
1684.4110110	0.18
1687.4797360	0.39
1693.6441650	0.20
1704.7147220	0.80
1705.5797120	0.20
1711.9056400	0.28
1723.7999270	0.10
1726.5067140	0.12
1743.3660890	0.46
1767.8537600	0.12
1780.8763430	0.25
1791.9246830	0.23
1796.2590330	0.07
1799.3020020	0.14
1802.9528810	0.12
1809.2340090	0.06
1818.0552980	0.14
1829.3239750	0.20
1839.6320800	0.05
1858.6800540	0.24
1879.2248540	0.27
1900.6014400	0.06
1908.9581300	0.19
1914.5255130	0.11
1928.5134280	0.09
1940.9632570	0.05
1968.4544680	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	650.2132
Annotation	Unknow
Peak:m/z	Relative Intensity
221.1528625	0.14
281.1147766	0.19
282.2196655	0.03
308.0845337	0.07
323.3717651	0.35
341.0319824	1.00
341.6640015	0.05
345.2144775	0.06
366.7626343	0.02
383.3920288	0.13
392.2385864	0.03
405.0562744	0.07
424.9769287	0.06
442.9902344	0.23
443.7010498	0.03
457.6146851	0.04
466.8946533	0.03
487.2998657	0.05
503.2339478	100.00
504.3206177	16.62
511.2482910	0.04
517.3602295	0.06
589.4833984	0.09
590.2669067	0.18
631.3037720	0.08
632.2890625	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.0983
Annotation	Deacetylasperuloside
Peak:m/z	Relative Intensity
113.0045166	1.64
114.9484024	0.03
120.9422455	2.35
126.9751663	0.03
128.2485809	0.05
129.0324249	0.08
130.9450989	0.08
156.9442444	0.15
163.9684448	0.01
167.0754700	0.04
175.1412659	0.75
181.3259125	0.02
183.1367035	0.05
188.9085999	0.04
191.0873413	0.20
193.2237854	0.10
197.1665039	0.10
202.9621429	0.10
205.0318298	0.04
208.2530975	0.06
209.0445709	1.46
223.1015930	0.38
225.2572021	0.07
231.1024780	5.70
239.2080994	0.08
242.4229736	0.02
243.3748169	0.06
249.0657349	100.00
249.6690674	0.09
251.0596008	0.10
254.1378479	0.04
254.9759827	0.03
255.8915710	0.18
265.3083801	0.04
267.2759094	0.08
277.4117432	0.04
281.0209351	0.19
283.3242493	0.12
284.9736633	0.04
291.2686768	0.03
294.9459839	0.09
297.1343384	0.03
308.3864746	0.07
309.1832275	0.22
311.3158264	0.30
318.4255371	0.28
325.1040649	0.54
326.1970825	0.09
327.0402832	0.58
329.5614624	0.06
333.3199768	0.09
334.6228027	0.23
335.2495728	0.68
338.5095215	0.10
341.4500732	0.06
352.1713562	0.13
353.1824951	3.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	500.1693
Annotation	Unknow
Peak:m/z	Relative Intensity
143.0070343	0.05
144.0608978	0.04
160.9687805	2.41
162.0296478	1.69
162.9604492	0.02
174.9054565	0.04
178.9805450	6.16
187.1866302	0.02
191.2164612	0.02
193.1009827	11.73
203.0559387	0.11
214.9439087	0.21
220.2899323	0.10
227.0518799	0.12
233.0526428	1.27
245.2160187	0.06
247.1404114	0.05
251.2927246	0.02
267.7943420	1.14
268.4424438	0.01
272.5898743	0.07
274.0159912	0.03
290.0947266	0.42
291.0964661	0.39
294.1770020	0.02
295.0736694	0.08
308.0835571	100.00
314.1583557	0.06
318.3534546	0.11
320.3241882	1.18
328.1192627	0.04
329.1269531	0.04
337.4323730	0.04
338.4612122	0.18
352.0721436	0.05
353.1427612	0.11
356.3454285	0.04
366.9800415	0.02
371.0335083	4.01
374.1638794	0.17
376.0292664	0.18
385.0818176	0.07
391.6526794	0.18
392.3568420	0.22
396.3913879	0.02
401.1781311	0.04
406.1850891	0.07
408.1759949	0.08
416.1040649	0.08
418.9288940	0.08
425.2804260	0.78
425.9496155	0.06
430.8184509	0.11
438.0249939	0.04
442.1332092	0.24
454.2913818	0.14
457.2834167	0.06
463.2922058	0.01
463.9124146	0.05
465.3055725	0.04
479.0923462	0.12
482.5025330	0.85
483.5153503	0.18
490.3092346	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
126.101387	6.38
130.7660828	12.90
165.2659454	18.94
199.1161194	11.59
202.3591919	5.78
258.3916931	4.72
265.1707764	11.27
286.0829468	7.66
299.2180481	3.11
305.0760498	2.21
307.2504883	3.22
317.1159058	4.99
330.331543	11.05
343.4083252	7.40
345.3032532	4.31
347.1599731	8.64
352.0303955	1.82
363.1128235	11.06
365.7070312	4.68
367.1848145	14.32
368.0710754	14.95
377.4408264	4.89
380.1439514	9.63
385.0903015	17.84
390.9659119	8.83
394.4156799	6.26
408.2843323	100.00
409.1725769	14.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1609
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
119.2197113	0.07
130.9632111	0.07
131.9290466	0.05
134.8676147	0.02
137.1763306	0.03
161.0974274	0.22
179.1808777	0.07
181.1540527	0.36
193.1728210	0.02
197.1593781	15.37
203.2757568	0.09
204.7553711	0.25
205.8163147	0.05
221.0831909	0.17
223.2096252	0.35
225.1684570	0.04
226.3416443	0.04
234.2542114	0.04
241.0942078	100.00
241.6991882	0.30
245.1856689	0.03
247.1913147	0.06
265.1404419	0.27
270.3501587	0.03
283.0597229	1.30
288.9717407	0.04
295.1493225	0.10
297.2601929	0.03
305.0982056	0.16
313.0614014	0.60
321.1654968	0.05
325.3601685	0.03
343.1939392	1.79
356.3253174	0.19
357.0660400	0.74
359.3034973	0.05
367.3451233	0.04
384.9322205	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0851
Annotation	7-Methoxyisoflavone
Peak:m/z	Relative Intensity
76.85585022	0.09
103.1106567	0.06
104.9036713	0.25
107.5948792	0.43
128.9812469	0.93
129.8616028	0.93
133.1950836	0.25
141.7089691	0.22
143.0944977	0.08
148.0851593	0.22
151.0316772	10.96
152.0398407	7.31
153.0621643	0.59
155.243042	0.52
158.2809601	0.46
166.1880341	0.36
167.0753479	0.24
167.9053802	0.43
168.7503357	0.06
170.122406	0.28
170.9917145	0.38
180.0457306	0.49
181.2046051	0.13
183.0296478	0.11
183.9913177	0.17
185.143692	0.18
185.8030548	0.08
194.0401917	0.42
196.9810028	0.59
198.263504	0.47
199.0711517	0.30
206.0187531	0.34
208.3296204	0.33
210.5026245	0.07
212.2680206	0.24
225.1399078	1.35
226.1676025	0.90
227.3029938	0.21
235.0986481	0.05
236.02771	0.35
238.1403198	2.00
239.1394196	4.05
240.2307129	0.23
251.0570526	0.65
253.0765533	100.00
254.1842651	17.15
255.3438721	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
78.85803223	3.30
84.70789337	1.13
94.94624329	3.11
96.73439026	1.03
98.89254761	2.22
102.8654022	2.88
106.8831024	2.46
108.9219208	1.51
125.7650299	1.21
128.8597107	16.55
129.9677734	0.66
133.3629761	2.03
135.0262604	3.49
136.8703766	2.98
141.2097015	2.21
148.9141388	5.66
151.0058136	74.75
152.1313324	7.45
152.9864807	5.47
153.9597626	3.90
155.1355133	5.44
161.1044769	11.72
163.0868378	0.72
167.7963257	1.14
169.2110748	3.17
171.1369324	5.03
175.0899963	4.75
177.2238007	1.37
179.1779633	1.33
183.0020752	6.22
185.2252655	1.68
190.175415	1.20
192.6177368	1.26
193.3260803	6.10
194.3068695	0.66
195.1456757	5.00
196.9415588	33.69
199.5375519	5.32
207.2400055	8.12
208.249649	1.49
210.0666199	3.31
211.1377869	3.33
217.2621155	15.83
218.1414642	1.57
224.5935974	2.19
225.1984253	19.67
226.1017303	3.07
229.0158234	1.14
232.1186066	9.48
233.9019012	2.32
235.1975861	57.05
238.0767822	14.13
239.1143341	2.71
253.0859528	100.00
254.0817413	5.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	460.77
Annotation	Unknow
Peak:m/z	Relative Intensity
206.7535400	1.98
208.8991852	4.08
212.7811584	0.24
244.3752136	0.47
265.3863220	0.20
265.9896545	0.45
287.0818176	0.94
290.7965698	63.70
292.8091431	100.00
299.0029907	1.08
324.8798828	0.37
340.7375793	2.95
368.9768066	0.29
370.2975159	0.22
374.6198425	7.00
375.9344482	22.30
376.7189026	53.20
377.3467407	0.25
386.6270447	1.22
400.7893677	4.47
414.7491150	0.89
443.1819458	0.26
444.3012695	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	368.12
Annotation	Unknow
Peak:m/z	Relative Intensity
105.1553726	0.04
116.0067291	0.07
117.2759247	0.15
119.9923706	0.27
120.7874298	0.04
131.9813690	0.15
134.0362549	0.75
136.9649353	0.06
141.0229187	0.06
141.8246460	0.13
145.1925354	0.07
147.2085876	0.14
149.0861969	0.21
151.8700867	0.04
158.9840393	0.06
162.1957092	0.12
164.0393677	1.93
164.9301147	0.25
169.9505615	0.24
171.0419006	0.04
177.1070557	0.07
180.6571045	0.28
181.2677612	0.16
182.2126160	0.14
183.0184784	0.07
185.1193542	0.04
188.9258728	0.18
191.9199219	0.05
193.2467346	0.05
194.9304199	0.04
199.1619110	0.47
200.9025726	0.22
201.9615479	0.04
205.1620636	0.04
206.0690002	0.04
207.8317871	0.10
210.0611420	13.24
211.1963196	0.30
212.8774109	0.22
216.0696411	0.07
216.9976959	0.74
217.7128601	0.15
218.9132080	0.23
222.3032837	0.05
225.9926758	0.59
228.0200500	3.20
231.3029480	0.09
237.2580566	0.07
241.0161133	0.20
245.9718018	0.55
247.0941467	0.09
250.3331604	0.15
256.2459106	0.09
261.0662231	0.05
264.5225525	0.08
268.2211609	0.29
272.1590271	0.26
273.3516846	0.17
278.2083740	0.96
284.1819458	1.74
285.7288818	0.06
286.8699951	0.34
290.3367004	0.13
294.2327271	0.04
296.3379517	1.48
302.3448486	0.63
304.0498657	0.05
304.9367676	0.05
306.0076294	0.18
314.2203979	3.35
315.2238159	0.09
319.3403320	0.06
324.4261475	0.08
327.1724243	0.88
332.0921631	12.45
332.7230530	0.20
339.3750610	0.08
346.1752625	0.30
347.0848083	0.19
350.1962280	100.00
351.1459961	1.87
351.8496399	0.25
353.0317078	0.03
358.1382446	0.08
359.0949707	0.18
368.3174744	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	628.4991
Annotation	Unknow
Peak:m/z	Relative Intensity
177.1972046	0.52
189.1476898	0.08
198.8451538	0.52
206.2648468	0.13
218.8141174	0.99
221.0021362	1.22
222.9313202	0.28
235.2313232	0.39
236.9540100	2.78
243.0346832	9.05
249.1778870	0.08
252.2765350	0.10
262.8642273	0.55
264.9610596	4.42
267.1231079	0.89
272.5192871	0.94
273.6060486	0.10
275.9896851	0.09
284.9262085	0.28
287.1018982	8.34
288.0577393	0.20
292.7873535	0.61
303.1848755	1.71
304.1790771	1.20
306.9171753	2.09
315.4981079	0.08
321.2950439	0.06
323.0845642	2.84
325.2956543	2.14
330.9826660	4.84
332.1556396	0.22
336.9946289	0.44
345.1373291	0.17
349.5738525	0.28
350.9677734	0.30
371.3510132	1.05
373.2251587	0.10
374.3065796	0.31
375.9684448	0.28
377.7254028	0.21
381.2180176	1.20
383.1373291	0.29
389.3565063	0.17
395.1961670	0.11
407.4993286	0.17
408.1138306	0.27
410.7204590	0.12
411.5222168	0.56
415.2893066	0.72
419.0031738	6.76
429.4121094	0.12
430.4174805	0.20
435.0916138	0.37
437.0360107	0.86
437.9479980	1.02
439.6083984	0.13
442.8409424	0.11
445.2021484	0.49
455.0936890	0.32
457.1920166	0.21
459.1018066	0.07
461.1517944	0.24
464.9388428	0.26
477.0762329	38.92
477.8375244	0.09
495.5010376	0.33
505.4660645	0.17
509.4362793	0.16
522.0162964	0.32
523.0853271	0.66
523.9598389	0.52
524.6996460	0.62
530.1078491	0.24
535.0186157	0.47
543.5772705	0.49
553.2153931	1.33
561.3288574	0.13
563.5582275	0.06
565.8930054	0.11
575.3991699	0.13
579.3457642	1.15
582.0151978	0.24
582.6342163	0.29
587.4082642	0.11
590.4797974	0.27
592.0432129	0.94
593.2760620	0.53
596.9253540	1.64
597.6531372	0.37
600.3847656	0.55
609.6908569	0.60
611.2348022	100.00
611.9274292	0.32
619.3967896	0.53
629.7836914	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	465.1029
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
141.0263824	0.30
149.7795563	0.19
170.9970093	0.35
185.1970825	0.16
238.0183411	0.34
238.8291931	0.06
247.1281738	0.20
254.8870850	0.08
262.1614990	0.05
264.4190369	0.15
271.2081604	0.09
289.7588196	0.10
297.1848450	0.33
303.1477966	100.00
315.0306396	1.12
318.2340393	0.60
327.0778809	2.71
328.1613464	0.25
332.2748413	0.29
335.3854980	0.22
336.2784729	0.73
341.5569458	0.94
345.1489258	4.39
354.9776611	0.10
359.4570007	0.26
367.2263794	0.17
368.3557129	0.15
369.2849426	1.91
375.0420532	0.48
381.0881653	0.49
390.4898376	0.17
399.2068481	1.02
407.4503479	0.25
411.2446899	3.55
416.8696899	0.44
419.6271057	0.34
429.0990601	3.77
447.1559753	18.44
448.5774841	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	641.1353
Annotation	Myricetin 3,3'-digalactoside
Peak:m/z	Relative Intensity
178.9912567	1.13
185.0821991	0.11
188.8813019	0.15
192.0354919	0.57
192.9557953	0.54
197.1469116	0.57
202.9437561	0.11
205.0632935	0.78
207.1188049	0.98
208.1394043	0.05
208.9191742	0.09
211.0008392	0.39
214.1148376	0.84
215.1157684	0.45
216.1943054	0.08
217.1295929	0.53
219.0017853	0.27
223.4164276	0.05
227.0647888	0.77
229.0867767	0.26
231.1190338	0.26
232.3901062	0.62
233.2320251	0.33
235.1749878	0.15
237.2542267	0.22
239.2642059	0.06
240.3269043	0.32
241.0801239	0.22
242.1017456	1.14
243.1540222	0.90
244.1670990	0.07
245.1632996	0.56
247.1897736	0.27
249.2660828	0.40
253.2799225	0.10
255.1803284	0.28
256.0722351	0.15
257.0943298	0.27
258.1672668	0.09
259.2225952	2.68
260.0304260	0.14
261.1700134	0.08
263.1675720	0.28
269.0364685	0.34
270.0329590	1.60
271.1520081	13.49
272.1576538	0.16
273.1378174	0.28
277.2427063	0.19
279.0214844	0.12
282.8439636	0.09
284.6077881	0.19
285.2562256	0.23
287.0980835	6.98
288.0473633	0.44
289.1303406	1.81
292.9255371	0.04
294.9302979	0.17
299.0369263	0.82
300.6317139	0.35
309.3479004	0.55
312.1039429	0.88
313.0747070	0.69
316.0487366	94.42
317.0875854	100.00
318.2192383	2.31
323.1518555	0.35
325.0222778	0.41
327.2208252	1.07
329.0902100	5.42
330.0502625	0.51
337.0488281	0.06
341.2189941	3.49
342.2844849	0.05
343.3259888	0.15
353.1850586	0.30
356.9752197	0.13
359.1777954	4.63
360.0622559	0.13
369.2339478	0.27
371.2650757	0.38
382.8995972	0.37
389.4013062	0.61
397.1312256	0.11
399.2586670	0.15
425.1761475	0.27
428.8813477	0.39
429.5227661	0.45
447.3504639	0.64
452.8186035	0.17
461.1206665	0.18
478.0499878	0.08
479.2085571	4.72
487.5743408	0.04
489.2005005	2.30
497.2935181	0.15
498.4780273	0.17
507.4385376	0.06
513.5251465	0.50
515.1513672	2.39
519.4380493	0.06
531.4493408	0.21
537.1283569	0.62
555.4841309	0.76
581.1765137	0.29
595.3016968	1.10
597.2373657	0.60
599.3340454	0.09
605.1668091	0.57
621.6206055	0.22
623.2258301	22.56
624.1879272	1.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1031
Annotation	3,5-Dihydroxy-6,7,8,3',4'-pentamethoxyflavone
Peak:m/z	Relative Intensity
131.0272064	0.13
142.7948303	0.04
185.0826416	0.12
187.0003052	0.06
191.0102386	0.12
205.3699951	0.05
211.1644592	0.07
219.1759033	0.21
225.9609222	0.06
227.0977478	0.06
229.2653503	0.01
242.9734497	0.10
246.9632263	0.06
247.5666199	0.07
249.8159180	0.05
255.4364929	0.02
261.2704163	0.12
265.0993042	0.14
269.3670654	0.06
271.0571899	0.03
272.4352722	0.44
275.2556763	0.06
283.1112671	0.06
284.0971985	0.03
285.1806030	0.06
287.3609009	0.05
289.3440857	0.22
296.9906006	0.18
298.1648865	0.27
301.6418457	0.04
303.4393311	0.05
307.2613525	0.06
309.7142639	0.08
311.1029663	0.48
311.9273987	0.28
313.2545776	0.98
317.1475220	0.25
321.2517700	0.05
323.3786011	0.03
328.3547668	0.07
329.2366638	0.48
331.3878784	0.02
332.1848145	0.05
335.2055054	0.07
339.0618286	0.49
339.7040405	0.12
341.1738892	0.20
342.0994873	0.07
343.1365967	0.13
348.3072815	0.04
349.5090942	0.04
353.3251648	0.10
356.2069397	11.95
357.3910828	0.58
358.1662903	0.08
359.2000427	0.57
364.1101074	0.18
365.0756836	0.14
366.0257568	0.25
367.2098083	0.86
368.0455627	0.07
371.1948242	21.19
372.5492554	0.39
373.2333679	0.37
375.2226257	0.06
384.7796021	0.63
385.4008484	0.39
386.2209778	0.04
386.9884949	0.06
388.1526184	100.00
389.2273560	0.44
399.6485291	0.12
403.4209290	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	603.0033
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
177.0338287	0.05
181.9467926	0.07
193.1461182	0.25
202.1776276	0.12
211.0579834	4.27
215.0395813	0.84
216.0453796	0.06
216.8312988	0.07
220.0776062	0.13
223.0631714	0.28
231.1436462	0.09
233.0155640	0.09
241.1550293	4.16
254.1398468	0.07
257.0417175	1.34
259.1087341	0.18
261.9420166	0.33
269.1260681	0.06
273.0254517	0.16
279.1212769	0.23
280.0514221	1.37
287.2138977	0.07
290.8588257	0.08
298.8658447	0.04
310.3530273	0.41
311.0094604	0.44
318.0036316	0.15
323.1026611	100.00
323.7712402	0.05
325.9740601	0.08
329.0990601	5.14
334.0867310	0.75
345.9444580	0.17
350.4004517	0.12
352.2811279	0.25
354.1704712	0.05
359.0917358	3.83
360.2518311	0.05
361.0355225	0.27
364.1104126	0.17
368.0587769	0.12
370.9258423	0.27
372.2318726	0.24
377.0647583	5.84
378.3333130	0.12
380.0304565	0.98
382.4527588	0.13
388.1175537	0.12
389.8857422	0.67
391.3268433	0.10
398.0244141	0.74
401.2011719	0.15
406.0884399	0.45
410.1217651	0.06
414.3164062	0.11
416.2281494	0.30
419.1455688	1.57
423.0656128	2.92
424.0585327	1.23
425.2367554	0.95
426.1246948	0.16
428.9446411	10.77
430.0915527	0.13
431.0997314	0.16
440.1728516	1.81
441.0820312	36.61
443.1697388	0.08
446.9582520	0.72
448.0536499	0.74
448.8915405	0.19
452.0018921	0.36
453.0182495	0.36
458.1186523	0.21
462.2346191	0.71
466.9255981	1.25
470.0636597	9.34
471.2988281	0.20
474.1975708	0.05
483.1217041	30.38
487.9793701	1.97
491.1372070	2.54
495.4249878	0.05
500.0697021	0.09
504.8037109	0.65
507.3038940	0.13
513.0526123	0.12
514.2199097	0.04
516.6027222	0.24
518.9224243	0.56
524.1034546	1.35
542.1267700	1.54
555.9160767	0.57
557.0893555	0.24
557.9282227	0.05
560.0702515	50.64
560.6803589	0.31
566.5166626	0.07
585.1464844	23.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.093
Annotation	5-(3',4',5'-Trihydroxyphenyl)-gamma-valerolactone-4'-O-glucuronide
Peak:m/z	Relative Intensity
128.9724426	16.09
159.1492310	0.24
160.9255371	2.10
173.0706787	0.41
178.1636963	0.17
187.0051880	2.88
191.0217896	0.12
193.0278320	1.39
204.9855499	100.00
205.9019775	0.35
223.1212463	86.29
244.8664246	0.09
261.0904846	0.52
283.2903137	0.15
337.2526855	0.35
352.3227234	5.50
353.2946777	0.30
355.2654114	0.30
367.0557556	0.44
380.8673401	7.91
381.5629578	0.05
382.2561951	0.08
398.1356812	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	512.4147
Annotation	Unknow
Peak:m/z	Relative Intensity
175.0877686	0.08
176.9040527	0.18
211.9995728	0.19
219.0520935	0.19
221.3009644	0.56
251.2991333	0.09
256.9808960	1.18
259.9909058	0.10
265.0637817	1.07
270.2630005	0.18
273.2763672	0.10
282.3459473	0.17
289.2710571	0.15
301.1094971	1.48
309.0898438	0.98
327.2260132	2.82
341.0874634	0.08
344.9337158	0.22
356.4540405	0.23
368.9285278	0.06
387.1621094	0.04
388.9593506	1.32
391.1741333	0.51
404.8125610	0.46
407.3023071	0.99
412.3884277	0.16
413.2874146	0.05
418.7013550	0.36
423.0777588	0.65
431.5672607	0.13
451.3140869	0.89
464.7701416	0.09
465.7467041	0.47
466.5569458	0.13
467.9230347	0.23
477.1085815	0.64
479.3224487	0.10
480.8947144	0.13
495.3328857	100.00
502.3377075	0.57
512.7866211	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	496.3
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0977631	0.03
177.1188049	0.03
197.0856781	0.10
199.7590942	0.05
213.1276855	0.14
221.3189392	0.03
235.4340820	0.10
259.5783997	0.15
263.5034790	0.07
271.0795898	0.45
291.5786438	0.07
297.1116943	0.03
309.0255737	0.03
327.2864380	0.03
363.9854126	0.06
366.8506470	0.16
373.2604980	0.13
375.2027283	11.19
389.2233582	0.09
397.3024902	0.16
408.7420654	0.05
414.1454163	0.10
415.2591248	0.05
417.2147827	0.16
435.6081848	0.28
441.3013306	0.08
443.2406311	0.03
447.4721985	0.27
450.5258179	0.17
454.4629211	0.45
461.0538330	0.03
465.4169617	0.18
477.3888245	0.19
479.1605530	100.00
487.2587280	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	582.0919
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0517883	0.05
190.8721924	0.31
191.8166504	0.08
209.1923523	0.04
211.0775299	0.05
234.0724182	0.03
238.1107483	0.04
263.3938904	0.05
270.2565918	0.02
272.8692627	0.05
274.0374756	0.09
279.4763184	0.02
287.2728882	0.05
288.3447876	0.04
294.0134888	0.03
301.2061768	0.01
303.3031006	0.03
309.2882996	0.02
323.0663452	0.04
325.1631470	0.05
326.0496826	0.04
327.5596924	0.02
333.2156982	3.58
338.0482788	0.03
358.1373901	0.02
359.1578979	0.06
373.8930664	0.04
374.9816284	0.02
378.5016479	0.06
399.2775879	0.07
401.4754639	0.02
402.2163086	0.36
411.1790161	0.06
413.1487427	0.03
418.0021362	0.17
419.1030884	0.51
420.1113281	3.48
425.4276733	0.02
430.0699463	0.04
449.4022827	0.03
451.3722534	0.04
452.3381348	0.01
461.0839233	0.15
463.3197021	0.69
467.4744873	0.04
474.1099243	0.07
477.3892822	0.02
479.1430054	0.03
481.5130005	0.04
485.4493408	0.02
490.6946411	0.04
492.0579224	0.29
495.1923218	100.00
502.0624390	0.12
507.3983154	0.02
510.4807129	0.06
520.9033813	0.17
522.4010620	0.04
535.1183472	0.35
535.8945923	0.07
537.2108765	0.26
538.5599976	0.20
540.3865356	0.22
544.3823853	0.10
545.0209351	0.08
545.8482056	0.05
553.3402100	0.04
563.2905884	0.29
564.1337280	0.31
572.1414185	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	223.0459
Annotation	Unknow
Peak:m/z	Relative Intensity
70.9660492	0.02
83.0178986	0.09
84.9025269	9.26
100.9661713	0.16
102.9646149	0.02
110.9429626	7.75
112.8557129	0.05
122.1273041	0.02
124.9591064	0.15
128.9408569	2.45
132.8995209	0.10
142.9517822	0.13
147.0521698	0.31
149.0147095	0.09
159.1436005	0.04
161.0617981	0.80
163.1768188	0.02
173.0593414	0.45
176.8645172	0.05
187.0171661	1.93
190.9935150	0.11
205.0115662	100.00
205.7611847	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	321.11
Annotation	Unknow
Peak:m/z	Relative Intensity
102.0108795	0.58
109.2476959	0.03
118.9743652	0.10
121.0637436	0.19
127.0041122	0.07
139.0356750	0.13
146.0590820	0.71
148.0315704	0.83
151.0592499	0.11
153.0050964	6.37
161.3002930	0.04
163.0781860	0.09
165.1608276	0.03
168.1229248	0.05
169.2822266	0.09
173.9180756	3.71
176.9738922	0.03
179.2742310	0.21
182.0294189	0.14
182.8584900	0.04
186.1242981	1.30
192.0598145	3.01
195.0521240	0.89
197.2156067	0.09
200.4174194	0.15
201.4076233	0.05
204.3049622	0.07
205.0731506	0.03
205.9214478	0.12
207.2958679	0.09
208.9800110	0.03
215.0516357	0.09
217.2631836	0.14
227.2513123	0.20
228.8276978	0.13
235.0100403	0.16
237.1849976	0.03
239.4606628	0.11
243.1524963	1.04
245.9827271	0.08
246.7592163	0.06
257.2285767	0.15
258.3603516	0.40
259.8425598	0.30
260.9730835	2.23
272.2909546	0.29
272.9945679	0.10
274.9812012	35.46
276.0289917	0.26
280.0090637	0.21
284.0770874	0.38
285.0498047	0.64
286.2483521	0.12
287.3285828	0.05
289.1014404	24.40
290.3347168	0.32
292.7708435	0.10
298.2919922	0.21
303.0111084	100.00
303.6734924	0.22
306.2025757	0.17
312.6148987	0.14
320.2693787	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	396.2026
Annotation	Echimidine
Peak:m/z	Relative Intensity
129.9204254	0.49
153.1841888	0.15
171.2127686	0.06
200.3692017	0.02
203.2200623	0.06
205.1854858	0.09
215.6060333	0.08
231.0766296	0.27
233.0327148	0.06
235.0408325	0.09
238.0492859	0.36
245.2011108	0.70
249.1076050	0.10
249.9453735	0.10
250.9070129	0.03
254.2152100	0.08
258.1947632	0.05
263.3276062	0.02
268.3442078	0.20
276.4981384	0.04
277.1156921	0.05
284.7042236	0.03
286.3665466	0.23
288.6320801	0.06
291.3823547	0.02
304.3547363	11.56
306.4934387	0.11
307.4187012	0.01
309.2799072	0.06
310.3660583	0.14
312.2720947	0.29
315.1716003	0.07
321.1333618	0.02
323.1921387	0.07
324.4203491	0.23
333.4337158	0.02
336.1482544	0.11
338.4085999	0.04
342.2328186	0.05
349.0300598	0.05
350.2874756	100.00
351.2158508	0.15
352.0935974	0.15
360.2731628	0.24
361.3171692	0.08
366.4174194	0.06
376.4530945	0.17
378.3644714	23.20
380.7726440	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	775.3389
Annotation	Unknow
Peak:m/z	Relative Intensity
225.3685608	0.02
317.3680725	0.02
369.3105774	0.11
373.2874756	0.03
387.2409058	100.00
388.2785034	6.27
410.8770752	0.02
470.1413574	0.00
493.4666748	0.01
494.2057495	0.01
497.5451050	0.00
514.9242554	0.06
525.0302734	0.02
531.7252197	0.03
580.3853149	0.01
595.2791748	0.78
596.1953125	0.06
598.9746704	0.01
607.2097778	0.01
613.3839111	0.01
621.1694336	0.04
622.6091309	0.01
677.0825806	0.01
694.2833862	0.01
714.5198364	0.02
729.2276001	0.01
731.7499390	0.08
754.9100342	0.04
757.3048706	0.05
758.5576782	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.0933
Annotation	3,4',5,6-Tetrahydroxy-3',7-dimethoxyflavone 3-glucuronide
Peak:m/z	Relative Intensity
149.1069336	0.03
151.0100708	0.54
153.1367035	0.04
162.0331726	0.10
163.1011658	0.04
164.0510864	0.05
169.1245117	0.13
177.1555481	0.02
178.9895020	2.17
180.3112030	0.03
181.1335144	0.03
183.0023193	0.06
187.0789185	0.02
188.9101105	0.13
191.4319611	0.06
192.0737762	0.02
192.9718323	0.04
197.1624298	0.14
199.3793335	0.02
200.8885803	0.03
203.2452698	0.06
205.2726288	0.02
206.1759644	0.26
206.9998779	0.31
208.9892273	0.15
214.4081268	0.04
219.2168121	0.10
224.0484924	0.05
225.0569153	0.01
226.2243195	0.04
227.1490173	0.10
229.1257172	0.04
231.0165405	0.05
233.1421814	0.25
234.9538116	0.04
237.2061005	0.05
241.1988525	0.04
242.1561127	0.36
242.8799896	0.15
245.1117249	0.13
245.9677582	0.02
247.2484131	0.09
249.1218262	0.12
253.1575623	0.02
255.0780945	0.03
258.0196533	0.08
259.1686401	0.25
263.2885742	0.04
266.8633728	0.03
268.2470703	0.02
269.1699219	0.02
270.1723633	0.64
271.1484375	2.41
272.3712158	0.12
273.3409424	0.13
283.0825195	0.04
284.5045166	0.01
285.1864014	0.10
287.0668335	1.27
288.2802429	0.36
289.0482788	0.08
291.3859253	0.03
295.2174683	0.03
297.1595459	0.10
299.3085327	0.21
300.9133301	0.11
305.0249023	0.01
311.0616455	0.03
313.2326050	0.46
316.1246948	100.00
317.0774536	31.51
318.0994873	0.17
322.0820923	0.03
323.2235107	0.05
325.2829590	0.04
327.5589600	0.14
329.2194214	1.18
331.3722534	0.03
335.2271729	0.02
339.2930908	0.02
341.2480469	0.58
343.0537109	0.02
344.3524170	0.04
351.3526001	0.02
352.5053711	0.01
355.0601196	0.02
357.7483521	0.35
359.2125244	2.03
367.1834106	0.09
369.1379395	0.28
370.1389160	0.01
371.0576172	0.15
377.6445312	0.01
379.4016724	0.02
382.0211792	0.04
387.5082397	0.02
389.2532959	0.05
390.0858765	0.02
395.2335815	0.72
399.4843750	0.03
400.1070557	0.09
401.1539917	0.04
405.1339111	0.08
411.2694092	0.16
413.4143677	0.03
414.4539185	0.14
417.0761108	0.11
421.3771973	0.05
423.3721313	0.02
424.4135132	0.11
425.5341797	0.14
433.3171997	0.02
435.3154297	0.12
443.2288208	0.14
448.1293945	0.03
449.3386841	0.02
458.2414551	0.07
459.3410034	0.13
461.2827148	1.28
462.4179077	0.03
470.8898315	0.03
474.4066772	0.08
475.4290771	0.66
477.2659302	0.39
479.2308960	13.95
480.0728149	0.09
484.3148804	0.04
484.9805298	0.09
486.2168579	0.02
488.5332642	0.10
489.5156250	0.01
501.4384766	0.09
502.1849365	0.05
503.1845703	3.05
504.3348999	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.32
Annotation	Unknow
Peak:m/z	Relative Intensity
219.1365509	0.32
225.2768250	0.04
253.0817871	0.17
254.4107513	0.07
255.7196350	0.09
277.4230957	0.48
278.3753052	0.94
279.4086914	0.96
280.2524414	0.92
307.1766052	0.27
319.1399536	0.09
337.2509766	0.24
403.4375610	0.25
409.4671021	0.11
416.2474976	0.31
418.2411499	0.19
430.4547729	0.44
432.6411133	0.33
447.3945312	0.05
473.3933105	0.16
476.8575439	0.10
477.4959717	0.09
478.5711060	0.31
489.0977173	0.06
492.1676636	0.17
495.3744507	0.27
499.8806152	0.14
502.3807983	100.00
503.3627319	42.25
504.0119019	0.09
513.1347046	0.22
514.4342041	0.50
516.1654053	3.33
517.2682495	1.16
517.9740601	0.22
519.2858276	0.08
524.4811401	0.24
525.3109741	0.14
528.6764526	0.39
533.4732056	0.08
545.1465454	0.83
563.3161011	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0877
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
107.1900635	0.05
122.8826447	0.59
124.8781738	0.14
128.8633728	0.14
143.2121582	0.04
151.2426453	0.06
152.9502869	0.08
167.0156860	40.76
181.0782166	0.08
188.3195038	0.04
190.9907227	100.00
195.1137695	0.12
205.0058899	0.03
205.9786530	0.21
207.1909790	0.19
209.1222534	4.33
212.9604492	0.06
221.1021729	9.78
226.9078979	0.01
233.1080933	1.09
239.0830078	0.39
241.4521484	0.03
251.0291138	0.84
255.3450928	0.05
257.1289978	0.04
262.8623962	0.02
267.1400146	0.13
269.0556335	6.96
270.1572266	0.18
280.9285889	0.04
283.3276367	0.09
285.1425476	0.27
297.1338806	0.02
301.0585327	0.03
311.1104431	2.57
313.1016235	0.09
314.0599365	0.04
315.0456543	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	508.2895
Annotation	FR901464
Peak:m/z	Relative Intensity
183.2173157	0.05
201.3097229	0.01
213.2559357	0.02
224.1665802	0.01
224.9598083	0.02
227.8757324	0.03
232.0977478	0.08
240.1813660	0.01
242.1793518	0.04
260.1774292	0.11
266.0082397	0.20
282.8594666	0.04
284.1987610	0.46
296.9089050	0.01
300.1746826	0.06
302.4197388	0.25
304.2823486	0.02
305.2460938	0.02
320.3328552	0.11
323.3649292	0.02
344.1576538	0.02
347.3244629	0.01
350.2513428	0.01
357.8661804	0.09
360.0506287	0.02
362.3140259	100.00
362.9306030	0.28
371.2819214	0.03
374.3734131	0.05
377.6794739	0.12
382.5993347	0.05
385.3656616	0.02
394.4683838	0.03
404.4364319	0.20
405.9413757	0.05
407.5838013	0.04
412.1512756	0.08
416.3297424	0.05
422.2881775	0.08
425.9710999	0.10
427.3314819	0.07
434.3955383	0.03
439.4071045	0.02
441.7615051	0.07
446.5744934	0.02
448.2028503	0.10
454.4561768	0.03
463.1174622	0.02
464.8306580	0.06
466.1129456	0.02
472.5160828	1.58
473.2040405	0.01
476.1170349	0.36
477.2646790	0.03
489.8325500	0.45
490.4617004	2.04
491.4416809	0.01
499.0194702	0.04
499.9848938	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	496.4211
Annotation	Unknow
Peak:m/z	Relative Intensity
175.2347107	0.27
182.8666382	0.04
185.1398926	0.15
193.1221924	0.29
208.0367737	0.08
215.0928650	0.28
221.0811462	0.05
227.1664886	0.11
230.9300537	0.07
241.2378845	0.12
242.9207306	0.33
245.1320496	0.19
246.9427795	0.17
248.7267456	0.13
255.0186157	0.17
257.0354004	0.18
262.9534912	0.13
265.2630310	0.18
267.1743469	0.07
271.1201782	0.13
277.1364746	0.08
279.3587341	0.36
280.0200806	0.05
283.2071228	1.60
286.3767700	0.75
287.1549683	1.93
289.3001709	0.07
292.8417969	0.06
297.2010803	0.14
300.3733521	0.06
303.2974243	0.06
305.4039307	0.05
306.9324646	0.42
310.9571533	0.12
314.5746155	0.10
323.2610474	0.14
329.1427002	0.05
334.1419067	0.10
345.0344849	2.73
348.5264282	0.07
351.4873657	0.04
352.3643494	0.08
354.8267822	0.58
356.3473206	0.14
363.1892090	0.08
368.7012329	0.17
373.2590637	0.04
375.2497253	0.09
376.9489441	0.19
378.5381470	0.39
381.3852844	0.03
383.3315125	0.11
388.9739685	0.16
395.4508362	0.08
403.2076416	1.07
407.2019043	0.08
408.6260681	0.05
409.3278503	0.07
413.2278137	0.06
415.1530151	0.08
419.3374329	0.11
421.3720093	0.15
429.1721191	0.06
431.3474426	0.14
433.3056946	1.61
436.2718811	0.04
438.2584534	0.47
442.3656311	0.13
447.3767395	0.41
451.2463074	0.74
455.0437927	0.13
460.5320740	0.09
461.3878174	0.59
465.2917786	6.51
479.1747742	100.00
479.8355408	0.23
482.5103149	0.58
497.7631226	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.1
Annotation	Caffeic acid 4-O-glucuronide
Peak:m/z	Relative Intensity
102.7040253	0.06
127.1298218	0.10
129.0221558	3.36
145.3193054	0.07
146.9937286	4.65
149.0510559	0.71
154.3498840	0.08
162.8197632	0.46
167.1194153	0.13
173.0404663	2.87
175.2892456	0.10
178.0406189	0.29
183.0226135	0.08
187.2234802	0.21
190.9634094	100.00
193.0936890	31.30
209.0183716	72.51
213.3002014	0.31
214.9407349	0.26
233.3995667	0.10
234.1413879	0.09
240.3819885	0.04
241.1771545	0.07
283.2674561	0.04
287.3036499	0.33
292.8333435	0.09
295.4415894	0.03
309.0542297	0.79
310.3092041	0.09
311.2114868	0.35
319.4307251	0.29
326.7988586	0.34
335.9127197	0.17
337.1168823	18.06
341.1620789	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	819.3453
Annotation	Unknow
Peak:m/z	Relative Intensity
265.4752502	0.01
266.3324280	0.10
267.3040161	0.04
268.1950378	0.06
277.4032593	0.02
286.2717590	0.01
299.3217468	0.02
301.2497253	0.08
305.3621216	0.07
309.1569214	0.28
311.0857849	0.07
314.2460327	0.05
337.2613525	1.15
338.3917847	0.07
339.4396973	0.05
345.4177856	0.02
346.3848877	0.04
354.7818298	0.15
355.6174622	0.03
356.4921875	0.13
384.3564148	0.02
385.4138794	0.15
386.2984619	0.16
388.2134399	0.03
399.3623657	0.03
400.2197266	0.05
404.2174072	0.13
418.5324097	0.11
430.2441406	0.17
434.3517456	0.03
442.0407715	0.02
459.1382446	0.15
460.3767090	0.39
461.3169556	0.07
472.1680908	0.12
473.4417114	0.10
475.1619873	0.19
485.5203247	0.08
487.2804565	0.19
488.4570923	0.04
491.2570801	0.06
492.3715210	0.16
495.9243164	0.02
499.5409546	0.02
502.7466431	0.01
504.3321533	0.10
507.2951660	0.06
508.7407227	0.01
510.2658081	0.04
517.2869263	2.32
518.3491821	0.72
519.4107056	0.07
520.4044800	0.03
521.5582275	0.02
535.2600098	0.05
536.4408569	0.19
537.5060425	0.05
538.3654175	0.02
539.1353149	0.02
546.1853027	0.02
560.3659058	0.05
564.9024048	0.47
565.9039917	0.25
566.7772217	0.12
567.4326172	0.03
568.6724243	0.04
572.1184692	0.10
575.5318604	0.16
576.4246826	0.03
579.3649292	0.02
585.7443237	0.03
591.5695801	0.06
592.4328003	0.02
594.4464111	0.05
605.5753174	0.01
607.4679565	0.41
608.2390137	0.24
610.4708862	0.02
611.6078491	0.07
615.4630737	0.02
620.3594971	0.35
623.5197144	0.11
624.4454956	0.16
625.4888916	0.13
626.4733276	0.02
628.4282837	0.09
632.4882812	0.02
633.5565186	0.14
635.0872192	0.02
636.4790649	0.08
639.4592285	1.06
640.4078979	0.38
643.8919067	0.20
650.3422241	0.44
651.4081421	0.04
652.6247559	0.09
656.3353882	0.05
657.4396973	0.03
659.2905884	0.17
664.4169922	2.15
665.3571167	2.99
666.3265991	0.50
667.7598877	0.02
669.1300049	0.07
673.6682129	0.02
682.6755981	0.02
683.3552856	0.09
684.6862793	0.15
687.6448975	0.05
693.7243652	0.02
695.7098389	0.13
696.7885132	2.98
697.4573975	7.42
698.5333252	2.76
699.5112915	0.02
701.2018433	0.27
701.8563843	0.02
712.3440552	0.13
713.6588135	0.24
714.4845581	0.20
717.5975952	0.04
719.5910034	0.27
720.5548096	0.25
727.2884521	0.14
728.4282227	0.14
729.5435181	0.02
732.4774170	0.11
733.4600220	0.36
734.4811401	0.16
737.5043945	0.08
741.4931641	0.05
743.3745728	0.31
745.3554077	5.39
746.4656372	4.02
747.4655762	1.38
752.5017090	0.03
755.3923340	18.08
756.4575195	7.72
759.2875366	0.49
760.4655151	0.27
761.8900757	0.02
769.3490601	0.81
770.4129028	0.18
772.4239502	0.02
774.4655151	0.02
776.3439941	0.02
787.4082031	100.00
788.3932495	36.15
789.2797852	0.05
791.3063965	0.22
800.5706177	0.12
801.5815430	0.26
802.4412231	0.08
821.6463013	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.065
Annotation	2-O-Caffeoylglucarate
Peak:m/z	Relative Intensity
116.8924789	1.08
135.0488281	1.98
145.0352631	3.21
151.2232666	0.28
162.9670105	100.00
174.5459900	0.28
181.0869446	0.63
185.9902344	0.20
192.2599487	0.91
192.9747467	0.13
205.2054443	0.19
216.1875305	0.82
221.0975647	0.11
222.2335205	6.73
223.3858643	0.98
235.0755920	0.07
263.1293945	0.24
274.9436951	0.47
276.9228516	0.06
286.3457031	0.13
293.2948303	0.38
294.2746277	0.19
297.2528076	0.22
297.9418335	0.35
308.3088379	0.28
309.1476440	1.32
313.7630310	2.10
318.3569641	0.10
318.9686584	0.08
322.4276123	0.10
323.4005127	0.59
325.0787964	0.08
326.8402100	0.98
331.1779480	0.33
335.1973267	0.10
336.9519043	14.67
337.5962219	0.10
354.3687439	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	215.03
Annotation	2-C-Methyl-D-erythritol 4-phosphate
Peak:m/z	Relative Intensity
70.9710617	0.04
86.9914627	0.45
88.8711700	1.54
96.9335938	0.03
100.8923645	0.30
106.5958557	0.36
113.0250549	0.52
119.0068359	1.64
125.0785217	0.23
130.8121490	0.50
142.9803772	2.96
149.0398102	0.76
160.9756317	3.54
171.9396210	0.07
177.0845795	0.04
178.9263153	100.00
184.8218231	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	498.2686
Annotation	Unknow
Peak:m/z	Relative Intensity
172.8984985	0.04
177.0582581	0.02
183.7837677	0.03
215.9713593	0.04
231.1133728	0.08
269.3037415	0.05
328.3139343	0.02
333.1043701	0.05
336.2699890	100.00
341.4473877	0.01
356.3189697	0.14
360.4790649	0.20
375.2819519	0.10
382.4906006	0.02
390.4839783	0.07
398.5869446	0.04
402.0889587	0.09
408.1904602	0.08
409.4878235	0.08
417.1131592	0.17
427.6235657	0.01
431.2718506	0.04
431.9828186	0.04
439.3179932	0.08
445.2663269	0.08
461.4528809	0.06
462.4883728	0.16
480.3584595	0.73
481.3888855	0.22
498.2355347	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	743.1298
Annotation	2-O-Caffeoylglucarate
Peak:m/z	Relative Intensity
209.1012878	10.15
210.0504608	0.06
246.9574585	0.03
258.8884888	0.05
291.1383057	0.17
297.3178711	0.06
335.1109314	0.08
353.1416626	5.82
371.0867920	100.00
372.0646973	0.22
399.1470337	0.08
435.0992432	0.07
441.2598877	0.04
485.1559448	0.05
501.2581787	0.08
514.7700806	0.13
517.3383789	0.05
531.2619019	0.05
533.0454712	0.74
547.3422241	0.04
562.7634277	0.36
563.3735352	0.09
575.2226562	0.04
580.8319702	1.89
581.5637817	0.11
599.3631592	0.05
650.1348877	0.08
699.1387939	0.14
707.4760132	0.06
724.5526733	0.42
725.2011108	1.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	819.3452
Annotation	Correolide
Peak:m/z	Relative Intensity
235.2706604	0.03
257.2132874	0.53
299.2653809	0.09
301.2965698	0.23
309.3265991	0.12
321.8939819	0.17
335.1306763	0.21
337.2680664	0.93
339.3589478	0.15
358.2581482	0.07
373.4008789	0.10
385.7172546	0.08
386.3699341	0.08
433.5557251	0.24
435.4930420	0.05
450.3482056	0.14
456.2312622	0.08
460.0708618	0.60
480.3599854	0.06
484.4637451	0.18
485.2507324	0.04
487.3233643	0.55
489.6906738	0.03
490.6026611	0.07
492.5125732	0.64
502.4780273	0.09
503.4259644	0.08
504.5630493	0.14
506.5573120	0.14
516.7807007	0.12
517.4031982	3.96
518.1572266	0.37
519.3347168	0.36
521.5789795	0.13
533.4525146	0.22
535.3311157	0.31
536.3533325	0.14
539.3919067	0.04
545.4245605	0.06
547.4277344	0.04
563.5997925	0.05
565.5456543	0.36
575.5969849	0.15
578.3087158	0.61
579.3322144	0.16
581.4956055	0.09
592.1705933	0.20
593.2309570	0.12
594.6506958	0.07
597.1550293	0.13
604.2362061	0.05
607.3959351	0.56
610.4561157	0.33
611.1703491	0.16
613.5606079	0.26
616.2253418	0.19
621.5446167	0.18
625.1617432	0.06
632.4878540	1.11
633.3632202	0.68
636.5059204	0.10
637.3661499	0.11
639.2305908	1.32
639.8639526	0.13
643.5081177	0.10
651.3244019	0.75
656.3566895	0.04
657.4322510	0.36
664.2982178	7.94
665.4147339	8.63
666.7201538	0.09
667.4499512	0.08
668.3218384	0.23
679.2286987	0.04
681.6208496	0.18
683.4768677	0.19
694.7061768	0.67
695.4030151	3.48
696.3583984	2.45
697.3605347	40.91
698.5579224	0.23
701.5147095	0.25
702.7608032	0.06
711.3438110	0.13
713.5205078	1.11
719.2688599	0.65
720.4596558	0.07
727.4450073	0.79
728.7354126	0.06
732.4342041	0.07
737.6583252	0.33
742.2807007	0.10
743.5897827	0.47
745.3364258	2.82
746.4880981	1.71
753.7280884	0.13
755.3486938	20.26
756.1194458	0.41
758.3351440	0.11
759.5038452	0.48
763.4353638	0.31
769.3998413	0.42
770.5546875	0.18
774.4299316	0.14
775.5921021	0.64
782.5198364	0.17
783.3872070	0.08
786.3336792	19.75
787.3998413	100.00
788.0286865	1.01
789.5050049	0.05
791.4130249	0.34
800.3949585	0.15
801.0542603	0.22
801.9531860	0.15
803.9131470	0.03
820.0744019	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
127.0591202	0.88
144.9741669	0.49
150.9431152	0.38
155.0989685	0.27
161.2996826	0.42
167.0952148	0.38
173.0056763	0.68
187.0557251	0.65
199.0040588	0.34
201.1394196	0.30
205.3729401	0.66
217.4468384	0.34
226.1018066	0.39
229.002594	3.52
231.1028137	0.65
239.5528259	0.70
243.3968506	2.68
251.3586121	1.44
255.0667725	0.80
257.2926025	1.49
261.1148682	0.30
263.3831482	3.19
267.088562	0.87
269.5493164	2.35
271.163208	2.31
277.2047729	0.94
281.2369385	0.68
285.2009583	1.85
286.2394409	0.26
286.9501953	0.59
292.8467407	0.18
293.4867554	0.25
295.2848206	2.68
296.3253784	0.56
297.1537476	0.72
299.3433838	0.72
311.0651245	7.27
313.2790527	8.92
314.2685547	0.86
315.3510742	0.94
319.6743469	0.74
321.0249023	0.53
322.043396	2.93
323.3104858	5.35
325.4833374	0.80
329.3763733	1.60
339.2477112	100.00
341.2647705	13.51
342.1977539	0.73
343.2166443	0.58
357.2932739	0.39
359.8766785	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	495.1123
Annotation	Quercetagetin 7-methyl ether 6-glucoside
Peak:m/z	Relative Intensity
180.3833618	0.16
227.0535736	0.14
228.3533325	1.09
229.0888367	0.06
240.3535614	0.07
246.2158661	4.42
247.2319946	0.92
249.9999542	0.04
255.3457336	0.07
259.6089783	0.57
270.1007080	0.15
283.1142578	0.16
287.1438293	0.08
289.2484741	0.09
294.3468628	0.07
305.0840454	0.32
311.2445374	0.22
315.1660767	0.32
319.2234192	0.42
333.1232910	100.00
336.2976379	0.34
343.1379700	0.98
344.1628113	0.16
345.0888367	0.05
354.5275269	0.15
355.5024414	0.61
357.2156067	1.19
368.0745850	0.08
370.3292236	0.31
375.1631165	0.95
383.2799377	0.33
387.4474182	0.30
389.3797913	0.12
395.4586792	0.08
396.4180603	0.16
399.1016541	1.04
401.5309448	0.69
404.6615295	0.13
406.3704834	0.10
408.5841980	0.32
409.5063171	0.37
411.1118164	0.48
412.6492310	0.19
413.4772034	0.63
414.3506165	0.10
416.1158752	0.28
419.3496704	0.34
423.1550598	0.29
427.0364075	0.22
429.2762756	0.88
431.9351196	0.11
433.5161438	0.57
435.2668457	0.29
441.3013611	1.20
449.1350098	0.05
450.4084167	2.44
451.3663025	1.30
453.7333374	0.20
458.3179626	0.66
459.3358459	0.67
461.2183533	0.24
466.3147278	0.07
470.8977966	0.10
476.4076233	4.34
477.2843323	3.48
478.4100952	0.45
486.3579712	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	912.68
Annotation	Unknow
Peak:m/z	Relative Intensity
259.3713379	0.31
261.2337952	0.46
262.3610840	0.10
279.1086426	0.39
283.2039795	0.16
285.1413879	1.48
301.1484680	2.75
303.1207886	7.95
304.5491943	1.11
305.2943115	6.48
306.1562805	0.92
315.0203552	0.09
327.4183655	0.20
345.2936401	0.52
347.3645630	1.07
357.3323364	1.41
379.1994019	0.64
385.2889404	0.76
391.2248840	0.12
393.5549316	0.28
394.3522339	0.29
395.4917297	0.78
396.4057007	0.58
408.3471680	0.66
411.2595215	2.22
420.2533569	0.12
421.4492798	0.22
423.2230225	9.92
424.2542114	2.25
426.5978394	0.38
427.2518311	1.95
428.0560303	0.44
429.0859375	4.00
430.1434937	0.55
433.0426636	0.24
437.9394531	0.39
439.1804199	4.79
440.4451294	1.17
441.1975708	5.94
441.9762573	0.93
447.3738403	0.20
449.2088013	0.34
452.0070801	0.19
453.2802734	0.27
463.1964111	2.49
463.9211426	0.39
465.3516846	0.49
467.2626953	0.53
468.6199341	1.05
469.3193359	0.20
471.3005981	0.30
476.2487183	0.13
480.1931763	0.45
481.1957397	5.81
482.7398682	4.52
483.3961182	3.07
502.5025024	0.67
505.3211670	0.50
506.1335449	0.33
507.0653076	0.45
539.3903198	0.63
541.4147949	1.19
546.3811035	0.46
547.2238770	3.43
549.1394043	0.41
552.3706665	0.18
553.2785034	0.12
557.2853394	0.36
558.5299072	0.66
559.2450562	1.97
560.8253174	0.44
563.1155396	0.21
564.0529785	0.67
565.1195068	3.59
567.0938110	0.26
569.3020020	0.30
571.0642700	0.50
575.9589844	1.57
576.6456909	3.34
577.2758789	1.04
578.4595337	0.50
582.0548096	1.22
584.2572632	0.13
586.4067993	1.03
587.5864258	0.62
589.0390015	4.71
590.1387939	0.13
591.3368530	4.03
592.3639526	0.23
601.0412598	0.49
602.1071777	0.63
603.3521118	0.16
606.0619507	1.35
607.1650391	15.97
608.2362671	10.26
609.1819458	14.62
610.2078857	1.62
617.2676392	1.04
619.1452026	4.67
620.3033447	0.15
629.1264038	0.10
642.0147705	2.81
642.7706909	3.06
643.6055908	0.73
648.6393433	0.82
649.2579956	0.30
651.2432251	2.24
652.2802734	0.51
655.4954834	0.30
658.4694214	0.96
661.9233398	0.34
663.2514038	4.25
664.1997681	1.56
665.3805542	1.52
666.3194580	3.54
667.2655640	3.00
669.5797729	0.32
670.1859741	0.16
674.3936157	0.51
675.1646729	0.44
676.1790161	0.23
679.5045166	0.67
683.3436890	0.22
687.3884277	0.46
691.5961304	0.36
693.3150024	0.33
696.6643677	3.10
697.5338745	2.91
715.2218018	1.26
716.1932373	0.97
717.3097534	3.10
722.3468628	1.01
725.2334595	4.51
726.3385010	25.42
727.2265015	10.00
728.2211304	3.89
731.2463989	0.54
733.1439819	6.10
735.1181030	18.16
735.8937378	2.36
738.4038696	4.04
741.2868652	0.29
742.4385376	1.13
743.2568970	5.03
744.1944580	16.99
745.1420898	4.06
747.0646973	2.69
747.7180176	0.32
750.3099976	1.64
751.3788452	0.48
755.1464844	0.16
756.2969360	6.64
756.9078369	1.54
759.2585449	18.18
760.1328735	10.16
761.0003052	1.65
765.1027222	1.02
765.7685547	0.25
767.1272583	2.53
768.4035034	0.12
769.6715698	0.47
771.9323120	0.12
780.3782349	1.03
781.6058350	1.06
783.9771118	0.51
785.1003418	3.06
786.1409912	4.45
787.3307495	7.33
788.2498169	2.36
794.2540283	1.46
797.4360962	1.28
801.1065674	1.66
806.6840210	0.29
807.4296265	0.30
810.3043213	15.77
811.0939941	0.13
815.3894043	0.89
819.1157837	100.00
819.7630005	21.15
826.8882446	0.81
827.6310425	4.38
828.2383423	29.62
828.8485718	8.79
829.5521240	0.98
831.0917969	0.34
834.1981812	0.26
839.0791626	0.22
840.1954956	5.13
840.8815308	1.18
843.1931763	0.85
845.1051636	1.16
845.7790527	0.88
849.3587036	33.47
850.4921875	0.93
851.3904419	3.94
856.3440552	3.10
863.3969116	0.80
867.0704956	0.88
868.4136353	2.12
869.1777954	2.65
870.3819580	1.05
877.4137573	0.29
882.7901001	0.62
889.5585327	0.52
890.4313354	1.26
893.2119141	4.26
894.4049683	4.86
895.1978149	2.01
896.2639771	0.52
900.4989014	0.52
914.2153320	0.27
916.1657104	0.79
923.1511230	1.42
955.4365234	0.46
956.3799438	0.38
968.9816284	0.27
993.5459595	0.47
1005.3131710	0.82
1013.6915890	0.43
1015.2128300	0.37
1019.0551760	1.78
1022.0332640	1.32
1023.2336430	0.35
1028.9183350	3.88
1030.5444340	1.47
1031.3554690	2.33
1032.1469730	0.17
1035.0167240	0.52
1037.0759280	9.01
1038.2294920	1.32
1043.2795410	0.59
1047.3256840	2.30
1049.2014160	2.19
1050.1843260	0.85
1054.8410640	0.30
1064.7020260	1.59
1071.1547850	0.55
1073.3740230	0.64
1076.8350830	0.55
1078.2252200	0.41
1087.8532710	0.71
1089.1166990	4.05
1090.5745850	1.43
1091.2441410	7.13
1092.1503910	2.30
1093.1202390	1.43
1107.1076660	0.83
1130.7081300	1.05
1135.3322750	0.15
1152.4145510	0.31
1153.4252930	0.94
1154.5739750	0.61
1155.1865230	0.34
1166.8959960	0.79
1173.3129880	1.08
1174.0080570	0.35
1181.1848140	0.61
1184.3967290	0.66
1195.1558840	1.21
1197.2893070	3.82
1198.1669920	0.60
1199.3765870	5.04
1206.4663090	0.24
1209.2946780	2.46
1210.0979000	0.20
1211.1929930	0.50
1213.2668460	3.51
1214.4888920	2.84
1215.1228030	25.45
1216.2866210	13.38
1217.1806640	17.74
1218.2543950	7.14
1219.1298830	0.84
1232.5880130	0.24
1242.2949220	0.43
1251.3438720	0.69
1259.0881350	1.48
1260.4443360	0.64
1269.3542480	0.54
1272.4185790	0.62
1275.5118410	1.35
1311.2026370	0.43
1322.8004150	0.67
1323.6810300	1.27
1332.9173580	3.40
1333.5645750	1.59
1334.7014160	0.57
1335.5697020	0.56
1336.5389400	0.74
1338.3568120	0.56
1339.0002440	0.38
1340.9913330	4.47
1341.7064210	1.07
1342.4383540	0.51
1351.0936280	1.00
1353.3248290	0.16
1354.1202390	0.36
1358.9537350	0.52
1377.9471440	0.90
1393.2650150	0.80
1394.1025390	2.62
1395.1390380	8.42
1396.2689210	3.07
1397.7392580	1.24
1441.4871830	0.27
1471.5476070	0.58
1476.2618410	0.18
1477.2469480	1.39
1501.3084720	0.26
1502.6362300	1.23
1503.3239750	0.18
1504.2711180	1.26
1518.2592770	3.42
1519.2630620	17.16
1520.2152100	5.93
1521.1195070	12.45
1522.1470950	2.96
1523.4813230	0.67
1531.0687260	0.08
1545.0488280	0.26
1562.2399900	0.53
1563.1713870	3.52
1564.3491210	1.17
1638.3532710	0.39
1680.9241940	0.27
1698.9154050	0.54
1699.7532960	0.12
1700.4562990	0.40
1823.8092040	0.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	303.05
Annotation	DIHYDROROBINETIN
Peak:m/z	Relative Intensity
106.9122238	0.23
113.0411301	0.20
124.9846191	4.89
134.9050598	0.10
137.0808716	1.75
138.2618866	0.55
146.9625244	0.14
150.7470703	1.50
156.7946777	0.14
161.0908966	0.53
164.9475708	6.67
169.1065063	0.24
175.1175537	1.60
176.0597992	0.17
177.1016846	12.06
179.1331177	0.24
186.1173248	0.06
187.0171661	0.25
188.3155518	0.65
189.138504	0.33
191.1454468	1.83
193.0346375	1.00
197.2691345	0.17
199.0293884	2.33
200.312439	0.30
201.1705322	0.17
203.1539001	0.17
204.0851746	0.14
207.0794678	6.74
211.8823547	0.22
213.3667297	0.77
215.0700073	2.92
216.973053	7.86
218.0642395	0.18
219.0761108	4.65
222.9451904	0.70
231.1853638	2.94
232.4588623	0.42
233.1598206	3.66
235.0274353	19.27
235.6538086	0.39
239.1699219	0.49
241.1081543	29.41
243.0725098	1.52
244.1408691	1.56
245.0696716	1.19
247.1066895	0.36
257.1194153	10.88
257.8450928	0.13
259.1965942	58.86
260.0033569	1.97
261.0318604	25.23
273.083313	0.60
275.1699219	41.33
285.0351562	100.00
285.6998596	1.43
303.3380127	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	382.258
Annotation	Unknow
Peak:m/z	Relative Intensity
110.9779663	0.10
117.0379791	0.05
129.0345917	0.15
131.9110565	0.03
132.8786926	0.16
133.9398346	0.02
134.9796143	0.19
136.3445740	0.02
138.1228333	0.06
140.8978424	0.14
142.0222473	0.03
143.0229950	0.02
144.9642181	0.21
146.9551697	0.10
152.9160767	0.17
155.1811218	0.04
157.0574646	0.12
162.2989807	0.02
165.2019653	0.08
166.9149780	0.08
168.0631104	0.04
169.3201752	0.04
171.0194855	0.24
173.1347961	0.20
174.7991791	0.09
183.1606445	0.07
185.5005188	0.17
186.3756561	0.03
189.1085968	0.05
194.2006226	0.04
195.0046692	0.13
196.0801697	0.06
197.2976074	0.23
198.3319397	0.03
200.9530945	0.07
203.1408386	0.11
206.1643372	0.38
207.0318604	0.03
208.7839355	0.18
212.0936890	0.08
215.1703491	0.04
224.2840271	0.56
227.1828308	0.03
232.5299072	0.18
242.2261658	0.25
244.2284241	1.01
246.4147949	0.27
247.0346680	0.02
254.1925964	0.15
258.4069214	0.02
260.3153687	3.48
263.1819458	0.17
263.9924316	0.03
268.1646729	0.07
272.3161926	3.65
278.1550598	0.14
280.0934448	0.27
282.3305664	1.17
286.2114868	0.26
290.3555298	6.67
291.4775085	0.14
292.3745728	0.62
297.0645142	0.04
298.3356323	2.50
299.2205811	0.15
300.3891602	0.61
302.3693237	0.35
308.2734375	2.69
310.2952576	6.48
316.4411621	0.52
318.2988586	0.08
319.2363281	0.05
328.3892822	8.88
329.3172913	0.07
336.1636047	0.04
341.8588867	0.02
346.2714233	25.71
347.2353516	0.18
363.3059387	11.28
364.3071594	100.00
365.4154663	1.26
370.8567810	0.10
372.8580627	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	469.2946
Annotation	Unknow
Peak:m/z	Relative Intensity
133.1884003	0.06
153.9017792	0.05
173.2018433	0.07
176.9038696	0.08
184.1051025	0.05
191.2309265	0.09
215.2693787	0.10
217.0503540	0.08
220.9934998	0.10
225.1779175	0.33
229.6739502	0.31
231.4542236	0.11
235.1294250	0.09
239.4492340	0.04
248.9678955	0.10
251.0260925	0.20
251.6826782	0.77
252.5189514	0.02
253.1806641	0.03
257.2202759	0.05
265.0174866	0.18
269.1438293	0.33
270.1698914	0.40
273.5599976	1.82
275.9290466	0.04
277.0643311	0.02
279.1672363	0.16
295.2535706	0.23
297.9822998	0.23
304.4598999	0.10
307.0606689	0.11
308.8812256	0.05
310.1318359	0.16
311.9533386	0.52
313.1615295	0.59
313.9490356	0.03
317.6322021	0.65
319.8150024	0.90
320.5644226	0.17
333.7426758	0.09
339.3829956	0.23
342.0679321	0.76
348.2806396	0.14
349.0515747	0.05
352.9905090	0.50
357.0877991	0.03
360.9259644	0.20
362.1134949	0.15
363.5016174	2.15
364.3285217	0.50
369.3685913	0.11
383.1687012	0.10
385.5563660	0.06
389.5346375	0.03
392.3684692	0.06
400.5524597	0.57
401.2917175	0.29
402.2434998	0.07
408.8892212	41.82
410.0021667	0.26
410.9360046	0.36
411.7599792	0.06
413.5455627	0.07
414.2494812	0.09
415.2436523	0.05
417.5596924	0.03
419.8340454	0.05
421.8937988	0.34
433.3604431	0.16
438.9139099	0.27
441.6830750	0.18
451.1659241	0.96
452.0602722	0.93
453.0440979	0.13
454.5981140	0.14
460.8491516	100.00
462.9247742	1.46
463.8524780	0.63
465.0351257	0.17
465.9538879	0.11
466.5941772	0.05
467.2933960	0.09
471.0043335	0.07
472.8427124	0.11
474.0871277	0.07
476.4991760	0.11
477.1056824	0.03
485.0667419	0.12
489.6307983	0.09
503.2791138	0.21
520.3662720	1.08
521.5263672	0.13
534.9741211	0.05
546.8400269	0.09
551.3419189	0.02
552.6105347	0.07
564.3341675	1.26
565.4526978	0.31
568.4598999	0.10
597.5901489	0.18
608.4003296	0.64
609.3626099	0.31
612.4433594	0.09
621.7780151	0.10
635.6111450	0.19
640.1423950	0.06
652.4954224	0.29
653.3593750	0.05
656.4493408	0.23
665.3793335	0.07
667.1350708	0.08
679.2600708	0.05
682.2257080	0.08
683.6355591	0.03
684.5294189	0.04
700.5060425	0.38
701.3815918	0.48
711.4637451	0.03
728.0166016	0.07
744.4231567	0.34
745.5134888	0.16
756.5518188	0.05
773.5739136	0.03
788.2890625	0.13
789.2691040	0.03
799.4689331	0.58
800.3380737	0.36
816.4111938	25.48
817.5441284	13.40
818.5706177	0.03
883.9229126	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	511.12
Annotation	Unknow
Peak:m/z	Relative Intensity
153.2238922	0.33
160.9793091	0.27
163.2620239	0.32
167.1340027	0.69
173.0234375	0.10
176.1755981	0.36
177.1231537	0.41
178.8961182	0.24
183.2393494	0.04
184.0867615	0.22
191.1459045	3.53
192.0160065	5.83
193.0767365	0.75
207.2042236	0.65
208.1853943	0.16
209.0457153	0.35
209.9076843	0.07
225.0380554	0.08
228.5605011	0.34
230.9643097	0.15
238.9713287	0.19
244.8324280	0.05
254.1293335	0.06
264.3900757	0.07
267.0279541	0.44
271.1781006	0.12
273.0796509	4.51
279.3326111	0.07
283.3731995	1.26
285.3311462	0.83
295.0202026	0.41
299.2666626	0.27
301.0762939	16.42
302.2508545	1.17
303.0333252	1.11
307.1500244	0.06
308.1930542	0.17
309.1943359	0.16
311.1233521	0.45
312.3340454	1.58
313.3569336	0.59
314.2721558	0.08
325.3889771	0.20
327.1571655	17.06
328.2350464	0.13
331.3357544	0.09
332.4586182	0.17
333.6396484	0.09
335.2042236	0.08
337.6266479	0.46
339.1810913	10.63
341.0133057	0.21
343.3331909	0.51
345.3798828	0.21
352.3994751	0.48
354.9454346	0.22
357.2675171	16.70
358.4151001	0.06
364.4699097	0.07
365.5493774	0.22
367.2145996	0.09
369.2686157	0.08
376.8301392	0.17
380.9757690	0.21
387.2725830	0.38
393.4692993	0.10
397.3623657	0.35
401.3289185	0.10
405.0567627	0.05
409.2635498	0.06
414.9125366	0.06
421.0875244	0.04
425.2410278	1.40
426.0222778	0.28
430.2289429	0.73
431.0970459	0.30
432.5684814	0.26
433.2034302	1.50
435.2617798	1.32
437.1813354	0.15
437.9939575	0.09
443.2062378	0.10
444.7189941	0.05
449.4610596	0.49
451.2691650	0.56
451.8798218	0.53
453.5924072	0.06
457.3996582	0.51
461.2049561	63.02
462.2249146	2.29
463.2344971	1.08
465.1693115	0.13
466.3797607	0.52
467.1066284	0.18
473.7341919	0.77
474.3845215	2.06
475.4241333	1.27
478.1905518	0.70
481.3343506	11.36
482.5145874	0.28
487.8032227	0.24
492.4282227	6.95
493.3341675	100.00
494.2597656	2.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	807.3424
Annotation	Unknow
Peak:m/z	Relative Intensity
281.0288391	0.20
290.1240845	0.14
309.0325317	0.17
338.1904907	0.12
353.1690369	0.05
369.2576294	0.58
404.6363525	0.24
414.2229614	0.05
415.4425659	0.04
416.5200806	0.28
432.2583618	0.18
433.0583496	0.10
448.2907104	0.16
460.2824707	1.54
477.0952759	0.15
480.3876953	0.67
492.2868652	10.89
495.5595703	0.27
522.2224731	0.88
523.2442627	0.18
524.3591919	0.55
539.9442139	0.11
548.2276611	0.08
551.1372070	0.06
559.0785522	0.03
569.3119507	0.11
574.2769165	0.09
587.8265991	0.05
594.2371826	0.16
595.1919556	0.46
611.4490967	0.05
613.1851807	15.02
613.8705444	0.29
617.2418213	0.32
627.1470337	0.76
627.7681274	0.26
629.6073608	0.06
638.7006226	0.13
639.5140991	0.09
642.2368774	0.15
645.1532593	100.00
645.8433228	0.34
647.3068237	0.18
652.5386353	0.18
654.1849976	0.14
655.1540527	0.35
677.4098511	0.09
679.6472168	0.11
681.2661133	0.05
684.4170532	0.38
685.3173218	0.16
686.0828247	0.04
692.6376953	0.13
704.3528442	0.04
729.2943726	0.19
731.2865601	0.30
739.1439819	0.26
743.7211914	0.06
757.2474976	2.08
761.2395630	1.20
770.5838013	0.17
771.5424194	0.14
773.5337524	0.16
774.4967651	2.76
775.3257446	10.50
776.0335083	0.34
779.3166504	0.42
788.4722290	0.06
789.3973389	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	436.2683
Annotation	Anthriscifolcine B
Peak:m/z	Relative Intensity
135.0495453	0.03
138.7723846	0.05
149.1862183	0.10
150.2145691	0.02
168.8411102	0.02
175.2187500	0.04
178.9149933	0.18
183.0521240	0.03
187.2250366	0.01
195.1428833	0.02
197.4066772	0.01
198.5883331	0.02
207.1745605	0.02
216.8915710	0.04
219.0302887	0.03
220.9827881	0.07
223.1531067	0.02
243.2084656	0.11
245.1152344	0.07
257.2631836	0.05
261.5274963	0.03
265.4889221	0.05
267.2440186	0.13
269.2310486	0.14
273.1438599	0.04
279.0381165	0.10
281.2260437	0.08
285.1488037	0.13
289.0327759	0.06
296.2282715	0.02
301.1938477	0.06
308.7762451	0.05
309.4496460	0.04
312.8757019	0.38
313.5201111	0.07
315.1661072	1.89
322.5015869	0.14
327.3201904	0.08
331.2255249	0.04
340.5511169	0.03
344.3607788	0.03
346.0968628	0.03
347.1757812	0.07
351.4335327	0.15
354.3510132	0.03
355.4637756	0.02
357.6126099	0.10
365.2492981	0.15
371.7323303	0.19
373.0925903	0.15
383.4351501	0.05
386.8867798	0.19
391.1911011	0.17
393.3633118	0.03
398.4210510	0.03
400.3639221	0.02
401.1169434	0.04
401.8369446	0.03
405.1629944	0.14
417.6855774	0.49
419.1656799	100.00
419.8391418	0.11
422.1495972	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	591.2615
Annotation	Pheophorbide a
Peak:m/z	Relative Intensity
194.3632355	0.11
208.8726196	0.08
236.0058594	0.06
244.4483337	0.08
253.1808167	0.11
265.2642212	0.11
267.3662109	0.18
278.9409180	0.13
281.5430298	0.25
311.3844604	0.24
330.5462646	0.04
333.5840454	0.05
339.4426270	0.11
347.1442261	0.10
367.3668213	0.05
369.6011353	0.07
383.1434937	0.06
388.9324951	0.03
395.0957642	0.22
411.2271729	0.13
419.0323486	0.12
421.6557617	0.07
429.3771973	0.14
444.4654541	0.31
448.4663696	0.16
457.2753906	0.10
475.4751587	0.13
484.6062622	0.11
487.6652222	0.16
489.7080078	0.11
495.2687378	0.04
497.2717285	0.13
500.9602661	0.58
501.9570923	0.08
515.3648682	94.46
516.0953369	0.34
519.3545532	0.33
523.2246094	0.13
529.7256470	1.23
530.8086548	0.10
534.8434448	0.26
535.5441895	0.43
536.3635864	0.25
537.4581909	1.03
546.4819946	1.03
547.2813110	1.32
549.7300415	0.11
553.4027100	0.24
554.3818970	0.13
555.3335571	0.28
557.8358765	0.34
559.2628784	100.00
572.8088379	0.52
573.6527710	0.41
575.9179077	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	326.2
Annotation	Awajanomycin
Peak:m/z	Relative Intensity
131.9544678	0.54
136.9257507	0.55
151.2085876	0.42
153.1840668	0.03
158.0517883	0.11
163.1864319	0.20
167.0701752	0.48
168.2063751	0.10
170.1260834	0.46
171.0777435	0.25
172.3096924	0.22
174.4134827	0.07
177.1202698	0.27
181.1754608	0.13
182.0903015	0.03
184.2122040	0.12
184.9438171	0.14
187.0318298	0.07
193.2845612	0.04
194.9678345	0.43
198.1715851	0.09
200.1794434	0.25
205.4438477	0.14
206.4197388	0.12
210.2762756	0.12
210.9548035	0.10
211.8982544	0.70
213.1911011	0.41
215.0318909	0.39
219.0616150	0.11
220.2824402	0.43
224.1230469	0.10
226.3916321	0.26
228.1629944	0.15
229.3586426	0.36
232.9386597	0.11
236.8256836	0.39
238.3176880	0.08
248.6028748	0.17
251.1180420	1.08
253.7115173	0.10
255.1900024	0.21
262.2624512	0.19
263.1619568	0.22
266.3990479	0.08
268.1012573	3.93
269.2077942	15.70
270.2981873	2.20
273.3554077	0.14
280.2016602	100.00
281.2694702	0.24
284.9054565	0.91
289.2919312	0.27
290.2171936	1.94
291.1437378	0.13
292.3463745	0.09
294.9881287	0.36
298.2073364	0.29
302.7462769	0.21
308.1478271	57.90
309.1532593	1.86
312.2110596	0.19
317.7474060	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	442.0302
Annotation	Unknow
Peak:m/z	Relative Intensity
138.9666443	0.31
157.9801178	0.27
165.0803070	0.39
175.0134277	0.65
177.0717468	2.14
178.9765625	2.09
190.0899963	0.28
192.1331787	3.92
193.1827850	0.24
194.0089111	6.58
195.1496429	3.79
197.0242615	4.80
199.9968262	0.38
206.1803131	0.33
207.0409698	2.97
208.1716919	5.05
209.0710144	79.01
211.0362244	0.79
222.8775940	0.60
224.1085205	0.29
239.1083374	38.19
240.8742371	0.25
248.1724854	0.25
252.1098938	0.56
254.2460327	0.29
254.9950256	0.55
257.2549744	0.10
259.1651306	0.45
264.0254822	0.46
271.6618958	0.11
272.9215088	34.46
274.3479004	0.12
287.2946167	1.21
288.3314514	1.27
299.2377319	1.55
301.1840820	0.94
303.1161194	0.33
305.9915771	3.74
307.0816650	0.09
310.9899292	0.17
316.3632202	0.52
319.5414124	0.29
321.1387939	5.57
323.0899353	0.93
337.1838379	2.00
338.2023315	0.88
344.2213745	1.30
345.1673584	0.47
353.3306274	0.61
355.1215210	100.00
360.3526611	0.13
367.2210083	0.15
369.4411926	0.54
381.0154114	13.81
381.6813660	0.50
394.9328918	0.87
398.0498962	0.62
423.3052063	10.84
424.2834167	8.15
425.2252197	21.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	486.1464
Annotation	Dasatinib
Peak:m/z	Relative Intensity
143.9279175	100.00
184.0394287	0.56
211.3328857	0.50
241.2224579	0.52
256.1904297	0.16
285.1049500	0.67
302.1242065	0.40
305.1692810	0.32
311.2235718	0.63
323.1144714	1.79
325.0339966	0.21
338.0515442	0.44
339.9332886	1.46
341.1282959	1.95
355.3755493	0.08
370.6490479	0.60
371.8824768	0.20
388.1766663	1.98
394.8457642	1.04
397.2843018	1.13
398.0635376	3.52
402.4015503	0.35
422.3326111	0.52
425.5681458	0.20
442.1680908	1.67
468.2421570	0.56
469.3380432	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.14
Annotation	Clitoriacetal 11-O-glucoside
Peak:m/z	Relative Intensity
171.1603699	0.07
173.1122131	0.10
175.9905243	0.02
177.3342590	0.05
179.0034180	0.21
180.1509094	0.06
181.1031189	0.08
191.0358124	0.83
193.9909210	0.12
194.9656677	0.05
196.2194672	0.04
199.2577362	0.04
203.1760101	0.49
209.1340942	0.75
215.1432800	0.32
216.2926636	0.03
222.0591736	0.02
224.0356903	1.01
231.3329163	0.04
235.0513916	0.15
236.1537476	0.06
237.1203156	0.36
238.8728333	0.48
245.1443329	0.03
250.2091675	0.13
252.2475739	0.39
259.1174927	0.10
263.0903320	0.06
265.0291138	0.56
267.1501465	2.02
277.1265259	0.05
278.1339111	0.49
283.4727783	0.05
287.0537109	0.03
293.2260437	2.04
297.1255188	0.15
300.1527100	0.02
305.1964722	0.38
313.0932617	0.15
319.2725220	0.07
323.1527100	0.04
324.1734619	0.07
325.4840698	0.07
326.0902710	0.12
327.0814819	0.02
330.0242920	0.05
331.2514648	0.05
334.9448242	0.08
338.8078613	0.23
340.0125122	0.47
340.6945190	0.05
342.0879517	1.11
343.2294312	0.34
344.3715210	0.05
347.0270386	0.11
351.3159180	0.71
352.2672729	0.78
353.3619385	17.75
354.2039185	0.18
355.1693115	0.94
356.5229492	0.65
357.2343140	4.82
358.3126221	0.43
359.3463135	0.25
360.2000122	0.29
366.3906250	0.41
367.2402344	0.31
368.2067261	0.09
369.3046265	0.75
370.1124878	0.07
371.2263184	1.33
372.0041504	0.11
373.1807251	2.08
374.1043701	0.36
375.1673584	0.50
377.3012695	0.11
378.6001587	0.12
379.2891235	0.20
381.3297729	0.26
382.1089478	0.57
383.0997314	0.23
384.2327881	1.25
385.3598633	0.87
387.2515259	3.42
388.1591797	40.30
389.1600952	100.00
391.3343506	0.06
396.4730835	0.06
397.2755737	0.15
398.1466064	0.34
399.1359863	5.45
400.2910767	0.18
401.2438354	2.50
402.7259521	0.22
403.3765259	0.35
409.3370361	0.05
410.0348511	0.03
411.1881714	1.80
413.2205811	1.38
414.7300415	0.22
415.5131226	0.31
416.2002563	0.11
418.9386597	0.10
419.5567017	0.23
420.4409790	0.27
425.1932983	0.08
429.1500244	0.52
431.1194458	14.24
431.7514648	0.02
436.3134155	0.09
441.1491699	0.13
443.1333618	3.49
450.3981323	0.23
454.0111084	0.03
457.3779907	0.22
459.3117065	0.51
460.8870850	0.37
464.3364868	0.12
468.1636353	0.22
469.0818481	0.06
471.1694336	0.05
479.1154175	0.04
483.0596313	0.16
485.2138062	0.06
488.4950562	0.06
490.7480469	0.07
491.3523560	0.10
501.0631714	0.12
504.2155151	3.15
505.2779541	0.74
506.2815552	1.36
507.2897339	0.68
508.6220703	0.23
511.9871216	0.06
513.3577271	0.05
514.2849121	0.82
515.3380737	0.43
519.1563721	3.93
519.7681885	0.08
528.2017822	0.16
532.0428467	0.13
533.2527466	0.48
536.2256470	0.24
536.9685669	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	984.2511
Annotation	Unknow
Peak:m/z	Relative Intensity
281.9837036	0.47
283.0710144	0.84
287.4859009	0.22
289.2245178	0.46
293.1711121	1.09
296.1412048	0.49
297.0658569	1.09
299.3315430	0.39
303.1062927	0.70
305.1768799	0.11
307.4505615	0.50
309.2394714	1.23
311.3833923	1.23
313.9291077	1.07
317.1103516	0.92
320.2207642	0.10
321.1243286	4.14
327.1790771	1.67
329.1810913	0.87
332.3584290	5.39
338.1770630	7.41
339.2557373	3.95
344.2270508	1.85
345.2852173	0.52
356.3003540	3.20
357.3352356	3.74
358.3733215	0.97
372.2421265	0.08
374.1713867	100.00
375.2626648	2.30
376.1855469	0.53
379.1215210	0.53
380.9596558	0.19
386.2210999	1.05
400.1079102	0.52
410.9495850	0.33
412.9797974	0.12
416.1862183	1.74
418.0909119	1.70
423.0388794	1.16
424.3248291	0.71
425.3544922	2.01
435.1810303	0.56
437.2315369	0.53
441.1137085	0.74
443.2965393	0.49
449.1156006	1.27
453.1486511	1.18
456.3750000	1.03
457.2507019	0.15
462.2978516	0.24
465.1896973	1.46
474.3215942	2.51
475.1672974	0.40
477.1325989	0.67
481.0187378	0.24
483.0037231	1.77
487.2565002	0.83
488.7486877	0.39
492.2913208	13.28
493.0671082	0.51
494.0859375	1.73
499.1954956	0.88
506.2573547	0.61
510.2120667	0.26
511.1544800	0.23
512.4652100	0.62
522.3508911	0.74
536.2388916	0.28
541.3551025	0.11
542.9616699	0.14
544.3806152	0.71
549.4377441	0.69
567.2978516	0.78
578.7888184	0.73
585.3297119	0.14
591.2988892	1.39
595.2489014	0.45
597.1168213	0.52
601.1258545	0.14
603.2586670	2.24
609.0844727	0.28
611.1821289	2.60
612.3769531	2.20
616.9113770	0.42
618.1995850	1.06
620.9127808	0.64
621.5212402	0.38
625.3546753	0.97
630.2407227	3.08
636.4237671	0.13
660.2196045	5.09
661.1923828	1.31
662.4270020	0.71
663.3350220	0.65
671.9885254	0.14
675.9309692	0.89
677.0518188	0.18
678.3175049	25.77
680.3845215	17.91
703.9631958	0.36
711.4256592	0.87
722.3383789	4.15
729.2340088	1.94
737.8067627	1.20
745.5939941	0.47
747.2747192	2.79
753.0462036	0.75
780.2039795	3.51
781.5131836	1.71
792.0179443	0.13
798.2391357	80.70
799.4051514	2.92
808.5892334	0.08
816.0516357	1.48
816.6866455	0.63
821.8173828	0.35
828.3026123	1.26
830.3950195	2.74
840.2508545	0.54
852.4019775	0.23
858.3928223	3.99
895.9560547	0.20
948.5529785	0.30
953.4278564	0.44
966.3452148	25.19
967.1246338	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	380.2631
Annotation	Unknow
Peak:m/z	Relative Intensity
108.9450378	0.23
112.8886566	0.04
118.9439774	0.03
126.1231155	0.02
155.0153809	0.01
156.2281494	0.04
161.1179810	0.19
162.9345093	0.04
165.0444946	0.36
171.1364136	0.02
172.0480194	0.06
174.1408997	0.14
182.1679382	3.50
183.1738434	0.30
184.9991150	0.11
189.0576019	0.05
190.0081482	0.03
192.1350403	0.26
197.9830017	0.02
200.1304626	15.41
201.1509552	0.56
209.1572571	0.06
218.1786194	100.00
224.0831909	0.06
224.9008484	0.09
230.7638855	0.09
233.9814758	0.13
240.3139038	0.02
242.2295227	1.04
246.0517273	0.10
252.2598877	0.05
255.6380615	0.04
258.6307678	0.06
260.1990967	7.43
260.9615784	0.61
262.1754150	0.13
264.7228394	0.07
266.3386841	0.38
272.5411987	0.09
280.0743713	0.08
284.1774292	2.58
290.0743103	0.13
293.3472900	0.02
296.3366699	0.68
298.8555298	0.02
308.2814331	2.43
309.3436584	0.09
311.1889648	0.15
314.2265625	0.98
315.9678040	0.08
318.2144775	0.13
319.9929199	0.02
326.3057861	4.45
334.5487671	0.27
335.2687988	0.09
336.2051697	0.05
344.2442627	11.84
344.9595337	0.04
349.2906799	0.03
362.3806763	17.27
363.4122009	0.39
364.3743591	0.11
370.7340698	0.42
371.8581543	0.18
374.8561096	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1404
Annotation	Leucocyanidin
Peak:m/z	Relative Intensity
173.2926025	0.04
175.1335297	0.10
177.0726624	0.27
178.4631500	0.10
179.0986023	1.06
182.2723541	0.01
187.2714844	0.04
189.9672546	0.04
191.1702576	0.23
193.1557007	0.03
200.1979218	0.02
201.2099304	0.09
203.2017975	0.12
204.1705780	0.17
204.9166412	0.07
209.0024567	0.03
213.1664734	0.03
215.0066223	0.22
217.0511627	0.06
219.1260986	2.55
219.9404602	0.07
221.0990295	1.59
227.0128937	0.08
228.2808228	0.05
233.1722412	0.17
241.3941498	0.04
243.3179626	0.21
245.1290894	0.08
247.1036987	0.35
255.1145935	0.13
259.2307739	0.06
261.1430664	0.97
262.1159363	0.12
263.1820679	0.18
268.8602905	0.17
271.0328674	0.13
273.1389465	0.36
274.2752075	0.04
275.0687256	0.06
276.9290771	0.07
286.9686890	0.33
303.2194214	0.32
305.1115112	100.00
306.2219238	1.21
307.1837769	0.27
308.0492249	0.01
315.2933960	0.07
317.0767822	0.12
322.2679443	0.06
333.2741089	0.05
344.4166260	0.05
367.5722656	0.03
371.2324219	0.09
373.4027100	0.05
375.1004028	0.01
381.4053345	0.04
394.2109375	0.05
396.4522095	0.12
398.2404175	0.02
400.0399780	0.07
401.2805176	0.52
406.3560791	0.04
408.0383911	0.03
409.2995605	0.03
413.7803345	0.03
419.4595337	0.05
420.3670654	0.04
423.2745361	1.99
424.2894287	3.36
425.2362671	1.62
426.3170166	0.06
429.7116699	0.11
430.7897339	0.05
431.4042969	0.05
441.2222900	2.29
442.1386108	5.10
443.2286987	1.09
444.3300781	0.05
445.1129761	0.03
448.9887695	0.38
454.3906250	0.09
467.5722046	0.03
472.1302490	0.08
473.2065430	0.09
474.2730103	0.07
475.4746094	0.03
476.4024048	0.04
479.4730225	0.06
481.3947144	0.04
482.2835693	0.03
483.4346924	0.24
484.2749634	1.14
485.1640015	0.27
491.2713013	0.25
496.4499512	0.07
503.1242065	0.03
505.1583862	0.05
509.7101440	0.04
513.4769897	0.03
517.5115356	0.14
521.4755249	0.10
526.2509155	0.28
547.4519043	0.10
548.1703491	0.02
549.4075317	0.04
564.1192017	0.34
565.1729126	0.18
566.2184448	0.46
566.9766235	0.17
567.6099243	0.09
573.1098022	0.03
574.6924438	0.12
581.5092163	0.07
583.8840942	0.11
592.2630615	1.52
593.3223877	0.68
595.3757324	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.13
Annotation	Unknow
Peak:m/z	Relative Intensity
175.1407623	0.09
177.1162872	1.48
178.9860840	0.24
187.0562134	0.15
190.8842468	0.29
201.0407410	0.27
203.1459045	0.15
205.1583252	0.09
219.1412048	0.74
221.1878967	0.28
229.1669312	0.07
234.9167023	0.23
243.1216431	0.27
243.9936829	0.07
259.2333374	0.26
260.6390991	0.33
261.2727356	0.91
262.0931091	0.12
263.2612610	0.13
271.1047058	0.40
273.1021423	6.18
286.8999634	0.94
299.1874084	0.12
300.3100586	0.11
301.2161865	0.10
303.1210938	5.12
305.0734558	25.60
306.1576233	0.42
307.2211914	0.15
315.1130981	2.83
317.0908203	0.28
342.8580933	0.22
344.3027954	0.09
345.0619507	0.11
347.2556152	0.61
353.0162354	0.07
355.2890625	0.53
357.2600708	0.33
366.1070557	0.39
369.1619873	0.10
373.0283813	0.04
386.2787476	0.09
397.2423096	1.02
407.2078247	0.11
411.9197998	0.07
413.3447876	0.38
421.1399536	0.14
423.2414551	78.39
424.3297119	0.43
426.6922607	0.08
429.0477905	0.48
430.0997925	0.06
431.5802612	0.63
432.3187256	0.55
433.8695068	0.28
439.2180176	0.17
441.1091919	100.00
443.1830444	0.45
447.2957764	0.47
451.2011108	0.06
452.4729004	0.38
453.2318115	0.53
461.1898804	0.29
465.1970825	0.66
471.2308350	0.29
475.8696899	0.06
477.5245972	0.13
479.2578735	1.60
481.1577148	0.50
483.1021118	20.21
484.2273560	0.04
515.4264526	9.90
516.4323730	0.42
517.3859863	0.07
519.1179199	0.08
524.4248657	3.13
525.2803955	1.14
526.8619385	0.12
528.7855225	0.08
536.7231445	0.09
538.3633423	0.10
545.3775635	1.51
547.3939819	1.29
562.4974976	0.09
563.4231567	0.39
565.1749878	2.11
573.1614380	0.22
577.2649536	0.32
585.8874512	0.10
587.5264282	0.47
590.7012329	1.14
591.3132935	9.66
599.2144775	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1199
Annotation	Malvidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
173.1119385	1.35
179.0203552	0.94
191.0973816	18.33
199.1236572	0.10
204.9932404	0.22
207.0600433	0.18
209.1210632	4.02
211.3171997	0.07
223.3709106	0.05
229.0834656	0.29
233.2489624	0.14
245.0532837	0.07
247.1722260	0.11
253.3205261	0.16
257.0235901	0.34
263.1223755	0.58
267.3068848	0.08
270.8736572	0.29
273.2857056	0.17
276.1945190	0.15
282.4713135	0.11
290.4118042	0.09
291.2184143	0.47
297.2639465	0.06
299.9264221	0.41
301.0903320	0.72
302.1709900	0.80
303.3825684	0.14
304.0346680	0.35
304.9992065	0.14
308.9392700	2.27
309.6079102	0.05
334.9442139	1.89
338.1500854	0.17
351.1821289	0.14
353.0938110	21.25
354.5086060	0.10
364.8121338	0.06
366.5263672	2.30
367.4205322	0.93
368.2927246	1.50
369.1434326	0.81
371.1531982	11.12
377.4982910	0.18
378.9856567	0.09
383.4207764	0.30
384.7869263	0.25
396.5496216	0.23
397.1674805	19.00
399.2041626	1.24
400.2901611	0.06
405.1047363	0.24
415.0813599	100.00
420.0579224	0.16
428.1968994	0.15
436.0321655	0.24
438.7971802	0.37
439.8863525	0.20
441.0234375	0.12
455.2141724	0.13
455.8981323	0.39
460.5460205	0.20
461.4853516	0.46
464.1459351	0.57
465.2535400	1.05
465.9006348	0.17
475.1137695	0.06
479.2263184	1.52
480.3542480	0.46
486.3085327	0.79
490.4567261	0.17
491.4754639	0.18
495.0409546	1.38
496.0792847	1.29
497.2791138	3.64
514.4224243	0.17
515.5642700	0.63
516.4215088	0.88
517.6788940	0.70
521.4019165	0.07
529.4360352	0.10
530.1221924	2.23
531.1700439	4.79
533.0693359	1.51
533.6838989	0.19
534.5070190	0.15
539.2516479	0.66
540.2727661	0.16
541.2926025	0.59
545.2750854	0.46
546.6618652	0.29
548.8645630	0.10
557.1994019	0.14
558.3616333	1.30
559.1378174	6.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	395.1921
Annotation	Creoside IV
Peak:m/z	Relative Intensity
161.0938110	0.11
192.9176941	0.15
215.0306091	0.17
228.6380310	0.08
230.0475159	0.26
233.3846741	0.22
235.0979309	0.09
245.4545288	0.22
250.8892517	0.24
255.1020203	0.07
256.0976257	0.08
256.9743652	0.72
258.1839600	0.25
258.8917542	0.05
264.2538757	0.13
267.4412842	0.06
269.0644531	0.10
270.2748413	0.09
271.1816711	0.94
275.0256653	0.18
280.8378296	0.10
283.2087708	0.08
293.3001709	0.19
296.1809387	0.15
303.1869507	0.09
305.0353088	0.18
315.3311768	0.07
316.3841553	0.15
324.3807983	0.64
330.1899414	0.16
331.1005859	0.29
335.2440186	0.59
347.1201477	0.08
349.2345581	100.00
349.9614258	0.33
351.0879211	0.37
359.3017578	1.09
360.4106140	0.10
364.4973755	0.13
375.3743286	0.06
376.5594788	2.19
377.3195190	0.94
378.4086914	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1446
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
175.2455444	0.06
175.9172974	0.01
177.1422729	0.28
178.0677795	0.05
179.0810852	2.29
180.0557098	0.27
181.2158966	0.01
183.3253174	0.07
185.1004791	0.25
186.9824219	0.03
192.2438202	0.13
194.2238312	0.09
197.0512695	0.51
198.1384888	0.14
203.1076050	0.06
208.0549927	0.16
210.1394348	2.58
211.1325226	0.28
213.0122375	0.19
214.2860413	0.02
226.4556732	0.21
228.2120056	0.14
229.2349396	0.05
231.1505432	0.06
236.1772614	0.25
237.3344727	0.01
242.1327057	0.13
243.1062469	0.04
252.1638031	0.10
254.0997620	12.55
255.1093445	1.18
260.3519592	0.07
263.2783813	0.09
269.3231506	0.02
270.0406494	0.04
272.1428528	35.27
273.1306152	3.92
273.7602539	0.03
286.2168579	0.84
288.0607605	4.54
289.0667114	0.51
294.2299805	0.06
304.1395264	13.59
306.1335449	100.00
307.2026367	10.89
319.7191772	0.05
320.3265381	0.28
321.1458740	0.03
338.0627441	42.87
339.1986084	4.23
353.2774048	0.15
354.1409302	0.01
395.0651855	0.10
400.1797485	0.04
425.3573608	0.01
426.0078125	0.04
461.1505127	0.04
464.1294556	0.88
465.0249634	0.31
465.6419678	0.05
482.1531372	35.03
483.2368774	5.47
536.3657227	0.06
559.4628296	0.02
575.2592163	0.49
576.4005737	0.28
593.1339111	17.08
594.2592163	4.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	351.0755
Annotation	N-(Carbethoxyacetyl)-4-chloro-L-tryptophan
Peak:m/z	Relative Intensity
119.0752487	0.15
121.1807785	0.03
125.9675598	0.15
127.2509460	0.02
131.0101013	0.03
137.9705505	0.09
143.1038666	0.05
161.0264740	0.34
170.1083069	2.08
171.1109009	0.54
178.8836365	0.31
183.1378479	0.04
187.0991516	0.04
188.5817566	0.04
189.2232819	0.10
197.3478394	0.03
201.2095337	0.05
235.0621643	0.12
254.9403076	0.08
265.1815796	0.13
289.3323975	0.11
305.0812073	100.00
307.0418091	0.22
308.0794678	0.13
312.9058533	0.04
314.1528015	0.15
315.1668091	1.00
317.3407288	0.21
321.0375366	0.13
329.2279358	0.08
332.0898132	0.08
333.1923218	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	689.3389
Annotation	Unknow
Peak:m/z	Relative Intensity
198.7228699	0.04
207.1810455	0.28
274.9613647	0.04
319.2498169	0.03
324.3937378	0.03
357.4887085	0.05
372.9708252	0.02
421.0709229	0.10
468.5543213	0.02
477.0704346	0.29
478.4492188	0.04
479.2377930	0.29
481.3793335	100.00
482.0024414	0.20
483.3955078	0.06
485.0910645	0.04
491.3679810	0.24
508.4038086	0.03
509.2182007	0.05
523.3552856	0.31
527.1072388	0.12
542.1829834	0.06
544.4622192	0.04
550.5426636	0.09
554.4197388	0.01
561.2725220	0.05
566.6685181	0.09
567.2958984	0.03
575.4086304	0.02
626.3167114	0.09
629.1191406	0.24
638.1605835	0.08
641.0162354	0.06
643.1461182	12.92
643.7633667	0.16
644.7952881	0.12
645.4425659	0.09
651.2847290	0.24
652.4662476	0.05
653.4546509	0.03
657.0017090	0.20
657.6103516	0.01
659.5234985	0.04
660.8095093	0.06
669.0076904	0.07
670.4461670	0.18
671.2844238	0.23
688.6947021	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.09
Annotation	Spiraeoside
Peak:m/z	Relative Intensity
159.1108246	0.68
163.0473328	0.45
169.0213776	0.84
179.0930176	1.71
184.7231903	1.01
188.8902588	0.62
205.0157776	1.58
212.9595947	1.51
222.1228027	0.44
243.0890198	0.37
251.0066528	1.08
254.2357483	1.44
257.0785522	0.58
283.1409912	1.24
285.1500549	1.32
292.9333496	0.66
299.0088501	1.34
300.0380859	23.52
301.0393372	100.00
304.9388428	0.49
313.3127136	0.63
316.4967651	1.33
327.3950806	0.38
330.658905	0.19
337.0927124	0.74
342.9830933	1.15
350.31604	2.69
353.4515686	0.19
357.3460083	0.30
371.1757202	0.24
389.4782104	0.38
390.304718	1.43
392.9944153	1.08
395.0515137	1.39
399.4962158	1.61
403.410675	0.65
406.1202087	0.33
417.2565002	6.05
419.1992493	9.34
424.9522095	0.31
426.6031189	1.33
427.2862854	6.75
428.1372681	0.31
434.8494873	0.54
444.0749207	0.48
445.0690308	15.03
445.993988	0.92
447.258606	1.34
448.5535278	1.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1506
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
178.7543335	0.13
191.1237793	0.38
205.0473785	0.40
208.8869019	0.56
214.8548584	0.26
224.1291199	0.97
236.9053650	0.29
239.1495056	0.84
241.0717621	0.19
251.1303101	0.08
252.1573944	0.47
257.2537842	0.13
263.0676575	0.52
264.1511230	0.40
265.1944275	0.17
267.2391968	0.81
276.4614258	0.12
277.0838623	0.13
278.1355286	0.38
293.2045898	0.57
299.4453125	0.38
321.2900391	0.13
327.1534424	0.48
339.5112915	0.42
340.4592896	0.16
342.1351318	5.47
343.1180420	0.48
350.8677979	0.06
353.0859985	0.42
355.2602539	0.22
357.2149048	5.17
359.0011597	0.23
366.7783203	0.36
367.4672852	0.55
369.1334839	0.07
370.3212280	0.17
371.2043457	0.44
373.0554199	1.61
374.1532593	1.02
375.1470337	1.37
378.8640747	0.13
380.9763794	1.35
382.4608154	0.76
385.1187744	1.81
387.1761475	2.99
388.1666870	27.32
389.2091675	100.00
391.2587891	0.05
395.7114868	0.35
398.1336670	0.14
399.2650757	3.71
400.1484375	0.11
401.1859131	1.02
403.0195312	0.79
409.3884888	0.16
411.2139282	0.54
413.1625366	2.02
415.0355835	1.05
416.1172485	0.07
429.1614380	0.27
430.0089722	0.30
431.1435547	9.64
436.8560181	0.15
441.1328125	0.13
443.1710815	3.82
460.3740234	0.26
461.4835815	0.50
469.1200562	0.34
477.2970581	0.10
486.1603394	0.11
491.4058228	0.06
497.0284424	0.11
501.3956909	0.28
502.8136597	0.23
507.3152466	0.18
513.2787476	0.77
521.2539673	0.27
529.9476929	0.27
531.4403076	0.24
533.1122437	1.12
534.1005249	0.22
543.3655396	0.08
546.4451294	1.37
547.1830444	0.16
548.8710327	0.41
549.5755005	0.54
551.3192139	0.13
556.3322144	0.05
557.2283325	0.32
561.3099976	1.09
562.4401855	0.09
573.1540527	0.36
574.3151245	0.24
575.4396362	0.38
578.2927246	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1251.2893
Annotation	Myricetin 3-neohesperidoside
Peak:m/z	Relative Intensity
385.2692566	0.02
463.1492920	0.12
579.5411377	0.11
584.0370483	0.08
601.5974121	0.11
603.5199585	0.15
625.2474365	100.00
626.1962891	0.10
627.7678223	0.06
815.0133057	0.19
925.3995361	0.07
926.3073730	0.13
1140.4960940	0.04
1153.2646480	0.04
1182.2508540	0.06
1233.8474120	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
147.178894	0.43
155.2092896	0.32
159.1229248	2.19
171.2381592	0.53
185.0582428	0.82
187.1586914	2.09
189.1935883	0.21
198.9171295	1.46
201.0845795	0.69
213.2605591	0.21
215.2177734	1.58
221.7858582	0.36
229.2598877	0.64
231.312561	1.20
240.9980774	0.78
243.0551758	2.91
249.144104	0.28
255.1228638	1.64
257.2719421	0.84
263.2913208	1.48
265.1087646	0.40
267.213501	2.72
269.1967163	0.20
271.3326416	0.61
277.3415222	0.20
283.1973267	2.18
285.2798767	2.87
286.2191162	0.61
286.8487244	0.65
287.5040894	0.23
292.9096069	1.13
295.2876587	1.71
297.3633118	1.08
299.3022461	1.32
310.1098633	0.24
311.2241821	4.75
312.360321	0.29
313.2019348	4.17
314.8503418	1.88
315.4504395	2.35
316.1381531	0.35
317.0699768	0.34
321.1340637	1.95
322.0031738	2.24
323.3076782	10.24
324.9661255	1.61
339.2453308	100.00
340.0229797	0.37
341.3391418	8.18
342.1423035	2.29
357.6659851	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	208.06
Annotation	4-(2-Aminophenyl)-2,4-dioxobutanoate
Peak:m/z	Relative Intensity
93.2046356	0.01
102.9647675	0.01
108.7512207	0.01
130.9513550	0.09
133.2735291	0.03
145.9815521	1.85
152.0049286	0.01
160.1122284	0.01
161.0799103	0.01
166.8693390	0.04
173.1794281	0.01
184.7538757	0.05
187.4281616	0.13
189.7845917	100.00
190.8445892	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	593.275
Annotation	Pheophorbide a
Peak:m/z	Relative Intensity
209.1007080	0.01
210.1704712	0.02
253.3885498	0.04
259.1625366	0.02
265.1512451	0.07
267.2124634	0.04
268.8839417	0.02
281.9282837	0.01
286.0091553	0.02
293.3941956	0.01
295.1139526	0.35
305.0737000	0.04
310.2811890	0.04
312.0144653	0.02
313.3276367	0.19
317.1340027	0.02
322.5327148	0.06
330.4319458	1.19
331.3666382	0.02
340.3662720	0.40
342.1063843	0.04
343.2510986	0.03
352.9127197	0.03
355.4951172	0.06
356.8992920	0.02
358.1983643	0.09
359.2845459	0.05
365.5462646	0.01
375.2551880	0.03
376.9937134	0.02
377.6520996	0.02
412.3403320	0.06
429.6925659	0.07
431.2788696	0.05
431.8887329	0.01
433.3533936	0.17
434.3781128	0.04
441.3825684	0.05
444.5366211	0.03
446.5778198	0.01
447.6634521	0.10
448.3978882	0.06
449.5093384	0.02
458.1046143	0.01
459.4731445	0.34
460.5240479	0.66
461.5014038	1.05
462.3668823	0.19
463.5375366	0.10
464.4689941	0.09
465.5715332	0.02
473.3653564	1.70
474.5031128	0.56
475.4511108	0.08
476.5176392	0.21
477.1226196	0.09
477.7334595	0.17
478.6113281	0.02
485.2998047	0.10
486.3894653	0.08
487.4306030	0.70
488.5192261	0.41
489.5916138	0.17
490.3287964	0.02
491.4124146	0.32
492.4100952	0.89
493.5458374	0.59
494.7876587	0.05
497.3117676	0.08
499.4048462	0.02
500.3482666	0.05
501.3859863	0.04
502.4332886	0.07
503.4989624	0.41
504.3777466	0.12
505.2215576	0.42
506.3284302	0.19
507.6754761	0.02
513.7951050	0.04
515.4473267	0.93
516.5795898	0.65
517.4957275	0.27
518.5211182	0.47
520.1500854	0.76
521.4505005	0.72
522.4530640	0.21
527.1035767	0.04
531.3042603	0.15
533.3952637	100.00
534.3759155	53.48
535.4458618	4.49
536.6417236	0.09
537.3417358	0.06
538.4530640	0.01
543.4741821	0.10
544.4986572	0.15
545.2671509	0.06
547.3913574	1.97
548.3619385	0.86
549.3343506	0.22
550.5929565	0.09
551.4315186	0.28
552.4654541	0.18
557.8715210	0.04
559.0827026	0.04
561.3439331	1.89
562.4162598	1.06
563.4116211	0.13
564.3330688	1.61
565.3590088	4.26
566.4305420	1.75
567.4626465	0.17
575.3970337	2.77
576.6475220	14.02
577.4387817	0.07
578.3795166	0.28
579.1941528	0.05
580.4320679	0.05
593.3762817	2.16
594.3656006	0.18
595.5281372	0.02
596.4175415	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	469.1806
Annotation	Unknow
Peak:m/z	Relative Intensity
165.0574036	0.06
181.3724976	0.04
184.7709351	0.03
236.8737488	0.08
239.2611237	0.09
241.2141571	0.22
246.3180847	0.05
253.1194763	0.04
257.1905823	0.04
260.7964783	0.07
269.0796509	0.04
271.3748474	0.02
277.0877380	0.10
305.5247192	0.12
307.1235352	1.70
318.2928467	0.24
322.6100769	0.18
325.2533875	4.03
331.2310486	0.50
349.2443237	9.10
357.3348083	0.06
358.9629822	0.03
362.8569946	0.09
363.4570618	0.16
368.5976868	0.05
371.9556274	0.03
377.3156433	0.13
379.3795471	0.05
389.0880432	0.80
406.4801941	0.10
407.1398010	0.64
408.9125061	0.02
415.2955017	6.96
423.1206360	0.06
433.1773376	30.27
438.1970520	0.19
442.3356018	0.07
451.2419128	100.00
452.3150330	0.20
459.8889465	0.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	427.1559
Annotation	Chitobiose
Peak:m/z	Relative Intensity
149.9859009	1.04
152.0881500	0.15
156.2302399	0.09
166.9459839	0.13
182.8273926	0.07
190.9154663	0.20
208.0154724	0.15
212.8950958	0.06
218.7835083	0.04
228.9191284	0.26
247.1570740	0.05
259.0606079	0.16
262.3176575	0.16
265.0840759	0.10
269.0863647	0.26
276.3060913	0.22
278.0132141	0.67
282.2449951	5.55
287.3123779	0.53
288.8517151	0.23
295.0821533	100.00
296.9208984	0.35
302.8580322	0.03
306.7547302	0.33
315.5008240	0.08
338.0717468	0.07
339.2685852	0.50
344.3973694	0.13
346.7557373	0.94
348.2870483	0.05
352.9689636	0.49
356.3251343	0.09
361.0371094	0.09
366.2829590	0.10
368.0227966	0.29
369.1755676	0.04
374.2377014	0.19
381.0185242	1.68
382.0904541	0.33
382.7537537	0.59
385.4968567	0.24
391.1499939	0.49
393.8453674	0.51
408.1962585	0.40
409.2399292	3.60
410.2151794	0.12
417.6133118	0.16
418.3482361	1.04
435.9171753	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	334.2005
Annotation	Dipivefrin
Peak:m/z	Relative Intensity
95.8903885	0.23
97.7997742	0.06
104.7308731	0.17
106.0151138	0.38
106.9310760	0.13
108.0377884	0.78
109.0261688	0.03
109.9128876	0.29
112.1991043	0.31
113.8407745	0.13
114.8978882	0.27
116.9579315	0.56
118.0571442	0.18
118.9165955	0.03
120.0163498	0.45
122.0408630	0.24
122.7953262	0.06
124.0755768	0.21
125.9996262	0.74
128.1498260	0.17
128.9222717	0.70
130.0651855	0.73
131.0377960	1.18
131.9312744	4.68
134.0157013	0.50
135.1399384	0.23
136.0721283	0.39
137.1433563	0.18
138.0036011	0.24
139.0723877	0.08
140.9240570	0.45
142.0532227	0.20
142.9914398	1.27
144.0649567	0.12
144.9863129	0.58
146.0701904	1.58
147.1374207	0.31
148.1631470	0.60
148.8874817	0.28
150.2417603	0.60
152.1784973	0.20
153.0838318	0.32
155.6186218	0.61
156.2447510	0.25
157.0781555	0.19
158.0486145	0.63
159.0437012	0.15
160.1880798	0.38
161.1615906	0.23
162.1316376	0.39
164.1447754	0.34
165.2693176	0.07
166.3309479	0.22
167.1521454	0.38
168.0834351	0.18
169.1110535	1.05
170.1424866	0.95
171.1489105	1.15
172.1986694	0.19
173.0653687	0.09
174.0732727	0.21
175.1703796	0.52
176.0635834	0.57
178.1215363	0.10
179.0794678	0.20
180.1387329	1.49
182.0087585	3.61
183.1689301	1.18
184.2426300	0.04
185.1363068	0.25
185.8446655	0.20
187.0931702	0.95
188.2570496	0.18
189.1223450	0.55
190.1722107	0.28
191.0570984	0.31
192.7291718	0.05
195.0987549	0.39
197.2259979	0.26
198.1775665	4.47
200.6256866	0.41
201.2562256	0.54
203.3465271	0.03
207.1160583	0.39
208.3973389	0.25
210.1700134	0.15
210.9955139	0.61
212.1967163	0.43
213.0219727	0.62
214.1722412	7.37
216.1551514	0.39
219.0192566	0.41
221.0709839	0.33
222.1818237	0.06
223.2212524	0.12
224.2817688	0.63
225.1503601	0.57
226.2592773	0.44
230.1991272	4.01
231.0875549	0.04
232.2689514	0.53
233.1841431	0.20
234.2690430	0.05
235.0937195	0.16
236.1493530	0.13
239.3338623	0.07
240.3011475	0.52
242.2351685	27.92
243.1777039	0.42
244.3500671	0.82
245.2929688	0.25
247.0212097	0.16
250.1626282	1.37
252.2367859	1.48
254.2941895	0.31
256.2618408	0.28
257.2418213	0.15
258.3276062	0.62
260.2469482	21.67
261.4635620	0.28
262.2297974	2.30
263.1784363	0.93
268.2017212	7.67
269.4455566	0.13
270.2041016	2.21
271.2082520	0.07
272.1899414	1.78
274.2393188	0.48
278.4398804	0.14
280.2391357	7.56
284.7454224	0.10
286.2805786	12.94
287.2579956	0.54
288.1730652	1.53
289.0389709	0.15
290.2485657	0.07
291.5664062	0.13
295.6939087	0.38
298.2380066	24.61
299.2380371	0.34
303.1802979	0.07
304.3518982	0.17
305.1928101	0.14
307.6131287	0.04
314.2603149	0.18
316.2162170	100.00
317.2098389	3.19
319.3935242	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	319.0457
Annotation	Amaronol A
Peak:m/z	Relative Intensity
114.9013977	0.11
123.0983429	0.07
125.0533295	0.14
129.0785675	0.06
138.0975342	0.69
140.0509949	0.11
151.1507568	0.55
162.8291168	0.05
169.0911865	0.06
175.0710754	0.25
179.0999908	0.90
180.1609650	0.33
181.2129211	0.25
182.0683899	0.43
183.1523438	0.03
184.1482544	1.21
186.1170959	0.02
187.2775574	0.16
191.8607330	0.10
192.9726562	100.00
193.6577148	0.16
205.1862793	1.52
214.2847595	0.04
215.2017517	0.29
221.2445374	0.13
223.0359192	3.95
231.3601685	0.06
232.2106018	0.04
235.0552368	0.09
237.5418396	0.04
239.4284363	0.09
241.3229370	0.21
242.8559570	0.22
245.0775452	0.16
246.0847168	0.25
247.1488647	0.65
255.5086670	0.43
256.1775513	0.14
257.1351929	0.72
258.9421997	0.04
271.7407227	0.32
273.1485596	0.64
274.2753296	0.08
275.0429077	0.84
275.9551697	0.23
283.1599731	0.83
287.2190552	0.90
289.1706848	0.31
289.8820801	0.23
290.7702637	0.08
299.2465820	0.29
301.0747375	22.53
302.0097656	0.14
303.0219116	0.07
304.2004395	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.1505
Annotation	Benzyl beta-primeveroside
Peak:m/z	Relative Intensity
240.1910095	0.02
259.3936157	0.02
269.0321350	0.13
277.1738892	0.04
317.4966431	0.01
401.1894531	100.00
402.0421143	0.01
411.3748779	0.05
429.3217468	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	425.1663
Annotation	3-Methyl-3-butenyl apiosyl-(1->6)-glucoside
Peak:m/z	Relative Intensity
124.7676392	0.02
131.1953735	0.11
144.0006409	0.43
149.1001892	0.08
156.2996368	0.05
164.0783539	0.05
173.3541870	0.02
186.9780273	0.01
191.2154694	0.06
202.0469971	0.03
217.2971344	0.03
226.1645813	0.06
243.1655579	0.06
244.3918762	0.07
247.2119751	0.02
248.9428711	0.03
250.5550232	0.02
256.1112976	0.06
261.0599060	0.01
262.2211609	0.03
266.0334778	0.02
277.8060913	0.06
279.8574219	0.06
283.0214844	0.08
284.9495850	0.09
286.0835571	0.06
287.1638794	0.06
292.0643616	0.07
297.0399170	0.14
298.1145630	0.25
303.2972107	0.08
310.9730225	0.06
320.5082397	0.06
325.2365723	0.04
329.1183472	0.02
333.0711670	0.01
335.3677368	0.05
343.4067993	0.02
345.4692383	0.10
352.4987488	0.02
357.3294067	0.02
361.2431946	0.04
365.4378052	0.02
373.1842651	0.04
374.1699524	0.02
379.2878723	100.00
380.0455933	0.09
381.0759888	0.13
388.5062256	0.02
398.4241943	0.07
405.0414734	0.02
406.2769165	0.12
407.0934143	0.27
424.8592529	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.0619
Annotation	2-O-Caffeoylglucarate
Peak:m/z	Relative Intensity
110.9625015	0.02
129.0856323	0.39
147.0358276	0.32
173.0512695	0.06
178.8289948	0.34
185.2806854	0.18
191.0065460	12.25
204.4712219	0.06
207.0009766	0.09
209.0274353	100.00
225.3180542	0.03
227.1716919	0.05
254.9115906	0.02
267.2303772	0.08
279.2394104	0.11
290.2947388	0.03
303.0056763	0.08
305.2670288	0.02
306.3427124	0.02
309.2080078	0.22
315.4044495	0.01
324.4498596	0.13
325.0650024	0.04
327.1091614	0.21
335.1791992	0.09
343.1509705	0.08
353.1541443	17.72
363.0283813	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.2345
Annotation	Unknow
Peak:m/z	Relative Intensity
178.8997345	0.04
191.2124329	0.05
209.0381775	0.19
221.0188141	0.15
228.9908142	0.06
238.3620911	0.15
245.1709900	0.15
250.8489990	0.10
275.0007324	0.17
277.3165894	0.12
287.0777588	0.04
293.0322876	0.64
303.1221924	0.06
311.0343933	5.22
311.6714478	0.02
321.1511230	0.04
338.1271362	0.03
353.2077026	0.15
354.2095947	0.04
358.2308350	0.12
359.4453735	0.07
363.2902222	0.12
367.3258057	0.06
368.9431763	0.05
371.2056274	0.08
372.5062866	0.15
382.1270142	0.10
385.2356567	0.49
387.5050049	0.05
393.1295776	0.15
401.2043457	0.38
413.4075317	0.05
429.4938965	0.03
430.6192627	0.31
440.1959229	0.16
441.2900391	0.03
443.2158203	0.26
445.1310425	0.04
448.6019287	0.08
451.2800293	0.05
462.1231079	0.03
475.5170898	0.06
485.5300903	0.05
496.8046265	0.16
498.9983521	0.08
517.2562866	100.00
518.3280029	0.25
519.3103638	0.24
523.5272827	0.02
526.2227173	0.15
527.6729126	0.05
534.9037476	0.07
542.4046631	0.08
543.2165527	0.02
544.2326050	0.61
545.3176880	0.63
546.2292480	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.0933
Annotation	5,4'-Dihydroxy-3,3'-dimethoxy-6,7-methylenedioxyflavone 4'-glucuronide
Peak:m/z	Relative Intensity
173.0648499	0.17
173.9762878	0.14
179.0486145	0.41
180.1522369	0.13
191.0035400	3.60
192.2924042	0.39
209.0204010	13.46
210.0734100	1.76
219.3009186	0.02
221.1884613	0.13
221.8854218	0.02
236.0036926	0.03
247.2140198	0.04
248.1070862	0.04
251.3867798	0.02
286.0608215	0.03
287.5778809	0.14
295.3739319	0.03
297.3988647	0.04
299.1810913	0.02
306.2591553	0.02
309.2785645	0.77
310.0435791	0.16
321.0245361	0.06
328.4101562	0.14
335.2405396	0.23
336.3506470	0.06
341.2599487	0.10
342.1494751	0.06
343.2078857	0.01
347.1144409	0.06
353.1203003	10.69
354.1577759	2.10
355.1467285	0.02
368.0833740	0.02
371.1077881	100.00
372.1275024	24.11
377.2616577	0.14
390.9008789	0.04
413.4161987	0.11
415.9749146	0.09
420.0746460	0.06
425.2921143	0.06
439.4554443	0.16
441.8981323	0.04
444.2343750	0.02
446.4236450	0.02
447.3776855	0.08
450.0397949	0.01
460.2238159	0.03
471.2012329	0.20
472.5173340	0.01
481.5737915	0.03
484.7795410	0.06
487.3255615	0.04
490.3411865	0.06
504.5401001	0.08
506.1307983	0.07
515.1434937	2.80
516.1183472	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	552.16
Annotation	Unknow
Peak:m/z	Relative Intensity
161.9885712	0.99
163.0662994	0.17
178.9595184	2.68
180.1295013	0.37
183.9736633	0.26
244.8986664	0.45
254.5894775	0.16
255.5068359	0.09
258.0336304	0.21
265.0662842	1.63
266.0093079	0.52
267.1271362	0.06
268.4960327	0.58
271.9914246	0.63
277.3895264	0.11
279.2885742	0.44
281.3030396	0.20
282.2117310	0.18
283.0427246	5.08
283.8350220	0.16
295.0311890	0.32
296.3529663	0.19
303.1192017	3.27
304.0466309	1.76
308.1598816	0.26
315.2399292	0.24
320.0343018	3.57
327.3540039	0.32
328.3374023	0.23
329.3363037	0.07
337.3624878	0.37
343.8097534	0.35
345.0971069	0.20
347.2677612	0.30
348.0576172	0.58
350.1158447	0.18
357.3742065	0.23
368.6013184	0.10
371.3294067	0.23
372.4580078	0.67
386.2812500	0.40
387.0186768	1.51
388.0529175	2.98
394.1857910	0.23
402.7308960	0.50
405.1263428	13.22
406.4462280	2.85
412.2061157	0.10
419.1961060	0.59
420.3273315	0.09
423.1523438	100.00
423.7575073	0.64
430.4098511	0.38
432.1134033	0.84
433.0474854	0.12
437.5161743	0.42
446.8931885	0.92
448.0192261	0.34
452.1081543	0.23
457.1894531	0.12
457.9066772	0.11
459.2095947	0.31
464.9990845	0.19
466.5147705	0.29
467.6546631	0.22
477.2634888	8.84
489.1242065	0.20
492.7863159	0.46
499.1286621	0.07
502.3372192	0.30
503.1110229	0.34
505.3079224	0.45
507.6981812	1.26
508.8480225	0.29
516.0732422	0.21
516.9141846	0.39
521.8870850	0.19
525.3903198	0.33
529.3401489	0.20
533.2369995	1.62
534.3409424	2.13
535.3251953	0.34
542.1126709	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	805.3312
Annotation	Unknow
Peak:m/z	Relative Intensity
235.1999512	0.05
251.0601501	0.07
264.3525085	0.08
265.3198547	0.01
265.9601440	0.02
279.3491211	0.11
293.2112427	0.01
295.2904968	0.01
310.2973633	0.01
337.2944946	0.07
352.2292480	0.04
353.2924805	0.01
360.3413696	0.04
370.3267822	0.02
373.5249634	0.02
384.4765015	0.02
385.3837891	0.01
400.3865967	0.01
401.2240601	0.01
402.4349365	0.59
407.1198730	0.01
413.4906616	0.07
414.2091675	0.02
426.5923462	0.01
427.3673096	0.02
429.5720215	0.11
438.3283081	0.03
441.4628906	0.02
443.5773315	0.02
445.3464355	0.04
446.3602905	0.09
448.3192139	0.04
458.4842529	0.05
473.5733643	0.03
475.3095093	0.31
476.3369141	0.07
477.4060059	0.04
478.4327393	0.01
479.4210815	0.04
482.3598022	0.02
487.3725586	0.46
488.4669800	0.03
489.3864136	0.03
490.4161987	0.07
494.3901367	0.04
498.4387207	0.01
503.3976440	0.04
505.3394165	0.23
507.5578613	0.03
517.2689209	0.07
521.3491211	0.08
522.2371826	0.10
523.2719116	0.05
533.6112061	0.05
542.5315552	0.03
546.5018311	0.42
549.3703613	0.02
551.4334106	0.87
552.4410400	0.14
562.4611816	0.11
564.4183960	0.62
565.4379883	0.09
567.3450317	0.03
575.2932739	0.02
577.3697510	0.04
578.5692749	0.03
592.4076538	0.06
593.4439697	1.70
594.4683228	0.10
595.3737793	0.05
597.2184448	0.04
598.2005615	0.02
601.3262329	0.01
605.7971191	0.40
606.4648438	2.18
607.7844849	0.17
608.6657715	0.07
609.4658813	0.10
610.2721558	0.52
613.8980103	0.01
619.4597168	0.04
620.1513062	0.04
623.5830688	0.15
624.3320312	0.24
625.3723145	0.21
626.1424561	0.01
632.3575439	0.04
633.4237061	0.02
637.1619263	0.90
638.4133911	0.59
641.3339844	0.01
642.4598999	0.19
643.4074097	0.20
650.4004517	4.09
651.3783569	1.59
652.2330933	0.07
654.3937378	0.08
655.3030396	0.02
659.5941162	0.02
661.4851685	0.49
664.5841675	0.05
667.1243286	0.02
668.0774536	0.07
669.3854980	0.66
670.2797852	0.26
682.2893066	3.80
683.3576050	0.47
684.9633789	0.15
685.5686646	0.45
687.4869385	1.50
701.4526978	0.26
705.4475098	0.22
711.6383057	0.07
713.4097900	0.01
727.5504761	0.19
729.4186401	11.26
730.3507690	0.05
731.4183960	0.15
732.5316772	0.79
733.6158447	0.14
737.6060181	0.02
745.3881836	1.83
755.4649658	1.00
761.3059082	0.37
769.3596191	0.12
773.3783569	100.00
774.1679688	0.11
777.4369507	1.03
782.6351929	0.02
786.9281616	0.28
787.5975952	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	398.2182
Annotation	Candoxatrilat
Peak:m/z	Relative Intensity
193.2719727	0.10
194.1553802	0.06
204.7163086	0.03
208.0100098	0.09
221.3451691	0.02
222.1593628	0.20
223.2912292	0.10
230.3709717	0.03
236.3296814	0.05
237.2139893	0.07
254.4892578	0.11
260.3224792	0.05
264.0924683	0.04
269.4391479	0.16
277.2467346	0.04
283.2999268	0.03
289.5412598	0.07
308.3136597	0.17
315.0684509	0.14
317.4259644	0.05
322.4988403	0.05
326.1963501	0.01
332.6502686	0.09
334.3462524	0.10
335.4218750	0.07
341.0286865	0.10
351.1394348	1.04
352.3335876	100.00
354.3169861	0.07
355.1526489	0.28
359.5382996	0.07
362.1492004	0.10
362.8840637	0.03
370.2810974	0.32
379.3303223	0.50
380.3871460	0.88
381.5059204	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	538.2999
Annotation	Unknow
Peak:m/z	Relative Intensity
155.0451355	0.02
164.0537109	0.05
236.3177185	0.02
271.8259277	0.01
310.4625244	0.18
315.1016235	0.03
322.3562622	0.02
328.3435059	0.66
334.2092285	0.02
344.4208374	0.05
346.3816528	0.28
356.1990356	0.01
364.3258667	0.02
370.3924561	0.15
376.5924683	0.10
388.3784180	0.39
389.7606201	0.06
390.7994385	0.02
404.4640503	0.54
406.3494873	100.00
407.1250000	0.24
407.8588867	0.01
409.3704834	0.07
416.1024780	0.07
418.3639526	0.03
421.6353149	0.03
424.4371948	0.16
439.3223267	0.02
440.2904053	0.05
442.3292847	0.30
448.4003906	1.51
450.6973877	0.09
455.3684692	0.05
456.6076050	0.02
460.4524536	0.20
462.4148560	0.02
475.3990479	0.01
478.0826416	0.16
478.8186646	0.03
484.3638306	0.21
488.1841431	0.02
492.0607910	0.06
493.1745605	0.03
496.1510620	0.02
502.4238892	3.98
503.8003540	0.11
505.0296021	0.06
506.5350342	0.04
509.4284058	0.01
520.4580688	3.32
521.5420532	0.08
524.8265991	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	297.153
Annotation	Unknow
Peak:m/z	Relative Intensity
118.7699356	0.50
155.8506165	0.42
169.4167023	0.16
170.1894836	1.37
182.9796143	62.70
183.9858246	100.00
184.9160461	3.75
197.0790405	1.77
198.0874023	0.33
199.3495178	0.24
212.3451233	0.18
225.0625916	0.56
226.2521667	0.19
227.1373901	0.17
233.2472534	7.92
234.2683716	0.18
235.0160522	0.35
236.1747437	0.07
239.1817627	1.32
240.3212280	0.07
251.2150574	7.30
252.2006531	0.96
253.3208313	29.56
254.5310364	0.34
266.0950317	0.30
267.2492065	0.27
269.1966248	0.13
278.3977661	0.21
279.3581238	5.72
281.4097900	0.11
297.2102661	21.02
298.2098694	2.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	209.0804
Annotation	Sinapinaldehyde
Peak:m/z	Relative Intensity
85.8875427	0.05
89.1333923	0.02
93.0965576	0.01
121.0743713	0.04
133.1745300	0.03
145.1014862	0.02
148.9848022	0.25
151.2125549	0.06
163.0601654	0.14
164.3369904	0.04
164.9860077	0.04
167.0435944	0.29
168.2202911	0.02
177.0058289	0.02
181.0788727	0.24
191.0213470	100.00
191.9359894	0.10
193.9917145	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	400.2167
Annotation	1,2,10-Trihydroxydihydro-trans-linalyl oxide 7-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
114.9086151	0.82
126.9444275	0.59
129.2192535	0.08
131.9226837	0.17
142.9050751	0.06
144.9643555	1.84
150.0314636	0.22
155.1560059	0.12
162.8584137	8.81
169.2540894	0.09
173.0122986	0.08
174.9427795	0.04
177.0873413	0.12
181.0118408	0.19
183.0961151	0.05
184.3843689	0.40
185.0216370	0.38
194.7977295	0.05
198.4688568	0.08
211.1249542	0.07
213.4089355	0.13
215.2963257	0.46
216.8951721	0.16
218.9726868	0.74
220.2929993	0.65
220.9683533	2.71
222.8330688	0.20
226.0423889	0.08
229.2015381	0.07
232.9289551	0.26
233.5306396	0.08
235.0593262	0.08
240.0527039	1.71
240.7435303	2.23
241.4198608	0.40
247.0820923	0.13
250.3045654	8.93
250.9118042	52.68
251.5559998	0.32
254.9724731	0.17
257.7461548	0.55
258.9590149	14.50
261.1285400	0.19
268.0070496	2.99
276.7823792	0.52
280.9049377	0.11
288.6765442	0.21
290.1690063	0.10
294.9528198	100.00
295.5986938	0.27
296.6986084	0.09
302.1459961	0.09
304.1713257	0.39
308.1881714	0.15
309.1619568	0.09
310.1310120	0.12
311.2710266	0.13
314.1581116	0.12
315.5730591	0.16
320.1166382	0.08
321.4948425	0.16
327.2950439	0.14
328.2043457	0.43
337.5250854	0.26
345.3592529	0.18
346.7305603	2.25
347.4038086	0.04
348.9090576	0.33
354.1605835	0.24
356.2037354	0.15
357.1627502	0.05
363.3194580	0.25
364.5542297	0.52
365.4985962	0.14
368.7693176	0.10
371.6664429	0.20
372.7353210	0.04
377.2014160	0.31
379.5394592	0.15
381.4362488	5.54
382.7546997	45.01
383.5854797	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.0986
Annotation	Quercetagetin 7-methyl ether 6-glucoside
Peak:m/z	Relative Intensity
150.8960114	0.14
166.2530518	0.05
176.8943481	0.04
179.0270844	0.14
183.5284271	0.03
188.0694885	0.08
189.8929138	0.13
192.9090424	0.03
199.0133209	0.06
205.0358276	0.18
206.1269836	0.13
213.0870972	0.10
219.5128632	0.19
222.2349243	0.02
226.2183380	0.16
230.0691528	0.04
233.1474152	0.03
236.9958038	0.04
241.0276489	0.06
242.0940857	0.14
243.2675476	0.15
244.3124084	0.11
245.4662018	0.06
254.2110291	0.02
256.8038940	0.02
259.1721497	0.29
263.2251587	0.12
264.4511108	0.04
267.3165588	0.24
268.3003540	0.05
269.2587891	0.52
270.0768127	0.64
271.1904297	0.19
272.3316345	0.22
273.2053833	0.04
282.2021484	0.03
283.2494202	0.02
285.1533203	0.14
286.1543579	0.22
287.0823364	3.92
288.2536621	0.40
293.1053467	0.06
295.9649963	0.31
297.2142944	0.03
298.2246094	0.12
299.3212280	0.02
300.2754822	0.26
301.2513428	0.20
301.8650513	0.20
302.7358093	0.04
303.4241943	0.03
306.3812256	0.11
310.2486267	0.17
311.1874390	0.14
312.1587830	0.30
313.1717834	0.32
315.1042480	100.00
316.1882935	8.29
317.2661133	0.84
324.0096130	0.06
325.9518433	0.02
327.4011230	0.23
329.1021118	0.71
330.0872498	17.11
331.2059631	14.46
332.1464844	0.15
339.5183716	0.08
340.2162476	0.03
341.3238220	0.19
343.1074829	0.32
344.9594421	0.30
346.4266357	0.11
347.6184692	0.09
349.0985718	0.03
355.2823486	0.10
356.1921692	0.05
358.0746460	4.33
359.1749878	0.27
361.2550659	1.21
361.9535522	0.16
367.1183167	0.11
373.1890869	4.86
374.0755310	0.37
374.9433289	0.12
376.0572205	0.04
380.2276001	0.12
381.2324219	0.04
384.1426086	0.02
386.9335938	0.05
388.1384277	0.86
392.0534668	0.09
396.1419983	0.05
400.1747131	0.11
401.4024353	0.14
403.2281189	0.24
404.6193237	0.15
405.4230652	0.07
407.2386780	0.08
413.2231140	0.02
414.7243958	0.12
418.3808289	0.12
419.1961975	0.09
421.3230896	0.26
430.4677124	0.04
433.2692566	0.07
434.4700012	0.22
447.1566162	0.24
448.3593750	0.37
449.4208374	0.64
450.3425293	0.54
451.4379578	0.07
454.1039734	0.02
456.3132324	0.17
457.5365601	0.11
460.3405457	0.22
465.2482605	10.68
466.4356384	0.15
473.2735901	0.07
474.9888000	1.25
475.6033020	0.69
478.1565247	38.24
479.1664734	0.59
492.9780884	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	635.1586
Annotation	Unknow
Peak:m/z	Relative Intensity
190.7413177	0.14
208.9901428	0.90
225.1082458	0.10
233.1461792	0.10
241.0260925	0.06
242.9699097	0.14
244.0226898	0.06
257.1359253	0.25
258.8688049	0.23
262.0223389	0.08
263.0371094	1.31
273.1416016	0.20
308.0242310	0.17
311.0236206	0.03
337.1203003	0.72
343.1657104	0.28
357.1463623	6.44
361.3347168	0.21
365.2285767	0.06
368.0710449	0.05
369.0085449	0.44
379.2181396	1.00
380.5092163	0.11
381.3947754	0.08
387.2438965	100.00
393.1873169	0.06
399.1429443	0.12
411.2752075	0.25
415.1723022	0.21
431.9820557	0.14
435.2536621	0.09
447.3709106	0.10
455.1351929	0.37
462.5839844	0.15
465.2412109	0.17
477.0711670	0.41
483.2078857	0.14
491.4562988	0.12
495.4703369	0.16
499.3932495	0.40
501.9496460	0.17
503.5543213	0.33
505.3281860	0.79
533.4091187	0.02
543.4512329	0.11
546.9465942	0.20
549.0299683	0.12
554.4252319	0.46
559.3930054	0.08
560.9221802	0.22
563.0733032	0.17
567.4711304	0.18
569.1418457	0.23
572.9689331	0.70
585.8302612	0.04
586.9630737	0.63
589.0532227	0.07
590.8743896	0.13
599.0571289	4.40
602.2788696	0.08
603.2624512	0.06
604.9323120	8.69
614.3750610	0.26
615.0059204	0.05
616.2937622	1.82
617.0390625	1.79
617.8184814	0.03
619.0976562	0.40
636.2063599	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	634.4511
Annotation	Nonoxynol-9
Peak:m/z	Relative Intensity
188.9854584	0.09
191.1625519	0.26
193.1676636	0.17
196.9968567	0.10
209.0284729	0.43
211.1693726	0.10
212.8700256	0.06
217.0856171	0.17
218.9353638	0.07
220.8990021	0.79
235.0694427	0.54
239.1842194	0.13
245.3154755	0.08
247.2028809	0.98
255.2095032	0.52
262.8181152	0.07
265.1103210	0.84
267.1754761	0.26
271.1406555	0.18
273.3397827	0.21
279.0244446	0.43
287.0369873	0.07
289.1835632	0.42
291.2079468	3.93
291.8836060	0.04
297.0618896	0.42
299.3305664	0.76
305.2414551	0.06
306.4030762	0.08
309.1693420	1.32
315.0435181	0.11
317.3492737	0.48
322.9831543	0.20
327.4448547	0.06
333.0488892	0.06
335.1525879	5.00
341.1533203	0.24
343.2660522	0.12
349.2708130	0.08
353.2533569	0.59
359.3094482	0.40
361.5223389	0.10
363.1907349	0.04
365.5610962	0.02
367.2186279	0.42
376.2010498	0.07
379.0301514	0.42
381.0589600	0.07
384.9232788	0.25
387.4719238	0.38
389.4573364	0.03
393.3684692	0.09
396.9764404	0.49
403.0081787	0.28
403.6422729	0.09
406.4106445	0.03
416.7379150	0.10
419.4740601	0.11
422.8407593	0.80
423.5464478	0.06
425.3461304	0.30
439.3635864	0.03
441.3074341	0.15
447.0443115	0.29
449.0900879	0.27
457.2824097	0.28
458.6130371	0.03
464.1744995	0.15
466.8491211	0.10
480.6030273	0.05
485.3530273	0.48
491.2749023	4.05
510.3856201	0.14
511.1825562	0.70
524.9290771	0.14
529.2943726	2.33
543.2023315	0.10
555.3998413	0.06
560.9102173	0.18
573.4402466	2.39
577.5911255	0.02
580.3107910	0.06
589.3095703	0.08
599.2490234	0.92
602.8381958	0.07
617.2875366	100.00
618.1253662	0.09
628.7453003	0.04
633.8639526	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	398.2527
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9681396	0.30
119.8212891	0.07
126.9458008	0.05
130.7916565	0.11
133.1946716	0.18
135.0106964	0.12
136.9131012	0.08
149.0417786	0.03
156.2955627	0.10
156.9937286	0.12
159.0883789	0.39
160.1278992	0.04
163.8710327	0.19
169.0817566	0.11
170.0792542	0.06
173.0357361	0.37
178.0922241	0.07
183.1147003	0.08
185.1762695	0.40
186.6251984	0.05
190.8487701	0.13
200.1821289	0.12
201.1451874	0.13
204.6026764	0.14
206.2156677	0.14
207.9668579	0.26
209.1294708	0.03
212.2046204	0.20
214.1791840	0.22
215.2369537	0.54
216.4801331	0.04
218.8408203	0.53
223.9959717	0.31
225.2768860	0.05
227.3992004	0.06
231.4315491	0.09
233.0917969	0.04
234.3125000	0.04
235.2407837	0.25
242.0933838	0.83
244.1888123	1.75
246.1655273	0.29
246.9869080	0.05
249.1732483	0.10
250.9898376	0.18
252.2470093	0.07
253.1951904	0.57
253.8648682	0.04
258.4766235	0.06
260.2594299	6.91
261.4339905	0.11
269.2586670	0.08
270.1151733	0.32
271.1771851	0.21
276.4056396	0.34
277.1397705	0.22
286.4157104	1.06
288.3250427	2.08
291.1069946	0.11
292.3048706	0.11
296.3040771	1.32
298.2423401	0.83
298.9401855	0.05
306.2976990	2.38
307.1208496	0.41
308.2323608	0.97
309.2131958	0.38
310.0506592	0.37
312.3497925	0.22
314.2894287	1.37
315.3690186	0.04
316.3050232	0.23
320.1892700	0.11
322.8490601	0.18
324.3909302	1.63
325.0200806	0.13
326.3359070	5.92
327.0759888	0.09
332.2050476	0.52
334.2513428	0.07
339.4807739	0.43
342.5597534	0.23
344.4024048	7.71
345.3687439	0.44
351.9732666	0.09
352.6219788	0.45
355.1899719	0.04
356.2854919	0.10
357.3266296	0.15
362.2743835	26.25
363.1589661	0.68
366.1578064	0.14
374.2206116	0.10
380.2947388	100.00
381.3098450	3.49
397.4847717	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	541.13
Annotation	Resveratrol 4'-(6-galloylglucoside)
Peak:m/z	Relative Intensity
161.0155182	0.07
162.1447296	0.05
179.0207520	1.44
179.9845886	0.33
180.8731232	0.12
185.0822601	0.03
199.1480865	0.05
218.1160583	0.05
221.0126038	0.57
222.2034912	0.06
223.2914734	0.11
249.0526276	0.02
250.8890686	0.08
263.3092041	0.04
280.7778931	0.48
281.4328613	0.04
307.2130737	0.09
310.8663330	0.10
323.1380005	0.79
324.1177368	0.09
340.5623779	0.20
341.1641846	2.01
342.1327515	0.51
343.2305908	0.07
355.4765625	0.05
377.1994019	2.97
378.1796875	4.56
379.1310425	11.98
379.8816528	0.02
383.2491455	0.41
384.2607422	0.10
424.7929688	0.10
443.2147217	0.12
444.3184814	0.10
485.0947876	0.04
503.3023071	100.00
504.2622681	51.49
505.2113037	16.24
506.0347900	0.07
539.2764282	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.04
Annotation	Unknow
Peak:m/z	Relative Intensity
175.0637512	0.12
193.0340881	0.04
210.8563538	0.40
212.8076477	100.00
213.7869568	0.04
228.9699097	0.06
251.0195312	5.96
255.8804321	0.01
260.2378540	0.03
261.1263123	0.04
279.1112366	0.83
281.3021240	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	336.2161
Annotation	Dendrine
Peak:m/z	Relative Intensity
130.1827545	0.06
132.0823517	0.40
136.0697937	0.02
137.1277466	0.04
141.9915771	0.03
157.2346191	0.04
164.2288361	0.04
169.0919647	0.05
170.2485657	0.01
171.0501099	0.06
175.3327942	0.02
183.2006378	0.02
191.1228790	2.33
209.0450439	0.15
210.9641113	0.01
216.1972961	0.07
218.3793335	0.10
221.2778625	0.02
223.2066345	0.09
225.2247925	0.02
232.0847168	0.08
237.4300232	0.04
246.2355042	0.44
253.3279114	0.05
254.3490906	0.08
256.2969055	0.04
259.4384460	0.23
260.1469116	0.03
262.1961060	0.01
263.9854736	0.02
266.3880005	0.33
267.3130798	0.03
272.4769897	0.08
273.1548462	0.03
279.3607788	0.03
282.1910400	0.06
283.2055359	0.17
284.2461853	1.21
288.9689941	0.01
290.4043884	0.02
291.5650330	0.02
300.3366699	0.02
302.2100220	3.27
302.8658447	0.04
320.2605896	100.00
321.2255859	0.03
329.1220398	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	166.0858
Annotation	Gentiatibetine
Peak:m/z	Relative Intensity
120.0176239	100.00
120.9140167	0.10
131.0643463	0.15
147.7966309	0.94
149.0103760	9.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	598.1212
Annotation	Unknow
Peak:m/z	Relative Intensity
189.1259308	0.06
215.2613068	0.06
221.0953674	0.06
245.0946960	0.08
258.1227112	0.15
273.0505371	0.03
291.2693481	0.45
311.2250977	0.04
317.1989136	0.02
319.1164551	0.10
327.4807739	0.08
330.3112183	0.05
347.2207642	3.05
349.1475830	0.21
369.2780151	0.15
381.3865967	0.04
390.2200317	0.04
395.3048706	0.02
413.1829834	0.10
415.1210938	0.25
418.9857788	0.06
436.0940552	100.00
436.9359741	0.02
445.0917358	0.07
460.2795410	0.15
464.1268921	0.16
468.3079834	0.11
478.1716919	0.74
482.1982422	0.33
492.9156494	0.12
495.3029175	0.09
500.1172485	0.21
507.5453491	0.18
514.1925659	0.23
516.7930298	0.54
518.1581421	1.34
526.5104980	0.18
535.2321167	0.14
538.8735352	0.10
544.2055664	0.46
545.3621216	0.19
548.1828003	0.04
551.5372925	0.03
552.4484863	0.20
562.1748657	2.02
563.1437988	0.94
565.4952393	0.25
570.2376709	0.10
576.8325195	0.09
579.3150024	0.28
580.1107788	5.51
582.1825562	0.19
588.4541626	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	532.35
Annotation	Daechuine S7
Peak:m/z	Relative Intensity
159.0873566	0.05
176.8067169	0.39
181.0413513	0.11
192.9553223	0.10
215.3867798	0.18
225.1410522	0.12
229.0691986	0.33
243.2889709	1.50
245.2590027	0.12
253.5348969	0.26
254.5027466	0.09
261.2511902	8.08
262.8718872	0.13
263.7614746	0.13
269.0242920	0.10
275.1734009	0.15
279.6225586	0.34
287.2889404	0.11
297.4640503	0.55
299.1120605	0.67
316.4227905	0.17
317.2308350	0.08
317.9130249	0.10
323.2758789	0.13
325.2602539	0.29
327.6656494	0.25
333.3206787	0.58
334.0612183	0.33
335.3200684	5.49
353.2649536	70.35
353.9185791	0.15
369.0097046	0.52
370.9274292	0.19
377.2022095	0.09
405.4938354	0.56
423.4877319	0.29
429.2020874	0.64
434.9828491	0.65
437.3270264	0.32
439.6857300	0.43
440.8835449	0.11
443.4020386	0.53
459.6648560	1.01
461.4605713	2.17
471.4789429	0.14
479.6150513	1.58
482.5522461	0.15
483.3580322	0.22
488.4887695	0.14
495.5130005	0.38
497.3257446	100.00
499.0292969	0.32
511.8249512	0.38
513.3024902	1.22
514.1734619	5.26
515.0258179	28.89
522.7655640	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	437.0547
Annotation	Unknow
Peak:m/z	Relative Intensity
124.9952850	0.16
179.1861725	0.10
188.0387726	0.09
191.9812775	0.28
193.1090698	0.04
207.0865936	3.51
208.0853729	0.17
211.2790222	0.09
215.1209259	0.05
216.1603241	0.35
223.0385742	6.05
227.1253967	0.17
229.1981812	0.26
241.0710144	0.05
242.1292114	0.12
245.2689209	0.34
248.0565186	0.16
249.1728210	0.17
257.1825256	0.96
260.9035950	0.21
263.1942444	1.22
265.1590271	0.08
267.2986450	0.24
268.3442688	0.04
271.2675476	0.02
272.2085266	0.03
274.5631104	0.17
283.0761108	0.10
284.2835083	0.28
287.0355530	1.77
289.5336914	0.04
290.1339111	0.59
291.2543945	0.11
295.0787964	0.08
297.0136719	2.21
298.1145020	0.06
299.1242065	0.61
302.4694214	0.06
303.1141968	0.12
305.1711426	10.05
305.9663696	0.10
307.9131165	0.10
309.1647644	0.19
311.0616455	5.98
311.6787109	0.05
313.2050171	0.54
315.0802917	0.55
316.0922546	0.90
317.1058655	0.19
321.3308716	0.23
329.8439026	0.11
331.0684509	57.72
331.6963196	0.23
333.0405884	0.09
334.3567200	0.05
341.1488037	0.08
343.1126099	0.49
344.3536377	0.12
347.0248108	0.05
349.0974731	35.95
349.8038330	0.12
351.2828674	0.25
353.1260986	1.96
356.0636597	0.04
357.3797913	0.43
362.4375000	0.13
365.0037842	0.07
373.3318481	0.13
374.2335205	0.14
375.0497131	0.18
378.3584900	0.25
383.0279236	0.12
387.0826416	0.36
391.2460022	1.02
393.2416687	3.25
394.2950439	0.37
400.2086792	0.34
401.1526794	0.47
404.2420959	1.68
405.6673279	0.07
409.2266541	0.94
419.1981812	100.00
420.1841431	0.09
422.0067444	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	651.2426
Annotation	3'-Sialyllactose
Peak:m/z	Relative Intensity
223.1526947	0.95
228.9589691	0.30
235.0846405	0.61
247.0328979	0.32
253.0470428	3.15
258.6710815	0.31
271.0567932	3.04
277.1217651	0.27
288.7075806	12.63
289.3883667	0.84
301.8472595	0.66
306.0042419	1.71
306.9457397	6.80
308.8359375	0.23
310.0932617	6.01
313.3609009	1.01
321.9718933	0.85
324.3726807	22.81
325.0375977	100.00
338.4717407	0.53
341.5681152	3.60
342.1976318	2.86
342.8795166	89.36
402.9833374	0.44
451.3656616	0.60
468.9296875	0.44
472.0812378	1.14
486.8611450	4.67
488.1829834	0.94
490.0892944	35.10
504.7588501	7.40
634.1779175	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.0669
Annotation	Caffeic acid 4-O-glucuronide
Peak:m/z	Relative Intensity
102.8874283	0.07
111.0069962	0.04
126.8749542	0.12
128.9226227	3.18
147.0328674	3.01
163.0961761	0.12
173.0230560	2.16
175.1942902	0.04
183.1338196	0.14
190.9963074	100.00
192.2715149	0.06
192.9560242	0.56
206.9492340	0.10
209.0167236	68.04
217.1705627	0.09
224.8241882	0.15
235.1847534	0.15
241.0512390	0.16
247.9234924	0.03
259.2518921	0.05
264.2147217	0.03
267.1783447	0.15
270.1206665	0.11
272.1376038	0.06
273.1340027	0.04
275.4707336	0.08
276.1527405	0.08
292.3847961	0.05
293.1124878	0.07
297.3912354	0.11
303.0983887	0.10
309.4534912	0.04
310.2974854	0.15
311.1136475	0.08
312.0957336	0.13
317.0626221	0.14
319.2143555	0.03
337.0946655	12.42
338.0546875	0.14
339.4150391	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	738.9261
Annotation	Unknow
Peak:m/z	Relative Intensity
211.1021423	0.01
232.8467407	0.03
241.0275726	1.01
262.0849304	0.07
280.0389404	0.27
323.1174927	13.45
324.1901245	1.52
329.1575317	0.01
351.0365601	0.01
359.1072083	1.25
360.1607666	0.10
361.2686157	0.01
376.9783325	1.07
377.5892334	0.01
378.2057495	0.07
384.7957764	0.05
390.9688721	0.07
422.9677124	0.06
429.2025146	0.04
429.8344116	0.03
432.0361938	0.01
436.8744507	0.02
441.0710449	0.77
458.9614258	3.94
459.9543457	0.26
469.9285889	0.01
471.2669067	0.02
475.2810059	0.01
483.0273438	0.43
484.0951538	0.04
491.1054688	0.06
494.8912964	1.80
495.8495483	0.09
497.0366821	0.28
497.8241577	0.06
522.0511475	0.01
542.1578979	0.02
560.1433105	0.45
561.1049194	0.02
564.7885132	3.89
565.7112427	0.13
568.6758423	0.04
576.9064331	0.24
583.6317139	0.02
585.0925293	1.40
586.0158691	0.29
603.0564575	100.00
604.0979614	19.38
604.8594360	0.42
618.9399414	0.20
627.1405029	0.01
642.7966919	0.01
652.1099243	0.09
652.8002319	0.08
655.8290405	0.33
656.6492920	0.40
663.1508789	0.07
668.6651611	0.02
678.1394653	0.06
693.1303101	0.11
693.8251953	0.18
695.8538208	0.08
720.8847046	1.89
721.8292847	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
134.962738	2.09
150.964325	0.63
189.2801514	4.20
191.1747284	1.35
197.0896301	1.87
211.2905579	3.85
214.0842743	0.57
215.2148438	2.27
215.9127502	2.05
222.2631378	3.43
243.8059692	2.64
261.4976501	1.67
267.2466431	1.96
267.8993835	0.97
278.1400146	0.84
281.1030579	1.06
284.0278931	2.80
291.144043	0.81
299.1493835	2.38
304.2005615	8.42
321.1295166	1.21
335.8406982	3.21
339.0110168	1.90
342.0001221	0.75
343.0490112	3.89
344.6297607	2.44
348.3150635	2.02
354.3180542	12.78
356.9465942	13.15
358.4060974	3.49
359.3946533	0.65
362.6230774	2.09
363.2304382	2.47
367.1593933	0.72
379.2878113	0.74
380.190155	2.73
381.0689392	1.54
382.1389465	3.92
383.408844	1.95
385.0826721	4.74
390.4198914	10.36
391.3118286	1.18
395.3462524	1.21
396.3272095	1.31
408.2655334	100.00
409.1871643	12.03
411.1636658	2.49
417.1876221	0.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	316.0225
Annotation	Unknow
Peak:m/z	Relative Intensity
106.6686096	0.04
135.1377869	0.08
136.0354309	0.20
150.3338013	0.24
150.9808044	0.85
151.9716187	0.36
159.1423798	0.08
163.0241547	0.28
164.0514832	0.36
165.3290710	0.07
174.0576630	0.02
176.1168365	0.07
178.9702911	4.21
180.0838318	0.25
185.9597473	0.15
187.2661285	0.09
188.1748810	0.14
191.2170715	0.05
192.0354767	0.40
192.9589233	0.26
197.1161499	0.03
198.1188354	0.03
200.9598999	0.03
202.9547729	0.03
204.0618286	0.42
214.0588684	0.51
215.1328430	0.15
216.0335693	0.37
217.9204712	0.05
219.1018372	0.11
220.1450500	0.04
225.9999695	0.13
227.1248169	0.26
228.2725220	0.03
230.0108032	0.09
231.0665894	0.20
232.1448364	0.94
242.0798645	4.72
243.1557617	0.82
244.1768494	1.42
253.9428406	0.02
259.1855164	1.04
260.1983643	0.44
270.0934753	33.38
271.0624390	100.00
272.1605835	1.05
273.9539490	0.05
283.3927307	0.02
287.0922546	33.36
288.1247864	10.09
289.2691345	0.21
297.1182861	0.07
298.1271362	0.33
299.0381470	0.24
316.2020264	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	473.1509
Annotation	D-Galactopyranosyl-(1->3)-D-galactopyranosyl-(1->3)-L-arabinose
Peak:m/z	Relative Intensity
138.9031372	0.49
142.6864777	0.31
149.0547028	1.83
151.0865173	30.75
155.1653442	0.19
157.0293274	8.14
163.0571594	1.54
173.0149231	25.12
173.9657593	0.58
179.0642090	0.16
183.0542603	0.23
189.1439209	2.37
189.9218445	0.08
198.8252563	1.23
201.0482788	1.20
205.1222534	8.99
206.9529724	0.37
208.0167542	0.38
214.9891510	10.84
222.7984467	0.15
229.1749268	1.19
245.0727539	5.23
247.0009308	3.28
249.0759277	0.57
250.1260071	1.10
263.0773926	2.76
265.1477966	4.37
277.0440063	0.29
283.1687927	44.44
289.3199768	0.20
290.2464294	0.39
290.9247437	0.50
307.1008301	0.11
317.3092651	0.24
318.1789551	1.04
321.1729431	1.24
322.0389404	2.86
323.0603638	0.26
326.9155273	0.22
340.2113037	1.63
353.2684937	1.90
361.0279846	1.00
362.2462769	0.93
372.1467896	0.75
379.2015076	6.01
381.1028442	0.23
383.3390503	0.23
394.2833252	0.94
395.1291504	1.83
397.2335510	21.53
411.1522827	2.02
412.1961975	13.40
413.2917175	5.30
423.1730347	0.37
427.0550232	0.67
429.3089294	3.81
441.2342834	100.00
442.4656372	0.23
454.5536194	0.47
455.5317383	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
129.015686	1.11
140.8665009	1.02
153.0782318	0.30
158.8757629	0.35
167.4988708	0.41
169.1276398	0.69
170.9101257	0.52
183.3085022	1.12
185.0889587	0.30
187.2749329	0.50
189.1924744	0.39
199.2816315	2.78
201.3072815	1.50
206.9263916	1.03
215.1465759	1.36
227.0644836	1.04
228.2433167	1.41
229.1965027	4.06
231.2170715	0.31
237.1425476	0.74
243.1106262	0.41
251.2180786	0.37
255.1343689	0.43
257.0484009	3.43
257.9167175	0.21
263.4558716	2.25
265.1026611	0.53
267.0192261	0.35
269.305603	0.21
271.0309448	1.54
273.520874	0.43
281.3540649	1.71
283.8487854	0.98
285.0410156	3.07
289.2261353	2.37
289.9642944	0.47
293.441864	0.45
295.0443115	1.54
297.4644775	3.93
299.33255	3.19
303.0651245	0.27
304.1383667	0.37
310.999176	4.85
312.3275146	2.44
313.2815247	4.51
314.1304932	1.34
315.5785217	1.48
319.3295898	3.01
320.2205811	0.76
321.652771	3.36
323.3247681	7.50
325.1264954	0.60
327.4212646	0.77
329.4894409	1.47
337.1849976	1.25
339.2423401	100.00
339.8451538	0.58
341.2448425	27.79
343.0937195	0.96
358.7572327	0.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.2524
Annotation	Elymoclavine-O-beta-fructofuranosyl-(2->1)-O-beta-D-ructofuranoside
Peak:m/z	Relative Intensity
170.1711884	0.49
177.2108154	0.16
188.0556335	35.63
189.0982666	0.09
195.0041199	0.24
205.0737610	100.00
211.2191772	0.07
212.8543701	0.31
372.1358032	0.13
373.3641357	0.05
374.0053101	0.25
375.0437012	0.30
396.4476929	0.31
399.0939941	0.13
407.9223633	0.16
466.8283081	0.17
535.5040894	0.07
560.2948608	0.03
561.1073608	0.12
569.4077759	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	343.2945
Annotation	MEDICA 16
Peak:m/z	Relative Intensity
99.18304443	0.12
108.9783325	0.21
121.0500107	0.21
123.0093689	0.57
124.9143219	0.13
134.9240112	0.05
145.0586853	0.17
149.1795959	0.37
151.1378021	0.12
158.8972168	0.63
164.7744751	0.33
170.9511108	0.13
175.1493073	0.12
182.088913	0.17
185.0037537	0.15
189.3227844	0.29
196.8421326	0.10
198.2090454	0.07
211.0867004	0.43
215.0474243	0.33
219.1782532	0.37
225.1635742	0.07
226.2251282	0.31
227.2523499	0.26
228.9269104	0.24
240.2432251	100.00
243.0722961	0.85
245.0743713	0.40
247.3078918	0.39
249.0670166	0.74
251.1353455	0.42
257.4890747	0.14
262.2327576	0.22
268.8374634	1.14
270.5064697	0.27
273.3249207	0.10
274.949646	0.10
279.2407532	0.21
281.341217	0.07
283.1937561	0.19
289.2147522	0.20
294.1013184	0.86
295.3788452	0.33
298.4550781	0.33
299.0617676	0.14
301.2172546	1.63
301.9229736	1.38
305.2531738	0.15
307.2607422	2.87
308.0699158	0.27
309.10672	0.28
311.0527344	0.26
314.9938965	0.71
323.2214661	0.57
325.2659302	61.01
326.3252563	0.68
334.473938	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	777.1143
Annotation	Unknow
Peak:m/z	Relative Intensity
232.9160919	0.19
241.0409851	0.37
323.2600098	0.27
330.8247681	0.05
348.9446411	0.06
358.4869995	0.05
359.1650391	0.16
365.1480103	0.12
369.0356445	0.12
370.9271240	0.10
377.4158936	0.09
388.9103394	1.55
396.6948242	0.07
406.1299438	0.04
406.8820801	0.32
426.2525635	0.33
428.8667603	1.54
430.8180542	0.21
442.8189697	0.11
444.8596191	0.07
446.7332153	0.18
450.9201660	0.15
472.2853394	0.05
480.6382446	0.15
490.6949463	0.25
492.4414673	0.04
497.0635376	0.63
504.9165039	4.52
532.9002686	11.93
534.8267822	0.27
543.2872925	0.24
545.1442261	0.03
551.0358276	0.05
565.1295776	0.36
566.6553345	0.24
581.1194458	0.25
587.7610474	0.07
588.7437134	0.03
592.8978882	0.10
596.2659302	0.12
598.3536987	0.28
603.0368042	100.00
603.6951294	0.76
609.1036377	0.05
612.9741821	0.12
614.7749023	0.53
620.9699097	0.85
622.1467896	0.50
622.9645386	0.82
625.8812866	0.67
630.9251099	0.11
638.1414185	0.06
640.9615479	9.78
643.8818359	1.97
656.9044800	1.06
657.8607788	0.03
661.8273315	0.04
665.0771484	2.42
668.7911377	0.16
673.9639282	0.13
678.4982300	2.32
679.3649292	0.39
686.0155640	0.03
690.0416260	0.81
690.8469849	0.05
692.3168945	0.33
692.9911499	0.16
693.8526001	0.26
699.4248657	0.05
702.4219360	0.07
706.1030884	0.07
713.0057373	0.04
715.8665161	1.12
716.8922729	0.13
725.3197632	0.23
730.2223511	0.07
730.9797974	1.31
733.3004150	0.54
733.9190674	8.38
746.3362427	0.16
759.8609009	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.0931
Annotation	5-(3',4',5'-Trihydroxyphenyl)-gamma-valerolactone-4'-O-glucuronide
Peak:m/z	Relative Intensity
128.9945984	1.76
146.9822388	2.68
172.9939270	3.54
190.9937744	100.00
201.2340698	0.11
205.0158539	0.07
282.6157227	0.08
303.5648193	0.12
313.3370361	0.05
337.1416321	0.71
353.3395081	0.06
354.3825989	0.03
355.3558044	0.14
362.3587341	0.19
363.1804504	0.03
371.1244812	0.13
381.0936890	15.08
397.2065430	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	412.232
Annotation	Isariotin A
Peak:m/z	Relative Intensity
132.0015869	0.69
146.8853912	0.23
148.6748505	0.09
163.1885986	0.03
172.2062073	0.07
172.9282990	0.15
175.5884857	0.02
178.2429352	0.04
182.8807678	0.03
185.2021484	0.09
186.9904022	0.07
189.0098267	0.10
194.0975342	0.10
198.2972412	0.08
201.0844727	0.07
202.0786591	0.06
203.1421204	0.06
209.2215729	0.04
210.0823364	0.05
215.0628815	0.27
216.1960144	0.04
222.2173767	0.18
223.1562805	0.09
225.1449585	0.27
231.1317444	0.18
232.6129150	0.21
233.3530884	0.39
236.3203430	0.04
240.1166077	0.05
243.2632751	0.03
244.2077026	0.11
247.1422424	0.02
247.8800049	0.06
248.9791260	0.18
250.2079773	0.07
251.0147095	0.10
253.3477478	0.34
254.2048645	0.04
258.1802979	0.86
260.2799988	0.20
261.2680054	0.28
263.0247803	0.16
274.0920410	0.15
276.2791443	4.77
277.2841187	0.08
278.2946167	0.08
280.2959595	0.24
286.6661377	0.47
289.9722290	0.15
292.3899841	0.20
293.3591919	0.11
294.6309814	0.28
295.3435364	0.02
298.1397705	0.12
299.5265198	0.03
304.2607727	0.29
305.2138977	0.09
307.2288513	0.14
309.0079041	0.28
310.2805176	0.91
312.3747253	0.22
314.3397827	0.04
322.2955933	1.71
323.3521118	0.12
327.0113525	0.04
328.2651367	5.11
330.1794128	0.05
331.5728760	0.03
334.2724609	4.68
338.5594177	0.09
339.3506775	0.35
340.3625183	6.64
341.1698608	0.15
345.3801575	0.04
346.3424683	1.08
350.3908386	0.07
353.0430298	0.04
356.5057678	0.02
358.2628174	12.70
366.1682434	0.45
368.0780945	0.62
369.0039978	0.05
370.8924866	0.15
376.3553772	18.97
377.1166687	0.07
392.3739929	0.14
394.2576599	100.00
395.2799988	0.24
403.1070862	0.24
406.8035583	0.17
413.2019348	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	647.2038
Annotation	Unknow
Peak:m/z	Relative Intensity
189.0429993	0.17
203.0038910	0.19
205.1877136	0.64
208.9519043	0.62
214.9569092	0.65
221.0044098	1.03
227.0647125	0.23
235.2978210	0.57
245.1244354	0.44
247.2083435	2.87
248.0668945	0.15
262.8132324	1.65
265.2190857	12.79
273.1417236	0.12
283.0427246	8.69
298.7083435	0.52
306.1220703	0.13
311.1312866	0.15
315.3198547	0.31
317.4577637	0.26
318.3526611	0.26
321.2945862	0.64
322.1068115	0.64
328.9641724	0.23
338.1466675	0.52
339.2669067	0.61
341.2272949	0.65
343.1984253	0.80
346.7068481	0.25
349.0361938	0.18
350.0619507	0.58
358.9592285	0.65
360.0575562	0.25
372.1813354	0.18
377.1810913	0.86
379.2131348	8.97
382.2649536	0.97
384.9177246	0.31
397.3204346	17.33
403.4423218	0.18
404.3486938	1.41
415.2984619	26.31
416.8989868	0.24
421.0933228	0.16
428.2500610	0.42
434.6679688	0.44
438.7995605	0.10
441.4110107	0.28
453.0865479	0.64
454.1939087	0.55
455.3329468	0.92
457.2149048	0.80
465.5079956	0.36
466.2687988	0.15
472.1007690	0.33
479.4727783	0.46
485.2449951	0.24
493.1728516	1.60
495.4970703	0.75
503.1499023	0.90
508.2821655	0.19
511.1346436	2.09
513.2470093	2.87
514.2811890	12.74
515.2667847	1.59
516.2633667	2.59
526.3307495	0.66
527.2586060	1.23
529.3220825	5.19
537.1598511	0.43
543.9224854	0.33
550.4468384	0.81
555.3082886	10.24
561.4530029	0.37
568.3050537	3.25
569.1757202	0.34
573.3095703	6.16
582.7551880	0.20
585.4500122	4.94
586.2549438	26.26
587.3110962	69.05
587.9185181	0.26
593.3989868	0.12
597.0795898	2.13
605.2755127	100.00
606.0901489	0.70
609.4600830	0.13
615.3325806	58.09
616.1006470	0.26
624.1359253	1.38
629.2160645	8.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	442.0448
Annotation	(-)-Pyralomicin 1c
Peak:m/z	Relative Intensity
169.1060638	1.05
185.0784302	0.41
197.0325317	0.38
198.1061401	0.06
202.2039795	0.42
210.0191650	0.09
211.1254730	0.28
213.0994873	0.34
214.2483826	0.21
227.1643066	1.02
227.8471985	0.66
229.7077637	0.57
230.3444366	0.04
232.8574219	0.14
243.0190735	0.45
245.2248840	0.62
261.9634094	0.09
265.1196594	0.33
269.1351318	0.21
270.4886780	0.20
280.0124207	0.21
294.1900024	0.09
298.0612793	0.22
302.2249146	0.07
303.1035461	0.23
303.9660645	0.12
310.1188354	0.34
312.7321167	0.17
321.0285645	0.96
321.8902588	0.36
326.1938782	3.86
327.1231384	0.36
328.2266541	0.41
334.0595703	0.25
342.1605530	1.43
343.2462158	0.28
352.0025024	1.14
354.0596008	0.20
360.2846985	0.33
378.1224365	0.29
380.2867432	0.16
383.6001282	0.26
384.3727417	0.28
388.9104309	0.15
395.2063904	0.21
399.0606995	0.13
401.0377502	100.00
405.4165344	0.35
412.8773499	0.29
414.4078674	0.33
415.2292175	0.44
417.4469299	2.31
418.4515381	9.06
419.2077332	0.12
420.1276245	0.37
423.3794556	0.66
424.0940247	3.22
432.7358398	0.31
442.1951599	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.1034
Annotation	Veranisatin B
Peak:m/z	Relative Intensity
107.9082184	0.14
123.1215973	0.08
125.1026993	0.10
128.1221924	0.82
131.9752808	0.14
134.0871582	3.48
143.1958313	0.07
146.0390930	0.10
147.1918030	0.03
149.1233063	1.51
160.0700073	3.15
160.9429779	0.05
170.9933319	0.06
173.0906677	0.40
175.1239319	39.58
175.8250732	0.06
178.1632385	0.63
178.9940338	0.06
191.2214050	1.75
193.0682678	100.00
202.0098419	0.63
203.1252594	0.17
206.1181641	0.04
207.0906677	0.86
209.0693665	0.12
211.2005310	0.04
217.0459900	61.12
218.9525452	0.09
221.1846313	0.30
223.1803284	0.19
225.1034851	0.51
226.1552124	0.24
231.2431030	0.11
233.2126465	0.09
235.1516724	9.08
247.0917358	2.32
253.0724487	0.17
257.1925354	0.09
259.1445312	0.98
265.1598511	4.29
266.6571045	0.05
275.2286682	0.11
277.1209412	0.33
283.4410400	0.14
289.2436829	0.18
290.8147583	0.12
291.9512939	0.10
295.2178345	4.69
302.9913330	0.08
306.2699585	0.04
309.0303650	0.15
310.2674255	0.22
311.2655334	0.29
313.4324951	0.08
319.3160095	0.26
334.9153748	0.20
336.2069397	1.87
337.2398682	2.12
340.1070557	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	758.16
Annotation	Unknow
Peak:m/z	Relative Intensity
226.1630707	0.04
227.1641541	0.03
229.3132935	0.02
230.1130981	0.07
239.2051086	0.15
243.1592560	0.42
255.2997284	0.13
258.0003052	0.04
260.1316528	0.03
265.2375488	0.09
270.9257202	0.58
272.1210938	0.03
273.0786743	0.03
280.0747986	0.06
286.0026855	0.15
287.1559143	0.30
299.1554565	0.55
300.2182617	1.30
301.2089844	0.45
302.4870605	0.07
303.1175537	0.44
304.4574585	0.08
308.3757019	0.01
314.0679932	1.00
315.1131287	1.55
316.0119629	0.02
325.1832275	0.19
329.1406250	0.11
332.0788269	32.34
342.8511963	0.16
343.4549866	0.08
347.1478882	71.44
355.0236816	0.05
356.1677246	0.06
358.0278320	0.52
366.2061768	0.04
369.1151733	1.76
370.0415649	0.08
372.9536743	0.08
374.1282349	0.03
386.9141235	0.04
387.5144043	0.17
389.2550049	0.22
391.0675659	0.04
398.2763062	0.07
402.2271729	0.08
409.2091675	0.07
410.3212280	0.08
414.1815186	0.27
417.1063843	0.05
434.0313110	53.14
434.7080688	0.23
448.3624268	0.05
449.1286621	0.05
451.4678955	0.08
461.3251343	0.14
464.3728027	0.08
470.1264038	0.05
475.0881348	0.41
476.2307129	9.72
486.1871948	0.03
487.6237793	0.07
488.2748413	1.77
505.7689209	0.06
513.1773682	0.05
518.3101196	0.33
531.2692261	0.11
533.1979370	0.03
541.9188843	0.79
559.5042114	0.12
566.3964233	0.08
572.3508301	0.04
577.1923218	0.02
581.0997925	0.04
595.1983032	1.39
596.2497559	1.20
605.1998901	0.12
607.3722534	0.58
608.3945923	0.22
625.4542236	0.11
626.1185303	0.19
627.6229858	0.03
638.2327271	0.08
645.3696289	0.10
647.2139893	0.11
649.2122192	0.03
655.4328003	0.03
657.2716675	0.31
662.2446289	0.05
665.3176270	0.16
667.9771118	0.39
669.2263794	0.05
671.2167358	100.00
671.8516235	0.33
680.2481079	0.11
682.2366333	0.85
698.1326904	0.80
705.4133911	0.24
711.3759766	0.07
712.0112915	0.05
713.6839600	0.10
726.3201904	2.37
739.0975342	0.47
740.1799927	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1193
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
130.7526855	0.29
136.1847839	0.08
139.1744385	0.08
146.8009338	0.06
149.0165405	0.64
163.0355225	0.02
175.0001221	0.04
176.8754578	0.07
179.1987000	0.03
189.3626862	0.07
191.1160736	0.07
193.1114349	0.03
194.0958405	0.13
208.3525085	0.20
209.2374268	0.04
218.0789185	0.05
220.9976807	0.19
223.1500397	16.70
233.1965027	0.17
234.9072571	0.13
241.3211670	0.05
251.1778870	0.03
256.0071716	0.06
259.2197876	0.04
269.1400757	0.12
275.1426392	0.04
278.2787170	0.04
280.9908142	0.14
283.0250854	0.07
287.4118652	0.05
288.0215149	0.04
293.1206665	0.15
297.4912720	0.06
298.9461670	0.18
303.2717285	0.03
306.8380127	0.03
315.1033936	0.25
354.3590088	0.08
356.4627380	0.17
357.2794495	0.05
359.1311951	0.05
361.2821350	0.10
371.0965881	0.05
383.3310852	0.20
385.2243652	100.00
387.2856750	0.12
395.0472717	0.17
396.5843201	0.07
400.8640442	0.04
403.2029114	0.10
410.9928894	0.30
412.4007568	0.12
413.3630676	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	711.1414
Annotation	Delphinidin 3-(6-malonylglucoside)-5-glucoside
Peak:m/z	Relative Intensity
208.9343567	0.03
243.3458557	0.08
308.2137756	0.13
332.2772522	0.03
355.1073303	0.34
404.4062500	0.08
490.0733643	0.09
495.2273560	0.56
505.3248291	0.14
549.2435913	0.47
576.3316040	0.11
579.1934204	0.07
582.0502319	0.23
587.0437622	0.18
595.5150757	0.31
616.3612061	0.36
620.9592896	0.28
625.4708252	0.03
627.0543823	0.41
629.1029663	0.17
635.2794189	0.12
639.1625366	0.25
663.7338257	0.17
665.2103882	0.35
667.2485962	100.00
675.2995605	0.06
691.9349365	0.24
693.2170410	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.162
Annotation	Unknow
Peak:m/z	Relative Intensity
175.0154114	0.20
205.0756531	2.03
209.2417908	0.24
211.0070343	1.93
223.1281433	33.25
224.1371155	0.12
241.1415405	1.15
259.0815430	0.14
273.0899353	0.07
275.3038940	0.10
280.0869751	0.71
285.1890869	0.20
299.5056763	0.06
303.4040527	0.10
321.1566162	1.07
323.1618652	100.00
337.4213257	0.06
339.8353882	0.05
341.2684326	0.47
346.1524048	0.02
355.3047485	0.09
359.1250610	0.07
364.4067993	0.22
366.3915405	0.07
381.2549438	0.05
385.0910645	3.52
399.0379028	0.21
401.6061401	0.09
403.0882568	2.69
411.7464600	0.18
419.2297363	0.12
421.4523926	0.25
426.8897705	0.16
428.1943359	0.41
429.2420654	0.08
433.1278687	0.02
445.1303101	0.14
446.0628052	0.16
448.3076172	0.35
456.9991455	0.13
461.1165771	0.10
464.2443848	0.16
467.2775269	0.58
480.2128906	0.09
501.2343140	0.15
501.9536743	0.21
527.0693970	0.48
528.8953857	0.70
545.2156372	0.47
545.9611206	0.03
547.1581421	0.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	743.1301
Annotation	Unknow
Peak:m/z	Relative Intensity
209.1067047	11.76
209.9832458	0.61
247.2897339	0.46
248.2921295	0.07
301.3948364	0.08
353.2137451	3.62
353.9283447	0.16
371.0745850	100.00
372.2217407	4.77
423.3646240	0.28
426.7644043	0.08
439.4271851	0.08
441.2015381	0.09
453.3311768	0.12
462.9649658	0.14
499.4229736	0.06
541.4301147	0.12
543.3192749	0.14
547.2929077	0.30
557.5103760	0.06
559.2476196	0.13
561.3713379	0.51
562.1178589	0.12
564.8549194	0.07
565.4637451	0.26
574.9436646	0.95
575.6427002	0.06
576.2858276	0.41
581.0872192	0.13
582.2728271	0.06
594.6138306	0.16
599.0648193	0.08
604.3643188	0.21
617.2491455	0.91
618.1184692	0.12
620.1228027	0.32
635.7120361	0.37
645.4995728	0.11
696.9824829	0.52
699.3261108	0.43
707.3818970	0.35
725.1402588	4.02
726.3270874	0.52
727.4295044	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	301.0022
Annotation	Unknow
Peak:m/z	Relative Intensity
99.0202026	0.04
107.0354156	0.03
113.1435623	0.01
114.0620117	0.02
114.9972839	0.02
127.9875946	0.01
134.9274292	0.01
141.0059052	0.02
148.0343018	0.03
151.1664734	0.01
151.9404907	0.01
159.1042175	0.01
160.0888062	0.01
161.0300446	0.04
164.9869995	0.03
168.8103180	0.03
170.0493164	0.02
171.1567535	0.06
174.9736023	0.05
179.3100281	0.02
179.9455109	0.01
184.0351257	0.34
185.1857910	0.10
186.1844482	0.01
192.1471405	0.03
195.2523651	0.01
200.9245300	0.05
205.1767883	0.03
206.1394043	0.02
209.0160522	0.01
212.0665894	0.04
213.0596008	0.01
215.4454956	0.02
221.0242004	100.00
223.1963196	0.05
225.3224182	0.03
226.4843140	0.01
229.2352600	0.03
231.5175476	0.01
233.1710510	0.03
239.1042175	0.13
240.3078918	0.02
241.3668213	0.01
243.2264404	0.01
255.2612000	0.17
256.2164917	0.07
257.0195312	0.07
259.2709656	0.01
262.0471191	0.02
265.1909485	0.01
269.0814209	0.03
270.2287598	0.01
271.1416016	0.09
272.8745728	0.13
274.4290161	0.04
282.2547302	0.19
283.0468750	0.32
286.1388550	0.01
291.8074341	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.14
Annotation	(+)-Abscisic Acid
Peak:m/z	Relative Intensity
105.2072449	1.37
110.9931183	1.54
111.7849274	1.04
117.1586456	0.70
127.0434875	1.00
130.5018616	0.95
134.7633209	0.67
136.8326111	1.07
139.0248718	2.51
148.0483551	2.49
149.2178192	2.43
151.2809296	4.48
157.35112	2.47
159.0374908	0.55
160.9439392	3.73
162.8292389	2.31
171.1775513	2.90
179.0911102	2.53
185.0469666	0.94
187.2834167	6.43
189.0614166	3.13
191.1309662	1.04
192.8674469	0.61
205.1620026	3.60
206.0107574	0.42
209.0279694	5.35
211.3295746	2.64
218.9889069	24.28
219.8904266	0.92
221.2321472	2.95
223.2324982	2.17
223.9130554	5.11
229.2135468	8.26
235.2099457	3.10
237.0454865	8.37
244.2705078	19.69
247.1350555	100.00
248.24823	6.54
255.9055176	3.85
256.6917114	3.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	613.1374
Annotation	Myricetin 3-sambubioside
Peak:m/z	Relative Intensity
175.1670227	0.05
207.2228699	0.01
245.1306458	0.05
255.0644073	0.10
259.1139832	0.05
273.1752625	0.10
306.0737305	0.02
313.1343994	0.04
319.1091309	100.00
332.7872925	0.04
343.0372925	0.09
354.1541748	0.01
361.1015625	0.82
364.2404785	0.01
385.2376099	0.15
396.8845215	0.06
415.3591919	0.02
427.2575684	0.16
433.6883545	0.07
435.1868896	0.06
444.3850098	0.08
445.1691284	0.16
447.1913452	0.04
450.1066895	0.01
451.0405273	0.53
456.0487671	0.04
457.2979736	0.07
463.1849976	1.09
464.2248535	0.01
475.1574707	0.11
481.0670166	39.69
481.9984741	0.04
493.1951294	0.12
499.0444336	0.01
504.8079224	0.06
508.3876343	0.08
517.4810181	0.06
522.9666138	0.14
529.0241089	0.04
531.1856079	0.04
541.0081177	0.09
559.2401733	0.26
565.7947388	0.02
567.2158813	0.02
568.0105591	0.02
577.2563477	0.22
584.9026489	0.03
589.5696411	0.14
595.1790161	0.45
601.4975586	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	789.3297
Annotation	Correolide
Peak:m/z	Relative Intensity
261.8761597	0.05
359.1132202	0.04
383.0530396	0.04
396.9240112	0.02
407.2249146	0.03
415.4071045	0.01
425.4118652	0.04
430.4359741	0.01
472.5703125	0.01
493.3753662	0.11
515.3125000	0.01
525.4387817	0.01
542.2617798	0.02
543.1655884	0.12
544.4737549	0.12
556.1951904	0.04
562.5015259	0.02
563.3798218	0.06
568.2495728	0.02
570.4972534	0.04
572.1670532	0.02
574.2075806	0.03
580.3440552	0.04
585.4543457	0.03
586.6551514	0.01
592.5595093	0.21
593.4077759	0.44
594.5095825	0.31
596.3297729	0.12
604.3211670	0.11
606.3119507	0.03
608.2370605	0.05
613.4530640	0.01
616.2273560	0.03
620.4797974	0.47
621.3834229	0.36
622.2404785	0.27
622.8590088	0.02
624.1591797	0.07
627.0140991	0.02
632.2722168	0.02
632.9670410	0.02
634.3526611	3.23
636.4061890	0.24
648.5271606	0.04
652.6231079	0.06
654.4352417	0.08
655.2108154	0.12
664.4301758	0.03
666.2728882	10.46
667.3641968	0.30
668.3644409	0.11
675.4157104	0.01
676.6969604	0.01
688.9082642	0.02
693.3143921	0.11
696.2807007	0.01
697.6274414	0.02
703.5756836	0.08
711.4307251	0.25
713.4920044	0.13
715.4677734	0.15
721.3685913	0.81
725.3507690	0.06
729.3515015	0.45
735.6770630	0.01
738.8839722	0.25
739.4854126	3.05
741.4833984	0.06
743.4070435	0.08
745.4234619	0.01
753.4078979	0.33
757.3128052	100.00
758.0127563	0.29
759.9932861	0.01
761.2923584	0.16
771.3762817	1.51
776.2866821	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	487.13
Annotation	Unknow
Peak:m/z	Relative Intensity
144.7967834	0.50
147.0735168	0.89
148.7946930	0.13
156.9720459	0.51
162.9091187	0.02
165.0460815	1.31
167.0257721	0.11
168.9860840	0.16
170.9593811	0.35
173.0537109	1.35
175.0366821	0.35
184.9448242	0.07
188.9519958	0.22
197.2906647	0.09
201.3452454	0.10
205.0117188	0.42
207.0504761	0.48
215.0211029	0.17
231.0830383	0.04
233.1144867	0.11
244.9471436	0.12
246.5932465	0.03
249.0933533	3.90
262.1836243	0.05
279.1087036	1.44
289.1435547	0.32
294.9357605	0.04
297.1018982	100.00
298.1939087	0.23
304.1502686	0.04
306.2568970	0.07
307.0169983	0.03
317.1827087	0.18
321.1713867	3.53
322.2253418	0.12
325.2578125	0.40
339.1418762	7.53
341.1731873	1.12
348.8102417	0.31
349.9092407	0.51
351.1080322	0.06
361.1954346	0.58
365.1477051	0.08
367.1493530	1.27
375.1319885	0.34
379.2031555	0.58
381.2877197	0.23
389.0576782	0.04
393.2911682	5.79
397.1578674	0.16
399.2077332	0.07
411.2629700	27.21
418.2943726	0.17
425.0690002	0.26
437.1665039	2.62
441.4260254	0.56
443.3174438	1.37
444.1838379	0.03
451.2375488	0.05
455.2102051	18.01
468.1151733	0.10
469.3049622	15.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	551.1024
Annotation	Delphinidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
177.1265411	0.01
195.2000580	0.04
213.4378662	0.02
230.3330994	0.03
230.9879608	0.13
249.1997375	0.06
265.3466492	0.02
303.1071167	100.00
303.9365540	0.01
315.2627563	0.02
327.2028809	0.10
345.1126099	0.50
356.9604492	0.05
369.1426392	0.04
375.1101074	0.02
381.2931519	0.05
388.6063232	0.03
399.1316528	0.15
404.3912354	0.09
406.3735352	0.01
411.2642212	0.13
413.1641846	0.04
418.0178223	0.01
418.6589355	0.07
429.1120605	0.18
447.3204956	0.08
451.9096069	0.03
455.0738525	0.05
461.7815552	0.07
465.2513428	0.04
482.6475220	0.04
489.1251831	0.11
507.2766724	0.06
514.6502075	0.21
515.3051147	0.03
519.3142090	0.01
532.0823975	0.03
533.1794434	0.96
534.5116577	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	387.1065
Annotation	Meliternin
Peak:m/z	Relative Intensity
114.5180740	0.28
116.9533844	0.23
117.9768524	0.07
119.0814667	0.26
129.9297028	0.91
130.9509125	3.39
133.0458984	1.33
137.0024261	0.09
146.9821014	2.59
148.9820557	1.47
150.9558411	0.52
160.9609070	12.23
161.9898224	14.96
163.0255432	9.78
165.0721436	0.06
177.0735474	0.81
179.2195740	1.77
179.9725494	0.56
181.1414490	0.21
193.1515350	0.12
197.2073364	0.16
205.1356506	0.77
207.0977478	2.06
208.9674072	9.72
216.9096069	0.09
218.2199860	0.36
219.3365784	0.28
221.0817566	1.19
223.1414185	0.74
229.1198425	0.16
233.1472168	2.04
235.0707092	0.14
245.0971069	0.16
249.4412842	0.19
250.2065430	0.13
251.3375549	0.07
263.0184937	16.50
266.9685669	0.07
277.1943970	0.14
280.8536377	0.12
284.9300537	0.08
307.1247559	0.13
311.0460815	0.79
312.1550903	0.08
323.1254272	1.15
325.2496033	0.61
327.1961060	0.25
329.3304749	0.60
337.1209412	100.00
339.1394043	0.73
341.1953125	0.23
346.0189209	0.06
350.4157715	0.11
351.2534790	1.20
357.1183167	66.81
369.2269287	95.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0876
Annotation	Grevilloside F
Peak:m/z	Relative Intensity
100.9494934	0.05
104.8322144	0.08
112.9322968	0.03
131.9942169	0.14
133.0199585	0.65
135.0119019	5.65
135.9913177	0.10
137.0088501	0.11
149.8474426	0.07
161.0584717	28.04
162.9871521	0.08
174.9687805	0.13
177.9319153	0.33
178.9935303	100.00
188.4632263	0.04
189.3460693	0.11
193.2345276	0.14
195.1339264	0.08
203.0655518	6.76
209.2272644	0.05
221.2090759	1.16
232.9900513	0.67
245.1655884	0.70
247.2778625	0.04
250.5502930	0.13
251.1626282	3.00
263.1203918	0.08
281.1374512	4.12
294.9851685	0.14
297.0298462	0.13
305.0660706	2.37
323.1472168	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1246
Annotation	Cyanidin 3-(6''-caffeylglucoside)
Peak:m/z	Relative Intensity
175.0186462	0.04
176.1954803	0.03
177.0592041	1.50
178.1116333	0.12
179.1329956	0.36
180.1893463	0.07
189.2744293	0.03
190.8259583	0.02
192.1656036	0.02
200.9841003	0.11
203.9648743	0.14
217.1403351	0.05
218.0358734	0.02
219.1406097	1.01
220.2408600	0.13
221.1318970	0.50
222.1683350	0.15
228.0472412	0.06
229.1482239	0.22
231.2641449	0.06
232.3653717	0.03
233.0713501	0.05
234.0455322	0.07
241.0851135	0.06
243.0014648	0.02
247.3227234	0.05
254.0245667	0.07
255.2486877	0.26
259.3250122	0.24
260.5467834	0.29
261.2136230	0.88
262.0524292	0.24
262.7965088	0.01
264.1820374	0.03
273.1006470	1.70
274.1735535	0.40
285.0324097	0.51
288.1502075	0.02
290.3864746	0.05
298.5049438	0.05
299.2711182	0.08
301.2843933	0.17
302.2836304	0.15
303.1419678	5.09
305.1298523	39.71
306.2349243	10.91
308.2060547	0.04
309.2199097	0.02
315.2418823	1.98
316.1866455	0.38
317.0218201	0.03
325.4750671	0.04
327.2125244	0.20
329.0513916	0.02
333.2421875	0.03
337.1465454	0.03
343.2959595	0.07
344.3975830	0.19
345.2134399	0.59
346.0004883	0.03
347.3566895	0.46
348.4329834	0.10
352.0411377	0.03
355.2943726	0.24
356.2186279	0.16
357.2406616	0.10
358.3097534	0.03
361.2185059	0.07
369.2026367	0.08
372.0830688	0.02
373.3345947	0.64
374.3054810	0.14
380.4039917	0.02
386.1066895	0.06
387.4705200	0.08
397.2409058	0.79
398.1120605	0.16
399.1152954	0.09
411.3635254	0.06
412.4940796	0.06
413.3320312	0.04
414.5208740	0.01
423.2191772	61.47
424.1901855	30.43
425.3576660	0.10
427.3109741	0.65
428.3398438	0.16
429.2542114	0.05
436.2160645	0.03
439.4151611	0.60
441.1636963	100.00
442.1774292	41.77
443.4949951	0.05
447.3709717	0.20
452.0330200	0.22
453.1882935	0.62
454.2284546	0.34
465.1921387	1.39
466.2462769	1.07
468.2491455	0.01
469.2010498	0.04
470.3269043	0.13
471.3948364	0.34
472.2667236	0.30
476.3063354	0.03
481.5594482	0.11
483.2133789	24.10
484.2364502	8.13
484.9796753	0.02
503.0473022	0.09
507.0488281	0.16
516.3496094	0.28
520.3443604	0.02
523.4363403	0.05
524.2458496	0.32
525.5093994	0.39
526.3893433	0.03
531.8524780	0.07
534.2946777	0.12
542.3944702	0.06
547.4817505	0.73
548.3079224	0.18
550.0145874	0.03
551.3850098	0.17
565.2384644	2.52
566.3826904	1.23
573.0913696	0.16
574.4322510	0.10
581.3435059	0.07
591.1979370	12.78
592.3012695	7.51
602.3302612	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
97.13148499	1.83
149.2181702	0.52
152.9927826	0.21
160.7996979	0.25
165.0844269	2.10
166.2227478	3.46
179.178421	0.94
180.9434814	2.30
183.1060638	6.81
194.1530304	6.44
195.1304169	1.32
204.9943085	1.18
206.0954132	0.43
207.198349	6.55
208.1666107	3.32
209.0930786	2.86
212.6730804	0.32
214.7814789	1.95
222.1742401	9.02
223.2192841	9.49
224.1092072	1.09
231.0717621	0.81
233.1194611	2.48
233.7969818	0.65
235.2283325	2.20
249.0851288	1.12
251.0656738	100.00
252.1164093	15.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.3598
Annotation	Unknow
Peak:m/z	Relative Intensity
171.0444336	0.13
172.9645233	0.13
177.1455841	1.95
178.0907898	0.05
178.9180908	0.08
188.9851990	0.07
193.1711731	0.11
194.1110535	0.26
195.2338715	0.21
201.1808472	0.36
205.1108398	0.09
207.6793365	1.07
211.0170898	0.05
221.1202698	4.53
222.0662384	0.36
223.1193848	0.16
224.0815277	0.13
225.1999207	0.50
226.3838501	0.31
228.5238342	0.15
229.5125122	2.80
230.2640991	0.72
233.0390625	0.16
234.9728394	0.31
237.5181732	0.05
238.3489532	0.07
239.9230652	0.25
243.5119019	1.16
245.5422821	0.16
246.6506653	0.09
251.3463440	3.17
252.1991882	2.88
253.1662292	0.45
254.0928040	0.12
255.0282288	0.38
256.0928345	0.80
261.0155334	0.06
265.2473145	2.38
267.3016968	0.61
268.2190857	0.54
269.1583862	3.84
270.2803955	2.07
271.5299072	0.15
272.4758606	0.11
273.6047363	6.36
274.8013306	1.48
275.6348877	0.07
277.5242310	0.09
279.1067505	0.73
282.2297974	0.49
283.3999023	0.33
286.9258118	0.50
289.4858398	0.47
290.1166992	0.24
295.4152832	6.88
296.1006470	0.35
297.5863037	0.44
301.3706665	0.05
309.1444092	1.66
309.8581543	0.23
311.4485474	0.68
312.1416321	0.46
313.1106567	1.85
314.1529541	1.09
317.4535522	2.32
318.3696289	1.78
319.5758057	3.39
320.3953247	1.19
321.3259277	0.11
326.2774658	0.51
327.4823608	0.09
332.7651367	1.01
333.5671387	0.48
334.4090576	0.26
339.2460938	2.14
339.9052124	0.81
340.9690552	0.42
341.8092651	8.29
342.7409058	1.23
344.1822510	0.79
348.4516602	0.30
349.3599243	0.25
353.2029419	0.94
356.2951050	0.32
357.1968994	0.72
357.8779297	0.42
360.1675415	0.18
361.0358276	1.10
363.4302979	7.62
364.2102051	1.64
368.9728394	0.12
375.2680054	0.14
376.2979736	0.30
383.2027588	2.20
384.1110840	0.25
385.4976807	9.75
386.1921997	3.42
387.5087280	0.04
388.1726074	0.09
392.2738037	1.11
393.5131836	0.37
394.9225464	0.48
397.1596069	0.58
398.3168335	0.07
400.1520386	0.18
400.9788818	1.31
401.8095093	0.18
402.7772217	0.48
405.3768311	0.51
407.4042969	2.98
408.3968506	1.06
409.4526978	0.04
419.1238403	0.87
420.0691528	0.15
421.3178711	0.16
422.8001099	0.05
426.8237915	0.64
427.5121460	1.29
428.3540649	0.14
429.5710449	1.53
430.3878784	0.70
432.2283936	0.50
436.2119751	1.15
437.2496948	0.32
441.3421631	0.36
442.7378540	0.68
445.3693237	1.16
447.1005859	0.05
449.1821289	1.22
451.4302979	0.77
452.4356079	0.23
453.4813232	0.87
463.4671631	0.37
465.9074097	0.16
471.8055420	0.52
472.8028564	0.09
473.5202026	1.54
474.7966309	0.27
475.4307861	0.07
476.2678223	0.76
480.3083496	0.95
481.3780518	0.52
482.8229370	0.63
484.9147339	0.12
488.6481934	0.26
489.8804321	0.81
492.8936157	0.15
495.8112183	0.60
496.5945435	0.41
498.1721802	1.01
504.9611816	0.11
507.2903442	0.18
507.9485474	0.05
510.4041748	0.68
511.8407593	0.45
516.3843994	0.16
517.5454712	3.12
518.9257202	39.79
519.8280029	7.25
520.4691162	0.74
521.3619995	0.09
522.4049683	0.07
524.1222534	1.44
525.3511963	0.35
526.0512695	0.25
526.8858032	9.33
527.7296753	0.30
529.2359619	0.91
531.8869019	0.20
533.2526245	0.56
533.9978638	0.56
535.3909302	0.63
539.5663452	0.23
543.6229248	0.20
544.5520630	0.23
547.2478638	0.15
548.9362183	5.36
550.0022583	2.21
552.6080933	0.14
559.7003784	0.96
561.5913696	3.82
562.3815308	7.09
563.3874512	1.10
564.3847046	0.43
565.2643433	0.37
568.4209595	0.66
570.8560181	100.00
572.0493164	1.68
572.8950806	0.93
574.2446899	1.05
576.7929077	0.24
579.8272705	0.15
590.6067505	0.32
591.3884888	0.28
592.2260132	0.45
594.3786011	0.11
595.3815308	0.17
596.3616333	0.37
606.9821167	0.21
608.4964600	2.64
609.4293213	1.09
610.4815674	0.06
620.8994751	0.91
621.9081421	0.73
623.2279663	0.40
635.3551636	0.33
636.4675903	0.17
639.4952393	0.04
640.3689575	0.20
652.3503418	3.02
653.4573364	1.04
654.7885132	0.15
659.5471802	0.11
661.0414429	0.06
661.7028198	0.20
662.3219604	0.18
679.2233887	0.44
680.5708618	0.06
696.4480591	4.05
697.4064331	2.30
698.3225098	0.24
700.6957397	0.12
702.6616821	0.17
705.1262817	0.16
709.0406494	0.44
709.9667969	0.09
711.4430542	0.12
723.4619751	0.88
728.5366821	0.45
729.3587036	0.33
731.3260498	0.05
740.4689331	4.75
741.5069580	1.45
742.7215576	0.24
743.4213257	0.25
744.7890015	0.20
745.4583130	0.82
746.3815918	0.33
749.2907104	0.23
753.1723022	0.16
754.6425171	0.15
761.2687378	0.13
766.2101440	0.12
767.4193726	0.15
772.3340454	0.45
784.3963013	2.24
785.5055542	1.88
786.4773560	0.19
788.2872925	2.83
789.5457153	1.22
790.4598999	0.19
797.2152710	0.29
814.5079956	0.09
815.4650269	0.41
816.6188354	0.10
828.4395142	0.94
829.3720703	0.56
831.7367554	0.21
832.4343262	3.48
833.4619141	1.94
834.4321899	0.27
839.0407715	0.35
841.9565430	0.10
842.7434082	0.23
856.4877930	0.29
858.7553101	0.13
873.7975464	0.21
874.6101074	0.13
876.6477051	3.83
877.5983887	3.59
878.5400391	0.58
893.5890503	0.12
903.0524902	0.46
904.3969116	0.43
905.6851196	0.08
918.5465698	0.04
920.3637695	2.48
921.4457397	2.57
922.5473633	0.76
947.0818481	0.13
948.5514526	0.05
949.5393066	1.03
963.5282593	0.09
964.4348755	1.70
965.6318970	1.74
966.6533203	0.41
993.4594116	0.18
1008.7910770	0.68
1009.5737920	0.58
1010.6597290	0.24
1021.3274540	0.10
1036.1430660	1.67
1037.1137700	2.29
1038.0351560	1.11
1038.8677980	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	305.0665
Annotation	Leucocyanidin
Peak:m/z	Relative Intensity
97.0956650	0.31
108.9879913	0.59
110.9145889	1.05
120.8968353	0.07
122.9603424	0.85
124.9979172	24.74
135.0916748	2.21
136.9482727	21.40
138.9806213	7.67
147.2219391	0.32
149.0948334	0.63
151.0946960	2.53
159.0471649	0.35
160.9825592	6.94
162.9866943	0.15
164.0884705	4.90
165.0311584	23.87
167.1394348	4.92
174.9146423	0.24
177.0213165	4.36
179.0148926	100.00
179.9187927	0.18
181.0431976	0.14
185.0829468	0.20
189.0893707	1.46
191.1749573	1.95
193.2096863	0.60
199.0949402	0.37
201.0344543	4.05
203.0883789	4.24
204.0492554	5.09
205.0269775	0.51
215.1056213	0.68
217.0795898	3.11
219.0573120	78.13
221.0863953	89.30
225.2842407	0.36
228.3271790	0.46
229.0789490	0.16
231.2011719	0.27
233.0482483	3.45
243.1772461	6.64
244.0810242	0.09
245.0327148	0.67
247.1079102	13.65
248.6376343	0.07
259.0561523	0.14
261.1868896	44.99
263.1254578	7.84
269.1115417	0.35
275.7878418	0.08
277.2009277	0.50
287.1395874	10.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	195.1012
Annotation	F 11334A1
Peak:m/z	Relative Intensity
56.8892250	0.16
76.9436111	0.07
78.8004379	1.82
89.0414429	0.21
90.9948883	0.27
92.8715973	4.25
94.8527985	0.16
104.9929657	0.57
106.9950562	3.54
108.9626312	0.31
109.9642487	0.16
110.9552155	0.21
117.0339355	7.44
117.9906769	0.25
118.8394318	0.07
120.9921570	27.54
123.0391541	0.06
124.2066498	0.09
125.0868683	0.14
131.0574951	3.33
133.0574341	1.90
135.0121307	22.12
136.8686218	0.21
137.9844360	5.20
139.0267487	1.78
140.9367523	0.18
147.0731506	0.12
149.0011139	31.81
149.6072235	0.25
151.0289154	0.82
153.0178070	4.86
158.9954987	0.99
161.9972382	0.05
162.9053345	0.04
164.2206879	0.16
167.0893402	1.23
177.0253143	100.00
180.0678711	0.04
195.1537628	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	262.237
Annotation	Unknow
Peak:m/z	Relative Intensity
78.9259644	0.01
80.7942810	0.09
82.8995895	0.04
84.9551620	0.11
94.9766083	0.32
97.0969391	0.14
107.2029724	0.17
108.9793549	0.40
110.8318481	0.11
113.0621490	0.17
121.0457458	0.43
122.2658386	0.06
122.9994507	0.17
124.9255219	0.15
127.3794556	0.03
128.9965363	0.02
135.0697784	0.72
146.1341248	0.02
147.0665741	0.04
149.2145386	0.26
151.1733093	0.14
154.1737061	0.02
158.5014648	0.03
159.9115753	0.07
163.3528900	0.05
164.9574432	0.19
172.6865234	0.02
176.0338898	0.03
178.8788300	0.01
180.9554901	0.02
182.1729584	0.03
184.1221619	0.01
189.2154388	0.02
191.1306458	1.94
202.1547394	0.18
206.2648773	0.14
208.2544098	0.09
209.1557159	1.58
213.0765381	0.13
214.4644318	0.04
216.1736908	0.10
220.0154572	0.01
221.1372528	0.21
226.1841888	4.80
227.2321320	0.44
232.1218109	0.01
234.0627594	0.12
235.3805389	0.03
239.0929108	0.02
244.2094269	100.00
245.1078949	0.27
247.0128937	0.03
252.6289673	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	672.408
Annotation	PI(22:1(11Z)/0:0)
Peak:m/z	Relative Intensity
191.1098633	0.01
201.0834503	0.03
207.2042999	0.01
210.9960327	0.03
217.0056305	0.02
219.0748444	0.05
220.0080261	0.04
221.1371613	0.40
222.1904297	0.04
223.0426788	0.13
225.1487427	0.19
226.1377106	0.07
227.1352234	0.02
235.1141968	0.04
237.2325134	0.10
239.2102966	0.02
249.0609741	0.02
250.3349152	0.02
251.2461700	0.35
252.1165161	0.03
253.1254730	0.20
255.1788940	0.06
256.1342163	0.02
261.4018860	0.04
262.8406982	0.03
265.0918274	0.34
266.1483765	0.07
267.0648499	0.04
268.9841309	0.23
270.2827759	0.02
271.3065491	0.03
279.9174500	0.02
283.3476562	0.03
284.9541931	0.03
293.2830811	0.01
295.1372375	0.14
296.2195435	0.19
297.2344971	0.05
298.3335571	0.10
301.1368408	0.04
304.9632568	0.01
307.2875366	0.04
309.0928345	0.50
310.2123413	0.06
311.3667603	0.22
312.1826172	0.06
313.2778320	0.30
314.1207275	0.03
315.1716309	0.07
316.0618286	0.03
323.2542725	0.04
327.2585449	0.13
328.3876953	0.09
329.1431274	0.20
329.9228516	0.11
330.8059082	0.04
332.1807861	0.01
337.1650391	0.04
339.1864624	0.11
340.0321655	0.04
341.2391357	0.13
352.9870605	0.29
354.1311035	0.03
355.1611328	0.27
356.0965576	0.02
357.0458374	0.73
358.0725708	0.10
359.1928101	0.10
360.1586304	0.03
371.3185425	0.08
372.0785522	0.02
373.2982178	2.76
374.2153931	0.72
375.2945557	0.04
376.3432007	0.01
385.3697510	0.02
399.1309814	0.08
401.1129761	0.56
402.1975708	0.14
403.3771362	0.07
404.4502563	0.06
409.4408569	0.02
415.1563110	0.04
417.0913696	1.31
418.1996460	0.58
419.2588501	0.82
420.2670288	0.05
426.8839111	0.07
428.2528687	0.02
443.2059937	0.10
444.6871948	0.22
445.3679810	0.48
446.3413696	0.07
447.3664551	0.16
459.3400879	0.07
461.0091553	0.47
462.3131104	0.11
463.3267212	0.60
464.2756348	0.35
479.3273926	0.22
489.5762329	0.02
492.1996460	0.01
503.4795532	0.03
505.1166992	0.27
507.0321045	0.82
508.1773071	0.05
508.8783569	0.02
523.2156982	0.37
524.4146118	0.13
531.0562134	0.02
533.1921997	0.37
534.0741577	0.06
539.2285156	0.01
549.1137695	1.51
550.2274780	0.61
551.2686157	11.43
552.3563843	4.78
567.2665405	0.77
568.3103027	0.62
568.9367065	0.02
577.0343628	0.04
586.5679321	0.02
592.8637085	0.11
594.5552368	0.08
611.3523560	1.18
612.2201538	0.50
612.8457642	0.01
627.4905396	0.06
637.0349121	1.31
638.1023560	0.38
641.2793579	0.09
655.2610474	100.00
656.2886353	36.41
656.9551392	0.34
673.6841431	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	477.1037
Annotation	Pedaliin
Peak:m/z	Relative Intensity
137.2110901	0.08
149.0726624	0.28
150.8379669	0.20
151.9465942	0.15
152.7987823	0.32
160.8296356	0.13
163.0961761	0.22
163.8774719	0.08
174.9229736	0.03
177.1671753	0.04
179.0936890	0.11
180.8282013	0.16
186.0566406	0.08
189.0289612	0.13
190.0712891	0.07
192.0409851	0.33
193.9870911	0.13
196.2919922	0.28
200.0623474	0.17
203.3744507	0.06
205.9575958	0.17
207.1762238	0.23
208.8945007	0.05
214.1441650	0.11
215.1933746	0.10
216.1201172	0.08
217.0712738	0.22
218.0847015	0.10
219.7644653	0.50
227.0814667	0.07
227.9550629	0.08
229.2125549	0.41
230.3620300	0.10
233.2209167	0.04
235.0915833	0.08
236.0829620	0.08
239.0144348	0.12
241.2582397	0.06
243.2014771	0.41
245.1813507	0.42
247.1298828	0.05
251.7239990	0.12
252.3588562	0.14
254.0480957	1.68
254.7908325	0.14
256.1333618	0.21
257.2128601	0.44
259.2252808	0.64
260.0395508	0.17
261.0312195	0.72
266.1811829	0.06
267.1775513	0.07
269.1027222	0.70
270.3312683	2.45
271.1873779	5.43
272.1927795	0.95
273.4466553	0.07
274.1344299	0.12
275.1213684	0.06
281.1657104	0.27
281.7991333	0.14
284.0849915	0.75
285.1049805	1.69
286.3890991	0.95
287.0978699	0.64
289.0701599	0.08
295.0466919	0.20
296.1548157	0.10
297.2056580	0.05
299.0674438	74.34
300.1473694	15.49
301.1365356	0.49
309.1576233	0.16
309.8971558	0.08
311.1274719	0.27
312.1401978	0.43
314.0846558	100.00
315.0853577	35.54
316.1018982	1.24
319.1902466	0.04
324.2404785	0.06
325.0829468	0.33
327.1546631	0.42
329.2402954	1.71
330.4105225	0.14
339.2443237	0.40
340.0756226	0.22
341.3269043	0.26
342.1406250	7.33
342.9632874	0.19
345.1353455	0.03
351.3243408	0.12
354.0502014	0.16
357.1730957	22.99
358.2901611	0.37
367.2579651	0.22
369.2404175	0.16
371.2600403	0.06
372.1784668	0.30
376.4234314	0.17
380.9620056	0.28
387.2297974	2.16
388.2646484	0.03
389.1867371	0.04
394.2739258	0.07
395.4159241	0.08
399.3184204	0.09
400.6435547	0.05
409.4028625	0.26
415.3133240	0.21
417.2435608	0.25
430.5601196	0.11
431.2726135	0.71
433.6466064	0.61
434.3927307	0.10
435.4792786	0.04
441.3941040	0.06
444.1202698	0.03
446.9931946	0.11
449.1984253	50.50
450.2043152	4.79
459.1578674	1.07
462.1404724	7.24
463.2359924	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	316.1385
Annotation	Unknow
Peak:m/z	Relative Intensity
109.1228104	0.07
134.0417786	0.27
137.0242462	0.11
139.1224976	0.01
141.3141479	0.05
152.9572754	0.02
155.1219788	0.04
159.5145721	0.02
161.2054596	0.03
163.1036987	0.03
165.0105591	1.43
168.7161560	0.01
173.0790710	0.07
175.0525818	0.01
177.3255920	0.03
178.1237793	0.02
181.7023468	0.01
182.9648590	2.13
184.2715454	0.02
185.3370209	0.06
191.7235107	0.04
199.0484619	0.01
200.8300476	1.26
217.3975525	0.02
221.3111267	0.08
226.0108948	0.24
234.0509338	0.03
237.2492065	0.03
242.9804077	0.03
244.1601257	0.06
249.7127075	0.04
252.0791321	7.61
253.0639038	0.12
255.2728882	0.03
258.2877808	0.04
261.3740540	0.15
262.0649414	0.01
263.1414490	0.03
265.2893066	0.03
268.0599976	0.02
270.1040649	7.74
272.0154724	0.13
274.5174866	0.06
275.1235962	0.12
277.3858032	0.14
280.0195312	10.21
281.0127869	0.20
283.5315857	0.04
284.9719238	0.11
286.3486023	0.04
288.0491028	0.19
289.0983276	0.16
295.1900635	0.16
298.0738220	100.00
298.7083740	0.37
299.4866943	0.08
301.0140686	0.01
302.0517883	0.74
307.8761902	0.06
314.0778809	0.01
315.9825134	0.04
325.1791992	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.0777
Annotation	Aesculin
Peak:m/z	Relative Intensity
110.9557495	0.82
126.2109299	0.04
128.9896698	2.45
135.1341705	0.12
147.0605774	0.52
172.8236389	0.21
179.0199890	0.36
186.8672333	0.19
191.0104065	9.32
203.1343231	0.05
205.0123444	8.93
207.1470184	0.03
208.9980621	6.89
222.9935303	100.00
223.6437073	0.05
247.0127869	0.47
259.0282288	0.08
261.1557007	0.05
287.0838013	0.20
305.2895508	0.25
320.9836731	0.35
322.9870605	0.31
326.9856567	0.06
334.8764648	0.04
341.2089844	0.24
349.1427307	0.24
353.2841492	0.25
353.9528198	0.02
367.1896057	6.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	714.3668
Annotation	Unknow
Peak:m/z	Relative Intensity
259.0272522	0.09
268.2077026	0.01
276.3158875	0.07
288.3794250	0.07
291.9440918	0.05
293.4967041	0.02
310.2998657	0.67
311.3193054	0.41
318.3732910	0.13
328.3380127	1.37
329.2794800	0.32
340.1817627	0.03
341.4085693	0.02
346.3912964	0.75
347.2051392	0.05
364.4270630	0.12
370.1813965	0.11
388.5443115	0.20
389.3510132	0.05
390.4907837	0.05
404.4368286	0.23
406.3053589	35.78
407.3916016	9.43
418.6452637	0.02
420.6243896	0.10
434.5495605	0.09
436.3468628	0.01
448.2675781	0.35
454.5015259	0.29
455.3993530	0.16
481.3629761	0.08
490.3823853	0.09
491.2265625	0.04
492.0285645	0.09
498.1639404	0.06
508.3733521	0.11
510.4917603	0.11
515.9256592	0.07
516.5980225	0.59
517.6297607	0.02
532.2239380	0.10
534.4928589	0.54
535.3850708	0.27
550.3744507	1.68
551.6954956	1.95
552.4398804	8.36
553.4559937	2.88
566.5682983	0.09
568.3771973	100.00
569.3827515	28.85
570.0101318	0.13
574.4547729	0.06
580.4816284	0.12
582.8937378	0.06
594.1008911	0.02
594.7288818	0.03
595.3781128	0.11
600.6303101	0.08
610.5669556	0.52
611.5316772	0.19
627.9088745	0.04
637.3278809	0.03
654.6774292	0.16
660.2626343	0.10
661.6510010	0.02
678.5465088	3.06
679.5067749	0.87
696.4584351	7.14
697.5076294	2.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.2287
Annotation	L-Linalool 3-[xylosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
152.8902893	0.03
162.7084351	0.05
187.1383667	0.02
199.2492981	0.03
215.2602386	0.02
247.3802795	0.02
273.1308899	0.02
281.1602478	0.02
283.1573792	0.02
287.2447510	0.02
293.2987061	0.03
298.1992798	0.05
299.4613037	0.07
310.9782715	0.06
312.3591614	0.04
315.3114929	0.06
317.4859314	0.04
327.0837402	0.05
331.0540771	0.38
346.4903259	0.18
348.3787231	0.02
357.4120483	0.02
361.3695679	0.34
371.2884216	0.03
375.2171631	0.05
379.2999878	0.02
395.3054199	0.06
397.0250854	0.02
401.3270874	0.18
406.1193848	0.17
407.6402283	0.04
413.4576721	0.03
418.2342529	0.06
419.2543030	0.04
425.4558716	0.09
429.5435486	0.17
431.5848389	0.03
433.2839355	1.79
434.0115051	0.01
439.5570984	0.03
447.2335815	100.00
447.9755249	0.16
448.9356384	0.28
449.6918945	0.06
451.3824463	0.46
454.2372742	0.12
455.1951904	0.08
456.3012390	0.34
457.4927979	0.11
458.1122437	0.29
464.4344482	0.03
466.0948792	0.02
474.2619324	0.10
475.1705627	0.14
476.2835083	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.1611
Annotation	Stereospermoside
Peak:m/z	Relative Intensity
150.1400604	0.07
151.0166016	0.38
152.0623169	0.31
160.6849518	0.09
165.0081177	1.07
167.0017090	3.49
175.2495728	0.29
181.1138916	0.06
190.0151062	0.06
195.0050049	2.06
206.0970306	0.67
209.2589722	0.06
211.0438232	0.06
220.2049255	0.09
224.2525024	0.18
235.1061707	0.08
241.0252686	0.19
243.1437988	0.04
253.1206360	0.20
284.4005127	0.12
301.2149048	0.26
303.1261597	0.11
305.2550659	0.29
307.3353271	0.16
310.3807373	0.27
311.1794434	0.33
315.1188354	5.58
317.2221069	0.20
329.1286011	0.86
335.2350464	0.20
341.1053467	0.09
344.9498291	0.45
347.0696411	0.26
351.5260620	0.14
361.1640625	0.11
363.1843262	100.00
383.1760864	0.12
387.4797363	0.22
390.4713135	0.23
391.3793945	0.10
399.2891846	0.06
403.2898560	0.08
404.9467163	0.71
406.3735352	0.10
409.0141602	0.08
411.2128296	0.17
415.6509399	0.21
419.1279297	0.19
421.1570435	0.22
421.9201050	0.11
424.2412720	0.13
428.3856201	0.35
429.2972412	0.24
431.9537964	0.42
433.0792847	0.08
435.1387939	0.36
437.2434692	0.11
441.4231567	0.24
444.1004028	0.39
446.3344727	0.09
447.1348267	0.26
464.5111694	0.29
465.2985840	0.20
479.2086792	1.32
481.1756592	1.41
485.4549561	0.56
486.5444946	0.06
490.1959839	0.07
494.7868652	0.06
497.0487671	0.22
506.1536255	0.05
507.0896606	1.56
508.1759033	0.17
515.7839355	1.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.0859
Annotation	Aesculin
Peak:m/z	Relative Intensity
123.2172775	0.11
132.9709167	0.09
134.8894653	0.07
137.9246674	0.05
144.9221497	0.06
151.1402283	0.16
154.8195190	0.02
178.9618988	100.00
195.1717834	0.05
209.0907288	0.05
212.1104126	0.04
217.1083679	0.12
220.2308044	0.03
231.0332031	0.01
270.3736267	0.05
276.5893555	0.14
286.9874878	0.27
291.2161560	0.05
293.0631714	0.06
297.0877075	0.26
300.0838318	0.07
304.9620361	0.14
306.3855591	0.04
313.3952637	0.16
321.8540649	0.12
323.1843872	0.77
324.0962219	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	491.3077
Annotation	Unknow
Peak:m/z	Relative Intensity
146.0991821	0.02
176.8186035	0.25
207.3479919	0.07
211.0096130	0.22
213.1921387	0.09
221.2241669	0.49
223.0060120	0.05
227.0135345	0.05
235.0318909	0.11
238.1203918	0.14
239.9433594	0.06
243.2730408	0.32
251.5969086	1.12
252.2407379	0.24
252.9049683	0.12
253.9523010	0.05
268.1240540	0.14
269.2029419	0.70
273.4094543	0.95
274.1043701	0.33
275.7364197	0.02
289.4424744	0.07
295.8511353	1.48
297.0734863	0.12
299.4077759	0.01
301.2315674	0.09
309.3782654	0.25
311.6401367	0.06
313.1337280	0.73
314.3634033	0.08
317.6054077	1.01
319.5466919	0.81
326.5208435	0.02
333.8010864	0.37
339.7740173	0.77
341.5403442	2.57
342.2571716	0.63
343.3647461	0.02
348.2598572	0.21
353.2398682	0.09
354.3793335	0.03
357.0198975	0.22
358.1127319	0.03
361.1158447	0.04
361.7500000	0.15
363.6588745	0.95
364.4270325	0.13
379.3024902	0.06
383.7069702	0.14
384.9922180	0.21
385.6128235	1.98
386.3164368	1.00
387.3567200	0.04
392.3740540	0.16
396.2640991	0.03
400.3125305	0.08
401.0982971	0.14
407.6125488	0.72
414.1659241	0.07
417.9822083	0.07
419.4008484	0.06
422.3380432	0.56
429.4925842	1.62
430.9397888	38.85
431.7666321	0.19
432.3952332	0.37
433.4520569	0.32
434.3913269	0.49
437.4881287	0.05
438.9121399	0.15
441.1135254	0.11
445.0786438	0.32
446.0414734	0.05
450.0964050	0.02
452.0175781	0.29
454.9628601	0.08
457.1016541	0.14
459.5163574	0.06
460.2673950	0.12
461.0633850	0.25
461.9518738	0.15
462.9174500	0.09
465.2604675	0.22
473.6712036	0.98
474.3661804	1.86
475.2039490	0.14
476.2062378	0.29
478.4694519	0.02
482.8753967	100.00
484.4816589	2.08
485.5023499	1.20
486.4800720	0.27
487.5055237	0.29
488.4688416	0.43
489.5393677	0.05
491.4214172	0.09
496.2973022	0.06
496.9134827	0.07
520.2753906	0.66
521.4570923	0.17
529.0452271	0.03
532.9051514	0.03
547.9117432	0.16
564.3248901	0.48
565.2749634	0.29
578.2965088	0.11
591.3301392	0.36
592.2498169	0.08
608.2871704	0.55
609.3912964	0.14
616.6573486	0.17
635.8471069	0.02
636.5820923	0.05
640.3121338	0.09
652.6097412	0.19
656.2546997	0.09
683.1655884	0.03
684.4858398	0.14
696.1171265	0.04
697.8024292	0.04
700.3546753	0.35
701.6901245	0.09
711.6084595	0.04
724.5559692	0.02
727.6690063	0.05
728.5647583	0.17
743.2090454	0.03
744.4170532	0.64
745.4266968	0.56
753.3343506	0.14
772.4525757	0.10
773.5346680	0.12
788.5045166	0.81
789.8871460	0.18
832.4756470	0.09
833.1916504	0.16
843.5498657	0.34
860.4749146	15.35
861.5646973	9.11
964.6271973	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	380.2423
Annotation	Ro 09-1543
Peak:m/z	Relative Intensity
117.6085205	0.01
147.2657776	0.03
151.1190033	0.02
157.2947083	0.02
163.1323700	0.02
164.9066772	0.05
186.9342651	0.05
200.1766052	0.07
201.0351868	0.02
205.0569611	0.05
230.3279114	0.29
238.2393494	0.11
239.3316040	0.07
239.9438782	0.08
242.2414856	0.14
249.0834656	0.14
260.4281311	0.10
262.2043457	0.02
263.0719299	0.02
271.2124329	0.06
274.1676636	0.29
277.4649048	0.03
292.0582275	0.05
299.2586670	0.04
308.5177612	0.03
309.3064575	0.02
313.4970703	0.03
322.3462830	0.02
325.1924438	0.06
326.2869568	0.55
334.2323608	0.13
335.3625793	0.08
336.5372620	0.06
338.6900024	0.17
343.1897583	0.16
344.2444458	0.82
345.3142700	0.03
356.3123474	0.12
358.8677063	0.08
362.3138123	100.00
363.3324280	0.25
364.3413086	0.03
370.8710022	0.06
380.7223511	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.1818
Annotation	Geniposide pentaacetate
Peak:m/z	Relative Intensity
178.9163361	0.15
195.1179504	0.16
207.0057373	0.08
209.0636139	0.08
225.2181091	0.23
244.1644592	0.11
247.0369568	0.03
251.4005280	0.16
255.1135864	0.10
256.1953735	0.06
272.0587769	0.05
275.1767273	0.07
300.1546021	1.18
301.2010498	1.95
302.1564941	0.21
303.2293701	0.46
305.4316101	0.21
315.2416077	1.23
327.2310181	0.08
344.0319824	0.05
345.0288696	0.21
355.5783691	0.07
357.1562500	100.00
357.7780151	0.38
369.2449341	3.41
373.0292969	0.03
375.1862793	0.09
383.0452881	0.07
385.4321899	0.20
387.2856445	86.06
389.1579590	0.08
399.3401489	3.06
403.0597534	0.19
405.3345337	0.08
411.2334595	0.57
413.4822998	0.08
417.2965088	23.46
418.3469849	0.09
429.1358643	2.20
429.8524780	0.03
434.4597168	0.13
435.3146973	0.05
441.2105103	1.56
445.3038940	0.16
447.0921021	0.92
456.9181519	0.07
457.7674561	0.47
459.2518311	20.97
464.2439575	0.21
465.4079590	0.48
471.3888550	0.96
475.0962524	0.14
477.2500610	89.93
489.2787476	17.52
507.1691284	9.38
519.3283691	0.82
533.3519897	0.20
537.3836060	0.51
543.3779297	0.09
551.1359253	0.17
561.2274170	2.14
567.4978638	0.14
579.2141724	20.45
579.8682251	0.54
581.2891235	0.09
587.5934448	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	552.3177
Annotation	Unknow
Peak:m/z	Relative Intensity
172.1100159	0.03
178.9866333	0.19
183.1848297	0.32
184.8870850	0.03
200.1515350	0.05
201.1506500	0.14
213.2196350	0.08
243.4276123	0.20
254.0725098	0.31
258.1835938	0.04
259.4182434	0.06
272.1806335	0.74
283.3967590	0.11
288.2392883	0.26
304.5247803	0.23
306.1246338	0.06
312.4512329	0.18
313.3468628	0.03
336.5163574	0.08
341.6953125	0.08
345.1895752	0.14
346.3308105	17.87
348.4038086	0.46
350.1326294	0.26
359.3085938	0.09
361.1864624	0.10
369.4192505	0.02
371.1438599	0.04
376.3687134	0.13
380.4182739	0.12
387.2561035	0.13
388.7495117	0.28
389.4535522	0.64
390.1746826	0.42
391.4050293	0.15
405.6400757	0.21
406.3153076	0.09
412.2889404	0.11
413.6340332	0.06
414.3668823	0.14
419.2335815	0.25
420.7139893	0.22
424.4752197	0.06
430.2754517	1.17
431.2346191	0.04
434.5399780	0.19
437.5142822	0.35
442.4017334	0.04
447.2053223	0.09
449.7591553	0.07
462.3873901	0.25
470.9199219	0.13
473.6050415	0.23
474.4501953	0.19
477.5637207	0.25
478.6649780	0.10
492.3773804	100.00
494.0477905	0.05
497.2017212	0.10
506.2246704	0.16
507.5203247	0.19
508.2199097	0.34
510.3563843	3.67
515.3342896	0.17
516.3071899	0.08
519.3814087	0.16
520.4271851	0.14
524.0078735	0.04
533.5959473	0.57
534.4761353	0.25
535.4590454	0.43
563.5153198	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1251.79
Annotation	Unknow
Peak:m/z	Relative Intensity
405.9886475	0.55
570.9262085	0.27
625.2193604	100.00
626.3337402	1.35
926.2174072	1.64
927.3596191	2.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2867
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
142.3195496	2.89
169.009491	4.63
189.3589172	3.86
197.3831024	3.48
199.0740509	1.79
202.0762787	2.89
208.8636169	4.19
220.9937744	4.41
225.7388	3.17
226.3881378	14.15
229.1046906	5.88
245.1456909	3.93
267.4023132	8.36
268.3636475	10.41
281.3258057	18.01
285.1741943	4.46
297.522644	1.65
301.3694153	2.53
311.2677917	5.56
312.0933533	4.88
314.9390869	10.43
320.3407898	3.31
322.2754211	3.61
326.7016602	5.84
331.9523621	9.54
336.2793579	5.16
339.3068237	12.68
341.4177246	8.57
351.2805481	3.49
354.6256104	7.10
355.5845642	2.89
356.1882629	5.56
357.4651184	9.75
359.3304138	6.87
364.0652771	7.36
380.3045654	3.58
381.3505554	15.56
383.4599609	9.41
384.956665	4.72
390.272583	47.30
391.1516418	12.86
398.4763794	6.03
403.9826355	4.70
407.1152039	11.20
408.2701721	100.00
409.0803833	14.15
425.0026245	11.95
427.1593323	3.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	524.3212
Annotation	Ambiguine
Peak:m/z	Relative Intensity
164.0414276	0.19
169.1014557	0.11
174.9726562	0.04
177.1121826	0.39
189.3200378	0.08
191.1278076	0.13
193.1591492	0.03
209.2377167	0.05
219.9227905	0.05
224.8960266	0.10
226.5298615	0.12
228.4548645	0.15
229.2419739	0.02
235.1653442	0.24
236.9498749	0.16
258.2741394	0.04
259.5894775	0.12
264.2326355	0.16
265.0112915	0.50
267.2536011	0.20
269.1816406	0.30
271.0485229	0.11
277.3187256	0.05
279.2232666	0.18
286.0364380	0.03
295.2720337	0.49
298.0647278	0.03
313.1404419	2.51
315.1178589	0.18
315.9754639	0.03
324.4485474	0.19
357.3211670	0.40
363.5021362	0.12
364.2629395	0.35
383.2374878	0.06
393.5991211	0.15
396.1444702	0.17
401.1307373	0.98
403.1213989	0.59
413.6480103	0.05
419.3097534	0.95
420.0296021	0.20
444.6611328	0.09
452.3246460	0.05
461.3787231	0.19
463.3522949	0.70
467.5009766	0.31
471.1328735	0.19
475.0066528	0.13
478.7373047	0.11
480.1354370	0.29
482.6043091	0.11
486.2664795	0.34
488.4584351	0.60
489.1343384	0.13
493.2194214	0.12
495.1659546	0.20
507.1965332	100.00
507.8963013	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	471.1354
Annotation	4-O-Methyl-a-D-glucosyl-(1->2)-b-D-xylosyl-(1->4)-D-xylose
Peak:m/z	Relative Intensity
139.0677490	0.69
142.8177643	0.79
149.0128174	0.08
157.1255493	0.65
172.8869324	1.09
175.0884247	1.57
185.2532654	0.14
189.0682678	2.70
205.2467651	0.20
207.0772705	2.41
215.0889587	0.58
217.2656555	0.72
220.7872620	0.41
233.2950592	0.22
249.1582336	12.47
261.1832581	0.05
287.2402954	0.09
289.0705872	4.93
305.2095337	0.13
307.0301208	1.47
317.1475220	5.08
321.0567017	22.27
339.2078857	15.33
341.2293091	0.17
344.5220947	0.48
349.4940796	0.32
361.0773926	4.06
361.6849670	0.06
375.1691589	0.12
379.1502380	7.01
381.1085815	0.86
387.1157532	1.32
393.2064514	16.57
411.2803040	100.00
421.0632629	0.23
424.9075928	3.11
439.1575012	4.62
453.4307556	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.34
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
165.9947357	0.09
183.9891052	88.70
184.6080170	0.05
207.1700287	0.21
211.2353973	0.03
213.3185577	0.02
244.4005890	0.02
252.2209320	0.11
258.2835693	0.73
292.2992249	0.06
311.1043701	0.16
340.3609619	0.03
358.1346436	0.74
362.4519653	0.10
379.3499756	0.42
386.2325439	0.06
451.1773682	0.04
452.0379028	0.04
457.2495728	0.32
460.1600952	0.09
467.3905640	0.15
472.9653931	0.10
489.8557129	0.05
502.4102173	100.00
503.5573120	0.78
519.5021973	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	612.3724
Annotation	13-Deoxytedanolide
Peak:m/z	Relative Intensity
175.0603943	0.10
176.9293671	0.45
191.1543121	0.02
193.2077637	0.14
196.8353577	0.04
209.2556000	0.14
219.1375275	0.11
219.9074097	0.06
221.0422058	0.37
223.1163635	0.05
224.9954834	0.19
227.1943512	0.05
235.0773315	0.16
237.1758118	0.09
243.0338287	0.03
251.2888794	0.41
253.0688477	0.21
255.3221436	0.25
265.0349731	1.09
265.6743469	0.01
266.7231445	0.09
267.4984741	0.02
269.1204529	2.09
271.2597351	0.27
277.0451355	0.10
279.1820374	0.54
281.2632751	0.06
283.2196045	0.06
293.1826782	0.06
295.3009033	0.21
297.1609192	0.27
299.1250305	0.26
304.2670288	0.05
305.0283203	0.02
309.1785889	0.86
311.0475464	0.02
311.6887817	0.04
313.1471863	2.06
314.5247803	0.04
315.1325684	0.08
321.3839111	0.07
323.2295837	0.22
324.9658508	0.02
326.2010498	0.17
329.0143433	0.02
339.2465820	0.13
340.1329346	0.10
341.0779419	0.05
343.2897949	0.02
353.0340576	0.72
355.1722412	0.12
356.9762573	0.53
359.2497559	0.36
367.2686768	0.36
372.0731201	0.04
374.5697021	0.12
375.2125244	0.13
377.5268555	0.06
383.2901611	0.14
385.2930298	0.28
391.6043701	0.02
397.1998291	0.22
400.5903320	0.21
401.2207642	1.36
403.1328125	0.62
403.7633057	0.02
410.8756714	0.04
419.2208252	0.27
427.3968506	0.04
431.7155151	0.03
445.1817017	0.77
447.2307739	0.45
448.8880005	0.06
457.1665649	0.08
463.3258057	0.51
472.5626831	0.07
473.5245361	0.09
478.2225342	0.05
489.1386719	1.77
491.2048950	2.08
492.0128784	0.01
493.2681274	0.05
505.3905640	0.05
507.3432007	2.71
511.5269775	0.04
513.7824097	0.02
516.3415527	0.03
522.4552612	0.08
523.8982544	0.07
532.0160522	0.09
533.5634766	0.01
537.6373901	0.11
539.1871338	0.03
540.1515503	0.02
551.3720093	1.70
552.4039917	0.33
554.2103882	0.05
566.2996216	0.07
567.2602539	0.16
568.5881958	0.05
576.5407715	0.14
577.1970825	0.97
580.5790405	0.04
583.2179565	0.11
584.1917114	0.01
589.5056763	0.12
595.2476807	100.00
595.9185791	0.16
614.1521606	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
90.88998413	0.53
95.04683685	0.27
97.04205322	0.39
100.9613953	0.43
107.0227509	0.93
108.9486847	0.39
116.9853363	0.25
123.0605011	0.34
132.982605	0.49
137.090744	1.11
139.176178	2.78
140.9038696	2.45
142.9663391	1.82
150.1164551	0.34
151.0429688	0.46
153.0252228	1.24
155.1633301	2.10
156.7459412	0.80
162.9103699	0.63
165.2028351	1.23
166.8969421	0.67
169.0528259	1.53
175.286087	1.38
177.3397675	0.21
178.6843262	0.47
180.8302002	1.59
183.0502625	0.41
185.2183228	0.62
189.2166138	0.13
192.2568817	0.91
195.3886566	2.43
197.1604919	0.67
199.0135193	0.74
204.9726562	0.50
209.1296387	3.06
210.0336609	0.46
211.3604431	2.38
213.0398865	2.22
215.2007141	0.55
217.0379639	0.82
219.3025208	2.00
221.2633057	1.68
223.2121887	3.37
225.0840454	1.34
237.2162781	2.46
239.5036621	1.92
241.5551758	1.71
244.8928528	0.28
247.0432129	0.61
249.5018005	0.20
251.0787354	2.18
253.0925293	6.39
255.1350403	0.88
257.2749023	1.79
263.2411499	0.30
265.3074341	5.17
267.2732544	0.75
268.3028564	1.02
269.336853	1.26
275.2832947	11.94
279.2718506	1.90
279.9209595	0.11
283.0263367	5.55
284.1217651	0.27
290.3776855	1.52
292.2080078	4.75
293.2030945	100.00
294.170105	0.82
302.2792969	1.62
303.1203613	1.96
311.2378845	2.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	369.0827
Annotation	Isoferulic acid 3-O-glucuronide
Peak:m/z	Relative Intensity
113.2561646	0.09
127.1803818	0.10
143.1229553	0.03
156.0317078	0.02
185.0905151	0.04
186.8838348	0.04
189.0639648	1.12
192.0479431	5.08
204.9615784	0.08
206.9720612	100.00
223.0594788	0.08
234.3893127	0.07
235.1888428	0.04
249.0224609	0.11
270.2721863	0.06
307.1539917	0.03
313.2838135	0.02
323.3110046	0.15
324.3673401	0.02
325.1706543	0.03
340.5032043	0.01
350.4310608	0.01
351.2890015	0.13
354.3854980	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	625.1404
Annotation	Myricetin 3-neohesperidoside
Peak:m/z	Relative Intensity
179.0479279	1.52
182.1019440	0.08
185.4878082	0.50
193.0371246	0.27
201.1779175	0.08
211.1239014	0.77
213.3941650	0.38
216.9600220	0.15
225.1249084	0.06
225.9524231	0.33
228.9739532	0.13
231.2092743	0.40
242.0995941	0.48
244.8421631	0.31
255.0298767	1.96
257.2691650	0.23
259.0658569	0.11
269.2268677	0.28
271.1627808	2.61
272.6798706	0.76
273.3074951	0.57
295.2104492	0.11
296.1384888	0.18
297.1373291	0.14
298.0220947	0.40
300.0419922	15.11
301.0922241	100.00
302.0960693	0.56
313.0782471	0.35
315.1152954	0.19
325.2728882	0.07
343.1671753	5.34
344.1435547	0.05
354.8929443	0.23
373.4412231	0.07
381.3047485	0.25
385.0194702	0.11
443.2356567	0.57
463.1601562	0.90
473.3332520	0.26
477.4876099	0.07
479.2993164	0.19
481.5040894	0.26
489.4177246	0.10
497.0454102	0.04
499.0842896	0.29
516.3704224	0.06
563.2322998	0.04
581.4331665	0.34
607.2764282	1.12
608.2989502	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	980.5895
Annotation	Apramide B
Peak:m/z	Relative Intensity
275.3777466	0.02
278.9846802	0.22
293.4348755	0.17
295.0692749	1.41
297.2418213	0.27
298.1790161	0.10
299.3035889	0.12
304.9345398	0.16
307.1786499	0.12
309.1008301	1.60
311.0279236	1.24
311.9191895	0.08
313.1855774	1.16
314.4058228	0.09
315.1233521	0.15
325.4145508	0.07
327.2257996	0.37
328.2293701	0.18
329.2920532	0.86
335.0184631	0.07
337.2189331	0.05
339.1752930	0.90
340.2215271	0.05
341.3437500	0.15
343.4115601	0.09
350.8776855	0.02
353.1090088	2.16
355.2606812	1.04
357.0930786	1.46
358.9158630	0.78
360.1135864	0.16
366.1401978	0.06
367.5373535	0.04
371.1531372	0.39
373.2674561	7.41
374.2517700	1.03
375.1728516	0.60
376.2164307	0.36
381.4212646	0.08
383.2318726	0.65
396.2875366	0.30
397.2421265	1.55
398.1826172	0.18
399.1652527	1.05
400.8938599	0.82
401.5377808	0.27
403.3574524	0.51
411.0503235	0.04
415.1084595	0.66
415.9255371	0.16
417.0308838	2.85
418.0909424	0.59
419.2186890	0.83
420.3350220	0.10
427.2517700	0.05
439.3204956	0.11
441.0741577	1.77
443.3467407	0.24
445.2092896	0.83
446.1575623	0.38
447.2291260	0.50
459.3911743	0.16
460.8965759	0.49
462.1398926	0.02
463.2939453	1.26
464.5967712	0.04
471.5213013	0.05
472.4516602	0.13
474.2316895	0.07
476.3521423	0.11
485.2633972	1.78
486.3145752	0.29
487.3762817	0.20
489.2922363	0.48
490.4183350	0.07
492.4479065	0.35
503.4460754	0.09
505.0083618	2.42
506.1835022	0.03
507.1568604	0.99
508.2791748	0.31
516.1512451	0.08
517.6009521	0.04
523.3819580	0.29
527.9030762	0.18
529.2346191	1.71
530.4919434	0.20
531.3725586	0.22
533.2894287	0.71
535.0205078	0.27
536.1600342	0.06
549.1875610	1.68
550.0950928	0.12
551.2990723	0.54
552.1759033	0.22
555.4191284	0.06
567.2947998	0.58
571.5815430	0.05
573.1188965	1.06
573.7633057	0.04
575.3031006	0.29
577.3073730	0.34
578.0679932	0.03
583.2729492	0.06
591.1878052	0.10
593.2143555	2.26
594.3092041	0.20
595.4631348	0.86
596.3983154	0.13
603.1752930	0.10
611.3832397	0.24
617.2780762	0.79
621.2586670	0.11
622.4372559	0.21
637.2127686	2.74
639.1208496	0.39
640.6333008	0.07
655.2952271	0.94
661.2675171	0.06
665.1688232	0.08
665.8187256	0.14
666.7103882	0.16
678.7622681	0.15
681.2685547	1.58
682.0749512	0.28
699.1722412	1.18
700.4760132	0.08
707.0242310	0.15
709.0690918	0.11
710.3659668	0.03
723.3297729	0.20
725.1957397	1.33
726.2725830	0.02
727.2878418	0.63
741.1997681	0.07
743.2916870	2.11
753.2106323	0.14
755.4005127	0.66
767.2697144	0.07
769.2359009	1.19
771.6187744	0.48
787.2783203	0.92
788.0980225	0.09
797.6748047	0.22
813.1405029	0.33
814.1596680	0.17
815.1622314	0.14
816.4125977	0.05
831.4263916	1.04
832.4631348	0.17
841.7135010	0.14
842.4548340	0.05
857.1485596	0.88
858.5144043	0.67
859.2570801	9.85
860.3621826	3.36
875.4125977	1.75
876.4720459	0.34
901.3558350	0.13
918.8250732	0.40
919.5261230	3.60
920.4636230	0.63
945.2054443	0.92
946.0187988	0.09
946.6837158	0.52
963.3403320	100.00
964.3518066	27.71
965.1773682	0.04
982.9705811	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	412.2319
Annotation	Isariotin A
Peak:m/z	Relative Intensity
140.0018921	0.03
164.1749725	0.03
182.7349091	0.01
190.8380127	0.06
199.3569946	0.04
204.1497650	0.03
206.3201752	0.04
215.2087555	0.12
220.0034485	0.03
231.0135803	0.03
237.3389282	0.01
240.2772522	0.02
243.2417908	0.03
249.9128113	0.03
251.0826111	0.06
253.2535095	0.02
262.1100769	0.05
265.0637817	0.02
296.3303223	0.10
302.3392639	0.07
305.2550964	0.02
311.2467957	0.05
315.7602539	0.04
319.9690552	0.02
331.0844421	0.59
331.8560791	0.03
337.7397461	0.03
339.3941956	0.03
340.2529297	0.10
341.6174622	0.02
348.3436584	0.01
358.4089966	0.32
364.4006042	0.05
366.0079651	0.26
366.8829041	0.20
376.3412781	0.96
380.9324951	0.04
388.8904419	0.10
394.2947083	100.00
395.3514709	0.12
411.0740356	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	700.4244
Annotation	Combreglucoside
Peak:m/z	Relative Intensity
206.7429199	0.05
211.0854492	0.02
212.1275330	0.02
217.0560150	0.28
218.4815369	0.05
219.1012573	0.37
220.4150696	0.23
221.1032562	0.95
223.1795044	0.07
224.3084106	0.03
225.2252655	0.43
227.2158356	0.04
235.1112366	0.74
236.1314697	0.11
236.9563751	0.10
239.0625763	0.04
251.2122345	0.43
251.9839020	0.06
253.0555267	0.05
255.1462097	0.54
256.3025513	0.18
261.3292847	0.17
262.7988586	0.18
265.0414124	1.64
266.1284180	0.33
267.1965942	0.21
269.1276855	4.58
270.1623230	0.55
275.2326660	0.02
277.4136353	0.07
278.2415466	0.01
279.0971069	0.29
279.9324951	0.14
283.1378174	0.03
285.2153931	0.07
291.5334167	0.04
295.1103516	1.21
295.9804993	0.06
297.1869812	0.33
298.2603149	0.07
299.2540588	0.46
300.2638245	0.05
302.8796387	0.04
305.2297974	0.10
306.3979492	0.16
307.2708435	0.03
309.0516357	2.41
310.1735535	0.06
311.2294312	0.14
312.9758606	4.02
314.0575562	0.69
315.5324097	0.05
316.1536255	0.03
319.3635864	0.04
321.0792847	0.10
323.0338745	0.54
324.1660156	0.10
325.4789429	0.06
327.1312256	0.22
339.2437744	0.53
340.8744507	0.14
343.1723022	0.09
344.4009399	0.05
351.4841919	0.03
352.4581299	0.08
353.1496582	2.29
354.2690430	0.25
356.9520874	1.85
358.1363525	0.14
358.9759521	0.28
360.1754150	0.16
365.3873291	0.24
367.1825562	0.21
368.2828979	0.09
371.4876099	0.11
373.2618408	0.02
375.4306030	0.08
382.8538818	0.22
383.5169678	0.15
384.2003174	0.05
385.2522583	0.03
386.9129028	0.10
388.5504761	0.10
396.4125977	0.10
397.0985718	0.82
397.9552612	0.09
398.5698242	0.08
399.2099609	0.07
401.0028687	1.44
401.8096924	0.55
402.4820557	0.13
403.1315918	1.15
403.9491577	0.09
411.1879272	0.14
417.2331543	0.03
419.1987305	0.54
420.2635498	0.03
426.9262085	0.06
428.8582764	0.08
434.2276001	0.10
441.2315063	0.53
442.3363037	0.09
444.4123535	0.20
445.1373291	0.65
445.8997803	0.05
447.1801758	0.71
448.2674561	0.16
455.2862549	0.09
463.1865845	0.90
464.0304565	0.13
470.8242798	0.04
472.0577393	0.10
473.2747803	0.05
475.2880859	0.08
485.4887085	0.13
486.5808716	0.03
488.2609863	0.06
489.1138916	0.66
489.9097900	0.42
491.2643433	0.89
492.2451782	0.08
500.0230103	0.01
507.2217407	0.67
508.2899170	0.16
509.3637085	0.06
515.0589600	0.15
520.6948242	0.19
533.1292114	0.75
533.9298706	0.05
535.0405884	0.13
536.3787842	0.05
541.4700317	0.10
551.2697754	0.88
552.3029175	0.36
555.5390015	0.08
559.4381714	0.12
577.1724243	1.45
578.2063599	0.32
579.1895142	1.46
580.4036255	0.36
595.2695923	2.51
596.4596558	0.76
599.6781616	0.06
603.3686523	0.03
615.8753052	0.13
624.2202148	0.07
637.3862915	0.11
639.2911377	3.21
640.4052124	1.42
664.3367310	0.12
665.1046753	0.91
666.2943115	0.22
673.4963379	0.12
683.2484741	100.00
684.2883911	29.55
684.9224243	0.05
701.5054321	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	514.133
Annotation	Unknow
Peak:m/z	Relative Intensity
165.1211700	0.09
170.9602509	0.23
172.0751648	0.18
207.1556091	0.04
215.0687866	0.38
329.2892456	0.13
334.2581787	0.14
341.2175293	0.59
377.1484375	100.00
377.7539062	0.09
430.0701294	0.33
451.6247559	0.17
464.3403320	0.07
469.8083496	0.05
478.1942139	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1687
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
92.97392273	0.04
96.92633057	0.13
118.9825439	0.23
143.29422	0.03
149.8817749	0.05
155.8284912	0.33
167.2123566	0.27
170.0723114	4.23
171.1265717	0.21
177.3794861	0.08
183.0046082	100.00
183.9841614	10.57
195.2341461	0.05
197.0236816	92.48
198.027359	15.60
199.1134949	1.00
200.1566467	0.21
209.066803	0.12
211.0623779	3.09
212.0632935	2.34
212.9709473	0.12
215.2087097	0.05
225.0910645	2.55
226.0491638	3.49
227.1813049	0.25
239.0609436	4.12
240.0092773	4.65
241.1549683	0.80
247.2642822	9.89
248.4151611	1.27
249.3468323	1.44
253.2969055	3.65
254.2044373	1.87
255.2006531	0.32
265.2460632	0.26
266.1515808	0.14
267.224823	1.96
268.1239624	0.65
269.1135864	0.07
275.1972656	0.24
279.1122437	0.08
281.0270386	0.26
282.1011658	0.32
283.2101135	0.24
293.253418	3.13
294.2904968	0.09
295.3462524	0.17
296.0512085	0.31
311.2139893	18.68
312.2410278	4.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
159.016922	1.87
168.9455566	14.69
170.8959351	6.21
172.6542969	2.76
174.29953	12.03
184.2598877	6.92
190.3575134	21.31
191.0776215	4.79
197.3790588	4.68
226.3053284	10.92
245.3635254	3.02
252.4946289	3.86
263.0996704	2.79
265.9845886	1.63
282.4750977	4.17
287.4390259	12.85
294.1317749	0.97
311.0421143	6.83
311.740509	2.79
314.3530884	1.26
320.0610657	3.41
322.2375488	3.66
334.5186768	3.56
336.4974365	5.12
351.4267883	7.15
355.193634	3.01
366.1747742	11.02
368.5360718	4.70
372.0463867	3.54
373.1094055	3.77
379.078949	3.70
380.1339417	1.71
385.2832947	3.01
390.6975098	5.33
395.309021	5.36
401.2597656	4.01
404.0950623	2.18
407.6700134	44.26
408.2788696	100.00
409.3626404	17.21
419.5959778	11.88
425.2732849	10.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	952.5754
Annotation	Unknow
Peak:m/z	Relative Intensity
267.5050964	0.08
269.3363037	0.22
270.9880371	0.12
279.0964966	0.05
295.2041016	0.37
297.3818054	0.18
301.2015076	0.12
306.5248108	0.15
309.1501160	1.63
311.1783447	1.19
313.0584717	1.68
315.0872192	0.07
325.2200317	0.23
327.2447510	1.20
329.2330322	9.60
333.1148682	0.09
336.9448242	0.12
339.3282776	0.07
341.4226379	0.19
343.0526123	0.08
350.9841003	0.20
353.1123657	1.88
355.1045532	0.61
357.1272278	0.77
361.3065491	0.12
367.2001343	0.15
369.3348999	0.05
371.3983154	0.32
373.1939087	2.95
375.2536011	1.12
383.0548401	0.19
397.1165771	2.02
399.3366699	0.25
400.9372559	0.67
409.4034119	0.07
411.3997803	0.44
412.4457397	0.13
413.4780273	0.24
415.2648926	0.99
417.0484009	1.40
419.1539307	1.42
431.2343750	0.06
431.8594971	0.21
432.6490479	0.22
433.4593506	0.20
435.2651978	0.27
439.2314453	0.11
441.2568970	1.14
443.3062744	0.22
444.8752441	0.45
445.5586548	0.11
459.2183228	0.28
460.2949219	0.30
461.0547485	1.42
461.9443970	0.05
463.2971802	1.84
477.2682495	8.42
479.1286011	0.10
485.5350342	0.34
487.0357666	0.34
489.1907349	0.42
503.1997681	0.83
505.3249512	0.55
507.3472290	0.90
519.2955322	0.17
520.2089233	0.47
520.9859009	4.86
523.1701660	1.43
528.8118896	0.21
529.4675903	0.66
533.4425659	0.24
548.4881592	0.03
549.3081055	0.87
551.2675171	0.42
563.1065063	0.22
565.1776123	0.33
567.2650146	2.40
577.6799316	0.21
583.1638184	0.75
586.1339722	0.16
593.1921997	0.91
595.3323364	0.50
608.8449097	0.33
609.4972534	0.67
611.2412720	1.80
614.3804932	0.26
637.2471924	0.50
639.5198975	1.18
651.1249390	0.08
653.1434937	3.57
655.2965698	1.28
670.6909790	0.13
671.4846802	0.78
675.8757935	0.04
681.3738403	0.56
683.3303833	0.59
695.3395996	0.16
697.2214966	1.43
699.2608643	0.81
702.5953979	0.14
714.9691772	0.93
715.5921021	1.33
725.3577881	0.22
727.2669067	3.09
730.4750366	0.19
741.1224976	1.08
741.7693481	0.07
743.2078857	3.65
759.4453735	0.49
767.4841919	0.15
769.1661987	0.52
785.1871948	0.95
786.7678833	0.18
787.3692627	1.76
803.2444458	1.10
813.1748657	0.35
813.7786865	0.09
821.0484009	0.05
829.2061768	2.09
831.3287964	44.68
832.0013428	0.09
847.3449707	2.70
872.3994751	0.06
891.2955322	3.87
904.0094604	0.09
906.8220825	0.10
917.3558350	0.76
935.3193359	100.00
936.0994263	0.23
936.7714233	0.31
951.8359375	0.51
953.9019165	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	787.1928
Annotation	Myricetin 3-rutinoside-7-glucoside
Peak:m/z	Relative Intensity
223.8980713	0.14
227.4552917	0.06
229.0869446	0.33
243.0711212	0.25
245.0413818	0.19
255.1251526	1.05
257.2123413	0.64
271.1087646	1.19
272.1300049	0.40
273.0170593	0.91
273.9161072	0.14
281.2938232	0.08
282.1022339	0.12
283.0369873	0.16
285.1451721	0.07
297.0624695	1.03
300.2049561	9.40
301.0499268	100.00
302.0299683	0.17
315.2666321	0.61
325.1055908	0.86
330.1543274	0.21
331.3243408	0.07
333.2918701	0.11
337.2971191	0.33
340.8786011	0.13
343.0967407	6.78
343.9674072	0.13
353.4138184	0.09
355.2982788	0.06
357.2398682	0.54
373.2112122	0.32
381.3691406	0.09
403.2319946	0.13
417.4111938	0.17
442.4049072	0.18
463.1586914	2.56
477.8910522	0.13
484.1901855	0.66
485.1545410	0.10
503.3002319	0.24
544.1129761	0.23
589.2338257	0.09
595.2617798	0.10
607.3135986	0.55
623.6431274	0.32
625.2495728	5.73
626.3942261	0.14
635.5064087	0.87
640.2922974	0.22
656.1794434	0.16
661.2528687	0.17
667.4030151	0.17
704.3930664	0.26
720.3583984	0.04
723.2981567	0.22
742.2921753	0.10
743.3941650	1.95
745.1958618	0.16
750.5970459	0.12
753.9628296	0.18
756.5617065	0.13
768.1341553	0.25
769.5228882	1.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.1377
Annotation	Cyanidin 3-(6''-caffeylglucoside)
Peak:m/z	Relative Intensity
171.1707153	0.22
178.9985657	0.15
181.1853333	0.04
190.9290466	0.05
199.0558472	0.24
200.8824768	0.26
205.1893005	0.13
213.2001953	0.18
216.9960022	0.21
231.2335052	0.13
241.2810364	0.50
245.0358429	0.75
257.1134644	0.43
259.3116150	0.11
261.4165344	0.12
263.1713867	6.47
269.2056580	0.19
271.2569275	0.22
275.1040649	4.34
276.6004944	0.30
277.2008057	0.67
283.0250854	0.03
287.0814819	14.16
289.0640259	6.00
299.2058105	5.27
301.1828003	1.24
303.2831116	0.23
305.0328369	11.29
307.0872803	13.38
308.1453247	0.13
311.1654053	0.88
317.0771790	27.23
317.7910767	0.32
319.0350342	0.33
325.4185791	0.13
329.1598511	4.37
331.1223755	0.30
335.2771606	0.15
341.0102539	0.33
349.1406250	2.43
353.0995483	0.06
355.4832153	0.05
356.2089233	0.04
359.0826416	0.56
370.9714966	0.11
389.5191040	0.27
393.9335938	0.04
397.1535034	0.05
407.1536255	0.11
409.0103760	0.10
410.1283569	0.11
413.2612305	0.25
415.3164062	0.04
420.9381714	0.09
425.1195679	75.50
425.7763062	0.38
429.1306152	0.06
430.9235840	0.34
431.5241089	0.13
435.0673828	0.07
437.1492310	5.32
439.3802490	0.18
441.2557983	0.14
443.0376587	100.00
443.7248535	0.85
448.2756348	0.52
449.2572632	6.59
455.0903931	7.97
457.2796631	0.05
458.9849243	0.07
464.0960083	0.11
467.2493286	27.75
471.0155029	0.08
473.1476440	5.36
485.0903320	42.23
485.8103638	0.40
507.3223267	0.19
522.2720337	0.11
525.3145142	0.16
536.2778931	0.14
540.4172974	0.15
545.4871216	0.16
557.3104858	0.51
560.0516968	0.57
564.4602661	0.12
575.2305298	9.92
593.1536865	33.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
133.0859833	0.12
145.2340698	0.14
155.0812988	3.04
157.1645813	0.39
165.1047363	0.19
170.9846039	2.28
177.0565643	0.95
183.0979004	1.33
185.0988159	0.67
187.0272217	3.03
197.3631134	0.85
199.0631561	2.01
201.2598877	3.79
215.0034485	0.21
221.3355713	0.19
227.0371704	0.30
229.2532043	0.55
231.0354309	0.36
231.9152832	0.51
241.1132202	2.24
243.1138306	1.69
245.3715515	1.07
251.2615051	0.17
253.3470764	0.18
255.1319885	0.24
257.3828125	1.27
259.2158813	0.65
265.0919495	0.55
269.2718811	0.61
271.1271057	0.74
273.3225098	1.00
277.298645	0.45
283.2250061	0.36
295.3237305	1.40
297.1953125	2.53
298.1008301	0.43
299.3932495	1.74
301.4552612	0.72
311.0697021	5.23
313.332489	2.40
315.2924194	1.18
319.0161438	0.31
321.0662231	3.24
322.0423279	0.80
323.3242798	10.14
325.1690674	0.57
327.3491821	0.15
329.361145	0.57
330.1158142	0.37
339.2501831	100.00
340.0231018	1.53
341.2147827	15.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	380.2424
Annotation	Ro 09-1543
Peak:m/z	Relative Intensity
116.0399475	0.87
131.0644684	0.06
160.2281189	0.11
168.9709778	0.26
180.3038177	0.11
181.3834076	0.06
190.2337494	0.04
192.3370056	0.12
200.0560760	0.11
201.3184052	0.04
204.1165771	0.04
211.4734192	0.02
222.2302246	0.53
226.4417114	0.05
227.0794067	0.05
234.9965820	0.05
240.3954773	0.08
241.2425232	0.06
244.3154602	0.36
246.2226868	2.22
260.0996094	0.09
262.2552490	0.05
271.1110229	0.23
282.5910950	0.15
284.2954407	0.36
289.1364136	0.12
290.1704102	0.02
298.2603455	0.31
300.2675171	0.40
302.3737793	5.07
306.3338318	0.06
308.2527161	1.50
314.3528442	0.03
316.3993225	0.17
318.2854004	0.20
326.2683105	13.80
334.4036560	0.07
339.2828979	0.08
344.3404846	29.06
349.0615845	0.09
353.4858704	0.14
362.3057861	100.00
363.0592957	0.38
379.1144714	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	728.8801
Annotation	Unknow
Peak:m/z	Relative Intensity
228.9548645	0.11
254.9254150	0.03
273.0116577	6.72
288.5854797	0.05
300.6349792	0.17
345.0829468	0.09
386.9144287	10.64
485.0043945	0.17
496.6990356	0.05
497.7296143	0.04
498.9600220	0.11
500.9093628	58.34
501.5893555	0.13
574.1284790	0.02
579.5325928	0.15
581.1137085	0.04
583.4423218	0.17
606.8163452	0.19
608.1342163	0.13
609.3852539	0.43
610.2932739	0.08
610.9121094	0.04
612.8077393	0.95
614.8497925	100.00
615.9202271	0.16
625.8393555	0.45
626.6760864	0.57
627.8533936	0.14
641.9863892	0.10
645.4431152	0.05
653.9652710	2.17
654.9419556	3.52
655.9325562	1.53
662.0443726	0.05
671.7500000	0.32
672.8737183	1.88
673.7462769	0.41
681.3499146	0.16
682.0200806	0.89
683.0037231	1.99
683.9138794	0.51
686.2852173	0.04
695.7976074	0.10
699.9902344	0.11
700.7188721	0.41
705.6572266	0.04
710.2997437	0.11
711.1158447	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	779.1263
Annotation	Unknow
Peak:m/z	Relative Intensity
231.8521576	0.23
293.0220337	0.67
319.0361328	0.19
337.2748718	0.30
349.2928467	0.14
400.9980469	0.53
442.9123535	0.89
444.9440308	0.52
455.0432739	1.94
456.2971802	0.06
468.8651123	0.38
481.1703491	0.76
484.1427002	0.25
506.9651489	3.28
518.9944458	1.53
525.3339233	0.39
526.3732300	0.07
533.7471924	0.19
535.1192017	0.13
537.0028687	11.71
542.5936890	0.24
548.7846069	0.30
563.6484985	0.22
567.1874390	0.16
578.4345703	0.12
582.0928345	0.29
583.1661987	0.39
584.0558472	0.07
585.5302124	0.25
594.0960083	0.09
602.1144409	0.13
603.3026123	0.03
604.7617798	19.37
605.4404297	0.44
610.5590210	0.12
614.2078247	0.11
615.0593262	0.25
616.8832397	48.18
617.5890503	0.12
623.3009644	0.94
624.2597046	0.37
642.9664917	13.18
646.2996826	0.14
646.9868774	0.15
650.9030151	0.14
664.5327759	0.31
678.0999756	0.27
681.0187378	100.00
681.7223511	0.69
682.7103271	0.28
690.6685791	0.90
691.3018188	0.08
694.7738037	1.29
698.9259644	0.44
701.2792358	1.81
705.9152222	0.18
709.6816406	0.47
722.9822388	0.31
732.6726685	0.61
734.8319092	0.23
736.2814331	0.10
756.1196899	0.06
759.1278687	0.26
760.8544922	0.85
762.3679199	0.06
779.2897339	0.56
780.4381714	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	469.2946
Annotation	Unknow
Peak:m/z	Relative Intensity
153.2823639	0.15
155.1770782	0.04
167.2659149	0.17
176.9444580	0.59
183.2063904	0.05
207.0713196	0.05
209.0769501	0.10
211.5292969	0.05
215.1331482	0.08
219.1835327	0.10
221.0698395	0.31
225.0432739	0.12
227.2180786	0.18
229.6859131	1.68
235.2626038	0.25
249.0333557	0.11
251.7483215	0.70
253.2165833	0.11
255.0750427	0.24
259.4060669	0.29
264.8157959	0.37
268.9778137	0.58
269.5834656	0.16
273.6145325	3.12
275.6581726	0.06
291.7069092	0.13
295.5432434	1.15
297.6164856	0.44
312.6448669	0.49
313.3041687	0.05
317.5747681	0.61
319.5839233	2.42
320.3415527	0.13
323.4716797	0.20
338.1883545	0.04
339.3773804	0.93
341.6822815	1.27
348.1325684	0.08
351.2276611	0.21
353.2988281	0.30
355.3610229	0.11
356.8822937	0.98
361.5077515	0.10
363.5454712	4.16
365.4143066	0.32
377.5903625	0.08
381.4577026	0.27
382.9083557	0.62
385.5659485	1.15
388.3763733	0.15
391.4660339	0.09
400.2933350	1.00
401.4713440	0.21
402.3472900	0.09
407.3778076	1.10
408.7548523	66.31
409.3964539	1.85
410.3829956	0.15
411.4499817	0.88
412.2672424	0.14
413.6785583	0.24
415.5393066	0.09
416.5969849	0.32
417.3540344	0.04
424.0576477	0.17
426.4247742	0.05
427.0334473	0.27
427.9460754	0.80
428.9482117	0.34
436.2687683	0.26
437.9123535	0.36
438.7662048	0.03
439.6443787	0.19
441.6439514	0.05
450.4679871	0.49
451.2447205	1.21
452.2529602	1.52
453.3078918	0.13
460.7411194	100.00
462.0093079	4.00
463.1969604	1.65
464.0354309	0.31
464.7412415	0.13
465.8560181	0.50
467.2613831	0.43
469.0358582	0.04
476.2569275	0.66
487.0749207	0.20
503.3601685	0.15
508.3068237	0.18
520.3673706	2.31
529.2437134	0.16
533.1793823	0.26
547.2729492	0.38
562.2051392	0.04
564.3014526	1.53
576.5446777	0.07
577.3545532	0.05
591.3432007	0.11
596.7201538	0.23
608.3577881	0.65
612.4883423	0.07
640.6691284	0.62
652.3533325	0.35
656.3706665	0.40
664.6381226	0.10
668.7639771	0.16
687.2507935	0.18
700.2575073	1.27
700.9439697	0.22
728.3937378	0.33
744.4654541	0.84
772.4943237	0.07
788.4536133	0.60
799.4094849	0.55
816.4208374	61.27
817.4301758	0.15
830.2221069	0.05
891.7045288	0.15
898.5565796	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	442.04
Annotation	(-)-Pyralomicin 1c
Peak:m/z	Relative Intensity
169.8266602	0.24
183.1665955	0.06
184.9597168	0.08
204.1222687	0.10
225.0931702	0.05
243.1411743	0.12
255.1961365	0.08
267.1009216	0.30
294.9848633	0.16
297.2518311	0.10
299.2135010	0.07
302.5726013	0.10
304.1066895	0.05
310.3619995	0.27
321.9431152	0.07
327.1912231	0.38
332.8541260	0.23
339.2277222	0.12
340.3660278	0.42
342.2532959	0.06
360.3531494	0.16
365.4465637	0.20
370.5878601	0.39
379.6840210	0.12
381.4452209	0.38
382.3031311	0.29
383.1557007	0.29
396.0750122	0.40
396.9816284	0.34
398.2273254	0.05
399.0319519	0.56
400.9952698	100.00
405.2919617	0.13
412.0267029	0.18
413.5437927	0.09
414.3490295	0.44
415.8050537	0.54
416.7368164	0.49
417.4622498	1.16
418.3636169	4.41
419.2570496	0.29
424.0570374	1.55
425.0480957	0.68
425.6656799	0.24
433.2318115	0.35
441.9277954	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	348.2737
Annotation	Broussonetine M
Peak:m/z	Relative Intensity
102.8644714	0.05
105.2106018	0.01
107.1287842	0.11
109.1105042	0.11
110.8436432	0.02
118.9552765	0.11
121.0102463	0.27
123.1074371	0.12
125.0546875	0.05
127.1800385	0.01
131.1052551	0.01
133.0091858	0.30
134.9649353	0.56
136.1082153	0.15
137.0539246	0.16
140.0854340	0.05
141.1083374	0.06
145.0802917	0.14
147.0205383	0.25
149.0971375	0.21
151.1138611	0.18
153.1216431	0.06
154.4525146	0.02
156.9447327	0.06
159.1416016	0.21
161.1349487	0.42
165.0885315	0.06
166.2723694	0.04
171.2093353	0.17
173.0906525	0.50
175.1651306	0.38
176.9852600	0.06
179.4880066	0.02
182.1273193	0.02
185.1199036	0.71
186.3703003	0.12
187.0884552	0.14
189.0924683	0.12
191.0314941	0.01
193.1531372	0.03
199.3144073	0.12
201.0777893	0.36
203.2915192	0.41
204.8163757	0.03
209.0283661	0.08
213.3813782	0.22
214.0779114	0.04
215.2541199	0.28
217.1203308	0.58
219.1420898	0.10
220.0263062	0.02
221.0807800	0.04
227.0582581	0.09
229.2883606	0.44
232.4741211	0.10
234.3786926	0.06
235.3015442	0.24
239.2068787	0.15
241.2066345	1.21
246.4032288	0.04
248.1766968	0.12
249.5229187	0.10
250.2297668	0.09
251.0646973	0.10
253.2628174	1.00
256.2779541	0.08
258.3553772	0.46
259.3148193	0.70
260.2434387	0.03
264.3904419	1.13
265.2601929	0.01
268.3166809	0.28
272.4273376	0.02
273.6105652	0.02
276.2774963	3.40
277.4005737	0.48
282.4195557	0.78
285.0371704	0.05
286.1914062	0.11
294.3754883	7.32
302.3163452	0.15
303.3829041	0.07
304.2879333	0.09
312.2607422	22.69
316.8947754	0.13
319.4523926	0.07
328.4949036	0.29
330.2861938	100.00
331.1755371	0.02
333.1316223	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	209.0667
Annotation	Sedoheptulose
Peak:m/z	Relative Intensity
67.1950760	0.06
68.9757843	0.18
71.0642395	0.51
72.9197464	0.10
82.9541016	0.64
84.9365540	10.50
86.9846191	12.58
88.9031067	1.51
97.0112305	2.94
98.9497223	5.56
101.0468292	0.53
110.9566498	14.47
112.9986115	0.14
114.8190765	5.54
117.0536652	0.04
129.0149536	100.00
131.1793060	0.18
132.7739410	0.05
134.9508209	0.22
141.0169830	7.95
143.0100403	0.07
144.8908386	0.11
147.0370789	0.11
158.9427643	49.20
162.8076019	0.76
164.9431763	0.49
166.0259857	0.04
176.9291229	0.83
190.9274139	3.14
208.6696014	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.31
Annotation	Dendronobiloside A
Peak:m/z	Relative Intensity
178.9956512	0.16
179.9972382	0.08
184.1940002	0.04
205.0843201	0.13
209.1291199	0.17
210.2156067	0.12
229.1007996	0.05
261.0010376	0.48
262.9756165	0.08
271.1807861	0.30
296.1167297	0.05
305.1332397	0.07
306.1721191	0.42
307.1033325	0.15
309.4070435	0.24
318.1452637	0.27
323.1510010	0.03
325.2504883	0.09
326.1675415	0.13
329.2860718	0.27
331.5374756	0.04
339.3262329	0.25
349.0625610	0.03
352.4589844	0.07
354.4863892	0.22
357.2170410	0.15
368.4239502	0.35
371.1928101	0.28
382.1454468	0.06
384.9565430	0.06
399.1644897	0.08
401.1017456	4.51
402.2260132	0.26
407.3670654	0.13
414.0068359	1.42
415.2022705	3.18
417.2041016	0.08
421.1889648	0.07
427.1473389	1.00
431.2655029	0.36
432.5433350	0.04
436.5931396	0.08
444.9105835	0.45
451.2011108	0.08
458.0999146	0.21
461.0421753	0.08
463.4295654	0.22
465.5584106	0.47
466.3760986	0.08
466.9893799	0.11
471.1859131	0.15
477.5312500	0.07
481.2092285	0.06
482.3278198	0.04
483.5330811	0.48
490.3594971	0.15
491.4706421	0.06
498.5177612	0.27
499.4836426	0.45
501.3229370	0.20
502.8124390	0.04
505.3945923	0.31
511.3936768	0.10
515.1352539	0.15
517.1859741	100.00
518.4053955	1.00
519.2966919	4.94
520.2434692	0.15
521.4035645	0.22
525.1906738	0.11
527.1994019	0.63
528.1380005	0.17
535.0650024	0.82
536.6676636	0.08
542.6564331	0.27
544.8982544	1.15
545.7660522	0.77
546.5871582	0.06
553.3688354	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.14
Annotation	Unknow
Peak:m/z	Relative Intensity
176.4984741	0.36
177.1706238	1.10
178.0468750	1.13
179.1025696	0.58
180.2198639	0.21
187.0278320	0.33
192.0870056	0.03
200.1635742	0.06
203.1119690	0.09
204.2738953	0.15
215.9239502	0.09
217.1294403	0.58
218.2664490	0.04
219.0737305	0.96
220.1882172	0.27
221.2261963	0.66
223.0046692	0.09
228.0509644	0.17
229.2465515	0.22
230.1907959	0.17
231.3056183	0.04
234.0933533	0.04
237.1146698	0.02
242.1699066	0.03
243.1362610	0.17
244.1231384	0.67
245.1726074	0.13
246.9893036	0.51
255.1858063	0.31
259.2208252	0.20
260.1432495	0.19
261.2981873	0.92
262.2005005	0.50
263.0442505	0.44
272.3253479	0.36
273.1902466	2.33
274.0564575	2.13
275.1779175	0.82
285.2335205	0.28
286.0913086	0.06
287.2628174	0.32
288.3204956	0.08
299.1177979	0.28
300.1265259	0.11
300.9893799	0.07
302.1544495	0.23
303.1676025	2.59
304.0874634	3.71
305.1484985	34.51
306.1174927	21.84
307.1632080	5.48
308.2064819	0.34
315.1148682	1.11
316.2180786	1.04
317.0408325	0.35
319.3222961	0.06
326.3904419	0.07
338.0654907	0.07
345.1523438	0.14
345.9591675	0.15
347.1666260	0.23
348.1494751	0.19
349.5264893	0.06
355.0502319	0.23
356.3364258	0.30
358.6856079	0.28
373.2620239	0.10
374.0560913	0.55
375.2213135	0.06
387.1846924	0.08
389.4015503	0.04
391.4262085	0.09
397.4168091	0.46
398.3304443	0.81
399.5588989	0.16
412.2249756	0.07
421.8927612	0.21
423.1747437	26.52
424.1986694	78.58
425.2291870	25.94
426.4705200	0.13
427.4822388	0.82
428.2395020	0.49
430.3233032	0.06
435.1256104	0.20
437.3876343	0.29
439.3209839	0.12
441.1616211	40.73
442.0935669	100.00
443.2130737	27.26
452.0545654	0.31
453.1344604	0.23
454.4464111	1.29
455.3840942	0.07
465.2027588	0.95
466.3663330	1.79
467.2300415	0.62
470.0317993	0.03
472.1513672	0.29
472.8847656	0.16
478.4412231	0.08
479.3710327	0.28
483.1851196	4.03
484.1329346	17.56
485.1948853	5.44
489.4109497	0.18
494.1192017	0.10
504.9299927	0.32
508.1104736	0.08
515.9803467	0.35
516.6609497	0.18
523.2081909	0.06
526.1063843	0.76
531.2146606	0.20
539.4172974	0.11
541.3588257	0.18
542.0578613	0.11
548.3350220	0.37
549.4665527	0.60
551.3765259	0.18
556.4797974	0.15
565.2813110	0.27
566.2603760	2.86
567.2506714	1.06
574.2503052	0.23
575.4060669	0.07
592.1919556	19.37
593.2861938	6.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	290.85
Annotation	gamma-Pentachlorocyclohexene
Peak:m/z	Relative Intensity
115.1031342	0.04
122.7645874	0.93
133.1172485	0.05
158.0933685	0.02
175.9854736	0.06
176.9838104	0.01
206.7984619	100.00
227.0358582	0.02
228.2734680	0.17
244.9423828	0.06
246.2809753	0.09
273.2068176	1.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	369.0826
Annotation	Isoferulic acid 3-O-glucuronide
Peak:m/z	Relative Intensity
110.9217224	0.37
126.9934845	0.03
129.0419159	1.02
161.1624756	0.06
163.0247040	0.05
186.8499146	0.09
189.0951843	0.45
190.2139893	0.02
192.0868530	13.51
201.3216553	0.01
205.0832825	4.45
207.0871277	100.00
218.8881226	0.02
220.4692688	0.09
223.1046448	13.11
235.2243347	0.17
249.2003479	0.06
323.2923889	0.26
324.0429382	0.03
348.0561829	0.02
350.9539490	0.35
354.2561340	1.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	785.3029
Annotation	Unknow
Peak:m/z	Relative Intensity
239.2229767	0.02
295.2932129	0.07
317.4030762	0.18
325.4170837	0.04
329.2020874	0.03
340.2165527	0.19
357.3879395	0.04
358.3970947	0.07
373.6995239	0.05
383.2625122	0.03
397.4408569	0.05
404.4751587	0.02
415.9160767	0.14
416.5286865	0.03
421.0154419	0.32
430.3843384	0.08
432.1154175	0.06
438.1817017	0.11
438.9413452	0.05
445.2644653	0.03
447.2334595	0.06
454.4688110	0.04
456.3226318	0.06
467.5733032	0.10
472.0451050	0.08
473.5034790	0.04
475.3084717	0.03
479.4616699	0.12
495.4692993	0.11
499.3769531	0.17
504.2246094	0.03
531.7005615	0.12
534.4096069	0.08
547.6087036	0.02
550.2884521	0.07
551.5947876	0.19
563.2125854	0.15
573.1560059	0.09
573.8433228	0.02
577.8489380	0.18
580.4082031	0.07
582.4450073	0.10
585.4848022	0.11
588.3295288	0.05
590.7443237	0.17
591.3722534	0.50
592.4428101	1.20
594.5000610	0.08
602.4062500	0.34
603.3080444	0.03
604.8225098	0.26
605.7984009	0.13
609.3922119	0.21
615.4411621	0.16
619.0267944	0.07
623.3662720	0.42
625.1434326	0.06
630.3540039	0.16
631.5169067	0.19
632.3734741	0.19
633.3309326	0.28
635.3978271	0.17
641.5342407	0.02
648.2352295	0.07
649.2705688	0.17
651.1119995	0.20
651.7542114	0.05
662.2881470	0.74
663.4367065	0.30
664.3671875	0.10
665.4511108	0.57
681.3385010	0.25
685.4635010	1.20
696.5479736	0.05
697.6151123	0.04
703.1493530	0.02
705.5460205	0.06
708.1910400	0.14
709.4206543	0.94
711.3452148	3.21
712.3751221	1.21
713.4450684	0.38
723.4343872	0.08
724.1524048	0.03
725.5222778	1.13
735.3709106	0.26
737.9053345	0.04
739.6130371	0.13
741.0823364	0.40
742.0060425	0.04
746.9195557	0.06
747.5516968	0.17
753.3081665	100.00
754.0481567	0.37
755.0180664	0.08
757.3865967	0.84
759.4268188	0.09
767.3335571	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.1331
Annotation	5'-O-beta-D-Glucosylpyridoxine
Peak:m/z	Relative Intensity
96.7444763	0.01
105.9433441	0.16
107.9948807	1.28
115.9889526	0.07
124.0593872	0.16
134.0208435	0.52
135.8789520	1.07
151.9761200	4.40
154.0153351	0.07
170.1036072	5.56
175.1455383	0.03
176.0570831	0.02
184.7943420	0.02
190.3798981	0.06
194.1269836	0.02
198.0219116	0.04
198.6900330	0.06
200.0951233	0.06
202.0359650	0.02
203.0099792	0.24
212.0247803	0.15
216.0140991	0.06
217.4002686	0.04
231.0489807	0.16
241.7223511	0.08
258.9993286	0.02
266.1885681	0.06
267.9930420	0.05
273.2720947	0.01
278.3850098	0.02
286.0581665	0.23
295.8851929	0.08
301.1134033	0.04
314.1882324	100.00
322.3866882	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.08
Annotation	6-Hydroxydelphinidin 3-(6-malonylglucoside)
Peak:m/z	Relative Intensity
210.1484680	0.03
222.2065125	0.04
244.4566650	0.03
299.0199585	0.04
323.2077637	0.21
343.2954102	0.02
359.1724854	0.20
365.5085449	0.02
367.0602417	0.12
370.4484253	0.05
371.3167725	0.02
373.1177368	0.03
385.0465698	0.05
386.2868042	0.03
389.6568604	0.01
402.2539673	0.03
403.1484375	0.23
423.2430420	0.04
433.3671265	0.11
445.3820801	0.04
446.3134155	0.08
459.2823486	0.04
462.2799683	0.09
468.1139526	0.02
469.3842773	0.04
475.3790283	0.07
476.4747314	0.08
479.2310791	0.27
502.3255615	0.02
503.1262817	0.02
505.3496704	0.09
517.3502197	0.05
518.2083740	0.09
519.0806274	0.18
521.1414185	100.00
521.7817993	0.23
522.7293701	0.05
523.3722534	0.06
527.1794434	0.01
527.8930664	0.06
529.4902954	0.04
534.5862427	0.02
546.3668823	0.11
547.3345337	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	479.0831
Annotation	6-Hydroxytricetin 5-glucoside
Peak:m/z	Relative Intensity
149.0706787	0.03
150.9757080	1.21
151.9376373	0.11
153.0242920	0.15
159.1244049	0.02
163.0402222	0.07
169.1012726	0.07
175.1600800	0.02
177.1708374	0.02
178.9052429	3.08
180.0761566	0.27
189.0440674	0.06
190.3325195	0.10
192.0757141	0.04
193.0543060	0.18
194.1431885	0.09
197.1040039	0.20
203.2949524	0.01
205.1369629	0.12
206.1062469	0.27
207.0669556	0.44
209.1493378	0.10
219.1619873	0.03
220.8632202	0.07
225.1323242	0.05
227.0455933	0.03
231.0208282	0.05
232.9825134	0.42
234.0469208	0.15
236.9283142	0.11
238.1067810	0.03
241.2382507	0.03
242.2210999	0.05
243.1362762	0.09
244.1741943	0.02
245.1454468	0.23
245.8713531	0.08
247.0444946	0.09
248.1882019	0.01
249.1992493	0.04
251.2243042	0.03
253.0562134	0.02
254.0666199	0.06
255.2341614	0.09
258.0849304	0.10
259.1000061	0.31
260.1793823	0.06
261.1394653	0.07
263.3825989	0.04
267.1740112	0.04
269.1597290	0.09
270.2247925	0.26
271.1493530	0.95
272.1200562	0.60
275.2655640	0.04
276.1206055	0.05
279.1211243	0.01
281.4185486	0.02
282.8663330	0.02
285.2383423	0.23
286.1902161	0.18
287.1755066	0.19
288.1779175	0.26
289.1852417	0.67
290.0359192	0.14
291.1675720	0.11
296.9907227	0.28
298.1321716	0.06
299.1900635	0.13
300.4935608	0.24
301.2288818	0.15
302.4452515	0.09
309.2905273	0.09
310.4200439	0.06
311.2721558	0.19
313.4973755	0.06
315.0151672	0.93
316.0932617	100.00
317.0898438	98.32
318.1610718	21.17
321.3856812	0.02
324.2838135	0.03
325.1833496	0.01
326.0214233	0.03
327.1553040	0.13
328.1757812	0.21
329.1092224	1.31
330.2113342	0.80
334.9506836	0.04
339.1963806	0.07
341.1979980	0.47
342.2018127	0.03
343.2796631	0.01
353.2579346	0.75
354.1437683	0.22
358.5360107	0.24
359.1734009	1.87
360.1095886	0.59
360.9679871	0.03
365.1225586	0.05
366.1569214	0.02
369.1657715	0.08
370.2825623	0.17
371.3999939	0.13
375.4016724	0.18
381.1995850	0.01
389.1697693	0.53
390.4016418	0.10
401.1246643	0.05
402.2289734	0.07
403.1830139	0.01
411.4114380	0.03
417.1709900	0.21
418.3432312	0.04
432.9728088	0.05
435.1679993	0.05
443.2750244	0.07
444.2139282	0.07
451.1784363	0.04
461.2295227	3.38
462.1546326	1.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	259.0786
Annotation	4'-Hydroxyflurbiprofen
Peak:m/z	Relative Intensity
113.2067871	0.01
131.2313995	0.02
140.0513000	1.69
145.1133728	1.89
157.8727112	0.06
167.0806427	0.06
184.4344177	0.02
185.3344116	0.01
187.0108795	0.01
191.1683807	0.03
196.0414581	5.49
208.6850128	0.02
211.0780029	0.11
213.0598145	100.00
214.0641022	1.00
214.9753876	0.35
215.8553772	0.02
224.1609955	0.07
231.0522003	18.97
232.1557770	0.03
233.0604095	0.05
241.0768890	0.40
249.1403961	0.01
259.1116028	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
77.79595947	0.14
93.02996063	0.71
95.94436646	0.21
107.1077576	0.21
109.0419312	0.09
120.1431122	0.05
124.0145111	0.34
128.0262299	0.11
129.1761169	0.71
129.9004517	0.42
136.0269775	0.23
140.0179443	0.07
141.7820129	0.82
145.960556	0.46
147.9636993	0.14
149.6352692	0.13
151.0326538	12.67
151.9927063	9.73
153.2575531	0.53
154.2408142	0.34
155.0637665	0.11
162.0484314	0.80
166.1268616	0.07
167.0884094	0.43
167.97612	0.17
171.3435516	0.11
176.922821	0.24
177.8882294	0.14
179.1578979	0.73
180.241806	0.59
182.3162384	0.98
183.0274506	0.51
184.2992096	0.12
185.0064545	0.05
186.0953369	0.27
187.0909424	0.25
188.2204437	0.11
195.1317596	0.31
197.0385284	0.64
198.1097717	0.59
199.3034515	0.07
206.0665131	7.03
207.2415924	0.43
208.2221222	1.07
210.9897919	0.26
212.1333771	0.13
212.9963531	0.66
218.1779327	2.91
218.8585052	0.79
225.1275482	0.89
225.9871979	1.33
236.045166	17.09
237.9611664	2.18
239.0601349	2.98
245.1937408	0.42
251.1899567	0.71
253.0951538	100.00
254.0911713	20.23
254.7581024	0.10
255.519104	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.0718
Annotation	Unknow
Peak:m/z	Relative Intensity
185.0605774	0.11
217.0500793	0.09
265.1449585	0.04
267.1962585	0.09
270.8650513	0.10
276.7801819	0.09
285.3779297	0.07
293.3439941	0.06
300.3359375	0.08
302.2251282	0.03
303.2733154	0.07
309.5175171	0.03
318.2709351	0.04
336.0366821	0.49
340.0253906	0.06
342.2049561	0.06
345.4841919	0.06
347.4237671	0.06
348.2979736	0.06
352.2199097	0.11
355.5850830	0.10
362.1533203	0.16
363.2981262	0.05
371.6217957	0.15
376.1932373	0.23
377.2070618	0.22
378.3298340	0.27
383.0473022	0.02
387.5867920	0.03
390.4072571	0.06
391.2693176	0.02
392.3151245	0.40
393.3703308	0.13
398.1366882	0.26
399.6753235	0.27
400.3015747	1.04
404.0750427	0.14
404.7736206	0.04
406.2427063	0.06
407.5942688	0.10
417.4457397	0.45
418.1220398	0.14
420.1308594	100.00
421.1378174	32.58
422.1564636	3.11
425.2811584	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	427.1818
Annotation	1,2,10-Trihydroxydihydro-trans-linalyl oxide 7-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
179.4056702	0.08
201.2230835	0.03
207.8837280	0.08
217.2744751	0.01
223.0546417	0.11
233.1226807	0.02
239.4664001	0.01
249.1725464	0.34
264.1258240	0.03
265.1656189	0.03
267.2839355	0.02
294.9598694	0.01
296.6531982	0.09
305.2577209	0.03
307.4737549	0.01
326.2937012	0.02
329.1171875	0.09
331.2326050	0.04
346.6250000	0.03
365.2985535	0.01
367.2554016	0.10
381.1959229	100.00
381.9417419	0.23
382.5940247	0.01
383.4643250	0.01
385.1883240	0.01
389.4373474	0.02
390.5625305	0.05
391.2284546	0.13
397.6947327	0.02
407.2687378	0.04
408.2940979	0.03
409.0480042	0.04
412.0107422	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	537.9333
Annotation	Unknow
Peak:m/z	Relative Intensity
198.7730408	0.18
380.7509766	0.12
394.1673584	0.21
422.9340820	2.40
423.9625244	4.69
425.0281372	0.66
433.7856445	0.27
440.4728394	0.31
441.5310059	1.01
442.6009521	0.75
445.1872559	0.04
451.1349487	0.13
462.9888916	0.11
464.6239624	1.10
476.6906128	0.16
481.0137329	1.14
481.9546509	0.20
482.9323120	0.55
490.9912720	11.91
491.9839478	100.00
492.9927979	10.05
493.6027832	0.19
501.4624634	0.27
506.8527832	0.20
508.9936523	4.84
509.8937378	41.27
510.9209595	4.97
512.9962769	0.17
516.7084961	0.32
524.6663818	1.06
526.0827026	0.30
527.1974487	0.60
528.1771240	0.37
528.9984131	0.17
533.6328125	0.08
545.9666138	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	569.32
Annotation	Unknow
Peak:m/z	Relative Intensity
162.2630005	0.14
177.4048462	0.05
178.0109863	0.04
180.1000366	0.05
183.2287598	0.33
191.0043945	0.04
198.4338074	0.04
208.2335510	0.09
211.1167603	0.05
212.0988770	0.15
213.1542206	0.10
214.8506775	0.09
225.9668884	0.24
228.4180450	0.12
229.2507935	0.05
232.1949310	0.09
239.9776306	0.12
243.0951843	0.20
256.0954590	0.07
258.2171021	2.43
259.4420471	0.76
260.2301331	2.53
271.1616516	0.06
272.1831970	0.16
283.5326538	0.10
284.6122437	0.09
286.3159180	1.22
287.1000977	0.75
298.3627930	0.08
308.1884766	0.09
309.6246338	0.08
311.7523193	0.02
316.2620850	2.69
317.4864502	0.74
323.9225464	0.07
325.1995850	0.06
326.3085327	0.32
327.3593140	0.16
338.3921509	0.07
339.0654297	0.14
343.3833618	0.15
344.1871338	0.57
353.3651123	0.04
354.2545166	0.13
354.9652710	0.07
360.9446411	0.09
362.1673584	0.06
363.7094116	0.16
365.1841431	0.03
373.3076172	1.98
374.5613403	0.07
375.4873657	0.09
377.3397217	0.06
380.4605103	0.27
381.3612671	0.14
384.5037231	0.08
386.3107300	2.27
387.3267212	0.47
389.3273926	0.24
391.2608643	0.23
399.3153687	0.16
400.2271118	0.35
401.3878784	0.27
402.3741455	0.03
404.3255615	7.97
405.3806763	1.82
406.2196045	0.12
407.1174316	0.47
410.0282593	0.04
411.4041748	0.13
418.3769531	0.09
419.2625122	0.08
420.4617920	0.17
422.3119507	100.00
423.3916626	23.83
427.0720215	0.08
430.1225586	0.14
432.2797241	0.04
434.4730225	0.11
437.2652588	0.18
440.2010498	0.61
443.3769531	0.07
444.3881836	0.98
453.3429565	0.06
454.5476074	0.12
457.2125854	0.08
458.5115967	0.17
462.3297729	2.19
463.2897339	0.22
464.5393677	0.48
465.4006958	0.29
467.4318848	0.33
469.3623047	0.09
471.1541748	0.66
472.3208618	0.28
473.0391846	0.07
476.6044922	0.05
478.7310791	0.06
481.4371338	0.03
485.4454956	0.05
487.9937134	0.08
492.1003418	0.77
492.7199097	0.19
493.5618286	0.82
494.4414062	0.30
498.6591797	0.04
502.7239380	0.24
503.9880981	0.32
508.4451294	0.15
514.1737671	0.38
515.4062500	0.33
517.9531860	0.18
519.4299927	3.06
520.2597046	0.92
522.9201660	1.05
532.1861572	6.79
533.4284058	2.03
537.3432617	0.02
538.4257812	0.11
543.5285034	0.24
545.8152466	0.03
550.3311768	58.24
551.3540649	21.75
551.9868774	0.34
552.6619263	0.18
555.2261963	0.06
556.9213257	0.53
560.6926880	4.60
561.4102783	0.16
569.2919922	0.04
575.1157227	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	358.9944
Annotation	Unknow
Peak:m/z	Relative Intensity
144.9161377	0.03
146.3120422	0.05
153.8579559	0.08
156.2042847	0.12
161.2959900	0.04
171.2116394	0.03
189.0252991	0.37
191.0700684	0.18
195.9459839	0.17
200.0267639	0.53
212.9716034	0.18
215.0467834	0.03
222.8100281	0.09
223.4498901	0.10
227.0711975	6.85
229.1416321	0.05
231.0561829	0.13
241.0747681	0.11
242.1944885	0.05
244.1186829	0.20
253.1112366	1.05
254.9708252	0.06
257.2391968	0.16
260.9602051	0.27
268.9901123	0.07
271.0051270	100.00
278.0440979	0.10
285.0466614	0.21
286.7137756	0.07
287.3376465	0.02
296.3559570	0.07
298.8831787	0.04
313.1105957	0.35
314.4324036	0.64
315.1130981	4.88
316.0132446	0.30
321.2587280	0.44
322.6598816	0.07
331.0924683	0.15
340.3130798	0.27
340.9971924	0.06
342.4217224	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	587.91
Annotation	Unknow
Peak:m/z	Relative Intensity
273.1004944	1.15
273.9697266	0.14
359.1704102	0.38
387.9938965	0.05
427.1287842	1.94
428.0556641	3.15
428.9925537	0.07
443.0582886	0.43
445.1278687	0.07
455.0833740	0.19
458.1192627	0.12
470.9760742	0.05
471.8009033	0.34
472.9494019	2.53
474.0533447	2.70
485.1112671	0.30
487.3992310	0.21
502.0618286	0.21
504.1463013	0.36
511.7745361	0.14
519.9707031	0.08
526.3120728	0.08
527.1473999	0.12
528.0755615	0.07
528.9761963	0.14
531.2612305	0.16
540.8667603	100.00
541.8571167	70.37
542.7941284	0.97
543.8458252	0.59
547.6792603	0.15
558.3329468	0.60
560.0702515	0.05
560.8117676	0.09
568.7411499	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	244.2267
Annotation	Lauroyl-EA
Peak:m/z	Relative Intensity
80.9932404	0.01
95.1074371	0.20
97.0125122	0.08
98.9681244	0.64
109.0491943	0.18
111.1794434	0.13
112.9359894	0.54
120.2764282	0.06
121.1881256	0.12
123.2150726	0.06
125.0240173	0.06
134.9612122	0.23
137.1461487	0.03
139.0745392	0.09
141.0655670	0.05
149.2272491	0.17
162.8738556	0.07
164.8194275	0.05
183.1017761	0.14
186.3421783	0.10
191.2255707	4.68
197.9476929	0.10
202.0429535	0.03
203.2035828	0.01
209.1858521	1.60
212.9067841	0.06
214.1330109	0.07
215.0247955	0.01
221.1360779	0.01
226.1777496	100.00
227.2346802	1.42
235.1993408	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	221.05
Annotation	Fraxinol
Peak:m/z	Relative Intensity
117.2140503	0.16
120.9692535	0.03
123.4444580	0.08
124.0942688	0.39
125.0337067	0.14
128.9973145	0.03
130.8334808	0.02
133.0543823	0.04
137.1073456	0.02
145.0477142	0.04
146.2687988	0.01
147.1008453	0.03
149.0509338	0.02
151.0765228	0.30
153.1052094	0.06
159.1058502	0.05
162.1378784	0.90
163.0078583	0.10
165.1741943	0.03
165.9924469	0.09
166.9951782	0.17
177.0676575	0.37
179.1120148	0.10
185.2232513	0.12
193.1791229	0.15
203.0449677	0.62
204.0916901	0.03
206.0191193	100.00
206.7593536	0.01
221.0713959	0.05
222.0392914	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	805.3292
Annotation	Unknow
Peak:m/z	Relative Intensity
256.9620972	0.04
279.2394409	0.12
337.1209717	0.02
338.2779846	0.04
350.3931885	0.13
402.3008423	0.41
418.6814575	0.11
461.4639282	0.11
472.1629028	0.19
475.5995483	0.28
478.1983643	0.10
487.1510620	0.06
488.4641113	0.22
491.8576660	0.09
503.3043823	0.06
505.1290283	0.11
508.7852173	0.11
518.3858032	0.04
522.5504761	0.17
524.4087524	0.08
550.3978271	0.05
551.5327759	0.31
552.4682617	0.15
564.3218994	0.35
565.5346680	0.21
567.7341919	0.09
578.8327026	0.02
592.4812622	0.04
593.3406982	0.94
594.4655151	0.46
595.2282104	0.04
598.3233032	0.04
606.3859253	0.88
607.4739380	0.60
608.1050415	0.01
609.0695190	0.03
610.6390991	0.32
614.3783569	0.22
619.6769409	0.04
620.5369263	0.30
621.5947266	0.11
623.5068359	0.11
625.4432983	0.09
636.3886108	0.09
637.4070435	0.37
638.2688599	0.46
643.4898682	0.12
644.1115112	0.05
650.2645874	2.90
651.4115601	1.80
652.3942871	0.55
653.9982300	0.11
657.3367310	0.09
661.3924561	0.65
662.7072144	0.02
665.3204956	0.04
669.5305786	0.40
670.6246948	0.20
671.3497314	0.05
678.0603027	0.08
682.3201904	5.57
683.4031372	2.04
684.3876953	0.20
685.3353271	0.16
686.2215576	0.10
687.4724731	0.62
688.3462524	0.24
701.6028442	0.08
705.2028809	0.14
706.4877319	0.07
713.6862183	0.17
716.2667236	0.14
727.0957642	0.11
729.4053955	3.85
730.4676514	1.34
732.2656860	0.40
733.3764038	0.10
745.6026611	0.78
746.6713257	0.52
755.5518799	1.05
756.5667114	0.32
761.1669922	0.04
762.2451782	0.07
773.4447021	100.00
774.3952026	43.67
775.0134277	0.16
777.3764038	0.28
778.7767944	0.09
787.4889526	0.47
788.5300293	0.05
803.8623047	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	404.1537
Annotation	Perphenazine
Peak:m/z	Relative Intensity
144.7841797	0.05
153.2783203	0.03
163.0660400	0.06
240.8661194	0.04
242.1827087	0.04
253.0759583	0.04
254.5167847	0.07
272.1539307	100.00
274.2839966	0.11
275.3062134	0.07
313.3453979	0.01
314.2850952	0.11
342.8985291	0.02
344.2399902	0.03
368.4107056	0.01
385.4034729	0.03
386.1293030	0.16
387.1088562	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	760.1456
Annotation	Unknow
Peak:m/z	Relative Intensity
219.1963959	0.41
243.0747375	0.41
243.8104553	0.45
259.1964111	0.14
261.0219116	2.23
262.1246338	0.05
269.1594849	0.33
284.9523010	0.92
287.1195068	0.45
303.1743469	7.19
304.1766357	1.47
305.2413940	11.75
306.0743408	2.56
311.8445435	0.07
315.0170593	0.23
343.2561646	0.21
345.3109131	0.19
347.1908569	0.51
348.4147339	0.13
355.2853394	0.14
357.1662598	0.33
359.3954468	0.40
362.4060669	0.26
379.2816772	0.32
385.3772583	0.14
397.0002441	0.26
398.1212158	0.17
400.0177612	0.09
406.1519775	0.25
409.6725464	0.48
411.1491699	1.51
412.2173462	0.25
413.2855835	0.12
421.0381470	0.97
423.1939697	8.99
424.3248901	2.94
425.5454102	0.24
427.0177002	0.26
427.9503784	0.05
429.2064209	3.62
430.5771484	0.52
432.0252075	0.24
437.4662476	0.33
438.2348633	0.25
439.2327881	0.76
440.5000610	1.76
441.2421875	4.80
442.3745117	0.21
444.0343628	0.06
447.0686646	0.21
465.4052124	0.30
467.2777710	0.09
468.6575928	0.45
469.2893677	0.16
471.2634277	0.34
473.2825317	0.21
481.3223267	2.38
482.3635254	0.12
483.1936646	3.19
484.1271362	1.00
489.9661865	1.21
490.9165649	1.80
498.3910522	0.37
499.1340332	0.89
500.2457886	0.23
501.0831909	0.15
502.7186279	0.59
505.0469360	0.20
507.1813354	0.15
508.2544556	0.43
510.1000977	0.22
511.5015869	1.80
512.3561401	0.14
513.9808960	2.62
514.8956909	0.07
516.3566284	0.12
517.0904541	0.17
518.3989868	0.88
520.4398193	0.40
523.5324707	1.22
524.7885132	0.88
529.0023193	0.37
530.3739624	0.46
536.1895752	0.24
537.6543579	0.26
541.3253174	0.57
542.0328369	0.11
544.4896851	0.09
545.1715698	0.37
545.8312378	0.08
547.1672974	2.00
548.3355713	0.81
557.3665161	0.10
561.9085693	0.23
565.4379272	2.63
566.0953369	0.08
568.2331543	0.08
570.1942749	0.40
571.4029541	0.36
574.3833618	20.28
575.2783813	2.15
576.1920776	0.18
580.3750610	0.17
583.3672485	19.33
584.3276978	1.71
585.6920776	0.16
586.7891846	1.12
589.2842407	1.43
591.3146973	3.22
592.3658447	10.40
593.2576294	0.80
595.7721558	2.31
598.2847290	0.15
600.4041138	0.62
601.2739868	0.09
603.4248657	0.08
604.5447998	4.41
605.2639160	0.38
607.1799927	14.49
608.0777588	8.83
609.1684570	15.99
610.3055420	4.70
611.3833618	0.40
613.5273438	2.44
619.3480835	0.15
620.3505249	0.26
634.6312866	0.65
645.1843872	1.94
645.9484253	1.39
649.5057373	1.00
651.2810669	2.74
652.3837891	0.33
654.1683960	1.11
654.8413086	0.17
658.3734741	10.71
659.3342896	0.68
661.4449463	0.35
666.6647339	3.09
667.4667358	100.00
668.2540283	10.20
668.8605957	0.50
669.7659302	0.22
673.8460083	0.67
676.4098511	36.52
677.3388062	3.27
678.6766357	0.58
679.6085815	0.45
681.4328003	0.06
683.5825806	1.36
688.3886108	3.20
690.0679321	0.67
697.4736938	11.52
698.2519531	2.34
701.5831909	0.58
709.4082642	0.25
710.6494751	0.13
715.2567749	0.25
716.2355347	0.17
719.4587402	0.12
723.5505371	0.27
725.1674805	4.10
726.3593750	1.83
727.2781372	1.95
728.2464600	0.37
731.2433472	0.39
733.0917358	3.38
734.2551880	1.42
737.1893921	0.22
738.5480347	0.07
742.3405151	1.57
743.3097534	2.14
744.0884399	0.20
745.2313843	2.69
746.4245605	1.06
747.3504639	0.14
751.3110352	0.66
767.0225220	0.07
768.0391235	0.06
769.1821899	0.73
770.2662354	0.15
772.2224731	0.23
785.1203003	1.11
787.1929321	7.81
788.1732788	2.87
788.9786377	0.20
793.0972900	0.15
802.3300781	0.08
834.1461182	0.44
845.2208862	0.90
847.4069214	0.17
849.4239502	0.27
851.1782837	0.80
852.0896606	0.48
853.0917969	0.09
860.9952393	0.54
863.8895264	0.30
869.0087891	2.51
870.6848145	0.47
871.3307495	0.13
873.2098999	0.08
876.1572266	0.13
887.3539429	0.04
893.2837524	1.13
894.2162476	0.33
895.2642212	0.75
897.4157104	0.22
903.4202271	0.12
905.3529663	1.55
906.1701660	0.51
911.1786499	18.69
912.0913086	5.55
913.1651001	16.96
914.3357544	5.86
915.3818970	1.00
923.2980347	0.08
935.3922729	0.11
937.4230957	0.24
953.3528442	0.10
955.4735718	1.04
956.4035645	0.29
957.3627930	0.65
963.4114380	0.15
966.9333496	0.07
981.0838013	0.08
983.1572266	0.19
987.1877441	0.57
988.8688354	0.30
993.3557739	0.07
995.1365356	0.16
999.4821777	0.16
1000.1040040	0.10
1011.1643680	0.35
1013.2639770	0.54
1014.6403200	0.05
1019.8185420	0.63
1021.2539060	0.39
1023.2925420	0.18
1024.1788330	0.18
1029.1489260	1.97
1030.2270510	1.43
1031.2457280	0.80
1032.0568850	0.62
1037.2121580	4.84
1038.1859130	1.25
1039.2202150	0.44
1047.2575680	0.21
1048.0627440	0.29
1049.2958980	0.79
1050.1911620	0.54
1056.4982910	0.26
1074.2253420	2.10
1079.0791020	0.14
1089.0844730	0.44
1091.1575930	5.96
1092.2910160	3.42
1115.2744140	0.04
1131.3571780	0.30
1149.2862550	0.14
1167.2358400	0.46
1173.2143550	1.61
1174.3637700	0.34
1180.2568360	0.30
1197.1638180	1.73
1198.4108890	0.55
1199.2915040	0.80
1200.1995850	0.97
1201.1962890	0.13
1209.4848630	0.17
1210.3619380	1.22
1211.2419430	0.06
1213.7944340	0.11
1215.1286620	15.32
1216.1950680	10.64
1217.1649170	6.63
1218.2131350	5.61
1219.1248780	0.52
1227.6591800	0.23
1228.2740480	0.29
1259.2463380	1.74
1260.1733400	1.53
1261.2978520	0.34
1274.0896000	0.12
1318.0880130	0.17
1334.9198000	0.79
1336.3238530	0.39
1337.2030030	0.18
1352.7281490	0.65
1353.5086670	0.29
1377.1423340	0.15
1378.1165770	0.14
1394.9749760	2.74
1396.1793210	2.30
1397.1766360	1.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1247
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
161.0823517	0.12
166.8757935	0.11
172.8911133	1.10
174.1089172	0.31
179.0996552	0.47
187.0802612	1.98
191.0937347	3.93
193.0357666	0.92
201.0880127	0.09
202.0820007	0.06
203.1704712	0.04
205.0781860	4.05
206.2059631	0.09
207.1310272	0.10
209.0778809	0.03
217.4085388	0.09
223.1083832	3.81
229.1281433	0.09
233.0291290	0.18
243.1161194	0.23
247.0841522	0.38
248.4145508	0.09
249.0576477	0.20
261.2080688	0.39
267.1098633	0.07
272.0586853	0.06
273.2395935	0.35
279.6061707	0.12
285.2480469	0.05
287.1485596	0.13
291.1422729	0.58
300.2333374	0.07
305.0368652	0.42
306.3802490	0.06
307.5280762	0.07
309.2309570	0.74
310.9020996	0.04
319.4907837	0.06
321.3878174	0.43
323.0199585	0.80
335.1752319	1.64
337.1380615	0.86
343.4694214	0.11
349.0159302	0.23
351.5471191	0.36
352.2114868	1.91
353.1247559	3.51
353.7304077	0.06
355.3804932	0.63
363.2118530	0.05
367.2144775	4.38
369.2686768	0.02
375.3817749	0.21
377.1185303	0.08
380.4605713	0.40
381.0724487	10.75
385.0759888	7.79
386.3176880	0.05
393.4290771	0.04
396.3246460	0.05
397.4481812	0.17
399.1281738	100.00
403.4385986	0.13
409.7615967	0.27
412.5231934	0.13
413.4551392	0.28
416.4196167	0.06
417.4248047	0.36
422.0992432	0.05
422.9462891	0.13
431.5404053	0.13
432.5609741	0.04
439.2756958	0.19
441.4392090	0.05
450.4082031	0.18
462.8780518	0.16
464.4041138	0.10
465.1890869	0.14
470.5780640	0.06
472.1427612	0.06
474.3696289	0.05
475.4882812	0.12
479.8248291	0.44
487.2285767	0.07
499.3419800	0.43
500.2783203	2.28
502.1774902	0.12
505.4567871	0.07
511.0101929	0.20
513.7631836	0.77
515.1118774	0.93
516.2079468	0.62
517.1992188	0.06
519.4568481	0.05
523.5007324	0.30
524.2850952	0.11
525.3602905	1.75
527.1540527	0.04
529.4151611	0.17
542.0690308	0.76
543.0990601	3.75
543.9017334	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	218.1033
Annotation	Pantothenic acid
Peak:m/z	Relative Intensity
70.9267120	0.58
87.8913727	100.00
99.5953674	0.06
129.0236664	0.05
136.9462433	0.11
145.9936676	12.42
161.8135223	0.04
173.8698425	0.62
175.2034302	0.14
190.2826080	0.34
190.9833069	0.07
200.0912628	0.22
202.8205566	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.13
Annotation	Quercetin 3-lathyroside
Peak:m/z	Relative Intensity
177.1047974	0.12
179.0505066	2.79
181.1452026	0.06
189.0731049	0.04
192.0970764	0.16
192.8558502	0.16
198.8353577	0.14
199.4754944	0.15
200.7709808	0.18
203.1144409	0.19
205.1346130	0.12
206.9024658	0.09
209.1318359	0.18
211.2374573	0.21
211.9627075	0.04
213.0143738	0.18
215.0854492	0.07
217.0896301	0.25
218.9441376	0.08
221.0669708	0.32
225.9545593	0.38
226.9316559	0.37
227.8504181	0.02
229.1336823	1.35
231.2456512	0.09
239.1054382	0.19
241.1128540	0.41
243.1694946	0.23
243.9662781	0.04
245.0847626	0.21
246.1159973	0.05
247.0365906	0.34
251.2079926	0.07
253.5099030	0.28
254.1818848	0.64
255.1589508	7.29
257.2172241	0.73
259.0569458	0.25
265.1177063	0.23
269.0154419	0.03
271.1259766	13.47
272.1925049	0.16
273.1584473	1.87
275.0001831	0.13
281.1600342	0.60
283.1247559	0.20
293.2869263	0.19
295.0270996	0.05
297.1761475	0.49
299.2700806	5.07
300.0912476	100.00
301.0722961	34.57
302.2166748	0.31
306.9986572	0.23
309.4173279	0.04
310.3096924	0.16
311.1531982	0.45
312.2580566	0.12
313.2967834	0.50
314.0376892	0.09
315.1542358	0.18
319.1672363	1.48
323.4520874	0.10
324.2637329	0.21
325.0666504	2.50
327.0493164	1.19
329.1090698	0.37
335.1093750	0.07
337.1290283	0.62
339.4293213	0.06
341.1015625	1.29
342.5223389	1.50
343.2227783	4.32
347.2810669	0.08
348.8013306	0.11
351.2513428	0.08
353.2490845	0.41
355.1477051	2.44
356.9851074	0.18
361.1963501	0.11
365.0474243	0.09
367.2243042	2.20
368.1561279	0.08
369.3510132	0.50
373.2031250	1.25
381.1373291	0.34
383.2435913	0.15
384.2139282	0.27
385.3455811	0.55
387.3628540	0.53
397.2689209	0.67
399.3316040	0.25
401.1475220	1.10
403.1246338	0.17
409.2416992	1.26
427.2080688	4.25
429.4614868	0.06
431.1685791	0.18
443.2118530	0.03
445.1422729	28.48
446.1374512	0.22
447.1467285	0.08
451.0292358	0.05
459.3934937	0.15
463.2256470	16.89
464.2199707	0.09
465.1424561	0.05
469.2076416	0.11
475.2216797	11.76
485.1459961	0.40
486.2493286	0.20
499.2708740	0.06
505.4376831	0.25
509.0861206	0.34
551.3716431	0.17
567.5945435	0.12
577.2162476	2.23
608.5454712	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	222.04
Annotation	N-Malonylanthranilate
Peak:m/z	Relative Intensity
68.9876556	0.06
119.0022125	0.12
119.8720703	0.07
123.9328156	0.08
132.1867828	0.07
133.8470154	0.06
150.0061035	48.86
160.0204926	29.95
161.9586334	100.00
162.9858093	0.05
176.1271667	0.35
178.0014801	15.89
188.1315613	0.09
192.1889191	0.04
203.9942780	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.14
Annotation	Leucocyanidin
Peak:m/z	Relative Intensity
174.8465271	0.34
177.1228180	1.02
178.1960144	0.28
179.0546112	0.78
180.1871185	0.40
187.0234528	0.10
189.0778809	0.17
191.2800293	0.14
192.0924988	0.13
200.8080139	0.09
204.1392670	0.39
209.1891479	0.07
210.0900269	0.74
210.8871307	0.10
215.1841888	0.10
216.8383026	0.07
219.1460571	1.90
221.0501709	1.27
223.9789429	0.12
226.9928284	0.03
229.0432587	0.30
233.4322205	0.09
236.9906769	0.08
241.1506653	0.09
243.1713867	0.86
247.0737152	0.42
252.8634033	0.14
254.0410461	2.29
255.1250916	0.48
257.3231506	0.12
261.0150757	0.96
262.3888855	0.54
263.2121887	0.10
272.5084839	2.16
273.1488342	1.04
274.1225891	1.74
275.0722351	0.24
285.0163574	0.48
287.1976929	0.10
288.1529236	1.65
289.1865234	0.76
301.3659058	0.09
303.1042480	1.86
305.0918579	100.00
306.1817627	48.14
307.1191711	8.04
315.1296997	0.30
316.2675171	0.30
317.1856079	0.14
319.0744019	0.24
345.4396362	0.34
346.2923584	0.07
347.1731567	0.05
358.2239380	0.06
359.2109985	0.06
369.3613281	0.10
371.1872559	0.23
372.3152466	0.10
376.3386841	0.07
380.9101562	0.26
398.3109741	0.41
399.2555542	0.59
402.9645386	0.23
411.1818848	0.28
423.1920166	11.32
424.1622925	29.52
425.1749878	10.43
428.1351318	0.10
429.2304688	0.06
431.3433228	0.29
439.2704468	0.06
441.2223511	15.04
442.1199951	32.77
443.1416626	10.56
443.7637329	0.05
446.4644165	0.25
448.9965820	0.44
453.2241211	0.15
454.4048462	0.10
456.5264282	0.14
466.3855591	0.54
481.3515015	0.32
482.1991577	0.47
483.4400635	3.29
484.2929077	8.63
485.3661499	2.55
504.2348633	0.34
517.6401978	0.31
521.1137085	0.08
523.3803711	0.11
525.0334473	0.43
526.2799683	0.15
530.2603149	0.06
544.5087280	0.12
556.0207520	0.08
565.0639038	0.27
566.3195190	0.70
567.3023071	0.09
574.3643799	0.42
579.2603149	0.19
579.9734497	0.07
588.9297485	0.07
592.1570435	6.36
593.2014771	2.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.1309
Annotation	4-O-Methyl-a-D-glucosyl-(1->2)-b-D-xylosyl-(1->4)-D-xylose
Peak:m/z	Relative Intensity
182.3913574	0.15
200.9294891	0.22
218.9337158	0.22
245.3525085	0.17
290.2014771	0.06
291.1869202	0.28
298.5612183	0.18
363.0744019	18.13
363.7227173	0.63
369.9262085	0.06
371.1920776	0.19
372.2561646	0.23
381.1087646	100.00
382.2076416	0.48
405.4633179	0.11
453.2369385	0.37
483.3731689	0.81
519.1849976	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	562.3146
Annotation	Unknow
Peak:m/z	Relative Intensity
186.9517517	0.03
215.1230621	0.06
217.9082947	0.05
224.3280640	0.03
228.1398010	0.19
229.1184692	0.11
230.7167664	0.13
242.1330109	0.04
244.9599762	0.10
277.2261353	1.32
279.0927124	0.09
280.3924561	0.20
290.3501587	0.07
291.5859985	0.03
364.4295044	0.12
378.6807861	0.25
386.2297974	0.10
399.4388428	0.05
408.6498413	0.04
410.0687866	0.05
419.3703613	0.10
428.2907715	0.10
434.3076172	0.06
436.7119141	0.05
447.2493286	0.03
459.9683228	0.05
465.8488770	0.02
468.3076172	0.12
471.4842529	0.04
472.4658813	0.14
475.2900391	0.10
477.3482056	0.04
489.4889526	0.04
502.3262939	100.00
503.4357910	0.68
505.9541626	0.03
507.6107178	0.04
514.0427246	0.08
515.1382446	0.09
516.1434937	0.10
518.4664917	0.16
519.0670776	0.04
524.1017456	0.21
526.4692383	0.26
527.4154053	0.04
530.0512085	0.07
534.9012451	0.04
543.8196411	0.30
544.7581177	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	132.1
Annotation	3-Aminocaproic acid
Peak:m/z	Relative Intensity
69.0086823	0.02
85.9230347	100.00
101.9761963	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	132.1
Annotation	3-Aminocaproic acid
Peak:m/z	Relative Intensity
69.1031494	0.08
85.9286652	100.00
87.1653137	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	388.1595
Annotation	6-(2Methoxybenzylamino)purine-9-beta-D-ribofuranoside
Peak:m/z	Relative Intensity
108.8815613	0.07
118.9407425	0.06
126.9243469	5.82
131.1449585	0.06
133.1797180	0.06
142.8290253	0.58
144.2508392	0.08
145.0256348	0.87
148.1386414	0.03
153.0107117	0.23
158.8442841	0.28
161.1252441	0.24
162.1350708	0.04
166.9909058	0.04
168.0366821	0.09
171.1097870	0.22
173.0203552	0.08
177.1166992	0.05
179.0233765	0.03
183.0648804	0.14
185.1557922	0.08
188.9900513	5.03
189.5933838	0.11
191.0198517	0.05
197.1934967	0.03
201.0329742	1.39
204.8823547	0.29
206.5403595	0.07
209.1594391	0.19
213.1007080	15.55
215.0164490	0.05
219.1338501	0.11
223.9964600	0.12
225.9427490	0.06
230.8864441	48.69
231.5058594	0.20
241.1707764	0.03
248.2199097	7.87
248.9187927	20.84
254.5313416	0.10
256.3568726	0.04
263.6207886	0.27
265.9963379	4.98
267.0806274	0.06
273.0387878	0.10
275.1128540	0.97
280.6920166	0.34
284.7574463	0.22
291.2465210	1.71
297.2928467	0.04
298.1584778	0.04
299.2065430	0.05
301.9038086	0.04
302.9808350	0.14
306.9151306	0.29
308.8128052	0.16
315.6493835	0.11
317.1707153	8.44
320.1578064	0.07
321.2185974	0.19
324.0247498	0.06
325.2985229	0.45
335.0480957	100.00
337.2421265	0.10
338.0428162	0.05
338.9890747	0.06
343.0256348	0.57
344.6073914	0.08
346.0891724	0.08
347.1261597	0.71
350.3692017	0.49
351.4598694	1.27
352.8726501	23.44
353.5942688	0.09
356.7862854	0.14
357.4605713	0.03
358.1873474	0.12
364.9207764	0.08
366.3676758	0.15
369.2696838	1.23
370.3029480	0.64
371.2426147	1.87
386.9549866	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	412.1491
Annotation	Altanserin
Peak:m/z	Relative Intensity
118.9755630	0.22
120.0209579	0.25
136.1568909	0.50
162.0688934	0.43
173.0915070	0.18
187.1396942	0.11
188.0694885	0.39
189.0892639	0.30
194.5576477	0.23
205.0961609	3.00
206.0211182	2.69
215.2511902	0.11
250.0875549	0.11
251.0869141	0.23
252.2382507	0.03
255.8906250	0.04
263.3892212	0.06
268.1531677	2.54
275.2597046	0.14
281.1271362	100.00
293.0502625	0.08
294.2959595	0.25
301.1723938	0.13
305.0481262	0.06
311.3321228	0.12
313.1799927	0.09
323.2471619	0.12
325.8281860	0.16
339.0822144	0.12
342.2498779	0.08
352.8701172	0.06
353.4914246	0.13
360.1374817	0.22
363.3364563	0.13
366.7005920	0.38
367.3790588	0.41
376.9302673	0.38
384.1052246	0.07
385.8718262	0.14
387.5188293	0.15
394.5440369	1.11
395.4140930	0.34
398.1758728	0.09
399.1156921	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.2394
Annotation	Unknow
Peak:m/z	Relative Intensity
149.0050049	0.41
160.9712067	2.15
172.9974976	0.34
175.0983276	0.15
179.1538239	0.19
191.0485840	7.14
192.1152344	0.39
203.2050171	0.05
207.0318909	0.20
209.1291809	0.98
213.1608124	0.05
215.2465515	0.42
220.3898621	1.65
220.9979095	6.54
250.9800415	3.17
263.0064087	1.01
275.2163086	1.17
281.1096191	1.13
287.1549072	0.03
293.1248169	11.97
309.1770935	1.01
310.9991455	100.00
311.6602173	0.88
313.2214966	0.08
316.2115479	0.19
317.2457886	0.25
319.3297729	0.06
321.0826416	0.13
323.1351318	0.14
323.9324341	0.08
327.4105835	0.06
335.1325073	0.49
338.2034302	0.42
339.2691040	0.06
344.9791870	0.14
346.2003784	0.14
347.2647095	0.39
353.0717163	6.12
367.0747070	3.55
371.1936646	1.59
383.3895874	0.19
385.1036987	29.73
386.4812622	0.04
403.6354980	0.06
413.3544922	0.22
414.2479248	0.23
415.3441772	0.55
416.6494751	0.08
417.4338989	0.28
421.2930908	0.09
427.0260010	0.09
427.6945801	0.11
431.2862549	0.15
443.2818604	0.05
450.0354614	0.12
460.4067993	0.11
479.3619995	0.23
485.5236816	0.04
497.9539185	0.14
499.9379272	0.82
500.8736572	6.53
501.6470337	0.41
503.3375854	0.60
509.9434204	0.15
511.4971313	0.07
515.4774780	0.28
529.2332764	5.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	543.2806
Annotation	Pharboside C
Peak:m/z	Relative Intensity
160.9075928	0.01
178.8824921	0.11
179.9313507	0.01
191.1473389	0.04
203.8671417	0.01
207.0788574	0.84
255.0389404	0.03
272.4224854	0.02
291.0496216	0.02
315.3713989	0.04
335.3381958	100.00
336.2890015	16.85
337.3150024	0.10
345.1610718	0.04
377.3312378	0.20
378.4135742	0.07
381.2678833	0.21
381.9327393	0.10
402.4460449	0.01
407.4478149	0.02
409.3060303	0.02
419.5253906	0.08
420.4822998	0.01
423.3860474	0.04
426.2404785	0.02
428.4050293	0.01
435.3080444	0.04
436.8101807	0.04
440.2111206	0.02
447.9824219	0.01
453.4202881	0.16
455.4063721	0.01
464.2815552	0.14
467.2144165	0.10
470.2146606	0.01
471.8771362	0.01
475.1710815	0.02
481.6995239	0.02
482.8793335	0.09
484.4685669	0.05
497.1234741	41.06
498.2283325	7.40
499.2077026	0.04
500.2168579	0.12
501.4379272	0.01
502.2367554	0.03
505.3423462	0.01
506.4034424	0.09
507.4876709	0.07
508.1520386	0.11
510.8416138	0.07
516.4241333	0.01
523.2028198	0.03
524.3265381	0.02
525.2460938	0.08
526.2934570	0.19
527.1060791	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	396.2026
Annotation	Echimidine
Peak:m/z	Relative Intensity
130.0559540	0.05
133.0365295	0.05
158.6469727	0.04
161.2606506	0.07
162.3920898	0.01
189.0560150	0.02
206.2271271	0.02
220.4205322	0.02
237.0985107	0.06
244.1851501	0.04
244.8861084	0.02
246.2767029	0.12
249.0489807	0.03
260.2753601	0.11
261.2963867	0.84
262.2452393	1.18
263.2628784	1.47
264.3639526	0.20
271.9308472	0.04
275.3745728	0.08
286.3822632	0.02
287.3636475	0.05
289.5368042	0.02
290.4346313	0.03
291.1920166	0.07
292.2822571	0.09
293.3814087	0.03
298.3978271	0.04
299.4869385	0.01
301.3594971	0.02
303.4043579	0.04
304.3945923	0.08
305.3923340	0.06
306.3540344	0.08
311.3996277	0.37
312.4726868	0.05
315.2650757	0.04
316.2502747	0.09
318.3923035	0.06
319.4011536	0.04
321.4410400	0.01
322.1231384	0.02
323.4028931	0.02
324.0387878	0.03
325.0045471	0.02
327.4683228	0.22
329.2711182	0.23
333.1664734	0.05
334.0527649	0.01
335.2316284	0.14
336.3683472	0.04
339.4173584	0.32
340.3897705	0.02
341.3949890	0.14
342.4071655	0.11
345.4211426	0.02
350.2960510	100.00
351.2409363	0.08
352.0052185	0.02
353.1361084	0.02
357.2972717	0.34
359.1643982	0.26
360.2809753	0.14
365.2634277	0.07
367.4001465	0.02
375.1703796	0.01
377.3003235	2.15
378.2415161	0.42
378.9880981	0.02
381.1235046	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	500.1405
Annotation	Unknow
Peak:m/z	Relative Intensity
149.0541382	1.68
153.1200562	0.32
158.1435852	0.21
162.9746704	0.58
163.9969940	3.62
170.2385254	0.27
179.0925598	5.55
192.0950623	0.75
193.1484985	0.62
204.1139526	1.00
205.1080322	0.90
205.9781799	0.12
207.1828918	1.69
208.0363159	7.25
217.1776886	0.05
218.2602081	0.48
219.0926056	0.06
221.2219238	0.33
222.0353394	3.65
223.0640564	100.00
232.2790375	0.31
234.1604309	0.12
235.1718140	0.39
236.2469330	0.19
242.1792908	0.29
245.1922302	0.24
246.0909729	0.12
246.9929199	0.15
248.0605164	0.27
250.1384583	2.08
254.1251221	0.06
263.0927429	0.15
265.1477661	1.57
273.1044312	0.18
276.1624146	12.50
279.1199646	0.16
285.1368408	0.08
289.8691101	0.12
291.2230835	0.23
294.1553650	46.61
294.9472046	0.11
300.2227783	0.43
306.2743225	0.23
307.4181519	0.18
317.9106445	0.63
320.1058960	1.26
322.3558350	0.12
324.0084839	0.14
325.7835999	0.09
331.3447266	0.19
336.2548523	2.39
337.1799622	1.06
338.2198792	15.12
348.2782288	0.54
357.2469482	0.18
363.0336914	0.07
366.5600586	0.40
367.4220581	0.35
371.4911499	0.13
376.3041382	0.22
379.7511597	1.40
385.0914001	8.70
400.3752747	0.25
410.5377808	0.09
412.3216553	0.26
437.2146606	0.28
438.0538025	0.53
441.2769470	0.18
454.1821594	0.15
456.2045898	4.73
457.0149536	0.57
458.2185974	0.29
460.9364319	0.20
461.8979797	0.50
464.0147705	0.44
473.9159851	0.06
477.0668640	0.13
480.1946411	0.17
482.1087952	2.32
491.2028198	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.1139
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
111.1168213	0.03
129.0049591	0.67
147.1584320	0.10
149.1495819	0.03
160.9921112	0.08
164.0313416	0.44
167.1490173	0.03
178.2084961	0.05
179.1385651	0.87
185.1603699	0.03
188.8898773	0.03
191.0657959	1.79
193.0327911	0.16
197.1733398	0.04
205.0528870	1.31
205.7274017	0.04
207.0364075	0.26
208.0456085	3.12
208.9976044	0.20
220.9333344	0.71
223.0719910	100.00
223.9370728	0.02
227.3692017	0.04
231.2171326	0.04
233.3904724	0.03
240.3499146	0.04
241.0528870	0.08
243.3935242	0.04
247.2012329	0.09
251.2634583	0.07
257.1338501	0.06
258.3547668	0.10
259.3816833	0.07
265.0822754	1.45
267.0052490	0.02
270.0906982	0.03
277.2621155	0.03
291.1245728	0.24
305.3833313	0.03
306.4498596	0.03
307.5263367	0.06
308.9804382	0.03
321.1762695	0.14
324.1105347	0.06
324.9969482	0.04
338.4480896	0.05
339.1860962	0.34
339.9113159	0.07
341.1260071	0.39
342.1033630	0.02
349.0390625	0.07
353.0215149	0.50
357.3677673	0.04
364.9694824	0.07
367.1033020	0.58
370.1184692	4.44
371.3310852	0.06
375.8087463	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	465.14
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
200.3975220	0.03
303.1002197	100.00
303.9392700	0.01
345.1621704	0.11
368.8603210	0.02
399.1138611	0.28
411.1989441	0.06
429.0088196	0.10
447.2128906	0.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	599.1956
Annotation	Geniposide pentaacetate
Peak:m/z	Relative Intensity
230.9931793	0.03
261.0540466	0.28
279.9398804	0.05
303.1459351	1.75
304.2568359	1.56
305.0970459	0.57
317.2455444	0.11
342.2453613	0.08
355.3587036	0.05
359.0011597	0.68
378.4442749	0.07
383.4051514	0.78
389.2896118	0.04
395.2760010	0.23
401.0568237	0.03
407.3270264	0.17
412.9520874	0.19
415.4538574	0.07
419.0853882	1.70
425.1348267	0.16
431.1464233	1.12
436.3555298	0.12
437.1596069	0.61
443.1698608	1.24
447.1498413	0.03
449.2943115	0.73
452.2155762	0.11
452.9053955	0.23
461.2551270	15.92
465.3682251	0.18
466.1767578	0.56
467.0540161	0.85
469.1713867	0.07
476.0428467	0.18
479.0000610	9.17
479.7584229	0.02
480.8446045	0.34
483.3001099	0.16
485.1915894	3.51
491.3494873	0.28
497.1731567	0.20
502.9858398	0.10
508.5775757	0.13
509.3197632	0.90
515.0714722	3.84
517.9358521	0.38
519.5695190	0.08
524.1293335	0.03
527.2442017	11.63
533.0668335	0.11
535.6952515	0.27
545.1456299	10.17
546.1844482	0.21
553.1370850	0.07
555.5414429	0.05
558.5606079	0.06
563.2514648	100.00
564.3625488	0.09
565.8378296	0.13
576.2366333	0.07
581.1393433	90.51
582.5167847	0.19
584.1065674	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	477.1039
Annotation	Pedaliin
Peak:m/z	Relative Intensity
147.0525513	0.07
148.9201660	0.03
150.9481201	1.39
152.1014862	0.19
153.0424042	0.35
157.1325989	0.03
160.0180969	0.07
161.2662506	0.05
161.9086914	0.05
162.9554901	0.15
163.8792419	0.06
165.1112518	0.19
169.1621246	0.18
173.1819153	0.17
175.0372620	0.04
175.9492950	0.03
177.0924988	0.22
179.0466614	1.09
180.9797516	0.33
186.1920624	0.04
187.7825928	0.03
189.0237427	0.69
190.0448914	0.15
191.1636963	0.28
192.1054382	0.09
193.0433044	0.22
194.1126404	0.02
196.1698303	0.03
200.9401550	0.42
202.1004639	0.36
203.9349060	0.92
205.0653992	0.87
206.2269745	0.03
207.0923309	0.26
210.0690918	0.06
214.1420288	0.04
215.1068420	0.08
216.0593262	0.03
217.1394958	0.61
219.3117065	0.07
221.2140350	0.02
226.3115540	0.04
227.1852417	0.17
229.4358978	0.04
231.2562866	0.10
232.2654724	0.05
233.0513306	0.39
234.8787842	0.42
241.1076355	0.04
243.1238403	1.74
245.0802917	0.45
247.0989227	0.32
249.0233765	0.02
251.2898560	0.06
251.9689331	0.04
253.2137451	0.04
254.1818542	0.02
255.1155701	0.08
257.1445923	1.37
258.1688843	0.05
260.0310974	0.02
261.2045593	0.25
267.2044373	0.06
268.2209167	0.03
269.2178955	0.17
270.0928650	0.57
271.1151428	4.68
272.5272827	0.76
273.2030334	1.28
275.1946411	0.26
280.1101990	0.12
281.0004883	0.05
283.1207581	0.26
284.0755310	0.14
285.0848694	6.72
286.1755981	2.44
287.2675476	0.53
289.1496887	0.88
290.2460938	0.10
291.0825806	0.12
293.1921997	0.04
294.4702454	0.02
295.3092041	0.16
297.1724243	0.37
298.1364746	0.54
299.0745850	6.15
300.1510010	2.01
301.2757263	0.44
302.3096313	0.07
305.1272583	0.11
306.2506104	0.07
308.1679382	0.02
309.3664551	0.11
310.3049316	0.22
311.3842163	0.08
312.0265808	0.06
314.0877075	100.00
315.0975952	35.99
316.1502991	0.44
322.4064331	0.16
323.8259277	0.13
324.9620972	0.03
326.1369019	0.24
327.2730103	0.97
329.1285095	2.66
330.3869934	0.14
333.3868103	0.04
337.1842651	0.06
338.9161072	0.02
340.5660095	0.10
341.3272705	0.06
342.3079529	0.96
344.2565308	0.14
345.7070007	0.16
348.1188965	0.05
352.2270203	0.05
353.3648071	0.14
354.0385132	0.03
354.9523926	0.07
357.1405945	22.80
358.1451721	0.48
359.4570618	0.10
360.0673828	0.07
361.2246704	0.12
367.2795410	0.06
368.0004883	0.13
369.1027527	0.31
370.4746704	0.02
371.4974670	0.07
372.2257080	0.15
377.1164246	0.03
380.1899414	0.06
381.0957947	0.50
383.5264893	0.08
385.1069946	0.12
387.1216736	2.02
388.3417053	0.19
389.3786926	0.26
392.2427673	0.14
397.1094055	0.04
399.2839355	0.26
405.0443726	0.08
409.2746887	0.19
410.3352356	0.06
414.2319641	0.17
415.0902405	0.36
416.5829468	0.15
417.5286560	0.37
423.6037903	0.02
428.7248840	0.07
431.0919495	0.97
432.0763245	0.14
433.4143372	0.09
434.8909607	0.07
439.2401428	0.06
439.9490356	0.09
440.5513000	0.04
441.2873840	0.13
445.2019348	0.03
449.2345276	1.82
452.9555664	0.04
457.3070374	0.09
458.4267578	0.46
459.4177551	0.52
460.4496155	0.02
462.1225281	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	368.206
Annotation	Isariotin D
Peak:m/z	Relative Intensity
123.8939819	0.10
131.9768219	0.46
137.8150330	0.10
144.0652924	0.06
145.9875183	0.18
148.0748291	0.66
149.0082703	0.08
155.0806580	0.05
161.1219330	0.15
164.0864868	0.07
172.2481079	0.09
173.8301392	0.04
177.0353851	0.30
177.9369965	0.65
183.0361938	0.05
187.2104950	0.06
188.2718811	0.19
189.2588501	0.02
193.1908722	0.21
195.0926361	0.02
196.2219238	0.22
198.3375854	0.04
199.1345978	0.14
201.2300110	0.63
208.2449951	0.06
213.4962921	0.03
217.2332001	0.21
218.6347656	0.13
220.3404541	0.05
224.2513733	0.10
225.0348511	0.07
226.2279358	0.05
226.9063721	0.06
229.3228455	0.06
230.6968689	0.21
232.3694458	0.06
241.5205383	0.16
248.2530823	0.44
249.1124268	0.12
256.3324890	0.11
261.2925720	0.02
262.2293396	0.25
262.9641113	0.11
268.2979736	0.79
269.2915039	0.03
272.2487183	0.06
274.1390991	0.48
278.2055054	0.53
280.2736206	0.87
282.1859741	0.15
286.2221985	1.50
288.3526917	0.21
292.3597107	0.46
295.3218994	0.65
296.2602539	0.44
297.3002625	0.10
298.3019409	2.56
302.2913513	0.14
303.1983643	0.53
304.3397522	0.47
308.0656128	0.15
312.9304810	0.08
314.3925476	0.18
316.1819458	11.31
325.1821899	0.12
326.2349548	0.03
327.9962158	0.45
332.5366821	0.27
334.2694397	21.48
342.3159790	0.08
352.2390137	100.00
353.2289124	0.15
353.8360901	0.21
361.0609436	0.18
382.3327637	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.224
Annotation	Javanicoside C
Peak:m/z	Relative Intensity
204.3180389	0.14
221.1781769	0.11
233.0539093	0.04
243.2794800	0.03
261.3135986	0.06
287.3163452	0.08
299.2555542	0.04
305.1239624	7.82
307.2059326	0.08
312.4302979	0.11
323.2780151	0.05
341.2570496	0.11
355.3267822	0.04
373.2602539	100.00
378.5433960	0.05
379.2021484	0.26
384.2738647	0.10
393.4077759	0.17
404.4458008	0.07
423.0537109	0.32
424.3316040	0.25
441.9721069	0.16
482.7603760	0.07
487.5299683	0.13
491.3378296	0.07
493.2623901	0.08
502.3821411	0.19
510.2147827	0.14
511.1118774	0.04
511.9174805	0.49
519.2045288	0.10
524.7694702	0.34
525.5985718	0.21
540.7153931	0.17
564.4140625	0.07
580.4880371	0.13
586.0126343	0.35
606.9719849	0.07
607.6431885	0.06
609.4483032	0.52
624.6772461	0.29
633.2446899	0.35
635.3278198	0.16
669.5745239	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	340.1244
Annotation	Unknow
Peak:m/z	Relative Intensity
134.8873596	0.04
136.1963196	0.05
140.1601257	0.03
147.9687805	0.53
161.0449829	0.09
177.6504517	0.08
181.1759338	0.14
185.3417358	0.26
190.0570526	0.93
208.1225281	100.00
211.4011230	0.22
218.9955139	0.08
231.1493530	0.10
240.1090698	0.10
251.0244751	0.03
261.8715820	0.12
268.1404419	0.20
278.4849243	0.12
292.3592834	0.11
295.3036499	0.05
296.2073364	0.14
298.1438904	0.31
299.1607056	0.41
303.9105835	0.43
304.9629517	0.24
311.7395020	0.08
313.2158813	0.08
321.6673279	0.30
322.2753906	2.87
323.2160339	0.08
330.7755737	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.1039
Annotation	Aesculin
Peak:m/z	Relative Intensity
116.9865570	0.59
118.6590500	0.14
121.1659241	0.35
121.9412766	1.25
123.1124344	2.00
131.1102905	0.50
132.9504700	1.21
134.0303345	0.40
135.0371399	1.35
136.0908508	0.84
137.0396881	0.11
143.1568298	0.16
145.1358337	0.38
147.0369263	0.06
148.9522858	1.50
150.9766083	20.28
151.9831085	52.59
153.0523682	4.76
158.3151093	1.10
159.1543732	0.07
161.0329895	0.56
163.0382690	18.07
164.0512543	0.29
172.9779053	0.86
174.9027100	3.92
175.5168457	0.07
177.0448456	5.84
179.0451050	14.00
181.1485901	0.57
183.1257172	0.38
187.1435242	0.67
187.9925690	0.59
188.7324829	1.01
190.0078888	0.35
193.1197357	2.35
195.1073303	0.74
203.2678375	0.23
205.0875092	3.17
207.1557465	7.03
219.0713654	4.49
221.2049408	0.24
223.1017761	4.77
225.1176453	3.82
237.0658875	1.15
241.0434875	100.00
242.2201843	1.18
249.2367554	0.36
262.9547119	0.24
267.1616516	8.34
269.0865784	0.39
285.1137695	36.46
286.2068481	1.31
293.1185303	0.37
299.3416443	0.19
301.4437256	0.09
327.1320801	2.04
359.1105957	0.08
370.9631348	0.20
373.1664734	3.90
399.1913147	8.84
399.9978943	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	760.1712
Annotation	Unknow
Peak:m/z	Relative Intensity
219.1109619	0.02
220.9258728	0.01
222.1977234	0.02
244.9361877	0.03
257.2113647	0.05
258.9584961	0.03
271.2043457	0.02
273.0249634	0.09
274.2705078	0.01
281.1098328	0.04
281.9588928	0.05
283.3439026	0.03
285.2129822	0.05
286.1260376	0.06
290.2327881	0.02
291.0286865	0.01
299.7629089	0.01
301.1403809	0.45
302.2860718	0.04
303.3709717	0.08
312.9965820	0.06
314.1837463	0.03
316.2898560	0.06
317.2390137	0.25
319.1550598	0.35
320.1743164	0.09
322.4748230	0.01
328.3621216	0.09
329.2191772	0.30
330.2676392	0.14
341.1713257	0.06
343.2914429	0.02
345.0601196	0.03
347.0952148	16.26
348.1480103	2.23
358.1444702	0.02
361.2015381	0.32
362.0796509	0.04
373.1519165	3.85
374.2520142	0.41
387.1387329	0.02
388.0355225	0.02
389.1170044	0.09
390.2608643	0.07
401.0169678	0.39
402.1151123	0.12
418.9583130	12.47
420.0510864	1.40
436.0951538	100.00
437.1838379	11.68
439.2057495	0.03
440.8269653	0.06
449.1710815	0.05
460.9609985	0.15
466.1490479	0.01
478.1535645	1.38
479.0891724	0.11
482.0077515	1.96
483.0086670	0.53
483.6359253	0.05
497.1412354	0.02
500.4559937	0.17
501.1440430	0.08
502.1885986	0.04
503.1402588	0.06
505.9951782	0.01
514.1472778	0.14
518.0753784	1.14
519.0968018	0.30
523.3201294	0.01
526.4329834	0.10
527.1727905	0.11
533.0594482	0.08
534.3394165	0.06
535.4773560	0.04
544.0430298	1.31
544.6815796	0.01
545.3081665	0.39
551.6613770	0.03
558.2391357	0.01
562.0661011	2.92
563.0195923	0.55
563.6315308	0.02
580.0946655	4.69
581.1582642	1.09
594.2915649	0.02
598.1028442	10.64
599.1823120	1.39
604.2326660	0.04
608.1530151	0.01
614.1896362	0.03
628.3867798	0.01
635.1163330	0.05
640.1050415	0.15
645.2140503	0.10
653.1625366	0.02
655.9954834	0.01
657.5584106	0.06
661.3834229	0.01
662.3491211	0.05
673.4616089	0.01
680.2185669	0.32
681.0827637	0.08
689.3013306	0.03
706.2052612	2.00
707.2002563	0.47
716.2462158	0.03
724.0189209	1.11
724.9673462	0.38
725.6793823	0.01
742.1058960	9.96
743.1458130	2.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.2837
Annotation	Ceriporic acid B
Peak:m/z	Relative Intensity
107.0055542	0.47
109.0857620	1.21
111.1384964	0.42
121.1185303	0.29
123.0668335	0.84
124.9833832	0.72
126.8049164	1.12
132.9973145	0.62
135.0051727	1.48
136.9136963	1.15
138.9466553	0.55
140.7456665	0.73
142.9023132	0.12
147.0349426	0.49
149.0545654	3.02
151.0444946	0.59
153.1206665	0.76
154.9747925	1.45
157.0541992	1.28
161.2594604	2.79
162.9924622	0.98
165.1114197	2.72
167.0992126	0.57
169.1415253	0.24
171.0943298	0.26
173.1072083	0.11
175.0777893	3.22
177.4121704	0.07
179.1271667	3.58
181.0462952	0.40
182.3135376	0.15
182.9451141	0.13
184.8769379	0.76
189.1709290	1.10
191.0295410	0.62
193.2264862	1.55
195.1116028	0.59
197.2351227	1.51
202.9709167	0.38
205.1833191	0.19
207.1165771	0.14
210.8361816	0.50
214.7849426	0.12
217.0809631	0.53
219.1433716	0.07
221.3471985	0.56
224.9010315	0.53
227.1370239	0.08
228.9594116	0.12
230.6929321	0.05
233.2288818	0.20
237.2110596	0.16
240.8491516	0.21
243.0353088	0.50
245.2499695	40.26
247.1533508	4.55
252.9983521	0.22
255.0820923	0.32
256.8229370	0.15
257.4719238	0.17
258.9251709	0.12
261.2839966	0.38
263.2406616	95.09
265.2643738	10.73
266.9815674	2.69
268.1925659	0.12
270.9804077	0.43
273.0762939	0.17
277.4502869	0.23
280.0010986	1.35
281.1322632	13.61
283.3811951	1.25
284.8849792	1.92
293.3302917	0.50
295.4746399	0.45
299.2389526	4.10
308.9296265	0.29
311.1369934	0.48
313.2637329	1.47
313.9999390	1.31
319.4319458	4.11
320.7532959	0.30
327.5159912	0.33
328.2599792	0.63
330.8868713	1.06
331.8151245	0.76
337.2896729	100.00
338.1242371	0.34
338.9768677	0.45
345.6696472	0.27
346.7349548	0.31
355.1853333	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1248
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
161.0380859	0.07
162.1353455	0.12
173.0715942	2.03
174.0283661	0.07
179.1016235	2.51
185.1727295	0.06
187.0320892	0.07
190.9812775	29.99
192.1371155	2.15
203.0882263	0.21
207.3024139	0.23
209.1550903	0.16
229.2626190	0.15
235.9662781	0.63
247.3157043	0.37
261.3779297	0.16
275.1281128	0.05
276.1760254	0.08
284.2034912	0.06
291.1523132	0.56
292.0902710	0.12
295.5974731	0.06
306.2214355	0.49
309.2003784	3.16
310.0559998	0.11
319.0083008	0.34
320.4249878	0.05
321.9837646	0.06
323.0418091	0.07
333.0001831	0.66
334.0910034	0.11
335.0780640	2.30
336.3272095	0.68
337.3142700	2.67
338.2059937	0.49
353.0729370	29.58
354.1190796	2.87
356.1018066	0.13
357.2729492	0.09
363.2682495	0.40
381.0985107	15.81
382.2450562	1.96
387.1302490	0.08
391.3546143	0.48
396.2264404	0.06
399.1441650	100.00
400.0706177	15.88
403.4032593	0.09
413.2453613	0.12
414.2683105	0.21
417.6424561	0.15
433.0682373	0.32
443.8620605	0.23
445.2406616	0.11
459.2310181	0.06
463.1549683	0.20
463.9897461	0.06
473.5067749	0.11
475.5573730	0.27
481.5444336	1.48
482.3854370	1.37
483.4163208	0.22
489.0927124	0.11
490.1719360	0.37
499.1657715	0.38
501.4291382	1.77
507.4666748	0.14
515.4132690	3.07
516.3947754	0.83
517.8410034	0.87
519.4680786	0.03
523.2816772	1.73
524.1481323	1.06
525.3317261	2.56
526.3584595	0.86
529.4640503	0.30
530.3471680	0.42
531.1373901	0.11
541.3849487	0.75
543.0281372	5.08
544.1374512	2.50
544.7991333	0.25
545.6994019	0.17
553.0027466	0.06
562.0637817	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	253.14
Annotation	(-)-trans-C75
Peak:m/z	Relative Intensity
75.10775757	1.09
93.09610748	0.28
101.331192	0.15
121.2067413	0.30
126.851944	0.47
130.0457001	0.12
151.0875854	0.09
155.0339813	0.91
157.2086029	0.16
162.7960663	0.69
165.2639008	0.22
169.1468048	0.75
178.974823	0.25
181.3092804	0.33
183.2149963	0.15
185.2949982	0.26
191.1629333	0.81
205.1439056	0.11
206.8805389	0.14
209.1525116	100.00
210.1622467	0.76
211.1887054	0.96
214.9094086	0.77
216.0983429	0.24
216.9211121	1.98
218.1286316	0.11
225.1996613	1.30
235.1871185	10.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	671.1611
Annotation	6''-Vanilloyliridin
Peak:m/z	Relative Intensity
203.3116455	0.06
227.1176300	0.08
235.0406799	0.03
242.9038086	0.16
255.0361938	0.05
271.1012878	1.09
272.0602112	0.17
273.1468811	0.15
299.0633545	12.29
300.0602417	2.83
301.1507263	2.49
302.1999512	0.41
306.2741699	0.04
310.2745361	0.02
313.2723999	0.21
314.1869507	0.11
314.9902954	0.13
316.9025574	0.09
323.2895508	0.04
325.1141357	0.11
341.4801331	0.07
342.2715454	0.08
343.2768555	0.25
344.0961304	0.04
355.1320190	0.05
371.7538452	0.09
374.0947876	0.06
376.2244873	0.02
401.0777588	0.03
417.1209106	0.10
418.2989502	0.10
420.3496704	0.07
426.5006104	0.07
433.1856079	0.04
434.1076660	0.13
451.2032471	0.53
452.3289795	0.12
459.3041382	0.04
461.1809692	100.00
462.1892700	37.50
463.1923218	2.62
464.3643799	0.42
467.1419067	0.02
473.4605713	0.01
475.5292969	0.12
476.2133179	0.06
477.3612061	0.13
478.5139160	0.06
479.3051147	0.11
480.2326050	0.23
486.5673218	0.02
489.5720215	0.02
491.1683350	0.35
492.2946777	0.07
502.2739868	0.18
505.2748413	0.03
509.1598511	12.15
510.2145386	4.24
521.0636597	0.06
543.2790527	0.05
588.5040283	0.02
592.5093384	0.05
594.7040405	0.24
596.2941284	0.03
597.2759399	0.08
598.2582397	0.04
613.4844971	0.03
614.2761230	0.19
615.2651978	0.10
615.8701782	0.10
617.5093384	0.14
625.8770142	0.07
627.8123779	0.03
628.7465210	0.04
633.3405762	2.09
634.4371338	0.61
635.3238525	0.65
636.2235718	0.14
639.5443726	0.04
640.3656006	0.03
641.2549438	0.61
642.1950073	0.19
643.9046021	0.07
653.1760254	0.71
654.1937256	1.23
672.0974731	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	472.9244
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0376892	0.02
229.0461731	0.01
245.1681519	0.08
272.9469910	0.17
275.0999756	0.01
357.2308960	0.02
358.9254456	0.30
426.9844055	100.00
428.0509033	0.14
429.0959778	0.14
430.0229187	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1687
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
106.1108627	0.16
119.0024261	0.48
128.9307404	0.10
129.9975128	0.03
143.2002563	0.07
156.1121368	0.31
162.320343	0.09
170.0679321	6.59
171.1217957	0.21
172.0760193	0.09
183.0041504	100.00
184.0060425	19.13
184.9889069	4.22
186.0457001	0.16
197.0126953	92.42
198.0118408	29.60
199.0235596	4.07
200.1735992	0.59
208.4925232	0.03
211.1534119	4.19
212.1038513	2.76
213.1572266	0.91
214.1348877	0.30
225.0940552	2.92
226.0863342	4.18
227.0752563	0.81
227.8745117	0.08
230.8083801	0.05
239.1417236	4.65
240.1152954	3.48
241.219696	1.66
242.1631775	0.18
243.2026367	0.16
247.2147217	9.80
248.3312988	2.63
249.3684082	0.44
250.1486206	0.32
251.0075989	0.33
253.1896362	3.09
254.1629639	3.34
254.9788513	0.39
256.4259338	0.18
265.2927246	0.06
267.2502441	1.31
268.1272583	0.85
269.545929	0.31
280.2597961	0.06
281.0955811	0.07
282.5874634	0.07
283.4373474	0.12
293.2966614	2.19
294.1652527	1.10
296.1351013	0.20
297.0463867	0.34
311.2381592	15.84
312.2344971	4.60
313.2192993	1.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	403.232
Annotation	5S-HETE di-endoperoxide
Peak:m/z	Relative Intensity
133.1045685	0.16
134.9875336	1.05
136.9316101	0.26
151.1788330	0.12
151.8073730	0.04
153.0084534	2.78
155.2953796	0.04
156.2294922	0.22
157.0308533	0.18
159.0518036	0.08
166.8195038	0.18
179.0986023	0.10
184.9625244	0.33
187.1658020	0.12
188.1614227	0.04
192.8896942	0.04
193.9717407	0.11
206.9805450	0.06
208.1030579	0.06
212.2058716	0.30
212.9829254	1.28
216.9571381	1.58
223.3330078	0.05
225.3752747	0.31
240.9253235	0.09
247.2332458	0.08
255.0994568	0.05
258.9870300	0.63
264.4078674	0.14
268.0080566	0.56
268.8330078	3.87
271.2883301	0.08
272.8312988	9.65
273.5082397	0.05
283.2005310	0.35
289.1441345	0.06
292.3711243	0.08
293.9556885	0.13
300.4454346	0.06
308.5500488	0.16
313.0617676	0.05
317.4251404	0.16
328.9577026	100.00
335.2658997	0.05
341.2629395	0.05
342.6582336	1.10
343.3560791	0.89
353.3775024	0.42
356.3855896	0.06
360.5311584	1.16
361.1456604	6.53
362.2885132	0.25
367.3410339	0.41
368.5005188	0.21
369.2029114	0.07
371.1861877	0.40
384.3093262	0.89
385.3404846	1.69
386.4242554	0.37
387.3073425	0.23
403.4220886	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	467.1671
Annotation	Unknow
Peak:m/z	Relative Intensity
151.0936279	0.11
153.0050507	0.18
154.8656616	0.03
161.1464691	0.36
179.8922729	0.03
188.4266663	0.08
189.1188660	0.86
203.0992126	0.42
206.8901825	0.01
220.1494598	0.03
229.9801483	0.07
233.1866302	0.48
243.1733398	0.85
253.2528381	0.02
259.1281433	0.13
261.1021118	0.43
265.0849915	0.04
266.4277954	0.03
279.8943787	0.04
286.1144104	0.08
288.3176270	0.02
293.3229675	0.08
295.2795715	0.14
303.0138550	0.93
304.1499634	1.29
305.1655579	8.35
305.8748169	0.11
306.9462891	0.01
313.3753052	0.24
314.1929016	0.45
315.2212524	0.22
323.1795654	100.00
327.2897949	0.03
333.3538208	0.04
334.3253174	0.05
335.2292786	0.02
336.2983398	0.04
346.0076904	0.03
359.1098022	0.09
360.9091187	0.02
362.6907349	0.02
365.2207031	9.42
366.4589844	0.02
369.1921082	0.03
370.7993774	0.12
373.2074280	0.05
377.4407959	0.05
379.1985168	0.04
380.0830383	0.07
381.3154297	0.04
387.3450012	0.15
388.2615051	0.02
389.5051270	0.05
393.1705017	0.06
405.1350098	2.05
405.7574158	0.01
406.4462891	0.07
407.2958069	0.06
419.9952393	0.04
421.2057190	0.41
422.7425537	0.06
425.3352051	0.02
427.7419434	0.11
431.4896851	0.04
448.0973511	0.10
449.1886292	0.24
452.5591431	0.15
453.3197327	0.12
458.0036011	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.146
Annotation	Clitoriacetal 11-O-glucoside
Peak:m/z	Relative Intensity
192.0297241	0.19
208.9740295	0.22
214.9857025	0.17
247.3536987	0.08
248.8016663	0.34
254.0103455	0.34
255.0542603	0.12
270.4667358	0.22
271.4258423	0.25
279.0825195	0.26
285.3884888	0.24
291.0981445	0.31
300.2723389	0.58
301.1466675	0.99
302.2460938	0.41
303.3068542	0.31
305.0472717	0.17
315.1513367	0.11
325.3267822	0.12
345.3594971	0.13
357.0291748	0.51
368.0031738	0.44
373.6817017	0.22
376.2627563	0.24
379.1978760	0.12
385.0614624	0.20
387.2944946	0.06
389.0255127	2.67
390.6848755	0.09
391.3966064	0.16
393.0784302	0.25
404.9193115	0.49
409.4783936	0.36
411.1937256	0.81
413.1723633	0.07
416.7257080	0.63
419.3203125	0.19
421.0396729	0.08
423.3385620	0.28
429.2232666	1.64
434.2368164	1.61
435.0073853	0.98
435.7026978	0.88
445.1447754	0.22
446.5145874	0.85
447.5074463	0.46
449.2408447	0.12
457.2573242	0.04
458.2029419	0.14
460.4645996	0.08
464.4840088	2.14
465.4899292	2.47
472.6823730	0.54
476.3693237	1.07
505.3076172	0.30
507.3792725	0.18
509.2866821	0.13
517.4252319	0.10
518.3234253	0.09
529.5501099	0.13
532.3535767	0.22
535.4396973	0.39
542.1953125	0.46
549.7976685	0.14
551.1715698	100.00
552.2807007	0.74
553.2294922	0.56
554.2517700	0.32
555.6005859	0.07
558.7440796	0.07
560.6362305	0.49
561.2998657	0.36
567.0289307	0.80
568.4112549	0.08
569.2118530	0.06
574.1311646	0.07
576.3753052	0.06
578.4014893	3.89
579.3969727	4.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.1614
Annotation	Rhamnocitrin 3-glucosyl-(1->2)-galactoside
Peak:m/z	Relative Intensity
178.9344025	0.22
186.3157349	0.12
191.0693359	3.15
192.0563202	1.50
193.1010437	0.09
206.0118713	15.52
207.0157623	11.33
209.3354492	1.07
242.8425751	0.13
279.3080750	0.40
283.2055664	0.15
285.2540283	0.08
297.2574768	0.16
303.0935669	0.11
307.2910156	0.08
309.4916077	0.10
319.3926086	0.12
327.1918945	0.25
329.3118896	0.17
336.2230835	0.12
339.9872437	0.05
348.4239502	0.41
353.0574341	0.10
359.1129761	0.40
371.2318726	0.20
385.1700439	0.52
395.3132935	0.13
397.3329468	1.07
402.4733276	0.09
409.6460571	0.13
415.1099243	100.00
415.7678833	0.65
419.5008545	0.05
425.0211792	0.17
431.4349365	0.05
435.6134033	0.30
441.5538330	0.48
442.3113403	0.17
453.5325317	0.21
454.1511230	0.41
454.9384155	0.36
459.2664185	1.67
460.2506104	4.41
461.3841553	2.39
479.2201538	0.58
483.4154053	0.25
484.2105713	0.17
485.2334595	0.15
491.3792725	0.23
493.2869263	0.25
497.3602295	0.26
500.5399780	0.09
503.4602661	0.15
505.4722290	0.18
519.5713501	0.17
521.6204834	0.56
535.4175415	0.34
542.2269897	0.22
546.2196655	0.07
546.9581299	0.37
561.0237427	0.09
562.3836060	0.66
563.2210083	0.87
574.7528687	0.20
576.1580200	1.18
576.7783813	0.84
577.5037231	0.95
578.3687744	0.11
579.2249146	0.54
584.1867065	0.27
586.9616699	0.97
587.7938843	0.11
591.4238281	0.30
595.5404663	0.22
599.4011230	0.24
600.2324829	0.45
604.4173584	0.94
605.2179565	2.65
614.8002319	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	830.2615
Annotation	Aromatized deshydroxy-C-1027 chromophore
Peak:m/z	Relative Intensity
238.1941528	0.21
244.9967804	0.37
249.3164062	0.33
250.9222717	1.77
263.0238342	1.90
269.2111816	0.08
280.0546875	1.47
281.0274048	12.27
282.1578979	0.13
294.1280823	0.25
298.7113647	0.07
310.4260254	0.11
314.9664917	1.08
320.0552979	0.17
322.9813843	1.12
336.0445557	0.43
340.2012634	2.56
341.1633606	1.12
350.3778687	0.12
352.3304443	1.11
353.3207397	0.22
358.0875854	0.82
364.3076172	0.32
368.5419922	0.08
376.0896606	0.10
379.3643799	0.23
381.8273621	0.16
383.1776123	0.33
393.6453857	0.16
395.1403198	0.13
397.4845581	0.65
412.2013550	0.09
413.2905273	0.22
414.4210815	0.07
423.9466553	1.20
424.9989014	0.33
426.9932861	0.28
428.2338257	0.21
442.1108398	59.35
443.1416626	100.00
444.2109375	0.61
445.2672119	0.91
475.8413696	0.06
506.1026611	6.97
507.1671143	0.62
514.0829468	0.49
558.9549561	0.09
560.2218628	0.15
577.9403687	0.06
581.7229004	0.07
603.9824829	16.94
605.0505981	3.88
628.3994141	0.20
640.1190796	0.28
643.4108276	0.73
667.9932251	18.36
669.0289917	4.33
698.6215210	0.09
736.3889771	0.10
740.4223022	0.26
741.3858032	0.26
771.7473145	0.14
777.5469360	0.58
812.4470825	0.34
813.8256836	0.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	286.9867
Annotation	Unknow
Peak:m/z	Relative Intensity
100.8786621	0.03
119.8608398	0.08
121.1163483	0.02
132.0773926	0.03
143.1756897	0.03
150.9810333	0.02
159.1755524	0.06
159.8968506	0.05
171.0962830	0.12
173.0705261	0.01
178.0709229	0.03
185.0884247	0.07
187.1301880	0.14
189.1149139	0.02
190.9636688	0.06
192.2182770	0.09
199.1551819	0.19
201.0030823	0.02
202.8228760	0.01
207.0947266	100.00
215.1279297	1.21
217.1307068	0.07
225.1208801	0.02
227.3225098	0.02
231.0552368	0.47
241.1470032	0.43
241.9472656	0.03
243.0452881	0.76
245.2110596	0.01
248.3509521	0.02
255.1680603	0.03
257.1315918	0.03
258.0343933	0.10
259.1063232	0.62
268.5361633	0.23
269.1814575	0.92
287.0431213	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.161
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
129.1693420	0.04
133.0715179	0.02
134.2289734	0.04
134.9699249	0.02
143.0092316	0.05
148.2192688	0.03
149.1240997	0.09
159.0990601	0.01
160.9879303	0.44
163.1991882	0.02
165.2199402	0.03
167.0912018	0.29
169.0324707	0.02
172.9194336	0.05
177.9336243	0.09
179.1029053	0.24
181.9961243	0.75
191.2727814	0.05
193.1748352	0.07
195.1702881	0.33
197.0668335	6.17
203.0368195	0.07
205.1333008	0.07
206.2484436	0.04
207.1303711	0.09
208.0684814	0.10
215.2548981	0.02
221.0585327	0.02
221.9499664	0.02
223.1786499	2.77
224.3422852	0.02
225.4904633	0.23
226.1198425	5.32
233.1696472	0.02
235.1665344	0.05
239.7202759	0.14
241.0898743	100.00
247.0627136	0.02
255.3303528	0.09
261.3467712	0.02
265.0900574	0.22
270.4236755	0.11
277.2905273	0.02
280.9400024	0.04
283.0836182	0.98
287.2278137	0.02
295.3323669	0.18
297.1599121	0.04
300.2463684	0.32
305.3390808	0.05
306.2794189	0.04
307.0703430	0.06
311.1572266	0.03
313.2232056	0.11
316.1137085	0.02
323.3860168	0.01
327.0981445	0.06
329.1120605	0.08
330.2225647	0.05
339.4909668	0.09
341.2090454	0.03
342.1380005	0.05
343.1398010	0.63
343.7845459	0.02
357.1392517	0.76
359.4151001	0.06
360.0623474	0.03
363.9218445	0.03
366.9541321	0.06
372.7458191	0.06
375.2558594	0.02
384.2013245	0.37
385.1867981	0.41
388.2308044	0.11
403.2039185	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.2866
Annotation	Atractyloside G 2-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
217.0784912	0.23
253.1052551	0.07
283.5116577	0.09
291.2681885	0.08
313.1495972	0.22
316.9331055	0.08
325.2847290	0.12
335.3406372	0.08
339.3607788	0.24
353.4788818	0.09
361.6334229	0.05
366.1886597	0.54
368.3025513	0.80
376.3825684	0.11
381.9746094	0.29
382.9443970	0.25
384.9325562	0.64
397.1577759	0.10
399.4632568	0.40
401.3470459	0.38
415.2901001	3.37
417.4792480	0.20
429.3086548	0.04
435.5624390	0.16
437.3745728	0.12
455.3607178	0.16
458.9285889	0.17
471.3894653	0.12
479.2355347	0.08
481.5010376	0.04
489.3028564	0.09
490.4563599	0.10
491.0930786	0.18
509.9794312	0.40
517.0289307	0.13
518.6303101	0.16
519.3685913	0.15
531.2907104	100.00
533.5747681	0.41
538.4143066	0.08
539.4556274	0.04
541.3392334	0.04
545.4044800	0.34
554.7080688	0.05
556.6054688	0.24
558.0056152	0.20
559.1620483	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	415.0652
Annotation	Kynapcin 24
Peak:m/z	Relative Intensity
131.2907104	0.11
132.9764099	1.72
137.0000305	0.45
139.0424347	0.11
149.0820007	2.00
160.8126678	0.42
165.2399750	0.23
166.8630676	0.63
170.8332520	0.09
172.1726379	0.29
177.1157379	0.45
178.1195984	0.44
181.2314453	0.24
191.1054688	0.34
193.0828705	100.00
194.9900513	11.77
198.1802979	0.11
207.1433411	0.76
209.1170502	25.86
211.0781860	0.48
212.2338867	0.21
220.2104797	0.10
221.1538086	0.08
222.9762573	2.15
224.1826172	1.12
229.2526245	0.11
233.0431519	0.14
235.1287537	0.08
237.3305664	0.34
239.1915283	0.81
244.7008972	0.62
251.1268921	0.32
254.2277832	0.20
261.4361267	0.07
267.2682190	0.10
269.2775574	0.27
271.3907776	0.20
276.0375977	0.55
280.2361450	0.24
294.9900208	0.37
296.1080933	0.17
304.9213867	0.13
321.2111816	0.15
324.1361694	0.38
326.4746704	0.14
327.2353821	0.48
330.3865967	0.07
332.3553772	0.29
333.4305115	0.51
337.4095154	0.55
338.3591309	0.35
341.0992126	0.23
345.1733093	0.27
351.2828979	0.48
355.0823975	1.40
357.4091492	0.29
359.1543884	3.51
364.9540710	0.39
366.2886658	0.21
367.2507019	0.19
369.4486389	0.44
371.3835144	0.38
374.2686157	0.17
378.7833862	0.72
379.4989319	1.72
381.4258728	0.06
383.0307617	0.94
383.9659119	0.12
387.1481018	2.46
391.4118958	0.57
396.3374939	3.51
397.2819824	4.58
398.5449524	0.62
400.4328308	0.36
401.0823059	0.29
404.0162048	1.00
405.9065857	0.34
406.9146423	0.33
411.1118774	0.29
414.7394714	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1487
Annotation	Unknow
Peak:m/z	Relative Intensity
126.9083023	1.78
127.9854660	11.66
132.1338959	0.13
145.0847168	20.55
145.9525909	100.00
191.9491577	0.15
218.0088196	0.10
222.1826782	0.07
242.1271973	8.16
243.2250366	0.27
255.3467102	0.20
270.3562012	0.64
271.3139038	0.11
293.3051147	0.08
305.0004883	0.39
309.2764893	0.11
329.4677734	0.16
343.1915283	0.13
344.2629395	0.24
383.8532104	0.28
384.9785767	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	381.192
Annotation	Cinncassiol A
Peak:m/z	Relative Intensity
113.2032623	0.01
126.9426498	0.02
137.1555786	0.22
155.5513000	0.01
175.2837830	0.03
190.9392700	0.08
196.9317474	0.05
199.3846588	0.02
200.8229675	0.03
207.2450256	0.03
217.2029419	0.04
219.2127991	0.02
221.0715027	0.02
223.0198975	0.02
225.3322754	0.09
231.2203064	0.02
233.0526733	0.12
233.7299805	0.07
235.3744812	0.12
237.4534912	0.02
239.0382080	0.03
241.0523682	0.07
243.0977173	0.01
245.2024841	0.25
247.4608765	0.12
255.2953796	0.02
257.3405457	0.40
259.4289246	0.01
261.2617188	0.21
263.2623291	0.33
265.3414307	0.14
267.4296265	0.02
273.3552551	0.49
275.3273010	0.92
277.3699341	0.05
279.1748657	0.10
282.9214478	0.04
285.0712280	0.01
291.3864746	0.52
293.3546753	0.64
301.5574951	0.06
303.4403687	0.01
305.2988281	0.15
307.3409119	0.11
309.3944092	0.55
317.2998047	0.02
319.3745422	1.22
320.5633240	0.03
335.3652649	1.31
337.2962952	100.00
338.3349609	0.28
344.7434082	0.05
345.3557129	0.31
350.2387390	0.15
361.0802002	0.01
362.3985291	0.32
363.3367615	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	324.1451
Annotation	Boveinine
Peak:m/z	Relative Intensity
101.1756134	0.06
101.9345169	0.22
125.8705978	0.06
127.9492798	39.97
130.1491394	0.61
144.0788879	0.47
146.0283508	4.54
164.8515930	0.03
170.1336517	0.12
177.0461884	0.14
194.0776672	0.05
195.1323242	21.22
200.8298187	0.04
202.9710541	0.08
205.0812683	0.11
207.0870667	0.05
233.8418579	0.13
236.1351013	0.58
241.3061829	0.08
243.3443909	0.11
245.3773499	0.04
247.1181030	0.12
248.2072754	0.06
262.3911743	0.62
278.0289612	0.29
278.8463745	0.04
280.2530823	7.61
288.1008301	0.30
306.1600342	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.02
Annotation	Unknow
Peak:m/z	Relative Intensity
223.8735962	100.00
240.2451782	0.02
241.7654572	17.56
242.4221954	0.05
247.1508636	0.01
264.8309631	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	286.9868
Annotation	Unknow
Peak:m/z	Relative Intensity
122.9992599	0.02
153.1955566	0.01
172.2937622	0.02
178.8006287	0.01
192.1390839	0.13
195.2184753	0.04
207.0170593	100.00
215.1142578	0.05
216.1599426	0.02
224.0956116	0.01
224.9843140	0.04
238.1740112	0.04
241.1769104	0.03
241.8166809	0.01
243.1037598	0.08
244.1003418	0.06
250.9878845	0.02
267.9031372	0.11
269.2357178	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	696.2106
Annotation	Unknow
Peak:m/z	Relative Intensity
233.9191589	0.15
276.2222900	0.13
299.3129272	0.37
302.9126587	0.58
310.2366333	0.07
315.0633545	0.21
325.3088989	0.11
326.3508911	0.17
327.2498779	0.19
329.3848267	0.17
330.2549744	0.22
336.1765137	0.07
336.7828369	0.10
337.4089355	0.34
338.4182739	0.34
343.1773682	0.42
344.4951172	0.07
354.1698608	7.90
355.2166748	23.07
356.2423096	3.71
357.1348877	0.05
361.3679199	0.13
370.4097900	0.06
372.1878662	100.00
373.2229614	22.11
379.0963745	0.10
397.3398438	0.43
399.1448364	0.22
411.1907349	0.69
414.3270264	3.00
415.2484741	0.20
420.0718384	0.08
422.3493042	0.09
438.2200317	2.14
439.3005371	0.55
447.1594238	0.14
448.5213013	0.09
451.1142578	0.22
465.0640869	0.32
466.4454346	0.13
468.3319092	0.20
480.2656860	0.32
481.0881348	0.40
498.4187012	1.46
499.3149414	0.15
500.5137329	0.15
516.3134766	4.13
517.4344482	1.52
534.1609497	16.14
535.1716919	8.35
535.8422241	0.02
562.5464478	0.13
576.4521484	0.23
582.0401001	0.10
608.3355103	0.09
609.3377075	0.21
617.4290161	0.27
622.5902710	0.16
642.4023438	0.10
643.1000366	0.06
652.9888306	0.10
653.6517334	0.11
660.4703369	1.43
678.2768555	24.16
679.3468628	8.92
680.5537720	0.26
697.9536133	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	395.1922
Annotation	Creoside IV
Peak:m/z	Relative Intensity
145.0526733	0.25
159.2448730	0.06
161.0784607	0.91
183.6457520	0.16
187.2300720	1.75
191.0152130	0.30
220.1849213	0.14
223.3902588	0.14
229.3030090	0.07
232.9147034	0.71
235.3290405	0.11
246.3433838	0.12
259.3786926	0.34
260.7641296	0.22
263.1702576	7.99
292.8549805	0.17
299.0336304	0.28
303.0895386	0.10
311.3006897	0.08
315.3556213	0.24
326.3746338	0.24
333.1853943	0.04
334.4714050	0.18
349.3051453	100.00
351.3030396	0.74
353.1853943	0.04
357.3277283	0.05
358.2020569	0.12
359.3935852	0.15
364.3122559	0.57
365.3833008	0.09
376.3087158	1.28
377.3133850	0.50
378.1166382	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	684.1212
Annotation	Unknow
Peak:m/z	Relative Intensity
194.9391022	0.12
203.1352234	0.23
277.4667969	0.19
278.2224731	0.14
281.0523071	0.05
282.1468506	0.66
304.4023438	0.38
309.1883240	0.04
314.8326416	0.13
319.2085266	2.88
326.5311279	0.12
331.2150879	0.13
341.0991821	0.87
343.2191162	0.04
347.1171875	23.74
349.0465698	0.88
349.9794312	0.21
359.3375244	0.18
361.0029907	0.29
363.4346313	0.07
371.2339478	0.40
373.1118164	0.20
388.9316406	0.21
390.3385010	0.69
407.4144287	0.18
416.1716919	0.06
418.7307129	0.77
428.9318237	0.53
436.1585693	100.00
439.2685547	0.07
440.6044922	0.09
446.1696167	0.17
463.6524658	0.30
464.3915405	0.15
478.1705322	1.65
482.1619873	4.13
499.7944336	0.14
501.9714966	0.17
522.2559204	0.11
526.0998535	0.81
536.9086304	0.05
544.3094482	0.31
550.2091064	0.20
551.4502563	0.17
555.2743530	0.38
562.7084961	0.39
564.2021484	0.05
570.3044434	0.02
577.2627563	0.21
586.0211792	2.00
597.8671265	0.15
602.3917847	0.25
604.1254272	4.92
608.6849976	0.28
609.5706177	0.30
612.1802368	0.90
630.2651978	6.05
631.0588379	0.13
648.1326294	1.99
649.3908691	0.12
664.3593140	0.12
666.1499634	9.88
682.8256226	0.03
685.3282471	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	321.1073
Annotation	N-(E-4-coumaroyl)-aspartate
Peak:m/z	Relative Intensity
101.8321838	0.02
113.0185852	0.02
130.1003876	0.08
139.0798340	0.04
146.0091858	0.95
148.0216064	0.25
153.0206909	0.42
173.9810791	7.40
181.9280548	0.02
191.4456482	0.30
192.0874481	1.22
214.9987488	0.02
221.2297668	0.04
225.2215271	0.05
249.3133240	0.07
256.1166992	0.29
256.8130188	3.38
257.4500732	0.05
258.9059143	0.18
262.0619507	0.04
266.2601929	0.08
269.6968689	0.13
275.1605835	24.67
277.2471313	0.14
279.7610474	0.01
284.9616394	2.85
289.3301697	0.13
290.8551025	0.05
300.7283325	0.05
303.0415649	100.00
303.6738586	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	305.0665
Annotation	Leucocyanidin
Peak:m/z	Relative Intensity
92.8300018	0.30
94.8325348	0.25
97.0476532	0.57
101.0305710	0.33
109.0320206	1.01
111.1027145	0.75
112.9877548	0.24
113.9837646	0.15
120.1265869	0.14
121.2314606	0.31
123.1197739	0.51
125.0575104	23.53
135.1927032	0.55
136.9712067	18.39
139.0393372	6.46
143.0770264	0.21
147.0027771	0.35
149.1984863	0.40
150.9507294	1.41
158.9691772	1.15
161.0581360	11.20
163.0939941	0.70
163.9454498	6.31
165.0539703	25.44
165.9345398	0.83
167.0998688	8.27
173.0404968	0.27
175.0275574	1.04
177.1626587	5.55
178.9620667	100.00
179.8412170	0.30
181.1071320	0.53
188.3647614	0.19
189.1130829	0.61
191.0756531	2.05
193.0543518	0.17
197.3379669	0.13
199.0944214	0.94
200.1087646	0.45
201.0917664	2.31
202.0614014	1.11
203.0674133	3.29
204.1107788	4.65
207.1846619	0.26
215.0462036	1.78
217.2559204	3.01
219.1593323	87.57
221.0455627	85.56
223.0046997	0.18
224.9704590	0.36
227.6257629	0.67
228.3648071	0.07
231.1380920	0.41
233.1813049	5.09
236.1534119	0.30
237.2243347	1.42
243.0167542	3.52
245.1114807	1.38
247.1527710	12.29
253.0595703	0.09
258.2124329	0.31
258.9689331	1.01
260.1803589	0.71
261.0966797	40.96
263.0255127	5.17
269.3417358	1.15
275.1878052	0.10
277.0326233	0.40
285.2424927	0.13
286.2508545	2.30
287.1500549	14.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1401
Annotation	Leucocyanidin
Peak:m/z	Relative Intensity
173.1434021	0.02
175.2441101	0.08
176.5124512	0.06
177.1663818	0.12
178.9551697	0.98
180.1673889	0.01
181.2593384	0.02
185.9931488	0.01
187.2734680	0.01
189.0972595	0.02
190.6224060	0.05
191.3747101	0.14
193.1053162	0.00
199.1445618	0.07
200.9842072	0.12
203.0894012	0.40
204.1529236	0.32
204.9555359	0.01
215.0433350	0.02
216.1041260	0.02
217.5033875	0.05
218.2040253	0.01
219.1112213	2.45
219.9816589	0.07
221.1573792	1.56
222.1846466	0.03
224.1200256	0.02
227.1298676	0.02
228.1414490	0.04
233.0260010	0.17
237.1312866	0.01
243.2386017	0.26
245.0894775	0.06
246.1422119	0.01
247.1979065	0.18
255.3738708	0.03
261.2690735	1.09
262.2596130	0.02
263.1542358	0.09
264.4028931	0.01
265.1283569	0.01
269.2752686	0.02
271.4642334	0.01
272.3063660	0.04
273.4130859	0.06
274.3034973	0.07
275.3619995	0.04
286.5227051	0.01
287.2936401	0.33
288.2941895	0.01
293.0302734	0.01
295.2410889	0.02
302.5108948	0.01
303.3388672	0.01
305.1127930	100.00
306.2030334	0.68
307.2277222	0.35
308.4312744	0.03
313.2405396	0.04
315.2298584	0.05
316.1210327	0.17
317.1973267	0.13
318.1380310	0.01
325.3595581	0.03
347.1566162	0.12
359.2519531	0.02
371.3675537	0.02
381.1481323	0.02
383.4611816	0.01
387.3967896	0.01
403.0377197	0.01
423.2412720	0.38
424.3001709	0.73
425.2723999	1.13
426.3784180	0.07
428.6804810	0.04
429.4183350	0.03
430.0896606	0.01
432.3109741	0.02
437.3958740	0.01
441.1728516	0.43
442.1784058	0.58
443.1650391	2.05
443.9484253	0.03
445.5609131	0.01
455.1553955	0.06
460.4384155	0.01
461.5372314	0.02
467.1088867	0.10
471.2861938	0.00
472.3111572	0.01
473.4320068	0.02
481.1863403	0.08
482.9442749	0.07
484.1475830	0.14
485.2073364	0.58
486.1126709	0.05
491.1956787	0.18
504.5215454	0.01
526.9279175	0.02
543.1289673	0.02
549.3608398	0.01
550.3251343	0.05
567.5504150	0.04
577.3641968	0.02
581.7821655	0.04
591.5298462	0.03
592.2350464	0.01
593.1654663	0.35
594.3013306	0.04
601.9277954	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.3122
Annotation	Daechuine S7
Peak:m/z	Relative Intensity
179.3154144	0.07
182.1159668	0.01
216.4050903	0.04
235.1501770	1.91
253.1287842	12.02
273.0281982	0.02
275.6190796	0.04
277.2934570	95.87
319.6490479	0.02
361.3616943	0.09
393.3511353	0.16
462.1550903	0.05
477.3033447	0.09
480.4627075	0.02
495.1144409	0.03
497.4048462	0.03
500.8935547	0.05
505.0856934	0.10
513.1369019	100.00
513.8404541	0.22
523.2910767	0.09
528.4802856	0.08
541.5318604	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	301.0555
Annotation	Fludiazepam
Peak:m/z	Relative Intensity
94.9928284	1.42
96.9515915	0.33
101.0491333	0.10
112.9434357	11.60
113.9995728	3.79
130.9205627	100.00
131.8755188	0.03
137.0189514	0.03
199.0247498	0.96
200.1257019	0.17
214.9841309	0.21
217.0739746	0.02
219.1613464	0.03
241.9601440	0.08
264.0292358	0.11
265.4066772	0.01
272.9750977	0.07
282.1819763	0.39
283.0951538	1.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	324.1816
Annotation	Awajanomycin
Peak:m/z	Relative Intensity
96.8023300	0.22
101.1020050	0.31
128.4552765	0.25
130.0011902	100.00
136.2875214	0.04
146.1631470	0.18
146.8608093	0.31
148.8440552	0.11
154.1206665	0.08
161.9583588	0.11
168.1282349	0.24
181.0307770	0.29
183.0323792	0.31
184.1561737	3.51
184.8679962	0.25
193.1078491	0.83
196.2371826	0.50
198.2270355	0.16
209.1265564	0.60
209.9419556	0.09
218.1178284	0.15
222.0744324	0.08
224.2084656	0.14
229.3097534	0.13
233.8085022	0.24
236.2579956	9.57
243.1583252	0.12
245.1838684	2.03
248.9735413	0.10
250.2262878	0.12
252.1639099	0.18
253.1346130	0.11
255.2462158	0.12
261.1797180	0.14
262.4830933	0.61
263.3109436	0.88
264.1052856	0.32
265.3509521	0.08
267.1386719	0.15
269.0536499	0.28
277.1687012	0.60
278.2302246	0.68
279.1224976	0.33
280.1752319	5.72
281.0572815	0.21
284.1474915	0.13
285.9816895	0.04
286.7984619	0.22
288.0690918	0.20
293.3284302	0.11
297.8890381	0.08
305.1629639	1.37
306.3261414	1.21
309.1115723	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	513.1461
Annotation	Unknow
Peak:m/z	Relative Intensity
157.0476379	0.33
165.1689911	0.06
172.9163971	0.33
175.1464844	1.45
189.0077515	2.10
207.0385284	4.55
215.1988525	0.21
223.1949615	0.14
228.0628967	0.17
231.0554199	0.10
238.3292847	0.09
240.4459991	0.11
243.2303162	0.07
244.7170715	0.05
249.1433258	1.91
254.0262299	0.25
287.7383423	0.10
289.1332397	0.10
291.0714111	0.15
304.2937012	0.18
315.2615356	0.30
317.1229248	0.83
321.1423950	12.19
331.1162109	4.80
332.1646118	1.80
337.2080078	0.35
338.0667725	0.05
339.1560059	1.01
343.9676514	0.24
345.4797974	0.12
348.8247681	0.60
351.0710449	0.14
359.2870483	0.26
361.2204590	0.10
362.6678467	0.20
363.3395996	0.67
366.2667236	0.08
375.1290894	1.38
377.2073364	0.33
381.1953735	20.23
382.1924438	0.09
383.3883057	0.75
384.3242798	0.23
391.2528076	0.23
393.1715698	1.01
398.3862305	0.13
403.0900269	1.37
411.2664795	0.68
421.1447754	1.39
422.7496338	0.87
423.5492554	0.09
435.1466064	13.42
435.7757568	0.09
441.3608398	0.09
444.7816162	0.22
453.1807861	100.00
463.1086426	0.15
467.0511475	0.62
469.4942627	0.31
471.2828369	8.70
477.1107178	0.12
478.6956177	0.10
481.1979370	0.27
494.9767456	1.21
499.0036621	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	765.2301
Annotation	Unknow
Peak:m/z	Relative Intensity
227.4311829	0.07
242.9555817	0.04
245.1736908	0.48
247.4203186	0.03
249.2988281	0.19
261.1588440	0.17
263.4719849	0.16
265.1378784	0.44
271.1775513	0.11
280.7216797	0.04
283.2228088	1.33
287.2879944	0.16
291.0899048	0.05
305.3475647	0.14
307.1557617	5.24
308.2308655	0.12
323.3072815	0.23
325.2124634	0.06
326.2846375	0.23
327.3377686	0.04
329.4009094	0.04
337.0979004	0.12
339.2391968	0.09
341.1487732	0.14
349.3661804	0.07
367.5509033	0.08
377.2899780	0.24
379.2379150	1.27
393.0197144	0.10
397.2769165	0.72
403.1250000	0.17
405.1804199	0.07
415.3985596	0.29
422.1681519	0.78
423.1269531	0.18
439.2514038	0.64
440.0734253	0.18
440.9872437	0.04
447.2038574	0.06
449.2491455	0.30
457.3118286	0.05
457.9814453	0.15
459.0929565	0.18
463.2820435	0.06
467.3313599	0.23
472.1708984	0.10
472.9762573	0.13
475.3213501	0.19
483.4543457	0.06
491.3872681	0.39
493.3013306	0.12
499.3508301	0.25
500.1557007	0.09
501.4270630	0.03
509.5353394	0.10
511.3769531	0.36
513.0964355	0.13
514.9389038	0.05
527.0540771	0.12
528.1708374	0.07
529.2605591	0.14
541.2787476	0.06
543.2501831	0.23
547.4098511	0.40
553.3531494	0.62
554.2399902	1.23
555.3496704	1.50
559.1640015	0.15
565.7795410	0.08
571.2411499	1.06
572.2772827	1.89
573.1861572	0.64
574.3289795	0.07
575.1931152	0.05
589.4849243	0.10
590.1307373	0.16
591.2594604	0.40
596.1757202	0.08
597.3984985	0.38
601.7697144	0.52
610.1416626	0.07
611.8707275	0.04
613.3865967	0.40
615.2381592	0.96
617.2896118	0.03
618.1253052	0.05
619.2244263	0.61
620.0837402	0.51
625.4385376	0.46
626.3059692	0.13
627.4115601	0.17
631.3342896	1.70
632.2609253	7.24
633.2677002	1.73
638.3707886	0.21
643.2847290	0.33
644.2089844	0.64
645.4569702	0.14
648.1381836	0.18
661.3853149	1.19
662.4370117	0.24
663.2195435	0.10
665.9590454	0.14
666.9606323	0.32
668.2791138	0.04
675.3650513	0.14
679.2941284	0.24
685.0238647	0.35
686.4265747	3.76
687.3258667	2.47
692.6386719	0.04
703.1661377	2.08
704.2974854	17.74
705.3060913	100.00
706.3858032	0.30
721.7518921	0.25
723.3661499	50.62
724.5375366	0.35
728.7371216	0.09
730.9192505	0.08
745.9983521	0.37
747.3029175	7.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.1141
Annotation	Luteolin 7-(2''-glucosyllactate)
Peak:m/z	Relative Intensity
151.2506714	0.04
156.9937286	0.08
159.9298401	0.07
168.0441742	0.02
191.9451447	0.02
193.3657532	0.02
194.1771545	0.03
199.9671478	0.02
204.3503571	0.03
206.1274109	0.05
214.3259277	0.01
218.1507721	0.03
219.0348511	0.02
225.9796295	0.02
229.3072815	0.04
230.2328033	0.06
232.3284149	0.03
233.2025757	0.03
239.0458069	0.05
242.2096405	0.01
243.2835999	0.08
246.9433899	0.01
253.4452057	0.04
254.3128662	0.20
255.4756165	0.11
256.5739136	0.04
257.3017578	0.14
259.0756226	0.03
261.2831421	0.06
263.0153809	0.04
266.4190063	0.01
267.3451538	0.03
267.9758301	0.06
269.0979309	0.21
270.4088745	0.12
271.1979980	0.91
272.2079468	0.22
273.0686035	0.03
280.0149841	0.03
280.9813232	0.01
282.2042236	0.05
283.3139648	0.05
284.2434692	0.19
285.0502930	0.52
286.0891113	0.08
287.2310181	0.37
293.2616272	0.04
295.1440735	0.02
296.4068909	0.03
297.2836914	0.03
299.0761719	7.27
300.0716553	6.47
301.0938110	0.19
306.2354126	0.07
307.1901855	0.05
308.4724731	0.04
311.1527100	0.07
312.6780396	0.25
314.0927734	9.23
315.0975342	100.00
316.2702026	0.10
320.3580933	0.12
321.1761475	0.04
322.3483887	0.03
324.2941284	0.02
327.0073853	0.27
328.1175537	0.07
329.2078247	0.16
333.2262573	0.02
335.2879028	0.04
337.3149414	0.13
338.1652832	0.09
339.3377075	0.08
340.4348145	0.02
341.1345215	0.01
342.0288086	1.00
343.2026367	0.09
344.4000854	0.06
349.1423950	0.02
353.2241821	0.01
354.3144531	0.01
355.2956543	0.26
356.3627930	0.79
357.2698975	2.44
358.2750244	0.08
359.1276245	0.02
363.2121582	0.01
371.2810059	0.04
372.2820435	0.04
373.2993774	0.05
378.3853760	0.01
380.9537964	0.07
385.4567871	0.01
387.2388306	0.35
389.2984009	0.07
393.5946045	0.11
396.4130859	0.15
399.0573120	0.03
405.2410889	0.04
407.2755737	0.03
407.9151611	0.07
411.3139038	0.02
412.3963623	0.01
413.5282593	0.02
415.3237915	0.14
417.2410278	0.03
423.2692871	0.28
425.2637329	0.18
431.3564453	0.03
432.3251343	0.06
433.3189087	0.05
437.1467896	0.03
443.5371094	0.04
445.1103516	0.12
449.2722168	0.02
450.4043579	0.02
455.4140015	0.02
456.3767700	0.13
457.0929565	0.04
459.1358032	2.39
459.8466187	0.01
461.3409424	0.03
462.1893921	0.02
464.6854248	0.08
465.3686523	0.02
470.4703369	0.05
471.5563354	0.06
472.2560425	0.32
475.4179077	0.15
477.1069336	0.30
480.1625977	0.04
481.3250122	0.09
482.1712036	0.16
483.2686157	0.22
484.0383301	0.05
487.0824585	0.08
488.2611694	0.15
491.2158813	4.37
492.3386841	0.09
498.0650635	0.14
499.3888550	0.02
500.2647095	0.47
501.3847046	0.29
502.2728271	0.08
504.2011108	0.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	223.05
Annotation	Nifuradene
Peak:m/z	Relative Intensity
70.8152695	0.06
84.9400330	8.85
86.7740631	0.09
94.9318543	0.14
96.7611694	0.05
101.0496063	0.10
110.9712372	9.99
125.0547638	0.48
128.9694824	1.75
132.3897247	0.09
135.1854401	0.08
146.9465942	0.07
161.1456604	0.17
173.0768127	0.34
179.0696869	0.17
187.1259918	2.54
194.8137970	0.12
205.0025482	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	242
Annotation	Unknow
Peak:m/z	Relative Intensity
88.0251160	0.63
151.9537811	0.26
155.9966583	0.16
158.9803925	0.35
182.8930206	78.13
196.0555115	35.21
196.9795532	0.49
197.9439850	3.87
198.7684784	1.08
200.3449249	12.68
200.9956512	100.00
202.8029022	0.26
214.0106201	13.27
216.3426666	0.15
218.8364563	15.37
219.7078247	1.25
223.9991150	20.60
224.7325287	0.29
231.6271210	1.52
241.9829254	6.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2622
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
140.0962219	0.12
143.9380493	0.17
152.9526215	0.37
154.0032959	0.08
164.9861755	0.08
184.4195251	0.14
189.0502014	0.15
195.9972229	0.03
205.0219116	0.04
207.2539978	0.13
214.1086884	2.17
215.3598785	0.13
223.8921356	0.06
233.1413879	0.43
255.3186340	0.15
257.4431152	0.21
259.3129883	0.12
273.0898743	0.16
275.3284912	0.34
277.2861023	100.00
278.2699280	33.59
278.8738403	0.20
301.5572815	0.05
305.0689697	0.09
327.3811035	0.15
332.7210083	0.22
333.3627319	0.13
349.4089355	0.08
369.0116577	0.08
379.3129578	0.03
385.2070007	0.08
387.5200500	0.05
389.4152527	0.23
399.4267578	0.05
413.2919617	0.18
416.9859314	0.25
429.3586426	0.53
430.5248108	0.55
431.3954468	0.52
432.0919189	0.08
437.2044373	0.12
439.2788391	0.39
440.1986694	0.10
457.3002014	0.69
458.3988953	0.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.0936
Annotation	5,4'-Dihydroxy-3,3'-dimethoxy-6,7-methylenedioxyflavone 4'-glucuronide
Peak:m/z	Relative Intensity
187.1479645	0.12
194.9392700	0.06
206.9234161	0.01
234.2744598	0.06
259.1727295	0.02
263.7111816	0.05
275.0582886	0.04
277.1694336	0.04
285.1716003	0.16
285.9624023	0.22
287.1712036	0.04
291.2266846	0.05
293.3798828	0.21
300.1656494	0.14
304.2395630	0.05
305.2530518	0.10
307.3711548	0.06
308.3665161	0.04
311.4127197	0.02
316.2123413	0.06
321.1939697	0.09
325.3795776	0.04
326.4671021	0.08
327.2587280	0.02
334.8709106	0.02
335.5410767	0.13
352.4600220	0.02
353.3787231	0.03
369.5260620	0.24
370.3167114	0.06
371.2366943	0.34
385.3470459	0.04
387.4268188	0.09
407.8422241	0.10
427.3085938	0.08
429.7299194	0.08
433.4918213	0.07
435.2272949	0.06
437.3729248	0.09
442.9824829	0.37
446.2923584	0.38
447.2853394	0.04
448.3937988	0.03
453.6348267	0.03
454.9395142	0.02
470.5820312	0.11
471.2817383	0.07
472.4325562	0.02
473.2889404	0.09
477.2011108	0.09
486.0552979	0.24
487.2440186	0.54
489.1876221	100.00
490.0770874	0.03
491.4487305	0.02
494.3039551	0.03
495.0443726	0.11
496.1820679	0.39
497.2232666	0.20
501.4011230	0.07
505.1845093	0.03
509.9686890	0.10
514.3022461	0.28
515.4265747	0.65
536.3128662	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	759.1738
Annotation	Monepalin B
Peak:m/z	Relative Intensity
281.1794434	0.34
327.2896729	0.77
329.2608643	0.18
361.1307068	0.53
364.7363281	0.34
369.1989746	0.64
429.8558350	0.07
434.4099731	0.29
447.6091309	0.08
467.1850586	0.13
472.7222900	0.24
493.4655762	0.09
494.9440918	0.30
503.3568115	0.09
507.3951416	0.28
511.2585449	100.00
531.0926514	0.12
535.2029419	0.14
536.4545288	0.05
553.2898560	4.74
573.3026733	0.69
577.2984619	0.23
577.9523315	0.38
581.3804321	0.79
589.5839233	0.26
600.9632568	0.07
619.3657837	0.27
627.4384155	0.46
637.6242676	0.12
656.3292236	0.31
679.3155518	0.14
687.1373901	0.23
697.2916260	0.12
708.3534546	0.20
711.5426636	0.12
714.6177368	0.05
715.4722900	0.24
723.0301514	1.52
723.7523804	0.30
726.2276611	0.07
737.3497925	0.47
741.1580811	5.88
741.8115234	0.12
742.5247192	0.31
758.5705566	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.2917
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
146.8850708	0.09
149.8424988	0.31
151.0080261	0.17
155.1539307	0.31
165.1401062	0.04
179.2640991	0.10
181.1520233	0.05
195.2533264	0.08
197.1381531	0.06
197.9586945	0.08
216.0432129	0.86
221.0559998	0.17
235.1417236	0.04
241.1480103	0.06
245.1981506	0.58
255.0649414	0.06
263.2003479	2.91
289.3783875	0.11
295.9597168	0.17
303.2596436	0.14
304.3926392	0.12
306.4727783	0.65
308.0549927	0.21
319.2578125	0.51
322.3649292	0.34
328.3578491	0.10
337.3093872	47.88
342.0820007	0.14
347.4742126	0.38
355.1237793	0.13
379.0114746	0.25
380.8645325	0.33
397.2154236	0.14
411.2043152	0.46
417.1860046	5.76
418.4821472	0.03
433.3862915	0.16
435.7723083	0.16
442.3518982	0.34
447.0982971	0.18
460.2250366	100.00
461.3246765	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.0475
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
159.2936249	0.07
193.1071625	0.03
211.0751648	2.40
211.7390900	0.01
223.0681458	0.05
241.0658264	1.09
259.2802734	0.27
273.2771912	0.03
280.1852417	0.92
281.1436768	0.19
305.0460815	0.09
321.1589966	0.62
323.0704346	100.00
324.1511841	11.45
325.0021362	0.04
385.1182861	1.45
386.1426392	0.18
387.2982178	0.03
391.0009766	0.41
391.8345337	0.04
403.1128540	1.94
404.1648560	0.32
467.1091919	0.28
468.2310181	0.02
469.2269897	0.12
481.2268066	0.02
520.0953979	0.03
522.3043213	0.08
547.2518311	0.50
548.0444946	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	583.2971
Annotation	Unknow
Peak:m/z	Relative Intensity
201.3324127	0.19
212.9738007	0.64
241.3778229	0.26
263.2760620	0.25
289.1400757	0.13
291.2891846	0.14
293.4794312	0.15
294.9775391	0.06
329.2276001	0.10
331.1404419	0.19
333.4188843	0.18
337.2300415	0.07
343.4080811	0.41
359.5138550	0.31
361.3716431	25.80
362.2255859	0.29
375.3516846	0.59
377.8034668	0.23
385.2990723	0.82
403.2769775	2.94
404.3504639	0.25
419.4073486	0.19
421.3361816	7.99
427.5216064	0.24
441.6267090	0.48
450.2752686	0.33
451.4562378	1.09
467.6588135	0.21
487.5447388	0.48
492.9459839	0.15
505.2723999	0.95
521.8041382	0.25
523.4038696	32.27
524.4559937	0.75
535.4025269	0.14
536.3525391	0.16
537.3886719	4.98
539.5068970	0.06
547.4385376	4.10
548.4113770	0.42
553.1733398	0.72
560.5213013	1.13
563.6636353	0.23
565.3623657	100.00
566.4834595	2.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.1845
Annotation	Neobritannilactone A
Peak:m/z	Relative Intensity
91.0804367	0.02
94.9625168	0.02
95.7403870	0.03
96.7202148	0.04
100.7469330	0.03
108.9030609	0.10
110.8864746	0.02
114.7741013	0.02
120.9437714	0.05
125.0977402	0.01
131.0319214	0.05
133.1719055	0.02
134.9825439	0.10
135.9593658	0.05
137.0148315	0.03
139.2651367	0.05
140.7946625	0.14
143.1491241	0.09
144.3648376	0.05
145.0985718	0.04
153.1960754	0.12
155.2044067	0.10
156.8068237	0.04
162.8499298	0.02
165.0932617	0.02
167.0881500	0.09
168.1685791	0.02
169.2008057	0.08
171.0237885	0.03
175.1067810	0.03
175.9592438	0.03
176.9015503	0.04
181.0184937	0.16
183.3529358	0.03
184.7720642	0.09
187.3669128	0.02
189.2362061	0.04
191.2257080	0.14
193.0245667	0.01
195.3243408	0.05
196.8775177	0.10
199.1767273	0.16
201.1900024	0.03
204.5454102	0.14
205.2837524	0.06
209.2053528	0.32
210.5162048	0.06
211.2290039	0.09
213.2352600	0.18
214.1959229	0.09
219.2413940	0.12
223.0385132	0.03
225.2875671	0.18
231.2004089	0.05
235.0734863	0.12
237.0454407	16.62
238.9433594	0.25
241.0944824	0.03
242.8838196	0.08
246.0380554	0.02
247.1836243	0.05
248.2380371	0.06
250.2485352	0.11
251.2216187	0.22
252.0917358	0.08
253.1850586	0.90
255.0929260	30.61
260.0933228	0.05
265.2090759	0.66
265.9540405	0.05
267.2290344	0.07
269.1005859	0.02
269.9356689	0.15
273.3245239	0.11
275.1711731	1.81
276.1349487	0.16
277.3859558	0.14
283.2593384	0.25
293.1632690	100.00
294.1618652	0.09
296.2961121	0.16
302.3818665	0.79
311.1082153	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	540.3368
Annotation	Isariin D
Peak:m/z	Relative Intensity
170.1631927	0.25
176.9720612	0.17
179.0315552	0.09
183.2353821	0.13
193.1756287	0.33
209.6191101	0.68
210.2495575	2.98
210.8862305	0.11
213.2856598	0.21
215.5492401	0.05
221.2103882	0.24
228.2636566	9.68
244.0048676	0.12
246.3012238	40.29
247.0338440	0.06
252.1482086	0.29
260.2027588	0.12
270.3085022	1.00
272.4429932	0.17
274.2744141	0.17
288.1974792	6.14
292.2371216	0.09
294.5781555	1.00
297.4191895	0.38
306.2545166	0.93
312.3914795	1.24
317.2295532	0.04
318.3344727	0.38
319.4846191	0.39
324.3679810	4.89
326.3998413	0.28
330.5532837	0.20
336.3459473	1.59
342.3563232	6.51
354.2904663	3.19
356.6665649	0.18
360.2990112	0.85
360.9311523	0.34
367.2938843	0.14
369.2272339	0.10
370.4481201	0.06
371.7364502	0.30
372.4140625	9.36
375.1331177	0.31
378.4226685	15.72
380.2994385	0.23
385.2996216	0.21
386.2939453	0.23
387.2830200	0.64
390.2903442	4.02
390.9272461	0.02
394.5867310	0.10
397.0169067	0.12
401.0502930	0.06
402.3062744	0.05
408.3270264	100.00
408.9521484	0.42
414.7014771	0.35
417.2562256	0.12
418.2867432	0.22
419.4274292	0.75
420.3839722	0.80
426.6693115	0.33
427.7583008	0.16
432.6353760	0.49
437.3652344	0.33
440.4250488	0.21
444.2807617	0.10
450.3946533	6.54
456.2847290	0.46
463.4128418	0.61
468.5753174	0.56
474.8333130	0.22
486.4273682	4.71
494.1564331	0.44
495.2411499	0.20
504.3344116	7.98
505.1019897	0.07
505.9605713	0.04
518.2200317	0.55
520.0299683	0.65
522.3054810	9.25
523.5217285	0.43
532.2811279	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	382.1003
Annotation	Succinyladenosine
Peak:m/z	Relative Intensity
114.9549408	5.21
127.9888000	0.35
132.9276123	0.08
134.0450439	16.85
160.2334595	0.10
162.0712891	1.27
164.0482483	0.06
165.0942688	0.25
178.8494263	0.13
183.5106506	0.15
188.0983276	1.04
201.4390564	0.24
202.1381836	0.24
206.0314636	100.00
219.2862854	0.22
220.0965424	0.08
221.2671509	0.07
231.0075684	0.06
232.0545959	3.53
237.8803406	0.17
248.0074158	0.41
250.1737061	27.34
256.1682739	0.12
257.3321228	0.18
266.1567688	13.35
267.0107117	0.44
271.7843933	0.12
275.1069336	0.13
276.4797974	0.24
278.2034912	0.16
291.8494873	0.10
293.2667847	0.36
296.1435852	0.13
296.8714600	0.18
307.3756104	0.16
319.1368103	0.33
319.9262085	0.06
325.9078674	0.22
336.1682434	0.40
338.0897217	1.16
345.9629211	0.07
354.2451782	0.29
363.1504822	1.20
364.2401428	3.05
365.2252197	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.0931
Annotation	5-(3',4',5'-Trihydroxyphenyl)-gamma-valerolactone-4'-O-glucuronide
Peak:m/z	Relative Intensity
122.9779892	0.26
128.8677673	13.16
133.0608826	0.12
136.9819641	0.17
147.4557343	0.31
149.3486633	0.18
152.0428619	0.08
160.9069061	2.44
173.0836029	0.15
174.1471558	0.17
177.7636871	0.09
178.9271545	0.18
187.0708618	3.76
190.9766846	6.64
192.0080566	0.07
193.1101532	1.68
195.1925507	0.12
196.9629211	0.22
201.1620483	0.26
205.0642395	100.00
223.1090088	63.42
224.2610474	0.14
227.0206299	0.12
244.9808655	0.16
253.2131348	0.16
254.6321411	0.14
255.2657776	0.34
261.1230774	0.83
262.9389954	0.08
269.2907715	0.28
278.0947266	0.13
294.2065125	0.11
295.0305481	0.20
298.1784058	0.07
300.9722290	0.26
303.5666504	0.10
305.0959778	0.18
308.0410156	0.23
314.1737671	0.64
315.1769409	0.09
318.7283325	0.16
320.1023254	0.54
323.2728271	0.92
324.3870239	0.30
326.9172974	0.08
327.9551392	0.30
333.6054077	0.19
334.6397705	0.12
337.3348083	0.80
341.4384766	0.16
352.2497864	0.19
353.1440735	1.50
354.2185974	0.46
355.1407166	0.53
357.2585144	0.19
360.1633606	0.14
361.5015564	0.40
362.4404297	0.80
363.2168884	1.03
363.9045105	0.23
365.5958557	0.14
371.3352356	0.30
380.8762512	6.28
381.6889343	0.12
383.2119446	0.71
384.1780701	0.27
385.1350708	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	514.26
Annotation	DAMGO
Peak:m/z	Relative Intensity
146.0771484	0.03
148.1270752	0.03
158.0345764	0.03
164.9862671	0.01
169.1098022	0.02
173.0839691	0.04
174.9981079	0.08
203.2131958	0.07
217.2185364	0.03
227.2904510	0.02
235.1348877	0.01
248.2884521	0.05
260.2868042	0.07
268.2229004	0.03
274.2276001	0.02
277.2706299	0.02
278.2848816	0.58
280.4213867	0.04
286.2672729	0.27
287.4020386	0.01
291.2661133	0.04
298.2761841	0.18
300.2365112	0.09
300.9849854	0.01
304.3961792	0.01
314.7262573	0.03
316.1682129	0.25
317.3986816	0.05
319.9883423	0.01
320.7437134	0.02
334.3169556	1.33
339.1726074	0.06
348.3481445	0.03
350.3973999	0.06
352.2870483	100.00
353.1398926	0.04
364.1140137	0.04
376.2280884	0.67
382.3192749	0.02
383.8905640	0.04
385.1415405	0.11
386.1336670	0.04
394.1860352	1.06
399.4188843	0.16
400.3378906	0.04
406.1193237	0.04
407.0220947	0.03
411.2509155	0.01
417.4445190	0.10
418.3170776	0.37
430.5614624	0.04
436.2999268	0.05
438.2506714	0.05
440.1749878	0.08
442.4154053	0.06
443.3594971	0.05
448.6656494	0.06
453.6159058	0.02
455.1641846	0.05
460.4294434	0.35
466.3439941	0.02
473.0017700	0.12
475.5709229	0.05
477.3069458	0.04
478.4297485	2.26
481.7338257	0.19
486.5632324	0.03
495.1678467	0.04
496.3833618	1.78
504.8185425	0.04
514.1403198	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.0989
Annotation	Quercetin 3-(6''-ethylglucuronide)
Peak:m/z	Relative Intensity
148.8656616	0.02
150.9824524	0.90
152.0310822	0.18
153.0890808	0.05
159.1477966	0.03
162.9986115	0.06
169.0203247	0.08
170.9568024	0.07
173.9288635	0.02
175.0939026	0.04
178.9879761	1.64
180.0589905	0.17
181.0122223	0.03
185.2332458	0.05
186.8993988	0.06
188.2164154	0.01
189.2176361	0.11
190.1915894	0.17
191.2065430	0.04
192.1484528	0.03
193.1225891	0.12
197.1006165	0.05
198.0718536	0.07
201.2128906	0.02
203.2255249	0.06
205.1449890	0.01
207.0736389	0.08
209.0337524	0.12
211.0005188	0.04
212.0895996	0.01
212.9640808	0.04
214.1407776	0.14
217.0686951	0.05
218.0663452	0.04
219.0082245	0.01
226.9821930	0.06
229.1294250	0.17
230.0701752	0.08
231.2453613	0.02
232.5061035	0.02
233.1825256	0.11
233.9145813	0.02
237.1618805	0.02
239.1926270	0.09
240.0315399	0.08
241.0925140	0.09
243.0654297	0.02
245.2933807	0.08
247.1182709	0.03
247.9168854	0.02
253.0861816	0.01
254.1465149	0.10
255.1877747	0.99
256.1244507	0.22
257.0997009	0.30
258.1609497	0.07
269.0837097	0.03
271.1237793	0.74
272.1263428	0.24
273.1098328	0.45
274.1195374	0.08
275.0941467	0.02
281.3457642	0.03
282.5067749	0.09
283.1900635	0.56
284.2281494	0.11
294.8921509	0.02
296.9953613	0.14
298.1362305	0.06
300.0987549	34.90
301.1118164	100.00
302.1826172	18.02
303.1639404	0.08
310.9749451	0.02
312.0982971	0.03
313.1851501	0.48
314.0039062	0.04
315.2535400	0.06
323.3046265	0.01
325.0654297	0.11
325.9474792	0.07
335.1904297	0.03
337.2230225	0.01
337.9492188	0.02
339.1521301	0.03
343.1963501	1.98
344.1392212	0.40
351.2265625	0.04
353.1635132	0.23
355.1866150	0.05
356.1110535	0.06
359.1643066	0.03
361.1082153	0.01
367.2777405	0.09
368.3227844	0.04
369.2773438	0.06
370.4414062	0.04
373.3071899	0.16
378.9366455	0.15
380.1718140	0.01
383.2782593	0.02
385.1510315	0.15
395.2017517	0.15
396.1427002	0.05
402.4809570	0.01
409.1875000	0.11
419.0281677	0.01
427.1367493	0.13
428.3034363	0.08
445.1848755	4.17
446.1199341	0.76
461.3072815	0.04
463.1393127	20.45
464.2029114	5.89
469.3031616	0.05
487.2335510	0.57
488.0122681	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	346.0946
Annotation	p-Hydroxybenzyldesulphoglucosinolate
Peak:m/z	Relative Intensity
115.9287567	0.03
120.7923737	0.08
121.9514236	0.63
129.0977783	0.02
137.9373627	0.12
152.0544434	0.09
165.2026367	0.01
165.9113617	0.06
182.8737335	0.01
183.9551849	0.14
193.0204773	1.75
195.0420074	0.09
197.0036469	0.15
207.1322937	0.96
210.0960999	0.05
216.9621277	0.04
223.5279541	0.01
225.0072327	100.00
231.1994629	0.08
231.9505310	0.02
246.0887146	0.06
256.4151306	0.03
265.8310547	0.04
270.1105652	0.03
271.1584473	0.06
283.4066772	0.05
286.0853882	0.02
287.2156677	0.06
298.1889343	0.56
310.1858215	0.44
328.0850830	68.81
336.9622803	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	342.1345
Annotation	N-cis-Feruloyldopamine
Peak:m/z	Relative Intensity
123.1765137	0.03
127.6661682	0.03
134.0615997	0.02
136.8508911	0.13
143.9497681	0.03
147.0656128	0.06
148.8545532	0.04
150.9176331	0.02
158.2262573	0.07
161.5173035	0.04
164.8900757	0.24
165.5244141	0.02
179.1620789	0.08
183.0380402	0.03
185.6757202	0.03
191.0980530	0.02
193.1485443	0.06
194.3208313	0.03
199.0952301	0.16
202.0682983	0.05
205.2337799	0.10
206.7986145	0.07
208.1689453	0.56
213.3213501	0.06
223.9020691	0.03
227.0107422	0.17
228.1910400	0.04
229.1665955	0.02
230.0514526	0.05
235.9852905	0.07
237.4446716	0.04
242.9134827	0.06
244.4289551	0.04
245.9551697	0.10
251.7711792	0.03
253.6871643	0.03
261.9816895	0.03
269.3709106	0.04
271.1687012	0.06
279.4946594	0.14
280.4221191	0.24
281.9961548	0.05
284.8791199	0.07
296.2354736	0.01
297.2096558	0.23
298.1697388	0.50
299.1447144	0.04
300.3269653	0.16
301.9900513	0.04
303.8593750	0.05
305.4205017	0.18
306.0970459	0.47
307.1074829	0.08
312.4255371	0.05
314.1885986	0.02
323.4030457	1.00
324.1641235	0.68
325.1242981	0.12
327.2015686	100.00
328.2455139	0.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	373.1503
Annotation	Deoxyloganin
Peak:m/z	Relative Intensity
106.9174271	0.11
112.9455566	2.24
117.0909958	0.14
118.9807739	2.93
130.9891968	1.58
132.9868164	0.54
143.0537109	1.41
147.2956543	0.07
149.0167847	100.00
151.1504822	0.38
161.1281738	0.74
164.1498108	0.27
167.1833801	0.40
191.0190430	0.18
192.9290161	0.43
195.2824402	0.90
196.0442047	0.41
202.8269958	0.14
207.1146851	0.29
211.0417938	1.69
223.2413330	0.19
236.9794006	0.17
273.1935730	1.22
298.3867188	0.10
305.0136719	0.33
311.2194519	0.56
327.3497925	0.77
329.4826660	0.74
355.3252869	20.93
358.2757263	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
131.1251526	0.96
139.2185211	0.49
156.7321167	0.21
173.3199158	0.48
183.0753784	0.36
185.0033569	1.69
187.1114197	0.53
188.9503174	0.14
196.796936	0.43
199.1924133	0.16
200.955307	1.07
203.2000122	0.48
208.9337616	0.24
211.2353363	0.16
213.38974	0.36
215.0261536	1.56
217.2555542	0.28
229.1611328	1.00
231.0187073	0.23
243.0754089	2.35
245.2592163	0.51
251.0689087	0.15
255.2033691	1.12
257.2122192	1.04
259.2456665	0.51
263.4309082	1.25
269.2818298	1.42
271.1218872	5.07
273.2910156	0.93
277.2155762	0.45
283.263916	1.53
285.2545776	6.74
287.3255005	1.40
292.920105	0.52
295.2279053	2.91
297.366272	16.09
299.1828308	2.66
301.1785278	1.18
309.1976318	0.40
311.2580566	1.61
313.2874146	2.49
314.2191772	0.47
315.2407532	2.15
316.1489868	0.73
321.5820923	1.94
323.3288879	16.93
325.4866333	0.43
327.3711853	0.29
329.1387939	0.54
335.480072	0.25
339.2532654	100.00
339.9377136	0.38
341.2995911	11.02
342.2054138	0.36
350.5594482	0.84
357.6928711	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	639.1562
Annotation	Nervilifordin C
Peak:m/z	Relative Intensity
183.1793671	0.04
183.9803772	0.01
185.1314392	0.01
188.1391602	0.02
198.1125793	0.02
199.1284180	0.02
200.1596069	0.02
201.1544189	0.03
202.2520447	0.03
205.2036743	0.02
211.1216583	0.06
213.0367432	0.03
214.0103149	0.02
215.0878601	0.04
216.0887756	0.08
217.3293915	0.03
218.0246429	0.02
221.2060242	0.02
227.1271820	0.25
228.1558228	0.06
229.2506104	0.03
233.2660828	0.05
238.8745880	0.01
242.3856201	0.06
243.0641174	0.48
244.1309814	0.17
245.1482391	0.02
253.2978821	0.01
254.2569733	0.23
255.1094666	2.13
256.1951904	0.39
257.0578613	0.02
258.1394043	0.02
259.1877441	0.01
260.1823120	0.05
263.0851746	0.01
268.9288635	0.02
271.1041870	3.62
272.2233276	1.20
273.1244812	0.02
283.2672424	0.15
283.9293823	0.05
285.1753845	0.04
287.4101562	0.12
288.1234131	0.06
291.2198792	0.01
298.3422241	0.03
300.0975952	37.07
301.1901245	5.91
302.2460022	0.01
310.2950439	0.03
313.2717896	0.17
315.1398010	100.00
316.1031799	14.06
317.3011475	0.01
326.2516174	0.01
329.0551758	0.07
331.1817627	0.05
332.9190063	0.02
335.4097290	0.02
341.0516357	0.01
342.2632446	0.01
343.2393188	0.04
357.1753540	0.15
358.2465210	0.07
363.3508911	0.01
393.0748901	0.04
397.1751099	0.02
405.9959106	0.02
421.3710938	0.01
431.8805542	0.06
438.5689087	0.01
444.1647339	0.02
446.3160400	0.01
447.6715698	0.01
459.4004517	0.01
463.2480469	0.06
469.1876831	0.01
477.4642334	0.07
495.0780640	0.06
508.3375854	0.02
549.5910645	0.06
567.7070923	0.04
579.3544922	0.02
593.2951660	0.07
595.4011841	0.02
596.3427124	0.50
597.0526733	0.04
603.2843628	0.04
604.1223755	0.02
607.1667480	0.07
608.3592529	0.07
609.5720825	0.01
611.2998657	0.27
612.2910767	0.17
619.2395020	0.06
621.3701782	0.17
622.5961914	0.05
624.4635620	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	298.13
Annotation	Duloxetine
Peak:m/z	Relative Intensity
89.9254761	0.12
105.2256851	0.35
110.8630905	0.15
117.8594055	0.14
129.9999695	5.07
145.1457825	0.53
147.0524597	100.00
152.0835876	2.28
159.1676331	0.29
161.4498291	0.12
162.8434448	0.89
168.8707123	0.08
173.9741211	0.15
180.6791534	0.47
188.1697693	0.20
196.2514648	0.17
198.4822388	0.19
199.1133423	0.99
207.4919434	0.82
208.1004944	7.98
208.7332764	0.17
233.9835815	0.21
235.5634460	0.23
238.8273926	0.43
251.3514404	0.25
252.1160889	0.59
253.3457642	1.15
256.9331055	0.27
262.7963257	0.63
270.3062134	0.29
279.4851990	0.91
280.2016907	2.41
280.9046326	0.73
282.2416992	3.10
289.0600891	24.65
299.7263489	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0196
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
57.0862312	0.07
85.0041351	0.33
86.9592743	1.03
110.8879242	100.00
126.8631287	0.10
129.0171051	2.37
130.9165955	1.16
146.9471741	0.39
154.9567108	0.22
172.9730530	21.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	227.9823
Annotation	Unknow
Peak:m/z	Relative Intensity
81.2585602	0.07
113.2594452	0.03
121.1286316	0.06
129.0195007	0.25
133.1226501	0.06
135.2778473	0.12
143.8819275	0.03
154.3247681	0.11
170.9967041	0.17
182.0120850	0.03
186.9417267	100.00
191.2104950	0.28
192.1118317	0.17
200.1210785	0.32
204.1949921	0.23
204.7955322	0.82
207.3354187	0.36
209.0200195	0.84
210.0750885	0.98
211.1030121	0.21
227.7049103	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.1584
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
219.2404480	0.02
225.1460571	0.04
227.8896179	0.01
229.4281311	0.18
236.4216461	0.05
237.0716553	0.03
247.2076721	0.12
251.1504822	0.02
254.2035828	0.12
255.4193420	0.17
257.1561279	0.05
267.0892639	0.02
268.7923279	0.03
272.6149292	0.15
273.3870239	0.13
275.2716370	0.04
287.2012939	4.39
303.1253662	100.00
308.9997559	0.31
316.9879150	0.16
329.2472534	0.12
345.1899414	0.38
369.0534668	0.04
394.8950806	0.07
398.7695923	0.07
413.3637085	0.08
429.0522461	0.01
431.2681274	0.21
441.1068726	0.06
446.0941772	0.02
447.2269287	0.61
448.9249878	6.38
449.6682129	0.01
455.3596191	0.03
459.1042480	0.07
463.6000366	0.08
464.9766235	40.37
465.6936646	0.27
473.2763062	0.10
489.0910034	0.05
539.0463257	0.03
540.0303955	0.03
543.5695190	0.07
551.0516357	0.03
557.3438110	0.24
575.1522827	0.29
593.1917114	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	388.1228
Annotation	Isoferulic acid 3-O-glucuronide
Peak:m/z	Relative Intensity
115.1262970	0.03
132.1255493	0.32
151.5825806	0.14
160.8016663	0.11
185.1032715	0.20
202.8515320	0.35
206.6138000	0.12
207.2543182	0.11
207.9882202	0.33
209.0973816	1.31
213.1426849	0.09
225.1340637	0.47
227.3349609	0.19
229.1838684	0.18
236.1753540	0.08
241.1072693	0.23
242.3560181	0.04
244.4224854	0.10
252.9741821	0.03
254.4621887	0.04
257.2890625	0.14
260.2024536	0.02
264.8883057	0.21
271.9984131	0.14
287.3579712	0.08
294.2638855	0.18
298.0272522	0.09
301.8370361	0.97
304.2911987	0.26
307.4792480	0.06
313.0533447	0.07
316.3870239	0.38
317.3876038	0.18
325.3833008	0.15
328.4423828	0.43
334.2139282	0.07
341.6503906	0.33
342.3862305	0.17
343.4194031	0.06
345.0409241	0.06
347.1656494	0.15
351.5552063	0.08
353.2702942	0.23
355.3012085	0.11
360.7044983	0.09
369.4160156	1.91
371.2834473	100.00
379.3997498	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1248
Annotation	Unknow
Peak:m/z	Relative Intensity
173.1485596	0.06
174.1219940	0.05
175.2782593	0.07
177.0766296	1.33
178.9950409	0.42
187.2720642	0.12
188.2248688	0.18
190.9354248	0.24
193.0133362	0.07
201.1193848	0.02
203.1962280	0.09
204.0530090	0.05
205.1351776	0.03
211.1931763	0.04
216.3819427	0.06
218.3105774	0.02
219.1419830	0.44
219.9852905	0.08
221.1084290	0.18
222.2250061	0.07
225.2711792	0.04
229.2790833	0.40
231.1776123	0.08
233.4331360	0.21
243.1527863	0.17
245.1830444	0.14
246.0001526	0.02
247.0820160	0.13
255.2062988	0.21
256.3094788	0.06
257.1025085	0.02
258.9984741	0.24
261.1401978	1.63
262.1321716	0.14
263.0569153	0.19
264.0859985	0.02
269.1200256	0.06
271.2116394	0.04
273.1360474	4.51
274.1672058	1.06
275.8432007	0.04
283.2904053	0.03
285.1499634	0.42
286.3888550	0.16
287.1889038	0.13
288.1511230	0.14
297.3615112	0.19
303.1212769	5.89
304.0502319	1.13
305.1508789	33.54
306.1485596	5.74
307.4718323	0.29
315.0828857	1.34
316.1533203	0.73
317.2501221	0.16
318.2186279	0.03
321.2532349	0.10
323.2301025	0.03
324.1511841	0.07
325.0930481	0.09
330.3833618	0.01
344.7893677	0.24
345.4435425	0.03
346.0794678	0.06
347.2703857	0.06
355.1285400	0.17
357.2866821	0.09
358.2125244	0.09
363.2531128	0.02
370.5024414	0.06
373.1964111	0.24
374.2335205	0.08
385.1259155	0.09
386.2460938	0.02
386.9008789	0.05
389.2767334	0.06
395.4322510	0.04
396.5877686	0.03
397.3627930	0.81
398.2647705	0.17
407.5100708	0.02
409.4017944	0.15
410.5830688	0.05
412.0260010	0.03
413.3280640	0.04
421.2901611	0.08
423.1718750	74.25
424.2597656	29.25
425.1936035	0.07
426.8417969	0.28
427.6652832	0.09
429.1938477	0.11
430.1492920	0.05
431.2514038	0.09
438.3088379	0.04
439.0919189	0.22
441.2060547	100.00
442.1480713	22.95
447.5656128	0.09
451.2348022	0.11
452.6750488	0.29
453.4196167	0.52
454.3620605	0.13
457.2747803	0.03
462.9817505	0.06
465.2420044	2.22
466.2631836	0.82
469.2188721	0.19
470.2669678	0.03
471.2493896	0.48
472.3258667	0.14
473.1946411	0.04
477.2352295	0.05
477.8549805	0.22
481.2348022	0.21
483.1643066	23.47
484.2564087	7.09
488.8854980	0.06
493.2901001	0.06
494.4553833	0.08
504.1444702	0.05
505.4931030	0.11
507.4408569	0.22
511.3708496	0.20
512.4420776	0.02
516.0150757	1.62
516.8539429	0.32
523.6819458	0.04
525.0988770	0.24
526.4330444	0.01
527.0623779	0.02
533.0363770	0.04
547.3093262	0.36
565.1646729	1.01
566.1501465	0.31
566.7699585	0.12
567.4574585	0.07
573.1961670	0.25
574.3712769	0.03
578.2051392	0.03
585.1367798	0.03
591.1928711	12.37
592.3447266	4.83
600.5272827	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.1139
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
111.2670593	0.04
112.8780289	0.02
129.0005188	0.79
137.0466309	0.04
146.9839172	0.55
148.9782867	0.07
162.9913940	0.03
164.0875244	0.43
173.0973816	0.67
179.0147095	0.40
191.0197449	24.81
205.0511627	0.23
206.9154053	0.26
208.0538025	2.26
209.0303802	9.72
223.0549622	100.00
237.2809448	0.14
241.0509949	0.11
247.1853027	0.15
262.9824219	0.05
265.1469421	1.28
291.1135864	0.06
297.0276184	0.12
306.9944763	0.06
321.2000122	0.11
322.9208984	0.22
325.1821899	0.13
332.4139709	0.06
334.7403259	0.06
338.1171875	0.07
339.2352600	0.17
341.6050415	0.05
348.5567017	0.07
351.5845032	0.12
353.0555725	0.85
367.1137085	3.27
370.1318665	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	539.9353
Annotation	Unknow
Peak:m/z	Relative Intensity
198.7000732	0.28
312.9497681	0.14
382.6819458	0.15
410.9647217	0.12
423.0130615	0.56
423.8852539	1.07
425.1362305	4.56
426.1052246	6.33
427.0220947	15.76
440.7718506	0.06
441.7749023	0.23
442.6541748	0.94
443.4541016	0.81
444.6532593	1.66
452.2488403	0.05
465.2940063	0.31
465.9168701	1.04
466.8705444	0.68
468.1105347	1.20
468.9332275	0.12
483.0227661	0.25
483.9038086	0.27
485.0281372	0.10
491.9987793	1.10
493.0939941	24.46
493.9882202	100.00
495.0989990	8.15
496.2385864	0.25
510.2404175	2.28
511.7081299	54.32
512.9882202	4.28
513.8218384	0.13
516.8162231	0.23
518.9726562	0.95
520.6792603	0.17
522.9868164	0.09
529.1691895	0.73
531.0419312	0.21
534.7086792	0.16
535.8217163	0.73
540.2003174	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	882.4515
Annotation	Unknow
Peak:m/z	Relative Intensity
356.5025635	0.12
386.0053711	0.23
423.0955811	0.05
452.4013062	0.63
461.1597900	0.11
488.6584473	0.39
492.5296021	0.16
508.1284790	0.52
523.3678589	0.29
526.1301880	0.15
535.4439697	0.16
536.3343506	0.22
547.3327637	0.14
553.3344727	2.34
565.4281006	0.34
578.1631470	0.25
583.7407837	0.17
590.1493530	0.07
610.3581543	0.10
622.2273560	0.08
624.2460327	0.08
629.6646729	0.22
638.3610229	0.22
668.1375732	0.10
676.6467896	0.13
682.8209229	0.09
686.4731445	0.11
696.5116577	0.08
701.2669067	0.20
714.0128784	0.11
718.5872803	0.93
722.7926636	0.09
725.3533325	0.11
727.7157593	0.07
738.7673950	0.08
745.2808228	0.20
748.2966919	0.13
753.6329956	0.91
767.3295898	0.10
777.3428345	0.17
791.7077637	0.21
792.4273071	0.16
795.7330933	0.08
801.3898315	0.40
805.3453979	0.31
807.5128174	1.01
808.5210571	0.14
810.8161011	0.28
816.4656372	0.32
818.1949463	0.15
819.3374634	0.06
820.3393555	0.45
822.5587158	2.45
834.4900513	2.02
835.6476440	0.07
836.9001465	0.05
840.4995117	0.49
842.6726685	0.42
846.6478882	0.57
852.4768677	100.00
853.1117554	0.72
853.7241211	0.27
864.4933472	12.78
865.1261597	0.59
873.2866821	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	333.0235
Annotation	Chlorphoxim
Peak:m/z	Relative Intensity
124.9557343	0.04
140.9858398	0.02
147.0453491	0.02
156.9915161	0.07
171.1001892	0.02
195.2144318	0.01
199.1006165	0.02
201.0300598	0.03
211.2378235	0.02
215.1386414	0.03
216.3571472	0.01
218.4241638	0.02
220.9414978	0.02
227.1203613	0.01
229.1942139	0.02
231.0625610	0.33
233.0175476	0.04
245.4084473	0.01
247.3301086	0.01
249.1961975	0.01
250.1917419	0.03
255.9891968	0.01
257.2769775	0.03
258.9456482	0.03
261.0190430	0.74
263.1546936	0.07
268.3251343	0.01
268.9285889	0.03
277.1557007	0.19
278.5151978	0.02
287.0413818	100.00
288.0293579	0.04
289.1137695	0.16
290.1278687	0.02
291.3859558	0.03
296.3767090	0.08
297.0941162	0.00
305.1315002	1.60
310.0764771	0.01
314.3092346	0.53
315.1917114	0.11
316.5768738	0.02
323.9373169	0.05
324.6564636	0.03
333.3361816	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0878
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
94.9462051	0.34
98.9462738	0.12
101.0191650	0.32
105.0250931	0.07
107.3053894	0.26
108.0059357	1.18
113.0138321	0.62
114.9924011	0.09
118.7459106	0.52
122.9440842	3.90
125.0265579	0.24
126.9188690	0.11
137.8957520	0.05
142.9198456	0.05
149.0390625	2.51
149.8385925	0.38
151.0969849	0.04
151.9315796	1.90
153.0602417	0.05
161.0431213	0.26
162.7823181	0.14
164.1892853	0.13
165.2036743	1.05
166.9601135	100.00
179.1854858	0.11
181.1069641	14.19
191.1140137	0.73
192.9293060	0.28
194.0578308	1.25
194.9520569	0.17
198.0646362	0.04
200.3181610	0.19
207.1011200	0.14
209.0047913	94.47
211.9313660	0.42
213.1869202	0.45
214.3567810	0.24
219.0266418	0.08
221.0646057	1.19
226.2075500	0.04
239.0597534	14.46
239.6738892	0.06
241.2290344	0.25
243.1906128	0.05
251.1774902	0.23
259.1376953	0.09
262.9763184	0.39
267.2550049	0.07
269.1175537	34.44
271.6944885	0.05
283.1060791	0.29
284.1516113	0.21
285.1893311	0.22
285.8560181	0.06
286.6267090	0.26
291.3030701	0.25
293.0843811	0.38
298.9818420	0.65
301.1217346	0.23
311.1990356	0.69
313.9405518	1.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.151
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
177.1123047	0.17
178.2499542	0.03
179.1530609	0.42
191.0263672	2.12
192.0455322	2.45
193.1527710	0.06
206.0213928	9.44
207.1101074	12.94
208.1304321	0.05
221.2074432	0.02
248.8933868	0.08
252.8336792	0.02
254.2606964	0.04
282.3712158	0.02
293.0506592	0.01
299.2022095	0.24
306.2498169	0.03
308.1219788	0.07
329.2147827	0.04
338.3457642	0.03
341.1159058	0.20
349.2982788	0.05
355.2079468	1.16
357.2785645	0.30
367.2487793	1.25
368.3515625	0.08
371.2612915	0.69
373.8085327	0.03
378.4841309	0.04
383.3992310	0.02
385.1162109	100.00
385.7565308	0.23
387.1310425	0.20
388.1496582	0.06
389.2125244	0.13
392.2618408	0.04
393.0870361	0.05
399.2779541	0.05
401.1106567	0.09
411.2481079	0.15
417.2247314	0.04
426.1811523	0.02
429.3448486	0.04
430.4514771	0.34
431.3977661	0.48
439.3153687	0.03
446.5381470	0.05
449.5572510	0.10
451.4664307	0.02
463.2850342	0.10
481.5658569	0.03
484.1362915	0.06
490.5317993	0.05
492.4512329	0.03
497.2734985	0.29
506.4428101	0.18
507.1694946	1.09
511.1648560	0.19
515.5254517	0.02
517.8798218	0.03
519.2576294	0.26
529.9309692	0.05
531.2197876	0.05
532.6898804	0.47
533.3730469	1.22
545.8213501	0.16
547.0474854	2.89
547.7849731	0.18
549.1491699	0.64
550.3273315	0.32
554.4545288	0.24
555.3159790	0.02
557.4541626	0.09
561.3909302	0.05
572.3551636	0.20
573.2083740	0.04
574.3991089	0.61
575.3973389	2.51
576.0561523	0.04
579.0614624	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
128.8629303	9.00
138.8847351	4.77
147.0022278	1.52
149.208374	2.26
166.2528687	3.33
173.0616455	4.03
185.2417603	6.22
187.1123352	2.95
199.1329346	8.18
247.5639648	4.83
262.903595	17.57
267.9020691	11.55
270.1841431	4.58
277.5220032	5.14
281.4624023	16.39
285.5092773	1.76
289.0584106	2.06
293.9844055	5.91
311.9673767	1.07
314.0983887	1.53
325.055542	2.16
329.1323853	4.20
339.3726501	21.44
341.4109802	3.12
348.1281433	3.51
350.2529602	2.28
354.9344788	2.87
356.3973999	19.80
357.3179321	9.06
358.2173767	2.15
359.2344666	2.78
361.3814697	1.92
364.2416077	6.08
365.5765381	4.72
371.8033142	9.83
374.5556335	3.76
377.4790344	8.17
382.2285461	2.27
383.6930847	3.47
391.0152893	6.83
395.2608948	10.87
407.4738464	13.02
408.2708435	100.00
409.2868347	14.50
422.4484863	4.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	722.5024
Annotation	Unknow
Peak:m/z	Relative Intensity
209.2877045	0.19
218.8287964	0.04
221.1144714	0.81
223.2640228	0.20
225.3610077	0.16
234.9542847	0.15
235.6230164	0.12
237.0422974	0.13
238.9736176	0.05
247.2471313	1.04
253.0714722	0.33
255.0765381	0.81
261.4702148	0.39
265.1703491	1.54
267.0556641	0.07
271.2261658	0.14
272.9763184	0.43
279.1043396	1.02
281.1380615	0.07
291.2593994	4.35
296.3558350	0.05
297.1749268	0.14
299.1687012	0.41
305.4254456	0.36
307.1643372	0.31
309.1314697	1.80
311.1186523	0.31
317.1860657	1.88
319.0177002	0.03
323.0239258	0.80
325.4094849	0.08
332.1389160	0.32
335.0244751	4.45
335.6388550	0.74
340.8118286	0.04
343.2573242	0.62
349.3783569	0.05
353.1240234	1.93
359.3826294	0.43
361.2728271	0.44
367.5761719	0.10
370.1168823	0.05
375.0334473	0.05
378.8608398	0.80
381.2199707	0.18
387.2565918	0.19
397.0966797	1.46
402.5617065	0.10
405.2490234	0.04
410.8137207	0.02
423.1021729	1.12
425.3637695	0.16
429.0941772	0.07
441.1019287	1.26
448.8383789	0.25
449.5231323	0.22
466.9416504	0.21
469.2718506	0.76
473.2533569	0.16
485.2731934	0.99
487.2287598	0.13
491.3147583	0.22
493.2440796	0.30
494.3879395	0.18
507.6461182	0.13
511.0662231	0.20
513.3477173	1.13
519.1063232	0.10
529.2979126	0.97
535.3568726	0.15
537.3444214	0.17
546.4656982	0.15
555.1742554	0.16
561.3464966	0.04
573.2706299	0.72
576.4895630	0.16
579.2662354	2.79
588.4627075	0.14
592.0200806	0.13
598.3177490	0.14
599.1455078	1.04
607.4413452	0.13
617.3566284	3.73
619.8902588	0.03
625.8793335	0.04
638.5249023	0.19
643.3656616	0.06
646.3188477	0.14
654.8231201	0.06
660.7387695	0.39
661.4146118	4.03
678.1850586	0.03
680.7819824	0.29
684.3243408	0.15
686.4297485	0.34
687.2501831	0.92
698.6449585	0.50
699.6561890	0.21
703.5496216	0.34
705.2752686	100.00
706.0091553	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	631.3906
Annotation	Unknow
Peak:m/z	Relative Intensity
195.4380493	0.02
199.0782471	0.40
206.8246155	0.29
207.5640869	0.42
209.0303650	0.05
210.0078583	0.06
210.9393311	0.07
212.0711823	0.08
219.0441284	0.04
221.1037903	1.79
222.0399475	0.11
225.1112518	0.47
228.5487976	0.44
229.5122986	1.36
230.1275940	0.21
234.0645752	0.12
235.3028870	0.46
238.0159760	0.11
239.1533966	0.16
243.1022034	0.93
245.7629395	0.05
248.7018890	0.10
251.4767303	2.04
252.1191254	0.04
253.1551971	0.19
255.3031921	0.09
256.3074341	0.14
265.1177368	1.34
266.4519348	0.05
267.2573853	0.26
269.2221985	0.20
270.0580444	0.10
272.4624023	0.39
273.6762085	1.18
279.0936279	0.03
281.1351624	0.04
282.4699402	0.05
283.4626465	0.05
284.2075195	0.06
287.3454590	0.09
289.6032104	0.39
295.4636841	2.24
296.4290771	0.15
297.2137451	0.17
299.1099854	0.09
300.1168823	0.09
301.1010742	0.02
305.2042236	0.02
306.9329224	0.03
308.9819946	0.09
310.0939331	0.08
311.3153381	0.23
313.0537109	0.60
313.9616089	0.17
315.4381714	0.05
317.6435547	1.40
319.7634277	0.64
320.3773193	0.16
325.4476318	0.08
326.2312012	0.08
327.2890015	0.44
328.3948975	0.22
329.1387329	0.17
330.5198975	0.06
331.5260620	0.15
338.7022095	0.56
339.6575928	0.42
341.4715576	1.15
342.3086548	0.33
345.0604858	0.05
349.6748657	0.75
351.2152710	0.08
353.3134766	0.30
354.1761475	0.13
355.2454224	0.06
356.6787720	0.03
357.3724365	0.18
358.3062134	0.09
359.2319946	0.15
360.8272705	0.40
361.7179565	0.61
363.7287598	1.24
364.3593750	0.07
371.6887817	1.05
373.1785278	2.62
374.6654663	0.06
375.4484863	0.50
376.2215576	0.23
381.4472046	0.04
382.3345337	0.03
383.4191284	0.21
384.0322266	0.09
385.5064087	0.63
386.3029175	0.13
392.3374634	0.05
393.6215820	1.53
394.3959961	0.49
397.3448486	0.13
401.2421875	0.46
402.0609131	0.03
409.3109741	0.13
414.7144775	0.07
415.9651489	0.65
417.0071411	0.44
417.6900635	0.05
418.3961792	0.14
419.6632080	0.27
426.6218872	0.09
427.8428955	0.48
429.6051636	0.16
431.0499878	0.04
432.2881470	0.05
434.8828735	0.08
436.2165527	0.03
437.7160034	1.05
441.2507324	0.22
443.4072876	0.11
445.1758423	0.36
447.5407104	0.05
449.4038696	0.17
452.2586670	0.12
460.0396729	0.02
461.1020508	0.12
471.5696411	0.10
472.3210449	0.02
475.0036011	0.18
479.1146240	0.30
480.0806885	0.08
482.1900024	0.06
485.4196777	0.11
487.7517090	0.09
488.9473877	0.16
495.9027710	0.52
496.6871338	0.53
497.7849731	0.03
502.7329712	0.03
503.5523682	0.22
504.3276367	0.19
505.3167114	0.46
506.7307739	0.04
507.9248047	0.03
510.6575317	0.15
513.3189087	0.36
518.9074097	8.14
520.1006470	0.13
521.4023438	0.03
523.3239136	0.27
524.4485474	0.27
526.9055176	1.71
527.6098633	0.13
529.1335449	0.05
533.0581665	0.13
534.0223999	0.40
540.4832764	0.19
541.3727417	0.08
546.4160767	0.06
547.5347290	0.60
548.8030396	1.76
549.4594116	0.10
550.3761597	0.22
551.4765625	0.08
552.7820435	0.04
556.8765869	0.57
561.3945923	0.09
562.4772339	1.03
564.4989624	0.24
565.5089722	0.12
567.2348633	0.12
569.7383423	1.11
570.9576416	100.00
571.8302612	2.60
572.6366577	1.40
573.9102173	0.83
574.7214966	0.07
575.5717773	0.34
577.2922974	0.14
578.5963135	0.98
579.2703247	0.63
580.1492310	0.15
581.3440552	0.16
582.1243896	0.05
583.8513184	0.22
584.5871582	0.15
585.5748901	0.38
590.4335327	0.08
591.3140259	0.03
593.0642090	0.94
594.3846436	0.23
595.6248169	0.04
596.2872925	0.05
600.6755981	1.53
601.2875977	0.45
605.0591431	0.11
607.7468262	0.57
608.6419067	0.35
611.3187866	0.03
614.2068481	1.14
615.3517456	0.12
619.3528442	0.08
621.3115845	0.09
622.7759399	0.73
635.2991333	0.28
637.1721802	0.39
638.3126831	0.18
651.0421753	0.17
652.4028931	1.91
653.5822754	0.32
661.0546265	0.06
662.9111938	0.05
665.2064819	0.07
679.3128052	0.28
680.5211792	0.03
681.3619995	0.17
682.4459839	0.02
696.4274292	2.21
697.4391479	0.53
705.0901489	0.08
705.7505493	0.08
716.4702759	0.13
723.0606689	0.23
724.5540161	0.03
739.6943970	0.17
740.4770508	2.00
741.5938110	0.29
744.5319824	0.61
745.4601440	0.05
747.3087769	0.03
749.8981323	0.11
753.0066528	0.03
754.1986084	0.15
760.1837769	0.08
767.6467285	0.19
770.6436157	0.15
771.2533569	0.32
772.4647827	0.09
784.4949341	2.35
785.3302612	0.46
788.4241333	0.37
789.6277466	0.10
793.4188843	0.18
798.3167114	0.12
805.7720337	0.07
814.5962524	0.02
828.5195923	1.13
829.3222046	0.36
830.0184326	0.03
832.4672241	0.28
833.3847046	0.20
839.0239868	0.12
841.6521606	0.16
849.1309204	0.25
855.3550415	0.06
857.3751831	0.12
858.0989380	0.04
858.7608032	0.06
859.4648438	0.07
860.4787598	0.08
871.1382446	0.05
872.6015625	0.60
873.5753784	0.22
876.4316406	0.50
877.2109375	0.08
890.8180542	0.04
892.7985840	0.81
899.5770874	0.18
901.2792358	0.14
902.2468262	0.16
916.7878418	0.35
918.2625122	0.20
919.4047241	0.15
920.5408325	1.16
921.6120605	0.28
936.6015015	1.25
937.6891479	0.45
945.0302734	0.07
947.6405640	0.06
948.4749146	0.07
964.4918823	0.41
965.5630493	0.63
974.7283325	0.07
980.5270996	1.37
981.5480347	0.66
1008.4207150	0.12
1024.5234380	0.96
1025.6368410	1.26
1034.5993650	0.12
1036.1872560	0.64
1036.9379880	0.85
1037.7048340	0.08
1053.7773440	0.16
1068.3715820	0.68
1069.2823490	0.15
1096.6884770	0.09
1112.6834720	0.12
1113.5529790	0.27
1123.4622800	0.33
1124.6126710	0.03
1140.6291500	6.91
1141.6718750	2.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	861.2832
Annotation	Sirohydrochlorin
Peak:m/z	Relative Intensity
262.9220581	0.14
271.1233826	1.07
273.2414856	0.43
286.9876099	0.32
316.0450439	5.01
317.1456299	2.58
318.0920410	0.25
319.4264526	0.33
337.2455444	4.38
338.4954224	0.43
345.2180176	0.52
374.9707642	0.08
381.2943115	44.60
382.4155273	2.91
461.3677979	0.23
479.1621094	100.00
480.2649536	7.73
521.7133179	0.27
530.0398560	0.06
551.3309937	0.20
577.3692627	0.11
649.2826538	0.38
699.3054810	0.23
714.1689453	0.18
741.3472900	0.14
786.6509399	0.49
787.5444946	0.26
800.3838501	0.18
816.4317017	0.12
819.4992676	0.15
843.2344971	0.35
844.4900513	0.04
845.5571899	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.12
Annotation	Cyanidin 3-(6''-caffeylglucoside)
Peak:m/z	Relative Intensity
176.9116974	2.31
178.9368286	0.50
187.0225983	0.10
189.1276855	0.06
191.0746307	0.14
201.1563416	0.09
204.0265503	0.10
217.1848755	0.19
219.1225128	0.13
221.1280212	0.20
229.2944336	0.06
243.1555481	0.25
244.2120056	0.12
255.2688599	0.11
261.1057739	1.21
262.8889160	0.03
267.1583252	0.16
271.1238098	0.10
273.1240845	4.30
277.0594482	0.05
283.2474365	0.14
285.0894775	0.46
287.2927246	0.07
302.0375061	0.16
303.1532593	3.02
305.1495667	28.22
306.2504883	0.07
307.2775879	0.05
315.0532837	1.90
321.2001648	0.02
325.4551392	0.08
343.3572998	0.10
345.3098755	0.46
347.1462402	0.68
355.3705444	0.26
357.0263672	0.20
373.2108154	0.27
385.1394043	0.03
386.1621704	0.25
388.3059692	0.04
389.4829102	0.05
395.1689453	0.12
396.2185059	0.03
397.2303467	1.08
403.1688843	0.06
405.2124023	0.04
412.2367554	0.19
423.1738892	90.93
424.0519409	0.20
424.9014893	0.14
427.2587891	0.50
429.3179932	0.07
439.2722168	0.57
441.1460571	100.00
441.7673340	0.34
447.3954468	0.10
453.2427368	1.05
455.1533813	0.06
456.1694336	0.17
465.2856445	2.18
468.1833496	0.29
469.4891968	0.15
470.2081299	0.12
471.3035278	0.45
481.3117676	0.11
483.2762451	15.40
485.3539429	0.03
493.0452881	0.08
501.0080566	0.05
503.3324585	0.11
515.5303955	0.48
524.2177734	0.19
524.8439331	0.10
536.2272339	0.18
545.6337280	0.04
547.0856323	0.28
563.2956543	0.05
565.2881470	1.98
573.3298950	0.17
580.6990967	0.30
590.6041260	1.49
591.3322144	9.64
592.6311035	0.08
599.5645752	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	532.8751
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0163727	0.04
174.9527588	1.50
215.1099243	0.23
244.8012390	0.19
273.0255737	1.41
274.3009033	0.03
289.0278625	12.69
301.5762939	0.10
304.9691467	4.82
362.8386841	0.10
379.1741943	0.12
387.0598755	0.64
388.3141479	0.13
389.2404175	0.13
403.0595093	7.29
418.8815308	100.00
419.5045776	0.35
443.0469360	0.04
458.9287720	0.37
461.0456543	0.06
485.8275146	0.18
486.9771729	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	594.9628
Annotation	Unknow
Peak:m/z	Relative Intensity
182.9765625	0.06
207.1055298	0.08
219.1009521	0.09
223.0444794	0.04
229.2998352	0.03
230.9955139	0.12
241.3142090	0.02
241.9749298	0.11
257.0649719	0.06
259.2911072	0.04
260.8738403	0.06
269.1140442	0.03
271.2189331	0.03
279.3264160	0.27
280.2678223	0.04
280.9472046	0.08
286.4082336	0.03
289.2850342	0.07
295.4639282	0.06
297.3081665	0.04
298.3284912	0.14
299.7241821	0.34
300.4725342	0.39
301.4744873	0.08
303.0455322	0.03
305.8253784	0.10
311.6328735	0.02
315.2640381	0.24
327.5750732	0.02
329.7552490	0.02
331.3533325	0.05
333.5324097	0.01
337.8712158	0.03
338.9571533	0.17
341.0798340	0.04
343.2232666	0.06
351.9143066	0.03
360.9578857	0.02
369.8285522	0.08
377.3904419	0.13
379.4862671	0.01
380.9284668	0.02
384.2473145	0.06
389.5079346	0.10
390.3038330	0.05
391.4865723	0.03
393.4129028	0.02
401.1735840	0.01
407.1330566	0.03
410.5541992	0.25
415.2846069	0.10
419.5266113	0.01
427.1503296	0.04
435.1319580	0.08
445.5086670	0.10
447.2215576	0.01
449.3092041	0.02
463.4132690	0.02
475.0127563	0.12
479.7641602	0.08
480.4147949	0.03
494.6969604	0.03
497.3588257	0.11
498.2377319	0.02
503.3164673	0.03
504.9951782	0.06
505.9802246	0.05
507.2161255	0.01
509.6951294	0.02
510.4606934	0.01
515.3795776	0.02
520.4968872	0.06
521.2234497	0.15
524.1991577	0.06
526.7838745	0.04
531.0230103	100.00
532.3786011	0.02
533.5114136	0.03
538.3326416	0.04
540.4006348	0.38
541.2377319	0.21
548.5775146	0.24
549.2348022	0.19
550.6975708	0.39
551.3826904	0.26
557.1511841	0.02
558.5213013	0.05
559.7371826	0.02
563.1682739	0.32
574.1524048	0.03
576.0651245	0.02
577.4315796	0.66
578.2488403	0.04
579.4046021	0.15
594.4937134	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1088
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
149.0427399	0.05
150.2299194	0.07
150.9787750	0.12
163.1664734	0.14
165.0611572	0.09
175.0335083	0.08
176.8117676	0.04
179.0305786	0.54
180.0463257	0.30
191.0133820	0.07
199.0497131	0.17
201.1347504	0.11
215.3032379	0.17
223.0783691	0.05
241.2018127	0.02
242.1365051	0.05
243.1612244	2.01
259.1596985	33.50
265.2155457	0.09
265.8722534	0.16
267.0901794	0.09
269.0721741	36.53
271.0279846	0.04
272.2021484	0.14
282.2469177	0.05
283.0753174	0.18
287.0897217	100.00
293.2020264	0.38
301.1857910	0.03
305.1121216	0.10
311.1731567	1.50
312.2363586	0.04
316.0520935	0.04
325.2006836	0.15
329.1758423	0.14
331.2143860	0.08
333.3998718	0.13
342.1229248	1.13
343.2402954	0.02
353.4310608	0.13
359.2187500	0.04
360.1057129	0.04
361.4312744	0.12
365.2211304	0.13
369.0357666	0.12
371.0770569	0.04
386.2013245	0.08
389.1413879	0.02
401.3949890	0.24
402.1973572	0.31
403.1895447	0.35
405.2159729	0.51
413.0203857	0.08
414.4399719	0.03
417.4030457	0.09
421.2888794	1.58
428.8037109	0.06
430.6293335	0.15
431.2320557	4.87
449.1461487	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	489.1037
Annotation	Isoscutellarein 8,4'-dimethyl ether 7-glucuronide
Peak:m/z	Relative Intensity
150.8883972	0.08
159.2906494	0.02
163.0337219	0.07
165.1318817	0.04
168.8764343	0.14
172.9756470	0.04
178.9372253	0.07
185.2866669	0.02
187.1133728	0.11
191.0603333	0.02
192.2105103	0.02
195.1740723	0.11
197.1260376	0.09
199.0655212	0.13
200.8616943	0.09
201.9186096	0.01
211.3054657	0.02
213.1476440	0.34
215.0267029	0.10
226.8977661	0.04
229.0685730	0.40
239.2139282	0.26
240.0812378	0.03
241.0821991	0.16
243.2399292	0.04
245.1009521	0.04
249.0944519	0.02
251.1626587	0.02
253.0439148	0.08
255.1149292	1.08
256.2077942	0.27
257.1493530	0.92
260.9166870	0.03
267.2856750	0.32
267.9910583	0.14
269.3153381	0.29
270.9177856	0.07
272.1770630	0.08
282.5172729	0.07
283.1930847	0.97
284.4460449	12.90
285.0663147	100.00
286.0830383	0.17
297.2287292	0.02
298.0859070	0.02
299.1253662	0.03
309.2444458	0.13
311.0369568	0.02
325.9254456	0.13
327.2046814	1.17
328.4410706	0.03
331.2736816	0.09
353.3358459	0.03
355.3050232	0.02
357.2537537	0.11
358.0843506	0.04
369.2907104	0.06
377.5250244	0.03
379.0340881	0.05
381.4435120	0.11
382.8639221	0.03
393.2345581	0.11
394.4642029	0.09
398.2094421	0.04
403.1837769	0.06
405.4898682	0.05
414.3483582	0.07
418.2891541	0.02
425.9823914	0.02
427.5390930	0.07
429.1739807	0.39
441.0694275	0.05
443.0674133	0.03
444.2912903	0.01
445.2734070	0.11
445.9806213	0.05
447.1564331	0.53
451.2098999	0.04
452.6022339	0.09
453.2756958	0.07
459.2632141	0.05
461.3025513	0.05
470.4242859	0.05
471.2110291	0.23
473.4446716	0.02
490.0194397	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	615.1727
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0263519	2.24
187.1831055	0.05
196.8778076	0.03
214.5416718	0.05
215.2519379	0.46
216.2614136	0.04
225.9763641	0.10
226.9282074	0.05
233.0673981	2.38
245.2860413	0.27
273.1173096	0.03
283.0532837	0.04
290.0197144	0.54
291.0296021	0.28
308.0774536	100.00
355.4453735	0.03
357.1710205	0.11
411.1537476	0.11
434.2468262	0.09
451.9539795	0.03
464.4117432	0.04
466.2012329	0.16
482.9835815	0.23
484.1684570	0.33
485.2406006	0.37
523.7018433	0.07
529.9070435	0.31
540.2011108	0.10
541.7683105	0.30
569.1569214	0.21
571.3664551	0.10
576.8942871	0.05
579.1265259	0.31
588.2221069	0.11
597.3806152	0.58
614.5527344	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	645.1882
Annotation	beta-D-4-Deoxy-Delta4-GlcA-(1->4)-beta-D-Glc-(1->4)-alpha-L-Rha-(1->3)-D-Glc
Peak:m/z	Relative Intensity
193.1097717	0.07
201.0384369	0.28
207.0354309	0.64
214.7870789	0.07
226.1402893	0.12
227.2593079	0.03
231.8787537	0.08
243.8042450	0.32
245.2525635	0.29
256.0739136	0.13
258.2746277	0.03
259.3453674	0.11
263.1305237	0.31
269.1349182	0.09
272.8720093	0.13
277.2622070	0.06
289.1871643	0.11
299.4299622	0.21
300.0575562	0.35
302.0237427	0.27
303.1922302	0.07
305.1618042	0.38
306.0686646	0.26
308.1835938	0.06
317.1453247	0.50
321.1151733	1.57
321.7300415	0.19
331.3075562	0.09
337.1829224	0.17
339.2260742	0.04
342.7309570	0.13
349.2664795	0.59
358.9134521	0.21
361.1322632	0.31
363.0198975	0.21
371.3752441	0.29
375.2761230	0.16
377.2848511	0.72
381.1928711	3.38
383.3325806	0.18
391.0665894	0.10
393.3331299	0.97
403.2484131	0.69
404.1757202	0.15
407.1932983	0.18
409.4628906	0.19
414.0397949	0.06
417.2170410	0.38
419.1901855	0.26
421.1275024	0.92
423.6139526	0.06
427.0881348	0.07
430.2111816	0.09
433.2916260	0.43
435.2827148	5.04
437.5173340	0.11
439.4042358	0.11
444.4546509	0.11
451.2730713	0.36
453.2350464	14.53
463.3656616	0.25
464.1535034	0.29
465.4887085	0.19
467.2960205	0.07
471.2721558	3.34
476.9719849	0.10
480.1421509	0.13
481.2985229	1.08
482.9619751	0.07
493.3886719	0.07
494.4387817	0.20
495.2413940	0.47
507.4157104	1.10
509.2378540	0.13
513.2050171	39.49
514.4254761	0.09
515.3941650	0.39
525.2841187	0.57
529.2350464	0.07
535.3229980	1.92
540.5138550	0.41
543.1838379	1.72
549.1508179	0.19
553.1785278	0.53
555.2094727	1.06
567.2723389	23.42
571.2806396	0.24
583.5915527	0.20
585.2463989	100.00
585.9171753	0.11
601.1351318	0.50
601.7852173	0.03
603.2600708	10.23
607.2969971	0.32
609.2798462	1.20
613.3252563	4.81
615.0677490	0.06
617.2026978	0.09
627.2645264	1.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	810.35
Annotation	Unknow
Peak:m/z	Relative Intensity
271.1932983	0.04
299.0343628	0.17
299.8627319	0.30
330.0595398	0.63
339.1790161	0.19
342.1364136	0.13
354.0966797	0.12
399.1152954	0.32
400.3652344	0.71
401.5935059	0.06
426.2503662	0.20
450.0068970	0.37
450.7260132	0.17
461.0699463	0.35
462.2048340	0.21
463.4239502	0.25
478.0910645	0.13
479.1634521	0.38
481.3279419	0.72
482.1828003	0.12
489.4237671	0.37
492.2497559	0.40
494.1566772	0.26
511.1573486	0.18
521.6977539	0.51
523.1406860	0.23
524.5239868	0.32
525.2703247	0.16
595.1249390	0.11
597.2355957	1.23
600.3908691	0.31
610.4732666	0.38
613.4260864	4.09
614.2852173	9.46
615.3219604	15.64
616.3744507	4.47
619.2211304	0.52
624.4943237	0.14
636.6920776	0.68
645.3585815	2.19
646.4460449	6.18
647.3179321	15.17
648.3865356	3.54
652.2896729	0.64
653.4430542	1.44
654.3201294	3.50
655.1766968	0.45
655.8625488	0.09
663.3753662	0.17
675.9644165	0.22
679.3034668	0.04
681.5565796	0.04
685.3128052	2.15
686.2802734	4.37
687.4254761	0.74
699.2284546	0.17
733.4050903	0.59
734.3682861	0.30
735.6127319	0.16
741.3802490	0.34
750.0657349	0.21
757.3502197	0.25
758.9732056	0.87
759.7647095	0.48
760.6168823	0.40
775.1857300	1.26
776.5538940	11.14
777.3303833	100.00
778.4070435	38.75
785.2823486	0.20
791.3652954	0.40
792.6398315	0.16
810.8074341	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	619.0608
Annotation	Unknow
Peak:m/z	Relative Intensity
187.8790894	0.11
203.0189514	1.24
209.1947632	0.44
211.1766052	0.03
246.9840851	100.00
279.1911316	0.09
316.8142090	0.10
371.4794922	0.10
373.1788330	0.19
377.1420898	0.22
391.3538208	0.10
394.2066650	0.09
397.6174927	0.13
409.2496338	0.23
411.1497803	1.66
413.3578491	0.06
414.3115845	0.13
421.1562500	0.44
423.3085327	0.28
439.0357056	0.06
441.3689575	0.19
451.1647339	0.30
453.3103638	0.18
456.2667847	0.09
473.4870605	0.11
489.3479004	0.25
493.1151123	0.42
537.6437378	0.36
564.8352661	0.18
574.3445435	0.21
582.0333862	0.48
596.0182495	0.04
598.4057007	0.15
599.4105225	0.33
600.1187744	0.18
601.2446289	0.96
610.3092651	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	544.73
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8244019	0.19
209.0447998	0.22
289.4537964	0.05
290.7223206	3.88
292.7503052	4.21
336.9264526	0.04
364.1932373	0.12
370.6986084	0.05
372.9160767	0.04
374.6641846	2.89
375.9078979	0.95
376.6385498	4.03
377.2598267	0.03
378.9100952	0.08
380.7269287	0.04
382.8032837	0.18
394.6309204	0.05
400.3399048	0.18
407.6984253	0.05
408.9252930	0.04
422.8655396	0.05
424.7753296	0.41
436.6453247	0.31
437.2855225	0.06
438.7999878	1.16
453.7081909	0.12
454.7017212	0.14
458.5941772	19.89
459.8056030	15.54
460.6141968	100.00
461.6145630	0.02
467.4358521	0.03
468.5512085	0.16
480.7473145	0.76
482.4733276	0.01
483.8333740	0.56
484.7189331	1.23
496.6548462	0.01
498.2582397	1.16
498.9539185	0.55
526.6013184	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.92
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0310822	2.73
160.0083160	0.64
161.0399323	0.95
199.0663452	0.27
200.0195007	0.14
201.0754395	0.42
202.0108643	0.19
217.2451019	0.17
218.1461639	0.04
219.1336975	0.09
220.0107422	0.03
229.1246643	0.52
230.0431213	0.17
231.0002747	0.30
231.6663971	0.01
273.0232544	26.07
274.0370178	14.83
275.0179749	32.01
276.0021667	5.71
343.1116943	0.01
345.8796997	0.01
386.9849548	26.75
387.9784851	24.68
388.9866333	100.00
389.9606934	25.80
390.5967712	0.04
417.9524536	0.03
429.0626526	0.09
430.0509338	0.14
442.0003662	0.02
457.1258850	0.07
458.0430603	0.02
459.1763611	0.03
472.7445679	0.02
485.7667542	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.0931
Annotation	5-(3',4',5'-Trihydroxyphenyl)-gamma-valerolactone-4'-O-glucuronide
Peak:m/z	Relative Intensity
128.9291382	5.46
142.8404083	0.07
146.8916626	3.67
148.0976257	0.34
161.0528870	0.31
161.8585815	0.20
171.8478699	0.09
172.9750214	5.67
174.1154327	0.40
175.3071289	0.10
176.2180786	0.48
178.5124969	0.04
187.0395050	0.65
191.0091400	100.00
193.2160950	0.05
200.2467804	0.07
204.9458160	12.52
207.1678314	0.28
208.0025635	0.27
209.1715698	0.04
210.9471130	0.11
214.0636902	0.10
218.1029663	8.24
219.1036682	1.55
221.0078735	0.04
223.0517578	17.22
227.1759949	0.23
230.9143982	0.28
236.1719971	0.20
237.1128845	0.59
238.0588074	0.11
261.2559814	0.45
279.2864990	0.36
283.0051880	0.05
307.1298218	0.11
309.1883850	0.09
310.1521606	0.21
318.3743896	0.49
319.3317871	0.55
321.3724365	0.03
322.4275513	0.07
323.1948853	0.11
325.6315308	0.15
330.3765564	0.05
332.5190430	0.07
337.1762390	0.60
339.4476929	0.11
346.5283203	0.72
349.1085510	0.10
350.4556885	0.13
351.1538391	0.07
352.3248596	1.95
353.3052368	0.27
355.1900635	0.40
363.1319275	0.97
367.0514832	1.07
370.2193298	0.93
380.9962158	13.94
382.2323914	0.18
384.1507263	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.3124
Annotation	Unknow
Peak:m/z	Relative Intensity
158.8823242	0.13
234.5932770	0.76
235.2205048	1.17
253.0951233	8.15
275.5997925	0.27
277.2770386	80.47
279.2316895	0.14
297.4232483	0.19
300.2647705	0.08
308.0971069	0.07
309.3391418	0.60
311.1330566	0.11
327.4478149	0.03
347.2413330	0.19
355.3355103	0.19
363.1296997	0.06
385.1928711	0.09
439.3223267	0.33
445.4537354	0.21
453.4792480	0.20
457.4020386	0.26
458.3348999	0.15
462.3189697	0.08
468.8106689	0.12
475.3270264	0.19
486.4403687	0.20
487.2036133	0.35
494.1395874	0.10
495.1793213	0.29
498.6782227	0.56
499.3529053	0.07
509.4661255	0.19
513.1033325	100.00
514.1838989	0.23
514.9859009	0.32
521.3384399	0.26
522.6397705	0.48
524.1824341	0.27
527.6361084	0.21
541.1851807	0.44
559.9033813	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	550.3
Annotation	Unknow
Peak:m/z	Relative Intensity
180.9838409	0.09
222.1550903	0.15
223.0676575	0.07
224.3793793	0.02
225.2009430	0.02
226.1310120	0.19
284.0098877	0.53
285.1829224	0.32
286.3384399	0.02
288.1895447	0.04
299.1907349	0.17
301.2041626	0.07
310.3239746	0.17
314.0775146	0.04
318.4622803	0.10
326.4851685	0.08
327.1380615	0.05
338.4996948	0.06
340.0744629	0.16
344.3612061	0.80
346.3339233	0.86
351.4599609	0.09
355.1036377	0.05
356.0183716	0.06
362.4265747	3.37
368.0248413	0.05
369.2728271	0.33
370.2801514	0.06
385.2835083	0.09
386.3439941	0.63
387.2692261	2.34
388.1662598	0.48
396.3107300	0.08
398.4520874	0.15
399.4116211	0.26
400.2848511	0.65
402.3155518	0.15
404.4051514	1.52
405.0759277	0.06
409.2661743	0.04
410.4226074	0.09
416.2277832	0.80
417.0478516	0.21
420.9894409	0.07
432.2878418	0.60
436.2838745	0.08
453.7316284	0.16
454.3771362	0.10
457.3980103	0.03
459.3929443	0.03
462.3946533	0.04
464.5098877	0.05
469.6062622	0.03
472.3322754	1.77
478.1831665	0.03
490.4428711	55.65
503.0654907	0.03
504.0845337	0.21
505.6574097	3.21
506.3226929	24.87
508.4041748	100.00
509.0193481	0.55
511.2966919	0.08
513.0459595	0.10
517.6457520	0.08
520.4080200	0.04
532.3358154	67.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.2184
Annotation	Excavatolide D
Peak:m/z	Relative Intensity
160.9961243	0.08
178.9812012	1.53
181.0823212	0.02
182.9944153	0.09
185.1251068	0.02
193.2545776	0.05
201.1771088	0.07
203.5070953	0.07
205.7211456	0.08
229.1248322	0.77
242.0952148	0.06
247.0886230	0.16
251.3679810	0.16
255.2895050	0.04
257.1618042	0.03
261.3464966	0.04
266.0358887	0.04
267.9013977	0.06
269.5048828	0.16
294.8490601	0.03
299.2730103	0.92
313.3497925	0.07
317.2411499	0.68
318.2296753	0.09
321.0363770	0.08
338.2175293	0.26
339.3134766	0.03
343.2801514	46.88
348.9669189	0.04
357.3673096	0.41
358.2503662	0.21
359.2069702	0.20
361.2191772	100.00
362.1198120	0.11
366.2570801	0.33
368.1203613	0.06
373.0599976	0.04
375.2194214	0.24
376.2205200	0.17
377.4093628	0.13
389.4161987	0.05
391.2870483	2.16
401.2722168	0.09
403.2490234	24.83
423.3782959	0.17
426.3877563	0.11
427.3544312	0.28
428.1900635	0.05
431.1289062	0.06
433.2572021	0.70
434.8699341	0.06
435.7125854	0.18
448.4431763	0.22
449.4787598	0.12
455.5196533	0.10
462.0634766	0.05
463.2512207	2.78
465.2476807	0.08
477.2130737	3.21
477.8405151	0.03
479.2453613	0.18
485.0189819	0.06
487.3901978	0.10
488.3316040	0.11
504.7825317	0.46
505.6732788	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	393.16
Annotation	Samaderine Z
Peak:m/z	Relative Intensity
113.2120514	0.18
121.0378723	0.05
143.0101471	0.03
151.3470764	0.17
161.0620880	0.12
172.0390167	0.18
183.3470459	0.10
189.3516541	0.18
193.0613251	0.19
203.2227783	0.18
209.1409149	0.18
213.2073822	0.52
217.2208252	1.07
227.0620422	0.17
229.1838684	1.04
229.9613647	0.20
231.3195801	1.40
233.3446045	1.52
243.1312561	1.42
245.0477600	0.16
256.0798950	0.16
259.2729492	1.34
260.4495239	0.14
261.2070312	1.16
269.2911072	1.17
275.0863647	0.65
277.1286011	0.05
285.3264160	0.25
287.2923279	14.91
289.8606873	0.25
291.0545044	0.63
292.9354553	0.15
295.2168274	0.06
303.2547607	0.76
305.2536621	34.03
313.3112183	27.18
314.4598389	0.33
316.9454651	0.43
319.2168884	0.09
321.2745056	0.61
331.2342529	100.00
332.3578186	0.48
333.3498535	0.09
334.9996033	0.10
336.8307190	0.45
343.4223022	0.29
347.0911865	1.45
347.7459717	0.61
349.2357178	34.76
350.1723022	0.49
357.2815247	2.31
363.2990723	0.06
364.1889954	0.29
366.2783813	0.11
375.2085571	57.77
376.4948730	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	787.1923
Annotation	Myricetin 3-rutinoside-7-glucoside
Peak:m/z	Relative Intensity
222.9696960	0.21
257.1389465	0.15
265.2597961	0.02
269.8774414	0.05
301.1438904	3.06
305.3146973	0.01
357.2112427	0.15
385.2699585	0.36
393.3694458	0.03
401.2669678	0.34
411.2156982	0.11
429.3715820	0.09
463.0864868	4.46
477.2281494	0.08
557.4015503	0.13
563.0054932	0.02
587.5143433	0.02
595.2409058	0.04
604.1144409	0.05
607.0891724	0.03
625.2456055	100.00
639.7639771	0.02
641.4113770	0.05
645.1775513	0.03
651.7629395	0.09
671.7180786	0.12
672.4586792	0.35
689.2726440	0.03
693.4127808	0.03
697.3494263	0.01
701.3344727	0.03
704.5557861	0.05
709.1026001	0.06
724.7608032	0.04
725.5680542	0.03
741.3734741	0.01
742.3595581	0.11
743.7410278	0.02
744.3594971	0.06
750.0177612	0.04
757.3992310	0.03
764.6094360	0.12
768.5712280	0.31
769.2142944	0.33
770.4080200	0.06
786.9550781	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	405.14
Annotation	Isaindigotidione
Peak:m/z	Relative Intensity
119.0148773	0.36
127.9470062	1.02
132.2170410	0.24
134.9551239	0.03
140.0946503	0.32
143.1286774	1.30
146.0434875	0.17
155.1491089	0.02
160.2334290	0.03
163.1437836	2.71
166.0906677	0.07
166.8330383	0.64
168.2508545	0.03
170.9969482	0.03
177.0860901	0.12
179.1055298	1.76
182.6818542	0.04
183.3899536	0.07
185.0927124	0.03
192.2339020	0.10
193.0274353	0.10
196.9688110	0.47
198.1983643	0.04
210.0980530	0.90
223.2472534	0.11
225.3496857	0.06
226.2391510	0.16
226.9827728	0.14
227.9847870	0.39
241.0527954	100.00
242.1156311	2.47
243.1504822	1.00
254.0927734	11.17
259.1739197	0.84
266.1293945	0.09
272.1173096	46.97
272.7565002	0.06
275.1355286	0.09
276.2549744	0.25
285.1296692	0.05
288.1703186	4.73
294.1833191	0.12
304.0326538	0.02
306.1135254	54.43
312.2318420	0.06
317.1873779	0.06
324.9333496	0.13
340.3786011	0.04
357.8554382	0.12
359.0784912	4.06
360.1330872	0.10
360.9892883	1.14
368.2583923	0.05
369.0051575	0.04
375.5639038	0.02
376.9107971	0.26
384.2220764	0.03
386.5387878	0.14
387.1844482	2.22
389.1240540	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	518.3226
Annotation	PC(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
166.0185242	0.77
169.0782471	0.09
172.6958160	0.07
184.0012512	79.00
212.1258545	0.30
219.2573853	0.04
241.2397461	0.29
243.2060089	0.26
258.2934570	0.74
265.6671753	0.11
271.3347168	0.10
308.8897705	0.39
310.0213013	0.15
325.4827881	0.10
336.2622681	0.14
346.8452148	0.25
348.3861694	0.13
353.3501587	0.34
355.4286499	0.11
363.3983765	0.10
368.4443359	0.18
383.3055420	0.05
404.2837524	0.18
404.9003906	0.15
414.6157227	0.18
416.3641357	0.19
423.1470337	0.05
428.3284302	0.44
443.6374512	0.23
444.2596436	0.31
451.7564087	0.15
456.3683472	0.11
458.4326172	0.16
464.3017578	0.12
465.3760376	0.27
468.1669922	0.25
468.8639526	0.30
472.3496094	0.11
473.1472778	0.05
477.0353394	0.94
480.6762085	0.46
482.6788330	0.50
483.3153687	0.38
486.5368042	0.28
487.4898071	0.31
495.3673706	0.19
500.4096680	100.00
501.0873413	0.23
502.3229370	0.16
517.6369019	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.1084
Annotation	Hydroxytyrosol 1-O-glucoside
Peak:m/z	Relative Intensity
98.9509735	0.02
105.3534546	0.03
108.0897522	0.04
108.9855728	0.64
122.0241089	0.10
123.0090637	5.72
136.9230499	0.23
150.7339172	0.05
152.9976501	100.00
165.0688324	0.03
176.8441010	0.25
183.8757019	0.05
189.1469269	0.08
193.0442200	0.11
195.4212036	0.02
207.3217773	0.04
215.2590332	0.05
240.0968628	0.09
242.4304810	0.05
268.3540649	0.11
269.3174438	0.07
271.1357727	0.20
272.2319946	0.09
280.9277039	0.04
283.2775879	0.07
284.1612854	0.03
285.0464172	0.14
287.2717590	0.14
295.1288452	0.09
296.9664307	0.34
297.9715576	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	216.9812
Annotation	3-hydroxybenzoic acid-3-O-sulphate
Peak:m/z	Relative Intensity
79.8701019	0.22
92.9724579	1.52
96.8732147	12.40
97.4770813	0.28
108.9739380	0.55
119.0654755	0.03
127.0601654	0.10
136.9364471	100.00
137.8030396	0.04
172.9252167	57.78
187.8426056	0.04
202.3013458	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	447.2818
Annotation	Unknow
Peak:m/z	Relative Intensity
133.0634155	0.03
147.2504272	0.10
176.1191711	0.06
177.2195435	0.02
188.9124451	0.07
191.0424194	0.10
195.1974030	0.09
203.2521973	0.07
207.5011902	0.27
212.0390015	0.02
219.5426025	0.02
226.7718353	0.03
229.6017609	0.02
234.8633728	0.22
251.6476746	0.18
253.8602905	0.02
255.2139587	0.08
265.8448181	0.24
268.9605408	0.23
273.4570618	0.11
274.1187439	0.19
275.1951294	0.17
279.1079712	0.01
286.7882080	0.21
294.6586914	0.11
295.6591187	0.47
297.7741699	0.24
303.1619263	0.03
307.2368469	0.03
311.6169434	0.08
312.9804688	0.09
314.1138306	0.13
315.3381653	0.02
317.2503052	0.12
320.0172729	0.21
320.7341309	0.14
331.0789490	0.02
336.4399109	0.06
337.3760681	0.05
338.4675293	0.21
339.6554260	0.42
341.6396790	0.57
342.4303894	0.11
343.2656860	0.06
344.2114868	0.03
345.3873291	0.05
348.0591431	0.13
353.1376343	0.12
356.4263611	0.12
357.1439819	0.02
359.0637512	0.07
363.6050110	0.30
374.1911926	0.12
378.2447510	0.45
382.3000793	0.03
383.0868225	0.07
385.5013123	0.98
386.8518372	18.72
388.0876160	0.21
389.1345215	0.09
389.7502747	0.11
390.6235046	0.15
394.4227905	0.15
397.4217224	0.05
399.7647095	0.18
401.1470032	0.18
406.0902100	0.06
411.4319763	0.07
412.3182068	0.06
415.7994080	0.06
417.1865234	0.04
419.3485718	0.04
427.2915344	0.04
428.6797485	0.10
429.6694641	0.87
430.3272705	0.66
431.1799316	0.23
432.3245850	0.02
433.4433289	0.15
436.7485657	0.05
438.8436584	100.00
441.1308899	0.96
442.1012268	0.33
442.7592468	0.59
443.7652283	0.74
444.4366760	0.08
445.2908630	0.12
446.0710449	0.03
448.6315002	0.12
449.3633728	0.01
450.0988770	0.09
451.7148132	0.20
476.3160706	0.02
486.6452026	0.05
489.0643005	0.02
503.3938293	0.07
520.3532104	0.57
547.2117310	0.09
564.4255981	0.65
565.5066528	0.18
569.5963135	0.10
591.1331177	0.17
608.5192871	0.15
613.5845947	0.05
639.1373901	0.01
656.3074341	0.19
657.2514038	0.12
668.5067139	0.09
684.4480591	0.06
700.3183594	0.32
701.2869873	0.20
727.3716431	0.05
728.4769897	0.07
744.4865112	0.03
745.6546631	0.04
755.3309326	0.71
756.4666138	0.19
772.4583740	28.80
773.4712524	11.13
774.1403198	0.06
788.5206909	0.01
876.5637817	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	744.8571
Annotation	Unknow
Peak:m/z	Relative Intensity
215.0880127	0.07
228.9449615	0.09
245.0254974	0.26
246.1997070	0.14
247.0043030	0.17
273.0722656	4.57
273.9922791	1.43
275.0567017	1.76
289.0124512	3.52
290.1912537	0.87
290.8894043	0.12
314.9691467	0.03
362.1351929	0.14
362.9317627	0.06
387.0303955	0.80
387.8275757	0.88
388.9779053	1.56
402.9564819	10.84
403.9698486	3.97
405.0715332	4.33
434.9420166	0.12
499.0780029	0.18
500.9321899	2.19
501.9724121	4.01
503.0621948	5.27
515.1439209	0.16
516.9057617	39.58
517.8784790	28.27
518.9889526	29.85
519.9606323	0.09
584.3969727	0.22
588.9473267	0.33
615.9118042	0.24
616.9694824	0.43
617.9614868	0.21
630.8489990	39.92
631.8390503	98.35
632.8073120	100.00
633.5416870	0.53
644.0299072	0.07
645.9963379	0.06
653.6380615	0.17
672.2116699	0.08
672.8936157	0.60
689.5314331	0.13
691.2279663	0.06
698.5963135	0.19
699.6018677	0.58
700.4541626	0.07
701.1126709	0.11
702.0784912	0.27
714.2968140	0.08
717.4826050	0.14
719.2432861	0.11
728.0670166	0.16
728.9810791	0.05
746.8459473	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	297.24
Annotation	cis-9,10-Epoxystearic acid
Peak:m/z	Relative Intensity
96.79982758	0.25
118.9598923	0.06
155.3782349	0.04
156.0614777	0.09
170.0200348	2.43
171.1984406	0.35
176.1042786	0.09
181.0032959	0.08
183.0118256	100.00
184.0218658	11.05
185.1773071	0.17
197.0056763	3.91
198.0728149	1.20
199.0919495	0.03
211.3812256	0.84
212.243103	0.81
213.2957458	0.45
214.0943298	0.05
225.230957	2.33
226.0969238	4.04
227.2328796	0.26
229.1772156	0.10
233.2819214	3.89
234.2579041	0.52
237.3529053	0.10
239.1008911	0.83
240.1620789	2.56
241.081543	0.04
250.9738159	0.06
251.6836853	0.09
253.3777771	3.78
254.2980042	0.67
279.3114929	1.25
281.0852661	0.45
297.2502747	10.11
298.2486877	1.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	209.0303
Annotation	Glucaric acid
Peak:m/z	Relative Intensity
84.9778595	7.98
103.0620880	0.17
110.8709564	0.11
115.0040894	0.01
122.7414703	0.03
128.9489899	1.15
132.8625336	0.08
147.0197906	0.93
151.0500336	0.03
164.9228821	0.03
167.0172882	0.07
173.0250702	1.18
181.1334076	0.03
190.9690399	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
94.98190308	0.59
96.8228302	1.80
104.8252869	0.48
107.8993683	0.58
153.2791901	1.47
160.9730072	2.20
168.9977875	2.13
178.2226715	0.92
179.2173309	0.50
181.0755768	0.97
182.8824158	2.19
187.2227173	0.40
189.1180878	0.52
193.1576691	0.80
194.0066376	0.54
195.3178558	4.38
196.9559021	0.42
205.1170349	0.99
206.6071472	2.69
207.2731781	10.37
208.2790375	4.22
209.2445984	6.49
212.8908844	2.26
214.9308929	24.05
220.387558	0.74
220.9977875	2.51
222.0103149	5.34
223.2226257	15.56
224.0265503	0.64
228.9187622	0.87
233.0462494	8.60
235.9813232	0.61
251.0637817	100.00
252.0823212	8.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	613.157
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
177.0250854	0.15
199.1369324	0.11
209.0992737	0.23
210.0112000	0.05
210.9837799	0.34
211.9464874	0.04
217.2209015	0.02
231.0834045	0.21
231.8299866	0.06
235.0590210	0.20
256.2995605	0.05
257.1702576	0.05
261.8924866	0.04
262.7069702	0.04
265.0559692	0.04
274.3765869	0.01
280.1754761	0.01
288.2919312	0.04
289.2603149	0.06
290.2077026	0.04
298.2871094	0.08
299.1094971	0.09
321.1248779	0.03
322.1743469	0.04
336.5259399	0.03
337.2460938	0.20
338.0257568	0.05
338.9465332	0.01
340.2383423	0.09
355.1362915	47.40
356.1547852	12.46
358.0455933	0.02
372.2653809	0.02
378.7321777	0.05
381.4137573	0.09
391.3879395	0.06
409.1909790	2.16
410.2089233	0.67
419.9174805	0.01
421.3111572	0.06
426.8941040	0.04
429.1354980	0.07
433.2269897	0.02
434.2792358	0.01
442.9129639	0.05
448.2203979	0.04
449.5615234	0.04
451.8509521	0.02
466.1561890	2.79
467.2565918	1.36
480.3675537	0.04
484.1824951	100.00
485.2070312	31.63
494.0321655	0.11
509.9946899	0.07
515.1195679	0.02
519.8338623	0.09
522.6908569	0.07
534.1891479	0.06
538.2313843	1.80
539.2514648	0.94
550.0058594	0.09
551.1305542	0.01
569.1129150	0.05
577.2188721	0.03
578.1911011	0.17
595.2056274	15.66
596.3203125	8.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	402.9168
Annotation	Unknow
Peak:m/z	Relative Intensity
130.8538818	0.02
159.0340118	0.03
174.8996887	0.37
233.1191406	0.04
245.0562744	0.18
273.0715942	3.37
288.9584351	100.00
289.7873535	0.02
328.9134216	0.01
346.9162903	0.14
356.0058594	0.11
357.2707214	0.04
359.2392578	0.02
385.0003357	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	823.2949
Annotation	Correolide
Peak:m/z	Relative Intensity
255.2942047	0.10
327.4300232	0.02
332.3410950	0.05
349.5432434	0.17
463.0589600	0.05
509.2448730	0.02
580.2095337	0.11
627.3320312	0.07
629.2412109	0.08
653.6753540	0.12
654.6500244	0.05
661.4682617	0.03
664.2836914	0.10
665.5053101	0.53
694.7816772	0.05
703.0022583	0.05
722.6277466	0.09
727.6166382	0.19
747.3831787	0.02
755.4711304	1.11
756.4580688	0.32
757.2437134	0.06
764.2774048	0.05
779.2424316	0.02
787.3752441	100.00
788.3696289	44.85
789.0207520	0.43
789.6420898	0.02
791.0471802	0.30
792.3090210	0.05
796.3173218	0.14
823.5975952	0.02
825.6154175	0.31
826.3829956	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.1309
Annotation	4-O-Methyl-a-D-glucosyl-(1->2)-b-D-xylosyl-(1->4)-D-xylose
Peak:m/z	Relative Intensity
201.1688385	0.13
251.1515503	0.30
260.0750732	0.07
320.2472534	0.08
347.0921631	0.16
363.0916138	2.06
381.1470947	100.00
423.3236694	0.20
452.9682007	0.13
525.3153076	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	913.1828
Annotation	[Gallocatechin-(4alpha->8)]2-gallocatechin
Peak:m/z	Relative Intensity
255.2539520	0.18
261.2138062	1.38
269.3986511	0.13
272.9646606	0.07
286.0579834	0.16
295.1533813	0.45
297.0252380	0.35
303.1981812	3.53
304.2268066	0.72
305.0555115	5.14
306.6289062	0.28
315.0123901	0.34
315.9966736	0.07
345.1687622	0.36
346.3055420	0.15
348.1908569	0.13
354.2474365	0.14
361.1325073	0.15
379.0640259	0.45
391.0355225	2.65
391.6423340	0.23
392.3735352	0.48
396.1433105	0.10
397.1287231	0.65
398.3344116	0.18
400.3013306	0.19
403.1535645	0.22
404.3106384	0.04
404.9977417	0.29
409.2319031	1.40
410.1815186	0.04
411.2842407	0.15
421.2353516	0.79
423.1454468	21.91
424.2141724	5.05
425.3230591	0.19
426.2963867	0.16
429.2977295	0.31
433.2777100	0.20
437.1314697	0.07
439.4115601	0.33
441.2008057	12.19
442.2236938	1.32
443.3040161	0.16
451.1726685	0.92
452.1475830	0.19
453.3706665	0.50
455.3533325	0.11
461.2064209	0.19
463.1933594	0.47
465.0818481	2.06
466.0591431	0.38
467.6524658	0.22
470.1116943	0.36
473.1691284	0.07
474.1557007	0.17
478.0637207	0.16
479.0133667	0.05
481.2065430	0.88
482.1723633	0.54
483.2820435	7.03
484.3753662	0.91
489.3940430	0.14
493.3432007	0.25
494.4513550	0.18
497.2968750	0.34
515.1857300	5.21
516.4316406	0.12
525.2096558	0.26
525.9025879	0.06
532.8245850	0.68
533.4981689	0.17
541.1934204	40.01
542.2030640	6.59
543.5649414	0.14
545.5050659	0.17
546.8161621	0.32
551.3878174	0.18
557.3786011	0.69
559.1833496	46.82
560.2388916	9.03
560.9391479	0.11
565.0451050	0.56
566.3135376	0.47
571.3074341	0.35
574.2156982	0.10
577.1190796	56.50
578.2155151	8.28
583.0984497	0.29
589.2155762	1.20
591.3043823	8.53
592.2869263	0.98
599.0664673	0.32
600.7210693	0.28
601.3311157	7.79
602.2223511	2.25
607.1219482	1.20
609.1588745	27.29
610.0658569	3.19
611.0993652	0.29
619.1118774	10.98
620.1361694	1.90
625.2636719	1.12
626.3516235	0.38
630.4531250	1.12
631.3621826	0.44
633.0464478	0.39
637.2717896	0.26
643.4197998	0.31
649.1116333	0.59
650.1078491	0.07
651.3841553	1.44
652.3854370	0.10
657.0282593	0.31
661.1692505	2.83
662.2715454	1.80
667.4855957	0.59
668.3256836	0.19
673.0899048	0.19
676.9639282	0.24
683.2532349	1.83
684.4940796	0.24
697.3139038	0.42
701.3229370	1.87
709.1686401	5.89
710.3937988	0.53
722.3553467	0.11
725.6203003	0.32
727.1473999	100.00
728.2422485	23.60
729.2180786	0.12
733.7088013	0.56
735.1595459	0.43
736.2893066	0.29
743.2866821	0.27
745.1030884	44.47
746.2555542	7.62
747.3970337	0.10
748.2887573	0.16
751.7576294	1.36
752.4448242	0.35
761.2802124	5.44
762.2833252	1.02
765.3212280	0.54
769.1117554	5.22
770.1298218	0.55
775.0596313	0.33
787.1512451	29.98
788.2483521	6.49
789.3810425	0.73
798.6553955	0.05
804.2786865	0.20
805.4109497	0.36
810.9199829	0.77
819.7947388	3.05
820.6735229	2.15
821.5724487	0.20
826.2614136	0.10
829.2711792	0.80
837.0971069	0.31
850.1473999	2.39
851.0043945	0.35
851.8855591	0.16
852.5787964	0.05
869.2352905	0.15
870.1171875	0.13
871.5926514	0.45
876.8930054	0.12
882.9970093	0.07
893.1436157	0.12
894.3502808	0.84
895.3339233	6.70
896.2206421	3.30
897.1805420	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	305.0666
Annotation	Leucocyanidin
Peak:m/z	Relative Intensity
93.0927277	0.06
94.9853363	0.23
97.0448532	0.30
109.1864471	0.78
111.0446701	1.09
113.0111694	0.17
120.8831940	0.17
123.0738907	0.55
125.0040512	21.78
133.1442566	0.26
135.0256653	1.24
137.0081787	19.18
139.0482788	7.93
141.1749878	0.44
145.1004944	0.41
146.8643188	0.84
149.0734100	0.27
151.1451416	1.00
157.2124481	0.18
159.1812744	0.17
161.0299988	7.33
163.1360931	0.61
163.9652100	3.83
165.1135864	29.26
167.0494995	6.81
173.1483765	0.28
173.7843628	0.08
175.0563507	1.69
177.1264343	6.28
179.0009155	100.00
180.1288300	0.22
181.0147552	0.67
184.2387238	0.11
185.7195282	0.23
188.6063538	0.44
189.2288361	1.33
191.0943298	2.98
193.2164612	0.22
199.0084229	1.01
201.1207581	2.74
203.0169067	3.73
204.0001526	5.24
205.0805664	0.22
207.1904297	0.24
215.1740723	0.89
217.1989441	1.13
219.0976257	74.36
221.0814514	88.65
225.1378479	0.30
227.3091736	0.09
228.3187866	0.45
230.9909363	0.61
233.0754700	4.99
243.1262207	7.86
245.2540283	1.85
247.0076294	12.14
247.6725769	0.04
259.2145386	0.18
261.1084290	42.45
261.8696289	0.25
263.0821533	5.66
269.1603394	1.88
277.0810242	0.40
285.2121887	0.26
287.2418823	12.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	485.2011
Annotation	Unknow
Peak:m/z	Relative Intensity
144.9090881	2.40
154.1238251	0.37
162.4835815	1.26
163.0956421	1.19
165.0052795	0.08
166.0436096	0.04
175.1123199	0.21
176.9999237	0.08
201.1949768	0.23
207.0699463	0.08
219.0400848	0.19
235.0400238	0.18
237.0438232	0.04
270.7559814	0.13
271.4156799	0.14
283.2214966	0.09
289.2142029	0.22
295.1260681	0.14
297.4223938	0.05
302.3273315	0.11
307.2098694	0.63
307.8625488	0.29
309.3421631	0.06
314.3511353	0.06
316.1535645	1.22
321.3251648	0.08
323.1524658	100.00
323.7637024	8.55
324.6921387	2.03
325.7838745	1.34
326.8651733	0.40
327.9408569	0.19
328.9922485	0.37
332.4685364	0.14
336.9131775	0.59
342.0114746	0.05
342.9984131	0.39
345.4287109	0.08
356.9544678	0.12
357.9278870	0.15
359.2908325	0.61
369.3286133	0.74
381.9191589	0.07
384.2301331	0.08
386.4155579	0.18
390.6752014	0.66
394.0791626	0.07
395.1385498	14.86
395.8559265	1.94
396.6731262	0.57
397.3474426	0.04
400.8829956	0.16
404.0466614	79.44
404.7921448	4.42
405.5917664	0.94
406.3249817	1.01
407.1086426	0.13
408.2488098	0.37
409.0620422	0.56
410.3220215	0.33
411.2142334	0.18
412.2486267	0.11
413.3062439	0.20
415.0652771	0.23
418.5866089	0.13
420.3327942	0.16
423.1076965	0.06
426.4629211	0.07
427.3935242	0.11
432.3901672	0.07
433.6697998	0.23
434.9549866	0.41
436.9829407	0.24
438.5986023	0.26
439.2272949	0.33
440.1019287	0.43
448.2716370	0.17
450.2295837	0.93
451.2955322	0.13
452.1402893	0.08
453.3097839	0.16
457.6289978	0.16
458.2658081	0.20
460.2074890	0.26
462.1880188	0.47
462.8702698	0.28
464.3258972	0.22
467.2917175	4.32
468.2749329	0.32
469.5478210	0.72
471.2472229	0.71
474.3699036	0.19
476.1025085	3.36
477.1699829	0.26
481.1869202	0.06
492.2445984	2.65
493.1649475	0.20
503.5439758	0.20
515.0867310	0.08
523.4199829	0.59
524.4475708	0.72
571.2179565	0.24
613.3718872	0.58
635.3942261	0.06
636.3014526	0.38
637.0497437	0.05
642.2097778	0.14
645.2211304	79.38
646.2543335	4.51
654.1895142	2.95
655.4163208	0.10
667.6243286	0.09
686.2854614	0.06
706.8287964	0.55
757.3297119	0.24
761.5065308	0.27
788.6785278	0.07
789.3216553	0.98
806.0419312	0.47
807.2966919	11.37
808.0085449	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.09
Annotation	Unknow
Peak:m/z	Relative Intensity
133.7902527	0.03
146.1035461	0.02
151.0148163	0.71
151.9436035	0.36
153.0059509	0.10
160.8403931	0.07
162.9456482	0.03
164.0462036	0.02
165.1175537	0.02
167.0635376	0.02
169.0441895	0.08
170.0274963	0.06
172.9238129	0.02
175.1619873	0.01
178.9813538	1.10
180.0854034	0.41
181.1352539	0.06
186.2915192	0.02
188.2587585	0.06
189.1126709	0.14
190.0622253	0.07
190.9857025	0.15
191.9430542	0.10
193.2588806	0.01
198.0584869	0.02
201.3185577	0.02
204.0672302	0.12
207.1384888	0.09
208.7380981	0.05
209.9863739	0.02
211.3081207	0.08
214.1901703	0.03
214.9198608	0.01
216.2252960	0.03
217.0714722	0.03
218.1063995	0.13
221.0273743	0.05
222.2235718	0.02
223.1613159	0.01
227.1299744	0.01
228.9313965	0.06
230.3765259	0.06
231.2305298	0.01
233.1236572	0.05
234.0695648	0.03
239.2486725	0.01
242.1074982	0.02
244.9398499	0.01
246.3956604	0.03
251.3975525	0.01
253.8489685	0.06
255.1505737	0.07
256.2181091	0.32
257.1995239	0.25
258.1600037	0.04
259.0682068	0.07
262.2467041	0.03
263.0442505	0.01
264.0482788	0.01
270.0167847	0.01
271.1072388	0.23
272.0494385	0.44
273.0885010	0.50
274.1764832	0.28
280.8779297	0.01
283.4714050	0.07
284.2495728	0.02
285.1354980	0.15
286.4799194	0.02
288.2749023	0.02
289.2415771	0.01
298.1319580	0.02
300.1249084	10.32
301.1069336	66.19
302.0895081	100.00
303.0891724	28.73
312.0714722	0.02
313.0950623	0.10
314.1790161	0.14
315.3481445	0.07
316.3679199	0.02
319.2942810	0.04
324.1064758	0.03
325.3368530	0.12
326.0941162	0.16
327.1114502	0.03
328.3136597	0.05
329.2675781	0.01
332.2486572	0.07
337.1529846	0.03
338.1496887	0.08
339.4226379	0.02
341.1167603	0.03
343.2892151	0.88
344.1126709	2.72
345.0540161	0.43
354.2127075	0.02
355.1479492	0.08
356.1392517	0.03
360.2918091	0.04
369.2539368	0.03
374.1481934	0.25
375.5170288	0.01
377.1186829	0.02
380.4195251	0.04
385.2805481	0.01
386.4258728	0.03
387.3043823	0.05
396.1836548	0.06
399.9750671	0.01
401.1074219	0.02
404.1975403	0.06
405.3868103	0.01
410.2943420	0.01
418.1882935	0.01
420.4242249	0.03
421.4985046	0.02
446.1850891	0.19
447.1035156	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.2288
Annotation	L-Linalool 3-[xylosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
162.9831238	0.05
174.8845978	0.06
190.0817871	0.05
203.1571045	0.04
227.4207153	0.04
255.2988281	0.14
272.2649231	0.10
273.2390442	0.10
283.2217712	0.16
284.2853394	0.11
286.0777893	0.10
287.0195618	0.20
289.2714844	0.08
312.3733215	0.10
313.2702026	0.13
315.2654419	0.30
318.0831299	0.03
325.4125671	0.17
329.6493530	0.07
331.2654419	0.45
336.8011780	0.03
345.2409058	0.13
346.3432617	0.41
347.3924561	0.08
363.3470459	0.05
376.0705872	0.07
392.1459045	0.06
393.6215515	0.18
395.5870056	0.07
397.3074951	0.03
399.0074158	0.08
401.2095032	0.14
402.4708862	0.15
405.0425110	0.47
406.2487793	0.75
408.3587341	0.04
411.5335999	0.05
421.3156738	0.18
422.4575806	0.03
423.3544617	0.05
429.3613586	3.26
430.3859558	0.05
432.6472168	0.16
433.4967957	0.72
434.4320374	0.06
435.2735291	0.05
445.3500061	0.12
447.2403564	100.00
447.8819275	0.62
449.1354675	0.99
449.7837219	0.08
451.4180603	0.40
453.9919434	0.12
455.3361511	0.17
457.3200378	0.74
458.1631470	0.17
460.1349182	0.04
463.3115540	0.24
475.3338928	1.81
478.2278748	0.03
490.9599915	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.0509
Annotation	Herbacetin 4'-methyl ether
Peak:m/z	Relative Intensity
93.0504303	0.01
108.0346222	0.04
109.0939789	0.02
120.9536896	0.02
139.0552826	0.01
147.2215271	0.02
150.9112396	0.01
152.0537109	0.01
161.1449127	0.02
163.2616577	0.04
173.2696533	0.02
177.7220459	0.01
181.1106262	0.03
185.2196045	0.01
190.8338928	0.01
192.8314514	0.03
197.9557953	0.01
199.2229004	0.01
209.2369080	0.02
218.2419739	0.02
223.3143921	0.02
229.2503052	0.05
238.1722717	0.04
239.2411499	0.01
242.5548706	0.05
243.2402649	0.15
246.9827576	0.05
252.0615845	0.01
253.1475220	0.12
254.0338135	0.04
255.2485352	0.03
257.2206116	0.04
266.4025269	0.02
267.2283936	0.03
269.1282043	0.31
270.1788940	0.04
271.2376099	0.31
272.1401062	0.12
272.9168091	0.01
277.0614014	0.02
278.8869019	0.12
281.8984375	0.05
283.1313171	0.02
285.3114624	0.03
286.3318176	0.03
287.1882324	0.99
287.8403320	0.01
292.5060120	0.06
296.3192139	0.03
297.2004395	0.39
300.0874329	100.00
301.0761719	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	557.3466
Annotation	Unknow
Peak:m/z	Relative Intensity
165.3055573	0.06
167.1825256	0.03
169.2427673	0.09
175.0183411	0.40
176.9984589	0.81
178.3148651	0.04
189.2352905	0.10
191.2387695	0.14
194.0072327	0.08
195.2113342	0.33
197.0981903	0.04
199.0636749	0.43
207.4075928	0.61
208.4298401	0.05
210.8326569	0.05
217.0891113	0.05
218.9802856	0.12
221.0194702	0.79
223.1514740	0.04
225.1811218	0.21
229.4831848	3.23
233.0814819	0.16
235.2286987	0.16
239.3338928	0.25
240.1714630	0.05
243.0831604	1.09
243.7793579	0.14
245.5400085	0.13
251.6823425	3.66
252.4904175	0.26
253.1144562	0.44
255.3231506	0.17
255.9941711	0.46
256.8969116	0.06
259.2388306	0.35
263.1453247	0.11
264.9541626	1.18
265.5955811	0.01
266.5832214	0.19
267.3679810	0.11
269.1102295	2.45
270.2853394	0.55
273.5321045	4.02
274.1833496	1.16
275.2784119	0.07
277.1608887	0.05
279.1118164	0.07
280.0124817	0.19
281.9042053	0.32
289.8916626	0.76
295.4334106	4.94
296.0946350	1.25
297.6398315	0.90
298.4422607	0.39
299.1544189	0.05
300.5460205	0.33
301.2266846	0.02
306.9675903	0.14
309.1797180	0.55
310.0269165	0.07
311.7454834	0.22
312.9097900	1.01
314.0856934	0.58
315.2651978	0.10
317.5124512	2.40
318.3083496	1.00
319.7712402	4.82
321.0720215	0.05
322.3592529	0.06
323.5141602	0.18
326.1257935	0.09
327.1079712	0.12
328.4163818	0.13
331.4235840	0.04
333.8372803	0.14
337.0375366	0.04
339.6560669	2.33
340.5183716	0.11
341.7438354	7.29
342.7642822	0.51
344.1965332	0.24
348.3087769	0.39
349.5145874	0.11
350.8680420	0.08
353.2374878	1.36
354.2321167	0.14
355.1704712	0.19
355.9846802	0.43
356.8070068	0.72
357.7744751	0.28
359.4027100	0.10
361.5896606	1.28
363.8593750	7.74
364.7282104	0.38
367.3435059	0.10
368.3298950	0.04
370.1836548	0.10
372.2784424	0.14
375.3443604	0.62
376.5234985	0.03
384.0338135	1.53
385.4440308	3.12
386.0572510	1.30
386.6899414	0.65
390.4732666	0.15
392.2384644	0.88
393.1641235	0.27
394.0288086	0.10
397.3466187	0.29
399.7354736	0.49
401.0974121	0.63
402.1535645	0.06
403.0678101	0.09
404.4186401	0.06
405.8771362	0.91
406.7445068	0.25
407.4786987	2.07
408.1066895	1.13
410.1799316	0.04
413.5439453	0.09
414.7355957	0.39
416.4386597	0.07
419.6023560	0.36
423.9582520	0.05
426.1165161	0.13
427.3521118	0.65
428.1423950	0.02
429.6102905	1.40
430.7613525	0.08
432.4035645	0.09
436.2015991	0.72
436.9486694	0.28
437.6835938	0.26
441.1121826	0.15
441.9411011	0.08
443.4735107	0.32
444.7463379	0.69
445.7625122	0.06
447.2388916	0.27
449.4865723	1.51
450.1824951	0.44
451.1010132	0.34
451.7308350	1.20
452.9580688	1.29
453.6110229	0.16
458.4912109	0.09
459.8579102	0.30
469.1625366	0.05
471.4781494	0.13
473.3915405	0.32
474.2611694	0.38
475.4904785	0.32
476.5498657	0.33
480.4351196	0.08
481.4299316	0.03
483.1658325	0.38
485.4782715	0.06
486.1575317	0.06
488.6417847	0.46
489.2762451	0.59
490.0418091	0.17
491.1520386	0.12
494.2474365	0.05
495.6574097	1.16
496.9713135	42.98
497.8619995	6.16
498.6596680	0.95
501.1253662	0.04
502.0097656	0.12
503.6786499	0.22
504.8241577	3.25
505.6475220	0.46
506.4078979	0.53
507.1817017	0.33
509.4220581	0.05
512.4318237	0.19
514.5695190	0.02
517.9639282	0.84
520.2773438	0.58
521.3913574	0.23
521.9944458	0.10
523.8087158	0.03
526.9302368	3.75
527.9351807	0.77
528.9982910	0.14
529.9662476	0.06
531.7486572	0.13
533.1339722	0.92
533.8894653	0.16
535.1920776	0.29
536.4896240	0.02
537.5086670	0.40
539.5293579	1.54
540.2196655	2.81
541.0868530	1.19
542.4165649	0.05
547.2371216	0.15
548.8348389	100.00
550.1572266	2.44
551.0822754	0.30
551.7282715	0.09
552.4381104	0.34
553.1665039	0.22
554.7435913	0.10
556.2681274	0.06
559.9280396	0.11
560.8701782	0.03
564.4331665	0.96
565.4944458	0.71
566.3417969	0.03
567.4938965	0.04
575.0862427	0.03
577.1165161	0.77
578.3430786	0.34
579.4028931	0.11
580.4644165	0.09
585.7318115	0.02
590.5344238	0.14
591.4072266	0.16
592.4689331	0.05
597.2060547	0.07
608.3484497	2.72
609.4013672	1.30
610.3193970	0.11
612.3748779	0.15
616.7446899	0.12
617.3739014	0.72
618.6671143	0.02
620.8721313	0.16
621.8817139	0.06
622.6372681	0.05
635.2730713	0.24
636.3046265	0.09
638.4556885	0.07
639.1621704	0.11
641.6132812	0.09
652.4187622	2.92
653.5237427	2.20
654.4658813	0.18
657.6309814	0.07
659.0232544	0.09
661.2590942	0.15
662.1106567	0.12
663.1089478	0.03
667.1838989	0.07
679.2911987	0.48
680.6507568	0.12
682.3931885	0.04
696.3727417	2.68
697.3749390	0.92
698.2558594	0.23
700.6601562	0.31
701.3519897	0.08
703.1181030	0.05
705.4315796	0.11
706.0952759	0.04
709.5545044	0.05
710.6668701	0.05
711.4175415	0.03
713.0471191	0.14
723.3101196	0.07
724.3248901	0.08
727.2280884	0.14
728.3268433	0.12
729.5642700	0.10
730.5505981	0.04
740.4279175	2.14
741.4044189	1.20
742.4797974	0.55
744.5171509	0.97
745.4603271	0.10
746.3789673	0.17
753.4353027	0.11
766.1403198	0.03
768.8419800	0.05
770.3516846	0.10
771.5502319	0.12
772.3427124	0.11
784.4026489	0.95
785.7116089	0.41
786.6939697	0.22
788.4453125	2.34
789.5713501	1.04
790.7036743	0.10
796.2973022	0.06
797.2528687	0.25
799.2238159	0.10
814.5200806	0.26
815.4705811	0.15
817.0281372	0.33
828.7525024	0.79
829.6508789	0.15
830.4252930	0.14
832.3672485	1.71
833.3532715	0.95
834.1668091	0.25
853.1952515	0.02
859.1359863	0.05
860.3242188	0.26
861.9674683	0.09
874.4689941	0.06
876.4821777	2.62
877.5034180	1.73
878.6282349	0.53
885.2117310	0.12
887.2214966	0.14
904.5255737	0.12
906.3723755	0.03
920.5941772	1.72
921.5518188	0.97
922.5163574	0.60
948.6145020	0.19
964.4982300	1.40
965.6076660	0.45
975.4376831	0.10
992.5344238	4.09
993.6335449	3.25
994.6686401	0.78
1052.5579830	0.06
1075.9052730	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.9393
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9058838	0.30
229.1629944	0.19
257.0655212	0.03
272.9466553	100.00
331.1683960	0.04
341.1881104	0.20
342.7039185	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1217.2402
Annotation	[Epigallocatechin-(4->8)]3-epigallocatechin
Peak:m/z	Relative Intensity
336.7844543	0.20
345.2157288	0.09
355.2391357	0.49
357.1226807	0.23
361.2483826	0.27
371.2403564	0.08
379.1923828	1.04
385.2565613	0.51
387.2385254	0.09
391.2875977	0.06
397.1333923	0.68
403.1809082	0.34
409.3350830	0.14
411.1629028	1.59
413.1435547	0.45
419.0837708	0.06
421.3189697	2.30
423.2785034	7.25
424.3835449	0.28
425.2608337	0.17
429.2517395	1.32
433.2453918	0.73
434.8806152	0.08
437.2081909	0.58
439.1339417	2.83
441.1593323	5.21
441.7870483	0.25
442.4051514	0.04
445.3809814	0.09
449.2005615	0.48
451.2800293	0.35
453.1450806	0.40
463.2617798	0.38
465.0443726	0.83
465.7759094	0.04
468.4093628	0.18
469.1012878	0.15
470.2124634	0.32
470.9837952	0.28
478.9291992	0.19
480.6067505	0.12
481.2493286	3.24
483.1320801	5.05
485.3239441	0.21
487.8171997	0.10
493.3249207	0.36
495.5413208	0.11
497.3275146	0.41
501.3526001	0.10
503.4458313	0.12
504.8856201	0.14
511.3070679	0.06
515.2609863	0.21
517.4591064	0.16
520.3479004	0.08
523.2616577	0.04
525.4128418	0.14
527.8708496	0.15
529.1627808	0.76
533.3539429	0.28
535.3743896	0.25
539.3873901	0.43
541.1701660	1.83
542.2668457	0.17
545.3838501	0.11
547.2091064	5.28
549.2799072	0.15
551.4176025	0.37
557.0203857	0.74
557.7085571	0.51
559.1684570	2.87
560.1794434	0.64
561.4404907	0.13
562.5268555	0.08
565.3078613	3.33
567.2679443	0.69
571.2919312	0.36
573.1616211	0.14
575.4270020	0.24
576.9909668	0.50
577.6318970	0.07
578.5228271	0.08
583.3892822	0.18
587.0627441	0.51
589.0841064	2.16
589.7816772	0.20
591.1409912	2.85
593.1973267	0.10
599.2575073	0.06
600.5256348	0.19
601.2445068	1.58
603.5652466	0.10
607.0987549	13.29
608.0200195	1.06
609.3212891	10.73
610.2513428	0.77
617.4912109	0.74
619.2780762	3.25
619.9666748	0.08
623.3116455	0.21
629.5267334	0.06
631.1030884	0.23
637.3193359	0.14
641.2679443	0.10
642.9642334	0.34
644.3319702	0.04
647.6571045	0.14
648.8642578	0.51
650.0054932	0.13
651.3195801	1.16
652.4036865	0.16
659.2777710	0.60
661.2655029	0.81
665.4390869	0.27
668.6705322	0.16
669.4178467	0.18
673.2337646	0.07
674.7854004	0.45
677.1766357	0.22
683.2142334	1.65
691.4986572	0.17
695.0710449	0.95
699.3578491	0.62
701.1458740	0.76
703.6140137	0.07
706.1558228	0.07
706.8763428	0.31
709.2726440	0.45
710.2446289	0.11
711.2205811	0.17
715.3634033	0.71
717.1847534	0.65
719.1870728	0.89
725.0949097	5.42
727.0978394	13.50
728.1328125	0.52
729.4730835	0.28
732.5940552	0.84
733.2358398	5.59
734.3626709	0.33
735.7738037	0.71
737.3253784	1.20
741.4888916	0.07
743.2391968	2.74
745.0822754	2.60
746.2069092	0.86
751.3452148	0.35
753.4637451	0.08
755.0275879	0.36
756.6593018	0.28
759.1646729	0.25
762.2108154	0.12
766.4671631	0.04
767.0751343	0.26
769.0394897	2.46
773.2016602	0.30
775.1546631	0.22
777.7673950	0.11
779.0529785	0.11
785.1961670	2.78
787.1547852	14.50
788.1530762	1.31
789.4537354	0.07
793.3426514	0.51
797.4030151	0.21
798.1459351	0.08
801.6533813	0.73
819.1540527	1.16
827.5056152	0.78
829.2382812	0.34
830.4569092	0.19
837.3820801	0.35
843.1252441	0.10
845.2635498	10.85
846.2852783	0.52
848.9421387	0.13
850.9497070	1.07
855.2308350	0.06
857.3460693	0.09
861.1427002	0.13
863.1297607	15.11
864.0581055	1.41
867.2282715	0.51
869.0321045	1.58
871.0898438	0.35
872.4600830	0.05
873.3439941	0.26
875.1229248	0.21
879.1315918	0.11
880.6535645	0.16
881.3117676	2.49
885.3424072	0.10
887.2299805	0.63
888.0042725	0.29
888.6634521	0.08
893.2077637	1.29
895.1900635	4.33
897.3015137	0.12
900.1513672	0.04
903.2725830	0.15
905.2235107	5.64
906.2875977	0.60
907.0788574	0.16
909.4881592	0.12
911.1851807	16.65
913.1387939	35.52
914.2525635	1.20
915.4591064	0.15
919.6516113	0.24
923.1066895	4.90
923.9729004	0.43
937.2564697	1.14
947.0755615	0.78
951.2271729	0.16
951.8516846	0.07
953.1890869	0.78
955.0747070	10.39
956.3215332	0.45
962.1729736	0.20
965.2381592	0.59
965.9558105	0.10
967.6778564	0.79
968.4094238	0.25
969.4218750	0.18
976.9541016	0.10
987.5485840	0.41
988.4301758	0.17
995.2218018	0.21
1001.3239750	0.28
1002.5854490	0.14
1005.1163330	1.65
1005.9404300	0.09
1013.2283940	10.30
1014.1491700	0.13
1022.5980220	0.12
1028.9438480	0.25
1031.1489260	100.00
1032.0065920	3.66
1035.5803220	0.17
1037.5996090	0.63
1038.6206050	0.10
1040.3426510	0.13
1047.2387700	0.29
1049.1118160	31.85
1050.0041500	1.51
1050.8139650	0.02
1051.4770510	0.17
1052.2919920	0.43
1054.8135990	0.07
1056.0751950	0.38
1061.0822750	0.15
1063.4390870	0.36
1064.2280270	0.30
1065.4257810	1.65
1073.1461180	4.16
1074.1809080	0.33
1077.9338380	0.08
1079.1719970	0.13
1085.2540280	0.14
1091.1201170	32.15
1092.4238280	0.94
1093.2489010	0.44
1106.1092530	0.07
1115.3991700	0.09
1123.3343510	0.20
1124.1765140	1.78
1124.8459470	0.55
1133.2174070	0.56
1139.4062500	0.16
1144.7467040	0.30
1145.7124020	0.61
1154.3619380	0.26
1155.3194580	0.06
1156.4936520	0.12
1158.5364990	0.08
1169.1086430	0.07
1173.2755130	1.01
1174.2639160	0.45
1181.2641600	0.92
1187.8060300	0.64
1199.1699220	18.73
1200.4042970	2.30
1201.4277340	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	600.37
Annotation	Unknow
Peak:m/z	Relative Intensity
175.1334381	0.08
183.2833252	0.12
209.0556793	0.23
213.0620422	0.31
219.0711060	0.31
220.8884430	0.68
233.2217102	0.23
236.0607910	0.23
256.3559265	0.52
257.1185608	1.60
263.1853027	0.61
264.9565735	0.74
271.2819214	0.10
273.1719360	0.27
275.0959167	0.42
281.8387146	0.10
287.9180298	0.29
289.1811523	0.06
300.0256958	0.29
301.0734863	1.94
304.3999939	0.27
309.0189819	0.85
313.2636719	0.12
316.8953247	0.15
327.2933960	0.54
330.4091187	0.11
335.3865356	0.29
344.8867798	0.29
346.8793335	0.14
353.1567383	1.01
365.7019043	0.15
375.1066895	4.11
378.4478760	0.15
383.5363770	0.24
390.4995117	0.14
396.1712036	0.20
397.2291260	1.19
398.5090942	0.14
415.2850342	1.86
416.4750977	0.14
419.9744263	0.47
426.1651611	0.47
431.0051880	0.05
433.2326050	0.14
439.2321167	0.08
451.4868774	0.26
453.0668335	0.47
474.2073975	0.06
476.9539185	0.36
479.1093750	34.58
480.6837769	0.36
494.6583252	0.32
495.4091797	0.70
517.6876221	0.09
521.1314087	0.06
527.4705200	0.15
528.6738892	0.28
539.3002319	1.36
543.6200562	0.18
547.3303833	0.23
551.1770630	0.74
553.2840576	0.15
554.2587280	0.52
555.0803223	0.12
564.2838745	0.72
564.9901733	0.42
568.7152710	0.29
572.7307129	0.16
583.1928101	100.00
584.0014648	0.12
600.7796631	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.2971
Annotation	Unknow
Peak:m/z	Relative Intensity
178.3859863	0.39
179.1096191	0.43
191.0558777	1.18
220.8139191	0.45
222.9240112	0.21
261.5016174	0.17
262.6734619	0.16
263.4544067	0.06
267.2508850	0.09
273.2523804	0.09
275.3789673	0.12
302.9499512	0.43
310.1820068	0.33
311.3789978	0.05
313.2633667	0.12
319.3275146	0.08
331.2518311	0.10
357.4814453	0.12
361.3746948	0.11
367.3318481	8.04
369.5640259	0.30
374.4769287	0.18
381.1906738	0.13
383.2504272	0.24
385.3600464	27.47
391.2704468	0.11
395.2591553	0.19
399.2852783	0.79
400.1767578	0.19
401.0529175	0.13
409.1313477	0.41
414.8651123	0.56
415.4867554	0.15
419.2243652	0.13
421.1591797	0.11
427.3756714	1.03
428.2267456	0.28
433.4761963	0.23
439.2815552	0.11
441.3416138	0.08
445.3975220	6.37
451.4609375	0.72
460.8988037	1.12
463.3669434	0.20
469.0516357	0.33
471.4595337	0.12
472.2060547	0.18
473.5285645	0.16
475.4241333	0.46
476.3862915	0.18
481.4750977	0.37
482.9231567	0.16
492.6740723	0.58
501.1420288	0.32
503.1354370	0.10
511.5703735	0.11
516.5457153	0.64
517.5564575	0.09
518.8219604	0.18
523.3008423	0.74
525.2025146	0.29
529.4472656	2.80
533.8179932	0.21
542.9172974	0.25
545.1217041	0.30
547.2770386	29.13
548.2255249	0.38
560.5158081	0.70
561.3648071	0.99
563.0991821	3.86
564.2229614	0.19
567.1752930	0.04
570.6604004	0.79
571.3241577	7.11
579.2501831	0.73
589.3937378	100.00
590.2143555	0.94
590.9340210	0.05
598.1997681	0.26
606.9277344	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	568.3475
Annotation	Unknow
Peak:m/z	Relative Intensity
171.2736969	0.02
175.0277557	0.08
177.1256104	0.37
190.9913635	0.15
195.3279114	0.10
209.1935883	0.20
210.7085571	0.03
217.0586853	0.06
219.0143127	0.03
221.0584717	0.43
234.8908234	0.23
251.5226746	0.08
252.7911377	0.05
255.1272430	0.56
262.9907227	0.06
265.1011353	0.65
267.2661743	0.20
269.1093750	2.35
271.4979248	0.05
277.0200195	0.15
279.0918579	0.14
286.3340454	0.06
287.0941162	0.06
291.3372803	0.02
295.2802429	0.66
297.1618652	0.30
305.4083252	0.06
309.1186829	0.36
313.0847778	1.25
314.1522217	0.08
315.5087891	0.05
316.2971802	0.05
323.1353760	0.25
339.3152466	0.32
341.1901245	0.03
343.2018433	0.06
353.1702271	0.19
356.4024048	0.63
357.1660767	1.60
358.0740356	0.18
359.2271118	0.28
360.2060547	0.12
368.4529419	0.06
369.2891846	0.05
371.0687866	0.08
375.1777344	0.02
381.2037354	0.08
383.0444336	0.05
388.1951904	0.03
393.4120483	0.09
395.1779175	0.08
401.1186523	0.17
403.2373657	0.10
411.0488281	0.06
419.3265991	0.49
422.1309204	0.05
426.8421021	0.16
427.4556274	0.14
428.1518555	0.04
433.4779663	0.12
438.5347290	0.21
445.0638428	1.60
447.1967163	0.74
463.2525024	1.67
464.2974854	0.08
465.5426636	0.03
470.4544067	0.02
477.3618164	0.06
477.9971924	0.04
481.2144165	0.05
488.8322754	0.08
489.5725098	0.13
503.3007202	0.15
504.1513672	0.13
507.3487549	0.87
508.8888550	0.17
515.3183594	0.05
521.8107910	0.18
522.4569702	0.02
524.2158813	0.04
533.1427612	1.18
549.4389038	0.25
551.2879639	100.00
559.9505615	0.10
567.3329468	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1399
Annotation	Nitidanin
Peak:m/z	Relative Intensity
147.3293762	0.23
150.9344025	0.05
152.9430847	0.07
161.1321259	0.16
180.2681885	0.06
185.3250275	0.07
198.9724426	0.25
232.9519653	0.08
239.2218018	0.17
241.1019592	100.00
241.7510376	0.09
244.4229126	0.07
283.0965576	0.17
287.1420898	0.07
291.4338074	0.06
297.9838257	0.07
301.1786499	0.09
304.0466309	0.14
305.1901855	0.07
307.2045898	0.44
311.4602051	0.05
313.2464600	0.09
315.2423096	0.26
317.0560303	0.12
322.1381226	0.48
323.0693665	0.18
325.2810669	0.10
327.2224121	0.08
329.4470825	0.60
337.3173828	0.11
338.0693970	0.27
339.1984863	0.53
341.3245850	0.20
342.1963501	0.39
343.3612976	0.70
345.1287231	0.44
346.8282471	0.19
356.0426636	1.09
357.2741394	0.32
357.9368896	0.10
359.0534363	0.34
359.8001404	0.41
361.2547607	0.85
365.2107544	0.10
366.1717834	0.48
367.1717834	2.30
368.5711365	0.16
371.0821228	0.76
373.7705383	0.30
375.0199890	0.10
384.5056458	0.89
385.2672729	2.07
388.0574646	2.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	557.3467
Annotation	Unknow
Peak:m/z	Relative Intensity
163.2484894	0.02
166.2530823	0.09
174.0305786	0.07
175.1054535	0.46
177.0563660	0.98
178.2114563	0.11
185.5273438	0.20
190.9516907	0.08
193.2655334	0.32
195.1376648	0.13
199.2852020	0.55
206.5096436	0.11
207.6756134	0.88
208.6772614	0.04
209.7852936	0.17
212.0372620	0.12
213.0179443	0.03
216.2147675	0.03
219.5227966	0.23
221.0738525	1.58
222.9564209	0.32
224.9434052	0.53
227.3266449	0.13
229.5208740	1.40
230.2161560	0.98
231.4124451	0.10
234.0025635	0.15
235.2612000	0.51
238.3201599	0.21
239.1195374	0.07
240.1461487	0.10
243.1632996	1.05
245.5852814	0.03
249.1872253	0.16
251.6015778	7.09
252.6528168	0.30
255.0793915	0.25
256.1177368	0.09
261.2770996	0.06
262.3035278	0.04
265.1201172	1.34
267.8778381	0.40
269.1268921	3.59
270.2172852	1.16
271.1970215	0.40
272.4325562	0.18
273.4779663	5.15
274.2051392	2.68
275.5786133	1.01
276.9748535	0.34
279.0991211	0.38
282.3673096	0.24
283.1765137	0.13
288.1797485	0.02
289.3588867	0.60
295.5182495	4.59
296.3118896	1.70
297.7341919	2.66
298.6854858	0.37
300.1892090	0.22
300.9365540	0.05
307.2671509	0.08
308.9361572	1.29
310.0541992	0.06
311.7028198	0.80
313.0639648	3.25
314.1253662	0.55
315.2429810	0.07
316.6217651	0.11
317.4959717	3.26
318.1830444	0.53
318.8119507	0.27
319.6140137	3.89
320.3890381	1.64
323.0740967	0.45
323.9115601	0.08
327.4044800	0.15
332.0131836	0.03
333.3118286	0.45
334.0914917	0.24
339.6544189	0.71
341.7152100	5.46
342.5717163	0.43
347.2020874	0.03
347.8653564	0.10
349.0101318	0.35
351.7641602	0.04
353.3338623	0.46
355.5495605	0.24
356.6578979	0.08
357.3758545	0.05
359.0512085	0.42
361.3509521	1.81
363.1157837	1.38
363.7684937	5.77
364.7309570	0.24
367.3868408	0.04
368.0231934	0.06
370.5629272	0.20
372.5660400	0.02
375.2786865	0.41
376.2760010	0.43
377.8137207	0.30
383.4989624	0.57
384.3458252	0.92
385.7150879	4.87
386.4238281	0.05
387.2734375	0.05
388.7858276	0.12
392.2120361	1.02
393.3870239	0.19
394.4207153	0.11
397.1644287	0.18
398.1500244	0.25
400.6058350	0.35
401.2279663	0.26
402.4313965	0.44
403.1682129	0.10
404.1177979	0.58
405.6419678	0.62
407.6752930	1.17
408.3474731	0.20
415.0324707	0.08
418.8578491	0.56
421.6986694	0.08
425.5304565	0.22
426.6302490	0.17
427.5618286	0.74
429.7089233	1.18
430.4031372	0.39
431.3704834	0.08
436.2359009	0.55
436.8439941	0.21
437.6550903	0.12
439.1494751	0.05
440.1533813	0.08
441.0264282	0.44
443.0256348	0.04
445.4191284	0.83
446.2615356	0.37
447.3399658	0.06
448.4225464	0.05
449.4678345	0.24
450.2155762	0.17
451.6860352	2.14
452.8026123	0.74
456.5375977	0.11
459.3925171	0.03
464.7272949	0.50
465.4596558	0.04
468.3143921	0.08
471.2659912	0.09
473.8800659	1.48
474.5341797	0.83
475.2972412	0.46
476.2161865	0.16
483.4462280	0.13
485.3049927	0.08
486.0949097	0.24
487.1325684	0.16
488.1255493	0.95
489.1580200	0.96
490.2936401	0.49
491.4188843	0.04
495.9185181	2.59
496.8088989	56.40
497.4409180	38.42
498.7490845	1.74
499.7963867	0.18
500.7097778	0.11
502.0863647	0.03
503.3966675	0.10
504.7761841	2.77
505.8965454	0.50
506.8435669	0.17
508.1850586	0.05
509.5734253	0.39
510.3433228	0.09
514.4962769	0.09
520.3004761	0.88
522.3590088	0.13
526.7503052	1.68
527.4124146	2.26
528.1828003	0.28
529.2999878	0.16
530.4905396	0.12
531.4166260	0.15
532.3742065	0.25
533.1521606	0.40
534.3487549	0.19
535.1926880	0.09
536.4727783	0.07
537.7030640	0.09
539.4520874	1.66
540.3946533	5.98
541.2235718	1.47
543.3861694	0.25
544.5474854	0.07
545.6618042	0.30
546.3646851	0.04
548.8422852	100.00
550.1503906	1.94
551.2088013	0.84
552.2509155	0.66
553.3346558	0.09
554.1197510	0.03
554.8953247	0.07
556.5268555	0.17
563.6583862	0.19
564.5099487	0.16
565.4740601	0.10
572.9882202	0.22
575.2582397	0.14
577.1026611	0.21
585.4868164	0.03
591.2068481	0.33
592.5147705	0.08
594.2300415	0.12
608.4579468	2.53
609.4675903	1.01
610.0922241	0.37
612.4732056	0.04
617.0895386	0.37
634.4600830	0.02
635.1296387	0.04
636.5200195	0.21
637.5247803	0.07
639.0595703	0.45
640.3148804	0.25
641.3166504	0.12
652.3943481	2.15
653.4475708	1.31
657.5184326	0.14
659.5718384	0.22
660.4600220	0.04
661.4998779	0.09
665.1705933	0.05
667.4244995	0.21
678.8093872	0.08
679.5055542	0.93
680.2177124	0.12
682.3286743	0.10
683.5359497	0.23
684.2409668	0.22
685.6665649	0.08
692.9634399	0.12
696.4196777	4.31
697.3829956	1.96
698.3959351	0.79
700.2254639	0.57
701.6792603	0.12
705.6498413	0.07
707.3403931	0.32
709.3330688	0.16
711.3665771	0.19
722.9706421	0.47
723.6113892	0.12
724.5347900	0.18
725.6665039	0.10
727.0972900	0.38
728.3858032	0.12
730.0025024	0.05
740.3907471	3.50
741.5056763	0.71
742.6973267	0.41
744.5366211	0.75
745.5028076	0.25
749.2842407	0.11
750.4077148	0.10
753.4668579	0.05
755.3511963	0.15
756.6295776	0.08
767.4126587	0.17
768.4686890	0.15
769.3880005	0.10
770.7754517	0.14
772.3466187	0.25
784.4436035	3.21
785.6835327	1.05
786.4575195	0.11
788.5880737	1.39
789.5291748	0.26
792.2593384	0.18
797.4296265	0.22
798.7059937	0.10
799.4065552	0.34
811.3678589	0.21
814.3587646	0.06
815.5931396	0.26
816.4926758	0.28
817.8040771	0.07
818.7203979	0.08
828.5905151	1.67
829.8622437	0.50
830.8705444	0.08
832.3574219	1.84
833.5175781	1.12
834.3336792	0.30
834.9823608	0.04
842.0929565	0.17
855.0034180	0.03
859.5798340	0.09
860.3698730	0.20
861.6474609	0.34
862.7080078	0.06
872.7402954	0.09
873.7055054	0.06
876.4926758	3.38
877.4309692	1.33
878.3994141	0.07
881.5263672	0.08
885.0471191	0.03
893.6024780	0.07
904.3016968	0.07
920.4354858	1.52
921.4545288	0.75
922.5739746	0.30
949.7456055	0.09
962.2470093	0.11
964.3578491	0.75
965.4176636	0.64
966.4535522	0.24
975.1218262	0.08
992.4752808	6.17
993.4833374	2.82
994.7250366	1.67
1055.0036620	0.09
1076.5891110	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	680.1937
Annotation	Unknow
Peak:m/z	Relative Intensity
190.9870148	0.14
196.1107178	1.24
203.0627899	0.18
208.3332977	0.28
210.9503784	0.06
212.9436951	0.11
219.1060181	0.53
220.1300354	0.20
223.2124329	0.12
230.1662598	0.72
231.3905334	0.20
233.0869751	0.22
236.1115265	0.12
237.4939423	0.34
238.2050629	0.28
242.2693176	0.56
243.0756073	0.13
245.3630524	0.07
248.0198517	0.35
251.2465973	0.22
253.2222443	0.21
255.3118286	0.09
257.1600037	0.22
261.2310791	0.06
263.1124878	0.86
265.2796326	0.33
269.0983582	1.23
271.2345581	0.05
275.2570190	0.26
276.9472656	0.09
277.9161987	0.21
279.2612915	0.38
281.2934570	0.37
282.2236938	0.08
283.0692749	0.35
285.2628174	0.16
287.2509460	1.58
289.2042542	0.61
293.1163940	0.51
296.5246582	0.35
297.1932373	1.42
298.3509216	0.41
299.2262878	1.16
301.1777344	0.16
303.1046143	0.46
305.2161865	1.01
305.8734741	0.18
307.3108521	0.26
308.2103882	0.62
309.0524292	0.47
310.2897034	0.11
311.2097778	1.39
313.5404053	0.74
314.2548218	1.22
315.1619263	3.16
317.1192627	3.76
319.2178345	0.68
320.3243103	0.54
321.1490479	0.98
322.3939209	0.37
326.1199951	8.06
327.1246338	3.62
328.0901489	0.08
329.3358765	1.16
331.0288696	0.09
332.1983643	15.52
338.1708984	7.32
339.1203613	8.10
340.2802734	0.25
341.1001282	0.93
343.1383667	0.30
344.2540894	4.13
345.1569519	0.07
346.2586060	0.36
349.0199585	0.28
351.0781250	0.25
356.1695557	5.66
357.1504517	6.36
358.9552002	0.10
360.0029297	0.21
362.3549805	0.28
364.1170654	0.29
370.1221924	0.04
372.4066772	0.25
374.1745605	100.00
375.7119751	2.05
376.3571777	1.52
383.0350342	0.40
388.1857300	0.18
394.2150879	0.18
395.2457886	0.04
416.3175659	0.07
418.3974609	0.57
425.1563110	1.32
441.0787964	0.20
443.1192627	1.78
443.9450073	0.38
449.4414062	0.15
454.3292236	0.19
459.3556519	0.70
465.3465576	0.17
467.0751343	0.45
467.7731934	0.07
469.9184570	0.09
476.2941284	2.55
477.2568970	4.64
483.1459961	0.54
486.9041138	0.14
488.0696411	0.84
489.1439209	0.40
492.3656006	0.54
493.1090698	0.64
494.2249756	84.58
495.2393799	4.61
496.5364380	0.04
498.4567871	0.29
499.9421997	0.12
506.4558716	0.36
508.0889893	0.08
512.1972656	5.86
515.9868164	0.17
517.4119263	0.17
518.0365601	1.31
524.3280029	1.08
530.3591919	0.07
531.2119751	0.06
533.0678101	0.16
536.2041016	0.47
550.1769409	0.28
551.2706909	0.25
554.3670044	0.90
557.0626221	0.44
577.2402954	0.44
583.9347534	0.14
586.8051758	0.70
587.4291382	0.08
596.3591919	0.08
609.2711792	0.13
610.1913452	0.12
610.9448853	0.37
625.3525391	0.10
627.1123657	0.50
635.2120972	0.16
636.0552368	0.07
641.7956543	0.24
643.1196899	0.37
644.3165894	0.58
645.3988647	0.27
646.8964844	0.15
653.2178955	0.21
662.2360229	13.14
663.1927490	3.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	851.7697
Annotation	Unknow
Peak:m/z	Relative Intensity
246.6883392	1.16
266.6013794	0.69
271.0168152	0.25
301.3339844	0.33
305.1423950	0.67
306.4570618	0.76
307.2120667	0.29
325.0493164	0.29
345.7308044	0.83
350.1715088	0.23
358.1954346	0.32
364.6156616	0.59
366.1978149	1.36
367.0396729	0.12
374.2415466	0.26
384.2149658	0.46
387.7583008	0.33
407.1471558	1.26
408.3087769	0.61
417.3042603	0.38
427.1804199	0.12
437.0209961	0.91
437.8001099	0.76
438.4060059	0.29
440.3659058	0.14
447.0953979	12.75
448.0729370	2.32
448.8479614	0.67
450.1461792	0.51
460.3305054	0.17
461.2207642	1.18
467.0595093	1.31
477.3590698	1.42
478.4230347	0.46
479.3078613	0.37
491.2890015	1.12
492.3032227	0.53
493.1038208	0.16
495.5561523	1.23
498.0225830	0.57
499.0489502	1.26
507.9718628	3.64
509.2678833	1.58
510.2824097	0.48
511.4696045	0.54
518.7457886	3.36
519.7103271	0.16
527.6909790	6.70
528.4466553	6.60
529.7130127	0.18
533.2150269	0.63
534.3457642	0.21
540.8233032	0.57
548.1160889	0.47
551.3107910	0.19
552.1921997	0.25
553.3148193	0.70
558.1499634	0.97
563.1818848	1.28
566.3285522	1.04
569.3145752	0.33
570.2051392	0.89
571.6627197	0.38
579.7646484	0.52
580.3888550	0.21
581.3845825	0.51
586.9757690	0.68
588.6749268	8.85
589.3615112	4.21
591.3611450	0.96
592.0390015	0.47
599.6488647	8.33
600.2909546	18.94
600.9411011	6.26
602.0598755	0.36
609.4145508	59.70
610.3387451	7.42
614.4511719	0.15
623.2269287	1.92
625.2448730	1.36
626.2722168	0.39
629.1055298	0.40
630.3247681	0.32
639.2034302	0.64
639.9173584	2.25
642.6254883	1.02
651.4703979	0.24
653.4019165	1.19
658.6045532	1.32
659.4570923	0.17
661.0295410	8.64
661.9252930	2.36
669.7533569	5.35
670.5892944	8.09
671.3192749	0.98
672.1901855	1.91
673.4227905	1.05
681.1934204	34.42
682.0936890	14.62
683.3584595	1.48
685.5300903	0.23
690.3432617	100.00
691.4186401	5.64
692.3886719	1.12
699.9247437	0.19
707.5189819	0.21
709.4815674	1.14
711.8592529	2.03
712.8474731	0.43
713.4609985	0.18
714.3709106	0.70
720.7756348	2.65
721.3804321	1.86
722.0958862	0.38
731.1087646	6.18
732.1550903	9.95
733.1896362	1.08
741.1542358	1.39
742.0527954	12.16
742.8360596	4.13
744.0873413	0.45
750.7992554	70.87
751.6279297	33.58
752.6549072	0.87
753.2997437	0.23
761.1546631	2.23
762.4993286	40.51
763.4178467	4.19
764.8242798	0.39
771.2299194	51.71
771.9533081	59.31
772.9962769	0.91
781.7924194	0.31
783.3921509	2.29
786.3123779	0.74
789.8854370	0.46
792.6403809	4.59
793.6141357	0.84
797.2641602	0.34
798.2050171	0.31
801.9628296	10.91
802.7803345	1.91
804.1486816	0.57
806.9081421	0.90
813.4844971	3.51
814.5381470	1.28
815.3618774	0.14
816.4511108	0.72
817.2003784	0.81
822.1680298	0.20
823.0020142	0.89
831.3592529	0.74
833.2169800	16.38
834.3230591	35.34
835.3045044	13.07
836.2061768	2.09
843.3825684	16.26
844.2183228	2.29
845.7282104	0.93
871.0380859	0.42
875.2991333	0.27
876.3439331	0.92
877.1487427	1.46
878.2766724	0.55
893.2887573	1.96
894.3460693	4.80
895.3865967	2.45
896.2576904	0.72
905.8045044	1.27
923.2765503	8.54
924.2583618	16.31
925.5884399	6.74
926.4858398	1.52
942.4982910	0.40
950.4494019	0.42
952.8934937	0.59
954.3784790	0.17
966.1550293	0.31
971.7001343	0.24
975.1882935	1.87
977.1577759	0.31
978.5742798	1.21
983.9225464	0.21
984.7855835	0.38
995.4199829	1.20
996.3740845	1.58
1013.0448610	0.27
1014.4561160	0.74
1015.9641110	0.41
1037.0175780	1.22
1038.3635250	4.76
1039.3094480	1.13
1055.3688960	7.93
1056.4442140	16.15
1057.3555910	12.59
1058.3444820	2.28
1086.6467290	0.94
1087.5368650	1.33
1098.2067870	0.51
1103.1542970	0.14
1115.9116210	0.61
1116.5480960	0.14
1138.4273680	0.32
1139.3006590	0.73
1140.0490720	0.37
1142.7365720	0.62
1145.3227540	0.43
1156.2418210	1.59
1157.3544920	0.10
1158.3145750	1.86
1175.0368650	0.47
1175.9001460	3.26
1176.7659910	1.55
1198.1013180	0.44
1200.2359620	1.49
1201.3376460	0.43
1216.7104490	2.10
1217.6096190	9.77
1218.4783940	14.50
1219.3488770	11.49
1220.4291990	3.60
1248.7668460	0.38
1250.0362550	0.70
1278.1413570	0.13
1301.6760250	0.09
1318.4165040	0.78
1319.7803960	0.36
1338.2044680	1.38
1339.5404050	1.23
1340.1729740	0.50
1360.4874270	0.27
1361.2174070	2.92
1362.2038570	2.27
1363.2882080	1.70
1379.1340330	0.12
1380.4925540	1.31
1391.8317870	1.07
1409.3652340	0.42
1412.3465580	0.53
1421.5689700	0.31
1440.7674560	0.46
1441.5123290	1.11
1469.9188230	0.17
1482.5264890	0.08
1483.3649900	1.54
1498.9558110	0.57
1500.1494140	2.66
1501.3347170	1.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	307.08
Annotation	Unknow
Peak:m/z	Relative Intensity
130.0160828	58.25
130.9441376	3.97
137.0654144	0.16
160.0673370	0.73
162.0877991	0.69
174.3526306	0.23
175.3169708	0.34
177.0794067	0.34
178.9537964	1.08
211.1290894	1.57
231.0668030	1.68
233.2662659	0.57
234.2700500	0.87
234.9300842	0.21
242.7613525	33.48
243.6215210	0.33
244.8668213	0.60
246.7306213	0.80
247.9727783	0.20
251.5146484	1.06
252.7482300	0.92
257.2509155	1.29
260.4734802	3.10
261.1490479	2.24
262.1404419	0.16
264.9066162	0.08
266.8203735	1.21
268.4096069	0.14
269.7132874	39.13
270.5969238	0.16
271.7038574	0.32
273.9034424	0.43
274.6983948	0.24
275.6817017	63.49
276.6329346	0.94
277.9289551	0.27
280.1577454	0.11
288.3439331	0.88
289.0913696	2.37
290.0621338	1.74
291.5109863	0.32
298.6072083	100.00
299.2811890	13.25
308.0430298	1.11
309.2622681	0.51
319.2718201	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	442.2444
Annotation	Unknow
Peak:m/z	Relative Intensity
127.9443359	0.02
153.2095032	0.04
201.1648102	0.02
226.3254242	0.04
231.0788269	0.04
232.0839539	0.02
243.2429504	0.01
249.0646973	0.26
250.1882629	0.28
252.0080872	0.01
261.2916260	0.02
273.2738953	0.02
279.2136230	0.01
287.0160828	0.01
304.2449646	0.01
335.0726624	0.05
354.2941895	0.02
361.2823486	0.03
362.5029297	0.04
365.4732056	0.02
367.8232727	0.01
378.4128113	0.29
379.8368225	0.04
381.5679321	0.02
386.2094116	0.02
394.2957764	0.03
396.2322083	100.00
397.6753845	0.08
398.3339539	0.08
406.2398682	0.05
410.6327209	0.01
412.2006531	0.04
421.3070984	0.12
422.5632019	0.02
424.1925354	0.24
426.2267761	0.01
433.3163452	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	253.14
Annotation	(+)-trans-C75
Peak:m/z	Relative Intensity
85.12002563	0.29
103.0626068	0.36
105.1620636	0.16
119.2388458	0.54
121.1252136	0.44
132.0338898	0.43
150.7924194	0.27
155.0833435	0.56
159.2177734	0.24
162.7751007	0.29
165.2471008	0.60
181.1150665	0.15
183.9590912	0.15
190.9650116	0.72
193.2210541	0.50
195.2088776	0.22
196.9778595	0.72
205.1985626	0.70
209.1472473	100.00
210.9998322	0.97
211.9421539	0.86
214.7393341	1.31
216.052475	0.34
217.0871124	4.32
217.9128571	0.15
219.4601898	0.15
223.3530426	0.58
225.3316803	2.54
226.0371857	0.43
233.0803833	0.50
235.1597443	6.30
237.197937	2.53
239.0048218	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	175.12
Annotation	L-Arginine
Peak:m/z	Relative Intensity
59.9141426	20.40
69.0456772	0.14
69.9247513	2.22
72.0558014	0.44
97.0060577	0.36
112.0020599	6.62
112.9787903	0.82
114.0660095	4.19
115.9624786	46.62
130.0275421	40.54
131.0945587	0.43
132.9587555	1.36
139.4049530	0.74
140.0339203	6.70
157.0211029	82.06
158.0661621	100.00
166.1627960	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1191.2708
Annotation	Quercetin 3-lathyroside
Peak:m/z	Relative Intensity
367.0962219	0.05
445.0863342	0.74
463.4508057	0.09
475.1932678	0.23
549.2019043	0.17
595.1308594	100.00
595.7578125	0.34
643.3907471	0.55
834.5704346	0.22
981.3999023	0.12
999.2272949	0.44
1039.5949710	0.26
1076.5316160	0.09
1113.5351560	0.08
1169.5595700	0.31
1172.2520750	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	682.1076
Annotation	Unknow
Peak:m/z	Relative Intensity
273.2575073	0.06
309.2317505	0.04
329.0386353	0.19
335.4652710	0.10
339.2351074	0.07
340.3703003	0.07
341.2492065	0.06
342.3127441	0.06
345.1672058	0.04
346.8892212	0.76
351.4636841	0.03
353.9165039	0.05
371.1145020	0.03
376.0095825	0.10
387.3108521	0.06
392.1384277	0.08
411.1827393	0.03
429.0336304	0.16
430.3615112	0.03
434.1304932	3.08
450.2750854	0.23
455.3609619	0.06
465.5065308	0.12
468.1503906	0.06
489.2897339	0.08
495.7269287	0.17
507.2492065	0.16
513.2750244	0.26
514.0078125	0.04
515.3212891	0.05
519.0222778	0.70
531.2059937	0.14
532.5049438	0.06
536.0073853	0.17
551.2291260	1.20
553.5337524	0.06
559.2257690	0.14
564.0651245	0.04
566.1904907	0.40
594.5534058	0.26
595.2201538	0.06
596.4055786	0.25
607.6925659	0.13
621.9382324	0.10
622.8800049	0.08
627.2692261	0.03
635.1022339	0.06
638.0929565	100.00
638.7528687	0.16
639.9871216	0.19
645.4284058	0.18
652.4005737	0.50
659.4971313	0.25
661.1412354	0.04
662.1260376	0.05
663.3903809	0.54
664.3356323	0.43
665.1438599	0.12
668.3344116	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	590.4254
Annotation	Unknow
Peak:m/z	Relative Intensity
175.0912781	0.04
176.9067078	0.08
189.0665894	0.15
207.2139740	0.06
209.0537415	0.05
215.1348877	0.19
221.0561829	0.66
235.1035156	0.70
237.2173615	0.07
246.1842957	0.03
247.4298706	0.14
253.1891937	0.15
254.9964142	0.52
264.9818726	0.92
272.9668274	0.08
279.0310669	0.32
291.2992554	3.40
295.6408386	0.21
297.0665894	0.16
309.1712646	0.34
312.9498291	0.09
315.2625732	0.23
316.9653320	0.39
317.6343994	0.09
319.2882080	0.23
323.0258789	0.65
333.5407104	0.20
335.1747437	1.93
341.3060913	0.05
343.2464600	0.31
349.1542358	0.02
353.1939697	0.31
359.1027222	0.05
378.7017212	1.71
379.3521118	0.31
383.2927246	0.13
397.2839355	0.04
403.5091553	0.40
404.7802734	0.07
405.5890503	0.16
423.1057739	0.30
425.1821899	0.08
441.0932007	0.11
447.3297729	2.59
455.6477051	0.09
464.7365112	0.03
467.2799072	0.48
469.4087524	0.17
472.1118774	0.03
485.2534790	1.91
490.6629028	0.14
500.6643677	0.04
508.9182739	0.18
511.1795044	0.06
525.8510132	0.26
527.5247192	0.13
529.2521973	0.88
541.9187012	0.11
544.4290161	0.06
545.3148193	0.11
554.9896240	0.87
555.6486816	0.31
559.0966187	0.06
559.7235718	0.06
571.3474731	0.39
573.2869263	100.00
573.9572144	0.28
589.6794434	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.1089
Annotation	Herbacetin 8,4'-dixyloside
Peak:m/z	Relative Intensity
173.8476410	0.06
175.1810608	0.05
179.2083282	0.05
180.1168976	0.11
187.4594116	0.12
188.2240601	0.03
191.0712280	0.03
202.3030853	0.02
203.1956177	0.21
205.0143890	0.80
206.0849609	0.10
207.0014648	0.09
220.1909180	0.03
223.0858307	8.50
224.0439758	2.67
225.1086426	0.90
230.1644897	0.06
246.4161987	0.01
247.0180054	0.05
272.8966064	0.06
274.1682434	0.02
291.1730347	0.16
292.3658447	0.12
301.1392822	0.02
306.1113892	0.12
323.2507935	0.02
324.0525513	0.05
325.2162476	0.02
331.0946655	0.05
339.4354248	0.05
342.2276001	0.04
349.2559814	0.08
350.5079956	0.17
351.3237915	0.02
355.2461548	0.03
357.5941162	0.09
367.1339111	0.82
368.1414795	0.90
369.1412964	0.05
385.1008911	18.36
386.1139526	34.61
387.1973267	4.17
401.9978027	0.05
417.4689941	0.01
420.3333740	0.03
427.1739502	0.03
459.3720093	0.07
462.9929810	0.02
489.6608276	0.06
503.5368042	0.05
505.1825562	100.00
505.8632202	0.09
507.8478394	0.01
514.3347778	0.09
517.3634033	0.06
527.9866333	0.02
530.0068970	0.95
530.9074707	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	151.04
Annotation	Unknow
Peak:m/z	Relative Intensity
102.5144348	0.04
109.8616486	100.00
110.6772766	0.04
127.8930359	7.67
130.3834991	2.16
139.2787476	1.58
151.2704315	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	817.0864
Annotation	Unknow
Peak:m/z	Relative Intensity
270.2560120	0.60
288.1236877	0.24
293.1549683	0.09
298.1425476	0.20
329.3540649	0.13
344.1937256	0.20
366.9233398	0.11
395.2329712	0.20
401.3583984	0.69
416.3964844	0.55
429.0897217	0.16
442.9768066	0.08
499.8934326	0.07
556.1020508	0.25
595.3853760	0.30
616.3128052	0.25
685.6029053	0.43
687.3361206	0.11
688.4057617	0.15
732.0362549	1.45
736.3910522	1.54
745.0236206	0.19
754.4985962	1.21
757.1571655	0.53
758.5541382	0.81
759.4064941	0.41
763.3761597	4.38
764.7030029	0.12
767.0156860	0.98
771.2929077	1.27
772.3016968	0.29
774.1685791	1.08
777.5695190	0.89
778.5718384	0.55
779.4878540	0.19
780.2686768	1.27
781.3788452	1.45
782.3764038	0.55
785.0081177	1.91
786.2196655	1.70
787.4980469	1.69
788.5331421	4.12
789.3016968	3.98
790.8920288	6.07
792.0846558	2.03
792.7252808	5.89
794.1508179	1.41
794.9240112	2.22
796.7442627	0.08
798.6069946	3.38
799.7956543	0.92
801.2716064	3.16
801.8932495	8.90
802.5986328	1.78
804.2379761	11.68
805.9063110	7.74
806.6796265	4.45
807.4515991	0.30
808.7163086	3.28
809.5247192	0.46
813.7077026	0.48
818.7359009	0.50
823.8112183	0.20
827.0059204	0.10
844.7479858	0.26
849.8566284	0.71
866.1782227	0.12
874.1135254	0.99
889.0012207	0.33
889.8397217	1.10
899.6823730	0.55
911.6740723	1.03
913.3366699	0.07
918.3920288	0.54
920.6843262	0.44
927.8079224	0.50
930.9140625	1.30
936.1865845	2.08
940.2354126	0.33
941.7852173	0.59
944.4738159	0.71
946.6333008	0.69
950.5949097	0.82
952.0796509	0.53
953.5842896	0.95
956.4673462	0.64
960.8474731	0.55
964.4850464	1.11
965.8324585	0.50
967.3923340	0.44
969.5392456	4.38
970.4597778	1.89
973.4500122	0.24
974.9758911	1.89
975.6776733	4.98
977.6430664	0.39
979.8329468	0.35
980.4448853	1.74
981.1403809	0.42
981.9601440	1.22
983.6713867	0.91
987.9205933	2.45
993.5524902	9.42
994.6093750	5.75
997.4855957	0.38
998.3729858	0.77
999.8159180	1.65
1000.7788700	0.22
1002.2444460	4.16
1003.0369260	0.41
1003.7043460	0.73
1005.2487790	1.35
1006.4168090	0.45
1007.8501590	4.22
1008.6502080	2.41
1009.7730100	0.09
1012.8046880	2.87
1013.9340820	10.75
1014.7489620	0.82
1016.4948730	0.19
1017.5598140	1.86
1018.4768070	6.63
1019.9548340	0.52
1020.7797850	3.01
1021.6111450	22.93
1022.6552730	1.33
1025.5314940	1.61
1027.4011230	13.68
1028.2928470	6.35
1029.3620610	0.57
1031.3017580	8.69
1032.2619630	3.51
1033.2438960	0.10
1034.4376220	4.19
1036.8853760	3.01
1037.9483640	2.06
1039.1506350	0.20
1040.2923580	1.42
1040.9477540	1.15
1043.3374020	1.19
1044.3189700	0.56
1044.9438480	1.41
1045.8061520	6.96
1046.6274410	4.49
1048.0949710	0.64
1048.7827150	0.57
1050.7209470	12.66
1051.8503420	10.11
1052.8183590	0.85
1053.8044430	1.89
1054.5408940	0.98
1056.4688720	100.00
1057.2738040	4.88
1058.5349120	3.06
1059.7636720	8.28
1060.8822020	0.80
1062.0161130	0.08
1063.7640380	0.22
1067.1899410	0.35
1067.8928220	0.26
1104.6435550	0.86
1139.1188960	0.10
1142.2065430	0.06
1160.5616460	0.96
1164.8110350	0.44
1167.0969240	0.49
1167.9416500	0.50
1174.7980960	0.62
1175.9080810	0.80
1196.2082520	0.60
1197.0124510	0.81
1214.1359860	0.26
1224.6418460	0.60
1225.4154050	0.71
1229.6406250	0.63
1232.5075680	2.46
1233.3974610	0.75
1244.6901860	0.63
1253.1361080	0.36
1255.0104980	0.62
1263.1585690	0.21
1275.3354490	1.12
1282.7037350	0.38
1299.1297610	0.09
1302.1021730	0.53
1306.2392580	0.21
1308.9940190	0.14
1323.5765380	0.79
1332.1973880	0.17
1355.1815190	0.48
1356.0191650	0.26
1363.8402100	0.16
1370.6959230	0.39
1374.6597900	0.97
1412.2033690	0.91
1417.1802980	0.43
1425.1343990	0.33
1440.7593990	0.33
1441.4935300	0.57
1445.1966550	0.05
1446.4178470	0.52
1461.5205080	0.22
1462.8325200	0.41
1496.9815670	0.18
1520.4252930	0.58
1535.2595210	0.16
1563.6419680	0.13
1577.3588870	0.38
1605.9984130	0.27
1606.7092290	0.06
1618.4310300	0.44
1708.7054440	0.11
1709.7873540	0.32
1759.2020260	0.07
1784.0896000	0.67
1784.8303220	0.44
1785.6936040	0.05
1800.0637210	0.40
1828.3035890	0.48
1837.0709230	0.14
1875.7771000	0.32
1895.5084230	0.25
1949.9281010	0.12
1967.7530520	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	396.2373
Annotation	Unknow
Peak:m/z	Relative Intensity
132.1300812	0.07
145.1603241	0.07
166.9246216	0.04
172.1396179	0.05
178.0894775	0.01
179.1270447	0.02
180.1255493	0.03
180.9744263	0.02
182.9790955	0.02
190.4176025	0.06
192.4164581	0.01
198.1488190	0.04
201.3850403	0.05
204.8346558	0.02
206.5384979	0.07
209.4359131	0.03
213.1541443	0.03
216.7288971	0.11
218.0847778	0.05
223.9691772	0.01
226.4046936	0.06
227.3054504	0.08
232.8244324	0.03
238.2200317	0.06
240.3715210	0.03
244.1555176	0.45
248.2527771	0.01
253.2764587	0.02
258.2248230	0.42
259.4183350	0.02
262.3232422	1.13
263.1205750	0.04
264.9984741	0.02
267.0958252	0.04
268.0796814	0.03
269.3227844	0.02
272.1714478	0.16
274.3166504	0.09
276.1646729	0.05
279.0525513	0.07
286.3361511	0.05
289.2434692	0.12
290.2055359	0.03
293.2161560	0.01
294.2209167	0.09
298.5508728	0.05
300.4480591	0.07
304.3175049	0.06
306.3794861	0.14
307.0881653	0.02
309.5234375	0.02
312.2437439	0.11
312.8728638	0.03
315.2745361	0.16
316.9891663	0.03
318.3052368	0.01
322.0108337	0.01
322.8985596	0.02
324.2999878	0.27
329.3507385	0.04
336.3680725	0.01
337.0048828	0.08
342.3248291	0.65
346.3928528	0.02
350.1894226	0.01
351.5553284	0.05
352.2197571	0.03
354.8876038	0.02
360.3066711	2.16
364.2571106	0.03
371.4036560	0.03
375.8921204	0.06
376.5005188	0.05
378.3118896	100.00
379.3642578	0.11
381.3725586	0.04
382.5580750	0.06
386.7839661	0.11
390.1343384	0.18
396.1390076	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.28
Annotation	Unknow
Peak:m/z	Relative Intensity
161.1106873	1.00
179.0673676	5.26
187.2995911	0.10
191.0449219	0.15
199.3193970	0.22
209.1378174	0.49
216.9613647	0.03
220.4325714	0.10
221.2397003	0.10
225.1456604	1.33
241.8388672	0.16
249.2315216	0.14
271.9688110	0.11
286.1742554	0.19
293.1979370	0.27
294.0288696	0.32
302.0771484	0.09
307.3475342	0.29
308.3690796	0.10
311.4015503	0.24
317.2745361	0.20
318.0114746	0.49
319.2226562	0.04
333.0897217	0.75
337.0013428	0.31
348.2108765	0.66
349.4266357	0.04
351.2766724	100.00
378.4616089	0.19
380.8848877	0.17
389.1614380	0.19
389.8955688	0.88
391.0699463	0.39
392.1731567	0.69
393.4340820	0.16
409.3808594	0.30
410.7381592	0.18
420.2781982	0.08
426.7043457	0.14
428.0585327	0.23
429.4446411	0.57
430.8729248	0.08
437.3695068	0.40
438.3530273	1.06
450.0911865	0.49
453.1704712	0.05
455.0385742	0.09
456.1563110	0.23
459.3797607	0.34
461.3795166	0.14
462.3081665	0.08
463.0350342	0.25
468.4967651	0.10
471.1513062	0.50
477.5658569	0.47
478.2963867	0.05
479.4923096	0.44
480.3203735	0.17
481.4020386	0.19
485.2416382	0.18
487.0398560	0.39
496.5139160	0.19
498.1144409	1.46
499.3801270	3.94
505.5137329	0.16
511.0890503	0.11
512.5667725	3.12
513.2890625	7.92
514.5702515	0.68
515.6094971	0.42
517.3537598	0.52
520.9325562	0.13
522.0155640	9.42
523.1107788	8.18
524.0254517	5.24
528.3109741	0.12
533.3324585	0.10
537.2169800	0.14
540.1954956	1.90
541.2263794	1.59
542.1644897	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	504.3098
Annotation	PE(20:2(11Z,14Z)/0:0)
Peak:m/z	Relative Intensity
168.1551819	0.27
170.9554138	0.29
177.6050262	0.23
191.8999481	0.08
207.9964905	0.18
210.7863312	0.14
222.0356598	0.06
224.2459106	0.22
235.9084473	0.18
242.2413635	2.11
255.2808228	0.09
271.0496826	0.23
279.3449402	100.00
282.1582031	0.07
300.1330566	0.26
301.1601562	1.91
302.8062744	0.25
312.9925232	0.13
317.5775757	0.24
330.9330750	0.13
343.4682007	0.31
391.4411011	0.11
397.2464294	0.20
401.0254822	0.37
405.8964539	0.16
414.2715149	0.09
415.2735596	0.09
418.1785583	0.07
428.0843811	0.22
433.2626343	0.12
439.2679443	0.09
444.2744446	0.09
449.3700256	0.16
451.4155273	0.33
454.4266052	0.08
458.1496277	0.28
460.1416321	0.30
462.1124573	0.09
463.3373718	0.26
466.2318115	0.47
467.7331848	0.59
468.3661804	6.05
469.4510803	0.39
470.5182800	0.05
472.4203491	0.28
476.2218323	0.15
486.0778198	1.37
487.2312622	0.28
489.1453552	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	280.9926
Annotation	Unknow
Peak:m/z	Relative Intensity
95.1499176	0.17
167.0628052	0.19
219.2967529	0.22
223.0223999	1.57
236.8262024	0.27
239.8550720	100.00
240.9672241	0.18
252.8457031	1.42
253.8790588	0.33
254.6973267	0.38
256.9058838	0.13
257.6187134	1.95
260.3325195	0.56
263.0815430	0.45
263.9886169	0.60
277.2410278	1.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	305.0648
Annotation	Elephantorrhizol
Peak:m/z	Relative Intensity
99.0628815	0.52
109.0181427	2.04
123.8751144	0.06
126.9133377	92.72
139.0379333	4.43
150.9713593	9.13
155.0025330	3.38
165.1977234	0.16
166.9769135	1.61
172.1749573	0.17
179.0423889	44.26
199.1097717	0.03
201.1289062	0.05
212.0916443	0.11
219.0610352	0.30
220.8858032	0.15
227.3909912	0.12
230.1170654	0.20
235.2183228	0.07
241.1852722	0.15
245.1582031	0.12
246.2536011	0.12
258.9261475	1.86
261.0621338	0.69
263.1875000	1.95
263.9761963	0.91
268.1373901	0.09
269.0560913	0.08
273.0816040	0.23
275.1549683	2.63
275.8367310	0.16
277.2079468	37.47
287.1971436	100.00
296.2564697	0.05
305.3407288	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	801.2983
Annotation	Kotschyin C
Peak:m/z	Relative Intensity
228.7698212	0.02
231.2670746	0.13
240.0940552	0.04
242.2864685	0.06
249.0074005	0.05
251.0256653	0.03
253.3696594	0.08
255.2243347	0.03
257.2433777	0.22
259.3078918	0.09
266.4941101	0.10
267.2578125	0.07
268.3260498	0.04
269.2702637	0.37
275.3074951	0.04
276.2673340	0.11
279.2570801	0.03
280.2934265	0.03
281.2280884	0.26
282.5250854	0.53
283.3477173	0.72
284.3058777	0.05
294.0309448	0.04
295.1119995	0.05
300.0405273	0.12
301.2575073	0.64
302.3371582	0.03
303.3668823	0.05
307.6331787	0.01
309.3424683	0.07
310.5227966	0.01
313.2261658	0.11
317.3613281	0.02
319.1405640	0.11
320.2879028	0.03
321.4687500	0.03
323.3721924	0.03
325.0361328	0.15
335.2730103	0.02
337.3490906	1.14
338.2224731	0.40
339.3497314	0.25
340.2218018	0.05
343.2296753	0.44
344.1330872	0.05
345.0870972	0.09
347.3067932	0.03
351.2254639	0.03
355.0841370	0.06
357.1672363	0.19
358.2196045	0.07
361.2296753	0.05
362.1256409	0.08
363.1126099	0.10
364.2366333	0.03
364.9542847	0.02
365.5915527	0.02
373.3539124	0.39
375.4934082	0.02
376.8948975	0.08
381.1862183	0.21
382.3208008	0.10
391.4865112	0.03
393.4569702	0.05
394.4216309	0.04
399.3577271	0.12
400.3630981	0.12
403.2327271	2.12
404.0931396	0.06
409.0938721	0.14
410.3416748	0.05
412.2913208	0.10
414.4689331	0.03
423.1956787	0.05
428.0028687	0.03
431.4267578	0.05
433.2077637	0.03
440.3586426	0.10
441.2812500	0.19
442.3920288	0.08
444.5799561	0.07
445.3693848	0.09
448.2949219	0.07
451.4036255	0.03
452.2724609	0.02
456.0333252	0.06
460.3012085	0.03
463.2296143	0.26
464.2750244	0.02
465.4180298	0.02
467.2801514	0.02
470.3120117	0.28
471.0461426	0.05
472.0957642	0.11
474.2036133	0.04
475.0764771	0.03
476.0983276	0.08
483.4999390	0.06
485.3745728	1.13
486.2799683	0.18
487.3170776	0.95
488.3735962	0.19
492.1511841	0.05
495.5068359	0.04
497.5074463	0.05
499.3168945	0.48
500.6195068	0.25
501.3442383	0.30
502.2889404	0.04
505.3322754	0.09
510.3864136	0.03
511.1058350	0.15
513.0592041	0.03
514.7686157	0.03
515.3941650	0.17
517.1512451	3.57
518.4822388	1.14
519.2828369	3.72
520.4408569	1.36
522.7272949	0.10
525.3645630	0.21
526.4087524	0.02
527.7401123	0.15
528.5217285	0.13
529.2780762	0.09
531.2270508	0.22
532.6004028	0.07
535.5409546	0.10
538.4546509	0.11
539.1220703	0.04
541.4419556	0.48
542.3142090	0.11
543.2753906	0.32
544.3571167	0.10
545.2863770	0.15
546.2566528	0.04
550.9356079	0.24
552.0458984	0.20
553.1659546	0.12
556.5794067	0.05
558.0169067	0.07
559.3549805	0.19
563.4740601	0.21
565.5071411	0.01
567.2444458	0.15
568.4042358	1.36
569.4266968	0.29
571.2682495	1.66
572.4393921	0.37
573.3004761	0.17
577.7299194	0.02
578.4184570	0.02
579.2312622	0.10
580.3724976	0.08
582.4495239	0.31
583.4248047	0.09
584.6801758	0.29
585.4417114	0.08
587.4197388	0.05
592.7822876	0.23
595.7966919	0.22
597.4373169	0.17
599.6358032	0.05
600.3350220	0.02
601.6452637	0.08
603.4755249	0.04
606.7798462	0.06
608.2709351	0.55
609.4622192	0.02
614.3593140	0.05
616.2212524	0.06
617.5460815	0.02
621.3375854	0.21
624.5111694	0.04
626.3004761	0.12
627.5046387	0.21
628.2942505	0.21
630.5728149	0.08
632.5433960	0.02
633.4161987	0.03
634.1595459	0.08
635.5834961	0.07
636.5296021	0.08
639.4724731	0.33
640.2097778	0.37
642.3354492	0.07
644.2893677	0.06
645.3019409	0.05
646.4387207	0.09
647.4190063	0.20
648.5554810	0.03
649.4802856	0.20
650.2717896	0.12
653.4423218	0.17
659.4019165	0.31
660.1964722	0.08
664.3984985	0.40
665.2230225	0.84
666.3121338	0.50
667.6311035	0.04
669.3326416	0.03
670.3717041	0.04
673.7133789	0.07
674.3384399	0.09
677.1356201	0.03
678.3276978	0.56
679.3985596	0.34
680.2823486	0.28
681.3059692	0.47
682.4939575	0.18
684.4472656	0.01
686.6576538	0.19
688.4485474	0.05
690.1784058	0.08
691.8253174	0.10
694.1352539	0.02
697.3683472	0.65
698.2208252	0.04
701.3447876	0.42
702.5090332	0.22
703.6203003	0.16
705.5189819	0.02
708.3952026	0.04
708.9987183	0.11
709.6384888	0.01
710.6564331	0.04
712.4180298	0.07
714.4296265	0.17
723.3392334	0.04
725.3936768	6.82
726.3948975	3.23
727.3598633	0.34
729.3709717	0.24
730.5939331	0.18
736.0645752	0.05
741.2620239	0.35
742.2471313	0.38
742.9255981	0.01
751.3999023	0.98
752.5176392	0.45
754.5350342	0.10
756.1806030	0.02
757.3422852	0.51
758.3889160	0.79
759.4566040	0.75
766.2145386	0.12
767.2544556	0.09
769.3368530	100.00
770.3588257	50.12
771.4397583	0.07
773.4168091	0.90
774.4452515	0.71
783.3965454	1.77
784.4573364	2.01
787.6765137	0.06
801.5896606	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	233.9816
Annotation	Unknow
Peak:m/z	Relative Intensity
145.8367767	0.05
153.9356689	0.12
157.8086090	1.23
162.0221710	0.03
169.9019928	0.32
172.0610657	0.09
173.9199982	7.86
175.8023529	0.34
177.3544159	0.08
185.9564972	16.65
187.1668549	0.35
187.8455353	0.26
188.9780884	0.08
189.9241333	0.28
191.0962219	0.17
192.0122681	0.08
193.0241547	0.17
193.7984772	0.12
197.9662323	1.12
203.8636322	24.06
204.9150238	0.15
205.9115753	0.56
206.8054810	0.08
209.8964539	0.04
210.9619293	0.44
211.7906342	0.03
213.1990051	1.26
213.9018707	0.19
215.8882141	100.00
216.7506409	0.10
218.5716400	0.62
219.2610168	0.13
220.2657166	0.21
221.3220215	0.08
222.2224274	0.19
222.9557495	0.12
224.6472626	2.30
225.5276947	0.12
231.4949951	0.24
233.6470337	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	788.4752
Annotation	Linckoside O
Peak:m/z	Relative Intensity
221.2092133	0.14
224.4240417	0.08
225.1645508	0.18
232.9708252	0.07
235.0661316	0.43
236.1148224	0.02
237.1704559	0.24
239.2042236	0.19
240.2004700	0.02
245.2091827	0.02
248.9561005	0.15
250.4453278	0.04
251.4517212	0.31
253.1291199	0.31
254.3704987	0.01
255.1625366	0.65
256.4014282	0.01
261.2951660	0.03
263.1271973	0.57
264.3173828	0.28
265.1291809	1.19
265.9179382	0.07
267.1342773	0.88
269.1562500	3.70
270.1813049	0.56
277.2846069	0.25
279.0458069	0.47
280.3009338	0.12
283.4404602	0.04
287.2193604	0.05
295.0874939	0.87
296.2244873	0.10
297.0922852	0.38
298.5216064	0.08
299.2374268	0.39
305.3510437	0.23
306.5404053	0.02
307.1882324	0.09
309.0328674	2.63
309.8815308	0.19
311.2009277	0.40
312.1095581	0.25
313.1359558	2.88
314.0624084	0.55
322.7648926	0.30
323.3953857	0.04
326.0708008	0.13
331.3137207	0.15
334.1799927	0.03
339.1177368	0.26
341.0922241	0.10
343.2593384	0.24
344.5443115	0.13
351.0152893	0.35
353.1027222	3.20
354.0532837	0.35
355.3230591	0.22
356.9480591	1.31
358.0299988	0.58
358.9849854	0.11
365.2799683	0.21
367.0679626	0.29
368.1412354	0.12
368.8917236	0.01
372.0424805	0.04
381.0530396	0.02
383.0330200	0.60
385.1199341	0.11
387.1898804	0.43
388.4927368	0.02
395.4590454	0.02
397.1430664	1.72
397.9099731	0.03
398.9179077	0.02
401.0369873	1.27
401.8228760	0.20
403.2362061	0.76
404.0149536	0.12
409.5803223	0.14
411.1067505	0.26
411.9361572	0.04
415.2222900	0.08
420.4314575	0.06
421.1366577	0.03
425.3704834	0.05
427.2033691	0.39
428.8465576	0.28
441.2038574	1.60
442.2800903	0.33
443.2380981	0.15
444.9880371	1.08
446.2004395	0.47
447.1524048	1.26
448.1953735	0.48
455.1146240	0.12
456.3099365	0.08
459.3391113	0.10
463.2276001	0.88
465.0519409	0.08
470.9473877	0.09
472.6050415	0.02
475.0278931	0.12
481.3103027	0.06
485.2523193	1.07
486.0975952	0.17
488.1235352	0.11
489.0962524	1.08
490.1128540	0.16
491.2025146	0.47
492.3568115	0.43
493.3583984	0.04
500.1584473	0.06
507.0899048	0.88
507.8615112	0.18
508.4819336	0.06
518.4943237	0.09
519.2943726	0.11
529.2943726	0.53
530.3645630	0.04
531.0985718	0.11
533.1062622	0.35
533.9381104	0.33
535.2749023	0.65
536.3798828	0.42
544.9439087	0.01
551.2218628	0.79
552.4644165	0.21
559.4155884	0.10
565.5491333	0.06
573.4260864	0.30
577.2269897	0.93
578.1466675	0.08
579.0834961	0.17
579.9519043	0.05
580.7230835	0.04
595.3308716	0.33
596.4463501	0.20
612.7075806	0.05
619.4913940	0.24
621.0534058	0.74
622.1079712	0.12
622.8439941	0.02
623.6161499	0.15
624.4566040	0.04
639.2307739	0.69
639.9049683	0.08
640.5463257	0.02
665.0982056	0.84
667.2092285	2.11
668.2528076	0.71
683.3001099	2.45
684.3355103	0.73
688.0541382	0.20
693.4618530	0.04
709.0855713	0.09
710.1105347	0.06
727.3679810	2.85
728.3566284	1.08
729.0115356	0.03
743.0996094	0.06
752.1270142	0.07
753.2163696	0.94
754.0966187	0.17
755.5637817	0.10
771.2991333	100.00
772.3975830	27.96
788.9596558	0.02
789.6370239	0.06
790.8099365	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	602.2984
Annotation	Unknow
Peak:m/z	Relative Intensity
184.8267212	0.08
255.1519470	0.37
265.3557739	0.04
276.9395752	0.12
283.3878174	0.08
286.9365234	0.08
287.5613708	0.05
290.1931763	0.03
298.8470459	0.11
301.3446045	0.24
314.8578186	0.07
319.2091675	0.13
330.1644287	0.15
333.2393799	0.62
353.3661499	0.03
366.1782227	0.09
371.5952148	0.15
375.2778931	0.04
405.0353394	0.70
414.7233276	0.12
418.3366089	0.06
422.3837891	12.82
423.4303589	0.04
427.4473877	0.21
440.2605591	18.45
455.2169189	0.33
468.9694214	0.06
473.2318726	0.02
481.3416748	0.23
482.6201782	0.02
484.2313843	0.18
487.0256348	0.05
498.4954834	0.11
509.3804321	0.03
512.3524780	0.28
516.1401978	0.44
516.7854614	0.04
525.7832642	0.26
527.1470337	0.05
538.5918579	0.04
541.2731934	0.15
547.4940796	0.33
548.2332764	0.10
557.3554077	0.10
558.0245361	0.03
561.3901978	0.06
567.0101929	2.83
567.6471558	0.50
572.4171143	0.04
575.1728516	0.90
584.3276367	100.00
585.3341064	0.92
593.0479126	0.20
602.3872070	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	635.1396
Annotation	Epicatechin-(4beta->8)-dryopteric acid
Peak:m/z	Relative Intensity
178.9005432	0.30
181.8086090	0.06
182.7512207	0.11
185.1901245	0.06
190.9937134	0.07
195.0907898	0.18
196.9358215	0.14
201.1664734	0.37
211.0359192	0.28
213.3190918	0.43
214.0918274	0.15
214.9412231	0.05
216.4251709	0.03
217.2098694	0.06
223.0010681	0.04
226.6431885	0.29
229.1290283	0.37
239.0497131	0.11
240.1136780	0.22
241.1969910	0.43
243.0953369	0.47
255.0693054	1.95
256.2487488	0.38
257.1324463	1.17
257.9755859	0.16
269.0895996	0.34
281.3877258	0.07
283.1880493	2.43
284.2148132	9.18
285.0883179	100.00
286.2185364	0.25
289.1524048	1.34
297.3483276	0.06
307.2431641	0.26
309.1777954	0.11
323.3896484	0.09
331.2232056	0.31
337.3514404	0.03
349.1882935	6.33
349.9190063	0.08
351.1550293	0.03
368.8234863	0.05
381.1403198	0.04
393.4775391	0.24
394.3387451	0.04
403.2526245	0.07
411.2853394	0.56
429.1994629	1.48
437.1630249	0.08
471.3696899	0.13
487.3458252	0.07
489.2286377	13.64
489.9961548	0.35
497.1545410	0.07
499.0187378	0.04
529.2042236	0.04
539.5706177	0.06
545.0556030	0.09
553.4536743	0.20
557.2070923	0.04
571.4469604	0.04
575.2952271	18.24
576.3306885	1.19
590.5881958	0.30
593.2761230	2.27
594.4050903	0.06
596.5315552	0.12
599.3047485	0.09
606.5594482	0.07
617.6538696	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.1348
Annotation	2'-(E)-Feruloyl-3-(arabinosylxylose)
Peak:m/z	Relative Intensity
131.8521576	0.33
133.0427551	1.83
133.9472046	0.53
138.9690247	0.08
143.2909088	0.05
144.8916626	0.22
147.0100861	0.20
158.0549622	0.12
159.0070953	0.16
161.0945740	5.82
162.9733124	100.00
163.9451294	13.00
173.2947083	0.07
175.9619446	0.18
179.1714020	0.20
184.9830322	0.55
186.9986877	0.06
187.9497070	0.23
191.0569153	0.48
201.1687622	0.11
205.0930176	9.83
206.1565552	1.47
217.0187988	0.87
218.2117615	0.10
227.2970123	0.27
228.3831177	0.10
229.1897736	0.25
235.1964722	1.14
236.1779785	0.22
241.1054993	0.18
244.0611267	0.10
246.1780396	0.05
250.0909424	0.30
257.4331665	0.06
259.2077637	0.08
271.0706482	0.24
276.0795288	0.10
277.3113708	0.10
277.9947205	0.05
281.1369019	2.22
282.2167664	0.81
283.1604309	0.05
293.0866089	1.47
294.1390991	0.37
295.1394348	0.51
296.2917786	0.20
301.9201965	0.04
307.2058411	1.80
308.1328735	0.16
323.2668457	0.28
325.1634521	13.06
326.2057495	1.91
332.7873535	0.05
337.0565186	3.55
338.2444458	0.50
341.0755920	0.36
342.3875732	0.19
343.2606812	0.05
358.7160034	0.12
359.6536560	0.35
360.3679810	0.08
368.0947266	0.05
373.2344360	0.06
374.6078796	0.07
377.4302673	3.22
378.2972717	0.16
383.9585571	0.26
387.3124084	0.11
390.3254089	0.25
411.6247253	0.37
412.3693237	0.73
413.2835388	3.03
414.2278442	1.89
420.0988464	0.17
439.2544556	1.99
440.2239990	1.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	406.2061
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
147.0655670	0.19
163.1547241	0.17
164.0348511	0.34
167.0377808	0.49
191.1862793	2.02
209.1381073	2.13
211.1727142	0.05
223.1359558	0.07
225.2426758	0.19
227.0479584	100.00
231.1431885	0.04
233.0048218	0.08
241.2537842	0.22
244.1377563	0.18
258.3164368	0.12
261.1354675	0.06
271.7850342	0.09
274.3451843	0.06
288.9985962	0.13
299.1434937	0.08
300.2008667	0.20
304.1522522	0.17
314.8139343	0.39
315.6726685	0.12
325.3312378	0.31
327.2427979	0.21
329.2020874	0.11
331.1047363	0.04
332.1247559	0.13
334.3695068	0.12
341.7406616	0.68
342.9486084	0.21
344.4214478	0.19
349.4578552	0.39
353.3936768	0.07
358.2284546	0.32
360.1785583	0.55
361.4595947	0.11
362.3250427	0.90
363.7990112	0.84
364.9687805	0.03
369.4665833	0.07
370.6952209	0.26
371.4132996	0.03
378.4160767	0.05
386.2366028	0.12
387.5882874	2.00
388.7791443	29.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	223.0459
Annotation	Unknow
Peak:m/z	Relative Intensity
82.8203125	0.22
84.8984985	9.72
85.5910187	0.01
86.6513367	0.03
101.1293030	0.20
102.9675140	0.07
110.9827118	8.63
125.0482330	0.02
128.9556122	1.83
132.9999695	0.14
142.9936066	0.31
146.8649902	0.25
158.9591980	0.15
160.9108124	0.67
172.9418945	0.26
177.2175293	0.02
184.5772858	0.03
186.9550781	2.00
191.1724701	0.04
205.0478058	100.00
205.8823242	0.04
208.1505432	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.11
Annotation	Theviridoside
Peak:m/z	Relative Intensity
113.0444565	0.45
121.9866791	0.06
125.1461029	0.23
128.9962616	0.33
131.0720520	0.05
137.1313019	0.12
145.2652283	0.03
146.8582153	0.08
149.0979614	1.02
153.0829620	4.52
160.9905090	1.82
161.9156342	0.08
164.0861816	3.77
165.3225861	0.04
174.8809052	0.27
177.0003357	0.50
179.0567322	1.34
181.0814667	0.06
186.8751678	0.05
190.0957184	4.25
191.1000977	0.74
201.2376709	0.06
203.2540588	0.05
205.0917511	54.75
205.8258514	0.04
207.0028076	0.32
208.0856934	1.34
209.0748596	0.10
218.1028442	0.45
221.0504761	1.53
223.0525818	100.00
231.1843567	0.35
232.0366211	0.52
233.1443176	0.06
235.0160828	0.08
237.2015076	0.84
239.4720764	0.15
240.8075867	0.07
247.1155090	53.33
249.4396057	0.31
251.2049255	0.66
252.3047485	0.25
262.3755188	0.15
263.1425171	0.08
265.0850220	8.42
271.1137695	0.05
277.2431030	1.74
278.9951477	0.22
285.0430298	0.04
289.1857300	1.57
295.1827698	4.60
296.3871765	0.12
305.2604370	0.40
313.3467102	0.26
323.1462708	0.10
325.2081604	4.70
327.2760010	0.11
339.0881348	0.53
340.9792175	0.45
343.2329712	0.10
349.2749939	0.08
353.5210571	0.05
366.2233582	0.08
367.1282349	1.85
368.0809631	0.08
370.2480469	0.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.0933
Annotation	5-(3',4',5'-Trihydroxyphenyl)-gamma-valerolactone-4'-O-glucuronide
Peak:m/z	Relative Intensity
128.9974060	3.33
146.9710388	2.64
163.9640808	0.05
173.0137329	3.46
190.9986267	100.00
192.8819885	0.06
195.0158691	0.07
205.3694153	0.20
207.1302490	0.18
218.0137329	0.03
228.4847412	0.23
245.2577820	0.04
245.9050903	0.03
247.1685791	0.07
267.1730652	0.40
271.2212524	0.42
275.0736694	0.14
278.0891724	0.04
295.3760681	0.10
297.1047974	0.08
306.9302673	0.04
312.5422363	0.03
318.3305054	0.27
319.3699646	0.04
323.3720093	0.08
334.1933594	0.11
336.3007812	0.07
337.1624146	0.20
338.5261230	0.05
341.0173645	0.14
354.3484802	0.17
355.2029114	0.22
356.0774231	0.08
362.4304504	0.48
363.1594238	0.67
365.3069458	0.04
367.1338806	0.07
370.2641296	0.13
379.3504944	0.12
381.0845337	16.05
381.6926575	0.18
382.8662415	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	584.2646
Annotation	Unknow
Peak:m/z	Relative Intensity
171.1021729	0.19
177.0831146	0.77
177.8976593	0.18
178.9983521	3.16
179.8725281	0.09
185.2246857	0.08
196.8450775	0.22
198.3758240	0.11
205.0287476	0.26
210.0418549	3.06
210.9826660	0.49
213.1873169	0.35
221.1474762	0.24
225.4258728	0.09
228.1961365	0.23
235.9321289	0.15
241.9152832	0.21
249.1378784	0.20
254.0642700	14.56
255.1799927	1.74
257.2473145	0.20
272.1602478	16.28
273.0975342	1.34
277.2217102	0.22
278.1915894	0.08
288.1128845	11.50
289.1074219	0.65
291.1077271	0.13
299.0050354	0.13
301.2340088	0.10
306.1135864	100.00
307.1060181	11.30
307.8444824	0.03
314.1080933	0.06
314.9129944	0.14
330.1718140	0.29
343.0945435	0.28
354.9808350	0.09
361.2819214	0.10
362.3389282	0.12
363.4889526	0.11
366.4652100	0.11
370.0867310	0.06
374.3792725	0.04
376.3141479	0.09
377.2312012	0.09
379.2753296	0.08
383.9772339	0.23
393.0932617	0.72
394.0355835	0.16
399.1005859	0.09
421.1373901	0.89
422.2666016	0.64
423.1575928	0.46
430.4225464	0.17
434.3652954	0.05
438.9830322	0.62
455.2813110	2.63
456.2678833	0.26
465.1109009	0.35
471.2161865	0.05
474.1870117	0.11
479.4213257	0.23
481.1724854	0.37
489.1544800	0.15
494.4351196	0.14
495.5443115	0.18
496.9207153	0.09
497.6232910	0.07
498.7374268	0.12
509.2807007	0.06
512.3988647	0.54
539.4253540	3.23
540.5583496	0.73
541.2661743	2.97
548.9859009	0.44
553.2236938	0.12
566.2800903	8.98
567.4064331	1.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	500.9195
Annotation	Unknow
Peak:m/z	Relative Intensity
154.9555054	0.01
159.0698853	3.05
160.0722809	0.42
170.6396179	0.01
173.0324402	0.01
199.0621338	0.27
200.0409241	0.14
217.0229797	0.16
217.9690552	0.02
229.0698242	0.72
230.0289307	0.15
273.0424194	52.74
274.0458069	11.63
275.2856750	0.03
371.3494263	0.01
385.3907166	0.12
386.9525452	100.00
388.0401306	37.70
411.3147888	0.04
427.0528870	0.08
428.2530212	0.03
454.8849792	0.02
456.8496399	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	206.0459
Annotation	4-(2-Aminophenyl)-2,4-dioxobutanoate
Peak:m/z	Relative Intensity
117.9588318	0.08
134.0021973	74.41
144.0343323	26.54
145.9557648	100.00
160.1853638	0.31
162.0372009	51.44
164.1381836	0.23
177.9179535	0.09
187.9947052	4.22
191.1133575	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.1036
Annotation	Mollugoside
Peak:m/z	Relative Intensity
119.1194992	0.04
120.9875031	0.96
122.0157471	0.80
123.0607910	2.64
123.9749756	0.15
131.0505219	0.27
133.0190430	2.74
134.0475159	1.06
135.0639648	1.58
135.9701538	0.55
137.0178680	0.40
139.0528412	0.02
143.0022430	0.02
145.1431274	0.36
145.9422913	0.03
147.1831970	0.30
148.0153961	0.15
149.0421448	0.37
151.0384827	20.92
151.9602203	45.39
152.9855957	10.22
154.0930939	0.77
157.1267090	0.09
158.0297546	0.26
159.0353088	0.20
160.0195007	0.26
161.0599365	1.19
162.9928284	19.34
164.0608826	2.26
165.1554565	0.44
166.2647095	0.05
167.0389099	0.14
170.9073334	0.07
173.1668701	0.09
175.0998840	4.72
176.1214294	0.52
177.0980835	7.84
178.0754089	0.84
179.0392456	17.84
180.0874023	1.79
181.1997986	0.56
183.0414124	0.28
187.0974426	1.13
188.0369873	0.15
189.0397644	0.26
190.2058563	0.14
191.0360107	0.43
192.9988556	2.36
194.0718079	0.47
195.1173096	0.72
196.0650330	0.07
203.2562866	0.01
205.1611023	1.40
206.2149811	0.76
207.1050110	5.91
208.1377411	0.28
208.9547882	0.07
213.2851257	0.01
219.0453186	5.97
220.1080170	1.02
221.1688995	0.07
223.0619659	5.08
224.1658783	0.77
225.1165466	2.93
226.1931000	0.22
229.0285950	0.02
231.0678406	0.51
235.1961975	0.04
237.1188660	1.46
238.1487732	0.18
241.1166992	100.00
242.1821899	11.20
245.1404419	0.03
247.1278076	0.02
249.2077332	0.48
250.1559448	0.08
255.0943298	0.12
262.2157898	0.13
263.1687012	0.16
264.1305237	0.04
267.2213745	10.13
268.1119080	1.02
272.3159485	0.03
283.2988281	0.04
285.1113586	38.45
286.2202454	6.17
287.0416870	0.03
288.2973328	0.05
294.3514709	0.03
297.1035767	0.06
302.3724365	0.01
303.9146423	0.07
309.2119141	0.02
322.1629639	0.10
326.1684265	0.08
327.1462402	0.75
328.3069153	0.21
340.8497314	0.07
343.1890869	0.08
344.1331482	0.06
355.3047485	0.04
356.1523438	0.04
357.0841675	0.05
358.5137024	0.02
373.1766052	4.54
374.2359314	0.51
379.3708496	0.04
381.1285095	0.31
382.0747986	0.11
384.1369629	0.03
387.0453796	0.05
399.1899719	9.20
400.1248779	2.39
402.9248962	0.01
417.5272827	0.04
418.3280945	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.3597
Annotation	Unknow
Peak:m/z	Relative Intensity
164.8999023	0.13
172.7263336	0.56
176.2809448	0.05
177.1448059	1.84
178.0688477	0.27
185.3640289	0.23
186.0399017	0.10
188.0317230	0.28
190.8062134	0.15
192.9348907	0.13
195.3488464	0.51
199.1659088	1.44
207.6407166	1.50
208.9741974	0.67
212.3642578	0.04
215.1900024	0.25
218.7579346	0.07
221.0689240	3.86
221.7447968	1.68
222.9903717	0.07
224.2385864	0.10
225.1929779	1.11
226.0005798	0.08
229.4872131	5.03
230.3570862	0.85
233.1222839	0.32
235.3113556	0.50
236.3630676	0.84
237.9105225	0.14
239.2046204	0.20
240.5137634	0.20
243.1758423	1.72
243.8129272	0.20
245.3456421	0.33
246.1937561	0.61
247.1209412	0.14
247.9962769	0.06
249.4191589	0.11
251.4879913	8.04
252.1712036	1.48
253.1609802	0.15
255.1311798	0.32
256.0606689	0.38
257.4216919	0.08
262.6014709	0.20
263.2089233	0.09
265.0887756	3.89
265.8977966	0.08
267.5783386	1.06
269.1366272	6.17
270.3304443	1.30
271.0972290	0.57
272.3497925	0.21
273.7349854	9.24
274.5511475	0.27
275.8049316	1.58
277.1567383	0.12
278.9545898	0.59
280.2717285	0.06
281.9821777	0.48
283.2621460	0.72
287.0892944	0.35
287.8326416	0.08
289.6397095	0.91
295.4413452	8.40
296.1645508	2.05
297.4585571	8.41
298.3896790	1.83
300.1559448	0.88
301.2603149	0.06
305.1697388	0.06
309.0697021	3.63
309.9263306	0.23
310.7255249	0.54
311.3471069	0.25
312.1614380	1.60
313.0771484	3.09
314.0888672	0.16
317.6594238	5.91
318.7383423	0.49
319.5517578	5.47
320.1605835	4.36
323.2755127	0.92
324.5644531	0.17
325.9169922	0.15
327.4755249	0.38
328.1336060	0.27
332.8538818	0.69
333.6980591	1.55
335.3692627	0.08
338.7670898	1.28
339.5933228	5.04
340.9135132	1.95
341.5735474	6.60
342.3559570	1.85
343.0068359	0.03
348.2484741	1.09
350.4476318	0.11
351.1115723	0.19
353.1666870	1.36
354.1559448	0.13
355.9454956	0.35
356.9031372	0.34
358.4603882	0.05
359.3912964	0.09
360.6795044	0.86
362.1328735	1.49
363.6520996	5.48
364.4397583	1.85
371.3464355	0.08
374.7254639	0.12
376.4815674	0.68
378.0547485	0.89
383.3783569	2.42
384.1939697	0.28
385.4627686	5.28
386.2006226	1.37
386.9826660	0.44
387.6803589	0.17
390.4673462	0.21
392.2221069	1.92
393.4212646	0.05
395.0220337	0.38
395.9735107	0.12
397.1094971	0.75
398.3561401	0.40
399.4328003	0.65
400.4757690	0.48
401.1495361	0.46
402.2338257	0.13
403.0620728	0.10
404.8576050	0.39
405.6731567	0.36
406.4718628	1.63
407.7377319	2.25
408.3811646	0.33
414.4376831	0.11
419.3239136	0.30
420.6815186	0.26
422.3313599	0.29
426.8124390	0.66
427.5513916	1.33
428.9508667	2.20
429.7574463	1.61
430.5767822	0.38
431.5280762	0.28
432.5848999	0.09
436.4114990	1.86
441.0792236	0.15
443.5051270	0.13
444.9941406	1.67
446.2774048	0.30
447.0578003	0.37
447.9876099	0.21
449.9869995	1.76
450.8417358	0.65
452.1801758	3.28
453.0916138	0.04
459.2108154	0.08
463.2322998	0.76
465.3538818	0.23
466.0620728	0.54
467.4053955	0.10
471.5532227	1.24
472.2535400	1.48
473.5569458	2.65
474.8074951	1.81
475.8135986	1.02
476.5474243	0.05
480.4578857	0.85
481.7828979	0.36
482.5853882	0.19
485.3507690	0.25
486.5208740	0.50
489.1408081	1.20
490.3153076	0.51
491.4773560	0.08
495.9564209	1.64
496.7482910	1.23
497.7999878	0.25
501.0081177	0.41
504.7485962	0.06
505.3858643	0.55
510.4966431	2.30
511.2692261	0.49
512.5343628	0.21
517.8502808	2.85
518.9851074	99.94
519.9860229	11.15
520.8591309	0.23
521.7503052	0.43
523.3023071	0.73
524.3069458	1.13
525.3267212	0.53
526.8289185	6.86
527.8524170	2.08
529.0742798	0.11
530.2572632	0.09
530.9239502	0.76
531.9932251	0.95
533.0205078	1.80
534.2658691	1.71
536.1973877	0.10
539.8355103	1.23
544.4262085	0.05
545.7395020	0.51
546.7525024	0.46
547.3633423	0.07
548.4658813	0.40
549.1243896	6.29
550.2433472	0.44
557.2083740	0.63
559.3806763	1.49
560.0305176	0.54
561.5797729	1.32
562.3547974	6.03
563.1493530	2.08
564.0576782	1.25
564.7230835	2.09
565.4025269	0.16
566.3010864	0.22
570.8818359	100.00
572.1807861	1.54
572.9564209	1.40
573.5684814	1.48
575.3255005	0.39
583.7179565	0.36
591.1344604	0.99
591.8364868	0.17
592.7067261	0.15
606.5040894	0.45
607.1456909	0.24
608.4450073	3.67
609.4707031	1.04
610.6463013	0.13
612.2058716	0.04
613.4807739	0.06
617.2653198	0.34
618.5371094	0.60
621.5646362	0.25
623.4259644	0.18
629.5949707	0.25
636.5815430	0.14
649.4918213	0.10
650.5526733	0.22
652.3591309	5.10
653.4813843	1.13
654.5243530	0.55
661.1232300	0.74
662.4702759	0.60
663.4051514	0.06
664.2171021	0.25
668.0377808	0.05
679.5094604	0.50
680.4780273	0.45
681.5075684	0.08
682.3446045	0.29
684.4335938	0.11
694.6299438	0.31
696.5134277	5.61
697.5396118	1.46
698.7205811	0.11
700.2390747	0.54
701.8523560	0.26
703.0662231	0.13
705.1589966	0.72
722.8626709	0.05
723.4915771	0.61
724.3080444	0.07
726.3540649	0.18
728.5724487	0.27
738.1528931	0.14
740.3359375	5.81
741.5732422	2.93
742.2733154	0.18
744.3728027	1.96
745.5005493	0.62
750.5693970	0.09
754.5231323	0.30
761.5029907	0.10
766.4221191	0.26
767.4389038	0.81
768.7088013	0.74
770.2852783	1.02
772.1555786	0.46
773.4685669	0.22
774.2353516	0.09
784.4101562	5.70
785.5317993	1.70
786.6314087	0.28
788.3991089	2.56
789.7205200	2.02
790.3551025	0.20
793.7153931	0.04
797.3323364	0.16
798.2525635	0.10
811.6891479	0.62
814.8397827	0.23
815.7715454	0.19
816.3750610	0.16
817.5926514	0.05
828.4616699	4.13
829.5646362	1.87
830.5896606	0.09
832.5197754	2.31
833.3820801	1.73
834.6674194	0.30
839.5503540	0.06
842.4052124	0.15
849.4978027	0.16
858.3052368	0.18
859.3196411	0.39
860.5338745	0.71
861.4443359	0.14
872.3665161	1.44
873.4850464	0.75
874.5648804	0.65
876.5073853	2.88
877.4946899	2.27
878.4542847	0.73
884.5583496	0.10
886.3123169	0.18
888.4390259	0.08
904.4158325	0.27
916.5871582	0.64
917.5839844	0.14
920.5485840	4.20
921.6342773	2.00
922.5033569	0.36
929.2470703	0.23
948.1906128	0.12
949.5944824	0.10
964.5126953	3.49
965.5866699	1.55
992.6835938	0.11
993.6345825	0.24
1008.4873050	1.89
1009.6008910	1.47
1010.8120120	0.35
1019.8788450	0.15
1036.4958500	6.87
1037.5072020	1.93
1038.5438230	1.35
1039.2729490	0.07
1057.8367920	0.36
1112.4296880	0.47
1119.8051760	0.29
1121.9954830	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	368.2059
Annotation	Isariotin D
Peak:m/z	Relative Intensity
107.9630280	0.02
113.9217453	0.04
115.9073486	0.04
118.9191589	0.07
122.2463608	0.04
124.1210251	0.01
125.8278046	0.09
128.9529572	0.03
131.9250031	0.62
133.2479553	0.07
134.9437866	0.03
143.0925598	0.06
145.2532043	0.21
146.0888824	0.08
147.2039642	0.10
158.4708710	0.04
159.0974731	0.10
162.1020813	0.22
169.1026306	0.04
171.0327759	0.25
172.0772858	0.08
173.0911407	0.19
174.1072540	0.04
178.1175842	0.09
180.0342255	0.14
182.9972382	0.05
184.8342285	0.02
191.0158691	0.02
196.3631439	0.03
198.5519714	0.47
199.3398743	0.16
201.2297821	0.04
203.3690338	0.01
205.9872284	0.05
209.1710510	0.03
211.0742493	0.05
213.1166229	0.11
214.2728882	0.07
215.3117371	0.20
216.0041656	0.05
216.9700623	0.33
218.9021912	0.03
225.2471313	0.02
228.0159912	0.08
230.2622681	0.11
234.1906433	0.12
235.3099976	0.02
237.2034607	0.06
240.2648926	0.08
244.2341919	0.05
246.3793640	0.18
248.1163635	0.37
249.2072144	0.18
250.1666870	0.26
253.3469238	0.07
254.2099609	0.07
255.2129822	0.04
256.3925781	0.18
260.2265015	0.23
266.2886963	1.05
268.2729797	0.13
270.4378967	0.07
272.2278442	0.20
274.2576904	0.16
276.1423645	0.28
278.2534790	1.45
279.5781555	0.03
284.2751465	4.73
286.1119080	0.13
290.3512573	3.13
294.3071899	0.32
295.2221680	0.09
296.1875916	3.87
297.1457825	0.02
302.2823792	1.06
303.9675598	0.22
308.1154785	0.04
310.3412476	0.02
314.3201294	8.09
322.8552551	0.11
323.4813538	0.03
324.5695496	0.08
332.3123169	15.18
341.1140747	0.07
348.2812195	0.06
350.2521667	100.00
362.1352234	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	372.07
Annotation	Unknow
Peak:m/z	Relative Intensity
114.8926620	0.02
128.9423523	0.67
130.1143341	0.17
135.2726135	0.10
147.1481018	0.23
147.9900208	0.12
164.8872375	0.03
167.1368408	0.37
168.2663574	0.11
168.9685059	0.09
173.9486084	0.11
177.1932983	0.02
178.9773865	0.02
180.1826019	0.27
183.1490784	0.02
186.9867859	0.07
191.0442047	10.52
192.0139465	2.91
197.0640564	0.03
207.2480927	0.20
209.0264587	100.00
210.1205444	17.07
212.1768036	0.05
225.3339844	0.05
233.1815491	0.36
237.1256714	0.07
243.3315735	0.06
251.0269165	1.08
252.2518616	0.25
253.3111877	0.11
256.3033447	0.08
279.2458496	0.02
281.4196167	0.24
282.2037659	0.03
283.3005676	0.04
286.9470825	0.32
288.2221375	0.05
291.1037292	0.02
294.3118591	0.04
295.6314697	0.07
301.8164368	0.20
303.1044617	0.08
308.3735657	0.02
309.3045349	0.26
310.1372681	0.15
315.3255005	0.05
326.0151672	0.41
327.4666748	0.08
328.6401062	0.14
334.8599854	0.06
335.7362671	0.02
353.0886841	14.85
354.1766968	8.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	616.2885
Annotation	Unknow
Peak:m/z	Relative Intensity
207.1891937	0.04
240.2167816	0.06
257.1086731	0.05
275.2562866	0.05
293.2752075	0.10
298.2094727	0.07
308.6244507	0.05
322.3497925	0.21
333.1732788	0.05
348.2965698	0.10
365.0759888	0.12
366.3098145	1.19
367.6510620	0.16
384.2777710	4.17
391.2244263	0.20
400.2102661	0.19
401.1380615	0.08
402.3276367	0.34
406.9736938	0.04
412.2539673	0.10
419.0629272	0.20
437.1111450	0.37
446.4096069	0.11
451.4590454	0.04
453.7261353	0.14
463.9135742	0.04
469.2996216	100.00
469.9171753	0.17
479.2610474	0.05
487.3723145	1.31
517.9290771	0.06
518.6373901	0.04
523.4314575	0.47
532.1100464	0.29
541.3901978	3.15
542.0363159	0.02
553.2282104	0.48
554.2715454	0.24
557.5873413	0.18
558.4412842	0.07
575.7125854	0.41
580.3582764	0.11
597.2717285	0.24
598.4702759	1.04
599.3710938	0.30
607.2796021	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.3396
Annotation	Unknow
Peak:m/z	Relative Intensity
175.3132324	0.16
186.0912170	0.03
196.3299408	0.13
207.3992615	0.23
209.0717316	0.43
210.0399780	0.08
219.0162354	0.11
221.2608337	0.03
223.2326050	0.15
229.6326447	0.42
242.9681854	0.09
251.5640259	0.98
267.2880249	0.27
269.1400146	0.14
273.5369263	0.30
274.2302246	0.11
287.0375366	0.11
291.5174561	0.05
293.2567444	0.08
295.5903931	0.45
296.2297974	0.08
297.6433716	0.11
309.9736328	0.10
313.1457520	0.35
321.2980957	0.15
327.9787598	0.25
329.1481934	0.18
331.0847168	0.35
339.5045166	0.12
340.1743774	0.12
341.4830322	0.42
348.4038696	0.15
349.2194214	0.10
350.1936646	0.07
353.2435303	0.13
356.6481934	0.37
361.7455444	0.12
367.2167969	0.05
371.4799805	0.33
372.4260254	0.25
373.2318115	0.48
373.9436035	0.08
375.1921997	0.09
384.1743774	0.12
385.6777954	0.11
394.0166626	0.47
400.5048218	0.12
401.2056274	0.10
403.2905884	0.04
407.8336182	0.15
415.3779297	0.05
416.9911499	0.51
422.8920288	0.09
429.2545776	0.16
431.0427246	7.27
431.9112549	0.04
434.0863647	0.04
436.4397583	0.08
437.7734985	1.27
443.9965210	0.04
452.0807495	0.48
461.0503540	0.09
465.0402222	0.03
474.4152222	0.74
475.9710693	0.25
480.3511353	0.31
482.9009399	100.00
483.9829712	2.39
484.7838745	1.21
485.5473022	0.49
486.4276123	0.31
487.5741577	0.35
488.4683228	0.40
489.0964966	0.13
490.7640991	0.79
492.2581787	0.04
493.3966675	0.13
494.1242676	0.11
496.3000488	0.20
506.6447144	0.20
512.6260376	0.55
514.1412354	0.11
516.8789673	0.21
520.5187378	0.33
525.1532593	0.09
526.0320435	0.54
527.3339233	0.09
534.6798706	9.16
535.6112061	0.86
536.9583740	0.35
537.9138184	0.09
540.0964966	0.10
543.7968140	0.10
546.9119873	0.09
564.3018188	1.01
565.6379395	0.06
593.3770142	0.12
608.3544312	0.74
609.5305786	0.18
635.2041016	0.28
637.2812500	0.17
652.5076294	0.33
656.4628296	0.05
696.5692749	0.47
697.6428833	0.03
700.3263550	0.13
716.6461182	0.10
717.5275269	0.06
725.3026733	0.10
727.3950195	0.09
740.6427612	0.15
744.5853271	0.18
760.1938477	0.18
770.5063477	0.07
771.4764404	0.16
772.1267700	0.06
773.3694458	0.11
786.5155640	0.10
788.3938599	0.08
789.2658081	0.03
804.4526978	0.08
805.3114624	0.06
832.0980835	0.08
842.9209595	0.09
844.1841431	0.13
848.3002319	0.75
849.4402466	0.33
858.5105591	0.14
860.4916382	3.78
861.4315796	0.83
862.1620483	0.12
876.5998535	0.08
877.6748047	0.16
892.4846802	0.19
920.4562988	0.10
936.6718750	0.02
948.5959473	0.19
964.4897461	35.45
965.5166016	16.18
966.2829590	0.05
983.4292603	0.09
1068.6406250	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.1951
Annotation	Unknow
Peak:m/z	Relative Intensity
122.9138947	0.08
153.2053070	0.60
182.8069458	0.18
188.8591919	0.23
216.0484314	0.16
219.1591797	0.26
221.1208038	0.08
224.9749756	0.05
231.2022400	0.11
233.2745972	0.13
253.8400574	0.35
259.3839722	0.04
261.3377991	0.27
267.2944336	0.05
277.2091064	0.59
283.2458496	0.18
288.9611816	0.36
295.3879395	0.07
301.4600830	0.17
304.5689697	0.15
317.5788879	0.11
334.0316772	0.09
335.2989807	0.09
337.3742065	61.13
338.3032227	0.37
338.9670715	0.07
349.0319824	0.15
353.3154907	1.22
354.3410645	0.86
355.3153381	100.00
357.2606506	91.17
358.3791199	0.13
371.1573792	0.40
373.2223511	0.54
374.1263733	0.69
380.4248657	0.11
381.2872314	0.98
382.2647095	0.10
385.1352539	0.16
389.2602234	0.35
390.5573425	0.07
398.2258301	0.69
399.3865051	3.14
400.2923279	0.29
401.3512878	0.52
402.2486572	0.34
411.2403870	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.1037
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
137.1658020	0.05
142.7888489	0.03
144.4589233	0.10
148.8324127	0.05
151.0808716	0.11
160.9669647	0.15
168.9864807	0.06
173.0999908	0.19
175.0839539	1.77
177.0515594	3.27
179.0504761	1.55
179.9031219	0.08
181.1781616	0.26
189.1586609	0.43
192.9690704	0.06
197.2573242	0.10
198.9253540	0.17
214.1012115	0.20
215.1433258	1.92
216.5601044	0.89
217.1988220	5.86
219.3519897	0.35
221.2545471	0.13
225.6174316	0.15
231.1988068	0.30
238.5091858	0.07
241.1303101	0.36
243.3412170	0.14
254.1702881	0.11
256.8388672	0.39
259.0883789	32.41
261.1401367	0.41
265.3499451	0.06
267.1967468	0.45
275.1763916	7.13
277.2893372	0.06
282.8079529	0.14
283.6520996	0.26
285.0614929	100.00
285.8413086	0.03
287.0715332	0.08
288.3094482	0.09
288.9758301	0.31
298.5914612	0.19
299.2166138	0.92
300.4609070	0.16
301.1100769	1.05
303.1506958	40.33
306.7762756	0.07
308.4981384	0.04
309.1115112	1.47
311.1734619	0.81
313.1245117	0.18
321.8896484	0.20
325.1171265	0.22
327.1428528	1.23
329.4317017	0.18
330.1437988	0.10
331.2186279	0.07
333.2329102	1.18
337.3528442	0.12
338.9707642	0.65
341.1442261	0.48
341.9016418	0.19
343.3188171	0.43
344.1506348	0.30
345.1952515	1.13
347.1585999	0.40
349.1959229	0.55
351.3771667	0.32
352.9891052	0.04
357.1300659	0.23
359.2890015	0.07
369.3486938	0.69
377.0918884	0.45
379.1168518	2.82
381.2019348	0.71
391.9364014	0.19
393.4747009	0.46
397.0896301	0.20
403.6856079	0.11
405.1210022	0.33
418.9450989	1.80
419.5832214	0.26
421.2454529	17.35
423.2976990	0.06
429.5180664	0.06
431.5668030	0.20
435.4903870	0.15
437.1863708	95.17
444.8753662	0.21
447.1299744	65.39
448.0071106	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	203.0826
Annotation	Ethotoin
Peak:m/z	Relative Intensity
71.8966293	0.41
73.9120331	0.74
74.9407578	0.08
79.9001923	0.63
93.0808105	0.05
108.0104370	0.12
115.9536591	32.35
116.5637360	0.18
122.9871063	0.81
127.8965607	0.47
129.1241608	0.28
129.9969177	0.79
132.1152496	0.36
138.9532166	0.04
141.9836884	15.88
144.1136322	0.04
157.1329193	0.27
158.9982910	100.00
160.9262848	0.10
172.9732361	1.81
175.0953674	0.21
176.2136993	0.03
185.0375519	0.95
186.0124664	9.75
186.8752747	0.03
203.0195465	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	864.5231
Annotation	Unknow
Peak:m/z	Relative Intensity
245.1613770	0.02
249.1347504	0.13
251.2768250	0.97
253.2976379	0.52
262.0733032	0.20
263.7954102	0.04
265.0187378	0.49
267.2948303	0.06
269.2136536	0.37
275.1076050	0.02
281.2921448	0.05
283.1739197	0.15
286.8924255	0.13
293.2673645	0.08
295.1696777	0.62
301.3798523	0.05
309.0961914	0.85
309.7344055	0.05
311.2485962	1.20
311.8758850	0.05
313.0450439	0.91
315.1127625	0.15
325.0640869	0.18
327.1481934	0.70
329.2489014	5.78
330.9447632	0.07
337.3235779	0.17
339.3740845	0.05
343.7476807	0.02
353.2312012	1.49
355.3194580	0.47
357.2834473	0.36
368.8013916	0.09
371.1372681	0.77
373.3164673	1.47
375.0294800	0.34
377.3721313	0.06
382.8373413	0.14
383.4615479	0.14
385.4705200	0.06
394.8275757	0.04
397.3417358	0.83
399.2496948	0.03
401.2221069	0.55
403.3676758	0.07
415.3540649	0.73
417.1973877	1.40
419.2580566	0.65
422.5148315	0.13
431.0838623	0.12
433.1742554	0.51
434.9564819	0.44
441.2689819	0.54
443.3787842	0.18
445.3554077	0.54
459.5595703	0.05
460.9238892	0.53
463.2376099	0.91
474.4802856	0.05
476.7232666	0.15
477.3609619	4.48
479.0844727	0.42
487.2178955	0.12
489.1083374	0.53
502.9447021	0.22
504.9490356	0.22
507.2575684	0.18
511.2425537	0.03
514.3772583	0.08
520.4912720	0.34
521.1853638	2.42
523.1672363	1.75
533.0599365	0.03
549.1915894	1.14
551.3341675	0.55
563.2797241	0.06
565.2832642	0.18
567.1907349	1.15
583.1974487	0.34
584.4957886	0.04
593.3146362	0.30
595.2669067	0.61
606.8444214	0.12
609.3516846	0.38
611.2224121	1.54
611.8787842	0.19
615.2360229	0.07
627.3864136	0.43
636.9280396	0.80
637.5553589	0.50
639.3265991	5.59
640.8646851	0.08
643.9863892	0.06
652.9995728	0.51
653.6392212	0.25
655.3392944	3.17
671.3646851	0.34
681.5094604	0.29
696.9863892	1.14
699.3121948	2.52
715.1492310	0.97
724.8696899	0.67
725.4714966	0.21
741.1704102	1.60
743.2449951	47.12
744.0280151	0.06
749.7896118	0.16
759.1859741	0.94
762.4512329	0.09
801.3446045	0.05
802.7053223	0.28
803.4915771	1.52
804.8740234	0.03
818.0294189	0.07
829.1955566	1.51
847.3488159	100.00
863.8837891	0.04
865.9719849	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	199.99
Annotation	Unknow
Peak:m/z	Relative Intensity
68.8571014	0.15
74.0447159	0.27
82.5811615	0.08
84.1467285	0.16
85.9063492	0.43
94.0063629	0.28
96.9410706	0.08
98.7286987	0.08
99.8703613	0.11
107.7482147	0.34
111.9228668	0.13
113.9827118	0.10
115.1872559	0.27
121.9750519	0.09
124.8842621	0.13
125.9835510	0.24
129.0435028	0.09
138.1488953	0.21
140.3327789	0.27
153.9278717	0.44
155.9811554	0.22
158.9409637	100.00
160.1323395	0.06
164.7254028	0.20
170.0641174	0.13
171.8908539	0.20
176.2678375	0.41
176.9271698	1.47
181.0782013	0.07
182.0298309	1.66
199.0650787	0.05
200.0061035	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	300.03
Annotation	Unknow
Peak:m/z	Relative Intensity
91.9165268	0.02
123.9423981	0.06
135.0553284	0.05
136.7949219	0.05
148.0831299	0.03
151.0090942	0.37
162.1821289	0.10
163.0650635	0.33
179.1250763	0.11
184.9636993	0.06
188.1494293	0.08
189.9222565	0.02
191.3012085	0.11
192.0601807	0.10
199.0595703	0.04
200.1265259	0.27
200.8379822	0.03
203.2984924	0.14
203.9930725	0.09
211.0824280	0.03
216.2032776	0.07
226.0875549	0.71
227.0905762	1.36
228.1562500	0.67
229.2696228	0.05
230.3017273	0.12
232.3434143	0.09
243.1766052	2.25
244.1568909	0.36
245.2307434	0.05
246.3907776	0.02
254.1255798	7.99
255.1622314	51.75
256.1373291	0.52
257.3457642	0.03
271.0745850	100.00
272.1058960	7.21
273.2066345	0.02
281.1470032	0.06
281.9909058	0.13
283.2038574	0.05
300.2096558	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	299.0773
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
92.9407883	0.88
101.0519333	0.12
128.7711334	0.26
132.3474426	0.07
136.9333191	100.00
160.9240112	0.33
176.9244232	0.03
212.8671265	0.03
226.9751282	0.12
253.0601807	0.21
255.0981445	0.08
281.1785889	0.05
284.3909912	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	534.1735
Annotation	Unknow
Peak:m/z	Relative Intensity
191.2188263	0.40
232.0437622	0.19
270.3279419	0.33
294.1939087	0.47
306.1019287	0.47
307.6853027	0.15
308.3121948	0.53
309.1390381	0.66
345.3374023	0.22
349.9356079	0.35
352.2048950	0.05
357.4980469	0.73
369.1552124	9.17
370.2194824	0.18
371.4579468	0.19
381.4343872	0.29
387.0477905	5.80
401.3511963	0.46
404.7636719	0.13
422.6736450	1.27
423.2858276	0.15
440.5396118	0.51
441.2499390	1.73
444.3099976	0.16
466.9561768	0.22
486.2749023	4.68
488.0285034	0.10
498.1641846	23.56
498.7651978	0.38
516.1037598	100.00
516.7539673	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.1717
Annotation	Spinosin
Peak:m/z	Relative Intensity
267.4313965	0.06
333.2619324	0.03
335.1699524	0.05
349.4191895	0.03
356.2108154	0.59
371.3007202	0.37
373.1473389	0.03
388.1354980	4.24
389.1904907	0.29
397.1374512	0.04
399.1729736	0.12
403.2117920	100.00
419.0349121	0.16
429.4067993	0.14
430.3022461	0.19
443.2287598	0.03
445.2360229	0.11
461.0625000	0.05
469.5823364	0.15
479.5127563	0.05
483.5637207	0.06
490.9620361	0.27
494.7047119	0.04
524.3748169	0.09
532.6920776	0.07
557.5470581	0.05
565.4872437	0.15
574.1338501	0.04
578.7618408	0.21
591.8747559	0.36
592.5953369	0.07
593.5708008	0.15
606.9863892	0.26
609.1696167	0.24
610.5079346	0.03
615.4823608	0.09
616.5209961	0.07
617.4613037	0.07
619.6127319	0.08
622.6098022	0.22
623.3852539	0.04
634.4151611	1.80
635.4802856	0.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	603.3017
Annotation	Unknow
Peak:m/z	Relative Intensity
207.1503143	0.14
229.3588562	0.05
251.1853790	0.03
272.2049561	0.31
285.5094299	0.13
305.0082397	0.21
306.2101440	0.23
307.1663208	0.23
308.1881104	0.32
309.1932373	3.15
317.2729492	0.16
325.3430786	0.06
335.4122925	0.15
361.1298828	0.11
367.3134766	0.12
377.2017822	0.04
395.0736694	0.08
399.2160034	0.17
405.4552002	0.04
415.2262573	0.09
421.0415039	0.09
422.1598511	0.55
423.3148804	0.46
441.1149292	0.85
442.3749390	0.11
443.0800781	0.07
457.1616211	0.10
464.7263794	0.06
478.1368408	0.06
481.3764648	1.25
489.5354614	0.22
497.4425049	0.47
499.2892456	16.35
499.9224243	0.06
504.6978760	0.21
507.3991089	0.06
510.2448120	0.15
513.1076050	0.12
515.5147095	0.10
516.6062622	0.39
517.2813110	0.71
522.6696777	0.43
523.6567993	0.08
528.2422485	0.11
531.6114502	0.14
535.5335083	0.09
540.4816284	0.47
541.2534180	0.81
557.2543945	0.89
559.2368774	100.00
559.9253540	0.30
565.2471924	0.08
568.5453491	0.32
572.4565430	0.10
576.1497803	0.15
583.2686157	0.09
584.5305786	0.55
585.3259888	1.98
600.8311157	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	927.1815
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
271.1338501	0.34
283.1504517	0.07
300.2094421	4.21
301.1510620	6.61
423.3342285	0.10
463.1902466	100.00
464.3302612	0.40
561.3681030	0.08
591.2318726	0.04
719.1495972	0.05
765.4351196	0.10
775.1726685	0.04
780.2091064	0.10
795.5000610	0.17
881.3351440	0.03
883.2293701	0.04
895.6632690	0.17
909.5604248	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.11
Annotation	Herbacetin 8,4'-dixyloside
Peak:m/z	Relative Intensity
158.8863373	0.05
160.9987183	0.02
173.2296753	0.02
175.1511536	0.02
178.4728699	0.09
179.0927277	0.21
187.0715942	0.17
191.0165863	0.37
201.3131409	0.03
203.2199097	0.01
205.0420685	1.86
207.1333923	0.04
216.0857086	0.06
219.1464844	0.20
223.0695343	15.40
229.1287842	0.15
234.3439636	0.04
238.3616943	0.03
241.4437256	0.02
247.1724701	0.25
259.1194458	0.03
273.1662598	0.27
288.2409668	0.02
291.2465210	0.46
293.3510742	0.05
299.1689453	0.05
301.0145874	0.04
305.2218018	0.03
307.2675476	0.92
322.9575195	0.04
331.2291870	0.03
337.1943970	0.76
341.1416016	0.35
349.3260498	5.55
363.2231445	0.08
366.0015259	0.09
367.1721802	3.33
371.0947266	0.15
383.5981445	0.21
385.0936279	100.00
397.4722290	0.24
398.2338257	0.10
409.3591309	0.26
414.9493408	0.25
415.6751099	0.14
425.4785767	0.04
427.1879883	0.74
438.9646606	0.25
446.1490479	0.06
449.2384033	0.09
451.2794189	0.09
455.3912354	0.04
457.0357666	0.18
467.6854858	0.02
470.3057861	0.06
472.2455444	0.05
473.8579102	0.03
479.1786499	0.05
489.9360962	0.06
496.8110352	0.02
500.2846069	0.25
501.8278198	0.18
503.2537231	0.32
505.3892822	0.10
508.4497681	0.04
509.1892090	0.09
510.3067627	0.31
511.2699585	0.17
526.1915894	0.03
527.1239624	0.05
528.8981323	1.76
529.6674805	0.22
530.4530640	0.03
532.4131470	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.09
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0974426	0.11
224.1806183	0.17
225.3383179	0.16
253.0542603	0.16
343.0160522	0.06
386.0909424	0.15
387.3507080	0.26
389.1824951	0.28
417.3470459	0.05
418.4268799	0.31
419.5762329	0.13
465.4521484	0.31
500.0772095	0.09
505.2036133	9.37
506.4122314	14.41
507.2140503	100.00
507.8358154	0.13
509.6074219	0.06
532.7684937	0.26
533.6499634	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	527.235
Annotation	Unknow
Peak:m/z	Relative Intensity
163.1647034	0.22
187.1901245	0.24
191.1351776	0.32
192.1081238	0.24
203.1558533	0.40
206.0661469	2.11
207.0950012	0.56
214.3116608	0.09
221.0756073	5.51
229.2529297	0.15
261.2764282	0.05
277.3027954	0.05
287.8549805	0.10
293.1816101	0.68
301.3688660	0.21
303.2749023	0.15
305.1603394	0.94
311.0720215	0.28
319.4019775	0.51
321.3733521	1.33
322.4512329	0.10
333.0773926	0.08
347.1608887	0.63
351.1995239	0.21
362.3299561	0.52
365.2504883	0.16
369.2348022	0.49
379.2114258	0.23
383.1996460	0.09
393.4623413	0.29
394.2946167	1.10
395.4479980	0.14
397.3083496	0.09
407.3798828	0.29
411.1385498	0.37
417.3759766	0.10
420.8273315	0.21
429.0636597	0.12
431.3853149	0.24
435.0374756	0.38
441.3731079	0.57
446.4413452	0.23
447.1964111	0.84
464.4816895	0.12
469.2744751	0.06
481.3674927	100.00
482.3860474	0.19
483.4815674	10.84
491.3477173	0.57
492.5482788	0.13
495.3477783	0.08
506.8569336	0.14
509.2452393	0.91
517.8401489	0.31
518.6109009	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1094.4421
Annotation	Unknow
Peak:m/z	Relative Intensity
311.3185425	0.83
314.1218262	0.75
322.2472534	0.26
329.4229736	0.63
340.0970764	0.38
345.2962036	0.32
350.9055176	0.73
359.2640686	1.62
361.1577759	0.47
363.3042908	0.44
381.0829163	0.21
393.3652039	0.12
402.4173889	0.37
403.2711792	0.47
409.1733398	0.42
416.2661743	0.31
425.4971008	0.39
444.4093018	1.23
446.8686218	0.92
460.2960205	0.14
461.2746582	0.09
462.1502686	0.51
472.2479248	1.04
484.3212891	0.50
495.4023438	0.24
497.3722534	1.49
498.1668091	0.54
501.3476562	0.63
506.0001831	0.19
511.5581970	0.56
513.5735474	0.60
515.1356201	0.65
519.7142334	1.27
528.0313110	1.59
531.4210815	0.14
544.5562744	0.45
556.1850586	0.25
557.1590576	0.31
558.4257812	0.93
566.7091064	0.34
568.4761963	0.22
574.5603027	0.43
590.4768066	0.64
593.3796387	0.46
594.8093262	1.05
611.0257568	1.18
628.5884399	0.58
629.8057861	0.61
636.3463135	0.28
637.6981201	0.29
646.7097778	0.14
670.6042480	0.16
685.2872314	0.20
686.6253662	0.49
697.4950562	0.07
724.7502441	0.52
726.6395874	0.29
742.0666504	1.26
742.7968140	0.56
743.4147949	0.61
759.3651733	0.76
774.4019775	0.09
784.1069946	0.15
786.3809814	0.17
787.3533936	0.48
798.3963013	0.23
802.2977295	0.90
803.6445312	0.41
837.5177002	0.72
849.2832031	0.22
854.9173584	0.14
860.7448730	1.62
865.4548340	0.83
867.8393555	1.49
871.2086182	0.53
871.8760986	1.68
877.4862061	1.46
897.5070801	0.44
898.6350098	0.49
899.3095703	1.66
900.5185547	0.93
907.1234131	1.27
910.3337402	1.08
924.5174561	0.89
927.2576904	1.27
938.7730713	1.97
941.0338135	0.28
942.6409912	2.09
947.6047363	0.31
948.5551758	1.42
960.2485352	0.33
962.2243652	1.52
964.9857178	1.69
966.4625244	1.97
967.4042969	2.77
969.2376709	1.99
969.8437500	3.12
970.6622314	1.92
971.4652100	3.23
973.1365967	1.92
975.2229004	4.88
976.2557373	1.73
977.1083984	1.20
978.1724854	1.62
979.6168213	5.00
981.4049072	2.45
982.2735596	3.40
983.4392090	0.30
984.6550293	5.46
985.9841309	1.55
987.9467773	5.85
989.2268066	0.61
990.1711426	4.84
991.6330566	1.48
993.1704102	1.40
994.0111084	4.40
995.0441895	2.46
996.0085449	5.75
997.3902588	2.96
998.2143555	1.26
999.0539551	5.35
999.9721680	6.51
1000.9665530	1.47
1002.3344730	2.25
1002.9453120	2.92
1004.7333980	2.15
1005.8830570	1.98
1006.7800290	0.24
1007.8072510	13.31
1008.6379390	2.32
1009.2836910	2.26
1010.9970700	0.64
1012.0407710	5.69
1013.0803220	4.26
1013.9440920	9.17
1014.6866460	0.79
1015.8520510	6.58
1016.5058590	3.68
1017.8629150	3.98
1018.7250980	7.45
1019.7420650	5.88
1020.7457280	4.35
1021.6978760	7.51
1022.7576900	3.24
1023.5786130	5.01
1024.4943850	7.73
1025.5493160	3.25
1026.4104000	6.35
1027.0274660	10.47
1027.9392090	9.28
1028.7087400	5.34
1031.4897460	3.51
1032.7890620	14.67
1033.6845700	13.10
1035.0034180	3.52
1035.8188480	2.16
1036.6329350	1.06
1037.5694580	0.90
1038.8762210	4.30
1040.0375980	5.94
1041.2432860	4.28
1041.9038090	2.43
1042.8967290	9.79
1043.7390140	4.53
1044.6269530	8.65
1045.5972900	12.16
1047.0928960	17.82
1048.2590330	4.52
1049.1846920	0.98
1050.2379150	16.62
1051.4285890	14.72
1052.4522710	12.38
1053.7465820	17.23
1054.6158450	6.82
1055.5423580	13.96
1056.6370850	44.19
1057.7254640	4.00
1058.4812010	4.41
1059.5324710	43.18
1060.3521730	14.44
1061.5360110	18.48
1062.4580080	78.10
1063.4477540	5.22
1064.4515380	12.23
1065.5363770	31.52
1066.3344730	9.83
1067.8857420	27.63
1068.7010500	13.50
1069.6193850	8.88
1070.2940670	1.96
1071.1716310	3.26
1071.8791500	6.73
1073.2253420	16.43
1073.8527830	48.69
1074.6657710	53.68
1075.5408940	8.39
1076.9211430	27.13
1077.8857420	46.92
1078.5971680	0.82
1079.6236570	9.65
1080.3176270	25.82
1081.0812990	7.04
1081.9060060	2.30
1082.7600100	12.19
1083.4631350	100.00
1084.3504640	3.01
1085.0521240	3.61
1086.4882810	0.75
1087.6339110	0.96
1091.1285400	0.28
1108.4826660	0.80
1119.3387450	1.67
1120.5673830	1.94
1138.7354740	1.01
1140.3706050	0.48
1148.4291990	1.07
1154.5600590	0.10
1161.9935300	4.18
1162.7706300	1.44
1168.2111820	1.08
1170.6302490	2.77
1177.5078120	1.30
1178.9011230	1.62
1181.2819820	0.43
1182.7631840	0.58
1183.7429200	0.67
1185.8275150	2.07
1189.1263430	0.34
1196.0972900	0.83
1202.7384030	0.39
1208.1905520	0.25
1210.7314450	0.35
1216.2211910	0.61
1220.8897710	1.48
1223.5664060	0.67
1224.9627690	1.41
1225.8095700	0.86
1227.7436520	3.10
1232.7409670	3.36
1233.4190670	2.58
1234.8503420	0.43
1236.7469480	0.48
1237.8955080	0.09
1238.5932620	2.46
1239.8031010	0.69
1241.1523440	13.92
1241.9995120	1.79
1242.8448490	3.98
1244.4729000	1.59
1248.6906740	2.47
1254.0498050	0.64
1255.4409180	3.21
1258.5303960	1.03
1262.1343990	3.55
1262.9899900	7.94
1268.9658200	2.82
1275.4660640	3.88
1276.8847660	0.65
1278.8862300	1.03
1280.6696780	0.26
1282.5935060	1.09
1283.7883300	0.32
1284.6929930	1.15
1286.5463870	0.43
1289.8742680	0.31
1290.7283940	2.36
1291.9066160	1.23
1295.1199950	0.12
1297.5889890	0.77
1298.6706540	0.11
1299.5598140	0.48
1301.4936520	2.33
1305.2678220	1.90
1306.2148440	2.59
1307.0585940	2.76
1307.8708500	1.94
1308.9810790	0.73
1309.7795410	1.43
1311.5448000	1.94
1312.7062990	1.65
1314.6514890	0.32
1319.1168210	12.62
1319.8380130	4.62
1320.6252440	4.65
1322.0834960	1.74
1323.9995120	1.36
1325.0666500	1.95
1325.8461910	0.25
1329.2797850	1.59
1330.2572020	0.62
1334.1405030	2.23
1338.7869870	0.53
1341.6578370	4.71
1342.9647220	2.81
1343.6556400	1.64
1346.6650390	3.56
1347.7613530	1.58
1348.4173580	2.19
1349.3959960	2.46
1350.3568120	1.50
1353.3167720	0.79
1355.4149170	9.58
1356.1765140	5.04
1356.8399660	1.15
1358.4620360	0.33
1360.0579830	2.54
1361.7885740	4.98
1363.5445560	11.56
1364.4777830	2.10
1365.4449460	1.95
1367.3615720	1.59
1370.0509030	0.87
1371.8321530	0.97
1373.8594970	2.22
1374.5886230	0.37
1375.7059330	2.61
1377.1595460	2.72
1379.6004640	1.31
1381.0684810	3.11
1382.4537350	4.44
1383.3380130	2.66
1384.0443120	1.98
1384.7653810	9.47
1385.5513920	9.84
1387.3038330	2.04
1388.6705320	4.10
1389.6145020	1.78
1390.7271730	0.92
1391.7031250	6.04
1392.8961180	3.25
1393.6701660	0.91
1395.2800290	0.98
1398.1732180	5.15
1399.2526860	2.92
1402.2612300	5.36
1403.4295650	4.44
1404.1702880	4.25
1404.7927250	2.19
1406.3765870	5.26
1407.3793950	3.92
1408.2305910	1.16
1410.1271970	2.78
1411.2775880	6.48
1412.1448970	14.79
1412.9854740	14.10
1413.9128420	5.36
1415.1070560	1.05
1417.4422610	3.12
1420.2955320	9.37
1421.3541260	8.81
1422.0344240	2.12
1424.9991460	3.23
1425.7807620	0.75
1426.5577390	0.37
1427.5869140	0.74
1428.3059080	0.55
1430.0770260	2.08
1431.1214600	0.19
1432.6945800	2.81
1433.3537600	3.49
1434.5230710	1.16
1436.0916750	0.33
1436.8348390	0.30
1439.1617430	1.31
1440.0366210	2.03
1440.7149660	0.23
1442.4719240	8.06
1443.5106200	1.97
1444.2926030	1.21
1446.0909420	5.90
1447.0229490	0.57
1447.9251710	1.43
1449.7808840	3.15
1450.6851810	0.85
1452.0989990	2.43
1453.5988770	4.41
1454.7757570	4.27
1458.4348140	1.74
1459.7117920	1.86
1460.3663330	1.69
1461.8045650	6.90
1462.7974850	19.32
1463.7170410	5.40
1464.4235840	0.71
1466.6582030	1.40
1467.3179930	2.74
1468.9293210	1.39
1470.4912110	9.83
1471.3188480	8.59
1471.9644780	1.99
1472.9742430	0.52
1473.8146970	1.42
1474.9693600	2.92
1476.1119380	0.73
1477.0728760	0.52
1478.2188720	20.03
1479.4631350	4.12
1480.4984130	1.05
1481.1234130	0.58
1482.2655030	1.52
1483.0858150	2.30
1483.8323970	0.95
1484.9938960	2.88
1486.1488040	4.63
1488.2227780	1.64
1489.7409670	6.30
1490.8739010	2.37
1496.0885010	5.16
1497.1762700	2.63
1498.2308350	19.18
1498.8905030	11.01
1499.8861080	5.87
1501.2342530	1.82
1501.9217530	1.35
1505.9356690	5.14
1506.8137210	0.56
1509.5187990	2.30
1510.5089110	0.75
1511.1827390	2.12
1513.0343020	1.39
1514.5496830	1.78
1516.4750980	1.79
1517.2138670	0.35
1518.1928710	3.53
1519.7304690	10.03
1520.5704350	3.69
1521.6030270	1.78
1522.6513670	0.61
1525.9548340	0.51
1528.0469970	8.73
1528.8647460	9.92
1530.4949950	8.82
1531.5693360	3.42
1532.6646730	3.23
1534.6221920	2.73
1535.9460450	3.05
1536.7725830	0.52
1539.7437740	8.84
1540.9458010	13.98
1542.2467040	1.66
1543.1741940	0.87
1544.8184810	0.56
1548.5145260	7.77
1549.1322020	7.54
1549.8238530	6.73
1550.9061280	1.05
1552.9680180	0.25
1554.8759770	0.74
1559.2034910	1.37
1559.8848880	1.34
1561.0675050	2.46
1562.3618160	0.61
1564.5770260	1.25
1567.4379880	1.05
1568.1645510	0.92
1568.9122310	2.40
1569.7803960	2.31
1574.8552250	0.14
1575.4703370	1.56
1576.1004640	0.25
1577.4997560	3.64
1578.5941160	4.75
1582.0113530	2.44
1583.1074220	1.10
1583.9569090	2.38
1584.9381100	0.97
1585.7010500	3.80
1586.4444580	1.86
1589.8621830	0.29
1592.1658940	9.35
1592.8218990	5.48
1593.6437990	6.71
1596.5067140	0.44
1597.5128170	0.52
1606.3543700	1.37
1609.8802490	1.43
1612.2485350	0.72
1624.7102050	0.35
1661.4312740	0.54
1673.8629150	0.61
1711.8962400	0.74
1724.5682370	0.47
1734.9910890	0.20
1742.6765140	1.16
1745.8400880	1.12
1779.6237790	0.52
1809.1107180	0.29
1836.7171630	0.53
1881.1105960	0.25
1919.9989010	0.26
1929.3900150	0.48
1957.9754640	0.41
1958.9562990	0.37
1969.6613770	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	869.8905
Annotation	Unknow
Peak:m/z	Relative Intensity
253.1379700	0.30
257.2763672	0.30
268.3049316	0.48
311.1193237	0.56
325.2390137	0.42
345.1742249	0.42
355.2020569	0.27
369.0168762	0.70
392.2590942	3.05
424.3320923	0.34
468.3728638	0.10
505.4865723	0.21
506.3477783	0.50
523.1216431	1.09
574.2463379	0.32
583.3994751	0.58
592.2150879	0.36
593.6437378	0.17
619.5531616	0.28
624.4521484	0.59
636.9605713	0.36
675.4492188	0.26
691.1240234	0.21
708.2348022	0.06
727.2583008	1.06
731.6443481	0.46
737.1930542	0.76
738.1331177	0.13
744.8913574	1.19
755.4768677	0.41
764.8907471	1.35
768.9415894	0.09
772.8186035	0.93
778.2307739	0.47
782.4881592	1.06
784.2909546	0.75
785.7565918	1.48
790.6337280	1.03
796.4874268	1.71
799.1774292	3.13
800.0335083	6.58
804.4378052	0.14
806.3727417	2.55
807.4107666	4.82
808.2625122	0.49
811.0769653	1.55
813.1194458	0.36
816.9465332	6.71
817.6812134	3.55
820.3883057	3.78
821.4500122	2.45
823.5508423	5.95
824.6079102	19.94
825.3704224	6.75
826.1116333	0.62
827.9111938	26.20
828.6677856	7.16
829.4762573	2.52
831.0820312	2.56
832.1705933	0.09
832.8927612	1.89
833.9335327	0.99
834.8547974	4.14
835.7186890	2.11
837.7234497	2.17
838.6220093	2.65
839.2728882	2.49
842.1501465	60.32
843.0878296	13.21
844.3018188	3.13
845.2481689	6.70
845.8742676	100.00
847.1726685	2.15
848.1840210	13.67
848.9392700	5.79
850.1589966	4.11
850.9338989	0.20
852.5720215	16.37
853.3916626	10.85
854.2189331	7.15
855.1257935	7.47
855.9006958	3.02
856.5553589	0.27
857.4697876	1.24
858.1582031	0.38
859.2655029	13.60
860.0367432	3.81
861.0304565	1.36
863.3192749	0.41
865.7340698	0.66
897.8413086	0.87
899.0372314	0.15
909.2089233	3.91
910.3410645	1.08
914.0925903	0.33
923.5803223	0.62
953.9169922	0.42
954.6962891	1.02
959.2957153	0.37
963.4653320	6.95
972.8532715	0.49
976.9775391	1.38
978.9187012	0.49
979.7163086	0.32
987.8064575	0.41
990.0803223	0.69
991.9773560	6.62
992.7985840	1.44
994.7758179	1.73
999.3137817	0.67
1000.5700680	1.40
1002.8694460	0.79
1004.5502930	2.58
1005.2871090	1.10
1006.9771120	1.73
1015.1362300	0.80
1017.8056030	1.71
1019.0354000	0.35
1020.0553590	1.41
1021.9955440	1.82
1022.6068730	0.06
1024.6557620	2.97
1025.7010500	0.74
1027.0876460	1.19
1028.0775150	1.79
1028.7009280	0.14
1029.5991210	7.46
1030.5327150	5.84
1031.4584960	0.68
1033.5378420	1.74
1034.3222660	0.94
1035.6433110	1.50
1037.5284420	8.23
1038.2907710	4.57
1038.8967290	1.25
1039.7761230	0.36
1041.3071290	0.17
1042.2521970	8.90
1043.2304690	3.32
1044.4282230	1.62
1045.8687740	3.13
1048.9488530	0.17
1051.2072750	0.91
1052.7861330	0.49
1054.0090330	0.57
1054.7104490	0.67
1055.5782470	1.07
1056.2785640	0.86
1057.5626220	1.93
1059.8989260	2.51
1060.7233890	3.37
1061.4904790	6.74
1062.5758060	2.76
1063.9459230	0.73
1065.1684570	2.59
1066.1403810	16.39
1067.2155760	1.86
1067.9681400	1.11
1069.4515380	7.76
1070.2054440	0.46
1070.9033200	2.07
1072.0571290	4.86
1072.9831540	4.89
1073.7934570	3.63
1074.6870120	7.52
1075.6668700	1.55
1077.4350590	2.78
1078.6876220	12.38
1079.4451900	4.70
1080.1042480	0.23
1081.2984620	0.55
1082.1242680	1.56
1082.9753420	0.60
1084.2692870	0.32
1085.3535160	0.48
1086.0587160	0.39
1087.7451170	0.75
1089.2270510	3.55
1090.3675540	5.88
1091.0904540	0.71
1092.0046390	0.97
1093.1000980	4.27
1094.0347900	6.26
1094.7476810	5.80
1095.8708500	2.19
1097.6341550	2.00
1098.5701900	15.89
1099.2436520	40.39
1100.0468750	9.39
1100.9272460	8.17
1101.6187740	0.79
1103.5848390	38.16
1104.6013180	5.58
1105.6285400	1.24
1106.5792240	3.53
1107.6876220	1.19
1108.5349120	0.39
1111.1295170	0.70
1112.2766110	0.45
1113.9501950	0.16
1114.8753660	1.19
1116.2952880	2.96
1117.0386960	1.21
1117.6914060	3.20
1118.3049320	0.49
1119.3941650	2.56
1122.3410640	87.37
1123.3591310	38.50
1124.4873050	1.33
1127.1877440	88.78
1127.9492190	49.02
1128.8120120	10.70
1130.1323240	5.78
1130.9521480	1.00
1131.6706540	2.49
1132.5076900	0.37
1134.7700200	0.31
1136.4272460	7.14
1137.2390140	5.72
1137.9909670	0.56
1140.3039550	1.49
1141.6188960	0.15
1145.0788570	0.48
1184.6671140	0.47
1186.6304930	1.80
1188.9765620	0.48
1201.3103030	0.47
1202.2932130	0.16
1213.8137210	0.20
1215.8999020	0.11
1218.9785160	0.12
1221.9482420	0.61
1227.3648680	0.42
1233.2170410	1.28
1235.2490230	0.72
1236.4599610	0.74
1238.2722170	0.34
1239.6127930	0.88
1269.5931400	0.23
1270.7827150	0.48
1279.9385990	0.73
1283.7507320	0.91
1288.7406010	0.50
1292.5206300	0.55
1298.2719730	0.38
1300.4862060	0.12
1305.9251710	2.33
1317.3043210	0.81
1319.0783690	0.61
1327.3120120	0.39
1327.9500730	0.82
1328.6141360	0.26
1332.0915530	1.15
1337.3940430	0.55
1341.2935790	0.13
1342.4295650	0.43
1346.2633060	0.96
1358.9675290	0.44
1362.5281980	0.98
1388.3001710	0.30
1388.9132080	0.81
1392.8586430	0.26
1395.6676030	0.58
1402.1910400	0.74
1406.7550050	0.86
1407.7827150	0.54
1419.1192630	0.34
1420.6585690	0.16
1423.7509770	0.60
1428.2078860	0.13
1430.3536380	1.81
1437.9301760	3.96
1439.5059810	1.13
1442.3435060	0.55
1452.3753660	1.18
1453.6035160	1.49
1461.0749510	0.22
1472.9056400	0.72
1478.2969970	0.49
1488.5554200	1.51
1489.2727050	0.65
1493.9943850	1.14
1494.7719730	0.58
1513.3267820	0.62
1514.2457280	0.20
1522.3714600	0.56
1525.7873540	1.66
1528.4726560	0.24
1530.1337890	0.25
1532.6131590	0.58
1533.8055420	0.36
1537.1767580	1.50
1539.1552730	0.21
1541.3765870	0.66
1547.4937740	0.50
1550.5563960	0.44
1552.8444820	0.25
1556.6879880	0.62
1557.8465580	0.60
1564.4454350	0.42
1565.8791500	0.76
1568.2563480	0.28
1587.6580810	0.13
1595.8087160	1.24
1597.8873290	0.71
1598.9698490	0.48
1602.2790530	0.65
1624.8034670	0.13
1652.3485110	0.32
1690.0367430	0.12
1756.3817140	0.24
1780.4128420	0.06
1842.5274660	0.13
1846.9854740	0.10
1856.8829350	0.16
1888.1722410	0.09
1944.0266110	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.27
Annotation	Unknow
Peak:m/z	Relative Intensity
166.9757233	0.23
178.9335022	2.41
182.0382690	0.13
187.1490479	0.37
195.1878662	0.80
199.0393524	0.74
201.1073608	0.27
204.9074707	0.58
209.0745850	0.43
211.2233887	0.27
212.1721802	0.41
219.2323761	0.14
220.8983459	1.20
227.1290588	0.24
229.1698608	1.42
239.0731354	0.67
240.0563354	0.16
241.3478699	0.32
241.9691162	0.18
243.1125488	0.27
252.9190369	0.31
255.0681152	18.48
256.1305542	1.99
257.1221924	11.71
258.2616577	0.48
265.2346191	0.93
267.0023193	0.23
279.2570496	0.24
281.2990112	0.82
282.1430664	0.49
283.9934082	100.00
285.1631470	95.67
286.1891479	5.08
295.3086548	0.20
296.2944336	0.51
297.1215820	0.19
298.1644287	0.58
306.2131958	0.17
308.4262695	0.31
309.1787109	3.94
310.1276855	0.57
310.9976501	0.21
313.3395081	0.24
314.9214172	0.54
321.0062256	0.18
323.1732788	0.08
325.3449707	0.71
326.1773682	0.74
327.2450562	11.75
327.9443970	0.32
329.1875000	0.19
333.1601562	0.81
334.1380615	0.30
337.3055420	0.40
339.1936035	6.36
349.1076660	0.73
351.1813965	1.32
353.1311646	1.52
355.2556763	0.47
357.3134155	20.54
365.0788574	0.54
367.3957520	0.43
369.3745117	1.59
375.3635254	0.29
381.2261353	1.25
385.2496338	0.29
387.1864014	0.13
393.2944336	4.84
394.3446045	0.23
397.1997070	0.47
399.1259766	0.21
401.2593994	0.45
402.9265747	0.14
411.2833252	3.25
415.0878906	0.43
417.2947998	3.98
418.2641602	0.31
423.0150146	0.62
429.1687012	89.52
430.2675781	5.13
431.3047485	2.98
433.3322144	0.23
446.2587891	1.88
447.1417236	25.80
448.3359375	2.09
459.2938232	5.44
460.3244019	0.98
478.4880371	1.32
489.3643799	0.96
491.2490234	0.70
501.2848511	0.15
511.2318726	0.39
515.3488159	0.44
516.4650879	0.45
517.4562378	1.37
518.3037109	0.11
519.4007568	12.18
529.4071655	0.26
533.2848511	0.62
535.2608643	0.74
543.4727173	1.62
544.2880859	0.81
549.6106567	0.12
551.2196655	0.30
558.0976562	0.15
561.3405151	10.93
562.4243774	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.182
Annotation	Geniposide pentaacetate
Peak:m/z	Relative Intensity
177.0617371	0.12
178.9248352	0.11
190.8722229	0.04
211.8218994	0.10
214.3199158	0.06
215.1202240	0.12
219.1532288	0.20
223.1481476	0.08
227.1422424	11.91
229.1184387	0.02
230.8771362	0.10
247.2669220	0.25
248.2580566	0.05
259.0693359	0.08
261.3532410	0.04
262.5000000	0.14
269.2305298	0.11
273.3854370	0.04
284.4654541	0.25
285.1172485	0.17
290.8952637	0.34
293.2199097	0.06
303.5590210	0.07
305.1969910	0.50
306.3183594	0.06
313.1706543	0.11
323.1040649	0.24
328.3120117	0.06
345.4738770	0.15
353.0250854	0.05
354.6544189	0.17
355.3335571	0.35
359.1054688	0.30
371.3556519	0.48
383.7324219	0.07
389.1684570	100.00
389.7824707	0.67
392.7617798	0.04
397.3026123	0.09
399.5834961	0.12
409.2758789	0.19
410.6775513	0.27
411.2778931	2.04
415.0559692	0.07
417.0513916	0.23
422.6120605	0.08
423.2345581	1.53
427.2972412	0.02
429.0789185	1.66
430.9942017	0.22
433.1755371	0.08
434.2919922	0.11
435.2221680	0.09
451.3067627	0.04
453.6422729	0.06
465.1094360	0.46
465.7302246	0.12
471.3926392	0.57
473.3394165	0.16
489.0171509	0.04
491.0949707	0.47
495.3316650	0.28
496.1125488	0.27
499.1919556	0.20
501.4104614	0.11
505.4213257	0.33
507.1421509	0.23
509.4155884	0.16
510.2249756	0.05
511.4065552	0.05
515.2210083	0.04
517.4437256	0.04
524.3145142	0.03
533.0797119	0.13
535.2009888	1.17
549.0088501	0.10
550.9857788	96.98
551.7932739	0.55
553.1920166	0.26
561.0756226	0.63
562.9376831	0.49
564.2374878	0.05
576.5643311	0.13
579.1522217	1.93
579.9406738	0.09
586.1841431	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.3281
Annotation	Unknow
Peak:m/z	Relative Intensity
181.9601593	0.05
213.0740509	0.04
221.3108521	0.24
227.4165649	0.15
229.3135529	0.14
230.4341736	0.02
249.1437683	0.08
263.2590332	0.02
267.5030518	0.03
269.1436157	0.21
278.9401855	0.01
289.4457397	0.03
292.3028564	0.09
297.5632324	0.11
299.3230286	0.13
303.6486816	0.06
305.1309204	0.05
316.7434082	0.14
321.2729492	0.06
323.9415283	0.11
324.5585327	0.04
335.4445801	0.15
365.3859863	0.02
377.6902466	0.15
387.4650269	0.50
389.3199463	32.40
390.4071655	6.79
395.4519653	0.01
405.3997803	0.04
406.0407715	0.02
413.4512939	0.70
414.5490112	0.15
419.4907837	0.03
431.4664307	2.53
432.4240112	0.58
445.5892334	0.11
447.0959473	0.04
449.4431152	4.85
450.4738159	1.52
453.6687012	0.03
455.3500977	0.10
456.5711670	0.15
466.2911987	0.06
473.3703613	0.02
478.4747925	0.06
483.3165894	0.12
485.6068115	0.03
492.2069092	0.09
513.1802368	0.09
515.2406616	0.18
516.3073120	0.21
526.4126587	0.02
533.4799194	1.83
534.6571655	0.13
539.3100586	0.05
544.3633423	0.03
549.4452515	0.58
550.4299927	0.75
551.3975220	38.92
552.4491577	10.53
565.3715210	0.01
568.6267700	0.05
573.8567505	0.06
575.4045410	4.34
576.4428101	1.69
577.3490601	0.06
582.5065918	0.03
583.2941895	0.02
593.4427490	100.00
594.4365845	32.89
612.3956909	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.0919
Annotation	Unknow
Peak:m/z	Relative Intensity
167.2559357	0.03
184.9555359	0.05
192.3169250	0.01
200.9784546	0.03
219.2480164	0.03
226.6371765	0.03
230.0297852	0.07
237.1610107	0.03
239.1159515	0.01
245.1129761	0.02
249.1266785	0.03
255.2913208	0.05
256.3935547	0.01
257.3255615	0.01
266.2961121	0.02
271.1255798	0.03
272.4054565	0.16
273.0686646	0.03
286.3717651	0.01
287.2985229	0.07
293.2213745	0.06
298.8388672	0.02
300.1835327	0.25
301.2577820	0.60
302.2310181	0.17
305.0872192	0.07
305.9702759	0.04
325.2916870	0.10
327.3835449	0.01
332.2232056	0.78
333.0589600	0.13
345.0559082	0.04
347.1175537	25.30
348.3062744	0.02
357.4111328	0.02
359.3027954	0.27
363.2172852	0.01
372.3622437	0.03
373.3953857	0.02
375.3455811	0.18
385.2106934	0.03
387.4298706	0.09
388.9946289	0.09
390.7003174	0.04
393.1312256	0.22
399.2947998	0.08
403.1302490	0.78
407.5073242	0.02
409.2782593	0.01
411.2442627	0.25
412.9635620	0.05
416.3203735	0.05
417.4694214	0.26
418.3856201	0.05
419.2987061	0.04
423.1437988	0.11
424.0419312	0.02
425.3369751	0.06
429.2807617	0.18
431.3182373	0.05
432.6264648	0.04
433.4354858	0.01
435.0615234	100.00
435.6796265	0.40
445.1800537	0.12
446.1036377	0.19
446.9910889	0.06
449.1231079	0.38
450.2163086	0.07
451.2689819	0.22
452.0000610	0.37
463.7512817	0.13
464.4536743	0.09
465.3906860	0.21
471.1498413	0.12
473.1627808	0.01
475.5120850	0.05
477.2118530	6.06
481.2798462	0.03
487.6198730	0.01
489.1768188	0.98
491.3034058	0.06
492.5107422	0.01
494.9675293	0.10
501.9133301	0.02
506.8641357	0.38
509.1787109	4.78
510.1879883	0.19
511.4916382	0.04
515.3820190	0.01
517.1478271	0.07
519.1318970	0.09
521.3089600	0.04
527.0830078	0.01
533.4237671	0.01
534.2558594	0.04
535.1982422	0.04
537.0313110	1.36
537.6854858	0.04
543.1406860	0.14
546.7376099	0.08
547.3490601	0.04
550.2506104	0.44
551.3760986	0.10
552.3949585	0.01
553.2188110	0.07
555.2557983	0.06
558.7821655	0.03
560.8906860	0.04
561.5916138	0.03
562.7754517	0.01
565.1996460	0.44
567.5199585	0.06
575.2285767	0.03
577.7088013	0.06
578.3733521	1.02
579.3668213	1.19
587.8888550	0.02
597.3320923	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1686
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
92.90853882	0.39
96.79191589	0.12
99.01823425	0.08
119.0854416	0.36
142.9685211	0.12
147.7597198	0.14
155.8095093	0.23
169.933136	8.82
170.9936066	0.63
181.135437	0.09
183.006546	100.00
184.0022583	12.46
185.1739349	0.75
186.0285797	0.19
196.9960785	36.32
198.1029358	12.50
198.9885254	1.33
201.2733307	0.07
211.0201721	9.46
212.1181335	4.14
217.2307739	0.26
224.0411682	0.27
225.1013184	5.47
226.1732788	3.87
227.0163879	0.79
228.1123047	0.05
239.2197876	4.99
240.1599426	2.92
241.2417908	1.15
245.48703	0.33
246.6243896	0.68
247.3434448	12.91
248.3167419	3.12
249.3557739	0.96
251.1358337	0.62
253.1444702	1.74
254.0163879	0.96
255.1798401	0.11
259.2929077	0.31
264.0812683	0.08
265.2342529	0.53
267.2736816	2.53
268.1425781	0.37
269.1508179	0.41
270.9750977	0.26
275.1560669	0.33
281.3074646	0.55
283.3049316	0.08
291.0862732	0.20
293.12323	6.00
294.171936	0.05
296.2842712	0.62
304.3106079	0.04
310.6867371	2.35
311.3668823	19.46
312.364502	2.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	499.3134
Annotation	Unknow
Peak:m/z	Relative Intensity
191.0364990	0.32
194.2795105	0.26
198.0340881	0.17
209.1614685	0.27
210.1882019	0.15
219.9725037	0.07
225.4294128	0.20
229.4940643	0.05
233.1492004	0.03
235.0997009	0.07
251.6152954	0.50
264.9981689	0.16
267.2749939	0.09
278.5314941	0.07
279.5592346	0.31
287.0200806	0.07
295.5157166	0.54
309.1075745	0.13
313.1848755	0.16
321.2515259	0.05
325.2099609	0.09
326.7729492	0.21
327.5935669	0.04
329.0902100	0.10
333.5474854	0.13
339.0403442	0.05
349.6386719	0.23
371.7934570	0.35
373.4613647	0.07
374.4463196	0.04
385.7625122	0.37
386.9523621	1.33
389.6842957	0.05
392.5110779	0.18
393.4982300	0.23
397.0654602	0.04
399.8543396	0.10
401.2903748	0.13
405.2355347	0.06
408.1022339	0.08
409.6268616	0.09
413.0812073	0.16
415.7157898	0.26
417.0039978	0.19
427.3871765	0.08
430.0282288	0.23
433.1607361	0.11
438.6755981	33.46
439.7471619	0.85
440.7005920	0.68
441.6141663	0.05
442.4526672	0.40
443.8682861	0.27
446.0421448	0.12
447.0934143	0.18
449.5485840	0.25
453.4590759	0.21
455.1767273	0.11
456.0511169	0.18
457.3326721	0.09
458.0401001	0.51
459.0268555	0.07
462.5992737	0.28
467.5256653	0.08
468.5236511	0.13
476.2347107	0.04
480.0328064	0.28
480.7210999	0.16
481.4070129	1.92
482.3942566	0.49
484.7902527	0.03
486.4702759	0.12
490.6558228	1.15
491.9340515	0.03
520.2854004	0.69
564.3223267	0.70
608.0234985	0.33
700.7823486	0.08
716.4821167	0.11
755.2148438	0.06
760.5994263	0.22
772.4509277	4.88
773.2991333	0.10
787.8306274	0.22
804.4437866	0.23
859.5521851	0.87
876.4599609	100.00
877.5964966	1.45
892.6171265	0.07
957.9776001	0.09
959.0336304	0.07
980.4526367	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	488.162
Annotation	4-O-Methyl-a-D-glucosyl-(1->2)-b-D-xylosyl-(1->4)-D-xylose
Peak:m/z	Relative Intensity
143.1187286	1.62
143.9307098	0.21
144.9515686	43.01
146.0238953	100.00
160.9460297	4.94
175.2020264	0.23
178.9669800	9.31
180.0193787	0.88
221.0381775	1.85
232.7023926	0.18
244.4268188	0.11
250.6882019	2.63
252.1805420	0.12
259.3912048	0.27
262.2363281	0.33
281.0312195	2.10
282.0081482	0.13
308.0923462	0.13
310.4309387	0.67
311.2634277	0.53
312.1396484	0.37
323.2197876	0.40
324.5261841	0.19
341.1574097	74.41
342.1210327	8.83
355.0922852	0.21
425.4027710	0.58
452.0756226	0.27
470.3340454	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	744.4496
Annotation	Pentandroside A
Peak:m/z	Relative Intensity
217.8764801	0.03
219.0790405	0.74
220.8998566	0.34
223.0659332	0.06
225.1392822	0.57
225.9698334	0.11
233.0827942	0.05
235.3224030	0.40
235.9729614	0.06
237.1078186	0.19
240.4695587	0.09
245.1599274	0.07
246.4934235	0.13
249.4496460	0.07
252.9655457	0.22
254.9605713	0.57
256.0338135	0.08
261.2010498	0.22
262.8939514	0.16
264.6220093	0.34
265.2550659	1.36
266.1878662	0.33
267.1671448	0.11
269.2091064	3.46
270.2077942	0.37
277.3959351	0.21
279.2518005	0.70
280.1515503	0.02
281.0746460	0.07
283.3754272	0.24
294.2072754	0.13
295.2107544	0.94
295.9282837	0.06
297.2149658	0.62
299.2450256	0.60
305.3392334	0.13
306.4887085	0.16
307.1901245	0.35
309.0975342	2.45
310.4657593	0.52
311.2142639	0.54
313.0606079	3.38
314.1560669	0.66
323.1472778	0.78
324.2619629	0.05
326.3286743	0.04
328.4085693	0.15
337.2541504	0.10
339.7550049	0.10
341.0252380	0.44
343.1625977	0.18
344.1182861	0.06
349.3828735	0.08
353.0405884	2.11
353.9020996	0.55
355.4429016	0.40
356.9998779	1.80
358.0846558	0.19
359.2279053	0.17
365.2928467	0.27
367.1982422	0.38
368.7369995	0.19
370.1655273	0.14
371.4633179	0.05
377.1719360	0.09
383.1729126	0.95
387.0046997	0.20
393.0209961	0.05
397.1228638	0.92
398.2164917	0.56
401.0134277	1.54
401.8909302	0.50
402.5012817	0.46
403.1422729	1.13
404.2176514	0.09
411.2984009	0.09
419.2919922	0.08
427.2089844	0.21
427.9392090	0.05
429.2078857	0.19
431.3037720	0.03
441.3940430	0.84
442.4163208	0.11
444.8684692	1.37
445.5795898	0.61
446.6027832	0.21
447.2947388	1.09
455.2925415	0.06
459.5554810	0.11
463.2986450	1.17
464.1317139	0.16
473.0447388	0.05
475.2522583	0.02
482.4984131	0.14
485.2931519	0.93
486.3615723	0.22
488.9852905	1.18
491.2943726	1.29
507.1932373	0.78
508.1749878	0.22
517.0758667	0.20
529.5069580	0.38
530.3197632	0.06
533.0982666	0.38
533.7943115	0.02
534.4222412	0.07
535.4688110	0.63
536.3084717	0.26
551.1675415	0.51
552.2375488	0.25
577.0844116	1.19
578.4537354	0.12
579.2793579	0.36
580.4166870	0.18
594.7470093	0.17
595.5074463	1.01
596.2462769	0.19
600.5021973	0.14
606.2003174	0.04
619.2576904	0.11
621.1284790	1.41
622.2640381	0.18
623.4651489	1.30
624.3352051	0.22
639.3916626	3.12
640.4030762	1.40
664.6274414	0.06
665.6649170	0.46
666.3815308	0.10
683.2875366	3.95
684.1923218	0.79
708.8829956	0.37
709.5026855	0.19
710.3561401	0.32
727.2758179	100.00
728.3024292	32.27
728.9684448	0.48
745.9008179	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	513.3207
Annotation	Unknow
Peak:m/z	Relative Intensity
149.3265991	0.04
164.8691559	0.11
174.8517303	0.25
176.9689789	0.59
178.0483246	0.05
181.0583954	0.05
185.4298553	0.10
191.1241302	0.20
192.2801819	0.05
193.0394745	0.16
195.1074066	0.42
196.0495300	0.03
197.2556763	0.04
207.4740601	1.43
208.1680603	0.24
211.9673004	0.13
218.9942474	0.04
221.0255127	1.61
223.0938110	0.45
224.2034302	0.13
225.0586853	0.08
226.2543335	0.02
227.0930328	0.15
229.5236206	1.22
230.1562042	0.42
235.2937927	0.05
237.9934387	0.10
239.1502380	0.18
240.0948181	0.04
243.2228088	0.74
245.6284332	0.09
249.2658844	0.03
250.4443665	0.08
251.5217590	1.46
252.1533051	0.67
253.2879791	0.08
254.9673767	0.17
255.9520416	0.02
265.1614990	0.56
265.8925171	0.08
267.8145142	0.08
269.1462402	1.87
270.2058716	0.58
273.5704346	4.94
274.3231201	0.13
275.8943481	0.67
276.9530334	0.09
279.3537292	0.09
280.2092285	0.03
282.2727661	0.05
283.4903870	0.07
286.7429810	0.41
287.8814697	0.06
289.6644287	0.31
295.6222534	3.52
297.5137939	1.98
298.4235840	0.18
299.0277710	0.10
309.2497559	0.47
310.0638428	0.05
311.7617798	0.34
313.0098877	1.57
314.0687256	0.21
317.5773926	3.94
318.2918701	0.35
319.7059937	3.15
320.7973022	0.20
323.0661621	0.29
324.1760864	0.06
326.1818848	0.03
331.0444336	0.09
333.7521973	0.52
339.4154663	1.30
340.0986938	0.16
341.7135010	3.61
345.1656494	0.08
348.2556152	0.54
349.1953735	0.12
353.3276978	0.42
355.4235840	0.52
356.2241211	0.18
357.1399536	0.36
359.2178345	0.06
361.5841064	0.98
362.2955933	0.14
363.5670166	3.59
364.2077026	0.77
365.1282349	0.04
367.1923218	0.14
376.2810059	0.02
378.2094116	0.23
381.0207520	0.08
383.7085571	0.53
385.5667114	0.80
386.3253174	0.29
388.0945435	0.11
392.2922363	0.60
393.0179443	0.06
395.0697021	0.11
397.4638062	0.08
400.3060303	0.08
401.1536255	0.15
402.2973022	0.14
405.6606445	0.71
407.0129395	0.37
407.6929932	2.41
408.7427979	0.08
409.3923340	0.11
416.4597778	0.03
419.6086426	0.04
424.3910522	0.04
429.7344971	1.37
430.7084351	0.12
431.3646851	0.17
436.4141846	0.21
437.3594360	0.04
439.1265259	0.36
443.8566895	0.88
444.8450317	1.00
448.5512085	0.06
450.6831055	0.13
451.6669922	1.24
452.8847046	100.00
453.9550781	1.81
455.1486816	0.47
456.4569702	0.18
457.1207886	0.13
458.0329590	0.27
459.0541382	0.07
459.8109741	0.42
460.6690063	1.20
461.3389282	1.19
463.7183228	0.05
465.7893677	0.73
466.5977173	0.02
473.6322632	0.62
474.3833618	0.12
476.3416138	0.69
477.3531494	0.07
480.2432861	0.05
482.8800049	2.70
483.6712646	0.01
485.1134033	0.22
489.1765137	0.21
490.1696167	0.04
491.4285278	0.36
495.4594727	0.74
496.1188965	2.82
496.7658081	1.40
497.9582520	0.03
499.1946411	0.21
502.6213989	0.14
503.3236694	0.30
504.8167725	78.83
506.1777954	1.51
507.0128784	0.49
507.6336060	0.14
508.5001221	0.19
509.2803345	0.07
510.7805176	0.30
511.8468018	0.42
516.2432861	0.04
517.1977539	0.04
520.3709106	0.73
521.5244751	0.08
529.3387451	0.07
532.7441406	0.38
533.6878052	0.40
534.3312378	0.04
547.3751831	0.05
548.3779297	0.04
553.3685913	0.03
564.3394165	2.09
565.4092407	0.79
571.1458130	0.10
573.2315063	0.12
574.0382080	0.12
576.3928223	0.10
578.0871582	0.22
579.0834961	0.09
583.4364014	0.20
591.2698975	0.27
593.4576416	0.03
596.6369019	0.10
608.3330078	1.79
609.3994751	0.50
612.0000000	0.06
615.0848999	0.07
617.4994507	0.09
618.1369019	0.08
622.2797852	0.06
623.6548462	0.14
624.3718872	0.06
635.5678101	0.29
640.6049194	0.05
650.3627930	0.04
652.5238647	2.64
653.5698242	0.65
656.5998535	0.38
657.5017700	0.03
661.6322632	0.02
664.8820190	0.04
679.7505493	0.10
680.5958252	0.14
682.6364136	0.02
684.3780518	0.20
696.4229126	2.48
697.4024658	0.46
700.4075317	0.46
701.5418091	0.20
704.0390625	0.07
705.0278931	0.06
709.5879517	0.07
710.6417847	0.08
711.3619385	0.08
723.2684326	0.19
724.2655640	0.05
727.2066040	0.06
740.4164429	1.06
741.5106812	0.31
744.4703979	1.38
745.5443115	0.96
754.4371948	0.18
755.5271606	0.05
771.2689819	0.03
772.6404419	0.17
784.1223755	0.17
788.4213257	2.56
789.5184937	1.12
797.4047241	0.07
798.6149292	0.07
816.2756958	0.19
817.3276978	0.04
832.4321289	0.97
833.4621582	0.61
842.5618286	0.02
859.7699585	0.06
860.4714355	0.02
876.6423950	0.72
877.5685425	0.67
886.8579102	0.13
887.5825806	0.31
888.5380859	0.03
904.4931030	19.15
905.4900513	11.30
906.1279907	0.07
986.5612793	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	468.0238
Annotation	Unknow
Peak:m/z	Relative Intensity
136.1295624	0.23
173.1950684	0.05
201.0631714	0.11
221.2658997	0.03
222.0877380	0.10
226.0087585	0.04
259.0390930	0.30
260.1265259	0.06
261.0334167	0.68
262.1444397	0.70
277.0773621	0.36
278.9366455	9.34
279.7231750	0.37
288.1841125	0.21
293.0621338	0.11
294.1715393	0.18
294.9790955	0.05
299.3137817	0.03
302.6368713	0.13
303.2704163	0.03
305.0028076	0.14
306.4184570	0.19
319.7408752	0.24
320.9184875	34.43
327.2792358	0.14
333.3959351	0.09
334.2190552	0.25
335.4098511	0.06
339.1400146	0.29
340.3591309	0.06
345.4746094	0.02
346.8984375	0.06
359.9749756	0.08
362.0554199	0.62
364.1872559	0.18
384.2524109	0.17
389.2893372	0.05
396.1566467	0.11
399.1311646	0.25
404.4427185	0.06
406.0072937	100.00
407.3468628	0.92
408.0920105	3.20
408.9999084	57.76
421.2805786	0.18
422.6874695	0.28
423.9859924	6.03
424.9322815	0.27
427.1077271	0.09
428.5843811	0.21
431.1966858	0.03
431.9155273	0.13
433.1406250	0.09
434.2556763	0.09
436.2716370	0.28
438.2450562	0.06
440.1235046	0.47
446.6222534	0.31
448.7499084	0.13
449.5837402	1.58
450.1977539	3.03
458.4563904	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	644.9601
Annotation	Unknow
Peak:m/z	Relative Intensity
202.2060547	0.09
247.1500092	0.03
275.3256531	0.03
279.3002930	0.07
288.0383911	0.04
303.4028931	0.04
311.3622437	2.61
312.4016113	0.46
315.2410278	0.10
316.3012695	0.05
325.5845337	0.20
364.5327148	0.11
389.2011719	0.30
390.2171631	0.11
399.0339966	0.12
413.5432129	0.05
420.4343262	0.05
507.4028931	0.10
515.2041016	0.08
548.1867065	0.11
556.6490479	0.05
560.4646606	0.08
570.5516357	0.13
572.8106079	0.05
581.1271973	100.00
583.4165039	0.17
585.4369507	0.19
587.7444458	0.29
598.0839233	1.23
598.8499146	0.33
600.6524048	0.70
601.9051514	0.05
603.1986694	0.04
607.9314575	0.14
609.6631470	0.19
622.1341553	0.12
626.8219604	0.40
627.7145386	0.10
628.7767334	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	402.3572
Annotation	Unknow
Peak:m/z	Relative Intensity
119.0763397	0.18
141.0183105	0.07
151.6588745	0.16
159.0849457	0.06
167.3652649	0.26
174.4291077	0.15
175.2653809	0.12
179.3965454	0.09
188.2317657	0.34
189.0993195	0.21
191.0912323	0.06
194.1633759	0.26
197.1442871	0.11
199.1675568	0.06
215.9058228	0.31
221.0927734	0.10
234.8934631	0.36
240.2284851	0.07
241.3672791	0.08
244.9849548	0.10
247.1363220	0.15
253.2177734	0.08
258.2822876	0.24
259.0087280	0.12
266.4609680	0.07
271.2589722	0.08
272.2573853	0.04
279.1710815	0.41
282.0294189	0.05
283.3104553	100.00
283.9390869	0.74
289.3642578	0.16
295.3587036	0.22
297.5912476	0.10
298.3734436	0.04
304.0176697	0.30
308.4455566	0.14
311.3450928	0.11
312.1002197	0.09
312.8291016	0.40
325.2893066	0.15
335.6065063	0.05
339.3285217	0.24
340.1613770	0.18
341.3560181	0.32
342.1435547	0.12
345.4431458	0.17
349.2092285	0.10
352.4126892	0.22
353.4437256	0.13
357.3702087	0.17
358.2935486	0.29
363.4969482	0.77
366.2187805	0.23
367.1019592	0.62
370.4564819	0.07
371.4310608	0.10
373.8190002	0.12
375.4796448	0.08
384.4887085	1.69
385.1752625	2.10
402.0588379	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	437.1219
Annotation	Benzyl beta-primeveroside
Peak:m/z	Relative Intensity
194.9769592	0.67
227.2170105	0.15
241.1108704	0.06
257.0742798	0.26
268.2518921	0.07
268.9732666	0.08
275.2847290	0.30
302.1749268	0.11
305.3134155	0.25
306.9323425	0.08
315.4160156	0.08
316.2220154	0.10
317.9202881	0.14
323.3161011	0.15
339.2351685	0.17
349.0484314	0.07
369.0312195	0.32
375.3304138	0.14
377.4575500	0.10
390.5638123	0.65
391.2513733	1.55
393.2383728	0.12
401.1966858	100.00
402.0982666	0.07
418.1954041	0.17
419.2383118	0.38
420.1970825	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	199.99
Annotation	Unknow
Peak:m/z	Relative Intensity
57.8616066	0.31
68.7068024	0.16
70.8039474	0.20
73.0440216	0.04
82.0595703	0.08
83.0021668	0.17
83.8446808	0.07
93.8896790	0.08
95.9862976	0.07
96.8908386	0.34
98.1759796	0.05
106.7845764	0.18
107.9934235	0.25
112.1627197	0.14
113.0530090	0.06
114.0416718	0.19
115.7933502	0.08
121.0168762	0.32
123.9734039	0.06
125.8768921	0.12
127.1666565	0.06
136.1298065	0.14
143.4180603	0.09
153.8124847	0.06
158.8450165	100.00
163.0149078	0.06
164.1014862	0.24
165.1594849	0.11
172.1614227	0.10
176.7972565	1.44
180.9755707	0.17
182.0882111	0.88
182.8957977	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.2915
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
160.9680481	0.06
172.9424896	0.03
189.1386414	0.05
198.0607300	0.05
216.1215668	0.06
227.1921387	0.03
235.2776184	0.01
239.0373688	0.08
245.3389893	0.11
263.3692627	0.04
266.5507812	0.08
276.1068726	0.02
281.4669495	0.07
306.2953186	0.47
319.5269470	0.03
337.3055420	100.00
337.9314270	0.28
347.5491333	0.08
380.6098022	0.03
390.1841125	0.07
391.0641174	0.02
397.3983765	0.03
403.3846130	0.03
417.0012207	0.30
418.3911133	0.03
435.3865967	0.15
445.3592529	0.07
447.1926575	0.02
448.1340637	0.02
455.3542175	0.07
460.2595520	6.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2871
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
144.9155121	1.76
165.0829773	3.44
169.1534424	2.33
171.1206055	6.10
173.0605774	5.39
181.0500793	15.18
187.0083313	5.89
199.0063019	1.76
207.2286682	1.76
217.2479553	2.56
223.1705627	15.63
229.3148499	2.62
231.0618896	3.33
237.3613892	2.76
240.0369873	4.97
244.0252991	4.47
245.0037842	5.57
253.6604919	6.29
261.2674561	3.56
271.7333679	4.28
273.1167603	3.76
277.3804932	4.25
279.2826843	9.75
281.1873779	20.59
286.5232239	4.85
287.2610168	1.49
289.3932495	7.91
293.1890259	5.31
294.9120483	6.55
304.0475159	1.62
314.2202759	10.01
315.0089111	1.62
317.0434265	4.25
328.6190186	6.38
336.2810059	2.84
338.0847168	3.97
339.2205811	7.11
341.0921631	16.26
341.9867554	3.90
346.2473145	10.42
352.0513306	3.99
355.3684387	8.98
356.9060059	9.24
361.2289734	2.14
366.6704407	5.97
375.1420288	2.44
377.3517151	24.97
380.1138916	18.44
381.1287842	8.66
390.3094788	26.09
391.2572021	10.97
392.0802917	3.62
394.2951965	6.81
398.2442627	1.62
407.6169739	40.40
408.2830811	100.00
409.3770142	16.98
410.1482849	8.13
414.1563416	5.10
417.3581848	3.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.13
Annotation	Peltatoside
Peak:m/z	Relative Intensity
177.0936584	0.10
178.9603577	4.84
183.4805908	0.09
185.085907	0.26
187.3018036	0.10
191.0123596	0.66
192.2148438	0.43
192.9834747	0.65
208.9529724	0.18
211.2014008	0.49
213.1854248	0.17
215.1305084	0.26
216.1663818	0.12
216.9247437	0.12
219.1259003	0.21
221.0197296	0.08
224.7780762	0.10
226.0652161	0.21
227.0958405	0.27
229.2058563	0.86
230.129425	0.24
231.1646118	0.08
237.1006927	0.17
239.1226807	0.34
242.2250366	0.32
243.1620483	0.33
245.3070984	0.19
247.180542	0.30
253.9736023	0.55
255.0357666	7.68
256.1581421	0.16
257.1616516	0.55
263.4161072	0.05
271.0977478	9.63
272.0527344	1.09
273.1608582	2.34
281.427124	0.34
282.2342834	0.08
283.1990356	0.69
285.1652832	0.20
289.1584473	0.34
293.3518677	0.34
297.0919189	0.45
300.0276184	100.00
301.0572815	44.06
302.0042114	0.20
303.081543	0.23
311.0978394	0.32
313.1807251	0.25
316.152771	0.11
319.1433716	0.16
323.0528564	0.28
325.0922852	2.59
327.182312	0.62
329.1489258	0.20
336.055481	0.33
337.0101929	0.69
339.1306152	0.39
340.6065063	0.09
341.206665	0.15
342.2462158	0.16
343.1274414	5.00
347.4291382	0.08
348.8121948	0.06
353.3005371	0.54
355.0621948	1.46
357.1967163	0.16
358.8440552	0.08
363.649292	0.07
365.4784546	0.06
367.0790405	1.63
369.3024292	0.42
370.3721313	0.19
371.5291138	0.06
373.2488403	1.31
376.9476929	0.04
377.7889404	0.08
381.130127	0.92
383.2192993	0.10
385.2935791	0.21
389.0886841	0.12
391.2416992	0.07
397.2231445	0.98
399.2980957	0.09
400.4606323	0.22
401.1687622	0.14
402.47229	0.17
403.3891602	0.42
407.2205811	0.25
408.6932373	0.21
409.3797607	1.09
414.3113403	0.08
415.4341431	0.25
417.2402954	0.18
419.237915	0.07
425.9812012	0.23
427.3745117	1.89
431.37323	0.09
432.3583374	0.88
433.2693481	9.40
443.1312256	0.08
445.2512207	18.70
451.4892578	0.28
457.4105225	0.07
459.1536865	0.25
460.312439	0.36
461.2408447	0.06
463.1953735	19.47
464.9328613	0.14
467.2109985	0.25
468.9766235	0.70
475.1711426	11.74
478.3153687	0.06
479.2975464	0.24
485.4393921	0.30
486.2788696	0.15
487.4956665	0.21
489.4179688	0.28
494.3812866	0.12
499.1012573	0.07
503.588562	1.21
505.387207	0.39
509.3853149	0.32
512.0065308	0.16
515.1942749	0.22
516.8673706	0.05
521.607605	1.42
522.5223389	0.06
533.4069824	0.11
534.9135132	0.23
548.3430176	0.23
548.9679565	0.99
550.6390991	0.19
551.3178101	0.96
553.5430298	0.12
557.2826538	0.17
558.2752686	0.33
559.1765137	0.66
563.34552	0.12
565.3084717	0.10
576.3064575	0.83
577.3259277	3.13
578.1669312	0.05
580.2692261	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.1092
Annotation	Herbacetin 8,4'-dixyloside
Peak:m/z	Relative Intensity
154.6375885	0.04
157.2407074	0.07
161.6339569	0.08
163.2142639	0.04
173.1026917	0.17
174.9679871	0.01
179.0262604	0.42
180.2537842	0.02
187.1945343	0.07
189.1336975	0.05
191.0477142	0.21
191.9255676	0.03
192.9426117	0.01
201.3075409	0.03
203.1886902	0.06
205.1135254	2.29
205.9620819	0.07
207.2389221	0.01
210.9796143	0.03
217.1417542	0.05
219.0089417	0.11
219.9406281	0.02
223.1552124	18.34
224.1033173	1.58
228.7714844	0.06
238.1654968	0.04
247.2295074	0.42
265.0763550	0.03
271.4632568	0.04
273.1372070	0.07
273.9526367	0.09
275.4340820	0.02
280.0565186	0.02
291.1459351	0.28
292.1023254	0.01
297.0988159	0.05
301.1257324	0.25
302.2197876	0.28
305.5474243	0.01
307.1205444	0.05
309.2901001	0.07
323.3048706	0.17
324.0933838	0.02
335.0721436	0.18
336.0702515	0.08
337.1657104	0.05
338.3408203	0.05
341.0880127	0.64
342.2777100	0.01
343.1813354	0.02
345.1127930	0.05
349.2197876	1.88
350.2285156	0.13
353.0461426	0.24
367.0895386	3.17
368.0711060	0.13
371.3140869	0.05
372.4398193	0.15
385.1063232	100.00
386.1275635	11.81
386.7507935	0.02
387.6539307	0.08
398.4550171	0.07
400.1752319	0.05
415.3933716	0.15
433.1527710	0.03
451.3753662	0.02
461.5159302	0.05
465.1707764	0.03
467.2983398	0.02
471.6598511	0.03
487.3280029	0.04
488.2089233	0.07
501.2499390	0.33
502.4603271	0.14
504.2680054	0.06
505.2759399	0.03
511.3114624	0.31
518.0764771	0.03
525.2103271	0.06
528.9620972	1.69
530.1464233	0.18
531.4046021	0.09
532.9730835	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.09
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
143.1387329	0.05
150.9303589	0.79
152.6849365	0.01
161.2955780	0.06
162.9472656	0.07
178.9920502	1.09
186.7621155	0.04
189.0325317	0.06
189.9716492	0.09
190.9378357	0.05
192.0007324	0.05
193.0734863	0.09
197.3496552	0.02
198.2458496	0.07
200.9534912	0.05
207.0702515	0.04
209.0991974	0.02
217.0693817	0.09
219.1019592	0.05
221.1202087	0.08
225.9597473	0.06
229.0878296	0.23
232.3878174	0.02
239.1448364	0.02
242.3254089	0.04
243.0331421	0.02
245.0756836	0.03
246.0896606	0.02
246.9638672	0.04
253.0578613	0.03
254.1456299	0.04
255.1761169	0.43
257.0554504	0.02
264.9129333	0.01
269.1179199	0.03
269.8699341	0.02
271.1232300	0.47
273.0879211	0.25
275.2758484	0.09
281.2504578	0.05
283.0974731	0.12
287.0244141	0.05
295.0916138	0.05
297.1911316	0.06
299.4782104	1.06
300.1527405	22.18
301.0726318	100.00
302.0568848	0.20
311.1972046	0.03
313.3181458	0.05
315.1839294	0.02
319.1340332	0.08
325.1243286	0.26
327.3102417	0.04
329.2341919	0.01
331.2736816	0.04
337.3388672	0.19
343.0758057	1.88
353.1293945	0.04
355.1230774	0.04
359.4155579	0.07
373.2440186	0.27
381.1985168	0.09
395.1300964	0.06
401.1879883	0.04
419.5588074	0.02
445.0906677	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	681.1304
Annotation	Delphinidin 3-(6''-malonylsambubioside)
Peak:m/z	Relative Intensity
271.4287109	0.07
274.2062378	0.01
280.1905212	0.04
285.2683716	0.04
330.1588135	0.04
355.4119873	0.02
361.3594360	0.08
376.3858032	0.03
393.3605347	0.05
408.0679932	0.02
417.3463745	0.03
425.2308350	0.05
435.1804810	0.19
440.3118286	0.14
447.2825317	0.06
451.3314209	0.09
452.4105835	0.14
465.0943604	0.16
466.3588257	0.10
493.4327393	0.17
495.2523193	0.11
500.9508667	0.06
517.3286743	0.12
518.0394287	0.07
519.1159058	0.23
522.3272705	0.13
535.2865601	0.04
547.0664673	0.05
553.1367188	0.02
561.2411499	0.08
566.2675171	0.04
589.1976929	0.04
594.5503540	0.11
604.4749756	0.04
610.3013306	0.03
617.3960571	0.10
619.2761230	0.04
633.3429565	0.09
635.2021484	0.60
637.2104492	100.00
638.2275391	17.27
638.8380737	0.05
645.1405640	0.07
647.2815552	0.04
649.3318481	0.05
657.8965454	0.28
660.1040039	0.25
663.3880005	0.08
664.7036743	0.19
666.1819458	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.1121
Annotation	D-Fructofuranose 1,2':2,3'-dianhydride
Peak:m/z	Relative Intensity
96.9764557	0.38
98.7638855	0.04
102.9133453	0.02
108.8153992	0.16
112.9963226	0.06
114.6612930	0.01
126.9497681	2.38
129.9161530	0.06
133.3241425	0.04
139.2012787	0.02
144.8754578	5.42
147.1045837	0.25
148.8538208	0.07
153.0039520	0.02
157.0065918	0.05
162.8601227	8.86
165.0127716	0.30
169.2335815	0.03
172.7217407	0.03
178.9550629	0.03
180.9561310	0.06
187.1870422	0.04
191.0742493	0.05
192.5765381	1.35
193.3468933	0.01
194.5033264	0.13
198.9325867	0.64
204.9827576	0.46
207.0333557	0.08
210.9701233	0.90
212.1790771	0.13
213.0206604	0.24
216.8263855	2.03
219.0390320	0.13
222.4393005	0.97
223.1503601	1.13
224.9731140	0.22
229.0450134	0.81
235.1671448	0.50
240.1263428	0.14
240.9237366	0.98
242.4199524	0.16
243.0866089	0.14
247.1057434	3.33
252.9670410	6.86
255.2506104	0.08
257.8457642	2.01
258.7561646	14.47
259.4310303	0.15
261.0755615	0.52
263.0347900	0.07
268.1989441	2.92
269.2567749	0.50
270.9625854	23.63
271.7103577	0.13
276.7284546	0.05
277.3830566	0.05
284.2402954	0.10
285.1144409	0.09
286.3256531	0.52
288.1988525	12.27
288.8879395	100.00
289.5842590	0.06
299.7474976	0.04
307.0664673	6.32
315.4835815	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	302.84
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9404602	1.35
158.9571381	0.02
182.2994080	0.07
200.0728455	0.07
201.1307678	0.04
218.9146729	100.00
219.6343994	0.05
236.5927734	0.02
240.0572205	0.04
241.0536194	0.03
257.1815491	0.26
259.1289978	0.07
284.1643677	1.52
285.1070557	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	805.329
Annotation	Unknow
Peak:m/z	Relative Intensity
257.2421265	0.09
313.1441650	0.04
341.4682312	0.03
381.3045044	0.02
445.3680420	0.07
479.1572266	0.11
487.4230957	0.06
493.2590332	0.01
498.4215698	0.04
504.3698120	0.07
525.4720459	0.03
540.4923096	0.05
552.3139038	0.03
558.1128540	0.04
567.5939941	0.05
575.4346313	0.09
576.5532837	0.06
600.5794678	0.08
606.2918091	0.18
609.4522095	0.05
610.4860840	0.07
613.4238281	0.07
618.5460815	0.05
624.4341431	0.01
625.1986694	0.08
637.4404907	0.04
638.2727051	0.02
642.2570801	0.22
643.1027222	0.40
650.4848633	1.05
651.5050049	0.99
653.2087402	0.04
654.4484253	0.04
666.0579834	0.07
669.0693970	0.08
670.5856323	0.07
673.3062134	0.03
678.4220581	0.06
680.5535889	0.02
682.3960571	2.39
683.2948608	0.05
684.3440552	0.02
685.3351440	0.19
698.5313110	0.24
715.4650879	0.02
726.4005127	0.03
727.4828491	0.09
728.1007690	0.03
728.7021484	0.11
729.5624390	0.50
732.4067383	0.06
735.0588989	0.02
742.2568970	0.05
745.7539673	0.22
755.5011597	0.08
759.9417725	0.09
760.6919556	0.10
763.0106812	0.03
766.8187866	0.02
769.5148926	0.04
773.3842163	100.00
774.1006470	0.14
777.6710815	0.08
784.6663818	0.10
786.4465332	0.62
787.3328247	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	649.2305
Annotation	Unknow
Peak:m/z	Relative Intensity
220.9584198	0.09
246.1066742	0.03
251.1005402	0.04
263.1133423	0.03
281.0482178	0.07
292.2238770	0.01
323.1857910	0.19
340.9591675	0.82
379.2019653	0.01
383.3021851	0.05
385.1782837	0.01
399.4287109	0.01
413.3432007	0.03
424.5480347	0.05
443.0901489	0.52
447.1126709	0.03
457.4511719	0.07
487.4235229	0.10
503.2399292	100.00
503.8404541	0.25
587.8356934	0.04
589.4336548	0.15
631.2661133	0.03
632.2310181	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1248
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
160.8593140	0.12
172.9795532	1.58
179.0883789	1.75
179.9453430	0.02
191.0424500	16.37
192.0652924	0.71
193.3221893	0.04
203.2268372	0.04
204.2516632	0.03
207.2132721	0.25
209.2923584	0.14
221.2117157	0.08
229.2716370	0.12
247.2057953	0.04
261.0754700	0.05
274.9621582	0.02
275.6166992	0.03
291.1412659	0.43
309.1472168	2.25
310.3783569	0.30
324.1087036	0.07
335.0718384	3.38
336.2135620	0.24
337.1995239	2.02
345.1291504	0.19
353.0452881	24.14
354.1549072	1.50
357.1491699	0.08
363.2579956	0.10
367.0233765	0.89
368.2173462	0.03
369.5939331	0.07
381.0595093	13.37
382.1892700	1.26
385.1814575	0.32
387.2705688	0.15
390.1242065	0.01
396.4222412	0.04
397.2360229	0.12
399.1548462	100.00
400.1575928	7.97
415.4354858	0.02
439.4056396	0.08
465.4186401	0.09
466.5402832	0.05
481.1076660	0.08
483.1412964	0.14
497.5980835	0.06
499.2744751	0.06
500.3599854	0.12
501.3395996	0.08
515.2412720	0.87
516.3434448	0.14
517.4601440	0.19
524.0756836	0.06
525.3097534	0.06
541.3891602	0.05
542.9556274	7.17
544.0159912	0.81
544.6741333	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.0776
Annotation	O-Feruloylgalactarate
Peak:m/z	Relative Intensity
110.9500275	0.31
129.0334625	3.34
135.1632385	0.01
147.1223755	0.02
161.0367737	0.26
168.9128876	0.02
172.5867310	0.02
175.1782227	0.01
176.8809204	0.03
179.1992188	0.19
183.1205902	0.04
187.0075684	0.14
190.0576172	0.03
191.0893555	0.57
197.1910095	0.01
205.1071167	8.12
206.1268158	0.22
207.1970367	0.02
209.0617676	0.08
215.3946686	0.05
223.0122375	100.00
247.1109314	0.59
251.3095398	0.02
252.8182678	0.05
253.5367126	0.04
255.2074890	0.02
262.0174866	0.02
263.1828003	0.08
264.1898804	0.03
273.1454468	0.02
281.3312988	0.02
283.0827637	0.02
287.1330261	0.01
289.0761108	0.13
294.0899658	0.01
296.8607178	0.05
299.1577454	0.05
309.1443481	0.04
310.8401184	0.05
311.5324097	0.01
321.0126953	0.04
323.2312622	0.32
325.0625610	0.03
326.2701721	0.06
329.2040100	0.02
335.0126648	0.13
337.8888550	0.07
339.2793884	0.07
340.4650269	0.01
341.1910400	0.17
347.2121582	0.05
348.2695312	0.05
348.9864197	0.21
352.0817566	0.04
353.0506287	0.01
354.6481628	0.02
357.1020203	0.04
367.0380859	4.61
368.1059875	0.05
370.1106262	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	504.808
Annotation	Unknow
Peak:m/z	Relative Intensity
149.0492096	0.22
153.8391876	0.20
175.1021729	0.13
176.9589539	1.88
183.9972076	0.16
189.1760559	0.14
195.9471741	0.21
199.0799866	1.28
201.0949402	0.06
207.5117340	0.98
209.2626343	0.14
210.7349396	0.11
221.0021973	2.26
222.2534485	0.27
223.2432556	0.21
225.1992188	0.83
226.8587799	0.27
229.6254578	3.29
237.1310425	1.06
243.1005249	2.61
245.4614258	0.30
250.8282013	1.17
251.6597443	2.90
253.2703857	0.06
256.3828125	0.95
259.4451294	0.13
265.0435486	4.10
267.5132751	0.97
269.1755066	5.02
271.1292419	0.35
273.5882263	2.94
275.6567078	1.36
276.6886292	0.29
279.1796265	0.37
281.0266724	0.07
282.4717407	0.39
286.5263062	0.13
287.2308044	0.91
288.4132385	0.47
289.5747375	1.45
295.0157471	2.29
295.7748108	1.18
297.5545654	1.78
306.5979004	0.46
308.3952332	0.58
309.0302124	0.66
311.0025635	0.85
311.6652527	2.69
313.1659546	1.79
316.8774719	0.73
317.7415771	0.11
319.6012573	1.85
320.2745667	0.59
322.7291870	0.17
332.3295898	0.11
338.5225830	0.06
339.4914551	0.15
341.6333618	3.30
343.1229858	0.23
348.3234558	1.67
353.2387390	0.50
354.3049316	0.19
355.5859985	0.72
356.8550720	0.44
359.0482178	0.13
363.6906128	0.96
365.0818787	0.53
367.5088501	0.19
372.2932739	0.27
374.6556702	0.34
377.1281128	0.15
385.4113159	0.30
392.3251343	0.23
396.9794312	0.71
399.7252197	0.09
400.9668579	1.59
408.8670349	0.42
419.2519836	0.32
427.2788391	0.11
429.3809509	1.23
430.2203979	0.50
430.8666077	0.19
431.4933167	0.26
443.3134766	0.32
444.2919006	1.39
445.3769836	0.10
446.0447693	0.09
446.9716187	0.24
452.7084656	100.00
453.4490967	3.51
454.2948303	1.37
455.4746704	0.41
459.4038696	0.10
460.8912048	0.62
463.5210876	0.25
466.2436523	0.34
468.6532593	1.05
469.3610535	0.26
476.4958191	0.31
477.4827576	0.27
480.2705994	0.20
482.6319885	2.80
483.2482605	0.20
486.0199585	0.67
486.7252502	1.46
487.5041199	0.46
488.9309692	0.87
489.5672302	0.24
495.1095581	0.67
495.8945923	0.32
517.2179565	0.08
520.2505493	0.82
532.9672241	0.51
547.5912476	0.97
558.7997437	0.10
564.3422241	3.05
565.0094604	0.07
573.1434937	0.43
577.2799072	0.34
591.3530273	0.96
596.3833618	0.29
597.6041260	1.38
606.7005005	0.32
607.6334839	0.13
608.4387817	4.41
612.4067993	0.32
635.1427002	0.72
640.3827515	0.24
652.4343262	4.77
653.0991821	0.29
656.5147095	0.79
684.4060669	1.53
696.5200806	4.78
700.2277222	1.76
710.7352295	1.05
723.6564941	0.14
728.2548828	1.19
729.3432617	0.20
740.3634033	1.29
744.4113159	3.75
745.0142822	0.05
754.3593140	0.07
755.2750244	0.10
770.7113647	0.37
771.5536499	0.92
772.5678101	0.36
788.5092773	4.80
789.6704102	0.40
798.5609131	0.08
816.7439575	0.56
832.4804077	1.47
860.3529663	0.12
876.4387207	1.87
887.1666870	0.85
904.4938965	31.73
905.5546265	0.22
969.2712402	0.22
969.9985352	0.06
978.5822144	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	584.472
Annotation	Unknow
Peak:m/z	Relative Intensity
175.0258942	1.86
177.0128632	0.17
189.7342377	0.10
193.2084351	0.36
196.3355103	0.09
198.8573608	1.89
202.9750366	0.12
204.8451691	0.33
209.8758087	0.07
219.1542358	0.34
221.1015320	2.45
223.0958252	0.46
228.5580444	0.37
229.2882385	0.04
237.3012543	0.39
239.1994019	0.06
243.0692139	1.25
247.1256256	0.10
248.8711853	0.33
257.1732788	0.56
261.0661316	0.36
263.0432129	0.92
265.4395752	0.13
271.1477051	0.16
273.2551880	0.16
278.8918152	1.97
281.2316895	2.78
287.0895081	15.16
300.5864868	0.15
301.1895142	0.50
305.4144897	0.17
307.1017456	0.53
308.9602966	0.08
314.4353027	0.10
315.1693115	0.05
316.9598999	0.89
322.7535400	0.05
327.4738770	0.09
328.1094971	0.15
329.4212036	0.11
331.0552368	1.88
336.8975220	0.40
343.3541260	0.27
347.1597900	0.18
351.0320435	0.49
352.0854492	0.08
353.0517578	0.06
355.2444458	0.04
363.0064087	0.15
365.3651733	0.13
371.3032227	1.14
373.4668579	0.05
375.0428467	5.69
389.1361084	0.38
391.3606567	0.38
393.3863525	0.53
401.6228027	0.08
406.9368896	0.40
413.2731934	0.56
415.1950073	0.05
417.1511841	0.15
421.4072876	0.19
422.9334106	0.04
433.0544434	26.60
433.6973267	0.58
445.4383545	0.16
449.1549683	0.44
451.2154541	0.64
455.6095581	0.11
456.6069336	0.06
458.9685059	0.20
463.4331055	0.44
477.2656860	0.20
477.8829956	0.23
479.0383911	0.12
490.6427002	0.95
491.2614746	2.74
493.4519043	0.12
495.3450317	0.06
496.8470459	0.22
503.6969604	0.24
504.4588623	0.11
509.3486328	1.94
512.6832886	0.17
520.7704468	0.23
521.4455566	0.08
523.3270264	0.33
527.3838501	0.29
528.1527100	0.20
528.7620239	0.11
531.1536255	0.42
534.0925903	0.21
535.5762939	0.56
537.1974487	0.08
539.7958984	0.19
540.5618896	0.26
547.5309448	0.24
549.1771240	0.86
553.2409668	4.23
554.0346680	0.20
566.5996704	10.11
567.3598022	100.00
583.8468628	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.15
Annotation	Dinocton 6
Peak:m/z	Relative Intensity
109.9612885	0.01
112.2409134	0.03
114.0223083	0.02
116.9638596	0.10
119.3191833	0.02
121.2982330	0.05
130.0469055	0.26
131.0537109	0.06
132.0145874	1.05
133.0643921	0.10
134.0770874	0.02
141.8778229	0.02
142.9704895	0.07
145.2495422	0.09
147.1539917	0.06
149.0329285	0.05
158.8289490	0.06
161.0897369	0.06
162.1992798	0.07
166.0403137	0.03
169.1013794	0.05
169.9589691	0.01
176.1079865	7.63
179.9373169	0.35
181.2861176	0.01
182.2191010	0.04
185.1052551	0.30
186.1150818	0.04
187.2227936	0.05
191.2605591	0.06
192.9349518	2.07
197.1924438	0.03
198.3998108	0.08
199.2509766	0.05
200.0586243	0.08
201.4035034	0.02
202.4558868	0.03
209.1795502	0.06
211.1877441	0.02
214.1401062	0.20
214.9560852	0.10
216.2619019	0.12
218.4070129	0.02
219.0179138	0.03
221.0478516	0.10
224.2227173	0.08
232.2647705	0.49
233.1903076	0.12
235.4967041	0.04
237.1285706	0.02
245.2250061	0.02
246.1903992	0.01
247.2503662	0.06
251.3274231	0.06
252.2940979	0.49
253.2941589	0.27
254.3598328	0.02
255.2655640	0.11
256.3224182	0.03
257.1913757	0.01
258.4167480	0.25
259.3939514	0.04
262.1133118	0.03
264.2424316	0.65
265.2979126	0.30
270.2798462	2.36
271.5032654	0.70
272.1888123	0.07
273.3164062	0.04
274.0927429	0.03
276.3431396	0.72
277.2557068	0.15
280.1712341	0.08
282.2767029	3.29
283.2156982	0.67
284.0346680	0.08
288.1852112	0.25
297.1234131	0.03
300.2345581	10.83
301.3069763	3.59
313.9127808	0.28
318.2821045	16.99
319.3800964	5.10
326.1332397	0.04
330.2490845	0.14
334.3700867	0.05
336.2768860	100.00
337.2924805	26.21
338.1307983	0.49
340.2644043	0.02
END